P BLOCK

TEST
CLASS XII
QA. Complete the reaction
1. Ca3P2 + H2O
2. P4 + SOCl2
3. PCl3 + H2O
4. PCl5 + H2O
5. HgCl2 + PH3
6. CuSO4 + PH3
7. PH4I + KOH
8. C2H5OH + PCl5
9. Al2O3 + NaOH
10. Se2Cl2
11. H3PO3
12. AgNO3 + H2O + H3PO2
13. I + H2O + O3 14. Fe3+ + SO2 + H2O 15. SO2 + MnO4 + H2O 16. Cu + H2SO4 conc.
17. S + H2SO4 conc. 18. CaF2 + H2SO4
19. KMnO4 + HCl
20. MnO2 + HCl
21. C10H16 + Cl2
22. NH3 excess + Cl2
23. NH3 + Cl2 excess
24. NaOH(hot conc.) + Cl2
25. complete hydrolysis of XeF6.
QB. Guess what it could be ?
1. colourless solid compound of Xe(explosive solid) 2. compound of 18th group element used in tracer technique
3. compound formed by the hydrolysis of inter halogen compound
4. it dissolves noble metals
5. a compound on reaction with NH3 gives white fumes
6. poisonous gases (3) formed from bleaching powder
7. prepared by deacons process
8. gas discovered by Scheele
9. an element (non metal) does not from any oxoacid
10. greenish yellow gas soluble in water
QC. Answer in one word / one line ( give reason)
1. halogens are coloured 2. which hydrogen halide does not give any ppt. with AgNO3
3. perchloric acid (HClO4) is more strong acid than H2SO4 . Why ? 4. iso electronic species (neutral) for ClO
5. H2SO4, CaCl2 and P2O5 not used for drying NH3. Why ? 6. compound used as dehydrating agent for NH3
7.where do we use Bosch process and cynamide process 8. allotropes of oxygen
9. I2 soluble in KI but not in water
10. sulphur disappears on boiling with aqueous solution of sodium sulphite
QD. Draw the shapes of
1. XeO3
2. XeOF4
3. SF4
4. IF7
5. ClF3
6. IF5
7. NCl3
8. NO2
9. XeOF2
10. XeO2F2 11. HClO
12. ClO4 13. H2SO4
14. NHO3
15. S6 and S8.

P BLOCK
TEST
CLASS XII
QA. Complete the reaction
1. Ca3P2 + H2O
2. P4 + SOCl2
3. PCl3 + H2O
4. PCl5 + H2O
5. HgCl2 + PH3
6. CuSO4 + PH3
7. PH4I + KOH
8. C2H5OH + PCl5
9. Al2O3 + NaOH
10. Se2Cl2
11. H3PO3
12. AgNO3 + H2O + H3PO2

3+

13. I + H2O + O3 14. Fe + SO2 + H2O 15. SO2 + MnO4 + H2O 16. Cu + H2SO4 conc.
17. S + H2SO4 conc. 18. CaF2 + H2SO4
19. KMnO4 + HCl
20. MnO2 + HCl
21. C10H16 + Cl2
22. NH3 excess + Cl2
23. NH3 + Cl2 excess
24. NaOH(hot conc.) + Cl2
25. complete hydrolysis of XeF6.
QB. Guess what it could be ?
1. colourless solid compound of Xe(explosive solid) 2. compound of 18th group element used in tracer technique
3. compound formed by the hydrolysis of inter halogen compound
4. it dissolves noble metals
5. a compound on reaction with NH3 gives white fumes
6. poisonous gases (3) formed from bleaching powder
7. prepared by deacons process
8. gas discovered by Scheele
9. an element (non metal) does not from any oxoacid
10. greenish yellow gas soluble in water
QC. Answer in one word / one line ( give reason)
1. halogens are coloured 2. which hydrogen halide does not give any ppt. with AgNO3
3. perchloric acid (HClO4) is more strong acid than H2SO4 . Why ? 4. iso electronic species (neutral) for ClO
5. H2SO4, CaCl2 and P2O5 not used for drying NH3. Why ? 6. compound used as dehydrating agent for NH3
7.where do we use Bosch process and cynamide process 8. allotropes of oxygen
9. I2 soluble in KI but not in water
10. sulphur disappears on boiling with aqueous solution of sodium sulphite
QD. Draw the shapes of
1. XeO3
2. XeOF4
3. SF4
4. IF7
5. ClF3
6. IF5
7. NCl3
8. NO2
9. XeOF2
10. XeO2F2 11. HClO
12. ClO4 13. H2SO4
14. NHO3
15. S6 and S8.

