You are on page 1of 973

CORROSION RESISTANT

MATERIALS
HANDBOOK
Fourth Edition

Edited

by

D.J. De Renzo

NOYES

DATA

Park Ridge,

CORPORATION
New Jersey, U.S.A.

Copyright G 1985 by Noyes Data Corporation


No part of this book may be reproduced in any form
without permission in writing from the Publisher.
Library of Congress Catalog Card Number: 854872
ISBN o-8155-1023-3
Printed in the United States
Published in the United States of America
Noyes Data Corporation
Mill Road, Park Ridge, New Jersey 07656

by

1098765432

Library of Congress Cataloging


Main entry under title:
Corrosion

in Publication

Data

resistant materials handbook.

Rev. ed. of: Corrosion resistant materials handbook I


lbert Mellan. 3rd ed. 1976.
Includes indexes.
1. Corrosion resistant materials--Handbooks,
manuals,
etc. I. De Renzo, D.J. II. Mellan, Ibert. Corrosion
resistant materials handbook.
TA418.75.C67
1985
620.11223
85-4872
ISBN o-8155-1023-3

NOTICE
To

the

tained

best
in

publisher
for

of

this
does

our

knowledge

publication
not

is

assume

the

any

or product

for

of any information

the use contemplated

by any user, and

the manner of that use, is the sole responsibility


We recommend

any

recommendation

publication
and that
standards.

should

of

intending

materials
himself

We strongly

mentioned

recommend

manufacturers

of the

to rely on
in

this

as to such suitability,

he can meet all applicable safety

adhere to the
structions

that anyone

satisfy

the

whatsoever

of such information.

of the suitability

user.

con-

however,

liability

the accuracy or completeness

Final determination

information

accurate;

that

and health

users seek and

or suppliers

for handling each material they use.

current

in-

Foreword

The

fourth

edition

and vastly
ful

reference

the

concerned

cially
to

first

engineer

available

corrosion
designers

having

Corrosion

specific

published

to cut

resistant

materials

and others

corrosion

The

more

resistant

materials.

corrosive

substances.

Trade
The

Name
various

alloys;

resins

nonferrous

mercial

engineering

from,

of

The vast amount


of contents

book

cover
rubbers

and alloys;

13 tables
directly

or distributors
of information

and the exhaustive

from

guide

which

by choosing

suitable

It would

in choosing

revised

and success-

information

application.

screening

work

lies in the extensive

tables

in the book

Index

is organized

to

specific

will

enable

commer-

also be useful

materials

selected

for

equip-

materials

the

categories

corrosive

chemicals

in the tables.

of corrosion
cements,

and other
A separate

resistant

materials,

mortars,

and asphalt;

and carbon-graphite.

A separate

anticorrosive

essential

manufacturers

by

of thousands

by types of corrosion

Listing are also included.

and elastomers;

compare

cross-indexing

are arranged

recommendations

and glass, ceramics,

which

and construction

taken

the makers

reader

useful

a particular

Name and Address

and polymers;
metals

a group

selections

in the

for

Material

the

provide

has been completely

This well-established

losses due to corrosion

reference

Corrosive

will

data.

requirements.

160 detailed

It refers

sections

presents
sent

The

than

Handbook

technical

as a valuable

resistance

Index and a Company

as synthetic

Materials

in 1966,

or manager

The great value of this outstanding


of substances.

Resistant

based on the latest available

volume,

equipment

ment

of the

expanded,

merits

to industry.

literature

made

of a cross section

The tables
at no cost

section
of com-

in the book
to,

nor

such
ferrous

repre-

influence

of these materials.
contained

in the

book

is evidenced

at once in the extensive

indexes.

Advanced composition
and production
methods developed by Noyes Data
Corporation
are employed
to bring this durably bound book to you in a
minimum
of time. Special techniques are used to close the gap between
manuscript
and completed
book. In order to keep the price of the book
to a reasonable level, it has been partially reproduced by photo-offset
directly from the original material and the cost savings passed on to the reader.
Due to this method of publishing, certain portions of the book may be less
legible than desired.

table

Contents

SYNTHETIC

RESINS

AND

1.1

ABS Jackets

1.2

ABS/PVC

.1

................................................

POLYMERS.

.I

.............................................

and Covers-CEEL-CO

1.4

................................................
Acetal Copolymers-Celanese
Plastics ............................................
Acrylic
Resins-Rohm
and Haas. ...............................................

1.5

Acrylic

1.6

Cellulose

1.3

Alloys-A.

Resin-Sohio
Acetates,

.2

Schulman

.6
.9

................................................

Chemical.
Butyrates,

Propionates-Eastman

.27

Chlorinated
Epoxy

Compounds-Devcon

1.9

Epoxy

Pipe and Fittings-Ameron

1.10

Epoxy

Resin-Duriron

1.11

Epoxy

Resins-Shell

1.12

Fiberglass

Reinforced

Epoxy

1.13

Fiberglass

Reinforced

Furan

1.14

Fiberglass

Reinforced

lsophthalic

1.15

1.23

......................
....................................
Fiberglass Reinforced
Polyester
Panels-Resolite
Fluoropolymer-Allied
Engineered
Plastics. ........................................
............................
Furan Resin-Koch
Engineering,
Maurice A. Knight Division
..........................................
lsopolyester
Resins-Amoco
Chemicals
Nylon 6/6 Resins-Celanese
Plastics ............................................
....................................................
Nylon 11 Resin-Rilsan
..........................
Nylon Reinforced
Vinyl Hose-Sethco
Division,
Met Pro Corp.
..............................
Oxirane Oligomer
of Resorcinol-Plastonics
International

1.24

Phenolic

1.25

1.29

....................................
........................................
Polyallomer-Eastman
Chemical Products
..............................................
Polycarbonate-Mobay
Chemical
......................................
Polyester
Engineering
Resin-Dart
Industries
Polyester
Laminates-Haysite
Reinforced
Plastics ...................................

1.30

Polyether

1.31

Polyethylene-Eastman

1.32

Polyethylene-Himont

1.33

Polyethylene-Lined

1.34

Polyethylene

1.17
1.18
1.19
1.20
1.21
1.22

1.26
1.27
1.28

and Vinyl

Polyester

Polybutylene

.32

.33
.34
.35
.37

Chemical

and Vinyl

..............

Smith-Inland

.39

..........................

Ester-Morrison

Molded

Fiber

Glass.

Plastics.

Resins-U.S.I.

Chemicals.

1.35

Polyethylene

Tank

1.36

Polyethylene

Terephthalate-Based

Material-Nalge.

1.37

Polymethylpentene-Westlake

1.38

Polyphenylene

Sulfides-Phillips

.65
.67
.68

107
108
110
111

Scientifics

Inc

..............

Chemical

..........................................
Chemical ........................................

113
114
116

............................................

vii

.63

106

..........................................

Plastics.

54

.60
.61

112

Tubing-Thermoplastic

Copolyester-Eastman

.52
.53

104

..............................................
.......................................
Products.
Acetate

.47

102

Electric.

.....................................................
Ethylene-Vinyl

.......

.95

..........................................

Resin-General

Amides-Rilsan.

Systems-A.O.

Oats Chemicals.

Terephthalate-Celanese

Chemical.

Oxide-Based

Ester Piping

Polymer-Quaker

Resins-Occidental

Block

Goodrich

.................................................

.............................................
.....................................................
Chemical ................................................

Reinforced

Phenylene

Pipe and Fittings-B.F.

.........................

1.7

Fiberglass

Chloride

10

...........................

Chemical.

1.8

1.16

Polyvinyl

.3

Products

.................

116
118
120

Contents

VIII

1.39
1.40
1.41
1.42
1.43
1.44
1.45
1.46
1.47

....................................
........................................
.........................
Polystyrene
Resins-Huntsman
Chemical .............
Polysulfone-Union
Carbide
...............................................
Polyvinyl
Chloride
Ducts-Dayco ............................................
Polyvinyl
Chloride Jackets and Covers-CEEL-CO .................................
Polyvinyl
Chloride
Liners-Fabrico.
..........................................
Polyvinyl
Chloride
Pipe and Fittings-Thermoplastic
Processes. ........................
................................
Polyvinyl
Chloride
Tank Liners-Peabody
Tectank.
Polypropylene-Eastman

Polypropylene

Chemical

Resins-Shell

1.52

....................................
Tetrafluoroethylene
Resins-Du
Pont .........................................
Vinyl Ester Resins-Interplastic
Corp. .........................................
Epoxy and Polyester
Pipe and Fittings-Ameron
..................................

1.53

Phenol-Formaldehyde

1.54

Polyester

1.55

Polypropylene

1.56

Acetal,

Nylon

1.57

Epoxy,

Fluoropolymer

1.51

Fluoride-Rilsan.

1.58

Isopolyester,

1.59

Polystyrene,

1.60

Polyvinyl

1.61

Vinyl,

Hose-Everflex

Ester

Alcohol-Formaldehyde

and Polyester

Lined

and Bisphenol

Polypropylene

1.62

Various

Glass-Reinforced

Various

Polymers-Westlake

1.64

Various

Resins-General

Resins and Elastomers

Resins and Metals-Phillips

1.67

Various

Resins for Membrane

1.68

Various

Resins for Plastic

1.69

Various

Thermoplastic

and Elastomeric

1.70

Various

Thermoplastic

Polymers

A Polyesters,

for

Linings

Lined

Piping
for

Products-Dow
Piping

Silicone

2.7

Urethane-American

2.8

Urethane-Devcon.

2.9

Urethane

2.10

Various

Elastomers-American

2.11

Various

Elastomers

and Rubbers-Du

2.12

Various

Elastomers

and Rubbers-Exxon

Chemicals.

2.13

Various

Elastomers

and Rubbers-Minor

Rubber

2.14

Various

Rubber

Rubber

Sealant-Stonhard.

Linings-Huron

Chemicals

........
Ltd ........

....................

Cyanamid

............................

AND

3.2

Epoxy

Flooring

3.3

Epoxy

Mortar

3.4

Epoxy

Surfacing

3.5

Furan

Grout-Atlas

3.6

Furan

Polymer

3.7

Polyester

Pont.

Tank

......
Co. ......

. 239
239

. 242
. 247

. .. .
.
. . . . . .
.

Concrete-Quaker

. .
.

.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......

. . .

. 290
. 293
294
. 296
. 297
. 297
.298
. 299
. 302

.355
. 367

..........
..........

. . . . . .. .. .. . . .

. .

. .

. . .

. .. . . . . . . . . . . .

284
284

.285
. 287

..........

. . . . .. . .
. . . . . .

Oats Chemicals

Technology.

.......................

.. .. .
. . . ..
.

Toppings-Pennwalt

. . . . . . . .

250

. 251
. 263
. 272

.......................

Linings-Acme-Fisher.

. .

Cements-Sternson.

Grout-Radiation

............

Systems-Stonhard

Compounds-Atlas.
and Floor

.............

Cyanamid.

ASPHALT
Surfacing

..............

Limited.

and Elastomeric

Floor

.................

.......................

Rubber

Cyanamid

Membrane-Sternson

MORTARS,

Chemical

Materials-Nibco.

2.6

Epoxy-Base

. 218
. 220
.221
. 223
. 225
. 236
. 238

. 240

Hose Stocks-Gates

Polysulfide

3.1

Chemicals

and Membranes-Atlas.

2.5

Elastomer

Resins-Amoco

Fabrications-Atlas.

..........................

Elastomer-American

Synthetic

Ester

Chemical

2.4

CEMENTS,

and Vinyl

..................................

..............
..................
Fluoroelastomer-Elkhart
Rubber.
...............
Fluorosilicone
Rubbers-Dow
Corning.
................
Polysulfide
Rubber-Morton
Thiokol

2.3

179

.............

Systems-Resistoflex.

......................
....................................
................................
Linings-Watersaver.

Various
Various

2.2

174

............................................

1.65

Acrylic

....

..............................
Resins-Celanese
Plastics ................................
Plastics ..........................................

1.66

2.1

Haveg Division.

Tubing-Barnant

Electric

RUBBERSANDELASTOMERS

. 170

Resins-Ametek,

Piping

and Polyethylene

and Fluoroelastomer

1.63

. 159

Pont ....................................
...........................
Resins-Duriron.

Resins-Du

and ABS Plastics-Monsanto.

Chloride,
Silicone

Fluoride

and Polyethylene

Halogenated

. 156
. 157

.....................................

Resins-Ashland.

and Polyvinylidene

SAN

151

. 152
. 154
. 155

Products

and Furfuryl

and Vinyl

147
. 149

155

Polyvinylidene

1.49
1.50

122

. 142

............................................

1.48

Tetrafluoroethylene

120

Products.

Chemical.

369
369
373

..........

375

..........

379

..........

382

..........

383

..........

383

Contents

3.8

Sulfur

3.9

Urethane

Asphalt

3.10

Polyester

and Epoxy

3.11

Various

3.12

Various

3.13

Various

3.14

Various

Concrete

and Coating-Sulcon
Flooring

..........
....

Compounds-Atlas

.....................
.............
Mortars-Koch
Engineering
Mortars-Pennwalt
...................
Mortars-Sternson
...................
Cements-Atlas

Austenitic

Alloy-Allegheny

4.2

Austenitic

Stainless

4.3

Ferritic

4.4

Ferritic-Austenitic

Stainless

Steel-Cabot

4.5

Iron Alloy-Cabot

Wrought

Products.

4.6

Iron

4.7

iron-

4.8

Stainless

4.9

Various

Duplex

4.10

Various

Stainless

Steels-American

4.11

Various

Stainless

Steels-Carpenter

4.12

Various

Stainless

Steels-Cyclops

..................
............................

4.13

Various

Stainless

Steels and High

Nickel

Stainless

Ludlum.

Steels-Jessop

Steels-Allegheny

Alloys-Cabot

Stellite

and Nickel-Base

Wrought

.........................
..........................

Division

Alloys-Stainless

Steel-Armco

Stainless

and Austenitic

Foundry

Steel Products.
Stainless

..................

Steels-Climax

Iron and Steel


Technology.

Alloys-Climax

Aluminum

5.3

Aluminum

Bronzes

5.4

Aluminum

5.5

Aluminum-Zinc

ALLOYS.

Alloy-Alcoa.

and Nickel-Aluminum

Bronzes-Ampco

5.7

...........................
Steel .................
Beryllium
Copper Alloy-Brush
Wellman ..................
......................
Cobalt-Base
Alloys-Cabot
Stellite

5.8

Cobalt-Base

5.9

Cobalt-Base

Alloy-Cabot

Wrought

Alloys-Wall

...............

Products.

and Copper

Colmonov

5.13

Copper

5.14

Lead and Lead Alloys-Lead

5.15

Magnesium-Dow

5.16

Nickel

5.17

Nickel-Base

Alloys-Arco

5.18

Nickel-Base

Alloys-Cabot

Nickel-Base

Alloys-Stainless

5.20

Nickel-Base

Alloys-Wall

5.21

Nickel-Base

and Other

Nickel-Base

Rods,

5.23

Tantalum-NRC

5.24

Tantalum

5.25

Titanium-Industrial

Brass

Association.

Alloys-Huntington

5.19

.......
..........

American

Wrought

Pipe and Tubing-Colt

and Wires-Cabot

and Tantalum-Columbium

Alloy-Cabot

KBI

Zinc

5.32

Stainless

5.33

Titanium,

...............................

Alloys-Teledyne

Wah Chang Albany.

and Molybdenum-Schwarzkopf
Nickel
Steel,

........

Titanium.

Coating-Alcoa.

Cobalt,

........

..................................

5.28

5.31

.
.
.
.
.
.
.
.
.
.

Industries

Stellite.

5.27

Zirconium

.........

& Engineering.

.....................

Colmonoy

and Stainless
Nickel

Zirconium

Steel Alloys-Cabot

and Copper

............

Development.
Alloys-Carpenter

and Tantalum-Astro

.
. . . .
. . . .
. . .
. . .
.. .
. .
. .. .
. . .
.
.
. . . .
. .. .
.
. .. .
. . .
. .

...............

Products

Foundry

High Alloy

...........

Alloys

........................
...................
Titanium
and Titanium
Alloys-Timet.
Zinc Alloy-New
Jersey Zinc.
.........................

Tungsten

.
.
.

.....................

Allvac

Electrodes

.
.
.
.
.
.
.
.
.
.

...........................

Alloy-Teledyne

5.22

Metals,
Industries

Chemical

and High-Nickel

5.29

Coating-Bethlehem

5.12

5.30

Metal

Coating-Alcoa

.....................
Columbium-Cabot
KBI .............................
................
Columbium-Teledyne
Wah Chang Albany.
Copper Alloys-Revere.
.............................

5.26

...

Molybdenum.

5.2

5.11

..........

Institute.

.......................
............................
................
Alloys-Aluminum
Association.
AND

....

Molybdenum

Aluminum

METALS

........

& Engineering

5.1

NONFERROUS

..........

Products

Stellite.

.......
.......

Technology.

Metallurgical.

.......

..
.
.
. .
. .
.
. .
. .
. .
. .
. .
. . .
. .
. . .

.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......

.........................
Steel. .......................
Ludlum
.....................

4.1

5.10

. . .
. .
.. .
. .
. . .
. .
. .

...........................................

FERROUSALLOYS

5.6

.
. .
.
.
. .
.
. .

......
......
......
......
......
......
......

......

Systems.

Membrane-Pennwalt.

. .
. .
. .
.
. .
.
.
.
.
.
.

.
.
.
.
.
.

.
. . .
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......
.......

ix

384

387

.
.. . .
. .
.. . .

388
389
391
399
406

. . .
.
. . .
.
. . .

.
.
.

.
.
. . . .
. .
. . . .

412
412
413
414
420
424
425
426
428
429
431

. . .
. . . .
. .

433

.
.
.
.
.
.
.
.

609
609
610
632
633
638
639
643
644
645
646
647
648
649
655
663
664
665
666
725
728
729
730
731
732
735
736
742
744
749
756
756
757
764

.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.
.

. . .
. . .
.
. . .
. . .
.
. . .
.
.
. . .
.
. . .
. . .
. . .
..
.. .
. .
.
. .
. . .
. . .
. .
.. .
. . .
. . .
. . .
. .
. . .
. ..

.. . .
. . . .
.
.

440
444

Contents

5.34

Tungsten,

5.35

Various

Metals

and Alloys-Duriron

5.36

Various

Metals

and Alloys-General

5.37

Various

Metals

and Alloys-Walworth

GLASS,

Tantalum

CERAMICS,

AND

Alloys-Kennametal .............
...............................
Metals Technologies.
.................
..............................

and Titanium

Carbide

Carbon-Graphite-U.S.

6.2
6.3
6.4
6.5
6.6

COMPARATIVE

Graphite.

RESISTANCES

OF MATERIALS

. . ..
. . . .
. . . . .

. . .781

. . . .
. . .
.
. . . .
. .
. . . .
. .

. . . 786
. . 786
.

. 790

.791
. 792

. . . 792
. 793
.796

Aluminum

Iron

and Steel

7.2

Metal,

Carbon,

7.3

Polymeric

7.4

Rubber,

7.5

iron,

................

839

7.6

846

7.9

..................
.............................
Various Resin, Elastomer
and Steel Tank Materials-Nalge.
..............................
Metal, Elastomer
and Plastic Pump Materials-Oberdorfer
......................
Glass, Metal and Plastic Piping Systems-0-I/Schott
Process Systems.

7.10

Natura!

7.7
7.8

Nickel

Filtration

System

7.12

Plastic

7.13

Steel, Titanium,
NAME

Fibers,
Titanium,

AND

MATERIAL

796

Lead, Glass, Concrete


for Castings

Porous

Stone

Ceramic,

Pump

or Porous

Rubber,

Carbon

Natural

Lining

Materials-Gates

Jabsco.

797
809
Rubber.

Cylinder

Filter

Tube

and Synthetic

854
882

......

Materials-Sethco.

Fiber

Pump

. . . . . .

Heating

. .

884

and
885
889

...............................

and Tantalum

.. 821

848

...........................................

Columbium
LISTING

and Wood
Materials-ITT

and Forgings-Janney

Materials-Thompson-Chemtrol.

Zirconium,

............
Materials-Corning
...................
Rubber.

Construction

and Brass Couplers-Gates

Materials-Sethco

ADDRESS

and Wood

Resin and Rubber

Alloys

and Steel Pump

TRADENAMEINDEX
CORROSIVE

Aluminum,

and Synthetic
Alloy,

Plastic

Aluminum

Synthetic

and Copper

7.1 1 Resin, Steel,

COMPANY

Rubber,

Hose and Steel,


Steel,

Materials-American

...................................................

Institute.
Ceramic,

Resin, Steel,

Construction

. 771
. 773
,777

Steel,

Bronze,

Plastic Tank

. . . . .. . .

........................

OF CONSTRUCTION

Reinforced

.
.
.
. . . .
. .
. . . .
.

.
.

7.1

Iron,

and Glass Fiber

.
.

. .
.
.
. . .
. ..
.
.
. . .
. .

CARBON-GRAPHITE.

.....
........
Ceramic Fiber Products-3M.
.........
Ceramic Linings-Abresist.
......
Foamed Glass Block-Pennwalt
..............
Glass Pipe-Corning
...........
Glassed Steel-Pfaudler.

6.1

. . . . .. ..

and Cooling

. . . . . . . .

.....

Coils-Vulcanium

. .

. .

891

. . . . . . . . . . . .892

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...897
INDEX.

. .

. . .

. .

. .

. . .

. .

. . .

.900

Synthetic

TABLE

1.1:

ABS JACKETS

AND

Resins and Polymers

COVERS-CEEL-CO

Typical

Resistance

Acetrc Acrd. I %, 30 days


Acetic Acrd. 50%. 30 days
Acetrc Acrd. concentrate
Acetone, 10%
Alummum Sulfate, 25%
Ammonra Gas
Ammonrum Hydroxrde
Beer (over 3 2% alcohol)
lBenzaldehyde Concentrate
*Benzene
lBenzyl Ether
Bromrne
lBromoethane
Butane
Butyrrc Actd
Calctum Chloride. 25%
Calcrum Sulfa!e,
25% solutron
Carbon Droxrde
Carbon Tetrachlonde
lChlorobenzene
Chloropropane
Chromrc Acrd, 30%
Citrrc Acrd, 25%
Cod Lrver 011
Collordal Sulfur,
30 days, 140F
Corn 011
Cyciohexanol
lCyciohexanone
Detergent
Drethanolamtne.
30 davs. 140F
Dtethylene Glycol
Diethyl Ether
Drethyl Ketone
Ethyl Acetate
Ethyl Alcohol. 50%
Ethylene Gfycol.
30 days, 140F
Ferrol 1s Sulfate, 25%
Form: Ildehyde, 30%. 30 days
*Freon 11
Freon 12

Features

of CEEL-TITE

100 Series

Gasorne
Glucose, 30 days.
30% 146F
Gfycerrn, 30 days, 140F
Grapefrurt Jutce 30 days
Heptane. 30 days
lHexane
Hydrochlonc
Acrd, 30 days
Hydrogen Peroxide. 3%
Kerosene, 30 days
Ltght Process Ori.
30 days : 40F
Liquid Wrench
*Methyl Ethyl Ketone
Mrnerai Spirits. 18 months
Motor 011. 6 months
Naphtha (lighter fiurd)
3 months
Paratftn, 30 days
lPentane
*Phenol
Phosphonc Acid. 30 days
Phosphonc
Acid, 30 days
140F
Potassium Chloride, 25%
Potassrum Hydrox\de.
Saturated sol&on
30 davs. 146F
Red Copper Oxrde. 30 days
140F
Sodrum Brcarbonate Solutton
30 days, 140F
Sodrum Chlonde Solutron,
30 days. 140F
Sulfunc Acid,
50% 30 davs
Syrup. SrmpleSugar
Tomato JUICP
Tnsodrum Phosphate
Ucon M-l@ Hydraulic Flurd
7 days. 160F
Unc Acrd. 30 davs
Vtnegar
Frim Remover

U
S

S -Satisfactory
U - Unsatfsfactory
Test Method

lSatisfactory
atmospheric
@-

ASTM D -

543 -

for use under


conditions

Regtstered

Trademark

72

z
S
;
:

s
S

s
U
s
S
S
il
U
S
U
S

S
S
S
S

s
s

Z
Z

Corrosion Resistant Materials Handbook

TAB.LE 1.2: ABSIPVC ALLOYS-A.

SCHULMAN

A special outdoor rigid polymer alloy, POLYMAN 507 retains more impact strength after UV exposure than any
competitive
material according to UL recognition tests. It is rated UL Bulletin 94 V-O and carries 95C continuous
use temperature
rating. In addition it offers the good electrical properties and tensile strength needed for wiring
devices and small tool housings. A rigid polymer alloy, POLYMAN 509 exhibits low shrinkage (0.0045 in/in) and
combines a 212F heat distortion
temperature
with a superior 430,000 flexural modulus to mold and hold strict
dimensional tolerances in critical fit applications such as printed circuit card holders. Its high arc track resistance
and compressive strength, along with a good balance of other properties, qualifies for applications in severe electrical service such as junction boxes and connectors. POLYMAN 511 offers the highest impact strength (83.5 tensile
impact; 320 in lb Gardner impact) of the POLYMAN UL V-O rated rigid polymer alloys. It also has excellent UV
color stability along with the exceptional stiffness and flatness required for large business machine and consumer
appliance housings.

POLYMAN

507, 509, 511 Chemical Resistance

Class S-Satisfactory (only minor absorption)


Class A-Surface affected only slightly; still performs mechanically
Class P-Poor resistance; not recommended exposure

CLASS

Linseed Oil
Mineral Oil
Motor Oil
Nitric Acid, 40%
Olive Oil
Potassium Hydroxide, 50%
Sodium Carbonate
Sodium Hydroxide,
50%
Sulphuric Acid, 97%
Ammonia, 30%

Brine Solution
Clorox
Citric Acid 2N
Gasoline
Glacial Acetic Acid
Hexane
Hydrochloric
Acid, 30%
Hydrochloric
Acid 2N
lgepal
Lactic Acid 20%

CLASS A
Chloroform
Chromic Acid 30%
Ethyl Alcohol
Formaldehyde,
35%
Formic Acid (Anhydrous)
Glycol
Isopropyl Alcohol
Oxalic Acid 50%
Phosphoric
Acid, 85%
Silicone Oil
Turpentine

CLASS P
Acetone
Benzene
Carbon Bisulfide
Carbon Tetrachloride
Ethyl Acetate
Methyl Ethyl Ketone
Toluene
Xylene

NOTE: For solvent welding, use such solvents as:


Perchlorethylene
with Cyclohexanone
Tetra Hydrofurane
with M.E.K.
For vapor degreasing,
use such agent as:
Freon TE with Alcohol

Synthetic

TABLE

1.3: ACETAL

CELCON
trioxane.

COPOLYMERS-CELANESE

PLASTICS

is a registered trademark
of the Celanese Corporation
used for its crystalline
CELCON
acetal copolymer
can be injection molded, blow molded, extruded,

machined. CELCON acetal copolymer


offers high mechanical
strength through broad ranges of temperature and environment.
Celcon Grade
Formulation

Melt Index

UlO-11

1.0

M25-01

M2504

Resins and Polymers

strength,

stiffness,

acetal copolymer

based on

rotationally
cast and easily
toughness, and practical impact

Range

Description

Application

Excellent processabillty
in extrusion
blow moldtng. injection blow molding
and extrusion. High melt strength. Low
odor grade for aerosols.

Aerosols, containers, industrial articles,


rod, tube, slab, profiles.

2.5

Excellent processability
Not lubricated.

Rod, tube, sheet, slab, wire coating

2.5

Good processability for injection molding in easy-to-fill molds. Possesses greater toughness and elongation
than
materials with 9.0 melt index. Same as
M25-01 except that it is internally lubricated.

Injection
molded parts requiring
timum toughness and elongation.

General injection molding.

in extrusion.

M90-04

9.0

Excellent moldability due to high flow


characteristics and stabtlity in processing High surface gloss and good dimensional
stability.
Internally
lubricated.

M90-08

9.0

Ultraviolet
stabilized.
Good maintenance of physical properties and resistance to chalking in outdoor exposures.

Injection molded
plications.

M270-04

27.0

Highest flow. Superior moldability for


hard to fill molds with somewhat less
toughness than M90. Internally lubricated.

H.igh speed injection


cavity parts.

seasonal

outdoor

molding

op

ap-

for multi-

M90-07

Celcon color Concentrates are provided


in a wide range of standard colors for
letdown into natural Celcon via extruinjection
molding
sion
or screw
machines.

To obtain body colored injection molded


or extruded products at cost savings.

GC-25A

2.5

M90 Resin reinforced with 25% by


weight of glass fibers together with a
unique coupling agent. Provides increased stiffness, tensile strength and
creep resistance.

Windshield wiper pivots, gears, pulleys


and other parts requrring the maximum
in stiffness and strength.

(continued)

Corrosion Resistant Materials Handbook

TABLE 1.3: ACETAL

COPOLYMERS-CELANESE

PLASTICS

Chemical

Resistance

of Celcon

Time

Temp

Yield

(continued)
M90,

M25, M270
o:cChange

Matenal

Months

Control (Air)
INORGANIC

Strength

12

73

6
12
6
6
12
6
6
6
12

73
73
180
73
73
73
73
73
73
180
73
73
180
180
73
73
73
73
180
180
73
180

0
0.7
-0.3

Tensile
Modulus
0

Length
0

Weight

Vwble
Effect3

0.22

N.C.

CHEMICALS

10% Ammonium

Hydroxide

3% Hydrogen Peroxide
10% Hydrochloric Acid
10% Nitric Acid
10% Sodium Chloride

2% Sodium Carbonate

20% Sodium Carbonate


1% Sodium Hydroxide
10% Sodium Hydroxide

60% Sodium Hydroxide


4-6% Sodrum Hypochlorite
26% Sodium Thiosulfate
3% Sulfuric Acid
30% Sulfuric Acid
Buffer, pH 7.0
Buffer, pH 10.0
Buffer, pH 4.0
Water (Distilled)

ORGANIC
CHEMICALS
5% Acetic Acid
Acetone

Aniline
Tint
Benzene
Carbon Tetrachloride

10% Citric Acid


Diethyl Ether
Dimethyl Formamide
Ethyl Acetate

:
12
6
6
6
12
6
12
6
6
6
6
6
12
6
6
4
6
12
12

6
12
6
12
6
6
6
6
12
:
12
6
6
6
12
6

0
-16
-12
-15
-12
X
X
-12
-15
-10
-9
-9

-6
-7
-12

0.2
0.2
0.2
0.2
0.2
0.4
0.2
0.2
0.2
0.2
0.2
0.2
-0.1
0.1
0.2

0.88
1.03
0.74
0.97
0.88
X
X
0.59
0.71
0.49
0.77
0.78
0.96
0.61
0.80
0.84
0.49
0.73
0.83
-0.18
-3.29
0.61

-8
-14
X
-15
-12
X
-12
-12
-18

0.4
0.2
X
0.3
0.3
X
0.2
0.2
-0.1

0.81
0.82
X
0.94
0.89
X
0.83
0.84
-3.32

73
73
120
180

-1
0.6
-4
-17
-19
-26

-15
-16
-20
-48
-48
-73

0.3
0.2
0.7
1.6
2.1
4.8

1.05
1.13
3.60
3.68
4.45
12.1

N.C.
N.C.
N.C.
N.C.
N.C.
Reddish

120
73
73
120
73
73
73
180
73
73
120

-17
-1
2
-11
0
3
-15
-19
-5
-17
-22

-43
-4
-6
-32
-12
-10
-26
-63
-20
-46
-50

1.8
0.2
0.1
1.2
0.3
0.2
1.1
3.1
0.6
1.6
2.1

3.93
0.86
1.39
5.23
0.74
1.93
2.09
7.7
3.62
4.25
5.23

N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.

:
X
X
2
3
4
0
6
3
3
1
2
1
-2
-3
-3
-6
3

73
73
73
180
180
180
73
73
180

3:

1;
2
2
-8
1;

0.3
0.3
0.4
0.3
0.3

Disc.
DISC.
Disc.
N.C
N.C.

N.C.
SI. Disc.
SI. Disc.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
SI. Disc.
St. Disc.
Pitted
N.C.
N.C.
N.C.
SI. Disc.
SI. Disc.
N.C.
N.C.
Disc.

(continued)

Synthetic

TABLE 1.3: ACETAL

COPOLYMERS-CELANESE

PLASTICS

Materral
Ethylene Dichloride
50% Ethylene Glycol
95% Ethanol

50% Ethanol

Heptane

Oleic Acid

5% Phenol
Toluene

OTHER

Temp
F

6
6
6
12
6
6
12
6
6
12
6
6
12
6
6
12
6
12
6

120
180
73
73
120
73
73
120
73
73
180
73
73
180
73
73
73
73
180

-17
-4
-5
-13
-2
3
-6
-1
3
0
-15
-10
-7
-7
-14

6
6
6
12
6
12
6
6

180
180
73
73
73
73
180
180

6
6

180
180
180
73
73
180
180
180

I;

6
6
6
6
6
6
6
12
6
6
12
6

120
120
120
180
180
180
73
73
180
73
73
180

-12
-6
0
8
4
-3
3
8
-1
5
5

Yreld
Strength

O0Change
TenslIe
Modulus

Vwble
Effect3

Length

Wetght

-45
-46
-17
-19
-43

3.2
0.4
0.6
0.7
1.3
0.6
0.7
1.0
0.2
-0.07
0.2
0.3
-0.04
0.5
2.1
1.4
0.4
0.7
16

10.05
1.33
1.43
2.19
2.54
1.62
1.98
2.27
0.04
0.09
0.35
1.05
-1.26
1.04
9.34
4.70
1.12
1.87
3.80

N.C.
SI. Disc.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
Disc.
N.C.
N.C.
N.C

5
0
0
3
-3
-0.5
-11
-5

5
-23
-12
-1
-13
-9
-41
-33

-0.07
0.6
0.3
0.2
0.3
0.2
1.4
1.3

-0.15
1.53
0.34
0.53
0.70
1.05
3.60
3.18

N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.

2
3
3
18
3
0

-11
-15
-10
-14
-15
-18
-20
-15

0.2
0.3
0.3
0.4
0.4
0.7
0.4
0.5

0.85
1.00
1.04
0.75
0.84
1.62
1.04
1.32

0.7
0.7
0.7
0.3
0.2
0.2
0.2
-0.06
0.0
0.2
-0.06
-0.06

1.30
1.50
1.43
0.34
-0.13
-0.03
-0.03
0.05
-0.18
0.02
0.04
-0.14

-23
0
1;

-68
-18
-19
-35
-31
-24
-32
-34
-13
4
-9
-15
-i

MATERIALS

Automatic Transmission
Anti-Freeze (Telar)
Brake Fluid, Super 9

Fluid

Brake Fluid, Lockheed 21

Brake Fluid, Delco 222


Detergents
Acclaim
Calgonite
Electra-Sol
50% lgepal

Detergent Solution2
1% Soap Solution
Gasolines
Mobil Regular (9315 Octane)
Mobil Hi-Test (99.0 Octane)
Sunoco 280 (103 Octane)
Kerosene
Linseed Oil
Lubricating Grease
Mineral Oil (Nujol)

Motor Oil (1 OW30)

:
12
6

-11

-12
-12
-10
-7
11
3
-14
-1
7
-9
7
0

SI. Disc.
SI. Disc.
N.C.
N.C.
N.C.
N.C.
SI. Disc.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.
N.C.

1. Type 1 TenslIe bars used nnthese tests measure 8!5 x % x / Inches. rutlal yleld strength IS 8800. tenslle modulus 410,000. weight 13 grams
2 Cowsts

(continued)
__~

Time
Months

Resins and Polymers

of 0 5 grams of an alkyl sulfonate + 0 20 grams of trisodlum phosphate per liter of water

3 X = Not recommended,

N C. = No Change; DISC = Dlscoloratlon.

SI DISC = Slight discoloration

TABLE

1.4: ACRYLIC

RESINS-ROHM

AND HAAS

0,

PLEXIGLAS is the registered trademark for acrylic plastic sheet produced by Rohm and Haas Company.
In its natural
tically clear, transparent,
lightweight
material having outstanding weatherability,
high impact resistance, good chemical
ity and machinability.

form, PLEXIGLAS
acrylic sheet is an opresistance, and excellent thermoformabil-

2
q
o
I.
2

Chemical Resistance of PLEXIGLAS

Sheet*

PROPERTY
1 Thickness
CHEMICAL

1 inches
RESISTANCE

0543

WEIGHT GAIN AFTER 7 DAYS IMMERSION AT 77F.


(WEIGHT GAIN OR LOSS OF 1% OR LESS IS CONSIDERED

COMPOUND
ACIDS

CLASS

TYPE
Glacial

Chromic Acid
Citric Acid
Hydrochloric
Hydrochloric

Acid
Acid

Hydrofluoric

Acid

Concentrated

Concentrated

Nitric Acid
Nitric Acid
Nitric Acid

CONCENTRATION. %
R-S
05

100
5

R-S
04

R-S

40
10

0.2
03

0.2
0.3

0.2

30
10

0.2
0.3

40
70
40
10

Olelc Acid

BASES

.0250

NEGLIGIBLE)

NAME
Acetic Acid
Acetic Acid

04

DL
0.5

0.4

-_
0.3

4-D
0.4

02
03

A-D-S
0.4

0.3

A
04

8 SE

0 SE

13E

A-D
20
0.3

A-D
2.8
03

D-R
5.3D
0.4

03

A
5-A
04

0.0

00

0.0

00

-0.1

04

Sulfuric Acid
Sulfuric Acid
Sulfuric Acid

Concentrated

96
30
3

D-R-S
0.2
0.4

D-R-S
0.2
0.4

D-R-S
0.3
0.5

0.2
0.4

DL
03
0.5

Ammonrum
Ammonium

Concentrated

20
10

0.2
0.4

0.2
0.3

0.3
0.5

0.3

0.3
0.5

Sodrum Carbonate
Sodwm Carbonate

20
2

0.2
0.4

0.2
0.4

0.3
0.5

0.3

0.3
0.5

Sodrum Hydroxrde
Sodwm Hydroxrde
Sodrum Hydroxrde

60
10

-0.2
0.3
0.4

-0.2
0.3
0.4

-0.2
0.4
0.5

0.3
0.4

-0.4
04
0.5

Hydroxrde
Hydroxtde

(continued)

TABLE

1.4: ACRYLIC

RESINS-ROHM

AND HAAS

(continued)

TYPE

COMPOUND

CLASS

COMMERCIAL

PRODUCTS

Cottonseed

011

Detergent

Solution

Kerosene

0.25

Plexrglas G
II UVA.
II-UVT. G-UVT

Plexrglas
K

Plexiglas
55

Plexrglas
IA UVA

Plexiglas
MC

er0.1

-rO.l

to.1

0.1

0.4

0.5

0.1

0.3

0.3

-:o. 1

-;O.l

c:.o. 1

DL

DL

0.3

DL

DL

USP

c.o.1

to.1

co.1

0.1

Olive Oil

Edible

Grade

..O.l

co. 1

<O.l

0.1

Soap

Whrte

Flakes

0.5

Sotutton
011

Turpentrne

Distilled

0.3

0.3

0.4

01040)

to.1

co.1

<O.l

0.1

Distilled Spirit
(ASTM 013)

<O.l

<O.l

0.1

0.1-c

0.4

0.4

0.5

0.4

0.6

(ASTM

Water

Hydrogen
Hydrogen

COMPOUNDS

Duty

PLASTICS

White,

Oil

Transformer

ORGANIC

Heavy

Thinner

Mrneral

COMPOUNDS

Edrble Grade

NO. 2 Fuel Oil


(ASTM 0396)

Lacquer

INORGANIC

TYPE

NAME

CONCENTRATION.
%

OF ACRYLIC

Peroxide
Peroxide

Sodium

Chloride

Sodium

hypochlorite

26
3

0.4
0.4

0.4
0.4

ct.7
0.6

0.4

0.8
0.6

10

0.3

0.3

0.4

0.3

0.5

0.3

0.3

0.3

0.4

DL

DL

R-S

DL

DL

DL

Acetone
Aniline

DL

DL

12R-S

Benzene

DL

DL

0.1

Carbon

--0. 1

Tetrachloride

0.1

DL

0.0

-3.0

-5-A-E

-0.1

-0.1

0.0

0.0

0.1

cro. 1c

I: O.lC

-0.1

R-S

DL

DL

A-S

DL

Ethyl Acelate

DL

DL

R-S

DL

DL

Ethyl Alcohol
Ethyl Alcohol

1.4
0.8

1.4

1.1
1.7

7.5
2.2

4.0
2.0

Drbutyl Sebacale
Dlethyl
Drmethyl

Ether
Formamrde

95

50

0.6

(continued)

TABLE

1.4:

ACRYLIC

RESINS-ROHM

AND

HAAS

(continued)

TYPE OF ACRYLIC

COMPOUND
ORGANIC

NAME

CLASS

COMPOUNDS

Ethylene

TYPE

CONCENTRATION. %

Dichlorrde

P-Ethylhexyl

Sebacate

Plexrglas

Plexrglas

55

IA UVA

Plexrglas
MC

4
2
2

DL

DL

R-S

DL

DL

co.1

0.0

0.0

0.0

0.0

0.1

lsooctane

-rO.l

co.1

<O.l

0.1

0.1
5.5s

0.1
5.8s

-0.2
14s

-0.1

A-C

A-C

A-C

A-C

DL

DL

0.0

DL

DL

Alcohol

Toluene

99

A
C
0
DL
E
R
S

=
=
=
=
=
=
=

Attacked
Crazed
Discolored
Dlssolved
Edge Swellmg
Rubbery
Swollen

*Weight change is affected by the thickness of the material. Values given are for the thickness noted in the column heading.
*Although
carbon tetrachloride causes negligible weight change in contact with PLEXIGLAS
sheet, it does cause optical distortion
used with PLEXIGLAS.

0.1

s-o.1

Phenol (Aqueous)

Code:

Plextglas

G-UVT

q.o.1

Methyl Alcohol

Resistance

II-UVT.

z.
s

Heptane

Isopropyl

Chemical

Plextglas G
II UVA.

PLASTICS

of the surface. Carbon tetrachloride

should not be

$
?
5
z
x
%
8
8
h

TABLE

1.5:

BAREX

210

ACRYLIC
Resin

RESIN-SOHIO

CHEMICAL

is an acrylonitrile-methyl

acrylate-butadiene

polymer.

Chemical Resistance of Barex 210% Resin


F/T

Observed

Change

ACIDS
1090
30%

73123
100138
73123
100138
73123
100/38
73123
lOdl38
73123
100138

Hydrochloric
Sulfuric

Acetic

100%

30% Phosphoric
10% Nitric

None
None
None
None
None
Frosted, Softened
None
None
None
Yellowed

Ammonium

Hydroxide

Barium Hydroxide
Calcium Hydroxide
10% Potassium Hydroxide
10% Sodium Hydroxide

73123
100138
73123
100/38
73123
100138
73123
100/38
73123
100138

None
Softened
None
None
None

73123
100138
73123
100138
73123
100/38

None
None
None
None
None
None

None
Slight
Frost

Frost, Softened
Slight Frost
Frost, Softened

HYDROCARBONS
Benzene
Toluene
Xylene

Trichloroethane

73123
100138

Trichloroethylene

73123
100138
73123

Methylene Chloride

100138
73123

1 ,l ,l,

100138

Observed

Change

None
None
None
None
None
None
Frosted, Rubbery
Frosted, Rubbery

KETONES
Acetone

73123
100138

Methyl Ethyl Ketone

BASES
10%

FiT

Carbon Tetrachioride

Methyl lsobutyl Ketone

73123
100138
73123
100138

Softened
Softened
Frosted, Softened
Frosted, Softened
None
None

ALCOHOLS
Ethyl Alcohol

73123
100/38

Isopropyl Alcohol
Glycol

73123
100138
73123
100138

None
None
None
None
None
None

ESTERS
Butyl Acetate
Cellosolve Acetate

73123
100/38
73123
100138

Ethyl Acetate

Exposure time in all testing was one year.

73123
100138

None
None
None
None
None
Frosted, Softened

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

TENITE
esters are cellulose derivatives of acetate, butyrate,
and propionate.
Tenite plastics for molding and extrusion are supplied in the form of pellets. These
resins
have good processability
and finished articles may be resoftened by heat and reshaped by the application of suitable forces.
thermoplastic

Effect of Various
Material

Tested

Percent

Increase

l-

Chemicals and Reagents on TENITE@

Observed Condition
of Plastic

hicknes!

Material

CHEMICALS

Alcoholr.

Acids

n-Am+
tert.Amyl
n-Bury1
seeBury
tert-Butyl

Acetic. 590

I year

5 53

3 19

Acetic,

1 week

5 44

3 03

17.03

22 57

2 63

1.67

10%

Acetic. 30%
*Chromic. 6%
Citric, 10%

1 week
6 days (100F
1 year

Citric. 10%
Citric, 30%
Fluosi!iclc, 10%
Fluosillclc. 28%
Formic, 3%

2 months l14OF)
1week (140F)
2 monrhs
2 months
20 days

Hvdrochlorlc.
+Hydrochlorrc,
lHydrochloric,
Hydrofluoric,
Hydrofluoric,

2 days
2 days
1 month
1 month
1month

6%
6%
10%
lo?/,
48%

-1.30
-1.67

1.26
0 06
2.06

2.03
0 00

0.05
-0 61
1 49

Shghtly

softened,

surface

attacked
Shghtly softened, surface
attacked
Softened
Softened and swollen
Unchanged
Decomposed
Decomposed
Slightly warped
Slrghtly warped
Unchanged
Unchanged
Softened
Softeled and swollen
Softened and swollen
Decomposed

Tested

2 days
2 days

N~rrlc, 10%
Ol0C
Phosphoric. 30%

1 week
1 year
2 months

Phosphoric, 50%
*Phosphoric, 75%
Pyrogallic. 4%
sreanc
Sulfuric, 3%

2 months
1week
1 week
1 week
1 month

Sulfuric, 10%
Sulfuric. 20%
Tannic. 10%
Tartaric
Trichloroacetlc

1 year
6 months
4 months (14OF)
2 days
1 month

3 14
6 80

1 50
4 34

-3 33
2 03

-0 83
0.63

1 63

-0 42

7.60

3 55

304

2.19

7.62
2.93

1 63
1.60

Unchanged
Shghtly softened, surface
atracked
Decomposed
Unchalged
Unchanged
Brittle, surface attacked
Decoliposed
Stamed yellow
Unchanged
Softened
Decomposed
Decomposed
Softened
Unchanged
Decomposed

Tim0
Exposed

l-

Percent
Wai#n

Increase
licknen

-r

Obsmad
of

Condition

Plastic

monohydric

2 days
2 days
Z days
2 days
Z days

-0.36
-0.17
1.41
0.36
-2.00

0.26
0.19
1.40
0.76
0.26

*Drawtone
Ethyl
*Ethyl, 50%
2.Ethylhexyl
lroamyl

2 days
1week
1 week
2 days

12.70
14.46

27.90

lsobutyl
*Isopropyl
Methyl
*Methyl, 5%
vvPropyl
lTetrahydrofurfuryl

2 days
2 days
2 days
I year
2 days
3 days

-1.70
10.90
22.60
3.96
2.20

0.42
16.40
51.00
2.59
4.22

Unchanged
Swollen
Blushed. softened, and swollen
Blushed and softened
Blushed
Softened and swollen

Ethylene Glycol
Oiethylene Glycol

1 year
1 year
4 months

-0.66
1.29
20.76

-0.15
1.39
15.94

Triethylene

4 months

25.40

22.69

0.39

0.42

Unchanged
Very slightI\ softened
Warped and softened; surface
attacked
Warped and softened, surface
attacked
Unchanged

Alcohols,

-0.36

0.14

Jnchanged
Jnchanged
Jnchanged
Surface bleached slightly
Unchanged
Dissolved
Swollen and softened
Swollen and softened
Unchanged
Unchanged

di. and tri-hydric

Glycerin

Lacttc, 10%
Lactic. 50%

Acetate

Glycol

Propylene Glycol
Bases
Ammonium Hydroxide, 10%
Sodium Hydroxide, 1%
Sodium Hydroxide. 10%
Trimethylbenzyl Ammomum
Hydroxide. 5%

2 days

1 month
1 month
I week
17 days

12.41
-0.12
-4.07

5.85

Softened; surface attacked


bftened and warped
I&composed
iwollen and checked

EltW

Acetate
sec.Bury1 Acetate
Ethyl Acetate
Ethyl Lactate
n-Rutyl

! days
! days

7.24
3.74

9.75
3.62

iurface attacked
iurface attacked
Irnolved
Irssolved

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTVRATES,

PROPIONATES-EASTMAN

Effect of Various
Time
Expord

Material Tested
&err

Pornon
Weidtt

l-

WOOS?

Otnervad Condition
of Plastic

hlckna

Material
Hydrocarbons

Glycol

Acetate

Monoethyl

Ether

(EKTASOLVE=

Acetate,
Ethylene

Cello~olve
Glycol

Acetate

Methyl

lNaphthalene

EM

Acetate

2 days

1.89

0.61

Surface attacked

Isobutyl

Acetate

2 days

7.82

4.32

Surface attacked

2 days

1.32

a.44

Surface

Acetate

attacked

1 month

silicate

(122F)

-2.39

2 days

Ether

Oi-Isopropyl

2 days

Ether

(Moth

094

46 hours flOOF,

balls)

-0.83

1.38
-9.31

11.20
-0.15

1.4.Oioxane

24 hours f14OF.

2.02

Ether

(EKTASOLVE

1.63

considerable

gas

2 months

0.00

liqurd

1 month

0.00

Unchanged

lToluene

1 year

a.92

Swollen

Xylene

1year

2.12

Unchanged

plashcizer

Unchanged
and slightly softened

Halogenatad

Tetrachloride

2 months

14.92

4.12

Unchanged

Unchanged

Chlorobromomethane

Dissolved

Chloroform

Dissolved

Orssolved

lo-Oichlorobenzene

3 days

p_Orchlorobenzene

3 days

2.24

0.73

Unchanged

3 days (100F.

6.57

4.03

Showed

9.80

4.44

Slightly

swollen

Blushed and swollen


Unchanged

p-Oichlorobenzene
*Ethylene

1.02

2 days

Showed

Chlorobenzene

Ethar Alcohols
Monobutyl

plasticizer

exudation

Surface attacked

slrghtly

06;

some plasticizer

exudation

80% R.H.)
Glycol

considerable

exudatron

Dissolved

Dissolved

Oiethylene

Showed

Propane,

Hydrocarbons,

EUWS
Oiethyl

balls)

Propane,

*Carbon
Acetate

Observed Condition
of Plastic

hicknos

88% R.H.)

Cellosolve

Tetra(2ethylbutyl)

(Moth

Oraolved

Ethel

klsoamyl

Methyl

Pann
Wei&

60% R If.1

Acetate)

*Isopropyl

Trme

Expoad

(Cont.)

Naphthalena

Acetate)

Monomethyl

Acetate

Tested

EE

(EKTASOLVE

Acetate;

Surface attacked

2 days

(continued)

Chemicals and Reagents on TENITE@

fCont)

*Ethylene

CHEMICAL

Orssolved

Chlorrde

lMethylene

Chlorrde

Propylene

Chlorrde

Dissolved
2 days

25.30

2.06

Blushed and blistered

3 days

5.36

3.45

Shghtly

Bury1 Carbitol)
Diethylene

Glycol

Monoethyl

(EKTASOLVE

lDiethylene
Ether

Glycol

Methyl

2 days

11.20

12.30

Swollen,

surface attacked

YTetrabromoethane

lTetrachloroethane
Dissolved

Monomethyl

(EKTASOLVE

Ethylene

Ether

DE. Carbitol)

Monobutyl

(EKTASOLVE

Ether

2 days

1.95

2.64

Surface attacked

shghtly

32 20

Surface attacked

Ketones

EBButyl

Glycol

Dissolved

Cyclohexenone
Monoethyl

(EKTASOLVE
Glycol

Dissolved

Acetone

Cellosolve)

Ethylene

16 hours

Trrchloroethylene

Carbitol)
Glvcol

Ethylene

Unchanged

2 weeks

Tetrachloroethylene

OM;

Ether

2 days

23.10

25 30

Swollen

and slightly

softened

EE. Cellosolve)
Dissolved

Monomethyl

Ether

(EKTASOLVE

Methyl

Cellosolve

Oi-Isopropyl

Ketone

Methyl

n_Butyl

Methyl

Ethyl

Ketone

2 days

0.04

0.31

2 davs

13.40

16.20

Swollen,

surface attacked

EM,
Methyl

lsobutyl

Ketone

2 days

40.40

Methyl

n-Propyl

Ketone

2 days

51.30

7.39
78.50

Swollen,
Swollen

surface attacked
and warped,

surface

attacked

I week
I year

Benzene
Butadiene-1.3.

liqurd

Butadiene-1.3,

gas

that material

5.94
-9.42

I month

Heptane

rc,,.

Unchanged
Dissolved

Ketone

Hydrocarbons

Vndtcotu

swollen

Orssolved

ir generally

4.21

I year

-5

unr0rirfacrar-y

Jar YIC in conmcr

36

17.47
a.85
2.77
-1.20

with TENITE

Softened
tiarped

and swollen

Phorone

2 davs

0.64

0.24

Stained yellow

and shrunken

Showed exudation
Unchanged
Acetalc under thr condimnr

of rhu

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Material

Time
Expo&?d

Tested

Percent
Weight

Increase

Obsetwd Condition
of Plastic

Thickness

salts

Material

Acetate
Time
EXpOnd

Tened

Percent
Weight

Increase

salts (Cant)

Aluminum

Acetate,

3 97

2 months

Basic,

2.07

Unchanged

Aluminum

Chloride,

Aluminum

Chloride,

saturated
Aluminum

19%

Ammonrum

Unchanged

2 months

0.34

0 00

Unchanged

3 months

2.95

2.00

Unchanged

I month

3.56

1year

19%

2 months

-5.84

-4.64

Discolored

and softened

*Potassium

Cyanide.

saturated

2 months

-1.15

-2.66

Discolored

Slightly

I.34

and softened

3.29

Iodide,

saturated

3 days

bleached

Potassium

Permanganate.

I month

Unchanged

0.36

1.43

solution

saturated

3.27

1.39

Stained

Unchanged

Sulfate,

sohd

1 year

0.06

0.40

Potassium

Sulfate,

10%

I year

2.60

1 46

Unchanged

2 days

1.97

0.61

Slightly

2 days

2.96

1.60

Unchanged

1 week

4.03

2.37

Unchanged

1.56

Unchanged

I week

0.14

008

Unchanged

Srlver Nitrate,

Ammonium

Nitrate,

10%

1 week

2.91

156

Unchanged

Sodium

Bicarbonate,

Ammonium

Sulfate,

solid

1 year

0.0

055

Unchanged

Sodium

Bisulfrte,

Ammonium

Sulfate,

16%

1 year

3.66

1.64

Unchanged

3%
solid

20%

Sodium

Borate,

Calcium

Chloride,

solid

2 days

2.91

0.61

Unchanged

Sodrum

Carbonate,

solid

4 days

-0.10

-0

Calcium

Chloride,

2.5%

1year

2.93

2.10

Unchanged

Sodium

Carbonate,

2.5%

1 year

-0.74

-2.25

Calcium

Chloride,

40%

2 months

0.61

0.16

Unchanged

Sodrum

Chlorrde.

1.96

Slightly

Sodium

Chloride,saturated

solution

1.38

Brittle,

Chloride,saturated

solution

Hypochlorite,
Phosphate,

3 months

6%

2.94
-1.09

1 year

Monobasic.

softened

Sodium
Phosphate,

Dibasic,

Calcium

Phosphate,

Tribasic,

Calcium

Sulfate,

solid
soled

solid

Cupric

Sulfate,

10%

Cupric

Sulfate,

saturated

solution

1 year

-3.27

-0.6

1 year

-3.74

-0.87

1 year

-0.20

Unchanged

Cyanide.

10%

Sodrum

Cyanide,

saturated

Unchanged

Sodrum

Ferrocyanrde,

Unchanged

Sodrum

Fluoride,

3.50

1.76

Unchanged

2 months

3.07

1.66

Unchanged

2.26

*Sodium

2.75

Unchanged

solution
Ferric

Chloride,

5%

2 months

2.93

2.12

Unchanged

Ferric

Chloride.

20%

2 months

2.50

1.91

Unchanged

2 months

2.61

046

Ferric Chloride,
Chloride,

46%
saturated

Magnesium

Chloride,

Magnesium

Sulfate,

Mercuric

Chloride,

Potassium

Aluminum

Potasswm

Chloride,

solution

solid
sohd

1week

Sulfate,
sohd

21%

Unchanged
Surface

Nitrate,

10%
sarurated

Sodrum

Nrtrite,

soltd

06

Unchanged
Slightly

softened

2.52

1.53

Unchanged

2 months

1.26

0.54

Unchanged

Nitrite,

saturated

Srlicate,

solid

*Sodium

Srlicate,

saturated

Trimethylbenzyl

2 days

3 12

1.94

Unchanged

Chloride,

5.66

I.75

Unchanged

3.89

2.61

Surface

0.02

075

Unchanged

attacked

Zinc Chloride,
slightly

Zmc

Chlorrde,

-0.52

Unchanged

2 months

2 months

-4.20

-5.60

Drscolored,

softened

2 months

-0.64

-2.59

Discolored,

softened

(140F)

1 03

Unchanged

1 week

0.37

1 month

3.60

2 days

solutron

solutron
solution

Ammonium

0 65
-0.26

Unchanged
0 35
-0.23

Softened.

1year

2.56

145

Unchanged

1.46

0 65

Unchanged

-0

42

-0.36

2 months

0.76

0.27

Unchanged

0.57

0.19

Etched

-0.34

-2.60

17 days

0.59

3 20

1 weak

0.96

0 00

attacked

Unchanged

2 months
2 months

wface

Unchanged

2 months
2 months

Sodrum

Unchanged

I year

2.66

1 year

2 months

Nrtrate.

I .64

(lOOoF)

5%

solrd

Sodium

2.93

4 months

solrd

Sodium

Sodium

tacky

solution

4%

Hypochlorite,
Nrtrate.

2 days
2 days

5%

10%

0.42

2 months

1 week

saturated

2 days

Sodrum

Sodium
Chlorrde,

2.5%

softened

surface attacked

solid

Cuprous

black

2 days

Potassium

sohd

Calcium

yellow

solution

Nitrate,

Calcium

Stained

solution

Ammonium

Calcium

Unchanged

solution

solution
Chloride,

saturated

1.65

10%

Cyanrde.

Potassium
30%

&fluoride,

saturated

3.25

solution
Sulfate,

Ammonium

2 months

Chloride.

*Potassium

Potassium

33% water slurry

*Ferric

Obwwd
Condition
of Planlc

Thickness

Softened
Unchanged

5%
hydrous
saturated

salt
solution

1week

Unchanged
Drssolved

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Time
EXpOpd

Materiel Tested
Miscellaneous

rhicknm 5

Chemicals,

Compounds.
Ammoniated

Observed Condition
of Plastic

,creas.?
Wei&1

Mercury

week (60C)

Unchanged

Carbon

Disulfide.

1 month
2 days

saturated

0.59
5 85

Aviarlon.

1.86

Unchanged

2.39

Unchanged

Chlorine.

dry

1 week

3.58

0.77

Crazed and brittle

Chlorme,

moist

2.96

0 12

Crazed and brittle

*Chlorine,

saturated

I week
1 week

*Ethylene

Oxide,

1 day

18.54

Softened

39 70

1 week

35%

0.94

11.82

Extra

Shell

High-Test

Shell

Regular

Softened

and swollen

Texaco

Fire Chief

Texaco

Sky Chief

Hydraulic

dry

1 month

Sulfide,

moist

2 months

Sulfide.

saturated

2 months

Hydrogen
Hydrogen

Slightly

-2 58
-2 33
-2 29
-1.90

Stamed yellow
Stamed yellow
Stamed yellow
Stained

yellow

-2 49
-3.35

Stamed

yellow

Stained

light

statned

Softened

and swollen

0.75
2.29
2.22

Unchanged
Unchanged

Kerosene

5 58
2.48

3 11
0 82

Stained

hght yellow

011s

Stained

hght brown

500

Jet Propulsion

Unchanged

-1.07
1.15
-6.00

Skydrol

1 05
3.95
1.58

yellow

FluIds

Skydrol
Sulfide,

-5 56

011

and conslderably

Dissolved

Eugenol

Octane

Vacuum

Esso Regular

swollen
gas

Hydrogen

Obreweci Condition
of P1asttc

Company)
Eao

solution

115145

(Soconv

atmosphere

Formaldehyde.

Time
EXPOred

Gasolines

Dissolved

Alllne
Dwlflde

l-

Material Te~ed
Aeronautical and Automotive Item!
(Cont.)

and Gases

Carbon

Acetate

(Humble

Fuel 3

-0 24
0.42
-1.64

Unchanged
Surface

dulled

Unchanged

Oil Company)

-084

Unchanged

Solution
Hydroquinone,
lodme,

saturated

1 week

20 g/gal
solution

2 days

3 days

Nitrobenzene

Softened,

swollen,

Aeroshell
and badly

warped
*Phenol,

5%

Sulfur

Dioxide.

dry

Sulfur

Dioxide,

moist

Sulfur

Dioxide.

saturated

solution

1 week
2 months
2 months
2 months

HO. SAE

Shell

Dlala

Socony

Decomposed

17.30
13 50
10.60

11.60
9.71
13.50

No

Purol

12

10

011 AX

Oil OTE

Mrdlum

-5.95
-0.31

4 weeks (122F)

-2 01

Unchanged
Unchanged

-1

72

-0

08

-0 82
-0 12

-1

92

-0.30

No change
Unchanged

Spew

Swollen

and warped

Swollen

and warped

Low-Temperature

Swollen

and conslderably

MIL-L-644B

Texaco

Hew

1 VfA3l

6 months
2 months
3 days

A50,

1692
011,

warped
Nonautomotive
Titanium

Tetrachloride

Triethanolamine
Triethanolamine,

10%

3 days
I week
I week

Very brlrtle
11.72
-5.16

24.90
Badly softened
0.69 Softened. surface attacked

Essential

Greases and Oils

Oils

Bitter

50% I n-Buranol

CItronella

COMMERCIAL AND NATURAL


PRODUCTS
Aeronautical and Automotive
Items

Unchanged

0 56

033
0 33

21days

0.28

0.14

Unchanged

21days
21days
21days
21days
71jays

0.26
004
0 98
1.03

0 09
0 19
0 51

Unchanged

062

Unchanged

2 days
2 days

0 10

I year

I year
I year

-2 80
-2 92
-4.41

-0.19

08
-1 12
-0

Stained ltght yellow


Unchanged
Slighrly stained

Eucalyptus
Lemon
Menthol,
Palmarosa
Pennyroyal
Spea!mtnt

Unchanged
Dtaolved

ClOVes

Gasolines,

Amoco Regular
Amoco Premium
Aviation, 100 Octane
(Standard Oil Company)

O&solved

Almonds

Borneol.

50% I n-Butanol

Unchanged
Uncianged
Unchanged

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Material

Time
EXpored

Tsned

Nonautomotive

Percent
Wei&t

IncreaLe

Observed Condition
of Plastic

Thickness

Greases and Oils

Howhold

(CotIt)
Oils

Hinds

Terpineol

2 days

Thyme

(White)

2 days

Turpentine

1 year

Wintergreen

2 days

Mmeral

Oil

Crude

Sperm

011

011
Oil. G.E.,

Transformer

011, Pyranol

No

10-C

0.09

0.37

0.05

Unchanged

0 16

Unchanged

1.58

Surface

-0.85
2.74

Unchanged

iced Coffee

1 week

1.87

0.86

Stained

Iced Tea

1 week

1.98

1.04

Air-Wick

Detergent,

Kool-Aid

Items
Odor

-0.72

2 months
3 weeks

Bacon

5.65

Burma

Halt

Soft

Esther

Dressing

(in

Shave Cream

Lemon

Unchanged

Lemonade

Juice

0.00

5%

Catsup
Clorox

Solution

Coffee

Grounds

Colgate

Dental

Cologne

Sticks

Cream

2 days

Slightly

3 days

Unchanged

swollen

Detergent.

5%

Dwin

Household

Insect

Dwin

Stamless

Glim

Detergent

Glim

Detergent,

Fly Killer

Stained

attacked

4.30

4.00

Unchanged

1 week

2.47

1.37

Unchanged

4 days (lOOoF)

0.97

1.24

Unchanged

Earle Talcum

-0.73

Unchanged

3 days

Base Cream

3 days

Unchanged

Powder

Mennen

2 days

Unchanged

3 days

Unchanged

Mercurochrome

2 days

2 days

Unchanged

Milk

3 days

Badly

Softened
Slightly

2 months
1 week
1 week

stained

Shave Cream

softened

warped
and swollen
brittle

and slightly

Maid Frozen

3 26

1.46

Stained

light pink

Unchanged

Concentrates:

Grapefruit

1 week

1.94

0.62

Unchanged

Orange

1 week

2.01

0.92

Unchanged

Tangerine

I week
1week

1.87

0.72

Unchanged

1.77

0.86

Unchanged

2.78

1.44

Stained

Lemonade

Unchanged
1.92
0.93
-0.02
0.24
-0.99

1.04

Unchanged

1.99

Mustard

2 days

Oleomargarine

3 days

Unchanged
Unchanged

1.31

Unchanged

Orange Juice Concentrate

3 days

0.00

Unchanged

Peanut

3 days

0.00

Unchanged

Pebeco Tooth

1.80

Slightly

1.49

Unchanged

warped,

spots on drying
2 months

slightly

Badly softened
2.61

Powder

Badly

1 week

warped

Unchanged

1 week

Slightly

2 months
10%

3 days

1 week

28 days

Killer

Surface

1 year

Marie

stained

Dreft

3 days

2 days

40 days

Concentrate

and slightly

Unchanged

Unchanged

LIpstIck

Pineapple

1.82

3 days

Coty

Frozen

-0.32

Mayonnaise

Barb Salts

Dole

2 months

Unchanged
Swollen

Decomposed

Coty

Pomade

Paste

Lysol

Minute

Lipstlck

10.05

1 week

I day
I day

Coty

-3.27

Unchanged

Max Factor
Acid.

MIX

Lipstock

Lever Tooth

3 days

Butter
Carbolic

OrInk

2 months

3 days

Unchanged

refrigerator)
Brilliantine

10%

Lard

Neutralizer

and softened
bleached

shghtly

Lady
Household

warped

Unchanged
Bleached

Joy

Unchanged

Slightly

Shghtly

warped

Unchanged

Unchanged

4.30

1.73

Detergent

0.00

0.74

1.80

2.95

*Joy

0.56

167

I week

3.10

stained

58

1 week

4.46

Shghtly

-3

Cream

1 year

-1.25

-2.94

Observed Condition
of Plastic

LI

2 days

-3.20

1 week (194F)

l-

5%

I year
1 week (180F)

1hickne!

3%

Unchanged
Slightly

bxreaLe

Peroxtde.

-0.95
0.00

Percent
Wei$t

Peroxide,

Hydrogen

-2.18
-4.03

3 days

*Hydrogen

attacked

(194F)

Syrup

& Almond

Horseradish

4 months
1 week

Transformer

0.06

EXpoad

(Cont)

Chocolate

Honey

Time

Tested

Items

Hersheys

Essenttal

Sour

Material

Acetate

Butter
Powder

Unchanged

3 days (100F)

2.65

2.00

Unchanged

1 week

1.38

1.17

Stained light green

showed surface
Pine Bath Oil
Port-a-Fount

Liquid

Dentifrice

2 days

Softened

and slightly

swollen

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

Effect of Various

Matwial
liousahold
Powder

Rad

lime

Tested

ltamr

EXpOpd

Percent
Wei&

Increase

CHEMICAL

Chemicals and Reagents on TENITE@

Obsewed Condition
of Planic

hicknes

(Cont.)

Miscellaneous
Caultmg
1 week

Unchanged

Spiro

1 week

Unchanged

Cherry

&lest

1 week

Unchanged

Chlordane,

Richard

1day

Hudnut

Cteme

Waving

(16OFi

1 day (lOOoF

3.57

4 90

Swollen

2.15

Unchanged

Time
EXpOred

Observed Condition
of Plastic

hicknes

(Coot)

Compound

Amolin

Cleaner

Acetate

Material Tested

Deodorants

Household

(continued)

(average

of

I week

~l40F)

-2

68

-0 05

Unchanged
Unchanged

five brands)

and showed

exudation

Smash

Syrup

Concentrare

20%

CowCola

Syrup

Concentrate

I year

2 58

1.36

3 days

1 83

3 20

Unchanged

I year

0 32

132

Statned

59

0.73

Unchanged

2 months

I 59

2 96

Swollen,

2 months

2 82

I 94

Very

8 months

Creosote

-2

sllghfly

Lotion
2.4.0
Ronronol

Lighter

Servac

1year

Fluid

Detergent

-5.85

-1.32

Softened

and etched

Decomposed

1 year

Shoe Polish
Kllafl

0.00

0.15

3 daYs

Stained

Soap,

I dav

10%

Type.

DOT.

solld

DOT.

6% in Flit

Type.

Floor

Stokelyr

Cleaner

Orange

Tamp

Cleaner

Tide

Detergent,

Tomato

Juice

Weed Killer

5%

Weed Killer,

0.07

Softened

Wave Lotion

2.50

1.36

Unchanged

Flit Insect Spray with &DOT

Unchanged

Inks

2 months

0.08

1.24

Shghtly

I week

2.06

1.52

Unchanged

3 daYs

4.72

0 86

Unchanged

Toni

Wave Lotion

Neutraluer

3.24

1.28

Unchanged

1.08

2 16

3 days

Vicks

Oecongestant

2 days

Vitalis

Hair Tonic

3days

Watkins
Welchs

Fly Spray
Frozen

(122F )

37.30
-1.34

2 months

Grape Juice

warped

Badly

Caners

Cream

stamed

No

011

Unchanged

Parker

,111.

Unchanged

039

Unchanged

2 months

2.80

2 months

1 48

1 week

0 38

VerY slightly

softened

1.41

Very

softened

0 39

Unchanged

-045

slightly

4 days

069

0 00

Shghtly

stamed

2 months

2 06

5 12

Stamed

blue

2 weeks

204

0 62

Unchanged

2 months

-4 49

Stamed

black

3 52

StaIned

amber

1week

Black
Ori.Line

1.02

Unchanged

Sanfords

I week

2.25

1.03

Unchanged

Sheaffars

1.30

Unchanged

Larkmg
Black

2 days 1tOOF)

Swollen,

3 days

Very

3 days

Stained

1 week
Lager Beer

5.28

lweek

Balsam

3.93
0.00

3 weeks

-0.01
26.60

22.50

2.76

0.81

Gas Antileak

Compound.

2months(100F)

Gas Antileak

Compound,

2 months

Spmts

Unchanged

Mortemoth

Swollen

Naphfha.

Swollen,

softened,

and stained

Insecticide.

Shghtly

stamed

stamed

slightly

sramed

red

is~encrolly

unkvisfacrory

for YIC tn conr~cr

with

TENITE

Acrurc

under

rhr condtrlonr

Yellow

of rhrl

StaIned

112

1 Year

-6

00

-2.23

Unchanged

IO days

-6

-1.4

Unchanged

1 69

2 months

0.68

Unchanged

82

Unchanged

I month

-3

24

-0

1 week

-1

52

-0.26

Pamts

Kemtone

rhor marenal

liquid

Industrial

Ou Poor
000F)

1month

Skrip

Em&Ion

Mmeral

vapor

*Indarer

Stencil

Superchrome

1.74

liquid
Carboreal

(for

Edge

Sanfords

1week
3 days

Blood

Carboseal

Bail Porn

and Oenison

E-Z Brite

Latex

Canada

10856

Oiagraph-Bradleys
swollen

Mioallaneour
Budweiser

0 00

0.38

Marking

Grape Juice

Wildroot

0 17

1 week

felt tip pens)

Considerably

0.04

addeN

Cado

Concentrate
Welchs

I week

4 tablespoons!gal

Cushman
Toni

(Ester

1.0

1 day
(Campbells)

Spray

and warped

softened

4 13

(19OFl

1 week
I week

Juice

Insect

softened,

slightly

12.7% free acid)

End-O-Weed
*Stanlay

14% free acid)

4 tablespoons/gal

End-O.Weed

Stamed

Shinola

(Amme

2.4-O.

Oulux

Outside

Enamel

Unchanged

1011 base)

I day

Unchanged

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Material
Miscellaneous

Time
Enpored

Tested

Percmt
Wei&

increase

Observed Condition
of Plastic

Thickness

Material
Miscellaneous

(Cont.)

Weed-B-Gon

Pamts
Luminall
L402

One-Coat

Interior.

1 week

331

1.61

Unchanged

Peach (water

Weedone

Semt-Gloss

Products

(All

Brand)

KODAK
Acid

White

1 week

-1.20

-0.42

Unchanged-

1 week

4 46

2.56

Unchanged

1 week

3.43

2 53

Shghtly

softened

1 week

4.58

2.89

Stained

light amber

Developer

Polycarbonate

Observed Condition
of Plastic

hicknw

I month

3.32

160

Unchanged

(Ester

Tvpe.

2 months

2 88

1.66

very

slightly

swollen

Weed Killer,

2 months

2.56

1.62

very

slightly

swollen

5 tablespoons/gal

Oweloper

OK.50

Increase

Weight

(Cont.)
Weed Killer,

Weed Killer

Weedone

Fixer

*o-72

EXpored

9% free acid)

(011 base)
Photographic

Percent

Time

Tested

2% tablespoons/gal

emulsion1
Pittsburg

Acetate

Plastic

(Laxan)

Unchanged

3 days (lOOoF,

(Polycarbonate

softened,

80% R.H.)

cracked

when

flexed)
2 days (120F)

Ouinine
Refrigerants.
Freon

Unchanged

11

2 hours

Freon

12. gas

1 month

Freon

12. liquid

1 month

22, gas

1 month

2.68

0.74

1 month

0.38

0.12

Unchanged

1 month

0.55

0.56

Unchanged

01

Unchanged

Showed
0.32
-3.37

0.16
-1.11

exudation

Unchanged
Unchanged

Freon
Freon
Freon
Freon
Solvex
Stoddard
Super

2 lb/l0

Scale

Solvent
Fly Spray

Paint

and Varnish

Taxite

Remover
U.S.P.

61% (12%solution)

Solvex

-1.30

3 days

-0.05

1 week

of Green Soap.

Toxaphine,

1 month

-1

gal

Market

Tincture

Ultra

114, gas
114. liquid

Mamtenance

Retarder.

Unchanged
Dissolved

22, liquid

Oescaling

Agent.

0.12

0 00

Unchanged

0 00

Unchanged
Swollen,

partially

7.98

Swollen,

slightly

1.94

2 50

Unchanged

3 00

1.45

Unchanged

1 day
2 months
3 days
1 month

(100F)

-3.59

3 lb/IO gal
Varsol No. 2 Solvent

1 week

water

I year

3.09

1.96

Unchanged

1 month

1.90

1.74

Unchanged

Weed-B.Gon
Type,

Weed Killer
13 8% free acid)

(Ester

-1.60

-0.28

Unchanged

dissolved
softened

i Tl ?NITE,
Most tests were conducted

by

placing dry, injection-molded

Most figures given are the

result of a single test, and the measured gains in weight and thickness
without
tions

rounding.

were

aqueous.

Unless

stated

otherwise,

tests

were

of TENITE Acetate

specimens

in contact with the other material for the period of time shown.

conducted

are reported exasrly,

at 73F

(23C)

and

solu-

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Time
Exposed

Material Tested

Percent
Werght

Increase

Observed Condrtion
of Plastic

Thickness

Material

CHEMICALS

Alcohols,

Acids

2.07
2.38

Slightly

softened

Slightly

softened

13.60

0 58

Softened

2 days

1.25

0.00

Unchanged

8 days (100F)

2.00

0.13

Slightly

stained

1.64

0.78

Slightly

softened

1.38

0.62

5%

1 year

Acetic,

10%

2 months

*Acetic,

30%

2 months

Acetrc,

Boric,

5%

Chromic,

6%

Citric,

10%

4 months

Citric,

10%

1 year

69%

4 months

*Citric,

3.59

5.22

fl4OFl
(140F)

and wollen

Monohydric

2 days

6 45

sec_Butyl

2 days

7 20

ltert.Butyl

2 daqs

3.62

Ethyl

(denatured)

1.20

Unchanged

4 69

3.57

Unchanged

Ethyl.

50%

10%

1 year

lHydrofluoric,

10%

1 month

Hydrofluoric,

48%

Hydrochloric,

Lactic,
*Nitric,

Unchanged
Surface

slightly

attacked

10.30

5.47

Slightly

swollen

and softened

2 days

10%

1.60

0.50

8 months

Oleic

1 year

2.31

1.53

5%

Alcohols,

Unchanged

11.60

Softened

2 12

23.40

25 10

Very

slightly

Softened,

softened

tacky

1 year

2.02

1.24

Shghtly

softened

2 days

1500

4.40

Slrghtly

softened

Di. and Tri-hydric


Hexanedrol.1.3

Ethylene

Unchanged

Glycerin

Phosphoric,

30%

2 months

1.26

0.80

Unchanged

Propylene

50%

2 months

1.58

0.75

Unchanged

Triethylene

75%

2 months

8 24

6.10

1 year

4.24

2.10

Unchanged

1 year

0.03

0.4 1

Unchanged

2 months

Glycol

2-Ethyl
Decomposed

Partially

Swollen
2 02

Orssoived

Drethylene

Phosphoric,
*Phosphoric,

13.40

lTetrahydrofurfuryl

0.53

Drssolved

50%

1 weak

Drssolved

n_Propyl

0.86

softened

Softened

Methyl
Methyl.

20 days

Shghtly

24.70

2 days

4.45

3.30

23.00

*Isopropyl

2 months

Swollen
SWollen

2 davs

Surface

2 months

7.20
1070

Drssolved

2 days

attacked

Observed Condaion
of Plastic

Thickness

Oracetone

Isoamyl

10%

Increase

Weight

(Cont.)

Unchanged

28%

Percent

n-Butyl

1 week

Fluosilicic,
3%

Time
Exposed

Tested

t.Ethylhexyl

Fluosilicic,

Formic,

Butyrate

2 days (lOOoF)

Glycol
Glycol
Glycoi

Softened
Unchanged

2 days

0.44

0 00

Unchanged

2 months

8.61

6 70

Softened

2 months

21.87

decomposed
Bases

Pvrogallic,

1 week

4%

1.08

Stained

yellow

0.97

Slightly

1 year

1.50

0.74

Slightly

discolored

1 year

0.91

0.31

Slightly

softened,

1 year

Sulfuric,

10%

*Sulfuric,

20%

Hydroxide,

Calcrum

1.60

3%

Ammonium

Unchanged

1 wek

Stearic
Sulfuric,

2 56

drscolored

saturated
Sodrum
surface

*Sodium

attacked

*Sulfuric,

3D%
94%

Tannic.

1 year

Trichloroacetrc,

-0.29

Surface

4 months

(lOOoF)

Unchanged

n-Buy1
sec.Butyl

1%

1month

3.28

0.50

Unchanged

5%

1 month

9.25

3.07

Softened

Dioctyl
Ethyl

tert-Amy1

2 days

14.00

Vndicarcr
ICII.

rhot material

isgencr4lly

unsatir/ncrory for use in conr4cr

wth

3 00
11.30

TENITE

Unchanged

Hydroxide,

1%

1 year

0.95

0.61

Unchanged

10%

8 months

3.19

2.20

Brittle

17 days

1.13

0.00

Unchanged

Ammonium
5%

Acetate

Dissolved

Acetate

Dr-2.Ethylhexyl

Alcohols, Monohydric
3.06

Softened

EStWS

1.20

2 days

0.65

attacked

2 75

n-Amy1

1 72

Hydroxide.

Trimethylbenzyl

Disintegrated

10%

Trichloroacetic,

-0.42

12.93

1 week

solutron

Hydroxrde.
Sulfuric,

10%

Hydroxide.

Phthalate
Acetate

Dissolved
Adipate

0.91

1 year
1 month

(122F)

Small

0 32

Unchanged

gain
Dissolved

Unchanged
Softened,

Burpore

tacky

under the condrrionr

o/this

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Time
EvJ=-t

Mearia Tened

Percent
Wei&t

Increase
Thickness

Observed Condition
of Plastic

Material
Hydrocarbons

Esters (Cont.)

Butyrate
Tnme
Exposed

Tested

Percent
Weight

Increase
Thickness

(Cont.)

Ethyl

Lactate

Drssolved

Propane,

ga:

2 months

0 34

0.64

Ethyl

Propionate

Drssolved

Propane,

liquid

2 months

1.42

4 55

Ethylene

Glvcol

Monoethyl

Acetate

lEKTASOLVEQ

Acetate;

Cellosolve

Ethylene

Glycol

Ether
EE

(EKTASOLVE

Acetate;

Methyl

Ether

Dissolved

lIsobutyl

Acetate

Dissolved

54.90

Softened

Xylene

1week

41.52

33.17

Softened

2 days

14 80

Halogenated

Tetrachlorrde

Acetate
Acetate
Acetate

Oiethyl

Ether

shghtly softened

Drssolved

lChloroform

Drssolved
3 days

Dissolved

lp-Dichlorobenzene

3 days

Dissolved

Ethylene

Dissolved

Methylene

Chloride

Propylene

Chlorrde

Softened
11.14

11.70

Chloride

end swollen

Swollen
Drssolved
Drssolved
Dissolved

3 days

Softened,

swollen,

and tacky

Dissolved

Ether

Di-Isopropyl

Surface

Chlorobromomethane

s-Tetrabromoethane

Orchloro

6 80

Drssolved

o-Drchlorobervene

Ethrfl
Diethyl

39.30

Chlorobenzene

Cellosolve

Acetate

n-Propyl

2 days

Carbon

Acetate)

Methyl

Unchanged

Toluene

Hydrocarbons,

Drssolved

EM

l,lsoamyl

Isopropvl

Unchanged

Acetate)

Monomethyl

Acetate

Dissolved

Observed Condition
of Plastic

Ether

2 days

46 00

2 days

0.78

50.00

1.06

Considerably

swollen

Unchanged

Tetrachloroethane

Dissolved

Tetrachloroethylene

12 days

Badly swollen

Trichloroethylene

1day

Badly swollen

Etbn-Alcohols
Ethylene

Glycol

Monoethyl

(EKTASOLVE
Ethylene

Ether

Ketones

Dissolved

*Acetone

EE; Cellosolve)

Glycol

Monomethyl

(EKTASOLVE

Ether

Hydrocarbons
Benzene

1year

Showed

in impact
5%

aromatic

content

23 days

Heptane

1year

Hexane

1 week

Showed

1.60

2.40

*Methyl

Ethyl

Methyl

n-Butyl

*Methyl

lsobutyl

Dissolved

Ketone

Dissolved

Ketone

Dissolved

Ketone

Dissolved
Dissolved

slight decrease in

tensile strength
Gas, Natural,

Ketone

Phorone

Orssolved
aromatic-free

Drssolved

Di-Isopropyl

EM; Methyl

Cello&e)

Gas, Natural,

Dissolved

Cyclohexanone

Dissolved

and increase

strength

slight decrease in

Salts
Aluminum
33% water

Acetate,

tensile strength and rncrease

Aluminum

Chloride,

in impact

Aluminum

Chloride,

Unchanged
Unchanged

strength

saturated
Alvninum
Ammonium
saturated

Basic,

2 months

10%

2 months
2 months
3 months

1.68

1.07

1 month

2.34

1.83

0.56

Unchanged

1.48

0.71

Unchanged

0.10

0.00

Unchanged

slurry

snlutron
Sulfate.

solid

Bifluorrde.

Unchanged
Slrghtly

bleached

solutron

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Material

Tested

salts Clnt.)

Increase
Material

Weight

Time

Tested

Exposed

1rh,cknes

Percent
Weight

Increase

Obwved

Chlarlde.

1 month

2.11

0 78

Unchanged

Potaswm

solwon

Cyanide.

saturated

2 months

046

0.04

Slightly

discolored

Nitrate,

solid

1 week

0 16

0.23

Unchanged

Potassium

Ferrlcyanlde,

Ammanurn

NItrate.

10%

1week

1 65

0 75

Unchanged

Potassium

Sulfate.

solid

1 year

0 12

0 57

Unchanged

Ammomum

Sulfate.

solid

1 year

011

0 58

Unchanged.

Potaswm

Sulfate,

10%

1 year

1 36

0 37

Unchanged

Ammonium

Sulfate.

10%

1 year

1 30

0.52

Unchanged

Sliver

2 days

1.46

0 00

Unchanged

3 days (lOOoF)

1 30

1 week

1 64

0.44

Unchanged

2 days

1 68

0 53

Unchanged

Nitrate.

Chloride,

2.5%

1 year

1 49

0 88

Unchanged

Sadlum

Acetare,

Calcwm

Chloride,

40%

2 months

0 44

0 00

Unchanged

S&urn

Aluminum

Calcium

Hypochlonte.

6%

1 year

6 00

Sodium

Bicarbonate.

Calcwm

Hypochlorlte,

30%

13 days

0 77

0 00

Unchanged

Sodturn

Bwlfate.

Calcwm

Phosphate,

1 year

1.73

0 54

Unchanged

Monobaw,

75

Softened

and cracked

Phosphate,

Dlbaslc,

Calcium

Phosphate,

lrlbaslc,

Calcwm

Sulfate

solld
solid

(Gypsum).

soled

58

0 58

Unchanged

Sodium

Blsulflte,

0 60

Unchanged

Sodium

Borate,

I year

-0

10

0.55

Unchanged

Sodium

Carbonate.

1 67

0 64

Unchanged

Copper

Sulfate.

saturated

solution

2 months

1 66

0 93

Unchanged

1 week

Sulfate,

solid

1 week

1 50
(lOOoF,

80% R H
Ferric

Chloride.

5%

Few

Chloride,

Ferric

Chloride.

Fernc

Chloride,

saturated

1.25

Unchanged

20%
2 5%

1 week

2.14

0 80

Unchanged

2 days

1 53

0.52

solid

Unchanged

1 week

025

Sodium

Carbonate.

2 5%

1 year

1 28

Sodium

Carbonate.

6%

3 days (lOOoF)

118

Unchanged

Sodturn

Carbonate.

10%

1 year

Sodium

Chlorlda,

2 54L

1 year

Sodium

Chloride,

10%

I year

2 months

1 73

0 96

Unchanged

Sodium

Chloride.

saturated

solution

2 months

1 34

043

Unchanged

Sodurn

Chloride.

saturated

soiutlon

2 months

0 30

Unchanged

Sodium

Chromate,

04

Unchanged

Bromide.

50%

Carbonate,
Aluminum

2 5%
Sulfate

-0

1 week

-0

2 days
4 months

0 75

0 88

1 week

l1OOF

68

3 90

1100F.

Unchanged
0 93

Unchanged
Unchanged

Unchanged

1 month

H.)

80% R H.)

2 months

Ltrhlum

(alum).

3 days (lOOoF)

2G?h

solution

(100F.

Unchanged

Unchanged

40%

solid

Unchanged

010

2 00

Bromide,

Potasswm

1 week

2 months

Llthwm
Magnesum

2 5%

1%

63

2 months

Ammomum

Bulfate,

-0

10%

Ferric

Sodium
-0

(CuprIcI,

solid

solId

1 year

Sulfate

solld

Sulfate,

1 year

copper

Chloride,

3%

4 days

80XR

salld

Calwm

10%

2 5%

Calctum

-3

-0

Unchanged

saturated

Unchanged
Unchailged
1 33
(140F)

1 week

0 54

Unchanged

0 79

0 31

Unchanged

0 89

0 89

Unchanged

0 57

0 20

Unchanged

0 28

Unchanged

solution

04

0.00

Unchanged

Sodium

Cyanide,

10%

155

1 00

Unchanged

Sodwm

Cyantde.

saturated

1.94

084

Unchanged

Sodium

Ferrocyanlde,

Sodium

Fluoride.

21%

1 02

2 months
solution

solId

4%

2 months

-0

18

-0

44

Unchanged

1 week

0 84

Unchanged

1 month

245

Unchanged

Potawm

Brcmlde.

3%

3 days (100F)

1.30

Unchanged

Sodium

Hypochlorlte,

13 days

111

09

Unchanged

Potasswm

Chloride,

solId

1 year

0 09

0.47

Unchanged

Sodium

NItrate,

solld

2 months

0 08

0 12

Unchanged

Potassium

Chloride,

10%

1 year

1 66

0 44

Unchanged

Sodium

Nltrate,

10%

1 year

1 23

0 42

Unchanged

3otassium

Chrome

3 days (100F)

1 33

Unchanged

Sodiurr

N~rrafe,

saturated

2 months

0 92

0 39

Unchanged

3otasswm

Cyanide.

2 months

1 40

Sodium

S~hcate. solid

2 months

0 30

0 20

Unchanged

Alum.
10%

10%

(brown)

solution

Ammonwm

Cuprous

Condttion

of Plastic

Thickness

salts nMlt.)

Ammonium
saturated

Percent

Tume
Exposed

Butyrate

0 32

Shghtly

discolored

(brown)

30%

soiut1on

-2

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@ Butvate

-r

Time

fasted

Material

Expnred

Percent I crease
Weight

thickne!

2 months

1.16

0.13

l-

Observed Condition
of Plastic

Material

selts (Cont.)
Sodium

Miscellaneous

Silicate,

saturated

Sodium

Sulfite,

10%

1week

2.08

Sodium

Thiosulfate,

20%

13 daYs

1.10

Thiosulfate,

24%

3days

Silicate

1month

Ammonium

I7daYs

1.13

0.06

Sodium
Tetra

(2Ethylbutyl)

solution

flOOFj
f122OF)

0.88
0.00

1.22
-0.74

Unchanged

Kant.)

Unchanged

Hydrogen

*Methyl

Unchanged

Percent
Weight

Increase

2 months

5.87

2.34

Unchanged

1 week

2.39

0.99

Slightly

solution
20 g per gallon

Methacrylete

Benzyl

Chloride,

Unchanged

stained yellow

Dissolved

Monomer

Nitrobenzene
Trimethyl

Observed Condition
of Plastic

Thickness

end Gases

Sulfide.

Hydroquinone.

Unchanged

-0 1

Chemicals

saturated

Unchanged

Time
Exposed

Tested

Dissolved

Ozone.

0.05-0.15

Ozone,

0.7 ppm

ppm

45 daYs (outdoors)

Unchanged

45 daYs (120F)

Yellowed

I week

Decomposed

5%

Zinc Chloride

(hYdroussalt)

I week

0.53

0.00

Unchanged

Zinc Chloride,

saturated

1 week

1.37

0.78

Slightly

Zinc Oxide,

solution

1week

sohd

*Phenol

etched

StYrene

Unchanged

Sulfur,

Chemicals and Gases

Mii&neous
Ammoniated

Mercury

I week (60C)

Oissolved

Benzeldehyde

Dissolved

I,3,

Butedrene-

liquid

S months

gas

1month

26.40

2.72

2.34

Unchanged
Softened

Oisulfide

1 week

25.62

1.56

*Carbon

Oisulfrde,

? days

1740

11.75

Swollen

end softened

dry

Chlorine,

moist

*Chlorine,

saturated

solution

I week
I week
I week

Dioxrde,

dry

2 months

19.40

8.60

Sulfur

Dioxide.

moist

2 months

31.90

10.20

Swollen,

slightly warped

8.60

2.22

7.77

0.14

*Sulfur

Dioxide.

saturated

Sulfur

Dioxide

in Hydrocarbons

Sulfur

Dioxide

and Hydrocarbon

Trtanium

Warped

swollen

and

solution

2 months

23.20

I6 10

Swollen

and warped

Drssolved
2 months

19.20

11.50

Swollen

Tetrachloride

Trinitrotoluene

(TNT).

water

COMMERCIAL

AN0

NATURAL

slurry

3 days

Very

4 weeks

Stained

brittle

3 weeks (122F)

Unchanged

Crazed and brittle


Crazed and brrttle
Consrderably

softened

and

PRODUCTS
Aeronautical

swollen

and Automotive

Dane Head Radiator

l1,4-Oioxane

Consrderably

Vapor

and swollen

atmosphere

Chlorine,

Unchanged

*Sulfur

warped

1925

*Carbon

saturated

I week

solid

Unchanged

*Aniline
Butedrene-1.3,

Dissolved

Monomer

Sealer

Hems

Drssolved

Ethylene

Oxide.

gas

IO minutes

lEthYlene

Oxide,

gas

I daY

Formaldehyde,

(105FI

4%

IO min per day

35%

! months

Unchanged
20.85

25.60

0.24

Swollen

and softened

Unchanged

*Amoco

Regular

Amoco

Premrum

Aviation

for 5 days
Formaldehyde,

Gasolines,

12.96

6.74

Swollen

and softened

100 Octane

(Standard
Avtation

Furfural

Dissolved

Hydrogen

Peroxide,

3%

I year

1.72

1.07

Unchanged

Hydrogen

Peroxide,

5%

1.40

1.30

Unchanged

Hydrogen

Sulfide,

dn/

2.26

0.81

Unchanged

Hydrogen

Sulfide,

moist

! days
! months
! months

3 04

1.65

Unchanged

1Year
1Year

5.5

Swollen

9.5

Swollen

and stemed Yellow

1 Year

3.03

3.20

Slightly

discolored

1 Year

5.21

6.06

Slightly

stained

9.8

Swollen

and stained pink

Oil Company)

115145

(SoconY

7.7
18.4

Vacuum

Octane
Oil

Company)
Exxon

Extra

1 Year

13.9

Regular

1Year

5.77

Swollen

and stained pink

*Shell

High.Test

I Year

11.9

7.5

Swollen

and stained pink

*Shell

Regular

I Year

9.9

8 1

Swollen

end stained Yellow

Exxon

5 19

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@ Bun/rate


Material
Aeronautical

Percent

Time
EXPOrag

Tatted

Weight

Increase
Thickness

Observed Condition
of Plastic

Itams

and Automotive

Matenal
Aeronautical

and Automotive

Weight

Increase
Thickness

Observed Condition
of Plastic

Items

(Cont.)

