1.

Define thermodynamics and thermochemistry

2. State the unit of work, energy and heat. Define what joules is. State what 1 cal and
1 kcal is equivalent to in terms of joules.
3. What is the net energy? State the formula for the net energy/ to find the energy
between reactants and products.
4. List and define the two main categories of stored energy.
5. In chemistry, potential energy results from ___ and ___ between charges. The
magnitude of this energy differs with the distance between the ____. Potential
energy changes therefore takes place during the ____ of ___ or the sharing of ___
when ___ are formed. It is sometimes called ___ energy.
6. The average kinetic energy of all the particles in an object is proportional to?
7. Temperature is an intensive property. What does this mean
8. What are extensive properties and give two examples.
9. Breifly explain thermal equilibrium temperature. State what the zeroth law of
thermodynamics state.
10.Explain the relation between heat and temperature.
11.Define heat cap and state its formula.
12.Is heat capacity an intensive or extensive property? Is c an intensive/extensive
property?
13.Define c. Give another name for it.
14.Give three equations to find the c of an object.
15.T/F: If heat is absorbed into a system, the heat change is positive. If heat is lost from
a system to the surroundings, the heat change is negative.
16.Define the molar heat cap and derive three formulas for it.
17.The molar heat cap is only used when there is a change in ___ without any phase ___
or chemical reaction.
18.Define latent heat. Explain it using boiling H2O has an example.
19.A system can be described as open, closed and isolated. Explain each.
20.Explain how work by expansion is done between ethane and oxygen.
21.In an expansion (increase in volume) delta V is ___; work is done by the system so
the system loses ___ and w=
is ____
22.In contraction (decrease in volume) delta V is ___; work is done by the surroundings
on the system so the system ___ energy w=
is ____
23.State the first law of thermodynamics.
24.T/F: A system can lose or gain energy but any change in the energy of the system
must be accompanied by an equivalent change in the energy of the surroundings,
so as to ensure that the total energy of the universe is constant. i.e. Delta E system +
delta E surroundings = 0
25.What is the internal energy, U. It is proportional to?
26.The internal energy of an ideal gas at temp T has zero potential energy, so state its
equation.
27.State two equations to find the change in the internal energy, U.
28.Read pg 78, the inter conversion of heat and work
29.T/F: When heat is applied to a system it can increase the temperature or it can do
work. Whereas the increase in temp can be detected, work on the system (delta
U=0) cannot and it is therefore latent.
30.State when the change of internal energy is negative and positive.
31.Define state function

32.Give two examples of state functions and state why they are state functions. Are
state functions reversible? What is the overall value if they are reversible?
33.How are state functions recognized in an equation? How are properties which are
not state functions recognized in a system?
34.What is the purpose of a colorimeter?
35.The internal energy in a colorimeter can be measured by the equation delta internal
energy= q. Why is this so?
36.For a system in which no work is being transferred between the system and its
surroundings, the internal energy will be equal to the heat absorbed or lost by the
system to its surroundings. What does this mean? State the equation and explain.
37.State the formula for work by expansion.
38.Define the bomb calorimeter and describe its function.
39.What is enthalpy? State its symbol (be sure to remember it)
40.When a change in enthalpy is positive, the process is said to be ___. Heat is ___ by
the system and it ___ energy. When the change in enthalpy is negative, the process
is said to be _____. Heat is ___ from the system and it ___ energy.
41.The enthalpy change depends on the?
42.State what the standard state refers to
43.What is the thermochemical equation
44.Define standard enthalpy of reaction and state its symbol.
45.State Hess law.
46.State the formula of Hess law to calculate the enthalpy change.
47.State two rules for applying Hess law.
48.Define each term give, state its abbreviated form and state whether its enthalpy
change is positive or negative or both:
i.
Enthalpy change of bond dissociation
ii.
Enthalpy change of atomization
iii.
Enthalpy of combustion
iv.
Enthalpy of neutralization
v.
Enthalpy of fusion
vi.
Enthalpy of vaporization
vii.
Enthalpy of sublimation
viii.
Enthalpy change of hydration
ix.
Enthalpy change of solution
x.
Enthalpy change of first ionization and enthalpy change of electron
gain/affinity.
49.Enthalpy of atomization is the sum of all the ___ ___ in a molecule.
50.For simple diatomic molecules, enthalpy of atomization is equal to the enthalpy of
___ __.
51.State the enthalpy of neutralization for all strong acid and bases.
52.The enthalpy of sublimation is equal to the sum of?
53.Define lattice enthalpy. It depends on two factors. List them.
54.Lattice enthalpy is proportional to the? The greater the charges on the ions, the ___
the attraction between the ions and the ___ is the ___ energy.
55.Lattice enthalpy is inversely proportional to? Therefore, for compounds with the
same charges on their ions, the smaller the distance between the ions, the ___ is the
attraction between the ions and the ___ is the ___ enthalpy.
56.State the formula to find the standard enthalpy change for a chemical reaction

57.Giving a general form of an equation, show how you can find the standard enthalpy
change of the reaction.
58.Give the formula to calculate the standard enthalpy of reaction using bond enthalpy.
59.The born Haber cycle is a method of?
60.We can get an indication of the stability of a compound from its starndard enthalpy
of ____. If it is negative, the reaction is __ and the compound formed is ___ and likely
to be formed.
61.

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