Professional Documents
Culture Documents
S K Mondals
1.
Chapter 1
Basic Concepts
List-I
A. Heat to work
B. Heat to lift weight
C. Heat to strain energy
D. Heat to electromagnetic energy
5. Thermal radiation
6. Bimetallic strips
Codes:
A
B
C
D
(a)
3
4
6
5
(c)
3
6
4
2
1.
2.
3.
4.
(b)
(d)
List II
[GATE-1998]
Nozzle
Endothermic chemical reaction
Heat engine
Hot air balloon/evaporation
A
3
1
B
4
2
C
5
3
D
6
4
Quasi-Static Process
GATE-3.
Page 3 of 121
Basic Concepts
S K Mondals
GATE-5.
Chapter 1
(c) Both internal energy and enthalpy of the gas remain constant
(d) Both internal energy and enthalpy of the gas increase
Air is compressed adiabatically in a steady flow process with negligible change
in potential and kinetic energy. The Work done in the process is given by:
[GATE-1996, IAS-2000]
(a) Pdv
(b) + Pdv
(c) vdp
(d) + vdp
In a steady state steady flow process taking place in a device with a single inlet
and a single outlet, the work done per unit mass flow rate is given by
outlet
inlet
[GATE-2008]
outlet
vdp
GATE-7.
GATE-8.
(a ) pdv
(b) vdp
(c) Tds
(d ) sdT
IES-2.
Page 4 of 121
Basic Concepts
S K Mondals
IES-3.
IES-4.
Chapter 1
IES-7.
IES-8.
IES-9.
Page 5 of 121
Basic Concepts
S K Mondals
Chapter 1
IES-12.
IES-13.
IES-15.
In a new temperature scale say , the boiling and freezing points of water at
one atmosphere are 100 and 300 respectively. Correlate this scale with the
Centigrade scale. The reading of 0 on the Centigrade scale is:
[IES-2001]
(a) 0C
(b) 50C
(c) 100C
(d) 150C
Page 6 of 121
Basic Concepts
S K Mondals
Chapter 1
IES-16.
IES-17.
IES-18.
IES-19.
Property) and
[IES 2007]
C
4
2
D
1
1
[IES-2002]
[IES-1997]
Match items in List-I (Process) with those in List-II (Characteristic) and select
the correct answer using the codes given below the lists:
List-I
List-II
[IES-2001]
Page 7 of 121
Basic Concepts
S K Mondals
Chapter 1
A. Throttling process
B. Isentropic process
C. Free expansion
D. Isothermal process
Codes:
A
B
(a)
4
2
(c)
4
3
IES-22.
1.
2.
3.
4.
C
1
1
D
3
2
No work done
No change in entropy
Constant internal energy
Constant enthalpy
A
B
C
(b)
1
2
4
(d)
1
3
4
D
3
2
The heat transfer, Q, the work done W and the change in internal energy U are
all zero in the case of
[IES-1996]
(a) A rigid vessel containing steam at 150C left in the atmosphere which is at 25C.
(b) 1 kg of gas contained in an insulated cylinder expanding as the piston moves slowly
outwards.
(c) A rigid vessel containing ammonia gas connected through a valve to an evacuated
rigid vessel, the vessel, the valve and the connecting pipes being well insulated and
the valve being opened and after a time, conditions through the two vessels becoming
uniform.
(d) 1 kg of air flowing adiabatically from the atmosphere into a previously evacuated
bottle.
IES-24.
(a) A B C
(b) B A C
(c) A C B
Page 8 of 121
[IES-2006]
(d) C A B
Basic Concepts
S K Mondals
IES-25.
Chapter 1
IES-26.
[IES-2004]
[IES-1992]
reversible process.
(a) Both A and R are individually true and R is the correct explanation of A
(b) Both A and R are individually true but R is NOT the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
IES-27.
If
pdv and
(b) Isentropic
(c) Isobaric
(d) Isothermal
Which one of the following expresses the reversible work done by the system
(steady flow) between states 1 and 2?
[IES-2008]
2
(a)
pdv
1
(b)
vdp
1
(c)
pdv
1
(d)
vdp
1
Assertion (A): The change in heat and work cannot be expressed as difference
between the end states.
[IES-1999]
Reason (R): Heat and work are both exact differentials.
(a) Both A and R are individually true and R is the correct explanation of A
(b) Both A and R are individually true but R is NOT the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Page 9 of 121
Basic Concepts
S K Mondals
Chapter 1
IAS-3.
Match List-I with List-II and select the correct answer using the codes given
below the lists:
[IAS-2004]
List-I
List-II
A. Reversible cycle
1. Measurement of temperature
B. Mechanical work
2. Clapeyron equation
C. Zeroth Law
3. Clausius Theorem
D. Heat
4. High grade energy
5. 3rd law of thermodynamics
6. Inexact differential
Codes:
A
B
C
D
A
B
C
D
(a)
3
4
1
6
(b)
2
6
1
3
(c)
3
1
5
6
(d)
1
4
5
2
Match List-I with List-II and select the correct answer:
[IAS-2000]
List-I
List-II
A. The entropy of a pure crystalline
1. First law of thermodynamics
substance is zero at absolute zero
temperature
B. Spontaneous processes occur
2. Second law of thermodynamics
in a certain direction
C. If two bodies are in thermal
3. Third law of thermodynamics
equilibrium with a third body,
then they are also in thermal
equilibrium with each other
D. The law of conservation of energy
4. Zeroth law of thermodynamics.
Codes:
A
B
C
D
A
B
C
D
(a)
2
3
4
1
(b)
3
2
1
4
(c)
3
2
4
1
(d)
2
3
1
4
Page 10 of 121
Basic Concepts
S K Mondals
Chapter 1
In free expansion of a gas between two equilibrium states, the work transfer
involved
[IAS-2001]
(a) Can be calculated by joining the two states on p-v coordinates by any path and
estimating the area below
(b) Can be calculated by joining the two states by a quasi-static path and then finding
the area below
(c) Is zero
(d) Is equal to heat generated by friction during expansion.
