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3 PROPERTIES
Production
3 Properties
As implied by the name, diamond-like carbon (DLC),
the value of such coatings accrues from their abilities to
provide some of the properties of diamond to surfaces
of almost any material. The primary desirable qualities are hardness, wear resistance, and slickness (DLC
lm friction coecient against polished steel ranges from
0.05-0.20[8] ). DLC properties highly depends on plasma
treatment (,[9] ([10] ) deposition parameters, like eect
of bias voltage ([11] ), DLC coating thickness ([12] ),([13] ),
interlayer thickness ([14] )etc.
However, which properties are added to a surface and to
what degree depends upon which of the 7 forms are applied, and further upon the amounts and types of diluents
added to reduce the cost of production. In 2006 the Association of German Engineers, VDI, the largest engineering association in Western Europe issued an authoritative
report VDI2840[15] in order to clarify the existing multiplicity of confusing terms and trade names. It provides a
unique classication and nomenclature for diamond-likecarbon (DLC) and diamond lms. It succeeded in reporting all information necessary to identify and to compare
3.1
Hardness
dierent DLC carbon lms which are oered on the market. Quoting from that document:
These [sp3 ] bonds can occur not only with
crystals - in other words, in solids with longrange order - but also in amorphous solids
where the atoms are in a random arrangement.
In this case there will be bonding only between
a few individual atoms and not in a long-range
order extending over a large number of atoms.
The bond types have a considerable inuence
on the material properties of amorphous carbon lms. If the sp2 type is predominant the
lm will be softer, if the sp3 type is predominant the lm will be harder.
A secondary determinant of quality was found to be the
fractional content of hydrogen. Some of the production
methods involve hydrogen or methane as a catalyst and
a considerable percentage of hydrogen can remain in the
nished DLC material. When it is recalled that the soft
plastic, polyethylene is made from carbon that is bonded
purely by the diamond-like sp3 bonds, but also includes
chemically bonded hydrogen, it is not surprising to learn
that fractions of hydrogen remaining in DLC lms degrade them almost as much as do residues of sp2 bonded
carbon. The VDI2840 report conrmed the utility of locating a particular DLC material onto a 2-dimensional
map on which the X-axis described the fraction of hydrogen in the material and the Y-axis described the fraction of sp3 bonded carbon atoms. The highest quality
of diamond-like properties was armed to be correlated
with the proximity of the map point plotting the (X,Y)
coordinates of a particular material to the upper left corner at (0,1), namely 0% hydrogen and 100% sp3 bonding.
That pure DLC material is ta-C and others are approximations that are degraded by diluents such as hydrogen,
sp2 bonded carbon, and metals. Valuable properties of
materials that are ta-C, or nearly ta-C follow.
STM image of surfaces at the edge of a 1 m thick layer of ta-C
3.1
Hardness
diamond-like coating on 304 stainless steel after various durations of tumbling in a slurry of 240 mesh SiC abrasive. The rst
100 min shows a burnishing away from the coating of an overburden of soft carbons than had been deposited after the last
cycle of impacts converted bonds to sp3 . On the uncoated part of
the sample, about 5 m of steel were removed during subsequent
tumbling while the coating completely protected the part of the
sample it covered.
4 APPLICATIONS
3.2
3.3
Tribology
3.4 Electrical
If a DLC material is close enough to ta-C on plots of
bonding ratios and hydrogen content it can be an insulator
with a high value of resistivity. Perhaps more interesting
is that if prepared in the medium cobblestone version
such as shown in the above gure, electricity is passed
through it by a mechanism of hopping conductivity. In
this type of conduction of electricity the electrons move
by quantum mechanical tunneling between pockets of
conductive material isolated in an insulator. The result
is that such a process makes the material something like
a semiconductor. Further research on electrical properties is needed to explicate such conductivity in ta-C in
order to determine its practical value. However, a different electrical property of emissivity has been shown to
occur at unique levels for ta-C. Such high values allow for
electrons to be emitted from ta-C coated electrodes into
vacuum or into other solids with application of modest
levels of applied voltage. This has supported important
advances in medical technology.
