Professional Documents
Culture Documents
Relevant identified uses of the substance or mixture and uses advised against
Not Available
Association / Organisation
Not Available
Alternative Number 1
Alternative Number 2
Not Available
Once connected and if the message is not in your prefered language then please dial 01
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
Poisons Schedule
GHS Classification
[1]
Legend:
S5
Metal Corrosion Category 1, Skin Corrosion/Irritation Category 2, Eye Irrit. 2, Skin Sensitizer Category 1, Chronic Aquatic Hazard Category 3
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
SIGNAL WORD
WARNING
Continued...
Chemwatch: 5141-60
Version No: 8.1.1.1
Page 2 of 8
Hazard statement(s)
H290
H315
H319
H317
H412
P234
P261
P273
Mixtures
CAS No
%[weight]
Name
68513-05-3
>50
112-57-2
<10
tetraethylenepentamine
111-40-0
<5
diethylenetriamine
Eye Contact
Skin Contact
Inhalation
Ingestion
Chemwatch: 5141-60
Version No: 8.1.1.1
Page 3 of 8
The presence of shock suggests perforation and mandates an intravenous line and fluid administration.
Damage due to alkaline corrosives occurs by liquefaction necrosis whereby the saponification of fats and solubilisation of proteins allow
deep penetration into the tissue.
Alkalis continue to cause damage after exposure.
INGESTION:
Milk and water are the preferred diluents
No more than 2 glasses of water should be given to an adult.
Neutralising agents should never be given since exothermic heat reaction may compound injury.
* Catharsis and emesis are absolutely contra-indicated.
* Activated charcoal does not absorb alkali.
* Gastric lavage should not be used.
Supportive care involves the following:
Withhold oral feedings initially.
If endoscopy confirms transmucosal injury start steroids only within the first 48 hours.
Carefully evaluate the amount of tissue necrosis before assessing the need for surgical intervention.
Patients should be instructed to seek medical attention whenever they develop difficulty in swallowing (dysphagia).
SKIN AND EYE:
Injury should be irrigated for 20-30 minutes.
Eye injuries require saline. [Ellenhorn & Barceloux: Medical Toxicology]
Fire Incompatibility
Fire Fighting
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Fire/Explosion Hazard
Minor Spills
Major Spills
Safe handling
Other information
DO NOT allow clothing wet with material to stay in contact with skin
DO NOT use aluminium, galvanised or tin-plated containers
DO NOT USE brass or copper containers / stirrers
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Store in original containers.
Keep containers securely sealed.
No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.
Chemwatch: 5141-60
Version No: 8.1.1.1
Page 4 of 8
Ingredient
Material name
TWA
STEL
Peak
Notes
diethylenetriamine
Diethylene triamine
Not Available
Not Available
Not Available
EMERGENCY LIMITS
Ingredient
TEEL-0
TEEL-1
TEEL-2
TEEL-3
tetraethylenepentamine
5 ppm
15 ppm
350 ppm
500 ppm
diethylenetriamine
1 ppm
1 ppm
1.25 ppm
100 ppm
Ingredient
Original IDLH
Revised IDLH
Not Available
Not Available
tetraethylenepentamine
Not Available
Not Available
diethylenetriamine
Not Available
Not Available
Exposure controls
Personal protection
Skin protection
Hands/feet protection
Body protection
Other protection
Thermal hazards
Chemical goggles.
Full face shield may be required for supplementary but never for primary protection of eyes.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the
wearing of lenses or restrictions on use, should be created for each workplace or task.
See Hand protection below
Wear chemical protective gloves, e.g. PVC.
Wear safety footwear or safety gumboots, e.g. Rubber
NOTE:
The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other protective
equipment, to avoid all possible skin contact.
Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed.
See Other protection below
Overalls.
P.V.C. apron.
Barrier cream.
Not Available
Recommended material(s)
Respiratory protection
CPI
BUTYL
NEOPRENE
VITON
Type AK-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI
Z88 or national equivalent)
Half-Face
Respirator
Full-Face
Respirator
Powered Air
Respirator
Continued...