IAS-6.
IAS-7.
[IAS-2002]
(d) Maximum
[IAS-1995]
IAS-8.
If
pdv and
Page 11 of 121
Basic Concepts
S K Mondals
IAS-11.
Chapter 1
Match List-I with List-II and select the correct answer using the codes given
below the lists:
[IAS-2004]
List-I
List-II
A. Bottle filling of gas
1. Absolute Zero Temperature
B. Nernst simon Statement
2. Variable flow
C. Joule Thomson Effect
3. Quasi-Static Path
D. pdv
4. Isentropic Process
5. Dissipative Effect
6. Low grade energy
7. Process and temperature during phase
change.
Codes:
A
B
C
D
A
B
C
D
(a)
6
5
4
3
(b)
2
1
4
3
(c)
2
5
7
4
(d)
6
1
7
4
[IAS-1998]
[IAS-1999]
1.
2.
3.
4.
Page 12 of 121
D
4
4
Basic Concepts
S K Mondals
Chapter 1
dQ
0,
dW
0,
dE
or E
Constant
V2
V1
P1V1 ln
V2
V1
800 0.015 ln
0.030
0.015
8.32 kJ/kg
GATE-4. Ans. (c) It is free expansion. Since vacuum does not offer any resistance, there is no work
transfer involved in free expansion.
2
Here,
U + W1-2 so,
U=0
V =1
vdp
Page 13 of 121
Basic Concepts
S K Mondals
Chapter 1
But remember 100% heat cant be convertible to work but 100% work can be
converted to heat. It depends on second law of thermodynamics.
A thermodynamic system is defined as a definite quantity of matter or a region in
space upon which attention is focused in the analysis of a problem.
The system is a macroscopically identifiable collection of matter on which we focus
our attention
IES-6. Ans. (b) In closed thermodynamic system, there is no mass transfer but energy transfer
exists.
IES-7. Ans. (b)
IES-8. Ans. (d) Isentropic means reversible adiabatic. Heat transfer in any finite temp difference is
irreversible.
IES-9. Ans. (a) The energy transfer as heat and work during the forward process as always
identically equal to the energy transfer is heat and work during the reversal or the
process is the correct reason for maximum efficiency because it is conservative system.
IES-10. Ans. (b) Isolated System - in which there is no interaction between system and the
surroundings. It is of fixed mass and energy, and hence there is no mass and energy
transfer across the system boundary.
IES-11. Ans. (a) All temperature measurements are based on Zeroth law of thermodynamics.
IES-12. Ans. (a) Entropy - related to second law of thermodynamics.
Internal Energy (u) = f (T) only (for an ideal gas)
Van der Wall's equation related to => real gas.
IES-13. Ans. (d)
IES-14. Ans. (d)
IES-15.Ans. (d)
0 300
100 300
C 0
100 0
C 150 C
IES-16. Ans. (b) Both A and R are correct but R is not correct explanation for A. Temperature is
independent of thermometric property of fluid.
IES-17. Ans. (d)
IES-18. Ans. (d) But it will occur at absolute zero temperature.
IES-19. Ans. (c) Time Constants: The time constant is the amount of time required for a
thermocouple to indicated 63.2% of step change in temperature of a surrounding media.
Some of the factors influencing the measured time constant are sheath wall thickness,
degree of insulation compaction, and distance of junction from the welded cap on an
ungrounded thermocouple. In addition, the velocity of a gas past the thermocouple probe
greatly influences the time constant measurement. In general, time constants for
measurement of gas can be estimated to be ten times as long as those for measurement
of liquid. The time constant also varies inversely proportional to the square root of the
velocity of the media.
IES-20. Ans. (c)
IES-21. Ans. (a)
IES-22. Ans. (c) In example of (c), it is a case of free expansion heat transfer, work done, and
changes in internal energy are all zero.
Page 14 of 121
Basic Concepts
S K Mondals
Chapter 1
= 100 kPa
IES-24. Ans. (d) WA
pdV
WB
pdV
WC
pdV
1
916
= 9.1 J
4 (2 1)
4 kJ
1
3 (7 4) 4.5 kJ
2
1 (12 9) 3kJ
pdv 1 bar
105
11000 Nm
pv
mRT
pdv vdp
pdv
0[
T is constant]
vdp
2
vdp .
IES-28. Ans. (b) For steady flow process, reversible work given by
1
IES-29. Ans. (c) A is true because change in heat and work are path functions and thus can't be
expressed simply as difference between the end states. R is false because both work and
heat are inexact differentials.
Page 15 of 121
vdp
Basic Concepts
S K Mondals
Chapter 1
IAS-12. Ans. (b) Start with D. PdV only valid for quasi-static path so choice (c) & (d) out.
Automatically C-4 then eye on A and B. Bottle filling of gas is variable flow so A-2.
IAS-13. Ans. (c) W = pdv where pressure (p) is an intensive property and volume (v) is an
extensive property
IAS-14. Ans. (a) Pressure is intensive property but such option is not there.
Page 16 of 121
Fir
rst Law
w of Therm
T
odyna
amics
Cha
apter 2
S K Mo
ondals
s
2.
Firstt Law
w of T herm
modyn
namic
cs
ASKED
GATE, IES, IAS)
D OBJEC
CTIVE QUESTIONS (G
P
Previou
us 20-Y
Years GATE
E Ques
stions
Applicatiion of First
F
Law
w to Ste
eady Flo
ow Proc
cess S.F
F.E.E
Co
ommon Data for Qu
uestions Q1
Q and Q2
2:
[GA
ATE-2009]
Th
he inlet and
d the outle
et conditions of
ste
eam for an
n adiabatic
c steam tur
rbine
are as indic
cated in the
t
figure. The
no
otations are as usually followed.