NUMERICALS
XII
TEST
Q1.When current of 0.75 A is passed through a CuSO4 solution for 25 min. 0.369 g of copper is deposited at cathode.
Calculate atomic mass of Cu.
Q2. The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500. What is the cell
constant . If the conductivity of 0.001M KCl solution at 298 K is 0.146 x 103 s cm1.
Q3. Heptane and octane form ideal solutions. At 373 K the vapour pressure of the two liquid compounds are
105.2 Kpa and 46.8 Kpa respectively. What will be the vapour pressure , in bar, of a mixture of 25.0g heptane
and 35g of octane.
Q4. The edge length of the unit cell is 408pm . Its density is 10.6g/cc. Predict whether the metal X is body centered
or face centered or simple cube. (molar mass of metal = 107.9 mol1, NA = 6.023 x 1023)
Q5. The vapour pressure of pure water at 373 K is 760mm Hg. While that of a dilute solution of glucose is 750 mm
of Hg at the same temperature. Calculate the mole fraction of solute and molality of the solution.
Q6. The reaction SO2Cl2 === SO2 + Cl2 is first order reaction with K = 2.2 x 105 S1 at 575 K. What percentage of
SO2Cl2 will get decomposed in 80 min. When the reaction is carried out at 575 K.
Q7. The following experiment data was collected for the reaction Cl2 + 2NO 2NOCl
experiment
[Cl]
[NO]
initial rate
1
0.01
0.01
1.2 x 104
2
0.01
0.03
10.8 x 104
3
0.02
0.03
21.6 x 104
Construct the rate law equation.
1
Q8. The molar conductivity of 0.025 mol L methanoic acid is 46.1 S cm2 mol1. Calculate its degree of dissociation
and dissociation constant. Given m (H+) = m(HCOO) = 54.6 S cm2 mol1.
Q9. Calculate E.M.F. of the cell in which the following reaction takes place
Ni(s) + 2Ag+(0.002M) Ni2+(0.15) + 2Ag(s)
E0 cell is 1.05 V.
Q10. Calculate equilibrium constant of the reaction Cu(s) + 2Ag+(aq) Cu2+(aq) + 2Ag(s) E0cell = 0.46 V.
Q11. For the reaction 2A + B + C A2B + C The rate = K[A][B]2 with K = 2.0 x 106M2S2. Calculate the
initial rate of the reaction when [A] = 0.1M, [B] = 0.2M and [C] = 0.8M. If the rate of reverse reaction is
negligible then calculate the rate of reaction after [A] is reduced to 0.06M.
NUMERICALS
XII
TEST
Q1.When current of 0.75 A is passed through a CuSO4 solution for 25 min. 0.369 g of copper is deposited at cathode.
Calculate atomic mass of Cu.
Q2. The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500. What is the cell
constant . If the conductivity of 0.001M KCl solution at 298 K is 0.146 x 103 s cm1.
Q3. Heptane and octane form ideal solutions. At 373 K the vapour pressure of the two liquid compounds are
105.2 Kpa and 46.8 Kpa respectively. What will be the vapour pressure , in bar, of a mixture of 25.0g heptane
and 35g of octane.
Q4. The edge length of the unit cell is 408pm . Its density is 10.6g/cc. Predict whether the metal X is body centered
or face centered or simple cube. (molar mass of metal = 107.9 mol1, NA = 6.023 x 1023)
Q5. The vapour pressure of pure water at 373 K is 760mm Hg. While that of a dilute solution of glucose is 750 mm
of Hg at the same temperature. Calculate the mole fraction of solute and molality of the solution.
Q6. The reaction SO2Cl2 === SO2 + Cl2 is first order reaction with K = 2.2 x 105 S1 at 575 K. What percentage of
SO2Cl2 will get decomposed in 80 min. When the reaction is carried out at 575 K.
Q7. The following experiment data was collected for the reaction Cl2 + 2NO 2NOCl
experiment
[Cl]
[NO]
initial rate
1
0.01
0.01
1.2 x 104
2
0.01
0.03
10.8 x 104
3
0.02
0.03
21.6 x 104
Construct the rate law equation.
1
Q8. The molar conductivity of 0.025 mol L methanoic acid is 46.1 S cm2 mol1. Calculate its degree of dissociation
and dissociation constant. Given m (H+) = m(HCOO) = 54.6 S cm2 mol1.
Q9. Calculate E.M.F. of the cell in which the following reaction takes place

