1. Sanity Reboot.

# shutdown -y -g0 -i6

2. Please add the below entry in menu.lst
# vi /boot/grub/menu.lst
#---------- ADDED BY BOOTADM - rootmirror ---------title Solaris rootmirror
root (hd1,0,a)
kernel /platform/i86pc/multiboot
module /platform/i86pc/boot_archive
#---------------------END BOOTADM-------------------Note: Now when you reboot, you will be able to see "rootmirror" option in GRUB
menu.
After break the mirror you can chose "rootmirror" from GRUB menu to boot
from the mirror disk.
3. Split off submirror:
metadetach <mirror> <submirror>
# metadetach d0 d20
# metadetach d1 d21
# metadetach d6 d26
4. mount the disk to be unencapsulated on mountpoint /mnt, perform normal
Solaris Volume Manager unencapsulation steps:
# vi /mnt/etc/vfstab file mounts for all root partitions,
make sure that they reference the /dev/dsk and /dev/rdsk
# vi /mnt/etc/system file and comment out the below entry
*set md:mirrored_root_flag=1
5. Update boot path in /mnt/boot/solaris/bootenv.rc file: and change bootpath
environment variable to reflect this "unencapsulated" disk
# vi /mnt/boot/solaris/bootenv.rc
setprop bootpath '/pci@0,0/pci1022,7458@11/pci1000,3060@4/sd@1,0:a'
setprop altbootpath '/pci@0,0/pci1022,7458@11/pci1000,3060@4/sd@0,0:a'
NOTE: If you missed this step, when you boot from the mirror disk, the server
will panic
panic[cpu0]/thread=fffffffffbc22d40: cannot mount root path
NOTE: If you are not sure what the physical path is that belongs
in the above, It is recommended you run the following command
to identify the physical device path:
ls -la /dev/dsk/c#t#d#s#
6. install a boot block on the unencapsulated disk: (substitute correct
/dev/rdsk... device above)
# installgrub -fm /boot/grub/stage1 /boot/grub/stage2 /dev/rdsk/cxtxdxs0
Updating master boot sector destroys existing boot managers (if any).
continue (y/n)?y
stage1 written to partition 0 sector 0 (abs 16065)
stage2 written to partition 0, 233 sectors starting at 50 (abs 16115)
stage1 written to master boot sector

7. Update the boot archive in /mnt

# bootadm update-archive -R /mnt
Creating ram disk on /mnt
updating /mnt/platform/i86pc/boot_archive...this may take a minute
# ls -l /mnt/platform/i86pc/boot_archive (ensure this is a new module)
8. unmount this disk from /mnt mountpoint before rebooting.
9. Boot from the mirror disk.
# shutdown y g0 i6
In some cases the BIOS disk numbering may change, it may be due to when BIOS
configuration is modified. Then you will be unable to boot from main disk and
mirror disk. In such a condition, we need to check and modify the BIOS boot
disk order.
hd0 -> 1st bios disk
hd1 -> 2nd bios disk
Where hd is the GRUB device name for Hard Disk and 0 is the 1st BIOS disk.
If the BIOS disk numbering got changed, when you boot the server You will get
an error message similar like the below mentioned.
root (hd1,0,a)
Filesystem type unknown, partition type 0xbf
kernel /platform/i86pc/multiboot
Error 17: Cannot mount selected partition
Press any key to continue...

REFERANCE
Please go through the below mentioned link, which will explain "The New
Bootloader for x86 Platforms"
http://www.sun.com/bigadmin/features/articles/grub_boot_solaris.jsp