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MALAYSIAN
STANDARD
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MALAYSIAN STANDARD
MS 417 : Part 1 : 1994
THE ANALYSIS OF FERTILIZERS : PART 1 : METHOD OF SAMPLING AND
SAMPLE PREPARATION (FIRST REVISION)
The attached amendment on MS 417 : Part 1 : 1994 has been formally approved by the
Technical Committee on Fertilizers.
Date: 9 May 2001
Amd. 1
(1)
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NOTE. In the event when the slot cannot be used in a normal sampling of the fertilizer, the
sampling has to be done randomly from selected packages according to the scale of sampling
as in Table 1. The weight of the sample shall not be less than 250 g.
(2)
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In the event that the fertilizer comes as lumpy material and flakes, where a probe cannot be
used then any suitable sampling device may be used.
Page 3, Table 2
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Type of Fertilizer
Ground phosphate rock, compound (ordinary and premium
grades), mixtures and organic fertilizers*
2.
0.25
1.
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Table 2 on the size requirement of fertilizers for analysis is to be replaced with the following
table:
0.50
1.00
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This Malaysian Standard, which had been approved by the Chemical and Pharmaceutical
Industry Standards Committee and endorsed by the Board of the Standards and Industrial
Research Institute of Malaysia (SIRIM) was published under the authority of the SIRIM Board in
August, 1994.
SIRIM wishes to draw attention to the fact that this Malaysian Standard does not purport to
include all the necessary provisions of a contract.
The Malaysian Standards are subject to periodical review to keep abreast of progress in the
industries concerned. Suggestions for improvements will be recorded and in due course brought
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to the notice of the Committees charged with the revision of the standards to which they refer.
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Date of issue
Text affected
CONTENTS
Page
iii
Foreword ..............................................................................................................
iv
Scope ....................................................................................................................
Apparatus ..............................................................................................................
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Tables
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3
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Figures
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ii
Committee representation
The Chemical and Pharmaceutical Industry Standards Committee under whose supervision this Malaysian Standard
was prepared, comprises representatives from the following Government Ministries, trade, commerce and manufacturer
associations and scientific and professional bodies.
Federation of Malaysian Manufacturer (Chemical Sector)
Malaysian Ceramic Industry Group
Malaysian Institute of Chemistry
Malaysian Paint Manufacturers Association
Ministry of Agriculture (Agriculture Department)
Ministry of Defence (Defence, Science and Technology Centre)
Ministry of Primary Industries (Geological Survey Department)
Ministry of Science, Technology and Environment (Chemistry Department)
Petronas (Non-Petroleum Matters)
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Department of Agriculture
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The Working Group on Fertilizers which prepared this Malaysian Standard consists of the following representatives:
Co-opted Members:
Dr. Alias Husin/
Dr. Abdul Manaf b. Mohamad Radzi
Encik Ramakrishnan
Invited Member:
Tuan Hj. Mohd Nor Abu Bakar
iii
FOREWORD
This Malaysian Standard was prepared by the Working Group on Fertilizers with is under the
authority of the Chemical and Pharmaceutical Industry Standards Committee.
This standard is the first revision of Malaysian Standard MS 417 : Method for the analysis of
fertilizers, which was published in 1976. This standard is the first part in a series to provide
method of sampling and sample preparation for fertilizers, both in packages and in bulk form.
Other parts are as follows:
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2 : Method for the determination of moisture content, particle size and ash content.
3 : Method for the determination of nitrogen.
4 : Method for the determination of phosphorus.
5 : Method for the determination of potassium.
6 : Method for the determination of magnesium.
7 : Method for the determination of boron.
8 : Method for the determination of secondary properties.
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Part
Part
Part
Part
Part
Part
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In this revision, besides giving consideration to local requirement, the following documents have
also been referred.
Laboratory Manual. General Analytical Laboratory (NFDC-TVA). Tennesse Valley
Authority. Division of Chemical Development Fundamental Research Branch. Muscle
Shoals, Alabama. April 1979.
(2)
Fertilizer Sampling and Analytical Methods (Fourth Edition). The Fertilizer Institute.
Washington, D.C 20036. July, 1982.
(3)
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(1)
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This revised standard purports to introduce into Malaysia uniform methods of sampling and
sample preparation on analysis of fertilizers. It does not deal with the specifications of the
materials but prescribes only the method of sampling and sample preparation for fertilizers, both
in packages and in bulk form.
iv
1.
Scope
This part of Malaysian Standard prescribes method of sampling and sample
preparation for fertilizers, both in packages and in bulk form.
Apparatus
2.1
A non-corrosive (brass, copper or stainless steel) slotted grain probe of sufficient length
to penetrate the whole bag diagonally. The probe shall have a continuous slot with
sharp edges.
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2.
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650 mm (min.)
2.1.2
Slot length
2.1.3
Slot width
2.1.4
Inner diameter
2.2
A sample probe and a sample cup as shown in Figure 1 and Figure 2 respectively shall
be used.
