SEM-9522E Water Treatment

SAMSUNG ENGINEERING CO.
, LTD
SAMSUNG SEI TOWER, 467-14 Dogok 2 Dong,
Kangnam-Ku, Seoul, KOREA 135-280
DESIGN MANUAL
SEM-9522E
PROCESS DESIGN MANUAL
Preparation of Datasheet
for Water Treatment
REV.
DATE
:0
: 2006.8.23
SAMSUNG ENGINEERING CO., LTD.
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE i OF
Contents
Page
1
PURPOSE AND MAKING METHOD.....................................................

1.1
1.2
1.3
2.
RAW WATER TREATMENT...................................................................

2.1
2.2
2.3
2.4
2.5.
2.6
2.7
2.8
2.9
GENERAL DESCRIPTION................................................................
SCOPE DEFINITION........................................................................
DESIGN CONSIDERATIONS.............................................................
PERFORMANCE GUARANTEE VENDOR SHALL GUARANTEE THE
FOLLOWING PERFORMANCE..........................................................
UTILITY CONDITIONS.................................................................
BATTERY LIMIT CONDITIONS......................................................
REMARKS..................................................................................
ATTACHMENT.............................................................................
RAW WATER TREATMENT PACKAGE MAKING GUIDE......................
DIMINERALIZED WATER..................................................................
3.1
3.2
3.3
3.4
3.5
3.6
3.7
PURPOSE......................................................................................
SUPPLEMENTARY ARTICLE.............................................................
MAKING METHOD..........................................................................
GENERAL DESCRIPTION.............................................................
SCOPE DEFINITION....................................................................
DESIGN CONSIDERATION...........................................................
PERFORMANCE GUARANTEE......................................................
BATTERY LIMIT CONDITION........................................................
ATTACHMENT.............................................................................
DEMINERALIZED WATER SYSTEM MAKING GUIDE.......................
POTABLE WATER PACKAGE...........................................................

4.1
4.2
4.3
4.4
GENERAL DESCRIPTION.............................................................
SCOPE DEFINITION....................................................................
DESIGN CONSIDERATIONS..........................................................
FLOW SCHEME..........................................................................
ii
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4.5
4.6
4.7
5
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REMARKS..................................................................................
ATTACHMENT.............................................................................
POTABLE WATER MAKING GUIDE...............................................
REVISION HISTORY..........................................................................
ii
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1
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PURPOSE AND MAKING METHOD

1.1
Purpose
This guide has sample data sheet about skill option that is
required to make raw water treatment, potable water treatment,
demineralized water treatment data sheet. it provide design base
about each skill option.
1.2
Supplementary Article
Major equipment and capacity should be entered on a base of
data accumulated in job. data about chemicals and basic
equipment is followed up by contact with vendor or gathering
data.
1.3
Making Method
Serial numbers is given about changeable articles by water
condition and job characteristic, design base and application
range is indicated in making guide.
2. RAW WATER TREATMENT

* Raw Water Treatment Package
This data sheet defines the minimum technical requirements for the raw
water pretreatment facilities. Vendor shall carefully study and verify
those requirements in this data sheet and shall execute related works.
2.1
General Description
Raw water treatment facilities shall treat raw water to produce
filtered water and to supply it to users in the plant as plant water
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and to water treatment facilities as raw feed water and to cooling

water system as make-up.
These Facilities Consists Of The Following Units.
- Clarifier unit
- Sand filter unit
- Sludge dewatering unit
- Chemical injection unit
2.1.1
Clarifier Unit
Raw water will be transferred from Sam-Bong lake and
Dae-Ho lake via 23 km pipeline and be received in the
raw water pond located in the east side of utility center,
which will have the capacity of 150,000 m3. raw water will
be pumped up from the raw water pond to the clarifier
unit to reduce the turbidity with injection of coagulants
and coagulant aids. Ph is adjusted by injecting NaOH
solution in order to reduce organic matter, chlorine shall
be also injected. The clarified water shall be feed to the
sand filter unit.
2.1.2
Sand Filter Unit

The overflow from the clarifier shall be transferred to the
sand filters by gravity flow for removal of small amount of
remaining suspended materials. The sand filter unit shall
be equipped with water backwash and air backwash
systems. The filtered water shall be collected in the
intermediate water basin and pumped to the filtered
water tank. Backwash waste water shall be collected in
the recovered water pit to be recycled to the raw water
feed line. Filtered water will be used as plant water,
cooling water make-up and RO feed water.
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2.1.3
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Sludge Dewatering Unit

The sludge removed from the bottom of the clarifier shall
be thickened and stored in the sludge chamber. The
thickened sludge is pumped up to the sludge dewatering
equipment and mixed with polyelectrolyte. Dewatered
sludge cake shall be loaded to truck and the separated
water shall be returned to the raw water feed line through
the recovered water pit.
2.2
Scope Definition
The plant shall include the following equipments, but those shall
be regard as typical. Vendor shall check raw and treated water
quality, and supply further equipments if necessary to meet
design conditions.
2.3
2.2.1
Clarifier Unit
2.2.2
Sludge Dewatering Unit for details, refer to equipment
2.2.3
Sand Filter Unit
2.2.4
Chemical Injection Unit
list as attached #2
Design Considerations
2.3.1
Design Codes and Standards Specification for This

Project.
(1) Design of the facilities shall be done according to
engineering specification for this project.
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(2) If there are no applicable standards or code, suitable

additional standards shall be adopted upon owner's approval.
2.3.2
Design Basis
1)
Design Capacity
2)
Inlet Conditions
Refer to attached # 1 for the specifications of raw
water.
3)
Outlet Conditions
The required specifications of clarified water
after clarifier and filtered water after sand filter
are as follows.
- Clarified Water: SS ...less than 10 mg/l
- Filtered Water: SS ...less than 2 mg/l
Ph ...6 - 8.2
Cod ...less than 10 mg/l
4)
Effluent Specifications
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Solid content in the sludge cake: min 15 %

2.3.3
Specifications for the Units

1)
Clarifier Unit
(1) This unit is considered to have four trains with
each train having
The capacity of 520 m3/hr
Treated water shall have SS less than 10 mg/l..
(2) Clarification shall be accomplished in the
slurry recirculation type clarifier with a slow
moving de sludge scraper.
(3) To reduce the water turbidity, poly aluminum
chloride (PAC) is used as a coagulants.
(4) If polyelectrolyte as flocaid is required in
flocculation, edible polymer aid permitted by
Korean authorities shall be used.
(5) Sodium hypo-chloride (NaOCl) shall be used
for chlorination.
(6) All equipments except for chemical storage
tanks, injection system including pumps shall be
suitable for outdoor installations.
(7) Sludge removal shall be automatically
controlled for intermittent operation.
(8) Inlet water to the clarifier unit shall be
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controlled by an automatic control valve.

(9) An integrating flow meter shall be provided on
the inlet water line to the clarifier unit with controls
to proportion chemical feeds to inlet flow.
(10) Clarifier is constructed as a concrete, the
internal of clarifier is composed of sludge agitator
and mixing chamber, sludge scraper to remove
solid state sludge.
2)
Sludge Dewatering Unit

(1) Sludge discharged from the clarifiers shall be
dewatered to minimum 15% in solids with
injection of cationic polyelectrolyte (PETR).
Coagulation tank with mixer shall be provided, if
necessary.
(2) One train of belt press type sludge dewatering
equipment shall be provided and shall have a
sufficient capacity based on 8 hrs per day
intermittent operation.
(3) All facilities for removal and truck loading of
dewatered sludge cake shall also provide.
(4) Sludge chamber shall have the capacity of
one day operation.
(5) A dissolving tank shall be provided for PETR
with a mixer and an auto feeder. The dissolved
PETR shall be introduced to the PETR day tank
by gravity flow.
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(6) All equipment except for chemical storage

tanks, injection pumps and sludge dewatering
equipment shall be suitable for outdoor
installation.
3)
Sand Filter Unit

(1) Multiple filters shall be provided to allow
continuous operation at full system design
capacity with one unit out of service.
(2) Gravity type sand filter shall be provided. The
filter shall be capable of being operated manually
and automatically. Back wash shall be initiated
either by push button, timer or high differential
pressure signal.
(3) The minimum run length shall be 24 hours per
filter.
(4) The volume of the recovered water pit shall be
more than the amount of water from one filter
backwash. The capacity of the recovery water
recycling pumps shall be decided to pump up the
backwash waste water during normal backing
interval.
(5) Interlocking system shall be applied in order to
prevent simultaneous backwashing.
(6) All equipments shall be suitable for outdoor
installation.
(7) An integrating-indicating flow meter shall be
installed on each outlet line of plant water and
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cooling water make-up.