Chemwatch: 5141-60
Version No: 8.1.1.1
Page 5 of 8
up to 10 x ES
AK-AUS P2
AK-PAPR-AUS /
Class 1 P2
up to 50 x ES
AK-AUS /
Class 1 P2
up to 100 x ES
AK-2 P2
AK-PAPR-2 P2 ^
^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 =
Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen
cyanide(HCN), E = Sulfur dioxide(SO2), G = Agricultural chemicals,
K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below
65 degC)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance
Physical state
1.24
Odour
Not Available
Not Available
Odour threshold
Not Available
Not Available
pH (as supplied)
>7
Decomposition temperature
Not Available
Viscosity (cSt)
Not Available
Not Available
>204
>94
Not Applicable
Taste
Not Available
Evaporation rate
Not Available
Explosive properties
Not Available
Flammability
Not Available
Oxidising properties
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Gas group
Not Available
pH as a solution(1%)
Not Available
VOC g/L
Not Available
Miscible
Not Available
Chemical stability
See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
See section 5
Inhaled
Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the
individual.
511hardamine
Inhalation of amine vapours may cause irritation of the mucous membranes of the nose and throat and lung irritation with respiratory distress and
cough. Single exposures to near lethal concentrations and repeated exposures to sublethal concentrations produces tracheitis, bronchitis,
pneumonitis and pulmonary oedema. Aliphatic and alicyclic amines are generally well absorbed from the respiratory tract.
Ingestion
Skin Contact
The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.
Ingestion of amine epoxy-curing agents (hardeners) may cause severe abdominal pain, nausea, vomiting or diarrhoea. The vomitus may contain
blood and mucous. If death does not occur within 24 hours there may be an improvement in the patients condition for 2-4 days only to be followed
by the sudden onset of abdominal pain, board-like abdominal rigidity or hypo-tension; this indicates that delayed gastric or oesophageal corrosive
damage has occurred.
Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.
511r38
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects.
Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Continued...
Chemwatch: 5141-60
Version No: 8.1.1.1
Page 6 of 8
Amine epoxy-curing agents (hardeners) may produce primary skin irritation and sensitisation dermatitis in predisposed individuals.
Eye
Chronic
510r36
Vapours of volatile amines cause eye irritation with lachrymation, conjunctivitis and minor transient corneal oedema which results in "halos"
around lights (glaucopsia, "blue haze", or "blue-grey haze"). Vision may become misty and halos may appear several hours after workers are
exposed to the substance
This effect generally disappears spontaneously within a few hours of the end of exposure, and does not produce physiological after-effects.
However oedema of the corneal epithelium, which is primarily responsible for vision disturbances, may take more than one or more days to clear,
depending on the severity of exposure. Photophobia and discomfort from the roughness of the corneal surface also may occur after greater
exposures.
Practical experience shows that skin contact with the material is capable either of inducing a sensitisation reaction in a substantial number of
individuals, and/or of producing a positive response in experimental animals.
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
IRRITATION
Not Available
tetraethylenepentamine
Not Available
TOXICITY
IRRITATION
diethylenetriamine
Not Available
Not Available
TOXICITY
IRRITATION
Not Available
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of
contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact
urticaria, involve antibody-mediated immune reactions.
Acute Toxicity
Carcinogenicity
Skin Irritation/Corrosion
Reproductivity
Mutagenicity
Aspiration Hazard
CMR STATUS
SKIN
diethylenetriamine
Sk
Persistence: Water/Soil
Persistence: Air
Not Available
Not Available
Not Available
Bioaccumulative potential
Ingredient
Bioaccumulation
Continued...
Chemwatch: 5141-60
Version No: 8.1.1.1
Not Available
Page 7 of 8
Not Available
Mobility in soil
Ingredient
Mobility
Not Available
Not Available
Marine Pollutant
HAZCHEM
NO
2X
1760
III
CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)
No relevant data
Class
Subrisk
Special provisions
223 274
Limited quantity
5L
1760
III
Corrosive liquid, n.o.s. * (contains diethylenetriamine and tetraethylenepentamine)
No relevant data
ICAO/IATA Class
8L
Special provisions
A3A803
856
60 L
852
5L
Y841
1L
1760
III
CORROSIVE LIQUID, N.O.S. (contains diethylenetriamine and tetraethylenepentamine)
Environmental hazard
Continued...
