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Original article
Institute of Resources & Environment, Henan Polytechnic University, Jiaozuo 454150, China
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China
A R T I C L E I N F O
A B S T R A C T
Article history:
Received 29 July 2013
Received in revised form 4 November 2013
Accepted 8 November 2013
Available online 27 November 2013
A new 2D coordination polymer, [Cd(tpim)(1,5-nds)]n (1), was constructed from 1,5-naphthalenedisulfonate (1,5-nds), 2,4,5-tri(4-pyridyl)-imidazole (tpim) and Cd(CH3COO)22H2O, which can be
subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with
remarkable catalytic activity. In addition, the thermal and luminescent properties of 1 in the solid state
were also investigated.
2013 Xin-Yi Wang and Dong-Sheng Deng. Published by Elsevier B.V. on behalf of Chinese Chemical
Society. All rights reserved.
Keywords:
Crystal structure
Organosulfonate
Coordination polymer
Epoxide ring-opening
1. Introduction
The rational design and construction of coordination polymers
(CPs) has recently attracted considerable interest, owing to their
potential application as functional materials in molecular magnetism, catalysis, uorescent sensing, and gas sorption [14]. Although
CPs catalysis is a relatively new eld, more and more related works
are being reported by many researchers [5]. Compared with
conventional homogeneous catalysts, the use of CPs as heterogeneous catalysts has many advantages, including separation and
recovery, disposal of spent catalysts, and so on [6,7].
So far, a lot of CPs, which are constructed out of cadmium (II)
and organic bridging units, including a variety of organocarboxylate ligands, have been extensively documented [8]. However, in
comparison with other organic acid anions such as carbonates and
phosphonates, the coordination chemistry of organosulfonates is
relatively rare, probably for their weak coordinating ability,
despite similar structures [9]. Indeed, the efforts of many groups
have recently evidenced that the use of different amines alters the
size and nature of the organic region. In the right chemical
environment of metal ions, the SO3 group can compete with
water molecules and coordinate to metal ions [1012].
* Corresponding author.
** Corresponding author at: College of Chemistry and Chemical Engineering,
Luoyang Normal University, Luoyang 471022, China.
E-mail addresses: waxiyi@163.com (X.-Y. Wang), dengdongsheng168@sina.com
(D.-S. Deng).
1001-8417/$ see front matter 2013 Xin-Yi Wang and Dong-Sheng Deng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
http://dx.doi.org/10.1016/j.cclet.2013.11.045
244
Fig. 1. Coordination environment of Cd(II) in complex 1 with the ellipsoids drawn at the 30% probability level. Symmetry code: (A)
z + 1/2; (C) x, y 1, z.
x + 1/2, y,
z + 1/2; (B)
x + 1/2, y
1,
245
1200
Intensity (a.u.)
80
Weight (%)
tpim
1,5-nds
polymer 1
1000
100
60
800
600
400
40
200
20
0
0
0
200
400
600
o
Temperature ( C)
Fig. 4. Thermogravimetric analysis (TGA) curve for 1.
800
350 400 450 500 550 600 650 700 750 800 850 900
Wavelength (nm)
Fig. 5. Emission spectra of polymer 1 and its constituting ligands.
246
Table 1
The ring-opening reactions of epoxides with amines catalyzed by 1a.
OH
OH
OH
NH or
R
NH or
R
NH
2 mol% catalyst
or
O or
O
NH2
R
R = H, Cl, CH3
.
Entry
Epoxide
Amine
Yieldb (%)
1
2
3
4
5
6
7
Styrene oxide
Styrene oxide
Styrene oxide
Cyclohexene oxide
Cyclohexene oxide
Cyclopentene oxide
Cyclopentene oxide
Aniline
2-Chloroaniline
2-Methylaniline
Aniline
2-Chloroaniline
Aniline
2-Chloroaniline
a
b
c
d
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