2.3
3.
3.1
In the absence of any other sampling plan agreed upon between the purchasers and
suppliers, representative samples shall be obtained in accordance with Table 1.
3.1.1
Lot
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2.1.1
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16 mm
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All packages in a single consignment of the material of the same grade and type, drawn
from a single batch of manufacture shall constitute a lot. If a consignment is declared to
consist of different batches of manufacture, the batches shall be marked separately and
the groups of packages in each batch shall constitute separate lots. In the case of a
consignment drawn from a continuous process, 2000 packages (or 100 tonnes) of the
material shall constitute a lot.
3.1.2
The number of packages to be chosen from a lot shall depend on the size of the lot and
shall be as given in Table 1.
Table 1. Scale of sampling and method of selection
Lot size
(packages)
Sample size
(packages)
1-3
4 - 15
16 - 50
51 - 150
151 - 500
501 - 2000
all
3
10
15
25
35
Method of selection
)
)
)
)
)
At random
NOTE. If the lot size exceeds 2000 packages, the sampling cycle is repeated.
The packages selected shall be intact and in good external condition. From each of
these packages laid horizontally take a full length diagonal core from bottom corner to
top corner or from two opposite corners using the non-corrosive probe. Mix the cores
thoroughly to form a representative sample and store in an airtight container.
3.3
When slotting into the bag the slot shall be faced down. When the probe has fully
penetrated, turn 180 so that the slot faces upward and is filled before pulling out the
probe.
4.
4.1
From each lot or batch take 20 samples (cores) at random from different parts and at
different depths using a non-corrosive grain probe of 130 cm to 155 cm length. Mix
the samples thoroughly and store in an airtight container.
4.2
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3.2
Take 20 samples (cores) at equal intervals through the whole period of passage of
the lot or batch using the sampling cup described in Clause 2.2. Mix the samples
thoroughly and store in an airtight container.
5.
5.1
Apparatus
5.1.1
5.1.2
Grinder/Mortar
5.1.3
Balance
Procedure
5.2.1
5.2.2
5.2.3
5.2.4
5.3
Precaution
5.3.1
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5.2
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Sieve size
(mm)
0.25
0.25
0.5
1.0
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Granular fertilizers
e.g. compound and mixture
Crystalline fertilizer
e.g. ammonium sulphate, ammonium nitrate, magnesium sulphate
(kieserite)
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Type of fertilizer
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Ketua Pengarah
Institut Standard dan Penyelidikan Perindustrian Malaysia
Persiaran Dato Menteri, Seksyen 2, Peti Surat 7035
40911 Shah Alam
Selangor Darul Ehsan
The SIRIM standard marks shown above are registered certification trade marks. They may
be used only by those licensed under the certification marking scheme operated by SIRIM
and in conjunction with relevant Malaysian Standard number. The presence of these Marks
on or relation to a product is assurance that the goods have been produced under a system
of supervision, control and testing, operated during production, and including periodical
inspection of the producers works in accordance with the certification marking scheme of
SIRIM designed to ensure compliance with a Malaysian Standard.
Further particulars of the terms of license may be obtained from:
Director-General
Standards and Industrial Research Institute of Malaysia
Persiaran Dato Menteri, Section 2. P.O.Box 7035
40911 Shah Alam
Selangor Darul Ehsan
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Standard-Standard Malaysia disediakan hanya setelah penyiasatan yang lengkap menujukkan bahawa sesuatu
projek itu disahkan sebagai yang dikehendaki dan berpadanan dengan usaha yang terlibat. Hasil ini berasaskan
persetujuan sukarela dan memberi pertimbangan kepada kepentingan pengeluar dan pengguna. StandardStandard Malaysia adalah sukarela kecuali is dimestikan oleh badan-badan berkuasa melalui peraturanperaturan, undang-undang persekutuan dan tempatan atau cara-cara lain yang sepertinya.
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The Standard and Industrial research Institute of Malaysia (SIRIM) is established with the merger of the
Standards Institution of Malaysia (SIM) and the National Institute for Scientific and Industrial Research (NISIR)
under the Laws of Malaysia Act 157 on 16th. September 1975: Standards and Industrial Research Institute of
Malaysia (Incorporation) Act 1975. The Institute is vested with the power to provide for the promotion and
undertaking of industrial research and for the preparation and promotion of standards for commodities,
processes, practices and services; and to provide for matters incidental to or connected with those purposes.
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Institut ini beroperasi semata-mata berasaskan tanpa keuntungan. Ia adalah satu badan yang menerima bantuan
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One of the functions of the Institute is to prepare Malaysian Standards in the form of specifications for materials
and products, methods of testing, codes of sound and safe practice, nomenclature, etc. Malaysian Standards are
prepared by representative committees which co-ordinate manufacturing capacity and production efficiency with
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replacement interchangeability, and adequate variety of choice without wasteful diversify.
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one and worth the effort involved. The work is based on voluntary agreement, and recognition of the community
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