(Cont.)
Texaco

Fire Chief

1 year

9.7

Texaco

Sky Chief

I year

15.0

7.0

Swollen

and stained yellow

Purol

12 1

Swollen

and stained pink

Shell DIala 011 AX

HD, SAE

IO

STP
Hydraulic

Super 3 Brake FluId

Pant No. 7 Heavy-Duty

1 week
Screwdriver
allowed

Brake Fluid (VV&860)

Swollen
handle dipped

in iluid and

and softened

requirement

of Federal

Head Brake Fluid

lSkydrol

Hydraulic

Skydrol

500 Hydraulic

Wagner

21-6

Jet Propulsion

Swollen

Fluid

Fuel IA

0.00

-0.16

0.09

4waeks

(122F)

30 minutes
011

0.00

Unchanged
Unchanged

0.17

(15OF)

5 weeks (140F)

Nonanomotive

1 week

Fluid

Low

10

Unchanged
-1.09

-0.09

Unchanged

Specificatmn

Fluid

Brake

-0
-0.08

Oil, MIL-L.6448

Temperature
Zerolene

GGG-S-12ld.
*Indian

No. 50, 1692

Winsorlube

Dissolved

to stand 3 days passed torsional

6 months
2 months
2 weeks

Texaco

Fluids:

lOelco
Do

Percent

Time
ExP=d

Tested

1 weak

and stained

Essential

Greases and Oils

011s.
Dissolved

Dissolved

Bitter

Dissolved

Citronella

2 days

6.10

4.20

Slightly

softened

Eucalyptus

2 days

0.45

1.01

Slightly

softened

Lavender

2 days

0.69

0.51

Unchanged

Lemon

2 days

041

0 00

Unchanged

2 days

5.40

4.50

Slightly

Swollen

and softened

8 months

3.42

3.01

Unchanged

6 months

3.87

3.22

Unchanged

Almonds

(Shell Oil Company)


Jet Propulsion
(Eao

Fuel 3

Standard

Jet Propulsion
(Humble

1.41

1.32

Unchanged

Fuel 4

Standard

Jet Propulsion

6 months

3.39

3.22

Unchanged

8 months

0.29

0.32

Unchanged

softened

Dissolved

Spearmint
Sweet

Oil Company)

Jet Propulsion
(Eao

1 year

Fuel 3

lPalmarosa
*Pennyroyal

Oil Company)

Dissolved

Orange

Terpineol

2 days

0 26

0.88

Unchanged

2 days

0.56

0.00

Unchanged

1 year

99.20

62.62

Oil Company)

Fuel 5

Thyme

Dissolved

Turpentine

(Shell Oil Company)

Softened,

swollen,

surface

attacked
Kerosene

1 week

0.41

1.32

Unchanged

Oils:

Vanilla

(Imitation)

2 days

11.80

9 70

Wmtergreen
Aeroshell

No. 2

2 months

0.27

0.00

Unchanged

Aeroshell

No. 12

1 year

0.60

0.34

Unchanged

Aeroshell

Turbine

3 days (12OF)

4 weeks

0.04

Bearing

Oil No. 300

Guard Oil

Unchanged

Fuel 011 iL1

1 week

Fuel 011 f2

1week

Unchanged

Oil

1 day

Unchanged

011

Heavy

Machine

Light Machme
DuoDrive

Oil

4 waeks (122F)

Houghton

Safe 1120

1 week

Lubricating
MIL-L-7808

Unchanged
<1

<1

handle dipped

in oil and

Oil
Oil

Screwdriver
allowed

to stand 3 days passed torsmnal

requirement
GGG-S-121d.

of Federal

Specification

Unchanged
Dissolved
Unchanged

1 day

Unchanged

Linseed

011

I month

Unchanged

Mmeral

Oil

4 months

Unchanged
Neatsfoot
NO.OX-IO

011

011. Dow-Corning

-0.16

#200

Unchanged
Unchanged
Slightly

3 days (14OF)

Grease

Pme Bath 011


Sihcone

-0.40

6 weeks

stamed

1 week

3.87

3 10

Unchanged

3 months

0 77

0.16

Unchanged

(continued)

TABLE

1.6:

CELLULOSE

BUTYRATES,

ACETATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Time
Exposed
Nonsutomotive

l-

Percent
Weight

Increase

-r

Observed Cnndltion
of Plastic

hicknes

Tame
Exposed

Greases and Oils

Hotwhold

(Cont.)
Sdicone

IO days (16OF)

Grease No. 44 (Dow)

StaIned

yellow,

properties

unaffected
Sour Crude

6 months

Oil

6 40

2.24

1 week

Soya 011
Sperm

Oil

1 week

Sperm

Oil

1 week

(194F)

Detergent.

5%

Dwin

Household

Insect

Dwin

Stainless

Unchanged

Glim

Detergent

Unchanged

Glim

Detergent,

-0.78

0 00

Unchanged

-0.48

0 00

Unchanged

Handy

Andy

Killer

Fly Spray
10%
Detergent

Chocolate

Syrup

131

0.50

Unchanged

018

00

Unchanged

1 week

0.51

0 38

Unchanged

2 monrhs

2 54

1.31

Slightly

2 months

147

0 60

Unchanged

1.97

1.50

Slightly

1week

1 30

048

Unchanged

1 week

1 20

1 50

Unchanged

1 46

0.80

StaIned

1 50

1.05

Unchanged

2 months

3 48

4.07

Slightly

2 months

1 67

0 82

Unchanged

Unchanged

Hinds

I week

(77F)

-0.90
-0.92

0.22

Oil, Pyranol

0.00

Unchanged

HorseradIsh

3 days

Transformer

Oil, Pyranol

1 week

(194F)

-0.74

0 00

Unchanged

Iced Coffee

1 week

Oil
Oil

1 week

0 19

3.56

Unchanged

2 days

0.12

0 00

Unchanged

Honey

Air-Wick

Items
Odor Neutralizer

12.55

Soap Flakes

1240

Swollen

and shghtly

softened

Joy

Detergent

Joy

Detergent,

6-12
10%

Armour

(694)

Flotilla

4 days

Unchanged

Mioma

Soap

4 days

Unchanged

Armour

No. 99 Soap

4 days

Unchanged

Lard

Armour

Pumex

4 days

Unchanged

Lava Soap, saturated

Atabrine
Avon

Cream

Bon Ami.

Cake

saturated

Borax,

2 5%

Breath

OPine

Brilliantine
Bubble

solution

DIsinfectant

Hair

Bath

Oressmg

Carbohc

Tomato
Acid,

Juice

Catsup
Clorox

Solution

Coffee

Grounds

Cologne

Lipstlck

Dart

Furniture

Dole Frozen
Concentrate

3 days
solution

stained

Unchanged

2 days

1 36

0 00

Unchanged

Lemonade

1 week

1 63

1.01

Unchanged

Lemon

Juice

2 days

240

021

Unchanged

Lighter

FluIds

0 78

StaIned

2 days

1 42

049

Unchanged

2 days

1 53

0 52

Unchanged

AMR

2 months

3 03

2 69

Unchanged

Badly

Energene

2 months

144

3 18

Unchanged

Exxon

2 months

1 83

1.28

Unchanged

Kwik-Lite

2 days

044

00

Unchanged

1 week
3 days
1.67

1 week

1 77

swollen

0 00

Unchanged

0 54

Unchanged

Ronsonol

1 year

0 25

0 95

Unchanged

Unchanged

ZlPPO

2 months

2 17

2 05

Unchanged
Unchanged

1.36

Unchanged
Decomposed

I week

Slightly

j weks
3davs

Unchanged

discolored

Polish

(Kress)

I days

Pineapple

Juice

week

unror~sf~crory for USCin cmmct

Very
0 54

wrrh TENITE

slightly

Disinfectant.

Malathion
diluted

Stamed

1.45

Cleanser
Soap, saturated

per gallon

Unchanged

12 days

Lighthouse
Lighthouse
Lysol

Dissolved

lbtdrcarer rhm morerlol rsgrnrrally


*cl,.

Slightly

012

Sticks

Cotv

3 days

Lipstick

warped

1 day (100F)

Unchanged

I week

5%

Unchanged

0.10

3 days

Campbells

Esther

IlOOF)

3 days (lOOoF)

1 week

Oil

Butter

Lady

Zdays

yellowed

Unchanged

1 week

Repellent

Armour

Soap

Cream

Iced Tea
insect

Household

and Almond

warped

1 year

Oil,

5in-1

Observed Candlt,on
of Planic

Thickness

I week

Transformer
Wesson

Increase

2 months

Transformer

1 week (180F)

Percent
Weight

Items (Cont.1

Dreft

Hersheys
G. E No. 10-C

Butyrate

Marie
stalned

Unchanged

Buryrrrre under rhr condirmnr

of thtr

solution

5 tablespoonsful

2 days

1 38

0 00

2 days

1 28

0 00

Unchanged

2 months

6.97

4.37

Slightly

I week

8.73

4 53

Softened,

softened

of water
Insecticide.

50% spray

pitted,

to 0 5%

Earle Talcum

Powder

3 days

2 93

2 36

swollen,
cloudy

surface
when wet

Unchanged

Mayonnaise

3 days

Unchanged

Milk

3 days

Unchanged

(continued)

TABLE

1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


TlWX
Exposed

Material Tested
Household
Minute

Items

Maid

-I-

Observed Condition
of Plastic

hickne

GrapefruIt

Tmcture

Juice

Lemonade
Juice

Detergent

146

0.64

Unchanged

1 week

1.34

0 62

Unchanged

Toni

Wave Lotlon

1 week

1.36

0.56

Unchanged

Toni

Wave Lollon

1week

1.41

0.46

Unchanged

OCedar

Furniture

Old Dutch

Polish

Cleanser,

saturated

3.42

2.74

Slightly
Stamed

(Potassium

Observed Condition
of Plastic

hickner

LISP

9 82

6 56

Shghtly

softened

3 days

173

0 62

Slightly

stained

3 days

2 23

0 78

Unchanged

0 00

2 monrhs

yellowad

Bromate

Swollen

2 days 1122F)

VapoRub

2 days

0 13

Va.Tro.Nol

2 days

0.14

2.30

0.50

0.12

0.45

Unchanged

Vicks

2 days

1 30

0 00

Unchanged

Vitalis

Salve
Solution

Hair Tome

Watkins

Frozen

Grape Jwe

0.00
33 90

3 days

Fly Spray

Welchs

yellow

Solut~anl

Vicks

11 days

Unchanged

Neutralizer

Decongestant

2 days

3 days

Percent Increase

Weight

(30% alcohol)

solution

Oleomargarine

-r

(Cont.)

1 week

1 year

Mustard

Items

of Green Soap,

Vicks
Mr. Clean

Tbme
Exposed

Materml Tested

Household

Concentrates

Jwce

Tangerine

Percent InneaSe
Wei*t

(Cont.)

Frozen

Orange

Butyrate

and stalned

Unchanged
Unchanged
Swollen

and softened

2 months

217

108

Unchanged

1 week

1 30

0.53

Unchanged

1 week

1 52

0 64

Unchanged

1 week

0.19

3 56

Unchanged

1.10

0.98

Concentrate
Peanut

Butter

Pebeco

Tooth

Penicillin

3 days
Powder

3 days (lOOOF)

(powder)

Unchanged
4.00

6.00

1 week (100F.

Welchs

Unchanged

Wesson

80% R H.)
*Perfume
Pme Bath

Oil

Grape Juice

Unchanged
Oil

Wildroot

2 days

34 80

29 10

1 week

3 87

3 10

Swollen

Wisk

Cream

Powder

Liquid

Denttfrlce

! days

16.70

Unchanged

3 days

Detergent

1 year

Swollen,

shghtly

crazed

and Plastics
3 days (lOOoF.

Polycarbonate

Deodorants

I week
I week
I week
I week

Amalin
cluest
Pride Wax

Unchanged

Polyurethane

3 days 1100F.

Foam

Unchanged
3 01

2 25

1 days (120F)

Unchanged

Vinyl

Plastlsol

(cured)

2 days (140F)

Softened

Shghtly

Vmyl

Plastic.

semwtgid

3 days (lOOoF.

Unchanged

softened

Polish

(Woolworth)

Richard

Hudnut

Cream

!vavlng

0.70

4 days
1 day (lOOoF)

Unchanged
Slightly

1.65

1 60

stained

Unchanged

Lotion

Servac

Cleanser,

Floor

Stokelys

0.22

0.22

Unchanged

solution

Detergent

Stanley

i days

Cleaner

Orange

Temp

Cleaner

Tide

Detergent,

Julce

Amway

L.0.C

Bitumastic

No

Detergent

1 year

104

Unchanged

Carboseal

1 week

1.8

0.06

Unchanged

liqwd

1 week

1.66

0.69

Unchanged

Carboseal

Unchanged

vapor

5%

Unchanged

Caulkmg

-0.24

dw

2 months

1.58

0 20

Unchanged

30 days il22OFi

Cone

50

32 6

3 days

24.9

Lager Beer
Balsam

(Average

Softened,

swollen

Unchanged

1 week

Budweiser
Canada

Miscellaneous

Blood

saturated

and distorted

Unchanged

1 day (16OF)

Cleaner

Radiant

Unchanged

80% R. H.)

80% R H

Ouinine

Sane-Genio

Unchanged

80% R H.)

Spiro

Rad Household

DIscolored

Unchanged
Polymers

Pan-a-Fount

Oil

1 week

2.71

0.77

3 weeks

0 85

0.34

Unchanged

Gas Am-leak

Compot

rnd.

:2 months

(100F)

26.90

23 20

Gas Anti-leak

Compo;

md,

:!

(1OOFl

9.56

8.80

Slightly

0 97

0 80

Unchanged

months

I week

Compound

Softened,

swollen,

and stalned

statned

of five brands)

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


PfXCWl
Exposed

Miscellaneous

3 33

2 42

Unchanged

5.45

Softened

3.60

Slightly

Miscellaneous
3 days

20%

1 year

Creosote
(Amine

Material

of Plastic

.hieknr

(Cont.)

Chlordane,
2.4-D

Observed Condition

Weight

Type).

11.65

4 months

Undiluted

5 02

four

per gallon

4 months

1.53

7.61

Very

Carters
swollerl

and soitened

sllght&

Weed Killer
(12.7%

Endowed

per gallon

Type).

4 months

19.50

8.19

as free acld)

Weed Killer.

spoons

(Ester

4 table-

Felt-TIP

Dyna-Flo

and dw

4 months

Pen Ink

Liquid

3.47

1.31

Slightly

softened

Cluick

Drying

Ink

Ink

(122F)

-0

Softened

159

Softened,

60.65

30 50

Softened.

swollen

I week

Unchanged
Slightly

swned
stained

1.56

Inc,

18 days

20

05

Black

3 days

Stained

Ink

SheaffersSkrip
StaIned

1.44

(Formulab.

Dri.Line

Marking

07

3 days (lOOoF)
3 days

Ink

1 month

4.09

2 40

1.11

0.31

Unchanged

ye!low
Latex

Unchanged

1year

Emulsion
250

Insecticide

48 hours

(lOOoF.

Unchanged
Surface

etched

80% R. H.)

Cherry
Smash

Coca-Cola

32 00

21.8

2 days (100F)

Syrups.

Cherry

38 40

IO days

Blue No. 353)

and swollen

Malaphos
Fountain

Condnion

of Plastic

1 week

3 days (100F)
Stencil

Superchrome

Sanfords
1 month

Phosphate,

Observed

Thickness

Pens)

Parker

Dissolved

(20% Disodium

Fertilizer,

swollen,

of water

Resin

Fertilizer

IncreaSe

colored

Hardener

Epoxy

Softened,

Ink

& Denison

Diagraph-Bradley

Undiluted

Epoxy

No 4,715

Cushman

swollen

of water
Endoweed

Percent
Weight

(Cont.)

(For

tablespoons

Time
Exposed

Tested

inks

(14% tree acid)


2.4-D.

Butyrate

Concentrate

Concentrate

Grape
Lemon

1 year

2.96

1.84

Unchanged

Mineral

1 year

2.08

1.04

Unchanged

Mortemoth

1 year

1.69

1.15

Stamed

I year
I year

1.61

0 00

Unchanged

3.34

1.14

Unchanged

shghtly

yellow

1 year

1.31

0.14

Insecticide.

Yarn

Size

3 days (100F)

(CPC 400)

Used as suggested

Remover

340

1.40

Unchanged

Do Pant

1 year

3.87

3.10

Unchanged

yellow

Pineapple

1 year

118

021

Unchanged

Root

1 year

5.02

1.15

Dwzolored

2 04

0 66

Unchanged

1.70

0.28

Unchanged

Dulux

(outside

enamel,

3 56
175

Unchanged

2 73

, 073

bymanufacturer

Softened

and swollen

Unchanged
Unchanged
Distorted.

surface

attacked

1 week

2 88

2 45

1 week

3.11

1 .B9

Unchanged

I week

0.75

0 62

Unchanged

Unchanged

1 day

Luminall,

one coat intenor


L-402

Pittsburgh

Unchanged

011 base)

Kemtone
and blistered

paint
1 year

1668

Dnhocryl

1 year

1year

21

26 45

1 month

Orange

Vanilla

2.0

1week

Paints

Unchanged

Strawberry

10 days

Industrial

Pepsi-Cola
Beer

liquid

Naphtha,

Pamt
Maple

Spirits

(water

Semi-Gloss

emulsion)
White,

011 base

Gas Odorizers,
Pentalarm

86 (Concentrate)

1 week

Badly

swollen

Penetrox

*Spotleak

1OOB (Concentrate)

1 week

Badly

swollen

Photographic

Spotleak

1009

1week

Badly

swollen

(Concentrate)

(All

A Lobwant
Kodak

Acid
Inks:
Cado
*Carters

4 days

5 09

5.37

StaIned

No. 10,856

Ball Point

10 days (140F)

1038

6.10

Stamed

No. 10.656

Ball Point

2 months

12.85

7 00

Stamed

4 weeks

(122F)

-0.9

-0

Unchanged

Products
Brand)

Fixer

1 week

2 I6

0 85

Unchanged

Developer

O-72

1 week

2 20

0.91

Unchanged

Developer

DK-50

1 week

2 33

0 80

Unchanged

Ink
*Carters

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

BUTYRATES,

PROPIONATES-EASTMAN

CHEMICAL

(continued)

Effect of Various Chemicals and Reagents on TENITE@


Material

Time
Exposed

Tested

Percent

lncreare

Obwved
Condttton
of Plasttc

Thxkness

Weight

Material

Mivxllaneour

(Cont.)

Miscellaneous

Photographic

Products-

Ultra

Ektachrome@

Processing

l/3

K!t
1 week

3.05

0 55

Hardener

1 week

1.56

0.28

Unchanged

Color

1 week

1.56

0 82

StaIned

1 week

1.56

0.28

Unchanged

Developer

Clearing

and Fixmg

Solution

Stamed

yellow
dark amber

Bleach

1 week

1 45

0.28

StaIned

Stabliizer

1 week

2.30

0.28

Unchanged

Dercallng

lb per gallon

Agent,

No. 2 Solvent

Water.

dlstllled

Weedone

1 month

0 88

1 month

22. gas

0 20

1875

1 month

9 50

4 28

Slightly

swollen

Unchanged

Freon 22, liquid


3 days

Weedone

(Ester

Weed Killer,

Type).

1.50

040

Unchanged

1 week

1.14

0 94

Unchanged

Unchanged

Type).

1.66

2 months

0 74

27.32

14.00

Unchanged
Softened,

swollen,

dlscalored,

and warped

5 tablespoons

2 months

1.98

0.55

Shghtly

6 58

Softened,

swollen

of water
Weed Killer,

Undlliited

1 month

(Ester

1343

(13.8% as

swollen.

dlscafored.

and warped

free acid)
Weed.B-Gon
Wine

S2 Flow
49.3

1 week

(9% free acldl

tablespoons

OiSSOlbFd

113

0 54

hght amber

Unchanged

1 20

1.70

1 year

Weed Killer.

Undiluted

1 month

of water

Varsof

Weed-B-Gon

Refrtgerants
Freon 12. gas
*Freon
12. ltquid

Fraon

(Cont.)

Solvex

per gallon

Freon

Observed Condnion
of Plastic

Tested

Urine

No. E2
First Developer

Butyrate

Weed Killer,
par gallon

112% Ethyl

1 month

2%

2 67

1.06

of water

Alcohol)

Softened,

swollert,

dtscolored.

and warped
2 months

7 BB

Unchanged

245

H3 Flow
Freon

114. gas
114. I,qutd

Freon
Showersan
Solvex

Disinfectant

Maintenance

115 lb per gallon


Steel Picklmg

0.5

02

I month

0.84

0 00

Unchanged

1 month

7.76

2 37

Unchanged

12 days
Scale Retarder,

1 month

1 58

1 year

1 60

Bath

Steel Plckhng

Bath

(8% Sulfuric

Acid

14% Ferrous

Sulfate)

Unchanged

062

Unchanged

1 year (140F)

1 52

1 year

1.46

0 58

Unchanged

1 .OB

Slightly

0 38

Unchanged

softened

and

specimens of TENITE Butyrate


Most figures given are the

result of a single test, and the measured gains in weight and thickness are reported exactly,
rounding.

Unless stated otherwise,

tests were conducted

tions were aqueous, i.e., Acid, Acetic, 5% indicates


tested at 73OF. Unless other characteristics
under Observed Condition

at 73F (23C) and solu-

a 5% solution

are specifically

of acetic acid in water

mentioned,

of Plastic refers only to the appearance

the information

given

and feel of the plastic

specimen.
B months

Solvent,

liquid

3 days

Stoddard

Solvent,

vapor

2 months

Fly Spray

Taxi@
Pamt and Varnish
Toxaphene
Insecticide.

by placing dry, injection-molded

in contact with the other material for the period of time shown.

without

Stoddard

Market

1.20

of water

(3% Sulfurtc Acid and


8% Ferrous Sulfate)

Super

1 BB

Most tests were conducted

116OF)

(lOOoF

-585

I -451
1

Softened

048

000

Unchanged

956

880

Slightly

stamed

Slightly

stalned

1 week

047

043

3 days

3 13

1 57

Dissolved

Remover

Unchanged

12% sOlUtlOn

(continued)

TABLE 1.6: CELLULOSE

ACETATES,

The

BUTYRATES,

Effects

PROPIONATES-EASTMAN

of Various

Chemicals

and

CHEMICAL

(continued)

Reagents

on TENITE*@, Propionate

:hange
Thlckr

Obretved

Slightly

Cond,tion

Percent

Time

of Plss,,c

Exposed

Weight

Premum

1 year

Regular

Change

Tfucknerr

Observed

Condition

of Plasttc

softened

Dissolved
Sligfwy swoiie
Dissolved
changed
Carbon

Softened,

dlsullde

Carbon

Softened.
Snftened,

tetrachlorlde

Chioroform
C,trtc
Citric

acid, IO.
acid (tablets1

swolien
wolien

Upchanged

Dssolved
Softened. swolie
Softened. swoiie
Unchanged
Dissolved

*Ethylene
acetate

Dissolved

5.38

I year
1 year

4.81
2.44

5.33
5.08

Shell

1 year

4.81

7.03

1 year
i year
1 year

3.58
3.22
6 96

5.48
6.91
23.25

2.2

-5.6

High-Test

Softened. swoIIe11
Dark yellow

35%

Quick drymg Blue No. 353;


Formulab.
Inc.
*Malath,on,
50% spray diluted

Nitric
acid
Oie~c acid
Dzone. 5-l 5 pphm
ozone.

70 pphm

Phenoi.
5%
Propane (gas)
Propane U,qu,di
soap 501tK. LISP
Sodturn carbonate.
2.5%
Sodium
Sodzum
S&urn
*Sodium
Sulfuric

chlorade, 10%
ferrocyantde
Idry crystals1
hydroxide.
1%
hydroxide,
10%
aad.
3%

Sulfurs
ac,d. 30%
TDlelle
Turpentine
Water
*Xylene

1
1
1
1
i

year
year
year
year
year

1 week

011

HD SAE

Texaco
Co
temperature
Texaco
Co
temperature
Sachet
Wcks

Dlslntegrated
Unchanged
Unchanged
Unchanged
Unchanged

080

0 9t

Unchanged
Unchanged
Unchanged
Drs,ntegrated
Unchanged
Shghtiy warped
Softened. swollen
Unchanged
Unchanged
Softened, saoiien

Most

9.36

svrface

Dark yellow
P,nk and warped
Yellow. slightly warped
Yellow
Swollen and pink

8.15

Softened, swollen. surface


p,tted and cloudy when wet

=50
=50

10 motor

011

2 months
6 months
1 week
(122F)
4 necks
(122-F)

011 1692 low


oil, MIL-L-644B
011 1692
low
01,. MIL-L-6440

powder

tests

an ontomate

were

-196
Unchanged
-0
10
-030
-2.04

changed
0.03

-3.38

-0.64

1 month
(122F)
2 days
(122F)

decongestant

nc temperature

-0.92

(122 Fl
4 weeks
,122 F)
I year

changed

year
year
year
year
year

1 year
1 week
1 year
1 year
1 year
1
1
1
1
1

DISIntegrated
changed
Unchanged

1 week

Crude oil

Unchanged
Unchanged
Dlssoived
Dssoived
Dlssnlved

1 year
1 year
45 days
,otdoars)
45 days
(12OF)

18 days

011

Bardah,

Purol
I year
1 year
i year

*avy

Brownish yellow
Pmk, wollen,
and warped

water to 0.5% Malathion

011:
Bard&

n:haged
nchanged
Dlsmteglated

10%

Hydrogen peroxide, 3%
Methanol.
5%
Methanol,
100%
Methyl ethyl ketone
*Methyl lsoamyl ketone

swo,ien.

Ink,

wth

glycol
monomethyl
ether
(EKTASOLYE
ERA Acetate1

Gasolme,
Regular
Glycerin
tieptane
Hydrochlor,c
acid.

12.16

2 25

*Shell Regular
Texaco Regular
Texaco Sky Ch,ef

F)

Ethyl acetate
Ethyl aicohol. 50%
Eulyi aicohoi. 95%
Ethylene giycol
Ethylene
g,yco, monoethyl
ether (EKTASOLVE
EEI

Formaldehyde.

6.28

1 year

Esso Prenvum
Esso Regular

Amoco

Vnchangrd

month

1
I122

Gasoline,
Amoco
swoilen

conducted

contact

wth

IS shown

by placmg
the
were

other

dry,

Badiy

mjectmn-molded

material

conducted

Unchanged

losted
at

73F

for the
(23GCl.

specimens
perpod

01 tome

ot TENITE
shown

stained.

Proplonate
Tests

for

whxh

sottened

TABLE 1.7: CHLORINATED

POLYVINYL

CHLORIDE

PIPE AND FITTINGS-B.F.

GOODRICH
CPVC PIPE/FITTINGS CKEMICAL RESISTANCE

The attached list is a compilation of chemical resistance data from three


companies involved in the CPVC pipe, fittings and accessories market.

Chemical

company
A

company
B

Company
C

739
Since each company has used a different scheme to report their findings,
the following key will be needed to interpret the data.

Company A

E - Excellent to operating limit of material


G-

Excellent to 80'F;
material

Good to maximum operating limit of

S-

Good to BO'F.

L-

Limited; may be used under certain conditions

u-

Unsatisfactory; not recommended

Maximum operating limit is 18O'F


225'F

Company B

1 - Good for 200F

(93C)

2 - Good for 185'F

(85'0

3 - Good for 140'F

(6O'C)

4 - Good for

(21%)

70F

Q - Questionable
NR - Not Recommended

Company c

R - Recommended
NR - Not Recommended
R* - Reconrmended to 21O'F

for pressure applications;


for "on-pressure applications

Acetaldehyde
Acetate Solvents,
Crude
Acetate
Solvents, Put-e
Acetic Acid, 10%
Acetic Acid, 20%
Acetic Acid, 50%
Acetic Acid, 80%
Acetic Acid, Glacial
Acetic Anhydride
Acetone
Acrylonitrile
Adipic Acid
Ally1 Alcohol
Ally1 Chloride
AlUUl
Aluminum Chloride
Aluminum Fluoride
Aluminum Hydroxide
Aluminum Oxychloride
Aluminum Nitrate
Aluminum Sulfate
Punaonia, Aqueous
Ammonia, Dry Gas
Ammonia, Liquid
Anrnonium Bifluoride
Anaoonium Carbonate
Ammonium Chloride
Ammonium Fluoride, 25%
Ammonium Hydroxide
Arrmonim Hetaphosphete
Anxnonium Nitrate
Anrnonium Persulfate
Anrnonium Phosphate
Anreonium Sulfate
Anmoniom Sulfide
Atnaonium Thiocyanate
Amy1 Acetate
Amy1 Alcohol
Amy1 Chloride
Aniline
Aniline Chlorohydrate
Aniline Hydrochloride
Anthraquinone
Anthrequinone Sulfonic Acid
Antimony Trichloride
Aqua Regia
Arsenic Acid
Arylsulfonic Acid
Asphalt
Barium Carbonate
Barium Chloride

u
u

1859

NR

U
R
R

NR
NR

L
L
IJ
u
c
S
U
E
E

R
NR

NR

NR
NR
R

NR

R
R

R
R

R
R
R
R

R
R
NR
R

R
R

R
NR

ti?

NR

NR

R
R

NR
R

NR

NR
R

E
E
E
E
E
E
E
E
E
E
E
E
E
E
E

E
E
E
IJ
S
U
II
U
u
E
E
e
L
E
L
E
E
E

9
1

(continued)

TABLE 1.7: CHLORINATED

POLYVINYL

canpany
Chemical
Barium Aydroxide
Barium Sulfate
Barirnn Sulfide
Beer
Beet Sugars Liquors
Benzaldehyde
Benzene
Benzene Sulfonic Acid, 10%
Benzene Sulfonic Acid
Beotoic Acid
Bismuth Carbonate
Black Liquor
Bleach, 12.5% Active CL2
Borax
Boric Acid
Boron Trifluoride
Breeder pellets, fish
Brine
Brwic Acid
Bromine, Liquid
Bromine Water
Butadiene
Butane
Butanol, Primary
Butanol, Secondary
Butyl Acetate
Butyl Alcohol
Butyl Amine
Butyl Phenol
Butyl Phthalate
Butylene
Butynedial (Erythrital)
Butyric Acid
Cadmium Cvanide
Calcium Bisulfite
Calcium Carbonate
Calcium Chlorate
CaIcium Chloride
Calcium Aydroxide
Calcium Hypochlorite
Calcium Nitrate
Calcium Phosphate
Calcium Sulfate
Cane Sugars Liquors
Carbon Bisulfide
Carbon Dioxide
Carbon Monoxide
Carbon Tetrachloride
Carbonic Acid
Casein
Castor Oil
Caustic Potash
Caustic Soda

CHLORIDE

E
E
E
u
U
E
E
E

NR
NR

NR

NR

NR
1

E
E
E
E
E
E
E
u
L
S
L
S
S
u
S

R
R

4
R
R

NR

NR

R
R

NR

NR

i
S

tm
S
S
L
E
E
E
E
E
E
E
E
E
u
E
E
E
E

E
E
E
E

NR
1

1
R
1
1
1
1
1

R
R
R

NB

4
1

R
R
R
R
R
R

canpany
A

company
B

185Q

(continued)

Chemical

1
1

1
1

GOODRICH

Company

Cwpany
B

73Q
E

PIPE AND FITTINGS-B.F.

Cellosolve
Chloracetic Acid
Chloral Hydrate
Cblaric Acid, 20%
Chlorine Gas, Dry
Chlorine Gas, Wet
Chlorine, Liquid
Chlorine Water
Chlorobenzene
Chloroform
Chlorosulfonic Acid
Chrome Alum
Chromic Acid, 10%
Chromic Acid, 30%
Chromic Acid, 50%
Citric Acid
Coconut Oil
Copper Chloride
Copper Cyanide
Copper Fluoride
Copper Nitrate
copper Sulfate
Core Oils
Cottonseed Oil
creso1
Cresylic Acid, 50%
Croton Aldehyde
Crude Oil
Cyclohexane
Cyclohexanol
Cyclohexanone
Decalin
Demineralized Water
Detergents
Dextrin
Dextrose
Diazo Salts
Diesel Fuel
Diglycolic Acid
Dimethylemine
Dimethyl Formamide
Dioctylphthslste
Disodium Phosphate
Dowtherm
Ethers
Ethanolamine
Ethyl Acetate
Ethyl Acrylate
Ethyl Alcohol
Ethyl Chloride
Ethyl Ether
Ethylene Bromide
Ethylene Cblorohydrin

E
S
E
E
S
II

Q
4

E
u
U
L
E
E

2
NR
NR
4

E
E
E
E
E
E
e
E
E
E
S
G
U
E

canpany
C
185Q
73Q

NR
R

NR
NR

NR

NR

4
2

R
R
R
R

R*
R*
R*
R

1
1

R
R

R
R

1
1

NR

NR

R*
R

Q
1
NR

U
U

Q
G
1

E
E
E
1
E
u
0
II
E
u
U
u
E
U
U
U
U

NR
NR
R

NR
NR

1
I
:
3

-.

(continued)

TABLE 1.7: CHLORINATED


Chemical

POLYVINYL

Company
A

Ethylene Dichloride
Ethylene Glycol
Ethylene Oxide
Fatty Acids
Ferric Chloride
Ferric Rydroxide
Ferric Nitrate
Ferric Sulfate
Ferrous Chloride
Ferrous Sulfate
Fish Solubles
Fluorine Gas
Fluoroboric Acid
Fluorosilicic Acid
Formaldehyde, 35%
Formaldehyde, 37%
Formaldehyde, 50%
Formic Acid
Freon - 11
Freon - 12
Fructose
Fruit Juices, Pulp
Fuel Oils
Fuel Oil with R2SOh
Furfursl
Gsllic Acid
Gas - Coke Oven
Gas - Manufactured
Gas - Natural
Gasoline - Refined
Gasoline - Sour
Gelatin
GllXClse
Glycerine (Glycerol)
Glycol
Glycolic Acid
Green Liquor
Aeptsne
Rexsne
Rexanol, Tertiary
Rydrobrmic Acid, 20%
Rydrochloric Acid, 0-25X
Hydrochloric Acid, 25-372
Rydrocysnic Acid
Aydrofluoric Acid, fOX
Hydrofluoric Acid, 30%
Rydrofluoric Acid, 50%
Hydrofluoric Acid, 60%
Rydrofluorosilicic Acid
Rydrogen
Hydrogen Cyanide
Hydrogen Fluoride, Anhydrous
Rydrogen Peroxide, 30%

u
E
u
E
E

CHLORIDE

1
1
1
1
1
1

E
E
E
E
E
L
E
E

3
3

S
E
E

Chemical

739

1859

R
R

R
R

R
R
R
R
R
R
R
R

NR
NR
NR
NR
NR
NR

L
L
S
E
6

NR
R

NR

R
R
R

2
2

2
2
2

R
R
R

NR

4
4
4

NR
NR
NR

NR

R*

R*

R
NR
3

(continued)
Cmpany

4
E
u
E
G
E
S
S
E
E
E
E
E
E
E
S
S
S
E
G
G
E
S
S

GOODRICH

Cwpsny

Company
B
NR
1

PIPE AND FITTINGS-B.F.

NR

Rydrogen Peroxide, 50%


Hydrogen Peroxide, 90%
Hydrogen Phosphide
Rydrogen Sulfide, Aq. Sol
Hydrogen Sulfide. Dry
Rydroquinone
AydroxyIsmine Sulfate
Rypochloraus Acid
Iodine fin Alcohol)
Isopropyl Alcohol
Jet Fuel, JP-4
Jet Fuel, JP-5
Kerosene
Ketones
Kraft Liquor
Lacquer Thinners
Lactic Acid, 25%
Lard Oil
Lsuric Acid
Lauryl Chloride
Lsuryl Sulfate
Lead Acetate
Lime Sulfur
Lineolic Acid
Linseed Oil
Liquors, Liquers
Lubricating Oils
Magnesium Carbonate
Magnesium Chloride
Magnesium Hydroxide
Magnesium Nitrate
Magnesium Sulfate
Naleic Acid
Yalic Acid
Mercuric Chloride
Mercuric Cyanide
Mercurous Nitrate
Mercury
Methyl Alcohol
Methyl Chloride
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
Methyl Sulfate
Methyl Sulfuric Acid
Methylene Chloride
Milk
Mineral Oils
n01ssses
Motor Oil
Naphtha
Nsphthslene
Nickel Acetate
Nickel Chloride

cwpa*y

Canpsny
C
185op
739
R

R
R
R

NR
NR

NR
NR

R
R

u
S
S

E
E
E
S
U
G

G
G
L
G
G
G
S
E
e
E
G
S
E
G
E
E
E
E
E
E
E
E
E
E
S
U
U
S
S
U
S
E
E
S
U
E
E

2
NR

1
1
1
1
1

3
NR
NR

NR

R
R

(continued)

TABLE 1.7: CHLORINATED


Chemical

POLYVINYL

company
A

CHLORIDE

c .

73oF
Nickel Nitrate
Nickel Sulfate
Nicotine
Nicotinic Acid
Nitric Acid, 10%
Nitric Acid, 20%
Nitric Acid, 30%
Nitric Acid, 40%
Nitric Acid, 50%
Nitric Acid, 60%
Nitric Acid, 68%
Nitric Acid, Anhydrous
Nitrobenzene
Nitropropane
Nitrous Oxide
OCWD3l
Oils and Fats
Oleic Acid
Oleum
Oxalic Acid
Oxalic Acid, 50%
oxygen
ozone
Falmitic Acid, 10%
Palmitic Acid, 70%
Paracetic Acid, 40%
Perchloric Acid, 10%
Perehloric Acid, 70%
Perchloroethylene
Phenol
Phenylhydrazine
Phenylhydrarine
Hydrochloride
Phosgene Gas
Phosgene Liquid
Phosphoric Acid, O-501
Phosphoric Acid, SO-752
Phosphoric Acid, 85%
Phosphorous, Yellow
Phosphorous, Red
Phosphorous, Pentoxide
Phosphorous, Trichloride
Photographic Solutions
Picric Acid
Plating Solution, Brass
Plating Solution, Cadium
Plating Solution, Chromium
Plating Solution, Copper
Plating Solution, Gold
Plating Solution, Lead
Plating Solution, Nickel
Plating Solution, Rhodium
Plating Solution, Silver

PIPE AND FITTINGS-B.F.

2
2

G
2
G
G
U
U
S
E
E
E
U
E

S
U
E
G
u
6
6
S
S
L
U
E
U
E
E
E
E
E
E
E
E

R
R
R
1

R*
R*
NR

NR

1
1

R
R

R
R
R
R
R
R
R

1
3

2
2

Cwpany
A

Ccmpany
B

185oF

NR
NR

E
E
S
S
U
E
U

(continued)

Chemical

E
E
E
G

GOODRICH

CCQKLXbV

Company
B

R
R

R*

NR

R
R
R
R
R
R
R
R
R

R
R
R*
R*
R
R*
R*
R*
R

Plating Solution, Tin


Plating Solution, Zinc
Potassium Acid Sulfate
Potassium Antimonate
Potassium Bicarbonate
Potassium Bichromate
Potassium Bisulfite
Potassium Borate
Potassium Bromate
Potassium Bromide
Potassium Carbonate
Potassium Chlorate
Potassium Chloride
Potassium Chromate
Potassium Cuprocyanide
Potassium Cyanide
Potassium Dichrmate
Potassium Ferricyanide
Potassium Fluoride
Potassium Rydroxide, 0-20X
Potassium Rydroxide, 35%
Potassium Rypochlorite
Potassium Nitrate
Potassium Perborate
Potassium Perchlorite
Potassium Permanganate
Potassium Persulfate
Potassium Sulfate
Potassium Sulfide
Propane
Propargyl Alcohol
Propyl Alcohol
Propylene Dichloride
Rayon Coagulating Bath
Selenic Acid
Salicic Acid
Silver Cyanide
Silver Nitrate
soaps
Sodium Acetate
Sodium Acid Sulfate
Sodium Antimonate
Sodium Arsenite
Sodium Benzoace
Sodium Bicarbonate
Sodium Bisulfite
Sodium Chlorate
Sodium Chloride
Sodium Chlorite
Sodium Cyanide
Sodium Dichromate
Sodium Ferricyanide
Sodium Ferrocyanide

E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
E
L
E
E
E
E
E
E
E
S
E
S
u
G
E
E
E
E
E
E
E
E
R
E
E
E
E

E
E
E
E

company
C
739
185oF
R
R

R*
R

NR

1
1
1
1

1
1

R
R

R
R

1
1

R
R

R
R

1
1
R
2

1
1
1

1
1
1
1

R
R
R
R

R
R
R
R

R
R

R
R

R
R
R
R

R*

R
R

(continued)

TABLE 1.7: CHLORINATED

POLYVINYL
Ccmpany

c=vny
A

Chemical

CHLORIDE

PIPE AND FITTINGS-B.F.

GOODRICH

(continued)

Company

Ccmpany

Chemical

Cwpany

1859
Sodium Fluoride
Sodirnn Rydroxide,
Sodium Rydroxide,
Sodium Rydroxide,
Sodium Hydroxide,
Sodium

Aypochlorite

Sodium

Nitrate

Sodium

Nitrite

Sodium

Phosphate

NR

White

NR

Wines

NR

Xylem

NR

Zinc

Chloride

Zinc

Chromate

Zinc

Cyanide

Zinc

Nitrate

Zinc

Sulfate

R
R
Acid

Sodium Silicate
Sodium Sulfate
Sodium Sulfide
Sodium Sulfite
Stannic Chloride
Stannoua Chloride
Stearic Acid
Stoddards Solvent
Sulfur
Sulfur Dioxide, Dry
Sulfur Dioxide, Wet
Sulfuric Acid, O-10%
Sulfuric Acid, 10-50X
Sulfuric Acid, SO-752
Sulfuric Acid, 80%
Sulfuric Acid, 75-902
Sulfuric Acid, 90%
Sulfuric Acid, 93%
kulfuric Acid, 94%
Sulfuric Acid,
95%
Sulfuric Acid, 96%
Sulfuric Acid, 98%
Sulfuric Acid, 100%
Sulfurous Acid
Sulfur Dioxide, Liquid
Sulfur Trioxide
Tamic Acid

R*
R*
R*
R*
NR
NR

NR

70%

739

Tanning Liquors
Tartsric Acid
Tetraethyl Lead
Tetrahydrofurane
Tetrahydrofuran
Thicmyl Chloride
Titanic Tetrachloride
Toluol, Toluene
Tributyl Phosphate
Trichloroethylene
Tricresylphosphate
Triethanolamine
Triethylamine
Trimethylpropane
Trisodimn Phosphate
Turpentine
urea and Urine
Vinegar
Vinyl Acetate
Water
Water, Acid Mine
Water, Demineralized
Water, Distilled Fresh
Water, Potable
water, Salt
water, Sea
water, Sewage
WI iskey

R
R*
R*

15%
30%
50%

Company

Liquor
or

Xylol

1859

NR

NR

NR

NR

NR

NR

NR

NR

S
U

NR

U
S
U
U
U
U
L
S
G
E
S
E

NR

R*

U
G
G

2
2
2

R*

R*
R*

R
R

R*

R
R

R*
R

R
R

R
R

NR
1

NR

NR

32

Corrosion

TABLE

1.8:

Resistant

Materials

Handbook

EPOXY COMPOUNDS-DEVCON

Chemical Resistance of Devcon Epoxy Compounds

Somple Size: l/2 x % x I Cure: 7 days at room temperature. Immersion: 30 days

Product Name
Plastfc Steel Putty
Plastic Steel Lfqurd
Piastrc Steel 5-Mtn Putty

VG

/ Alumtnum

Puttv

VG

/ Alumfnum

Lrqutd

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

Tile Adhesrve

VG

Pump Repour Compound

VG

VG

VG

Hfqh Temp Wear ResIstant Putty

VG
VG

/
/

VG
VG

Hugh Temp Mold Maker

VG

VG

Tonkfte II

VG

VG

Lrqurd

VG

VG

Putty

VG

VG

/
I

VG
VG
VG

/
1
1
1

VG

VG

VG

/
/

VG

VG

VG

VG

j
/
/

VG

VG

j
i
]
1
1

VG
VG

VG

VG
VG

VG

VG
VG
VG
VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

/
/
I

VG

VG

VG

VG
VG

VG

VG

VG

II

VG

VG

VG

leOOf

VG
VG

/ Wet Surface Reparr Puttv

VG

/ Hfah lmpoct Bockma

son SOIuftOn.

VGF

VG

i
t

VG

1
1
1

VG

_
are Vti In Water, SOtUrOted

VG

VG

VG

VG

1 All products

VG

VG

Epoxy Sealer 100

1
/

1
1
~
/

VG

1 Bocktnq Compound

VG

VG

VG

Backfng Compound

VG

VG

Ceromfc Puttv

VG

/
/

/ Wear Resstant

HrahTemp

VG

1 Wear Reststant Puttv

Ceramfc Wear Compound

VG

1
1
j

VG

VG

Lraurd

VG

VG
1 Carbrde Putty

VG

/
/

VG

VG

VG

/
/

VG
VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

gasolrne, mtneral spwts, ASTM 3 011and propylene glycol

CAUTION: Epoxres ore generally not recommended for long term exposures to concentrated ocfds and orgonfc solvents

Key. VG-Very Good; F-Fas U-Unsdsfoctory

TABLE

1.9:

EPOXY

PIPE AND

FITTINGS-AMERON

BONDSTRAND
Series 1200 and Series 1600 are unlined epoxy products produced by the filament-winding
process. Series 1200 piping offers the user a locked
Q-ring joint for quick, reliable joining of either suspended or buried pipe systems, even under adverse weather conditions.
For those users who prefer the rugged
strenqth and performance
of the QUICK-LOCK@
adhesive bonded joint, Ameron offers Series 1600 piping with its heavier pipe walls, longer spans and greater
ring stiffness..

Chemtcal Solution

Chemical Solution

oncen-

1,

-L

.3t10lY

150

66

Chloroform

NR

NR

Formaldehyde

75

24

NR

NR

Chlorine Gas wet

NR

YR

Formc Acid

NR

75

24

Chlorinated Bwe

NR

VR

Fuel O,i

210

99

NR

Acrylic Acid

NR

NR

Chlowated

Wale?

I-50 ppn

150

66

Gasoi~ne

150

66

NR

Air

210

99

Chlorinated Water

>50 pprr

NR

VR

Glycerin

210

99

rr

210

99

Chrome ACIC

NR

UR

Green Liquor (paper)

100

38

klum~num Chloride

210

99

C~tw Acid

210

99

r/

Heptane

150

66

Aluminum

Nitrate

200

93

Copper Chlwde

2w

93

Hexane

100

36

Alumuum

Sulfate

210

99

Copper N~tra:e

200

93

Hydraulic 011s

200

93

--F
Acetic Acid
1

ACelOne

A,rnlrn

Potassium Sulfa te

O-IO%

Ammonla Gas Dry

150

66

Copper Sulfa%

210

99

Hydrobromlc

Aced

Ammonium

Chloride

120

49

Crude Oil (sweet 8 sour)

210

99

NR

Hydrochloric

Acid

Ammonium

Hydroxide

100

36

Cyclohexano

100

38

NR

Ammomum

Phosphate

150

66

Detergents

120

49

I/

Hydrofluoric

Ammontum

Sulfate

210

99

D~ailylpnthalate

120

49

Hydrofluosillc

Ammonium

Nitrate

210

99

0-Dichlorobe?zene

150

66

NR

Hydrogen Chiortde Gas

75

24

Diesel Fuei

200

93

NR

Hydrogen Peroxide

Barium Chloride

200

93

Diethylene Tr,anine

NR

VR

Benzene

120

49

D,prooylene Gyco!

150

66

1/

Al?lllX?

Magnewm

NItrate

200

93

Magnesum

Sullate

210

99

rr

Male~c Actd

770

77

NR

Maleic AnhydrIde

150

66

NR

Mefhyl Alcohoi

1w

38

Methyl Chlor,de

NR

\IR

NR

Methyl Ethyl Ketone

100

36

NR

Methyl lsobutyl Ketone

100

38

NR

Methylene Chloride

NR

\1R

Mineral Oil

210

99

NR

Monochlorobenzene

1W

36

NR

NR

4R

%or IX

75

24

Z-1

NR

dR

Naphtha

210

99

NR

NR

JR

Natural Gas

210

99

NR

Nickel Chloride

210

99

Nlckei N~frale

160

62

Nickel Suitate

210

99

1.10%

75

24

10.70%

NR

QR

Acid

NR

ilR

150

66

NR

JR

Hydrogen Sulllde

150

66

r*

N,,ric Acid?

lodlne (Sal @ R T)

120

43

NI!~ Aod

Acid

NR

O-25

O-30

NR

150

66

Ethyl Acetate

120

49

Isopropyl Alcohol

120

43

1/

Oil (crude)

210

99

NR

BornAcid

200

93

Ethyl Acrylatf

120

49

Jet Fuel

200

93

NR

Ole~c Acid

2cc

33

NR

Bromine Water

150

66

Ethyl Alcoho,

100

38

r/

Kerosene

210

99

NR

Perchloric Acldl

75

24

NR

Calctum Chlonde

210

99

Ethyl Benzene

100

38

NR

Lactic Acio

170

77

NR

Perchlowthylene

100

36

NR

Calcium Hypochlonte

150

66

Ethy: Chloride

NR

\iR

Latex Solulions

210

99

<l%

75

24

NR

Calaum Nitrate

200

93

Ethyl Ether

100

36

Lead Nitrale

170

77

lr

>I%

NR

\lR

Calcum Sulfate

200

93

Ethylene Dlch,ortde

NR

\iR

Linseed 011

200

93

NR

38

Carbon Dlsulflde

75

24

Ethylene Glyco

210

99

Lllhium Chloride

210

99

150

66

Fatty Acids

100

36

NR

L,thum Hydroxide

150

66

Black Liquor (paper mfg

Carbon Tetrachlorzde
Chloroacetlc Acetic
Chloroacellc

Acid-Glac\a

Chlorobenzene
-

NR

Phenol

Phosphoric Acid

_
_

0.70%

0.2%

1W

2.25%

75

24

!5-50%

75

24

75

24

Femc Chloride

170

77

rr

Magnesium

Carbonate

170

77

NR

NR

YR

Ferric Nitrate

150

66

Magnewm

Chloride

210

39

Polyvinyl Alcohol Em&Ion

103

38

75

24
-

Femc Sulfate

210
-

210
-

39
-

rr

Potaswm

210

99
-

on- lued)

39
-

Magnestufr

HyOroxlde

jO-65%

Chlonde

_
I/

TABLE

1.9:

EPOXY PIPE AND FITTINGS-AMERON


Chemical

(continued)

-B

Solutton

SL

Chemical

Soiut~on

Chemvzal

bll

210

99

Sodurn Cyanide
S&urn

Po:aswrr

Cyanide

Potaw~m

Fluortde

0.30%

150

66

Potassium

Hydroxide

0.50%

1cO

36

Potaswm

Nitrate

210

99

Polaswm

Sulfate

99

Propylene

Glycol

210
T
210

99

Sodturn Bromide

210

99

SDd~um Blsulfate

200

93

Sodium Carbonate

S&urn

Chlorate

c-10%

210

99

0.50%

150

66

210

99

210

99

TABLE 1.10:
DURCON

1
Toluene

Tr,chlorcethylene
Trlethanolam!ne

Vinegar

rr

Water (dlslllied or delorwed:

i,

water (salt)

Water (fresh)

v
NR

Xylene

,,

Ztnc Chloilde

EPOXY RESIN-DURIRON

6 js a solid, cast thermosetting

Acetic Acid, 7O?, 200F


Acetic Acid, Glacial, 200-F
Acetone, boiling
Acetyl Chloride, boiling
Alcohol, 175F
Alum, 2OOF
Aluminum
Chloride, 2@IcF
Ammonium
Bisulfite, 150F
Ammonium
Chloride, 200-F
Ammonium
Sulfate, 200F
Amy1 Acetate, 2OOF
Amy1 Alcohol, 175F
Amy1 Chloride, 200cF
Aniline, 15OF
Anod zing Solutions, 200 F
Antimony
Trichloride,
150-F
Benz;Idehyde,
200. F
Benzene, boiling
Benzene Hexachloride,
I75* F
Black Liquor, 200~F
Brine, 200-F

Tanmc Acld

Tetrachlorwthylene

epoxy

which

Butvric Acid, 200F


Calcium Chlorate.
150 F
Calcium Chloride. 200 F
Carbon Tetrachloride,
boiling
Chloracetic
14cid . 125F
Chlorinated
\Vater, IFiOF
Chlorine Dioxide. 150 F
Chlorine, IYet, 150 F
Chlorobenzene,
175-F
Chromic Acid, 305, ambient
Citric Acid, 2OOF
Copper Sulfate, 2OOF
Cupric Chloride, 200 F
Dichlorobutane,
2OOF
Dimethyl
Formamide,
200-F
Diethyl Sulfate, 200F
Ethyl Alcohol, boiling
Ethyl Ether, boiling
Ethyl Nitrate,
boiling
Ethylene
Dichloride,
150 F
Fatty Acids, 2OOF

is silica

filled.

Concen-

Temperature

Gasket

;.,.;.~
.Tartaric Acid

Hydroxide

Solution

The following

is a list of typical

Ferric Chloride, 150. F


Ferric Nitrate,
2OOF
Ferric Sulfate, 200cF
Formaldehvde,
boiling
Formic Acid, boiling
Hydrobromic
Acid, 40$. 200F
Hydrochloric
Acid, IO?, 200F
Hydrochloric
Acid, 205, 200 F
Hydrochloric
Acid, 305, 2OQF
Hydrochloric
Acid, cont.. boiling
Hydrocyanic
Acid, 125F
Hypochlorous
Acid, 125-F
Lactic Acid, 200-F
.Ilagnesium
Chloride, 2OOF
Magnesium
Sulfate. 200 F
?rlaleic Acid, 200 F
Malic Acid. 200 F
Mercuric
Chloride, 200 F
hletal Plating Solutions,
150-F
hlethyl
Alcohol. boiling
Methyl Ethyl Ketone, boiling

applications

I
I
I
I
Where no concentration is shown,
recommendations apply to any concentration
up to 100% or to saturatton.
%enes 5000 pipe can be expected to provide
a ionger service life in thts environment.
JGeneral fluid compatibility of standard polymer
used in O-ring gasket for Bondstrand Series
1200 piping.
Vor water contaminated with oil or fuel, standard
polymer provides suitable performance at
temperatures up to 180F (82C).
ti Standard Gasket OK
NR Not Recommended
- Not Tested

for DIJRCON

Nickel Chloride, 200 F


Nickel Sulfate, 2OOF
Nitric Acid, IO%. 175-F
Nitiic Acid, 5O%, ambient
Nitrobenzene,
150-F
Oleic Acid, 2OOF
Oxalic Acid, 200F
Perchloroethylene,
200-F
Phenol, 125-F
Phosphoric
Acid, 85%, 2OOF
Phosphorous
Oxychloride,
150F
Phthallc
Acid, 2OOF
Potassium
Nitrate, 200F
Rayon Spin Bath, 200-F
Sea RBter, 200-F
Sodium Bicarbonate,
li5F
Sodium Bisulfate. 200 F
Sodium Chloride, 200 F
Sodium Nitrate. 200 F
Sodium Perchlolate,
100 F
Sodium Sulfate. 200 F

6.
Sodium Thiosulfate,
200~ F
Stannic
Chloride. 200 F
Sulfite Liquors. I5OF
Sulfur Chloride. 15O.F
Sulfuric Acid, 305, 200 F
Sulfuric Acid, X-r, 150-F
Sulfuric Acid, PO%, 125 F
Tannic Acid, 2&I F
Tartaric
Acid, 200-F
Thiophenol,
200 F
Toluene,
175 F
Trichloroacetic
Acid. 125F
Trichloroethylene,
boiling
Urea, 200F
Linegar, 200 F
Water, boiling
Zinc Chloride, 200F
Zinc Sulfate, 200F

4
8
9.
9
$
P
6
w
x

3
3
8
*

Synthetic

TABLE

1.11:

EPOXY

RESINS-SHELL

35

Resins and Polymers

CHEMICAL

These amine-cured
EPON resin coatings are unique because they cure at room temperature.
They are outstanding
for their resistance to heat, solvents, salt water, and most other corrosive
materials,
and have notable
resistance to
mechanical
shock and abrasion.
EPON resin coatings exhibit
excellent
adhesion and flexibility
over wood,.ferrous
and nonferrous
metals, and green or dry concrete. These coatings have outstanding
weatherability
and the high solids
content
which is possible at application
viscosity.
Applications
for these coatings are as finishes for wood, metal, and
environment,
as chemical
resistant
finishes for installed
equipment
Coating formulations
must be supplied
as two-package
systems, i.e.,
base component
containing
the EPON resin. The usable working life

concrete
in marine and other severely corrosive
where high-temperature
baking is impractical.
the curing agent packaged separately
from the

is a 10 to 15 hour period after the curing agent

is added.
A high
solvent
portant
coating

degree of cure is obtained

overnight,
but about five to seven days are required
for maximum
chemical and
resistance properties
to develop.
More rapid cures can be obtained
by forcedrying
or baking. The most imreaction
involves the crosslinking
of the EPON resin with the polyfunctional
amine curing agent. The epoxy
systems referred to below are as follows:
System 1: A fourcoat Svstembased on two coats of a long oil linseed ester red lead
primer Plus two Coats of a long oil soya ester topcoat for a total film
thickness of 6 to 6 mils.
SWem 2: A fourcoat swtem based on two coats of EPON resin lOOl/EPON curing
agent C-l 11 red lead primer plus two coats of the EPON resin 1001/C-l 11
topcoat for a total film thickness of 6 to 6 mils.
Swtem 3: A four-coat system based on two coats of EPON resin lOOl/EPON curing
agent V-15 red lead primer plus two coats of the EPON resin 1001/V-15
topcoat for a total film thickness of 6 to 6 mils.
System 4: A two-coat n/stem based on EPON resin 815/EPON curing agent H-2 applied to a total film thickness of 8 to 10 mils.
Code:

R = Recommended for immersion service


R(S) = Recommended for spillage only
NR = Not recommended

Coating Systems
1

Hydrogen peroxide, 30%


Sodium hypochlorite, 5%
Calcium hypochlorite, 5%

NR

NR

R(S)

NR
R

NR
R
R

Chromic acid, 40%

NR

Chromic acid, 5%

NR

R
R
NR
NR

Sulfu dioxide solutions

R(S)

Chlorine water

Oxidizing

Agents

R(S)

R
NR

NR

NR

NR

R(S)

NR
R

Carbon dioxide

Sulfur didxide

NR

Chlorine

NR

NR

NR

Hydrogen sulfide

NR

NR
R

Gases (Moist)

Acids
Sulfuric, 10%

R(S)

R(S)

NR

Sulfuric, concentrated

NR

NR

NR

NR

Hydrochloric, 10%

R(S)

R(S)

Hydrochloric, concentrated

NR

R(S)

R(S)

R(S)

Nitric, 10%

R(S)

R(S)

Nitric, concentrated

NR

R(S)
NR

R(S)

NR

R(S)
NR

R(S)
NR

Phosphoric, 10%
Phosphoric, concentrated

R(S)
NR

NR
R
NR
(continued)

36

Corrosion

TABLE

1.11:

Resistant

Materials

Handbook

EPOXY RESINS-SHELL

CHEMICAL

(continued)

Coating Systems

Hydrofluoric, 10%
Hydrofluoric, 30%
Lower fatty, e.g., acetic, 20%
Lower fatty, e.g., acetic, concentrated
Higher fatty, e.g., oleic
Organic food, e.g., citric

NR
NR
NR
NR
NR

R(S)
NR
NR
NR

R(S)
NR
NR

R(S)
NR
NR
NR
R

R(S)

R
R

NR
NR
R

Alkalies
Sodium hydroxide, dilute

R(S)

Sodium hydroxide, concentrated

R 61
R

Ammonium salts

R(S)
P

Sodium carbonate

R(S)
R
R

R(S)
R
R

R
NR
R

Calcium hydroxide
Ammonium hydroxide, dilute
Ammonium hydroxide, concentrated

Salt Solutions (5%-l

0% concentration)

Alum

Ferrous sulfate

R(S)

Copper sulfate

R(S)
R

Sodium chloride
Calcium chloride

Sodium sulfate
Sodium phosphate
Sodium acetate

R
R
R

Water
NR
NR
NR

NR
R

NR

R
R

R(S)
R

R(S)
R(S)

Alcohol (methyl, ethyl, and butyl)

R(S)

Ethers

R(S)
NR

R(S)

R(S)

Ketones
Phenol
Furfuryl alcohol

NR

R(S)

R(S)

NR
NR

R(S)

R(S)

R(S)

R(S)

R(S)

R(S)

Furfural

NR

R(S)

R(S)

R(S)

R(S)
R(S)

R(S)

Animal

R(S)

Vegetable

R(S)

R(S)

Chlorine

NR
NR
NR

NR
NR

NR

Bromine

NR

NR
NR

NR

NR

NR

Tap
Distilled
Sea
Solvents
Chlorinated hydrocarbons (except methylene chloride)
Aromatic hydrocarbons
Aliphatic hydrocarbons

Esters

R
R

Fats and Oils


Mineral

Halogens (Moist)

lodi ne

*Esters are not recommended for continuous immersion service, only limited service.

MIBK

and above.

Synthetic

TABLE

1.12:

FIBERGLASS

REINFORCED

EPOXY

AND

VINYL

ESTER

PIPING

Resins and Polymers

SYSTEMS-A.O.

37

SMITH-

INLAND
RED THREAD
II Pipe:
An unlined
fiber glass reinforced
epoxy resin pipe with the ability to solve corrosion
problems in light chemical
service at temperatures
up to 21OF. GREEN
THREAD
Pipe:
Fiber glass reinforced
epoxy
resin pipe with a glass mat reinforced
epoxy resin liner. Provides superior corrosion
resistance at temperatures
up to
225F.
POLY THREAD
Pipe:
Fiber glass reinforced
vinyl ester resin pipe with a glass mat reinforced
vinyl ester
re.sin liner intended
for use in corrosive services at temperatures
to 200F. Final liner thickness
not less than 20 mils.
Vinyl esters have better chemical resistance than epoxies in high acid concentrations
and to oxidizing
agents.

Chemical Resistance
MAXIMUM

RECOMMENDED

TEMPERATURE

F FOR PRODUCTS LISTED


Red
Green
Thread II
Thread
Thread

N.R.-Not

MAXIMUM

Recommended

RECOMMENDEDTEMPEFIATUAE

pw

CHEMICAL

Acetic Acrd, 10%


Acetic Acid, 25%
Acetrc Acid. 50%
Acetlc Acid, 75%
Acetic Acid. Glacial
Acetone
Acryhc Acid, 95%
A&r(Wet or Dry)
Alummum Chloride. 1%
Alumtnum Potasstum Sulfate, 56%
Aluminum Sulfate, 50%
Ammonia Gas-Dry***
Ammonium Hydroxide. 10%
Ammontum Hydroxide. 26%
Ammontum Persulfate. 30%
Ammontum Nrtrate, 25%
Anolyte
Beer
Benzene
Benzene Sulfonic Acid, 5096
Benzene Sulfonic Acid, 75%
Benzene Sulfonic Acid, 100%
Black Liquor (Pulp Mill)
Boric Acrd. 4%
Bone Acid, 20%
Bromoform
Bromme Water, 4%
Butyl Acetate
Bury1 Cellosolve
Calcrum Chloride, 37.5%
Calcrum Hypochlorite, Satd.
Carbon Disulfrde
Carbon Tetrachloride
Chloroacetic Acid, 10%
Chloroacetic Acid, 25%
Chloroacetrc Acrd, 50%
Chloroacetrc Acrd, Glacial
Chlorobenzene
Chloroform
Chlorothene
Chlorine Gas, Wet t l **
Chlorine Saturated Brine d
Chlorinated Water-G100
ppm Cl,
Chlonnated Water-1~2CQ+mCI
Chlorinated Water - Saturated $
Chromic Acrd. 5%
Chromic Acid, 10%
Chromic Aod. 30%
Citric Acrd. 32%
Coca-Cola (Syrup)
Copper Sulfate, 17%
Cresol 5%
Cresol 10%
Dichlorobenzene (Ortho)
Drethylene Triamine
Drmethyl Formamide

150
N.R.
N.R.
N.A.
N.R.
N.R.
N.R.
210
210
210
210
150
lo0
100
N.T.
210
N.R.
210
120
N.T.
N.T.
N.T.
150
210
200
N.R.
N.R.
75
150
210
N.R.
120
150
100
N.T.
N.T.
N.R.
100
N.R.
100
N.R.
N.R.
150
N.R.
N.R.
N.R.
N.R.
N.R.
210
100
210
75
N.T.
150
N.R.
N.R.

200
120
120
120
75
120
100
225
225
225
225
225
150
100
75
225
150
225
150
N.T.
N.T.
N.R.
225
225
225
N.R.
N.R.
150
150
225
N.R.
120
150
120
N.T.
N.T.
N.R.
150
N.R.
120
N.R.
N.R.
225
200
N.R.
N.R.
N.R.
N.R.
225
150
205.
120
75
150
N.R.
N.R.

200
200
150
150.
75
N.R.
N.R.
200
200
N.T.
200
N.T.
120
150
200
2oD
N.T.
N.T.
75
150
150
N.R.
N.T.
200
200
N.T.
N.T.
N.T.
N.T.
200
150
N.T.
150
N.T.
120
150
N.T.
N.R.
N.T.
75
150
150
200
200
156
150
150
N.R.
N.T.
N.T.
200
N.T.
N.T.
N.T.
N.R.
N.T.

CHEMICAL

Dioxane
Distillery Stillage
Distillery Syrup
Divinyl Benzene
Dowanol EE
Dowanol EM
Dovviax BNB-Surfactant (NonylPhenol-Ethylene Oxde Condensate)
Dow Latex 560
Dow Latex 700
Dow Latex 2144
Ethyl Acetate
Ethyl Acrylate
Ethyl Alcohol
Ethyl Benzene
Ethyl Ether
Ethylene Glycol. 100%
Ethylene Glycol-50%
in Water
Femc Chloride, 10%
Ferric Chlonde 40%
Ferric Sulfate, 10%
Ferric Sulfate, 40%
Formaldehyde
Formic Acid, 88%
Freon 12 OT 22 (Gas or Liquid)
Gasolrne, 100 Octane
Glycerine
Glyoxal
Green Liquor (Pulp Mill)
Hexane
Hydrdwomic Acid, 10%
Hydrcbrornic Acid, 20%
Hydrobromic Acid, 51%
Hydrochloric Acid, 1%
Hydrochloric Acid, 10%
Hydrochlonc Acrd. 20%
Hydrochloric Acid. 36.5%
Hydrofluoric Acid, 1%
Hydrofluoric Acid, 5%
Hydrofluoric Acid, 10%
Hydroflweilicic Acid, 25%
Hydrogen Chloride-Gas,
Dry***
Hydrogen Peroxide, 10%
Hydrogen Pemxide, 27.5%
Hydrogen SuHie Gae**
Iodine (Satd. at Room temp.)
Isopropyl Alcohol
Jet Fuel (Super Refined Kerosene)
Kerosene
Lactrc Acid, 50%
Lithium Chloride
(Satd at Room Temperature)
Lithium Hydroxide
(Said. at Room Temperature)
Magnesium Chloride, 24%
(Mp Cf,6H,D)

N.T.-Not

Tested

F FOR PRODUCTS LISTED


Red
Green
POIV
rhread II
Thread
Thread

N.R.
150
150
100
75
N.R.

75
150
150

N.T.
N.T.

100.

N.T.
N.T.
N.R.

75
N.R.

100
210.
210
210.
75
120
75.
120
100
210
210
150
150
210
210
75
N.R.
N.T.
210
210
N.T.
100
100
N.R.
N.R.
N.R.
75
N.R.
N.R.
N.R.
N.T.
N.T.
N.R.
N.R.
150
N.R.
N.R.
150
120
100
150
210
120

100
225
225
225
120
120
120
150
100
225
225
205
205
225
225
120
N.R.
75
225
225
120
205
loo
15Ql)
15ql)
loQ1,

15Ql)
15Ql)
1541)

75.11
N.T.
N.T.
7541)
loql,

N.T.

N.T.
N.T.
N.T.
N.T.
N.T.
N.T.
N.T.
N.T.
N.T.
N.T.
N.T.
200
2clo
200
200
N.T.
75
N.T.
75
N.T.
N.T.
N.T.
75
2Dct
200
150
200
2cxl
200
150
150
150
75

150
N.R.
N.R.
150.

200
N.T.
75
75
N.T.

150
120
150
225
225

N.T.
N.T.
N.T.
N.T.
N.T.

210

225

200

150

205.

N.T.

225

200

210

(continued)

TABLE

1.13:

FIBERGLASS

REINFORCED

FURAN

POLYMER-QUAKER

OATS CHEMICALS
QUACORR

QUACORR
is the trademark
for furfuryl alcohol based resin/catalyst
systems developed by the Quaker Oats Company
for the manufacture
of fiberglass reinforced plastic (FRP) equipment.
QUACORR
laminates exhibit a broad range of
solvent and chemical resistance combined with excellent physical, flame spread,
and smoke development
properties.

ACETIC

for the proper application

GUIDE

CONCENTRATION

MEDIA

ACID

ACETIC

The QUACORR@
Media Guide provides guidelines
QUACORR
FRP equipment
in corrosive media.

MEDIA

25%
25%

ACID

25%
100%

(GLACIAL)

100%
ACETIC

ACID,

CHLORIDE,

SODIUM

CHLORIDE,

XYLENE,

ACETIC
METHANOL,

ACETIC

ANHYDRIDE

ACETIC

ANHYDRIDE,

POTASSIUM

POTASSIUM

DICHLOROPHENDL,

DICHLOROPHENOL,
HYDROXIDE,

ANHYDRIDE,

Unsatisfactory

R.T.

Rcnrr

Temperature

(70F

to

Unknown

CHLORIDE,

XYLENE,

X
X

METHANOL,

I50

150

DICHLDROPHENOL,

TRICHLOROBENZENE

ACID,

SODIUM

ACETONE

100%

I 501.

ACETONITRILE

100%

R.T.

100%

R.T.

176

I50

190

ACRYLIC

ACID

ACRYLIC

ACID,

SULFURIC

ACID,

METHACRYLATES,

6:60:5:5:24

WATER2.
100%
(HEAVY),

SODIUM

ALKYD

RESIN
CHLCRIDE

ACID

MALEIC

HYDROXIDE,

HEXANE

ALKYL

(pH

ACID,

FUMARIC

SODIUM

BISULFITE,

Unknown

I-12)
100%

(TRACE),

R.T.

R.T.

100%

R.T.

Sat.

150

Unknown

HYDROCHLORIC

(AQUEOUS1

gOoF)
ALLYL

I Ing

(240)
150

100%
SODIUM

HYDROXIDE,

HEPTANE,

X
X

I50
B.P.

X
X

SODIUM

ACETIC

ACID,

Satisfactory

R.T.

TRICHLOROBENZENE

CHLORIDE,

ALCOHOLS

I50
B.P.(214)

Unknown

ACRYLONITRILE

R.T.

BROMO-

BRDMODICHLCROPHENOL,

METHANOL,

-KEY

100%

of

The data in this bulletin have been compiled from laboratory


testing of QUACORR
1001/2001
laminates prepared in accordance with U.S. Department
of
Commerce
Product Standard 15-69. Laminates were evaluated using the ASTM
C-581 test method which requires total immersion of the laminates in test media.
Data were obtained from coupons exposed to media for a minimum of three
months and, in most cases, one year and compared
to unexposed
control
laminates. Recommendations
are based on an evaluation
of the following
properties:
weight
change, thickness
change, visual appearance,
flexural
strength,
flexural
modulus,
and Barcol hardness.
Based on the results of one year testing in the
media specified in ASTM Test C-581, this corrosion guide can also be used for
QUACORR
1500 FR.

TESTofEMP.

@.P.

Boi

SAT.

Saturated

CONC.

Concentrated

CHLORiDE

Point
ALUMINUM

FLUORIDE

ALUMINUM

POTASSIUM

SULFATE

5%

R.T.

5%

I50

5%
AMINES

(ORGANIC),

HYDROCHLORIC

::

NITRO

COMPOUNDS,

Unknown

B.P.
R.T.

(212)

X
X

ACID

Tested
under
Recommendation

pressure.
based

on

successful

case

histories.

(continued)

TABLE 1.13:

FIBERGLASS

REINFORCED
QUACORR

MEDIA

FURAN

POLYMER-QUAKER

QNCENTRAT

ACETATE

I oh

Sat.

AMMON I UM BROM I DE

TEMP
OF

R.T.

HYDRDSEN

At+t0JIUM

HYDROXIDE

SULFATE,

SULFURIC

ACID

Sat.

150

01 lute

250

20%

R.T.

100%

150

ANILINE

TETRACHLORIDE,

CELLOSOLVE

ACETATE

CELLOSOLVE

SOLVENT

CHLORAL
AQUA

REGIA
100%

150

BENZENE

100%

150

100%
100%

R.T.
150

X
X

100%
100%

R.T.

150

CHLORIDE

0-BENZYL-p-CHLOROPHENOL

BLACK

PULP

MILL

LIQUOR2

Icd*

SOLUT

AROMATIC

MLCRINATED
CHLDROETHANE,

SOLVENTS
(TRACE).
TRIHYDROCHLORIC
ACID
(DILUTE)

CHLORINE

(FREE?.
ACID

(MONO)

CHLOROACETIC

ACID

(TRI)

R.T.

CHLOROFORM

150

150

Sat.

SODIUM

CHLORIDE,
ACETIC
HYDROXIDE,

CARBON

TETRACHLORIDE,

(MIXED

WATER

ISOMERS)

BRCMODICHLOROPHENOL,
PHENOL,
SCDIUM

SOLVENT

CHLORDACETIC

(FREE13

POTASSIUM

WATER

CHLORINATED

CHLOROPHENOL
BROMINE

CHLOROFORM,

ALCOHOLATE

CrlLOROFORM,
BORAX

GUIDE

BENZALDEHYDE

BENZYL

MEDIA

CARBCN
AfwINILIM

(continued)
QuACCRR

EST
MEDIA

Af+!CNIUM

OATS CHEMICALS

GUIDE

CHLORIDE,

XYLENE,

Unknown

150

ANHYDRIDE,
TRICHLORO-

X
X

95%

R.T.
150

100%

R.T.

100%

R.T.

100%

150

CYCLMEXANE

100%

150

CYCLCHEXANONE

100%

150

(312)

100s

150

100%

R.T.

100%

150

DICHLDRC-

ACID,
ACETIC
METHANOL,

150

95%

p-c%lLOROPHENOL

100%

CHLOROSULFQNIC

ACIDI.

BENZENE
CHLCROTHENE
BUTYL

ACETATE

100%

I I3

CRESOL
BUTYL

ALCOHOL

lOO%

100%

BUTYRALDEHYDE
CALCIUM
CARBON

150

DISULFIDEA

100%

QuaCorr

service

Consult

Technlcal

Servlce

3.

Maxlmum

allowable

concentrations

In

thls

concentrations

Recoranendation

(MIXED

ISOMERS)

X
X
100%

2.

4.

(243)

HYPQCHLORITE

1.

loh

3.P.

N.U.

media

may
based

on
be

on

should

be

temperatures
have

satisfactory.

successful

dlscussed
higher

not

been
Testing

case

historles.

with
than
deftned.
Is

3.P.fll5)

Technical

Service.

CYCLOHEXYLAMINE
DEMINERALIZED

WATER

15OF.
QuaCorr
recommended.

servlce

100%

at
DICHLDRETHANE

1.

Maximum
low

IOOl

(1.2)

allowable

concentrations

concentrations
may

be

satisfactory.

have

not

B.P.

B.P.f212)
150

been
defined.
QuaCorr
Test
1 ng is reccminended.

X
X

servlce

at

(continued)

TABLE 1.13:

FIBERGLASS

REINFORCED
@JACDRR

MEDIA

FURAN

ACID,

:EST TEMP
OF

100-120

Z-ETHYL

ETHYLENE
WATER

CHLOf?OtiYDRIN,

Unknown

ETHYLENE

DIAMINE

Unknown

ETHYLENE

DIBROMIDE

ETHYLENE

DICHLORIDE

UHYLENE

GLYCOL

DNCENTRAT

0-DICHLOROBENZENE,
HYDROXIDE

(pH

IO

98%
HYDROCHLORIC
ACID
bYDROXlDE,
MALEIC
ACID,

ISOPROPYL

190

Unknown

SODIUM

SODIUM
MALEIC

HYDROXIDE,
ACID,
FUMARIC

ACID
(2.4)

100%

DICHLOROPHENOL,

SDCIUM

ACID,

CHLORIDE,

POTASSIUM

XYLENE,

CHLORIDE,

SODIUM

ACETIC

FLUDE0RlC

Unknown

ACETIC

HYDROXIDE,

150

FDRMALIN

100%

B.P.(257)

FDRMIC

FUEL OIL

100%

R.T.

DIMETHYL

FORMAMIDE*.

100%

R.T.

DIMETHYL

PHTHALATE

100%

300

DIMETHYL

PROPANOLAMINE

100%

I50

100%
100%

150
3.P.(212)

100%
100%
100%

R.T.
I50
3.P.(l71)

DIETHYLAMINE

WATER

ETHYL ACETATE

ACIDl

FUMARIC ACID, HYDROCHLORIC ACID (DILUTE),


SODIUM HYDROXIDE,
MALEIC ACID,
ISOPROPYL
ALCOHOL, o-DICHLOROBENZENE
FUMARIC ACID, MALEIC ACID,
HYDROXIDE,
SODIUV BISULFITE,
HEXANE, HEAVY ALCOHOLS (pH

FUMARIC ACID, SOOIUM HYDROXIDE,


MALEIC
ACID, o-DICHLORDBENZENE,
ISOPROPYL
ALCWOL

X
X

FUNDAL

sat.

II3

ETHYL ACRYLATE

100%

R.T.

951
95%
95%

R.T.
I50
3.P.(l73)

FUNDAL,

METHYL PARATHION

FURFURYL
ALCOHOL

1.

Tested

2.

Maxlmum
lower

(ETHANOL)

in

combination

allohable
concentrations

with

otter

concentraticns
may

be

GAS OIL, MINERAL


PENlACHLCi?Df+lENOL

1.

satisfactory.

not

been
Testing

defined.
Is

QuaCorr
recommended.

ALCOHOL RESIN

media.
have

SODIUM
HEPTANE,
l-12)

ETHYLACFTOACETATE

ETHYL

ACID

FDRMALDEHYDE

IO05

CARBONATE

DISTILLED

ACIDl

FLUOSILICIC

FUEL

DIETHYL

ACID,

TRI-

CHLOROBENZENE
DIESEL

HYDROCHLORIC

METHANOL,

BROMODICHLOROPHENOL,

ANHYDRIDE,

ACID

IO)

o-DICHLOROBENZENE,
ISOPROPYL
ALCOHOL,

DICHLOROPHENDL

BUTYRIC

GUIDE

ALCOHOL

513%
7

(continued)
QJACORR MEDIA

DICHLOROBENZENE1
o-DICHLOROBENZENE,
(DILUTE),
SODIUM

OATS CHEMICALS

GUIDE

MEDIA

FUMARIC

POLYMER-OUAKER

servlce

al

f+!axlmum allowable
lower

2.

SPIRIT,

part

concentrations

COnCentratlOnS
Fundal

to

KEROSENE,

may
7

parts

be

have
sailsfactory.

not

been
Testlng

defined.
Is

QuaCorr

ser~lce

a+

recomnended.

water.

(continued)

TABLE 1.13:

FIBERGLASS

REINFORCED
QUACORR

MEDIA

FURAN

POLYMER-QUAKER

GUIDE

IC+

IC DNCENTRAT

GLYOXAL
GREEN

40%
PULP

MILL

LIQUOR.

100%

n-HEPTANE

SODIUM

ACID,

HYDROXIDE,

HEXANE,

HEAVY

HEXANE,
SODIUM

MALEIC
BISULFITE,

ALCOHOLS

SODIUM
ALCOHOLS

(pH

HYDROBRmlC

FUMARIC

ACID,

150

R.T.

150

R.T.

X
X
(208

Unknown

199

Unknown

190

48%

R.T.

BISIJLFITE,
(pH

l-12)

FUMARIC
ACID,
HEPTANE,
HEAVY

ACID
ACID

HYDROCHLORIC
ACID
CHLORIDE
(TRACE)

CAQUEOUS,,

ALKYL

15%

R.T.

15%
25%2.

I50

30%2.

I50

HYDROCHLORIC

ACID,

ETHYLENE

CHLOROIYDRIN,

HYDROCHLORIC

ACID,

NITRO

HYCJROCHLORIC
WATER

ACID,

PHOSPHOROUS

HYDROCHLORIC
WATER

ACID,

PHOSPHOROUS

HYDROCHLORIC

ACID

(DILUTE),

Unkrow

VINYL

Unknown

HYDROFLUDRIC

ACI D1

HYDROGEN
HYPOCHLOROUS

HYDROXIDE,

MALEIC

o-DICHLDROBENZENE,

ACID,

FUMARIC

ISOPROPYL

HYDROCHLORIC
MONCCHLORIDE

ACID,
SULFUR,
(VAPORS)

HYD7OCHLORIC
ACID
ETHANE,
CHLORINATED

(DILUTE),
SOLVENTS

160-180

R.T.

19

R.T.

6:75:

19

150

190

ACID,

FUMARIC

ACID,

II3

Unknown

190

ALCOHOL,

ISOPROPYL

ALCOHOL,

MALEIC

ACID

(DILUTE)

Unknown

190

SODIUM

HYDROXIDE,

MALEIC

ACID,

Unknown

190

100%

II3

95:5

185

75

FUMARIC

L ETHER
MYRISTATE.

L I GANC

SULFURIC

SULFURIC

( SOLVENT

ACID,

ACID

EXTRACT

U know

I O+J 1,

KEROSENE

KEROSENE,
GAS
PENTACHLORCPHENOL
KEROSENE,

Unknown

200

Unknown

R.T.

KELEX

ACID,

SPIRIT,

KELEX

(SOLVENT

ACID;

LIGAND

EXTRACTION);

ACID,

Consult

Technlcal

2.

Recorrnendatlon

Service

based

on

OTT temperatures

successful

case

higher
hlstorles.

than

150F.

150

Unknown

75

Unknown

75

B.P.

34%
PULP

MILL

FUMARIC
SODIUM

HEAVY

(266)

KEROSENE

ACID

HYDROXIDE,

150
B.P.

32:31:32:5

CHLORIDE

MAGNEFITE

HEXANE,

MINERAL

SULFURIC

SULFURIC

t4ALElC

OIL,

R.T.

100%
100%
100%

LlpUOR3.

ACID,

BISULFITE,

ALCOHOLS

(pH

SODIUM

Unknown

(280)

R.T.

I50

190

HEPTANE,
l-12)

1.

o-DICHLDROBENZENE

ISOPROPYL

LITHI,UH

TRICHLORO(TRACE)

R.T.

ACID

ALCOHOL,
HYDROCHLORIC
ACID
SOOIUM
HYDROXIDE,
MALEIC
ACID,

ISOPROPYL

ALCOHOL
SULFUR

I%

100%

ISOPROPYL
(DILUTE),

I SDfRDPY

6:75:

Unknown

SODIUM

R.T.

I SOPHORONE

LIGAND,
(DILUTE),

R.T.

15%

PEROXIDE

(ORGANIC)

ACID,

WATER

KEROSENE
COMPOUNDS,

TEMP.
OF

ION

ACID

R.T.

20:5:75

ACID

CHLORIDE,

KELEX

HYDROCHLORIC
WATER

CONCENTRAT

MEDIA

o-DICHLORDBENZENE,

150

Unknown

__ __
TEST

I-12)

HYDROCHLORIC

AMINES

ACID,

TEMP
OF

B.P.

100%
MALEIC

__..__.. __

I50

100%

HEPTANE,

(continued)

rEST

MEDIA

OATS CHEMICALS

1
1.

Consult

Technical

Servlce

2.

Maximum

allowable

concentrations
have
my
be satlsfactoy.

low

3.

COnCentratiOnS

Consult

TechnIcal

Service

on

on

hydrofltiorlc

temperatures

acid
not

been
Testing
higher

appltcatlons.
defined.
QuaCorr
is recommended.
than

15DoF.

service

at

(continued)

TABLE 1.13:

FIBERGLASS

REINFORCED
~ACDRR

MEDIA

FURAN

POLYMER-QUAKER

(continued)
QUACORR MEDIA

CONCENTRAT I ON

MEDIA

OATS CHEMICALS

GUIDE
TESTo:EHP.

METHYL PAP.ATH I ON,


X

MALEIC ACID, HYDROCHLORIC ACID (DILUTE),


SODIUM HYDROXIDE,
FUMARIC ACID,
o-DICHLOROBENZENE,
ISOPROPYL ALCOHOL

Unknown

MALE~~ ACID

U know

190

Unknown

190

(DILUTE),

ISOPROPYL

190

MALEIC ACID,
SODIUM HYDROXIDE,
FUMARIC
ACID, o-DICHLOROBENZENE,
ISOPROPYL
ALCOHOL

176

Crude

185

METHALLYL CHLORIDE,
SODIUM CARBONATE,
TRIETHYLAMINE
SALTS, METHALLYL ETHER OF
o-NITROPHEYOL,
WATER

Un know

170

METHALLYL ETHER OF o-NITROPHENOL


(CRUDE),
METHALLYL CHLORIDE,
SODIUM CARBONATE,
TRIETHYLAMINE
SALTS, WATER

Un know

METHALLYL

ACID,

ACRYLIC

CHLORIDE

100x

SPIRIT,

170

Un know

9.P.f

150)
150

INWSTRIAL

100%
100%

R.T.
150

X
X

100%

100

100%
100%
100%

R.T.
150
B.P.fl76)

X
X
X

R.T.
200

X
X

CHLORIDE1
KETONE

100s

KETONE

based

100%

on successful

70s

150

:32:5

150

R.T.
150
I.P.(27D)

150

100%

150

52
51

R.T.
150

X
X

NAPTHA
2.

ACID

case

hlstories.

PESTICIDE

2.
3.
4.

150

R.T.

GAS OIL,

KEROSENE,

5:3l

:32:32

150

R.T.
150
235-250
l.P.(250)

150

I50
150

100%

R.T.

I51
15%
15%
90s

R.T.
I50
l.P.(214)
150

loos
100s
loos
IO01

fFUNDALj3
52
SOS4
RESIN

PHOSF+lORlC

1.

975
Unknown

H2S04)

P+lENOL
PHENOLIC

(ORGANIC),

X
X

loos

PERCHLOROETHYLENE
176

METHYLENE

Recomndatlon

150

MORPHOLINE

OLEUM (CONC.

1.

I 005

II3

I SOBUTY L.

II3

5:60:6:5:24

loos

PENTACHLDROPHENOL,
MINERAL SPIRIT

ACID,

l.QNOETHANOLAMINE

NITRC COMPCUNDS, AMINES


HYDRCCHLORIC ACID

100%

METHYL

32:3l

METHYL CELLOSOLVE

METHYL ETHYL

KEROSENE,

NITRCBENZENE

METHANOL, ACETIC ACID,


SODIUM CHLORIDE,
POTASSIUM CHLORIDE,
XYLENE, ACETIC
ANHYDRIDE,
DICHLOROPHENOL,
SODIUM
HYDROXIDE,
BRDMODICHLOROPHENOL,
TRICHLOROBENZENE

METHYLATED

ACIDl

EST TEMP.
OF
120

50:50

SULFATE

MINERAL SPIRIT,
GAS OIL,
PENTACHLOROPHENOL

NITRIC

METHANOL

METHANOL, SULFURIC ACID,.ACRYLIC


METHACRYLATES,
WATERl.

FUNDAL

ION

MONOCHLORCBENZENE
5:60:6:5:24

METHACRYLATES,
SULFURIC
ACID, METHANOL, WATERI*

METHYL

METHYLSULFONIC

ALCOHOL

CNCENTRAT

MEDIA

IJ

GUIDE

ACID

X
X

X
X

Maxlmum allowable
concentrations
have not been defined.
DuaCorr
service
at
lower concentrations
may be satisfactory.
Testlng
Is recommended.
Not remmended
for concentrations
over 51.
I part
Fundal
to 7 parts
water.
Not recmnded
at hlgh concentrations
or hlgh temperatures.
Consult
Technical
Service
for concentrations
above 5% and temperatures
In excess
of 15OOF.

(continued)

TABLE 1.13:

FIBERGLASS

REINFORCED
QUACORR MEDIA

MEDIA

POLYMER-QUAKER

(pH

HYDROCHLORIC

t-3).

ACID,

WATE

EST TEMF
OF

Unknown

200

75:6:
75:6:

R.T.
150

19
19

POTASSIUM

(PHOSPHORYL

CARBONATE

POTASSIUM CHLORIDE,
SOCiUM CHLORIDE,
XYLENE, DICHLOROPHENOL,
ACETIC ACID,
BRCh4ODIWLOROPHENOL.
ACETIC ANHYDRIDE,
SODIUM HYDROXIDE,
METHANOL, TRICHLOROBENZENE
WTASSIUM

FERRICYANIDE

POTASSIUM

HYDROXIDE

POTASSIUM

PERMANGANATEI

POTASSIUM

PEROXIDEl*

POTASSIUM

PYROPHOSPHATE

PULP MILL

PULP MILL

PULP MILL

PYRIDINE

1.
2.
3.

Ll&OR

Licx~o~

LiwoR

(GREEN13

(RED)~.

(wHITE)~.

QUATERNARY

LIQUORl.

SILICON

TETRACHLORIDE

SLIMETROL

150

100%
100%

R.T.
150

X
X

Sat.

150

SODIUM EISULFITE,
MALEIC ACID, FUMARIC
ACID,
SODIUM HYDROXIDE,
HEPTANE, HEXANE,
HEAVY ALCOHOLS (pH l-12)

Unknown

150

$00

Sat.

150

R.T.
150

SODIUM CARBONATE, METHALLYL CHLORIDE,


METHALLYL ETHER OF o-NITROPHENOL,
TRIETHYLAMINE
SALTS, WATER

X
X

Sat.

SLIMICIDE

I50

X
X

(TKPP)*

At+4044 IUM SALTS

Sat.

50%
50%

60%
60%

R.T.
150

X
X

R.T.
150

R.T.
150

I UM

CARBONATE

SODIUM
(2.5%),

CARBONATE,
SULFUROUS

SODIUY

CHLORIDE

SODIUM HYDROSULFIDE
ACID

SODIUM CHLORIDE,
POTASSIUM CHLORIDE,
XYLENE, DICHLOROPHENOL,
ACETIC ACID,
BROMODICHLOROPHENOL,
ACETIC ANHYDRIDE,
SODIUM HYDROXIDE,
METHANOL, TRICHLOROBENZENE

X
X
X

SODIUM CHROMATE

R.T.
150

SODIUM HYDROXIDE

R.T.
150

150
150
R.T.

QuaCorr
Maximum allowable
concentrations
have not been define
low concentrations
may be satisfactory.
Testing
Is recommended.
Tested
in comblnatlon
with other
media.
Consult
Technical
Service
on tervperafures
higher
than 150F.

GUIDE

X
X

PHOSPHOROUS CHLORIDE

(continued)

RED PULP MILL

PHOSPHOROUS BROMIDEl*

PHOSPHORUS OXYCHLORIDE
CHLORIDE)

OATS CHEMICALS

&JACORR MEDIA

ONCENTRAT ION

PHOSPHORIC ACID SCRAP LIQUOR


SODIUM PHOSPHATE
PHOSPHOROUS ACID,

FURAN

GUIDE

X
X
service

SODIUK HYDROXIDE (3-13%),


BENZENE (pH 7 10)

o-DICHLORO-

at
1.

Consult

Technical

Service

on temperatures

higher

than

15DF.
(:.ontinued)

TABLE 1.13:

FIBERGLASS

REINFORCED

FURAN

POLYMER-QUAKER

OATS CHEMICALS

(continued)
@lACORR MEDIA

MEDIA

CCNCENTRAT I ON

SODIUM HYDROXIDE,
o-DICHLOROBENZENE,
ISOPROPYL ALCOHOL, MALEIC ACID,
FUMARIC
ACID

Unknown

SODIUM HYDROXIDE,
HYDROCHLORIC ACID
(DILUTE,
MALEIC ACID,
FUMARIC ACID,
o-DICHLDROBENZENE,
ISOPROPYL ALCOHOL

Unknown

SODIUM HYDROXIDE,
MALEIC ACID,
FUMARIC
ACID, SODIUM BLSULFITE,
HEPTANE, HEXANE,
HEAVY ALCOHOLS,
(pH I-12)

Unknown

SODIUM HYDROXIDE,
SODIUM CHLORIDE,
ACETIC ACID,
POTASSIUM CHLORIDE,
XYLENE,
DICHLOROPHENOL,
BROMODICHLOROFHENOL,
ACETIC ANHYDRIDE,
METHANOL, TRICHLOROBENZENE

Unknown

SODIUM

HYPOCHLORITE

SODIUM
LIQUOR

PHOSPHATE,
(pH l-3)

SODIUM

SULFIDE

PHOSPHORIC

SCRAP

(HYDRO)

SODIUM SULFIDE-HYDRO
CARBONATE, SULFUROUS
STANNIC

ACID

SODIUM

CHLORIDE

STYRENE
SULFONIC ACID (CONCENTRATED),
ACID,
SULFUR DIOXIDE
SULFUR,

SULFURlC

SULFUR CHLORIDE

(MONO)

SULFUR DIOXIDE,
SULFURIC ACID

SULFONIC

SULFUR MONOCHLORIDE
HYDROCHLORIC ACID

ACID,

(VAPCRS),

SULFUR,

190

190

150

Not recomnended
Maximum allowable
low concentrations

at

higher
concentrations.
concentrations
have
may be satisfactory.

not

SULFURIC

:DNCENTRAT lo1

ACfD

25%
25%
25%
5@%1.
5Obl.
60%**

SULFURIC ACID,
MEMACRYLATES,

ACRYLIC
WATERI*

ACID,

SULFURIC

ACID,

ISOPROPYL

SULFURIC

ACID,

KEROSENE,

SULFURIC
DIOXIDE

ACID,

SULFONIC

METHANOL,

MYRISTATE

200

TETRAHYDROFURAN

176

Unknown

176

I oog

I50

100%

R.T.