(8) Turbidity meter shall be installed on the
outlet of the intermediate water pump.
4)
Chemical Injection Unit

(1) Separate chemical feeding systems shall
be provided for coagulants, coagulant aids,
naoc1, and NaOH solution.
(2) The chemical feeding systems shall be
sized to the 7 days capacity at design flow
rate.
(3) Agitators shall be motor driven with shaft
and impeller materials suitable for chemical
mixed.
(4) Chemical storage tank and pump materials
shall be suitable for the chemicals.
2.3.4
Instrumentation and Control System.

Automatic control system shall be applied where
process values are kept constant, or where frequent
manipulation would otherwise be required, local
control panel with plc shall be installed in the local
control room. Control of the facilities shall be done
with this local control panel. In addition to the local
control panel, the following monitoring function shall
be supplied from plc through communication line to
DCS which will be installed in the central control
room.
- Operation and Regeneration Status of the Sand Filters
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2.4
Performance.
- Turbidity Indicator
- Tank and Vessel Indicators
- Alarms
Performance Guarantee Vendor Shall Guarantee the Following
2.4.1
Product Capacity and Quality

(1) Clarifier
- Capacity : 520 m3/hr/train

- SS
: Less than 10 mg/l
(2) Sand filter
- Capacity : 300 m3/hr/train (exclude
backwash loss)
- SS
: Less than 2mg/l
- COD : Less than 10mg/l
2.4.2
Utility and Chemical Consumption

(1) Chemicals
-
PAC ------------------------ * kg/day

NaOCl ------------------------ * kg/day
Polyelacrolyte --------------- * kg/day
Others (if req'd) ------------- * kg/day
(2) Power
2.4.3
------------------------ * kwh/day
Effluent
Dewatered Sludge Cake

Quantity ---------------------- Max. * kg/d
Solid Content -------------- Min. 15 %
2.4.4
Operation Cycle
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Filter - Operation Time: Min 24 hr/cycle

- Backwash Time : Max. 1 hr/cycle
2.5.
Utility Conditions
Refer to Attached # 4.
2.6
Battery Limit Conditions

PRESS
TEMP
(kg/cm2)
()
INCOMING
RAW WATER
2.0
LP STEAM
INST. AIR
AMBIENT
3.5
195
7.0
AMBIENT
OUTGOING
PLANT WATER
CW MAKEUP
2.7
5.0
3.0
AMBIENT
AMBIENT
Remarks
(1) Vendor to State Blanks Marked with *
(2) Vendor is encouraged to bid an alternative proposal
which is economical and reliable under the conditions that
his system is able to meet the design requirements.
2.8
Attachment
Process flow diagram and equipment list attached herewith are
for reference.
(1) Specification of Raw Water.
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(2) Equipment List

(3) Utility Conditions
(4) Process Flow Diagram
Attachment #1 specifications of raw water - a pollution level measurement 1.
NORTH KOREA RIVER
2.
SOUTH KOREA LIVER
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3.
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HAN LIVER DOWNSTREAM
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4.
NACKDONG RIVER
5.
KEUM RIVER
6.
YEONGSAN LIVER
DATE : 2006. 8. 23
7.
SUMZIN RIVER
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8.
MANKYEONG RIVER
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EACH PROJECT WATER SPECIFICATION
1.
SPC NO.2 WATER SPECIFICATION (ULSAN)
* : AVERAGE
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DATE : 2006. 8. 23
2.
EA CORPORATION. BACO3 WATER SPECIFICATION

(ONSAN)KOR
CHARACTERISTICS
RAW
FILTERED
PROCESS
WATER
WATER
WATER
s/cm
380
420
6.0~7.0
6.5~8.5
TOTAL HARDNESS
CaCO3
70.0
70.0
Ca++
CaCO3
41.2
41.2
Mg++
CaCO3
28.8
28.8
(Na+), (K+)
CaCO3
97.3
105.5
NH4+
CaCO3
3.3
3.3
M-ALKALINITY
CaCO3
45.0
45.0
Cl-
12.4
14.1
NO3-
NO3-
2.6
2.6
(SO4)-
(SO4)-
45.5
45.5
SiO2
SiO2
7.0
7.0
FREE CO2
CO2
7.0
7.0
TURBIDITY
DEGREE
10 MAX
<1
O2
4.2
3.5
CONDUCTIVITY
PH ( 25 )
Cl-
COD(Mn)
UNIT/ppm AS
6.5~8.5
5.0
170.5
3.3
45.0
14.1
2.6
45.5
7.0
7.0
<1
3.5
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178.9
TOTAL CATION
CaCO3
170.6
178.9
180.0
TOTAL ANION
CaCO3
170.7
180.0
-
COLOR
DEGREE
7.0
3.
SAMSUNG ELECTRONICS SEMI-CONDUCTOR WATER SPECIFICATION
(KIHEUNG)
CHARACTERISTICS
UNIT
16 K
64 K
256 K
1M
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RESISTIVITY
.cm AT 25
-15
15 ~ 16
17 ~ 18
17 ~ 18
PARTICULES
0.2
0.2 ~ 0.1
0.1
0.1 ~ 0.05
no/
200 ~ 300
50 ~ 150
20 ~ 50
TOC
ppm
0.5 ~ 1
0.05 ~ 0.2
0.05
BACTERIA
no/
0.5 ~ 1
0.02 ~ 0.2
0.01
SiO2
ppb
20 ~ 30
10
10
DO
ppm
0.1 ~ 0.5
0.1
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3.
DAEGU ARSENIC ACID WATER SPECIFICATION (DAEGU)
CHARACTERISTICS
CONDUCTIVITY
PH ( 25 )
UNIT/ppm AS
RAW
FILTERED
WATER
WATER
/cm
200
6~8
TOTAL HARDNESS
CaCO3
Ca++
CaCO3
55
Mg++
CaCO3
45
(Na+), (K+)
CaCO3
32
M-ALKALINITY
CaCO3
Cl-
50
Cl-
4.8
HCO3-
HCO3
10.7
(SO4)-
SO4-
67.2
SiO2
SiO2
7.0
Fe
Fe
Mn
Mn
TURBIDITY
DEGREE
10
0.05
0.05
100 ~ 120
50
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evaporation residue
TOTAL CATION
CaCO3
TOTAL ANION
CaCO3
5.
EAST AREA S.M WATER SPECIFICATION (YEOCHUN)
CHARACTERISTICS
UNIT/ppm AS
RAW
FILTERED
WATER
WATER
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DATE : 2006. 8. 23
CONDUCTIVITY
PH ( 25 )
/cm
TOTAL HARDNESS
CaCO3
Ca++
CaCO3
Mg++
CaCO3
(Na+), (K+)
CaCO3
Fe
M-ALKALINITY
Cl-
30 ~ 40
Fe
CaCO3
Cl-
HCO3-
HCO3-
(SO4)-
(SO4)-
SiO2
CaCO3
Mn
Mn
TURBIDITY
7 ~ 7.5
ACIDITY
CaCO3
TOTAL CATION
CaCO3
TOTAL ANION
CaCO3
30 ~ 43
1.4 ~ 2.0
6 ~ 11
2 MAX
6~8
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S.G.C COMBINAT WATER SPECIFICATION (SEOSAN)
CHARACTERISTICS
UNIT/ppm
RAW
FILTERED
COOLING
DEMI
POLISHED
BOILER
AS
WATER
WATER
WATER
WATER
WATER
FEED
WATER
CONDUCTIVITY
PH ( 25 )
s/cm
Ca++
CaCO3
Mg+
CaCO3
(Na+), (K+)
CaCO3
NH4+
CaCO3
M-ALKALINITY
10
7.7~8.2
7.0~8.2
7.0~8.0
104.5
177
174.9
194
696.1
1118
1.2
119.5
50
128.3
213
36.4
36.7
P-ALKALINITY
Cl-
HCO3-
CO3-
Cl-
HCO3-
CO3-
0.2
0.2
8.5~9.0
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130.5
-
(SO4)
(SO4)
162.2
1
Fe
Fe
0.02
5.5
SILICA
16.5
SiO2
0.2
1203.3
0.02
0.02
2100
TOTAL DISOLVED SOL.