Chemwatch: 5141-60
Version No: 8.1.1.1
IMDG Class
Page 8 of 8
IMDG Subrisk
EMS Number
F-A,S-B
Special provisions
223 274
Limited Quantities
5L
"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG
Code) - Substance Index","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia
Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","Australia Inventory of Chemical Substances (AICS)","OECD List of
High Production Volume (HPV) Chemicals","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International
Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","OSPAR National List of Candidates for
Substitution United Kingdom","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations
(Spanish)","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA)
Dangerous Goods Regulations"
tetraethylenepentamine(112-57-2) is
found on the following regulatory lists
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","International Council of Chemical Associations (ICCA) - High Production Volume List","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Maritime Dangerous Goods
Requirements (IMDG Code) - Substance Index","FisherTransport Information","Australia FAISD Handbook - First Aid Instructions, Warning
Statements, and General Safety Precautions","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations
(English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production Volume (HPV)
Chemicals","Australia Inventory of Chemical Substances (AICS)","OSPAR National List of Candidates for Substitution Norway","Belgium
Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A:
Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","OSPAR National List of Candidates for Substitution
United Kingdom","Sigma-AldrichTransport Information","United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List - GESAMP Hazard Profiles","Australia
Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Hazardous Substances Information System - Consolidated
Lists","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","International Air Transport
Association (IATA) Dangerous Goods Regulations","IMO IBC Code Chapter 17: Summary of minimum requirements"
diethylenetriamine(111-40-0) is found on
the following regulatory lists
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule
5","Australia Exposure Standards","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance Index","Australia FAISD
Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","United Nations Recommendations on the Transport of
Dangerous Goods Model Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action
Codes","Australia Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV) Chemicals","OSPAR National List
of Candidates for Substitution Norway","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International
Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","OSPAR
National List of Candidates for Substitution United Kingdom","Sigma-AldrichTransport Information","United Nations Recommendations on the
Transport of Dangerous Goods Model Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List GESAMP Hazard Profiles","Australia Dangerous Goods Code (ADG Code) - Dangerous Goods List","Australia Hazardous Substances
Information System - Consolidated Lists","International Air Transport Association (IATA) Dangerous Goods Regulations","Australia Standard
for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","IMO IBC Code Chapter 17: Summary of minimum
requirements"
end of SDS
Relevant identified uses of the substance or mixture and uses advised against
Not Available
Alternative Number 1
Alternative Number 2
Not Available
Once connected and if the message is not in your prefered language then please dial 01
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
COMBUSTIBLE LIQUID, regulated for storage purposes only
Poisons Schedule
GHS Classification [1]
Legend:
S5
Flammable Liquid Category 4, Skin Corrosion/Irritation Category 2, Eye Irrit. 2, Skin Sensitizer Category 1, STOT - SE (Narcosis) Category 3,
Acute Aquatic Hazard Category 2, Chronic Aquatic Hazard Category 2
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
SIGNAL WORD
WARNING
Continued...
Chemwatch: 5141-59
Version No: 8.1.1.1
Page 2 of 8
Hazard statement(s)
H227
Combustible liquid
H315
H319
H317
H336
H401
H411
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P271
P280
P261
P370+P378
P302+P352
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Mixtures
CAS No
%[weight]
Name
25068-38-6
>60
1330-20-7
1-10
xylene
Eye Contact
Skin Contact
Inhalation
Ingestion
Chemwatch: 5141-59
Version No: 8.1.1.1
Page 3 of 8
Treat symptomatically.
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result
Fire Fighting
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
On combustion, may emit toxic fumes of carbon monoxide (CO).
Fire/Explosion Hazard
Minor Spills
Major Spills
Safe handling
Other information
DO NOT allow clothing wet with material to stay in contact with skin
Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
Store in original containers.
Keep containers securely sealed.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Ingredient
Material name
TWA
STEL
Peak
Notes
xylene
Not Available
Not Available
EMERGENCY LIMITS
Ingredient
TEEL-0
TEEL-1
TEEL-2
TEEL-3
Continued...