160-180

TETRAHYDROFURFURYL

Unknown

(2.5%

ALCOHOL

TETRAPOTASS I UM PYROPHOSPHATE

THICNYL

CHLORIDE

TOLUENE

X
TOLUENE

DIISOCYANATE

TOLUENE

SULFONIC

ACID

(IN

WATER)

METHANOL)

300

200

X
TOLUENE

SULFONIC

ACID

(IN

100%

150

TOLUENE

SULFONIC

ACID

(PARA)

TRIMLOROACETIC

Unknown

160-180

Unknown

200

service

ACID

TFI I CHLOROBENZENE , ACET I C AC ID. SOD I UM


CHLORIDE,
POTASSIUM CHLORIDE,
YYLENE,
DICHLOROPHENOL,
BROMODICHLWOPHENOL,
ACETIC ANHYDRIDE,
SODIUM HYDROXIDE,
METHANOL

at

2.

1.
_

Reconmwndatlon
_
. . acla
SdlterIc

based on successful
case
recomnenaea
to maxlmum of

~EST4EHF
S

R.T.
I50
3.P.f216:
150
250
150

X
X
X

X
X

I76

185

75

160-180

176

100%

R.T.

100%

R.T.

60%
60%

R.T.
150

100%

R.T.

100%

100%

R.T.
150
1.P. (230)

100%

R.T.

70%
85%

R.T.
R.T.

X
X

70%

R.T.

180

50%

R.T.

Unknown

150

100%

hlstorles.
50% concentration

Unknown

100%

Unknown

been defined.
QuaCorr
Testing
is reccnmended.

Unknown

SULFUR

Unknown

60:6:5:5:24

5:95

KELEX LIGAND
ACID,

SULFUROUS ACID,
SODIUM HYDROSULFIDE
SODIUM CARBONATE

SULFUR TR10XlDE2
1.
2.

MEDIA

Unknown

SULFUR

190

R.T.

MOLTEN

SULFUR, HYDROCHLORIC ACID,


MONOCHLORIDE (VAPORS)

.lS

2%
(2.5).
ACID

TESTO:EHP*

GUIDE

X
X

and 250F.
(continued)

TABLE 1.13:

FIBERGLASS

REINFORCED

FURAN

WACORR

POLYMER-QUAKER

MEDIA

TRICHLOROETHANE

(l,l,l)
(MIXED

GUIDE
TEST

MEDIA

TRICHLOROETHANE

CONCENTRAT I ON

ISOMERS)

TRICHLOROETHANE,
CHLORINATED
SOLVENTS
(TRACE),
HYDROCHLORIC ACID (DILUTE1

100s

R.T.

R.T.

150
B.P.(lB9)

X
X

Unknown

TRIETHANOLAMINE

100%

PHOSPHATE

VINYL CHLORIDE,
HYDROCHLORIC
(DILUTE),
WATER

ACID

R.T.

100s
100s

TRIETHYLAMINE
SALTS, METHYL ETHER OF
o-NITROPHENOL,
METHALLYL CHLORIDE,
SODIUN
CARBONATE, WATER

TEMP.
OF

100%

TRICHLOROETHYLENE

TRISODIUM

OATS CHEMICALS

II3

Unknown

170

sat.

150

Unknown

R.T.

WATER (DEMINERALIZED)

loos
loos
IO01

R.T.
150
B.P.(ZlZ)

X
X
x

WATER (DISTILLED)

100%
100%

150
B.P.(212)

X
x

R.T.
150

X
X

WdlTE

XYLENE

PULP MILL

(MIXED

LIQUOR.

ISOMERS)

XYLENE, SODIUM CHLORIDE,


POTASSIUM
CHLORIDE,
DICHLORORIENOL,
ACETIC ACID,
BROMODICHLORO~ENOL,
ACETIC ANHYDRIDE.
SODIUM HYDROXIDE,
METHANOL, TRIMLOROBENZENE
ZIRCONIUM
RAFFINATE
(ZIRCONIUM
DXYCHLORIDE,
HCI,
MIBK, THIOCYANIC

ACID)

ZIRCONIUM
RAFFINATE
(ZIRCONIUM
3XYCHLORIDE.
HCI, MIBK, THIOCYANIC

ACID)

100%

B.P.(284)

Unknown

150

100%

R.T.

100%

150

(continued)

Synthetic

TABLE 1.14:

FIBERGLASS
MOLDED

REINFORCED

ISOPHTHALIC

POLYESTER

Resins and Polymers

AND VINYL

47

ESTER-MORRISON

FIBER GLASS

EXTREN is a proprietary
combination
of fiberglass reinforcements
and thermosetting
polyester or vinyl ester resin
systems produced in standard structural shapes and sheets by Morrison Molded Fiber Glass Company. EXTREN is
widely used in industrial construction
and maintenance, commercial construction,
and as components of industrial
equipment and commercial products. The information
below is based on data collected from several years of actual
industrial applications.
In addition it is based on conservative evaluation of the changes which occur in certain properties of replicate laminates after exposures of one year or longer, both in the laboratory and the field, according to
the American Society for Testing Materials (ASTM C-581). These properties include hardness, flexural strength, and
flexural modulus. Surface stability is also a major characteristic and must be evaluated.

CHEMICAL
polyester

Series 500 and 525-lsophthalic


Series 625-Vinyl
ester

SERIES500525
RT

160F

EXTREN

RESISTANCE -

NR = Not resistant
R = Resistant
SERIESso&525

SERIES 625
RT
160F

RT

SERIES 625
RT
16c)F

CHEMICAL

CHEMICAL
NR

NR

NR

NR

Ammonium

Phosphate

Acetlc Acid O-25%

Ammonium

Sulfate

Acetic Acid 25-50%

NR

Arsenious

Acid

Acetic AnhydrIde

NR

NR

NR

NR

0-Benzoyl

Bentoic

Acetone

NR

NR

NR

NR

Acrylonltrile

NR

NR

NR

NR

Barium Acetate
Barrum Carbonate

Alcoho!, Butyl

NR

NR

NR

Barium Chloride

Alcohol, Ethyl 10%

NR

NR

150

Barium Hydroxide

Alcohol, Ethyl 100%

NR

NR

NR

Bawm

Alcohol, Isopropyl

10%

NR

NR

150

Alcohol,

100%

Acetaldehyde

Isopropyl

Acid

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

Butyric Acid 040%

NR

Butylene Glycol

NR

NR

NR

120

Calcium Bisulfite

Calcium Carbonate

NR

Calcium Chlorate

Calcium Chloride

Methyl lsobutyl

NR

NR

150

NR

NR

150

Benzyl Alcohol

R
120

Benzyl Chloride
Brass Plating Solutton.

Aluminum

Potassium Sulfate

Ammonia,

Aqueous

Ammonia,

Gas

O-10%

NR

NR

100

NR

NR

100

NR

120

Ammonium

Bicarbonate

Ammonium

Bisulfite

NR

NR

120

Ammonium

Carbonate

NR

NR

120

Ammonium

Citrate

Ammonium

Flouride

NR

120

NR

NR

100

Ammonium

Hydroxide

5%

NR

120

Ammonium

Hydroxide

10%

NR

120

Ammonium

Hydroxide

20%

NR

NR

120

Ammonium

Nitrate

NR

NR

120

Persulfate

120

Alcohol,

fl

120

NR

Nitrate

NR

NR

Aluminum

NR

NR

NR

NR

NR

NR

NR

Methyl 100%

Alcohol,

NR

R
R

NR

Beer

R
R

Benzene

NR
NR

NR

5%

NR

150

Hydroxide

NP
R

Aluminum

NR

R
R

Chloride

NR

120

NR

NR

Aluminum

NR

Alum

NR

NR

Butyl

NR

Sulfate

NR

Alcohol, Secondary

NR

Barium Sulfide

Alcohol, Methyl 10%

Ammonium

160F

5% Benzene

in Kerosene

Benzene Sulfonic Acid


Benzoic Acid

(3%
6%
1%
3%

Copper Cyanide
Sodum Cyamde
Zinc Cyangde
Sodum Carbonate)

Bury1 Acerate

Cadmium

Chloride

Cadmium

Cyanide

(3% Cadmwn Oxide


10% Wum
Cyantde

Plaling Solution:

1% Causticsoda)

R
R
(continued)

48

Corrosion

TABLE 1.14:

Resistant

Materials

FIBERGLASS
MOLDED

Handbook

REINFORCED

FIBER GLASS
SERIES 500-525
RT
160F

ISOPHTHALIC

POLYESTER

RT

NR

120

Copper

RT

16O'F

Pickling Bath.
NR

NR

R
R
R
R

011

Crude Oil, Sour

(10% Ferric Sulfate


10% Sulfuric Acid)

Calcium Hypochlorite

NR

120

Calcium Nitrate

Copper

Calcium Sulfate

Corn Oil

Calcium Sulfite

Corn Starch -

Caprylic

NR

Corn Sugar

Acid

Carbon Dioxide
Carbon Disulfide
Carbon Monoxide

NR

NR

NR

NR

Sulfate

Cottonseed

R
R

120
R

Chlorine Dloxlde,

NR
NR

NR
NR

R
R

R
R

Dichloroethylene

Diesel Fuel

Acid 040%

Chlorobenzene

NR

NR

NR
NR

NR
NR

R
NR

100
NR

R
R
NR

NR
NR
NR

NR

NR

NR
NR
R

NR
NR

Carbon Methyl Cellulose


Chlorinated Wax
Chlorine Dloxlde;Alr

NR

NR

R
NR

NR

NR

NR

NR

Chlorine, Llquld
Chlortne. Water

R
R

NR

loo

Chlorine, Wet Gas

NR

Dry Gas

R
R
R

Wet Gas

R
NR
NR

NR

Castor 011

Crude Oil, Sweet

NR

Acid

Slurry

Cyclohexane

NR
R

Carbon Tetrachloride

Chloroacetlc

SERIES 625

160ct-

CHEMICAL

Calcium Hydroxide

Chlorine.

ESTER-MORRISON

SERIES MO-525

SERIES 625
RT
160F

CHEMICAL

Carborw

AND VINYL

(continued)

Detergents, Sulfonated
Di-Ammonium Phosphate
Dibromophenol
Dibutyl Ether
Dlchloro

Benzene

Diethylene
Dimethyl

NR

NR
NR

NR
NR

R
NR

NR
NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

Glycol
Phthalate

Dioctyl Phthalate
Dipropylene
Dodecyl

NR

R
NR

Glycol

Alcohol

NR

NR

NR

NR

NR

NR

NR

Esters, Fatty Acids

Acid

NR

NR

NR

NR

Ethyl Acetate

NR

NR

NR

NR

Chromic Acid 20%

NR

NR

Ethyl Benzene

NR

NR

NR

NR

Chromic Acid 30%

NR

NR

NR

NR

Ethyl Ether

NR

NR

NR

NR

Ethylene

Glycol

Cltrvz Acid

Ethylene

Dichloride

Coconut 011

NR

R
NR
NR

R
NR
NR

R
R

R
R

NR

NR

Chloroform
Chlorosulfonlc

Chromium

Sulfate

Copper Chloride
Copper Cyanide
Copper

Fluoride

Copper

Nltrate

Copper

Plattng Solution

(Copper Cyanide
10 5% Copper
14% Copper Cyantde
6% Rochelle Salts)

Copper

NR

Brite Platmg

NR

120

(Causttc Cyanide)

NR

NR

Copper

Matte Dipping

(30% Few Chloride


19% Hydrochloric)

NR

NR

R
NR
R

Ferric Nitrate

Ferric Sulfate

Ferrous Chloride

Ferrous Nitrate

Ferrous Sulfate

8-8-8 Fertilizer

NR

NR

NR

120

Fertilizer
NItrate)

Flue Gas
Fluosilicic

Bath

R
NR

Fatty Acids

Fluoboric

19% Copper Sulfate


8% Sullur~c Acid)

R
NR

Ferric Chloride

(Urea Ammonium

Copper Plating Solution.


(45%Copper Fluoroborate

R
NR

Acid
Acid O-20%

NR

NR

NR

NR

NR

NR

120
R

Formaldehyde

NR

Formic Acid

NR

(continued)

Resins and Polymers

Synthetic

TABLE 1.14:

FIBERGLASS
MOLDED

REINFORCED

FIBER GLASS
SERIES

500-525

16oF

RT

ISOPHTHALIC

POLYESTER

AND VINYL

49

ESTER-MORRISON

(continued)
SERIES

SERIES

625

RT

160F

CHEMICAL

RT

500525
160F

SERIES

625

AT

160-F

CHEMICAL
R

Fuel Ott

NR

Kerosene

NR

R
R

NR

NR

NR

Laurlc Acid

NR

Gas. Natural

NR

Lactic Acid

Gasoline,

NR

Laura1 Chloride

Auto

Gasoline,

Aviation

NR

Gasoline,

Ethyl

NR

Lead Acetate

NR

Gasoline.

Sour

NR

Lead Nitrate

NR

Lead Plating Solution.

NR

NR

NR

NR

Glucose

Glycerine

Levulinlc

Glycol. Ethylene

Linseed 011

Glycol. Propylene

Lrthium Bromide

Glycolic

NR

Lithium Sulfate

NR

NR

Magnesium

Blsulflte

NR

Magnesium

Carbonate

NR

NR

NR

140

Gluconic

Acid

Acrd

Gold Plating Solution:


(63% Potasswm Ferrocyanlde
.2% Potassum Gold Cyanide
.0% Sodurn Cyanide)

Heptane
Hexane
Hexylene

Glycol

Hvdraulic

Fluid

.4%

Actd
Acid)

BOW

Acid

Magnesium

Chloride

Magnesium

Hydroxide

NR

Magnesium

Sulfate

NR

R
R
-

Hot Stack Gasses

(II% Fluoborlc

NR

340

NR

Maleic Acid

Mercuric

NR

Chloride

Mercurous

Chloride

NR

Methylene

Chloride

NR

NR

NR

NR

Hydrobromic

Acid O-25%

NR

Hydrochloric

Acid O-37%

NR

Methyl Ethyl Ketone

NR

NR

NR

NR

Hydrocyanic

Acid

NR

R
R

Methyl lsobutyl

NR

NR

NR

NR

Hydrofluoric

Acid 10%

NR

NR

120

NR

Acid

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

Hydrofluosilicic

Methanol

Carbitol

(see alcohol)

Methyl lsobutyl

Ketone

Hydrogen

Bromide,

Wet Gas NR

NR

Methyl Styrene

Hydrogen

Chloride,

Dry Gas NR

NR

Mineral

Hydrogen

Chloride,

Wet Gas NR

NR

Molybdenum

Disulfide

Hydrogen

Peroxide

NR

NR

120

Monochloro

Acetic Acid

Hydrogen

Sulfide Dry

NR

Hydrogen

Sulfide, Aqueous

NR

Motor 011

Hydrogen

Fluoride,

NR

NR

MyFIstic Acid

NR

NR

120

NR

NR

Hydrosulfite

Vapor

Bleach

Hypochlorous

Acid O-10%

Iron Plating Solutlon:


(45% FeCIz. 15% CaCI,
20% FeSOa 11% (NH.) zSO,)

Iron and Steel Cleaning


(9% Hydrochloric
23% Sulfuw)

Isopropyl

Amtne

Isopropyl

PaImItate

Jet Fuel

Bath

NR

NR

NR

NR

NR

NR

NR

Oils

Monoethanolamtne

Naphtha

Naphlhalene

NR

Nickel Chloride

NR

NR

NR

R Nckel Nltrate
Nickel Plattng.
(6% Lead
R

9% Fluobortc Acld
4% BOK
Acld)

NR
R Nckel Plating.
(11% Nckel Sullate
2% Nlckei Chlortde
R
1% BOW

Acid)

(continued)

50

Corrosion Resistant Materials Handbook

TABLE 1.14:

FIBERGLASS
MOLDED

REINFORCED

FIBER GLASS
SERIES 500525
RT
160F

ISOPHTHALIC

AND VINYL

ESTER-MORRISON

SERIES M&525
RT
160-F

SERIES 625
FIT
16oF

CHEMICAL

SERIES 625
RT
16oF

CHEMICAL

Nickel Plating:
(44% Nfckei Sulfate
4% Ammonium Chlorfde
4% Bone Actd)

Nckel

POLYESTER

(continued)

NR

Potassium Permanganate

NR

Potassium

NR

150%

NR

NR

120

50-100%

NR

NR

NR

NR

Persulfate

Potassium Sulfate

Sulfate

Nrtrrc Acrd 05%

Nrtric Acid 20%

NR

NR

120

Propylene

Nrtric Acid Fumes

NR
NR

NR
NR

R
NR

R
NR

Pulp Paper Mill Effluent

Octanorc Acrd

NR

011. Sour Crude

Oil. Sweet Crude


Oleic Acid

R
R

R
R

R
R

R
R

Nrtrobenzene

Propionic

Acid
Glycol

NR

NR

NR

NR

NR

Salicylic Acid

NR

NR

Sebacic

NR

NR

NR

NR

NR

NR

Pyridine

Selenous

Acid
Acid

Silver Nitrate
Oleum (Fumrng Sulfuric)

NR

NR

NR

NR

Olrve Oil

Oxalic Acid

Peroxrde Bleach
(2% Sodium Peroxlde
96%
.025% Epsom Salts 5%
SodturnSlllcate. 4TBE
1.4% Sulfurtc Acid. 66-BE)

Phenol

NR

NR

NR

NR

Phenol Sulfonic Acid

NR

NR

j\lR

NR

140

Srlver Plating Solution:


(4% Sher Cyanide
7% Potawum Cyanide
5% Sodium Cyanide
2% Potasswm Carbonate)

Soaps

NR

Sodium Acetate

NR

Sodium Benzoate

NR

Sodium Bicarbonate

R
NR

R
R

R
R

Sodium Bifluoride

R
R

Phosphoric

Acid

Sodium Bisulfate

Phosphoric

Acid Fumes

Sodium Bwlflte

Pentoxide

Sodium Bromate

Phosphorous Trichloride
Phthalrc Acid

NR

NR

NR

NR

Sodium Bromide

.R

NR

Phosphorous

Pickling Acids

(Sulfuric and Hydrochloric)

Picrrc Acid, Alcoholtc


Polyvinyl Acetate

Latex

Polyvinyl Alcohol
Polyvinyl Chloride
(Parts DOP)

R
R

R
NR
NR

R
R
R

R
R
R

Latex w/35

Potassium Aluminum

NR
Sulfate

NR

120

Potassium Brcarbonate

NR

140

Potassium

Bromide

NR

Potassrum Carbonate

NR

140

Potassium Chloride

Drchromate

NR

Potassium Ferricyanide

Potassium

Potassium
Potassium

Ferrocyanide
Hydroxide

R
NR

R
NR

Potassium

Nitrate

R
R
R

140
R
R
120

Sodium Carbonate

O-25%

Sodium Chlorate

NR

Sodium Chloride

Sodrum Chlorite

NR

Sodium Chromate

Sodium Cyanide

NR

Sodium Dichromate

Sodium Di-Phosphate

Sodium Ferricyanide

Sodium Ferrocyanide

Sodium Fluoride

NR

NR

120

Sodium Fluoro Silicate

NR

NR

120

NR

120

Sodium HexametaphosphatesNR
Sodium Hydroxide

O-5%

NR

NR

120

Sodium Hydroxide

5-25%

NR

NR

Sodium Hydroxide

50%

NR

NR

120
NR

R
(continued)

Synthetic

TABLE 1.14:

FIBERGLASS
MOLDED

REINFORCED

FIBER GLASS
SERIES 500-525
RT

160F

ISOPHTHALIC
SERIES 625
RT

NR

Sodium Hypochlorite

NR

120

Sodium Lauryl Sulfate

NR

Sodium Mono-Phosphate

R
R

Sodium Nitrate

NR

ESTER-MORRISON

SERIES 5Ob525
RT
160F

160F

AND VINYL

Sodium Sulfate

Sodium Sulfide

NR

SERIES
RT

(16%
7%
9%
2%

Stannous Fluoroborate
Tin
Fluorobonc Ac!d
Bow Acrd)

Toluene
Toluene

Sulfonic Acid

Transformer

NR

NR

NR

NR

NR

NR

NR

NR

N:

N;

Oils:

(Mneral 011 Types


Chloro-Phenyl Types)

Sodium Sulfite

NR

Sodium Terra Borate

Trichlorethylene

NR

N:

NR

NR

NR

NR

NR

NR

Trichlorophenol

NR

NR

NR

NR

Tricresyl

NR

NR

Sodium Tripolyphosphate

NR

Sorbitol Solutions
Sour Crude Oil
Soya Oil

R
R
R

NR

NR
R
R

R
R
R

R
R
R

Stannic Chloride

Stannous Chloride

Stearic Acid
Sugar, Beet and Cane Liquor
Sugar, Sucrose

NR

NR

NR

NR

NR

R.

Suifamic Acid

NR

Sulfanilic Acrd

NR

Sulfated Detergents

R
R

NR

NR
NR

NR

NR

Sulfuric Acid O-30%

Sulfuric Acid 3040%

NR

NR

Dry or Wet

Sulfur Trioxide/Arr

Sulfuric Acid 50-70%


Sulfurous Acid

NR

NR

120

NR

NR

100

NR

Tall Oil

NR

140

Tannic Acid

NR

120

Tartaric Acrd

NR

NR

NR

NR

Superphosphoric

Acid

(76% PaOs)

Thronyl Chloride

Tridecylbenzene
Trisodium

Sulfonate

Phosphate

Turpentine
Urea
Vegetable

011s

Vinegar

Styrene

Sulfur Dioxide,

Phosphate

NE

Sodrum Thiosulfate

Sodium Xylene Sulfonate

625
160F

CHEMICAL
Ttn Plating

Trichlor Acetic Acid

Sodium Thiocyanate

51

(continued)

CHEMICAL
Sodium Hydrosulfide

Sodium Silicate

POLYESTER

Resins and Polymers

NR

100

NR

NR

NR

NR

100

NR

140

NR

NR

NR

NR

Deronized

Demineralized

Distilled

Vinvl Acetate
Water

Fresh

Salt

Sea

NR

NR

NR

NR

NR

Zinc Chlorate

Zinc Nitrate

NR

NR

120

NR

White Liquor (Pulp Mill)


Xylene

Zrnc Plating Solution.


(9%21ncCyamde
4% Sodwn Cyantde
9% Sodtum Hydrowde)

Zrnc Platrng Solution:


(49% Zvnc Fluoroborate
5% Ammontum Chlonde
6% Ammonium Fluoroborate)

Zinc Sulfate

52

Corrosion Resistant Materials Handbook

TABLE 1.15:

FIBERGLASS

REINFORCED

POLYBUTYLENE

TEREPHTHALATE-CELANESE

PLASTICS

A series of thermoplastic
polyesters,
polvbutylene
terephthalate,
was developed
by Celanese and introduced
under
the trademark
CELANEX. CELANEX@ resins are highly crystalline,
and exhibit
a unique combination
of properties
including
high strength,
rigidity
and toughness,
low creep even at elevated temperatures,
minimal
moisture absorption and exceptional
dimensional
stability,
resistance to the effects of a wide range of chemicals, oils, greases and solvents, excellent
electrical
properties
and outstanding
processing characteristics.
Chemical Resistance of CELANEX

Material

YoChange
Time Temp. Tensile % Change % Change
(Days) F Strength Weight Diameter*

InorganIc Chemicals
10% Ammomum
90
Hydroxide
180
360
9
24

73
73
73
180
180

-13
-58
-73.5
-92
-99

+0.6
+03
+09
+2.1
-4 2

+0.3
0.0
+06
+0.3
+01

Glass-Reinforced Resins

Material
Carbon
Telrachlorlde

x Change
Time Temp. Tensile % Change % Change
F Strength Weight
Diameter
(Days)
90
73
0
+o 1
00
180
73
+o 1
00
360
73
+o 1
+0.1

Dlefhyl Ether

90
180
360

73
73
73

50% Ethylene
GlycollWater

90
180
360
24
90
180
360

73
73
73
180
73
73
73

Perchloroethylene

60
180

-6
-:

+0.3
+03
+0.5

+o 1
+o 1
+o 1

-3
-3
-3
-50
-3
-6
-5

+0.3
+0.4
+03
+2.4
+0.2
+0.3
+04

+o 1
+o 1
co 1
+0.4
+0.1
+0.3
+o 1

180
180

-30
-32

+65
+67

+0.6
+06

-2
-1
-3

-0
+0.11
-0.1

::
00

1% Sodium
Hydroxide

90
180
360
24

73
73
73
180

-47
-72
-84
-96

+oe
+0.5
+03
-1.9

+0.6
+o.,i
+0.7
0.0

10% Sodtum
Chloride

90
180
360

73
73
73

1;
-4

+03
+0.2
+0.4

+0.2
+0.1
+02

10% Hydrochloric 90
Acid
180
360
24
64

73
73
73
180
180

-4
-12
-20
-24
-68

-0 1
+o 1
+02
-06
-24

+0.2
+0.1
+01
0.0
-10

Freon 113

3% Sulfunc
Acid

90
180
360
24
64

73
73
73
180
180

-7
-10
-8
-25
-65

+02
+0.2
+0.2
+0.2
+02

+0.2
-0.1
+o 1
+0.1
+o 1

180
51
360

73
73

Gasoline
(Amoco.
Unleaded)

180
360
135
240

73
73
140
140

-1.6
-2.2
-74
-164

+0.2
+0.2
+1.4
+19

0.0
+o 1
+03
+03

40% Suifunc
Acid

90
180
360

73
73
73

-2
-4
-4

+0.4
+o.o
+o 1

0.0
+o 1
+o.r

Aulomatlc
Transmlsslon
Flwd. (Type 6)

90
180
360
60

73
73
73
100

-5
-3
-5
-3

-0.3
+03
+0.3
-

+o 1
+o 1
+0.1
-

73
73
200
200

1;

Water (Tap)

180
360
30
48

-31
-51

+o 1
+03
+04

+o 1
+ 1
00
+ 1

Delco 222
Brake Fluid

90
180
360

::

-6

+1
-1
-43
-60

00
+20
-22

00
+ 1
co3
+ 4

1;

+0.1
+0.2
+02

73
73
200
200

73

+03
0.0
+07

180
360
30
48

Motor 011
(10-20-40)

90
180
360

73
73
73

-4
-7
-8

+0.3
+0.3
+0.4

+0.1
+0.1
+0.1

180
360
60
100

73
73
200
200

-3
-3
-43
-61

+o 1
+02
+0.2

+01
+o 1
00
-0 1

Lubncatcng
Grease

180
360
60
100

73
73
200
200

-6
-4
-34
-64

+01
+o 1
+03

+02
+01
-0 1
-0 1

Hydraukc FluId
(Skydrol 500s)

180
360
60
240

73
73
180
180

0
-1
-2
-55

0.0
+03
+05

00
+o 1
+0.1
co 1

Turbine
Lubncattng Oil
(Texaco Sate 15)

18G
360

73
-17.3

-05

-0 1
-

+0.1
+0.1

Houron - Cosmo
Lubnc 2425

180
360

73
73

Cl
-167

00
-

180
360

73

-5
-24

+0.1

+0.1

Buffer, pHl0

Buffer, pH 4

95%
Ethanol/Water

Organic Chemicals
5% Acetlc Actd

90
180
360
:z

73
73
73
180

0
-5
-55
-77
-41

+03
+0.3
+0.2
+11
+0.7

+02
+0.1
+0.2
+0.2

90
180
360

:;

-4
-4

+0.5
+0.4
+08

+0.1
+0.1
+02

2::

120

-40
-Z

+5.9
+4.4

+0.9
+0.5

90
180
360

73
73
73

-15
-20
-27

+1.0
+2.0
+2.4

+0.2
+02
+0.6

1% Soap
Solwon

2::

120

-32
-35

+3.6
+3.4

+0.7

Presoak
(AxIon) Sol.

180
360

:;

1:

90
180
360
60
240

73
73
73
180
180

-8
-7
-8
-36
-39

+0.4
+4.2
+4.3

+0.1
+0.1
+0.1
+0.8
+0.8

Calgon Water
Softener
Sol.

180
360

73
73

1;

Bufler. pH7

BTX

90
180
3M)

73
73
73

I;

+0.1
+0.1
+0.1

Calgomte Dishwasher Sol.

:z
73
73

-10

+0.4
+0.5
-

180
360
180
360

Heptane

90
180
360

:il

-4

180
360

73
73

1;
-14
-17

+oo
0.0
00
+o 1
+02

Laundry
Detergent

73
180
180

+0.2
+0.1
+05
+06

Benzene

Acetone

Toluene

73

l/B x 2 diameter discs.

00
00

- 1
+o

1;
-3
-23

+03
+03
+1.3

+0.1
+o 1
+0.2

-4
-24

0,

Synthetic

TABLE

1.16:

RESOLITE
tions. The
application.

FIBERGLASS

REINFORCED

POLYESTER

CR panels are fiberglass-reinforced,


polyester
resin used in RESOLITE

polyester
CR panels

53

Resins and Polymers

PANELS-RESOLITE

sheets in flat and various corrugated


and ribbed configurawas developed
to withstand
chemical abuse in heavy-duty

Acids
AC&C

5
o-75
o-50
50-75
100

Aqua Reglo
Benzene Sllonlc
Benzolc
Bone
Butyric
Chloroocetlcs.
Mono. di
ond +r,

Chromic

Hydrobromac
Hydrochlorx
Hydrocyonlc
Hypochlorous
Hydrofluow
Loctlc
MOlelC
N,trnc*

Nl,,OS

OklC
OXOllC

Perchlorlc
Phorphotuc
steonc
Slf,l<
TOrtON

IOIC

Wet

Gases

Carbon Dioxide
Carbon Monor,de
Chlonne
Ammomo
Bromine
Flwwne
Hydrogen
Hydrogen
Chlonde
Hydrogen
Fluoride*
Hydrogen
Bromde
Hydrogen
Sulfide
Owdamg Gores
Redvcmg Gores
SteOlIl
Sulfur D,ox,de
Svlfut T&oxide
Chlorine Dioxide
Svlfur

o-100
o-50
50 100
o-30
30.50
oil
011
o-30
o-25
O-50
oil
011
011
o-10
O-20
011
011
0 35
35-60
over 60
O-10
oil
011
ol!
011
011
0-80
over 80.
011
011

S
S
S

S
S
S
T

5
5
5
S
S

S
5
S
S

T
T
S
:
S

z
S
5
5
T
S
S
S
S

T
U
S
T
5
S
S
5
T
S
S
S
S
T
s
s
S
T
T
S
5
5
T

:
S
T
S
S

:
S
T
S
S

:
5
:
S
S
S
S
S

and Fumes

011
OII
011
011
011
011
011
011
011
all
oli
011
011
011
011
011
011
011
011
011
011
OII
all
oil
all

Arrenoter

Bicorbonoter
B,tluorvder
B,rulfoter
B,rulf,tes
Borotes
Bromldel
Corbonotes
Chlorates
Chlorlder
Chromate!
D8chromotei
Fluorlder
Hydrorulf,des
lodfder
Ntt,oter
Perchlototer
Perrvlfoter
Phosphates
Phorphfter
SillColel
Slhco-fluor,der
wtoter
Sulflder
Sulf,ter

Solvents

S
S
S
:
S
S
S
5
:
S
S
S
5
S
S
S
S
T
S

S
S

S
S
S

S
:
T
T
;
S
S
S
:
S
5
T
S

and Orgomcs

Acerone

Alcohols (all]
Benzene
Benzoldehyde
Benzoyl Chlor,de
Carbon
Tetrochlorlde
Chlorobenzerer
Chloroform l
Ethers
Acetone,
Ethylene Chlonde
Formaldehyde
Gorol,ne
Glyc&

ep,one
S
S
S
5

s
S

Herone
Kerosene
Methyl Ethyl
Ketone
Naphtha
Nophtholene
Phenol l
Perchlorethylene
Tvchlorethylene
Thnonyl Chloride
StyretIe
Sulfuryl Chlonde
Toluene
Xylene
OllS
Ethylened,chlot,de
Ethylocetote

100
100
100
100
100

S
S
S
:

T
S
S
T
T

100
100
100
100
100
100
37
100
100
100
100
100

S
S
S
S
S
5
S
S
S
S
S
S

S
T
S
T
T
T
S
S
5
S
S
S

100
n
rn
v,v

S
S
S
S
T
S

T
S

100
100
011
100
100
100
100
100
100
100
100
100
100

z
:
S
S
S
5
S

:
T
:
T
S
T
:
S
T
T

Amll?olm
Hydroxide.
Borlum
Hydrwde
Coiclum
Hydronde
POtorrlm
Hydronde
Sodium
Hydrcwde

10
o-30

S
S

S
T

10

o-50

O-50
O-10
o-50

S
S
5

T
S
T

20
SAT
011
3
011

S
S
5
S
5

S
S
S
5
T

15

T
S
S
S
S

Mlscelioneous
COlCllV
Hypochlonte*
Chlorine Water
Chlorine Dmxlde
Hydrogen
Peroxade
Sodturn
Hypothl?r,te
Underaround
Wafer-D,rtilled
M,ne Wo1err
Se0 Water
Coohng Tower
Water
Metal Plotmg
Solt~oni
P,cklmg
Soltlonr
Metal Plotlng
Solutlonr
Phorphow
Oxychlonde
Phosphorur
Trichlcrgde
Plrkling
Solvt,ons
Strlpplng
SOltlOr
Petroleum Ether
Moune
Atmosphere
Hum,d,ty, 100%
Chlonter
Cyclohexone
Coprylic Acid
Polrmtic
Ethyl Acetate
Cool Dust. moist
lodrne Vopar
Nut 0~1s
Olw? Ollr
Weed Killers,
organic
Fung,c,dei
organic
Insect,c,del,
orgon,c
Anthrocene 011
Sulfur, wenoble
DDT

S
S
S
5

(acid)

(ocvd)

011

011

(olkollne)

S
S
S
S

_
_

(olkollnei

:
S

:
:
T
S

LEGEND
S = Sof,sloctory

w,th expected long and econom,c 1116

T = Tests suggested. Under some conditions


materials moy not be sultoble.
U:

Unrotirfoctory

for continuous service.

TABLE

1.17:

FLUOROPOLYMER-ALLIED

ENGINEERED

PLASTICS

HALAR
ECTFE is a melt processable
fluoropolymer
from Allied Corporation.
It possesses a unique combination
of properties
as a result of its chemical structure-a
1: 1 alternating
copolymer
of ethylene
and chlorotrifluoroethylene.
HALAR
fluoropolymer
offers excellent
chemical resistance, good electrical properties,
broad use temperature
range-from
cryogenic
to 34OF, and meets the requirements
of the UL-94 V-O vertical flame test in thicknesses
as low as 7 mils. It is a
tough material with excellent
impact strength
over its broad use temperature
range. HALAR
ECTFE also maintains
useful properties
on exposure to cobalt 60
radiation
at dosages of 200 megarads. It is one of the best fluoropolymers
for abrasion resistance. HALAR
fluoropolymer
is a thermoplastic
which can be processed by virtually
any technique
applicable
with polyethylene.
It can be extruded,
injection
molded, blow molded, rotomolded,
and applied by ordinary
fluidized
bed or electrostatic
coating techniques.
It is available in a range of viscosity grades for extrusion
and molding applications.
HALAR
ECTFE powders are available
in three different
particle sizes optimized
for specific coating processes.
HXARB

ECTFE

R - Recommended
NR - Not Reco,'m,ended
-- _ NO Avalla~la Data

CHEMICAL RESiSTANCE

Chemical
Acetic Acid, 10%
Acetic Acid, 20%
Acetic Acid, 50%
Acetic Acid, 80%
Acetic Acid, Glacial
~
Acetic Anhydride
Acetone
Acetyl Chloride
Acetylene
Acetyl Nitrile
Acrylonltrile
Adipic 105 Acid
Alcohol, Amy1
Alcohol, Benzyl
Alcohol, Butyl, Primary
Alcohol, Butyl, secondary
Alcohol, Diacetone
Alcohol, Ethyl
Alcohol, Hexyl
Alcohol, Isopropyl
Alcohol, Methyl
Alcohol, Propyl
Ally1 Chloride
Alum
Alum, Ammonium
Alum, Chrome
Alum, Potassium
Aluminum Chloride
Aluminum Fluoride
Alurcu~um Hydroxide
Aluminum Nitrate
Aluminum Oxychloride
Aluminum Sulfate
Ammonia, Gas
Ammonia, Aqua, 10%
AmmonilnnAcetate
Ammonium Bifluoside
Ammonium Bisulfide

73OF
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

Temperature
15O'F
250'f
--R
R
R
R
R
-_
R
R
R
R
__
R
R
R
R
R
R
R
_R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
--__
NR
-_
__
_-_R
R
R
R
NR
R
-R
R
R
R
R
R
-R
R
R
R
R
__
R
R
R
__
R
R

Chen;cal

3OO'F

__
___
-_
-__
NR
___
_-_R
R
R
R
NR
R
_R
R
R
R
R
R
-R
R
R
R
R
__
R
R
-__
R
R

73F
---

Ammonium Carbonate
Armnonium Chloride
Ammonium Dichromate
Ammonium Fluoride, 10%
Ammonium Fluoride, 25%
Ammonium Hydroxide
Ammonium Metaphosphate
ArmnoniumNitrate
Ammonium Persulphate
Ammonium Phosphate
Anlmonlum Sulfate
Ammonium Sulfide
Pmyl Acetate
Amy1 Chloride
Aniline
Anthraquinone
Anthraqulnone Sulfonic Acid
Antimony Trichloride
Aqua Regia
Arsenic Acid

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

Barium
Barium
Barium
Barium
Barium

R
R
R
R
R
R
R
R
R
R
R
R
R
R

Barium

Carbcnate
Chloride
Hydroxide
Nitrate
Sulfate
Sulfide

Bt?WZ
Beet Sugar Liquors
Benzaldehyde, 10%
Benzaldehyde, Above 10%
Benzene, Benz01
Benzene Sulfonic Acid, 10%
Benzoic Acid
Bismuth Carbonate
Black Liquor
Bleach, 12.5% Active Cl2
Bleach, 5.5% Active Cl2

R
R

Temperature
150F
250F

XF

R
__

R
-_

R
R
R
R
R
__
R
R
R
NR
R
NR
_--R
R

R
R
R
R
R
-R
R
R
NR
R
NR
___
-_
-_
R

R
R
R
-_
R
R
_-NR
NR
NR
NR
R
__
R
R
R

R
R
R

_-

R
R
R
R
R
R
R
R
R
R

R
NR
R
R
__
R
R
R
R
R
-R

R
R
R
R
NR
R
R
R
-R
R
R

R
R
___
NR
NR
NR
NR
--_
R
R
R

(continued)

s
7
g
5

$
v)
5
$
q
h.
fi
x
$

TABLE 1.17:

FLUOROPOLYMER-ALLIED

Chemical

ENGINEERED

73OF
__---

Temperature
150F
250'F

BOrZlX
Boric Acid
Brine, Acid
Bromic Acid
Bromine, Liqud
Bromine, Vapor 25%
Bromine, Water
Bromobenzene
Bromotoluene
Butadiene
BUtme
Butyl Acetate
Butyl Alcohol
Butyl Cellosolve
Butylene
Butyl Phenol
Butyl Stearate
Butyrx Acid

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
NR
R
R
R
R
R
-_
R
R
__
R

R
R
R
R
_NR
R
NR
NR
R
R'
NR
R
_R
R
_R

Cadmium Cyanide
Calcium Bisulfide
Calcium BisulfitC
Calcium Carbonate
Calcium Chlorate
Calcium Chloride
Calcium Hydroxide
Calcium Hypochlorite
Calcium NItrate
Calcium Oxide
ca1c1um Sulfate
cane Sugar Liquors
Caprylic Acid
Carbon Dioxide, Wet
Carbon Dioxide, Dry
Carbon Disulfide
Carbon Monoxide
Carbon Tetrachloride
Carbonic Acid
Castor Oil
Caustic Potash
Cellosolve
Cellosolve Acetate
Chloracetic Acid
Chloral Hydrate
Chloramine
Chlorine Gas, Dry
Chlorne Gas, Wet
Chlorine, Liquid
Chlorine Water, Saturated
Chloracetic Acid
Chlorobenzene

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
-R
R
R
R
R
R
-R
R
-_
R
R
R
R
R
R

-_
R
R
R
R
R
R
R
R
R
R
-_R
R
-__
R
R
R
R
R
-R
__
-_
NR
R
R
R
R
NR

PLASTICS
300F
R

R
R

NR

NR
NR

NR
R

__
R
R

R
R
R
R
R
R
R
R

R
R

-NR

NR

(continued)

73'F

Temperature
150F
25O'F
--

Chlorobenzyl Chloride
Chloroform
Chlorosulfonic Acid
Chromic Acid, 10%
Chromic Acid, 30%
Chromic Acid, 40%
Chromic Acid, 50%
Citric Acid
coconut 011
Coke Cven Gas
Copper Carbonate
Copper Chloride
Copper Cyanide
Copper Fluoride
Copper Nitrate
Copper Sulfate
Corn syrup
Cottonseed Oil
creso1
Cresylic Acid, 50%
Croton Aldehyde
Crude Oil
Cupric Fluoride
Cupric sulfate
Cuprous Chloride
Cyclohexane
Cyclohexanol
Cyclohexanone

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

NR
R
_R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
NR
R
R
R
R
R
R
NR

NR
R
_R
R
R
R
R
R
R
_R
R
R
R
R
R
R
NR
NR
NR
R
R
R
R
R
NR
NR

Detergents
Detergent Solution (Heavy Duty)
Dextrln
Dextrose
Dichlorobenzene
Dlchoroethylene
Diesel Fuels
Diethylamine
Diethyl Cellosolve
Diethyl Ether
Diglycolic Acid
Dimethylamine
Dimethyl Hydrazine
Dioctyl Phthalate
Dioxane
Dioxane,1.4
Disodium Phosphate
Divinylbenzene

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
NR
NR
R
NR
R
--NR
NR
NR
R
R
R
NR

R
R
R
R
NR
NR
R
NR
R
--NR
NR

Epsom Salt
Ethyl Acetate
Ethyl Acetoacetate

R
R
R

R
R
_-

Chemical

NR
NR
NR
R
--

XF
NR
_-_____
R
R
__
_R
R
R
R
R
R
R
NR
NR
NR
R
R
R
R
NR
NR
R
R

NR

NR
R
NR
R
-_NR
NR
NR
NR
NR
R
--

3
"s
9
w.
4
2
5
D
"s
Q

_-_

(continued)

R
--_

TABLE 1.17:

FLUOROPOLYMER-ALLIED

ENGINEERED

PLASTICS

(continued)

lkmperarure
Chemical

73'F
--

150F

250F

TWperatUIe
3OOF

R
R
__
R
R
R
NR
NR
NR
R
R

NR
R
__
__
R
R
NR
NR
R
R

NR
R
__
__
R
R
NR
NR
NR
R
R

R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
__
-R
R
R
-R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
_-_
R
___R
R
__
-_
__
__
_---

R
R
R
R
R
11
R
-_R
-_
__
_-_
--_--__
_-_

R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R

__
R
R
R
R
R
R
R
R
--

_R
R
R
R
-_
R
R
R
--

Ethyl Acrylate
Ethyl Chloride
Ethyl Chloroacetate
Ethyl Ether
Ethylene Bromide
Ethylene Chloride
Ethylene Chlorohydrin
Ethylene Diamine
Ethylene Dichloride
Ethylene Glycol
Ethylene Oxide

Fatty Acids
Ferric Chloride
Ferric Nitrate
Ferric Sulfate
Ferrous Chloride
Ferrous Nitrate
Ferrous Sulfate
Fluorine Gas, Wet
Fluoboric Acid
Fluoslliclc And
Formaldehyde, 35%
Formaldehyde, 37%
Formaldehyde, 50%
Formic Acid
Fornnc Acid (Anhydrous)
Freon F-11
Freon F-12
Freon F-21
Freon F-22
Freon F-113
Freon F-114
Fruit Juices, Pulp

Gallic Acid
Gas, Natural
Gasoline, Leaded
Gasoline, Unleaded
Gasoline, Sour
Gelatin
Gin
GlUCOSZ
Glycerine, Glycerol
Glycolic Acid

R
R

R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R

NR

Chenlcal

73'F

150F
--

25OOF

3ooF

Glycols

Fkptane
Hexale
Hydrobromic Acid, 20%
Hydrobromlc Acid, 50%
Hydrochloric Acid, Cone 37%
Hydrocyanlc Acid
Hydrocyanuz Acid, 10%
Hydrofluoric Acid Dilute
Hydrofluoric Acid, 30%
Hydrofluoric Acid, 40%
Hydrofluoric Acid, 50%
Hydrofluosiliclc Acid
Hydrogen
Hydrogen Cyanide
Hydrogen Peroxide
Hydrogen Peroxide, 50%
Hydrogen Peroxide, 90%
Hydrogen Phosphlde
Hydrogen Sulfide, Dry
Hydrogen Sulfide, Aqueous Sol.
Hydroquinone
Hypochlorous Acid

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
R
-_
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
R
--_-R
_R
R

R
R
R
R
R
R
R
R
---R
R
R
---_
-R
-_
-_
R

Iodine
Iodine Solution, 10%
Isopropyl Ether
1sooctane

R
R
R
R

R
R
-_
__

R
R
___

---_
--

Jet Fuel, Jl'-4


Jet Fuel, JP-5

R
R

R
R

R
R

R
R

R
R
R
R
R
R
R
R
R

R
__
R
R
R
R
R
R
R

--R
R
R
R
R
R
R

__
__
R

Lactic Acid, 25%


Lactic Acid, 80%
Lard Oil
Laurie Acid
Lauryl Chloride
Lead Acetate
Lead Chloride
Lead Nitrate
Lead Sulfate

-_
R
R
R
R

(continued)

TABLE

1.17:

FLUOROPOLYMER-ALLIED

ENGINEERED

PLASTICS

!continued)
Ten-eratce

Chemical

Lemon Oil
Lime Sulfur
Linoleic Acid
Llnoleic Oil
Linseed Oil
Linseed Oil, Blue
Lithium Bromide
Lubrlcatinq 011, ASTM #1
Lutxicatinq 011, ASTM #2
Lubrlcatlnq 011, ASTM #3

73'F
--

15O'F

2SOOF

_)L-*

--

_-

__-

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R
R
-_
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
_NR
R
R
R
NR
NR
NR
_R
-NR
NR
NR
R
R
__
R

R
R
R
R
R
_--_
_--_
R
__
-NR
R
R
R
NR
NR
NR
-_
R
_NR
NR
NR
-R
-_
R

Maqneslum Carbonate
Maqneslun Chloride
Maqneslum Hydroxide
Magnesium Nitrate
Maqneslum Sulfate
Malelc Acid
Mallc Acid
Mercuric Chloride
Mercuric Cyanide
Mercuric Sulfate
Mercurous Nitrate
Mercury
Methane
Methoxyethyl Oleate
Methylamine
Methyl Bromide
Methyl Cellosolve
Methyl Chloride
Methyl Chloroform
Methyl Ethyl Ketone
Methyl Isobutyl Ketone
Methyl Methacrylate
Methyl Sulfate
Methyl Sulfuric Acid
Methylene Bromide
Methylene Chloride
Methylene Iodine
Milk
Mineral Oil
Molasses
Motor Oil

R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
-NR
R
R
R
R
R
R
_R
R
NR
NR
NR
R
R
R
R

Naphtha

R
R
R
R
R
R

R
R
R
R
R
R
R

R
R
R
R

R
R

R
R
R

_-__-

R
R
R

Chemical
Naphthalene
Natural Gas
Nickel Acetate
Nickel Chloride
Nickel Nztrate
Nickel Sulfate
Nicotine
Nlcotinic Acid
Nitric Aad, 10%
Nitric Acid, 30%
Nitrx And, 40%
Nitric Acid, 50%
Nitric Acid, 70%
Nltrlc Acid, 100%
Nitrobenzene
Nitrous Aad, 10%
Nitrous Oxide

73OF
__---

15O'F

25O'F

31)0OF

__
__-_

R
__
R
R
R
R
R
R
R
R
R
R
R
R
R
--

R
R
R
-R
R
R
R
NR
NR
NR
NR
R
--

R
R
R
__R
-_
-NR
NR
NR
NR
-_

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

__
--

Oils, Vegetable
Oleic Acid
0lelL-J
Oxalic Acid
Oxalic Aad, 50%
Oxygen, Gas
OZOIUZ

R
R
R
R
R
R

R
R
NR
R
R
R
R

R
R
NR
NR
NR
R
R

R
__
NR
NR
NR
R
R

Palmit-c Acid
Palmitlc Acid, 10%
Parhfflrl
Perchlorlc Acid, 10%
Perchlorlc Acid, 70%
Pa-phosphate
Petroleum Oils, Sour
Petroleum 011s. Refined
Phenol
Phenyl hydrazine
Phosphoric Acid, 10%
Phosphoric Acid, 50%
Phosphoric Acid, 85%
Phosphorus Yellow
Phosphorus Pentoxlde
Phosphorus Trlchloride
Photographic Solutions

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
-R
R
R
-R
R
R
_R
R
R

R
R
_-

___
_-

_-

--

NR
__
R
R
R
_R
R
-_

NR
_R
---_
-_
-_
-_

(continued)

TABLE 1.17:

FLUOROPOLYMER-ALLIED

Chemical

Plcric Acld
Plating Solutions, Brass
Plating Solutions, Cadmium
Plating Solutions, ChrCJUE
Plating Solutions, copper
Plating Solutions, Gold
Platrng Solutions, Lead
Plating Solutions, Nickel
Plating Solutions. Rhodium
Plating Solutions, Silver
Plating Solutions, Tin
Plating Solutions, zulc
Potash
Potassium Alum
Potassium Alur;inun Sulfate
Potassium Bichromate
Potassium Blsulfate
Potassium Berate
Potassium Bromide
Potassium Carbonate
Potassium Chlorate Aqueous
Potassium Chloride
Potassium Chromate
Potassium Chlorate
Potassium Cyanide
Potassium Dichr9mate
Potassium Ferricyanlde
Potasslun Ferrocyanide
Potassium Hydronde
Potassium Iodide
Potassium Nitrate
Potassium Pa-chlorate
Potassium Permanganate, 10%
Potassium Pennanganate, 25%
Potassium Persulfate
Potassium Sulfate
Propane
Propylene Oxide
Pyrldine
Pyrogallic. Acld
Salicylic Acid
Salicylaldehyde
Silxlc Acid

ENGINEERED
72F
I?

__

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
NR
NR
R

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
-R
R
R
R
R
NR
NR
R

R
R
R

R
NR
--

II
R

PLASTICS

Temperature
,=,oc
250F
--

330'F

__
-___
___
__
_--i_
--

-_
--

R
R
R
R
R
-R
R
R
R
R
R
R
R
R
R
-R
R
_R
R
-_
R
R
NR
NR
--

R
R
R
-_

_NR
-_

(continued)

-_

Chemical
Silicone Oil
Silver Cyanide
Silver Nitrate
Silver Sulfate
SOSPS

-_

__
R
R
R
R

R
R
R
R
R
R
__
-_
R
-_
R
R
-R
R
NR
NR

NR

Sodian Acetate
Sodium Alum
Sodium Benzoate
Sodium Bicarbonate
Sodium Bichromate
Sodium Bisulfate
Sodium Sisulfite
Sodium Bromide
Sodium Carbonate
Sodium Chlorate
Sodium Chloride
Sodium Cyanide
Sodium Dichromatc
Sodlun Fluoride
Sodiu Hydrande, 15%
Sodium Hydroxide, 30%
Sodium Hydroxide, 50%
Sodium Hydroxide, 70%
Sodium Hypochlorite
Sodium Iodide
Sodium Metaphosphate
Sodium Nitrate
Sodium Nitrite
Sodium Perchlorate
Sodium Peroxide
Sodium Phosphate, Alkaline
Sodium Phosphate, Acid
Sodium Phosphate, Neutral
Sodium Silicate
Sodium Sulfate
Sodium Sulfide
Sodium Sulfite
Sodium Thiosulfate
Sour Crude 011
Stannlc Chloride
Stanncus Chloride
Starch
Stearic Acid
Stoddard's Solvent

73F
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

__

__

--

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
__
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
_R
R
R
R
-R
R
R
R
R
R
R
__
R
R
R
R
-R
-R
R
R
-R
R
R
R
R
R
R
R
R
R
R
R
-_R

R
R
__
_R
R
R
R
_R
R
R
R
R
R
R
-R
R
-_
-_
-R
-R
R
R
-_
R
R
R
R
R
R
R
R
R
R
R
R
_-_
R

(continued)

TABLE 1.17:

FLUOROPOLYMER-ALLIED

ENGINEERED

PLASTICS

(continued)

Terneratme
Chemical

73'F
----

15O'F

250'F

303'F

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
___
R
-_
R
R
R
R
R
R
R
R
R
R
R
R
R
R
-_
R

R
__
_R
__
R
-R
R
R'
R
R
R
--_
__
-_
-_
-__
R

__
-_
___
--_-_
___
__
__
-_
__-__
--_
-_
__

R
R
R
R
R
R
NR
KR
R
R
R
R

R
R
R
R
R
R
NR
NR
R
R
R
R

R
R
R
R
R
R
NR
NR
-R
NR
R

R
-_
-R
__
R
NR
NR
_R
NR
__

Succinic Acid
sulfate Liquors
Sulfite Liquor
Sulfur
Sulfur Chloride
Sulfur Dioxide, Dry
Sulfur Dioxide, Wet
Sulfuric Acid, 10%
Sulfuric Acld, 30%
Sulfuric Acid, 50%
Sulfuric Acid, 60%
Sulfuric Acid, 70%
Sulfuric Acid, 80%
Sulfuric Aad, 90%
Sulfuric Acid, 93%
Sulfuric Acid, 94%
Sulfuric Acid, 95%
Sulfuric Acid, 96%
Sulfuric Acid, 98%
Sulfuric Acld, 100%
Sulfurous Acid

Tall Oil
Tannic Acid
Tanning LiqUOrS
TX
Tartaric Acid
Tetraethyl Lead
Tetrahydrodurane
Tetrahydrofuran
Thlonyl Chloride
Thread Cutting Oils
Toluene, Toluol
Tomato Juice

Chemical

73F
_~____

Transformer 011
Transformer Oil DTE/30
Tributyl Phosphate
Trlchloroacetic Acid
Trichloroethylene
Triethanolamlne
Trlethylamine
Triosodlum Phosphate
Turpentine

Temperature
250F
150F

300F

---

R
R
NR
R
R
NR
R
R
R

R
_NR
NR
R
NR
NR
R
R

NR
R
R

NR
NR
R
NR

Urine

R
R

R
R

R
--

__
__

vase11ne
VUlegar
Vinegar, White
Vinyl Acetate

R
R
R
R

R
R
R
R

-_
R
R
R

-__
_--

water
water, Acid Mine
water, Demineralized
water, Distilled or Fresh
water, Salt
water, sea
water, sewage
Whiskey
White Liquor
WlilES

R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R

xy1ene (xylol~

--

--

Zinc Chloride
Zinc Nitrate
Zinc Sulfate

R
R
R

R
R
R

R
R
R

R
R
R

X-E!.3

Corrosion

60

TABLE

1.18:

Resistant

FURAN

Materials

RESIN-KOCH

Handbook

ENGINEERING,

CHEMICAL

RESISTANCE
Meaning

E-Excellent

r&stance;

all concentrations

Ga

uitable for general


an d temperatures.

MAURICE

service -

resistance; suitable for most servicesconcentrations


and temperatures to 2 12 F.

most

A. KNIGHT

DIVISION

OF PERMANITE

of Symbols

F-Fair
resistance; suitable for some services-dilute
concentrations
and temperatures
to 90F.
NR-Not
recommended
for this service under most
conditions.

Resistance
Chemicd
Resistance
Chemical
Chemical
Rerirtrnce
......
E Coconut Oil
Acetic Acid (to 85%)
.......
...
E Nitric Acid
,.. ,,.... NR
G Copper Cyanide
Acetic Acid, Glacial ...............
........
E Oleic Acid
E
..........
G Copper Sulfate ..............
Acetic Anhydride
E Oxalic Acid
.
...E
I.....................................
.
Acetaldehyde
.................
......
E Paraffin
.._ ..,.,.
E
Corn Oil
E Cottonseed Oil
Acetone
...............................................................
................
E Petroleum
Erher
.,.,,....... E
.E Cresylic Acid ...........
Aluminum Chloride ......................................
...... .... NR Phenol
,.,.,........... E
E Cupric Chloride
Aluminum Sulfate ...
...... ....... E Phosphoric Acid (to 7% cone.)
E
Ammonium Bromide ........ .._......_........ E Dibutyl Phthalate
...... ........
.. .:....
E Phosphoric Acid (70 to
E Ethyl Acetate .............. ................. E
85% cont.)
_ G
Ammonium Carbonate ........
Bisulfate
E
.................
.I.........E Ethyl Alcohol
Ammonium
Chloride
E Potassium
............ ......................
E
E Eth;l Ether
Amnionium
Fluoride ...................
E Potassium Carbonate
______...._._____~
._.........E Potassium Chloride
E
.................... E Ethylene Dichl&i&
Ammonium
Hydroxide
Ammonium Nitrate .... .._...................... E Ferric Acid Salts (to 45% cont. )
E Potassium Hydroxide
EE
...................
... E Ferric Salts ....... .................................
Ammonium
Phosphate
E Potassium Iodide
E
Ammonium
Sulfate ........................ E Ferrous Salts ....................
.E Potassium .Sulfate
.
.
.
.._________...__._........................
F
Pyridine
E Formaldehyde
Amy1 Acetate ........................................................
................. ... ..... ..... E Pyridine Sulfate __._.._._____.._.___...........
G
................................ F Formic Acid ..........
Aniline
___......_....._..._
E Sodium Bicarbonate
E
E Sodium Bisulfate
......................... G Fuel Oil .................
Aniline Hydrochloride
E
Furfural
_._..._
.....___________
::....:I................... . Sodium Carbonate
NR
Aqua Regia .......................................................
.E
E Furfuryl Alcohol .................................... E Sodium Chloride
Barium Chloride ..............................................
E
..........................................
.E Gasoline ...................
Barium Hydroxide
...........E Sodium Chlorite, Acid Soln.
I
_...E Glycerine
Beer ..........................................................................
.................E Sodium Hydroxide
..........
E Hydrobromic
Benzene ........................................................................
E Sodium Hypochlorite
Acid .................................
E
E Hydrochloric
Benzene, Monochlor ......................................
.E Sodium Iodide
Acid .................................
Sodium Sulfate
E
......................................
.E
Ben-e,
o-Dichlor
Hydrofluoric
Acid (to 50% cont.)
E Sodium Sulfide ,...,..
E
....................
.E Hydrofluoric Acid (50 to
Benxene, 1, 2, &Trichlor
Sodium Sulfite
,.
E
G Sodium Thiosulfate
70% cont.) ....................................................
E
Benxoyl Chloride .................. ...................
E
E Stearic Acid
Acid ....................................
G Hydrofluosilicic
Benzyl Alcohol ...................................................
E
E Hydrogen Peroxide (to 3% cont.) ... F Sulfur Monochloride
E
Borax ............................................................................
Sulfuric Acid (to 5096 cont.)
E
.
Boric Acid ...............................................................
Hydrogen Peroxide (over
G
....................................... NR Sulfuric Acid ( 50 to 60% cont.)
3% cont.)
.NR
Bromine ...............................................................
F
E Sulfuric Acid (over 60% cont.)
Sulfide ..........................................
G Hydrogen
Bromine Water .................................................
,,
E
NR Sulfurous Acid
...E Iodine ... ..................................................................
Butyl Alcohol ...................................
.,,....
E
E Tannic Acid
Isoamyl Alcohol ..............................................
.
Calcium Bisulfite ...............................................
E
E Tartaric Acid
Alcohol ..........................................
..........E Isopropyl
Calcium Chloride ..................................
Tin Chloride
..,................
E
E Trichlorethylene
..................................................................
_.............................
E Kerosene
Calcium Hydroxide ..............
__........_..._.._.................E
E Trisodium Phosphate
.................
.....................................
P lactic Acid .............................................
Calcium Hypochlorite
E
E Toluene
E Lead Acetate ........................................................
Carbon Bisulfide .................................................
.,,
E
E
..
_.
.....
Magnesium
Chloride
.......................
E
....... ......... ............E
Carbon Tetrachloride
Turpentine
E Vegetable Oils
..,..
,._....
.._....
E
.........................
E Magnesium Sulfate ......................................
Castor Oil ..................................
E
.,
.E Vinegar
.................................................
G Maleic Acid ............................................................
Chlorine
(dry)
E
E Water. Distilled
G Manganese Sulfate .............................................
Chlorine
(wet) ................................................
.
.._...............
E
E Water, Salt
..............................................
Chlorine Water .........................................G Methyl Alcohol
,_......... .
.
_E
S ,Wine
.........................................
E Methyl Ethyl Ketone .....................................
Chloroform
Whiskey ...................................
......................
E
E
Xylene
Mineral
Oils
...........................................................
................................
P
Chromic Acid (dilute)
...... ..................................
......................
E z.mc Chloride
Nickel Chloride ......................................
..............
........NR
Chromic Acid (concentrated)
...................
E
..............................
......E 2rnc Sulfate ............................................ E
E Nickel Sulfate .................................................
Citric Acid ....._...........................................................

Synthetic

TABLE

1.19:

ISOPOLYESTER

RESINS-AMOCO

Resins and Polymers

61

CHEMICALS

Corrosion
resistant
isopolyesters
are characterized
among resin suppliers
and users by the molar ratio of the aromatic to the unsaturated
acid and by the glycol used in synthesis.
In this nomenclature,
Amocos
recommendation
for a cost-effective
resin with outstanding
corrosion
resistance to a broad range of liquids over a wide temperature
range is a 1 : 1 propylene
glycol isopolyester.
That is, the resin is made with equal molar amounts of maleic anhydride
and isophthalic
acid and reacted with a sufficient
excess of propylene
glycol to ensure esterification
to a high molecular weight.
While the basic
basic formulation
three laboratory
The resin
stability.
than the
desirable

corrosion
suitable
variations

resistant
resin offers the most versatile
range of resistance properties,
variations
of the
for specific applications
are available from many resin suppliers. The second table shows
of the recommended
formulation.

with higher levels of maleic anhydride


has greater crosslink density and thus offers very good temperature
It should maintain
mechanical
properties
up to 100C. It also shows better resistance to aromatic
solvents
basic formulation,
although
its resistance to mineral acids is not quite as good. Its brittleness
may be unin some applications.

Adipic
acid improves
flexibility
formulations
is not as consistent
lowers resistance properties.

and neopentyl
glycol improves caustic resistance, The gasoline resistance of these
as that of the other formulations
shown in the second table. Adipic acid generally

Chemical

resistance
Temperature,

Medium

93
71

NaCl

Saturated

Distilled

H,O

of laboratory
C

synthesized

Composite

resin*

Rating

Applications
Marine,

Acceptable

bnne

Excellent

71

Excellent

49

Acceptable

Pipe, water

handling

10% Na,CO,

49

Excellent

25%

93

Acceptable

Chemical

5% HCI

71
71

Good
Excellent

Chemical

15% HCI

71

Excellent

Descaler

handltng

15% H,PO,

49
71

Good
Good

Fertilrzer,

food handling

71

Good

Chemical
Chemical

handlrng
handling

71

Acceptable

Food storage,

71

Acceptable

Food processing,

pH, Soil Slurry

38

Excellent

Burial conditions

pHlo Soil Slurry

38

Good

1N NH,OH
2% NaOH

38
23

Acceptable*
Good

5% NaOH

23

Complete

38% Urea
100% Household

49

Acceptable

49

Excellent
Excellent

H,SO,

85% H,PO,
5% HNO,
25%

Acetic

Vinegar

Acrd

(5% Acetic

Saturated

Acid)

Bleach

Alum

100% Corn Syrup


50% Citric Acid
50% EtOH
50% 34-5-5 Fertilizer
Lead Free Regular
50%
75%

Toluene/50%
Toluenel25%

In Water

Propylene

Blistering

glycol

rsopolyester

Failure
Fertrlizers

Excellent

Food handling

71
49

Good
Acceptable

Food, beverage
Fertilizer

23

Excellent

Gasoline

23

Good

Petroleum

23

Good

23

Good

lsooctane

cooked

handling

Chemical

Excellent

lsooctane

handling

Fertilizers

71

Gas

was apparent.

handling

49
71

Benzene
1:l

storage

to less than 15 acid number

Food handling

storage
storage

Chemical
ASTM

C581, one year rmmersron.


(continued)

62

Corrosion

TABLE

Resistant

Materials

ISOPOLYESTER

1.19:

Handbook

RESINS-AMOCO

Resin formulations
Isophthalic/Maleic
Adipic

Acid,

Ratio,

for corrosion

resistant

Properties

% Elongation
Heat Distortion

Temp.,

ASTM

Strength,

IOpsi

(MPa)

Flexural

Modulus,

106psi

(MPa)

1 .3

2.4

132

105

2.7
103

14.8

19.5 (134)
1.074

(7400)

0.887

56

Hardness
Corrosion

Distilled

45

C581

Flexural

Water

5% HNO,at

neopentyl

45

1 .6

Properties,

0.3

neopentyl

45

116

0.7:1

1 :l
-

propylene

45

% Styrene
Clear Casting

performance

1 :2
-

propylene

Laminate

(continued)

1 :l
-

Moles

Moles

Glycol

Barcol

CHEMICALS

at 71 C

71 C

17.6 (121)

(102)
(6110)

0.843

53

Resistance,

Composite

ratings

18.6 (128)

(5810)

0.795

from

(5480)
53

50
one year data

excellent

excellent

excel lent

unacceptable

good

good

excel lent

good

5% HCI at 71 C

excellent

excellent

good

unacceptable

25% H,SO, at 71 C

excellent

acceptable
complete
failure

excel lent

good

5% NaOH at 71 C

complete

unacceptable

unacceptable

#2 Fuel Oil at 23C

excellent

excellent

excel lent

excellent

Ethyl Gasoline

excellent

excellent

excel lent

unacceptable

excellent

excellent

unacceptable

excellent

good

excellent

unacceptable

unacceptable

Unleaded

at 23C

Regular

Benzene

at 23C

at 23C

A partial

list of materials

handled

failure

and stored

in corrosion

resistant

isopolyesters

Acetic

Acid

Gasoline

Premium

Acidic

Fumes

GI\,cols

Salt Solution

Grain

Sa It Spray

Grapes

Seawater

HCI Solutions

Sewage

Hs (NH.)
H NO,

Soap Curd

Ammonia
Beer

Hydrogen

Brine

H,SO, Solutions

Soybean

H, PO.

Sugar Solution

Acrylic

Emulsions

Agricultural

Chemicals

Alcohols
Alum

Cheese
Chlorine

Dioxide

Chlorinated
Coconut
Crude

Oil
Oil

Fatty Acids
Ferric

Chloride

Solutions

Oil

Oil
Dioxide

Vegetable

Oils

Vinegar

Milk
Monomeric

H,O

Sour Crude

Sulphur
Solution

Meat

Oil

Distilled

Soil
Sulfide

Lye
Manganese

Lye

Cod-Liver

PO,

Gasoline

Vinyl
Plasticizers

Water

Acetate
Treatment

(NH.)z SO,

Wet Gases from

(NH,)
Pasta

Whey

Fertilizers

Peanut

Fruit Juices

Pickles

Fuel Oil

Potable

NO,
Oil

Copper

Smelting

Wine
Zinc Chloride

H,O

Chemicals

Synthetic

TABLE 1.20:

NYLON

6/6 RESINS-CELANESE

Resins and Polymers

PLASTICS

1000
series nylons are of the 6/6 type polyamides.
They are used in the replacement
weight,
corrosion
resistance,
self-extinguishing
properties,
self-lubricating
qualities
and
lower cost.

CELANESE
reduced
stantially

Chemical

Resistance

Of Cklanese

Acetaldehyde.
Acetamrde.
Acetrc acid,

A/B

Acetone,

offering
at sub-

& 1003

Dimethyl formamide,
Dioctyl phthalate.
Droxane.

D
A

[h;;o;ats

Ally1 chlorrde.
Alummum chloride,
Aluminum sulfate,

gaseous,

Ammonrum~carbonate.
Ammonrum chloride,
Amvl acetate.

Aniirne.
Antrmony trichloride,
Asprrin.

Barium chloride,
Barium sulfide,
Benzaldehyde.
Benzene,
Benzene sulfonic acid,
Benzoic acid,
Bdumen.
Bleaching lye,
Boric acid,
Boron trifluoride.
Bromine,
Bromine water,
Butanol.
Butvl acetate.
Butilene glycol.
acid,

Calcium chloride,
Calcium chloride in alcohol,
Calcium hypochlorite.
Camphor,
Carbon disulfide,
Carbon tetrachloride,
Carbontc acid
Chloracetic acid,
Chloral hydrate,
Chlorine,
Chlorine water,
Chlorobenzene,
Chloroform,
Chlorosulfonic
acid,
Chromic acid,
Citric acid,
Creosote,
Cresols.
Cresylic acids,
Cupric chloride,
Cupric sulfate,
Cyclohexane,
Cyclohexanol,
Cyclohexanone.
Decalin,
Detergents,
Dibutyl ohthalate.
Drchlordrfluoromethane,
Dresel 011.
Drethylene glycol,
Dimethvl carbinol.

10%
10%

Ferric chloride,
Ferrous chloride,
Ferrous sulfate,
Fluorrne.
Fluorosilrcic acid,
Fluothane,
Formaldehyde,
Formic acrd.

1009;
100%
10%

10%

10%
100%
100%

10%
lo&&

Heptane,
Hexane.
Hydrobromic
Hydrochloric

30%
100%
100%
100%
20%
20%

Iodine
Iodine

100%
10%
10%

1OFh
100%
lo-100%
1%
10%
10%

9Gh
-

Mixture

::
B/C
D
B/C
A

100%
-

:
A

1OFh
100%
-

A:B
A/B
AIB
A/B
BBC
;

80:2Gj
-

:
AD
A
A
;
A/B

;
acid,
acid,

10%
2%
10%
4%
0.5%
3%
Saturated
-

CD
:
Bl?
A/B
A

in alcohol,

in KI solution.
Iso.octane,

10%

A;B

A0

Hydrogen sulftde,
Hydroquinone,

100%

960/,

100%

400/,
3%
10%
-

Hydrofluoric
acid,
Hydrogen peroxide,

10%

;
A

10%
10%
10%
10Yo

Fruit juices,
Gasoline
Gasolrne/Benzene
Glycerine,
E/;:;ol.

Saturated

lOC%
-

and oils,

Ether,
Ethyl acetate,
Ethyl butyrate.
Ethylene chlorhydrin,
Ethylene chlorrde.
Ethylene dramine.
Ethylene dichloride.
Ethylene glycol,

Alcohol, benzyl,
Alcohol, phenyl ethyl,

Butyric

1000

aliphatic.

Ammonia,
Ammonra.

Nylons

of metals,
colorability

EFFECT

CHEMICAL

Alcohols,

63

GJ
-

i!
A

Lactic acid,
Lead acetate.
Lead stearate.
Linseed oil,

10%
10%
-

BgC

Magnesium chloride,
Magnesium hydroxide,
Magnesrum sulfate,
Manganese sulfate,
Mercuric chloride,
Mercury,
Methanol,
Methyl acetate,
Methyl ethyl ketone,
Methylene chloride,
Mrlk,
Mrneral oils.

10%
-

1osj
100%
100%
100%
-

:
:
AC
A/B
:
AC
A

Naphthalene.
Nickel sulfate,
Nitrrc acid,
Nitro-alcohols.
Nitrobenzene.
011s of vegetables
Olerc acid,

10%
8%

;
10%

and spices,

lo@)

:
C

100%

A
A

(continued)

64

Corrosion Resistant Materials Handbook

TABLE 1.20: NYLON 616 RESINS-CELANESE

EFFECT

CHEMICAL

Oleum.
Oxahc acid.
Paraffin,
Perchlorethylene.
Perchloric acid.
Petroleum ether,
Phenol,
Phosphoric acid,
Phthahc acid.
Potasswm bicarbonate.
Potassium bromide.
Potassium carbonate,
Potassium chloride.
Potassium dlchromate,
Potassium ferrlcyanlde.
Potassium ferrocyanlde.
Potaswm
hydroxide.
Potassium
Potassfum
Potassium
Potassium
Pyrldlne.

nltrate,
permanganate.
sulfate,
sulftde.

10%
100%
10%
10%
Saturated
60%
10%
60%
90%
5%
30%
30%
10%
50%
10%
1%
100%
90%
-

Resorcinol.

100%

Sallcyhc acid.
SIllcone flulds,
Sliver nttrate.
Soap solution.
Sodium acetate,
Sodlum benzoate.
Sodturn bicarbonate.
Sodium blsulfate.
Sodlum blsulflte.

100%
-

Sodium bromtde.
Sodium
Sodbum
Sodium
Sodbum
Sodturn
Sodium
Soolum

PLASTICS

carbonate.
chlorate,
chloride.
cyanide.
hydroxide.
hypochlorite.
nitrate.

6&$
50%
10%
10%
10.50%
10.9oq/,
10%
50%
15% Cl
10.50%

(continued)

CHEMICAL

EFFECT

Sodbum perborate.
Sodwm phosphate,
Sodium skate.
Sodturn sulfate,
Sodium sulhde.
Sodium thlosuifate.
Stanmc chloride.
Stannlc sulfate,
Stearic acid,
Styrene.
Sulfur,
Sulfur dioxide.
Sulfuric acid.

A/B

5%
Sulfurous

90.10&+,
10.9oqo
2590%
10%
100%
2%
and alb&e

acid.

Tallow,
Tar,
Tartaric acid.
Tetrachlorethylene,
Tetrahydrofuran.
Tetralm.
Thlonyl chloride,
Toluene.
Transformer
oil.
Trlchlorethylene.
Triethanolamine.

;
2
;
:
A
:
C
ii

:
10%
1oGj
-

Urea.

VaselIne.
Vegetable oils.
Vinegar,
Vinyl chloride.

AB
A
1
A
A?*
A
A
;

B/C
1oG$o

Water, cold,
Water, hot,
Wax. molten,
White spirit.
Wmes and splrlts,

;
A
A$

Xylene.
Xylenol.

Zinc chloride.
Zmc oxide,
Zinc sulfate,

AC
A

4. No attack, little or no absorption, little or no effect on mechanical properties.


3. Liile or no attack, some absorption causing slight swelling and slight reduction in mechanical properties
at 73F (23C)
C. Some attack or considerable absorption at 73F (23C) material not suitable for contact unless limited product
life is acceptable.
D. Material decomposes at 73F (23C) in a short time.

TABLE 1.21:

NYLON

11 RESIN-RILSAN
RILSAN

NYLON

11

CHEMICAL

RESISTANCE
RATING

RATING
CONCENTRATION

CHFMICAL

6aoF
20-c
a

AWIafd&lde

104OF
4o=c
6

14ooF
60C
x

BESN BLACK T
194pF 9OC

CONCENTRATiON

CHEMICAL
Dwlhyl

WF

lOJ=F

140~1

&

203

- (,Oi

5%

D,octylphosphate

Acetoc Ac,d

10%

D,ocrylphd,alare

Acetoc Aud

50%

Ethanol

A+

PW

El

Ethyl AceWe

At

Ethylene Chlorhydrtn

Ethylene

Glycol

A+

At

A-

Ethylene

Oxade

Fatty Aad

Hydrorade

FlOrll-le

Ammonium

Nllrate

Formaldehyde

Ammo,m

Sulfate

Formic Actd

Amy1 Acetate

Anethola

Pure

ACetOW
ACZ?tlee
Aluminum

SuItate

AllllIWl~
Amonwm

Pure

Aniline
Barun

sat. sol.

Chloride

Esrers

Freon 12

Freon 22

B+

Freon 502

Fru,t Jutices

Furfuryl

A+

Gas (Coal)

Gasolme (High Octane)

Glucore

Beer

Benzaldahyda

BeWe*

A+

Benzyl Alcohol

Bromine

Blxx

GlCOl

But, Alcohol

At

Gr.?aSl?s

Heplane

Hydrogen

Concenlrated

Calcium Chloride

sat

Ca,cum

Hydrogen

Carbon D,rult,de

A+

a+

Carbon Tetrachk,r,de

Chlorane

Chloroform

Chromtc Actid

10%

Coder

Citrtc Actd

Copper Sulfate

CWSOl

Cyclohexane

CClOhe~.3~Ol

Cyclohexanone

D D. T. Preparat~onr

D,ammonum

Phosphate

D,cnloroerhylene
Dnrthanolammc

NIlrate

20%

I3

PW

Glycerine

Calcwm Arsenate

sol.

Alcohol

A+

Peroxde

Hydrochlortc

Ac,d

Hydrochlor,c

Ac,d

Hydroxy

2%

20%

Oumolme

B
B

A
B

Isopropyl

Alcohol

Kerosene

Lacttc Acid

Lmseed Cake

Magnesrum Chloride

50%

Mercury
Methane
Methanol

PlJre

AI

Methyl-Cellosolve

Methyl

Acetate

Mrthyl

Bromtde

A+

IY)cyanaleS

194OF 9OC

Ether

Acettc Acid

Ace,,c AnhydrIde

BESN BLACK

(continued)

TABLE

1.21:

NYLON

11 RESIN-RILSAN

(continued)
RATING

CHEMlt34

CONCErJTCATlQW

WF

lWF

14OOF

- 20C

GOC

RATING
BESN BLACK

194OF 9O*C

CONCENTRATION

WF
--7GC

104OF
40C

14WF
6LlC

Methyl Chloride

4oc
X

Methyl Sullale

Milk

Monochiorobanlene

Mustard

Naphtha

A+

Ndphthalene

A7

Otis Crude

At

011 Refw2d

Ole,c Actd

Oxalx

Melhy tthvl

Ketcne

Methyl Isobutvl

Krrone

All Concenrration

Ntrrbc Ac\d

Ai

A
A

Oxygen

Perchloroerhylrne

Ai

Phenol

t3

At

Fit

A+

Acud

Phosphoric Acid

401

P,cr,c Ac,d
PJ,ars,m

Cdrbcnate

Potauwm

Hydroxade

Potai,um

N,rrats

Potrwum

Parmmp~rl*lu

Pa,arsim

Sll~l.

lro??

bl.

Propane

Pydraui F9

Pure

Pyr,d,ne

Soap Solution
Sodum

Carbonate

Concenxaied

Sodum

Chlortde

Saturated

Sodurn

Hydroxide

SC%

Sodurn

Hvpochlwtte

Concentrrred

Sodwm Hypochlorlte

Dduw

Commrrcnl

Grade

Synthetic

TABLE

1.22:

NYLON

REINFORCED

VINYL

HOSE-SETHCO

DIVISION,

Resins and Polymers

67

MET PRO CORP.

Sethcos
NRV (Nylon
Reinforced
Vinyl)
grade hose may be used at working
pressures ranging from 100 to 250 psi
(depending
upon size). Its flex life exceeds that of rubber and its characteristic
inertness satisfies requirements
for
a wide range of industrial
and laboratory
applications.
The reinforcing
nylon mesh is encapsulated
in the walls of the clear vinyl, providing
a high strength,
smooth surface
hose. The imbedded
mesh is never in contact
with fluid or atmosphere.
Working
temperatures
range from 20 to
175F as discharge hose and 20 to 140F as suction hose. The vinyl is fire resistant and self-extinguishing.

Sethco Nylon Reinforced Vinyl Hose Chemical Resistance Guide


Excellent

Chemical

Resistance

Acetic Acid
Air
Alcohols
Aluminum Chloride
Aluminum Sulfate
Alums
Ammonia Gas
Ammontum Chloride
Ammomum NItrate
Amnlonlum
Phosphate
Ammomum Sulphate
Amy1 Alcohol
Animal 011s
Ant:mony Salts
Arsemc Salts
Barium Salts
Basic Copper Arsenate
Beer
Benzolc Acid
Benzyl Alcohol
Boric Acid
Basic Copper Sulphate
Bordeaux Mixture
Butanol
Butter
Calcium Hydroxide
Calcium Hvnochlorlte
Calcium .&its
Carbolic Acid
Carbon Monoxtde
Caster Oil
Corn 011
Cottonseed
011
Caustic Potash (-20%)
Caustic Soda (-20%)
Chloroform
Chromic Acid
Chlortne IDrvt
Chlortne (Water)
Chromium Salts
Copper Chloride
Copper Sulphate
Cltrlc Acid
Cresvllc Actd
Cupric Sulphate

Also

Recommended

Essential Oils
Ethgl Alcohol
Ethyl Chloride
Ethylene Glycol
Fatty Acid
Ferrtc Chloride
Ferric Sulphate
Fluoborlc Actd
Flue SI~ICIC Acid
Formic Actd
Formaldehyde
Freon
Galhc Actd
Gas (Natural)
tS;sa;;;e
(NonA:omattc)
El;S;i?pendtng

Oxahc Acid
Oxygen
Palmmc Actd
Picrtc Acid
Phosphoric Acid
Potassium Chloride
Potassium Sulphate
Propane
Pyrethrum
Sodium Btsulflte
Sodturn Bicarbonate
Sodturn Borate
Sodium Carbonate
Sodium Chloride
Sodium Cyanide
Sodwm Hydroxtde
Sodium Hypochlorlte
Sodium Nitrate
Sodium Phosphate
Sodtum Slltcate
Sodium Sulohlde
Sodhum Sulphate
Sodturn Thlosuiphate
Steanc Acid
Stannous Chloride
Sulphur Dtoxtde
Sulphurlc Actd (DII
Sulphurous
Acid
Tanmc Acid
Tartartc Acid
Tar 011
Turpentine
Urea
Uric Actd
Vinegar
Water
Whiskey
Wine
WOOI 011
Zinc Chloride
Zinc Hydrate
Zinc Sulphate

for

manufacturer

Acetlc Anhydrtde
Acetone
Acetyl Bromide
Acetyl Chlortde
Ammonium
Hydroxtde
Amy1 Acetate
Aromabc Hydrocarbons
Butyl Acetaie
Carbon Bisulfide

on type)

Glycerine
Hydrochloric
Acid
Hydrocyantc
Acid
Hydrofluonc
Acid
Hydraulic 011
Hydrogen Gas
Hydrogen Peroxide (DII.)
Hydrogen Sulphlde
Lacttc Acid
Lard
Lead Arsenate
Lead Sulphate
Lime
Linseed 011
Magnesium Chlonde
Magnestum Hydroxide
Magnesium Sulphate
Malelc Acid
Milk
MIneral 011
Molasses
Ntckel Chloride
Ntcottne
Nttnc Acid 20%
Nitrogen Oxtde
Nitrous Actd
011

Aniltne
Benzlne
Benzol
Borax
Butane
Bromine
Calcium Btsulphlde
Calctum Chlonde
Carbon Tetrachlonde
Caustic Potash (+ 20%)

Check with

for:

Causttc Soda (+ 20%)


Chlordane
:t7zot
e
Gasoltne (AromatIc)
Hvdroaen Peroxlde Icon.)
K&o&e
Mercunc Chloride
Methyl Chlonde
Olelc Actd

Pentane
Perchlortc .Actd
Perchlorethylene
Phw?olates
Ph Jnols
Stoddard Solvent
Sulphurtc Acid (Cont.)
Trtchlorethylene
Trichloracetlc
Acid

or test in your plant


Chloracetlc
Acid
Cresols
Cyclohexanone
Ethyl Acetate
Ethylene Dlchlorlde
Fuel 011 (AromatIc Gas) 100 octane
Fuel 011
Isopropyl Acetate
Ketones

Laquer Solvent
Naphtha
Nltrobenzene
Paint Solvents
Pyridlne
Toluene
Toluol
xylol
Xyiene

68

Corrosion

TABLE 1.23:

Resistant

Materials

OXIRANE

Handbook

OLIGOMER

OF RESORCINOL-PLASTONICS

INTERNATIONAL

KEY PROPERTIESOF PYROITE ll


1) Corrosron

resistance
to most solvents
(See compatibMy
chart.)

chemrcals
Erosion

2)

resistance

3)

High dielectric

4)

Stability

and corrosive

5)

Excellent
bondrng characterrstrcs.
Bonds to metals, glass. concrete,
glass. plastics, etc.

and toughness.

strength

to temperatures

from -80F

to over

500F.

6)

High resistance

7)

Non-galling

to thermal

fiber

cycling.

capability.

DATA INTERPRETATION

M ETALS

DEPTH OF CORROSION PER SURFACE


*

002 In. per year

020 In per year (4


050 In per year (4

050 In per year or exploswe

(4

RESULT

mm. yr.)

05

5 mm. yr )
1.27 mm. yr.)

C
NR
-

Not recommended

No data

cl

Questronable
rate to mrlllgrams per

To convert

decimeter

per year

mdd

(mdd)

= I

yr

,695

specific

gravity

of metal

PLASTICS
SWELLING
OR DIMENSIONAL
CHANGE.
(ANY DIRECTION.)
WHICHEVER
IS GREATER.

LOSS OF
TENSILE STRENGTH

DESCRIPTION
CHEMICAL
ATTACK

RESULT

LIttIe or none

4 1000

4 1500

4 1500

4300

42000

45000

Ltmlted

,2000

,5000

Attacked
or dissolved
wlthln minutes
or years (Not recommended)

NR

No data

Good

resistance
resistance

No data

No data

(Manor attack)
(Moderate

attack)

Ouestlonable
Note

When

botllng

IS tndlcated.

boiling

temperature

varies

with concentrahon

of corrodent

EXAMPLES OF TYPICAL CALL-OUT


METALS
w

002

yr

I any

002

yr

al

concentration

200

002

an yr

saturated

010

yr

I any

050

yr

saturated

050

yr

0 to w

050

CentratIon)

can

yr

70F

lo

212F

A to 200

to 212F

A at 200

at 212F

at 70F

A
between

200

and

between 70F

50.

and

140F

B 20.500

at 70F

eftect

70.140F
NR

concentration

saturated

greatly

from

a1 212F

concentration

I any
in

0.20%

concentratnn

at 70F

at 70 F
corrosion

Just

NR any
a few

degrees

Comblnattons

of temperature

marked

dtfterence

A NR are crltlcal

(or percentage

points

as to concentration

concentration

of con.
A NR

or temperature

PLASTICS
Llttle

to no chemical

200F
Ltttle
200
Good
from

(temperature
to no chemical
F

(temperature
resistance

70F

Attacked

lo

4 lo00

swelling

or 415O

D loss

of tensile

strength

at lOOn

concentration

at 70F

or
A

at top of column)
attack

4 10O0 swelling

or 4 15 o loss

ot tenslie

strength

from

0 to 200

concentration

at 70F

or
A to 200

at top of column)

(minor

chemical

attack)

4 150

Swelltng

or *30

o loss

01 tenstle

strength

lrom

20

to 500 concentration
B 20.50e

140F

or dissolved

~twnm=rati~re

attack

W200

at too 01 column

swelling
1

01 b50

I) loss

of tensle

strength

I concentrated

at 70F

70.140F

or 200-F
NR

(continued)

ABLE

1.23:

OXIRANE

CHEMICAL

OLIGOMER

OF RESORCINOL-PLASTONICS

PYROITE II
200F

KVNAR
200F

STAINLESSSTEEL
316 70F

INTERNATIONAL
TEFLON FEP
70F

EPOXV
70F

(continued)
HASTELLOV 6
70F

VINVL
ESTER

THERMOSET 70F

TEFLON PFA
200F

PYtlgrE

Acetamide
Acetate
Solvents
Crude

Acetic
AcidVapors100% (hot)
Ace& Anhydride
100% (boilng)
Acetic
AcidGlacial
70F
Acetone100%
Acetonilrik

Akohol,
2 Aminoethanol

(continued]

TABLE

1.23:

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS

PYIl#$E II

CHEMICAL
I

KYNAR
200F
I

INTERNATIONAL
TEFLON FEP
7O'F

STAINLESSSTEEL
316 7O'F
I

(continued)

EPOXY
70F
I

VINYL ESTER
THERMOSET 70F

tlASTEl.LOY
C
7O'F
I

PYROITE I

TEFLON PFA
ZOO'F
I

70F

Aluminum Sutphata 10%


Aluminum Sutphata 410%

hating

Aluminum Sulphate ~10%

boiling

Aluminum Chbrohydroxtde (wet)

Ia

1 I. 201'F

"I

as

L I, 70F

Lb 7D'F

1E fn11w 6qIl?q

AC Ia50% ,a210F

A* to50%
I#200F

Amines

Ammonium Chloride 10%


Ammonium ChMde

410%

baiting

Ammonium Chhnide blO%

hoiting

(continuec

(continued)

TABLE 1.23:

OXIRANE

OLIGOMER

CHEMICAL
Bromine

Butane

Moist

OF RESORCINOL-PLASTONICS

PYROITEII
200F

1Bromine
watt,

A BI,llli(le
WIIC 50% II 212-F

Gas

STAlNLESS STEEL
316 70F

KVNAR
200F

WI

25% to 212F
A to 212'F

"Rh*

wit"

INTERNATIONAL
TEFLON FEP
70F
A ,a 200-F

(continued)
NASTELLOV
70F

EPOXY
70F

A
A BR.im WIk

WA II VJ'F
0c Broannrwater

VINVL ESTEA
TNEAMOSET 70 F

TEFLON PFA
200F

AC ID 100% to 80F
IdAliquid

A
A 25% 8w"m.e
Wll" la 200F

PYFly\TE
0 1
"R to 70F
Bc Bmnlm wt.3

100%

Buttermilk

Butykne

Bulyl

Phthalate

Cakium

Carbonate

Cakium

Chloride

(saturated)

Cakium

Chbride

(dilute)

Cakium

llypochbrile

100%

A II 15'F

A,. 125'F

AC D WJ'F
I

A
I

74
Corrosion

-0
a

Y
t

I
<

v
s

Ye

-0
<

P
*

Resistant

:a

a;

Pr

:r

E;

<

<

Materials

<

Y
::
D

Handbook

Y
0
::

<

I
f
<

<

TABLE 1.23:

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS

INTERNATIONAL

(continued)

Copper Flumtdc
Copper Nitrate (hot, concentrated)
Copper Sulfate (hot, concentrated)
Coltonreed

oil

(continued)

TABLE 1.23:

OXIRANE

OLIGOMER

CHEMICAL
I

Oebqcnts(general)

D*IAybther

OF RESORCINOL-PLASTONICS
KVNAR
ZOO'F

PY?tI$E II
I

AI * 70F

BDlrz"F

7@"F
Kd,L*'F

INTERNATIONAL

STAINLESSSTEEL
316 70F

A.

(continued)

EPOXY
7O'F

TEFLON FEP
70F
I

VINVL
ESTER

NASTELLOV C
70F
I

TEFLON PFA
200F

THERMOSET 70F
I

PYROITE I
70F

Ah300"F

Olbobutybne
DinethylAnillee

Mmelbyl Fomumlde
IAmelbyl Pbthalate
Mnw?tbyl SuSexlk

(continued)

ABLE 1.23:
CHEMICAL
P-Dioxanc

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS

PYROITE II
200F

KYNAR

200F

Ch lZ2"F

WI II 151F
ws ls0l.r 1.1

STAINLESSSTEEL
316 70F

INTERNATIONAL
TEFLON FEP
70F

Ill

WDF

(continued)

EPOXY
70F

(I

HASTELLOY C
70F

VINYLESTER
TNERWOSET 7O'F

TEFLONFTA

PYll)bFTE I

1 ,a 70F

200F

Dow Therm

Ethyl Benzene

Ethyl Ether

Ethyione Diamine

(continued)

TABLE 1.23:

OXIRANE

OLIGOMER
PYIN$E

CHEMICAL

OF RESORCINOL-PLASTONICS
II

KVNAR
200F

STAINLESS STEEL
316 70F

INTERNATIONAL
TEFLON FEP
70F

EPOXY
70 F

(continued)
NASTELLOV
70F

VINYL ESTER
TNERMOSET 70 F

TEFLON PFA
200F

PYI$ITE

Hexamine

Hydraulic

Fluid (Petroleum)

Hydraulic

Fluid (Synthetic)

Helium

Hydrochloric

Acid

l-20%

Hydrochloric

Acid

41%

Hydrochloric

Acid

1%

Nydrochlodc

Acid

h-2%

175F

Hydrochloric

Acid

,2%

175F

175 F

(continued)

TABLE 1.23:

OXIRANE

OLIGOMER
PYROITE

CHEMICAL

200F

OF RESORCINOL-PLASTONICS
II

KYNAR
200F
I

INTERNATIONAL
TEFLON FEP
70F

STAINLESSSTEEL
316 70F
I

(continued)

EPOXY
70F
I

NASTELLOY C
70F
I

VINYLESTER
TNERMOSET 70F

PYROITE

TEFLON PFA
200F

70F

(continued

TABLE 1.23:

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS
KVNAR
200F

PYIl$-f$E II

CHEMICAL
I

Lime-Sulpher (Cakium Sullide)


Linokk Acid
Linseed Oil
Lithium Chloride 30% al 200F

Lithium Hydroxide 10% al 200 F

INTERNATIONAL

STAINLESS STEEL
316 70F
I

(continued)
NASTELLOY
70aF

EPOXY
70F

TEFLON FEP
70 F
I

TEFLON PFA
200 F

VINYL ESTER
TNERMOSET 70 F
I

PYROITE I
7OF
I

ABLE 1.23:

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS
STAINLESS STEEL
316 70F

INTERNATIONAL
TEFLON FEP
70F

EPOXY
70F

(continued)
HASTELLOV
70 F

VINYL ESTEA
TNERMOSET 70 F

TEFLON PFA
200F

PYROITE I
70F

Mineral Oil

Morpholhw

Nickel Chloride
Nickel Nitrate

(continued)

TABLE 1.23:

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS

PYllIfTE0

CHEMICAL

II

With Acid Fuming

HiIrk ACM

(70% cont.)

