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EXAMINATION,
MAy_2015
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CHEMISTRY (34)

Times: 3 Hour 15 Minutes

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Max. Marks:70

q'
lnslructionst
(i) The question paper
uoer has four
fr:ur parts
oarr.q A,
A Bl
F g & D. A[ rhe parts are compursory.
(ii) write balanced chemical equations and draw lauerreJ
(iii) Use los tables and simple catcutators ir necessary.

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wnererrer asked.

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no, a,owed)

PART-A

2.

Answer atl questions :

(Answer each question in one word or in one sentence)
Express 0.000056 in scientific notation.
What is thermal energy?

3.
4.
5.

Define PH.
State modern periodic law.
What is a reducing agent?

6.

write the balanced chemical equation for the reaction

between Na2o2 and
'- water.
"-'::'
write the general erectronic configuration of 13th group
elements.
Give reason: Graphite is used as lubricant.
Write the functional group of aldehydes.
Write the IUPAC name of the compound.
CHgCH = C(CHg)z

'1.

7.
8.

L
10.

10x1=10

ll
11.

12.

13.

14.

15.
16.
17.
18.
lll
19.
20.
21.
22'
23'

PAHT.B
Answer any Five questions:
(Each question carries two marks)
State law of multiple proportions.
A vessel of 2S0 ml capacity contains a qas
at 35oC and 2.4 bar pressure. The gas
is transferred to another vessel of ,otufi" 400
ml at the same temperature. W-nai
would be its pressure?
State Octet rule.
Why Lithium shows anamolous behavior over the
other elements of the same
group?

5x2=1O

How is diborane prepared from BFg?

State Markownikoff,s rule.

Explain Friedel-Craft's alkylation with an example.

What are pesticides? Give an example.
PABT-C
Answer any Five questions:
(Each question carries three marks)
Define ronisation entharpy. How does it vary
arong a period and down the group?
Mention the favourabre conditions for the
formation of an ionic bond.
Based on VSEpR theory mention the shapes
of
a) BeCl2
b) CH4
c) NH3
Draw the energy level diagram for He2 molecule
using Mor. write its electronic
.
configuration. Calculate its
b-ond order.
Balance the foilowing redox reaction by
oxidation number method.
Cr.Oiu", + SO3;", r cti;, + SOi^- in acidic
medium.

24. a)
i)
ii)

b)

5x3=15
3

1+1+1
3
.)

Complete the following reactions

PbS(.; -F H.or,"n,.+
+ 2HrO,,, ->
What is singas ?

2Na1s1

1
1

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25.
26.

How is plaster of paris prepared? Mention its use.

Write any three anomalous behavior of carbon over other elements of the same group.
PART-D

27.

Answer any Ftve questions:

(Each question carries five marks)
a) An organic compound contains 807o carbon and 207" hydrogen. lf the
molecular lormula of the compound is 30,, determine empirical formula and
molecular formula of the compound.

28.

Define mole. Write the value of Avogadro constant.

a)

Write any four postulates of Bohr's theory

Who discovered neutrons?

Derive de-broglie's matter-wave equation.

State Hund's rule of maximum multiplicity;
What is an orbital?

Write any four assumptions of kinetic molecular theory of gases.

Define normal boiling point.

What are extensive properties? Give an example.

Define enthalpy of combustion.
State first law of thermodynamics.

2
2

a)

b)

-6)
30. a)
b)

31.

a)

b)
e)

32.

3
2

b)
b)

29.

5x5=25

a)

b)
33.

a)

b)
c)
34.

a)

b)
c)

2
1

Calculate the enthalpy of formation of methanol (CH3OH(4), given that,

enthalpy of combustion of methanol, caibon and hydrogen are, -726 KJmol'1,
-393 KJmol-1, and -286 KJmol-t respectively.
Define entropy.

State Le-Ghatelier's pri nciple.

Whai is homogeneous equilibrium? Give an example.
Give an example for the reaction in which Kp = Kc.

2
2

What are weak electrolytes? Give an example.

Calculate the [H"] of a solution of Hydrochloric acid, whose
Write the value of ionic product of pure water at 298 K.

{I

PH

is 3.6.

2
2
1

Answer any Two questions:

(Each question carries five marks)
5x2='t0
a) Explain chain isomerism with an example.
2
b) What is inductive effect?
2
c) Name the reaction intermediate formed, during homolytic fission of a covalent
bond.

OE

36.

a)

Explain the principle and calculations involved in the estimation of halogens

by carius method.

b)

How is sodium fusion extract prepared?

a)

Explaln the rnechanism of Chlorination of Benzene.

How is ethyne prepared from Calcium Carbide?

37.

b)

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