Chemwatch: 5141-59
Version No: 8.1.1.1
Page 4 of 8
125 / 4 / 50 ppm
500 ppm
xylene
100 ppm
130 ppm
920 ppm
2500 ppm
Ingredient
Original IDLH
Revised IDLH
Not Available
Not Available
xylene
1,000 ppm
900 ppm
Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls
can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
"adds" and "removes" air in the work environment.
Personal protection
Skin protection
Hands/feet protection
Body protection
Other protection
Thermal hazards
Recommended material(s)
Respiratory protection
CPI
PE/EVAL/PE
PVA
TEFLON
VITON
Type A Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88
or national equivalent)
Half-Face
Respirator
up to 10 x ES
A-AUS / Class
1
A-PAPR-AUS /
Class 1
up to 50 x ES
Air-line*
up to 100 x ES
A-3
100+ x ES
Air-line**
Full-Face
Respirator
Powered Air
Respirator
Chemwatch: 5141-59
Version No: 8.1.1.1
Appearance
Physical state
Page 5 of 8
Clear to yellow liquid with a very slight odour; not miscible with water.
Liquid
1.15
Odour
Not Available
Not Available
Odour threshold
Not Available
Not Available
pH (as supplied)
Not Available
Decomposition temperature
Not Available
Not Available
Viscosity (cSt)
Not Available
>120
65
Not Applicable
Taste
Not Available
Evaporation rate
Not Available
Explosive properties
Not Available
Flammability
Combustible.
Oxidising properties
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Gas group
Not Available
pH as a solution(1%)
Not Available
VOC g/L
Not Available
Immiscible
Not Available
Chemical stability
See section 7
Unstable in the presence of incompatible materials.
Product is considered stable.
Hazardous polymerisation will not occur.
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
See section 5
Inhaled
Ingestion
Skin Contact
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by narcosis, reduced alertness, loss of reflexes, lack of
coordination and vertigo.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead to narcosis, unconsciousness, even coma and possible death.
Inhalation of aerosols (mists, fumes), generated by the material during the course of normal handling, may be harmful.
Accidental ingestion of the material may be damaging to the health of the individual.
Considered an unlikely route of entry in commercial/industrial environments. The liquid may produce gastrointestinal discomfort and may be
harmful if swallowed. Ingestion may result in nausea, pain and vomiting.
Skin contact with the material may damage the health of the individual; systemic effects may result following absorption.
The material produces moderate skin irritation; evidence exists, or practical experience predicts, that the material either
produces moderate inflammation of the skin in a substantial number of individuals following direct contact, and/or
produces significant, but moderate, inflammation when applied to the healthy intact skin of animals (for up to four hours), such inflammation
being present twenty-four hours or more after the end of the exposure period.
Skin irritation may also be present after prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The
dermatitis is often characterised by skin redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and
thickening of the epidermis.
Eye
Evidence exists, or practical experience predicts, that the material may cause severe eye irritation in a substantial number of individuals and/or
may produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental animals. Eye
contact may cause significant inflammation with pain. Corneal injury may occur; permanent impairment of vision may result unless treatment is
prompt and adequate. Repeated or prolonged exposure to irritants may cause inflammation characterised by a temporary redness (similar to
windburn) of the conjunctiva (conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Chronic
On the basis, primarily, of animal experiments, concern has been expressed that the material may produce carcinogenic or mutagenic effects; in
respect of the available information, however, there presently exists inadequate data for making a satisfactory assessment.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or
biochemical systems.
Limited evidence shows that inhalation of the material is capable of inducing a sensitisation reaction in a significant number of individuals at a
greater frequency than would be expected from the response of a normal population.
Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary allergy may be accompanied by fatigue, malaise and aching.
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
IRRITATION
Nil reported
Chemwatch: 5141-59
Version No: 8.1.1.1
Page 6 of 8
xylene
Not Available
TOXICITY
IRRITATION
Not Available
XYLENE
for RTECS No: SL 6475000: (liquid grade) Equivocal tumourigen by RTECS criteria Somnolence, dyspnea, peritonitis
The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may
produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic). This form of
dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.
