300 2013, Vol.34, No.

11

12211,2,*
(1.

2141222.

450002)

Application of Rare Earth Luminescent Materials in Detection of Food Safety

SONG Chun-mei 1ZHI Ai-min2JIA Guo-chao2XU Chuan-lai1ZHANG Gai-ping1,2,*
(1. School of Food Science and Technology, Jiangnan University, Wuxi
214122, China2. Key Laboratory of Animal Immunology,
Ministry of Agriculture, Henan Provincial Key Laboratory of Animal Immunology, Henan Academy of Agricultural Sciences,
Zhengzhou
450002, China)
AbstractRare earth luminescent materials are one kind of new functional materials with great application potential. In
order to provide some references for further development and wider application of rare earth luminescent materials, the
types, light-emitting mechanisms, luminescent properties, preparation techniques of rare earth luminescent materials have
been reviewed. Its applications in food safety test have also been summarized. Finally, the future development of rare earth
luminescent materials has also been prospected.
Key wordsrare earth luminescent materialsfood safetydetectionimmunolabelling
TS201.6X592

1002-6630(2013)11-0300-05

doi:10.7506/spkx1002-6630-201311064

171794Gadolin

312

1947

Marinsky150

[1-3]

0.0153%

(6s 25s 25p 6)5d1

4f4f

()

2012-12-10
(3107212131272547)
(1985)E-mailzhiya007@163.com
*(1960)E-mailzhanggaiping2003@yahoo.com.cn

2013, Vol.34, No.11 301

1.1

1.3

1)

4f

2)

nsms 6

3)

4)
1

Table 1

Classication of luminescent materials according to excitation

5)

patterns

1.4

1.4.1

[8-10]

-8

10 s

10 -8s

()(

1.4.2

[11-13]

()

()

[4-7]

1.2

1.4.3

-[14-16]

4f

30000

302 2013, Vol.34, No.11

2.1

1.4.4

(TRFIA)

[17-19]

(Eu 3+Tb3+Sm3+Dy3+)

()

()

--

()

1.4.5

[20-22]

[23-26]

Bacigalupo[27]Eu3+-BCPDAIgG

1ng/mL

[28]Eu 3+

0.02g/L

91%101%Ma

Zhihong [29]Eu 3+-DTTAIgG

0.2ng/mL

76%132% [30]
2

Eu 3+ -DTTAIgG

0.5g/LIC 504.32g/L(IC 20IC 80)

1.1428.85g/L

2.2

3+

Eu

[31]Eu 3+

SDS

Eu 3+

1.2107mol/L[32]

2013, Vol.34, No.11 303

Eu3+TiO2
3+

()-()

Eu TiO 2

Eu3+TiO2

57ng/mL

-11

2.510 mol/L

[33]

3+

Eu
3+

95.5%
[39]YVO 4:Eu

Eu

0.34mol/L

2.010 -5g/L [40]()

6G(Rh6G)

2.3

2080

4.010-7mol/L[41]

(ILFLX)Tb3+

Ce()-SO3-2

5-

[34-35]

LFLX
2.510-10mol/L

[36]

1.0ng/mL

[37]

-SiO 2

[1]
[2]

. [D]. : , 2008.
. [D].
: , 2010.

[3]

, , , . [M]. :
, 2005: 35.

[4]

AUZEL F. Upconversion and anti-stokes processes with f and d ions

in solids[J]. Chemical Reviews: Columbus, 2004, 104(1): 139-174.

00.51510ng/mL
1
Fig.1

2.4

[5]

Competitive immunoassay test of chloramphenicol

applications[J]. Accounts of Chemical Research, 2011, 44(5): 322-332.

[6]

[38]Eu3+(Eu-PB)

COHEN B E. Biological imaging: beyond fluorescence[J]. Nature,

2010, 467: 407-408.

[7]

van der ENDE B M, AARTS L, MEIJERINK A. Lanthanide ions as

spectral converters for solar cells[J]. Phys Chem Chem Phys, 2009, 11:

WANG Guofeng, PENG Qing, LI Yadong. Lanthanidedoped nanocrystals: synthesis, optical-magnetic properties, and

11081-11095.
[8]

, , , . ZnO/Eu3+
[J]. , 2010, 21(6): 53-56.

[9]

, , , . Sr
0.96Al2O4: Eu2+ 0.02, Dy3+ 0.02[J]. , 2011, 74(4): 372-375.

304 2013, Vol.34, No.11

[10]

precipitation method[J]. Journal of Alloys and Compounds, 2011,

, , , . N, FeTiO2

509(8): 3638-3643.

[J]. , 2010, 25(9): 921-927.

[11]

YU Jiaguo, YU Xiaoxiao, HUANG Baibiao, et al. Hydrothermal

[23]
[24]

Chemistry, 2011, 400(9): 2847-2864.