Ni(s) + 2Ag+(0.002M) Ni2+(0.15) + 2Ag(s)

E0 cell is 1.05 V.
Q10. Calculate equilibrium constant of the reaction Cu(s) + 2Ag+(aq) Cu2+(aq) + 2Ag(s) E0cell = 0.46 V.
Q11. For the reaction 2A + B + C A2B + C The rate = K[A][B]2 with K = 2.0 x 106M2S2. Calculate the
initial rate of the reaction when [A] = 0.1M, [B] = 0.2M and [C] = 0.8M. If the rate of reverse reaction is
negligible then calculate the rate of reaction after [A] is reduced to 0.06M.
DIFFERENCES BETWEEN
1. Schottky defect and Frenkel defect
2. amorphous and crystalline solid
3. ferromagnetic ferri magnetic and anti ferromagnetic 4. piezo electricity and pyro electricity
5. metallic crystals and ionic crystals
6. CCP and HCP arrangement
7. maramagnetic and di magnetic solids
8. tetra hedral and octahedral voids
9. stoichiometric and non stoichiometric defects
10. isotropic and anisotropic crystals
11. n-type and p-type semiconductors
12. ideal and non ideal solutions
13. molarity , normality and molality
14. hypotonic , hypertonic and isotonic solutions
15. solvent solute
16. osmosis and diffusion
17. mass fraction and mole fraction
18. order and molecularity
19. rate of reaction and rate constant
20. saturated and unsaturated solution
21. conductance and specific conductance
22. strong electrolyte and weak electrolyte
23. equivalent conductivity and molar conductivity
24. potential difference and E.M.F. of a cell
25. primary cells and secondary cells
26. electrochemical and electrolytic cell
27. adsorption and absorption
28. physisorption and chemisorption
29. homogeneous and heterogeneous catalysis
30. catalytic promoter and catalytic poison
31. true solution , colloidal solution and suspension
32. multimolecular and macro molecular and associated colloids
33. lyophillic and lyophobic colloids
34. electrophoresis and electro osmosis
35. o/w and w/o emulsions
36. sols and gels
37. sols and emulsions
38. crystalloids and colloids
DEFINE
1. Unit cell
25. Henrys law
2. Crystal lattice
26. Boiling point
3. pseudo solids
27. Melting point
4. Molecular solids
28. osmosis
5. Ionic solid
29. Diffusion
6. Amorphous solids
30. Raoults law
7. Coordination number
31. Coligative properties
8. Intrinsic defect
32. Molal elevation constant (ebullioscopic constant)
9. Interstitial defect
33. Molal depression constant (cryoscopic constant)
10. Stoichiometric defect
34. Osmotic pressure
11. Crystalline solids
35. Isotonic solution
12. Paramagnetic solids
36. Hypertonic solution
13. Dimagnetic solids
37. Hypotonic solution
14. Ferromagnetic substances
38. Molar conductivity
15. Ferrimagnetic substance
39. Conductivity
16. Antiferromagnetic substance
40. Equivalent conductance
17. Molarity
41. Kohlrauschs law
18. molality
42 primary cell
19. Normality
43 Secondary cell
20. Mole fraction
44. Faradays first law
21. Vapour pressure
45. Faradays second law
22. Zeta potential
23. Enzymes
46. Craft temperature
24. Associated colloids (micelle)
47. CMC

48. Chemical kinetics

49. Order of reaction
50. Molecularity of the reaction
51. Collision frequency
52. Catalyst
53. Rate constant
54. Half life
55. Activation energy
56. Threshold energy
57. Adsorption
58. Enthalpy of adsorption
59. Peptisation
60. Hardy Shulzes rule
61. Electrodylasis
62. Electrophoresis
63. Emulsions
64. Lyophillic sols
65 Lyophobic sols
66. Electro osmosis
67. Brownian movement
68. Tyndall effect

inorganic
1. Ores 2. minerals 3. Gangue 4. metallurgy 5. Flux
6 . Slag 7. Depressant in metallurgy 8. Zeolite
9. Ligand 10. smelting 11. chromatography 12. Enthalpy of atomization
13. Disproportionation reaction
14. Inter halogen compounds 15. Lanthanide contraction 16. Homoleptic complex 17. Hetroleptic complex