13
20
*ORGANIC MATTER
10
-
(PO4)3
PO4
HYDRAZINE
0.01 MIN
50
TURBIDITY
12
10
DEGREE
HEAVY METALS
** 0.005
975.5
TOTAL CATION
TOTAL ANION
O2
0.007MAX
NOTE * AS KMnO4 CONSUMED

** AS COPPER
7. HANJU WATER SPECIFICATION (ULSAN)
CHARACTERISTICS
UNIT/ppm AS
RAW
FILTERED
DEMI
WATER
WATER
WATER
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DATE : 2006. 8. 23
CONDUCTIVITY
/cm
190 ~ 210
190 ~ 210
PH ( 25 )
6.5 ~ 8.5
6.5 ~ 8.5
(Na+), (K+)
ppm
10 ~ 36.8
10 ~ 36.8
NH4+
ppm
Mn++
ppm
CATION HARDNESS
ppm
44
44
TOTAL HARDNESS
ppm
68 ~ 70
68 ~ 70
M-ALKALINITY
ppm
40 ~45
40 ~45
Cl-
ppm
17 ~17.6
17 ~17.6
(SO4)-
ppm
22.6 ~ 29.8
22.6 ~ 29.8
NO3-
ppm
6.1 ~ 6.5
6.1 ~ 6.5
NO2-
ppm
Fe
ppm
0.2 ~ 1.0
0.2 ~ 1.0
SiO2
ppm
7.2
7.2
TURBIDITY
ppm
MAX 10.0
<2
TOTAL CATION
ppm
82.8 ~ 98
82.8 ~ 98
104.2 ~ 112
104.2 ~ 112
TOTAL ANION
< 10
< 0.1
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FMA
ppm
35 ~ 45
35 ~ 45
TDS
ppm
62 ~ 93
62 ~ 93
ABS
ppm
0.1 ~ 0.11
0.1 ~ 0.11
COD
ppm
4.5 ~ 8.3
4.5 ~ 8.3
8. KEUMHO Y.D.R WATER SPECIFICATION (YEOCHUN)

CHARACTERISTICS
UNIT/ppm
RAW
GROUND
PROCESS
COOLING
POTABLE
AS
WATER
WATER
WATER
WATER
WATER
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CONDUCTIVITY
PH ( 25 )
s/cm
Ca++
CaCO3
Mg++
CaCO3
(Na+), (K+)
CaCO3
6.5~8.0
6.6~6.6
50
10~11
20
29~30
60
1500~1800
6.5~8.0
6.5~8.0
50
15-~175
20
60~70
5.8~8.6
60
30
M-ALKALINITY
540 **
30
P-ALKALINITY
Cl-
HCO3-
Cl-
HCO3-
CO3-
CO3-
(SO4)-
(SO4)-
Fe
Fe
SILICA
SiO2
FREE CO2
CO2
TOTAL DISOLVED SOL.
TOTAL CATION
TOTAL ANION
3.7
16.6~15.9
10.1
200
19.8
41.3
9~10
0.3
0.066~0.08
30
6.8~6.0
1.1~1.2
130
11.2~13.1
10.1
19.8
260
3.7
49.4
148~173
0.3
0.3
30
90~105
268.5
130
780~910
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10
*ORGANIC MATTER(COD)
2
-
(PO4)
0.4~0.48
PO4
30
15~20
6~7
74
TURBIDITY (S.S)
100
BACTERIA (COLIFORM
ORGANISM)
100
MPN/100ml
100
MAX
9. YUGONG P.X SEPERATION WATER SPECIFICATION

CHARACTERISTICS
UNIT/ppm AS
CIRCULATING
MAKE-UP
COOLING WATER
COOLING WATER
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CONDUCTIVITY
PH ( 25 )
/cm
TOTAL HARDNESS
CaCO3
Ca++
CaCO3
Mg++
CaCO3
TOTAL-ALKALINITY
CaCO3
7~8
7 ~ 7.5
30 ~ 40
20 ~ 27
10 ~ 13
30 ~ 43
P-ALKALINITY
Cl-
SILICA
TURBIDITY
DISSOLVED SOLIDS
1.4 ~ 1.9
Cl-
6 ~ 11
SiO2
1~2
DEGREE
300
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10. MAIN PLANT WATER SPECIFICATION (NAJU)

CHARACTERISTICS
PROCESS
COOLING
WATER
WATER
/cm
70 ~ 210
143 ~ 320
HARDNESS
dH
2.3 ~ 3.7
4.1 ~ 7.8
PH ( 25 )
6.0 ~ 7.1
(Na+), (K+)
meq/l AS Na
0.76
meq/l
0.68 ~ 1.06
0.49 ~ 1.02
ppm
14.2 ~ 52.1
30.7 ~ 101.6
SO4-
meq/l
0.73
NO3-
ppm
SIO2
ppm
5 ~ 7.2
CO2
ppm
10
Fe
ppm
0.36 ~ 0.89
0.17 ~ 0.37
NH3
ppm
0 ~4.1
TRACE
CONDUCTIVITY
M-ALKALINITY
Cl-
EZ
UNIT/ppm AS
1.3 ~ 2.2
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DATE : 2006. 8. 23
P2O5
ppm
4.6 ~ 7.1
TOTAL CATION
meq/l
1.65
TOTAL ANION
meq/l
2.0
ppm
9.6 ~ 76.6
TURBIDITY (S.S)
11. KEUMHO SBR WATER SPECIFICATION (YEOCHUN)

CHARATERISTICS
UNIT/ppm AS
RAW WATER
7.7 ~ 11.5
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DATE : 2006. 8. 23
CONDUCTIVITY
S/cm
MAX 120
PH
6.5 - 7.5
Ca++
CaCO3
++
CaCO3
Mg
(Na+)+(K+)
Cl
CaCO3
CaCO3
MAX 10
(SO4)=
CaCO3
MAX 10
CaCO3
HCO3
NO3-
CaCO3
M-ALKALINITY
CaCO3
MAX 70
TOTAL CATION
CaCO3
100
TOTAL ANION
CaCO3
100
TOTAL HARDNESS
CaCO3
MAX 10
TURBIDITY
DEGREE
COD Mn
CaCO3
SiO2
CaCO3
10
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Attachment #2 Equipment list for raw water treatment package

ITEM NO.
SERVICE
REQ'D NO.
SPECIFICATION
FD-0100A-D
CLARIFIER
SLURRY RECIRCULATION
REMARKS
TYPE 520 m3/hr per TRAIN

AD-0100
FLOCCULATION CHAMBER
BY VENDOR
ONLY INCLINED
TYPE CLARIFIER
GD-0100A-C
FLOCCULATOR
BY VENDOR
ONLY INCLINED
TYPE CLARIFIER
FB-0100
PAC TANK
BY VENDOR
FB-0103
NaOCl TANK
BY VENDOR
GA-0100A,B
PAC PUMP
1+1
BY VENDOR
GA-0101A,B
NaOCl PUMP
1+1
BY VENDOR
FB-0104
NaOH TANK
BY VENDOR
GA-0104A,B
NaOH PUMP
1+1
BY VENDOR
AD-0102
SLUDGE CHAMBER
BY VENDOR
FD-0102
SLUDGE WATERING
BY VENDOR
EQUIPMENT
GA-0102A,B
SLUDGE FEED PUMP
1+1
BY VENDOR
GA-0103A,B
POLYELECTROLYTE PUMP
1+1
BY VENDOR
ITEM NO.
SERVICE
REQ'D NO.
SPECIFICATION
REMARKS
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DATE : 2006. 8. 23
FA-0101
POLYELECTROLYTE
BY VENDOR
BY VENDOR
7+1
GRAVITY TYPE
DISSOLVING TANK
GD-0102
POLYELECTROLYTE
TANK MIXER
FD-0103A-H
SAND FILTER
300 m3/hr per TRAIN

BACKWASH CYCLE :
ONCE A DAY/TRAIN
AD-0103
INTERMEDIATE WATER
520 m3
BY VENDOR
1+1
BY VENDOR
BASIN
AD-0104
RECOVERED WATER
PIT
GA-0104A,B
INTERMEDIATE
WATER PUMP
GA-0105A,B
BACKWASH PUMP
1+1
BY VENDOR
GA-0106A,B
RECOVERED WATER
1+1
BY VENDOR
1+1
BY VENDOR
RECYCLE PUMP
GB-0101A,B
BACKWASH BLOWER
DATE : 2006. 8. 23
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2.9
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Raw water treatment package making guide