(Suflng)

soxm2~F

KYNAA
200F

*s*,t2~F
CnM rh@nur 70F

II IS%

INTERNATIONAL

STAINLESSSTEEL
316 70F

TEFLON FEP
70F

Ab125"F
"(Id 212'F

170% ,#L,)"F

1111U,.,I,F I

A OS% B SO%
II me.

A 2540K
Alw CUT.

A ,470-r
sC w*-t,*'F

A 100% ,040D"F

A,. 300F

1 II600F

A,# 300-F

A I,1,2*F

I b 122'F

A,#IOO'F

Ati Z,t"F

I I.212"F

s 1sX II212'F
Is 10% ,I150F
AI 10.100xbIO"F

A,# too-F

YII.,
70-F

s 100%

A ,,7DDF

N-octane

Al4 176F

MIS Animal

OilsCrude

Mb

-en

Nitmmethanc

NAnus Acid

Nllmus

Oxtdc

Mineral

"II

NASTELLOY C
70F

Atl,ZS"F

C,@ 122'F
nn * Z,?OF

PYI$j~E

TEFLON PFA
200F

ml funllnp
C/M SO'%a IO'F
MD 50% a,l.l'F

A * 248'1
1.90% c 73'F

I) 10%
20%

Cnl sx
AC 2x
s-ox

A 70%

WA

s 100% b 211F

CnM I0100% Is100F

M 10IO'F
C 10122-F
WR I,212'F

A to600F

AilII-3ZO'F

A ID100F

A ,a,OODF

AC I#10% ID150F

s 100%

A I.IO'F

1s* 140F

Ah 28s'F

IIO"Ftr M
UlrPx

)IhZDO"F

xs,# 100% ,a210F


,ma*HUr)

k,, Z75"F

A 7)'FU b,

A IO2ss"F

AB,a ,sOX 1sl,O"F

A,4 7O'F

Ash ,OOK b 210F

)1

Ash ,OOK h 210F

Mb

,00x h 21O'F

As 1, ,OOK m 210F

A IO212F

OlisVegetable

A,,17I"F

A 70170F

A,. 70F

Okk

AD 248F

LB IO"F,#500F
080% ti120F

A ,a200F

A ,005 IO160-F
B,OOW ,ss"Fh 212-F

Oxalk Ac!d

Ah 12O'F
CW 200F
UI ti211-F

s te4ox WR cute.
IM ,040# * 212F
A W+s# 11100F

A ,,2OO'F

1 I#112-F

s,O~OOX 70-F
IO21*-F

Oxygen

A 11FzlS'F

Ozone

AD t7s'F

palmltk ACM

A ,It,.'F

PWMII

A Is'F,.Wn

A ,a70F

Pentane

C
C r.Fwa*,,S*F

AIUO'F

A * 1W"F

Asb75DF

&

Antardq

A I.,*s'F

AII,%?ll'F

1 I.70F
AClrWO"F

A ,eIDO'F

As,~,sox I#12O'F

It)Cmm,Nld
v.1 I.(50F

M k 70-F
"II,!
212'F

MkMve

Acid (redo/l)

VINYLESTER
TNEAMOSET 70F

SC 10 70F

AsI0 212F

Wobmuene

(continued)

EPOXY
70F

(continuec

rABLE 1.23:

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS

PYIH$E
D II

CHEMICAL

INTERNATIONAL

KYNAR
200F

3TAlNLESS STEEL
316 70F

TEFLON FEP
70 F
A !0 70F

(continued)
VINYL ESTER
THERMOSET 70 F

TEFLON PFA
200F

PYROITE I

A 10 170F

A 10 1OF
Slqif ~ktf,Dk*I

biB 10 180F

L IO 180F

A 10 70F

A 10 lWF

110 210F

&

A 10 *se F

EPOXY
70F

HASTELLOV
70F

70 F

Plating

Solutions

Nickel

A to IllF
AC IO 14OF
wa ckt,rnk**

Plating

Solutions

Silver

A I0 120F

A 10 IZDF

1 ID 70F

1 I0 12DF

A ,a 120F

As IO 1.30F

Plating

Solutions

Tin

Aa

c 11 10s F

A ID 70F

A 10 100F

110 100F

1s II *IO-F

Plating

Solution

Zinc

1s

1 Syllidt II 7s F
aa Chhlrld~L
obofltr

A 10 10F

L l0 150F

A 10 150F
rlclpl 1cld Chbnidl

AB 10 IeoF

A 10 70 F

A 10 275F

A8 10 15OF

I ,a 200F

AE 10 30s F

?.e 10 100% 10 220F

1s IO ZISF

a 10% I0 21ZF
e WOY. 10 IOF

A I# 7OF

a 10% ,D ZlZF
a 100% 10 70F

Aa I0 50% I# 150F
1s 10 100% 10 l,OF

L.

1 10%
c 100%

a 100% a 70F
e lll.wh IO 212F
a 1OfJ% II 1501F

Ia 10 lee*

10 212F

A 1* 30% 11 IOF
a 100% IO 212F

Ia lo 100% 11 110F
AC 10 IelI% 10 110F

As 10 sex IO 150F

Potassium

Acetate

Potassium

Aluminum

Potassium

Bicarbonate

Potassium

Potassium

Bichromate

Bromide

Sulphate

(alum)

A ID 27SF

A *a.sox I0 212F
a CMC. I0 1WF

A 1v 275F

s I0 70% 1D
212F (pit,)
A l1lY tt I(15F

A II 200F

A lee% 11 1500F
A lo-es% ID 21zv
a 100% d 70F

A 10 2eev

A I# 200 F

YR rylnldr 11 180 F
As 10 160F

Potassium

Carbonate

A to 275F

A I, 17% 10 240F
a 2o.lash II 70F
*20-70x II 211F

Potassium

Chlorate

A to 27SF

A 104llK I@ 212F
s Io.1eeh ID 7OF

1 e 200F

s 30% I0 21ZF
c se.7e% I, 212F

AB I0 lluJ% (0 110F

Potassium

Chloride

Ah 275F

As lwh to 70 F
A 10~30K 10 212F

A 10 250F

A loll% It 350F
a 100% IO 7OF
A8 10.sclx (0 212F

Aa 10 100% 10 21OF

Polassium

Chromate

AI II 275F

I IO-40% I# ?1?F
e 10~100% II 70F

A 10 7OF

A 1040% I0 212F

Aa lo 10% 10 IlOF

A ID 70F

Potassium

Cyanide

A I@ 275F

II II lOOK l0 2,2F
a le.,oo% 10 70F
a 10.30% ,D 212F

A lo 200F

a ID-JO% 1. Z12F
e 100% II 70F

AI 10 loll% I0 14ev

e 100% II 7OF
a 1e.eex IO 212F
II 100% aI 1500F

Ae 10 100% I# 2WF

II

a wwh

10 Z12F

As 10 100% 10 210F

A JO,. 10 70F

a 10-w,.

IO 212F

Aa to 1Oil% 10 210F

Potassium

Dichromalc

ii

A lo 275F

A 10-60~ I# 212F
a OOIU. 10 150F

A 10 2OOF

A ID%
c 100%

Potassium

Ferricyanide

AD 275F

a IO-WY. IO 212F
a 10.100% I0 7OF

A 30% I@ 70F

Potassium

Fetrocyanide

AC 275F

s IO-100% ,a 212F
A 5% 170F

A 10 2OOF

Potassium

Hydrate

A loax 11 70F
a lll~ssx t. 211F
we IODK #I 5DOF
I so.*w. I, 212F

A *ox l0 250F
A 1alw I0 125OF

c 10% II 70F
II 100% n 7ev
II 30% d 70F

A IO 70F

A II 212F

Aa 10 130F

Potassium

Hydroxide

Ah ,s7v
I IO 212F
c e 230F

Potassium

Hypochlorlte

A*

Potassium

iodide-iodine

Potassium

Nitrate

a 10-6ax 10 3DOF
a 100% II 7llF

a 10~1wh
7OF I# ssev

I\ so 200F

eme ID wh

I( IIIDF

a lw/. II IDF
e IO-soy*
70F ,a 212F

I,0

1aaF

1 IO 70F

1a I0 lo**/, 10 ZOOF

A II 70F

18 10 100% ID 210F

a 10.1!wh
7DOF I# 212F

11027SF

A b 70F

(continuec

(continued)

TABLE

1.23:

OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS

PYIi$JE

CHEMICAL

ssll Arhle
(Sodium Chbrkb

Silver

Bromide

Sodium

1 H 122F
s 8, 15sF
E ., 211F

(continued)
EPOXY
70F

TEFLON FEP
70F

VINYL ESTER
TNERMOSET 70F

NASTELLOV C
70F

TEFLON PFA
200F

1 In ,lsF

PYl$$TE

).

Solution)

Sinconc
Oil

Wlvcr Chbrlde

INTERNATIONAL

STAINLESS STEEL
316 70F

KVNAR
200 F

SIlCyklddlVlb

II

Aluminum

Sulfate

x
a=*h
1

@MIs-100%

70F

)1

1 h 70F

Ah

lk125F

A,CWX
a,211F

1 h rOF

xs ,, ,WF

1 U 2sVF

s t. (0% I0 r,ZF

1s 10 ,usx

10 120F

Sodium
Bcnzoate
Sodium

Rkrrbonate

Sad&mBichmmale
Sodium

Aisulfate

Sodium
flisulSte
Sodium

Borate

(Borax)

x b 27sF

xs 10 ,DO# I, 1,DF

(continued)

YABLE 1.23:

OXIRANE

PYlgl_F

CHEMICAL
Salbm

sodium

OLIGOMER

II

Bfomtda

CSf&onale(Sodx

ash)

sodbnl chbrate

II

STMLEI
WEE1
316 70F

KVNAR

2OOF

B 1CSSU

1 U 275-F

A II 27S'F

A,4 27s"F

(brbe)

OF RESORCINOL-PLASTONICS

"175F

AuPr*I
11,155X
b212'F
S IWX 8,500"F
MS.15.WX
S1CIWX

Y 212'F
U7O"F

"SISK II 12S'F
S 2030% b 212F
A IWX ta 71.212-F
bMSt%.7SF

INTERNATIONAL
7ERON FEP
70F

At, 20.-F

AD

200-F

A 10X N 2W"F
A t,c11.t,20O~F

CtMdr

Sodbm

Chmmate

I,lCWK
71.ZIZ'F
.lSOX"IS'F

So&m CNfab

S 15%,.212*F
Sl,lSS%at7S'F

Ata7O'F

ChsdatlZSZF
A IS% @212-F
AlCIW(X,!7SDF
Yt3SX
al IllOF

At4 71'F

Sodium

Cyantde

Sodium

Dkhmmab

Sedbm

Fafttcyantds

Sodium

Fluodde

Sodium

Hydroxide

,I*dLi,
A

(cruxliC Sodldp)

Sodium Hydroxide
(mette11)WKt4
:F

1,.

275-F

Aa

xab

A5X*lAny
SICIWK
4l771'F
CM .X al l.0.F
AS%#bNh*c

Ata27S*F

A lCZOX Ia 212F
I "MD%~~2~F

A WY. I, 212-F
&".r-M25S.F

SC,OS%.45S*F

as

YI

lit,

xc

275-F

w
x k%2;170 F

Sadbm

Hypochbrtte

(sobtbn)

Lt.

275'F
A.,%,.
ul-Y5x

I,,

AOXl.ZW"F

12F

ASlWX
r2sx5aa2

A 20% t. 122-F
C ~1.b 7S"F
YIIul.
aI 122-F

SlOTOK
SIOX

A IaZlZ'F

At, tWX

71-F

ta212"F

II 212'F
aI 7O'F

t. 212-F

Al0IWX
7C212'F

AUZ12'F

AS!4 IDS% t# 1SO"F

A II 212'F

ASb SSK
t. 215-F

50% Ia 215-F

l012O'F

ASI8 50%
blW"F

AU71'F

AS,. ,00X t. IIS-F

AS,, ISSOX b 21,-F

AIt4 210-F

AS,, lWX

II 21,-F

ASt.2lO'F

Aw7O'F

A.U

xa

IIs

xn

lln

12OXt.2W'F
A IS% ,a 2SO'F

C 20%
SS-

Sodium

Nitrate

Sodium

Nttttte

So&urn

Perborate

Sodium

Pemxtde

AU

275F

A 70.212'F

Ab2W'F

1,.50X
AIcCW&.

Sodium

Phosphates

At. 275F

AS 10.100X
70212F

ADIW'F

A 1X
AIlSOX

AS5X.tl2S'F
SC S.lSX .tlSO"F

AS"

A Ia 70F

1 * lOOF

A II 2SO'F

"I1

AS

S 30~1OOX
1,.20X

: z;:::
Ai:w9:

ASU 20%
I, ,.0-F

AZSXtr2W'F

LSD 20X
at210'F

SS

xn

I
AS!, IWX

1.2tS'F

111

ASI0 100% I. 210-F

AII2WO"F

At,7.'F

20% U 210-F

2lS"F

(mkwvb

A YX )I 241F
A ".&,a 7.-F

A ,00X at 70F
510% U 212-F

AS WX to *IS-F
AS 100% t.22)'F

AA-."
7S'F
2X 45-W% al 210-F
Uils-25% til25'F
AS5X121SDF

A l&SO% U 212'F
S 1204L d 70-F
S 15~00% at 251F

AStl2OX
AC-.

A 5SX ,, 122OF
D55H
.I ISO'F

0 1,70X11 212-F
A 100% "IS-F

Nitrate

AbIO'F
A SK UIZZ'F
14OU b 122'F
C4,X ., 212F

Sodium

A k 275-F

10 1W 'F

A 1&1OOX
70212F

AS10~2SX

Al.lOOX Ia 12S'F
ASSXt.2W~F

Metasltbate

AS t, 1SO'F

l--w

Sodium

KS

A.taISSX"lSS'F

(motten)~5S6F

PYilfjFFTEI

to ZIO'F

ASb2SX

Ab2OSQF

Metaphospbate

Ata 2759

7EFLON FFA
ZOOF

ASUIOOI

AIH

A tS5X lO.llS*F
I ISX

At, 7,'F

Sodium

YtNYL ESTER
lNEttMO3E7 70F

SlSaOX
A 1OSX

A 101WX1121ZF
S 1WY.U 15W'F

At.212'F

Sodium
HyposulAta

24,-F

NMIELLOY
70F
SIC5.K

AO2SO'F

Sodtum

275-F

(continued)

EPOXY
7OF

A
I

AS

S 10% I. 212'F

AS*

A 1&100X
70.212F

SO-F

AS,4 IWX 10 210-F


ru#pl rlJdilJ8
*I.mMa**tM*

AS

A Ia SD%
h 150-F

~~

(continued)

TABLE 1.23: OXIRANE

OLIGOMER

OF RESORCINOL-PLASTONICS

INTERNATIONAL

(continued)

SlrnnkChbrkb
Stannous
Chloride

liti
SSO'F

Steam

Sutphate
Bbck Liquor

Sulphate
6mn liquor

Sumnol

SUlphll l.kplu
(100% soktion
wtth10% SO,)

PdSSS'F

)rb,IOO'F

At.2SO"F

Ah27S'F

It, 212'F
Ek,SS'F

A.Z"'F

Al, 70F

)I,212F
A

Al978~F

AI)II
212F

At.,O'F

At. SSO'F

ABt,tZO'F

At,212-F

AOh

It, 175F

AStelOOX

100% U 20.-F

te2OO'F

At,,SO'F

A
A

ABM

212F

AIt. 100% WZOO'F

Ata7ST

ASleIOOK
II 220F

(continued)

TABLE

1.23:

OXIRANE

OLIGOMER

CHEMICAL
Thioey(

Tb

Triethykne

Ttiethyl

Trtphenyl

As * MF

,449F

Tnchbromoneiberoatham

Glycol

Phosphate

(Freon

STAINLESS STEEL
316 70F

KYNAR
200 F

ZOOF

Chloride

Mottrn

OF RESORCINOL-PLASTONICS

PYROITE II

INTERNATIONAL
TEFLON FEP
70F

m It 70DF

A ,I 125-F

ne

ee

(continued)
EPOXY
70 F

NASTELLOY
70F

WY1
ESTER
TNERMOSET 70 F

TEFLON PFA
200F

PYROITE I

we

MR

IIR

*uil

* war

WR
AC tnnw*

70 F

17)

I
A

A* 125F

I
A

A I. 200F

YII

!
AS ID 100% IO 2OPF

1 IO 2OOF

Phosphite

(continued)

ABLE

1.23:

OXIRANE

OLIGOMER
PYIttI;E

CHEMICAL

OF RESORCINOL-PLASTONICS
II

KYNAR
200F

STAINLESS
STEEL
316 70F

INTERNATIONAL
1

TEFLON
7OF

FEF

EPOXY
70F

(continued)
I
I

HASTELLOY
70 F

VINYL ESTER
THERMOSET
70F

TEFLON
PFA
200F
I

PYl$ltE
D

Trisodium Phosphate
Tung MI (china wood oil)
Turponline

Vinylkline Chbride (Resb)


Water.

Acid

Mine

Water. Boibr Feed


Water.

Uirtllbd

Water. Fresh
Water. Ueknlzed
Water. lb-mineraLed
Water. Brackish
Water. (salt) See ah0 Sea Water
Wax
Whiskey

(continued)

TABLE 1.23:

OXIRANE

CHEMICAL
WhHc Liquor(PulpMill)

OLIGOMER

OF RESORCINOL-PLASTONICS

INTERNATIONAL

(continued)

PYROITE II
200F

KVNAR
200F

STAINLESSSTEEL
316 70F

TEFLON FEP
70F

EWXV
70F

HASTELLOY C
70F

A Ia70F

Al4 7D~F

VINYL
ESTEA

THERMOSET 70F
mm

1ml"F

TEFLON PFA
200F
A

PYliy\TE
D
1

TABLE 1.24:

PHENOLIC

RESINS-OCCIDENTAL

CHEMICAL
Durez

The following
chemical resistance data was obtained
by exposing several
DUREZ
materials to common known chemical contaminants
for variable
periods of time and then calculating
the percent change in specimen dimensions
and weight.
The specimens were either 2 diameter
discs by
l/6. thick;
or X by I$ bars, 5 long. The appearance
of the afterexposed specimen was graded according
to the following
codes:
A - Smooth,
glossy
G -Wrinkled
B - Slightly
dull
H - Swollen
C - Dull
I - Cracked
D - Fiber shows
J - Warped
E - Pimpled
K - Blistered
F - Mottled
or unsigned
values indicate
specimen
growth
or weight
values indicate specimen shrinkage or weight loss.

Positive
negative

13856

% Change
Chemical
Acetic

Acid

(Glacial)

Acetic

Acid

(5%)

791

CHEXICAL

Black

% Change
Chemical

in

118

x 2

Diameter

Aretic

Acid

(5%)
Hydroxide

(10%)

Aniline
Tetrachloride

Cztric

Acid

Hydroxide

(cont.

Ammoxuum

Hydroxide

(10%)

Solution

Dimethyl

(0.25%)

Formamide

DistIlled

Acid
Acid

Detergent

Acetate

Ethyl

Alcohol

Ethyl

Alcohol

Ethylene

Hydrogen
Nitric

Acid

Oleic
Phenol

9.00

Hydrochloric

Acid

(cont.

1.20

Hydrochloric

Acid

Hydrofluoric

Acid

Acid

(cont.

(50%)

1.20

5.00

Nitric

Acid

0.06

Nitric

Acid

1.80

Oleic

Phenol

Soap

Sodium

Hydroxide

(10%)

Sodium

Hydroxide

(1%)

Sodium

Hypochlorite

Sulfuric

Acid

(30%)

Sulfuric

Acid

(3%)

Toluene
Oil

9.21

11.11

(10%)

2.70

6.40

8.20

(40%)

3.00

8.00

14.00

fuel

oil)

White

USP

38

I
1.10

I
1.70

5. a0

0.01

-0.39

0.21

0.04

-0.66

0.30

0.05

0.13

0.39

(40%)

(10%)

Acid
Solution
Solution

(5%)
(1%)

0.20

0.04

1.30

0.99

0.60

5.40

1.10

0.49

5.30

Sodium

Carbonate

(20%)

0. a2

0. a1

4.50

0.45

0.90

Sodium

Carbonate

(2%)

1.10

1.40

5.90

2.70

5.40

11.00

Chloride

4.50

9.20

Sodium

Hydroxide

(60%)

1.90

3.80

a. 50

F
G
G

So&urn

2.30

Sodium

Hydroxide

(10%)

1.60

3.00

7.10

Sodium

Hydroxide

(1%)

Sodium

Hypochlorite

I
7.00

3.20

(4-b%)

I
0.15

(10%)

(#Z

-0.29

2.71

(3%)

Nltrtc

Chloride

(28%)

Sodium

0.66

0. 36

Peroxide

Oil,

-0.31

2.10

Peroxlde

0.49

(2%)

4.70

0.21

Hydragen

-0.11

(5%)

-0.61

1.10

0.02

Hydrogen

0.09

(1%)

0.

(95%)

Carbonate

Turpentine

Dichloride

Mmeral

Sodium

Transformer

Ethylene
Heptane

Kerosine

Solution

1.17

-0.99
-0.44

3.20

(10%)

Solution

Acid

5.29

4.40

9.80

0.68

1.20

lsooctane

4.60

1.00

0.98

2.10

5.05

(50%)

(3%)

0.68

Alcohol

0.54

Peroxide

-2.29

1.00

Ethyl
G

0.87

-1.10

0.14

0.26

0.63

-0.55

0.29

0.20

0.21

(10%)

0.98

32

-0.37

0.09

a. 10

Acid

1.50
-1.

(95%)

0.18

0.25

30

Alcohol

a. 70

0. 36

8.

0.95

-0.18

Heptane

2.50

Ethyl

9.70

-0.25

1.80

Acetate

3.90

0.03

12.00

Ethyl

4.60

2.30

-0.39

5. 60

-0.16

Water

2.40

1.80

Dichloride

Hydrochloric

DIstilled

0. 56

18

13.00

17.00

0.14

-0.05

0.51

0.02

-0.75

0.05

-1.20

0.10

2.70

0.01

9.90

(10%)

1.00

(4-a%)

1.40

1.90
0.06

5.50

2.70

10.30

-7.90

13.00

Sulfuric

Acid

(cont.

Sulfuric

Acid

(30%)

3. 30

5.50

13.00

Sulluric

Acid

(3%)

0.94

1.50

4.90

TClhleIle
Trauaformer
Turpentme

0.
Oil

16

0.04
0.00

-0.02
1.00
-1.00

0. 61

0.02

-0.05

23-C.

5.50

3.90

0.12

FormamIde

12.00

-0.03

-0.22

(0.25%)

at

D 543-60T

Appearance

Weight
-0.03

1.60

0.65

Ether

2.10

32

(40%)

Solution

Dlethyl

Appearance

-0.72

-0.02

(10%)

0.09

Water

Ethyl

W+ight

-0.21

0.06
Tetrachloride

Exposure
ASTM

Thickness

0.

Citric

D 543-601

One-Year

bsk

Diameter

Benzene
Chromic

at 23-C.

x 2

Anll~ne

A
C
G
G

0.00

(10%)

Detergent

Thickness

-1.

-0.29

Carbon

iS.TM

5.00

2.40

Exposure

Disk

-0.35

-0.23

Ammonium

One-Year

6.00

2.90

Acetone

Soap

RESISTANCE

l/8

-0.04

Ammomum

Dimethyl

IIurez

RESISTANCE
in

1.10

Acetone

Carbon

gain;

CHEMICAL

Black

(continued)

TABLE 1.24:

PHENOLIC

Exposure

Material
Condition

and

RESINS-OCCIDENTAL

Chemical

Resistance

Various

Chemicals

to

X Change

X Change

Length

Thickness

for

(continued)

CHEMICAL

1 Week

Exposure

X Change
Width

2 Change

Uaterial

Weight

and

Condition

23570
l

.12

+1.34

.78

+ .8b

Boiling

10% E2SO4

.04

l1.20

.60

10% H2SO4

10% NaOH

.I3

+3.5a

+I.85

+2.24

10% NaOH

10% WOH

.02

.I5

.13

10% N-&+OH

.16

.lO

Leaded

.12

.lO

lo-30

-14

.I1

.Ol

Transmission

-1.23

.43

.03

Brake

Water

Leaded

Gasoline

Motor

Transmission

Brake

Resistance

Various

Chemicals

to

for

1 Month

X Change
Length

X Change
Thickness

X Change
Width

X Change

+2.73

+1.42

+2.64

Weight

23570

BoillnR

lo-30

Chemical

Oil

Fluid

Fluid

.88

.lO

50% Glycol

.Ol

.a7

.40

.09

50%

5% NaCL

.o:

.91

.46

.11

50% Alcohol

.Ol

.93

.45

.09

Water

.12

.03

Oil

Fluid

Fluid

Glycol

.28

.18

.13

.I0

.07

.09

.Ol

.14

.ll

.09

.98

.47

.07

Gasoline

Motor

.Ol

.23

-02

.90

.41

.20

5% NaCl

.03

.94

.44

.24

50%

.07

.63

.42

.20

Alcohol

Not

Deteriorated

Available

(continued)

TABLE

PHENOLIC

1.24:

RESINS-OCCIDENTAL

Chemical

Exposure

to

Various

CHEMICAL

(continued)

Resistance

Chemicals

for

and

Change

% Change

Length

Condition

-Thickness

X Change
- Width

Various

Chemicals

Material

and

to

X Change

X Change

Length

Thickness

.08

10% H2S04

10% NaOH

X Change
Weight

Condition

for

1 Week

X Change

%Change

Width

Weight

+1.09

.25

+6.95

+3.06

+4.56

.16

+2.54

+1.27

+2.48

29502

23570

Bolllng

Boiling

Water

10% B2S04

10% NH40H

Leaded

-34

Transmission

+7.11

Water

.24

.5fJ

10% NH40H

.90

.46

.11

.08

.02

Leaded

.77

.46

.06

.04

.04

lo-30

.BO

.43

.06

.14

.11

.Ol

Transmission

.64

.44

.02

.79

.39

.Ol

.92

.41

.lO

.80

.46

.06

.92

.40

.05

Fluid

Gasoline

Motor

.02

.98

.50

.17

Brake

50% Glycol

.06

.83

.33

.47

50% Glycol

5% NaCl

.08

.83

.36

.61

5% NaCl

50% Alcohol

.06

.82

.22

.47

50% Alcohol

Fluid

Not

Deteriorated

.55

.28

Brake

.64

.09

Oil

+2.56

Gasoline

Motor

+5.66

10% NaOH

lo-30

Resistance

6 Months
Exposure

Material

Chemical

Oil

Fluid

Fluid

.01

-01

.Ol

Available

(continued)

98
Corrosion Resistant Materials Handbook

::
0;
+

x
Y;
+

8
A
+

2
+

2
+

z
+

::
+

z
+

2
+

1.

z
+

TABLE 1.24:

PHENOLIC

RESINS-OCCIDENTAL

CHEMICAL

(continued)
Chemical

Chemical

10

Days

in

25OF

Vapor

at

X Change
Weight

Material

Resistance

96

16 psls

Change

Pressure

X Change
-Diameter

-Thickness

Appearance
Code

156

1.72

.76

.50

165

2.17

1.19

.73

B, E. K

13856

2.64

1.24

.05

.92

.66

22829

1.98

30169

3.27

2.55

1.22

30698

1.74

.a7

.57

Chemical

10

Days

in

25OF

X Change
H.3teria1

Weight

156

2.67

Water

Resistance

ilt

16

2 Change
Diemeter
-

Code

1.03

1.55

3.00

13856

3.56

1.11

30169

3.75

Appearance

2 Change

165

2.20

Pressure

-Thickness

1.74

22829

psis

.77

1.. 09

-95

.59

B, E, K

30698

1.97

.80

In

Boiling

Water

X Change

X Change

Material

Weight

Thickness

111

7.24

5.72

1.71

8.

118

7.68

4.45

1.23

B.

123

5.14

6.03

1.26

B.

145

2.36

1.13

.63

B.

152

4.13

2.33

1 .oo

4.05

Change
Diameter

Appearance
Code

153

5.00

1.19

C.

156

2.09

.92

-48

B,

161

3.39

1.46

.76

B,

165

1.62

.60

.33

791

6.24

3.61

1.64

B,

3948

6.42

4.49

1.67

3856

3.80

1.70

.91

14900

2.82

1.21

.60

B,

16378~

3.39

1.65

.64

B.

18420

6.17

3.13

1.60

18441

6.79

3.47

1.76

21028

6.44

3.35

1.88

B,
A

21210

7.52

5.11

1.00

22257

7.08

4.02

1.63

23570

1 .oo

.22

.I5

29237

6.20

5.03

1.19

B.

D,

30270

2.77

1.30

.69

B.

30614

.a9

.32

.21

2.14

.59

.34

30698

3.00

1.20

30806

3.20

30645
2.59

Rours

Resistance

1.28

.52

.9O

.80

A.

.80

B.

(continued)

TABLE 1.24:

PHENOLIC

RESINS-OCCIDENTAL
Chemical

96

Rours

in

X Change

Naterial

We IRh t

BoilinR

CHEMICAL

(continued)
Chemical

Resistance
Sulphuric

X Change
Thickness

Acid

96

(H2S04)

X Change

Appearance

Diameter

Code

Hours

X Change

In

Boiling

Resistance
Caustic

X Change
Thickness

(.5%

NAOH)

X Change
Diameter

Flaterial

Weight
9.41

7.88

.90

Appearance
Code

111

18.49

15.58

2.72

C.

F.

111

118

24.53

14.15

2.59

C.

D.

118

12.88

4.32

1.26

B,

123

16.46

15.29

2.80

B.

H,

123

7.36

6.54

1.44

R,

145

7.92

12.76

1.25

C.F

145

4.89

1.17

.77

R.

152

15.14

12.39

2.25

C. F

152

4.64

2.57

1.19

B.

153

11.58

11.14

2.19

C. F

153

6.38

5.54

1.47

C,

1.51

1.18

.63

B.

R,

C.

156

11.17

10.36

1.27

C. E. F

156

161

4.71

3.74

1.02

C. F

161

3.96

1.79

1.00

165

1.63

1.25

.61

C. F

165

2.14

.81

.49

791

17.66

13.93

7.20

C, D. H

791

7.16

4.39

1.87

B,

3948

10.20

7.31

2.43

B,F.R.J

3948

7.29

4.75

2.10

7.10

4.55

1.56

13856

3.91

1.80

.94

R,

C.

14900

2.87

1.38

.62

B,

3.69

1.90

.79

B,

13856

8.76

8.01

1.13

16.75

11.37

.60

D,

16378A

18420

6.05

3.55

1.78

B,

18420

6.64

3.89

1.71

18441

8.84

4.98

2.27

R,

D,

18441

7.27

3.84

1.84

B.

21028

26.67

16.66

4.89

C,

D.

21028

2.10

C.

14900
16378A

21210

12.03

10.57

J
F

23570

1.05

.31

.22

3.30

C.

D,

29237

5.76

.57

1.22

C,

3.73

1.33

B.

E.

30270

3.65

8.08

.94

B,

E.

30614

29237

22.03

15.80

30270

5.21

30614

4.91

3.91

1.88

E.

8.84

7.10

2.27

5.84

H.

12.92

7.41

30698

9.36
8.16

C.

16.76

30806

B.C.H,J

6.31

C.

22257

25.75

4.21

22257

23570

30645

2.39

7.68

21210

2?.56
2.73
3.53

2.53
.86

3.59
.93
1.66

.99

2.05

.90

.55

.24

R.

-33

C.R.C.R.1

30645

2.23

C.

30698

3.12

1.32

.82

R.

30806

3.70

1.12

.91

.59

D,

(continued)

TABLE 1.24:

PHENOLIC

RESINS-OCCIDENTAL

CHEMICAL

(continued)
Chemical
96

Material

Change
Weight

111

8.05

2
chemical
168

Hours

(7

Days)

in

Sodium

Aypochlorite

(52

NeOCl

X Change

2 Change

Thickness

Diameter

at

Appearance
Code

118

6.08

1.80

.84

123

4.22

1.99

.83

165

1.6C

.55

.47

C.

D.

791

3.18

1.65

C,

1.01

3940

4.05

2.02

1.21

C.

13856

2.90

1 .Ol

.71

C.

14900

1.18

.41

.27

C.

18420

4.26

1.93

.14

C,

18441

4.89

2.39

1.28

C.

21028

1.46

.93

C.

22251

4.58
2.92

.67
2.70
1.95

1.47
.93

C,
C,

2, Change
Thickness

(5%

Ivory)
X Change
Diameter

Appearance
Code

6.16

1.79

C,
C

118

11.46

5.48

1.49

123

2.96

6.72

1.51

C.

145

2.26

1.24

.52

C.

152

4.45

2.65

.99

153

5.77

4.58

1.37

f
156

2.11

1.09

.37

C.

161

3.51

1.73

.88

165

1.92

.64

.43

C,

791

7.43

4.45

1.93

S.

3948

8.13

5.76

1.99

C.

13856

3.70

1.70

.80

B,

14900

2.94

1.37

.62

8,

16378~

3.47

1.78

.73

B.

18420

7.40

4.11

1.93

C.

18441

7.59

4.07

2.01

B,

21028

7.44

3.90

2.12

C,

21210

9.34

6.66

2.36

B.

22257

8.58

6.30

1.95

C.

23570

1.01

.26

.19

2.65

1.32

.76

30614

1.28

.03

-07

C,

30645

1.41

.31

.33

C.

30698

.83

.02

.50

C,

.50

.43

C.

D,

1.61

Soap

30270

30806

Boiling

50-c

)lateria1

21210

In

Resistance

Change
Weight

Hours

Resistance

F
29237

7.39

8.02

30270

3.34

1.61

.88

30614

1.00

.39

.24

30645

2.34

.49

.33

30698

3.21

1.10

.a3

S.

30806

3.50

1.10

.80

B.

1.55

C,

D.

TABLE

1.25:

PHENYLENE

OXIDE-BASED

RESIN-GENERAL

ELECTRIC

COMPATIBILITY

NORYL
resins are especially noted for their outstanding
hydrolytic
stability.
The water absorption rate of all NORYL
resins, both at room temperature
and
at elevated temperatures,
are among the lowest of any engineering thermoplastic, which contributes
to the retention
of properties
and dimensional
stability
in the presence of water, high humidity
and even steam environments.
In addition,NORYL
resins are also virtually unaffected
by most aqueous solutions, detergents, acids, and bases.

TESTING

PROCEDURE

Introduction
This test is used as a method for predicting the longterm effects of contact materials or environments
on the
physical properties of Noryl.
The test uses specimens
which are exposed under strained conditions at various
temperatures
duplicating as closely as possible the effect
of residual and induced stresses in a fabricated part.
By
measuring the loss of certain physical properties we can
estimate the effects of exposure to the environment on a
Noryl application.
Test Procedure

NOSYI
QFN3Rssti

NORYL
731,831 Resin

Nom-l.
QFNZ Ream

APPUd%WS.Pl

0 8.ooO 0 WC0

0 3aOO

0 38ooApplied~,pSi

0 8Dw

HJdEdl0mACid(lcrrs)

Ii

IiJdmao~Acid(mnc.)

-Aud(lc%)

-And(m)

NN

NA

-Aua(m)

BA

IU?MCAdd(lulb)

NoiricM(lm)

NN

NX

-emc@Jm>

KTdmfmo*Add(m)

-UtUEi

NNNNNNN

W(lW)

x
x

aEcade(lB)

NNNNNNNN

OlelcAcld

NNANNNA

MamiacQmo11

NNANANA

Unssedoli

Unenrloil

NNNNNNNA

vammle

NNNNNNNA

x
x

xliaptane

bm,haml

NNNANNNN

Impropanoi
EthylcmeQlycai

NNNANNNA

Ammonia

NNXXXXXX

Qulf_~Ofi

NNNNNNNN

-w(lm)

NNNNNNNN

Ryhon

NNNNNNNN

-ImF=Jdee(mno.)
dmmonflno

phosphate(~)

NNNNNNNA
NNNNNNN
N

GE.6lllmneC)-e87

NNNNNNN

Hcw&tm6&6SO

NNNNNNN

--(sat)

LlcmeaQmao

NNNNNNNX

--(eat)

NNNNNNNN

lnm6cm/m

NNNNNNNN

-O-illoIlds(Bat)

NNNNNNNN

BesterNo.

13.5

NNNNXXNN

QOKIX

NNNNNNNN

NesterNo

164

NNNNXXNN

Lesml(28)

NNNAXXXX

NNNNNNN

2.

Test

3.

Apply the contact material to the tensile bars making


sure the material is in direct contact with the bars.
If the material is a piece of tubing or gasket material,
it may be secured by using a copper wire to tie it to
If the material is a liquid, the tensile
the tensile bar.
If the
bars and strain jigs should be totally immersed.
material is a grease or paste, coat the tensile bars.

0 3800 0 3800

4.

xxx

AAANALXX

2EP

Place the tensile bars in the strain jigs which dupliFor a standard
cate the stress levels to be checked.
test use 0%. l/2% and 1% for unfilled grades and O%,
l/4% and l/2% for glass-filled
grades.
a minimum

of 3 tensile

bars

for each stress

level.

TwsEl

0 6,CM

NORYL
Resin

1.

Place the specimens in suitable containers and place


one set in an oven for 3 days at 185'F and the other
leave out at room temperature for 7 days.
Example:

If testing a material with NORYL


number of specimens would be:

731 the

0%

l/2%

1%

3 days

@ 185O~

=9

7 days

@ RT

=9

Total 18
5.

At the duration of test, remove the specimens from the


oven and leave at room temperature
for a minimum of 30
minutes.
Then use the Instron to determine tensile
strength and % of elongation.

Reporting

Results

The contact material is considered compatible if there is no


cracking, embrittlement
or less than 10% loss in tensile
properties.
The material is considered marginal if there is
no cracking, crazing or less than 20% loss in tensile properties.
An incompatible material is one which cracks, crazes or
loses more than 20% of its tensile properties.
(The above
are compared against a control).
(continued)

TABLE 1.25:

PHENYLENE

OXIDE-BASED

RESIN-GENERAL

ELECTRIC

COMPATIBILITY

Effect en
731

Aggres

(continued)
TESTING

RESULTS

Effect

Norvl

N-190

siveness*

731

Aggres-

Aggres

en

Nor!1

N-190

A5grcs-

siveness*

siveness'

siveness'

n-PtntAne

Qlase

Craze

n-IItxk7e

Craze

craze

Ethy~ne

No

CctAne

Cr*se

Qaze

Ethyltncdiamine

No Effect

Dodccane

Cr*ze

Craze

Diethylamine

SW811

Swell

n-Amylarome

Qack

swell

hiethylamine

Crack

Crack

Aromatic

Effect

NC

Effect

No Effect

Toluene

Solvent

Solvent

Ketones

Xylem

swell

Swell

Acetone

Craze

Craze

Methyl ethyl ketone

Well

swell

V
V

Hethyl propyl Ketone

SW11

swell

mtiyl

Crack

Crack

Methyl phenyl ketone

Craze

Iscphorone

Crack

aazt=
QaZe

Cyclohexmone

Solvent

Swell

Swell

SVISll

!4

Crack

Swell

Qack

Swell

n-Propyl acctAt-e

SW11

Swell

isopropyl acetate

Crack

we11

Acetic anhydrlde

No Effect

No

Propionic anhydride

Crack

Craze

Alcohols

No

Effect

Qare

Et!!nol

NO

Effec?

craze

Isopropanol

No Effect

n-Butin

No Effect

Pentan

Craze

Isohexanol

No L=fcct

OCtanOl

NO Effect

Methan

2-Ethyl B-01
Trimethyl-3.5,

5-3-huancl

U-are

Craze
Craze

Craze

Craze

Qaze

Qate

Acetates

Ethyl

Solvent

Solvent

Solvent

Solvent

Trxhloroathylene

Solvent

Solvent

l,l,l-hichloroethme

Craze

Craze

1.1,2-hichloroethane

Solvent

t4

Solvent

Chlorobentcne

Solvent

Solvent

Chloroform

craze

Chlorinated

Chloride

Q*2.S
S

Methyl

Methylem

iscbatyl ketone

acetate

acetate

Anhydrides

AggressivencsS:

S-Slight, M - Moderate. V - Veri

Effect
S

104

Corrosion

TABLE

1.26:

Resistant

Materials

Handbook

POLYALLOMER-EASTMAN

CHEMICAL

PRODUCTS

The effects of various


chemicals
on TENITE
Polyallomer
Formula
5020 were determined
by
and measured
injection-molded
samples of the plastic in the chemicals and maintaining
them
73F (23C) for one year. After one year, each sample of plastic was removed
from the jar in
wiped dry, and quickly
weighed
and measured. The appearance
of the sample after exposure
was also recorded.

immersing
weighed
at a temperature
of
which
it was tested,
to the test medium

The shelf-life
tests were conducted
using 50 ml capacity,
0.010 inch (0.25 mm) wall thickness
blow-molded
bottles
of TENITE
Polyallomer
5020 filled with selected household
items. The filled bottles were stored at temperatures
of 73F (23C) and 140F (60C) for one year. Changes in bottle
weight
and
appearance
were
determined
at the
end

of

the

test

period.

Polyallomer
is highly
resistant to chemical attack and to stress-cracking.
and attack
the surface slightly.
These chemicals
are mainly
chlorinated
the higher aliphatic
hydrocarbons,
such as gasoline.

Resistance

of TENITEE

Polyallomer

[Exposure:

One

5020

Year

WeIghI. 0i0 Thickness.

4,

5L<

Cl 04

c 28

Nc Ciange

lsooctane

cone

? ?8

i^ 33

NC Change

Kerosene

1 94
0 01

c 74

NC, Change

lysol

Ace;one

ChaII#E

Raagenl

Acellc

Chemicals

(23(Z)]

WeIghI, % Thicknass.
6 30
15 90

Appearance

Ace:~c Acid
Acid

to Various

at 73F

Change in

Reagent

However,
a few chemicals produce swelling
compounds,
aromatic
hydrocarbons,
and

1750

ifl

% Appearance
B.lt.stered. Discolored.

Swollen

5 50

BlIstered,

Swollen

DIscolored,

DIsInfectant

0 11

0 12

No Change

0 04

Nc Change

Methyl

Alcohol

0 12

0 08

No Change

Ammonium

Hydroxide

cone

0 37

c 04

Sli;htly

D~scolore:!

Mmeral

011

0 59

0 12

No Change

Ammomum

Hydroxide

10%

0 13

0 20

Slqhtly

D~scolorec

Molasses

0 03

0 28

No Change

15 10

5 70

Swollen

Mouthwash

0 35

0 16

No Change

c 38

0 12

NC Change

Mustard

6 04

0 12

No Change

6; 50

11 20

Swollen

Nltrlc

Acid, cone

4 70

0 45

Badly DIscolored

-0 08

c 04

Sl~;h!ly

Nltrlc

Acid.

40%

0 79

0 16

Slightly

DIscolored

(1 08

0 08

No Change

Nltnc

Acid,

10%

0 02

0 08

Slightly

DIscolored

0 03

0 12

No Change

Olelc Actd, 03%

0 51

0 12

No Change

Aicorrox

Decrgent

(0 25,L!

Benzene
Brake

Fluid

Carbon

Tetrachlorlde

Chromic
Citric

Acid. 40%.

Acid.

10%

Coffee

DIscolored

011

c 05

0 08

No Change

Ohve 011

0 04

0 08

No Ghange

Dibatyi

Sebacafe

1 51

0 29

No Change

Orange

Drink

cl 05

0 04

No Change

Dlerhyl

Ether

14 10
0 20

5 so

Sfiollen

Phenol,

5%

0 04

0 08

No Change

0 08

No Change

Soap Solution,

0 01

0 04

No Change

0 37

0 20

No Change

Sodium

Chloride,

-0 01

0 00

No Change

0 01

0 04

No Change

>odlum

Cabonate.

2090

0 04

0 04

No Change

0 ia

0 24

No Change
No Qlange

Cottonseed

DI 2-Ethyl
Dlme:hyl

Hexyl

Pn!halate

Folmarmoe

Delomzed

Water

1%
10%

Ethanol

100%

0 26

0 12

No Change

Sodium

Carbonate,

2%

Ethanol,

50%

0 07

G 21

No Change

Sodtum

Hydroxide,

10%

-0 03

0 00

5 20

1 60

No Change

Sodium

Hydroxide.

1%

-0 01

0 04

No Change

Sodium

Hypochlorite,

0 08
-0 03

0 12

Discolored

Ethyl Acetate

3 5%

Ethylene

Dichlortde

10 60

1 90

Si4ollen

Gasolme.

Regular

19 40

7 60

BlIstered,

Sulfuric

Acid, cone

0 04

DIscolored

Gasolme.

High Test

17 60

6 80

Swollen

Sulfuric

Acid.

30%

-0 005

0 12

No Change

16 90

6 70

Swollen

Sulfunc

Acid,

3%

-0 008

0 08

No Change

19 50

6 20

BlIstered.

0 07

0 08

No Change

3 50

1 50

No Change

23 70

7 50

Blrstered.

Hexane

Swollen

Hydrochlonc

Aud,

cone

0 11

0 24

No Change

Toluene

Hydrochloric

Acid.

10%

0 01

0 08

No Change

Tomato

Hydrogen

PeroxIde.

28%

Hydrogen

Peroxide,

3%

lodme

Juice

0 01

0 08

No Change

Transformer

-0 01

0 16

No Change

Turpentme

011

0 08

Stalned

011

Swollen

Swollen

(continued)

Synthetic

TABLE 1.26:

POLYALLOMER-EASTMAN

Shelf-Life

CHEMICAL

PRODUCTS

Resins and Polymers

(continued)

Data on Blow-Molded Bottles of TENITE@ Polyallomer


[Exposure: One Year at 73 F (23 C)]

5020

Change In
Weight. %

Appii~llC8

Mustard

-0 33

No Change

Molasses

-0.13

No Change

Orange Ormk

-1.66

No Change

Mouthwash

-1 14

No Change

Tomato Jurce

-1.06

No Change

Coffee

-0 61

No Change

Lysol Drsinfectant

-0 14

No Change

lodme

-1.69

No Change

-0 12

No Change

Shoe Polrsh

-0.29

No Change

Margarme

-0 07

No Change

Grape Jurce

-1.00

No Change

Cheese Spread

-0.32

No Change

Grape Jelly

-0.42

No Change

+o 14

No Change

ivory Detergent,

1%

Peanut Butter

Shelf-Life

Data on Blow-Molded Bottles of TENlTE@ Polyallomer


[Exposure: One Year at 140 F (60 C)]
Changs
In

fleapent
Walght. %

Appanncs

Mustard

-4.2

No Change

Molasses

-3.9

No Change

Orange Drink

-10.8

No Change

Mouthwash

-24.0

No Change

Tomato Juice

-5.0

No Change

Coffee

-9.1

No Change

Lysol Disinfectant

-6.0

Bottle Stained

-31 .l

Bottle Stained

iodine
ivory Detergent, 1%

-4.0

No Change

Shoe Polish

-4.1

No Change

Margarine

Bottle cracked at seams in

Grape Juice

-5.0

No Change

Cheese Spread

-6 7

No Change

Grape Jelly

-6.5

No Change

Peanut Butter

1 day

Bottle cracked at seams in four weeks

5020

Corrosion

706

TABLE 1.27:

Resistant

Materials

Handbook

POLYCARBONATE-MOBAY

CHEMICAL

The combination
of mechanical
and optical properties
offered
of the characteristics
of a transparent
metal. It is a thermoplastic
toughness,
and a temperature
capability
up to 250F.
Because of a combination
bonate sheets are finding

MERLON

is resistant

of optical
application

characteristics,
impact strength,
and dimensional
stability,
MERLON
as glazing, especially
in those areas where glass breakage is high.

at room temperature

Industrial

Acetic acid (20%)


Aluminum
chloride
Aluminum
sulphate
Ammonium
ctiloride
Ammonium
nitrate
Ammonium
sulphate
Antimony
trichloride
Arsenic
acid (20%)
Butyl alcohol
Calcium
chloride
Calcium
nitrate
Chlorinated
lime paste
Chlorinated
lime solution
Chrome
alum
Chromic
acid (20%)
Citric acid (40%)
Copper
chloride
Copper sulphate
Cuprous
chloride
Cyclohexane
Decahydronaphthalene
Ethyl alcohol
(96%)
Formic
acid (10%)
Formalin
(30%)
Glycerine
Glycol
Hydrochloric
acid (10%)
Hydrochloric
acid (20%)
Hydrogen
peroxide
(30%)
Hydrofluoric
acid (20%)
Iron chloride
Iron sulphate
Isoamylalcohol
Lactic acid (20%)
Magnesium
chloride
Magnesium
sulphate
Manganese
sulphate
Mercuric
chloride
Nickel
sulphate
Household

Nitric
acid
Nitric
acid
Dleic acid
~,xxa$$id

(2%)

Chocolate
Cinnamon
Cod tiver

(10%)
(20%)

Petroleum
ether
Phosphoric
acid, cont.
Propyl alcohol
Potassium
aluminum
alum
Potassium
bichromate
Potassium
bromate
Potassium
bromide
Potassium
chloride
Potassium
nitrate
Potassium
perchlorate
Potassium
permanganate
Potassium
persulphate
Potassium
sulphate
Propargyl
alcohol
Propionic
acid (20%)
Silicone
oil
Silver nitrate
Sodium
bicarbonate
Sodium
bisulphate
Sodium
bisulphite
Sodium
carbonate
Sodium
chlorate
Sodium
chloride
Sodium
hypochlorite
Sodium
sulphate
Stannous
chloride

Mineral
heating
zvtse$water

Detergents
(nonionic
Fish 011
Floor polish
Fruit syrup
Glaziers
putty
Grapefruit
iuice
gcps;f~tt
peel
Ink
Insulating
tape
Linseed
oil
Linseed
oil standard

and

anionic)

MERLON

has

limited

Petrol
Refined
oil
Spindle
oil
Transformer
oil
Vacuum
pump oil

resistance

Orange
jurce
Orange
peel
Paraffin
oil
pepper
Rapeseed
011
Rum
Salad oil
Salt solution
(10%)
Soap (soft and hard)
Table vinegar
Tincture
of iodine (5%)
Tomato
concentrate
Tomato
juice
Turpentine
Vodka
;;&ng
soap

varnish
Wine

to:

Cycloheranol
Gasoline
(high aromatic)
Hydrochloric
acid (cont.)
M~RLOW is not
Acetaldehyde
Acetic
acid
Acetone
Acrylonitrile
Ammonium
;;nyz;$rn

resistant

Milk of lime
Nitric
acid :conc.)
Sulfuric
acid (cont.)
to:
Ethane
tetrachloride
Ethylamine
Ethyl ether
Ethylene
chlorohydrin
Formic
acid (cont.)
Freon*
(refrigerant
& propellant)
Nitrobenzene
;;t;o;fllulose
lacquer

(cont.)

fluoride
sulfide

Benzoic
acid
Benzyl
alcohol
Bromobenzene
Butyric
acid
Carbon
tetrachloride
Carbon
drsulfide
Carbolic
acid
Caustic
potash
solution
(5%)
Caustic
soda solution
(5%)
Chlorobenzene
Cycle hexanone
Cyclohexene
Dimethyl
formamrde

lDupont
unstressed
MEaLon

trademark,
MERLON

is dissolved

except
at room

Phosphorous
hydroxy
chloride
Phosphorous
trichloride
Propionic
acid
5$cJr~n~ sulfide
Sulfuryl
chloride
Tetrahydronaphthalene
;f$.x$~ne
Xylene
Freon
113,
temperature.

which

may

be

used

by:
Ethylene
Methylene
Pyridine

dichloride
chloride

oil

$$ar~il

%z!

Products

Chloroform
Cresol
Dioxane

Materials

oil

Petroleum

Axle oil
Brake fluid (room temp.)
Compressor
oil
Diesel oil
Gasoline
(low aromatic)

~~!$~:ic
acid (10%)
Sulphuric
acid (50%)
Tartaric
acid (30%)
Trichloroacetic
acid (20%)
Zinc chlorrde
Zinc sulphate

Beer
Borax
Cocoa
~~Z;;;il

polycar-

to:

Chemicals

Common

by MERLON
gives the designer a material with many
which provides good optical properties,
exceptional

Dimensional

Change

Water A$sorption

vs. Per Cent Water Absorption

DimenGo,~nChartge
Conditions

I
I

MERLON

Samples

Original

0.0003

50%

0.0013

Room
Boiling

0.0008

Aged in Hot Water for 6 Months

Dimension
(Inches)
1.3373
1.3374
0.8735

0.0
R.H.
Temp
Water

(212F)

Dimension
after
6 months
immersion
(Inches)
1.3382
1.3390
0.8740

on

Synthetic

TABLE 1.28:

POLYESTER

ENGINEERING

RESIN-DART

Resins and Polymers

INDUSTRIES

XYDARM RESINS
CHEMICAL
TENSILE

STRENGTH

AND ELONGATION

Original Value
60% RH (5 wks. @ Rm. Temp.)
Water (200 Hrs. @ llOC)
Water (30 days @ 82'C)
Acetic Acid (1 week @ reflux)
Ethyl Acetate (1 week @ reflUX)
Bleach (1 month @ 5O'C)
Brake Fluid (1 month @ 50C)
10% NaOH (1 month @ 5O'C)
Transmission
Fluid (1 month @ 50Cl
Motor Oil (1 month @ 5O'C)
Skydrol (2 weeks @ 71'C)
Antifreeze
(1 month @ 5O'Cl
20% ~~S04 (1 month @ 50C)
37% ~~S04 (1 week @ 50C)
100% H2S04 (1 week @ 5O'C)
20% HCl (1 month at 50C)
70% HNO~ (11 days @ Rm. Temp.)
Gasoline (Leaded) (1 month @ 50C)
MEK (1 week @ reflux)
Isopropyl Alcohol (1 week @ reflux)
JP-4 (1 month @ 5OC)
Detergent (1 month 4 5O'Cl
Trichloroethylene
(1 week @ 5O'C)
(*l % Decrease in tensile
30%; D = >30%.

strength

RESISTANCE
BEFORE

AND AFTER

XYDAR- SRT-300
Tensile
Elong
Rating
(%l_
(psi)
16810
4.9
16900
A
3.0
13770
B
4.9
15900
A
3.3
17290
A
3.9
16290
A
3.1
16640
A
3.9
16390
A
3.8
16010
A
3.4
17320
A
3.6
17090
A
4.7
17940
A
3.9
17990
A
4.2
17230
A
3.9
15600
A
3.2
----Disintegrated---16520
A
3.6
16400
A
2.8
16840
A
4.3
16200
A
3.2
17680
A
4.4
16860
A
5.1
17800
A
5.1
19000
A
4.0
after exposure

EXPOSURE(*)

Tensile
(psi)
17730
17000
13380
17100
15420
18160
16920
17540
16490
17220
17580
17280
17700
17600
11080

XYDAR-

SRT-500
Elong.

Racing

(%C

B
A
A
A
A
A
A
A
A
A
D

4.8
3.1
4.2
3.4
3.2
4.0
3.1
3.8
3.3
4.0
4.6
3.7
2.8
3.8
3.6

17410

3.5

16840
18150
19420
17030
16840
19900

A
A
A
A
A
A

4.9
5.4
6.0
4.8
4.9
4.1

A
C

- A = 0 to 10%; B = 11 to 20%; C = 21 to

107

108

Corrosion

TABLE

1.29:

Resistant

Materials

POLYESTER

Handbook

LAMINATES-HAYSITE

REINFORCED

PLASTICS

HCR-191
is a chemical resistant polyester laminate produced by the match metal molding of fiberglass mat, inert
fillers and HETRON@
197 resin. HCR-191
laminate when compared to other corrosive resistant materials offers excellent weight to strength ratio (specific gravity of HCR-191-1.9
. . stainless steel-8.0)
and ease of handling and
fabrication.
HCR-196
is a chemical resistant polyester laminate produced by the match metal
fillers and DERAKANEB470
resin. The DERAKANEB470
is a vinyl ester resin.
HCR-197
is a chemical resistant polyester laminate produced by the match
fillers and ATLAC
382 resin. The ATLAC
382 system is bisphenol A fumarate

CHEMICAL

RESISTANCE

Concentration Temp.
Materials

Acetlc Acid
Acetic Acid
Acetlc Acid. Glaclai
Acetlc Acid. Vapor 8 C:ondensate
Acetophenone
Aluminum Tnchlonde
Aiumlnum Fluonde
2.Ammoethanol
Ammoma Aqulous
Ammomum Chlonde
Ammomum Fluonde
Ammomum Hydroxide
Ammomum Nltrate
Ammowm
Persulfate
Ammomum Phosphate, Monobasic
Ammorwm Salt of Pnmary Alcohol
Glycol Ether Sulfate
Ammomum Sulfate
Ammomum Thiosulfate
Amy1 Acetate
Amy1 Alcohol
AnlIme
Antimony Pentachlonde
Antimony. Tnchlonde
Antimony. Tnchlonde
Banum Carbonate
Banum Chlonde
Benzene
Benzene Disulfonic Acid
Benzene, Sulfontc Acid
Benzolc Acid
Bromme, Dry Gas
Butyl Acetate
Butyl Carixtol
Butyl Phthalate
Butyric Acid
Calwm Chlorate
Calcium Chloride
Calccum Sulfate
Caprylic Acid
Carbon Dioxide
Carbon Tetrachlonde
Chlorine Gas, Dry
Chlonne Gas,Wet
Chlorofluocarbon

Note: S -

F.

25
10
100
25
100
40
100
100
28
45
40
20
45
25-100
65

210
65-95
100
180
75
210
75
05
80
200
150
150
200
150
225

S
S
S
S
S
S
S
S
S
S
S
S
S
S
S

100
60
60
100
100
100
100
50
100
100
100
100
100
25
100
100
100
100
100
20
All
All
100
100
100
100
100
100
100

100
250
100
75
200
125
75
200
75
250
250
75
194
200
250
75
75
85
100
200
250
250
250
140
250
120-122
40
220
158

S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S

s
S
S
S
S

of fiberglass

mat,

inert

metal molding
resin.

of fiberglass

mat,

inert

DATA OF HEIRONe

Test
ReSUI1S

molding

Materials

197
Concentration
%

32
Chromic Acid
Sat
Chromous Sulfate
All
Copper Chloride
All
Copper Cyamde
Sat
Copper Nltrate
100
Dtbuty Phthalate
100
Diesel Fuel
1iW
DIethanoI Amme
100
Dlethyl Sulfate
100
Dlethylene Gycol
Dlethylene Gycol N-butyl Ether
100
100
Dilsobutyl Phthalate
100
Dodecene. trace WI
Sat
Ethyl Acetoacetate
Ethyl Alcohol
o-95
Ethyl Chlonde
100
Ethylene Chlorohydnn
100
Femc Chlonde
100
Fernc Nttrate
100
Ferrous Sulfate
100
37-44
Formaldehyde
Gasoltne
100
Glycenne
o-75
100
Heptane. Vapor 8 Condensate
Hydrochlonc Acid
O-20
Hydrogen Chlonde Gas
100
Lead Acetate
All
Magnestum Carbonate
TM)
Mercury
100
35% So Vapor
Nitric Acid
Perchlonc Acid
O-72
Stanmc Chlonde
100
Steanc Acid
100
Sulfunc Actid
O-50
Tetrapotassium Pyropl losphate
60
1.l .l-Tnchloroethane
100
100
Trimethyl Carbinol
100
Tnphenyl Phosphite
100
Trisodium Phosphate
O-50
Urotroptne
28
Xylene
100
21nc Chlonde
70
Zinc Hydrosulfite
Sat.
Zinc Sulfate
All

Temp.
F.
140
150
250
250
140
100
75
75
100
100
85
80
120
80
150
75
200
250
250
250
150
194
250
120
230
392
250
250
250
200
85
75
250
200
125
80
80
100
122
75
00
100
300-310
160
250

Test
Results
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S
S

S
S
S
S
S
3
S
S
S
S
S
S
S
S
S

S
S

Satisfactory

(continued)

Synthetic

TABLE

1.29:

POLYESTER

LAMINATES-HAYSITE

REINFORCED

PLASTICS

Chemical Resistance of Dow DERAKANE


MAXIMUM

SERVICE

CONCENTRATION
%

CHEMICAL
ENVIRONMENT
Acebc Acld
Acebc Acld
Acetlc AnhydrIde
Acetone
Ac,d Cleaner
hydrochloric
acld
Acrykc Acid
Ally1 Chloride
Alkyl Benzene Sulfow Acld
Alummum Chlonde
Alummum Chlorohydroxld.?
Aiummum Nitrate
Alum~nw Sulfate
Ammo,um
Chlortde
Ammonun
Phosphate. dlbaslc
Ammomum Thlocyanate
Ammonium Thwxulfate
Barlum Sulfate
Benzaldehyde
Benzene
Benzene, Ethyl Benzene
Basulflte I Scrubber
Black Liquor recovery

25
50
100
10

31.

_
25
A,,
92
All
50
10
All
All
65
50
60
A,,
100
100
I/32/3
Gases
_

Bow Acld
Brine
Butrylc Acid
Capryl~c Acid
Carbon Tetrachlortde
Chlonne dry gas
Chlorine. wet gas
Chloroacetlc Aod
Chromic Acid
Copper Matte Dtpping Bath
3Oo FeCI3. 19% Hydrochloric

TEMPERATURE

VS CHEMICAL

MAXIMUM
F/C

CHEMICAL
ENVIRONMENT

210199

180/82
loo/38
180/82
190188
100138
80127
120149
2501121
210199
180182
2501121
210/99
210199
100138
100/38
250,121
70/21
100138
100/38
350,177

100
All
A,,
100
A,,
100
100
100
50
20

3501177
200193
210/99
210/99
120149
210/99
180182
250/121
2501121
150165
150165

200/93

CHEMICAL

(continued)

470 Resin

ENVIRONMENT

CONCENTRATION
%

Dethano, Amine
Dlethylene Glycol
Dwobuty Phthalate
Ethanol
Ethyl Alcohol
Ethyl Benzene Benzene
Ethylene Chlorohydrln
Erhy, Sulfate
Femc Chloride
Hydrochloric Acld
Formic Acid
GaSOllne
HeptZle
Hydrobromlc Acld
Hydrochlonc Acld
,sopropy, Myrlstate
Jet Fuel (JP-4)
Lead Acetate
M&c
Acld
Morphollne
Naphtha
N,tr,c Acid
Oxakc Acld
Phenol S,fo,c Acid
Pla,lm
Piatlng Solution
Propvavc Acld
Sodium Chromate
Sodlum Hydronde
Sod,m Lauryl Sulfate
Stvrene 80 F Bath

120149
210199
150/65
100138
W/38
120149
100/38
100138

29 185
All
100
100
62
37
_

180182
100/38
180/82
210199
100138
180/82
2301110
180/82
230/110
2501121
80127
210199
80127
210199
80127
180182
100138
210199
180182
160171
120149
3001149
100138
100138
3001149
3101154
2501121

A,,
100
100
40
Ali
65
100
50
10
Ail
100
_
75
Ail
_

_,
Transformer 011s
Z,nc Chloride
Zinc Sulfate

OF ATLAC

MAXIMUM
FIC

30
100
100
95
All
213 l/3
100
100

/1)

RESISTANCE

Resins and Polymers

70
Al,

382

The data below represknt the current knowledge of corrosive envlronmental conditions which Atlac 382 blsphenol
A fumarate resin will withstand when properly used In relnforced olastlc laminates:
CHEMICAL
Acetic Aad
Acetic Acid
Acetic Acld
Ammonium Hydroxide
Ammomum Chloride
Ammonum
Sulfate
Amvl Alcohol
B&l Alcohol
C&urn
Chloride
Calaum Sulfate
Chlonne Dlox,de
Chlorme Dry
Chlorme Wet
Chloroacetlc Acld
Chloroacetu Acld
Chromic Acad
Ethyl Alcohol
Ethylene Glycol
Ferric Sulfate
Ferrous Nltrate
Fluos~luc Aod
Gylcerm
Hydrochlonc Acld
Hydrochloric Aad
Hydrochlonc Acld
Hydrogen Peroxtde
Hypochlorous Acld
Lactic Acid

CONCENTRATION
%
10

25
50
20
All
20
All
All
A,,
All
5
_
_
25
50
5
All
A,,
All
All
10
too
10
20
37
30
20
All

MAXIMUM
OF
220
220
140
140
220
220
220
180

220
220
220
220
220
220
140
200
180
220
220
220
80
220
220
160
160
160
220
220

CHEMICAL
Magnesum Sulfate
Metal Plating Solubon
Methyl Alcohol
Napthalene
N,tr,c Acld
N,tr,c Ac,d
Perchlorlc Acld
Phosphoric Acld
Potassum Carbonate
Potassum Carbonate
Potassium Hydroxide
Scdlum Blcdrbonate
Sodurn Carbonate
S&urn Carbonate
Sodium Chlonde
?&&urn Hydroxade
Sodium Hydroxide
Sodurn Hvdroxlde
Sodurn H&chlor&
Sullonated Detergents
Sulfur Dloxlde Drv
Sulfur Dloxlde, Wet
Sulfunc Acld
Sulfwc Acid
Sulfunc Ac,d
Trtchloroacetlc Acld
Zinc Chloride

CONCENTRATION
%
All

loo
All
100
5
20
10
50
10
25
10
10
10
25
A,,
5
10
25
15
100
_
_
25
50
70
50
A,,

MAXIMUM
OF
220
180
140
220
200
80
160
220
140
100
160
180
140
80
220
220
180
80
180
160
220
220
220
220
160
220
220

109

110

Corrosion Resistant Materials Handbook

TABLE

1.30:

POLYETHER

BLOCK

AMIDES-RILSAN

PEBAX
is ATOCHEMs
registered trade name for a family
of polymers
known
as polyether
block amides (PEBA).
The structure
of all PEBAX
products
comprises
linear and regular chains of rigid polyamide
segments and flexible
polyether
segments.
In addition
to their copolymeric
structure,
the various grades of PEBAX
show other original
characteristics:
very wide range of flexibility;
absence of any plasticizer;
excellent
impact resistance, even at low
temperatures;
little variation
in flexibility
between
-40C and +8OC; low density;
very high elastic memory;
excellent mechanical
properties;
and good chemical resistance.

Chemical

Resistance

in stress

Change

,n elongation

Chonge

I volume

Temperatures

7 days/23 C
I.
,.

- 15
- II
-

- 20
- 20
-

-;2

-32

,.
7 days/100 oc

I
3 days/IQ3 oc
7 days1121 C

1.2
1.2
1.5
1
1,2

+
-

7
5

- 24

I
0

+
+

4.7
1.8

- 14
-

3 days/ 100 C
7 days1121 oc

ASTM No 3 011

0
+
+
+
+
+

3533 SN 00

4033SNOO

- 64
DiSSoiVeS

SKIP Detergent 30 g/l


Potasswm 34O Boume

ot break in %

m %

7 days/l21

Lockheed H 55
Skydrol
ASTM No I 011

ot break m %

5533 SN 00

Time

SulphuracAcid. 100/O
Sc&m Hydroxade. 10%
Z,nc Chloride. 5090
Water
Bo,lmg Writer

Polymers

Change

Test

Chemicals

of PEBAX

47

7 days/95 OC
7 days/79 OC

0
0

12.5
0

+ 2.4
+ 1.5

- 12.5
20

Lrxkheed H 55
Skydrol
ASTM No 1 01

3 dqs/lcn
7 dqS/l21

ASTM No 3 011

SKIP Detergent 30 g/l


Potosrlum 34 Baume

oc
oc

- 55

-50

3 doys/lLm oc
7 days/l21 DC

- 92

- 49

+ 17.7
+ 40

+ 135
+ 51

7 days/95 =C
7 days/79 C

5533
SN 00

Tests
Time

Chemicals

4033
SN 00

3533
SN 00

2533
SNOO

6312
MN00

5512
MN00

~+27~+45~+60~+22~+33~
+ 30
+ 54
+ 54
+ 51
+ 128
+ 405

+ 20
+ 25

+ 32
+ 37

Temperatures

Ethanol
Propnol
Butanol

lsooctane
loo OCtonepetrol
M 15 luel
Kerosene
Poraffm

7 do&23

OC

7 days/23 OC
2 days/50 OC
7 days/23 OC

+
7
+ 21
+ 31
+fJ.5
+ I8
+ 32

+ 9
+ 44
+ 64

+ 21
+ 110
_

+ 28
+ 110
_

0
+ 3.5
_

+
+

+ 27
+ 15

+ 48
+ 26

+A8
+ 26

+5
+ j.5

+74
+ 2:6

16
5

0
14

(continued)

Synthetic

TABLE 1.30:

POLYETHER

BLOCK AMIDES-RILSAN

Tests
Chemicals

111

(continued)

5533
SN 00

Time

Resins and Polymers

4033
SN 00

3533
SN 00

2533
SNOO

6312
MN00

5512
MN00

0.

Temperature
0

ASTM Fuel B

7 days/23
2 days/50

OC
OC

+a
+ 21

tt3
+ 41

ASTM Fuel C

2 days/50

Benzene
ACHOW

27

+ 33
+ 4.2

Me?h leth

TABLE 1.31:

POLYETHYLENE-EASTMAN

CHEMICAL

41

t 60
t 42
+ 4.5

I ketone

t 182
+ 45
t 4,5

t
t
t

210
a
n,5

t 12
+a
+4,5

t 22
+ 45
+a

PRODUCTS

Two-inch
diameter
by /s-inch thick
disks injection
molded from a 0.918 density
TENITE
Polyethylene
formulation were immersed
in the chemicals
listed in the tabulation
and stored under a constant
temperature
of 73OF for
one year. The disks were weighed
and measured at the beginning
of the test period and again at the end. The percent change in weight and thickness
was calculated
for each chemical at the end of the test. The change in appearance was also noted.
Chemical
resistance
of polyethylene
is density
related-improving
with
increasing
density.
Therefore,
the lowest
density
formulation
of the TENITE
Polyethylene
family
was tested to represent the greatest change that would be
expected
from contact with the various chemicals.

The Effect of Various Chemicals on TENITE@ Polyethylene (Exposure:

%Change
Chemical
Acetone
Acellc Acid
Ammomum

5%
Hydroxide

Butyl
Acetate
Calcium
Chloride
Carbon
Carbon

2-_0%

Dlsulflde
Tetrachlonde

Chloroform
C,trlc
Acld
Ethanol

10%

Ethylene

Dlchlorlde

Ethylene

Glycol
Glycoi

Formaldehyde
Gasolme
Gasolme

Monoethyl
35%

(Regular)
(Awatlon)

Glycerme
Green
Heptane

0.2

No change

Hydrochloric

08

00

No change
No change

Hydrogen
Methanol

0.0
41

00
08
01
7.7

No change

4.3

Swolien
Swollen

0.1
00

Ethanol
95%
Ethyl
Acetate

Ethylene

1.2

00

5040

Soap

Solution

2.6
6.9
Ether

Appearance

00

0.0
0.3

2.6
0.0
01
00
0.6
09
0.0

No change
Swollen

No change
No change
No change
No change
Swollen
No change
No change

PeroxIde
59~

00
0.0

30%

Acid
Acid

(COW

24

05

No change

0.3
02

00

No change

00

No change

00

00
00

No change
No change

0.0

No change

0.0

NO change

00
01

Sodwm
Sodium

tiydrowde
Hypochlorlte

1%

00

13.5

3.2

15 1
0.0

3.0
0.0

Swollen
No change

Water

00

03

No change

10.0

2.5

Swollen

Wesson
Xyiene

-01

No change
Yellowed

2%
lOoa

-01

30%

0.0
00

3%

00

-01

Oil

agent, but not tested for this characteristic.

Solution

5%

NO change
No change
No change

48

Carbonate
Hydroxide

Sulfuric
Actd
Toluene
Turpentme

00

Appearance

No change

Sodium
Sodium

Acid

0.2

01

Chloride

Sulfwc

10%

In
Thickness

0.6
14

00
05

Sooturn

0.1

Listed as a stress-cracking
agent.
Believed
likely to be a stress-cracking

-02

10%

vmOlli,e 011
-Phenol
5%

0.0
0.0

No change
Swollen,
Pink

Acid

Methanol
100%
Motor
011
Nltrtc
*Oleic

and warped

Welghc

Chemical

Thickness

25 1
10%

K Change

In

Weigh!

36.6
37.9

One Year)

00

No change
No change
No change

15 1
14.5

2.9
3.3

Swollen
Swollen

00

0.0

No change

0.2
15.4

00

No change

31

Swollen

112

Corrosion

TABLE

1.32:

Resistant

Materials

Handbook

P~LYET~~YI_ENM~IMoNT

1900 UHMW Polymer is an ultrahigh molecular weight, high density polyethylene


resin having a molecular weight
range between 3 and 6 million. The extraordinary
wear properties of parts manufactured
from 1900 UHMW Polymer
result in superior replacement
parts or long-performance
components
on original equipment.
Used either way, they
offer outstanding
resistance to impact, abrasion, and chemicals,
plus high energy absorption
and self-lubricating
properties.

Test

pieces,

Appearance

0.040

x 1 x 2

and weight

inches,

change

immersed

reported

in

reagent

on removal

from

under
reagent

conditions
and wiping

given:
dry.

Synthetic

TABLE 1.33:

POLYETHYLENE-LINED
SCIENTIFICS

BEV-A-LINE,
translucent,
tate shell and a polyethylene

ACETATE

713

TUBING-THERMOPLASTIC

INC.

flexible
liner.

The shell excels in durability


A-LINEIV
retains flexibility
from -60 to 200F.

ETHYLENE-VINYL

Resins and Polymers

tubing
for purity
systems, combines
two tubings
Liner and shell are merged by a patented
extrusion

with superior
at temperatures

in one: an ethylene
process.

aging characteristics.
Tubing burst strength surpasses that
from -60 to 160F and BEV-A-LINE
V HT withstands

vinyl

ace-

of PVC. BEVtemperatures

The liner is ideal for use where purity


must be maintained
and good resistance to alcohols,
acids, caustics and solvents is required.
This tubing will resist stress-cracking.
Its inert and neutral contact surface provides a stable environment in which the pH of the content
is essentially
maintained.
The interior
is exceptionally
resistant to stains and
it resists absorption
of liquids, stays translucent
and cleans easily.

Chemical and Environmental Properties of BEV-A-LINE


Chemical

or Solvent

Concentration

Ace:aloa+de
A-E c Acid (Glacial)
ACelOW
Alumnurr
Chloride
Al~mium
Hyaoxlde
Al!,rr,rurr~ Sula!e

lo?&
COK
103%
Dilute
COC
COC
COC
521 d
Sa d
Sa 2
Sa d
Sa d
100%
1 00%
1 00%

Ammo;un~
Carbowale
Ammonwm
Chlor,ae
Ammon~u~,Ntlrafe
Ammonium
Persulla?a
Ammowm
Suliare
Ammonlurr
TWxyanate
Amyl Ace:ate
Amyl Chloride
Allle
Antimony Chloride
Arsenic Acid
Bawm
Carbonate
Bawm Chior!de
BarNurn Hydroxide
Barturn Sulfa!e
Benzene
Benzo~c Acid
Borax
Botlc Acid
Bow Acid
Butanediol
Bu:aedlol
Butanedzol
Calcwm
Calcium
Calcium
Calcium

Carbonate
Chlwde
Hydroxide
Hypochlorw

Calcium
Calwm

NItrate
Sulfate

Copper
Copper

S
S

S
S

s
U

S
S
S
S

Sa! d
Sa d
COC
Dlill:E
100%
60%
10%

0
S
S

U
s
S
S

S
S
s
S
S
S

S
S
S
S
S
S

S
S
S

S
S

35%
100%
100%
Sa! d
Sal d
Sal d
Sal d
40%

S
S
S
S
S

S
S
S

S
S
S
S
II
U

U
U
U
S
S
S
S

S
S
S
S

S
0

S
0
0

U
S
S
U

S
S
0

U
0

U
S
S

0
S
S

S
S
S

= sflghf &tack

U = unsatisfactory

S
S
S

s
s

s
s
S
S

s
S

s
s
S

S
S
S
S

I s
s

s
s
S

S
s
S

s
S
5
i

s
s
S

ss

s
I s
I s

/ :
/ s
I
7OF

= 21C

ConccntratiooBEV-A-LINE
Outer Shell

L:uCtoSf
Sa!lrc Acid

52 d
Sa 0

GyCeWe
Glycol~c AC<?
Hepiane
Hydrobronlc
Acid

OOC
30%
1004.

Laclic Acid
La:ex
Lead AceWe
Magnesium
Carbonate

S
S
S
5
u

S
U
U
S

or Solvent

hidroger

s
: s

Chemical

IV and V HT Liner and Shell at Room Temperature (73F)

S
S

Sa d
Sal d
Sa d
Sa d
100%

100%
100%
100%

S
S

100%

(no attack)

S
S
S

IS = satlafacfory

S
S
S

S
S

Sat d

Few
Sulfate
Ferrous Chloride
Formaldehyde

II

Sa, d
100%

Sat d
Sa d

Ethyl Buryrate
Ethyl Ether
Ferc Chloride
Femc Nl!ra!e

Sa! d
Sal d
Dilute
100%
100%
100%
100%

Ethyl Ace!&
Ethyl Alcohol
Ethyl Alconol

0
0

s
: s

50%
Sa 0

DeXtKJse
D6odlu-m Phosphate
Dlethylene
Glycol
D~octyl Phthalale

i,
S
Cl
5
S
S
s
s
S
S
S

B-V
Liner

U
S

Sal d
Sa! d
100%

CoDpe Sulfaw
Cottonseed
011
CresOl
Cyclohexane
Cyclohexanol
Dexwl

B-IV
_iner

U
0
S
S

Sa! d
Bleach sot n

Chloride
N~!r.ale

--__

Sa! d
Sat d

Castor Oil
Chromic Acid
C~lric Ac!d

EV-A-LINE
IV
Outer
__-- Shell

Pcroxde

Magnewm
Magnesium
Magnesluv

Chlortde
Hydroxide
Nitra:e

Magnewm
SLllfa!e
Male~c Acid
MecurIc
Chloi~oe
Melhylene
Chloride
MIneral 011
Naphtha
Nickel Chloride
Nickel Nttrate
Nickel Sulfate

Po!assium
Poiassium
Pcxass~um

Blcarbow!e
Boraie
Broma!e

PoiassiuV
Po!aswm
Po!asswm
Potassun
Po:asswr

Bromide
Carbonate
Chloride
Dlchromale
Ferrtcyaplde

Polaswm
Polasswm
Poasslum
Polassu~
Puassium

Hydroxide
N!tra!e
Perchloiale
Permangdnale
Sulfate

Potaswm
Propylene

Sul!tte
Glycol

SI~ICIC Acid
Sodium Blcarbonale
Sodium Borate
Sodium Carbora!e
Sodwm
Sodurn
Sodwm
Sulfuw

Chloride
Hydw.!de
Sulfaw
Acid

Sul:ur!c

Acid

chemvzal

contact

Sa* d
Sa: d
Sat d
Sa! d
Sat d
Sa d
Sa: d
100%
100%
100%

0
0
S

S
S
0
S
S

10%
Sat d
COC
Sal d
40%

Sat d
20%

S
S

Sat d
Sal d
20%
COC
COC
100%

S
S
U
S
S

S
S

Cone
Sal d
50%

100%
S&d

Thermoplastic

charactenstlcs
Sclentiflcs.

S
U
U
u
u
U

100%

u
U
S

of Bev-A-Ltne
Inc.

0
S
S
S
s
S
S
S
S
S
S
S

3
S

S
S
S

S
S
S
S

S
S
S
S

S
S
S

S
S
S
S
S
S
S
S
S
S
S
S

S
S
S

S
S

COC
70%

5
S
S
S

S
S
S
S
S
S
S

S
S
S
S
S

V HT

c
S
c
S
0
S
S
S
S
S
S
S
S
S
S

S
S
S

Sa! d
Sal d
COIX

I
/

0
S

Sa! d
1%

S
s
5
S
S
S

S
S

100%

B-V
LItlet
__

S
S
S
.I
0

30.50%
C0C
Sal d
85?0
1%

7-

S
S
S

S
S
S
S
S

100%

reststance

5
c
S
S
5
S
S
S

100%

Kylene
7.1-c Sulfate

0
S
S
S
S
S
S

98%
100%

Tetrahydroturan
roluene
le!rachloroethylee
rnchloroethylene

For

50%
COC
31 1%
309
90%
100%
Sal d

S-IV
Liner
5
5
S
c

Sat 0
COC
Sal d

N,cotlnlc Acid
NI!W Acid
01.x Acid
Oxalic Acid
Pnosphorlc
Acid
PICK Acid

IV

S
S
S

S
S
S
S

0
i:
U

S
S
S

U
U
U
S

0
0
S
S

outer

shell

114

Corrosion Resistant Materials Handbook

TABLE

1.34:

POLYETHYLENE

PETROTHENE
density appear
marked. There
density may be

RESINS-U.S.I.

CHEMICALS

resins are available across the entire range of polyethylene


densities 0.91 to 0.96. The variations in
very small, but the effect of even a very small change in density on certain essential properties is very
are many applications
for which resins of higher density and many others for which those of lower
preferable. The three density ranges of polyethylene
are:
Low density
Medium density
High density (linear)
Chemical

Reagent
Acetaldehyde
Acetic Acid
Acetic Acid
Acetic Acid
Acetic Anhydride
Acetone
Acrylic Emulsions
Ally1 Alcohol
Ally1 Chloride
Aluminum Chloride
Alummum Chloride
Alummum Fluoride
Aluminum Sulfate
Alums tall typesl
Ammonia, 100%
Ammonium Carbonate
Ammonium Chloride
Ammonium Fluoride
Ammonium Hydroxide
Ammonium
Metaphosphate
Ammonium Nitrate
Ammonium Persulfate
Ammonium Sulfate
Ammonium Sulfide
Ammonium Thiocyanatc
Amy1Acetate
Amyl Alcohol
Amy1Chloride
Aniline*
Aniline Hydrochloride
Antimony Chloride
Aqua Regia
Arsenic Acid
Barium Carbonate
Sariurn Chloride
barium Hydroxide
Barium Sulfate
Barium Sulfide
Beer
6enzenc
Benzene Sulfonic Acid
Benzoic Acid
Bismuth Carbonate
Slack Liquor
@leach lye
Soras
Soric Acid
Boric Acid
Bromic Acid
Bromine Liquid
Bromine Water
Butanediol
Butanediol*
Sutanediol
Butyl Alcohol
Butyric Acid
Calcium Bisulfide

Resistance

gjTz=

Concen

tration

100%
1.10%
IO-SO%
80.IDOX

Dilute
Cone.
Cont.
Cont.
Cont.
Dry Gas

1
1
i
I
I

I
,
I
I

Satd.
20%
0,880 s.g
Satd.
Satd.
Satd.
Satd.
Satd.
Satd.
100%
100%
100%
100%
Satd.

(
4
!
a
,
!
I
s
I
1

S
1
100%
Satd.
Satd.

:
:

Satd.
Satd.

All Cont.
Satd.
10%
Cold Satd.
Dilute
10%
100%
10%
60%
100%
100%
Cont.

of Low and Medium

:
:
S
S
S
S
:
:
S
U
U
S
S
:
U
S

Calcium Carbonate
Calcium Chlorate
Calcium Chloride
Calcium Hydroxide
Calcium Hypochlorite
Calcium Nitrate
Calcium Sulfate
Camphor Oil
Carbon Dioxide
Carbon Dioxide
Carbon Dioxide
Carbon Oisulfide
Carbon Monoxide
Carbon Tetrachloride
Carbonic Acid
Castor Oil
Chloracetic Acid
Chlorine Dry Gas
Chlorine Moist Gas
Chlorine Liquid
Chlorine Water
Chlorobenzent
Chloroform
Chlorosulfonic Acid
Chrome Alum
Chromic Acid
Chromic Acid
Chromic Acid &
Sulfuric Acid
Cider
Citric Acid
Coconut Oil Alcohols
Cola Concentrates
Copper Chloride
Copper Cyanide
Copper Fluoride
Copper Nitrate
Copper Sulfate
Copper Sulfate
Cottonseed Oil
Cresol
Cresylic Acid
Cuprous Chloride
Cyclohexanol
Cyclohexanone
Detergents, Synthetic*
Developers,
Photographic
Oertrin
Dextrose
Dibutylphthalate
Disodium Phosphate
Oiazo Salts
Oiethylene Glycol
Diglycolic Acid
Dimethylamine
Dioctyl Phthalate
Emulsions, Photographic

0.910-0.925
0.926-0.940
0.941-0.965
Density

Polyethylene

Conccn.
tram

Satd.
Sat-d.
Satd.

7
t
,

100% dry
100% wet
Cold Satd.

_..I
S
S
S
S
S
S
SU
S
S
S
U
s
U
:S
S
Iu

Cont.
100%
100%

I% Satd. So

100%
Satd.
20%
up to SO%

Satd.

Satd.
Satd.
2%
SaYd.
Dilute
Satd.
100%
50%
Satd.

Satd.
Satd.

!
!
U
I
s
uI
S
U
S
S
U
0
0
U
S
U
U
U
S
S
S
s
S
s
s
:
f
E
5

i
i
I
i
i
,
I
i

to Various

Reagents

ry L

Concen-

Bleach Sot?
SO%

g/cc
g/cc
g/cc

I!
Iu
3
IJ
IJ
IJ
<i

Si
!i

Cb
d1
S1
5,
51
s
S
:
S
S
S
UI
s
S
U
S

s
S
s
S
S
S
:
S

II

tration

Ethyl Acetate
Ethyl Alcohol
Ethyl Alcohol*
Ethyl Butyrate
Ethyl Chloride
Ethyl Ether
Ethylene Chloride
Ethylene Chlorohydrin
Ethylene Dichloride
Ethylene Glycol
Ferric Chloride
Ferric Nitrate
Ferrous Chloride
Ferrous Sulfate
fish Solubles
fluoboric Acid
Fluorine
fluosilicic Acid
fluosilicic Acid
Formaldehyde
Formic Acid
Formic Acid
Formic Acid
Fructose
Fruit Pulp
Fuel Oil
Furfural
Furfuryl Alcohol
Gallic Acid
Gasoline
Gin
Glucose
Glycerine
Glycol
Glycolic Acid
Grape Sugar
Heptane
Hexanol. Tert:
Hydrobromic Acid
Hydrocyanic Acid
Hydrochloric Acid
Hydrochloric Acid
Hydrochloric Acid
Hydrochloric Acid
Hydroftuoric Acid
Hydrofluoric Acid
Hydrofluoric Acid
Hydrogen
Hydrogen Bromide
Hydrogen Chloride Gas
Hydrogen Peroxide
Hydrogen Peroxide
Hydrogen Phosphide
Hydrogen Sulfide
Hydroquinone
Hypochlorous &id
Inhs
Iodine tin KI Soln.)

100%
100%
35%

p .tC
f

7 I
5
,j
(1
1I

II

1I
1I
1I
!,
s1
s,

Satd.
Satd.
Satd.

32%
Cont.
40%
O-20%
20.50%
100%
Sat-d.

100%
Satd.

30%
Sard. Aq.

50%
Satd.
10%
30%
35%
Cont.
40%
60%
75%
100%
10%
3Z
93%
lW%

:
S
S
S
S
S
S
S
S
S
S
S
0
U
U
S
U
U
S
S
S
S
S
U
S
S
:
s
S
s
S
:
S
!
S
S

Corn.

Cont.

IS
s
U
U
U
u
U
U
S
S
s
S
S
S
S
U
s
,0
s
s
s
5
S

j
IJ
tJ
IJ
ci
J

I1
>
<,
<b
5
s
1I
S
s
s
s
S
S
S
S
S
D
S
S
S
0
U
S
S
S
S
S
U

(continued)

Synthetic

TABLE 1.34:

POLYETHYLENE

RESINS-U.S.I.

CHEMICALS

400

Reagent

F II

Lactic Acid
Lactic Acid
Latex*
Lead Acetate
Lead T&a-Ethyl
Linseed Oil
Lube Oil
Magnesium Carbonate
Magnesium Chloride
Magnesium Hydroxide
Magnesium Nitrate
Magnesium Sulfate
Maleic Acid
Mercuric Chloride
Mercuric Cyanide
Mercurous Nitrate
Mercury
Methyl Alcohol
Methyl Bromide
Methyl Chloride
Methyl Ethyl Ketone
Methylene Chloride
Methylsulfuric Acid
Milk
Mineral Oils
Molasses
Naphtha
Naphthalene
Nickel Chloride
Nickel Nitrate
Nickel Sulfate
Nicotine*
Nicotinie Acid
Nitric Acid
Nitric Acid
Nitric Acid
Nitric Acid
Nrtrobenzena
Ocfyl Cresol
Oils and Fats
Oleic Acid
Oleum
Orange htract
Oxalic Acid
Oxalic Acid
Oxygen
Ozone
Perchioric Acid
Petroleum Ether
Phenol
Phosphoric kid
Phosphoric Acid
Phosphoric Acid
Phosphorus (Yellow1
Phosphorus Pentoxide
Phosphorus Trichlorida
Photographic Solutions

7OCf = wc,

14w

= 60OC

S&d.
100%

Satd.
Satd.
Satd.
Satd.
Satd.
Satd.
Satd.
Satd.
S&d.
100%

100%
lDG%

Comm.

wd.
Cont.
Satd.
Dilute
0.30%
30.50%
70%
9198%
100%

Cont.
Cont.
Dilute
Satd.
100%
100%
10%
90%
up to 30%
309D%
90%
lW%
100%
100%

Reagent
I

Pickling Baths
Hydrochloric kid
Sulfuric Acid
Sulfuric-Nitric*
Picric kid
Plating Solutions
Brass
Cadmium
Chromium*
Copper
Gold*
Indium
Lead
Nickel
Rhodium*
Silver
Tin*
Zinc
Potassium Bicarbonate
Potassium Borate
Potassium Bromata
Potassium Bromide.
Potassium Carbonate
Potassium Chlorate
Potassium Chloride
Potassium Chromate
Potassium Cyanide
Potassium Oichmmate
Potassium Farril
ferro Cyanide
Potassium Fluoride
Potassium Hydroxide
Potassium Hydroxide
Potassium Nitrate
Potassium Parborate
Potassium Parchlorate
Potassium
Permangamte
Potassium Persulfate
Potassium Sulfate
Potassium Sulfide
Potassium Sulfite
Ropargyl Alcohol
Propyl Alcohol
Propylene Dichloride
Propylene Glycol
Rayon Coagulating
Bath
Sea Water
Selenic Acid
Shortening*
Silicic Acid
Silver Nitrate Soln.
Soap Solution
Sodium ketate
Sodium Benzoate
Sodium Bicarbonate

Kay: S-satisfactory

Resins and Polymers

115

(continued)

Concen-

Conccn-

tration

tration

1%

U
S
S
:
S
S
S
S
s
S
s
s
S
S
S
S
s
S
S

SaFd.
1%
10%
S&d.
Sagd.
S&d.
40%
SaYd.
40%
Satd.

E
5

20%
corm.
Satd.
SaFd.
10%

;
E
E
i
5

20%
S&d.
Cont.
Cont.
Cone.

I
i
i
i
i
i
i
1
i

100%

i
i
i
,
i
i
;
1
,
1

Any Concn.
Saw.
35%

s&d.

O-some

attack

Sodium Elsulfate
Sodium Bisulfita
Sodium Borate
Sodium Bromide
Sodium Carbonate
Sodium Chlorate
Sodium Chloride
Sodium Cyanide
Sodium Dichromata
Sodium Farricyanida
Sodium Farrocyanide
Sodium Fluoride
Sodium Hydroxide
Sodium Hypochlorite
Sodium Nitrate
Sodium Sulfate
Sodium Sulfide
Sodium Sulfide
Sodium Sulfite
Stannic Chloride
Stannous Chloride
Starch Solution
Stearic Acid
Sulfur
Sulfur Dioxide
Sulfur Dioxide
Sulfur Trioxidc
Sulfuric Acid
Sulfuric Acid
Sulfuric Acid
Sulfuric Acid
Sulfuric Acid
Sulfuric Acid, Fuming
Sulfurous Acid
Tallow
lannic Acid
Tanning Extracts
Tartaric Acid
Tartaric kid
Tetrahydrofurane
Titanium Tatrachloridc
Toluena
Transformer Oil
Trichloroathylene
Triethanolamine
Trisodium Phosphate
Turpentine
Urea
Urine
Vinegar
Vanilla Extract
Wetting Agents*
Whiskey*
Wines
Xylene
Yeast
Zinc Chloride
Zinc Sulfate

Safd
S&d.
Dil. S&n.
Cont.
Satd.
S&d.

1t
F

3
3

s
s
S
i

S
Satd.
Satd.
Satd.
Satd.
Cent.

i
S
:
:

25%
Satd. Soln.
Satd
Satd.
Tatd. Sofn.
Satd.
100%
Colloidal
Dry, 100%
wet. 100%
0.50%
70%
80%
96%
18% LConcJ

:
S
S

S
S
S
S
S
S
S
S
S
S
S
0
3
:

S
10%
Comm.
10%
Satd.
Satd.

100%
Satd.
rp to 30%
Comm.

