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3, October 2013
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Abstract
Microstructure of the Friction Stir welded was characterized
by its much finer grains as contrast with the grains of parent
material. At the ambient temperature 0.2 M NaHSO3 and 0.6
M NaCl solution, the electrochemical corrosion behavior of
friction stir welded 6061 aluminum alloy and 6061 parent
material were comparatively investigated by static weight
loss experiment (gravimetric test), potentiodynamic
polarization curve and scanning electron microscopy (SEM)
observation. The corrosion rate of the weld with the tool
rotation rate of 800 r/min, the traverse speed of 160 mm/min,
was less than that of the parent material; and the weld
showed more positive corrosion potential, less current
density, larger Rp (polarization resistance) than the parent
material. SEM observation showed that a few shallow pits
were presented on the surface of the weld. However, a large
number of deeper pits emerged on the surface of the parent
material.
Keywords
Friction Stir Welding (FSW); Electrochemical Corrosion; Weld;
6061 Aluminum Alloy
Introduction
Friction stir welding (FSW) was invented at The
Welding Institute (TWI) of UK in 1991 as a solid-state
joining technique that unites thermal and mechanical
aspects to produce a high quality joint, and it was
initially applied to aluminum alloys (Thoms et al. 1991;
Colligan et al. 1998; Murr et al. 1998). Because it is a
solid state joining process that no melt metal emerges
during welding, and it can avoid many defects in
fusion welding techniques, FSW has been used on
many alloys that are typically difficult to be welded
(Liu et al. 2007), and many advantages of friction stir
welding make FSW extremely attractive for the joining
of aerospace aluminum alloys and magnesium alloy.
In a relatively short duration after invention, quite a few
successful applications of FSW have been demonstrated.
Meanwhile, many researchers have devoted to
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Element
Si
Fe
Cu
Mg
Mn
Cr
Wt%
0.4
0.70
0.15
0.8
0.15
0.04
Zn
Ti
0.25 0.15
Al
bal
200
m
60 m
1 2
(1)
Sample
F
s10-6
(m2)
1160
m1
(g)
6.4494
m2
(g)
6.4428
t
(h)
24
v10-1
(g/(m2h))
2.37
v 10-1
(g/(m2h))
2.53
1160
6.4478
6.4411
24
2.41
1160
6.5848
6.5770
24
2.8
1160
6.4463
6.4346
24
4.2
1160
6.4525
6.4418
24
3.84
1188
6.6798
6.6702
24
3.37
3.8
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F
P
2000
Zim/ohm.cm2
1000
-1000
-2000
-1000
1000
2000
3000
4000
5000
6000
7000
Zre/ohm.cm2
MATERIAL
Icorr
C
Fcm2
Sample
Ecorr
mVSCE
-559.85
0.26
8.597
3496
2343
6.3
-685.11
1.45
7.852
911.9
1422
12.6
-0.2
Acm-2
F
P
-0.4
E/VSCE
-0.6
-0.8
-1.0
-1.2
-1.4
-1.6
-7
-6
-5
-4
-3
-2
-1
logI/A.cm2
EIS Results
Fig. 3 was the Nyquist plots of FSW weld and the
parent material, from which all the Nyquist complex
planes were composed of two semi-arcs. For the high
frequency region, a capacitance loop appeared, which
should be attributed to a polarization reaction
processed on the surface of the electrode, with the
attenuation of frequency, a inductive loop emerged
which was induced by the continuous absorption and
desorption of the reactants on the surface of the
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100 m
b
100 m
FIG. 5 SEM MORPHOLOGIES (a) FSW WELD AND (b)
PARENTMATERIAL
Discussion
During FSW process, the material undergoes intense
plastic deformation at elevated temperature, resulting
in generation of fine and equiaxed recrystallized
grains. The dynamic recrystallization grains caused to
the density of dislocation of the sample decreased. At
the same time, after severe plastic deformation (SPD),
the change of actual microstructure of FSWed sample
made the weld chemically homogenized. Based on the
principle of electrochemistry, the homogenization of
the chemical constituent made less prone to forming
the localized microcells; meanwhile, coupled with the
decrease of the density of the dislocation, the crystal
linear defect, or the number of the weld reduced, and
the decreased active sites (herein, the high-density
dislocations) for the anodic dissolution of weld metal
enhanced the ability of the corrosion resistance.
2122.
Ferrer, K S, Kelly, R G. Comparison of methods of removal
of corrosion products from AA2024-T3. 57 (2001):110117.
Liu, Shuhua, Liu, Meng, Wang, Deqing et al. Friction stir
welding of copper alloys.16(2007):64-67.
Lomolinoa, S, Tovob, R, Santosa, J D. On the fatigue
behaviour and design curves of friction stir butt-welded
Al alloys. 27(2005):305316.
Mahoney, M W, Rhodes, C G, Flintoff, J G et al. Properties
of friction stir welded 7075-T651 aluminum. 29(1998):
1955-1964.
Mishra, R S, Ma, Z Y. Friction stir welding and processing.
50 (2005):1-78
Murr, L E, Flores, R D, Flores, O V, et al. Friction Stir
Welding Miscrostuctural Characterization. 1 (1998):211223.
Peel, M, Steuwer, A, Preuss, M et al. Microstructure,
mechanical properties and residual stresses as a function
Conclusions
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