GA
ATE-1.
If mass
m
flow rate
r
of steam through the turbine is 20 kg/s
s the power
r output of
the
e turbine (in
n MW) is:
(a) 12.157
GA
ATE-2.
[GA
ATE-2009]
(b) 12.941
(cc) 168.001
(d) 168.785
Asssume the ab
bove turbin
ne to be par
rt of a simp
ple Rankine
e cycle. The density of
3
water at the inlet to the
e pump is 1000 kg/m . Ignoring kinetic
k
and
d potential
ene
ergy effectss, the specifi
fic work (in kJ/kg) supp
plied to the pump is:
[G
GATE-2009]
(a) 0.293
(b) 0.35 1
(c)) 2.930
(d) 3.510
3
GA
ATE-3. The
e following
g four figures have been dra
awn to re
epresent a fictitious
the
ermodynam
mic cycle, on
n the p-v and
d T-s planes
s.
[G
GATE-2005]
Page 17 of 121
IES-2.
Two blocks which are at different states are brought into contact with each
other and allowed to reach a final state of thermal equilibrium. The final
temperature attained is specified by the
[IES-1998]
(a) Zeroth law of thermodynamics
(b) First law of thermodynamics
(c) Second law of thermodynamics
(d) Third law of thermodynamics
Page 18 of 121
For a closed system, the difference between the heat added to the system and
the work done by the system is equal to the change in
[IES-1992]
(a) Enthalpy
(b) Entropy
(c) Temperature
(d) Internal energy
IES-4.
(a)1
(c)1
IES-5.
v3
1
v1
(b) 1
p2
1
p1
v3 v1
p2
p1
p1
v1
(b) 1
v3
1
v1
p2
1
p1
1 v3 v1 p1
p2 p1 v1
[IES-1998]
(b) Negative
(c) Zero
[IES-2007]
(d) Unpredictable
IES-6.
A closed system undergoes a process 1-2 for which the values of Q1-2 and W1-2 are
+20 kJ and +50 kJ, respectively. If the system is returned to state, 1, and Q2-1 is 10 kJ, what is the value of the work W2-1?
[IES-2005]
(a) + 20 kJ
(b) 40 kJ
(c) 80 kJ
(d) +40 kJ
IES-7.
IES-8.
IES-9.
IES-10.
Page 19 of 121
Q kJ/min
W kJ/min
AB
BC
CD
DA
+687
-269
-199
+75
+474
0
-180
0
(d) 98
The values of heat transfer and work transfer for four processes of a
thermodynamic cycle are given below:
[IES-1994]
Process
1
2
3
4
300
Zero
-100
Zero
300
250
-100
-250
The thermal efficiency and work ratio for the cycle will be respectively.
(a) 33% and 0.66 (b) 66% and 0.36.
(c) 36% and 0.66
(d) 33% and 0.36.
IES-12.
A tank containing air is stirred by a paddle wheel. The work input to the
paddle wheel is 9000 kJ and the heat transferred to the surroundings from the
tank is 3000 kJ. The external work done by the system is:
[IES-1999]
(a) Zero
(b) 3000 kJ
(c) 6000 kJ
(d) 9000 kJ
For a simple closed system of constant composition, the difference between the
net heat and work interactions is identifiable as the change in
[IES-2003]
(a) Enthalpy
(b) Entropy
(c) Flow energy
(d) Internal energy
IES-14.
Assertion (A): The internal energy depends on the internal state of a body, as
determined by its temperature, pressure and composition.
[IES-2006]
Reason (R): Internal energy of a substance does not include any energy that it
may possess as a result of its macroscopic position or movement.
(a) Both A and R are individually true and R is the correct explanation of A
(b) Both A and R are individually true but R is NOT the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
IES-15.
IES-16.
Page 20 of 121
IES-18.
A system undergoes a process during which the heat transfer to the system per
degree increase in temperature is given by the equation:
[IES-2004]
dQ/dT = 2 kJ/C The work done by the system per degree increase in
temperature is given by the equation dW/dT = 2 0.1 T, where T is in C. If
during the process, the temperature of water varies from 100C to 150C, what
will be the change in internal energy?
(a) 125 kJ
(b) 250 kJ
(c) 625 kJ
(d) 1250 kJ
IES-19.
[IES-1997]
IES-20.
IES-21.
Page 21 of 121
Enthalpy
IES-23.
IES-25.
Which one of the following is the steady flow energy equation for a boiler?
(a) h1
v12
2 gJ
h2
(c) h1
v12
2 gJ
v22
2 gJ
h2
v22
2 gJ
(b)
Q (h2 h1 )
(d)
Ws
[IES-2005]
(h2 h1 ) Q
A 4 kW, 20 litre water heater is switched on for 10 minutes. The heat capacity
Cp for water is 4 kJ/kg K. Assuming all the electrical energy has gone into
heating the water, what is the increase of the water temperature?
[IES-2008]
(a) 15C
(b) 20C
(c) 26C
(d) 30C
A system executes a cycle during which there are four heat transfers: Q12 = 220
kJ, Q23 = -25kJ, Q34 = -180 kJ, Q41 = 50 kJ. The work during three of the
processes is W12 = 15kJ, W23 = -10 kJ, W34 = 60kJ. The work during the process 4 1 is:
[IAS-2003]
(a) - 230 kJ
(b) 0 kJ
(c) 230 kJ
(d) 130 kJ
Page 22 of 121
IAS-2001]
IAS-3.
A reversible heat engine operating between hot and cold reservoirs delivers a
work output of 54 kJ while it rejects a heat of 66 kJ. The efficiency of this
engine is:
[IAS-1998]
(a) 0.45
(b) 0.66
(c) 0.75
(d) 0.82
IAS-4.