Satd.
Satd.

S
S
S
J
J
J
;
J
i
E
S
S
S
5
i
;
S
I
i
i
i

S
0

u
u

U
U
S
0
S
S
S
U
U
U
U
U
U
u
S
U
S
S
S
S
S

U-unsatisfactory

*The values are obtained from tests made under static conditions and using nonstressed specimens. Reagents marked with an asterisk (1 may, under certain conditions, cause environmental stress cracking if the polyethylene
products are improperly designed
or not made of the best suitable resins.

116

Corrosion Resistant Materials Handbook

TABLE

1.35:

POLYETHYLENE

TANK

MATERIAL-NALGE

The XL-200
D.O.T.-exempted
mini-bulk
tank is a reusable, lightweight
200 gal tank system for hazardous
liquids.
Rotationally
molded
of cross-linked
high-density
polyethylene
(XLPE),
the XL-200
has superior
resistance to impact and stress-cracking
and is compatible
with a wide range of chemicals
(see chemical
resistance summary).
Its
strong over a wide temperature
range, from -20 to +16OF (-29 to +71C).
Chemical Rcslstance Summary
Class of Substances at 20C
Acids, dilute or weak

Excellent

Acids*,

-Excellent

strong and concentrated

Alcohols, Aliohatic

Excellent

Aldehydes

Good

Bases

Excellent

Esters

Good

Hydrocarbons, Aliphatic
Hydrocarbons, Aromatic- -

Good

Good

Hydrocarbons, Halogen&d

Fair

Ketones

Good

Oxidizing Agents, strong

Fair

This Chemical Resistance Summary IS mrended as a


genera/ guide only.

Except for ox:dizmg acids; for oxidizing sods, see


Ox/d,z,ng Agents, strong.

TABLE

1.36:

POLYETHYLENE

TEREPHTHALATE-BASED

COPOLYESTER-EASTMAN

CHEMICAL

PRODUCTS

KODAR
PETG Copolyester
6763 is a clear, amorphous
polymer
based on poly(ethylene
terephthalate)
and has a
number average molecular
weight
(Mn) of about 26,000. To obtain the data shown below, sections of unstressed injection-molded
tensile bars l/s inch (3.2 mm) thick were weighed and measured and immersed in the chemical or reagent shown and stored at 73F (23C) for a period of one year. At the end of the test period, each sample of plastic
was removed
from the jar in which
it was tested, wiped dry, and quickly
weighed
and measured again and the
to the test medium
changes in weight and thickness
were calculated.
The appearance
of the samr !e after exposure
was also recorded.
Ordinarily,
a plastic would not be suggested for continuous
immersion
in a reagent that causes an
increase of 5% or more in weight or thickness.
This does not imply that a change in weight or thickness of less than
5% necessarily indicates suitability
for immersion.
The results of these tests showed that KODAR
PETG Copolyester
6763 is resistant to a variety of chemicals, highmolecular-weight
esters, aliphatic
hydrocarbons,
and dilute solutions
of acids and salts. PETG 6763 was significantly
affected
by concentrated
acetic acid, acetone,
benzene,
toluene,
carbon tetrachloride,
dimethyl
formamide,
and
phenol and was completely
deteriorated
by concentrated
nitric and sulfuric acids and by ethylene
dichloride.

(continued)

Synthetic

TABLE 1.36:

POLYETHYLENE
PRODUCTS

TEREPHTHALATE-BASED

%Change
Weight

Acettc Acid. 5%

Acetone
Hvdroxlde.

cont.

A;r.:r:on~um HvdroxIde.

10%

I
!

,n

Thickness

!
/
1

0.5

A cct~c Acad. cone


Ammonum

COPOLYESTER-EASTMAN

117

CHEMICAL

(continued)

Reagent

Resins and Polymers

192
15.6

Appearance of Plasrlc After Exposure

0.2

Verv sllqht vellowmq

18.5
234

I
~

Dwolored

and swollen

Dwolored

(brown). swollen, rubber-like

Turned white - outslde crumbling off


~--.___
DIscolored (pInkI - surface has blisters

Cttrlc Acid, 10%


Cottcnseed 011
Detergent, Alconox

(0

25%)

Demnlzed Water
Dlbutvl

Sebacate

Dlmethvl

Formamlde

Ethanol,

100%
_
Ethanol, 50%

21.9

06

Ethyl Acetate
-___
Ethylene Dlchlortde

Gasolme. High Test

Gasoline, Regular

202

Hvdrochlortc

Acid, cont.

Hvdrochlorlc

Acid. 10%

1.3

0.9

0.3

04

I
I
I

Nltrlc Actd. 40%

1 Oleic Acid, 83%

I Olwe011

05
02

0.1

0.8

0.5

!
:
I

0.1

0.2

02

I
j
I

0.2

0.5

10%

1 Sodium Carbonate, 2%

0.5

1 Sodium Hvdroxlde.

8.0

Sodwm Hydroxide,

0.4

10%
1%
3.5%

Turpentine
unkn

rhe/igure

h precede

Very slight vellowng


_~___
Very sltght vellowng
Very slight vellowlng. crazing

[
/
/
1
I

/
j

Completelv

detertorated

Slight vellowng
Verv shqht vellowinq

Verv sltaht vellow~nq

Turned black
Slight vellowmg
Slight vellowmg

0.2

Sllqht vellow~ng

0.4

Sllaht vellowina

6.4

Sliaht vellowinq

Completely

/ Slight yellowing

0.2

0.4

0.2

25.9

31.0

0.3

0.2
Sisn.

after one week


__-

Turned%hlte

0.2

b.v (I nfFtti

I
I

jvsllghtvellowlng

Shght vellowng

Toluene

0.5

Oil

_~._____

Sllqht yellowlnq

0.2

increases

0.2

- blisters under surface

Sltqht vellowmg

Slight -veliowlng

0.6

I Sulfuric Acid, 3%

Badly dlrcolored

0.8

0.3

were

14.3

!n one week

/
/
I

0.8

Sulfuric Acid, 30%

lC!wtgesshown

0.3

deteriorated
-__

-_____Sltght vellowmq
.__L__
S!lght vellowlng

1
j

Sulfurtic Acid, cont.

Transformer

01

i
I

Sodium Hvpochlorite,

0.7

0.3

Sodturn Carbonate. 20%

0.2
0.2

13.2

-__
1%

04
0.3

;
~

14

Nltrlc Acid. 10%

Cloudy

I
/
i

Methyl Alcohol

Nltrlc Acid, cone

Completely

0.2

___-

Badly dtscolored and swollen - rubber llke

0.3

_~--~

Slight vellowng

0.9

0.8

0.3

Badly discolored and dtstorted


____Very slight vellowlng

02

0.6

Mineral 011

0.8

Kerosene

Sodwm Chloride,

I
05
/ __-___
24.5

01

lSOOctane

Phenol, 5%

0.7

11

1 Hydrogen PeroxIde, 28%


1 Hvdrogen PeroxIde. 3%

/
~

38.6

Hexane

Soap Solution,

05

Slight vellowmg

deteriorated

in one week

Slight vellowing
Very sltght vellowng
Turned white - rubber-llke
Slight vellowng

118

TABLE

Corrosion Resistant Materials Handbook

1.37:

POLYMETHYLPENTENE-WESTLAKE

PLASTICS

The high resistance of TPX (polymethylpentene)


to chemical
attack, combined
with its excellent
transparency
and
high temperature
performance,
makes it particularly
suitable
for a wide range of applications.
TPX polymers
are
highly resistant to inorganic
environments,
are not attacked
by aqueous solutions
of inorganic
salts nor by most mineral acids or alkalis even in a concentrated
form. They are, however,
affected
by oxidizing
reagents. TPX polymers
show good resistance to many organic chemicals
although,
as with other polyolefins,
absorption
does occur in certain cases leading to a loss of rigidity and a decrease in yield stress. Tests on injection molded samples at 20C (68OF)
and 60C (140F) over a period of 3 months are listed and give an indication of the behavior in practice.

Acetic acid (glacial)


Acetic acid (dilute)
Acetone
Aluminum chloride
Aluminum fluoride
Aluminum sulfate
Ammonia
Ammonium carbonate
Ammonium chloride
Ammonium fluoride (20%)
Ammonium hydroxide (10%)
Ammonium nitrate
Ammonium sulfate
Ammonium sulfide
Ammonium thiocyanate
Amy1 acetate
Amy1 alcohol
Amy1 chloride
Anisole
Barium carbonate
Barium chloride
Barium hydroxide
Barium sulfate
Barium sulfide
Beer
Benzaldehyde
Benzene
Benzoic acid
Benzyl alcohol
Brake fluid
Bromine liquid
Bromine water
Butylacetate
Calcium carbonate
Calcium chlorate
Calcium chloride
Calcium hydroxide
Calcium hypochlorite
Calcium nitrate
Calcium phosphate
Calcium sulfate
Calcium sulfite
Carbon dioxide
Carbon tetrachloride
Carbonic acid
Chlorine water
Chlorobenzene
Chloroform
Chromic acid

2oc

60C

B
A
B
A
A
A
A
A
A
A
A
A
A
A
A
B
B
C
B
A
A
A
A
A
A
A
C
A
A
A
D
D
C
A
x
A
A
A
A
A
A
A
A
c
A
D
C
C
A

B
A
B
A
A
A
A
A
A
A
A
A
A
A
:
C
C
C
A
A
A
A
A
A
B
C
A
A
;
D
C
A
A
A
A
A
A
A
A
A
A
C
A
D
C
D
A

Citric acid
Copper chloride
Copper cyanide
Copper fluoride
Copper nitrate
Copper sulfate
Corn oil
Cuprous chloride
Cyclohexanol
Cyclohexanone
Decalin
Diesel Oil
Dimethyl formamide
Dioctyl phthalate
Ether
Ethyl acetate
Ethyl alcohol
Ethyl oleate
Ethylene glycol
Ferric chloride
Ferric nitrate
Ferric sulfate
Ferrous chloride
Ferrous sulfate
Fluosilic acid
Formaldehyde
Formic acid (100%)
Fruit juices
Gear box oil
Gin
Glycol
Hexane
Hydrochloric acid (50%)
Hydrochloric acid (30%)
Hydrochloric acid (20%)
Hydrochloric acid (10%)
Hydrofluoric acid (60%)
Hydrogen peroxide (70%)
Hydrogen peroxide (35%)
Hydrogen peroxide ( 10%)
Isopropyl alcohol (100%)
Iodine in ethanol solution
Lead acetate ( 100%)
Lemon oil (concentrated)
Linseed oil
Lubricating oil
Magnesium carbonate

2oc

6OC

A
A
A
A
A
A
A
A
A
B
C
B
A
A
C
B
A
B
A
A
A
A
A
A
A
A
A
A
A
A
A
C
A
A
A
A
A
A
A
A
A
A
A
C
A
B
A

A
A
A
A
A
A
A
4
B

D
A
A
C
C
B
C
A
A
A
A
A
A
A
A
A
A
B
A
A
C

B
A
A
A
A
B
B
A
B
A
A
C
A
C
A

(continued)

Synthetic Resins and Polymers

TABLE 1.37:

POLYMETHYLPENTENE-WESTLAKE

Magnesium chloride
Magnesium hydroxide
Magnesium nitrate
Magnesium sulfate
Magnesium sulfite
Mercuric chloride
Mercuric cyanide
Mercurous nitrate
Mercury
Methyl alcohol
Methyl ethyl ketone
Methylene
chloride
Milk
Mineral oil
Motor oil
Nickel nitrate
Nickel sulfate
Nitric acid (fuming)
Nitric acid (70%)
Nitric acid (50%)
Nitric acid (10%)
Nitrobenzene
Oleum
Olive oil
Oxalic acid (50%)
Paraffin ozone
Paraffin wax
Paraldehyde
Petrol
Petroleum
ether
Phenol
Phosphoric
acid (50%)
Photographic
developer
Potassium bicarbonate
Potassium bromide
Potassium
carbonate
Potassium chlorate
Potassium chloride
Potassium chromate
Potassium cyanide
Potassium dichromate
Potassium ferricyanide
Potassium ferricyanide
Potassium fluoride
Potassium hydroxide
Potassium nitrate
Potassium perborate
Potassium perchlorate
Potassium permanganate
Potassium sulfate
Potassium sulfide
Potassium sulfite
Pyridine
Resorcinol
(saturated)

PLASTICS

2oc

60C

A
A
A
A
A
A
A
A

A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
A
D
A
A
A
A
D
A
A
A
A
B
B
C
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
li
A
A
B
A

B
B
A
B
B
A
A
D
B
A
A
B
D
A
B
A
A
C
C
C
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
A

119

(continued)

Rum
Silicone oil
Soap solution (concentrated)
Sodium acetate
Sodium bicarbonate
Sodium bisulfite
Sodium borate
Sodium carbonate
Sodium chlorate
Sodium chloride
Sodium chlorite (20%)
Sodium cyanide
Sodium dichromate
Sodium ferricyanide
Sodium ferrocyanide
Sodium fluoride
Sodium hydroxide
(50%)
Sodium hypochlorite
Sodium nitrate
Sodium nitrite
Sodium silicate
Sodium sulfate
Sodium sulfide (25%)
Sodium sulfite
Stannic chloride
Stannic sulfate
Stannous chloride
Sulphamic acid
Sulfuric acid (98%)
Sulfuric acid (60%)
sulfuric acid (30%)
Sulfuric acid ( 10%)
Tannic acid
Tartaric acid
Tetrahydrofuran
Toluene
Transformer
oil
Trichloroacetic
acid (10%)
Trichloroethylene
Turpentine
Vaseline
Vinegar
Vodka
Water
Whisky
White paraffin
White spirit
Wines
Xylene
Zinc chloride
Zinc oxide
Zinc sulfate
A =
B=
C=
D =

Negligible effect
Limited absorption
or attack
Extensive absorption
Extensive attack

20c

60C

A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
C
C
A
A
C
C
A
A
A
A
A
A
C
A
C
A
A
A

A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
B
A
A
A
A
A
C
C
C
A
C
C
A
A
A
A
A
B
C
A
C
A
A
A

120

Corrosion Resistant Materials Handbook

TABLE

1.38:

POLYPHENYLENE

SULFIDES-PHILLIPS

CHEMICAL

RYTON
polyphenylene
sulfide resins and compounds
are engineering thermoplastics
developed by Phillips Petroleum Company.
Available in both molding and coating grades, these materials feature excellent dimensional stability, inherent flame retardancy,
thermal stability, chemical resistance, desirable electrical properties and ease of processing.
RYTON
resin compounds are resistant to a very broad range of chemical materials and at elevated temperatures
are
considered
second only to PTFE in overall
resistance to corrosive
and hostile chemical
environments.
Environments to which
RYTON
compounds
do not have adequate
resistance include oxidizing
environments
such as 50%
nitric acid, 30% sulfuric acid, sodium hypochlorite,
bromine water, etc., all at 200F (93C) or above.

ENVIRONMENTS

COMPATIBLE

WITH RYTON COMPOUNDS

200F (93C)

Room Temperature

Hydrocarbons

Hydrocarbons

Esters

Esters

Ketones

Ketones

Alcohols

Alcohols

Chlorinated
Hydrocarbons

Chlorinated
Hydrocarbons

Bases

Bases

Amines

Dilute

Acids

Acids

TABLE

1.39:

POLYPROPYLENE-EASTMAN

Resistance

of TENITE

CHEMICAL

Polypropylene

Chemical

PRODUCTS

Wwght

4231

to Various

Chemicals*

Change in

Appearance

Thickness

Acetone

2.2

1 .o

No change

Acetic Acid 5%

0.1

0.1

Slightly

bleached

Slightly

bleached

Slightly

bleached

Slightly

yellov.

Ammonium

Hydroxide

Bury1 Acetate
Calcium Chloride

10%

0.0
6.3

212%

0.1

-0.1
1.8
-0.4

(continued)

Synthetic Resins and Polymers

TABLE

1.39:

POLYPROPYLENE-EASTMAN

CHEMICAL

PRODUCTS

121

(continued)

*Injection-molded
disks 2 inches in diameter and %-inch thick were immersed in the chemicals and stored under a constant temperature of 73F for one year. Polypropylene
is highly resistant to chemical attack and to stress-cracking. However, a few chemicals
produce swelling and attack the surtace slightly. These chemicals are mainly chlorinated compounds, aromatic hydrocarbons, and
the higher aliphatic hydrocarbons, such as gasoline.

122

Corrosion Resistant Materials Handbook

TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

EXPOSURE

Acetaldehyde

Temp., OF

Time, days

68
122

180

365

140

30

70

100

140

100

S
M

73
72

30

176
68

30

S
S
M

180

1.06

180
100
30

S
M

6.4

S
M
M

4.2

73
73

Acetic Acid (50%)


Acetic Acid (Glacial)

Acetone

(100%)

(DMK)

122
140
68
68
122

100
180

140

100

Acetophenone

73

Acetylene
Acriflavine

73
68

S
S

176

68

140

S
M

(2% aq. soln)

Acrylic emulsions
Ally1 chloride
Almond Oil
Aluminum

Aluminum
Aluminum

chloride

fluoride
Sulfate

Alums
Ammonia

(15% sol.)

Ammonia

(25%)

Ammonia (30%)
Ammonia, concen.
Ammonia (gas-liquid)
Ammonium Acetate
Ammonium Bicarbonate
Ammonium

Carbonate

39.6

M
M

Acetic Acid (5%)

Acetic Acid (20%)

PERMEABILITY
(gm./24 hr./
100 rq. inlmil)

180

Acetate solvents, pure

Acetic Acid (10%)

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.
M= Marginal
U= Unsatis.

68
140
73
68

U
117

0.0

140

212

68

140

73

S
S
S

73
72

30

73

180

9.5

140

180
365

17.4

100

S
S

73
73
73
73
68
140
73

S
S
S
S

(continued)

Synthetic Resins and Polymers


TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

Ammonium

Chloride
fluoride

CHEMICAL
EXPOSURE
PERFORMANCE
S =
M=

Temp., OF

Ammonium

(continued)

EXPOSURE

REAGENT
,Soldr onsaturated ~ol~tton
unlessandncated orherwsel

Time, days

73

(10% aqueous sol.)


metaphosphate

Ammonium
Ammonium

Ammonium
Ammonium
Ammonium

s
S

73

365

68

140
212

S
S

Nitrate
persulphate

73
68

S
S

Phosphate
Sulfate
Thiocyanate

140
212
73
73
68

S
S
S
S
S

140
212
73

S
S
S

68

Amy1 Acetate
Amy1 Alcohol

Amyl Chloride
Aniline

Anisole

140

212

S
M

68
140

68

180

0.165

122

180

2.77

140

30

68
140

S
M

212
Anti-freeze
Chloride, satd

68

180

0.0

122

180

0.45

68

140

212
Apple Juice
Aqua regia

Aromatic
Asphalt

Marginal

U= Unsatir.

Hydroxide

Ammonium

Antimony

Saris.

PERMEABILITY
(gm.124 hr.1
100 sq. inlmil)

S
s

68
140
212

Ammonium

123

Hydrocarbons

Barium Carbonate

73
68
140
212

M
43

73
73

S
M
U
U
U

68
140

S
S

1.78

(continued)

124

Corrosion Resistant Materials Handbook

TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(continued)

EXPOSURE

REAGENT
(Sohdr

m saturated solution
unlessmdicated otherwKl

Temp., F
Barium

Carbonate

Barium Chloride

Barium Hydroxide

Time, days

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.
M= Marginal
U= Unsatis.

212

68
140

s
s

212

S
s

68
140

212

Barium Salts
Barium Sulfate

73
68
140
212

Barium Sulfide

68
140
212
72

30

73
73
68

180

S
S
S
S
S
S
S
S
S
M
U

Beer
Beet Juice
Benzaldehyde
Benzene/Benz01
Benzene Sulfonic Acid

PERMEABILITY
(gm.124 hr.1
100 sq. inlmil)

100% loss

68
140

Benzoic Acid

73

Benzoyl Chloride
Benzyl Alcohol

73
68

180

S
S

0.22

122

180

1.0

Bismuth Carbonate

68
140

212
73

S
S

Boric Acid,

73
73

S
S

Brandy
Brine Solution

73
73

Bluing
Borax

Bromine Gas (weak)

365

68
140

S
M
M

Bromine water, satd


Butane

73
73

U
M
M
M
M

Butanol
Butter
Butyl Acetate

73
73
73

365

S
S
S

72
176

80
30

S
S

Bromine

Liquid

Butyl Phthalate

68
140

Synthetic Resins and Polymers


TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(continued)

EXPOSURE

1
Temp., OF

Time, days

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.
M=
Marginal

PERMEABILITY
(gm.124 hr./
100 sq. in/mill

U = Unsatir.

Calcium Bisulfite

73

Calcium Carbonate

68

140
212
68

S
S

Calcium Chlorate

125

140

S
S

212

Calcium Chloride
(2.5% aqueous solution)
Calcium Chloride
(50% Solution)
Calcium Hydroxide

73

365

72

30

176
68

30

S
S

140
212

S
S

73
68

140

212
68

Calcium Salts

73

Calcium Sulfate

68

140

Calcium Hypochlorite
Calcium Nitrate (50% soln.)

Calcium Phosphate

Calcium Sulfite

S
S

212

68

140

212
73
73

86

Carbon Bisulfide

73

365

Carbon Dioxide, dry

73

Carbon Dioxide, wet


Carbon Dioxide Solution

73
68
140

S
S
S

Carbon Disulfide

73
68
140
73

365

140

106

Camphor Oil
Cane Sugar Liquors

Carbon Monoxide
Carbon Tetrachloride
Carbonic Acid
Carrot Oil
Castor Oil

365

3.64

S
S
S
U
U
S

68
140

S
S

73

73

S
U
S

143

0.0

(continued)

126

Corrosion

TABLE

1.40:

Resistant

Materials

POLYPROPYLENE

Handbook

RESINS-SHELL

REAGENT

CHEMICAL

(continued)

PERMEABILIT)

EXPOSURE

(Sol,dr ,n salurated $oIlm


unless indtcated othenwe)

Castor Oil
Caustic Soda, cont.
Caustic Soda, dil.
Cellosolve@
Cetyl Alcohol
Char-co-sol
Chlorobenzene
Chlorine

Gas

Chlorine

Liquid

Chlorine Water
Chlorine

(wet)

Chlorine

(dry)

Chlorinated

Hydrocarbons

Chloroform
Chlorosulfonic

Acid

Chlorox
Chrome Alum

Chocolate Syrup
Chromic Acid (10%)
Chromic Acid (30%)
Chromic Acid (40%)
Chromic Acid, 2 N
Cider
Citric Acid (10%)

sitric Acid, 2 N
Zitrondropar (Lemon)
Zlove Oil

73
73

365

73

365

68

140
212
73

S
S
S
S
S
S

73
73
73

365

140
73

30

30

S
S

68

140
68

180

S
S

0.48

122

180

2.3

140

30

73
68

365
109

S
S

6.43

122

109

22.77
0.0

73

302

140

159

5.35

Zoconut Oil

73

162

0.0

96

0.0

Zod Liver Oil

73

Coffee

73

Zoke Oven Gas

73

(continued)

Synthetic

TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

ISohds

I saturated solutmn
unless,nd,cated otherwsel

Temp., F

Time, days

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.
M= Marginal
U = Unratis.

Copper Salts

73

Copper Sulfate
Core Oils

73
73

S
S

Corn Oil
Cottonseed Oil
Creosote
Cresal
Cresol
Cupric Chloride
Cupric Cyanide
Curpic Fluoride
Cupric Nitrate
Cupric Sulfate
Cuprous Chloride
Cyclohexane
Cyclohexanol
Cyclohexanone
DDT Spray
Decalin
Detergent Solution
(Heavy Duty)
Developers
(Photographic)
Dextrine
Dextrose
Diacetone Alcohol
Diazo Salts
Dibutyl Phthalate

73
140

PERMEABILITY
(gm.124 hr.1
100 sq. in/mil)

158
167

S
S

0.0
0.0

73

191

0.0

140
73
73

113

S
S
U

0.0

68

S
S

68
140

68

140

S
S

68
140

68

140

68

140

68

140
68
122

180
180

S
M
M

194.0
100% loss

68
122
68
122

180
180
189
180

S
S
M
M

0.13
1.63
0.22
13.4

68
73

S
U

73

30

140

30

68

140

68

140

68

140
68

180

S
S

0.21

122

189

3.94

68
140
73

127

(continued)

EXPOSURE

REAGENT

Resins and Polymers

s
S
M

(continued)

128

Corrosion Resistant Materials Handbook

TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(ccIntinued)

EXPOSURE

REAGENT
(Solids

an rarursted solution
unlessmdicated ocherwise~

Temp., o F

Time, days

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.
M= Marginal
U= Unsatis.

Dichloroethylene

73

Diethanolamine

68

Diethyl

Carbonate

Diethylene

Glycol

Di-iso-octyl

Phthalate

Dimethyl

Ether

Dimethyl

Formamide

Dimethylamine
Dioctyl

Phthalate

(DOW

140

68
140

S
M

68
140

68
140

S
S

68
140

PERMEABILITY
(gm./24 hr./
100 sq. in/mill

73

30

140
68

30
180

S
S

1.1

122

180

10.6

70

100

140
73

M
M

68
140
73
140

78
160

S
S
S

68
140
68
122

180
180

S
S
S

0.0
0.40

73
68
122

180
180

S
S
S

1.42
17.9

Solution)

73

365

Ethanol (95%)
Ethanolamine

73
68

365

S
S

Dioxane
Disodium

Phosphate

Distilled Water
Dobanic Acid
Donax 8
Dye (Rit)
Epichlorohydrin
Ethanol

S
0.55
5.03

(50% Aqueous

140
73

Ethers
Ethyl Acetate

S
S

73

365

7.0

122

180

100% loss

140

100

M
M
M

Ethyl Acrylate

68
140

Ethyl Alcohol

73
140

365
100

S
S

68

30

Ethyl Alcohol

(50%)

(continued)

Synthetic

TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

Time, days

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.
M= Marginal
U-i Unsatis.

Ethyl Alcohol

(50%)

140

30

Ethyl Alcohol

(95%)

73

100

140
68

30

Ethyl Chloride

S
M

Ethylene

140
68

Chloride

140

68
70

180
30

M
M

Ethylene Glycol
Ethylene Oxide
EthYl Oleate

73
50
68

365

S
M
S
M

140

Ferric Chloride
Ferric Nitrate
Ferrous Chloride
Ferrous Sulfate
Fish
Flit

Insecticide

Fluosilicic Acid

PERMEABILITY
bnJ24 hr./
100 tq. in/mill

Ethyl Ether
Ethylene Di-chloride

Fatty Acids, Ce

212
68
140
73
68

M
S
S
S
S
S

140
73

73

73
68

S
S

68

140

73
72
73

90

S
S

72

30

S
S

Formic Acid (Anhydrous)

73

365

Freon@

73

Fructose

68

140

68

140

68
140
73
68
140
73

S
S
U
M
M
S

0.31

S
S

0.31
24.7

Fly Spray (Ortho)


Formaldehyde, (35% Solution)
Formaline, (40% Solution)
Formic Acid (85%)

Fruit Juice
Fruit Pulp
Fuming Nitric Acid
Furfural
Furfurol
Gas Oil

68
122

129

(continued)

EXPOSURE

Temp., OF

Resins and Polymers

180
180

(continued)

130

TABLE

Corrosion Resistant Materials Handbook

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(continued)

EXPOSURE

REAGENT
LSolldr I saturated solution
unlesstndacatedofherwsel

Temp., OF

Gasoline

Gasoline (Aviation)
Gasoline (Sour)
Gearbox Oil

Time, days

CHEMICAL
EXPOSURE
PERFORMANCE
S = S8tis.
M= Marginal
U= Unutis.

73

100

73

365

100% loss

140
73
73

100
365

M
M

100% loss

140

S
M

73
73
73

S
S
s

Glycolic Acid (30%)

68
140
68

Glycerol

140
68

S
S
S
S
S

Grape Sugar

122
68

Glycerine

180
180

140

S
S
S

68

Green Soap Solution

73

365

Heavy Duty Detergent

73

30

(OMO)

73

100

73
73

180
365

M
M

(5%)

Heptane
Hexane
Household Detergent
Household Ammonia
Household Soap
Hydrobromic
Hydrochloric

Solution

Acid

-0.14
-0.86

Grease

Solution

100% loss

68

Gelatin
Glucose
Glue

PERMEABILIT? I
(gm.124 hr./
100 sq. in/mill

70

100

140

100

73
73

100% loss

S
S

68

140

Acid

(Cont.) (38%)
-lydrochloric Acid (10%
aqueous solution)

73

100

73

365

100
365

S
S

iydrochloric

Acid (30%)

140
73

hydrochloric

Acid (35%)

68

180

73
140

100
100

S
M

72
176
73
73

90
10

S
S
S

365

iydrochloric

Acid (36%)

iydrochloric

Acid (50%)

iydrochloric

Acid, 2N

.35

(continued)

Synthetic Resins and Polymers

TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(continued)

EXPOSURE

REAGENT
IWads

m saturated solution
unlerrmdxated otherw84

Temp., o F
Hydrocyanic

Acid

Hydrolfluoric

Acid, Dil.

Time, deys

CHEMICAL
EXPOSURE
PERFORMANCE
S = Setir.
M= Marginel
U= Unsetis.

73

73

Hydrofluoric

Acid (38%)

73

30

Hydrofluoric
Hydrofluoric

Acid (40%)
Acid (50%)

140
73

30

Hydrofluoric

Acid, Techn.

72

90

S
S

68

Hydrogen Chloride Gas, dry

140
68

S
S

Hydrogen fluoride

140
73

S
S

Hydrogen
Hydrogen Peroxide

73

(3% Solution)

73
73

100
365

S
S

73
140

30
30

S
U

Hydrogen Bromide (10%)

PERMEABILITY
(9mJ24 hr./
100 sq. inlmil)

Hydrogen Peroxide
(28% Solution)
Hydrogen Sulfide, dry

73

73

68

Hydrogen Sulfide
(wet + aqudbus solut&n)
Hydroquinone

140
lgepal
Ink, Washable

73
73

Iodine Solution

73

Iodine (in alcohol)


losan
lpana Plus

S
365

S
S

365

S
S

140

30

73

30

73

68

180

122

180

68
122
73

186
80
30

M
M
M

140

30

109
86

Kerosine

68
122
73
68

180

S
S
S
S

Kerosine (No. 2 fuel oil)

122
140
73

180
106
30

M
M
M

Isopropyl Alcohol
Isopropyl

Ether

lsooctane

5.10
0.25
3.74
48.0
100% loss

Kardemommudropar
(Cardamom
Karo Syrup

0.110
2.89
4.27
59.0

131

132

TABLE

Corrosion Resistant Materials Handbook

1.40:

POLYPROPYLENE

RESINS-SHELL

(continued)

CHEMICAL

REAGENT

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.

EXPOSURE

ISohdr I saturated solutcm


unless tndicated otherwise)

Temp.. OF

180

180

S
M

140

Kresol

73

73

Lacquer and Lacquer Solvents


Lactic Acid

73

Lactic Acid (20%)

73

Lanolin

68
73
73

Ligroine

140

65
14

68

180

122

180

73

365

Linseed Oil (blue)

73

30

73
140

100
100
303

be
Machine Oil
Magenta Dye (2% Soln.)
Magnesium Chloride
Magnesium Carbonate

Magnesium hydroxide

73
73

S
S

68
140
73
68
140
212
73
140

S
M
M
M

258.0
100% loss

S
M
M
M
S
S
S
S
S
S
S
S
S
S
S

140
212

S
S

68
140

S
S

212
73

S
S

Manganese Salts

73

Mayonnaise

73

Meat Sauce

68

Malic Acid

23.5

73

Magnesium Sulfide

1.56

212
Magnesium Sulfate

4.62
5.38
0.85
4.53
0.23

73

Linseed Oil

Oil

S
S

Lime Sulfur

Lubricating

U
S

365

140
Lead Acetate
Lemon Oil

U= Unsatis.

68
122

Kleenosan
Windshield

M= Marginal

140

140
140

Washer Solvent

Time. days

30
30
30
69
68

Kerosine (No. 2 fuel oil)


Kleenezy
Kleer-View

PERMEABILITY
kgn.124 hr.f
100 sq. inlmilb

S
180

0.29

Synthetic

TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

CHEMICAL
EXPOSURE
PERFORMANCE

(Sol&

I saturated solution
unlesstndlcated otherwtre)

s *

Meat Sauce
Mennens Skin Bracer
Mercuric Cyanide
Mercurochrome
Mercuric Chloride
Mercurous Nitrate
Mercury
Methyl Alcohol

(100%)

Methyl

Bromide

Methyl

Ethyl Ketone

Methyl

lsobutyl Carbinol

Methyl

lsobutyl

Methylene

Ketone

PERMEABILITY
(gmJ24 hr./
100 sq. in/mill

Satir.

M= Marginal

Temp., OF

122
73
140
68

Time. days

180
23
23

u - Unsatir.

S
S
S

140

S
S

73
73
68

S
S
S

140
73

S
S

73
140

365
30

68
140
68
122

180
180

1.3
0.68
6.8

S
S
M
U
M
M

3.5
84.0

68

180

0.21

122

180

2.7

70

100

140

100

U
M

Chloride

73

Milk
Mineral Oil (White)

73
73
140

30
30
30

S
M
M

Molasses
Mondludropar

73
68
122

109
86

S
S
S

68
140
73
68

180

S
S
S
S

0.031

122

180

0.26

140

100

Monochloracetic

(Almond)
Acid

MothSpray (Black Flag)


Motor Oil (Shell X-100)

Mustard Paste

73

n-Heptane
Naphtha

140
68

Naphthalene

68
140

Natural Gas
Neatsfoot Oil
Nickel Chloride

0.16
1.29

S
100

M
M

M
M

212

73
73
140

S
S
S

73

133

(continued)

EXPOSURE

REAGENT

Resins and Polymers

103
110

0.0
0.06

(continued)

134

Corrosion Resistant Materials Handbook

TABLE 1.40:

PGLYPROPYLENE

RESINS-SHELL

CHEMICAL

EXPOSURE

Temp.. OF

Nickel Nitrate

Nickel Salts
Nickel Sulfate
Nitric Acid, Cont.

(continued)

Time, days

CHEMICAL
EXPOSURE
PERFORMANCI
S = Sstir.
M= Marginal
U- Unratcs.

68

140
212

S
S

73
73

S
S

73
122
140
70
140

365

S
S
U
S
M
tvl

73

180
30
100
100
100

Nitric Acid (40%)

73

365

Nitric Acid, Cont.

140
70

30
100

U
M

Nitric Acid, Oil (10%)


Nitric Acid, (30%)

(50%)

140

100

Nitric Acid (75%)

68

180

Nitric Acid, Fuming

73

365

Nitrobenzene

Nitrogen Oxides

68

180

122

180

140

100

73
73
73

82

73

100

68
122

180

S
S

180

140
68

30

3ils. Vegetables
3leic Acid

Ileum

0.42
0.40
8.4

Vutmeg Oil
(21%)

0.42

Vitrous Acids
DPC 60 Solution

PERMEABILITY
(gm.124 hr.1
100 $9. idmil)

73

1.25

0.076
0.27

U
U

140
212
73

365

U
S

140

152

0.0

68

180

0.28

122

180

2.3

Oxalic Acid (50%)

73

365

Oxygen Gas
almitic Acid

73
73

S
S
S

3live Oil
3xalic Acid

araffin

Wax

araldehyde

S
S

68
140
68

M
M

140
)eanut Oil

73

133

0.0

(continued)

Synthetic

TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

CHEMICAL
EXPOSURE
PERFORMANCE

lSol,ds

on saturated solution
unlessmdlcated otherwsel

Peanut Oil
Peppermint

Oil

Perchloric Acid
Petroleum Oils, Sour
Petroleum

Oils, Refined

Phenol
Phenol Solution

(5%)

Phosphoric Acid (25%)


Phosphoric Acid (25-50%)
Phosphoric Acid (85%)
Phosphorous Oxychloride

s = Satis.

Temp., OF

Time, days

Marginal
lJ= Unsatis.

140
73
120

73
196
95

S
S
M

M=

73
73
73

100 sg. inlmil)

0.07
0.14
39.3

73
140

100
loo

S
S

73
140

365
30

S
S

73
73
70

S
S
109

140

108

S
M

68

Picric Acid

73

68

140

Chromium,

PERMEABILITY
(gm J24 hr./

S
M

Plating Solutions:
Brass, Cadmium,

135

(continued)

EXPOSURE

REAGENT

Resins and Polymers

Copper, Lead, Gold, Indium,


Nickle, Rhodium, Silver,
Tin, Zinc.
Potassium Bichromate/
Sulphuric

Acid/Water

(5/l 00/5)
Potassium Bicarbonate

70

106

140

108

68
140

S
S
S

Potassium Borate

68
140

Potassium Bromate

68
140

Potassium Bromide

68
140

S
S
S
S
S

Potassium Carbonate

73

Potassium Chlorate
Potassium Chloride

73
73

S
S

Potassium Chromate

68
140

S
S

Potassium Cyar.ide

68
140

212

S
S

Potassium Ferricyanide
Potassium FerrVFerrocyanide

68
140
68

S
S

(continued)

136

Corrosion Resistant Materials Handbook

TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(continued)

CHEMICAL
EXPOSURE
PERFORMANCE

EXPOSURE

REAGENT
(Sohdr

m saturated solution
unlerr mdicated otherwsel

Temp., OF
Potassium FerrVFerrocyanide

140

Potassium Fluoride

212
68

Potassium Hydroxide

140
212
68

Potassium Hydroxide
Potassium iodide
Potassium Nitrate

122
73
73
68

(50%)

Potassium Perborate
Potassium Perchlorate

(10%)

Potassium Persulphate

Time, days

S = Satis.
M= Marginal

PERMEABILITY
(gm./24 hr./
100 sq. inlmil)

u= Unsatir.

S
S

180
180
365

S
S
S
S

140

S
S
S
S
S

212
68

S
S

140
68

S
S

140
68

140

0.0
0.48

Potassium Permanganate
Solution
Potassium Sulfate

70

100

140
73

100

M
M
S

Potassium Sulfide

68

S
S
S

Potassium Sulfite

140
212
68

Propane
Propionic Acid
Propylene Dichloride
Pyridine
Rice Barn Oil
Rosin (light)
Safflower

Oil

Sauerkraut
Shell X-100
Shellac

140

S
S

212
73
68
140

S
M
S
M

68

140

73
73
140

S
S
S

106
111

73

73
140
73
68

161
63

122
73

0.0
0.0
0.0
0.0

180

S
S
S
S

180

0.26

0.031

(continued)

Synthetic

TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

Shoe Polish (liquid)


Sea Water

73
68

Silica Gel

140
212
68

Silicone Oil
Silver Nitrate
Soap Solution

(1%)

Soap Solution

(5%)

Soapless Detergent
Sodium Acetate

Sodium Benzoate (35%)

Time, days

CHEMICAL
EXPOSURE
PERFORMANCE
S = Sotis.
_
M= Marginal
U= Unsatis.

140

212
73
73

365

S
S

73

30

140

30

70

100

140
73

100

S
S

68

140

212
68

140

S
S

2t2

73

Sodium Bisulfate

73

Sodium Bisulfite

73
73

Sodium Bromide Oil Soln


Sodium Carbonate
Sodium Carbonate,

68

S
S

140
68
140

S
S

73
72

365
30

S
S

176

30

73

30

140

30

73
73

365
30

S
S

(20% Solution)
Sodium Chlorate

140

30

sodium Chloride,

72

90

176

30

73

365

140

30

Satur. Solution
Sodium Carbonate
Sodium Carbonate
aqueous solution)
sodium Carbonate

Solution

(2% Soln)

PERMEABILITY
(gm.124 hr./
100 sq. in/mil)

S
S
S
S

Sodium Bicarbonate

Sodium Borate
Sodium Bromide

137

(continued)

EXPOSURE

Temp., OF

Resins and Polymers

(2.5

73

Sodium Chloride
(10% Solution)

(continued)

138

Corrosion Resistant Materials Handbook

TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

REAGENT

(continued)

CHEMICAL

EXPOSURE

Gollds

&n saturated solution


unlessindicated otherwse)

Temp., OF

Sodium Chlorite

(2%)

Time, days

68

Sodium Chlorite

(20%)

140
68

Sodium Chlorite

(30%)

140
68

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satis.
M= Marginal
U= Unsatis.

S
S
s
M
S
M

Sodium Chromate

140
68

Sodium Cyanide

140
73

68

140
212
68

S
S

Sodium Dichromate

Sodium Ferricyanide

Sodium Ferrocyanide

PERMEABILITY
(gm.124 hr./
100 sq. in/mill

S
S

140

S
S

212
68

140

212

Sodium Hydroxide

73

365

(1% Solution)
Sodium Hydroxide

140
72

30
90

S
S

(30% Solution)
Sodium Hydroxide,

176
70

30
365

S
S

(50%)
Sodium Hydroxide

140
73

100
30

S
S

(60% Solution)
Sodium Hypochlorite

30
180
180
30
30
30

S
S
S
S
M
M
M
M

Sodium Hypochlorite

(5%)

Sodium Hypochlorite

(10% Soln)

140
68
122
73
140
73

sodium Hypochlorite

Soln Cont.

73
70

100
100

140

100

0.58
1.92

M
S

sodium Metaphosphate

73

sodium Nitrate

73

sodium Palmitate

73

30

(5% Solution)
sodium Perborate
Godium Phosphate, Alkaline

73
73
73

100

sodium Phosphate, Acid

73

sodium Phosphate, Neutral

73

Aodium Silicate

73

S
S

(continued)

Synthetic

TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

139

(continued)

PERMEABILITY

EXPOSURE

REAGENT

Resins and Polymers

(Solids in saturated solution


unless indicated otherwise)

Sodium Sulfate
Sodium Sulfide
Sodium Sulfite
Sodium Thiosulfate

(hype)

Soybean Oil
Spindle Oil
Stannic Chloride

Stannous Chloride
Starch
140
Stearic Acid
Succinic Acid
Sugars and Syrups

Sulfate Liquors
Sulfur
Sulfamic Acid

212

73
73
68
140
212

S
S
S

73
73
68
176

S
S

Sulphur Dichloride

68

S
S
S
S
S

Sulfur Chloride

73

Sulfur Dioxide

(dry)

73

Sulfur Dioxide

(wet)

73
73
140
70

365
30
100

140

100

73

30

140

30

72
176
72

90
10
90

S
S
S

176

10

73
68

365
180

S
S

Sulfuric Acid (3%)


Sulfuric Acid, Dil. (10%)
Sulfuric Acid (30%)
Sulfuric Acid (50%)
Sulfuric Acid (96%)
Sulfuric Acid (97%)
Sulfuric Acid, cont. (98%)

S
S
S
S

-1.01

(continued)

140

Corrosion Resistant Materials Handbook

TABLE

1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(continued)

EXPOSURE

REAGENT
(Solids m saturated solution
unlesslndlcsted othmwr~~

Sulfuric Acid, cont. (98%)


Sulfurous Acid

Temp., OF

Time, days

122
140

180
100

S
M

180
180

S
M
M

73
68
122

Super Shell

68

Tallow

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satir.
T
M= Marginal
U= Unsatis.

Tannic Acid

73

Tar
Tartaric Acid

73
73

S
S

Tea

73
514 Solution (27%)

Tetrahydrofurane
Tetralin

73

S
S
M

365
100

S
M
M

Tomato

73

2T Oil

68
122
73

180
180
30

S
S
M

140
72
176

30
90
30

U
M
M

Transformer

Oil

Transformer

Oil, DTE/3D

Trichloracetic Acid, 2N
Trichloroethylene
Triethanolamine
Tri-sodium

Phosphate

Two-stroke

Oil

Varnish
Vaseline
Vaseline Oil
Vinegar

S
U

68
140
73

S
S
S
M

365

140

30

70
140

100
100

S
M

73

Urea
Vanillindropar

73
73

73

Turpentine

(Vanilla)

68
122

100% loss
100% loss

S
100

73
73
73
73
140

Thiopen
Toluene

-1.44

140

Teepol

PERMEABILITY
(gm.124 hr.1
100 sq. in/mil)

0.0
4.1

S
109
86

S
S

1.99

73
68
122

180
180

S
S
S

0.0
0.073

72

90

176
68

30
180

S
S

0.64

122

180

2.81

(continued)

Synthetic

TABLE 1.40:

POLYPROPYLENE

RESINS-SHELL

CHEMICAL

(continued)

EXPOSURE

REAGENT
(Sol,dr

I saturated solutmn
unlesslndacated otherwml

Temp., OF

Time, days

365
14

Water (brine)

73
140
73

Water (fresh)

73

Water

Water (potable)
Wax Crayon

176

Wedac
Wesson Oil
Wheat Germ Oil
Whiskey
White Paraffin

Resins and Polymers

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satir.
M= Marginal
U = Unsatis.

PERMEABILITY
(gm.124 hr./
100 sq. in/mill

S
S
S
S

30

140
72

30
30

S
S

2.46
0.10

73

160

0.01

140

58

0.0

73

73

68
176

S
S

White Spirit (low aromatic


content)

73

100

White Spirit (high aromatic


73

100

Wines

73

30

Xylene

68

180

100% loss

73
122
140

365
180
100

M
M
M

100% loss
100% loss
100% loss

content)

Yeast
Zinc Chloride
Zinc Oxide
Zinc Sulfate

68
140
73
68
140
73

S
S
S
S
S
S

141

142

Corrosion

TABLE 1.41:

Resistant

Materials

POLYSTYRENE

Handbook

RESINS-HUNTSMAN

CHEMICAL

These thermoplastic
resins are crystalline,
rigid and of brilliant
clarity.
They are formulated
applications.
All the polystyrene
resins are processed by extrusion,
thermoforming,
blow
only the rubber-modified
impact polystyrene
or ABS can be thermoformed.

REAGENT

CHEMICAL
EXPOSURE
PERFORMANCE

EXPOSURE

(Solodr 4 saturated solutm~


unless indscated otherwtsee)

s =

Temp., OF

Time. days

Satis.

M= Marginal
U= Unsatis.

Acetic

Acid 5%

77

365

Acetic

Acid

10%

77

365

S
M

Acetic

Acid

100%

77

365

Acetophenone

Adrenalin

S
M

Hydrochloride

Adrenalin
in oil
Ally1 Alcohol
Chloride

(Sat.)

122

365

Aluminum
Ammonia

Sulphate

(Sat.)

122

365

S
S

122

365

Ammonium

Hydroxide

Amyl

Alcohol

Amyl

Acetate-n

U
U

Amy1 Phthalate
Amseed Oil
Aspirin (pwd)
Atropine
Sulphate
Barium Carbonate
Beef

(pwd)

365

Z
S

122

365

S
U
S
U
S

122
122

365

365

S
U

122

Benzaldehyde
Benzedrine
Benzene
Acid

Acetate

Borax (Sat.)
Boric Acid
Bromine

a SolventI

Aluminum

Benzyl

SOLVENT
(X lndtcater that
the reagent acted as

Acetone

Benzoic

to suit a wide variety of


molding
or injection
but

Liquid

Butter
Butyl

Acetate

iso

Butyl
Butyl

Acetate
Alcohol

n
iso

Butyl Alcohol n
Butyl Phthalate
Caffeine (Sat.)
Calcium Hypochloride
Calcium

Hypochlorite

Camphor
Carbon Tetrachloride
Carbolic

Acid

Carbolic Acid
Cassia Oil
Castor Oil

50%
100%

77

365

S
S

15%

U
S
M
U
M
U
M

U
U
S
(continued)

144

Corrosion Resistant Materials Handbook

TABLE

1.41:

POLYSTYRENE

RESINS-HUNTSMAN

CHEMICAL

(continued)

CHEMICAL
EXPOSURE
PERFORMANCE
S = Satir.

EXPOSURE

REAGENT
(Soltdr in saturated solution
unless md~cated otherwant

30%
jlycerine
ieptyl Alcohol-n
fexane
iexyl Alcohol-n
horseradish
ioney
hydrochloric Acid
iydrochloric Acid
iydrofluoric Acid
iydrogen Peroxide
iydroquinone
odine Tincture
so-propyl Alcohol
(erosene
.actic Acid 16%

M=MargiMl

Temp., OF

Time. dayr

77

240

SOLVENT
(X lndoutn
that
the r+gent acted *I

a 5ob4ent)

U- Unutir.

;lucose

10%
38%
10%
30%

77

365

77

365

77

365

s
S
s
M
S
S
M
U
S
M
M
M
U
U

_anolin
_ard
.auryl Alcohol

S
U
S
M

.ead Arsenate
_ead Nitrate

122

365

_emon Juice
_ime Water
_ipstick
Aagnesium Carbonate
Aaleic Acid 10%

S
U
S
M

122
77

365

365
365

S
S

dercuric Chloride 5%
Jlesityl Oxide

122

U
U
M

vlethyl Acetate
wlethyl Alcohol

vlethyl Ethyl Ketone

U
U

Methyl

wlethyl Chloride
lsobutyl Ketone

Methyl Propyl Ketone


Methyl Salicylate

(Oil of
U

Wintergreen)
Methylene

Chloride
77

Milk
Mineral Oil
Mono-Chloro

Benzene

Motor Oil
Mustard
Nitric Acid 20%
Nitroglycerine

14

S
S
U
M

M
U
S

(continued)

146

Corrosion Resistant Materials Handbook

TABLE

1.41:

POLYSTYRENE

RESINS-HUNTSMAN

CHEMICAL

EXPOSURE

Tannic Acid 2%
Tartaric

Acid

Tea (Sol.)
Tetrahydrofurfuryl

Alcohol

Tetralin
Thionyl Chloride
Titanium Tetrachloride
Toluene
Trichloroethylene
Trisodium Phosphate (Sat.)
Triethylene

Glycol

Triethylene

Tetramine

Turpentine
Water
Water Carbonated
Witch Hazel Distilled
Worcestershire

Sauce

Zinc Carbonate
Zinc Chloride
Zinc Stearate

50%

(continued)

Synthetic

TABLE

1.42:

POLYSULFONE-UNION

Resins and Polymers

147

CARBIDE

UDEL
Polysulfone
is a high performance
thermoplastic
known for its high temperature
resistance [3OOF (149C)
UL listing for continuous
use], hydrolytic
stability,
and excellent
close tolerance
moldability.
Polysulfone
also
possesses good resistance to a wide variety of aggressive environmental
conditions.
In the most general terms, POlYsulfone is highly resistant to aqueous mineral acids, alkali, and salt solutions. Resistance to detergents and hydrocarbon oils is good, even at elevated temperatures
under moderate levels of stress. In polar organic solvents such as
ketones, chlorinated
hydrocarbons,
and aromatic hydrocarbons,
polysulfone will swell, dissolve, or stress-crack.
Chemical
Inorganic

Chemicals

(22C.)600C.)(tt50C.)(990C.)
730F: i40F: ittSF.ilOOF.

Acids
Chromic

Acid,

Chromic

Acid,

12%

Resistance

(121C.)(1490C.)
.25OF.
300F

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NK

Hydrobromic

Acid,

20%

Hydrochloric

Acid,

10%

Hydrochloric

Acid,

15%

Hydrochlonc

Acid,

20%

Hydrochlorw

Acid,

37%

LR

NR

NK

NR

Hydrofluoric
Nltnc

60%

Acid,

50%

Acid, 10%

YR

Acetlc Acid. .50%


AC~IIC Acid.

N#tr!c Acid,

71%

NR

Phosphoric

Acid,

YK

*
R

Sulfuric

Actd, 65%

Acid. 75%

NH

Sulfunc

Acid. 85%

\K

NR

UK

1K

Anhvdrlde

Arc=tnnl=

40%

Acetic

Acod. 95%

NR

YK

YK

Bases
Ammonia.

15%

Ammonia.

29%

Potawum

Hydroxide,

20%

Potawum

Hydroxide,

35%

I?

\K

lo%

Benzene.

___-

100%

Butanol,

100%

Butvl

Acetate.

Butyl

CELLOSOLVE

5%

Hydroxide,

10%

K-

Solvent

Carbon

CELLOSOLVE

III~IC

UK

Crude

UK

C!clohexane.

*
*

Tnchlorlde,

Sat.

Calcium

Chloride,

Calcium

Hypochlorlte
100%

Sat.

Wet

100%

Oxygen

Ozone
Narrate,

Sar.

Ethanol,

NR

Ethanolamlne.
Ethyl
2.Ethvl

*
R

Freon:

BF,

Freon

TMC

LR

Furfural

Gasoline,

Sodwm

Hypochlorite,

17%

Glucose

Sodium

Stl~cate, 1.7%

LR

Clvcerlne.
n-Heptane,

\K

YR

NK

NR

.
.
.
*

*-

NK

NR

*
.
.
1
f
*
f

*
+
.
*
f
.

UR

YK

UK

NK

NK

UK

rK

UK

CK

YK

.
.
.
.

f
.
.
r

f
*
.
.

.
.
.
.
NK

NK

ZiK

UK

UK

\iK

LK

vuK

\iK

UK

\K
R

\K

\K

*K

\K

.-

100%
100%

11 , lOOo/
0
Freon22. 100%

5X%

100%

Glycol.

Hypochlortte.

S.U.

Acid.

Ethylene

Carbonate,

Chloride,

100%

D~am~ne, 92%

Sodium

Zinc

NK

100%

Butvrtc

Sodium

1.7%

100%

Ethylene

Freon

YK

100%

Acetare,

Formaldehyde,

UK

LR

100%

100%

Phrha!ate,

100%

ether,

UK

Dwopropyl
Dtoctyl

100%

100%

ether,

NR
NR
R

Green Liquor
-Hydrogen
Peroxide,

.
*

NK
NR

100%

Cvclohexanone,

Liquor

\R
UK

40%

011. Texas.

Dwthyl

100%

100%

Oil.

Chlorine,

Solvent,

4cld.

Cottonseed

100%

100%

100%

Tetrachlorlde.

YR
UK

100%

40%

UK
UK

Toluene,

Persulfate,

YR
JR

Hydroxy

Ammonium

hK

Prop~onate

\R

UK

Butylated

*
*

UK

Calcium

\K

25%

*
*
.
.

NK

\K

LR
R

50%

NR

100%

Hydroxide.

lOO6

Hydroxide.

24%

Solvent.

Sodium

Persulfate.

i\n~sole.

Sodium

Other
Ammonium

R
LK

Hvdroxy

Butvlated

Chloroform,

Hydroxide.

Antimony

100%

Chlotobenzene.

Sodium

Potawum

100%

CARBITOL

Sodium

Black

Glacial

Aceton~trtle.

Suifwc

Sulfuric

R
R

NR

Acid,

R
R

UK

Sulfuric

R
R

100%

10%

NR

NR

Acid,

Ar,d

LR

(149Y.J
300F.

Actd. 20%

UK

LR

depending

Acetic

possible

Acetic

NR

appllcatmns

(22C.)(600C.~(850C.)(990C.~
73F.
140F. lBSF.
210F.

Chemicals

20%

(many

No data

40%

Phosphoric

NR
*

Acid,

Actd, 50%

Recommendation

on stress level)
Not Recommended

LR

Acid,

Acid. 85%

LImIted

LR

Nitric

Phosphoric

Recommended

LR

Nifric

Phosphoric

rarrngs

IO

Organic

NR

20%

Key
R

Chart

n-Hexane,

100%

, 1007

loo&

100%
100%
100%

LR
LR
LR

.-

UK

UK

YK

NK

PUK

NK

NK

NK

NK

NK

LR

R
R

*
*

*
*

*-

(continued)

148

Corrosion Resistant Materials Handbook

TABLE

1.42:

POLYSULFONE-UNION
Organic

CARBIDE

Chemicals

Irooctae,

(22OC.)(6OOC.) (85~C.J(9s~C.)(149~C.)
73OF. 140F. 185OF. 210F.
300F.

(continued)

100%

Iropropanol.

100%

Kerosene,

100%

Lactac Acid,
Laurie

(continued)

60%

Acld

Linseed

Oil,

Malomc
MEK,

100%

Acid,

100%

100%

Methanol,

100%

Methylene

Chloride,

100%

LR

1.R

*
*

SR

K
R

*
1

*
*

*
.

*
.

NK

NK

NK

YR

NR

NR

NK

UK

zrK

NR

NR

NR

NR

NR

NR

100%

Oxahc Actd, 20%

NR

NR

NR

UR

Morphoiine
Oletc

Aad,

Pyrtdine

*
hR

,,,.2.2-Tetrachloroethane.
100%

UK

UK

UK

4K

Tetrachloroerhylene.

NR

UK

UK

.R

iK

NR

NR

NK

uK

\R

Sorbx

Acid,

Tnl,apn.-

100%

100%

Inns.

Trlchloroethylene,
Tributyl

100%

Phosphate

Turpentine,

VM&P

100%

Naphtha,

Xvlene.

+
hK

JR

\K

UK

QK

4iK

NK

NR

UR

NR

hiR

IR

100%

100%

Pipe 5eal Compounds


Lot-Tote

AV 100%

NK

UK

CK

LK

\K

Lx-Tire

FJ, 100%

NK

*K

UK

VK

\K

NK

NK

NK

rK

\K

Lx-Tire

E. 100%

Masters

Metallic,

Permatex
Trtion

100%

LK

*
*

Commercial

miscellaneous

n2. 100%
TF-15.

100%

Products

Clobber
Acldlc

Drain

Copperbwe
Duckreal

Cleaner,

100%

Copper

Cleaner,

Sealant.

LR
100%

100%

Odr:
ASTM

Oil

ASTM

011 82. loo<.

ASTM

011 #3, lOo%a

IK

IK

IK

A,TM

011 #lO

K
LR

*
*

*
*

W,

100%

100%

.
1

Slllcones.
SlidstIr
RTV

refers

chlorine.

speclfrcaiiy
as chlorine

to 100%
expocure

lOOY,

RTV-106

(GE)

RTV-109

(GE)

Zephlran

Thrs

140. lOO%I

88 (GE).

chlorme

(wet),

In many

Dwnfectant.

100%

It IS recognlred

of these

environmentr,

that

WIdespread
polysulfone

mdustry

practice

can provide

*
*
*
*

IS to refer

excellent

corrwon

to many

envwonm?nts.

protection

other

than 100%

Synthetic

TABLE 1.43:

POLYVINYL

CHLORIDE

Resins and Polymers

149

DUCTS-DAYCO

PLIADUCT is a continuous,
all plastic extruded
strip, so shaped that when coiled, the edges interlock
to form a rigid
duct. It is flexible.
Hand bend it to any position.
It will remain in that position
until bent again. Lightweight
and
durable,
PLIADUCT
has no wire or metal reinforcement.
It will not corrode
or oxidize.
PLIADUCT
is self-extinguishing. Service temperature
range is -10 to 150F.
Chemical Resistance Chart*
CHEMICAL

TEMlEFR^rTR;
0
0

Acetaldehyde
Acetic Acid, to 80%
Acetic Acid, over SO%
Acetic Acid, glacial
Acetic Anhydride
Acetone
Acetylene
Adipic Acid
Allyl Alcohol, 96%
Allyl Chloride
Alum
Aluminum Saks
.Ammonia (gasdry)
Ammonia (liquid)
Ammonium Fluoride, 25%
Ammonium Hydroxide
Ammonium Salts (other)
Amy1 Acetate
Amyl Alcohol
Amy1 Chloride
Anilineand Salts
Anthraquinonesulfonic
Acid
Antimony Trichlonde
Aqua Regia
Aromatic Hydrocarbons
Arsenic Acid, 80%
Arylsulfonic Acid
Barium Salts
Beer
Beet Sugar Liquors
Benzaldehyde, 10%
Berualdehyde, above 10%
Benzene
Benzoic Acid
Bismuth Carbonate
Black Liquor
Bleach (12% Cl)
Borax
Boric Acid
Breeder Pellets
(fish derivative)
Bromic Acid
Bromine, Liquid
Bromine. Vapor (25%)
Bromine Water
Butadiene
Butane
Butanol, Primary
Butanof, Secondary
Butyl Acetate
Butyl Alcohol
Butyi Phenol

NR NR
R
R
R
NR
R
NR
NR
NR
NR
NR
A
R
-R
R
R
NR
NR
NR
A
R
R
A
A
R
NR NR
R
NR
R
R
R
R
NR NR
R
NR
NR NR
NR NR
R
R
R
R
R
R
NR NR
R
R
R
R
R
R
R
R
R
R
R
R
NR NR
NR NR
A
R
R
R
R
R
R
R
R
R
R
R
fl
R
NR
R
R
R
R
R
R
R
R
R

R
R
NR
R
R
R
R
NR
NR
R
NR

CHEMICAL
Butyne Diol
Butyric Acid
Cadmium Saks
Calcium Salts
Carbon Bisuffide
Carbon Dioxide
Carbon Monoxide
Carbon Tetrachloride
Carbonic Acid
Castor Oil
Caustic Potash
Cellosolve
Caustic Soda
Chloracetic Acid
Chloral Hydrate
Chloric Acid, 200~
Chloride (water)
Chlorine (dry)
Chlorine, Gas (dry)
Chlorine, Gas (wet)
ChlorineMater
Chlorobenzene
Chloroform
Chlorosulfonic Acid
Chrome Alum
Chromic Acid, 10%
Chromic Acid, 5090
Citric Acid
Copper Salts
Corn Syrup
Cottonseed Oil
Cresol
Cresylic Acid, 50%
Crotonaldehyde
Crude Oil
Cyclohexanol
Cyclohexanone
Detergents
Dextrin
Dextrose
Diazo Salts
Digtycolic Acid
Dimethylamine
Dioctylphthalate
Disodium Phosphate
Distilled Water
Esters
Ethers
Ethyl Acetate
Ethyl Acrylate
Ethyl Alcohol
Ethyl Chloride
Ethyl Ether

TEMPERATURE

72F 140F

R
R
R
R
NR
R
R
R
R
R
R
R
R
R
R
R
R
NR
NR
NR
R
NR
NR
R
R
R
NR
R
R
R
R
R
R
NR
R
NR
NR
R
R
R
R
R
R
NR
R
R
NR
NR
NR
NR
R
NR
NR

NR
NR
A
R
NR
R
R
NR
R
R
R
NR
R
R
R
R
R
NR
NR
NR
R
NR
NR
R
NR
NR
R
R
R
R
NR
R
NR
R
NR
NR
R
R
R
R
R
R
NR
R
R
NR
NR
NR
NR
R
NR
NR

CHEMICAL

T~~PERITuRE
72-F 140F

Ethylene Bromide
Ethylene Chlorohydrin
Ethylene Dichloride
Ethylene Glycol
Ethy!ene Oxide
Fattv Acids
Ferric Salts
Fish Solubles
Fluboric Acid
Fluorine, Gas (wet)
Fluorine, Gas (dry)
Fluorcsilicic Acid, 25%
formaldehyde
Formic Acid
Fructose
Fruit Juices and Pulp
Furfural
Gallic Acid
Gasoline
Gasoline, High Octane
Gasoline, Jet Fuel, JP4
Gasoline, Jet Fuel, JP-5
Glucose
Glycerine
Glycol
Glycolic Acid
Grapesugar
Hsptane
Hezane
Hexanol, Tertiary
Hydrobromic Acid, 20%
Hydrochloric Acid, to 25%
Hydrochloric Acid, over 35%
i-iyfiocyanic
Acid
Hydrofluoric Acid, to 50%
Hydrofluoric Acid, over 50%
Hydrogen
Hydrogen Peroxide, to 93%
Hydrogen Fhosphide
Hydrogen Sutfide
Hydroquinone
Hydroxylamine Sulfate
Hypochlorene Acid
iiypochlorous
Acid
Iron Salts
Jodine
Kerosene
Ketones
KraR Liquors
&tic
Acid, 25%
Lard Oil
Laurie Acid
Lauryl Chloride

NR
NR
NR
NR
NR NR
R
R
NR
NR
R
R
R
R
R
R
R
R
R
R
R
NR
A
R
R
R
R
NR
R
R
R
A
NR NR
R
R
R
R
R
R
R
R
R
R
A
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
NR
NR
R
R
NR

R
NR
NR

R
R

R
R
R
R
R
R
R
R
fl
NR

R
R
R
R
R
R
R
NR
R
NR
R
R
R
R
R

fl
NR
R
R
R
R

(continued)

150

Corrosion

TABLE

1.43:

Resistant

POLYVINYL

CHEMICAL

Oxygen
Ozone
Palmitic Acid, to 70%
Palmitic Acid, over 70%
Paraffin
Perchlotic Acid, to 10%

Handbook

CHLORIDE

TEMPERATURE

Lead Salts
Linoleic Acid
Linoleic Oil
Linseed Oil
Liquers
Lithium Bromide
Lubricating Oil,
ASTM #1.#2. u3
Machine Oil
Magnesium Salts
Maleic Acid
Malic Acid
Manufactured Gas
Mercury Salts
Mercury
Methyl Alcohol
Methyl Chloride
Methylene Chloride
Methyl Ethyl Ketone
Methyl Iso-butyl Ketone
Methyl Sulfate
Methyl Sulfuric Acid
Milk
Mineral Oils
Mixed Acids
Molasses
Muriatic Acid
Naphtha
Naphthalene
Natural Gas
Ntckel Salts
Nicotine
Nicotine Acid
Nitric Acid. Anhydrous
Nitric Acid, to 66%
Vitric Acid, over 68%
Nitrobenzene
Nitrous Oxide
OCHlOl
Oils and Fats
Oil, Sour Crude
Oleic Acid
Oleum
Oxalic Acid

Materials

72F 140F
R
R
R
R

R
R
R
R
R
R
fl
R
R
R
R
R
NR
NR
NR
NR
R
R
R
R
R
R
R
R
NR
R
R
R
R
NR
R
NR
NR
R
R
R
A
R
NR
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
NR
NR
NR
NR
NR
R
R
R
R
R
R
NR
R
R
R
R
NR
R
NR
NR
R
R
R
R
R
NR
R
R
R
R
NR
R
R

DUCTS-DAYCO
CHEMICAL

Perchloric Acid, to 70%


Perchloric Acid, over 70%
Petroleum Liquefier
Phenol
Phenylhydrazine
Phenylhydrazine
Hydrochloride
Phosgene. Liquid
Phosgene. Gas
Phosphoric Acid, to 85%
Phosphorus (yellow)
Phosphorus Pentoxide
phosphorus Trichloride
Photographic Solutions:
DK#3
Dektal Developer
Kodak Fixer
Kodak Short Stop
Picric Acid
Potassium Alum
Potassium Bicarbonate
Potassium Bichromate
Potassium Borate
Potassium Bromate
Potassium Bromide
Potassium Salts
Potassium Hydroxide
Potassium Pemanganate,
10%
,Potassium Permanganate,
15%
Propane
Propane Gas
Propargyl Alcohol
Propyl Alcohol
Propylene Dichloride
Plating Solutions:
%rass
Cadmium
copper
Gold
lndium
Lead
Nickel
Rhodium
Silver
Tin
Zinc

KEY. R-fiecommsndod
NR-NU
Recommended
BLANK SPACES lodie

kslr ofmfic

(continued)

tacommwodatcms

TEMPERATURE
72-F
140F

R
NR
A
R
NR

NR
NR
R
NR
NR

R
NR
R
R
R
R
NR

NR
NR

NR

R
R
R
R
NR
R
R
R
R
R
R
R
R

R
R
R
R
NR
R
A
R
R
R
R
R
R

NR
above
125.F

R
R
R
R
NR

R
R
R
R
NR

R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
A
R

CHEMICU
Rayon Coagulating
Rochelle Salts
Sea Water
Selenic Acid
Sewerage
Silicic Acid
Silver Safts

mCFm2T

Bath

R
R
R
R
R
R
R
R
R
R
R

Soaps
Sodium Acetate Salts
Sodium Hydrox!de
Sour Crude Oil (west Texas)
StannicSalts
R
Stannous Salts
R
Starch
R
Blearic Acid
R
Btoddards Solvent
NR
Sulfur
R
Sulfur Dioxide, dry
R
Sulfur Dioxide, wet
R
Sulfur Trioxide
R
Sulfuric Acid, to I%%
R
Sulfuric Acid, over 8096
NR
Sulfurous Acid
R
fall Oil
R
Tannic Acid
R
Tartaric Acid
A
fetraethyl Lead
R
Tetrahydrofurane
NR
Thionyl Chloride
NR
Tirpineol
R
Titaniumfetrachloride
NR
Tanning Liquors
R
TOluol or Toluene
NR
Tri Butyl Phosphate
NR
Trichloroethyiene
NR
Triethandamine
R
Trimethyl Propane
R
Trisodium Phosphate
R
Turpentine
Fi
Urea R
Urine
Fl
Ymegar
NR
Vinyl Acetate
R
Water Acid Mine
R
Water Deionized
R
Water Demineralized
R
Water Distilled-water trash
R
Wprer Saft
R
Whiskey
R
White Liquor
R
Wines
Xylene or Xylol
NR
Zinc Satts
R

R
R
R
R
R
R
R
R
A
R
R
R
A
A
NR
R
R
NR
R
R
NR
R
R
R
R
NR
NR
NR
R
NR
NR
NR
NR
A
R
R
R
z
NR
R
R
A
R
R
R
R
R
NR
R

Synthetic Resins and Polymers


TABLE 1.44:

POLYVINYL

CHLORIDE

JACKETS AND COVERS-CEEL-CO

Typical Resistance Features of CEEL-TITE

Acetrc Acrd 20%


Acetone
*Alcohol, Ethyl
Alumfnum Chloride
Alumnum Sulfate
Ammonia Gas
Ammomum Chlonde
Ammomum f-tydroxde
A-nmontwn Sulfate
*Amy1 Chlonde
AntIme
Barium liydroxrde
Barium Sulfate
Barium Sulfide
Beet Sugar Lrquors
*Benzene
Benzorc Acrd
Black Lrquor
Bleach 12.5% acttve Cl,
Bone Acid
Bromrc Acid
Calcrum Carbonate
Calcrum Chlonde
Calctum ttydroxrde
*Carbon Btsuffide
Carbon Morwxrde
Carbon Telrachlorrde
Carbonrc Acid
Caustrc Soda
Caustrc Potash
Chlorrne Waler
Chlonne
lChlorobenzene
Chrome Ac!d 10%
Chromrc Acid 30%
Cttnc Acrd
lCcke Dven Gas
Copper Cyanrde
Copper Sulfate
lCreosol
lCvclohexanol
Cjclohexanone
Drmethvlamrne
Droctylphthalate
Drsodrum Phosphate
Ethers
Ethylene Glycol
Fatty Acrds
Ferrtc Chlonde
Ferrous Sulfate
Fluonne (gat-wet)
Fluoailicic Acid
Fomaldehyae
Formrc Acrd
Fruit Jutces + PUID
*Furfural
Qasokne (refined)
Glycenne
Hydrochloric Acrd
t-tydrocyanrc Acrd
lttydroiluorrc Acrd 50%
Hydrogen Sulfide (dry)
Hydroqurnone
Hypochlorous Acid
lodlne Trncture
Kerosene
Magneswm Chlorrde
Malerc Acrd
Metnyl Alcohol
*Methyl Ethyl Ketcne
*Methyl Chloride
Mrxed Acrds
Nickel Chlonde
Nrckei Sulfate

300 Series PVC-UVR

and 500 Series PVC

lNrtnc Acrd Anhydrous


Nttnc Acrd, 10%
Nrtrtc Acrd. 63%
Nitrous Oxrde
011sand Fats
Olerc Acrd
Oleum
Cxalrc Acrd
Palmrtrc Acrd, 10%
Perchlonc Acid, 10%
?eFe;;um 011s (sour)
Phosgene Gas
Phosphonc Acrd, 25%
Phospnorrc Acid. 50%
*Phosphorous Trichlonde
Phthalrc Anhydrrde
Plattng Soltirons
Potassrum Chlonde
Potassum Cyanide
Potasscum Drchromate
&w;ss;
Hydroxide
Permanganate. 10%
Propy Alcohol
*Propylene Drchlonde
Sea Water
Stlver Cyanrde
Silver Platrng Solutron
Srlver Nrtrate
Sodrum Brsulffte
Sodrum Chlonde
Sodrum Cyantde
Sodturn Ferrocyanrde
Sodrum ttydroxrde
Sodrum l-typcchlonte, 125%
Sodrum Sulfate
Sodrum Sulfite
Sodium Throsulfate
Sour Crude 011
Stannrc Chlonde
Steanc Acrd
Stannous Chlonde
Sulfur
Sulfur Dfoxide (dry)
Sulfur Droxfde (wet)
Sulfunc Acid, Ib%
Sulfuric Acrd. 70%
Sulfurous Acid
Tannrc Aced
Tartanc Acrd
Tetrahydrofuran
lToluene
lTnchloroethylene
Triethanolamine
Trisodtum Phosphate
Turpentine
Urea
Vinegar
Vl$ter (acrd mane water)
Whtskey and Whrte liquor
Xylene
Zfnc Chloride
Zrnc Sulfate
S-Satrsfactory
U-Unsatisfactory
Test Method ASTM -

D - 1784

Satrsfactory for use under atmcephenc


condrtrons

751

Corrosion Resistant Materials Handbook

752

1.45:

TABLE

POLYVINYL

CHLORIDE

LINERS-FABRIC0

CHEMICAL

RESISTANCE CHART
R-Recommended
RT-Room

ANIC

IN0
Chemical

Reagent

INORGANIC

ACIDS
Id .t
P.

x;i

he.

0
Aqua

6or1c Acld
10

Carbonic

Aad

Chromac

Acld

Chromium,

R-130

R-130

R-110

R-l 10

R-130

R-130

Trloxade

R-130

Hydrobromlc

R-l 10

R-130

Acjd

Hydrochlonc

Acid @

30

R-RT

R-RT

Hydrochlortc

Acad@

20

R-100

R-130

Hvdwluonc

Acad

20

Acid

R-120

R-RT

R-110

40

Nttrwz Ac,d

R-100

30
Acld

PhosPhOrlC

R-100

75

R-l 10

R-110

Sulfuric

Acld

10

R-150

R-100

Sulturlc

Acld

40

R-RT

R-RT

R-RT

R-RT

Sulfurous
Mw.ed

Acid

20% HN03

INORGANIC

ALKALIES

Chemical

Reagent

:onc.

R-130

R-150

R-RT

R-130

R-150

R-AT

Copper

Sulfate

R-130

R-150

R-RT

R.130

R-150

R-RT

R-130

R-150

R-RT

Fcrr~c Chloride

R-110

R-130

R-RT

Fernc

R.l10

R-130

R-RT

Chloride
Phosphate

NItrate

Ferrous

Chlorade

R.l10

R.130

R.RT

Ferrous

Sulfate

R.l10

R-130

R-RT

R-l 10

R-110

R-RT

R-RT

R-RT

R-RT

Hydrogen

PeroxIde@

Hydrogen

Peroxnde@

Hydrogen

Sultade

-I-

3
10

R-l 10

R-130

R-RT

Magnestum

Carbonate

R.120

R-140

R-RT

Magnesum

Chlorade

R-120

R-140

R-RT

Magneswm

Nitrate

R-120

R.140

R-RT

Magnerwm

Sulfate

R-120

R.140

R-RT

Chloride

R-110

R.130

R-RT

NItrate

R-110

R-130

R-RT

R-130

R.150

R-RT
R-RT

Phosphorus

(Yellow1

R-100

R-110

Phosphorus

PentoxIde

R.lOO

R-110

R.RT

Potasr~um

B+carbonate

R.130

R.150

R-AT

R-130

R-150

R-RI

Chloride

R-130

R-150

R-RT

Potarswm

Chromate

R.130

R-150

R.RT

Potasswn

Cyamde

R-110

R-130

R-RT

R-RT

Potaswm

Nitrate

R-130

R-150

R-RT

R-100

Potaswm

Perchlorate

R.l10

R-130

R-RT

Potasrlum

Permanganate

R-130

R-150

R-RT

Potassium

Sulfate

:DMPOl JNI >s


&tori al r ecommendad
tenw.
nwx I. E,,nrtmt
BORN

R-RT

Carbonate

2699

4LT.S

2699

R-150

Potasswm

at

INORGANI(

651

R-130

Potassium

BORN

Nitrate

Mercurv

R.140

7%HF

at

Chloride

Mercurous

Sta~nlesr Steel plcklmg

(Contd.1

Material
recommended
max. Costat twnp.

Copper

Mercuric

Aclds for

DUNDS

Copper

Dlsodwm

R-140
R.120

:onc.

Alum

Cuprous

R.140

30

- co
&

0
Chrome

R-RT

Fluor~l~c~c Acid

Nnrlc

Reagent

26990

Regaa

Brom~c Acid

Chemical

SAL

Temp.

at

2699@

R-130

R-150

R-RT

Salver Nitrate

R.130

R.130

R-RT

Sodun

Bicarbonate

R-130

R-150

R-RT

Sodum

Bwltlte

R-120

R-140

R-RT

Sodwm

Borate

R-130

R.150

R-AT

Sodium

Carbonate

R-130

R-150

R-AT

Sodium

Chlorate

R-130

R-150

R-RT

Alunvnum

Chloride

R.130

R-150

R-RT

Aluminum

Fluoride

R.120

R-140

R.RT

Sodtum

Chlorado

R-130

R.150

R-RT

Alummum

Sulfate

R-130

R-150

R-RT

Sodium

Dachromate

R-130

R-150

R-RT

Ammomum

Carbonate

R-130

R.150

R.RT

Sodum

Ferrocyanlda

R-130

R-150

R-RT

Ammomum

Chloride

R-130

R-150

R-RT

Sodium

Fluoride

R-130

R.150

R.RT

Ammonium

Fluorldc

R-130

R-130

R-RT

Sodium

Hypochlorite

R.130

R-150

R-RT

Ammonwm

Nnratt

R-130

R-150

R-RT

Sodium

Nwate

R-130

R-150

R-RF

Ammonwm

Sulfide

R-130

R-150

R-RT

Sodium

Sulfete

R.130

R-150

R-RT

Chlonde

R-130

R-150

R-RT

Sodium

Sulfite

4.130

R-150

9.RT

q-130

R-150

7.RT

Antwnony

50

20

6srlum

csrhvlate

R-130

R-150

R-RT

Trisodium

Barurn

Sulfate

R-130

R-150

R-RT

Zinc Chlonde

q-130

R-150

=I-RT

Zinc Sulfate

q-130

R-150

9.RT

Bismuth

Carbonate

R-130

R-150

R-RT

Calcium

Btsulfatc

R-1JO

R-15P

R-RT

Calcium

Carbonate

R-130

R-150

R.RT

Calcwn

Chloride

R-130

R-150

R-RT

Calcrum

Hyoochlorlte

R-130

R-150

R-RT

Calcaum

NItrate

R-130

R-150

R-RT

Calcwm

Sulfate

R-130

R-150

R-RT

Phosphate

(continued)

@I

Synthetic

TABLE 1.45: PoLYvlNYL


PLATING

CHLORHDE LINERS-FABRIC0

ORGANIC

Material

recqmmded

3/32

& l/8

PVCType

651 are the materials

plating and rinse tanks. The combinatton


sol~t~qn

strength

Electroless

and mechamcal

Solutions

8 mil PVC Type

29L9

(dIsposableI

ORGANIC

Chemical

COMPOUNDS

Reagent

IContd.)

Reagent

Material recomm en ded at


m;r:
K. CO,,P, te mp.

rJnc.?i
@I

BORN

NR

Gallx

Acid

NR

NR

GhXqse

R.120

R-150

Glvcertne

R-l 20

Hvdroqulnone

NR

Alcohol@

00

Acid

100

NR

NR

NR

NR

NR

NR

NR

R-100

R-100

Mallc

R-100

R-100

NR

rvR

Acid

Methyl

Alcohol

Methyl

Ethvl

00

@
Ketone

NR

NR

Naphthalene

NR

NR

Nltrobenrene

NR

NR

led at
RP.

Olefc Acid

R-RT

R-RT

Oxalic

Acid

R.lOO

R-110

BOEE

Phenol

Acid

NR

NR

NR

NR

Polvv~nvl

Acetate

R-RT

Acetic

Acid

80

NR

NR

Acetic

Acid

10

R-130

R.130

Acetlc

AnhydrIde

NR

NR

Acetone

NR

NR

Tetrahvdrofuran

NR

NR

Alkvl

Alcohol

NR

NR

Trlethanolamlne

NR

NR

Alkvl

Chloride

NR

NR

Amvl

Alcohol

NR

NR

Amvl

Acetate

NR

NR

Amvl

Chloride

NR

NR

Allle

NR

NR

Benzene

NR

NR

R-100

R-110

Eutvl

Alcohol

NR

NR

Butvl

Phenol

NR

NR

8enro1c

Acid

Butvr~c

Acid

NR

NR

Carbon

Dwlfrde

NR

NR

Carbon

Tetrachlor!de

Chloracetlc

Acid

Chlorobenzene
Chloroform
Chlorosulfonw
Cltrlc

Acid

Acid

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

R-110

R-130

Cvclohexanol

NR

NR

Cvclohexanone

NR

NR

DeXtrl

R-130

R.150

Dlbutvlphthalate

NR

NR

Dlethvl

NR

NR

NR

NR

NR

NR

NR

NR
NR

Ketone

Dimethvlsmine
Ethyl

Acetate

Ethyl

Alcohol@

Ethyl

Bromide

NR

Ethyl

Chloride

NR

NR

Ethyl

Ether

NR

NR

R-RT

R-UT

NR

NR

Formaldehvde
Formtc

Acid

100

40

R.130

Sodwm

Acetare

R-100

R-110

Stearlc

Acid

R-100

R.l10

Tann~c Acid

R-100

R.130

Urea

R-100

Crude 011. fuel 011s and other allphatx


h
use wth PVC Type 3134. an 011 res~sta~

jrocarbonr

MIS<

Chemrcal

Reagent

LANf

Dtrtllled

Water

Fert~llrer
Grape

Solutions

IORN

ed
,P.

R.150

I-RT

R-RT

2699 @

R.RT
R-150

Sugar

R-110
R.150

No. 31

Photographic

R-100
Solut~or

011

Sea Water

I-RT

R-RT

IR

NR

l-130

R-150

sugar Salutlo

R-150
R-140

VlBgH
Water

are s#t ab le for

651

l-150

Mustard

Peanut

R-130

Matenal
r
max. c,

Juicer

Dakjre

IS COMPOUNI

0C. 9
0

Fruit

BOEE

R-150
r

Lead Acetate

Phev)hvdrazle
Acetaldehvde

661

NR

Lactic

this.

WNC

Furfural

lswropvl

of choice for

of temperature.

abuse drctates

COh

at
Chemiul

Note:

153

(continued

SOLUTIONS

Resins and Polymers

R-150
(Potable)

R-150

Wine (non-fortifIedI

A-RT

Yeast

R-150

Wet strength
Kvmene

557

Kvmene

709

Perez Rcs~ns

resins:
R-95
IR

R.70

l-95

R-95

NR

The above ratjngs are based on the consideration of chemical resistance only. Potable water will not attack flexible vinyls, but
to store it safely from the standpoint of toxicity, a specially formulated vinyl must be used. This would also apply to any
material that is intended
for human consumption.
In this latter category, the possibility of the migration of very small
amounts of plasticizer having an effect on the taste of the stored liquid should be considered.
@Hydrochloric
Acid must not be contaminated
with organic chlorides (500 ppm max. concentration)
@Applies only to inhibited hydrogen peroxide. Unrnhibited
10% H202 will not deteriorate
lining, but lining will contaminate
Solution.
02699
material is specially formulated
for pit 81 pond lining applicationsand
is generally serviceable after installation
between
-20 deg. and +150 deg. F. It has a bacteriostat which resists attack by soil microorganisms. Some of the recommended
uses
for particular compounds are shown above, however specific applrcations should be checked with the factory, particularly
those containing mixtures of the compounds mentioned above.
@Concentrations
of 10% or less are suitable with all vinyls listed at right for non-food use.
@All concentrations
left blank are 100% or Saturated solution.

154

Corrosion

TABLE

1.46:

Resistant

Materials

POLYVINYL

Handbook

CHLORIDE

PIPE AND FITTINGS-THERMOPLASTIC

Chemical Resistance of EXCELON

RECOMMENDED
(tested
@72F. 140F)
ACETIC ACID. 10%
ACETIC ACID. 20%
ACETYLENE
ADIPIC ACID
ALUM
ALUMINUM ALUM
ALUMINUM CHLORIDE
ALUMINUM FLUORIDE
ALUMINUM HYDROXIDE
ALUMINUM
OXYCHLORIDF
ALUMINUM NITRATE
ALUMINUM SULFATE
AMMONIA (GAS-DRY)
AMMONIUM ACETATE
AMMONIUM ALUM
AMMONIUM BIFLUORIDE
AMMONIUM
CARBONATE
AMMONIUM CHLORIDE
AMMONIUM HYDROXIDE
AMMONIUM
HYDROXIDE. 10%
AMMONIUM
HYDROXIDE, 28%
AMMONIUM
METAPHOSPHATE
AMMONIUM NITRATE
AMMONIUM
PERSULFATE
AMMONIUM PHOSPHATE
AMMONIUM SULFATE
AMMONIUM SULFIDE
AMMONIUM
THIOCYANATE
AN~~H;AOUINONESULFONlC

._.. ._

ANTIMmd

TRICHLORIDE
AkSENlC ACID, 80%
BARIUM CARBONATE
BARIUM CHLORIDE
BARIUM HYDROXIDE
BARIUM SULFATE
i;,bM
SULFIDE

-_-.

BEET SUGAR LIQUORS


BENZOIC ACID
BISMUTH CARBONATE
BLACK LIOUOR
BLEACH112%CLI
BORAX
BORIC ACID
BREEDERS PELLETS
,d~;p,fc~~
CADMIUM CYANIDE
CALCIUM BISULFIDE
CALCIUM BISULFITE
CALCIUM CARBONATE
CALCIUM CHLORIDE
CALCIUM HYDROXIDE
CALCIUM
HYPOCHLORITE
CALCIUM NITRATE
CALCIUM SULPHATE
CARBON DIOXIDE
CARBON MONOXIDE
CARBONIC ACID
CASTOR OIL
CAUSTIC POTASH
CAUSTIC SODA
CHLORAL HYDRATE
CHLORIC ACID. 20%
CHLORIDE (WATER)
CHLORINE WATER
CHROME ALUM
CITRIC ACID
COPPER CARBONATE
COPPER CHLORIDE
COPPERCYANIDE
COPPER FLUORIDE
Unless specified,

COPPER NITRATE
CORN SYRUP
c&PER
SULFATE
COTTONSEED
OIL
CUPRIC FLUORIDE
CUPRIC SULFATE
CUPROUS CHLORIDE
DETERGENTS
DEXTRIN
DEXTROSE
DIAZO SALTS
DIGLYCOLIC ACID
DISODIUM PHOSPHATE
DISTILLED WATER
ETHYLENE GLYCOL
FATTY ACIDS
FERRICCHLORIDE
FERRIC HYDROXIDE
FERRIC NITRATE
FERRIC SULFATE
FERROUS CHLORIDE
FERROUS SULFATE
FISH SOLUBLES
FLUOBORIC ACID
FLUORINE
GAS (WET)
FLUOROSILICIC
ACID,
25%
FRUCTOSE
FRUIT JUICES 8 PULP
FREON 11
FREON 12
GALLIC ACID
GASOLINE. JET FUEL
IP.l

k.i

GLUCOSE
GLYCERINE
GLYCOL
GLYCOLIC ACID
GRAPESUGAR
HYDROBROMIC
ACID.
H:gOCHLORIC
ACID.
10.
30.
35%
HYDROCYANIC
ACID
HYDROGEN
HYDROGEN PEROXIDE,
30%
50%
H::;OGEN
SULFIDE
HYDROQUINONE
HYDROXYMMINE
SULFATE
HYPOCHLORENE
ACID
HYPOCHLOROUS
ACID
KEROSENE
KRAFT LIOUORS
LACTIC ACID. 25%
LAURIC ACID
LEAD ACETATE
LEAD CHLORIDE
LEAD SULFATE
LINOLEIC ACID
LINSEED OIL
LITHIUM BROMIDE
LU[c;;A;;NG
OIL
ASTM C2
MACHINE OIL
MAGNESIUM
CARBONATE
MAGNESIUM CHLORIDE
MAGNESIUM
HYDROXIDE
MAGNESIUM NITRATE
MAGNESIUM SULFATE
MALEIC ACID
MALIC ACID
MANUFACTUREDGAS
MERCURIC CHLORIDE
MERCURIC CYANIDE
MERCUROUS NITRATE
MERCURY

deta 6 basedon

7OY mm

h?mperature

METHYL ALCOHOL
METHYL SULFURIC
MILK
MOLASSES
MURIATIC ACID
NATURAL GAS
NICKELCHLORIDE
NICKEL NITRATE
NICKEL SULPHATE
NICOTINE
NICOTINE ACID
NITROUSOXIDE
OILS 8 FATS
OIL, SOUR CRUDE
OLEIC ACID
CI$$lC$CID

ACID

OZONE
PALMITRIC ACID, 10%
PERCHLORIC ACID. 10%
PETROLEUM LIOUIFIER
PHOSGENE. GAS
PHOSPHORIC
ACID. 10%
PHOSPHORIC ACID. 25%
PHOSPHORIC
ACID. 75%
PHOSPHORIC
ACID, 85%
PHOTO SOLUTIONS DK
#3
DEKTAL DEVELOPER
KODAK FIXER
KODAK SHORT STOP
POTASSIUM ALUM
POTASSIUM
BICARBONATE
POTASSIUM
BICHROMATE
POTASSIUM BORATE
POTASSIUM BROMATE
POTASSIUM BROMIDE
POTASSIUM
CARBONATE
POTASSIUM CHROMATE
POTASSIUM CHLORATE
POTASSIUM CHLORIDE
POTASSIUM CYANIDE
POTASSIUM
DICHROMATE
POTASSIUM
FERRICYANIDE
POTASSIUM
FERROCYANIDE
POTASSIUM
FLUORIDE
POTASSIUM HYDROXIDE
POTASSIUM NITRATE
POTASSIUM
PERBORATE
POTASSIUM
PERCHLORATE
POTASSIUM
PERMANGANATE.
1046
POTASSIUM SULFATE
PROPANE
PROPANE GAS
PLATING SOLUTIONS
BRASS
CADMIUM
:zlER
INDIUM
LEAD
NICKEL
RHODIUM
SILVER
TIN
ZINC
RAYON COAGULATING
BATH
SEA WATER
SEWERAGE
SILICIC ACID
SILVER ZYANIDE
SILVER NITRATE
SILVER PLATING
SOLUTION
:A:;:
SULFATE

PROCESSES

R-4000 Pipe and Fittings

SODIUM ACETATE
SODIUM ALUM
SODIUM BENZOATE
SODIUM BICARBONATE
SODIUM BISULFATE
SODIUM BISULFITE
SODIUM BROMIDE
SODIUM CARBONATE
SODIUM CHLORATE
SODIUM CHLORIDE
SODIUM CYANIDE
SODIUM DICHROMATE
SODIUM FERRICYANIDE
SODIUM
FERROCYANIDE
SODIUM FLOURIDE
SODIUM HYDROXIDE.
10%
30%
50%
SODIUM
HYPOCHLORITE
SODIUM NITRATE
SODIUM SUl~rlTE
SODIUM SilLI IDE
SODIUM SULFITE
SOUR CRUDE OIL (WEST
TEXAS)
STANNICCHLORIDE
STANNOUS CHLORIDE
STARCH
STEARIC ACID
SULFUR
SULFUR DIOXIDE. (DRY)
SULFUR TRIOXIDE
SULFURIC ACID 3.
10%

20%
33.
50%
SL?&ROUS
ACID
TAN OIL
TANNIC ACID
TARTARIC ACID
TANNING LIOUORS
TRISODIUM PHOSPHATE
UREA
URINE
VINEGAR
WATER. ACID MINE
WATER. DEIONIZED
WATER,
DEMINERALIZED
WATER, DISTILLED
WATER, FRESH
WATER, SALT
WHISKEY
WHITE LIOUOR
WINES
ZINC CHLORIDE
ZINC SULFATE
ZINC NITRATE

RECOMMENDED
(@72F)
ANTHRAOUINONE
ARYLSUFONlC
ACID
BUTYL ALCOHOL
BUTYL PHENOL
CELLOSOLVE
CHLOROACETIC
ACID
CRESYLICACID,
50%
CRUDE OIL
ETHYL ALCOHOL
FORMALDEHYDE
FORMIC ACID
GASOLINE
HEPTANE
HEXANOL. TERTIARY
HYDROFLUORIC
ACID.
46%
LINOLEIC OIL

LUBRICATING
OIL,
ASTM X3
METHYL SULFATE
hlAPTU&
NITRIC ACID. 10%
NITRIC ACID. 30%
NITRIC ACID, 60%
PHENYLDHYDRAZINE
HYDROCHLORIDE
PHOSPHORUS
(YELLOW)
PHOSPHORUS
PENTRIOXIDE
POTASSIUM
PERMANGANATE.
25%
@ 125F
PROPARGYL ALCOHOL
PROPYL ALCOHOL
TETRAETHYLLEAD
TRIETHANOLAMINE
TRIMETHYL PROPANE
.I

.I.