2.9.1
General description
2.9.1.1 Clarifier unit
1) Raw Water Source: It indicates namely river,
sea, pond etc.
2) Raw water pond capacity : Generally it is
designed on a basis of 2 day (48 hrs) capacity. If
fire fighting water is stored together, the fire
fighting water capacity should be added and
designed.
3) Coagulants: The natural water has suspended
matters charging negative, they exist safely,
but if positive charged coagulants is added, they
are neutralized electrically, particles collide each
other, and precipitation is created easily.
4) Coagulant aid: It is used to promote floc.
reaction and to reduce coagulant amount used at
the early start up, the rainy season, drought.
5) NaOH: Generally a coagulant injection
increased acidity, so NaOH should be added to
neutralize.
6) Chlorine: Chlorination is executed, because
organic material disturb clarification.
2.9.1.2 Sand filter unit
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1) Gravity flow: Gravity flow is applied in gravity

type, but if we use press. Type sand, we must set
up clarified water pit and pumping.
2) Use of filtered water should be filled up.
2.9.1.3 Sludge Dewatering Unit
It could be dealt with independent vendor
package.
2.9.2
2.9.2.1 Design Basis
1)
Capacity
- Intermediate water basin: 10 -20 min.
holding. Of nor. Pump capacity
- Filtered water tank: 1 hr - 1 day above
by user.
(sgc: 2 hr, ss bp : 18 hr)
2)
Outlet Conditions
- De-muddy ability of clarifier
Water muddy degree Treated water muddy degree

20 - 100
5 below
100 above
10 below
* The muddy degree of water should be
10 ppm ~ 1000 ppm, the change of
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DATE : 2006. 8. 23
muddy degree should be below 100

ppm/hr, the change of water temp. should
be 0.5 - 1 per hour. The rising flow rate
could get to 60 mm/min., but suitable
range is 32 - 42 mm/min. in the light of
density.
- Sand filter filtering ability
Muddy degree of water
20 - 30
Muddy degree of water disposed

2 below
- pH : The acidity is increased by each
coagulant injected, if amount injected is
bulk, caustic soda should be injected to
neutralize for adequate cohesion ph
condition.
(Table 2)
TABLE 1. The coagulant and PH of proper cohesion

coagulant
pH range
strength
weakness
Al2 (SO4) 18H2O
5.5 - 8.0
cohesion is speedy and general.
Proper alkali degree is

needed.
Fe2 (SO4)3
5.5 - 11
The cohesion pH range is wide and creation of FLOC, cohesion

precipitating time is short.
FeSO4 7H2O
Ca(OH)2
8.5 - 11
FLOC is heavy and has fast
More alkali is needed and
precipitating time. Although PH is
discoloration is
high, FLOC is not dissolved.
impossible.
It is used to PH control agent and
precipitation of FLOC is better than

Na2CO3.
Na2CO3
It is used to PH control agent.
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FeCl3 6H2O
8.5 - 11
It has same property with Fe2 (SO4)3.Corrosive property is

strong.
Al(OH)mCln
wide
It is not affected by pH, and
(PAC)
cohesion effect is good.
TABLE 2. Effect of water quality that receive by coagulant and amount of alkali
that is needed to neutralize a coagulant 1 ppm.
coagulant
The change of water quality when coagulant 1 ppm is amount of alkali that is needed
added.
to neutralize a coagulant 1 ppm.
alkali degree SO4
Na2CO3
Na2CO3
Na2CO3(4
(99%)
(93%)
5%)
decrease
increase
CO2 increase CO2 increase
(ppm AS
(ppm AS
from heavy
from carbonate
CaCO3)
CaCO3)
carbonate
(ppm AS
(ppm AS
CaCO3)
CaCO3)
Al2 (SO4)3
0.45
0.45
0.40
0.20
0.48
0.36
0.80
FeSO47H2O
0.36
0.36
0.32
0.16
0.16
0.29
0.64
Fe2(SO4)3
0.68
0.67
0.60
0.30
0.30
0.54
1.21
18H2O
2.9.2.3 Specifications for the Units

1)
Clarifier Unit
(1) Clarifier type : there are slurry
recirculation type, slurry blanket type,
inclined plate type in clarifier, slurry
recirculation type is mainly used. The
cohesion effect of rotating slurry and sully
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blanket is similar, inclined blanket is more

efficient than others, but early investment
cost is expensive. if quality of water is
good, DYNA-sand filter can be used
because it has double function of clarifier
and sand filter. When muddy degree is
below 30 and clarifier setting space is
narrow, the coagulant is injected by line.
(refer to flow scheme as attached #3).
(2) Coagulants: the coagulants that is
used in cohesion precipitation are
Alh2So4 , feso3, PAC (poly aluminum
chloride), feso3(i), aluminum soda, PAC.
PAC is not affected with ph and it has
good cohesion effect. (fig.1, fig.2).
(3) Coagulant aids: it is used to promote
floc. Creation and to enhance precipitating
property by strengthening mechanical
strength and specific gravity. it is divided
by organic and inorganic matters. The
organic matter is used to cohesion agent
because cohesion effect of those is good
by minimum injection and those are not
affected by ph.
(4) NaOCl : The aim of NaOCl is to
oxidize NH3, COD, BOD, nitrous acid and
to remove taste, smell. So precipitation is
created easily.
* The effect of chlorine residue to ion
exchange resin
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: if chlorine disposal is exceed in proper

amount, smell of chlorine is excessive,
equipment is corroded , so ion exchange
resin is oxidized.
Fig. 1 Coagulant dosing effects
On Water of Low Turbidity
On Water of Low Turbidity

FIG. 2 Coagulant Dosing Effects
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Dosage of Coagulant (ppm as Alum)

2)
Sand Filter Unit

(1) Filter type: ther are gravity type and
pressure type, pressure type is used for
small space. (Table 4).
(2) Backwash: the aim of backwashing is
to remove impurities in bed.
TABLE 3. Backwashing Type and Method

TYPE
DESCRIPTION
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1. WASHING
- BACKWASHING FLOW RATE : 25 - 90 m/hr
WITH WATER
(15 - 25 % EXPANSION OF THE FILTER BED)
- 3 - 10 MIN. REQUIRED FOR COMPLETE WASHING.
* AFTER BACKWASHING, WATER SHOULD BE FILTERED TO WASTE

UNTIL THE TURBIDITY DROPS TO AN ACCEPTABLE VALUE.
THIS MAY REQUIRE FROM 2 - 20 MIN. DEPENDING ON
PRETREAMENT AND TYPE OF FILTER.
2. WASHING WITH AIR
- THIS APPLIES TO FILTER BEDS COMPOSED OF FINE SAND OR
AND WATER IN
LOW DENSITY MATERIALS.
SUCCESSION
- AIR IS USUALLY APPLIED FOR 3 OR 4 MIN. BEFORE THE BACK
WASHING BEGIN. AIR FLOW RATE : 600 - 960 m/hr
- A BACKWASH OF WATER WITH A SUFFICIENTLY HIGH FLOW RATE

TO BRING ABOUT THE EXPANSION OF THE FILTERING MATERIALS
ENABLES THE IMPURITIES DETACHED DURING THE FIRST STAGE
TO BE REMOVED FROM THE BED AND CARRIED AWAY.
3. SIMULTANEOUS
- USED IN THE SINGLE MEDIUM UNSTRATIFIED FILTER BED.
AIR AND WATER

WASHING WITHOUT
EXPANSION
- AIR AND WASH WATER ARE APPLIED SIMULTANEOUSLY FOR

SEVERAL MINUTES.
- AIR FLOW RATE : 50 m/hr
- WASH WATER RATE : MIN. 5 m/hr
- CONTINUE THE BACKWASH AT A CONSTANT RATE OF FLOW

UNTIL THE DISCHARGED WATER RUNS CLEAR.
- FLOW RATE : 12 - 20 m/hr
DATE : 2006. 8. 23
2.9.3
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Performance Guaranty
2.9.3.1 Utility and Chemical Consumption
(1) Chemical Consumption For Clarification
- Alum or Iron Sulfate
Muddy
degree
a coagulant a coagulant + (POLY-ELCTROLYTE)management

management
50PPM
below
50PPM
25PPM
50~200PP
75PPM
50PPM
200PPM
above
100PPM
75PPM
- PAC: See the table 5

