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1.1 discuss the structure of the Rutherford model of the atom, the existence of the nucleus and
electron orbits
Rutherford fired alpha particles at gold foil and found that most went through, some were
deflected nearly through 180 degrees
Indicated a small positive charge at centre, and negative electrons in orbits around the
positive nucleus
1.2 analyse the significance of the hydrogen spectrum in the development of Bohrs model of the
atom
Rutherford's model could not explain the hydrogen spectrum
i.e. that when a gas is heated or an electric current is passed through it, it produces a line
spectrum
Bohr's model explained it by stating electrons exist in stationary states and radiate energy
when they fall from a higher energy level to a lower one
1.3 define Bohrs postulates
Electrons exist in stationary states without radiating energy
When an electron falls from a higher energy level to a lower energy level, it emits energy that
is quantised by Planck's relationship:
Angular momentum is quantised and can only take values of where n is the principle
quantum number
1.4 discuss Plancks contribution to the concept of quantised energy
Planck explained black body radiation by stating that
that is, that the amount of
energy in a photon is proportional to its frequency, and that it is quantised according to a
constant 'h'
1.5 describe how Bohrs postulates led to the development of a mathematical model to account
for the existence of the hydrogen spectrum:
1.6 discuss the limitations of the Bohr model of the hydrogen atom
Ad hoc mixture of classical and quantum physics, it assumed some laws held and others did
not
Didn't work for heavier elements
Couldnt explain relative intensity of spectral lines
Couldnt explain hyperfine spectral lines
Splitting of spectral lines when sample placed in a magnetic field (Zeeman effect) could not be
explained
1.7 perform a first-hand investigation to observe the visible components of the hydrogen
spectrum
Spectroscope
Power source
Discharge tube
1.8 process and present diagrammatic information to illustrate Bohrs explanation of the Balmer
series
9.8 Option - From Quanta to Quarks Page 33
series
1.10 analyse secondary information to identify the difficulties with the Rutherford-Bohr model,
including its inability to completely explain:
the spectra of larger atoms
the relative intensity of spectral lines
the existence of hyperfine spectral lines
the Zeeman effect
2.1 describe the impact of de Broglies proposal that any kind of particle has both wave and
particle properties
Matter waves - all particles behaved as waves and could be diffracted and had a wavelength
etc.
Explained stability of electron orbits
Led to further developments in quantum mechanics
2.2 define diffraction and identify that interference occurs between waves that have been
diffracted
Diffraction is the bending of waves around obstacles or through barriers
Interference occurs between waves that have been diffracted
2.3 describe the confirmation of de Broglies proposal by Davisson and Germer
Davison and Germer fired electrons onto a Nickel crystal and upon detecting the intensity of
electrons reflected, found an interference pattern, providing evidence for de Broglie's
hypothesis
2.4 explain the stability of the electron orbits in the Bohr atom using de Broglies hypothesis
Electrons can only exist in stationary states, which are standing waves
Standing waves do not radiate energy
Number of wavelengths is equal to the principle quantum number
2.6 gather, process, analyse and present information and use available evidence to assess the
contributions made by Heisenberg and Pauli to the development of atomic theory
Heisenberg - uncertainty principle:
9.8 Option - From Quanta to Quarks Page 35
That is the uncertainty in momentum and uncertainty in position is greater than or equal
to a constant - there is a limit to how precisely the momentum and position of an
electron can be known
Pauli - exclusion principle:
No two electrons can occupy the same quantum state of an atom: explained regularity
of elements in periodic table
Also predicted neutrino (see later sections)
3.1 define the components of the nucleus (protons and neutrons) as nucleons and contrast their
properties
Components of nucleus are nucleons:
Proton: positive charge, relative mass of 1
Neutron: neutral charge, relative mass of 1.5
3.2 discuss the importance of conservation laws to Chadwicks discovery of the neutron
Chadwick found that when the unknown radiation passed through paraffin wax, protons were
emitted which could be detected.
By calculating the velocity of the alpha particles, and the protons, he used the conservation
laws of momentum and energy to postulate the momentum and energy of the unknown
radiation (neutron)
3.9 explain the concept of a mass defect using Einsteins equivalence between mass and energy
In all nuclei, there exists a 'binding energy', a result of the strong nuclear force
In nuclear reactions, this results in a 'mass defect', that is, the mass of reactants does not
equal the mass of the products, due to
,the equivalence of mass and energy (that is,
some of the mass is converted into binding energy)
3.10 describe Fermis demonstration of a controlled nuclear chain reaction in 1942
Graphite blocks as a moderator
Uranium reactor
46 tonnes of natural uranium and uranium oxide interspersed in 40 000 graphite blocks
Cadmium rods acted as controlled rods
By withdrawing the cadmium rods he showed that the pile started to heat, the fission reaction
had begun
3.11 compare requirements for controlled and uncontrolled nuclear chain reactions
Controlled - every fission should produce only one neutron, others are absorbed by control
rods
Uncontrolled - each fission produces 3 more neutrons, which fission 3 more, etc. etc.
3.12 perform a first-hand investigation or gather secondary information to observe radiation
emitted from a nucleus using Wilson Cloud Chamber or similar detection device
Supersaturated alcohol vapour produced using liquid nitrogen
Ionising radiation attracts alcohol to the ionised particles, leaving 'streams'
Alpha are thickest but shortest, then beta are thinner but longer. Gamma rays produce
intermittent streams
3.13 solve problems and analyse information to calculate the mass defect and energy released in
natural transmutation and fission reactions
Charge
-1
II
III
Up
+2/3
Electron
Down
-1/3
Electron Neutrino 0
Charm
+2/3
Muon
-1
Strange -1/3
Muon Neutrino
Top
Tau
-1
Tau Neutrino
+2/3
Bottom -1/3
Carrier
Gravity
Proposed to be Graviton
EM
Photon
9.8 Option - From Quanta to Quarks Page 39
EM
Photon
Formulas
Sunday, 13 March 2011
10:35 AM