ETHYLENE DICHLORIDE
ETHYLENE OXIDE
FLUORINE. GAS
FURFURAL
HEXANE
HYDROFLUORIC
ACID.
_.
0

IOZE

::aTuooNAEss
METHYL CHLORIDE
METHYLENE CHLORIDE
METHYL ETHYL KETONE
METHYL ISO-BUlYL
KETONE
NAPHTHALENE
NITRIC ACID,
ANHYDROUS
NITRIC ACID. 68%
NITROBENZENE
OLEUM
PALMITRIC ACID, 7090
PERACETIC ACID. 40%
PERCHLORIC ACID, 15.
RECOMMENDEDPERCHLORICACID.
700.
PHENYLrlYDRAZINE
ACETALDEHYDE
PHOSGENE. LIOUID
ACETIC ACID. PURE
PHOSPHORUS
ACETIC ACID. 80%
TRICHLORIDE
ACETIC ACID. GLACIAL
PICRICACID
ACETIC ANHYDRIDE
PROPYLENE
ACETONE
DICHLORIDE
ALLYL ALCOHOL, 96%
STODDARDS SOLVENT
ALLYL CHLORIDE
SULFUR DIOXIDE. (WET)
AMMONIA (LIQUID)
SULFURIC ACID.
AMMONIUM FLUORIDE,
60%
25%
85%
AMYL ACETATE
940.
AMYL ALCOHOL
95%
AMYLCHLORIDE
TETRAHYDROFURANE
ANILINE
THIONYL CHLORIDE
ANILINE
TITANIUM
CHLOROHYDRATE
TETRACHLORIDE
ANILINE
TOLUOL OR TOLUENE
HYDROCHLORIDE
TRI BUTYL PHOSPHATE
AQUA REGIA
TRICWLOROETHYLENE
AROMATIC
TUHPENTINE
HYDROCARBONS
VINYL ACETATE
BENZALDEHYDE.
10%
XYLENE OR XYLOL
BENZALDEHYDE.ABOVE
._.

NOT

I%

BENZENE
BROMINE, LIOUID
BROMINE WATER
BUTADIENE
BUTANE
BUTANOL. PRIMARY
BUTANOL.SECONDARY
BUTYL ACETATE
BUTYNE DIOL
BUTYRIC ACID
CARBON BISULFIDE
CA.RI-mN
TETRACHLORIDE
CHLORINE (DRY)
CHLORINE. GAS
CHLORINE GAS (WET)
CHLOROBENZENE
CHLOROFORM
CHROMIC ACID, 10%
&l;g;c
ACID, 50%

_. __..

CROTONALDEHYDE
CYCLOHEXANOL
CYCLOHEXANONE
DIMETHYLAMINE
DIOCTYLPHTHALATE
ESTERS
ETHERS
ETHYL ACETATE
ETHYL ACRYLATE
ETHYL CHLORIDE
ETHYL ETHER
ETHYLENE BROMIDE
ETHYLENE
CHLOROHYDRIN

Synthetic Resins and Polymers

TABLE 1.47: POLYVINYL

CHLORIDE TANK LINERS-PEABODY

TECLINE
TL990
liners are suitable
for the storage of
which TECLINE
TL990
liner will safely store includes:

Acetic Acid (10%)


Ammonium Hydroxide (30%)
Ammonium Phosphate
Ammonium Sulfate
Antifreeze (Ethylene Glycol)
Animal Oil
Boric Acid
Bromic Acid
Calcium Chloride Solutions*
Calcium Hydroxide
Chlorine Solution (20%)
Chromic Acid (10%)
Clorox
Crude Oil
Diesel Fuel
Ethyl Alcohol
Fertilizer Solutions*

FORAFLON@

variety

of

chemicals.

However,
solutions.

TECTANK

Gasoline*
Glycerine
Hydraulic Fluid
Hydrochloric Acid (60%)
Hydrofluosilicic Acid (30%)
Hydrogen Peroxide (30%)
Isopropyl Alcohol
Jet Fuel (JP-4)
Kerosene
Magnesium Chloride
Magnesium Hydroxide
Methyl Alcohol
Mineral Spirits
Naptha
Nitric Acid
Phenol Formaldehyde
Phosphoric Acid (75%)

TABLE 1.48: POLYVINYLIDENE

a wide

155

A partial

guide

to chemicals

Potassium Chloride*
Potassium Sulphate
Salt Water*
Sea Water
Sodium Acetate Solution
Sodium Bisulfite Solution
Sodium Hydroxide (60%)
Sulphuric Acid (40%)
Tannic Acid (50%)
Turpentine
Urea*
Zinc Chloride*
May be stored in Peabody TecTanks
TherrnoThane 7000, factorycoated bolted
tanks.

FLUORIDE-RILSAN

in general resists mineral acids, bases, saline solutions, oxidizing agents, and halogens.
it is attacked by concentrated
hot sulphuric acid or nitric acid and very concentrated
alkaline

FORAFLON

resists alcohols,

It swells in certain
dimethylacetamide,

chlorinated

solvents,

aliphatic

and aromatic

hydrocarbons

and crude oil.

polar solvents like ketones and esters and dissolves in aprotic solvents like
dimethylformamide
and N methylpyrrolidone.
It is also attacked by hot amines.

As an indication, the following table shows the good resistance


in some particularly
aggressive reagents.

of FORAFLONQD immersed

under stress

Test pieces are cut according to ASTM D 1708 from an extruded plate 0.7 mm thick, and either unbent
or bent by the device recommended in standard ASTM D 1693: the.y are immersed in a reagent at the
temperature indicated.
The tensile

properties

are checked

periodically.

For the reagents indicated, the yield strength of both bent and unbent test pieces varied by at least 10%
after one year, as compared with that of a control left in the air at the same temperature.
Reagents
Concentrated hydrochloric acid, 36%
Sulphuric acid 80%
Nitric acid 32%
Chromatosulphuric
mixture (CrO3, 50%, H2SOq. 15%, H20, 35%)
Acetrc acrd 50%
Caustic soda 45%
Sodium carbonate 40%
Ethylene glycol, pure
Perchloroethylene
Crude 011

Temperature
130
::
90
130
::
90
130
90
90
130

156

Corrosion Resistant Materials Handbook

TABLE

1.49:

TETRAFLUOROETHYLENE

PARTIAL

LIST OF CHEMICALS

HOSE-EVERFLEX

AND MATERIALS

PRODUCTS

COMPATIBLE

WITH TEFLON

HOSE

Teflon@ TFE fluorocarbon resin is so broadly chemically resistant that factors such as temperature, pressure and their
fluctuations are usually the primary influence on the serviceability of this material in a specific application. Solvents and gases
known to require special consideration due to these factors are indicated by asterisk(*).
Also, selection of material for fittings is influenced by reagent, concentration, duration of exposure and other
considerations. For guidance only, our preliminary recommendations for coupling material are indicated by letter following
the reagent, thus: (B) brass; (Cl carbon steel; (S) stainless steel; (M) monel.

Teflon is attacked bv only two classes of chemiulr:


al Molten alkali metals rueh as sodium 11 potassun
bi Fluorahemicals rush as chlorine tnflwride ICIF,

._-

I andoxggnn

Synthetic Resins and Polymers

TABLE 1.50: TETRAFLUOROETHYLENE

Table I-Tvoical
Abietic acid
Acetic acid
Acetic anhydride
Acetone
Acetophenone
Acrylic anhydride
Ally1 acetate
Ally1 methacrylate
Aluminum chloride
Ammonia, liquid
Ammonium chloride
Aniline
Benzonitrile
Benzoyl chloride
Benzyl alcohol
Borax
Boric acid
Bromine
n-Butyl amine
Butyl acetate
Butyl methacrylate
Calcium chloride
Carbon disulfide

with TEFLON
2.

Some

conducted

RESINS-DUPONT

Chemicals with Which TEFLON Resins Are Comoatiblel

Cetane
Chlorine
Chloroform
Chlorosulfonic acid
Chromic acid
Cyclohexane
Cyclohexanone
Dibutyl phthalate
Dibutyl sebacate
Diethyl carbonate
Dimethyl ether
Dimethyl formamide
Di-isobutyl adipate
Dimethylformamide
Dimethyl hydrazine,
unsymmetrical
Dioxane
Ethyl acetate
Ethyl alcohol
Ethyl ether
Ethyl hexoate
Ethylene bromide
Ethylene glycol

1. Based on expenmenls

157

up lo the bolllng

Ferric chloride
Ferric phosphate
Fluoronaphthalene
Fluoronitrobenzene
Formaldehyde
Formic acid
Furane
Gasoline
Hexachloroethane
Hexane
Hydrazine
Hydrochloric acid
Hydrofluoric acid
Hydrogen peroxide
Lead
Magnesium chloride
Mercury
Methyl ethyl ketone
Methactylic acid
Methanol
Methyl methactylate
Naphthalene
Naphthols
Nitric acid
points

of the liquids

Itsted.

Nitrobenzene
2-Nitro-butanol
Nitromethane
Nitrogen tetroxide
P-Nitro-2-methyl
propanol
n-Octadecyl alcohol
Oils, animal and
vegetable
Ozone
Perchlorethylene
Pentachlorobenzamide
Perfluoroxylene
Phenol
Phosphoric acid
Phosphorus
pentachloride
Phthalic acid
Pinene
Piperidene
Polyacrylonitrile
Potassium acetate

Potassium hydroxide
Potassium
permanganate
Pyridine
Soap and detergents
Sodium hydroxide
Sodium hypochlorite
Sodium peroxide
Solvents, aliphatic
and aromatic2
Stannous chloride
Sulfur
Sulfuric acid
Tetrabromoethane
Tetrachloroethylene
Trichloroacetic acid
Trichlorethylene
Tricresyl phosphate
Triethanolamine
Vinyl methacrylate
Water
Xylene
Zinc chloride

Absence of a speclflc chemical does not mean that 11is lncompatlble

resns.

halogenated

solvents

may cause

moderate

swelling.

Note

Values

are averages

only and not for speckatlon

purposes.

Table II-Exposure of TEFLON Resins


to Acids and Bases.
Exposure
Exp,s;re

Weight
Increp&

Reagent

Temp.,
C (F)

Hydrochloricacid
10%

25 (77)

12 mo.

50
(122)
70 (158)
100 (212)
200 (392)

12 mo.
8 hr.
8 hr.

:
0
0

25 (77)
70 (158)

12 mo.
12 mo.

E.1

20%
Nitric acid

Sulfuric

10%

acid

Sodium
hydroxide

30%

25
70 (158)
(77)
100 (212)
200 (392)

12 mo.
8 hr.
8 hr.

:
0
0.1

10%

25 (77)
70 (158)
100 (212)

12 mo.
12 mo.
8 hr.

0
0.1
0

25 (77)
70 (158)

12 mo.
12 mo.

0
0.1

50%
Ammonium
hydroxide

10%

(continued)

158

Corrosion Resistant Materials Handbook

TABLE 1.50: TETRAFLUOROETHYLENE

RESINS-DU

PONT (continued)

Table Ill-Exposure
of TEFLON Resins
to Solvents.
Exposure
$rng;;

Exyzre

InCZF,

Solvent
Acetone

25 (77)
50 (122)
70 (158)

12 mo.
12 mo.
2 wk.

0.30
0.4
0

Benzene

78 (172)
loo (212)
200 (392)

96 hr.
8 hr.
8 hr.

0.5
0.6
1.0

Carbon
tetrachloride

25
50
70
loo
200

(77)
(122)
(158)
(212)
(392)

12 mo.
12 mo.
2 wk.
8 hr.
8 hr.

0.6
1.6

25
50
70
loo

(77)
(122)
(158)
(212)

0
0
0

200(392)

12 mo.
12 mo.
2 wk.
8 hr.
8 hr.

Ethyl acetate

25 (77)
50 (122)
70 (158)

12 mo.
12 mo.
2 wk.

0.5
0.70
0.7

Toluene

25 (77)
50 (122)
70 (158)

12 mo.
12 mo.
2 wk.

0.3
0.6
0.6

Ethyl
alcohol (95%)

Table IV-Absorption
of Representative
fluorocarbon
resins(l)

::95
3.7

Table II and Table Ill Notes:


Many of the laboratory evaluations were run at the
boiling point of the chemicals listed. This should not be
considered the upper use temperature for TEFLON
resins in such environments, which can be
considerably higher.
l These are essentially equilibrium test values:
additional exposure times would not increase the
values significantly.
l Weight changes less than 0.2% are not considered
to be experimentally significant.
l Values are test averages only and are not for
specification purpfxes.
l Tests at over the boiling point of the reagent were in
an enclosed chamber, hence at its vapor pressure.
l

0.1

0.3

Liquids In TEFLON@160 FEP and TEFLON@350 PFA

168 Hour Exposures to Solventsat Their Boiling Pointsm


Range of
Temperature
Weight Gains
C F
%
__
185 (365)
0.3-0.4
Aniline
201 (394)
0.6-0.8
Acetophenone
179 (354)
0.4-0.5
Benzaldehyde
204 (400)
0.3-0.4
Benzyl Alcohol
78 (172)
0.3-0.4
n-Butyl Amine
78 (172)
2.3-2.4
Carbon Tetrachloride
190 (372)
0.1-0.2
Dimethyl Sulfoxide
1.2(3)
47 (117)
Freon@113
99 (210)
0.7-0.8
Iso-Octane
210 (410)
0.7-0.9
Nitrobenzene
121 (250)
2.0-2.3
Perchloroethylene
68 (154)
1.7-2.7
Sulfuryl Chloride
110 (230)
0.7-0.8
Toluene
200()(392)
1.8-2.0
Tri-Butyl Phosphate

166 Hour Exposure to Acidic Reagent


Temperature
C F
Bromine (anhyd.)
Chlorine (anhyd.)
Chlorsulfonic Acid
Chromic Acid, 50%
Ferric Chloride, 25%
Hydrochloric Acid, 37%
Phosphoric Acid (Cone)
Zinc Chloride, 25%

22
120
150
120
100
120
100
100

(-5)
(248)
(302)
(248)
(212)
(248)
(212)
(212)

Range of
Weight Gains
%
0.5(3'
0.5-0.6
0.7-0.8
0.00-0.01
0.00-0.01
0.00-0.03
0.00-0.01
0.00-0.03

Table IV Notes:
(1) No significant differences between FEP and PFA
resins in these tests.
(2) These are essentially equilibrium values;
additional exposure times would not increase the
values significantly.
(3) PFA data only.
(4) Not boiling.
(5) Values are test averages only and are not for
specification purposes.

TABLE 1.51:

VINYL

ESTER RESINS-INTERPLASTIC

CORP.

Chemical Resistance Co-Rezyn3 Vinyl Ester Resins*


Maximum

Concentratlor
Chemical

% by Weigh

1
1

\IE

8100

\IE

8300

Recommended

Temperature

Concentration
VE 8440

Acataldehyde

All

NR

NR

Acetlc Acid

O-25

210

210

VE 8710

VE 8520

NR
210

25-50

180

180

210

50-75

150

150

180

150
150

Acetlc Anhydrlde

All

NR

NR

NR

ACetOm

100

NR

NR

NR

Acrylic

Acid

AcfyIonltrlle
Alcohd.
Alcohol,

Butyt

25

100

100

100

All

NR

NR

NR

All

Ethyl

10
100

Alcohol,

Alcohol,

teopropyl

Methyl

Atcohol,

Methyl

lrobutyl

Alcohol,

Secondary

Sutyl

100
156
SO

Maximum

OF

160
150
SO

% by Weigh

Chemical

100

10

156

150

150

100

100

100

120

t50

10

150

150

100

NR

NR

10

150

150

150

150

10

150

150

150

150

150
NR

Ally1 Chloride

All

NR

NR

NR

NR

Alum

All

210

210

220

210

Aluminum

Chloride

All

210

210

210

210

Aluminum

Fluorlde

All

80

80

80

80

VE 8300

VE 8440

VE 8710

VE 8520

Slcarbonate

O-50

150

150

150

150

Ammonium

Slsultlte

All

150

150

150

150

Ammonium

Carbonate

All

150

150

150

150

Ammonium

Chlorlda

All

210

210

210

210

Ammonium

Citrate

All

150

150

150

150

Ammonium

Fluoride

All

150

150

150

150

Ammonium

Hydroxlda

NR

150

Temperature

Ammonium

120
150

Recommended

VE 8100

180

180

180

150

IO

150

150

180

150

20

150

150

180

150

29

100

100

150

100

Ammonium

Nitrate

All

180

180

180

180

Ammonium

Persulfate

All

180

180

180

180

Ammonium

Phosphate

65

210

210

210

210

Ammonium

Sulfate

All

210

210

210

210

Amyl Acetate

100

NR

NR

NR

NR

Anlllne

All

NR

NR

NR

NR

All

150

150

180

150
210

Anlllne

Hydrochloride

Anlllne

Sulfate

Arsenlous

Acid

All

210

210

210

All

180

180

180

0
0-Benroyl

Benzolc

Acid

All

780

180

180

Acetate

All

Aluminum

Hydroxtde

All

180

180

200

150

Barium

210

210

210

210

Aluminum

Nltrate

All

160

160

180

150

Earlurn

Carbonate

All

210

210

210

210

Chloride

All

210

210

210

210

O-IQ

150

150

180

15r

All

210

210

220

210

O-20

140

140

140

140

Sarlum

Hydroxlda

180

100

Barium

Sulfate

All

210

210

210

210

NR

NR

Earlum

Sulfide

All

180

180

180

180

Atumlnum

Poteulum

Ammonia.

Aqueous

Ammonia,

Gas

100

100

Ammonia,

Ltquld

NR

NR

80

60

60

Ammonium

Acetate

Sulfate

Barlom

65

Seer

120

(continued)

OF

TABLE

1.51:

VINYL

ESTER

RESINS-INTERPLASTIC
CORP. (continued)
Maximum Recommended Temperature OF

Concentratio
% by Weigh

Chemical

senrene

100

in Kerosene

5% Benzene
Benzene

Sullonic

Acid

All

VE 0300
NR

VE8440

VE

8710

210

210

210

210

210

210
210
NR

All

210

210

Benzyl Alcohol

100

NR

NR

1.90

Benzyl Chloride

100

NR

3%
6%
1%
3%

325

180

Solution:

NR

NR

32.5

180

350

180

Copper CyanMe
Sodium Cyanide
Zinc CyanIda
Sod&
Carbonate

Sromlne,

Llquld

Bronze Plating
4%
5%
3%
4.5%

NR

NR
210

Bcnzolc Acid

Brass PIstIng

VE 8520

NR

210

Black Liquor Recovery,


(hrrnace gasses)

Solution:

NR

NR

NR

180

180

190

180

180

190

NR

Copper Cyanlde
Sodium Cyanide
Sodlunl carbonate
Rochelle Salta

Bulyl Acetate

100

NR

NR

NR

Sutyrlc

O-50

210

210

210

Acid

I
Concentratio

VE 8100

100

NR

Chemical
Csdmlum
Cysnlde
Plrtlng
3% Cadmium Oxide
10% Sodium Cyanide
1% Caustic Soda

Phthslate

Butyl Carbltol

100
100

Sutyl Cellosolve

100

Eutylene

100

Glycol

150

160

160

Chorlde

All

180

180

8440

VE 8710

9
180

180

200

180

180

180

180

All

Csiclum

Carbonate

All

180

180

180

180

Calcium

Chlorate

All

210

210

210

210

Calcium

Chloride

All

210

210

210

210

Calcium

Hydroxtde

All

180

180

210

180

Cslclum

Hypochlorlte

All

160

180

180

160

Calcium

Nltrate

All

210

210

210

210

Calcium

Sulfate

All

210

210

210

210

Calcium

Sulfite

All

180

180

180

180

Cane Sugar Llqwr

All

180

180

180

180

Capylic

Acid

100

Carbon

Dloxlde

Carbon

Dlsulflda

NR

NR

NR

NR

Carbon

Monoxide

210

210

240

210

100

100

150

150

150

150

Carbon

Tetrachlorlde

Carbon

Acid

100

180

180

210

180

210

210

240

210

Carbowsx

100

100

100

Castor

210

210

210

210

150

150

150

150

011
Methyl

Cellulose

100

Chlorinated
(caustic

Brine Liquors
chlorine cell)

10

100

Chlorinated

Wax

180

Chlorine

DIoxIdelAIr

Chlorine

Dloxlde,

180

180

Wet Gas

VE 8520

150

c
Cadmium

VE

Blsulflte

100
150

Sotn.:

IE 8300

Calcium

Carboxy
Sutyl Senzyl

% by Weigh

Maximum Recommended Temperature OF


IE 8100

190
All

180

180

180

15

200

200

200

Satd.

160

180

180

180

180

Chlorlne,

Dry Gas

100

210

210

210

210

Chlorine.

Wet Gas

100

210

210

210

210

Chlorine,

Llquld

NR

NR

NR

NR

(continued)

TABLE

1.51:

VINYL

ESTER

RESINS-INTERPLASTIC

CORP.

(continued)

Maximum Recommended Temperature F


Concentratio
% by Weigh

Chemical
Chlorine

Wsbr

Chioroecetk

Acid

Maximum

Concentratio

fE 8100
fE 8300

VE 8440

VE 8710

All

160

180

190

25

120

120

120

VE 8520

Chemical

% by Weigh

Copper Pickling Bath:


10% Ferrk Sulfate
10% Sulturlc Acid

Recommended

Temperature

IE 8100
IE 8300

VE 8440

VE 8710

200

200

200

210

210

210

210

210

210

210

210

VE 8520

50

100

100

100

Con.

NR

NR

NR

NR

Corn Oil

Chlorobenxene

100

NR

NR

100

NR

Corn Starch

Slurry

210

210

210

210

Chloroform

100

NR

NR

NR

NR

Corn Sugar

All

210

210

210

210

100

NR

NR

NR

NR

Chloraulfonk

Acid

copper

sunate
Chromic

Acid

Chromium
Cltrlc

SuMate

Acid

Coconut

20

150

150

Cottonseed
Cresyllc

140

Chrome PIstIng 60th:


19% Chromic Acid
Sodium Fluoroslllcats

Sulfate

Oil

Acid

100

210

210

210

210

210

210

210

210

Cyclohexene

100

120

120

120

Cyclohexenone

100

100

100

120

All

210

210

210

150
NR

NR

NR

140

All

150

150

190

All

210

210

210

210

210

210

210

210

Detergents,

Sultonated

210

210

210

210

Diallyl

210

210

210

210

Di-Ammonium

Copper

All

210

210

210

210

copper Plating Sokls.


Copper Cyenlde
10.5% CopPer
14% Sodium Cyenlde
6% Rochelh Bells

Copper Brlts Plellng


Csustlc-cyenlde

Copper Plating Boln.


45% Copper nuoroborate
19% copper Sulfate
8% Sulturk Acid
Copper Matte Dlpplng Beth:
30% Ferric Chloride
19% Hydrochloric

All

210

210

210

160

150

190

210

phthalate

All

150

150

190

65

210

210

210

210

Dlbromophenol

100

NR

NR

NR

NR

Dibutyl

100

100

100

150

160

160

160

190

Benzene

Dichloroethylene

160

100

NR

NR

120

NR

100

NR

NR

NR

NR

Dichloromonomethsne

100

NR

NR

NR

NR

Dichloropropane

100

NR

NR

NR

NR

Dlchloropropene

100

NR

NR

NR

NR

Diesel

100

160

160

200

160

Fuel

200
DIethanoI

160

Phosphate

Ether

Dlchloro

160

NR

100

All

Nitrate

210

NR

011, Sour

All

Copper

210

NR

011, Sweet

Chloride

Fluoride

210

NR

Crude

CopperCyanide

Copper

210
100

Crude

30

011

All

200

Amine

100

60

60

120

100

NR

NR

NR

60

60

100

NR

NR

NR

Dlethyl

Amlne

Diethyl

Benzene

100

Dlethyl

Carbonate

100

NR

NR

(continued)

OF

TABLE 1.51:

VINYL

ESTER RESINS-INTERPLASTIC
Maximum

CORP. (continued)

Recommended

Temperature

OF

Maxlmum

Concentration 1 \IE 8100


Chemical
Oiethytane Glycol

% by Weigh t
100

Concentratio

\{E 8300

VE 8440

VE 8710

150

150

200

120

120

150

Diethylhexyl Phosphoric Acid


(in Kerosene)

20

Diethyl Sulfate

100

NR

NR

Diisobutylene

100

100

100

150

Oiisobutyl Phthalata

100

100

100

150

Dllsopropanol Amlne

100

100

100

150

Dlmethyl FormamIde

100

NR

NR

NR

Olmethyl Morpbollne

100

NR

100

150

150

180

100

150

150

150

Dlpropylene Glycol

100

150

150

150

DMA 4 Weed Killer 2,4D

100

120

DMA 6 Weed Killer

100

120
150

150

% by Wefgt

VE 8300

VE 8440

VE 8710

VE 8520

100

EthyleneGlyeolMor&utyiEttw

All

Ethyl Sulfate

100

80

80

100

F
NR
NR

NR

Dioctyl Phthalate

100

120

Chemical

Temperature

NR

Dimethyl Phthelate

Dodecyl Alcohol

VE 8520

Recommended

WE 8100

180

Fatty Acids

All

210

210

210

Ferric Chloride

All

210

210

210

210

Ferric Nitrate

All

210

210

210

210

Ferric Sullate

All

210

210

210

210

210

Ferrous Chloride

All

210

210

210

210

Ferrous Nltrate

All

210

210

210

210

Ferrous Sulfate

All

210

210

210

210

8-8-8 Fertllirer

120

120

120

FertillzerUrea Ammonium Nitrate

120

120

120

E
5

150

150

150

150

Flue Gas

340

340

340

Epichlorohydrin

100

NR

NR

NR

NR

Fluoborlc Acid

All

180

180

210

180

Epoxidlzed Soybean 011

100

150

150

150

150

FluosillclcAcid

10

210

210

210

210

Esters, Fatty AcIda

100

180

180

180

20

180

180

180

180

Ethyl Acetate

100

NR

NR

NR

NR

Formaldehyde

All

150

150

15c

Ethyl Acrylate

100

NR

NR

NR

NR

Formic Acid

10

180

180

180

180

Ethyl Benzene

100

NR

NR

All

100

100

100

100

Ethyl Sromlde

100

NR

NR

NR

NR

Freon 11

100

100

100

Ethyl Chloride

100

NR

NR

NR

NR

Fuel Oil

180

180

180

NR

NR

NR

Furfural

Electrosol

Ethyl Ether

100

Ethylene Chlorohydrln

100

Ethylene Glycol

All

NR

NR

100
210

210

210

210

100
5

120

120

150

10

100

100

120

100

NR

NR

NR

NR

(continued)

OF

TABLE 1.51:

VINYL

ESTER RESINS-INTERPLASTIC
Maximum
Concentratio

Chemical

% by Weigh

CORP. (continued)

Recommended

Temperature

Maximum

OF

VE 8100
VE 8300

Concentration
VE 8440

VE 8710

VE 8520;

Chemical

200

100

200

O-20
20-37
30

210
190
190

210
190
190

210
180
190

210
180

Hydrocysnlc Acid

All

180

150

180

190

Hydtolluwlc Acid

10

150

150

150

150

20

100

100

100

100

10

180

190

190

190

190

190

Gasoline, Auto

190

180

190

Hydrochloric Acid
Hydrochloric Acid
saturated wlth Chlorine gse

Gssollne, Sour

150

190

190

190

180

190

190

210

Gluconk ACM

50

150

190

190

150

Glucoee

All

210

210

210

210

Gluteraldehydc

SO

120

120

120

HydrotluoslllclcAcid
Gluterk Acid

50

120

120

120

Glycertne

All

210

210

210

Glycol. Ethylene
Glycol, Propylene
Glycollc Acid

All
All

210
210

210
210

210
210

10

190

150

200

70

80

90

100

Hydrogen Sromlde, Wet Gas

100

160

190

Hydrogen Chlortde, Dry Gas

100

210

210

210

210

210

210

210

210

210
Hydrogen Chlortde, Wet Gas

100

Hydrogen Peroxlde

O-30

150

150

150

150

Hydrogen Sulflde, dry

All

210

210

210

210

Hydrogen Sulfide, Aqueour

All

210

210

210

210

190

190

190

190

210
210

Hydrogen Fluorlde, Vapor


Glyoxal

40

90

80

80

190

190

180

190

190

150

180

10

190

150

100

150

20

150

150

150

150

PtathIg Solutton:
45%FeCl
: 15%CeCl
20FeSO,:ll%(NH,),SO~

190

180

180

Iron end Steel Clesnlng Seth:


9% Hydrochlork
23% Sulturk

190

180

190

Hydroeultlte Bleach
Gold Plating Solution:
63% Potserlum Ferrocysnlde
2% Potarrlum Gold Cysnlde
.8% Sodium Cyantda

190
Hypochlorous Acid

H
troll

HOptllll~

150

150

150

150

liexane

i50

150

150

150

Hexylene Glycol

150

150

150

150

Hot Stack Gerres

340

340

340

Hydraulk Fluld

210

210

210

Hydrerlna

NR

NR

NR

VE 8520

180

210

190

VE 0710

100

210

150

VE 8440

180

210

180

1IE 8300

O-25

Gas.Natural

Gssollne, Ethyl

Temperature

25-50

Hydrobromlc Acid

Gsrollne, Avletlon

% by Weight

Recommended

IIE 8100

210

isopropyl Amlno

All

100

100

120

NR

lropropyl Palmltate

100

210

210

210

210
(continued)

TABLE

1.51:

VINYL

ESTER

RESINS-INTERPLASTIC
Maximum

Concentration
% by Weigh1

Chemical

CORP.

Recommended

(continued)

Temperature

fE 8300

VE 8440

VE 8710

VE 8520

Chemical
Mercuric

180

Jet Fuel

180

180

K
180

KeImene

180

180

180

L
Lactic Acid

All

Lasso (50% Chlorobenzone)

100

NR

NR

NR

NR

lsobutyl

Carbltol

100

NR

NR

NR

NR

Methyl

Isobutyl

Ketone

100

NR

NR

NR

NR

Styrene

100

NR

NR

NR

NR
210

210

Monochloro

Dlsulflde
Acetlc

210

210

210

210

Motor 011

All

210

210

210

210

Myrlstlc

180

180

IS0

210

210

210

210

210

210

210

210

210

210

210

210

All

All
All

210

210

210

210

210

210

100

200

200

200

100

NR

NR

NR

NR

100

NR

NR

NR

NR

Ollr

Molybdenum

Acid

210

210

210

210

100

210

210

210

210

Naphtha

100

180

180

180

120

Naphthelene

100

180

180

200

180

Nickel

Chloride

All

210

210

210

210

Nickel

Nltrate

All

210

210

210

210

Nickel Platlno
8% Lead .S% fluoborlc
Acid
.4% Sorlc Acid

180

180

180

180

Nickel Plating
11% Nickel Sulfate
2% Nickel Chloride
1% Sorlc Acid

180

180

180

180

Nickel PLetlng
44% Nickel Sulfate
4% Ammonium Chloride
4% Sorlc Acid
Nickel Sulfate

180

180

180

180

210

210

210

Acid

210

M
Magnesium

Slrulflte

All

180

IS0

180

180

Magnesium

Carbonate

All

180

180

180

180

Magnesium

Chloride

All

210

210

210

210

Magneelum

Hydroxide

All

210

210

210

210

Magnesium

Sultate

All

210

210

210

210

All

210

210

210

210

Acid

Ethyl Ketone

Methyl

All

Linseed 011

Sulfate

Methyl

210

Lead Pletlng Solution:


6% Lead
.8% fluorborlc Acid
.4% Boric Acid

Lithium Bromide

xI(

210

Lead NItrate

LevullnlcAcid

210

210

Lead Acetate

210

NR

210

Ail

210
210

Monoethynolamlne

Laurie Acid

210

NR

Mineral

120

210

210

NR

210

All

NR

120

210

VE 8520

210

NR
120

VE 8710

All

Ntt
120

VE 8440

100

210

210

IE 8300

Chloride

210

All

% by Weigh1

Chloride

210

100

Temperature

Methylene

210

Laura1Chtorlde

Chloride

Recommended

fE 8100

Marcurous

Methyl

titex

Malelc

Maximum
Concentration

Llthlum

OF

ilE 8100

All

210

(continued)

OF

TABLE 1.51:

VINYL

ESTER RESINS-INTERPLASTIC
Maximum

Temperature

% by Weigh1 I

\iE 8300

VE 8440

VE 8710

150

150

150

150

Phthallc

Pickling Acids,
Sulfurlc and tiydrochlorlc

Concentratior
VE 8520

20

120

120

140

120

52

NR

NR

120

NR

Nitric Acid Fumes

160
NR

160
NR

160
NR

% by Weighi
All

Acid

160

160

160

100

160

160

210

160

Oil, Sour Crude

100

210

210

210

210

Oil, Sweet Crude

100

210

210

210

210

Oleic Acid

All

210

210

210

210

NR

NR

NR

NR

Oleum (Fuming

Sulfuric)

Olive 011

100

210

210

210

210

Oxalic Acid

All

210

210

210

210

P
Perchlorathylene

Acid

Phorphorlc

Acid

Acid

210

210

210

210

210

210

210

210

210

210

210

210

210

210

Polyvinyl

Acetate

All

210

210

Polyvinyl

Alcohol

100

120

120

120

120

120

120

120

120

All

210

210

220

210

O-50

150

150

150

150

210

210

Latex

Potassium

Alum Sulfate

Potassium

Blcsrbonate

Potssslum

Bromide

All

210

210

Potassium

Carbonate

All

150

150

150

150

Potassium

Chlorlde

All

210

210

210

210

Potassium

Dlchromate

All

210

210

210

210

Potassium

Ferricyanlde

All

210

210

210

210

Potassium

Ferrocyanlde

All

210

210

210

210

Polarslum

Hydroxlda

All

150

150

150

150

Potassium

Nltrate

All

210

210

210

210

100

100

100

Potassium

Permanganate

All

210

210

210

210

10

150

150

150

150

Potasrlum

PersuIfa1e

All

210

210

210

210

30

100

100

100

100

Potassium

Sulfate

All

210

210

210

210

210

210

PropIonIc

20

200

200

200

200

60

160

160

160

160

210

NR

210

NR

NR

NR

Propylene

Acid

Gtycol

100

NR

NR

NR

NR

Pulp Paper Mill Effluent

All

210

210

210

210

Pyrldlne

210

210

220

210

PentoxIde

o-54

210

210

210

210

Phosphorous

Trlchlorlde

100

NR

NR

NR

NR

Rayon Spln Bath

Acid

VE 8520

10

Phosphorous

Phosphoric

VE 8710

100

100

Phenol Sulfonlc

VE 8440

100

Peroxide Bleach
2% Sodium Peroxlde g6%
.025% Epson? Salt& 5%
Sodium Sillcrfe, 42BE
1.4% Sulhirlc Acid, 86Be
Phenol

VE 8300

NR

160

Acid

Temperature

Picrlc Acid, Alcoholic

Polyvinyl Chloride Latex


with 35 parts DOP

Oaklte Rust Stripper

Perchlorlc

Chemical

Recommended

VE 8100

160

Oclanoic

Maximum

OF

vE 8100

Nitric Acid

Recommended

Concentration
Chemical

CORP. (continued)

Fumes

100

NR

NR

NR

NR

All

210

210

210

210

160

160

160

NR

NR

NR

150

150

150

100

NR

(continued)

QF

TABLE 1.51:

VINYL

ESTER RESINS-INTERPLASTIC
Maximum
Concentration

Chemical

% by Weigh

CORP. (continued)

Recommended

Temperature

Acid

All

Maximum

rlE 8300

Concentration
VE 8440

VE 8710

VE 8520

S
Selkylk

WE8100

160

160

160

Chemical

Recommended

Temperature

1IE 8100

% by Weigh

IIE 8300

VE 8440

VE 8710

VE 8520

Sodium

U-Phosphate

All

210

210

210

210

160

Sodium

Ferrkyanlde

All

210

210

210

210

Ferrocyanlde

All

210

210

210

210

Seback

Acid

All

210

210

210

210

Sodium

Selenlus

Acid

All

210

210

210

210

Sodium

Fluoride

All

180

180

180

180

210

Sodium

Fluoro Silicate

All

150

150

130

150

Sodium

Hexametaphosphetes

All

120

120

120

120

Sodium

Hydroxide

180

180

200

160
150

Silver Nltrete

All

Sllvar Plating Solution


4% Silver Cvsnlda
7% Potas&m
Cyanide
5% Sodlum Cyenlde
2% Potassium
Cerbonete

210

210

210

200

200

200

10

150

150

200

25

130

130

200

120

180

200

180

50
All

210

Sodium

Acetate

All

210

210

210

210

Sodium

Hypochlorlte

o-5

Sodium

Alumlnete

All

120

120

120

120

Sodium

liypochlorlte

5-15

Sodium

Alkyl Afyl Sulkmates

All

150

150

150

150

Sodium

Lwryl

All

S&urn

Benmate

100

160

180

210

180

Sodium

Mono-Phosphate

Sodium

Skarbonste

All

160

160

160

180

Sodium

Nltrate

Sodium

Bllluorlde

All

120

120

120

120

Sodium

Sodium

Elsulfata

All

210

210

210

210

Sodium

210

Sodium
Sodium

-eP*

210

210

Sodium

180

210

210

210

180

180

180

160

130

150

150

130

180

180

180

180

All

210

210

210

210

All

210

210

210

210

Nltrlte

All

210

210

210

210

Persulfate

20

130

130

130

130

Silkate

All

210

210

210

210

Sulfate

All

210

210

210

210

Hydrosulflde

Sullste

All

210

Sodium

Slsulflta

All

210

210

210

Sodium

Bromste

10

210

210

210

Sodium

Sromlde

All

210

210

210

Sodium

Sulfide

All

210

210

210

210

So&urn

Co&mete

o-25

160

160

180

Sodium

Sulllte

All

210

210

210

210

35

160

160

180

Sodium

Tetra Borate

All

200

200

200

200

210

210

180

180

160

180

180

180

Sodium

Chlorate

All

210

Sodium

Chloride

All

210

210

Sodium

Chlorite

All

150

150

Sodium

Chromate

50

210

210

Sodium

Cyenlde

All

210

210

Sodium

Dlchromete

All

210

210

210

210

210

Sodium

Thlocyenste

37

210

210

Sodium

Thlosulfste

All

180

180

210

150

Sodium

Trlpolypho8phste

All

210

210

210

210

210

210

Sodium

Xylene Sullonate

All

210

210

210

210

210

210

Sorbltol

Solutlonr,

All

150

150

150

130

210

Sour Crude 011

100

210

210

210

210

(continued)

OF

TABLE 1.51:

VINYL

ESTER RESINS-INTERPLASTIC
Maximum

soya

Chloride

Slsnnous
Slasrk

Chloride

Acid

Temperature

OF

Maximum

VE 8440

VE 8710

VE 8520

All

210

210

210

210

Thioglycolic

All

210

210

210

210

Thionyl

All

210

210

210

210

All

210

210

210

210

Tin Plating
16% Stannous Fluoroborate
7% Till
9% Fluorborlc Acid
2% Boric Acid

% by Weigl 1t

Oil

Stannk

Recommended

1VE 8100
bE 8300

Concentratia n
Chemical

CORP. (continued)

Chemical
Acid

Chloride

StyWe

100

NR

NR

succlommltrlle

Ail

100

100

Sugar,

Bee1 and Cane Liquor

All

160

160

160

160

Toluene

Sugar,

sucrose

All

210

210

210

210

O-26

210

210

210

210

Transformer
Oils:
Mineral 011 Types
Chloro-Phenyl
Types

All

210

210

210

210

Trichlor

All

210

210

210

210

210

210

210

All

210

210

210

210

O-50

210

210

210

160

SO-70

160

160

160

160

75

120

120

120

Over 75

NR

NR

NR

Sullamk
SultanIlk

Acid
Acid

S&sled Detergents
Sulfur Dloxlde, Dry or Wet
Sulfur Trloxlde/Alr
Sulturlc ACM

Sulfurous

Acid

SuperphosphorIc
76% Pz 0,

Acid

NR
100

All

100

100

100

105% H, PO,

210

210

210

Tolusne
Solfonlc

Acetlc

Acid

Acid

% by Weigl

WE 8300

Recommended

VE 8440

VE 8710

100

100

100

NR

NR

NR

200

200

200

100

NR

NR

100

NR

All

210

210

210

210

210
NR

210
NR

210
NR

210
NR

210

210

210

210

NR

NR

NR
100

50

100
100

60

60

Trlchlorophenol

100

NR

NR

NR

100

100

120

All

210

210

210

100

120

120

120

Sullonate

Trlethanolamlne

NR

100

Trlchloromonofluoro-Methane

Phosphate

NR

NR

210

100

NR

NR

NR

NR

All

210

210

210

210

Turpentine

100

100

100

150

Tween

All

150

150

150

O-50

150

150

210

210

210

210

Trlsodlum

Chlorobromlde
Phosphate

Surfactant

OF

VE 8520

10

100

Trkresyl

Temperature

100

Trlchloroethylene

Trimethylene
210

VE 8100

Trkhloroethane

Tridecylbenzane
NR

Concentratia

150

T
Tall Oil

160

150

150

Tsnnk Acid

All

100

100

100

Tartsrk Acid

All

210

210

210

Tetrschlorosthylene

100

60

60

100

Tetrasodlum EthylensDlemlns

All

120

120

120

U
210

Urea

V
Vegetable

Textone- 50% Aqusous


Sodium Chlorete

210

210

210

Vhwgar

011s

210

210

(continued)

TABLE

1.51:

VINYL

ESTER

RESINS-INTERPLASTIC

CORP.

(continued)
*Co-Rezyn

Maximum
ES100

% by Weight

EE300

VE 8440

NR

NR

Vinyl

Acetate

100

Toluena

100

Temperature

60

60

VE8710

VE8520

NR

NR

60

lor filament

physlcal

hand

winding

lay-up

levels,

and

custom

remforced

Co-Rezyna

fabricated

plastic

tanks,

210

210

210

210

and

Demineralized

210

210

210

210

This resin
properties

Dlstlllcd

210

210

210

210

Fresh

210

210

210

210

210

210

210

210

210

210

210

210

160

160

dary

Sea

Used

excess

Liquor

(Pulp

HI)

demonstrates
which makes

Catalyst

chemical

or crarlng

This

excellent
adheswe
for reliable
secon-

wmdlng

lay-up

SMC
match
Pullruslon
Tank linmgs
Coatmgs
has a v~scoslty

melal

lay-up

die

molding

of 500 cps and CO-

100

NR

NA

100

NR

properties

as VE 6300.
Cenlrlfuaal

resistance
reswance,

Used

of VE 6710.
as

an

Altalns

example.

chlorobenrene
Although
a tough

sacrlflce

this

stablll(y.
excephonal
good
IS un-

at amblent
rest there IS

property

versus

Vmyl
Other

Esters
uses

to

add

addItIonal

toughness.

Coatmgs
Tank lmmgs

for.

Primers

casting

Adheswes

Co-Rezyn@ MVR-Modified

Zinc Chlorate

All

210

210

210

210

Zinc

All

210

210

210

210

I60

160

160

Nitrate

21C Plating Solutlo:


9% Zinc Cyanide
4% Sodium
9% So&urn

MVR 6000 - Good


where

the optimum

MVR

6040

spread

conoslon

- Fire

of IeSs than

resistance

vinyl ester
retardant.

resin

and physical

properties

brominated

25 per ASTM

Vinyl Ester Resins

Modilied

E 64 Tunnel

properties.

Hydroxide

A ecOnomlc

are nof required.


Vinyl

Test.

choice

- No fire retardant.

Ester

Resm

with

a flame

used with 3% antmony

when

trioxlde.
DOeS not slfsl
the optimum
physical
proprrttrs
associsled
with the Vmyl Ester Resm. VE 6440

Cyanfde

and corrosion

resistance

MVR 6050 - Fire retardant.


brominated
Modlfled
Vinyl Ester with a flame spread
rate of less then 25. per ASTM E 64 Tunnel
Test, when used wlth 3% antimony

PMng

21C
solutto:
49% Zinc fluoborat*
6% Ammonium
Chloride
6% Ammonium
Ftuoroborate

!OO

200

trloxlde
An economic
propertles
are required

200

the ASTM
resfstance
21C Sulfate

choice
where superior
corrosion
resistance
and
over fire relardanl
lsophthallc
polyester
resins

MVR 6060 - Ffre retardant


require the use of SntlmOny

All

IO

210

210

210

E 64 Tunnel
and

physical

Test

VE

m~nlmlze
crackmg
or crazmg
due to thermal
or mechanlcal
shock
and physlcal
abuse.
Relalns
very good
chemical
reslstance.
Is
100% compatible
wth the other Co-Rezyn@

Xylane

causllc

the

VE 6520
An extremely
tough epoxy based vinyl ester
havmg 20% elongation
This IS a non-rubber
resin, developed
for SPI Lmer appltcallons
to

VE 6100
A lower cham length version of VE 6300 havmg lower
lnlrmsic
and ewdent
~1stc0s111e.5.
llsco?.lty
Contains 50% styrene wlh a nommal
of 100 cps. HSS eSSentlSlly
the Sam e cured

hydrolytic
by

6300

lams 45% styrene.

160

and

demonstrated

solvent

some

and spray

reslstance

density rest than VE 6300


dIstortion
and exceprlonal

resistance

IS

affected
by
temperatures

OperStlOnS.

Filament
Hand

VE 8300
Whfte

VE 6710
A higher cross ilnk
giving hlgher heat

be fabricated

cracking

and corrosion

materials.

as

values

warping.

bonding
I:

wlthout

properlles

I a Vinyl Ester resm Lower halogen


content
and cost than VE 6400 and same competitive

pipe,

Outstanding
propertles

VE 6300 can

mlo thick sections

All

Resins

VE 6440
The fire reslstanl
brommated
counterpart
01
Ve 6300.
When
used
with
3% antlmonv
InoxIde.
has a flame spread rate of less than
25 per ASTM E 64 Tunnel
Test. Excellent

and
process
equipment.
toughness
and
fatigue

satt

Ester

The most versatile of all Ihe vinyl esters with


excellent
corrowon
resistance
from acids lo
alkalies
and oxldlzmg
chemicals
The m0S.t
wdely
used rest of the family of vinyl esters

demonstrated
by high cycle pressure
on lhin wall filament
wound pipe.
By suitable
control
of promoter
-

water
Defonlzed

Vinyl

OF
VE 6300

Concentration
Chemical
Vinyl

Recommended

bromfnated
Modlfled
Vlnyl Ester
trloxlde
or other flame retardant
rstlng

propertles

of less than 25 Only a small


from

the unmodified

vlnyl

physical

not

resin which does


chemicals
lo achieve
sacrifice
ester

of chemical

VE 6400.

(continued)

TABLE 1.51:

VINYL

ESTER RESINS-INTERPLASTIC

CORP. (continued)
Chemical

Concentration
% bv Weight

Chemical
Acetic

Add

O-25

MVR 8000

Resistance Co-Rezynr

Maxlmum Temperature
MVR 8040 MVR 8050

MVR 8060

170
150

!70

170

200

50

150

150

180

100

NR

NR

NR

NR

MVR Reslns

Chemlcel
Glycol,

Ethylrne

Alcohol,

Alcohol,

Ethyl

Methyl

100

80

10

150

60
150

80
150

NR

NR

.NR

NR

10

150

150

150

150

Ammonls,

Aqueous

Ammonla,

Oar

Ammonia,

Llquld

All

170

170

170

210

o-20

140

140

80

140

100

100

100

100

NR

NR

NR

NR

200

200

200

150

150

150

180
150

180

210

150

150
120

180

10
20

150
100

150

150

150

100

100

100

All

200

200

200

200

Jot Fuel

180

180

180

180

KerrnOn*

180

180

180

180

Hydrolluorlc

Add

Suttlde

180

180

180

180

5
20

150
120

150

150

120

120
100

50

60

80

NR

120
NR

Naphtha
NR

Nltrlc
Ammonium

Carbonate

Ammonium

Hydroxide

Senzene
SrllN
Sromln.,
Calcium

All

150

120

Acid

150

O-20
29

150
100

150

80

100

80

150
100

011, sour

200

200

200

210

100

NR

NR

NR

NR

011, Sweet

200

200

200

210

200

200

170

210

All
Ltquld
Carbonate

150

All

200

200

200

210

Phorphorlc

NR

NR

NR

NR

Plckllnp A&b,
Sulfudc 6 Hydrochloric

170

170

170

180
Potsulum

Cslclum

SuItate

Chlorine

Qar, Wet or Dry

Acid

Hydroxide

200

170

210

150

150

150

120

120

120
100

200

200

210

100

180

180

180

210

Sodium

Carbonate

o-25

180

180

120

150

NR

NR

NR

NR

Sodium

Hydroxldo

O-10

140

140

NR

160

10-25

120

120

NR

140

50

180

180

NR

180

o-15

150

150

NR

150

Chlorine

Dloxlde

All

150

150

100

180

Chlortna

Water

Ail

180

180

180

180

Sodium

Chromic

Acid

20

150

150

NR

150

Sultur Dioxide,

All

120

120

80

120

Ethylene

Glycol

Atl

180

180

180

210

Fluailicic

Acid

10

200

200

80

200

180

180

180

Avletlon

180
180

180

180

180

Ethyl

180

180

180

180

Auto

200
10
25

200

Ltquld

Gasoline,

All

All

Chtorlna,

Cycloh*xane

210

150

Acid

Hydrogen
Alum

All

MVR 8060

All

Hydrochloric
80
150

100

MVR 8000

O-20
20-37

H9X4M
ACetOll*

Maximum Temperature
MVR 8040 MVR 8050

Concentration
% by Weight

Hypochlorlte

Dry or Wet
Sultur Trloxlds/Alr
Sulturlc

Acid

Toluene
Water,

Dlrtlllcd

or Sea

150

All

200

200

170

210

Alt

200

200

170

210

O-50
50-70

200

200
160

150

210

100

80

180

75

120

120

80

120

NR

NR

NR

NR

200

200

200

210

TABLE

1.52:

EPOXY AND POLYESTER

PIPE AND FITTINGS-AMERON

BONDSTRAND

TEMPERATURE

CHEMICAL

RESISTANCE CHART

LIMIT

CHEMICAL
SOLUTION

Acetic Anhydride
ACNOIX
Acetonitrile

II
!I

-I/ 120
11 120

I
1

49
49

-120
120
N
loo
3004

I
I
1

--49
49

I
I

NH
NR

I
I

NR

---

1 NR 1 NR 1 -NR
NR
1 -NR
38
NR
NR
I -14Q4)
200
93 / RP-34
93
100
38
/ UP-34
93
100
38
I RP-34

Acrylic Acid
Acrylonitrile

NR
100

Air
Alcohol, Amyl

3004
200

93

203

Alcohol, Butyl
Alcohol. Ethyl

200
180

93
82

200
180

82

__

__

__

Alcohol. lsobutyl

180

82

180

82

loo

38

RP-34

Alcohol, Methyl
Alcohol.
Isopropyl

180
150

82
66

180
160

82
66

100
--

_38

RP-34
--

Alcohol, Polyvinyl
_
^

150

66

150

66

loo

38

RP-34

.M

NR
38
14Q4

l
I
1

I
II

Amy1 Acetate

100

38

100

38

NR

NR

--

Amy1 Chloride

100

38

100

38

NR

NR

--

Aniline
Antimony Pentachloride

NR
--

NR
--

NR
--

NR
--

NR

NR

100

38

RP.34

220

104

220

104

150

66

RP-34

--

Carbon Disulflde
Carbon Monoxide
Carbon Tetrachkwde
Carbonic Acid
Castor Oil

NH

I/

Eutadiene

150

66

NM

150

NH

66

-2OiI

-93

-200

-93

150
180
220

66
82
104

150
180
220

66
82
104

I --

NR
180
200

1 --

--

1 --

NR
93

-RP-34

NR
82
93

-RP-34
RP-34

(continued)

J,

TABLE

1.52:

EPOXY AND POLYESTER

PIPE AND FITTINGS-AMERON

(continued)

CHEMICAL
SOLUTION

Formic Acid

0.10

NR

Dcalc~umPhosphate-_

(continued)

TABLE

1.52:

EPOXY AND POLYESTER

PIPE AND FITTINGS-AMERON

TEMPERATURE
CHEMICAL
SOLUTION

tlvowhlorour

COflCWl
tration

LIMIT
SERIES 5000

(continued)

TEMPERATURE

LIMIT
SERIES 5000

Acid

wine
Jet Fuel
KWOWW
Lactic Acid
Latex
Louric Acad
Lead Acetate
Lead NItrate
Levulinic Acid
Lime
Linseed Oil
Lithium Chloride
Lube 011
Magnesium Carbonate
Magnesium Chloride
Magnesium Hydroxide
Magnestum Nitrate
hlagneswm Sulfate
Maleic Acid
Mercuric Chloride
Mercurous Chloride
Mercury
Methacrylic Acid, Glacial
Methyl Chloride
Methyl Ethyl Ketone
Methyl Isobutyl Alcohol
Methyl lrobutyl Cdrbitol
Methyl Isobutyl Ketone
Methyl Methaaylate
Methyl Sulfonic Acid
Methylene Chloride
Mineral Oil
Naphtha
Naphthalene
Nickel Chloride
Nic!xel Nitrate
Nickel Sulfate
Nitric Acid
Nitnc Acid
Nitrobenzan
hlitrogen Solutions
31, Sour Crude

(continued)

TABLE

1.52:

EPOXY AND POLYESTER

PIPE AND FITTINGS-AMERON

TEMPERATURE
2000

CHEMICAL
SOLUTION

___ ._

---1--

LIMIT

TEMPERATURE

LIMIT
--II

SERIES 5060
,Pds,W,

SERIES 4000
IEDcd
OF

(continued)

OF

OC

Adhesivetm

OC

NR

NOTES:

Sugar
Solutions

I!
II

Sulfite Liquors

2204
150

(
I

NR

Sulfur Chloride

II

NR

1.

Concentration
Where no concentration
is shown, recommendations
apply to
any concentration
up to 100% or saturation.
Where a concentration
range is given, recommendations
apply
to any concentration within that range.
Where a single concentration
is given, only that specific concentration has been tested.

2.

Use RP-34 adhesive for all applications


food applications up to 200F (93C).

3.

Use adhesive shown for field installation


RP-GA adhesive for food applications.

4.

Use Bondstrand
filament-wound
fittings and flanges.
flanges may be used in Series 5000 systems.

104
66
NR

NR

1 150 1
NR

NR

66

NR

NR

200

NR

1 NR j

NR

93

NR

RP-34

--

--

,,

NR-Not

Recommended

except
except

use RP-GA for


use RP-105

or

Molded

TABLE 1.53:

PHENOL-FORMALDEHYDE

AND FURFURYL

ALCOHOL-FORMALDEHYDE

RESINS-

AMETEK,

HAVEG DIVISION

Mmmum

Haveg 41 NA is a lhermosetting
of phenol-formaldahyde
fillers.
salts

It is generally
and chlorinated

Haveg 61NA
of furfuryl
silicate
dilute

resin

plastic,
end inert

recommended
aromatic

alcohoLformaldehyde

acids,

for service

with

Chemical Service

silicate
mineral

Acetaldehyde.

acid,

90%

based

on a composition

recommended

reactions

for service

and chlorinated

hydro

carbons.

ACelOl-te
201

Acetonltrile.
Haveg 46 is a phenol-formaldehyde
Its primary
fluosilicic

consideration
acid,

resin

is for use with

and related

with

a graphite

hydrofluoric

fluorinebearing

filler

acid,

Acelyl chloride

compounds.
Acrylic acid. Bosh

Haveg 66 is furfuryl
filler.
Haveg

In addition

alcohol-formaldehyde

to its resistance

66 has the same

resin

with

lo HF and related

resistance

to alkalies

a graphite

Acrylonltrile

compounds,

as Haveg

61 NA.

Alurmnum chloride
Aluminum

KEY:

Ammonium

E = Excellent. Can be used generally, and is to all intents


affected at all by chemicals at the test temperature.
G = Good. Can be used quite generally.

Satisfactory

F = Fair. Can be used for some purposes.


sample or discolor solution.

and purposes

sulfate
hydroxide. 26%

not
n-Amy1 alcohol

in most se&ices.

May involve some tendency

AflillfW
to swell
Anilmt

hydrochloride

NR = Not recommended.
Aqua regm

SODIUM
For alkaline

service,

HYDROXIDE

Ally1 chloride

(NaOH) AND HAVEG

Haveg 61 NA is the recommended

4i NA
c, Mb

y,..^

NR
UEI

..I.

41 NP

E.120

61 NA

NR.120

.1 NA

E-212

61 NA

E
Trot
.__.

G.212

dl NC
Acel~c anhydrIde

with

aromatic

sO*F

Grade

_ .

resin and inert non.asbestos

It Is generally
alkaline

on a composition

hydrocarbons.

is a thermosetting.plastic

fillers.

based

non-asbestos

TWllperatUre
F

160F

51 NA

01 NA

NR

R,NA

41 NA

F.133
NR
F

61 NA

G
NR

61 NA

Tl?st

41 NA

61 NA

NR.212

11 NA

41 NA

NR

61 NA

41 NA

E-300

61 NA

E-300

41 NA

E-2.W

61 NA

41 NA

NR

61 NA

41 NA

NR-212

61 NA

G-278

41 NA

NR

61 NA

NR

01 NA

61 NA

Test

91 NA

NR

61 NA

NR

41 NA

TeSt

61 NA

G-100

grade.

Haveg 61 NA can be used with varying concentrations


of NaOH, even concentrations up to 60% at elevated temperatures;
however, it is affected . There is a
surface effect that can contribute to contamination
of the solution.
Haveg 61 NA should be considered only where NaOH is used to neutralize
conditions
or as a reactant in a particular
process.
Haveg

41

overnight.

NA, when exposed to 0.5% NaOH in water, will be seriously


1% NaOH will begin its attack immediately.

acidic

attacked

(continued)

TABLE 1.53:

PHENOL-FORMALDEHYDE

AND FURFURYL

ALCOHOL-FORMALDEHYDE

RESINS-AMETEK,

HAVEG DIVISION

(continued)

Maximum

Maximum
Temperature
F

Temperature
Chemical Serries

Chemical Service

Benzotrachlonde

Chlorosulfornc
*I

______
61 hC
41 luc

een2yl chloride
Bow

acid

Bromine, 3% maximum

_~

chloride,

n-Bulyric
Calcium

acid
chlorlde

Calcium hypcchlorile
Carbon disulfide
Carbon letrachlonde
Chloral

___

F
F.9a-Y

41 h'

E
E

41 NL

E-300

61 NC

E.3W

41N

E.140

I
1
I

F I

E
E

G.266

61 NA

G.266

41 N

E-300

61 NF
dl ML
.

E
NR
,..

61 NC

NR

41 NC
Al&J

Chloral hydrate
Chlordlne

BCX!. 2% (with sulfuric

Copper lullate
Cupw

chlorfde

Cyano,en

chlonde

Dibutyl

ether

Dabutyltin dichloride

F
E

E-212

61 NA

G.212

41 NL
kl NL

&

E
c

E-257

NR.203

E
c.

E.203

dl NL

E
R

61 NL

41 NA

E
Test

61 NA

Chromic

ac~dl

80F

1 NA

6 NA

1es1

4: NA

NR

61 NA

NR

41 NA

NR

61 NA

NR

41 NA

NR

61 NA

NR

l&F
hR

41NA

E-300

61 NA

E.3W.l

Al NA

E.300

61 NA

E-300

41 NA

61 NA

Test

41 NA

41 NA

1
E I

E-212

61 NA
4, NA

E.212

61 NA

E-212

41 NA
61 NA

E
E

E
F

4, NA

61 NA

E-212

61 NC

10%

Dibutyl phthalate

41 NA

E
F
G-257

41 NA
40% and MCB, 59%

E-212

41 N&

Chloral.

Chromic acid

Test
E

61 NL.

30%

NR-212

..r

acts

Em0
__..

F.-&n
-1

41 NL

ac,d

61 NP

I.

Chlorel. 32% and MCB, 64%

Chromic

I IWL

41NF
r. .I,
sec.butyl chlor#de

hl hL

41 NC
~Butyl

NR

Test
F

61 N

n_Bulyl alcohol

Grade

Dlethyl ether
Dlethylkelone
Dtethylene

~lycol

Dusobutyl ketone
Dimethyl

phfhalate

Eplchlorohydrln
Ethyl acetate
Ethyl alcohol

41 NA

G-212

61 NA

G-212

41 NA

TM
E

E-23C
I=.,,,

61 NA
dl +.I&
_.
.

_._

61 NA

G-212

41 NA

61 NA

41 NA

61 NA

NR

E.212
E.212
I

NR

41 NA

Tell

61 NA

41 NA
kl NA

F
F

NR
r:

(continued)

TABLE 1.53:

Chemiul

PHENOL-FORMALDEHYDE

Servia

GWJ9

80F

1 NA
Methyl isobulyl

ketone. 100%

chloride

Monochloroacelic
Uonoch1oroacetoe.

acld
10%

Hoochloroberet
Uonoethanolamme.
Monoethmoiamlne.

20%
50%

methyl arsenate

Naphthylene

G-212

6 NA

4: NA

T&

6 NA

NR

4, NA

Test

61 NA

Ntlrilotriacetic

aud

Nitrobenzene
Nitrophenol

Phenol. 9%
Phenol. 6%

41 NA

E-212

E.212

41 NA

TCSl

6, NA

G.l!U

41 NA

61 NA

Test

I
F-212

61 NA

E-223

41 NA

E
F

E
F

E.300
l=.!aY

NR

, G_
11
_ NA I NF)
.

61 NA

61 NA

NR

41 NA

E.233

____

W3ctyl

chloride

Oleic acid
Oxsl~c wad. 20%
PlWil
FetachloroethSe
Pentan&ione
Pwchloroethylene

PhOSpee

Phosphorous orychlorlde
Phosphorous

trlchloride

bisullate

HR.212

F-2t2

E-265

Potasswm

E.212

41 NA

E.212

61 NA

E-212

41 NA

E.265

61 NA

G-265

41 NA

G.xx)

61 NA

E.200

41 NA

E-212

61 NA

E.212

41 NA

E.212

61 NA

G.212

41 NA
61 NA

NR
r.

Al NA

61 NA

1
1

dlchromsle.

5%

PolPssslum permangana1e
Proplonic

l#d. lCQ*A

Ropiorw

aad, 30%

Pyrldlne
Resorcinol. 46%
Sodwm bisulfate
Sodaurn bwltile

8dF

4: kA

NR

61 NA

NR

41 NA

61 NA

NR

(continued)

Maximum
Temperature
F

160-F

NW212
F.212

41 NA

61 NA

NR

41 NA

G.212

61 NA

NW212

41 NA

NR

61 NA

7 NA

I
1
I

Test

41 NA

61 NA

E.212

.I

G.212

61 NA

G.212

41 NA

E.300

61 NA

E-300

41 NA

E.300

61 NA

NA

1
1

F
E

61 NA

I F
1 F

41 NA

NR

_.

NR

11 NA

F-212

61 NA

Grade

41 NA
61 NA

F-212

61 NA

_. .

50%

Potassium cyanide
G

HAVEG DIVISION

61 NA

Phosphoric awj.

Polasswn

41 NA
61 NA

Phenyl ether

11 NA
n.Octyl alcohol

FT,eol. 100%
Penol, 65%

61 NA

41 NA

Chemwzat Service

61 NA

Nitric acid. 2% maximum


(with sulturic acid not recommended)

RESINS-AMETEK,

Maximum
Temperature
F

l&F

6: NA

41 NA

Uwosodwm

ALCOHOL-FORMALDEHYDE

NR

P! NA
Methylene

AND FURFURYL

6, NA

EP12

E-300
I

1
I
I

E-212

41 NA

61 NA

41 NA

61 NA

41 NA

NR

61 NA

NR

41 NA

61 NA

41 NA

61 NA

E-300

41 NA

E.303

61 NA

E-300

E-212

Eaco

E-212
E-212

(continued)

TABLE 1.53:

Chemiul

PHENOL-FORMALDEHYDE

Service

Grade

AND FURFURYL

BOF

160-F

Maximum
Temperature
-F

ALCOHOL-F0

ALDEHYDE

RESINS-AMETEK,

HAVEG DIVISION

Grads
4

NA

(continued)

80F

1SOF

-rest

ND

Temperature
F

61 NA

PI NA

TfZ.1

Nfi

67 NA

E.212

41 kA

G.212

61 NA

E-212

Synthetic Resins and Polymers


TABLE

1.54:

POLYESTER

AND VINYL

H-RON

ESTER RESINS-ASHLAND

CHARACTERISTICS

RESIN SERIES

92

SUGGESTED APPLICATIONS

Maximun fwe retardancy. Class I flame spread cm he


achreved. Good corrosion resistance.

Frimmily for severe fume handling equipment to 25OF.

HETRON 197

Habganated polyester. Maxbtmn corrosbn and heat


resistance. Class I or II flame spread can be achiiad.

All eqwpment where maxrmum corrosron and heat resrstance are


required - intemrittent service to about 600F: contrnuously rn
350F range. Excelbnt for hot wet chlorine and other hrghly
oxidizing environments.

HETRON 72

Similar to HETRON 197 series.

General corrosbn resrstant equrpmant. linings, coatmgs. toppings,

HITRON 700

9isphanol~A Fumarate resins. Excellent corm&on resistance.


Non-fire retardant.

All corrosbn resrstant equipmmt except fume handhng systems


to about 250F. Ideal for caustrc and hvwchbnte.

HETRON 900
I
AROPOL 7240
Series (Includes
7241 and 7242)

AROPOL 7430
Series (Includes
7530 and 7532)

HETRON 99P

179

Vinyl ester restns. Nonfire retardant. Excellent corrosron


resistance.
Isophthahc resins. Nonfire retardant. Moderate corrosbn
resistance.

All equipment except fume handling systems to about 190 F.


AFtOf 7242 can be used for FDA applicatrons.

Resilient isophthahc resms. Nonfire retardant. Moderate


corrosbn resrstance.

All equpment except fume handling systems to about 150F.


Excaflent for filament winding applicatrons.

Fee retardantlisophthafic with grnrd mrrosbn resistance.


Class I f&ins spread can be achiied.

For ftane handling equipment to 250F.

The following

definitions

will aid readers using this Guide.

Service Temperature - Temperature data is not

Asterisks - Resins marked with an asterisk indicate


that it is preferable to use this resin over another resin
even though both are resistant at the temperatures
listed in the Guide.

necessarily the maximum service temperature. It is the


upper temperature at which a specific resin has been
satisfactorily tested or used.
AMB -

Refers to ambient temperature

LS - Indicates that limited service life can be


expected. This means that some chemical attack will
occur but not enough to render the equipment useless.

of 7!XOF.

Blank Space - Showing no service temperature


recommendation indicates that insufficient resistance
data was available. It does not mean that the resin is
unsuitable for that environment.

NR-

I\

Resin is not recommended.

SERVICE

TEMPERATURE.

OF FOR RESIN TYPES

CONCEN.
TRATION %

CHEMICAL
ENVIRONMENT
Acid: Salt

ACID: SALT ENVIRONMENT.

HETRON 92 SERIES
LAMINATES.

GOOD FOR 25oF


VAPORS FROM
THE ACID:
SALT SOLUTION.
HETRON

99P recommended

for fume service only.

THESE RESINS RECOMMENDED


AT AMB. (AMBIENT 7540F)
TEMPERATURE
OR TEMPERATURE
IN F SHOWN FOR
ESTIMATED 10.15 YEAR LIFE. HETRON 197 SERIES RESIN PRE.
FERRED AT 2UOF OVER HETRON 72 SERIES RESIN AT
2OOF. THESE RESINS MAY BE SUITABLE AT HIGHER
TEMPERATURES
BUT NO DATA IS AVAILABLE. HETRON 922
RESIN RECOMMENDED
FOR LIMITED SERVICE. AT 100-F
WITH ABOUT 5 YEAR SERVICE LIFE.

(continued)

180

TABLE

Corrosion

1.54:

Resistant

POLYESTER

Materials

Handbook

AND VINYL

ESTER RESINS-ASHLAND

(continued)

List of Trademarks and Product Names


Adogall*
...
Aemsol
.
Allpal ..........
Abdlrm ........
Am&em
.
Amerex . . . . . . . .
Amine Salt Solutbns.
73g73 M-A, m-0, M-C

Sherex Chemical Co.


American Cyanamid Co.
Chemical Div., GAF Corp.
Amchem Products Inc.
Amchem Products Inc.
Drew Chemical Corp.
W. R. Grace Co.,
Dewey 8 Almy Div.
American Mineral Spirits Co.
International Dioxide Inc.
Wyandotte Chemical Co.,
J. P. Ford Div.
Armak Co.
Armak Co.

AmscoBKOH Solvent
Anthlum Dbxtde

Apache
Amlaal

Arquad

Benteo

Wyandotte Chemical Co.,


J. P. Ford Div.
Velsicol Chemical Corp.
Bet2 Laboratories, Inc.
Drew Chemical Corp.
Oxy Metal Industries Corp.,
Parker Div.
Spartan Chemical Co., Inc.
Colgate-Palmolive Co.

Bmuoflu:Brominex
Betxsulllte3..
BlocidaCWT.102.
Bondarlte

Bowlcloanm
Build

C-56
Calgun

carbitd
Celbeolve
cell Putty
Cham-Rex c2m5.
C-2009, C-2075
Chbrothene
Clhex
clealler508.....
CWTlM
Cyaf
cygon

Hooker Chemicals &


Plastics Corp.
Calaon Coro.
Union Carbide Corp.
Union Carbide Corp.
Rowe Products Co.

.
.

Ashland Oil, Inc.


Dow Chemical Co.
Peabody Engineered Systems
Quaker Chemical Co.
Drew Chemical Corp.
American Cyanamid Co.
American Cyanamid Co.

Darux ___.._..___..___,..

Dynd

W. R. Grace Co.,
Dewey 8 Almy Div.
W. R. Grace Co.,
Dewey 8 Almy Div.
Arapahoe Chemicals
Huntington Laboratories
Diversey Chemical Co.
Dow Chemical Co.
Drew Chemical Corp.
Hooker Chemicals &
Plastics Corp.
Staley Chemical Co.
Union Carbide Corp.

Electrasol
Elvase
EP 52.A55
Eptam
Erbnal NW
EVA
Exalt
_.

Economics Laboratory,
Union Carbide Corp.
Ashland Oil, Inc.
Stauffer Chemical Co.
Ciba-Geigy Corporation
Union Carbide Corp.
Pennwalt Corp.

FClW, 2w, 206A


Fluomluhes

3M Co.
Hooker Chemicals 8
Plastics Corp.
Buffalo Color Corp.

Daxad

..__....__..__...

DFR.121
Dkrohe
Diversey

Dowclem
DmwSpenN
Durex
DW-575

Furbn

12.62

G.51
Glass Cleaner

..

Gbhrlte 15, X-200 .........


GokbnGb ..............
Halao Sg

................

Igepal ..................
lrgasd DA ...............
Isocure .................
Isoprep .................
JM-235, JM-271

...........

Chemical Div., GAF Corp.


Ciba-Geigy Corporation
Ashland Oil, Inc.
The Richardson Co.
Johns-Manville
Hercules Powder Co.

Lasso ..................
Lix 54N .................

Monsanto Co.
General Mills Chemicals,

Magnllbc ..............
Matar ..................
Mulsollne ..............

American Cyanamid Co.


Huntington Laboratories
Dye & Chemical Co.
of Canada, Ltd.

Neodol .................

Shell Chemical Co.

Oaklte .................
Olin ...................
i%lD..
.................
OPM-i,OPM-2 ...........

Oakite Products, Inc.


Olin Chemical
BASF Wyandotte Corp.
Olin Chemical

Parco...................

Oxy Metal Industries Corp.,


Parker Div.
Oxy Metal Industries Corp.,
Parker Div.
G. H. Packwood Mfg. Co.
Spartan Chemical Co., Inc.
Ashland Oil, Inc.
Spartan Chemical Co., Inc.
Borden Co.
Uniroyal, Inc.

Pax Hyspeed ........


PD34 ..............
PepSet..
..........
Plus 6 ..............
Polyco .............
Pdywet ............
Raylene .................

Sam-Fresh

Stackfas Mastic
Telona ..................
Tergitol .................
Textone .................
Thermolln ...............
35D..
..................
Tlnoflx OF ...............

Dow Chemical Co.


Union Carbide Corp.
Olin Chemical
Olin Chemical
BASF Wyandotte Corp.
Ciba-Geigy Corporation

u-3400,
U7ooo. ...........
Ultrawet ................

Staley Chemical Co.


Atlantic Richfield

........
........
........
........
........
........

Varlquat
Varlsoft
Vamx 155E
Varsol
. .
vtdden
VlvoZyne .
Zlmmite

..

..

Inc

Wyandotte Chemical Co.,


J. P. Ford Div.
The Richardson Co.
The Richardson Co.
Ashland Oil, Inc.
Envair, Inc.
Spartan Chemical Co., Inc.
Monsanto Co.
Sherex Chemical Co.
Tretolite Div., Petrolite Co.
H. B. Fuller Company

SD-20.........
Skydrol .......
Softener B .....
SP-101 ........

Rohm 8 Haas
Spartan Chemical Co., Inc.

Hooker Chemicals 8
Plastics Corp.

Kymene .................

Rkhamlde ...............
Rkhonate ...............
RJ.4 ....................

Inc.

Ashland Oil, Inc.


Spartan Chemical Co., Inc.

Sherex Chemical Co.


Sherex Chemical Co.
Sherex Chemical Co.
Exxon Company
Dow Chemical Co.
Gcoch Feed Mill Corp.
W. E. Zimmite. Inc.

(continued)

Synthetic Resins and Polymers


TABLE

1.54:

POLYESTER

AND VINYL

ESTER RESINS-ASHLAND

181

(continued)

HETRONandAROPOL ResinSelectionGuide ior CorrosionResistantRTPAPPliceti0n-s


SERVICE

CONCENTRATION %

CHEMICAL
ENVIRONMENT
Acotaldehyda ................
Acotaldehyde, 1% In air ........
Acetaldehyde Fumes ..........
Acetk Acid ..................
Acetk Acid ..................
Aoetlc Acid ..................
Acetk Acid ..................
Acetic Acid ............................
Aoetk Aotd. about 10% In Hydrocarbon,
Liquor end vapor .....................
Acetic ACM. Glackl .....................
Acetk Acid. Gkckl
.....................
Acetlc: Gkckl: 70% Nltrlc: 49% Hydrolluorlc
AcetIc ACM: HCI ........................
Acetlc: HCI: H,O ........................
Aoetlc: H,O, ............................
Acetic Acid: Sodium Dkhromato ...........
Acetlc Actd Vapor ...............
Acetic Acid, Vapor 6 Condensate . .
Acetic Anhydrtdo ...............
Acetic Anhydrlde .........................
Acetone .................................
Acetone .................................
Acetone .................................
Acetona: Cyclohoxanc Hexane: Water ........
Acetorw Water ...........................
Acetonltrtk ..............................
Acetophenona ............................
Acetyl Chlorldo ...........................
Awtyl Chkrlde ...........................
Acid Rinse, PhotographIc ....................
Acldlc Gaseous Atmosphem, Saturated,
Weak Phoaphorlc, Hydrolluork.
Sulfurous, Etc., at 3900 fpm ..............
Aclda (Sullurk, Phosphork, Acetic),
Soda Ash, Organk Salts, Dye Sulk,
2.5%Soll&,pH2-5..
....................
Acrykmlde
..............................
Acrylk Actd ..............................
Acrylk Acid ..............................
Acrylic Acid ..............................
Acrylic dlrperslon: Acryknltrlk ...............
Acrylic dkpersion: Vlnylldene Chloride ........
Acrylic Emulrlon ...........................
Acrylic, Glrclrl ............................
Acrylk Spray Liner, Water Reduolbk
at 12OF(PPG Indwtrks) ..................
Acrylic Stynne Emulsknst
DW-975, U-3400, U.7091 ...................
Acrylk Wet Ink Vamk h. Water Reduclbk
at 120F(PPG Industrka) ..................
Acrylonitrlk ...............................
Actlvatad Carbon Bedr, Water Treatment ......
Adlpk Acid, Adipyl Chloride and
Hydrochloric ACM ........................
Adlpyl Chlortde, Adlpk Aold and Hydrochkrk
Ad0g.n~381: xylem .......................
..............................
AdottAdo9en449
..............................
Aemsolt, Wettlng Agent ....................
Alr, Humid, Trace Sulfur Fumes ...............
Air: Methyl Sulfide: Methanol; Smell
Amounts H,O. H,S, Methyl
Mercrptrn, Acetone, TurPentlne ............
Alcohol, Ethoxylatad, pH 8.5, C,,.C,, ...........

100
(40 Ibsm
10
15

NETRON
92/99P
NRI490
90
150

125

25

125

50
75

AMBKJO

TEMPERATURE,

HETRON
920 sEmw9so

NR
-

NR
-

NR
-

NR
-

210
210

170/150
170/150

2101200
21omo

210
125

17ol150
1541125

21wW
150
16a150

21w22u
160

180220
NFUNR
NR
-

100
100 @ 120-F
3:5:1 @ 1WF

NR/-

10011ocu1w
LYLSJNR
NR

50:2U
50:16.5:315
95:1.5

AMB/66
AM0

25
100
1W @ 12o.F
10
100
100 @ 133F
10:10:1:79

NW1801NR
NR
NR

1090
100
1W

100
100 @ 13OF
-

NR/-

50
100 @ 1WF
25
10
96:2
9&2
loo

AMB
66
AMB
160
160
loo
LS/LS/NR
NR
NR

NR
_
-

NR
NR
NR
-

NR
NR
-

NR
NR
NR
NR
NR

AMBlNR
NR
NR
NR
-

90
2101220
2101220

lXU-

NWNR
NR
NR
NR
-

NR
-

150

AMB
-

NR
-

NR
NR

NR
NR
-

AI.40

NR
_

90

10 165/-

lo 16Y-

--/lSQ

NR

-/to
165/--1w-

Unknown

TYPES

HETRON
700170Oc

70:30
@ 212-F

RESIN

MOP01
724017430 SERYS

la,

OF FOR

HETRON
72/197119711

NR

NR

loo
100
AMB
AM0
-

100
-

90
--I-/NR

AM0
--I-/NR

loo

NRI-

2al

Unknown
Unknown

25:75

lMYlW/NR

NR

NR

120/-

AM0
loo
_

AMBllOO
AMBilW
_

NR

SAT

SATI-

NR
NR
-

SAT
NR
-

NR
NR
-

SATINR
_

12W120/AMBI-

120
120
AMB
200

120/120
1201120
-

120
120
-

120/12W-

652.56
100

165
120

120

SAT under SERVICE


TEMPERATURE
= S.stisl.%tory
With mlemnce to mcommendaNons under s
,gqyh;;;?l;gps.
W_UT%Y= First two msrerials sat at 1
msisrance unknown
100/100 = Both mareriels sefislactoty,
tirsl pn?lwr&,
efc.
125 = Pmhrmd mahrial, a/thou h others sm suifabfe at 125
.R.
100150 = Temperalum varied w!I m hmlls shown
tSee

list of trademarks

and product namt?s.

(continued)

182

Corrosion Resistant Materials Handbook

TABLE

1.54:

POLYESTER

AND VINYL

ESTER RESINS-ASHLAND

bxntinued)

SERVICE

CHEMICAL
ENVIRONMENT
Algaecide, phenate based ...............
Alipal C0433t
........................
Alkaline Film Stripper, Butyl Cellosolve:
Monoethanol-Amine @ 136F ............
Alkaline Soak Cleaner .................
Atkanolamide, Fatty Acid ...................
Alkanolamide Nonionic Surfactant ...........
Alkyl Benzene Sulfonic Acid ...............
Alkyl Dimethyl Benzyl Ammonium Chloride:
Phosphoric Acid: Inerts ..................
Alkyl Dimethyl Beruyl Ammonium Chloride:
Tributyl Tin Chloride/Ethylene Oxide/Amine:
Hydrochloric Acid: Inerts ................
Alkyl Ether Amine Oxide Surlactant ..........
Alkylate, Substituted Benzene Type, Relinery
Alkylate Sulfonates, Linear .................
Atkylrtion, Aromatk Hydrocarbon ...........
Ally1 Chlortde .............................
AlmondOtt ...............................
Alodine 461/45t, pti 2 ......................
Alpha Otefin Sulfonate .....................
Alum ...................................
Alum ...................................
Alum, Potassium ..........................
Aluminum Chloride ........................
Aluminum Chloride: Fluosllkk AtId .........
Aluminum Chloride Spent Catalyst Solution,
1DWppmBenzene
rB13tt.F ..............
Alumlnum Chlorohydmte ...................
Aluminum Chlorohydroxlde .................
Aluminum Citrate .........................
Aluminum Desmutter 6 Deoxidtzer ..........
Aluminum Etchant. Phosphate Free .........
Aluminum Fluorlde .......................
Aluminum Hardening Fixing Bath, ,
..........................
Photographic
Aluminum Hardening Raptd Fbtlng
Bath, Photographic ......................
Alumlnum Hydroxide .....................
Aluminum Hydroxide .....................
Aluminum Nltrate .........................
Aluminum Oxide Drying ....................
Aluminum Oxide Wet with HCI, Drying ........
Aluminum PIatlng,Sulfuric,
Sodium Dlchromate .....................
Aluminum Potassium Sulhte ................
Aluminum Potassium Sulfate, Vepor &
Condensate..
...........................
Aluminum Reduction Pot Plant Rooflng
andSIdIng ..............................
Aluminum Sulfate ..........................
Aluminum Trkhloride .......................
Amchem 616t: Nitric .......................
Amemx 2Dlt ..............................
Amerex 209t ..............................
Amine Salt Solutions, 73673 MA,
M.Band MCt ...........................
2.Aminoethanol ............................
Amlnoethoxy Ethanol rB 2TO.F ... , ...........
Aminoethyl Piperezlne ......................
Ammonia, Dry .............................
Ammonla, Liquid ...........................
Ammonia, Wet ............................
Ammonia: Ammonium Nitrate: Hydra
fluosilkk: Nitric: Phosphoric 6
Sullurlc, Wet Vapor ......................

CONCEN.
TRATION %

HETRON
9299P

100

28
57.30
10 ouga1
-

NPJ-

55 amtde

TEMPERATURE

HETRON
7211971197A

1251-

125
1w

NR
-

NR
NR

120
-

1W

0 1:01:23.77

100
120
AMW-I-

120
AMBI-

120
120
2cu
160

loo/-

1201-

NR
NR

125

-!120

210
210

165

2101220

1601150

2w/150
160'

2101220
2101220

2101150

2101220
-

160130
170/150
-

AMB

2OOll50

17ol150
170/120

2001150
2w/150
-

165!AMB

1651150

AMB
AMBiW

2201200

NR

Sat'd

NW30
-

1701150

5oz/gal
All

1001-

120

NIV-

SlImy:2

50
50

NPJ160/-

100

100
10
Sat'd
5
All

NR
160
-

100
-

100
100

TYPFS

125
100

120

COtlC.
Jnknown Q 10512O'F

RESIN

HETRON
920 SEAIESI9.90

0.1125.75

FOR

HETRON
7001100c

100

100

AROPOL
724017430 SERIES

AM0

16O/165/AM&--

60
60

Satd
20
Sald

160

210

16OJ-

160

13Oi250

40
6:16
103
100

100
100
100

-/lso

All

FUllas

220&?90/-

All

220/2901-

150
16wl40
-

17w150

2101220

210/230

1601150
-

1701150

125
125

LS125

125
125

65

NfU-

65
NR
NR

NR
NR

90

100

NFU-

Gas

-I90

180/200
16W2W
160/160
-

Gas

to assure

AM0
170/150

250
210
6595

90
NR
-

125

6595

AMBINR
AM&-

250

15:5:2.5:2.5:Trace

HETRON SSP for fums service only


IGood fesf results a/far shon axoosum
Synthehc
suriacing
WI/ recommended
lor ax~mu
msistance
l3enzo / Peroxrde - D#methyl am/ins cum system recommended
SaYISr sctory satwcc
Post-cure
racommendbd
Solution
may discolor
Nonrh!xotroprc
resms preleradle
Unsetlslacro/y
as /mmg

1701150

AMB

LYNR
NR
90
601NR

NWNWlW1160
lW/lM

NR

Acceptable
ss to odor end tasfe Ior AROPOL 7242 type resm. SNamed
4 hours wirh atmospheric
steam pnor to axposum
*Three 3 hour exposures to 30% nitric at 1CiYF to simulate cksnin
No dwxlorstion
occurs af 5 lt/ga/. sod wrfh AROPOL 7242 and A ETRON
7W ryps construcfmn
il surfaces are acid or steam cbanad
*C veil on/
-AROPOL
7r 4OOnly
*Apoears to be erosion/corms!on
AROPOL
7240 SAT al 1ZOF
1See M

01 trademarks

and oroducl

names

(continued)

..

.
P

::

::::::::

:::
1::

:::
:::
:

::::

. . . . . . . . . . . . . . . . . . .

a:.
.p..,::::::::.:::

. .
. . 5:::..2..:::::::
.,.;jc:;
::::::::::::: . . . .

::.:::

::.

:
:

::

:
G

Corrosion

184

TABLE

1.54:

Resistant

POLYESTER

Materials

Handbook

AND VINYL

ESTER RESIIN! j-ASHLAND

(continued)

SERVICE

CONCEN.
TRATION %

CHEMICAL
ENVIRONMENT
Ammonium Thiocyanate: Hydrochloric Acid
Ammonium Thiocyanate: Thiosuliate:
Sulfate: Water ........................
Ammonium Thiosuliate ...................
Ammonium Thiosuliate: Thiocyanate:
Sulfate: Water .........................
Ammonium Tungstate ....................
Amsco BKOH Solventt ....................
Amyl Acetate ............................
Amyl Acetate @ 120F ....................
Amyl Alcohol ............................
Amy1 Alcohol ............................
Amy1 Chloride @ 120-F ...................
Anaerobic Sewage .......................
Aniline .................................
Aniline Hydrochloride .....................
Anlllne Hydrochloride, Substltuted:
HB r. HCI: Br,: H,O .....................
Anlllne Sulfate ...........................
Anionlc Polyelactrolytes, Blend .............
Anionic Suriactant .......................
Anodizing Solutions ......................
Anthium Dloxidet ........................
Anthracene Oil .........................
Anthraquinone Disulionic Acid Q 150F .....
Antimony Pentachloride ...................
Antimony Trlchloride .......
.......
....
Apachet
...............................
Apple Acid ..............................
Aqua Ragia (Cont. Hydrochloric:
Cont. Nitric, 33) .......................
Aqua Regia .......................
Aqua Ragla Fumes .................
Armeen Ct ........................
Armeen DMCDt ..................
Aromatlc Hydrocarbon Alkylatlon .....
Aromatic Solvent: Tributyl Phosphate
ArquadUSOt ......................
Arsenic Acid .......................
ArsenouoAcid .....................
Asphalt ..........................
Atmosphere, Chemical Plant .........
Atmosphere. Coal Dust .............
Atmosphere, 100% Relative Humidity
Axelaic Acid .......................
B Crude 011 .....................
Bacterlclde Phenate Based ..........
Barlum Acetate ....................
Barium Carbonate .................
Barium Chloride ...................
Barium Hydroxide .................
Barium Hydroxide .................
Barium Sulfate ....................
Barium Sulfide ....................
..........
Beer
Beer, BrewIn; I&i; &ei
.........
Bwt Sugar Liquor ..................
Bentact
.........................
Berual Chloride ....................
Benzaldehyde .....................
Benzene ..........................
Benzene @ 120F ..................
Benzene @ 2WF..
................
Benzene, HCI (trace), Water .........
Benzene I Hydrogen Chloride Vapors
Benzene, Vapor ....................
Benzene, Wet Acid (HCI) .............
Benzene: Ethyl Benzene .............
Benzene Disulionlc Acid ............
Benzene Sulionic Acid ..............
Benzene Sulionic Acid ..............
Benzene Sulionic Acid .............
Benzene Sulionic Acid: Sulfuric: Water
Benzoilex 9.SEt ....................
Benzoic Acid .....................
tSee

l!st of trademarks

HETAON
92199P

4:5.5:2.3:68
60
5.5:4:2.3&I
Satd
lco
All
100
All
Vapor
loo
_
IM)
loo

-/NR

100
NW100

1601120

1w/200
-

NR

200
140
-/LS/NR

IWNA
140
NR

65

65

65

65

125
-

NR
-

NR
l&3/-

NW-

14011401Ls140

AMBIAMBf90
2CO/l&l
AMBI-

160
-

1oollOO/-

Satd
-

AMB
NR

200
140/NR

10
Satd
All

120/-

-/NR
2ca160
200
NWNW--/150
-/NR
NR

200
125
120
AMB
100
AMB
--ISAT/NR
AMB
200
150
95

NR
LS12YNR
AMB
SATIAMB
1601150
-

130
-

NR
NR

AMB

NR
NR

120
120
120
AMB
120

NPJSAT
65
NW150/160
140/1601220
_
SATIWI2001220
-

130/NR

NR

NR
-

NR
-

NR

100

100
100

100
100

100
100

120
_

120
_

120
-

100
120
AMB
125
160
200
200
_

195/-

AMB
125
NR
LSl6OINR
1601150
LS.AMB/NR
NR

160
-

170/15u
NR

50
100

160
-

1W
100
100
100

NFUAMBISO
NR/-

NR
AMB
NR

NRI-

LS
176

AMW-

AMB

AMBI-

AMB
100
194
200
NR

65

100
140
120
250

NR
NR
LS:AMB/NR
NR
NR
-

160

60/16O/-

AMBI-

150
-

250

NRJ-

180
-

1CO
Satd

NR
AMB
AMB
-

120
-

AMB

Satd
68715

120

NR

160
NFUAM B/W
-

140
225l220
125
120
_

120
NR
-

150
-

1/3:2!3
100
30
loO@ 16OF

140
NR

120
-

15W-

vapors

lCO/-

LS/NR
NR
NR

19 Be

Satd
All
All

130/110
-

130/-

NR

lOO/NR

100

130/110

100/1w/-

COW.
All

Satd
-

AMBIW
NR

65%

130
-

COllC

COW.
COX.

130/110
-

Cont.@ 160F
COW

160

HETAON
920 SERIES1980

130/110
-

2iW150
-

10

130/110/-

TYPES

HETAON
700/790c

130/110/-

Satd
100
56

100
Satd
50

180

F FOR RESIN

AROPOL
724017430 SERIES

15:4.5:1.5:1:76

TEMPERATURE,

HETRON
72/197/197A

125
160
200
200
200/l 50
150
160
150/b
AMBlNR
NR
NR
NR
NR
-

lW210/220
210/1501160
150/2101160/AMBINR
16O/NR/NR/NRilOO
NR
NR
_

AMB
-

15OlNR
NR

200
-

NR
140
120
170/150

200
140
120
2201200

2 101220
SAT
210/220
140/120/210/-

and product names

(continued)

Synthetic Resins and Polpm

TABLE

1.54:

POLYESTER

AND VINYL

ESTER RESINS-ASHLAND

(continued)

SERVICE

CONCEN.
TRATION %

CHEMICAL
ENVIRONMENT
Benroic Anhydride
......
.....
Benzotnchloride
Benzoyl Benzoic Acid to) .....
: : : :::
Benzoyl Chloride
....
Benzoyl Chloride Vapors with HCI,
H,O, Benroic Acid ..................
...........
Benzyl Alcohol
...........
Benzyl Benzoate ........................
Benzyl Chloride ..........................
BetzSullite3t,pH5.5..
...................
.................
Biocidet 207
Biocidet 205 @ 125OF : : ...................
Biocide: Chlorophenate, Organic Sulfur Type
Biocide; Chlorophenol, Methylone
Thiocyanate Blend @ 125F .............
Biodegradable, All Purpose
Liquid Cleaner ..........................
Biodegradable Detergent, Liquld .............
Biodegradable Detergent Ultrawrtt 5OK .......
Biodegradable Dotergent Ultrawott 4tiDS .....
Biodegradable Detergent Ultrawrtt BOL .......
BKOH, AmscoT. Solvent ....................
Black Chrome Bath: Chromic, Acetic,
Barium, Acetate ........................
Black Liquor, pti > 7 ......................
Black Liquor Recovery Fumaca Gases
@ 210.325*F ..........................
Black Liquor Room Flooring, Spills ...........
Black Liquor, Spent Sulfite, Calcium Bass
Mill pH 1.52 (Trace Formic & Acatate) ......
Blanch, Peanut, Hot Water,
Detergent @ 16QF ......................
Bleach, Ferricyanide with K Bromide
for Photography .........................
Bleach Reactor. 6% Sodlum Hypochlorlta ....
Bleached Pulp .............................
Blow Gas Absorber .........................
Bonderitet 73 ............................
Bonderitet 722X? ..........................
Bondarttrt K.7lCl-g 701-P ....................
Bonderitet K.761. pH 56 ....................
Bonderitet 37,3?S, 39 ......................
Bondoritet 721-S ..........................
Bonderitet 1303 Makeup ....................
Bonderitet 1303 Replenishing ................
Borax ....................................
Bordeaux Mlxturo ..........................
Bork Acid ................................
Boric Acid: Nickel Chlorlda Nkkrl Sulfate ......
Boric Acid: Sodium Sulfate with 0.25%
Sulfuric Acid, 0.03% H,O,, 100 ppm Iron,
3OG3 ppm Chloride, Temperature Cycled ....
Bottle Washer Solution .....................
Bowl Cleanset ............................
BowlCleanse,MildT
........................
Brake Fluid ...............................
Brass Plating Solutton 3% Coppen 1% Zinc
and 5.6% Sodium Cyanides, 3% Sodium
Carbonate
.............................
Brew Kettle Fumes .........................
Brine,CI,Sat.,pH2
.........................
Brine, Dechlorinatsd: pH 2-3, Free
Chlorine (Traces) @ 2W~22gDF .............
Brine, Salt ................................
Broke Chest Fumes ........................
Bromine, Dry Gas ..........................
BromineFumes ............................
Bromine, Liquid ............................
Bromine Water ............................
Bromine: Water ............................
Bromine, Wet Gas .........................
Bronze Plating, 4% Copper, 5%
Sodium Cyanides, 3% Sodium Carbonate,
4.5% Rochelle Salts ..............
Brown Stock Washer Hoods, Ducts
.... : : : :
tSee list Of tradem.wks and product names
*HETROf,
c,d,,,dns

rg, ,nd 700 IC,,CI


w,,h Some
crazmo

loo
loo
All
100

WETROM
92199P

F FOR RESIN

AROKIL
7240/7430 SERIES

TYPES

WETRON
7001700c

HETRON
Pm SIIIIFI~PI

NR

210:-

NR

NR

NR

NRJ-

NR

NR

NR

AM0

_
NW-

NR

Jnknown Gt 194-221
1W

TEMPERATURE,

HETTROll
7211971197A

NFCNPJ-

185

-/NR

NPJNW30
-

AMBlNR

100
100

NRI-

200
125

ID0
100
100

NW0
-

NR
200

125

125
SAT
125

SAT

SAT

100

loo
1tM

loo
loo

loo/-

IO0
loo

1w
150
130

100
loo

100
lWfloo/-

LYNR

loo/-

IW

LS/LYNR
125
LSiLYNR

125
SAT

lW/-

115

NR

NRINR

--ISAT/NR

NR

1001-

2201180

21OQ20

NR

NWSAT

AMB
@ ZlZF

NR
-

NFU-

80
140
190

NR

NR
-

12w-

185
1M
100

120
150

NR

Satd
&I253

agal

167mcVI67
-/180
-

1525
5.10

la3
Satd @ 75-F

,es,ns rpprrr 10 DC unswtabk under


but l e n?sisf&7f
under
SUIK
CondmnS.