FULL ORGANIC TEST

CLASS XII

Q1. Convert :- (a) anisol to phenol (b) acetone into ter.butyl alcohol (c) ethylene into propanoic acid
Q2. Write short notes on
(a) Clemmensens reduction (b) Wolf Kishner (c) Rosenmund (d) Reimer Tiemann
(e) coupling
(f) Gattermann
(g) aldol condensation.
Q3. Identify the unknown
P / I2
Mg
(i) HCHO (ii) HO / H+
(a) CH3CH2OH
A
B
C
HI
aq.KOH
I2 / NaOH
(b) CH2=CH2
A
B
C
H2SO4 / 443K
HBr
aq.KOH
(c) CH3CH2CH2OH
A
B
C
NH3

P2O5 /
(d) RCOOH
A
B
C
NH4OH

Br2 / KOH
(e) RCOOH
A
B
C
P / I2
AgNO2
reduction
CH3Cl
(f) CH3OH
A
B
C
D.
Q4. How will you distinguish between
(a) methanol and ethanol
(b) acetaldehyde and acetone
(c) phenol and benzyl alcohol
Q5. Identify the unknown
(a) CH2Cl
CH2NO2
CH2NC
?
Sn /HCl
NaOH / H2O /
O
O
?
O
?
KOH / Br2
?
(b)

NO2
Sn / HCl
O

NaNO2 + HCl / 00C

Br2 excess
?

H3PO2 / H2O
?

KOH / Br2
?
conc. HNO3/conc. H2SO4

(c)
A

Sn / HCl /

CHCl2 + KOH /

H2 / Pt
D

F
NHCOCH3
O

(d)

Cl2 / Fe+++

conc. HNO3/conc.H2SO4
O

(e)

?
[O]

HCHO

Sn / HCl
?

CH3COOH / MnO2 /

+ CH3COOH
NaNO2 + HCl/273K
?

I2 / NaOH
?

Ag powder
?

HgSO4 1% + 49% H2SO4

CH CH

CuCl + HCl
?

ALL DEFINITIONS
1. Mole 2. molarity
3. molality
4, normality
5. element
6. mixture 7 compound
8. Law of conservation of mass 9. Law of constant composition 10. Law of multiple proportion
11. Law of reciprocal proportion 12. Gay Lussac law of combining volume 13. Daltons law of partial pressure
14. Avogadros law 15. Boyles law 16. Charles law 17. Grahms law of diffusion 18. Empirical formula
19. Molecular formula 20. dipole moment 21. isotopes 22. isobars 23. isotones 24. photoelectric effect
25.
Hunds rule of maximum multiplicity
26. Heisenbergs uncertainty principle 27. Paulis exclusion principle 28.
degenerated orbitals 29. Aufbaus principle 30. Mendeleevs periodic law 31. modern periodic law
32. diagonal relationship 32. Ionization enthalpy
33. Inert pair effect
34. electron affinity
35. isoelectronic species
36. screening effect
37. electronegativity 38. electrovalent bonding
39. covalent bonding
40. valency
41. lattice enthalpy 42. boiling point
43. hydration enthalphy
44. bond dissociation energy 45. dative bond 46. Lewis acid
47. Lewis base 48. bond order
49. hybridization
50. hydrogen bonding 51. enthalpy of neutralization
52. enthalpy of sublimation
53. enthalpy of combustion 54. entropy
55. free energy
56. first law , zeroth, second law and third law of
thermodynamics
57. surface tension 58. viscosity 59. critical temperature 60. vapour pressure
61. Le- Chateliers principle 62. extensive properties
63. state functions
64. isothermal process
65. adiabatic process
66. isobaric system 67. isochoric system 68. internal energy
69. molar heat capacity 70. Hesss law
71. Henrys law 72. Ostwalds dilution law 73. pH
74. buffer solution 75.common ion effect 76. solubility product 77. Disproportionation reaction
78. redox reaction 79. decomposition displacement
80. electrochemical series 81. oxidizing agent
82. reducing agent
83. resonance
84. law of mass action