Reproductive effector in rats
The following information refers to contact allergens as a group and may not be specific to this product.
Contact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of
contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact
urticaria, involve antibody-mediated immune reactions.
Acute Toxicity
Carcinogenicity
Skin Irritation/Corrosion
Reproductivity
Mutagenicity
Aspiration Hazard
CMR STATUS
Not Applicable
Persistence: Water/Soil
Persistence: Air
Not Available
Not Available
Not Available
Bioaccumulative potential
Ingredient
Bioaccumulation
Not Available
Not Available
Mobility in soil
Ingredient
Mobility
Not Available
Not Available
Chemwatch: 5141-59
Version No: 8.1.1.1
Page 7 of 8
Marine Pollutant
HAZCHEM
3Z
UN number
3082
Packing group
UN proper shipping name
Environmental hazard
III
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)
No relevant data
Class
Subrisk
Special provisions
Limited quantity
5L
3082
III
Environmentally hazardous substance, liquid, n.o.s. * (contains epoxy resin)
No relevant data
ICAO/IATA Class
9L
Special provisions
A97A158
964
450 L
964
450 L
Y964
30 kg G
3082
III
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains epoxy resin)
Environmental hazard
IMDG Class
IMDG Subrisk
EMS Number
F-A,S-F
Special provisions
274 335
Continued...
Chemwatch: 5141-59
Version No: 8.1.1.1
Limited Quantities
Page 8 of 8
5L
bisphenol A/ epichlorohydrin
resin(25068-38-6) is found on the
following regulatory lists
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard
Facilities (And Their Threshold Quantity) Table 2","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) Schedule 5","WHO Model List of Essential Medicines - Adults","International Maritime Dangerous Goods Requirements (IMDG Code) Substance Index","Australia FAISD Handbook - First Aid Instructions, Warning Statements, and General Safety Precautions","United Nations
Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List
of Emergency Action Codes","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances
(AICS)","Belgium Federal Public Service Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by
Rail - Table A: Dangerous Goods List - RID 2013 (Dutch)","Australia National Pollutant Inventory","Sigma-AldrichTransport
Information","Australia High Volume Industrial Chemical List (HVICL)","United Nations Recommendations on the Transport of Dangerous
Goods Model Regulations (Spanish)","OECD Existing Chemicals Database","Australia Dangerous Goods Code (ADG Code) - Dangerous
Goods List","Australia Hazardous Substances Information System - Consolidated Lists","International Air Transport Association (IATA)
Dangerous Goods Regulations","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part
2)","Australia - New South Wales Protection of the Environment Operations (Waste) Regulation 2005 - Characteristics of trackable wastes"
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","International Maritime Dangerous
Goods Requirements (IMDG Code)","International Council of Chemical Associations (ICCA) - High Production Volume List","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","OSPAR List of Chemicals for Priority
Action","Australia Exposure Standards","International Maritime Dangerous Goods Requirements (IMDG Code) - Substance
Index","FisherTransport Information","IMO Provisional Categorization of Liquid Substances - List 3: (Trade-named) mixtures containing at least
99% by weight of components already assessed by IMO, presenting safety hazards","Australia FAISD Handbook - First Aid Instructions,
Warning Statements, and General Safety Precautions","United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations (English)","Australia Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production
Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia Drinking Water Guideline Values For Physical and
Chemical Characteristics","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Australia
Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix I","Belgium Federal Public Service Mobility and Transport,
Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID 2013
(Dutch)","UNECE - Kiev Protocol on Pollutant Release and Transfer Registers - Annex II","Australia National Pollutant Inventory","Australia Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm - Domestic
water supply quality","Australia High Volume Industrial Chemical List (HVICL)","WHO Guidelines for Drinking-water Quality - Guideline values
for chemicals that are of health significance in drinking-water","United Nations Recommendations on the Transport of Dangerous Goods Model
Regulations (Spanish)","OECD Existing Chemicals Database","GESAMP/EHS Composite List - GESAMP Hazard Profiles","Australia
Dangerous Goods Code (ADG Code) - Dangerous Goods List","International Air Transport Association (IATA) Dangerous Goods
Regulations","Australia Hazardous Substances Information System - Consolidated Lists","Australia Standard for the Uniform Scheduling of
Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia - Australian Capital Territory - Environment Protection Regulation: Ambient
environmental standards (Domestic water supply - organic compounds)","IMO IBC Code Chapter 17: Summary of minimum
requirements","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 7","International Fragrance
Association (IFRA) Survey: Transparency List","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule
6"
end of SDS
Chemical Name
Not Applicable
Not Applicable
Chemical formula
Not Applicable
Not Available
Not Applicable
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Mixed with Chockfast resin and hardener to form epoxy grouting compound..