22CV140
-

210/-

2W

210122u
,

-I206

--12ow206

loo

2061I ?O/twiloOiNFVIX)

180

150
220

IM
NR

2121200

2101220

SAT
220

1801150

200

210/220
-

NR
NR

AM0

NR
NR
-

NR

gpl

la,

1BoIlXl

loo/loo/-

lXV-

S&d
Satd

1801140

100
loo

180

loo
1w
-

IW

300310

140
200

NR

a5
NR

Satd

180
SATi
AMBFaO
14WNRI-

180

NR,-

SAT
AMB
140
NR

5%
AMB

IBOI-

NR

Boll00
AMBIIW
NR
SAT
180/2w
80

100

AM&W

180SATISAT
SAT
'D,Ssolvcd solids. 1574.2183 ppm PO..
0.25 ppm: rota/ PO.. 1.3 ~ppm:
CU. 0 7 pm. In. 3.4 pppm. Fe. 7.8 ppm: C&o, 4x) ppm mar.. Chromafr.
hexa. 18.22 ppm Cl2 rosrduel.02045 p@n:NeCl. 527.02 pprn

CyCllC

(continued)

186

Corrosion

TABLE

1.54:

Resistant

Materials Handbook

POLYESTER

AND VINYL

ESTER RESINS-ASHLAND

(continued)

SERVICETEMPERATURE.'FFOR

CHEMICAL
ENVIRONMENT
Build? Detergent Solution. pli 9.10
Butadisne Latex
...........
P.Butoxyethanol
2.2.Butoxvethoxvethanol
: : : .. :. .......
B;tyl Acetate
:
...
Butyl Alcohol: Ethyl Hrxylacatate:
Di4sobutyl Ketone ......................
Butyl Alcohol, Normal ....................
Butyl Alcohol, Secondary ...................
Butyl Alcohol, Tertiary .....................
Butyl Carbitolt ...........................
Butyl Cellosolvet ...................
Butyl Cellosolvet: Monoethanolamine
Film Stripper Q 136F
.................
Butyl Ether ....
Butyl Ether. Phosphorfc: ~Hydr&lo&
: : : :,I : :
Butyl Phthalate ...........................
Butylamlne ..............................
Butylena Glycol ...........................
Butylrne Oxide ...........................
Butyric Acid .................
.........
Butyric Acid .............................
Butyric Acid ..........................
Butyric Acid .............................
C56T ..................................
C.56t.Crudo
.............................
C56t; High Purfty .........................
C56T; Beg. P High Purfty Wet With H,O .......
Cadmium Cyanide Plating Bath, (3% Cadmium
Oxide; 10% Sodium Cyanide; 12% Sodium
Hydroxide) ............................
Calcium Bisulfide .........................
Calcium Bisulfite .........................
Calcium CarbonateJ .......................
Calcium Carbonate, 90%; Magnesium
Hydroxide, 10%; Nickel & Iron Hydroxides
.
Calcium Chlorate .........................
Calcium Chloride .........................
Calcium Chloride, pH 5.5 ...................
Calcium Chloride, pH 8.5 ...................
Calcium Chloride: Phosphoric Acid ...........
Calcium Chloride: Sodium Chloride:
Magnesium Chloride ....................
Calcium Hydroxide .......................
Calcium Hydroxide .......................
Calcium Hydroxide .......................
Calcium Hypochlorttea ...................
Calcium: Magnesium: Sodium Chlorides ......
Calcium Nitrate ...........................
Calcium Oxide ............................
Calcium Sulfate ..........................
Camphene, Chlorinated 68%: Xylene .........
Camphor ...............................
Can Cleaner, Acidic, pH 1.2, Sulfuric &
Hydrofluoric, Aluminum 6 Oil
Impurities .............................
Can Treatment, ChromeFree, pH 5-6 .........
Can Treatment, Chrome Phosphate, pH 2 ......
CaneSugar Liquor.. ......................
Canning Plant Waste ......................
Capric Acid ..............................
Capric Acid ..............................
Caprylic Acid .............................
Caprylic Acid ............................
Carbamide ..............................
Carbon Beds, Water Treatment ..............
CO,: SO,: N,: 0,: H,O Vapors ................
Carbon Dioxide, Wet. Acidic .................
Carbon Disulflde ..........................
Carbon Dlsulfide Recovery Fumes ............
Carbon Disulfide Vapor .....................
Carbon Monoxide Gas ......................
Carbon Tetrachloride .......................
Carbon Tetrachloride, Vapor ..............
Carbonic Acid ....................
.......

CONCENTRATION %

HETROW'
92199P

1012'b sollos

HETRON
721197;197A
120'
-

AROPOL
7240:7430 SERIES

m-

RESIN

TYPES

HETRON
700 7ooc
'20
_
_

HETAON
920 SERIES,980
1:: -

loo
100
100

AMBi90

5 10:85

80

100

100

8OINR

60 120

80INR

lCK!NR
-

100
100

-I93
-90
-1190
-

BOINR
-

%3'120
NRIOO

100

-ma

851-

220150

21G,-

5730

NPJ-

NR

801-

80
AMB

100
-

NR
*0.:_
-

NR

100
Unknown

NR8C' -

NR

100

100
IOU @ 75-F
100
100
25
50
70
100
100
100
99+

-/160
NW12OI150
-/150
--I150

a5
85
AM0

100
100
85
85

120
NR

1601140

120
-

120

AMB

AMBI-

AM0
200

180
90

wix%-

LSAMB,luR

NR
15oi130
1501-

160!140

25
Sat'd

25cf180

--ILSI20
1501120

10:12:2
15
25
Sat'd
Sat'd
10:2:12
Sal'd
Sat'd
Sat'd
90.10
100 @75-F

--/lM)
--ilfxJ

150
-

-/160

175'/175/-

-I100

120

NR

lEo/15c
180193
160190

150

120/-

-llE!O

150

220~200
1.60
210
200
225/220
27&23&_
180
160
160
120

180
210220
210>220
2101220
180,160,180
-

150

1801150
-

2201200
-

210'220
-

18OflM

122
-

2101220
-

--INR

NR

22012cO
-

120
120

Sat'd
5
--I160
--116O

Sat'd

AM0
160/120

1601120

140
140
160

200

12zO0.1:70:5:14
by vol
100
100

250
NR

120
250
NR

25

140
NRI-

160
125'

100
Sal'd

160

160

140

180
-

160

NRBO
180200

16OllW
160/100

160
16C
160

150190
-

160190
-

!80:200
1601-

2W/lYl
NR

250/200
NR
-

NR

160/200
125/14OlAMB

120

100
100

210~220
_

250

250/200
-

Satd
5

NR-

--12w100

210*16C -

180,-

-I170
-/160

250
--127e*/-

120
200:150

Sal'd
Sat'd

160'180

16011701110

2M

2001120
NR

NR
_

35
2510

8G'?20

160,N9100
_

Sat'd
55

AMB
NR

90

250

80
-

.P

NR
-

Sat'd

AMB

NR
2001150
LS.AMB.NR
AM0
16Oi130

160
NR
NR
AMB

NR80

21013ol
NR
210,300
LSAMB150
AMB.150
AMB

tseellsl Of trademarksand
product "arnes
(continued)

188

Corrosion Resistant Materials Handbook

TABLE 1.54:

POLYESTER

AND VI

L ESTER RESINS-ASHLAND

(continued)

SERVICE

CONCEN.
TRATION %

CHEMICAL
ENVIRONMENT

Chlorine Dioxide Process Generator Covers


Chlorine Dioxide Retention Tower
Chlorine Dioxide: Sodium Carbonate and
Bicarbonate. pH 6
Chlorine Dioxrde: SodiumChloride
..............
Chlorine Dioxide, Vapor
Chlorine Dioxide-Washer
Hoods, Ducts ...
Chlorine Dioxide, We? ..............
Chlorine Dioxide: Sulfuric (lO.Shl) ..........
Chloroacatlc Acid ........................
.......
Chloroacetic Acid
Chloroacetic Acid ......... : : :
:::
Chloroacetic Acid Plant Water Scrubber
::
Chlorobenzene .... ..
Chlorobenzene Vapor 6 Condensate
...
::
Chlorolluocarbon ........................
Chlorofon Alkaloids, HCI, Acetic, Sodium
Chloride, Water Fume System ............
Chloroform, Llquid .......................
Chloroform: Methylsno Chlorida: Carbon
Tetrachloride, Small Amount Methyl
Chloride, ii,O, HCI @ lOOoF ............
Chloroform, Vapor ..................
Chlorosulfonic Acid ......................
Chlorothene N.U.f ...............
Chlorotoluene (0) ..........
: : ........ : :
Choline Chloride; Reactlon of Trtmethylamlne
HCI and Ethylene Oxide .................
Chromate-Zinc
Blend lnhlbltor Strbillzed ...
Chrome Acid Plating Bath Vapor ............
Chrome Anodizing Solution ..............
Chrome
Barrel Plating Fumes .............
Chrome Bath, Black, Chromic, Acetic,
Barium Acetate .......................
Chrome Bath, 19%
Chromic Acid with Sodium
Fluorosilicate and Sulfate ...............
Chrome Frae Can Treatment, pH 6 ..........
Chrome, Hard, Plating Baths .......
:. ......
Chrome Phosphate Can Traatmant, pfi 2 .....
Chrome
Plating ..........................
Chrome Plating Bath Vapors ...............
Chrome Reduction Process .................
Chrome Raductlon Procass Liquor .........
Chromic Acid ...........................
Chromic Acid ............................
Chromk Acid ............................
Chromic Acid ............................
Chromic Acid ............................
Chromk Acid ............................
Chromic Acid ............................
Chromic Acid ............................
Chromic Acid ............................
Chromic Acid ...........................
Chromic Acid Evaporator, Vacuum, Recovery
Units wlth 20% by Volume Concentrated
Sulfuric @ 160-F .......................
Chromic Acid, Intermittent ..................
Chromic: Nitric: Hydrofluork Acids ..........
Chromic: Nitric Hydrofluork Acids ..........
Chromic: Phosphoric: Hydrofluoric Acids .....
Chromic: Phosphoric: Hydrofluoric Acids .....
Chromic Acid: Sodium Fluoride.
High Agitation .........................
Chromic: Sulfuric Acids ....................
Chromic: Sulfuric Acids ....................
Chromic: Sulfuric Acids ....................
Chrornlc: Sulfurk Acids ....................
Chromic: Sulfuric Acids ....................
Chromic: Sulfuric Acids ....................
Chromic: Sulfuric Acids ....................
Chromic: Sulfuric Acids ..................
Chromic: Sulfuric: Hydrofluosilicic Acids .....
Chromic: Sulfuric: Hydrofluosilicic
(Chrome Plating) .. ...
Chromic Oxide in 300F end 160FAir,
...
Quenched with 1OOF Water, 5060 fps
t&e

hsl of trademarks

and product names

HETRON
92 99P

_
-

180

loo
120

5.3 7
35.23
Satd
-

TEMPERATURE.

HETRON
721971197A

F FOR RESIN

AROPOL
724017430 SERIES

180

200
SAT

Sald
-

140
120

1201Qa
-

25

NR

90

50

NR

AM6
NR

1301NR
NR

TYPES

NETRO
700700c

HETRON
920 SERIES!990

NR

NR

120
QO
-

200
150

NR

NR
-

lo(1
NWNRI-

NR
-

NR
-

N F&SO
-

COX
3040 Q 110-F

NR

100
100 0 12OF

NR

Nh-

NR
-

100

15&-

156

At.46
NR

NR

NR

NR

100

NW-

39:65:5

NR

NR

NR

NR

NFU-

NR
NR

NR

100
100 0 6OF

NRNR-

NR

NR
-

NR
NR
-

NPJNR
-

100 @ 200-F

NW-

NR

100

NR
100
-

125

160
LS125iNR

12Ol-

200
150
-

115

200

NR
-

NR
-

100

NR

125
-

NR-

1M
130

1M
-

Q 100-F

@ 12OF
25

10

2Ockl&Y-

2w
1%

15

LS2001LSXXllNR
150

20
30

140
NR

40
M
6.5 ltwgal
60

NR

AMBI-

NR

lOQi120

NR

NR

601100

NR

NR
NR

- 180
NW60

NR
NR
NR
-

NR
NR
NR
-

22@220/2301230/-

NR
-

40 vapor/-

140
140*11404150

1%

Sat d

NR

120

56 oz/gal

NR

NR
-

NR
NR
NR
NR
-

NR

NR

NR

NR

NR
NR

NR

SAT/-/-

NR

xx)

NR

60

NR

62:1.5
7:40.2

60
103

9.3:6.5:11

100

NR
NR
NR

136

153

NR

6353 oz/ga1
33:0.33 or/gal

140
140

NR
NR

530.53

177

NR

NR

NR

NR
NR

36:ppm
150-

odgal

3:16

16.5

x)s?g
12.5.16

180
225/225/-

2032

QO

35.2:O 2:0 4
450305

OUgal
<2

115

115
NO chemical

attack wth

NR

1520
5:2:3

40:0.4 ougal

SAT
-

NR
-

NR
NR

NR
NR

197. not swtabie

NR

due to abrawn

(continued)

Synthetic Resins and Polymers

TABLE

1.54:

CHEMICAL
ENVIRONMENT

POLYESTER

AND VII Ni fL ESTER RESI

(continued)

SERVICE TEMPERATURE, OF FOR RESIN TYPES

J-

Chromic: Phosphoric: Hydrofluoric Acids. ....


Chromic: Phosphoric: Hydrofluoric Acids. ....
...... .................
Chromic Sulfate
Chromium Hardening Fixing Bath,
........
Photographic
.. ..
Chromium Hardening Stop Bath;
Photographic
. ........................
Chromium Potassium Sulfate ................
Chromous Sulfate ..........................
Citrate Process for SO, Removei ..............
Citrext Process for SO, Removal .............
Citric Acid ...............................
Citric Acid
.............................
..........................
Citric Acid .....
Citric: Lactic Acids ........................
Citric AcidlSuifate/Chlorlde in Mixed
Solvents-Minerel
Spirlt Type @ 7S-220F ....
Clay Slurry 20%, 20% Potash in
.
Sat.Brine@AMB..
Cleaner 508T ..............................
Cleaner, Biodegradable, All Purpose
Liquid ..................................
Cleaner 8 Disinfectant, Pd 94t ...............
Coal Dust Scrubber ........................
Coal. Med. Sulfur, Particulate Scrubber,
pH 1.439, Ci560-1200 ppm, 300,ooO ACFM ....
Coal/Water Slurry @ 8oF ...................
Coatlngs, Water Reducible @ 120F
Acrylic Wet Ink Varnish (PPG industries) .....
Polyester White Enamel (PPG industries) .....
Epoxy Spray Liner (PPG Industries) ..........
Acrylic Spray Liner (PPG Industries) .........
Cobalt di (2 ethyl hexyl) phosphate:
tri-m.butyl phosphate: Shells
livestock spray base ......................
Cobalt Nitrate .............................
Cocamidopropyl Betaine ....................
Cocamidopropyi Dimethyiamine ..............
Coconut Fatty Acid Dlethanoi Amide ..........
CoconutOil..
.............................
............
Codliver Oil ..................
Collee Roasting Fumes ...................
Combustion Gases, Particulate, Cooling
and Washing with Water ..................
Condensable Liquor, pH 9, Pulp and
Paper Mlii ..............................
Cooling Tower Inhibitor, ChromateZinc
Blend, stabilized .........................
Coollng Towers ............................
Cooling Water, ph 5.57 ....................
.......
Cooling Water, 20 ppm Chromate
...........
Copper Acetate
...............
Copper Chloride ...........................
Copper Chloride: Silver Nitrate ...............
Copper Cyanide ...........................
Copper Cyenide Plating .....................
Copper Cyanide Plating Bath, (10.5% Copper and
14% Sodium Cyanides; 6% Rochelie Saitsp
@ 19tIOF ...............................
Copper Cyanide, Potassium Cyanide,
Potassium Hvdroxide
Copper Electrolytic Cells
Copper Extractant,
Ion Exchange Oxime Type
Copper Fluoride]
CopperLeachTanks........................
Copper Matte Dipping Bath, 30% FeCI,;
19% Hydrochloric
.
.
Copper Nitrate
Copper Oxide: PbSO,: S: FeO: ZnSO,: Bi,(SOJr
Dust
..__....
Copper Oxychloride
Copper Oxychloride
Copper Pellet Smelter
Copper Pickle Bath, Sulfuric/Water
_

S-ASHLAND

189

CONCEN.
TRATION %

HETRON
92/99P

HETAON
7211971197A

9.3:6.5:11
All

60

80
-

7:40 2

Satd

Satd
Satd @ 265-F
-

150
140
140
160
BP
-

-1200
BP1200
_

150

170/l 40
1601150
160/150
NR
-

loo

100

150

Liquor

Hetron

1O/90

30:5:65
Satd
100
100

150
197-3 with abrasion

NR

SAT

NW
NR
NR

SAT
NR

176
-/140/-

120

120
100
-

loOI-

100

130

At.40
-

-/I20

125
AMB
160
360
-

14017YAMB
-

140175
_

Fumes
1 gal19 gal

Dissolved
so/Ids. 1574.2183 ppm: PO.. 0.25 ppm; tofal PO., 7.3 pprn;
Cu. 0.7 ppm; Zn, 3.4 ppm; Fe, 7.8 ppm; CaCo, 450 ppm max.; Chromate,
hexa. 18-22 ppm. C/, res,doal, 0.2-0.45 ppm: NaCI, 527.702 ppm.

tSee

130/-

AMB
-

AMB

1601130
160/-

180

1601150
-

2201200
-

115
-

AMBI_

LS125INR

125

175
150

1401-

AMB
1501130

1401160

120/15Ol160
_

130

NR

--INR
-

120/-

NW-

1CHl

120
-

200
160

SATINRISAT!-

120

AMB

SATI-

120/-

200190
-

250

SAT

at 7 fps

120/-

Satd
Fumes

Satd

BP
NR
-

140/-

250
-

l&25:25 10.6 3
20

2101220

140/-

Satd
1533

6:3:2 angal
-

Filler Satefactory

NR
--I-/NR

150/-

100
-

resistant

-/-/NR
-/--INA

1W
100
100
-

Satd

160
220
NR
_

160

100
-

Satd Q 75F

140
140
-

SAT @ 12 fps

100

Satd

_
150

Unknown
40 Slurry

HETAON
920 SERIES/980

too
_

HETAON
700/700c

100

Satd

50

AROPOL
724017430 SEAIES

WNR
-

200.

170
180
1601160
2101220
_
2101220
-

SAT

1201-

200
_

150

NR
-

160
140

160/140

200
300/3001175

list 01 trademarks

zoo/-

220/200

210/220

NR

NR
-

and product names

(continued)

190

Corrosion

TABLE 1.54:

Resistant

POLYESTER

Materials

Handbook

AND VINYL

ESTER RESINS-ASHLAND

(continued)

SERVICE

CONCEN.
TRATION %

CH.#lCAL
ENVIRONMENT

Copper Pickling Bath (Fe,(SO.),, &SO.)


Copper Plating Solution(45% Cu(BF.),;
19% Copper Sulfate; 8% Sulfuric .....
Copper Refining Cells .................
Copper Smelter Fumes .........
CopperSullate
................
::::...I:.
Copper Sulfate: Sulluric ...................
Copper Sulfate: Sulh~ric ...................
Copper Sullate: Sulfuric Acid ...............
Corn

Oil

_
-

Satd
50.xX1

gpl

................................

2@3O.@JO
gal

220

180
SAT

150

1801120
-

120
-

lM/-

250

Slurry
All

100

loo

100

100
100

lWl-

100

-/NR

100
-

100
NR

100
100 @ 75-F

-/NR
-/NR

AMB
-

NA
NR

100
12:5

-/NR

SO
-

NR

130

134X-

10:1020
-

_
22o:zw
-

20 -

laa
2iOi250
-

150

120
1eOllW

120*:150200
20>22C

210 220
_

180rloo
-

50 200
-

NR
-

NR
IBOI_

130
-

210

180,150
1301110

2w
-

2101220

210

18ollM

200

2101230

180

100

LS125iNR
-

AMBI125
-

125
90

650

LSSAT

212

212/NR

217J2w
LS to 2lOiNR
NR

14W-

1W

175

175
140
NR
NR

Q 100-F
100

100

3 75

103

NFU-

150
NR

14W-

2.5

17Y1601NR
150/NR
-

NR
NR
-

NFL-

180
180
-

200

loo

l&I
212

1SO/w
AMBINR

NRI-

80
-

2101220
-

2!0~220
-

1801212

200

AMB

AMBI-

AMBI-

NR

NR

NR

120

120

loo

loo

loo

100

loo
100
16LX-

100
Satd

1w

160
I40

loo/-

tSee

NRI120/1&l
1201lW/:001-

lW/-

1w

lW/-

120

100
-

NR
180,-

list of trademarks

I&l/-

NR-

loo

NFU-

150
-

Satd

loo
-

Kv120

150

IS0

1w

160

Satd
-

100

Cone
-

HETROH
920 SERIES980

Vapor
100
10:10:1:79

lank

22Ol220

AMB

100
-

955

TYPES

HETRON
700!700c

15Ol-

1228
100

F FOR RESIN

AROPOL
7240:7430 SERIES

I50

250
-

5-18

Starch ..................
........
Corn Sugar ...........
.............
Corn Syrup, Acid, Decoloriring ............
Corn Syrup, Crude Acidic .....
CottonseedOil
.............
1: .:..::::
Cresol .................................
Cresol Fumes ...........................
Cresylic Acid ............................
Cresylic Acid Fumes .. ...................
Cresylic Acid: Sodium Hydroxide ...........
Cresylics, Water, Neutral Oils,
Mercaptans. H,S, Waste Liquor, pH 56 ....
CrudeOil,B
.............................
Crude Oil, Sour .........................
Crude Oil Storage Tank Bottoms ...........
Crude Oil, Sweet .........................
Cupric Sulfate: Fe& Bulfair:
Sulfurtc Acid ..........................
Cutback Diluent, Refinery .................
cw-ft 102 ..............................
CyafSlOlt..
...........................
Cyanoacetic: Methyl lsobutyl Ketone;
0.6 Sulfuric in Saturated Sodium
Chlorfde @ lOOoF ......................
Cyanuric Acid Tank with 16% Sulfuric,
Steam and Calcined Urea ................
Cyanuric Chloride Scrubbed with 6.26% NAOH
Cyclohexanr ............................
Cyclohexane ............................
CyClohOxaM: Acetone: Hrxan: Watr .......
Cyciohexanono ..........................
Cyclohexylamine: Hydrochloric Acid ........
Cycl~Octadlrne
.........................
Cygont 400 .............................
Cygont 400 .............................
Darext46 ...............................
Daxadt 30 ...............................
DDT. Inrectlcide Bolutlon ...................
Decanol .................................
Dechlorinated Brlnr pH 2.3, Fm
Chlorine (fracre) ........................
Deionized Watep .........................
Deionized Water, High Purity, 1.5 )rmho/cm. ....
Demineralized Water ......................
Depleted Na 6 K Brines ....................
Deamuttor I Deoxidizer for Aluminum ..... , ..
Desulfurtzer Feed/Rofiney
.................
DosulfurIzing SO,, H,S wlth
Monoethanolamlnr
.....................
Detergent Alcohols ........................
Detergent Base-Tridecylbenrenr
Gulfonatr
Detergent, Biodegradable, Llquid ............
Detergent, Dimethyl Benzyl NmAlkylType
with 23% HCI. 77% Inerts ................
Detergent, Dlmethyl Benzyl N-Alkyl Type
with 25% Phorphorlc. 75% Inert r ..........
Detergent, Dirhwrrhing. Llquld,
Biodegradable ..........................
Detergent, Organic pH l&11 ................
Detergent, Pax Hyrpwdt ...................
Detergent, pH 6 ...........................
Detergent Solution, Buildt pH 9.10,
1012% Solids .........................
Detergents, Germicidal ....................
Detergents, Organic .......................
Detergents, Sulfated .....................
as m

TEMPERATURE.

HETRON
72/1971197A

_
-

Corn

NO change m ware, at 0 1 tf z lammare/gal.


AROPOL 7530 satslactory

HETROW
92!99P

120
-

_
1201100
-

and product names

(continued)

Synthetic

TABLE

1.54:

POLYESTER

AND VII

CHEMICAL
ENVIRONMENT

........................

Dichloroethene ...........................
Dichloroethylene ..........................
Dichloromethane
.........................
Dichloropene: Dlchloropropane ..............
Dichlorophenol ...........................
Dlchlorophenoxyacetlc Acid ................
Dichloropropane ..........................
Dichloropropane: Dichloropene ..............
Dichloropropene ..........................
Dichloropropionic .........................
Dichromate Bleach, Sulfuric,
Photographic ..........................
Dicoco Dlmethyl Ammonium Chloride ........
DiCrobe NNT, Germicidal Detergent ..........
Dlcyclopantadiene
........................

DieselFuel...............................
Diesel Fuel, Premium ......................
DiethanoiAmine ..........................
Diethanol Amine ..........................
Diethyl Benzene ..........................
Diethyl Carbonate .........................
Diethyl Ether .............................
Diethyl Formamide ........................
Diethyl Ketone ...........................
Diethyl Maleate ...........................
Diethyl Maleaie: Water .....................
Diethyl Sulfate ..........................
Diethylamine ............................
Diethylene Giycol .........................
Diethyiene Glycol Nebutyi Ether ..............
Diethylene lmide Oxide ....................
Diethylene Trlrmine ......................

Diethylene Triamine: Ethylene Diamine:


Sodium Hydroxide: Water ................
Dlethylhexyl Phosphoric Acid (In Kerosene) ....
Digester Blow Down Vapors @ up to 220F ....
Digester Room, Pulp Mill, Floors, Spills .......
DigiycolamineG 270F ....................
Diglycolamine. Satd. with CO, and
H,S @ 27OOF.. .........................
Dihydrcgenated.Tallow Dlmethyl Ammonium
Chloride: Aqueous isopropanoi ............
Diisobutyl Ketone: Ethyl Hexyiacetate:
Butyi Alcohol ...........................
Diisobutyl Phthalate ................
......
Diisobutylene ............................
Diisocyanate, Diphenyl Methane .............
Diisopropanolamine .......................
Dimethyl Acetamide .......................
Dimethyl Acetamide .......................
Dimethyl Benzyl N-Aikyl Type Detergents
with 23% HCI or 25% phosphoric
and rest inerts ..........................
tSee

11s of trademarks

(continued)

SERVICE TEMPERATURE. F FOR RESIN TYPES

CONCEN.
TRATION %

Detergents, Sulfonated ....................


Developer, Photographic, Caustic ..........
Developer, Photographic, Moderately
Alkaline ............................
Developers, Color .........................
DFR.lZlT ......................
^. .......
Dialiylphthalate ...........................
Di-Ammonium Phosphate @ 225OF ..........
DFAmmonium Phosphate: Ammonium Sulfate
Di.Ammonlum Phosphate Vapor .............
Dlbromophenoi ...........................
2,3Dibromopropanol
Q 120F ..............
Dibromopropanol; Small Amount Trim
bromopropane & Brominated Organics .....
Dibutyl Ether .............................
Dibutyl Phthalate .........................
Dibutyl Sebacate .........................
Dlcalcium Phosphate gas: Llquid;
ScrubbingpH54..
.......
. ..............
2. SDichioroJ-Aniline in 32% HCI @ 170F ....
Dichloroacetaldehyde
.....................
Dichioroacetic Acid .......................
Dichlorobenrene ..........................
1.2.Dichloroethane

L ESTER RESINS-ASHLAND

191

Resins and Polymers

All
65
10:10
100
6%12OF

100 @

100
IW
100
-

IWF
100 @ 265F
100
100 @

100
100
100

HETRON
92199P

HETAON
721197/197A

AAOPOL
724017430 SERIES

100
LS/LS/NR
LSlLSlNR
80
Ah40

HETAON
920 SERIES/980

16OllW

2W
-

2101220
-

80/80/60
80/80180
80180180

HETAON
700/700c

lW/IW
160/13a
AM0
-

100
180
-

lCOI1501180
I W/SAT
-

NR
-

NR
NR

NR

NR

SO/-

80
15O/AMB

801150
1M/200

Ah40

NR
NR

210/150
300
-/LSINR
NR
NR
NR
NR

LS/NR
-

LSlNR
-

NR
NR

NR

LSI_
NR

NR

NRIlW

NR
NR

NPJNRI-

NR

NR

NR
NR

NR
NR

NR
-

NR
-

NR
NR
NR

IO0
2

NR

NR
-

NR
-

NRI-

100
@ 100-F

NR
NR

NR
-

NR
-

NR
-

100
100

NR

NR

NR
-

NR

100
Q 1WF

80

120

100
loo

loo
100
175
-

120112u
-

120
-

175040
AMBI-

30
100

110
110

AMBI-

IW
100

120
-

NR
-

NR
-

100 @ 75F

NR
-

NR
-

NR

100 @ 75F
loo
100 @ 75F
97~3 @ 212F
100
loo
100
100
10
100
10:10:10:70
20
-

NR
1w
100
85
100
NR
-/SAT/-

NR

NR
NR

NR
NR
-

NR
NR
-

1801150
-

2M)
-

NR

NR
-

LS
AMB

NR
120/1501200
804120
80 120
801120
NR
NR
NR
NR
NFVNFUIOO
NR
1501200
so
_
1201150
-

loo

NR

NR

LSiNR

NPJ-

100

NA

LS/NR

NRI-

75:25

120

1201120

120

120/-

80

100

AMB
IM)
-

loo
70
100 @ 75F

150
NR

loo

@5:10:5
100
100

120
-

100/l 50
AMBIlOO
-

NR
_

NR
NR

801120
_

lOOI-

and product names

(continued)

192

Corrosion Resistant Materials Handbook

TABLE

1.54:

POLYESTER

AND VINYL

ESTER RESINS-ASHLAND

(continued)

SEnVICE TEMPERATURE, F FOR RESIN T\ PES


CHEMICAL
ENVIRONMENT
Dimethyl Distearyl Ammonium Chloride:
Aqueous lsopropanol
Dimethyl Formamide ........................
:::::::
Dimethyl Formamide .....................
Dimethyl Formamide @ 9OF ..............
Dimethyl Formamide: Terephthalic
Acid: HCI: Water ........................
Dimethyl Morpholine Q 120F ..............
Dimethyl Phthalate ........................
Dimethyl Phthalate: Methyl Ethyl Ketone:
MEK Peroxide ..................
......
Dimethyl Sulfoxide ........................
Dimethyl Tin Dichloride. ..................
Dimethylamine
..........................
Dimethylamine ...........................
DMP: MEK: MEK Peroxide ..................
Dinitrobutyl Phenol in 25% Sulfuric
Acid Weste @ 150F ....................
Dloctyl Phthalate .........................
Dioxane .................................
Diphenyl Ether ...........................
Diphenyl Methane Diisocyanate .............
Diphenyl Oxide ...........................
Dipropylene Glycol ........................
Dipropylene Glycol Dibenzoate ..............
Dishwashlng Detergent, Liquid,
Biodegradable ..........................
Dishwashing Liquid .......................
Disinfectant, Chlorinated Phenol Type ........
Disinfectant & Cleaner, Pd 84T ..............
Dispersant, Anionic, Blend ..................
Dispersant, Nonionic, Blend ................
Dispersing Agents ........................
Distilled Water ...........................
Di-Syston ...............................
Dlversey 514T ............................
Diversey808T ............................
Divinyl Benzene ...........................
Dodecane ...............................
Dodecene ...............................
Dodecene, Trace HCI ......................
Dodecyl Alcohol ..........................
Dodecyl Benzene Sullonic Acid:
Sulfuric Acid: Water: Oil ..................
Dodecylbenrene Sulfonic Acid
Dolomite Kiln Gases, Wet ..................
Dowclene ECt ............................
Drain Cleaner, Liquid (Spartan Chemical)
Q 80F ...............................
Drewsparse 732t ..........................
Drewsperse734f
..........................
Drewsperse735T Q 12SF ..................
Drewsperse 738T @ 125OF ..................
Drewsperse 74lT Q 125F .................
Drewsperse780f
..........................
DW-875T, Styrene, Acrylic Emulsion ..........
DXE: Xylene; Trace H,SO,; Flake Caustic ......
Dye Plant Water Treatment, pH 2-3 ...........
EDTA ...................................
Electrasolt Detergent ......................
Electronics Plant Waste ....................
Electrostatic Precipitator Fumes, 11%
Carbonate, 3% Sulfate, 1110% Fluorides,
1110% Bicarbonates .....................
Electrostatic Precipitators, S; H,S; SO, ........
Elvaset .................................
Emulsifier, Oil and Grease,
Alkanolamide Type ................
EP52.A85t .........................
Epichlorohydrin ................
Epoxidized Soybean Oil ..........
Epoxy Spray Liner, Water Reducible
0 120F (PPG Industries) ......
Eptamt, Herbicide ..............
Erional NWf
..................
Esters, Fatty Acid ..............

+~eelist

of

trademarks and productnames

CONCENTRATION %

72~25

HETAON
92/99P

HETRON
72119711971

AROPOL
7240/7430 SERIES

HETAON
700170lc

7.2

120/-

120
100

1201120
_

30
100

go
NR

NR

120
_

NR

NR

NR

NR

NW00

NR

150

120/150

NR
-

NR
-

7:14:26:51

100

NPJ-/NR

100
36:63:1
100 @ 75F
50
4

NR
-

100
LSILSINR
--lLS65/NR
NR
65.60
130
--ILSBO/NR
--lLSWNR

120/NRINR

60
36:63:1

NRI-

up to 16
100
100

NRI-/NR
-

NR
-

NR

150
NR
_

120
NR

NR
_

16a120

160

120

120

120

1504160
120/-

100

100
-

100
-

100
-

100 @ 75F
100
1GfJ
100
100

NR
160
-

1M)
-

120
100

100

100
125

100

125
125

-/NR
NR

125
-

125

100
100
1 to 10 Dilutmn

lW/-

14 ozlgal

&I

140
AMB
-

NR
-

NR
_
-

5.3 ozlga1
1W

210
120

125
1601140
-

125
200
_

120/150
NR
60/120
60/120

100
loO/_
2101220
NW120

100

100
100
100

NR
-

AM0
120
100

NR
NR
-

15X-

150
-

150

65:10:4:1
All
1W

100
100
100
1CO
100
@ to 165-F

60

601150
_
1501160
2101220
-

NR/-

NR

125
125

125
125

125
125

SAT

LS/NR

SAT

SAT
SAT

LSlNR
LS/NR

125

125
-

SAT
SAT
125

100

5050

HETAON
920 SERIES/980

NR/-

36
5

100
1M)

100
100

60
NR
180
AMB
-

165
260/260/100

NR
-

NR
-

_
-

AMB
-

AMB

165
_

185/k
-

100

loo/-

AMBI-

1001100

120

AM8
-

AM0
-

120
AMB
-

125

150
AM0

NR
1201150

NR

COilC
1Cil

120
AMB

NR
_

NR
-

NPJ-

AMB

AMB!-

loo

120

1801150

180

160

(continued)

..........................
...
,,,:::
:::
...
.............

194

Corrosion

TABLE

1.54:

Resistant

POLYESTER

Materials

Handbook

AND VINYL

ESTER RESINS-ASHLAND

(continued)

SERVICE
CONCEN.
TRATION

CHEMICAL
ENVIRONMENT

........
Fertilizer Scrubbing
Fertilizer Solullon ...................
Fertilizer Solution ..................
Fertilizer Solution, Nitrogen ...........
Fire Retardant Liquld (Osmose Co:) ........
Fish 011 and Meal Exhaust Gas ..............
Flsh Tanks ..............................
Flxlng Baths. Phologrrphy .................
Floor Wax Polymers .......................
Flue Gas @ 26&34O*F ....................
Flue Gas @ 190.280F ...................
Flue Gas, Bohr up to 45oF ................
Flue Gas, Chemical Incinerator ..............
.............
FlurGas,CorlFlredupto350F
Flue Gas, Garbage lnclnrrator ...............
Flue Gas, llog Fuel, Some HCI, pli 3.7-7 .......
Flur Gas, Ruovery Bolla up to 400.F ........
Flur Gas Scrubbing, Ammonia Process .......
Flue Gas, Wet* ...........................
Flue Gasn; Some Sulfuric Acid Fumos.
Abraslvo Clay Partlcl~s ..................
Fluoborlc Acid ...........................
Fluoboric Acid ...........................
Fluoride Salts + HCI ......................
Fluorinated. ChlorlnaI4 Acid Organlcs
N@utralizad Wlth Limo. Effluon~ ...........
Fluorlna ................................
Fluodnr Gas ............................
Fluorlnr: Phosphorus Pontoxkte ............
Fluorine Scrubber, Rocovr H,SIF, ...........
Fluomlubos~, Ollr and Gnasoa .............
Fluoslllck Acid ..........................
Fluosiliclc Acid ..........................
Fluoslliclc Acld ..........................
Fluoslllclc Acid ..........................
Fluosillclc Acid Furnn, Wop ................
Fluowlfonk
Acid .........................
Fly

ASJl Sluny

............................

Formaldahydo ............................
Formaldohydo ............................
Formaldohydo ............................
FormaldrhydeO
150F ....................
Formaldehyde. Phenol, Sulfuric Fumos .......
Forrnsmlde ..............................
Formk: Acetlc Acids ......................
Formic Acid .............................
Formic Acid* .............................
Formic Acid .............................
Formic Acid .............................
Formic Acid 60%, Satd with NACI:
Unknown Organlcs ......................
Formic Acid Vapor ........................
Fourdrinier Drying Section Fumrs ...........
Fourdrlnier Liquor ..........................
Freon II .................................
Fruit Julus
.............................
Fuel Oil, No. 1 and No. 2 ....................
Fuel Oil, Naval, ML-F-669A .................
Fumigant, Sol1 ............................
Fumigants ...............................
Fungicide, Phsnate Based ..................
Fungus, 95% Relative Humidity MIL E4272C
Aspergillus Flavus (lCl636) ................
Chaelomlum Globosum (6205) .............
Memenoniella Echinata (9597) .............
Ponicllllum Cltrinum (9649) ................
Furfural .................................
Furfural ..................................
Furtural ..................................
Furturyi Alcohol ...........................
Furnace Oil ...............................
nAROPOL
2 vol.

H,O.

7343 SStr~lSclOy.

: SO,, 0.25: SO,. 0.03; CO,

76. I/y ash. 5.0 9rrms

12.5: NI. 74.6. 0,. 4.9:

w. nlocrry60 IPS

VoI. I SO,. 0.25: SO, 0.003. CO,. 12.5. N1. 74 6. 0,. 4.9.
H.O. 76 t/v ash. 1.2 WW7U I?: YCIOCI~Y 8 IDS

HETROW
92l99P

6.6.6

15w-

10340
26

5oL

16

TEMPERATURE,

HETRON
7U1971197A

F FOR RESIN

AROPOL
7240 1430 SERIES

801

w-

@Q

175

175/-

175
-

AMB
-

60

80

160

160

160
-

180
180
-

10
Sald

BPil6O
-rw

3O:10

100 @ 75-F
im

3m13m/SATISATINR
lea
155
SATISATINR
125

BP

Nix-

AMBI-

NPJ-

LSlSY-

NR
-

1%X251-

NW-

to 25
2x37

xx)
--190

5052
37M

-l9O

--190

lx)
NR
AMB
2m

AMB

150
1M

NR
-

AMB
-

100

NR

150
-

i 50~2m
-

AMB

50

AMB

100

NR

15c1
SAT

AMB

NR
-

im*iLs
-

imks

200

15&W

150

140

1201NR
NR

150

160
120

AMB
-

120
-

100.
im

1m

13OiW

130

17W17YNWNWAMBJw86/-

86/-

mlAMB

170
175
NR

AMB
17w130

AMB
-

NW-

NR

NR

125

125

66

86

66
66

66
66

66
AMB

66

100
-

120
-

125

lx)/150

NR
-

NR
AM&-

rrO. 72% S0,5% O/12%


C0,70%
N,ll3 4% H,O; 5 pm7WlP
2.3&X7 burn HQ 1020 Pam HF. rus, 14h?1
t!See list of trademarks

75
-

10

50100
im

loOi-

120

Gnlc.

AMB
-

194

300
im

801120
1m

194/-

100

COW.

AMBJNR
-

40

5350

loo

1x1

im200
AMB

150~1rn
AMB

1501120
AMB

10:10

25

2101220
16012rn
-

NFU-

im

160
120
-

twi-

700

S&d

NPJ-

160

10

SATiNR
-

160
AMB

NR

10

NR
-

NR
-

-IAMB

@ 200-F

65

35

Unknown

NR

25

1751-

NWNRI-

105
-

160
180

AMB

im

12on50
_

NR
NR
-

120140

10

im @ 80-F

HETAOW
920 SERIES/990

NR

lx)

1.5:1.5

100

SATlSATlNR
SATISATINR
SAT/SAT/NR

TYPES

HETRON
7001700c

and product

lm/wO
NR
01 1.2%

H,SC-.

names

(continued)

Synthetic Resins and Polymers

TABLE 1.54:

POLYESTER

AND VINYL

ESTER RESINS-ASHLAND
CONCEN.
TRATION %

CHEMICAL
ENVIRONMENT
Fusion 12.62t Q 175OF ....................
G.61T ..................................
Gallic Acid
........................
Gallotannin ...........
.... .............
Galvanizing Line Fumes .................
Garbage Incinerator Fumes .................
Garbage Incinerator Water Scrubber .........
Gas Oil. Dirty, Refinery .....................
Gasohol; 91.6% Unleaded: 6.2% Ethanol ......
Gasohol; 93.6% Unleaded: 6.4% Ethanol ......
Gasoline ................................
Gasoline, Aviation ........................
Gasoline: Benzene ........................
Gasoline Components .....................
Gasoline, Ethyl ...........................
Gaaollne, Lead Free .......................
Gasoline, Martna ........................
Gaaollna. MS-08 ........................
GelstIne; ...........................
Geothermal Water ...................
Gamtlcidal Detergents ................
Geyser Water, Condensate ............
Glass Cleaner, Fortified with NH,
(Spartan Chemical Co.) ..............
Globrita 15T .........................
Globrite X2tMT ......................
Gluconic Acid .......................
Glucose ............................
Glycerin Still Talllnga with Small Amount
Sulfuric to 330F ...................
Glycerine ...........................
Glycerine in Salt Satd. Water ..........
Glycerol Dibromohydrln; Small Amount
Tribromopropane & Brominated
Organic8 .........................
Glycol..............................
Glycollc Acid ........................
Glycollc Acid ........................
Glyoxal ............................
Glyoxylic Acid @ 215OF ...............
Glyoxylic Acid: SO, @ 215OF ...........
Gold Pickling, Sulhuic ................
Gold Plating, pH 4.4 ..................
Gold Plating Solution (23% Potassium
Farrocyanide with Potassium Gold
Cyanide and Sodlum Cyanide), .......
Gold Smelting Furnace Gas and
Dust.Wetupto4CxYF
...............
Golden.GloT ..............................
Golf Ball ScouringCleaning Solution ..........
Green Liquor .........................
Gypsum Slurry + 1% H,PO,, + Trace HF
Gypsum Slurry Cooler (Fertilizer Plant) .....
HalsoSSt .............................
Hard Chrome Plating Baths ..............
HAS (Hydroxylammonium Acid Sulfate):
Sulfurlc: Water ......................
HAS (Hydroxylammonlum Acid Sulfate):
Sulfuric: Water ......................
HCI: Methylimlno Ether. Methanol:
Isobutyronitrile: Impurities .............
Heating Oil ...........................
Helium, Liquid .........................
Heptana, Dissolved Heavy Organics. Traces
H,O, ZNCI,, HCI .60% Methanol, H,O, HCI,
ZNCI,, Organics .2 Phases .............
Heptane, normal .......................
Heptane, Traces Water, HCI; Other
Heavy Organic8 ......................
Haptane, Vapor & Condensate ...........
Herbiclda, Liquid* ......................
Herbicide Powder & Fumes ..............
Hexachlorocyclopentadiene
.............
Haxachlorocyclopentadiana,
Crude .......
Hexachlorocyclopentadiana;
High Purity ...
tSee hst ottrademarks and

100
Sat'd

(continued)

SERVICETEMPERATURE.FFOR

I
HETRON'
92/99P
NR
-

HETRON
7211971197A
NR
125

100
-

60
200

200
160

60
-

194/l%
1751-

194

100
100
SO:10
-

160
-

175
AM6
_

AROWL
7240/7430 SERIES

RESINTYPES
HETAON
7001700c

NR
-

NR
_

AMBI-

1W'YNR

NR
-

100

100

100

100

100
160

16011CQ

1601150

100

100

100

125
160

125
1601150

1M)
100

-020
160

100
70

200
-

12Y125/-

200
7C-240

160/150
-

100 @ 60.12O'F

All
35

250/-

250125012w
140

16Oll50
14011x)

70100
40
25
25:Sat'd
25
-

140
120

NR
160
-

NR
220/200

loo/160/lOOI100/125
210/220
NPJ2101220

NW200
16012cC

103
-

120
-

NW-

NR

NFU-

NR

NR
NR

LS'INR
LS"NR

80
Ls/LSi-

150
-

lW/-

150
125i-

150
_

200

200

180/-

NR

NR

NR

100
-

100
-

100
-

loO/-

NR

SATI_
NR
-

NRIAMW-

@2CO'F
-

140
100
-

103
-

1601100
60

100

50
100

AMB
AMBI-

__
-

100

100

C0fh.Z.
-

NR
-

100
-

loOI-

&I
AMBI-I-

HETRON
920 SERIES/980

1301100
1751100

1OO'YNR

100
-

100

195

NRJ-

SATlSATlNR

AMBJlDO

SAT
_

100

NR

100
190
NR
130

NR
-

20:60:20

100

100

11:75:14
23:74:2:0.3:1
100

-/77/HETRON

AMBI-

31 SAT, NO Ve!. to .452"F

140

1M)

AMBi120

2001200/-

206

100

120
-

120
120
100

100
-

60/-

100

w-

2M)
180
90

NR
-

110 10
-

NW-

ZOO/-

2ca150

120
_

NR
-

160
160
-

120
tlO/NR

160

product
names.
(continued)

196

Corrosion Resistant Materials Handbook

TABLE 1.54:

POLYESTER

AND VII

L ESTER RESII

;-ASHLAND

(continued)

SERVICE TEMPERATURE, OF FOR RESIN TYPES


CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Hexachlorocyclopentadlene; Reg. & High


Purity Wet With H,O .....................
HexachloroendomethyleneTetra.
hydrophthalic Anhydride, Wet .............
Hexamethylenetetramine
..................
Hexane .................................
Hexylene Glycol Ammonium Chloride ........
High Purity Water, 1.5 pmhdcm. .............
Hog Fuel Flue Gases, Some HCI, pH 3.707 .....
Huff, Misrourf, Okla. or Texas .............
Humid Air, Trace Sulfur Fumes ............
Humid Atmosphere ........................
Hydraulic Fluid, Skydrol SWT ...............
Hydrazine ...............................
Hydrazine ...............
...............
Hydrfodlc Acid ...........................
Hydrobromlc Acid .........................
Hydrobromlc Acid .........................
Hydrobromic Acid .........................
Hydrobromic Acid: Copper
Oxide: Bromine .........................
Hydrobromlc Fumes Q 290F ...............
Hydrocarbon Alkylation ....................
Hydrocarbon With About 10% Acetic
Acid, Liquor and Vapor ...................
Hydrocarbons: Ferric Chloride Mist ..........
Hydrochlorfc Acid ........................
Hydrochloric AcIda ........................
Hydrochlorfc Acid ........................
Hydrochlortc Acid ........................
Hydrochloric Acid ........................
Hydrochloric Acida ........................
Hydrochloric Acid ........................
Hydrochloric Acid ........................
Hydrochloric: Amine Q 2oOF ..............
Hydrochloric: Ammonium Thlocyanate .......
Hydrcohlorlc Acid (12%) + Aqueous
Ammonia to pH 0.3 ......................
Hydrochloric Acid, 2o Be: Amine ............
Hydrochloric Acid @ B.P. ...................
Hydrochloric: Brighteners ..................
Hydrochloric: Chlorinated Hydrocarbons ......
Hydrochloric (BZ%):Chlorinatsd Organic
Contaminates (phase separation 213 acid: 113 organic) .....................
Hydrochloric Acid (32%):
Chlorfnated Organlcs ....................
Hydrochloric (32%): Chlorinated Organics:
Trlchloroethylene .......................
Hydrochloric: Cl,; Aromatic Sulfonic
Acid; H,SO. ............................
Hydrochloric Acid, Cl,. Water,
Chlorinated Organics ....................
Hydrochloric Acid: 2, &Dlchloro-4
aniline @ 170F ........................
Hydrochloric: Fluoride Salts .............
Hydrochlortc Acid + Free Cl, ............
Hydrochloric Acid, Fumea @ 22529oOF ....
Hydrochloric: Hydrofluorlc: Nitrate .......
Hydrochloric Acid: Inerts: NoAlkyl Dimethyl
Benzyl Ammonium Chloride: Tributyl Tin
ChloridelEthylene Oxide/Amine .........
Hydrochloric: Methyl lsobutyl Ketone ......
Hydrochloric: Methyl lsobutyl Ketone;
NH,CNS..
..........................
Hydrochloric: Nitric Acid ...............
Hydrochloric: Nitric: Sulluric @ up to 225F
Hydrochloric: Phenol: Aqua Regia .........
Hydrochloric: SW ppm Phenol; Ml ppm
Octyl, Decyl, Butyl, Phosphorous
Chlorides ...........................
Hydrochloric Acid: Phenol: Water ........
Hydrochloric: Phosphoric Acids ..........
Hydrochloric: Phosphoric: Butyl Ether .....
Hydrochloric Acid Pickling Tank
Covers & Fumes .....................
Hydrochloric: Silicone Oils ...............
NO change m water at 0.1 It. laminate/gal.
*AROPOL
7530 satmlactory.

HETRON'

92/99P

HETRON
HETAON
AROPOL
727197119711724017430SERIES 700179ac

!3+

90/-

90

100
28

86/80
-

86

80
WI56

_
-

120

80156!1201120

80.156

120/-

100
1OU
100
100 RH

155
9w--/-

200
120
160

120

1M)
10
70

NW-

1058
18

-/160
-/WI
-

25
46
50:5:Trace

100

w2w120

120
LSlSY-

100
NR

NR

NA

NR
_

200

NR
160/100

2001160
ZOO/160

210/220
2M)

1W

150
-

160/100
16W_

AMB
SATlSATlNR

230

16Otl50
180/150

LS200
230/200

230

150

85190
85l90

230
180
150

15OtlOO
125(90
125190

150
150

8Y-

100

lCQ/NR

230
230
230

36
36.37

SAT/SAT/NR
160

Unknown

160
77

98.8:0.2w/w
20
10:30

@ 60-F

88.3:11.7 @ 104F
-

99:1 @ 104F
104-F

Unknown
32

158-203/-

15
20:5

Unknown
Unknown

NW-

tSee

180/-

NR

NR

NRI-

60/60/NR

NPJ-

-/LS/NR

LS/NR

LS/NR
-

LSI-

100
-/156-203JNR

loo/-

203
2lot210/-

NR
-

NRI-

200
-/SAT/NR

100
NR

NRt-

21

SATI-

60

30

150
100
-

NR

100

15:100

NR

160

23:77:0.1:0.1

180
_

2101220
2101220
210/220
2101220

120
2al/-

77:13:10

6 Mola~lWO:10
Conc:0.5:0.5

SATiNR
-

160.220/-

80

10:30
All

120
-

25

37
10:20:70

150
1501120
140/LSAMB/NR

37.5
1.1:z.g

68.1:0.9:14@

-iEa-

15
20
32

20
1501180
_

10

100
120/-

120
-

120

Unknown
1.5

as !n 2~3O.LWO gat. tank

AMBVNR
-

80

130100
-

200
200

Unknown

32:<5

HETAON
920 SERIES/990

120
120
-00

215/195

list of trademarks

NR
-

NR

NRI-

and product names

(continued)

Synthetic

TABLE

1.54:

POLYESTER

;-ASHLAND
CONCEN.
TRATION %

Hydrochloric: Sulfuric .........


Hydrochloric: Sulfurk: Antimony Trioxide ......
Hydrochloric: Sulfuric: Nitric
Hydrochloric: Teraphthalk Acid: DImethyl
Formamida: Water
Hydrochlork Acid, Trace Phanol; &yl,
Decyl. Butyl Chlorldor 6 Phosphorous
Trichlortde .............................
Hydrochlork (aqueous) + Organic Solvents ....
.....
Hydrochloric wlth 2 6 Dlchlor4nltroanlllnr
Hydrochloric, 10% by volume with Ferrk
and Ferrous Chlorides, pH 1 ..............
Hydrochloric, Satd. Ferrous Chloride .........
Hydrochloric. Small Amount Acetone ..........
Hydrochloric, Traca Organks ................
Hydrochlork. Traca Phenol and
Cresylic Acid @ 175*F ....................
Hydrochlork, Trrca Toluena 6 Chlorotoluene ...
Hydrcchlork Trfmathylamlno ................
Hydrochloric,
60% by Vol.: Hydrofluork,
20% by Wt.: Sulfuric, 29% by Wt.:
Sodium Dlchromate, 3% by Wt.a ............
Hydrocyanlc Acid ..........................
Hydrolluork Acid ..........................
Hydrofluoric Acid ..........................
tfydrofluork Acid ..........................
Hydrofluoric Acid ..........................
Hydrolluorlc Acid @ 195-F ..................
Hydrofluork Acid Q 195.F ..................
Hydrofluork Acid ..........................
Hydrofluork Acid @ 1WoF ... ..............
Hydrofluork: Chlorfne: Nitric Oxide Fumes .....
Hydrofluorlc: Chromic: Nitric Aclds ...........
Hydrolluork. 49%: Glacial Acat!c: 70% Nltrk ...
Hydrofluork, 49%: Glacial Awtic: 70% Nltrk ...
Hydrolluork: Hydrochlorfe Nltrfc ............
Hydrofluork, 20% by Wt.: Hydrochloric,
80% by Vd.: Sulfurk, 29% by Wt:
Sodium Dkhromato, 3% by Wt. ............
Hydrofluork Actd: Nltrk ....................
Hydrolluorlc Acid: Nltrfc ....................
Hydrofluorlc Acid: Nltrlc ....................
Hydrofluork: Nltrlc Acids ....................
Hydrofluoric: Nitric Acids ....................
Hydrofluork: Nitric Acids ....................
Hydrofluorlc: Nltrk Pkkllng .................
Hydrofluoric: Nltrk Pkkllng Solutfon .........
Hydrofluoric: Phosphork: Chromic ...........
Hydrolluork: Phosphork: Chromic ...........
Hydrofluork Acid: Stannous Fluorfde ..........
Hydrofluosillcic Acid .......................
Hydrofluosilicic Acid] ... ...................
Hydrogen .....
...........................
Hydrogen Bromide, Dry .....................
Hydrogen Bromide, Wet .....................
Hydrogen Chloride .........................
Hydrogen Chlorfdr, Absorber ................
Hydrogen Chlorfdo, Anhydrous ...............
Hydrogen Chloride and Benzene Vapors .......
Hydrogen Chlorldo: Chlorfne Saturated with
Trtrachlorocyclopentano,
Ccl., Trace
..................
Hexachlorocyclopentane
Hydrogen Chloride, Cl,, CO,, CO, H,,
N,, 0, ..................................
Hydrogen Chloride Fumos @ 350F ...........
Hydrogen Chlorfde Gas: Chlorine @ 392-F .....
Hydrogen Chloride Gas, Dry .................
Hydrogen Chlorlda Gas, Wet .................
Hydrogen Chloride. Steam ..................
Hydrogen Fluorfde, Cl .. Nltrk Oxide Fumes ....
Hydrogen Fluoride, Vapor ...................
Hydrogen Fluoride, Wet ....................
Hydrogen Fluoride. Wet ....................
Hydrogen Iodide: Iodine Vapor ...............
Hydrogen Iodide: Sulfuric ...................
.........................
Hydrogen: Ozone
.......
Hydrogen Peroxide ...........

fSee1st01trademarks

HETRON
92199P

1445

15355
302010

37
@ 194F

Unknown

TEMPERATURE.

HETRON
7tlPlI19lA

OF FOR RESIN

uomt
72407430 SERIES

1W

80

NR

170

15

NFL-

36

32

NW-

2s-30
37:1W

170

LSJLSINR

1201-

NR

NFU-

80

SO

LYNR

120

BM @ BP
10

2w
NFUNW-

2W
NR
NR

100

AMB

15

loo

20

NR

22
40
15
Unknown.

Hot

SAT

3-6:2
1:2:5 @ IlOF
1:X8 @ 1WF

90
SATlSATlNR
SATlSATlNR
AMB
--I-/LS
-

NPJ-

80
NR

NRI-

NR

13.77:10

120
240/240/-

140
130

5M @ BP

HETRON
920 SEAIESPBO

NR

32

Satd

TYPES

HETRON
7001700c

140
loo
90

28 14:7:51

197

(continued)

SERVICE

CHEMICAL
ENVIRONMENT

Resins and Polymers

lWNR
NR

200
NR
NR

1OChNR

1w

wNR
NR
NR
NR
-

lM/NR
NR

93

153
1w

100
LYNR
NR

LYNR

--ILS
NR
-

loo

SAT

loo

120
515
2.57.5
23:20
24:12 Q BOF

165
165

NRI-

135
NR
-

4.15 @ 190-F
5:50 @ 120-F
Unknown

NFU-

3.520
24017
11%.59.3
X1:50 @ 220-F
10
35
1W
100

NR
HOI

@ 210212F
36
100

NR

NR

NR

NR
NR
lOY-

NR
NR
lOY-

105
loo
1w

loo
NR

180

loo/-

15o/lW

150

1M)

NR

250
90

250
-

AMB
-

100
-

AMB

180

AMB
NR

l&I
-

NR

100
Cont.

250

23yz?Y-

NR

250

AMB

NR
-

85

65.35

125

Unknown

AMB
SATlSATlNR

Ul-lknOWn

SATISATINR

100
100
Unknown

120

95

12

90

100

90
150/-

lx)

120

120

120

not
95
l&3
150

IBOIAMB
-

21w2u
21w22u
-

NR
AMB
-

95
-

loo

210

18OiNR

AMB

158

2u)/24w-

Uh-lOW~
35

66 BP1 25 gPl
-

18012w
AMB
150

and product names

(continued)

798

Corrosion Resistant Materials Handbook

TABLE

1.54:

POLYESTER

AND

VII

L ESTER

RESI

j-ASHLAND

(continued)

SERVICETEMPERATURE.'F

CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Hydrogen Peroxide ...........


.......
Hydrogen
Peroxide ....................
Hydrogen
Peroxide .....................
Hydrogen Peroxide: Sulfuric:
ZnSO,:NA,S:O,
.............
........
Hydrogen
Peroxlde, Vapor 6 Condensete ......
Hydnqen Peroxide Vapon .................
Hydrogen Sulfide .........................
Hydroxyrcetic Acid .......................
Hydroxyecetlc
Acid .......................
Hydroxyrcetlc: Phosphoric: Sullurlc Acids ....
Hydroxylrmlne
Acid Sulfate (Hydroxyl.
ammonium Acid Sulfate) ................
Hydroxylrmine Acid Sulfate: Sulfurtc .........
Hydroxylrmmonlum Acid Sullate
(Hydroxylamlne Acid Sultrto) ..............
Hydroxylrmmonium ACM Sulfato:
Proplonic Acid: Weter .....................
Hydroxylrmmonlum Actd Sulfate: Sulhrrk ......
Hydroxylrmmonlum Acid Sullrte:
Sulturic Watep ..........................
Hydroxylrmmonium Acid Sulfete:
Sulfuric Watep ..........................
Hypochlorour Acid .........................
Hypochlorous Acid .........................
Hypochlorour ACM .........................
Hypophoephortc Acid .......................
Hypophorphorour Acid .....................
l9eprlCO-B39t
..........................
Ilmenite On: Sulfurlh SteernAb
Agitation Q 220F .......................
Iminoethyl Alcohol .........................
Incinerator, Chemical ......................
Incmerrtor,Gerbege.
Fumes .................
Incinerator Water Scrubber ..................
lodlne:
Hydrogen lodlde Vapor ...............
IodlneKeroeoneBrtne
......................
lodlne Vapor ..............................
lqjarol DAt ...............................
Iron Porchlortdo ...........................
Iron Perchloride ...........................
Iron PlotIn Solution 45% FOCI,; 15% C&I,;
29% FeSO.; 11%; (NH.),SO. ...............
Iron and Steel CleanIn Bath, 9%
Hydrochloric; 23% Sulluric ...............
lrobutyl Alcohol ...........................
lrocunt
399 ..............................
lsocuret 399 ..............................
Irocuret 999 ..............................
Ieocyanrte, Polymethykne Potyphoqt ........
IsoDecrnol
...............................
Isoprep 33t ..............................
Isoprep Ut ...............................
Isopropyl Alcohol .......................
._
Isopropyl Alcohol ..........................
Isopropyl Alcohol: Sodium Xyhne Sultrte:
OPhonytphmol: Potrulum Rlclnoteata
Inertr ..................................
lropropyl Amine ...........................
Isopropyl PaImItate ........................
ltrconic Acid ..............................
Itaconic Acid ..............................
Jet Fuel A ................................
Jet Fuel (JP.4) ............................
Jet Fuel PFB ..............................
JM.23E.t Adhe8lvo ..........................
JM.27lt Adhoslvo ..........................
JP.9 Fuel .................................
JP.10 Fuel ................................
Kaolin Slurry ..............................
Kerosene .................................
Kerosene, 70%, 10% Irodecanol. 29%
organicr: 39% Phosphoric .................
Kerosene: Vapor & Condenrate ...............
Kerosene: Xylene: 85% Phosphoric ...........
Knofler Fumes ..........................
Kymenet,Resin
tSee

Solution

1151of Irademarks

..................

and oroducl

names

30
35
50

HETROII'
92199P

HETRON
72/197:19lA

FOR

AROPOL
724017430
SERIES

105/120
loO'/-

1051105iNR
loo':lm/-

Nfi

RESINTYPES
"ETRON
7001700c

AMB
NR

100

120
140

All

250

253

35
70
29:51:20

140

140
100

140
-

140
-

2.15.Trac.a
5
50

12W-

go

6%1:10

Gmc.
50
50

100
Flue ge.s

100

100

160

100

100
104
AM0

104
AMB

104
AMBlNR

AMB

AMB

AhlB/NR

AMB
AMB
-

loo
AMB

105
NR"/-

110
300X0160
160

150

150
120

1751180
-

175

AMB

AMB

-ia

lR10&6%7

10

AMB'

AMB'

AMB

AMBI-

AMB
AMB
-

AMB
AMB

AMB

AM&AM&-

120
160/-

NR

1651150
NR

165

15&156l-

601NR

lW156l-

13ol60

-/lBO
95

160
AMB
AMB

80

100
100
im

17Y120

175

100

120

120
103

150

160
90

6OiloO
80:100

imi16O/-

160/150
AM&-

100
100
-

150160
16511601-

100/120

100

100
-

3&w

AMB

100

AMBI-

33:33:35

2001-

AMB

100/120

150
-

10

25

50z@l
lOoz/gal

im
im

AMBI-

14CV-

All

100

AMB

160

100
im
100
100

1M
120

115

160

All

175

-I140

20

100
3&401(>20

2 101220
-

212

x):60:20
10
20

210 -

Bwao:10
11:75:14

1x
LS:6of-

24Y24y212
125

S&d:70
go

HETRON
920 SERIES'980

100

100
80
eel00
16Oll50

22ol125
125
AMB
-

im
100

2101220
1201210
1201210
120
-

loo/imi-

150

150

(continued)

Synthetic Resins and Polymers

TABLE

1.54:

POLYESTER

AND VIN

L ESTER RESIP

-ASHLAND

199

(continued)

SERVICE TEMPERATURE, OF FOR RESIN TYPES


CHEMICAL
ENVIRONMENT
Lactic Acid
..............................
Lactic: Citric Acids .........................
Lasso ECT ...............................
Lasso ECT ................................
Lassot Herbicide ........................
Latex, Acrylic .............................
Latex Dispersion in Water ...................
Latex, Rubber .............................
Latex,Vlnyl ...............................
Laurie Acid ...............................
LauriclMyristic Monoethanolamide:
Sodium Xylene Sulfonato Solution ..........

CONCENTRATION %

HETRON'
92/99P

All

200
-

Sat'd
lOO@ 140-F
100
1 to 10 Dllutlon
All

62
All

LaurylAlcohol .............................
Lauryl Chloride ............................
Lauryl Chloride, Crude, Acidic ................
Lauryl Mercaptan ..........................
Lauryl Pyrldinium Chloride ...................

Lead Acetate ..............................


Lead Chloride .............................
Lead Nitrate ..............................
Lead Plating, Acid: Fluobortc, Boric Acids* .....
Lead Plating, Alkaline, Pb (C&&O),, NaOH* .....
Lead: S: CuO: FeO: &SO,: Bi,(SO,), Dust .......
Lead Smelter Fumes, Duct ...................
Leather Dyeing & Finishing ..................
Leather Tanning, Drums .....................
Levullnic Acid .............................
Light Gas Cycle Storage .....................
Light Water, FC195T ........................
Light Water, FC203T ........................
Light Water, FCZOgAT .......................
Lignin: Crude Tall Oil: Spent Acid:
Sulfuric, pH3 ............................
Lignosullonate, pH 1.5-2 ....................
Ligno-Sulfonic Acid ........................
Lime Kiln Stack Gases ......................
Lime Neutralization Effluent; Chlorinated
Fluortnated Organica. Chlorlder, Fluortdee,
HCI, HF, H,O ...........................
Lime Slurry ...............................
Lime, Thiosorbic ...........................
Limestone Injectlon, SO, Removal, Fossil Fuel,
Mist After Scrubber, pH 2.12 ...............
Linear Alkylate Sufonates ...................
Linoleic Acid ..............................
Linseed Oil ...............................
Linseed 011, Chlorfnated .....................
Liquid Chlorine ...........................
Lithium Bromide ...........................
Lithium Carbonate3 .........................
Lithium Chloride ..........................
Lithium Chloride ...........................
Lithium Chloride ...........................
Lithium Chloride ...........................
Lithium Chloride: Methyl Alcohol .............
Llthium Hydroxld3 .........................
Lithium Sulfate ............................
Llvestock Spray Base (Shells)z cobalt
di(2-ethyl hexyl) phosphate: tr-mbutyl
phosphate ..............................
Lix54Nt ..................................
LPC .....................................
Machine Oil & Sulphur Fumes ................
Magnesite Mill Spent Liquor .................
Magnesite Recovery Boiler Blow-Down;
Acetic: Sulfuric: Sulfurous: Formic
Acids; Acetone ..........................
Magnestum Bicarbonate ....................
Magnesium Blsulfite .......................
Magnesium Btsulflte Acid Liquor, 5% SO,,
Chlorides, pH 4.55
...................
Magnesium: CakYurn: Sodium
Chloride Solution ........................
Magnesium Carbonate ......................
Magnesium Chloride .......................
Magnesium Chloride, Hexahydrate; Filter Aid;
Activated Carbon ........................

200
160
NR

AROPOL
724017430 SERlES

HETRON
7001700c

1601130

2201200
-

160/130
-

HETRON
920 SERIES/980
2101220
-

NR

NPJ-

120
-

60
_

601100
-

100

100

60

All

Sat'd

160/130

100
103

22Ol200

100
2101220

120'

120

120/-

100

120
212

120
-

1201_

212

120/-

120
155

160

100
100
100
10
All
Sat'd

160
-

Sat'd
25:25:16:10:6:3
-

NW-

100

200
NR

200

SAT

SATI-

SAT
SAT
-

100

160/NRINR

w:10:29:1

100

160/-

Sat'd
-

--@

HETRON
72l1971197A

212-F
-

160

160/AMW-

120
120

120'
120'

200
AM6
300

_
-

160
220/2cil
22OuOo
200
160
-

120
120
2cxl
NR
-

160
150

140

108

100
-

100
-

150/-

COW.

100
All
Sat'd
045
2840
4555
Sat'd
25175
Sat'd
All

65:5:30
100
10
-

Sat'd
All
2:10:12

NWZMI140/160
NW-

203
90
LS55
180

160/-

155

212
-

180

210/220
NWNR
NW-

170
-

_
-

NR
-

-55

.55/2101220

160

150

160
-

2101220
2101220

2101220
-

140/-

HOT
150

21w220
16O/-

2101220
-

140
160

176
115

2101220
210/220

2001150

1601130
-

--/150

170160
-

250/250/265l265i-

170
NR

105
160

Sat'd
Sat'd

160/-

160'

NR
160/130

212/200
180
-

Sat'd
Sat'd

160
220

150
160

160/150

150

220

160/15a

2201200

66

31013101-

2101220

150
210/220

_
_
-

160
160
_
_
160
2101220
-

+See lislollrademarks and Droduct names

(continued)

200

Corrosion

TABLE

1.54:

Resistant

POLYESTER

Materials

AND Vlh

Handbook

_ ESTER RESII

-ASHLAND

(continued)

SERVICE

CHEMICAL
ENVIRONMENT

CONCENTRATION %

Magnesium Chloride, Occasional


HCI Vapors ...........................
Magnesium Chloride: Sodium Chloride:
Calcium Chloride ........................
Magnesium Hydroxide ....................
Magnesium Nitrate .........................
Magnesium Oxide ..........................
Magnesium Oxide Acid Condensate ...........
Magnesium Oxide - Fluoride Mist
and Fumes .............................
Magnesium Sulfate ........................
Magnifloc 509.Ct ..........................
Magnifloc 573Xt
..........................
Magnifloc
E343t ...........................
Maleic Acid ..............................
Maleic Acid ...............................
Maleic Acid, Trace Phthalic,
Fumaric, Benzoic, Quinone ................
Maleic Anhydride ..........................
Malelc Residue ............................
Maleic Residue, > 0.5% Phenol ...............
Malic Acid ................................
Manganese: Ammonium Sulfates, pH5 .........
Manganese: Ammonium Sulfates: Sulfuric pH5
Manganese Sulfate ........................
Manganese Sulfate: Sulfuric .................
Manganese Sulfate: Sulfuric Acid .............
Marine Fouling ............................
Marine Gasoline ...........................
Matart, Germicidal Detergent ................
MEK: DMP: MEK Peroxide ...................
MEK, 100%: Sulfuric Acid, 50% ...............
MEK: Toluene: Steam: Maleic Acid;
Chlorides present ........................
Melamine Resin ..........................
Mercaptan, Aromatic .......................
Mercaptan, Organic, H,S, H,O, Butanol ........
Mercapto-Ethanol ..........................
Mercapto-Ethanol Tall Oil ...................
MercapkkEthanol Tallate ....................
Mercaptopropionic Acid .....................
Mercaptopropionic, Crude Acid ...............
Mercuric Chloride ..........................
Mercurous Chloride ........................
Mercury ..................................
Metal Phosphate Salts ......................
Metal Phosphates, Trace HF.
Hydrofluosilicic .........................
Metal SulfatsSalts: Sulfuric Acid .............
Methacrylic Acid ...........................
Methacrylic Acid ...........................
Methacrylic, Glacial ........................
Methallyl Chloride Q 165OF ..................
Methanamide @ lOOoF .....................
Methanol 60%, H,O Trace, HCI, ZnCI,,
Organic& Heptane, Dissolved Heavy Organlcs,
Traces H,O, HCI, ZnCI,, 2 Phases ...........
Methanol/Nitrogen Oxide Fumes, @ 220F .....
Methyl Acrylamlde .........................
Methyl Alcohol ............................
Methyl Alcohol: Lithium Chloride
Methyl Alcohol: Methyl Chloride:
Hydrochloric ............................
Methyl Alcohol: Turpentine ..................
Methyl Alcohol: Water:
Hydrochloric @ 150F ....................
Methyl Bromide: Ethylene Dlbromide ..........
Methyl Chloride .........
..................
Methyl Chloroform .........................
Methyl Ethyl Ketone ........................
Methyl Ethyl Ketone Q 120F ................
Methyl Ethyl Ketone: Dimethyl Phthalate:
MEK Peroxide ...........................
Methyl Ethyl Ketone, Vapor & Condensate ......
Methyl lsobutyl Ketone .....................
Methyl lsobutyl Ketone; 200 gpl Fluorides;
500 gpl Sulfuric Acid& 3 ....................
f See

llsl 01trademarks

and pmduct names

HETRON
92199P

Cont. Q 275F lo
500F at limes

2:12:10

Satd

-I160

Satd
S&d

lW/200

Satd

2iw-

Satd

16

@ 165F
10
13:156 gpl

13:135:40
Satd

gpl

9ozlO
50~~6 (gp0
100
Ccnc.
63:36:1
1o:w

100
100
100
100
100
100
Satd
Satd
100
Satd

NFU125/125/lW/601-

150
160
-

_
-/NR
1601130
-

200
2W
1x)/120/-

1601150
90
%I
90
16o/lW
-

TYPES

HETRON
7001700c

HETRON
920 SERIES.1980

NR
_
200
-

200
200

2101220
_
2101220
160

150
_

NR
-

125

125

125
-

loo

203
1w

60
loo
-/LS-BYNR
60.

60
-

80

65.60
65.60

60
-

60

60/-

_
2101220
-

801-

NR
-

65-W
NR

NR

NR

NR

NR

NR

212

212

1601150

220/2w

2 101220

212
250
-

212
250

1601130
16O/-

22012w
22012w

2101220
-

NRJNRI-

1W

Unknown
48

100
75:25

AMB
-

94:0.4:0.2
o 65: lo 46 @ 150F

93:5:2 Vapor
NRI-

100
100

40/-

100
IW

NRINR
NR/-

NWNRI-

60

NR
-

NR

SATiLS

SATiLS

LS

NR
-

170

901NR
-

1501NR
-

NW120
-

135
-

--INR

NFV-

--/NR
-

80

100
IW

63:36:1
100 Q 120-F

95
125

12Y-

NRI-

@ 75-F

165
NR

100 @ 145-F
10

loo

150
_

30
24:10

3070

F FOR RESIN

AROPOL
724017430 SERIES

154u120

100
-

TEMPERATURE,

HETRON
721197/197A

135
NR
loo
90
--ILS/NR
SAT

140
90
125

-/LS/NR
NR
40
60
NR
NR
--/LS-65/NR
-

NR
NR

NR
NR

NR
NR

-/NR
-

NR
-

50

NR

NR

NR

60

(continued)

Synthetic Resins and Polymers

TABLE 1.54:

POLYESTER

AND VI

L ESTER RESI

;-ASHLAND

(continued)

SERVICE

CONCEN.
TRATION %

CHEMICAL
ENVIRONMENT
Methyl Isobutyl Ketone; 300 gpl Fluorides;
40 gpl Hydrofluoric Acida
............
Methyl lsobutyl Ketone: Hydrochloric Acid
Methyl Methrcrylrte
.......
........
......
Methyl Parathion
Methyl Phenol Fume;. : : 1..........
: : 11: : :
Methyl Styrene ..........................
Msthylene Blsthiocyanrtr, Polychlorophenol
Blend @ 125-F..
......................
Methylene Chloride .......................
Methylene Chloride: Chlororcetic Acid .......
Methylone Chloride: Chlorotorm: Carbon
Tetrachlorlde, Small Amount Methyl
Chloride, H,O, HCI .....................
Methylene Chloride Distillate Bottoms;
High Caustic, Water, to 212-F ............
Methylene Chiortde: Ethyl Acetate:
Caustic, 50% ..........................
Methylene Chloride: Toluene ...............
Methylene Chloride: Toluene: Xylene:
MEK 6 MIBK: Benrenes: TCE: Ccl, ........
Methylene Succinlc Acid ..................
Methylimino Ether Methanol:
Isobutyronitrile: HCI: Imputities ..........
Methylisobutyl Ketone: Cyanc+acetic; 0.8
Sulfuric in Saturated Sodium Chlortde
@ lOOoF .............................
Methylol Acrylamlde ......................
Milk & Milk Products ......................
Milk Wsgon Cleaner ......................
Milk Waste
.............................
Mineral Oils
..........................
Mineral Wool Slurry ......................
Moisture ...............................
Molten Salt .............................
Mortal 6 Nickel Cleaning Baths; HCI, CuC4 ...
Monel 6 Nkkel Cleaning Bathr;
HCI, Fh(SOJ, ..........................
Monochloroacetic Add ...................
Monochloroaoetk ACM ....................
Monochlororcetic Acid ....................
Monochlorobenzeno .......................
Monoethrnolamine
.......................
Monoethenolamine: Butyl Cellosolve
Film Stripper @ 138OF ...................
Monc+thrnolrmlne Dosulturtzlng SO .. H.S ....
Monohydroxysuccinic Acid .................
Monosodlum Phosphate, pH l-3 .............
Morphollnr ..............................
Morphollne @ 1zOF ......................
Motor Oil
............................
MS.08 Gasoline
..........................
Mulsollnr 6WOt ..........................
Murirtic Acid .............................
Mustsrd (3% Sodium Chloride, 5%
Acetic Add) ............................
Myrlstic Acid ............................
MyristlclLaurk Moncethrnolrmidez Sodium
Xylene Sullonate Sotution ................
Naphtha .................................
Naphthrlene .............................
Naphthenic Acid ..........................
Naphthoquinone. 1,4 ......................
Naphthoquinone (scrubbing with water) .......
Naphthylamine Sullonic Acid ...............
Neodol253St
............................
Neopentyl Glycol .........................
Nickel Anolyte Llquor (Into Metsls) ...........
Nickel, Bright . . . . .
..
Nickel Chlortde: Nickel Sulfate: Boric Acid . .
Nickel Chloride
NickeCCobalt + Solvent Extraction Circuit;
pti 1.8~4.5.0.31.5gpl fluorides
Nickel Electrolyte. Purified (Into Metals)
Nickel 6 Monel Cleaning Bath; HCI, CuCI,
Nickel & Monel Cleaning Bath; HCI, Fe,(SO.),
tSee 161of trademarks and voduct

names

10015
1W

HETRON
92199P

158203/-

@Zt75F

TEMPERATURE,

HETRON
72.1971197A

60
--115&203/NR
-

100
100

NRI-

100

201

80
NR
--ILSINR
NR
-

*F FOR RESIN

AROPOL
7240 7430 SERIES

TYPES

HETRON
700,700c

HETROH
920 SERBS990

NR

NR
-

NR
-

NR

NR

NR

NR

SATINR
NR

SAT
NR
-

NR
NR-

NR

NR

NW-

NR-

100

NR

9x5

NR

65.39:s

NR

NR

NR

NR

NR

NR

NFU-

83:16:1

NR

NR

NR
-

NR

NR-

rw

-l771-

LSSAT
-Mio
-

AMB

90
AM0

WM
33:39:9:2:36:,
25
74:2:0.3:23:1

603
46
-

Acid

ltW150

100
Unknown
loo RH
Splash

h Spills

50
80 @ 1WF
100 0 145-F
100

AMBll&l
AMB
Hetron@ 197.3 wth
120

7w-

NWNWNR

loo

120

lt3oll5c
filler satisfactory
-

AM%

80
_
220iAMB
for a@tated tank

ao/1801200:2 10
Amblenl

750

180

l&l
AMB
NR

NR

NR
NR

NR
NR

NR

NR

NR

NR75

AM8

NR

AM0

NPJAMB

NRINPJ-

30:57

NR

NR

NR

NR

NW-

loo

NR
-

NR

NR

NR

NFU-

NR
-

NR
_

10
510
10
1w
loo

95
203
100

NR
-

NR
AM&-I-

150

See Hydrochloric

1W

100

200
4MB1130

21 o/220
120
200

180/150

AMB

1501120

Satd
150
150

Satd
Unknown
Satd

1w
w
81 Nl etc.

loBi-

;ia*

1801-

120
1%
180
-

120/18012w
1BOiZW
-

120

150
lW/-

180
180

12:53% ozlgal
Satd

NRI2101220
-

Acid

lWAll

220

220

1801150

22012w

2101220

185

180

140/-

180

(continued)

202

Corrosion

TABLE 1.54:

Resistant

POLYESTER

Materials

AND VIF

Handbook

L ESTER RESI

;-ASHLAND

(continued)

SERVICE

CHEMICAL
ENVIRONMENT
Nickel Nitrate
::
Nickal Plating; Electrorafining pH 1.5
Nickel Plating (Nickel Sulfamate:
Magnesium Chloride: Boric Acid) pH 3.7
Nickel Plating Solution (11% Nickel Sulfate:
2% Nickel Chloride: 1% Eorlc Acid) .......
Nickel Plating Solution (44% Nickel Sulfate,
4% Ammonium Chloride: 4% Bortc Acid)
Nickel Soap Catalyrt .......................
Nickel Sulfate .............................
Nickel Sullate: Nickel Chloride: Boric Acid .....
Nickel Sulfate: Nickel Chloride: Boric
Acid: Brightener (Nickel Plating) ...........
Nitrating Acid Spent ...................
Nitrating Acid, Strong ....................
Nitration, Spent Acid .......................
Nitric Acid ................................
NitricAcid ................................
Nitric Acid ................................
Nitric Acid ................................
Nitric Acid .......................
Nitric Acid ...............................
Nitric Acid ..............................
Nitric Acid .............................
Nitric: Amchem 616f ......................
Nltrlc Acid: Copper Salts ....................
Nltrlc:
Copper Salta ........................
Nitric, 70%: Glacial Acetic: 49% Hydrolluodc .
Nitric. 70%: Glacial Acotlc: Is% Hydrofluoric
Nitric: Hydrochlork ........................
Nitric: Hydrochloric Acids .................
Nitric: Hydrochloric: Hydrofiuorlc ..........
Nitric: Hydrofluoric ........................
Nitric: Hydrofluorlc ........................
Nitric: Hydrofluorlc Acids ...................
Nit&: Hydrofluorfc AcIda ...................
Nltrfc: Hydrofluortc Acldr ...................
Nltrlc: Hydrofluorlc Acids ...................
Nitric: Hydrofluorlc: Chromic Aclds ...........
Nltrfc: fiydrofluorlc Pickllng sdutton .........
Nitric: Hydrofluorlc Vapors ..................
Nitrfc Acid: Phosphoric .....................
Nitric (34%): Phosphoric (65%) ...............
Nitrtc: Phorphortc: Sulfuric:
Nonionic Surfactant .....................
Nitric: Sodium Dlchromato ...................
Nitric: Sodlum Dlchromate: Mqfybdlc Acid:
.......................
Water @ 13DlWF
Nltrlc: Sulfuric @ 210F .....................
Nitric: Sulfuric: Cbpfmr Saltr .................
Nitric: SulfurlcDlnitro-Toluene
Fumes .........
Nitric: Sulfuric: HCI @ up to 226OF ............
_.
Nitric: Sulfuric: Hydrochloric: Water ........
Nitric: Sulfuric: Hydrochloric .................
Nitric: Sulfuric: Na dichromate: Cr,(SOJ, .......
Nitric: Sulfuric 6&50 ........................
Nitric: Sulfuric: Water .......................
Nltrlc Acid Vapor ...........................
Nitric Acid Vapor ...........................
Nltrfc Acid Vapor ...........................
Nitric Acid Vapor ...........................
Nitric Acid Vapor ...........................
Nitric Acid. Vapor 6 Condonsato ..............
Nitric Acid: Wettlng Agent ...................
NitricAmmonia Fumra .....................
Nltrtc, Gone.; Sulfurfc. Cont. .................
Nltrfc Oxldo, Cl,, HF Furnor .................
Nitric Oxldr. Chlortnr. Hydrofluorlc Fumes .....
Nltrfc, Rod Fuming .........................
Nltrlc. 70%: Sulfurk. 70% Pickling Acid ........
Nltrobenzene ..............................
Nitrogen ..................................
Nitrogen Fertilizer Solution .................
Nitrogen, Liquid ..........................
Nitrogen OxideMethanol Fumes, @ 22OF ....
Nitrogen: Oxygen ........................
N,: CO,: SO,: 0,: H,O Vapors ..............
AROPOL

7343

samlacmly

CONCEN.
TRATION %

HETRON
92199P

sa:
-

220

220
-

F FOR RESIN rYPES

AROPOL
724017430 SERIES
100 150
-

150

M-3 5 5 07.&a

TEMPERATURE.

HETRON
7U1971197A

150

HETRON
7ooi7ooc

ETRON
920 SERIES980

220 200
-

210,2X
_

1451-

200
Satd
53126

220
-

orlgat

40.6:6: Trace oz/gai


-

NW-

@ 160-F

NRI-

2
5
10

AMB

150
60/6O/NA

NR

NR

60160/NR

NR

NR
NR
160
150

NR
NR

AM0
NR

1001150
-

140

NR

NR

NR

110

NR
-

NR

NR
-

15&JNWNW-

65.95
150
10160
NR
NR

200

NR

NR
-

zoo/-

loo

NRI-

165
165
NR

NW-

135
NR

NR

NR
NR

7.5.2.5
15:5

.Yl

20x5
35:5

105
-

3:60
4:7 by vol.

203
125

60
NR

NR

al

NR
NR
-

NRI-

90

SAT/SAT/NR

9.5:17:112 gpl

IO160

1020:10z6 molar
10:20:30.40
12:x):30

NW-

40180
180

NR/-

WNRJNR

NR

NR

17Y95
-

175
-

160

NR
NR
-

60
120

NR

NR

ml-

NRIlM)il&l
1601180

2cm

46 @ 1WF
5
2% ougal
-

160/160
-

Hot
NR
-

NR
NR

26
Go/-

W5C
t! jee

NR

NR

NR

NR
160/-

60
NR
-

&l/NR
-

60

100
100

0.12 0.1:5 14 by VOI

001NRI-

2So.w:<o.1:75
%m

100
Unknown

x):11:59.1

unknom
not
100 0 75-F
1o.S:51

105
-

120

?0?8oz/gal@80

:S3 ty vol. @ 1OO.F


UIllUlOW

NR

154 @ 1Bo.F
2013

60%

6595
-

1201140

NR

21w2101-

5:x)
10.77 13

24 @ 183-F

210,220
160

140
140

NW-

36%
10%

_
NRINR,-

m
140

52 4

3.0:7.0:25 gpl
30
!m39

210/220
-

1401175

NWNW-

0 12QF
2z3.8

22G200
-

160/120
AMWNR

Qp 110-F

505

l&J/-

a
50

12:24 @ 60-F

2w
-

210

6:3:1 0 1WF
lo.10

521

16celo

lBO/-

21w2@l

20
J5

166
15:lal gpl
2crlW
gpl

220
160

200

65
120
lisl of trademarks

60

Hetron 31 SAT also, no veil


NR
and product names

_
(continued)

Synthetic

TABLE 1.54:

POLYESTER

AND VII

L ESTER FiESl

i-ASHLAND

Nitrogen: Oxygen: SO,, droplets 60% Sulfuric


Nitromethane
Nitromethane(tris, hydioxymethyl):
Formaldehyde: Water, pH3 ........
Nitrophenol
.....
: : : : ..
pNitrololuene !&Ironic Acid
..............
Nitrous Acid ..........
: : ..............
Nitrous Acid .............
Nonandioic Acid ..........................
Non-Condenrrble P&P Mill GJe .............
Nonionic DispersJnt, Blend a 12SDF .........
Nonionic SurfJctrnt, Afkanolrmide .........
Nonionic SurfJctJnt, Alkyl Ether Amine
............
Oxide
............
NonylPhenol::::::::::::::::
..................
Nonyl Phenol, Ethoxylrted
NonylphenoxytrfethoxyethJnol SulfJte,
SodiumSJlt ............................
Nuclorr, RJd WJste .......................
NucloJr Swimming Pool ReJctor Liner ........
Nuclear Waste Ammonium Nitrate
.....................
Fluoride Solution
Nuclear Waste, Water, Low Level
........................
ionexchange..
.........................
NutOif,Ground
Oakitet Cleaner, pH 11.12 @ 185F ..........
Oakitet Strfpper SAt ......................
Octanoic Acid ............................
........................
Odichlorobenzene
Oil. Crude, B .............................
Oil, Crude Storrge Tank Bottoms ............
Off,Fumace.
............................
Oil. Gas, Dirty, Relinery ....................
Oil, Heating ..............................
Oil, Low Sullur Crude ......................
011, Medium Sulfur Crude ...................
Oil, Mid-Continent Sweet ...................
Oil, Oxidized Petroleum Heavy Bottoms,
7.6 fbr/gJf with JbOUt 10% Acetic Acid ......
011. Refinery WJste Eflluent .................
Oil. Slop, Refinery .........................
Oil, Sour Crude ..........................
Oil, Sour Crude, Wyoming ..................
.........................

oil. SWJJt CNdJ

Oil, Waste, Various Ketones, ArOmJtiCS .......


Oil, Water SepJration ......................
Oil, West Texas Sour ......................
Oil, West Texas Sweet .....................
Oilr:AnimJl..............................
MinerJl................................
Vegetable .............................
Olefin (JiphJ) Sulfonate ....................
Oleic Acid ...............................
OfeoparJthion ............................
Oleum (fuming sulfuric) ....................
Oligomertc Dlspenunt ......................
Olint 58981 ...............................
OliveOil..
................................
1gODt: VlnylidJne Chlorlde ..................
OPM.lf
..................................
opht.2t
..................................
Ore Smelting Furnace Gas, Wet, with dust:
4O%NJ. 23% Cd, 6% Pb, 21%B, 6%Zn
Jnd other Oxides to 400F ..............
.....................
Orgrnic DJlJgJntJ
Organic Solvents + Aqueous HCI .........
OrgJnotin, Quetemary Ammonium
S~ltr, Amlne Selts Blended .............
OStnOSJ COmpJny

TEMPERATURE.

F FOR RESIN

TYPES

CONCEN.
TRATION %

HETROn
92!99P

HETRON
72ll971197A

79 157
100

_
-

AM0

_
-

120
-

NR

120-

51 0649
1W

175

NW-

200

10
Satd

AM0

AM0
AM0

100

24
100

HETRON
700~700c

lx)/-

55 aInN%
100
100

100

165

LSNR
-

120
110

12O
llr! 110
-

100

loo
SAT

12OF

NFU-

la,
-

NR/-

Unknown
AMBI-

120

110

120.1 IO,-

loo
-

120

100 -

AM0

LSI-

AM0
-

NR

16Oirw
NR

160
NR

1601200
NRlW

AM0
lx, loo
AMB/AM&-

2001210
-

AM&-

140
-/LS12QNR

160.220/-

12aAM&AM&--

AM0

210

liM~15O
ZICUIM

210
-

16@15O

AM0

200

210

2101150

210

200
-

AM0
AMBI-

AM0
-

AM&-

1W
100
-

1W

120

100
3
-

2w
140/-

xx)
-

100

13W-

loo

14tN-

s&2

100

NR

NR
130
122
14O

leeJ130
NR
lx)
1801130

AM0
180
180

SATISATINR
pHl2 @ 75F
Unknown @ 194-F

NR

100

125

tSee hsl 01 lrademarks

220

loo

AM0

21.1.5:o 9.0.2.5
5050
15 79:7
5.70:12:0 1.14 by vol
3

220
AM0
200

65
175
120
100

200
200
200
-

200
-

200!210
-

NR
130
-

NR
130.-

AM0
-

2wi210
-

NR_

NR
NR

210
NR-

LSl2YNR

125

180 140
-

02-

100; 5O L 16
All

SAT

AMBI-

Unknown
-

loo

HETAOH
920 SERIES980

loo

14O/-

Satd

lzol-

SAT
1M

loo
-

26

Cone. 0

AROPOL
7240:7430 SERIES

PrJmix; Jnd Fir0

Retardant Liquid Formulationr ..........


Oxalic Acid .......................
... ....
Oxidizing Gases
Oxygen: CO,: SO,: SO,: H,O, Trace; cl;.N, : :
Oxygen: Nitrogen ...................
Oxygen: Nitrogen: SO,; Droplets 8!% Sulfuric
0,: N,: CO,: SO,: H,O Vapors ...........
................
Ozone
....

203

(continued)

SERVICE

CHEMICAL
ENVIRONMENT

Resins and Polymers

2201200
AM0
-

216 220
_
_

_
_

and product ndnws

(continued)

204

Corrosion Resistant Materials Handbook

TABLE

1.54:

POLYESTER

AND VINYL

ESTER RESINS-ASHLAND

(continued)

SERVICE

CHEMICAL
ENVIRONMENT
Ozone/Cyanide

CONCEN.
TRATION %
Fumes

Ozone:Hydrogen
Ozone:
Ozone

Oxygen,

..............

........................
Wet
.................

20 Ibs/day 8 1%
Unknown

HETRON
92199P
0,

1.5-2.5.0,

Sewage Treatment .....


