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2.3
bomb calorimeter. It is simply the amount of energy a specific fuel will produce
during combustion. This is useful in determining the quantity of fuel to be used in
specific applications such as in boilers[8.3].
3. Material/Equipment Used
3.1
Memmert Oven used to heat sample and crucible for exactly 1
hour
3.2
3.3
of sample
3.4
3.5
cooling
3.6
3.7
3.8
sample
4. Methodology
4.1
Proximate Analysis
4.1.1 Preparation of Samples
4.1.1.1 Brown Algae samples were sun-dried for a number
of hours in a day for 1 week.
4.1.1.2 After drying, the samples were then milled.
4.1.1.3 The samples were then mixed with starch having an
amount of 20% the total mass.
4.1.1.4 Specific samples were taken for proximate analysis
and others were briquetted, dried, and placed inside air-tight plastic
containers.
4.1.2
4.2.6
4.2.7
4.2.8
covered.
cover and the stirrer was turned on until the temperature of the water was
constant.
4.2.9
After, the stirrer was turned off and the ignition button was
pressed.
4.2.10 During ignition, the change in temperature was recorded
until it remains constant and starts to fall down.
4.2.11 After ignition, the bomb was taken out of the container and
the fuse wire was obtained.
4.2.12 The wire was then measured and the corresponding
correction for heat of combustion of firing wire, e3 was recorded.
4.2.13 The gross of heat of combustion was then computed.
5. Data and Discussion
Sample: Brown Algae (80% Algae, 20% Starch)
Table 5.1 Moisture, Volatile Matter, Ash Content and Fixed Carbon of sample
Parameters
Percentage (%)
Moisture
22.37
Volatile Matter
67.88
Ash
2.48
Fixed Carbon
7.27
CALCULATIONS:
CONSTANT WEIGHT METHOD
Equipment used: Memmert Oven
Duration: 1 hour
Table 5.2 The mass of crucible before and after subjecting it to the Memmert oven
Before Heating
After Heating
20.9738 g
20.9735 g
Since the difference between the two readings is .0003 which is within the
permissible tolerance of .0005 as stated by the chemist, the porcelain crucible now has
negligible amount of moisture and can now be used to determine the following
parameters.
MOISTURE CONTENT
Equipment Used: Memmert Oven
Duration: 1 hour
total mass = mass of crucible + mass of sample = 20.9735 g + 1 g = 21.9735 g
Table 5.3 The total mass before and after subjecting it to the Memmert oven
Before Heating
After Heating
21.9735 g
21.7463 g
VOLATILE MATTER
Equipment Used: Electric Furnace
Duration: 7 minutes
Table 5.4 The total mass before and after subjecting it to the electric furnace
Before
After
21.7463 g
21.0675 g
(21.7463 21.0675)
100
1
ASH CONTENT
Equipment Used: Electric Furnace
Duration: 1 hour
Table 5.4 The total mass before and after subjecting it to the electric furnace
Before
After
21.0675 g
21.0427 g
FIXED CARBON
To calculate fixed carbon easily, this equation is used:
100% = MC + VM + AC + FC
where:
so,
after ashing are considered as the fixed carbon and that the brown algae sample does not
contain any sulfur.
HIGHER HEATING VALUE
W = Hg/t
[eqn 5.1]
Temp Rise
e2
Brown Algae
.34 C
5.25 cm
2.54 cal
rearranging equation 5.1 and including correction for heat of combustion of firing wire
Gross Heat of Combustion = H = [(t)x(W) - e2] / (g)
6. Conclusion
6.1
matter, ash, and fixed carbon are 22.37%, 67.88%, 2.48%, and 7.27%,
respectively. Ash content of solid fuels is preferred to be lower. The reason for
this is that an increase in the percentage of ash causes reduction to the calorific
value [8.3].
6.2
8. Bibliography
8.1
Speight, J. (2005). Handbook of coal analysis. Hoboken, N.J.:
Wiley-Interscience.
8.2
Bloch, Heinz. Practical Lubrication For Industrial Facilities. 2nd
ed. Lilburn: The Fairmont Press, Inc, 2009.
8.3
Miller, B. and Tillman, D. (2008). Combustion engineering issues
for solid fuel systems. Amsterdam: Academic Press/Elsevier.
8.4
Rochleder, F. (1862). Proximate analysis of plants and vegetable
substances. Philadelphia: Merrihew & Thompson, Printers.