NUMERICALS
ASSIGNMENT FOR REVISION
CLASS XI
Q1. Calculate the number of significant numbers in 0.0000000420.
[Ans. 3]
Q2. Carbon and oxygen forms two compounds . The first compound contained 42.9 % C. While the other
has 72.7% O. Show that this data is the aggrement with the law of multiple proportion.
[Ans. the ratio of mass of C combining with fixed mass of O is 2:1 which is a simple ratio.]
Q3. Calculate the mass of one atom of hydrogen.
[Ans. 1.66 x 10 24 g.]
Q4. Calculate the number of atoms and volume of 1 gm He gas at NTP.
[Ans. 5.6 litre (NTP)]
Q5. Calculate the total number of electrons in 1.6 gm methane.
[Ans. 6.02 x 1023 electrons]
Q6. What weight of sulphur has as many atoms as in 3 gm of carbon ?
[Ans. 8.0 gm]
Q7. Calculate total number of atoms in 18 gm H2O.
[Ans. 18.06 x 1023 atoms]
Q8. Calculate the number of Cl1 ions in 111 gm anhydrous CaCl2.
[Ans. 12.04 x 1023 Cl]
Q9. Calculate the number of oxalic acid molecules in 100 ml 0.02 N oxalic acid.
[Ans. 6.02 x 1020 mol]
Q10. What is the weight of one molecule of a compound C60H122 ?
[1.4 x 10 21gm]
Q11. The composition of a compound is : Ca = 25.3%, P = 39.2 % and O = 35.5 % . What is the molecular
mass of the compound ?
[ Ans. 216]
Q12. How much chlorine is required to evolve out 1.6 gm of bromine from KBr ?
[Ans. 0.71 gm]
Q13. 24 gm of sodium sulphate was dissolved in water and BaCl2 solution mixed in it. What substance
will be precipitated and what will be its mass ?
[Ans. BaSO4, 39.3 gm]
Q14. Yellow light emitted from a sodium lamp has a wavelength of 580 nm. Calculate the frequency and
wave number of this light.
[Ans. frequency =5.17 x 1014 s 1 wave number = 1.72 x 106 m1]
Q15. The e energy of the ground state of H atom works out to be 1.312 x 106 J mol 1. What change will
occur in the position of the e in this atom if an energy of 9.84 x 105 J mol1 is added to the H atom ?
[Ans. electron transition occurs from n = 1 to n = 2 level]
Q16. Calculate the wavelength and energy of radiation emitted for the electronic transition from infinity ()

to stationary state one of H atom.

