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Mehl, A.;
Nogueira, L. S. C.;
Pessoa, F. L. P. 1; Silva, S. M. C.
ABSTRACT
Supercritical propane is a powerful solvent in the extraction of light hydrocarbons from crude oil residues.
The extraction efficiency is a function of pressure, temperature, oil composition and the ratio between
solvent and oil rates. This work presents the results of computer simulation studies in the investigation of
the capabilities of supercritical propane in the extraction of a light fraction from the atmospheric
distillation residuum (RAT). The experimental physical-chemical characterization of the feed was used to
generate a mixture of pseudo-components representing the RAT. It was observed that the extraction
efficiency increases with the solvent/oil ratio and the pressure, whereas it decreases with the increasing
temperature. A practically complete recovery of the light fraction was reached at 100 bar, with propane
feed at 100 C and a solvent/oil ratio of 15:1 in volumetric basis.
KEYWORDS
1. INTRODUCTION
2. LITERATURE REVIEW
Result
44.34
24.70
42
0.9193
21.8
C
382.2
410.8/427.2
441.8/457.5
475.4/493.9
512.3/530.9
568.2/587.3
607.1/627.6
649.1/673.0
700.8/726.7
750
87.8
2
5.4
0.28
0.28
0.09
86.1
12.9
0.5
8
<3 (*)
9
<1 (*)
<1 (*)
2
Method
ASTM D445
ASTM D445
ASTM D97
ASTM D 1298
ASTM D 1298
ASTM D2287
IP 143
ASTM D524
UOP 864 (LECO)
UOP384 (Kjeldahl)
UOP 269
ASTM D5291
N 2440
(*) lower than the
method quantification
limit.
MW
388.10
411.75
461.98
494.63
535.01
577.11
619.16
664.68
712.82
786.66
886.37
983.43
1080.3
1160.23
1219.08
1271.89
mfle
.100
mflRAT
mfme
%Medium_Re c. =
.100
mfmRAT
mfpe
%Heavy_Rec . =
.100
mfpRAT
%Light_Rec. =
(1)
(2)
(3)
where:
mfle - mass flow rate of pseudo-components in the
light fraction of the extract stream;
PC
Acentric
TC (C)
(kPa)
Factor
578.50 1102.09
1.02
596.66 1017.27
1.08
621.50 939.46
1.14
639.80 872.21
1.20
661.08 791.37
1.26
683.20 720.80
1.32
705.77 662.82
1.38
728.09 609.74
1.44
750.24 560.51
1.49
784.53 490.65
1.57
830.67 407.39
1.68
873.30 344.68
1.77
926.31 268.63
1.89
970.39 219.40
1.98
1017.10 168.78
2.08
1064.14 130.00
2.18
Pressure
(bar)
60
75
90
92.8
60
75
90
100
60
75
90
100
60
75
90
100
130
150
200
130
150
200
130
150
200
130
150
200
Propane Feed
Temperature (C)
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
125
125
125
150
150
150
175
175
175
%Light_Rec.
(% mass)
1.01
1.85
3.49
3.92
0.44
2.38
8.30
15.08
2.63
17.46
45.99
68.67
18.60
67.50
99.42
99.98
100.00
100.00
100.00
99.90
100.00
100.00
98.60
100.00
100.00
78.60
99.80
100.00
%Medium_Rec.
(% mass)
0.11
0.27
0.62
0.7
0.33
0.19
0.78
1.61
0.14
1.35
5.14
7.84
1.38
8.38
27.53
44.38
71.63
79.06
85.59
59.35
77.13
93.08
34.9
66.09
96.61
21.90
50.91
97.25
%Heavy_Rec.
(% mass)
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
Zero
3.45
4.94
5.98
2.95
5.06
9.73
2.10
4.56
13.10
1.80
3.92
15.33
4. CONCLUSIONS
LIST OF ABBREVIATIONS
ACKNOWLEDGMENTS
We thank ANP (PRH-13), CNPq and FAPERJ for
financial support.
5. REFERENCES
Concha, V.; Quirino, F.; Koroishi, E.; Rivarola, F.;
Maciel, R.; Filho, R.M.; Medina, L.; Barros, R.
Simulao Computacional de Desasfaltao de
Resduo de Vcuo Realizada em Unidade Piloto.
In: RIO OIL & GAS 2008 EXPO and CONFERENCE,
Rio de Janeiro RJ, CD-ROM.
Hwang, J.; Milind, D. D.; Hanson, F. V. Dynamic
behavior of supercritical fluid extraction of a