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Pipelines for heavy crude oils have recurrent clogging situations due to paraffin deposition that may lower
production rates and be responsible for leakages. This work evaluates the effect of three polymers on crude oil
wettability and on paraffin deposition inhibition: polypropylene (PP), high-density polyethylene (HDPE), and
a vinyl acetate copolymer with 28% oxygen content (EVA28). Under static conditions, the interfacial tension
between the crude oil and the linings was determined by the contact angle being 12% and 17% higher for
EVA28 and HDPE, respectively, than for that of PP. As the crude oil inside the pipelines is flowing at high
rates, the dynamic interfacial tension was also observed for high flow rates when molecular effects overtake
hydrodynamic ones. For this, the perturbation of intermolecular orientation within the flow, caused by the
beginning of deposit formation and by the wettability, was determined using depolarization of the fluorescence
induced by laser. Under flow, EVA28 and HDPE caused an increase of interaction with the crude oil of 79%
and 43%, respectively, compared to that of PP. HDPE yielded globular wax deposits. The higher tendency of
HDPE than PP to form deposits was attributed to the absence of methyl branches in the first. The EVA28
tendency to form deposits was attributed to the oxygen atoms on the surface as well as to its high polycyclic
aromatic hydrocarbon sorption. Thus, under a high flow rate, PP is better suited to inhibit wax deposition than
HDPE and EVA28.
1. Introduction
Heavy crude oils with a low API degree as well as a high
wax or paraffinic content are usually found in aging reservoirs
or in reservoirs of lagoon origin. These oils have the advantage
of allowing the refineries more options according to international
prices. Nevertheless, the same characteristics can lead to
problems during their production, pumping, and transport, as
paraffinic deposits1,2 may lead to low pumping rates and to the
need to increase differential pressure as well as higher pumping
capabilities. This may increase both equipment failures and
leakage probability,3 thus decreasing the profit margin of the
operation and changing the finance forecasts of companies.
The paraffin crystallization depends on the crude oil paraffin
content, on the thermodynamic and fluidynamic conditions, and
on the paraffin molecular structure.4 The increase of intermolecular orientation of paraffins leads to their nucleation and,
consequently, to the beginning of crystal formation.5,6
* Corresponding author. Tel: 55-71-99647876. Fax: 55-71-2355166.
E-mail: cristina@ufba.br.
Universade Federal da Bahia.
University of Ottawa.
(1) Venkatesan, R.; Ostlund, J. A.; Chawla, H.; Wattana, P.; Nyden, M.;
Foler, H. S. Energy Fuels 2003, 17 (6), 1630-1640.
(2) Cosulchi, A.; Garciafigueroa, E.; Garca-Borquez, A.; Reguera, E.;
Yee-Madeira, H.; Lara, V. H.; Bosch, P. Fuel 2001, 80, 1963-1968.
(3) Ajienka, J. A.; Ikoku, C. U. J. Pet. Sci. Eng. 1995, 13, 87-94.
(4) Andreatta, G.; Gonc alves, C. C.; Buffin, G.; Bostrom, N.; Quintella,
C. M.; Arteagalarios, F.; Perez, A.; Mullins, O. C. Energy Fuels 2005, 19
(4), 1282-1289.
(5) Dorset, D. L. Energy Fuels 2000, 14 (3), 685-691.
(6) Rocha, N. O.; Gonzalez, G.; Vaitsman, D. S. Quim. NoVa 1998, 12
(1), 11.
Quintella et al.
Figure 3. (A) Scheme of the flow cell for PLF-FI. (B) Experimental
setup for polarized laser induced fluorescence within liquid induced
flows (PLF-FI) to detect fluorescence depolarization. CW - laser, M
- mirrors, L1, L2 - lenses, P1, P2 - Glan-Thompson Polarizer, PD1,
PD2 - photodiodes, I - interface, PC Personal computer, FI - liquid
flow, F- color filter, BS - beam splitter. [Figure 3B reproduced under
permission of Qumica NoVa 2005, 28 (2), 227-339. Sociedade
Brasileira de Qumica].
I | - I
I | + I
c
((2)
cos c
((0.01)
PP
HDPE
EVA28
BSi
SnO2
42
30
28
22
27
0.743
0.866
0.829
0.891
0.927
polarization (%)
77 ( 2
44 ( 4
16 ( 2
Figure 4. Scheme of the crude oil PAHs being aligned within the
flow.
Quintella et al.