[Ans. 2.18 x 1020 J]
Q17. Calculate the energy of one mole of photons of radiation whose frequency is
5 x 1014 Hz.
[Ans. 199.51 x 103 J mol1]
Q18. Two particles A and B are in motion . If the wavelength associated with particle A in motion is 5 x 10 8m
calculate the wavelength associated with particle B if its momentum is half than that of A. [Ans. 107m]
Q19.Calculate the momentum of a particle which has a de Broglie wavelength of 2.5 x 1010 m.
(h = 6.6 x 1034Kg m2 s1]
[ Ans. 2.64 x 1024 Kg m sec1]
Q20. Calculate the product of uncertainty in position and velocity for an e of mass = 9.1 x 1031 Kg.
(h = 6.6 x 1034 Kg m2 s1)
[ 0.577 x 105 m2 s1]
0
Q21. The weight of 350 ml of a diatomic gas at 0 C and 2 atm. is 1 gm. Calculate the weight in gm
of one atom.
[Ans. 2.66 x 1023 gm]
Q22. The volume of a gas at 750 mm pressure is 25 L. If the pressure is increased to 800 mm, what would
be the new volume , temperature remaining constant ?
[Ans. 23.4 L]
Q23. Calculate the pressure of the mixture, if at constant temperature 250 ml of N2 at 640 mm pressure
and 380 mL of O2 at 700 mm pressure are filled in a flask of 1 L capacity.
[Ans. 426 mm]
Q24. If 50 volumes of H2 diffuse from a vessel in 85 sec, then under the same conditions how much time
will 35 volumes of nitrous oxide take in diffusion ?
[Ans. 279]
Q25. Calculate the enthalpy change for the following reactions CH4(g) + 2O2(g) CO2(g) + 2H2O(l)
given , enthalpies of CH4, CO2 and H2O are 74.8 kj mol1, 393.5 kJ mol1 and 286.2 kJ mol1
respectively.
[Ans. 891.1 kJ]
0
Q26. At constant pressure and 17 C, the heat of formation of C6H6 is 130800 cal. What will be its
heat of reaction at constant volume ?
[ Ans. 129640 cal.]
Q27. The molar heat of formation of C2H6, CO2 and H2O are 21.1, 94.1 and 68.3 k cal respectively.
Calculate the molar heat of combustion of C2H6.
[Ans. 372 k cal.]
Q28. Bond energies of H H and Cl Cl bonds are 430 kJ/mol and 240 kJ/mol respectively .
If the heat of formation of HCl (Hf) = 90 kJ/mol, then calculate the bond energy of H Cl bond .
[Ans.H = 425 kJ/mol]
4
0
Q29. For a reaction K = 1.958 x 10 at 400 K. What is the value of G at this temperature ?
(R = 8.314 JK1 mol1)
[Ans. 28.40 kJ]
0
Q30. Calculate the entropy change in melting of 1 gm of ice at 0 C in S.I. units. Latent heat of fusion of
ice is 80 cal gm1.
[Ans. 1226.08 J Kg1Kg K1.]
Q31. The entropy values (in JK1 mol1) of H2(g) = 130.6, Cl2(g) = 223.0 and HCl(g) = 186.7 at 298 K and
1 atm. Calculate the entropy change for the reaction H2(g) + Cl2(g) 2HCl(g)
[Ans. 19.8 JK1 mol1]
Q32. (i) For the reaction , Ag2O(s) 2Ag(s) + O2(g). calculate the temperature at which free energy
change (G) is equal to zero. H = + 30.56 kJ mol1 and S = 0.066 kJ K1 mol1 at 1 atm pressure.
(ii) Predict also the nature of the reaction at this temperature and below it.
(iii) Calculate the temperature at which the rates of forward and backward reactions will be the same
[Ans. (i) 463.0 K (ii) at equilibrium (iii) grearer than 463 K spontaneous ]
Q33. Calculate the standard Gibbs energy change , Gf0 for the following reaction at 298 K using standard
Gibbs energies of formation (Gf0) provided to you. CaCO3(s) + 2H+(aq)
Ca2+(aq) + H2O(l) + CO2(g)
0
1
Gf /kJ mol for different species are
CaCO3(s) = 1128.8 ; H2O(l) = 237.13
2+
+
Ca (aq) = 553.58 ; H (aq) = ; CO2(g) = 394.36
[ Ans. 56.27 kJ mol1]
3
Q34. The value of Kc for the reaction , 2A = B + C is 2 x 10 . The composition of reaction mixture is
[A] = [B] = [C] = 3 x 104 M . In which direction the reaction will proceed ?
[Ans. the reaction will proceed in the reverse directions.]
Q35. A mixture contained 30.92 gm H2, 2.794 gm I2 and 1308.16 gm HI at equilibrium. Calculate the
equilibrium constant for the thermal decomposition of HI.
[Ans. 1.628 x 103]
Q36.PCl5, PCl3 and Cl2 are at equilibrium at 500 K and having concentration 1.59 M PCl3, 1.59 M Cl2 and
1.41 M PCl5. Calculate Kc for the reaction.
[Ans. 1.79 M]
0
Q37. At 20 C 0.1 N formic acid dissociates to the extent of 4.5% . Calculate the dissociation constant
of the acid.
[Ans. 2.12 x 104]
0
3
Q38. The solubility of AgCl at 20 C is 1.435 x 10 g/L. Calculate solubility product of AgCl at this

temperature.
[Ans. 1 x 1010]
Q39.The solubility product of a salt MX2 in water is 4 x 1012. What is the concentration of M2+ ions in the
aq. solution of the salt ?
[Ans. 1 x 104 M]
Q40. The solubility product of AgCl is 1 x 1010. Calculate the solubility of AgCl in mol/L [Ans. 1 x 105]
Q41. What will be the pH of 0.1 N HCl ?
[Ans. 1]
+

Q42. Find out [H ] and [OH ] of 0.0001 M NaOH solution

[Ans. 1010 M]
Q43. The pKa of acetic and pKb of NH4OH are 4.76 and 4.75 respectively . Calculate the pH of
ammonium acetate solution.
[Ans. 7.005]