If a heat engine gives an output of 3 kW when the input is 10,000 J/s, then the
thermal efficiency of the engine will be:
[IAS-1995]
(a) 20%
(b) 30%
(c) 70%
(d) 76.7%
IAS-5.
IAS-6.
In a thermodynamic cycle consisting of four processes, the heat and work are
as follows:
[IAS-1996]
Q: + 30, - 10, -20, + 5
W: + 3, 10, - 8, 0
The thermal efficiency of the cycle will be:
(a) Zero
(b) 7.15%
(c) 14.33%
(d) 28.6%
IAS-7.
Match List-I (Devices) with List-II (Thermodynamic equations) and select the
correct answer using the codes below the lists:
[IAS-1996]
List-I
List-II
A. Turbine
1. W = h2 h1
B. Nozzle
2. h1 = h2
C. Valve
3. h1 = h2 + V2/2
D. Compressor
4. W = h1 h2
Codes:
A
B
C
D
A
B
C
D
(a)
4
3
2
1
(b)
2
3
1
4
(c)
4
3
1
2
(d)
3
2
4
1
Page 23 of 121
IAS-9.
IAS-10.
[IAS-1994]
(d) 30 J
(c) 25 J
[IAS 1994]
Which one of the following is the correct expression for change in the internal
energy for a small temperature change T for an ideal gas?
[IAS-2007]
T
(a) U Cv
(b) U C p
T
(c)
Cp
Cv
(d)
C p Cv
IAS-12.
IAS-13.
During a process with heat and work interactions, the internal energy of a
system increases by 30 kJ. The amounts of heat and work interactions are
respectively
[IAS-1999]
Page 24 of 121
(a) 30 kJ
IAS-15.
Enthalpy
IAS-16.
[IAS 1994]
(d)
ML3T-2
IAS-18.
When air is compressed, the enthalpy is increased from 100 to 200 kJ/kg. Heat
lost during this compression is 50 kJ/kg. Neglecting kinetic and potential
energies, the power required for a mass flow of 2 kg/s of air through the
compressor will be:
[IAS-1997]
(a) 300 kW
(b) 200 kW
(c) 100 kW
(d) 50 kW
Match List-I with List-II and select the correct answer using the codes given
below Lists:
[IAS-2004]
List-I
List-II
A. Bottle filling of gas
1. Absolute zero temperature
B. Nernst Simon statement
2. Variable flow
C. Joule Thomson effect
3. Quasistatic path
D.
pdv
4. Isenthalpic process
5. Dissipative effect
6. Low grade energy
Page 25 of 121
A
6
2
B
5
5
C
4
7
D
3
4
A gas chamber is divided into two parts by means of a partition wall. On one
side, nitrogen gas at 2 bar pressure and 20C is present. On the other side,
nitrogen gas at 3.5 bar pressure and 35C is present. The chamber is rigid and
thermally insulated from the surroundings. Now, if the partition is removed,
(a) High pressure nitrogen will get throttled
[IAS-1997]
(b) Mechanical work, will be done at the expense of internal energy
(c) Work will be done on low pressure nitrogen
(d) Internal energy of nitrogen will be conserved
Page 26 of 121
h1
1
3000 70
1000
P2 P1
kJ/kg = 2.93
GATE-3. Ans. (a) Fig-1 & 2 both are power cycle, so equal areas but fig-3 & 4 are reverse power
cycle, so area is not meant something.
GATE-4. Ans. (c)
dQ du dw
Q u2 u1 W or 2000 u2 u1 5000 or u2 u1 3000kJ
GATE-5. Ans (a) The final Temp. (T2)= T1
and
P1
T1
P2
( v
T2
const.) or T2
P2
T1
P1
v1
T1
v3
( p
T3
const.) or T3
v3
T1
v1
Efficiency,
Q31
Q12
c p (T3 T1)
cv (T2 T1)
(T3 T1 )
(T2 T1)
Page 27 of 121
c p (T3 T1)
Fir
rst Law
w of Therm
T
odyna
amics
Cha
apter 2
S K Mo
ondals
s
or
v3
T T
v1 1 1
P2
T
P1 1
(v 3 v1) p1
( p2 p1) v1
T1
c) It is du = Q W, as u is a thermo
odynamic pro
operty and itts cyclic integ
gral must be
IES-5. Ans. (c
zeroo.
IES-6. Ans. (b) dQ
dW
W
or Q1 2 Q2 1 W1 2 W2 1
or 20
10
50
W2
or W2
40kJ
du
dw as u const.
IES-7. Ans. (d) dQ
d
dw
300kNm
m
Theerefore du = 0 or dQ
IES-8. Ans. (d)
V2
Q Wx
h
gz
2
O Wx
or Wx
140 10 0
150 kJ / kg
Cha
ange of internal energy = -100 kJ/kg is superfluous data.
IES-9. Ans. (b) Q = E+ W
E = 30 kJ (d
decrease in in
nternal energ
gy)
W = + 50 kJ (work
(
done by the system
m)
Q = 30 + 50 = + 20 kJ
IES-10. Ans. (a
a) Net work =
74 180 kJ/m
min = 294 kJ
J/min = 294/6
60 kJ/s = 4.9 kW
dW =47
IES-11. Ans. (b
b)
th
Wo
ork ratio
Work done
heaat added
3000 100
300
w
w
0..66
550 350
5
550
0.36
6
olume
IES-12. Ans. (a) This iss a case of constant vo
n is isocho
oric process.. By
process or an
perrforming worrk on the sysstem tempera
ature
can
n be raised. In an irrev
versible constant
volu
ume process, the system
m doesn't perrform
worrk on the surrrounding at the expense of its
inteernal energy.