- Polyelectrolytes
Polymer 0.1 % solution on a Dry Basis is used
and 0.1 ~ 0.5 ppm is injected.
- NaOCl: A mount of injection should have
0.1~0.2 ppm concentration in outlet.
TABLE 5. CHEMICAL DOSING RATE OF CLARIFIER OPERATION
CHEMICAL
CHEMICAL
SPECIFIC
DOSING RATE
INJECTION POINT
CONC.(wt%)
GRAVITY
(max ppm)
NaOH
25
1.27
10
INLET LINE
NaOCl
10
2.49
INLET LINE
PAC
1.0
1.19
10
MIXING CHAMBER
FLOC AID
0.1
1.0
MIXING CHAMBER
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2.9.3.2 Operation Cycle

Back Wash Time of Filter: Usually 10 ~ 15 min
3
DIMINERALIZED WATER
Dimineralized water system
This data sheet defines the minimum technical requirement for the water
treatment facility. Vendor shall carefully study and verify those
requirements in this sheet and shall execute all necessary design
3.1
General Description
Dimineralized water treatment facilities shall treat filtered water
fed from raw water treatment facilities to produce demineralized
water. This demineralized system shall be composed of two
trains, each having a production capacity of 500 m3/day
3.1.1
Raw Unit
Raw unit shall be adopted as pretreatment for make-up
cooling water to increase concentration number of
cooling water system and pre demineralization to reduce
the load of following demineralized unit.
Filtered water shall be fed to the safety filter through the
raw feed water heater and then to the raw unit
chemical shall be injected to control ph and to protect RO
membrane from scaling, slim formation and hydrolysis
RO treated water shall be decarbonated by the
decarbonator and then stored in the raw permeated
water tank and fed to the demineralizer unit.
3.1.2
Demineralizer Unit
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Raw treated water shall be fed to the demineralizer unit

which will be 2-bed, 3-tower type consisting oxidation
tower, de gasfier, anion tower demineralized water shall
be sent to demineralized water tank
3.1.3
Regeneration and Neutralization Unit

Sulfuric acid and caustic soda shall be used to
regenerate the ion exchanger of demineralized unit
regeneration waste water shall be neutralized and shall
be discharged to the waste water treatment facilities by
pumps together with the raw brine
3.2
Scope Definition
The unit shall be include following equipment
(1) Raw unit
(2) Demineralizer unit
(3) Regeneration and neutralization unit
: 2 train
: 2 train
: 1 ea
Further detail equipment are shown in the equipment list

attached as #1
3.3
Design Consideration
Design codes and standards
(1) Design of the facilities shall be done according to engineering
specification for this project
(2) If there is no applicable standard or code, suitable additional
standard shall be adopted upon owner's approval
DATE : 2006. 8. 23
3.3.1
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Design Basis
(1)
Design Capacity
Raw unit
:2 210m3/hr/train
Demineralizer
:2 220m3/hr/train
RO permeate tank
:1 1500 m3
Demineralizer water tank :1 1500 m3
(2)
Inlet condition
The specification of the raw water and the filtered
water refer to attachment table 1 and 2
(3)
Outlet Condition
The required specification of RO permeated
water and demineralized water are as follows
- Raw permeated water
Cl : less then 35 mg/l as cl
- Demineralized water
Conductivity: less then 10 micro s/cm
SiO2
: less then 0.2 mg/l
(4)
Chemicals and Utility Conditions

Refer to attachment #2
(5)
Effluent Specification
- neutralized waste water
pH
: 5~9
3.3.2
Winterizing
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The minimum design temperature (dry bulb temp) shall

be -14.3c resin tower
Raw unit and chemical injection system shall be installed
indoors for outdoor installation of equipments, piping, and
instrument material, winterization shall be considered.
3.3.3
Instrumentation and Control System

Automatic control system shall be applied where process
variables are to kept constant or where frequent
manipulation otherwise be required local control panel
with plc shall be installed in the local control panel control
of facilities shall be done with this local control panel in
addition to local control panel, following monitoring
function shall be supplied to DCS which will be installed
in the central control room
- Operation and regeneration status of the demineralizer

- Analyzer such as conductivity meters and silica meter
- Tank level indicator
- Flow indicators
- Alarms
3.3.4
Raw Unit
(1) Two train of raw module set shall be provided shall
have capacity of 210m3/hr
(2) Raw module shall have the following performance

after three years operation
- Recovery ratio: more then 85 %
- Chloride ion : less then 35mg/l in permeated water
(3) RO feed water heater-1 shall be provided to keep the
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water temperature from 20c to 30c using the hot cooling

water as heating water as heating medium RO feed
water heater-ll shall be provided for back of raw feed
water heater-l by using low pressure steam a
temperature control valve shall be provided on each bypass of the RO feed water heater
(4) Multiple safety filter shall be provided to allow
continuous operation at full system design capacity with
one unit out of service which shall be 10 micron meter
polyethylene cartridge type filter replacement cycle of
cartridge shall be more then 2 weeks
(5) Necessity of polishing filter shall be considered to
meet the fouling index (FI) or silt density index (SDI)
requirement of membrane supplier
(6) Chemical cleaning system for RO membrane shall be
provided
(7) RO brine shall be discharged to the waste water
treatment facilities together with neutralized regeneration
waste water from demineralized unit
(8) Automatic start/stop sequence shall be provided for
RO unit
(9) Chemical tank shall have 7 day operation
(10) RO unit except the RO permeated tank shall be
installed indoors
(11) De carbonate shall be provided for stripping CO2
gas in RO permeated water a pH meter shall be provided
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for de carbonate water

3.3.5
Demineralizer Unit
(1) Two train of demineralizer unit shall be provided and
each train shall have a full capacity of normal required
quantity when one train will be in generation another train
will be started in operation if pollutable condensate will
be divert to train, two train shall be operated
(2) The demineralizer shall be regenerated using
counter regeneration system to save chemical
consumption
(3) Demineralizer except for the demineralized water
tank shall be installed indoors
(4) Regeneration shall be conducted automatically once
a day per train
(5) Automatic sequence control system by PLC shall be
applied for the demineralizer
(6) In order to detect the endpoint of service run following
indicate recorder with alarm and conductivity recorder
with alarm shall be installed on the outlet line of the
demineralizer
(7) Conductivity recorder shall be installed on the inlet
line of the demineralizer
(8) Demineralized water to demineralized water tank
shall be controlled by a flow control valve and level
indicating alarm shall be installed in the demineralized
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water tank
(9) Resin trap shall be provided on the outlet of the
demineralizer to prevent resin from entering into
downstream equipment
(10) An integrating/indicating flow meter shall be installed
on the outlet of the demineralizer to downstream
(11) Vendor shall verify the necessity of the degasfier
considering co2 removal in the RO permeate water by
the decarbonator of RO unit
(12) When the pressure of the demineralized water pump
becomes low, the stand-by pump shall start automatically
3.3.6
Regeneration and Neutralization Unit

(1) The volume of the neutralization pit shall be such that
the amount of water from one regeneration of the
demineralizer
(2) Interlocking system shall be applied in order to
prevent simultaneous regeneration
(3) PH value of the waste water shall be adjusted from 5
to 9
3.4
(4) 10 % caustic soda will be fed by piping from outside

but an unloading connection for tank lorry shall also be
provided for caustic soda tank
Performance Guarantee
Vendor shall guarantee the following performance articles
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marked "*" shall be specified by vendor

3.4.1
Product Capacity and Quality

(1)
RO
Capacity : 210 m3/hr/train
Quality : cl less then 35 mg/l as cl
(2)
Demineralizer
Capacity : 220 m3/train

Excluding regeneration loss for
demineralizer and mixed bed polisher
Quality : conductivity less then 10 micro s/cm
less then 0.2 mg/l
3.4.2
3.4.3
Utility and Chemical Consumption

(1)
Chemicals
NaCl
*kg/day
H2SO4
*kg/day
NaOH
*kg/day
NaHSO3
*kg/day
Shmp (sodium hexametaphospate) *kg/day
NaCl (if required)
*kg/day
(2)
Power
*kw/day
Effluent
(1)
Neutralized Regeneration Waste Water

demineralizer
Quantity
Max *m3/cycle
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pH
SS
(2) RO brine
5-9
Max *mg/l
Quantity
pH
3.4.4
Max *m3/hr
*
Operation Cycle
(1)
Demineralizer
Operation cycle
Max 24 hour/cycle
Regeneration time
Max * hour/cycle
(2)
Polisher
Operation cycle
Max 336hour/cycle
Regeneration time
Max * hour/cycle
3.4.5
Attrition Loss for Resins