Not Available
Association / Organisation
Not Available
Alternative Number 1
Alternative Number 2
Not Available
Once connected and if the message is not in your prefered language then please dial 01
HAZARDOUS CHEMICAL. NON-DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
Poisons Schedule
GHS Classification
[1]
Legend:
Not Applicable
STOT - RE Category 2
1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
SIGNAL WORD
WARNING
Hazard statement(s)
H373
Continued...
Chemwatch: 5141-61
Version No: 8.1.1.1
Page 2 of 7
Mixtures
CAS No
%[weight]
Name
14808-60-7
60-90
65997-17-3
1-20
glass, oxide
70657-70-4
<1
Not Available
<1
Not Available
<1
Eye Contact
Skin Contact
Inhalation
Ingestion
None known
Fire Fighting
Fire/Explosion Hazard
Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves in the event of a fire.
Prevent, by any means available, spillage from entering drains or water courses.
Use fire fighting procedures suitable for surrounding area.
Non combustible.
Not considered a significant fire risk, however containers may burn.
Chemwatch: 5141-61
Version No: 8.1.1.1
Page 3 of 7
Minor Spills
Major Spills
Safe handling
Other information
Storage incompatibility
Ingredient
Material name
TWA
STEL
Peak
Notes
0.1
mg/m3
Not
Available
Not
Available
EMERGENCY LIMITS
Ingredient
TEEL-0
TEEL-1
TEEL-2
TEEL-3
0.3 ppm
0.3 ppm
0.3 ppm
50 ppm
glass, oxide
5 ppm
15 ppm
60 ppm
500 ppm
Ingredient
Original IDLH
Revised IDLH
50 mg/m3
glass, oxide
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Not Available
Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls
can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
"adds" and "removes" air in the work environment.
Personal protection
Continued...
Chemwatch: 5141-61
Version No: 8.1.1.1
Skin protection
Hands/feet protection
Body protection
Other protection
Thermal hazards
Page 4 of 7
Recommended material(s)
Respiratory protection
Type AX-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI
Z88 or national equivalent)
Required
Half-Face
Minimum
Respirator
Protection Factor
CPI
Full-Face
Respirator
Powered Air
Respirator
up to 10 x ES
AX P1
Air-line*
AX PAPR-P1
-
up to 50 x ES
Air-line**
AX P2
AX PAPR-P2
up to 100 x ES
AX P3
Air-line*
Air-line**
AX PAPR-P3
100+ x ES
Red coloured sand granules with no odour; insoluble in water. Slightly wetted to inhibit dusting.
Physical state
Divided Solid
Odour
Not Available
Odour threshold
Not Available
pH (as supplied)
Not Applicable
Decomposition temperature
2.57
Not Available
Not Applicable
Not Available
1710
Viscosity (cSt)
Not Applicable
2330
Not Applicable
Not Available
Not Applicable
Not Available
Not Available
Oxidising properties
Not Available
Not Applicable
Not Available
Not Applicable
Not Available
Taste
Explosive properties
Not Applicable
Immiscible
Not Applicable
Not Applicable
Gas group
Not Available
pH as a solution(1%)
7 (5% slurry)
VOC g/L
Not Available
See section 7
Product is considered stable and hazardous polymerisation will not occur.
Continued...