TEST
FULL PHYSICAL 2013
Q1. The normal B.P of methanol is 640C and its standard enthalpy of vaporization is 38KJ/mol . calculate vapS for this liquid.
Q2. What will be the sign of S, (+ve) or (ve) or zero for the following reactions
Cu2+(aq) + 4NH3(aq) [Cu(NH3)4]2+(aq) (b) Ca(OH)2 (s) + CO2(g) CaCO3(s) + H2O(g)
(a)
Q3. Calculate the enthalpy of formation of acetylene from the following information
(a) 2C2H2(g) + 5O2(g) 4CO2(g) + 2H2O(l) H0 = 2600KJ (b) C(s) + O2(g) CO2(g) H0 = 394KJ
(c) 2H2(g) + O2(g) 2H2O(g) H0 = 484 KJ
(d) H2O(l) H2O(g) H = +44KJ.
Q4. Calculate the number of atoms and volume of 1 gm He gas at NTP.
Q5. The volume of a gas at 750 mm pressure is 25 L. If the pressure is increased to 800 mm, what would
be the new volume , temperature remaining constant ?
Q6. How much chlorine is required to evolve out 1.6 gm of bromine from KBr ?
Q7. What type of forces of attraction are present between the pair of compounds given:(a) NH3 and water (b) CF3 and CH4 (c) HCl and HCl (d) NO3- and I2.
Q8. An atomic orbital has n=3. What are the possible values of l.
Q9. States physical significance of 2.
Q10What is disproportionation reaction ?
Q11. Write electronic configuration of Fe+++ and Fe++ . Compare their magnetic property.
Q12. Indicate the number of unpaired electrons in Cr and Kr.
Q13. Which of the following have higher ionization energy (i) Kr , Xe
(ii) I , I .
Q14. Arrange the following in increasing order (a) F,Cl,Br,I (electron affinity) (b) Br+, Br and Br (atomic size).
Q15. Out of NH3 and NF3 which has higher dipole moment and why ?
Q16. H2O and CO2 both are triatomic but CO2 is linear and H2O is bent . Why ?
Q17. Predict the sign of entropy in the following (a) a liquid crystallizes into solid (b) 2NaHCO 3 (s) Na2CO3(s) + CO2 + H2O(g)
Q18. Under what conditions H and U become equal.
Q19. How is G related to (i) equilibrium constant (ii) e.m.f. of a cell.
Q20. What is the effect of temperature on an exothermic reaction for which S is negative
Q21. Prove that heat change measured at constant volume is the measure of initial energy.
Q22. How many and bonds are present in toluene.
Q23. Write position of an element with at. no. = 53 in periodic table.
Q24. Out of NH3 and N2 which one will have higher value of a and b Vander Waals constants.
Q25.What is the effect of temperature on (a) viscosity (b) vapour pressure of a liquid
Q26. Arrange the following in decreasing order of bond energy H 2, H2+ and He2.
Q27. Plot graph between PV against P at constant T.
Q28. Answer in one word / one line
(a) drop of water is spherical . Why ?
(b) the space in an orbit where probability of finding e is zero. (c) all C C bond lengths in benzene are equal. Why ?

TEST
XI
(mole concept , atomic structure, periodic classification , bonding)
Q1. Arrange the following species in increasing order of stability. Li 2, Li+2 and Li 2. Justify with energy level diagram .
Q2. Write differences between (a) and bonds (b) VBT and MOT.
Q3. Isobutane C4H10 undergoes combustion in oxygen according to the reaction
2C4H10(g) + 13O2(g) 8CO2(g) + 10 H2O(l) When 10.0 lit of isobutene is burnt at 270C and 1 bar
pressure. Calculate the volume of CO2 produced at 800C and 1.5 bar pressure.
Q4. Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or
different ? Justify your answer.
Q5. How does dipole moment help to find out geometry of a molecule ?
Q6. Give reasons (a) BF3 is triangular coplanar but NH3 is pyramidal (b) NH3 bottle is cooled before opening the seal?
(c) N2 is inert ? (d) benzene contains 3 double bonds still it is stable and less reactive . Why ?
Q7. What is dipole moment ? Explain its one application with example.
Q8. Why is Be different from other members of the family ?
Q9. Find out the type of hybridization of Xe in XeF4 , P in PO4 3.