IES-13. Ans. (d
d)
IES-14. Ans. (a)
( The interrnal energy depends
d
only
y upon the in
nitial and fin
nal states of the system.
Inteernal energy
y of a substa
ance does no
ot include an
ny energy th
hat it may possess
p
as a
resu
ult of its ma
acroscopic position or movement.
m
T
That
so why in SFEE v2/2
/ and gz is
there.
Page 28 of 121
Fir
rst Law
w of Therm
T
odyna
amics
Cha
apter 2
S K Mo
ondals
s
If in
nternal energ
gy include po
osition or movement then
n why this v2/2
/ and gz term
ms is there.
Bur Remembe
er:
Miccroscopic view of a gas is a collectio
on of particlles in rando
om motion. Energy
E
of a
parrticle consists of transla
ational energy, rotatio
onal energy
y, vibration
nal energy
and
d specific ellectronic en
nergy. All th
hese energies summed ove
er all the parrticles of the
gass, form the sp
pecific interna
al energy, e , of the gas.
b) dQ dU pdV
if V is cons tan t
dQ v
dU v
IES-15. Ans. (b
IES-16. Ans. (a
a)
Q2
IES-17. Ans. (d
d)
180
0kJ
U1
100kJ, U2
U3
270 180 40
u ( 40))
100 170
270
0 kJ,
130 kJ
p
1-2
For the process
dQ = +85 , dW = 0
For the process
p
2-3
dQ = -90 kJ, dW = -20kJ
For the process
p
3-1
dQ = 0, dW = ?
For a cycclic process
dQ
dW
85-90+
+0 = 0-20+ dW
W
-5 = -20+ dW
5 = +15kJ
dW = -20+5
IES-18. Ans. (c
c)
dQ du dw
2.dt
du
2 0.1T
0
dT
150
0.1
T2
100
2
IES-19. Ans. (c)
( Change of internal en
nergy
be same
s
even allong path AD
DB.
or
du
IES-20. Ans. (d
d) dQ
0.1Td
dT
dE
dW
0.1
02 1002
6
625kJ
150
2
from A to B along path
p
ACB = 180
1 - 130 = 50
5 kJ. It will
Heat flow
fl
along AD
DB = 40 + 50 = 90 kJ.
or
dQ
d
d
dt
dE
dt
Page 29 of 121
dW
d
d
dt
25
0.25t kJ and
dE
0.25 kJ / K
dt
dQ dE dW
Therefore
dt
dt
dt
dW
dt
0.75 kJ / k
then
0.25 0.75 kJ / K
1.00 kJ / K
(0.25kg) 200
u=
u = 275
kJ
kg
dQ
Page 30 of 121
PTS=
1
Area (WVUR)
2
work output
Heat input
Work PTS=
3 103 watts
10.000 J/s
W
Q
1
48 =24 Nm
2
54
54 66
0.45
0.3 30%
U2
U1
or 0
U2 U1
Q2
U1 U2
or W2
Q2
W1 2
5000
W2
or U2 U1
5000 J
U1 U2
Q2
U2
U1
1000 5000
6000 J
IAS-6. Ans. (c) Net work output = 3 + 10 8 = 5 unit and Heat added = 30 + 5 = 35 unit
5
Therefore efficiency,
100% 14.33%
35
IAS-7. Ans. (a)
IAS-8. Ans. (d) Q123 = U13 + W123 or, 100 = U13 + 60 or, U13 = 40 kJ
And Q143 = U13 + W143 = 40+20 = 60 kJ
IAS-9.Ans. (b) Total work = 5 3 +
1
2
du
1
2
1
5 1 17.5 J or W
2
(5 1) (4 2)
(5 1) (4 2)
(1500 500)
3000
5000
0.6
du
du
dW if du
du
30kJ then dQ
du
50kJ and dW
80kJ
pdV
106
or 84
= du + 1
(0.06 0.03) = du +30 kJ or du = 83 30 = 54 kJ
IAS-15. Ans. (a) Q1-2 = U2 U1 +W1-2
Or 0 = U2 U1 - 6000
or U2 U1 = +6000
Q2-1 = U1-U2+W2-1
or W2-1 = Q2-1 - (U1-U2)
=1000+6000=7000J
Page 31 of 121
dQ
dt
m h2
Page 32 of 121
300kW
3.
IES-2.
IES-3.
[IES-1996]
(b) First Law of Thermodynamics
(d) Third Law of Thermodynamics.
Page 33 of 121
[IES-1993]
Assertion (A): Heat cannot spontaneously pass from a colder system to a hotter
system without simultaneously producing other effects in the surroundings.
Reason (R): External work must be put into heat pump so that heat can be
transferred from a cold to a hot body.
[IES-1999]
(a) Both A and R are individually true and R is the correct explanation of A
(b) Both A and R are individually true but R is NOT the correct explanation of A
(c) A is true but R is false
(d) A is false but R is true
Clausius' Theorem
IES-6.
cycle
violates
first
and
An inventor says that his new concept of an engine, while working between
temperature limits of 27C and 327C rejects 45% of heat absorbed from the
source. His engine is then equivalent to which one of the following engines?
(a) Carnot engine
(b) Diesel engine
[IES-2009]
(c) An impossible engine
(d) Ericsson engine
A reversible engine operates between temperatures T1, and T2, The energy
rejected by this engine is received by a second reversible engine at
Page 34 of 121
T1 T3
2
(b) T2
T12 T32
(c) T2
T1T3
(d)
T2
T1 2T3
2
IES-10.
A reversible engine operates between temperatures 900 K & T2 (T2 < 900 K), &
another reversible engine between T2 & 400 K (T2 > 400 K) in series. What is the
value of T2 if work outputs of both the engines are equal?
