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Homework
Chapter 4: Aqueous Reactions and Solution Stoichiometry
Exercises: Sections 4.5: Concentration of Solutions
1.

a) Suppose you prepare 500 mL of a 0.10 M solution of some salt and then spill some of it. What happens to the
concentration of the solution left in the container?

b) A certain volume of a 0.50 M solution contains 4.5 g of a salt. What mass of the salt is present in the same volume of a
2.50 M solution? Follow ALL math work rules!

2. What is the difference between 0.50 mol of HCl and 0.50 M HCl?

3.

a) Calculate the molarity of a solution made by dissolving 0.0715 mol Na2SO4 in enough water to form 650 mL of solution.
Follow ALL math work rules!

b) How many moles of KMnO4 are present in 75.0 mL of a 0.0850 M solution? Follow ALL math work rules!

c) How many milliliters of 11.6 M HCl solution are needed to obtain 0.105 mol of HCl? Follow ALL math work rules!

4.

a) How many grams of solute are present in 50.0 mL of 1.33 M CoSO4? Follow ALL math work rules!

b) If 1.50 g of (NH4)2SO4 is dissolved in enough water to form 250. mL of solution, what is the molarity of the solution?
Follow ALL math work rules!

c) How many milliliters of 0.510 M NiCl2 contain 1.009 g of solute? Follow ALL math work rules!

5. A person suffering from hypoatremia has a sodium ion concentration in the blood of 0.118 M and a total blood volume of 4.6 L.
What mass of sodium chloride would need to be added to the blood to bring the sodium ion concentration up to 0.138 M, assuming
no change in blood volume? Follow ALL math work rules!

6. Which will contain the greater number of moles of chloride ion: 40.0 mL of 0.35 M NaCl or 25.0 mL of 0.25 M CaCl2? Follow
ALL math work rules!

7. Indicate the concentration of each ion present in the solution formed by mixing: Follow ALL math work rules!
a) 20.0 mL of 0.100 M HCl and 10.0 mL of 0.220 M HCl;

b) 15.0 mL of 0.300 M Na2SO4 and 10.0 mL of 0.100 M NaCl;

c) 3.50 g of KCl in 60.0 mL of 0.500 M CaCl2 solution (assume that the volumes are additive).

8.

a) How many milliliters of a stock solution of 12.0 M HNO3 would you have to use to prepare 0.500 L of 0.200 M HNO3?
Follow ALL math work rules!

b) If you dilute 20.0 mL of the stock solution to a final volume of 1.00 L, what will be the concentration of the diluted
solution? Follow ALL math work rules!

9. Glycerol, C3H8O3, is a substance used extensively in the manufacture of cosmetics, foodstuffs, antifreeze, and plastics. Glycerol
is a water-soluble liquid with a density of 1.2656 g/ mL at 15oC. Calculate the molarity of a solution of glycerol made by
dissolving 40.000 mL glycerol at 15oC in enough water to make 250.00 mL of solution. Follow ALL math work rules!

10. How would you prepare 250.0 mL of 0.150 M silver nitrate solution starting with pure solute? You will need to both explain
and calculate to adequately answer this question. Follow ALL math work rules!

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