(1)
Demineralizer
Cation resin
*% resin
Anion resin
*% resin
3.4.6
3.5
Life of RO Membrane
* years
Battery Limit Condition

Pressure and temperature at the battery limit of the facility are
summarized as below
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INCOMING
PRESSURE
TEMPERATURE
Kg/cm2 G
MEDIUM PRESSURE STEAM
17.0
280
LOW PRESSURE STEAM
3.5
195
INSTRUMENT AIR
7.0
AMBIENT
PLANT AIR
7.0
AMBIENT
PLANT WATER
5.0
AMBIENT
COOLING WATER(SUPPLY)
4.0
32
COOLING WATER(HOT)
2.0
42
14.6
43
( TO RO FEED WATER HEATER)

10 % CAUSTIC SODA
Note 1) Temperature of processing condensate and steam condensate shall be

finalized at the detailed engineering stage
OUTGOING
PORABLE WATER
3.0
AMBIENT
ATM
AMBIENT
DEMINERALIZED WATER
6.0
AMBIENT
COOLING WATER RETURN
2.0
42
COOLING WATER
1.0
32
LOW PRESSURE STEAM
3.5
195
WASTE WATER
3.0
AMBIENT
MAKE-UP COOLING WATER
(FROM RO FEED WATER HEATER)
(NEUTRALIZED REGENERATION WASTE RO

BRINE)
Note 2) Temperature of polished water shall be finalized at the detail

engineering stage
DATE : 2006. 8. 23
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Attachment
Process flow diagram (d-u2b-1) and equipment list are attached
here with for reference
TABLE 1 SPECIFICATION OF RAW WATER

CALCIUM
mg/l AS CaCO3
104.5
MAGNESIUM
mg/l AS CaCO3
174.9
SODIUM
mg/l AS CaCO3
654.8
POTASSIUM
mg/l AS CaCO3
41.3
AMMONIUM
mg/l AS CaCO3
1.2
M-ALKALINITY
mg/l AS CaCO3
119.5
CHLORIDE
mg/l AS CaCO3
723.1
SULPHATE
mg/l AS CaCO3
135.9
NITRATE
mg/l AS CaCO3
2.4
TOTAL IRON
mg/l AS Fe
1.0
SILICA
mg/l AS SiO2
5.5
COD Mn
mg/l
13
TURBIDITY
DEGREE
1203.3
TDS
mg/l
7.7 - 8.2
pH
TABLE 2 SPECIFICATION OF FILTERED WATER

SS
mg/l
2 MAX
COD Mn
mg/l
10 MAX
TABLE 3 SPECIFICATION OF STEAM CONDENSATE

QUANTITY
NORMAL
124.5 T/H
2 max
MAXIMUN
168.5 T/H
10 max
TEMPERATURE
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NORMAL
90
MAXIMUN
100
QUALITY
PH VALUE
8-9
CONDUCTIVITY
micro S/cm
20 max
SILICA
mg/l as SiO2
0.5 max
IRON
mg/ l as Fe
0.05 max
COPPER
mg/ l as Cu
0.005 max
SUSPENDED SOLID
mg/ l as
1 max
TURBIDITY
NTU
1 max
OIL AND GREASE

COD Mn
nil
mg/ l
1 max
Note 3) Quantity and temperature shall be finalized at the detailed engineering

stage
TABLE 4 SPECIFICATION OF VACCUM STEAM CONDENSATE
QUANTITY
NORMAL
- WINTER
86.5 T/H
- SUMMER
108.7 T/H
MAXIMUN
150 T/H
TEMPERATURE
QUALITY
NOTE 4)
49
SAME AS ABOVE
NOTE 4) QUANTITY SHALL BE FINALIZED AT THE DETAIL ENGINEERING STAGE
TABLE 5 SPECIFICATION OF SM PLANT CONDENSATE

QUALITY
NORMAL
49 T/H
MAXIMUN
74 T/H
TEMPERATURE
40 - 90
Fe
mg/l
0.02 MAX
CONDUCTIVITY
micro S/cm
10 MAX
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 61 OF 68
DATE : 2006. 8. 23
QUALITY
PH
HARDNESS
8.3 - 8.6
mg/l AS CaCO3
0.1 MAX
OIL
NIL
ATTACHMENT #1 EQUIPMENT LIST FOR DEMINERALIZED WATER

TREATMENT PACKAGE
WATER TREATMENT FACILITY (PACKAGE DEALING UNIT)
ITEM NO SERVICE
REQ'D NO SPECIFICATION
REMARK
RO UNIT
CP-2201 RO UNIT
5000m3/day PER TRAIN
DA-2201 DECARBONATOR
BY VENDOR
EA-2201 RO FEED WATER HEATER l
BY VENDOR
EA-2202 RO FEED WATER HEATER ll
BY VENDOR
FB-2201 RO PERMEATED WATER TANK 1
BY VENDOR
FD-2201 SAFETY FILTER
5+1
BY VENDOR
GA-2201 RO TRANSFER PUMP
5+1
BY VENDOR
GA-2202 RO HIGH PRESSURE PUMP
5+1
BY VENDOR
GA-2203 DECARBONATE WATER PUMP 1+1
BY VENDOR
GA-2204 CHEMICAL CLEANING PUMP
BY VENDOR
GA-2205 H2SO4 PUMP
5+1
BY VENDOR
GA-2206 NaHSO3 PUMP
5+1
BY VENDOR
GA-2207 SHMP PUMP
5+1
BY VENDOR
GB-2201 DECARBONATION BLOWER
1+1
BY VENDOR
FA-2201 DECARBONATED WATER TANK 1
BY VENDOR
FA-2202 NaHSO3 TANK
BY VENDOR
FA-2203 SHMO TANK
BY VENDOR
FA-2204 CHEMICAL CLEANING TANK
BY VENDOR
CS+EPOXY LINING
DESIGN MANUAL
SEM 9522E
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for Water Treatment
PAGE 62 OF 68
DATE : 2006. 8. 23
GD-2201 CHEMICAL CLEANING TANK
BY VENDOR
BY VENDOR
MIXER
GD-2202 SHMP TANK MIXER
WATER TREATMENT FACILITY (PACKAGE DEALING UNIT)

ITEM NO SERVICE
REQ'D NO SPECIFICATION
REMARK
DEMINERALIZER UNIT
DA-2301 CATION TOWER
1+1
BY VENDOR
DA-2302 DEGASFIER
1+1
BY VENDOR
DA-2303 ANION TOWER
1+1
BY VENDOR
FB-2301 DEMINERALIZED WATER TANK 1
BY VENDOR
FA-2301 DEGASFIER WATER TANK
1+1
BY VENDOR
GA-2301 CATION TOWER FEED PUMP
1+2
BY VENDOR
GA-2302 DEGASFIER WATER PUMP
1+2
BY VENDOR
GA-2303 DEMINERALIZED WATER PUMP 1+1
BY VENDOR
GB-2301 DEGASSING BLOWER
BY VENDOR
1+1
REGENERATION AND NEUTRALIZATION UNIT

FB-2304 H2SO4 STORAGE TANK
BY VENDOR
FB-2305 NaOH STORAGE PUMP
BY VENDOR
FA-2302 H2SO4 MEASURING TANK
BY VENDOR
FA-2303 NaOH MEASURING TANK
BY VENDOR
FA-2304 RESIN MIXING AIR TANK
BY VENDOR
AD-2301 NEUTRALIZATION PIT
BY VENDOR
GB-2302 MIXING BLWER
1+1
BY VENDOR
FA-2204 CHEMICAL CLEANING TANK
BY VENDOR
GA-2307 WASTE WATER PUMP
1+1
BY VENDOR
GD-2202 REGENERATION PUMP
1+1
BY VENDOR
CS+EPOXY LINING
DATE : 2006. 8. 23
3.7
DESIGN MANUAL
SEM 9522E
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for Water Treatment
PAGE 63 OF 68
Demineralized Water System Making Guide