[IES-2005]
(a) 600 K
(b) 625 K
(c) 650 K
(d) 675 K
IES-11.
Two reversible engine operate between thermal reservoirs at 1200 K, T2K and
300 K such that 1st engine receives heat from 1200 K reservoir and rejects heat
to thermal reservoir at T2K, while the 2nd engine receives heat from thermal
reservoir at T2K and rejects heat to the thermal reservoir at 300 K. The
efficiency of both the engines is equal.
[IES-2004]
What is the value of temperature T2?
(a) 400 K
(b) 500 K
(c) 600 K
(d) 700 K
IES-12.
IES-13.
An engine working on Carnot cycle rejects 40% of absorbed heat from the
source, while the sink temperature is maintained at 27C, then what is the
source temperature?
[IES-2009]
(a) 750C
(b) 477C
(c) 203C
(d) 67.5C
IES-14.
A reversible heat engine rejects 50 percent of the heat supplied during a cycle
of operation. If this engine is reversed and operates as a heat pump, then what
is its coefficient of performance?
[IES-2009]
(a) 1.0
(b) 1.5
(c) 2.0
(d) 2.5
IES-15. A heat engine is supplied with 250 kJ/s of heat at a constant fixed temperature of
227C; the heat is rejected at 27C, the cycle is reversible, then what amount of
heat is rejected?
[IES-2009]
(a) 250 kJ/s
(b) 200 kJ/s
(c) 180 kJ/s
(d) 150 kJ/s
IES-16.
One reversible heat engine operates between 1600 K and T2 K, and another
reversible heat engine operates between T2K and 400 K. If both the engines
have the same heat input and output, then the temperature T2 must be equal
to:
[IES-1993]
(a) 1000
(b) 1200
(c) 1400
(d) 800
Page 35 of 121
A heat engine is supplied with 250 KJ/s of heat at a constant fixed temperature
of 227C. The heat is rejected at 27C. The cycle is reversible, if the amount of
heat rejected is:
[IAS-1995]
(a) 273 KJ/s
(b) 200 KJ/s
(c) 180 KJ/s
(d) 150 KJ/s.
IAS-3.
[IAS-1996]
IAS-5.
Page 36 of 121
Q2
Q2
T2
1200
Q3 or T1
T2
T2
T3 or T2
or 1
or T2
300
T2
1200 300
600K
Page 37 of 121
T1
T3
2
900
400
2
650K
Seco
ond La
aw of Therm
modyn
namicss
Cha
apter 3
S K Mo
ondals
s
IES-12. Ans. (c
c)
Sou
urce Tempera
ature
T1,
Inte
ermediate Temperature
Sin
nk Temperatu
ure
W1
T
T1
Q1 1
T2
W2
T2
T
Q2 1
T1
T
1
T
T1
T2
T
T1
T
1 1 2
T
T
T1 T2
T1 T2
180 20
0
T
100 C
2
T
2
2
IES-13. Ans. (b
b) Sink temp
perature = 27
7 C = 27 + 27
73 = 300K
It is given that engine rejeccts 40% of ab
bsorbed heat from the
sou
urce
Q
Q2
Forr a carnot cyccle engine 1
T1
T2
Q
T
IES-14. Ans. (c
c)
Q1
T1
Q1
T1
0.4
4Q
30
00
Q2
T2
0.5 Q1
T2
30
00
0..4
T2
T1
750K
477 C
0.5
T1
T1
T2
1
T
1 2
T1
1
1 0.5
5
IES-15. Ans. (d
d) Heat supp
plied by the Heat
H
Engine = Q1 = 250 kJ/sec
k
Sou
urce tempera
ature = 227 C = 500 K
Sin
nk temperatu
ure = 27 C = 300K
3
Q
250
0
2
Q 2 250 0.6 150kJ / sec
500
0 300
d) Two reverrsible heat en
ngines operatte between liimits of
IES-16. Ans. (d
160
00K and T2;
T2 and 40
00K
Botth have the same heat inp
put and output,
i.e..
1600 T2
T1 T2
is same for booth or
T1
16000
Page 38 of 121
T2 4000
or T2
T2
8000 K
Q1
T1
Q2
T2
Q
300 + Q1 + Q2 = 50
IAS-4. Ans. (b) For reversible cycle
T1
Q1
T2
Q2
or
T1 T2
T2
T3
T3
Q1 Q2
Q2
or T1 T2
(Q1 Q2 )
Similarly
T2 T3
If T1 T2
T2
Q2
T3
Q3
Q2 Q3
T2 T3 then Q1 Q2
Q2 Q3
or W1 W2
IAS-5. Ans. (b) Reversible engine has maximum efficiency where
Page 39 of 121
Q1
T1
Q2
T2
Q1 Q2
T1 T2
W
T1 T2
Entropy
S K Mondals
4.
Chapter 4
Entropy
[GATE-2003]
(d) 200 kJ
GATE-3.
The entropy change for the Universe during the process in kJ/K is: [GATE-2003]
(a) 0.4652
(b) 0.0067
(c) 0
(d) 0.6711
GATE-4.
One kilogram of water at room temperature is brought into contact with a high
temperature thermal reservoir. The entropy change of the universe is:
(a) Equal to entropy change of the reservoir
[GATE-2010]
(b) Equal to entropy change of water
Page 40 of 121
Entropy
S K Mondals
Chapter 4
The relation ds
dQ
, where s represents entropy, Q represents heat and T
T
Q6.
1000
(285 273)
492
(5 273)
0.02233 kW / K
IES-4.
A Carnot engine operates between 327C and 27C. If the engine produces 300
kJ of work, what is the entropy change during heat addition?
[IES-2008]
(a) 0.5 kJ/K
(b) 1.0 kJ/K
(c) 1.5 kJ/K
(d) 2.0 kJ/K
Page 41 of 121
Entropy
S K Mondals
Chapter 4
Temperature-Entropy Plot
IES-5.