Q10. The mass of an electron is 9.1 x 10 31 Kg. If its K.E is 5.0 x 10 25J. Calculate its wavelength.
Q11.Draw the shapes of obitals for which l = 1, l = 2.
Q12. Why is Ne2 not possible. Explain with energy level diagram?
Q13. Write electronic configuration of Mn2+ ions? also comment on its magnetic behaviour

ORGANIC

BASIC PRINCIPLES AND TEHNIQUES

TEST

CLASS XI

Q1. A compound of carbon, hydrogen and nitrogen contains the elements in the ratio 18:2:7. Calculate its
empirical formula. If the molecular mass is 108, what is its molecular formula.
Q2. Give a brief description of the principles of the following techniques taking an example in each case.
(a) crystallization
(b) distillation
(c) chromatography
Q3. Describe the method , which can be used to separate two compounds with different solubilities in
a solvent X.
Q4. Name a suitable technique of separation of components form a mixture of calcium sulphate and camphor.
Q5. Will CCl4 give white ppt. of AgCl on heating with silver nitrate ? Give reason for your answer.
Q6. Why is nitric acid added to sodium extract before adding silver nitrate for testing halogens ?
Q7. 0.3780 gm of an organic compound gave 0.5740 gm of silver chloride in carius estimation . Calculate
the percentage of chlorine present in the compound.
Q8. An organic compound contains 69% carbon and 4.8% hydrogen , the remainder being oxygen. Calculate
the masses of carbon dioxide and water produced when 0.20 gm of this substance is subjected to
complete combustion.
Q9. During the test for nitrogen in Lassaignes filtrate, sometimes red colouration is obtained when ferric
chloride is added.
Q10. Suggest a method to purify
(i) kerosene oil containing water (ii) a liquid which decomposes at its boiling point
(iii) essential oil.
Q11. In an estimation by Dumas method 0.15 gm of an organic substance produced 22.5 mL of N2 collected
over KOH solution at 220C and 720 mm pressure. Calculate the percentage of nitrogen by mass in the
organic compound. [Aqueous tension at 220C = 20 mm]
Q12. Why is it necessary to use acetic acid and not sulphuric acid for acidification of sodium extract for
testing sulphur by lead acetic test ?
Q13. Why a solution of potassium hydroxide used to absorb carbon dioxide evolved during the estimation of
carbon present in an organic compound ?

ASSIGNMENT
CLASS XI
ORGANIC
Q1. Draw the structures of (a) 2-methyl-3-isopropylheptane (b) dicyclopropylmethane (c) 2-phenyl ethanoic acid .
Q2. Which of the following compound can show geometrical isomerism
(a) (CH3)2=C(CH3)2
(b) CH3CH=CHCH2CH3
(c) C6H5-CH=CHCH3 (draw).
Q3. Give IUPAC names of the products formed by addition of HBr to hex-1-ene (i) in the absence of peroxide and
in the presence of peroxide and (ii) in the presence of peroxide.
Q4. A reproductive ozonolysis of an alkene gave propanone and acetaldehyde. Give structure of alkene with its
IUPAC name.
Q5. How will you distinguish between ethane ethene and ethyne ?
Q6. (CH3)2C=CH2 + HI A. What is A ? Write its IUPAC name.
Q7. How will you convert 2-butyne into (i) cis-2-butene (ii) trans-2-butene.
Q8. Which of the two is stronger acid ethyne or propyne. Why ?
Q9. Give two reasons to show that ethyne is acidic in nature.
Q10. Convert ethyne into (a) ethanal (b) benzene.
Q11. How will you prepare (a) ethane from methane (b) ethyne from ethene (c) butane from ethane

(d) ethene from ethane.

Q12. Draw structural formulas and write IUPAC names for all possible isomers (a) C4H8 (b) C5H8
Q13.Propanal and pentan-3-one are the ozonolysis products of an alkene?What is the structural formula of the alkene ?
Q14. Write the chemical equations for the combustion reaction of the following hydrocarbons
(a) butane (b) pentene (c) hexyne
(d) toluene.
Q15. Draw the cis and trans structures of hex-2-ene. Which isomer will have higher B.P. and why ?
Q16. Why is benzene extra ordinary stable though it contains three double bonds ?
Q17. What are the necessary conditions for any compound to show aromaticity ?
Q18. How will you convert benzene into (i) p-nitrobromobenzene (ii) m-nitrochlorobenzene.
(iii) p-nitrotoluene
(iv) acetophenone ?
Q19. What effects does branching of an alkane chain has on its melting point ?