Professional Documents
Culture Documents
Product identity :
9525049810
Product type :
Curing agent
1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application :
Ready-for-use mixture :
Identified uses :
Company details :
HEMPEL A/S
Lundtoftegrdsvej 91
DK-2800 Kgs. Lyngby
Denmark
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue :
26 May 2015
21 May 2015.
Mixture
C; R34
R43
See Section 16 for the full text of the R-phrases declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
Hazard pictograms :
Signal word :
Danger
Hazard statements :
Precautionary statements :
Prevention :
Avoid breathing vapors, spray or mists. Wear protective gloves/protective clothing/eye protection/face
protection.
Response :
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove person to fresh air
and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Rinse skin
with water or shower. Take off immediately all contaminated clothing. Immediately call a POISON
CENTER or doctor.
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9525049810
3-aminomethyl-3,5,5- trimethylcyclohexylamine
2,2,4- and 2,4,4- trimethylhexamethylene diamine
2,4,6-tris(dimethylaminomethyl)phenol
triethylenetetramine
octadecanoic acid, 12-hydroxy-, reaction products with ethylenediamine
Not applicable.
Not applicable.
None known.
Product/ingredient name
Identifiers
%
67/548/EEC
3-aminomethyl-3,5,5trimethylcyclohexylamine
Xn; R21/22
C; R34
R43
R52/53
benzyl alcohol
Xn; R20/22
C; R34
R52/53
Xn; R22
C; R34
R43
R52/53
Classification
Regulation (EC) No.
1272/2008 [CLP]
Type
[1]
[1]
[1]
[1]
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact :
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation :
Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
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9525049810
Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners. In case of burns flush with water until the
pain ceases. While flushing remove clothing from the affected area unless it is burnt into the skin. If
hospital treatment is necessary flushing must continue during transfer and until the hospital staff takes
over the treatment.
Ingestion :
If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders :
No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact :
Inhalation :
May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to
decomposition products may cause a health hazard. Serious effects may be delayed following
exposure.
Skin contact :
Ingestion :
Over-exposure signs/symptoms
Eye contact :
Inhalation :
No specific data.
Skin contact :
Ingestion :
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician :
If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments :
No specific treatment.
In a fire or if heated, a pressure increase will occur and the container may burst.
Decomposition products may include the following materials: carbon oxides nitrogen oxides metal oxide/
oxides
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9525049810
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9525049810
Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :
Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection :
Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face
respirator may be required instead.
Hand protection :
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:
Recommended: Silver Shield / 4H gloves, polyvinyl alcohol (PVA), Viton
Not recommended: nitrile rubber, neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl
chloride (PVC)
Body protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing.
Chemical-resistant apron.
Respiratory protection :
If working areas have insufficient ventilation: When the product is applied by means that will not
generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P. Be sure to use an approved/certified respirator or
equivalent.
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9525049810
Liquid.
Color :
Light green
Odor :
Non-characteristic.
pH :
Flash point :
Evaporation rate :
Flammability :
Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge.
Slightly flammable in the presence of the following materials or conditions: heat.
Vapor pressure :
Vapor density :
Relative density :
1.66 g/cm
Solubility(ies) :
Partially soluble in the following materials: cold water and hot water.
Auto-ignition temperature :
Decomposition temperature :
Viscosity :
Explosive properties :
Slightly explosive in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Oxidizing properties :
Weighted average: 8 %
Water % by weight :
Weighted average: 0 %
VOC content :
35.6 g/l
TOC Content :
Solvent Gas :
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9525049810
Result
Species
Dose
Exposure
Rat
>5.01 mg/l
4 hours
LD50 Dermal
LD50 Oral
LC50 Inhalation Dusts and mists
LD50 Oral
LD50 Oral
Rabbit
Rat
Rat
Rat
Rat
1840 mg/kg
1030 mg/kg
>4178 mg/m
1230 mg/kg
910 mg/kg
4 hours
-
LD50 Dermal
Rat
1280 mg/kg
LD50 Oral
LD50 Oral
Rat
Rat
1200 mg/kg
2169 mg/kg
ATE value
Oral
Dermal
Inhalation (vapors)
6292.7 mg/kg
23835.7 mg/kg
142.5 mg/l
Irritation/Corrosion
Product/ingredient name
3-aminomethyl-3,5,5trimethylcyclohexylamine
benzyl alcohol
2,2,4- and 2,4,4trimethylhexamethylene diamine
2,4,6-tris(dimethylaminomethyl)
phenol
Result
Species
Score
Exposure
Rabbit
Rabbit
Man
Rabbit
Mouse
48 hours 16 milligrams
24 hours 100 milligrams
-
Rabbit
Rabbit
24 hours 50 Micrograms
Rabbit
24 hours 2 milligrams
Sensitizer
Product/ingredient name
3-aminomethyl-3,5,5trimethylcyclohexylamine
2,2,4- and 2,4,4trimethylhexamethylene diamine
Route of exposure
Species
Result
skin
Guinea pig
Sensitizing
skin
Guinea pig
Sensitizing
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9525049810
Category
Route of exposure
Target organs
Category
Route of exposure
Target organs
Aspiration hazard
Product/ingredient name
Result
Other information :
Result
Species
Exposure
Algae
72 hours
Aquatic plants
Daphnia
Fish
Daphnia
Algae
72 hours
48 hours
96 hours
21 days
72 hours
Algae
72 hours
Fish
96 hours
Test
Dose
Inoculum
92 - 96 % - Readily - 14 days
Product/ingredient name
3-aminomethyl-3,5,5trimethylcyclohexylamine
benzyl alcohol
2,2,4- and 2,4,4trimethylhexamethylene diamine
2,4,6-tris(dimethylaminomethyl)
phenol
Result
Aquatic half-life
Photolysis
Biodegradability
Not readily
Readily
Not readily
Not readily
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9525049810
LogPow
3-aminomethyl-3,5,5- trimethylcyclohexylamine
benzyl alcohol
2,2,4- and 2,4,4- trimethylhexamethylene diamine
2,4,6-tris(dimethylaminomethyl)phenol
0.99
0.87
0.77
0.219
BCF
Potential
1.37
-
low
low
low
low
Mobility :
Not applicable.
vPvB :
Not applicable.
14.2
Proper shipping name
14.3
Transport hazard class(es)
14.4
PG*
14.5
Env* Additional information
ADR/RID
Class
Not regulated.
No.
IMDG
Class
Not regulated.
No.
IATA
Class
Not regulated.
No.
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9525049810
C - Corrosive
Xn - Harmful
H302
H312
H314
H317
H318
H332
H412
Harmful if swallowed.
Harmful in contact with skin.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Causes serious eye damage.
Harmful if inhaled.
Harmful to aquatic life with long lasting effects.
Justification
Calculation method
Calculation method
Calculation method
Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.
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