4 Applications
Applications of DLC typically utilize the ability of the
material to reduce abrasive wear. Tooling components,
such as endmills, drill bits, dies and molds often use DLC
in this manner. DLC is also used in the engines of modern
supersport motorcycles, Formula 1 racecars, NASCAR
vehicles, and as a coating on hard-disk platters and harddisk read heads to protect against head crashes. Virtually
all of the multi-bladed razors used for wet shaving have
the edges coated with hydrogen-free DLC to reduce friction, preventing abrasion of sensitive skin. It is also being
used as a coating by some weapon manufacturers/custom
gunsmiths. Some forms have been certied in the EU for
food service and nd extensive uses in the high-speed actions involved in processing novelty foods such as "chips"
and in guiding material ows in packaging foodstus with
plastic wraps. DLC coats the cutting edges of tools for the
high-speed, dry shaping of dicult exposed surfaces of
wood and aluminium, for example on automobile dashboards.
Medical applications: The wear, friction, and electrical properties of DLC make it an appealing material for
medical applications. Fortunately, DLC has proved to
have excellent bio-compatibility as well. This has enabled many medical procedures, such as Percutaneous
Despite the favorable tribological properties of DLC it coronary intervention employing brachytherapy to benet
must be used with caution on ferrous metals. If it is used from the unique electrical properties of DLC. At low voltat higher temperatures, the substrate or counter face may ages and low temperatures electrodes coated with DLC
carburize, which could lead to loss of function due to a can emit enough electrons to be arranged into dispos-
5
able, micro-X-ray tubes as small as the radioactive seeds
that are introduced into arteries or tumors in conventional brachytherapy. The same dose of prescribed radiation can be applied from the inside, out with the additional possibility to switch on and o the radiation in the
prescribed pattern for the X-rays being used. DLC has
proved to be an excellent coating to prolong the life of
and reduce complications with replacement hip joints and
articial knees. It also has been successfully applied to
coronary artery stents, reducing the incidence of thrombosis. The implantable human heart pump can be considered the ultimate biomedical application where DLC
coating is used on blood contacting surfaces of the key
components of the device.
The Space Black stainless steel Apple Watch[16] is coated
with diamond-like carbon.
Environmental
benets
durable products
of
7 References
[1] Robertson, J. (2002). Diamond-like amorphous carbon.
Materials Science and Engineering: R: Reports 37 (46):
129. doi:10.1016/S0927-796X(02)00005-0.
[2] Name Index of Carbon Coatings
[3] Kran, B.; et al.
(2009).
Tribological behavior of tungsten-doped DLC coating under oil lubrication.
Tribology International 42 (2): 229.
doi:10.1016/j.triboint.2008.06.011.
[4] Evtukh, A.A; et al. (2001). Silicon doped diamondlike carbon lms as a coating forimprovement of electron eld emission.
Proceedings of the 14th International Vacuum Microelectronics Conference: 295.
doi:10.1109/IVMC.2001.939770.
[5] Louis Bergeron (Oct 17, 2011). Amorphous Diamond,
a New Super-Hard Form of Carbon Created Under Ultrahigh Pressure. Science Daily. Retrieved 2011-10-21.
An amorphous diamond -- one that lacks the crystalline
structure of diamond, but is every bit as hard -- has been
created by a Stanford-led team of researchers. ... That
uniform super-hardness, combined with the light weight
that is characteristic of all forms of carbon -- including
diamond -- could open up exciting areas of application,
such as cutting tools and wear-resistant parts for all kinds
of transportation.
[6] Yu Lin, Li Zhang, Ho-kwang Mao, Paul Chow, Yuming Xiao, Maria Baldini, Jinfu Shu, and Wendy L. Mao.
Amorphous diamond: A high-pressure superhard carbon
allotrope. Physical Review Letters, 2011
[7] Achieving ultralow nanoscale wear
[8] DLC Coatings
[9] Argon plasma treatment on metal substrates and eects on
diamondlike carbon (DLC) coating properties By Abdul
Wasy ZIA et al. DOI: 10.1002/crat.201300171
See also
Chemical vapor deposition
Cathodic arc deposition
poly(hydridocarbyne)