IES-6.
Page 42 of 121
Enttropy
S K Mo
ondals
s
Cha
apter 4
[IES-1995]
IES-7.
[IES-1997]
The
e same cyc
cle, when re
epresented on the pre
essure-volum
me coordin
nates takes
the
e form
IES-8.
Ma
atch figures
s of Colum
mn-I with th
hose given in Column
n-II and se
elect given
bellow the colu
umns:
[IES-1994]
Collumn-I (p-v diagram)
Colum
mn-II (T-s diagram)
Page 43 of 121
Enttropy
S K Mo
ondals
s
Cod
des:
(a)
(c)
IES-9.
A
1
3
Cha
apter 4
B
2
1
C
3
2
(b)
(d)
A
2
3
B
3
2
C
1
1
A cyclic
c
proce
ess ABCD shown
s
in
the
e V-T diagra
am perform
med with
a constant
c
ma
ass of an id
deal gas.
The
e process of
o p-V diagr
ram will
be as shown in
n
[IES-1992]
IES-10.
Thr
ree processses are repr
resented on
n the p-v an
nd T-s diagr
rams in the
e following
figu
ures. Match
h processess in the two diagrams
s and selec
ct the corre
ect answer
usiing the code
es given bellow the diag
grams:
[IES-1994]
Page 44 of 121
Entropy
S K Mondals
Codes:
(a)
(c)
IES-11.
A
1
3
Chapter 4
B
2
2
C
3
1
A
2
1
(b)
(d)
B
3
3
C
1
2
Two polytropic processes undergone by a perfect gas are shown below in the
pressure-volume co-ordinates.
[IES-2008]
IES-12.
dQ
T
0 but
(b)
dQ
T
[IES-2005]
Page 45 of 121
(c)
dQ
T
(d)
dQ
T
Entropy
S K Mondals
IES-14.
(a)
IES-15.
Q
T
(b)
Q
T
(c)
Q
T
[IES-1998]
Q
T
(d)
IES-16.
Chapter 4
dQ
T
(b)
[IES-1994]
dQ
0
T
(c)
dQ
T
(d)
dQ
T
dQ
0 and S 0
T
dQ
0 and S 0
(c)
T
(a)
(b)
(d)
dQ
T
dQ
T
0 and
0 and
IES-18.
IES-19.
IES-20.
Which one of the following temperature entropy diagrams of steam shows the
reversible and irreversible processes correctly?
[IES-1996]
Page 46 of 121
Entropy
S K Mondals
Chapter 4
A Carnot engine operates between 27C and 327C. If the engine produces 300
kJ of Work, What is the entropy change during heat addition?
[IES-2005]
(a) 0.5 kJ/K
(b) 1.0 kJ/K
(c) 1.5 kJ/K
(d) 2.0 kJ/K
IES-22.
IES-23.
(a)
(c)
(T2 T1 )
T22 T12
(b)
T23 T13
/ T12
(T2 T1 )
ln
T2
T1
T22 T12
/ T1
2 (T2 T1 )
IES-24.
IES-25.
Page 47 of 121
Entropy
S K Mondals
Chapter 4
A reversible engine exceeding 630 cycles per minute drawn heat from two
constant temperature reservoirs at 1200 K and 800 K rejects heat to constant
temperature at 400 K. The engine develops work 100kW and rejects 3200 KJ
heat per minute. The ratio of heat drawn from two reservoirs
(a) 1
IES-27.
(b) 1.5
Q1200
is nearly.
Q800
(c) 3
[IES-1992]
(d) 10.5
In which one of the following situations the entropy change will be negative
(a) Air expands isothermally from 6 bars to 3 bars
[IES-2000]
(b) Air is compressed to half the volume at constant pressure
(c) Heat is supplied to air at constant volume till the pressure becomes three folds
(d) Air expands isentropically from 6 bars to 3 bars
[IAS-2007]
Heat flows between two reservoirs having temperatures 1000 K and 500 K,
respectively. If the entropy change of the cold reservoir is 10 kJ/K, then what is
the entropy change for the hot reservoir?
[IAS-2004]
(a) 10 kJ/K
(b) 5 kJ/K
(c) 5 kJ/K
(d) 10 kJ/K
Page 48 of 121
Enttropy
S K Mo
ondals
s
Cha
apter 4
Te
empera
ature-Entropy Plot
IA
AS-3.
[IAS-1997]
The
e same cyclle on temperature-entr
ropy diagram will be re
epresented as:
IA
AS-4.
The
e
therma
al
efficien
ncy
of
t
the
hyp
pothetical heat
h
engine
e cycle show
wn
in the
t
given figure is:
(a) 0.5
(b) 0.45
(c) 0.35
0
(d) 0.25
[IAS-2000]
IA
AS-5.
Wh
hich one of the followiing pairs be
est expresses a relatio
onship similar to that
exp
pressed in the pair
r pressure
e-volume for a the
ermodynam
mic system
und
dergoing a process?
[IAS-1995]
(a) Enthalpy-en
ntropy
(b) Pressu
ure-enthalpy
P
mperature
(d) Tempe
erature-entro
opy
(c) Pressure-tem
IA
AS-6.
[IAS-1999]
Page 49 of 121
Enttropy
S K Mo
ondals
s
AS-7.
IA
Cha
apter 4
[IAS-2004]
The Ineq
quality of Clau
usius
IA
AS-8.
Cla
ausius inequ
uality is sta
ated as
Q 0
(a)
IA
AS-9.