Chemwatch: 5141-61
Version No: 8.1.1.1
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
See section 5
Page 5 of 7
Inhaled
Limited evidence or practical experience suggests that the material may produce irritation of the respiratory system, in a significant number of
individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the
irritant and then repairing the damage. The repair process, which initially evolved to protect mammalian lungs from foreign matter and antigens,
may however, produce further lung damage resulting in the impairment of gas exchange, the primary function of the lungs. Respiratory tract
irritation often results in an inflammatory response involving the recruitment and activation of many cell types, mainly derived from the vascular
system.
Ingestion
The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of
corroborating animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where
pre-existing organ (e.g liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses
producing mortality rather than those producing morbidity (disease, ill-health).
Skin Contact
Eye
Chronic
Limited evidence exists, or practical experience predicts, that the material either produces inflammation of the skin in a substantial number of
individuals following direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four
hours, such inflammation being present twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after
prolonged or repeated exposure; this may result in a form of contact dermatitis (nonallergic). The dermatitis is often characterised by skin
redness (erythema) and swelling (oedema) which may progress to blistering (vesiculation), scaling and thickening of the epidermis. At the
microscopic level there may be intercellular oedema of the spongy layer of the skin (spongiosis) and intracellular oedema of the epidermis.
Limited evidence exists, or practical experience suggests, that the material may cause eye irritation in a substantial number of individuals and/or
is expected to produce significant ocular lesions which are present twenty-four hours or more after instillation into the eye(s) of experimental
animals. Repeated or prolonged eye contact may cause inflammation characterised by temporary redness (similar to windburn) of the conjunctiva
(conjunctivitis); temporary impairment of vision and/or other transient eye damage/ulceration may occur.
Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Serious damage (clear functional disturbance or morphological change which may have toxicological significance) is likely to be caused by
repeated or prolonged exposure. As a rule the material produces, or contains a substance which produces severe lesions. Such damage may
become apparent following direct application in subchronic (90 day) toxicity studies or following sub-acute (28 day) or chronic (two-year) toxicity
tests.
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
silica crystalline - quartz
glass, oxide
IRRITATION
Y
Not Available
Not Available
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
IRRITATION
[CCINFO]*
Not Available
WARNING: For inhalation exposure ONLY: This substance has been classified by the IARC as Group 1: CARCINOGENIC TO HUMANS
GLASS, OXIDE
The International Agency for Research on Cancer (IARC) has classified occupational exposures to respirable (<5 um) crystalline silica as
being carcinogenic to humans . This classification is based on what IARC considered sufficient evidence from epidemiological studies of
humans for the carcinogenicity of inhaled silica in the forms of quartz and cristobalite. Crystalline silica is also known to cause silicosis, a
non-cancerous lung disease.
Intermittent exposure produces; focal fibrosis, (pneumoconiosis), cough, dyspnoea, liver tumours.
No significant acute toxicological data identified in literature search.
A similar spherical glass powder was nontoxic to rats at 5,000 mg/kg. All animals survived, gained weight and appeared active and healthy.
There were no signs of gross toxicity, adverse pharmacologic effects or abnormal behavior. There are no known reports of subchronic
toxicity of nonfibrous glass. There are no known reports of carcinogenicity of nonfibrous glass When tested for primary irritation potential, a
similar material caused minimal irritation to eyes and was non-irritating to skin. Dust in excess of recommended exposure limits may result in
irritation to the respiratory tract
Continued...
Chemwatch: 5141-61
Version No: 8.1.1.1
Page 6 of 7
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic
condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating
compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with
abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern,
on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine challenge testing and the lack of minimal
lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS.
