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COLLEGE OF ENGINEERING
MECHANICAL ENGINEERING DEPARTMENT
EXERCISE / EXPERIMENT #
DATE PERFORMED:
DATE SUBMITTED:
FENOL, MELCHOR M.
BS M.E 4
c = QmT
Specific Heat Capacity
Heat capacity of a substance is denoted by C. It is defined as the amount of energy which
is required to increase the temperature of the substance by 1C. According to the definition, if
heat Q given to the substance increases the temperature of the substance by TT, then
Q = CT
Specific Heat Formula
Specific heat is essentially a measure of how thermally insensitive a substance is to the
addition of energy. If the specific heat capacity of a substance is more, then for a given mass m
of a substance, for a particular T temperature change, more energy Q needs to be transferred
to the substance as compared to the second substance having less specific heat capacity.
Therefore, more the specific heat capacity, more energy needs to be transferred to the substance
if the other conditions (Q, m,T ) are same.
Formula for specific heat can be written as,
c = QmT
Specific Heat Table
Specific Heat Table for some of the substances is given below at 25 0C and Standard
Atmospheric pressure
Substance
Specific Heat(J/kg. C)
1830
230
387
322
129
448
128
703
234
380
837
2090
860
1700
2400
140
4186
2010
900
540
120
830
2.3 K
Calorimetry
is the science or act of measuring changes in state variables of a body for the purpose of
deriving the heat transferassociated with changes of its state due for example to chemical
reactions, physical changes, or phase transitions under specified constraints. Calorimetry is
performed with a calorimeter. The word calorimetry is derived from the Latin word calor,
meaning heat and the Greek word (metron), meaning measure. Scottish physician and
scientist Joseph Black, who was the first to recognize the distinction
between heat and temperature, is said to be the founder of the science of calorimetry.
Indirect Calorimetry calculates heat that living organisms produce by measuring either
their production of carbon dioxide and nitrogen waste (frequently ammonia in aquatic organisms,
or urea in terrestrial ones), or from their consumption of oxygen. Lavoisier noted in 1780 that
heat production can be predicted from oxygen consumption this way, using multiple regression.
The Dynamic Energy Budget theory explains why this procedure is correct. Heat generated by
living organisms may also be measured by direct calorimetry, in which the entire organism is
placed inside the calorimeter for the measurement.
A widely used modern instrument is the differential scanning calorimeter, a device which
allows thermal data to be obtained on small amounts of material. It involves heating the sample
at a controlled rate and recording the heat flow either into or from the specimen.
Applications of calorimetry
Calorimetry is a method to measure the heat effect of a process,which could be physical
changes, such as melting, evaporation, dehydration (could also be defined as chemical change),
or it can be a chemical change, such as acid-base neutralization, dissolving, solid-state reaction,
and crystal phase transition. Calorimeter is an instrument which determines heat effect in it by
directly measurement of temperature. Calorimetry is well applied in thermochemistry field, by
determining the enthalpy formation trends, phase stability, heat capacity, surface effect, etc. This
content contains theory, introduction of different calorimeters, and will focus on the application
of high temperature oxide melt solution calorimetry in the study of different materials, such as
nanomaterial, ceramics, zeolite.
As a simple calorimeter for thermochemistry lab, coffee cup calorimeter uses Styrofoam
cups with insulated lid to prevent the heat lose and thermometer to measure the temperature
changing. It works at atmosphere pressure which is assumed as a constant. Since the enthalpy
changing is equal to heat transfer at constant pressure(H=qp), this calorimeter can be used
easily to measure the enthalpy change of some simple processes, like fusion enthalpy, dissolving
enthalpy,and determine the heat capacity (Cp) of material, such as metals. This calorimeter
usually works with well heat conducting solvents for measure convenience, such as water and
must be calibrated by a material with known heat capacity. In this type of calorimeter, heat is a
function of temperature difference, which can be written in formula:
So the change of internal energy of combustion of sample U1 and changing of internal energy of
water U2 are related by:
U1+U2=0
U1 =-U2
Since the process is at constant volume, Cv is the constant heat capacity of calorimeter and water.
U2=CvT
The enthalpy of combustion can be calculated by:
Hc=U1+PV= -U2+nRT
In which n is the change of moles of gas during the combustion. Thus, by measuring the heat
change of water, enthalpy of combustion can be obtained.
Reference: wikipedia.com