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1. Shaft Work:
Shaft work
Let
dWs
d
= T.
T.
dt
dt
2N
where N = rpm of the shaft
60
2NT
Shaft work, Ws =
watts
60
But =
2. Stirring Work: Stirring work is nothing but shaft work is done on the system by using a
stirrer which is driven by a shaft.
of the weight lowered through a distance dz and T is the torque transmitted by the shaft in
rotating through an angle d, the differential work transfer to the fluid is given by
w = mgdz = Td
and the total work transfer is w = 12 mgdz = 12 W1dz = 12 Td
where W1 is the weight
lowered
3. Electrical Work: When a current flows through a resistor, taken as system, there is work
transfer into the system. This is because the current can drive a motor, the motor can drive a
pulley and the pulley can raise a weight.
System boundary
I
dC
d
Thus dC is the charge crossing a system boundary during time d. If E is the voltage
potential, the work is w = E.dC
= EI d
w = 12 EI d
dw
The electrical work is, w = lim
= EI
0
d
This is the rate at which work is transferred.
4. Work done in stretching a wire: Consider a wire as the system. If the length of the
wire in which there is a tension is changed from L to L + dL, the infinitesimal amount of work
that is done is equal to, w = - dL
The -ve sign is used because a positive value of dL means an expansion of the wire, for
which work must be done on the wire i.e., negative work.
For a finite change of length, w = - 12 dL
With in the elastic limits, if E is the modulus of the elasticity, is the stress, is the strain,
and A is the cross sectional area, then
= A = E..A
Therefore w = - E..AdL
But d = dL/L or dL = L x d
w = - dL = - E..A. L d
i.e., w = -EAL 12 d
Dr. T.N. Shridhar, Professor, NIE, Mysore
=-
AL 2
2 12
2
5. Work done in changing the area of a surface film: A film on the surface of
a liquid has a surface tension which is a property of the liquid and the surroundings. The surface
tension acts to make the surface area of the liquid a minimum. It has the unit of force per unit
length.
The work done on a homogeneous liquid film in changing its surface area by an infinitesimal
amount dA is
w = - dA
when = surface tension (N/m)
2
w = - 1 dA
Network Transfer: The network interaction between the system and the surroundings for
any process will be the algebraic sum of all types of work interaction that has taken place
between the system and the surroundings.
Therefore if W1-2 represents the net work transfer then,
W1-2 = (Wd)1-2 (Ws)1-2 (We)1-2 (Wmag)1-2 ......
+ve sign has to be used when the work transfer takes place from the system to the surroundings
and ve sign to be used when work transfer is from the surroundings to the system.
Heat: Heat is a mode of energy transfer that takes place between the system and the
surroundings solely due to the temperature difference. Thus, heat is a transient phenomenon. It
can be recognized only during a process. It is not a thermodynamic property of the system. Like
work, heat is a path function i.e., the magnitude of heat transfer between the system and
surroundings depends upon the type of process the system is undergoing.
Heat transfer always takes place from a region of higher temperature to a region of low
temperature. The magnitude of the heat transfer into unit mass of the fluid in the system during a
process from state (1) to state (2) will be written as 12 q 1 q 2 or q1 2 and not as 12 q q1 q 2
Dr. T.N. Shridhar, Professor, NIE, Mysore
12 q represents the total heat transfer that takes place when the system undergoes a change of
state from state 1 to state 2.
Sign Convention:
System
+ve
System
-ve
Heat transfer is considered as positive if it takes place from the surroundings to the system and it
is considered as negative if it takes place from the system to the surroundings.
During an adiabatic process, Q = 0
Units: Since heat is a form of energy transfer it will have the same units as that of energy. In SI
units it is expressed in Joules (J) or Kilo Joules (kJ).
Dissimilarities:
Heat is energy interaction due to temperature difference only; work is by reasons other than
temperature difference.
In a stable system, there cannot be work transfer; however there is no restriction for the
transfer of heat.
The sole effect external to the system could be reduced to rise of a weight but in the case of a
heat transfer other effects are also observed.
Heat is a low grade energy whereas work is a high grade energy.
Problems:
1. Evaluate the work done in the following processes. The systems to be considered are
underlined.
a) An agent slowly raises a body of mass 2 kg a distance of 3 mts in a gravitational field of
standard acceleration.
Solution: By definition, considering agent as the system, it does positive work. The magnitude of
work is measured by the product of the weight its lifts and the distance through which it is lifted.
W = + mg .l = 2 x 9.81 x 3 = + 58.86 J
Dr. T.N. Shridhar, Professor, NIE, Mysore
Zero
mass
1 tonne
50 N
50 N
1 tonne
No drag
Force
2. Indicate in the following cases, the heat exchange and work exchange are positive, negative
or zero, and why
a) A copper block of 1 kg heated to 1000 C is dipped into water at 150 C. Consider copper as
system.
Ans: W = 0, Q is negative
b) Heat is added to a gas in a rigid container such that pressure and temperature increases.
Consider gas as system,
Ans: W = 0, Q is positive.
c) Gas from a bottle is used to inflate a balloon which is originally flat. Consider gas as
system.
Ans: W is Positive, Q = 0
d) An insulated wire is stretched. Consider wire as a system.
Ans: W is negative, Q = 0
e) A mouse climbs 20 steps of a stair case. Consider mouse as the system.
Ans: Q = W = 0
f) Gas in an insulated cylinder expands as the piston is slowly moved outwards.
Ans: Q = 0, W is positive
g) A closed rigid vessel containing steam at a temperature of 2000C is left standing in an
atmosphere which is at 200C. Consider steam as the system.
Ans: For a closed rigid vessel, there is no change in volume and accordingly work done is
zero. i.e., W = 0. Since the steam is at a temperature higher than that of the surrounding
atmosphere, the heat is rejected to the atmosphere. i.e., heat interaction is negative or Q is
negative.
h) The air in a tyre and connecting pump the pump plunger is pushed down, forcing air into
the tyre. The tyre, pump walls and connecting tube can be thought of to be nonconducting. Consider air as a system.
Ans: W is negative and Q = 0
i) An electric current flows steadily through a resistor which is immersed in running water.
Ans: Considering resistor as system, current flows through the resistance i.e., electrical work is
done on the system We is negative
Due to the flow of current the resistor gets heated up resulting in heat transfer to the
surrounding cold water from the resistor.
Q is negative (heat transfer from the system)
j) A container with rigid non-conducting walls holds a complete electrical circuit consisting
of a heating element and charged storage battery. The temperature and pressure of the air
in the container increases.
Ans: No interaction taking place across the boundary. The system boundary does not move as the
walls are rigid. W = 0
The walls are non-conducting though the temperature inside the system increase, no heat
transfer to the surroundings can take place Q = 0
k) 0.1 kg of gas contained in an insulated cylinder expands moving the piston slowly
outwards
Ans:
The cylinder is insulated No. heat transfer is possible Q = 0
The gas expands the system boundary expands Wd is positive
Dr. T.N. Shridhar, Professor, NIE, Mysore