3.7.1
General Description
3.7.1.1 R/O Unit
It is composed of high pressure pump, module, a
measuring instrument. main activity is to remove
Nacl ,colloidal matter, organism, other organic
matter in water. 90% of nacl is removed, life of ion
exchanger resin is increased 10 times and
regeneration of ion exchanger resin is reduced.
so time and cost is reduced and discharging
equipment disposal cost is reduced one-tenth.
3.7.1.2 Demineralizer Unit (2 B 3 T)
This unit is used when many hco3- ion exist in
water. this unit consume lower anion exchanger
resin and NaOH than 2 bed 3 tower, because co2
is removed in de gasifier.
3.7.1.3 Regeneration and Neutralization Unit
It is the process that activates ion exchange resin
by injecting regeneration agent. Sulfuric acid and
caustic soda is diluted to fixed concentration
(2~5%) by ejector or pump, they are injected at
ion exchanger resin tower tail.
3.7.2
3.7.2.1 R/O Unit
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 64 OF 68
SiO2 max. Content is 30 ppm, fe is 0.3 ppm, min

is 0.1 ppm, cl2 is 1ppm in water. Membrane has
ph permission range. If ph in water exceed
permission range, ph should be controlled by
chemical injection. If residue chlorine in r/o
discharge water is in flowed to ion exchanger,
purity of pure water is decreased. So, reductant
(na2so3) should be injected.
(1) Though same materials would be used, its
capacity or effect is different by design method.
There are large tube, plate & flame, spiral wound,
hollow fine fiber type in module design. Packing
density and water output per unit volume of
hollow fine fiber are excellent but not applicable in
Korea water condition, so spiral wound is mainly
used in Korea.
(2) Generally if temp. rise 1, pass rate by
osmosis is increased 2%. Although high temp.
Solution is very economical, but membrane has
application range. If temp is different with
application temp. (25) of membrane, it should
be controlled by cooling tower or heater.
(3) Generally, if numerical value should be
controlled below 4.
(4) If r/o equipment is operated for long time,
scale and bacteria is created on the surface of
membrane, so flow rate and reject rate is
decreased. So, inorganic contamination should
be cleaned by Na3PO4, NaOH, citric acid, organic
contamination should be cleaned by triton x-100,
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 65 OF 68
2na-edta, HCHO.
(5) Vacuum degas method is used to remove
oxygen in water. Material of tower is stainless,
vacuum degree is 70cmhg - 76cmhg.
3.7.2.2 Demineralizer Unit
(1)
Counter-current
Regeneration method: -It consume lower
regeneration agent than co-current and
amount of waste water regenerated is
low.
(2)
De gasifier Set Up
- When HCO3- is high concentration in
water
(i) m-alkalinity + co 20 ppm as caco3
100 ppm as caco3 (by flour)
(ii) HCO3- concentration
30% of
total anion (flour)
De gasifier should be set up.
- The amount used of anion exchange
resin is low and so,Naoh consumption is
reduced.
- 9095 % of CO2 is deleted.
- In boiler water over 60 kg/cm2g boiler,
vacuum decarbonator is used.
- De gasfier can be used commonly in
multi-train.
3.7.2.3 Regeneration and Neutralization Unit
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 66 OF 68
DATE : 2006. 8. 23
(1)
Regeneration Water
- Cation exchange resin: natural water
use
- Anion exchange resin: de-cationized
water or pure water use.
(2)
Regeneration Chemicals
- H2SO4 is best economical in cation
exchange resin.
H2SO4 : 15% solution
HCl : 10% solution
Na2SO4 : 5% solution
- Anion exchanger resin
caustic soda : 4% solution
3.7.2.4 Chemical Consumption

(1)
Chemical Consumption
- Chemical concentration : 3.7 article
- Countercurrent, parallel regeneration method
regeneration method
counter-current
co-current
regeneration
cation resin
4060
100
Level
anion resin
4060
100
about 2 hours
about 4 hours
regeneration time
passing rate time
cation resin
(m/hr)
LV =20
LVmax =40
anion resin
LV =10
LVmax =40
LV =20
LVmax =50
LV =10
LVmax =50
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 67 OF 68
4 POTABLE WATER PACKAGE

4.1
General Description
Clarified and filtered water from the raw water treatment facilities
(filtered water) is stored in the filtered water tank. Pump is
installed for transferring feed water to the potable water unit.
NaOCl solution is injected by metering pumps for chlorination
and the concentration is controlled to maintain more than 0.2
ppm as free residual chlorine. Before chlorination, activated
carbon filter is to be installed to remove mainly color and BOD.
4.2
Scope Definition
This specification should be regarded as typical. The potable
water package will consist of the following major equipments.
4.2.1
Equipments
(1) NaOCl storage tank : 1 ea
(2) NaOCl injection pump : 2 ea
(3) Line mixer : 1 ea
(4) Activated carbon filter : 1 ea
(5) Micro filter : 1 ea
(6) Vent scrubber : 1 ea
4.2.2
Instrument, Electrical and Piping

(1) All interconnecting piping, valves, instrumentation &
control, electrical & instrument wiring within the package
to be installed.
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 68 OF 68
(2) Local control panel & MCC panel.

4.3
4.3.1
Design Conditions
1) Capacity - flow rate , max : 6.3 m3/hr
, nor : 2.1 m3/hr
2) Feed water condition
Source : filtered water
Temperature : 5-20
Pressure
- Inlet : 5.0 kg/cm2-g
- Outlet : 3.5 kg/cm2-g min
Water quality : Refer to attached sheet #1
3) Chemical Injection
Chemical : NaOCl solution (10% as Cl2)
NaOCl : 0.5 - 1.0 mg/1 (Cycle water)
Injection method : by metering pump
Injection mode : continuous
4.3.2
Equipment specifications
1) Carbon Filter
Quantity : 1 ea
COD removal - inlet : 2-5 ppm
- outlet : less than 1 ppm
Carbon- volume : 0.08 kg-cod/kg-carbon(ref. figure)
- lifetime : *
Service flow : 10 -25 m3/m2hr (ref. figure)
Backwash
- flow rate
: lv =20 m/hr (ref. figure)
- Bed expansion: 50% (ref. figure)
- time
: 30 min(ref. figure)
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 69 OF 68
Const. mat'l
: carbon steel (c.a. = 3mm)
2) NaOCl storage tank

Quantity
Holding time
Volume
Chemical
Const. mat'l
: 1 ea
: 14 days for normal consumption
: * m3
: NaOCl solution (10 % as cl2)
: C.S + PVC or PE lining
3) NaOCl injection pump

Type
Quantity
Capacity
Material
: diaphragm
: 2 ea
:*
- Diaphragm
- Head
- Cylinder
: teflon
: pvc
: sus 304
Capacity control
- Manual stroke adjustment
- Range : 0 - 100%
4) Micro-filter
Type
Quantity
Element fineness
Material
: cartridge
: 2 ea (1 stand-by)
: 10 m
- Casing
: sus 304
- Element
: sus 304
5) Line mixer
(1) Type
(2) Quantity
(3) Material
: static inline mixer

: 1 ea
- Casing: sus 304
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 70 OF 68
DATE : 2006. 8. 23
- Internal: sus 304

6) Vent scrubber
(1) Type
: water spray/packing
(2) Gas to be treated : cl2 gas evolved above 30
(3) Evolved gas
- flow rate
:*
- concentr'n : *
(4) Treated gas
- concentr'n : *
(4) Material
- tower : pvc
- Packing
: pvc
- Internal
: pvc
(5) Dimension
- tower dia
:*
- Tower height : *
- Bed height : *
4.3.3
Instrumentation, Piping, and Electrical

(1) All interconnecting piping, valves, instrumentation and
control, electrical and instrument wiring within the
package to be included in contractor's scope.
(2) Local control panel and MCC panel to be included.
4.4
Flow Scheme
Refer to attached schematic flow diagram
4.5
Remarks
(1) Vendor to state marked as *
(2) Piping material: CS + PE or PVC lining with bronze valves
(3) Cl2 evolution from the NaOCl storage tank shall be reduced
enough to meet environmental regulations.
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 71 OF 68
(4) Vendor shall submit calculation basis for vent scrubber

design if purchaser request to get governmental approval.
(5) Residual cl2 analyzer with low alarm and recorder to be
supplied.
(6) Vendor shall submit deviation list for those items that do not
follow the specifications described here.
4.6
Attachment
#1. Raw water specification
#2. Raw water specification (well water)
#3. Flow scheme
DATE : 2006. 8. 23
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 72 OF 68
Attached #1. raw water specification