No data for material. Data for isomer only as its alpha isomer; propylene glycol monomethyl ether acetate:
Acute Toxicity
Carcinogenicity
Skin Irritation/Corrosion
Reproductivity
Mutagenicity
Aspiration Hazard
CMR STATUS
Not Applicable
Persistence: Water/Soil
Persistence: Air
Not Available
Not Available
Not Available
Bioaccumulative potential
Ingredient
Bioaccumulation
Not Available
Not Available
Mobility in soil
Ingredient
Mobility
Not Available
Not Available
Marine Pollutant
HAZCHEM
NO
Not Applicable
"Australia Hazardous Substances Requiring Health Surveillance","Australia - Tasmania - Work Health and Safety Regulations 2012 Restricted hazardous chemicals","Australia Exposure Standards","Australia - Western Australia Hazardous Substances Requiring Health
Surveillance","Australia - Northern Territories Work Health and Safety National Uniform Legislation Regulations- Requirements for health
monitoring - Hazardous chemicals (other than lead) requiring health monitoring","FisherTransport Information","Australia - Tasmania
Hazardous Substances Requiring Health Surveillance","United Nations Consolidated List of Products Whose Consumption and/or Sale Have
Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments","Australia - Northern Territories Work Health and Safety
National Uniform Legislation Regulations- Restricted hazardous chemicals","Australia - Tasmania Hazardous Substances Prohibited for
Continued...
Chemwatch: 5141-61
Version No: 8.1.1.1
Page 7 of 7
Specified Uses","OECD List of High Production Volume (HPV) Chemicals","Australia Inventory of Chemical Substances (AICS)","Australia Queensland Work Health and Safety Regulation - Restricted hazardous chemicals","Australia - South Australia - Work Health and Safety
Regulations 2012 - Restricted hazardous chemicals","Australia - Western Australia Hazardous Substances Prohibited for Specified Uses or
Methods of Handling","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Australia
Occupational Health and Safety (Commonwealth Employment) (National Standards) Regulations 1994 - Hazardous Substances Requiring
Health Surveillance","Australia - South Australia - Work Health and Safety Regulations 2012 - Requirements for health monitoring - Hazardous
chemicals (other than lead) requiring health monitoring","Australia - Queensland Work Health and Safety Regulation - Hazardous chemicals
(other than lead) requiring health monitoring","Sigma-AldrichTransport Information","Australia - New South Wales - Work Health and Safety
Regulation 2011 - Requirements for health monitoring -Hazardous chemicals (other than lead) requiring health monitoring","Australia High
Volume Industrial Chemical List (HVICL)","Australia Work Health and Safety Regulations 2011 - Hazardous chemicals (other than lead)
requiring health monitoring","OECD Existing Chemicals Database","Australia - New South Wales - Work Health and Safety Regulation 2011
Restricted hazardous chemicals","Australia Hazardous Substances Information System - Consolidated Lists","Australia - New South Wales
Hazardous Substances Requiring Health Surveillance","Australia Work Health and Safety Regulations 2011 - Restricted hazardous
chemicals","Australia - Tasmania - Work Health and Safety Regulations 2012 - Requirements for Health Monitoring - Hazardous chemicals
(other than lead) requiring health monitoring","Australia - South Australia - Hazardous Substances Requiring Health Surveillance","Australia New South Wales Hazardous Substances Prohibited for Specific Uses"
glass, oxide(65997-17-3) is found on the
following regulatory lists
"FisherTransport Information","Australia Inventory of Chemical Substances (AICS)","OECD List of High Production Volume (HPV)
Chemicals","International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs","Sigma-AldrichTransport
Information","Australia Hazardous Substances Information System - Consolidated Lists"
"International Maritime Dangerous Goods Requirements (IMDG Code)","International Maritime Dangerous Goods Requirements (IMDG
Code) - Substance Index","United Nations Recommendations on the Transport of Dangerous Goods Model Regulations (English)","Australia
Dangerous Goods Code (ADG Code) - List of Emergency Action Codes","OECD List of High Production Volume (HPV) Chemicals","Australia
Inventory of Chemical Substances (AICS)","OSPAR National List of Candidates for Substitution Norway","Belgium Federal Public Service
Mobility and Transport, Regulations concerning the International Carriage of Dangerous Goods by Rail - Table A: Dangerous Goods List - RID
2013 (Dutch)","International Chemical Secretariat (ChemSec) SIN List (*Substitute It Now!)","Australia National Pollutant Inventory","United
Nations Recommendations on the Transport of Dangerous Goods Model Regulations (Spanish)","Australia Dangerous Goods Code (ADG
Code) - Dangerous Goods List","Australia Hazardous Substances Information System - Consolidated Lists","International Air Transport
Association (IATA) Dangerous Goods Regulations"
end of SDS