(b)
[IAS-2001]
(c))
Q
T
(c))
dQ
T
(d)
For
r real therm
modynamic cycle:
(a)
dQ
T
0 butt
(b)
dQ
T
Q
T
[IAS-2003]
(d)
dQ
T
IA
AS-10(i). If a system undergoes an
a irreversiible adiabatic process
s, then (sym
mbols have
usu
ual meaning
gs)
[IAS-1999]
dQ
0 an
nd S 0
T
dQ
0 an
nd S 0
(c)
T
(a)
(b)
(d)
dQ
T
dQ
T
0 and
0 and
IA
AS-10(ii). A cyclic
c
heat engine rece
eives 600 kJ of heat fr
rom a 1000 K source and
a
rejects
450
0 kJ to a 300
3
K sink. The quanttity
dQ
a
and
efficien
ncy of the engine
e
are
T
resspectively
(a) 2.1 kJ/K and
d 70%
(c) + 0.9 kJ/K an
nd 70%
[IAS-2001]
(b)) 0.9 kJ/K and
a 25%
(d)) 2.1 kJ/K and
a 25%
A
Applicat
tions off Entrop
py Prin
nciple
IA
AS-11.
Wh
hich one of the
t
followin
ng statemen
nts is not co
orrect?
[IAS-2003]
(a) Change in entropy
e
durin
ng a reversiblle adiabatic process
p
is zerro
(b) Entropy increases with the
t addition of heat
ansion processs
(c) Throttling is a constant entropy expa
hen a gas is heated under
u
consta
ant pressure given by
(d) Change in entropy wh
s2
s1
mC
C p log e
T2
T1
Page 50 of 121
Entropy
S K Mondals
IAS-12.
Chapter 4
IAS-14.
IAS-16.
Page 51 of 121
Enttropy
Cha
apter 4
S K Mo
ondals
s
Answ
wers with Expla
anatio
on (Ob
bjectiv
ve)
Previo
ous 20-Years
s GATE
E Answ
wers
GA
ATE-1. Ans. 11858 J/K, 12787 J/K.
GA
ATE-2. Ans. (b) w1
m
mRT
In
p In
200 1 In
GA
ATE-3. Ans. (c) It is reveersible processs so
univerrse
2
kJ 138.6 kJ
k
1
GA
ATE-4. Ans. (d)
GA
ATE-5. Ans.. (d) It is a case of spoontaneous prrocess i.e. irrrepressibility
y involved that
t
so why
entropy change of the univerrse is positiv
ve.
dQ
T
R
Rev
IES-2. Ans. (b
b) The chang
ge of entropy
y may be regarded as a measure
m
of th
he rate of av
vailability of
hea
at for transformation into
o work.
IES-3. Ans. (c))
IES-4. Ans. (b)
Q1 Q1 Q1 Q2
W
T1 T1
T1 T2
T1 T2
Q1
600kJ
Thee entropy ch
hange during heat addiition
Q1 600
1 kJ / K
T1 600
Page 52 of 121
Enttropy
S K Mo
ondals
s
Cha
apter 4
IES-12. Ans. (b
b)
IES-13. Ans. (b
b)
IES-14. Ans. (b
b)
c)
IES-15. Ans. (c
dQ
T
a)
IES-16. Ans. (a
IES-17.
Con
nsider the prrocess 34 iff it is
irreeversible prrocess then also
entropy will deccrease.
( In reversiible adiabaticc expansion, entropy chan
nge is zero and no change
e in entropy
IES-18. Ans. (c)
of surroundings
s
s.
IES-19. Ans. (b
b) Entropy in
ncrease in prrocess = 100 (0.4 0.3) = 10 kJ/kg
Enttropy change
e of surround
dings = 5 kJ/K
K
Thu
us net entrop
py increases and
a the proce
ess is irreverrsible.
( In reversiible process entropy
e
chan
nge is zero an
nd in four figu
ures it is rep
presented by
IES-20. Ans. (c)
stra
aight vertical line. Howev
ver, in irreve
ersible processs, entropy in
ncreases in all
a processes
(exp
pansion as well
w as compression).
IES-21. Ans. (b
b)
T1 T2
or
300
600 300
1 kJ / k
IES-22. Ans. (c
c)
T1
IES-23. Ans. (d
d)
dQ
T
T1
T1
T1
2 T
T
dT
T
ln
T2
T1
2 (T2 T1 )
Page 53 of 121
Entropy
S K Mondals
Chapter 4
Q2
100
Q4
100
Q2 Q4
1
Q1 Q3
6
800
8
600
3 4
1 4 3
6 8
0.85
Thus,
Thus,
or
or
Qs2
800
QR
400
Qs1
1200
9.2 106
800
2Qs1
Qs1
6 3.2 106
400
3 9.3 106
6 3.2 106
9.2 106
8.4 106
Page 54 of 121
0
0
Enttropy
S K Mo
ondals
s
Cha
apter 4
8.4
=10.5
0.8
IES-27. Ans. (b
b) It is isoba
aric compresssion.
He
ence ratio =
IES-28. Ans. (d
d)
Previious 20
0-Yearrs IAS Answ
wers
IA
AS-1. Ans. (b)
IA
AS-2. Ans. (b)
Q
10
0
500
or Q 5000 kJJ
Q
5000
S1
5kJ / k
1000 1000
1
Heat added to
t thesystem
m is +ive
S2
Work done
d
Heat ad
dded
area1 2 3
areaunder curve 2 3
1
2
5 1
IA
AS-5. Ans. (d) That so wh
hy we are usin
ng pv or T
s diagram.
IA
AS-6. Ans. (a))
IA
AS-7. Ans. (b
b)
IA
AS-8. Ans. (d)
IA
AS-9. Ans. (b)
Page 55 of 121
5 1
800 40
00
800
0.25
Entropy
S K Mondals
IAS-10(i). Ans. (a)
IAS-10(ii). Ans. (b)
dQ
T
Chapter 4
Q2
Q1
450
600
0.25
25%
Page 56 of 121
1600
800
2kJ / K