====================================
pH( 25 )
Conductivity
Total hardness
Ca++
Mg++
(Na+) + (K+)
NH4+
m-alkalinity
ClNO3SO4SiO2
Free CO2
Turbidity
COD(mn)
Total cation
Total anion
Color
s/cm
ppm as caco3
ppm as caco3
ppm as caco3
ppm as caco3
ppm as caco3
ppm as caco3
ppm as caco3
ppm as caco3
ppm as caco3
ppm as sio2
ppm as co2
degree
ppm as caco3
ppm as caco3
degree
6.5-8.5
420
70.0
41.2
28.8
105.5
3.3
45.0
79.3
8.3
47.4
7.0
7.0
less than 2
3.5
178.9
180.0
-
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 73 OF 68
DATE : 2006. 8. 23
Attached #2. raw water specification (well water)

=================================================
pH ( 25 )
Conductivity
s/cm
2+,3+
Fe
mg/
T-Fe
mg/
NH3
mg/
T-Na
mg/
+
Na
mg/
K+
mg/
3+,6+
Cr
mg/
Total alkalinity mgcaco3/
SO32mg/
Clmg/
4+
Si
mg/
BOD
mg/
TDS
mg/
Turbidity
degree
7.3
230
<0.01
<0.01
0.1
2.2
2.2
0.15
<0.02
120
3.2
2.2
20
0.6
144
30
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 74 OF 68
DATE : 2006. 8. 23
ATTACHED #3. FLOW SCHEME

FIL T E R ED
W A T ER
A C T IV A T ED
CA RB ON
FIL T E R
V E NT
SCR UB BE R
LS
HY POC HLOR INA TOR

POT A B LE
W A T ER
T A NK
M
HY POCHLOR INE
C
PUMP
ST A T IC
MIX E R
MICR O
FIL T E R
M
S
POT A B LE
W A T ER
PUMP
DATE : 2006. 8. 23
4.7
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 75 OF 68
Potable Water Making Guide

4.7.1
General Description
1) Raw water source: filtered water / underground wellwater
2) Activated carbon filter: I is main aim to remove
chromaticity and organic matter.
According to degree, ii is not used.
(The quality of water standard table: attachment #1)
4.7.2
Scope Definition
4.7.2.1 Instrument, Electrical & Piping
NaOCl line usually use PVC, C.S + PP, PE lining
but after mixing, it use sus or C.S.
4.7.3
4.7.3.1 Design Conditions
1) Chemical Injection: 10% NaOCl (as Cl) is
normally available and used without dilution.
4.7.3.2 Equipment Specifications
1) Carbon Filter : carbon characteristics should
be carefully checked to meet performance.
2) NaOCl : Although frp, PE tank could be used, if
nozzle connection is weak, it is not used.
3) NaOCl Injection Pump : on a base of injection
DESIGN MANUAL
SEM 9522E
REV. : 0
for Water Treatment
PAGE 76 OF 68
DATE : 2006. 8. 23
amount (1 - 2 ppm), it must be choose to (0 - 100

%)
Ex)
Flow rate : 2 m/hr
w = 2 1 = 2 g/hr 2/hr
Pump capacity = 4/hr
Pump material : if we consider durability of liquid
contacting part, we can use alloy steel.
4) Micro Filter
material : cs is used to casting, sus304, polyester
is used to element.
5) Vent Scrubber
It is used to catch CI gas by water-spray. CI gas
is created with thermal disjointing
NaOCl is used to pasteurization agent in more
30.
Bed-height : usually 300500 mm
Dia : 200400
5
REVISION HISTORY
Rev
Date
Page
06.08.23
All
Revision Status
- Team : Process Eng'g Team

- Made by : G.O. Jung
- Checked by : J.C. Ro, E.D. Lee, Henry Sung, B.S. Son
- Approved by : C.S. Jung
ATTACHMENT
#1. Each country water quality standard table
country name
Korea
W.H.O
America
Japan
N(NH3)
0.5 below
0.5 below
N(nitrous acid.)
10 below (total sum)
10 below (total sum)
n(nitric acid)
10 below
40(80) below
CL
150 below
200(400) below
20 below
200 below
10 below
10 below
10 below
a bacterium
100 below in 1cc
100 below in 1cc
100 below in 1cc
a colon bacillus
detecting failure in
50cc
50cc
CN
detecting failure
0.01 below
0.01(0.2) below
detecting failure
Hg-
detecting failure
0.05 below
detecting failure
organic phosphor
detecting failure
detecting failure
Cu
1.0 below
1.0 below
1.0 below
1.0 below
Fe
0.3 below
0.3(1.0) below
0.3 below
0.3 below
1.0 below
1.0(1.5) below
0.8-1.7(1.4-2.4)
0.8 below
Pb
0.1 below
0.1 below
(0.05)below
0.1 below
Zn
1.0 below
5.0(15.0) below
5.0 below
1.0 below
Cr
0.05 below
0.05 below
(0.05 below)
0.05 below
As
0.05 below
0.2 below
0.01(0.05 below)
0.05 below
Mn
0.3 below
0.1(0.5) below
0.05 below
0.3 below
phenol
0.005 below
0.001(0.002) below
0.001 below
0.005 below
Ca
75(200) below
Mg
50(150) below
total solidity
300 below
100-500 below
as CaCO3 300 below
pH
5.8-8.5
7.0-8.5(6.5-9.2)
7.0-10.6
5.8-8.6
smell
detecting failure
Inoffensive
detecting failure
taste
detecting failure
detecting failure
detecting failure
chromaticity
5 degree below
15 below
5 degree below
muddy degree
2 degree below
5 JTU
5 JTU
2 degree below
(KMnO4 consumption)
10% below
50cc
evaporation residue
500 below
500(1000) below
500 below
SO4-
200 below
200(400) below
250 below
Se
0.05 below
(0.01below)
Ba
(1.0 below)
Cd
0.01 below
0.01 below
(0.01)below
(0.01below)
cleaning agent
0.5 below
advice0.5 below
0.5 below
0.5 below
10-9c/
Rec/e225.3
3000
beta 10-8c/
year 5.90 10'
(anion interface agent)
permition limit1.0
below
radioactivity
total
resident chlorine
0.2 above
carbon chloroform
union resident chlorine extraction amount 0.2

1.5 above
hospital life pollution
1.8 above
permition limit 0.5
100'
0.05-0.1 above
0.1 above
0.05 carbon
union resident chlorine
chloroform extraction
1.5
amount 0.2
hospital life pollution

1.8 above

SEM-9522E Water Treatment

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SAMSUNG ENGINEERING CO.

SAMSUNG ENGINEERING CO., LTD.

for Water Treatment

PURPOSE AND MAKING METHOD.....................................................

RAW WATER TREATMENT...................................................................

POTABLE WATER PACKAGE...........................................................

for Water Treatment

for Water Treatment

PURPOSE AND MAKING METHOD

2. RAW WATER TREATMENT

for Water Treatment

and to water treatment facilities as raw feed water and to cooling

Sand Filter Unit

for Water Treatment

Sludge Dewatering Unit

Sludge Dewatering Unit for details, refer to equipment

Sand Filter Unit

Chemical Injection Unit

Design Codes and Standards Specification for This

for Water Treatment

(2) If there are no applicable standards or code, suitable

for Water Treatment

Solid content in the sludge cake: min 15 %

Specifications for the Units

for Water Treatment

controlled by an automatic control valve.

Sludge Dewatering Unit

for Water Treatment

(6) All equipment except for chemical storage

Sand Filter Unit

for Water Treatment

cooling water make-up.

Chemical Injection Unit

Instrumentation and Control System.

for Water Treatment

Product Capacity and Quality

- Capacity : 520 m3/hr/train

Utility and Chemical Consumption

PAC ------------------------ * kg/day

Dewatered Sludge Cake

for Water Treatment

Filter - Operation Time: Min 24 hr/cycle

Battery Limit Conditions

for Water Treatment

(2) Equipment List

NORTH KOREA RIVER

SOUTH KOREA LIVER

for Water Treatment

HAN LIVER DOWNSTREAM

for Water Treatment

for Water Treatment

for Water Treatment

for Water Treatment

EACH PROJECT WATER SPECIFICATION

SPC NO.2 WATER SPECIFICATION (ULSAN)

for Water Treatment

EA CORPORATION. BACO3 WATER SPECIFICATION

for Water Treatment

for Water Treatment

for Water Treatment

DAEGU ARSENIC ACID WATER SPECIFICATION (DAEGU)

for Water Treatment

EAST AREA S.M WATER SPECIFICATION (YEOCHUN)