WADIA C, WU Yue, GUL S, et al. Surfactant-assisted hydrothermal

synthesis of single phase pyrite FeS 2 nanocrystals[J]. Chemistry of

[25]

Materials, 2009, 21(13): 2568-2570.

[13]

QIAN Jiangfeng, ZHOU Min, CAO Yuliang, et al. Template-free

[14]

[26]

, . [J].

[27]

BACIGALUPO M A, MERONI G, SECUNDO F, et al. Time-resolved

, 2012, 14(5): 203-206.

Journal of Physical Chemistry C, 2010, 114(8): 3477-3482.

fluoroimmunoassay for quantitative determination of ampicillin in

HSU W H, SHENG M H, TSAI M S. Preparation of Eu-activated

cow milk samples with different fat contents[J]. Talanta, 2008, 77(1):

strontium orthosilicate (Sr1.95SiO 4: Eu0.05) phosphor by a solgel method and its luminescent properties[J]. Journal of Alloys and

126-130.
[28]

Compounds, 2009, 467(1/2): 491-495.

[15]

LI Ling, YANG H K, MOON B K, et al. Photoluminescent properties

as label[J]. Journal of Rare Earths, 2009, 27(6): 1088-1091.

[30]
[31]

NaYF4 nanocrystals for tuneable up-conversion phosphors[J]. Journal

of Alloys and Compounds, 2009, 480(2): 706-710.
[17]

[18]

LATHIKA D S, SUDARSANA K K, BALAKRISHNAN A. Rapid

by solution combustion method[J]. Materials Letters, 2011, 65(1): 35-37.

[36]
[37]

128(12): 1975-1979.

[38]
[39]

DONG Yan, WU Zhisen, HAN Xuelin, et al. Preparation of

BaMgAl 10 O 17 :Eu 2+ phosphor with small particle size by co-

, , , . YVO4: Eu
[J]. , 2011, 69(10): 1205-1210.

[40]

precipitation in nanochannels[J]. Materials Letters, 2012, 70: 101-104.

[22]

, , .
[J]. , 2010(11): 57-60.

MU Cheng, HE Junhui. Synthesis and luminescent properties of

Rare Earth (Eu2+, Tb 3+) doped Ba 3(PO 4) 2 nanowires by chemical

, , , .
[J]. , 2010, 32(6): 496-498.

by the co-precipitation method[J]. Journal of Luminescence, 2008,

[21]

, , , .
[J]. , 2009, 30(6): 32-34.

PAN Wen, NING Guiling, ZHANG Xu, et al. Enhanced luminescent

properties of long-persistent Sr2MgSi2O7: Eu2+, Dy3+ phosphor prepared

, , .
[J]. , 2011, 32(17): 380-383.

synthesis of pure and narrowly distributed Eu doped ZnO nanoparticles

[20]

, , , .
[J]. , 2011, 27(6): 261-264.

[35]

phosphors[J]. Journal of Luminescence, 2011, 131(8): 1692-1695.

[19]

.
[D]. : , 2009.

[34]

QIAN Xianhua, PU Xipeng, ZHANG Dafeng, et al. Combustion

synthesis and luminescence properties of NaY 1-x Eu x (WO 4 ) 2

, , , . Eu (3+) TiO2
[J]. , 2012, 31(2): 417-420.

[33]

propagating combustion method[J]. Materials Research Bulletin, 2008,

43(7): 1694-1701.

, , , . [J].
, 2005, 26(4): 46-48.

[32]

DONG Tiaotiao, LI Zhaohui, DING Zhengxin, et al. Characterizations

and properties of Eu 3+-doped ZnWO 4 prepared via a facile self-

, , , .
[J]. , 2012, 33(8): 216-220.

YANES A C, SANTANA-ALONSO A, MNDEZ-RAMOS J, et al.

Yb3+-Er3+co-doped sol-gel transparent nano-glass-ceramics containing

MA Zhihong, HUANG Biao, ZHANG Jue, et al. Time-resolved

uoroimmunoassay of zearalenone in cereals with a europium chelate

and sol-gel method[J]. Materials Chemistry and Physics, 2010, 119(3):

471-477.

, , , . Eu3+
[J]. , 2010, 31(20): 307-310.

[29]

of Ln2O3: Eu3+ (Ln= Y, Lu and Gd) prepared by hydrothermal process

[16]

, , , .
[J]. , 2011, 32(10): 110-114.

hydrothermal synthesis of nanoembossed mesoporous LiFePO 4

microspheres for high-performance lithium-ion batteries[J]. The

HAGAN A, ZUCHNER T. Lanthanide-based time-resolved

luminescence immunoassays[J]. Analytical and Bioanalytical

1474-1480.
[12]

, , , .
[J]. , 2006, 27(12): 886-889.

synthesis and visible-light photocatalytic activity of novel cage-like

ferric oxide hollow spheres[J]. Crystal Growth and Design, 2009, 9(3):

, , , .
[J]. , 2007, 26(1): 125-127.

[41]

, , , . [J].
, 2008, 36(6): 823-826.