3
:. : .........
Ozone Treatment Condominium Waste .......
4 lbslday @ 2% 0,
Palmitic Acid .............................
Satd
Paper Machine ...........................
Fumes
Paper Mill Liquor ..........................
Unknown
Parathion, Wet ...........................
Parco 450/45t, pH 1, HF presenta .............
Parco Cleanert 556R ......................
100
Pax Hyspeedt,
Detergent
...................
Satd
Peanut Oil ..............................
100
Peel Oil ..............................
100
PepSet1505t..
..........................
100
Pep Set2596 .............................
1W
Perchlorlc Acid ...........................
5
Perchloric Acid ...........................
10
Perchlortc Acid ...........................
30
Perchloric Acid ...........................
to 70
Perchloroethylene
.......................
100
Perchloroethylene, Vapor & Condensate ......
100
Petroleum Ether ..........................
100
Petroleum Oil 61Waxes, Water Emulsion .....
Phenate Based Algaeclde ..................
1M)
Phenate Based Bactericide .................
100
Phenate Based Fungicide ..................
100
Phenol ..................................
2
Phenol ..................................
5
Phenol ..................................
10
Phenol ..................................
65
Phenol ..................................
100
Phenol, Formalin, Sulfuric Fumes ............
Unknown
Q 2CilF
Phenol, Fumes ...........................
Phenol: HCI : Water .......................
20:10:70
Phenol Sulfonic Acid ......................
Satd
Phenolic Resin. Urea Modllied
(Durezt 24942) ..........................
PH 78
Phenolic Spent Caustic, Refinery ............
Phenollc Spent Caustic, Refinery,
Neutralized to pH 5-6 ....................
Phenols, Some: Sulletes, H,S, Water, Waste
Liquor, pH 5-6 ..........................
0.Phenylphenol: Sodium Xylene Sulfate:
Isopropyl Alcohol: Potassium Rlcinoleate:
6:10:10:6:67
lnerts .................................
Phosphate MIX (NaOH + H,PO,) ............
PhosphatelPhosphoric Acid Waste
510
Liquor, pH 1-3 ..........................
Phosphate Rock Dust Scrubbing .............
Unknown
Phosphate Salts ..........................
25
Phosphonitrilic Chloride, Cl,, HCI,
Benzene. H,OVapors ....................
Phosphoric Acid ..........................
65
Phosphoric Acid: Calcium Chloride ...........
lo:25
Phosphoric Acid, 26%, Some Fluorides,
Fumes
Ammonla; Reactor ......................
40:7:2
Phosphoric: Chromic: Hydrofluorlc ..........
Phosphoric: Chromic: Hydrofluorld ..........
8.5:9.3:11
Phosphortc: Fluorine: SIO, ..................
54:1.2:2
65
Phosphoric, Food Grade ..................
15:9
Phosphoric: HCI, Sat. with Cl, ...............
15:9
Phosphoric: HCI, Sat. with Phosphorous ......
Unknown
Phosphoric: Hydrochloric Acids .............
Unknown
Phosphoric: Hydrochloric: Butyl Ether ........
Phosphoric: Hydrochloric: HP ..............
65:1:5X
ppm
50:2:7
Phosphoric: Hydrofluoric: Cr,O, .............
6:11:9
Phosphoric: Hydrofluorlc: Cr,O, .............
Phosphoric: Hydroxyacetlc: Sulfuric Acids ....
5129120
Phosphoric, 36%: 70% Kerosene, 10%
lsodecanol, 20% Organics ................
35:33:33
Phosphoric 65%: Kerosene: Xylene ..........
Phosphoric Acid: N-Alkyl Dimethyl Benxyl
25:0.1:75
Ammonium Chloride: lnerts ...............
tSee

list of Irademarks

and product

TEMPERATURE,

F FOR

RESIN

TYPES

AROPOL
7240/7430
SERIES

HETRON
7001700c

100
AMB

_
-

_
_

AMB

160
-

2201200
-

140/-

1801120
-

1601-

_
-

HETRON
7211971197A
AMB
1cO1100/140

140/160

76-120
AMBJ120
120

NRINFUNPJNFU-

110
140
-

175/-

AMB

120
AMB

AMB

AMB

65165/B516Y-

NR

65/6=5/651851100
120
-

NR
NR
NR
NR
_

AMBI-

AMB
-

AMBI-

1801150/-

SO/-

NR
_

100
_

_
-

125

125

125

125

125

125
-

125
125
-

160

NR
NR
NR
NR
_

AMB

140
125

100
NR
NR
-

HETAON
920 SERIESi

loOI-lOOINR
NR
_

8ollW

NW30
NR/NR
-

NR

NR/-

80-110
NR
-

NR
-

NR
-

AMB

130

130/-

130

130

130/-

130

130

130/-

130

loo/1701-

AMB

1801150
-

2201200
-

2101220
_

_
-

100
200
SATIAMB
220
_

AMB
120
250/250/200
100
to 250
100

NR
NR
-

100
_

1OOINR
_

100
-

175
180
220
220

SAT
SAT

NFVNR

AMB

100
100

243/243/-

150

100

100

loo/-

230/230/-

NR
-

namrs

(continued)

206

Corrosion Resistant Materials Handbook

TABLE

1.54:

POLYESTER

AND VI

L ESTER RESI

;-ASHLAND

(continued)

SERVICE

CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Potassium Carbonate
Potassium Carbonate ......
Potassium Chlorate
............
......
Potassium Chloride
Potassium Chloride: Cl,, Br, Satd;. pH 2.4
Potassium Chloride, Mercury Grade .........
Potassium Chloride: Potassium Hydroxide:
Hypochlorite with Treces Chloropicrin
@ 194OF ...........................
Potassium Chloride, Wet Vaporr ............
Potassium Cyenide
Potassrum Cyanide: K Hydroxide:
Copper Cyanide ......................
Potassium Dichromate ..................
Potassium Ferrlcyenide ..................
Potassium Ferrocyanlde ..................
Potassium Fluoride2 ......................
Potessium Hydroxide ....................
Potassium Hydroxide ....................
Potassium Hydroxide ....................
Potassium Hydroxide .................
Potassium Hydroxide
.................
:
Potassium Hydroxide: Potassium Chloride:
Hypochlorite with Traces of Chloropicrin
@ 194OF .......
..
..........
Potassium Hydroxtde: Potassium
Cyanide: Copper Cyanide ................
Potassium Nltrate .........................
Potassium Oxalate ........................
Pota*sium Permanganrte ..................
Potassium Peroxide ......................
Potassium Persultate .....................
Potassium Pyrophosphate
.................
Potassium Ricinoleate: 0-Phenylphenol:
Sodium Xylene Sulfate:
Isopropylalcohot Inorta ..................
Potessium Sulfate ........................
Power Plant Scrubber, Med. Sulfur
Coal, pH 1.936 .........................
Power Plant Scrubber, Med. Sulfur
Coal, pH 1.936 .........................
Premix Liquid (Osmose Co.) .................
Propenoic Acid See acrylic acid
Propionic Acid ............................
Propionic Acid ............................
Proplonic Acid ............................
Propionic Acid @ 12CtvF ....................
Propionyl Acid @ i2tJF ....................
Propionyl Chlortde ........................
Propylene Glycol ..........................
Pulp, Bleached .........................
Pulp and Paper Mill Bleach .................
Pulp end Paper Mill Condensable
Liquor, pH 9 .......................
Pulp and Paper Mill Digester ................
Pulp and Paper Mill Recovery Boiler ..........
P 6 P Mill Waste, Acidic ....................
PulpStock..
.............................
Pulp Stock, Chlorinated, pH 4.5 ..............
PVC Latex with 35 partr DOP ................
Pyridine .............................
Quaternary Ammonium Compound, In
Isopropanol, Cationic ....................
Quaternary Ammonium, Dialkyl, Dimethyl
Type: Aqueous lropropanol ...............
Ouatemary Ammonium Salts, Organotln,
Complex Amine Selt Solution Q 125OF .....
Ouatemay, Dlcoco Dimethyl ................
Ourternary, Dimethyl, Dlrtraryl
In Isopropenol ..........................
Ouatemary, Dimethyl, Dlstearyl in
Neutral Organic Solvent ................
Quaternary, Hexylene Glycol ................
Quaternary, Methosultate Type ............
Quaternary
Softener,
Difatty Complex .......
R.2 Solutions ....
Rad Waste, Nuclear
: : :
:
: : : :
:
tSee

115101 trademarks

25
sac d

HETRON
9299P

TEMPERATURE,

HETRON
72i19lf197L

OF FOR RESlh

AAOPOL
7240 7430 SEPIES

AMB

110

AM6

NW90

AM6

110
_

2w
-

250
190

:60150
-

180

Sal C Q 265F
All
Sat d
Sal d

15:15:1

AMB
-

Sald

200, -/zoo

175
200
-

180,150

Satd

200

200
150

1801150
-

Satd
3.2 8 origai
All

Sotd
10
25
45
50
2 oz/gat

NFUNFUNFU-

15.15 1
-

arlgal

2:3$

All

NR
-

180
_

220,206
_

NR

210,220
-

NRI-

NRJ-

1843!-

200

21ci22c

lM/NR
-

22O~lt3C
2201180
150

210220
210!220
150

150lAMB

150

15OIAMB
AMB
_

150
150
150
150

1751-

175

175

NFL-

101220

200

220
-

1801150

22012w
-

150
-

150
-

12YNR
-

2w115l
-

2101220
-

AMB

AMB

Satd
All
Sald Q 80-F
All

HURON
920 SERIES980

:5G

AMBI-

TYPES

ETROH
700 7OQC

100

loo

AMBI-

200
100

2101220
1001-

6:0.10:10.%7

loo

All

2W

220

180150

22012w

Liquor

150

150
-

02J-

806

80

Mist 8 Fumes
100
1
20
-

100
80

NRI-

NR

80

NW-

NR
NR

100 0

1WF
All
-

Fumes
-

NR/lOOU70
AMBI-

Fumes

AMBI-

Fumes

AMBI-

FUMS

184
190
-

80
NR
LSINA
1701150
_

130
-

150
-

AMB

120
-

80
NR
LSNR
2001180
-

lW/2101220

80
2008NRINRINPi-

2101220
_

130
-

1301-

AMB
-

AVB
-

190

NR

NR

NR

100

NR

110
NR

120

120

1201120

120

12OI-

1201-

120

120~120

120

1201-

SAT
120

LS

SAT

1X4-

1201120

120

120/-

120/-

120

1201120

120

120/-

1%X-

190

1w

1901-

120/-

120
120

190150
120 120

120
120

120 120 -

120
-

120 _

75.25

75

1201Sald
-

1201-

120.
180
100

120 120
120 120
_
_

and product names

(continued)

Synthetic

TABLE

1.54:

POLYESTER

AND VIP

L ESTER RESI

;-ASHLAND

CONCEN.
TRATION %

Radiochemical Hoods, Glove Boxes

50
-

....

Raylenet

: I.
....
RayonSpinBalh
.....
Rayon Spin Bath Evaporator/
Crystalizer to 16O0F
Rayon Spin Bath Fumes C 195.2C13bF : ......
Rayon Spinning Fumes ...............
Recovery Boiler Biow.Down; Acetic:
Sulfuric Sulfurous: Formic Acids:
Acetone ...............................
Recovery Boiler Flue Gas to 400F ......
Recovery Boiler (Kraft), no contact rvap.;
59100 ppm SO,, 12.14% CO,, 19% by vol.
..........
moisture, 37 lps to 4U0F
Recovery Boiler Stack Gases 6 3&F ... ....
RedLiquor ...............................
Reformer Charge .........................
Renderlng Fumes, Ozone, Chlorine ...........
Rhodium Plating, phosphate ................
Richamide CDAT ..........................
Richonate 165Ot .........................
RJ-Qt Fuel .............................
Rock Wool Slurry .......................
Salicyiic Acid .........................
.I:
Salt, Molten
........................
Sand, Dry, 60-70 Mesh, 350 cfm ...............
send,

Slurry

.............................

Sani-Fresht Soap Solution ..................


Scrubber, Med. Suitur Coal, Particulate, pH 1.9
3.6, Cl560-1200 ppm. 309,ooO ACFM Gas .....
Scrubber, Med. Sultur Coal, Particulate. pH 1.9.
3.6, Cl560-1200 ppm. 300.9W ACFM Gas .....
Scrubber Sludge; 30% Solids
(96% Ca SultetelO% Ca Sulfate),
.....................
15%FlyAsh,pHll
Scrubber Sludge; 36% Solids (90% Ca Sulfate
10% Ca Sulfato). 15% Fly Ash, pH5. .........
swat
SIa

hsl01trademarks

and product

140

212
SAT!SAT/NR

NR
NR

SAT/SAT/N,?

SAT!SATINR

NR
NA
-

-/MO/-

Fumes
-

100
Unknown

8 Spells

kY%'Qai
@8o.F

804Hetron

80
satlstactow

120

80
tank. Amblent

for aaltaled

Restslant

Liner

120

120
100
180
--/LSINR

180

All

132
-

loo

loo

IWi-

18WlM
-

180
-

2101_

2101-

AMB
-

AM0

AMB

AM0

125

125

85

85
AMB

85
AMB

125
-

AMB

AMB

AM0

AM0
AMB
--IAMB
-

150

2.75 x Normal

100
-

NOrmal
175 x Normal

160,-

150
-

150

120
120

Sallsfactoly

NW-

e-

750
31

NW-

All NR wtth Abrasnn


Hetron
-

7501-

NPJNR-

120

80
197.3 with llller

wmes

AMBI-

21212W

120
120
120

Sal0
Splash

1401-

--,LSSI-

NW-

100
100

HETRON

920 SERIESI9EO

180

1671-

TYPES

HETRON
700700c

150

NRI140011W

F FOR RESIN

AROPOL
724017430 SERIES

AMBI-

TEMPERATURE,

HETRON
7219711971

92199P

...................................

Water ................................
See Water, Desalination, pti 7.5 @ 265.F .......
Sea Water,
Desalination, pH 7.5 ..............
Sea Water, Desalination, pH 7.5 ..............
Selenious Acid ............................
Septic System .............................
Sequestering Agents .......................
Sewage, Anaerobic .........................
Sewage, Municipal, Treated 6 Untreated .......
Sewage Treatment .........................
Sewage Tmatment Fumes ...................
Sewage Treatment, Ozone, 3% ...............
Sewer Gas; H,S ..........................
Shampoo, Carpet ..........................
Shampoo, Liquid ..........................
Silicone Oils: Hydrochloric Acid ..............
Silver Cyanide .............................
Silver Nitrato ..............................
Silver Nitrate: Coppw Chloride ...............
Silver Plating Solution. 4% Silver;
7% Potassium and 5% Sodium Cyanides
2% Potasslum Carbonatti .................
Silver Refining Cells ........................
Single Vessel Chlorine Dioxide
Process (Hooker) ........................
Skydroi 500t, Hydraulic Fluid
Siimicide, Organotln Amine Blend r@125F .....
Slimlcide, Polychlorophenate
organosulfur blend .......................
Slimicide, thiocyanatepoly&lorophenol
blend @ 125OF.. ........................
Slurry, 20% Clay: 20% Potash In Satd. Brine ....
Slurry, Coal/Water @ 6OF ..................
Slurry, Lime ...............................
Slurry. Mineral or Rock Wool .................
...............
Slurry, Sand/Water Q 60F
Smelting Furnace Gas and Dust,
Wet to 4OOF ........................
tSee

HETRON'

207

(continued)

SERVICE
CHEMICAL
ENVIRONMENT

Resins and Polymers

AMBI-

AMB
-

AMB

AMB

AMB

100
AM0

AM0
AMB
-

AMB
AMB
-

AMB

AMB

100

LSlWINR

1w
-

AM0
lW/2101-

100

120

7921

195
-

PO

180/150

200

2101-

NR
-

200

2W/-

Satd
All

200

x3:15

80

NR

100
loo

SAT
etro
-

197 SAT throughout

125
-

10190
Satd
Unknown

--ILS/NR
Hetron

197 SAT @ 12 tps

for absorption
Ah48
LSiNR

125
SAT

Hetron

180
197.3 wth t!ller satlsfaclory
Hetron
SAT.SATINR

resistant
170180

NaOH
150/1&l
-

SAT

125

197-3 with abrasion

lEOI-

Of Cl, or ClO,m

SAT
-

Hetron

4 lbsigai
-

except

160
SAT

100
100
40 Slurry @ 80-F

Fuller Satisfactory
for agitated

at 7 ips
170

tank. Amblent

31 Satlsiactory
-

(continued)

208

Corrosion Resistant Materials Handbook

TABLE 1.54:

POLYESTER

VINYL

S-ASHLAND

(continued)

SERVICE

CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Smoke, Particulate, Cooling and


Washing with Waler
Soap Plant Fumes
Soap Solution
:::: :.
Soap: Sulfuric
.,....
Soap Tower Exhruat Fumer 1 : : :
Soda Ash; Sodium Carbonate
.......
..
Thickener Fumea
..........
Sodium Acrtrte
..........
Sodium Acid Sulfite
.....
Sodium Alkyl Benzene Sulfonrte
..........
Sodium Alkyl Xanthate
Sodium Alkylaryl Sulfonate; pH 6 ..........
..........
Sodium Aluminate
Sodium Ammonium Phosphate
Sodium Benzdate ........................
Sodium Bicarbonate .....................
Sodium Bicarbonrts .....................
Sodium Bichromate ......................
Sodium Bichromate: Sulfuric: Sugar
..
Reaclion Product, pH 26 ............
Sodium Bisullaie .......................
Sodium Birullide ........................
Sodium Blsulfider ......................
Sodium Bisulfide ........................
Sodium Bisulflde: NaOH ..................
Sodium Blsulflte .........................
Sodium Bisulflte: Sodium Sulfate:
Sodium Sulfite ........................
Sodium Birulflte/Sulflte ...................
Sodium Borate .........................
...
Sodium Bromide .....................
Sodium Carbonate .......................
Sodium Carbonate ......................
Sodium Carbonate Q 206OF. ..............
Sodium Carbonale .......................
Sodium Carbonate .......................
Sodium Carbonatea .......................
SodiumCa~otWt~:SodaAah
Thlckrner Fumoe ......................
Sodium Carbonate, Vapor & Condensate .....
Sodium Chlorate .. ......................
Sodium Chlorate .......................
Sodium Chlorate, Sodium Chloride ..........
Sodium Chlorate: Sodium Chloride with
....
350ppmCr,10ppmCa,10,000Ampr..
Sodium Chbrato: Sulfuric: Chlorinr
Dioxldr: Methyl Alcohol .................
Sodium Chloratr, Sulfuric. Methanol,
Sodium Sulfate .........................
.........
Sodium Chloride ................
Sodium Chloride: Calcium Chloride:
...................
Magnesium Chloride
Sodium Chloride, Cl, Satd., pli 2 .............
Sodium Chloride, Cl, Satd .. pH 2.6 ...........
Sodium Chloride: CIO, .....................
Sodium Chloride, Dechlorinated: pH 25
Free Chlorlno (Traces) ...................
Sodium Chloride: HCI ......................
Sodium Chlorldo, Mercury Grad r ............
Sodium Chloride, pH 3 .....................
Sodium Chloride. pH 3, Cl, Satd .............
.......
Sodium Chloride. pH 3.5 ............
Sodium Chloride, pH 10.5, Cl, Satd ...........
Sodium Chloride, pH 11, some Cl, ............
Sddlum Chloride. Satd. Chlorine .............
Sodium Chlorldo: Sodium Chlorate ...........
Sodium ChMdo: Sodium Chlorate wlth
366 ppm CR. 10 ppm Ca. lO.WO Ampa .......
Sodium Chloride: Sodium Nltrate: Sulfuric .....
Sodium Chloride: Sulfuric Acid ..............
Sodium Chloride: Sulluric. Chlorine + CIO, ....
Sodium Chloride, Vapor & Condensate ........
Sodium Chloride, Wet NaOH. Chute ..........
Sodium Chlorite .......................
..................
Sodium Chlorite ...
tSee

list of lrademarks

Unknown
-

100

HETRON
92199P

TEMPERATURE.

HETAON
721971197A

lW/-

lee

AMB
AM0
-

AMB

AMB

AMB
-

AM6
215!-

1M)

160
15Ol-

165
100

2001150
-

150'-

120iAMB

1201lie-

NR
-

Unknown

176
14Ol140

120
NR

NR
-

2cHl
176
140

-I90

140
-

200
-

200
160

200

15:15:15
5CU53 Sald
Sald
All
2
10
10
25
32
6&d

170
220
120/12O/-

90
Satd
3.2M:3.4M

150
170

140

1401-

NR

140
2oa

140/-

16W90

16oirro

22Of140
-

2101220
1&J:1601-

AMB
AMB/-

1801160
160

160/l&I-

160

1601-

LS

180
203
200

160116Q

160
130
NR
-

2co
200
-

160
210

Satd
Sald

Sald

NIU-

Satd
Satd
3.4M:32M

210
165
190
220

NRI-

NR
-

LS
-

ZlW2101-

NR

150

120

tons/day
2

gpl

23:35

25

212/200

2101220

160

160
212

100150

200

165

6:620
6.12
Sald

210!220
-

160/150

ZM)

Satd
Sald

210:220

170
120

Satd
SstdJ

2w:340

2M
1M
212

2335

150
145

12:10:2

2101220

16CllW

160

-310
QVI
Satd

1601NR
-

AM0

200

210/220

125
Sald

2101220
l40'-

160/160/-

IWAMB

20:450 gpl:Sald:Trrce

150/-

1601150
150,-

AM6

gpl

2101220
1601-

250
160/160/-

AMBI-

-i90

210/220
-

200
140
_

165
-

lW160

10

200

160~160
16oi140

1e01150

160
160

45
15%

150
-

176l160/120
1601-

140

Satd

2ao

40
sat d

15
65

All

AMB

14O/-

10
Satd

IiETROH
920 SEWS980

2001150

15

Satd

TYPES

HETRON
700'7ooc

AMWlOO
-

100
All

340%0

OF FOR RESIN

AROPOL
7240 7430 SERIES

160
-

160
AM0

212

175

175

210:220
210~220

and product name8

(continued)

Synthetic Resins and Polymers


TABLE 1.54:

POLYESTER

AND VI

L ESTER RESII

S-ASHLAND

(continued)

SERVICETEMPERATURE.OF

CONCEN.
TRATION %

CHEMICAL
ENVIRONMENT

......
....
Sodium Chlorltr
....
.........
Sodium Chromate
...
Sodium Cumene Sullonate ....
Sodium Cyanide
......
: .... : ..
SodiumCyanide.
..........
1:::. ........
SodiumCyanides..
Sodium Dichromato ......................
Sodium Dkhromatr: Acetic Acid ............
Sodium Di-phoaphato .....................
Sodium Dodocylknzeno Sulfonata, pH 8 .....
....................
Sodium Ethoxyrullatr
.....................
Sodium Forrkyanide
Sodium FormcyanIde .....................
Sodium Fluoride .....................
...................
Sodium Fluororilkatr
..............
Sodium Hoxamotaphasphate
Sodium Hydmgon Phoaphato ..............
Sodium IiydrcHulfldo .....................
Sodium Hydrosulfldoa .....................
Sodium Hydmsulflde: NaOH ..............
Sodium
Hydroxide .......................
Sodium Hydroxide .......................
Sodium Hydroxide .......................
Sodium HydroxIdea ......................
Sodium Hydroxide ......................
Sodium Hydmxido .......................
Sodium
Hydroxldr .......................
Sodium
Hydroxldo .......................
Sodium Hydmxldo: Ccl.: Alumlnum Chlorida . .
Sodium Hydroxide Croaylk Acid ...........
Sodium Hydroxldr: Ethylonr Dlamlne:
Diethylena Triamlnr: Water .............
Sodium Hydroxldr: Gluconic Acid ...........
Sodium Hydroxldr (10% lxpoauro time):
H,SO, Paato (90% rxporun tlmo),
sulf1da Roductkn Proco8aJ ..............
.....
Sodlum Hydmxkk, Intomtlttont Smlo
Sodium Hydroxldo: NaHS .................
Sodlum Hydroxide Noutmlizatlon
of Acidk Organks .....................
Sudlum Hydroxide Nwtralizatkn
of
Acidic Totuono, Naphtha ................
Sodium Hydroxide Scrubbing Cl, Blow Gas ...
Sodium Hydroxldo Scrubbing Cl,. CIO, ......
Sodium Hydroxldo: Sodium Thio4fate
6 Sulflde .............................
Sodium Hydroxldo Vapor & Condonsatti .....
..............
Sodium Hypochlortto34.47..
..............
Sodlum Hypochloftt&~47..
...............
Sodium Hypochlorlt&~*7..
Sodium Hypochloriter 4 5. 7 ................
Sodium Hypochloritr Reactor,
10% Excess Cl, .........................
Sodium Hypochlorlto Reactor,
....................
10% Excorr NaOH
Sodlum Hypochlorlto Vapora ................
Sadlum Lauryl Sulfatr .....................
Sodium: Magn4um:
Calcium
ChlorIdr Solution .......................
Sodium mota~araonltr .....................
Sodium Mothacrylatr, pH 10.10.5 ...........
...................
Sodium Monophoaphatr
Sodium Nitrato ...........................
SodiumNitritr..
..........................
Sodium Nlttitr: Sodium Chlorldr: Sulfuric .....
Sodlum Porsulfrtm ........................
Sodium Phoaphato. Mono, pH 1-3 ............
Sodium PhosphatePhorphotic
Acid
Scrap Liquor. pH l-3 .....................
Sodlum Polyactylatr. pH Oslo.5 .............
Sodium Silicate ..........................
Sodium Silicate, pH 1223 ...................
Sodium Sulfate ...........................
Sodium Sulfate: Boric Acid with 0.25%
Sulfuric. 0.03% H,O,, 100 ppm Iron,
3000 ppm Chlorldr, TomPoratun Cyckd"
+fETRO%
COndrt~onS

197

and

wtth

700
Some

Serk?S

r.?s!s

CtsZ!g

but

dogear

Sat d
Satd
43
Sat'd
50
10
Sald

under

METROW
72119711971

FOR

AROPOL
7240!7430 SERIES

--ILSlSO~NR

103 -

--ILSl2O/NR

lx):-

180
-

1M

210!2co

9ot160
120'
120'

Sat'd

220

250

180150

Sat'd
All

--1220

180
-

180150

All
Sst'd
Unknown
15.65
45
15:15

1
5
10

150'

160
-

155

NW1401180
NRl1B.I
NFU-

15

NIU-

25
50

NW-

120
220/200
220'200
-

140

NR

140
-

14O/ldoi_

LS2cO~120

150

LSAMB
NR

NR

212'150

150

NR

2121150

NR
NR
-

212115a
2lZlM
NR
-

120
120

NR
NR

520
-

80

NR
-

150

NR

140
NR

@W'F
2Q
5
NW-

NR

NR

120
120

100

NR

NR

NR
-

180
125
120
110

120
LSJNR
NR

125
120
120
125

125

100

100

150
130

180~150

--1150

Sat'd
B:8:20

220
18CN-

20

1401
-

loo
120

150
150
1M
150

120
180

250
180
180
-

l@OllM
1801150
-

2201180
22cul80

2101220
2101220
210/220
-

120/-

l&3-

150

200

25
6
-

All

AhW180

cond,t,ons

180

510

StaOc

150

25

25:15

1W

Sat'd
Sat'd

180
1801-

10

122:10
50

15
15
5%

140

@lO'F

NR
12Y-

2101220
180
1501150'/-

15
2

210:220

1M

10

LS125:NR
120'NR

NW-

1Bo
125z'NR
1WNR

2101-

140
LSAMS

30.1.6

5
5%

210,2101-

lcoNR

10:10:10:70

302

2101-

LS/LYNR

Unknown @ 160-F
5:12

15
15:15

2101220
2101220
-

120

200
160

HETAON
920 SERIES!980

180'-

Sat'd
40
100

0.5
%@14O'F-33%&3'F-I

HETRON
700 7ooc
'50
200~180
-

180
120
LSl60iLSl60iNR

-/loo
-

RESINTYPES

ha
-

150

30.70

to be unsurrable under cyclic

are res,stdnt

HETROM'
92/99P

209

tsee lslol

200
180
160

9CjNR

160'

2ao

NR

200'

2101220
-

175150

220.200

2101220

AMB

--12061206
trademarks

-206

2ffi'f-

and product names

(continued)

Synthetic

TABLE

1.54:

POLYESTER

AND Vlh

L ESTER RESI

;-ASHLAND

Sugar Solution
Sulfamic

CONCEN.
TRATION %

....

Acid

::

Sullanilic Acid
:
Sulfate: Ferrous Sullate
...
1. : : 1.
Sulfate Recovery Boiler Gases
...
.............
Sulfate Salts. Sulfurk
.....................
Sulfated Detergents
Sulfide Anolyte(NiS0 . . NiCI,.
H,BO, @ pfi 1.5) for ekctro
.............
nfinlng process ...........
Sulfide Reduction Process
Sullurk Acid Paste (go% exposure
time): NaOH (10% exposure time) ... .......
........
Sulfldic Spent Caustk. Petrochemical
Sulfidk Spent Caustic, Petrochemical,
....................
Nwtrallzod to pH S-6
SMte Liquors .............................
Sulfltr, Spent Liquor, Calcium Base
MIII. pH 1.52 (trace lormk 6 acatk) .........
SSull4sophthalk
Acid, Na Salt ..............
Sulknate, Alpha Olefln ....................
Sulfonated Allphatks. HCI, H.S. Butanol .......
Sulfonated Detergents Nwtrslization Fumes ...
Sulfonated Detergents: Sodium Hydroxide:
Sodium Trfpolyphosphate: Hypochlortte:
Blsulflto Fumos ..........................
Sulfonk Acid, Alkyl Benzene .................
Sullonk Acid, pnitrotolueno .................
Sullonyl Chlorfdo .........................
Sulfonyl Chlorfde, Aromatic ..................
.....................
CSulfophthalic Acid
CSullcphthalic Acid: Sulhwk Acid ............
Sulfur ....................................
Sulfur Burner Gas Coolor. Wet to 3SOF ........
Sullur Burner Gas, Wet to 35OF ..............
Sulfur Chlorfde ............................
Sulfur Chlortdr ............................
Sulfur: Cue: PbSO,: FsOz 2&O,:
Bt,(SOJ, Dust ...........................
Sulfur Dlchkrldo ...........................
Sulfur Dichloride ...........................
Sulfur Dioxldo, Ammonia Scrubber Process .....
SO,: Ammonia, Vapor .......................
Sulfur Dioxide Burner Gas,
Cooler, Wet to 350*F ....................
Sulfur Dioxide Burner Gss, Wet to 35O.F .......
SO,: CO,: N,: 0,: H,O Vapors .................
Sulfur Dloxtde, Dry or Wet ...................
Sulfur Dioxldr. HF, H,S, F,H,SO. .............
Sulfur Dloxido; Oxygen: Nitrogen,
droplets 80% Sulfuric ....................
........
Sulfur Dioxide Pulp Mill ..........
SO, Removal by Cltroxt m Citrate Process ......
SO, Removal; Fossil Fuel; Limestone
Injection Mist after Scrubber, pH 2.12 ........
Sulfur Dloxldr Satd. H,O: tracs
HF, H,SO,, H.S. P .......................
SO,: SO, Fumos ...........................
SO,: SO, Fumes, Watrr Spray ................
SO,: So,: HCI: H,SO,: Caustk It,0 Fumes ......
Sulfur Dioxidr: SO,, Wet @ 14gooF.............
Sulfur Dioxidr, Trace Sulfur Trtoxide ...........
SO,Vaportzatlon ...........................
Sulfur Dioxide, Wet; Wet:
CO .. N,, 0 .. .Dust to 350-F .................
Sulfur Fungklde ...........................
SulfwHumld Ah. Fumos ....................
Sulfur snd Machlne 011 Fumes ...............
Sullur. Molton @ 250.28oF ..................
Sulfur, Molten (H,S, SO,, H,O,
SO, in ppm) @ 260~30CrF ..................
Sullur. Molten, Vapors .................
Sulfur Trioxide, Dry ......................
Sulfur Trioxide: SO,, Wet 2 140-F ...........
Sulfur Trioxide, Wet ......................
,See

I,$., or lradrmarks

and product nem~~

TEMPERATURE.

NETRON
721197!1971

50
Sal d

... :
......

HETTRIJN
92199P

164

All
-

15 16
-

3003co/-

24.10

135

050

200

OF FOR RESIN

AROPOL
724017430 SERBS

AM0

160~100
-

160~150
150
-

1601100

130
160

200

25
501.6
-

130
-

2101220

NR

100
-

Vlpor

a0
120

NR
-

NR
-

LSW/NR
-

NRNPJ-

NR

NR
-

NRI-

NR
NR
-

NR
-

SATlSATlNR

NR

SATlSATlNR

NR
NR

200

115
120

by VOI

100
Water

Sard

7.15:79
Fumes

2101220
NR
_

0.06:0.02 by VOI

).1:1270:5:14

190
-

Vaoor @ 60-F
100
-

2101220

NR

@ 80-F

25:1&z!k10:83

190

NR

100

NR

100 @ 75-F

im

130/1601120

193

24

1M
140

190
100

NR

SAT/SAT/N R

NR

SAT/SATlNR

NR

120
250
170
175
--/10400/-

160/150
-

22Ol-

170
-

1W
6.10
-

190
-

120/-

250
140

NR

lEOI-

NRI-

SATlSATlNR
200
HOT
-/SAT/NR

100

-/SAT/NR

100

2101250
-

190
-/LYNR

100

100
100
24 76

NR/NR/-

1501-

7614
2

NFV-

140

Unknown

NR

140

2101220

130

100.

100

210

21012101_

2001-

4p 212-F
25
100
-

HETRON
920 SERIES990

lx)/-

150
130

TYPES

NETRON
7001700c

170

20:5

211

(continued)

SERVICE

CHEMICAL
ENVIRONMENT

Resins and Polymers

30013cO/-

NR
NR
-

SAT/NR

NFU-

NPJ-

AMB
-/LSiNR

NR
-

AMB

NR

21OQ20
NRI-

(continued)

212

TABLE

Corrosion Resistant Materials Handbook

1.54:

POLYESTER

AND VINYL

ESTER RESII

;-ASHLAND

(continued)

SERVICE

CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Sullur, Wettable. Fungicide


..........
.... ........
Sulluric Acid
Sulfuric Acid
Sulfuric Acid
.
: 1:::
.
:
Sulfuric Acid
SulfuricAcid..
... :.:.:::.:::.:..:::::::::.
Sulfuric Acid ..............................
Sulfuric Acid .............................
Sulfuric: Ammonium Blsulfste: Surfactrnt ......
Sulfuric Acid: Ammonium Sulfate:
Manganese, pH 9 ...................
.....
Sulfuric: Anodizing Solution
Sulfuric: Benzene Sulfonic Acid: Water : .......
Sulfuric: Chlorate, Methanol, Sodium Sulfite ....
Sulfuric: Chlorine Saturated
..............
Sulfuric: Chromk ..........................
Sulfuric: Chromk ..........................
Sulfuric: Chromic Acid ......................
Sulluric: Chromk Acids .....................
Sulfuric: Chromic Acids ....................
Sulfuric: 2% Chromic Oxide ...............
Sulfuric (106N): CIO, .......................
Sulfuric, Cont.: Nitric, Cont.
Sulfuric: Contaminated with Maganese
Sulfate and Oxide ........................
Sulfurfc: copper Salts ......................
Sullurk: CopfJer Salts .......................
Sulfurtc: Copper Sullrte .....................
Sulfuric: Copper Sulfate ......................
Sulfuric: Copper Sulfate .....................
Sulfuric: Cu: Fe: Zn SlurryrThickener ...........
Sulfuric: 1% Dodecyl Benxene
Sulfonic Acid ............................
Sulfuric Evaporation .......................
Sulluric: FeO.TiOI Ore, Sterm.Air
Agltrted @ 220-F ........................
Sulfuric: Ferric Sulfate:
Cupric Sulfate ...........................
Sulfuric Acid Fume Scrubber .................
Sulfuric Fumes In Steam ....................
Sulfurk: HCI .............................
Sulfuric: Heavy Polymer, Trece Iron
and Hydrocarbons
....................
Sulfuric: Hydrochloric Acids .................
Sulfuric: Hydrochloric: Antimony Trioxide ......
Sulfuric. 26% by Wt.: Hydrofluortc, 20%
by Wt.: Hydrocfrlorlc. 66% by Vol.:
Sodium Dichromate, 3% by Wt. ............
Sulfurk: Hydrogen lodlde ...................
Sulfuric: Hydroxylemine Acid Sulfate ..........
Sulfuric: Hydroxylrmmonium Acid Sullrte ......
Sulluric: llmenite Ore, Steam.Air
Agitation a 22OF .......................
Sulfuric: Llgnin: CrudeTell Oil, pH3 ............
Sulfuric: Manganese: Ammonlum Sulfates. pH,
Sulfuric: Manganese Sulfate .................
Sulfuric: Manganese Sulfate .................
Sulfurk: 60%: MEK, 160% ...................
Sulfurlc: Metal Sulfate Baits .................
Sulfurtc: Na, Mg, Zn Sulfrter .................
Sulfuric: Na Sulfate ........................
Sulfuric: Na SulfrteSatd. with Cl, ............
Sulfuric (10.6N), Na,SO,, 0.06 gpl
NeCIO,, 0.2 gpl N&I .....................
Sulfuric: Nltrtc Acid 609
....................
Sulfuric: Nitric Acldr ........................
Sulfurtc Nltrk Acldr ........................
Sulfuric: Nitric Acids @ 160~200aF ........
, ...
Sulfuric: Nltrtc Acids @ 210F ................
Bulfuric: Nltrtc: Copper Baltr .................
Sulfuric: Nitric: DinitroToluene Fumes. ........
Sulfuric: Nitric: HCI @ up to 22SF ...........
Sulfuric: Nitric: Hydrochloric
...............
Sulluric: Nitric: Na dichromrte: Cr,(SO.), .......
Sulfuric: Nitric: Phosphoric:
Nonionic Surfactant ...................
tree

!istof

trademarks

andprod!Jcl

names

HEmON
92 99P

8
25
50
50 Q 250-F

Iti230

70

150
loo-

75
80
93
30:6:10

2x
NR-

LSLS:NR
190
175/175/NR

724017430 SERIES

NR
NR

1M
NR
110

LSNR
190/16i
AMB
NR
-

NR
_

--11001100

AM0
140

125
60

?OfJ-

NR

NR

NR
NR
NR

160

NR

225

NR

3220
80

NR-

90
165

NR-

120
NR

NR
-

140

10
gpi
-

33.31 gpl

150

120
150

200:50 gpl
10%.60 10:5gp1

NR-

NR
120
-

150

165

NR

NRY-

2a10:10

160

33

194
300/140

0.05
45 15

60

80

30.1

160

x15:5

100

10.86-W
1KU.3040
3OsO.10
40:13.135 gpl
1090

NR 125 -

gpl

90:10
lo:24

Kv-

lo:24
-

35:23
35.23

30
56:26 8

16OF

156

125
160

200
125

125
-

203

60
135

molar

20 1030
7 013.6.25 gpl
5.20 11 0 1

200
-

60/-

60

aoi-

135
160
130

130
160

NR

NW-

NFV-

60

8Ol-

AMB
SATISATINR

ppl

1W

NW-

20:s
179.5:112

NRIMB/-

f&:26
38a.5

10:1020:6

-no

lh7

25 gpw
QPI
70:Satd

2650

1x1/-

150
160

NW-

120
-

NR

212

NR60
-

NR
-

160

a12
l&5

1020:3&40

220:2co

NR
-

70
to 70

210~220
210 226
NW160:120/NR

20:20
16.12.5

a:31

_
22512oC

NR

1oO.F

HETRON
920 SERIES,980

NR

5353 OzlQal
1613 a 155-F

53:47byvol@

TYPES

HETRDM
7001700c

1601120
1501NR
NR

30 125.13 gpl
-

60

F FOR RESIN

AnomL

140
25025a200
200

NR
-

7.6x.5
Unknown

TEMPERATURE,

HETRON
7211971197A

NR

160

NR

NRI-

NR
90
40160

(continued)

Synthetic

TABLE

1.54:

POLYESTER

AND VII

L ESTER RESI

;-ASHLAND

(continued)

SERVICE TEMPERATURE.
CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Sulfuric, 70%: Nitric, 70% Pickling Acid


Sulfuric: Nitric: Water
::
Sulfuric: Organic (Alkyl Benzene)
Sulfuric Acid Paste (90% exposure time):
NaOH (10% exposure time), Sulfide
.............
Reduction Process

Sulfuric, 93%: Phosphoric, 85% @ 160F


.... .. ...... : : :
Sulturic: Phosphoric Acid
Sulluric: Phosphoric: Hydroxyacetic Acids ....
Sulfuric: Phorphortc Acid: Sodium
Hydroxide: Trisodium Phosphate: Water ....
Sulfuric: Phosphoric Acid: Sodium
Hydroxide: Trisodium Phosphate: Waler ....
Sulfuric Acid, pickle liq. tank covers ..........
...........
SuIturic: Soap ...............
Sullurfc: Sodium Chlorate: Chlorine
Dioxide: Methyl Alcohol .................
Sulfuric: Sodium Chloride ..................
Sulfurtc: Sodium Chloride, Chlorfne and CIO,
SuIturic:Sodium Chlorfde: Sodium
Chlorate: Cl,: CIO,: Steam ................
Sulfuric: Sodium Dichromatr ................
Sullurlc: Sodium Dichromatr ...............
SuIturic: Sodium Dichromate .....
: : ....
Sulfuric: Sodium Dichromate .....
Sulfuric: Sodium Dlchromate: Chromic Sulfate
Sulfuric: Sodium Dichromate
Over Storm Coils ......................
Sullurfc: So&urn Nflralr: Sodium Chloride .....
Sulfurfc: Sodium Sulfate, H,S and CS, ........
Sulfuric: Soya Oil to 3WF ..................
Sulfuric: Sullate Salts ......................
Sulfuric: CSulf~phthalic Acid ...............
Sulfuric: Traca Dichlorides ..................
Sulfuric: Trace Dichlorides @ 196OF ..........
Sulfurk: Trace Nitrogen 6 Nltrobenzene ......
Sulluric: Trace Organiw ....................
Sulfurtc: Trace Organic8 ....................
Sulfuric: Traca Organics ....................
Sulfuric: Trace Organic8 ....................
Sulfuric: Trace Organics ...................
Sulfuric: Trace Organics ....................
Sulfuric Acid Vapor ........................
Sulfuric Acid Vapor ........................
Sulfuric Add Vapor ........................
Sulfuric Acid Vapor ........................
Sulfuric Acid Vapor with Trace Niltic .........
Sulfuric Acid, Waste, with up to 16%
Dinitro Butyl Phenol @ lsOF .............
Sulfuric Acid, Waste, Leaching, pH 2-5 ........
Sulfuric Acid Waste with Metal Salts .........
Sulfuric Acid, wasle pickle Ilq. ................
Sulfuric Acid: Water: HAS (Hydroxylammonium
Acid Sulfate) ...........................
Sulfuric Acid: Watrr: HAS(Hydroxylammonium
Acid Sulfate)* ...........................
Sulfuric: lg20%: Xylene Derivative:
T-Amine: Alkaline Metal Sal1 ...............
Sulfurk: Zinc Sulfatr: Sodlum Sulfate .........
Sulfurfc: Zfnc Sulfatr: Sodium Sulfate .........
Sulfuric 134% Zn Sulfate 1.3% Na Sulfate
38%. CS,. Amines. Satd. with H,S ..........
Sulfuric 5.10%. Zn Sulfate I-8%,
Na Sulfate S-25% Satd. with H,S.
Trace Amines ...........................
Sulfurous Acid ............................
Sulfurous Acid ............................
Sulfuryl Chloride ...........................
Sulfuryl Chloride ...........................
Sulphidr Anoiyte. Nickel Plating Tank pH 1.5 ....
Super Phosphoric Acid ..............
...
Super Pnosphoric Acid .....
:::
Surfactants, Alkanolrmide ..............
Surfactants. Amide Type .................
Surfactant. Anionic .....................
Surfactants, Linear Primary Alcohol Type
tSee

lisl 01trademarks

51 10.5
5.399
75 2

20:5
5050

HETRON
9299P

80
80:&,/N R

NIX-

L.YSATI160

x)51:29

160

NR
_

150

Unknown
45X?ogpl.Sstd:Trace
12:a
35:23

TYPES

HETRON
7001700c
80
NR
-

NR
-

100

loo
200
-

HETRON
920 SERIES/980
aoNR-

243/243l-

2 14.2:0.5:82
2.5.20.2.0.5.75
25

lF FOR RESlN

HETROM
AnomL
721197l1971 7240'7430 SERIES

NR-

lOso

213

Resins and Polymers

21512w

145
-

212
120

4N 1M lM.Satd
30.3

30.5 ozfga1
32.4

42 5 oz/gal

180

150

NR
NR
NR

180
160
1M)

60

952 gpl:Satd
-

22+?6:3.5-5
2cKa:a
10:20
10%
lo:24

1.6:M

30
76
30 @ 160-F
30
47 @ 166-F

NR
180
125
SAT/SAT/NR
135
100
166
-lLS/NA

76
60 0 166-F

NR
SAT
-

LSlMllNR
-

NR

NR
-

166

62 0 166-F
72 @ 166F

NR
-

60

140

140

NR
NR
-

50

140
NFU-

140
NR

120
NR

NR

NR

220

1wJlsl

98 @ 1Bo.F
1520
65.70
25

166

to xx)
NW-

l&I
NFU-

-/NR
AM6

177 gpl

-/go
-

w:20:20
75:14:11

200

NR

100

100
loo

1MYNR

NR

1.55:3:5

10

Satd
99 @ 120-F
100 0

75-F

l&7'/-

205/-

610:18:1wo

w-

16Y-

165

M2wI-

%2oo
150

NR

150

NR

AM6
-

NA
NR

NR

NR

loo/NR

NR

NR

NR

AM0
NPJNW-

1001-

lscl
76%

P,O,

300/3001-

AMWNR

22012oo

210/22fl

2201200

210:220

120

100

120

AMWNF
-

100
58

120

120

loo

120

loo

160

120
120
120

and product n.snes

(continued)

274

Corrosion Resistant Materials Handbook

TABLE 1.54:

POLYESTER

AND VII

CHEMICAL
ENVIRONMENT
Surtactants, Linear Primary Alcohol
Type-Ethanol
Surfactant, Nonionic. Alkyl Ether
Amine Oxide
Surlactant, Nonionic, Tergitol 15&9t
: : :
Surtactant, Nonyl Phenoxytriethoxy
EthanolType ........................
Surlactant, Polyethylene, oxy Derivative ......
Sweet Crude Oil ..........................
Sweet Oil ...............................
...
....
Sweetwater
35Dt: Acrylonitrile : : :
...........
Tall Oil
Tall Oil, Crude, ;.iO/.&en; hcid: Lien& &I 4:3
Tall Oil, 2% Spent Acid, pH1, Lignin
Tall 011: Sulfuric: Llgnin, pH3 ........
: .. : : :
Tannic Acid ..............................
Tanning Leather, Drums ....................
Tar Camphor .............................
Tariaric Acid .............................
Teller Scrubber, Wet Process P,O, Plant ....
Telonett. Fumigant
..
............
Terephthalic Acid: HCI: Dimeth;;
Formamide: Water ..................
..........
Tergitol 15&9t ..............
Tetrachlorocyclopentane Saturated with
Cl, and Trace HCI. Ccl., Dlcyclopentadleno
and Hexachlorocyclopentane
..............
Tetrachloroethylenr
........................
1.1,2, P.Totrachlorethylene
: ................
Tetrachlorophenol, Sodium Salt ..............
Tetrachloropyridino
.......................
Tetrakls (Hydroxymethyl) Phosphonium
Chloride ..........
.......
Tetrakis (Hydroxymethyl) Phosphonium
........
Chloride, HCI, Ii,0 Vapors .................
Tetrapotasslum Pyrophosphatr ..............
Tetrasodium Ethylenediamine Totraatate
.....
Tetrasodlum Pyrophosphatr .................
Tetrasodlum Pyrophosphate .................
Textonet Bleach
Thermolin RF-23Ot .........................
Thermolin RFe230t .......................
Thioglycol, Mono ..........................
Thioglycolic Acid ..........................
Thionyl Chloride ...........................
Thionyl Chloride, Vapor .....................
Thiosorbic Lime ...........................
Tin Fluoborate Pletlng Bath, 18% Stannous
Fluobrate; 7% Tin, 9% Fluoboric Acid;
2% Boric Acid .........................
Tin, Molten, 7W*F, Fumes ..................
Tinoflx DFt ...............................
Titanium Sulfate Ftsduction Process ...........
Tobias Acid ...............................
Toilet Tanks, Aircraft .......................
Toluene ..................................
Toluene @ 120F..
........................
Toluene Dllsocyenete .......................
Toluene Sulfonic Acid ......................
Toluene Sulfonic Acid ......................
Toluene, Vapor ............................
Toluene, Vapor 6 Condensate ................
Toluene, Vapor & Reflux ....................
Toluene: Xylene: Aromatic: Aliphatic ..........
Tolyl Chloride (0) ...........................
Toxaphene: Xyleno .........................
Transformer 011 ............................
Trensmlsslon Fluid, Automatic ...............
Tributyl Phosphate
Tributyl Phosphate: Aromatic Solvent .........
....................
Trichloroacetaldehyde
Trichloroacetic Acid ........................
Trichloroacetic Acid .....
....
.........

..........................

.........................

tSee

hst of wademarks

L ESTER RESI

;-ASHLAND

(continued)

SERVICE TEMPERATURE.F FOR RESIN TYPES

CONCEN.
TRATION %

HETRON
9Zi99P

HETROM
721197'197A

1W

12C

120

120
loo

12C
-

120
-

12011
-

loo

1W

28
100
100
98.2
10:30:60
Satd
100
Satd
Cone
14:287:51
100

100
100
loo
13
loo
loo

105
210

loo

AMB
-

200

200

200

All
loo
loo
Satd
65
loo
loo
loo
loo
86.3:5:6
100 @ 200-F
90:10
loo
loo
loo
35.65
100 @ 1WF
o-50
50

2W
250

AMWNR
NW-

loo
loo

12016s

loo
--ILS12ChNR
AM0

NR

ea1w

NR
-

NR
NR
120

120/-

17011701NR

NRI-

AMB

125

SO/NR
1ZY-

65-80
NR
lYX1501NR

130
22wOO

BOlNR
-

210/220
-

NR

NR

AMB
-

200
-

AMBINR

NR
NR

NR
-

AM0
loo
-

200

120

230/230/901--iNR
122
AMB

NR
-

150
loo

lW/-

NR

200

AMBIAMBINR
NR

150/150/-

SAT
AME
80

lW/-

lW/-

so/--

zoo/210/LS.AMBllW
NR/.30/210/210/-

AMB

AMB

ZlOi-

AM0lNR
AMB

AMB

NRI210/2101_

AM0

NRI2wi-

1501NRINRI-

200
22a2w
-

150

NR/-

180
-

95
95

12U/-

210;230
-

22012w
-

AMB
NIV-/NR

125
-

SATI-

SERIES!980

1801150
-

125
-/125
-/125

NWNW-

"ETRON
920

250
95
NR

120
-

2@J
2w

80

200
-

160/1w

SAT
6w220
-

Satd

50

140
-

HETROW
700 7ooc

100
-

16nilM

14af-

AMW-

80
All
5
Satd @ 75-F
Pure
Impure
loo
10
loo

AROWL
7240:7430SERIES

NR

200
AM0

LSlBOrNR

AM&-

NR

180

NR
2101-

180

210/-

and Droducl names

(continued)

Synthetic

TABLE 1.54:

POLYESTER

AND VINYL

ESTER RESI

;-ASHLAND

Resins and Polymers

215

(continued)

SERVICE TEMPERATURE. F FOR RESIN TYPES


CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Trichloroacrtonitrile. Trace
Acetonitrile and HCI ................
Trichlorobenzene
Trlchlorobenxene Vapors Wet wrth HCI : :
...
1, 1. l.Trichloroethane
1. 1, Z~Trtchloroethane .......
.. 1: : 1: : ...
Trichloroethylene
......................
I, 1.2.Trichloroethylrne
..................
Trlchlomethylene, 50%. ..................
Trtchloroethylenr: Chlorinated Orpanics:
........
Hydrochloric (32%) ... ...
Trichloroethylrne Fumes; 22% MI;
10% Cl,; 9% 0,; 6% CO; 4% H, ...........
Trichloroethylene, HCI, Ct,, H,O Vapors ......
.....
Trtchloromethane
........
Trichloromonofluommethane
... : : 111: .....
Trtchlorophenol ..........................
Trtcmyl Phosphate ......................
Trldecyl Benzene BulfonateDetergent
Base
Triethanol Ammonium Lauryl Sulfate ........
Trtethanolamine Llnaar Alkylate Sulfoneto ...
Trlothylamine ...........................
Triethylamine Hydrochlortde ...............
Trlethanolamlne .......................
Trtethylene Glycol ................
Trtfluorovlnyl Chloride, Oils and G&ares .....
Trthydroxybenxoic Acid ..................
Trtmethyl Borate In Methyl Alcohol* .........
Trlmethyl Carblnol .......................
Trimethylamlne Hydrochlodde .............
Trimethylamina Hydrochloride, pH 54 .......
Trlmrthylamine: HCI .....................
Trimethylamine HCI: Ethylene Oxide Reactlon
Trtphenyl Phorphlte ....................
Trtr (Hydroxymethyl) Nltromethane:
Formaldehydr: Water, pH3 ..............
Trtsodlum Phosphate .....................
Trtsodlum Phorphatr ......................
TunaOil .................................
Turpentlnr: Chlortno .......................
Turpentine, crude sulfate @ loOoF ...........
Turpentine: Methyl Alcohol .................
Turpentine, Pure Gum ....................
U-34EQt and U7000t. Styrene
Acrylic Emulsions .......................
Ultraformer Fead, Reflnory ..................
Ultralormer Faa&Xylena ...................
Ultraformer Heavy Faed. Rrflnery ............
Ultrawett BOK Blodagrrdable Detergent .......
Ultrawet 46DS Btodegradable Detergent ......
Ultrawrt WL Biodegradable Detergent ........
Underground, Clay Soil .....................
URAN Ferlllizer~Ammonium Nitrate
Composition; 44.3% Ammonium Nitrrtr.
35.4% Urea, 20.3% Water ...............
Uranium Bxtraction ........................
Uranium Fluoride, KOH, HF, KF, K.0, K,UO.,
Cb, KCI, KOCI, KCIO,, KCIO., CO,, K,CO,,
KHCO*, H,CO,, UO,CO,, F,, CIF,, DF, .......
Uranium SX Units .........................
Urea ....................................
Urea: Ammonium Chloride: Ammonium
Nitrate ................................
Urea: Ammonium Nitrate: Water .............
Urea: Ammonium Nitrate: Water .............
Una: Ammonium Nitrate: Water .............
Urea~Fonnaldehyde Resin ..................
Urea Modified Phenolic Rerln (Durazt 24942) ...
Urotropine ...............................
Vanasol @ 6ClF ..........................
Variquatt K-300 ...............
..........
Varisottt 222-90 ......................
Varoxl6SET..
..........................
Varsolt @ 2G1F ....................
Veneer
Drying Fumes ..................

tSeeltst01trademarks

and Droducl names

HE7RON
92199P

loo

100
-

NW-

100

NPJ-

100
100

NPJ-

100 @ 120-F

NFU-I175

14:0.9:85.1 @ 104F

NRJ-

175l12ui-

100 @ 80-F
1W
100 @I 175-F
100

HETROI
72119711971

AsomL
724017430 SERIES

NR-

NR
-

NR
-

80 -

NR

NR

NPJ-

NR

NR
-

NFU-

NR

212J212180
BOINWNR
AMB
NR

NFU-

NR

NR

NR-

NRJ-

NR

NR

NR

ml/NFV-

NR

120
80
-

80
loo
-

180
AMB
80

loo

AMBI-

&Id
-

15C:-

13W-

130
130
NR

122

9O/NR

Satd

NR

NW-

NR

lSo/120
NR

LY-

LS
-

SATlNR

-f90

120

AMBI-

15O.F

100

en
-

AM&--I-

1w
loo
-

1w
AMB

Satd

SAT

-Do

160

38:2.5:20

AMB
-

210/-

LS
AMB

NRIAMBilW

AM0

AMB

loo
-

loo

loo/-

SAT
1SOIAMB

SAT
ll301-

150190

80

100
@a-

12iX-

120

SATI1201120

120/-

120

120/120

NW-

120
SATISATI10 3w/3Wi-

120/-

AMB
80
-/SAT/NR

1201-

120
-

160/NFVSATI-

AMB

2cK3o:50
354420

loo
-

2101-

AMB

120

28
1
-

180

SAT

pli 78

lWi-

150
130
AMBI-

180
-

AMBIAMBI-

loo

130/-

1201-

150
AMB

AMBJ-

loo
SC++*.3 @ 320-F

4oI10:50

130
-

120

2s

51a8:49

to48:loB5Q

NR
-

-190

BW120
210/-

15OI-

lx)
loo
130

loo

loo
Satd a 75-F

too
1W
loo.37
-

120
NR
-

loo
SO

98
loo

NETRON
920 SERIES980

NR
-

85
NR

120

loo
loo

HETROW
700700c

120
SATINR
-

SAT

SAR-

120

1201-

120
120
SATINA
-

120/1201SAT,-

(continued)

216

Corrosion Resistant Materials Handbook

TABLE 1.54:

POLYESTER

AND VI NY L ESTER RESINS-ASHLAND

(continued)

SERVICETEMPERATURE.FFORRESINTYPES

CHEMICAL
ENVIRONMENT

CONCEN.
TRATION %

Vegetable Oils
:. : .....
Viddbn Dt Fumigant
Vinegar
.......
: ....
Vinyl Acetate
........
Vinyl Toluene
:
:
:
:
:
:
:
1 : : : : : : 1. .. 11 : .. :
Vlnyl Trkhlortde
VlvoZynet .............................
Wash Solution. pli 13.6 ...................
Washer Hoods, Ducts, Chlorination, CIO,.
and Brown Stock .. , ...................
Waste Oils, Gear. Cutting, etc., Treated with
...............
Lime and 93% H,SO.
Waste, Organic, H,O, HCI, Cl, Vapors ......
Waste Water Treatment
Water: Acid: Organic contambtated : : : : : :
.
Water, City (t&69 pal) .....................
Water, Condonaate. pH 7.342 with
NH,, NO,, SO., B, Cl, 0,, H,S .............
Water, Condensate, Buffered ..............
Water, Condensate, Traa Amounts Mercaptan,
H,S. Turpentine, Acetone ..............
Water, Condensate, Zero Hardness,
pH 8.595 @ 2W.210F .................
Water. Contaminated with Aromatic Solvents,
Salts, Hydrocarbon Rosins, Organics;
.
Slightly Acid to Basic ...................
..
wltaf, Cooling, ph 5.57 ..................
Water, Cooling, 26 ppm Chromate ...........
Water, Cooling lower .....................
Water, DelonLuP~ s ......................
Water, Doionized, High Purity 1.5 pmhdcm. ...
Water, Deminerallzedd ...................
Water, DistIllad .........................
Water, Drinking ........................
Water: Ethylene Glycol rg 212OF ............

Water,GoothomlJl........................

Water, Geyser, Condensate ................


Water, Ground, Organic(1.310 ppm)
Contaminated, Untreated, pH 5.7 .........
, ..........
Water, lrrtgatlon ...............
.........
Water, Light, FC195T ...........
Water, Light, FC203t ......................
......................
Water.09 Separation
Water. Organic: acid contaminated @ 15rYF ...
Watec pH3, pH7. or pH 10 ..................
Water, pH 5 to 9 (1.13 at tlmos) with
HCI: Cl,, Benzok Acld; Baruoyl, Bansal,
Bonql Chlorldoa Praaent .................
Water, 13,ooO ppm latk acid ...............
Water, 6.ooO ppm chlorobenzeno .............
Water, 166 ppm methylone chloride ..........
Water, 3,DW ppm 15ooctyl alcohol ...........
Water, 56 ppm Phenol ......................
Water, 566 ppm sodium chlorldo .............
Water Satd. with 1.525% Ozone in Oxygen ...
Water, Sea ...............................
Water, Sea. dorrllnatlon pH 7.5 ..............
Water, Sea, deaalinatlon pH 7.5 ..............
Water, Saa, dosalinatlon pti 7.5 @ 265.F ......
Water, Steam Condanutaa .................
Water, Storm Condonsate, Steam; Buried
......................
Pipe B upto2Ul.F
Water. Sulfuric: Aoatlc: Methylanr Chloride:
Octyl Alcohol: Sodium Chlorlde:
.........................
Chlorobenzrm
Water, Tap ...............................
Watr Treatment, Dye Plant, pH 2-3 ...........
Watn Treatment, SoHonIng
end Coagulating .........................
W8tar, Vapor 5 Condarwato~ ................

"AROPOL

_
_

COnC
100
100 Q 75-F

AM&-

1OOGi BO'F

100

100

NW-

HETRON
72:1971197A

NR
AM0
80

NR
-

NR

AROPOL
7240.7430 SERIES

HETROh
700~700c

1BOilM
NR
NR
-

2101220
NW-

NR
-

8Ol-

100'
-

100
150

SAT

NW-

NR
175

NR
-

150/150/NR

15OINR

100

l&X-

180

1801150

100

loo/-

AM&-

100
103
100

loo/160/-

loo
-

NW-

%x0
-

SATISAT'I-

100
180
180'
120
180
212/212/180
210/210/180
NR

NW-

LS/-

AM&160/-

100
100

NWAM&-

g&5:1.5.2
-

110
AMB
160
120
AMB
SATlSATlNR

180
120

1801120
1601140

2cK!l%

AMB"/-

1.7xNormal
2.75xNormal
100

2owNR

413:0.3:1.3:0.01:0.3:0.5:0.8 -

2p30.WOga~ tank

180
AMB/18011

2101220
2101220
AM&-

700 NR as mola~ng cpd


-

125l-

AMB
120'
AMB
SATiNR

Ah48
-

AMB
-

120

NW-

NR

NW-

120
150

150'

150'/120

150'
140
1%3

212'
NR

150
150

150
150

150
150
-

150

153
-

1Sc4u50

180

180
132
-/LSINR

Normal

120
210/220
-

AMBI-

AMB

l&l

180114O
-

18oiXl
AMB"!NR"

125

150'
150'
150'

12Y-

NW160/220

12Y-

NR
-

100
@15O'F

AME
NR

-I103

HETRON
920 SERIES'900

l.SOf-

96 5.2 1.5

"D~ssolvea SOCUS. 1574.21#~~m'f'O,


0.25Mm; fOra PD., 7.3pPm:
Cu. 0 7ppm. zn.3.4ppm; Fe. l.Bpprn:CaCo,
450ppm mex.; Chromate.
hexs. 1~22ppm. 0, resrdual. 0.20.45p~". NaQ
527.702wm
'@NO change m waler a! 0 1 It' lammarelgal. as m

WETROW'
92 VVP

210/-

lSou50

NR

15011501NR

1501NR

NR

l&I

1801150

180
-

180
AMB

180/-

NW180

AM0

212

Such es mefhylene chloride. 50 ~,wn: chlorolorm.


2;
tnchloroethylene
8 tncnloroelhane.
14:
alcohols. 7W. MEK 8 MIBK. 2X Benzenes. 105.
Acetone. 50 Phenol. 2 etc
AROPOL

7242 safrslaclory

7430 Set~SIac~ory.

(continued)

TABLE 1.54:

POLYESTER

AND VII

CHEMICAL
ENVIRONMENT

L ESTER RESI
CONCENTRATION %

Water, Waste with Pine Oil, Kerosene,


Methoxychlor, Melathion, Xylene, Detergents,
Chlorophyll, Surface Active Agents
and Other Oils
Water, Waste, With Solids. Oil, Grease
Water, Waste, Trickling Filters ...........
..........
Water, White
..........
::
Wax, Chlorinated : : : : 1. ... :.
Weed Killrrs ...........................
Whey ...................................
..............
Whiskry .................
White Liquor (Pulp Mill) ..................
.............
White Water ........
White Water, Splash 6 Spills ................
.......................
Wine Fermentation
Wine Storego ............................
Winery Waete ............................
Wire Pickling Fumes .......................
Xylone ..................................
Xylone @ 120-F ..........................
Xylene: Adogent 381 .....................
Xylene: Camphene. Chlorinated 68% .........
Xylene Derlvatlvr: T-Amine: Alkallne Metal
Salt: 10.20% Sulturlc Acid .............
Xylene: DXE; Trace li,SO.; Flake Caustic
Xylene: Koroaeno: 05% Phoaphortc ..........
........................
Xylene:Toxaphene
Xylene/Ultraformor Fnd ...................
....................
Zlmmltet, Mud Remover
Zinc Casting Fumos .......................
Zinc Chloride @ 310F .....................
Zinc Chloride .............................
Zinc Chloride Plrting Bath; Zinc
Chloride: Sodium Chlortde: Ammonium
Chloride, pH 4.862 ......................
Zinc Cyanlde Plating Bath, 9% Zinc rnd 4%
Sodlum Cyanides 9% Sodium Hydroxide ...
...............
Zinc Dimethyidlthlocarbanate
Zinc Electrolytic Collr ......................
........................
Zinc Fluoborate*
ZincFluoborste Plrting Bsth, 49% Zinc
Fluoborate; 5% Ammonium Chlortde;
8% Ammonium Fluoborate ..............
Zinc Hydrosulfite .........................
Zinc. Nick.1 Hydrophosphstr, HF rnd
Fluoslliclc ............................
Zinc Nltrste ..............................
Zinc Phosphate ...........................
Zinc Smelter Fumes .......................
Zinc Sulfate ..............................
Zinc Sulfite ..............................

tSe llsl 01lrsdcmarks

Unknown
-

(continued)

SESVICE TEMPERATURE. OF FOR

WETRON
9C99P

HETRON
721197!197A

AKBAMBI-

en

AROWL
7240 7430 SERIES

AM8

BT,PUB

AM0

AMB

AM0

100
@

BOF

ll@-

TYPES

HETRON
7001700c

80
AM0

AMB
-

HETRON
920 SERIES990

80
AM8
AM0
lBo12W

NR

17Y-

Bi:-

180
-

1501-

RESIN

AM0
110

AMB/AMBIAMB

9YNR
NR

AMB
NR

NRllOO
NW-

140

100

-rw

100

NW-

75125
10:90

5050@185

NR-

333335

l-2
70
Satd

l@Y2al

18.31:3 oLlga,

3.5
50

NW90
14W-

Satd

SATINWNR
100
122
100
NR

cwYxwoJSAT/SAT/-

loO/-

265

la5150

220/200

210/-

AM0

NR

180

160

-JlElO

80
180

210/-

200
lXU15O

200
250
-

160/-

140
-

2w

200
--153

NR

SAT
All
Sald

lt<)iNR
NR
-

100

160

S&d
Sald
Unknown

lSo/lwI-

100
122
AbIB/--/-

10%

NR
l&w50
15C:100

2001-

180
-

210/-

2201200
-

210/lBO/-

and c)roducI names

HETRON 99P tar turns service on/y


Good hst nsutts 8tkr short exposure
YJynmelic sudecing veil mxmmended
for mrximum resistance
BenZoyl PeIVXid8 - Dimefhyl uniline cure system recommended
t0 8Ssur8 satist8ctOty cervice
*Postcure recommended
Solulion
mry discolor
Nonthixotropic
ns@ prefenbk
_
....

=U/7SUtfSlUClO~

;-ASHLAND

217

Resins and Polymers

Synthetic

US Ill7hlg

Acceptuble
8s to odor 8mi Iusfe tar AROPOL 7242 fype resin. Steumed
4 hours with rtmospherlc
steam prior to exposurs
Three 3 hour exposures lo 30% nrtrlc 8t 100F to simukte cleenin
NO discvlorution
occurs et 5 rttfgul. ucid with AROPOL 7242 md A ETRON
700 type construction
M SlJ1f8soSS810 8cid or Steum C/UUned
rYY
- veil
. _ an/v
_ ..
aA ROPOL 7$40 only
uAppceIs to be eroslon/comXion
AROFOL 724LSATut 12Q.F
HETRON 197 and 700 series resins appear to be unsuitable under cychc
conditions
with some crazing but are resistant under static conditions.
Dissolved
solids, 1574-2163 ppm: PO,, 0.25 ppm; total PO, 1.3 ppm;
Cu, 0.7 ppm; Zn, 3.4 ppm; Fe, 1.8 ppm; CaCo, 450 ppm max.; Chromate,
hexa, 18-22 ppm. Cl, residual, 0.20.45 ppm; NaCI, 527.702 ppm.

NO change in water at 0.7 ft. laminate/gal.


gal. tank.
AROPOL 7530 SatiStUCtOrj.
MAROPOL 7343 SUtiSfUCtOrY

as in 20-30.000

Vol. % SO, 0.25; SO,, 0.03; CO, 12.5; N, 74.6; O,, 4.9;
H,O, 7.6; f/y esh, 5.0 grams fr; velocity 60 fps.
Vol. % SO,, 0.25; SO, 0.003; CO, 72.5; NI. 74.6; 0, 4.9;
H,O, 7.8; t/y 8sh. 1.2 grams fr; velocity 8 fps.
0.12% Sop%
O,ll2% CO,RO% NJ13.4% H,O; 5 grams/fr
of 1.2% tf,.S@, 2-3ooo ppm HCI. 1020 ppm HF, rust water.
z4Such as methylene chloride, 50 ppm; chloroform, 2;
trichloroethylene
8 trichloroethane,
74;
alcohols. 760: MEK 8 MIBK. 200; Benzenes. 105:
Acetone, 50; Phenol, 2 etc.
AROPOL 7242 satistactory.

TABLE

1.55:

POLYPROPYLENE

AND POLYVINYLIDENE

Chemical

Acetic Aad iGlacial


Acehc Acld 150%)
Acetic AnhydrIde
Acetone

(1 O%l

Acetone

150%)

Acetylchlonde
ACWlOnltrlle

Allyf Chfortde
Aluminum

Ammonium

Albmlnum

Chlortde

Alummum

Fluoride

Alummum

1Alummum

Hydrowde
Nitrate

Aluminum

Potassum

Sulfate

(Alum1

75

1 NR

Sulfate

! Ammonium

Chloride

1 Ammonwm

Fluorlde(25%1

Ammonium

Hvdroxlde

Ammomum

Nltrate

Ammonlum

Phosphate

Ammorxum
Sulfate
Amyl Acetate
Amyl Alcohol
Amyl Chloride

120
100
NR
225
225

Acid (31!?, w!? 0 3:, H&O.1

Chromyl

Chlonde

qromme~Dvl

NR

170

I/ Bromine(Llqu!d)

NR

170

Citric Acld

Bromme

120

1 Butadlene

NR

1 Bufyl Acetate

Water (25%)

NR

212t

75

NR

/ Butyl Acrylate
/ n-B&y Alcohol
1set-Butyl Alcohol
j F;f;;$A;rhol

NItrate

70t

275

copper

Sulfate

7ot

275
NR

NR

275

NR

Butyl Chloride

NR

275

150
225

212t
275

Butylphenol

Butyrlc

225

275

n-Bury

Mercaptan

1Calaum

Blsulfate

Calcum

Blsulflde

70

212t

Aud

Calclbm

Chloride

Calcium

Hydroxide

125

Calcium

Hypochforlte(PO%l

275

Calcium

Hypochlorltef94%1

Calcwm

Nitrate

Calcium

Sulfate

BarNurn Carbonate

70t
225

Barurn

225

Barwm f-lydroxlde
Banurn Sulfide

225
225

Benzaldehyde

70t
NR

/
/

275
275

120
70t
70t

275
275

Carbon Dlsulllde

275

CarbonTetrachlorlde

275
275

castor 011

125
170

(Wet1
(Dry)

150

150t

275

Dlmethyianllme

15ot
NR

275

DImethyl

70t
275

p-Dtoxane
Dtstllled

212t

275

Chloroacettc
Chlorobenzene
Chloroform
Chlorcsulfonlc

(15%i

212

NR

212t

NR
NR
NR

NR

EthyleneOxIde

Ferric NItrate

225

140

275

Ferric Sulfate

225

140

275

Ferrous

Chlorloe

225

275

Ferrous
-___.

NItrate

225

120
140

275

Ferrous

Sulfate

275

70

150

Formaldehyde
Formx Acld

140
__

70
NR

150

Fuel Oil
FUrane

275

Furfural

275

Gall~c Acjd

150

Gas-

Manufactured

70

Gas-

Natural

120t

70

Unleaded
Sour

12vt

275
70

GasolmeGasoline-

/ EthyleneChlonde
! EthvleneChlorohydrln

---I--

GlUCOSe

Glycol
~-

p-e

120

Glycol~c Aad

701
2121

Heptane

/
1

HeXarle

275

NR
70

NR

275

NR

275

NR

275

225
225

275

150t

275

150t
NR

70
275

75

275

140

275
275

Acid 12%)

225

275

Hydrochlonc

Acid flO%l

185

275

70
NR

Hydrochlonc

Acid 120X,!

175

275

Hydrochlonc

Acfd Cone l3E%I

150

275

~ 275

Hydrocyamc

Acid

140t

275

120t
100

212

Hydrlodrc

NR

Hydrobromlc

Aced i50%

225

NR

Hydrochlonc

70

225
_----t_
120t
i

NR

ACE 48$,

HydrofluorlcAc,d(35$1
Hydrofluorlc

Acid (70%)

Hydrofluorlc

Aud I1 00%)
Acid

Yydrogen

Chloride

Hydrogen

Cyanide

Hydrogen

Peroxtde

NR

230

+iydrogen

PerOxIde l90$1

230

iydrogen
,ydroge

Phosphlde
Sulftde (Dry1

70

250

7.
140

212

140t

275

140

275

275

275

275

1
1

(Dry1

NR
NR

130%)

70

/
I

7o
140

275

150

275

70

I
:

Glyceme

120t

I
,

275

Leaoed

Alcohol

250t

275

Gasoline-

1Ez;.srtate

Bromide

275
120t

140t
NR

NR

Yydrogen

Chloride

225
140

NR

2301

NR
/
:
I

137%)

150t

70

225

:50:,;

120

70

__)

225
NR

275

i
I
I

NR

.EDCI

140

Hydrofluoslllclc

Ethylene

NR
Acid

2121

i Ethyl
~Ethyl

NR

Acld !50%1

GlycO

140

NR

Water

Ethylene

275

Phthalate

NR

(5% I Ccl.1

Dloxlde

275

Dtabutylene
DImethyl Amne
I_
Dimethyl Formamtde

Chlorine

Gas [Wet or Drvi

225

275

Eplchlorohydrm

Chlorine

225

275

Esters
Ether

Chlorine

Borax

Ketone

275

275

Boric Aad
--

Dllsobutyl

275

230

275
275

275

70t
NR

150t

Black Liquor

Acid

DIchlor,oe

Ferric Chloride

Cellosolve

CellOSOlVe
Chlorine L,qwd

160t

Dtethylamine

Dlamlne

Ethylene

Fatty Acids

t
/

Ettylene

1201
275

275

/
-T,,

170

275

Fuels

Dlglycollc

225

I
NR
/
-+ -120t

Chlor,neWater(Saturated)

70t

, Dfesel

275

225

Capryl~c Acid
Carbon Dloxlde
Carbon Dloxlde

Dlethyl Ether
cDlethyleneTrlamme
120

Dlacetone
Alcohol ---/--

Dethyl

120

70

275

225

275

Acid

275

225

Cyclohexanone

225

Carbonate

-___

011

j Crude 011
~iie( Cyclohexanol
/

Chlorate

i
I

Cresyc
ACd
Crotonaldehyde

275

Calcium

140t

Benzene

225

Calcum

Cottonseed
CreSOl

~ Dextrln

212

i
1 NR (

Chloride

corn 011

275

275

120
NR

230t

225

225

275

225

225

Fluortde

Copper

I Copper

275

225

Cyanide

75

225
140

225

1Copper

275

/
,

1 275
I 275

(KYNAR)

140

011

Copper Chloride

70

I
/

Cocoanut

: 160
!
/
; 140t

Gas

70t

NR

1 tert-Butylamlne
Butylene
T___
Butyl Bromide

225

Coal

250

275
275

Aqua Regla
Arsenrc Acld

Benzyl Chloride

Chromic

230t

225
225

AnttmonyTr!chlonde

Benzac Acid
Benzyl Alcohol

275

LAnlflne

BenzeneSulfomc

225
NR

~sec.Butylamlne

~
/
/
1
(
,
I

and FLUOROFLEX-K

, Er1ne

120
NR

i 120t
, 70
1 212
;;:

(Polypropylene)

I BromtcAcld

275

Ammoma Aqua (30%)


Ammonium
Blfluorlde
Carbonate

70
NR

LINED PIPING SYSTEMS-RESISTOFLEX

Ratings for RESISTOFLEX-PP

225

AmmontaiDryGasi
Ammonium

70
212

120t

/
I

Acetoohenone

70
225
120t

Acetonttrife

Resistance

FLUORIDE

212
757
120t
275

(continued)

j
I
I
/

TABLE 1.55:

POLYPROPYLENE

AND POLYVINYLIDENE

FLUORIDE

LINED PIPING SYSTEMS-RESISTOFLEX

SE
IRE

(OF

SulftdelWetl

Hywchlorous

Acid

150
NR

Potaswm

Chlorate

225

275

Potassium

Chlorlae

225

70

275

Potassium

Cyamde

Naphthalene

225

212

Potaswm

1 Sot

Nickel

Chloride

225

275

212t

Nickel

Nitrate

225

212

Nickel

Sulfate

225

275

Monochlorobenzene

275

Morpholme

150t
170

Naphtha

NR

lodlne(Dryi
IodmeiLiqutd)
lodme (Wet;

70t

lodoform
Jet Fuel - JP4and

NR

JP5

NR

Kerosene

275
NR

70

Ketones

Lactvz
Acid
Laur~c Ac!d

Acetate

Lemon 011

I-

**

Dloxlde

70t
170

230

120

Acid (30%)

200

230

Nltrlc Acid - Cone

120

Propylene

120
NR

Sulfuric

250t

70
NR

Sulfuric

Acid (50%~ !60%1

175

225

275

Nltnc Acid -

NR

250t

NltrlcAc!d

250t

Nltrobenzene

140

275

Nitrogen

70

275

N~tromethane

(70%~

Fummg

250t
250t

Perchlorethylene
Perchlorlc

Ac,d (lO%l

Mercuric

150t

275

Perchlorvz

Acld(72%)

275

Phenol,lO%l

250t

225
70t
(50%)

;i NItros
/

Actd

Oleum

Fuming

Sulfuric

Oxalic Acld
Gas

275

Phenol llOO$,

i12t

Phenylhydrazme

275

Phosgene

IGas 8 LIquIdI

Methyl

Bromjde

NR

275

Phosphoric

Acid 130%)

Methyl

Cellosolve

75t
NR

275

Phosphoric

Actd (52%)

150

Phosphoric

And

tzot
NR

Phosphorus

120
NR

70
NR

70

225

212t

70
._

275
NR

at publication

* Not

recommended

in anhydrousconditlon

Not

recommended

I processes

where

jl

!
;

165%)

PentoxIde

Phosphorus

Trlchlorlde

Polyvnyl

225

275

Sulfurous

SilverCyamde

225

275

Tall 011

275

Sliver NItrate

225

275

Tann~c Acld

230t

Sodturn Acetate

225

275

Tartar~c Acjd

Sodium

Benzoate

225

275

Tetraethyl

Bicarbonate

225

275

Telrahydrofuran

275
250t

NR

Sodturn

IOleum)

NR

NR

t50t

212t

250t

Lead

225
NR

275

Sodwm

Blsulfate

225

Sodwm

Blsulflte

225

275
275

Terramethyl

230

225
NR

275

Sodium

Bromide

225

275

TOlUerla

120

70

Acid

120

275
NR

Ammonium

Hydroxide

150X,

212t
170

NR

70

140

75t

Sodwm

Carbonate

225

275

Tnbutyl

Sodium
--

Chlorate

225

275

Trlchloroacetlc

Acid i tOh1

70t

Sodium

Chloride

225

275

Trlchloroacetlc

Acid

Sodturn Cyamde

225

275

Tr~chloroethylene

NR

275

NR

120

275

Sodturn
S&urn
Sodwm

NR

Fluoride
HydroxtdellO%l

225

275

Trlethylamlne

225

Hydroxide

225

120
NR

Turpentine

150

212

UDMH-Hydrazlne

275

(50 x I*+

225

275

Sodaurn Hypochlorlte

225
140

250

Sodium

230

212t

70t

140
75

I
i

212
70t
275
275
275

temperature?
type

I1 7%1

Hypochlorlte(ZO%Y

Sodium

NItrate

150
225

Sod!m

NItrIte

225

Sodwm

Peroxlde

225

275
275
-

75

150t

275

NR

275

urea (50%)
VarSOl

225
NR

250t

Vmyl Acetate

NR

water

225

250t
275

White Acid (Ammonium

Trtsodlum

Phosphate

(50-501

70

Sodium

Phosphate

225

275

Sodium

Sltlcate

225

275

Dtfluonde

Sodwm

Sulfate

225

275

Sodwm

Sulfide

225

225

Sulfite
Thlosulfate

225

275
275

xytene
Zinc Chloride
Zmc NItrate

225

150t

275

zmc Sulfate

225

Sodium
Sodium

-_
reactlow

Phosphate

NR

70t

225

amalgam

11 12 8 22

70

225

mercury

Acid (96%)
Acld - Fuming

Sea wzter

alkylatlon

Sulfunc
Sulfunc

275

I
at htgher

130

120

212t

se

150

125

NR

Bromide

for

140

Acid 196%)

NR

Carbonate

factory

Acld (93%;

Sulfuric

212

Potawum

as m Frledel-Craftsand

Sulfuric

120

potaswm

consult

120t
212t

Sahcyl~c Ac!d

Acetate

230
170

120t

-I---

PICNICAcid

140

212t

Phthallc AcldiOrthol

150

Sallcyl-aidehyde

75t

Phosphorus

i76%1

170

140

140

Sulfuric
Acid

70

150

Alcohol

120

NR

Pyrogallol
Refrlgewlts

NR

Acldi

Pyndlne

120
70

70

Olelc Acid

Oxide

NR

120

Octane

NR

NR

50

Octane

Methyl

70

_NA_

Dloxlde

225

275

190%)

Acid50

-Sulfuric

Mercur~cCyan~de

temperature

Sulfur

NltrlcAcld150%1

Paimltic Acid

Maximum

250

230t

250t

Permanganate

150

140

__

Potaswm

70t

250

Ozone

Monoethanolamme

250t

250t

NR

225

Oxygen

011

Dxhlonde

Acid (10%)

275

Mineral

Sulfur

Sulfuric

250t

Milk

Sulfur Chloride

250

275

NR

Ketone

275

140

:20%1

Propane
Propyl Alcohol

n-Butyl

Methyl-isobutyl

Nttrate
Permanganate

225

70

Potaswm
Potaswm

130

275

Acid

275

250t
140

100

225
140

Chloride

Sulfur

Nltrlc Acid !30%1

Sulfate

Sulfuric

212t

275

Magnesium

Methylene

225

70

NItrate

Methyl

Hydroxide

225

Magnewm

Potaswm

Acid (5%)

275

Ethyl Ketone

275

s Solvent

Sulfur
Trloxide

225
225

Methyl

Stoddard

Sulfuric

Methyl Chloroform

i-

275

275

Hydroxide

Methyl Chlonde

225

275

Magnesium

Methane
MethaneSulphonlcAc!d

Ferrocyanlde

225

275

Mercury

275

Potasswm

225

275

Nttrate

120t

Sulfide

225

Chloride

Stearlc Acid

Sulfate

225

Mercunc

275

Potassium

Chloride

(40%1

225

Potaswm

Carbonate

Chloride

275

Dlchromate

Chloride

170

Magnesium

Mercuric

225

Magnewm

Maltc Acld

Stannous

150

011

Mercaptan

275

N~trlcAcld(Z%)

Lubncatmg

Malelc Acid

275

225

NltrlcAcld(lO%)

L~noletc Acid
Linseed 011

225

125t

Lauryl Chloride

c Lead

275

275

NlCOtlne

Nlcotlmc
Acid

It.,

Sour Crude 011


Stanmc Chloride

125

140

120%)

Lactx Acid ,60%1


Lard 011

Ch.mul

D~0Pl-A

Chembc,l
-

&y

Hydrogen

PVDF

POW

PVDF

Ck.ld

(continued)

250t

8 HCI;

250t
212t
275

NR

275
-

275

___~
***

1s formed

Polypropylene
from

NR

Not

the

IS not

formatnon

recommended

recommended
of sodium
-

severely

where

hypochlorlte

affected

tree

chlorine

or from

IS present

deCOmDOSltlon

as a residual

reactant

220

Corrosion Resistant Materials Handbook

TABLE

1.56:

ACETAL,

NYLON

AND

POLYESTER

DELRIN

RESINS-DU

Acetal

PONT

Resins

Resistance

Resists weak

acids (pH 4). Not recommended

in strong

Basic Resistance

Resists weak

bases (pH 9). Not

for strong

Solvent

Excellent
resistance to a wide variety of solvents,
gasoline and other petroleum
hydrocarbons.

Acid

Resistance

ZYTEL
Acid

Resistance

Base Resistance
Solvent

Resistance

Resistance

Base Resistance
Solvent

Resistance

ethers,

acids.
alkalies.
oil, greases,

Resins

Limited.
Attacked
by strong acids. General order of resistance 612>66>
copolymers
or 6.
Excellent
at room temperature.
Attacked
by strong bases at elevated temperatures.
Generally
excellent.
Some absorption
by such polar solvents as water, alcohols,
and certain halogenated
hydrocarbons
causing plasticization
and dimension
changes.

RYNITE
Acid

Nylon

recommended

Polyester

Resin

Good at room temperature.


Attacked
by strong and weak acids at elevated
temperatures.
Good at room temperature.
Attacked
by strong and weak bases at elevated
temperatures.
Excellent
resistance to a wide variety of fluids such as gasoline, motor oil,
transmission
fluid, hydrocarbons
and organic solvents. Some absorption
by ketones and esters causes plasticization
and small dimensional
changes.

Synthetic Resins and Polymers


TABLE

1.57:

EPOXY,

FLUOROPOLYMER

AND POLYETHYLENE

DURCON
DURCON
Olrrrn
--.__

TFF

Durco
Symbol

Silica filled epoxy


Glass fiber reinforced

PFA
UMPE

__._..I_.__...

1
1
1

*Most

Durco equipment

totally

lined with TFE

eooxv

polymer

T~trnfltlnrnPthylene
.

TFF

Durco PFA
Durcothene

Max. Service
Temperature

Description

DU6
D700

6
700

RESINS-DURIRON

NON-METALLICS

DURCO
Durco
Designation

221

Perfluoroalkox
y polymer
Ultra high molt ecular weight
polyethylene

is limited to 300

215O
225O
400
400

F (102O C)
F (1070 C)
F (204O C)
F (2040 C)

200

F (93O C)

F (149OCI.

__rr_.

ynn-r

silver nitrate

. .

.._._

IG&E
Ic
Is

IE

Ferrous sulfate

Formaldehyde

Formic acid
Glvocrin. crude

HCL waste pickle liquor

Hvdrochloricacidc150F&50CI
Hvdrochloric

cid>15~F65Ct

_.. ___.___
jW
/Lactic

acid

Lead acetate

E
-

E
E
E

E
E
E

G
E
E

E
E
E

r-1

IG IP

Ii

1:

1G

IG

IE

IE

1;

1;

IE

JE

(continued)

222

Corrosion Resistant Materials Handbook

TABLE 1.57:

EPOXY,

FLUOROPOLYMER

AND POLYETHYLENE

RESINS-DURIRON

(continued)

Sodium

_Mangawse chloride
Mercur,c chloride
Mercuric

E
E

E
E

E/E
E

G
E

G
EiE

nrtrate

Mercuric sulfate

I Mercuvcus sulfate

7-E

IE7ElF

SE

jG(GjEjG

Oleum

IP

Oxalic acid

IGIGIE

Phenol

iElPiE

Phosphoric acid
1 +2%H,SOd.l%HF
_
.
c
Phosphoric acid, all strengths

(P

E-1

E-1

SI

(E

1P
G
P

tSlPlEtE1
G

Picric acid

GGE

Phthalic acid

GGEE

E
E

Potassium bisulfate

Potassium chloride

Potassium

hvdroxide

Oleic acid

E
E

Nftric acid. all strengths


Nitrobenzene

Nitric acrd + 3%.

5% HF

bisulfate

I Tar and ammonia

E = Excellent - Virtually
unattacked
under all conditions.
G = Good - Generally
S = Satisfactory - Suitable under Some conditions: not recommended
for remainder.
for details. P = Poor - Unsuitable
under ah conditions.

TSlSrEl

El

acceptable with a few limitations.


Consult The Duriron Company,Inc,

Synthetic Resins and Polymers


TABLE

1.58:

ISOPOLYESTER,
RESINS-AMOCO
Comparison

HALOGENATED
CHEMICALS

of commercial

AND BISPHENOL

corrosion

resistant

A POLYESTERS,

resins

after

AND VINYL

one year

223

ESTER

immersion

The lengths of the bars reflect the tested performance


of the resins after one year in the indicated environments.
The Composite
Ratings are the ten year performances
projected
from the 1, 3, 6 and 12 month evaluations. All
laminates were made according to ASTM Method C581 with a glass fiber content of 25f2%.
To assure high quality,
the ATLAC-based
laminates were supplied by ICI United States. The other laminates were fabricated in the laboratory.

Flexural
psi

MPa

I
I

20

5.000
I

Flexural

Strength
1 cl.000

40

60

I
80

15.000
I
I
100

I
120

20.000
I
I
140

I
160

25.000
I

3
3

Modulus

200,000
400.000
I
I
I
I
I
1000
2000
3000

600.000
I

4000

800.000
1

5000

6000

l.Ooo.oKJ
I

7000

8000

Corrosion Resistant Materials Handbook

224

TABLE

1.58:

ISOPOLYESTER,
RESINS-AMOCO

HALOGENATED
AND BISPHENOL
CHEMICALS (continued)

10
I

1. ICI United States

20
I

30
I

AND VINYL

ESTER

Composite Ratings

Barcol Hardness
0
I

A POLYESTERS,

40
I

2. Dow Chemical Company

50
I

60
I

3. Hooker Chemical Corporation

H,O at 71C
5% HNO,at 71C
5% HCI at 71 C
25% H,SO. at 71C
X2 Fuel Oil at 23C
Ethyl Gasoline at 23C
Unleaded Regular at 23C
Benzene at 23C/time
to failure

excellent
good
good
good
excellent
excellent
excellent
1 year

H,O at 71 C
5% HNO, at 71 C
5% HCI at 71C
25% H,SO. at 71 C
X2 Fuel Oil at 23C
Ethyl Gasoline at 23C
Unleaded Regular at 23C
Benzeneat 23C/time
to failure

good
excellent
good
good
excellent
excellent
excellent
3 months

HI0 at 71C
5% HNO,at 71C
5% HCI at 71C
25% H,SO, at 71 C
#2 Fuel Oil at 23C
Ethyl Gasoline at 23C
Unleaded Regular at 23C
Benzene at 23C/time
to failure

good
acceptable
excellent
excellent
excellent
excellent
good
6 months

H,O at 71 C
5% HNO,at 71C
5% HCI at 71 C
25% H,SO, at 71 C
X2 Fuel Oil at 23C
Ethyl Gasoline at 23C
Unleaded Regular at 23C
Benzene at 23C/time
to failure

good
excellent
good
excellent
excellent
failure
acceptable
1 month

H,O at 71C
5% HNO, at 71 C
5% HCI at 71C
25% H,SO, at 71 C
X2 Fuel Oil at 23C
Ethyl Gasoline at 23C
Unleaded Regular at 23C
Benzene at 23C/time
to failure

acceptable
good
acceptable
good
excellent
excellent
good
6 months

TABLE 1.59:

POLYSTYRENE,

SAN AND ABS PLASTICS-MONSANTO

The data shows results under Test Procedure ASTM D.543, h&tante of Plastics to Chemical Reagents. This method requires molded
two-inch diameter disc specimens to be placed in a separate container
and totally immersed for 168 hours (seven days) at 73.2F. Appearance,
weight and dimensional changes are noted as evidence of chemical
attack. To obtain information on chemical resistance at elevated temperatures, these immersion studies were repeated at 50C (122F) and
the results are set forth under the column Heat Reduces Resistance.

The rating of certain reagents is followed by the designation ( t ).


This designation indicates that the reagent was applied to a bar specimen which was then placed in a bending jig and held under constant
29& outer fiber strain at 23C (73F) for 72 hours.
TEST CLASSIFICATIONS
73 - Resistant. No visual change
MR

ModeratelV

Not ReSiStSnt.

Resistant

Some

WRS observed
visual

in the plastic for 1 duratoon of the test.

change

(discoloration.

crazmg.

The plastic was severely crazed. or was softened.

checking)

or was d6solved

occurred.
by the end of the test.

Chemical Resistance of Lustrex and Lustran Plastics


~LUSTREX POLVSVYRENE~

SAN

LUSTRAN

lLUSTRAN

ABS

LUSTRANa

LlJSTREX*POLVSTVRENE
73-F

H#st Reduces
Resistance

73-F

SAN

LUSTRAN

tImat Redwas
Rnistanw

ASS

73-F

Acids
Acetic l-5%

Yes

NO

Acetic 25%

MR

Yes

NO

Acetic 50%

MR

Yes

Yes

X
R

Acetic Glacial 100%

Benroic

Yes

NO

Boric

Yes

NO

ButYric

Carbolic 50%
Carbolic

100%

Chromic 20%

A
j

Yes

Yes

No

MR

Chromic Sulfwc
Acid Mixture

Alcohols
Yes

n-AmVl

MR
R

YSS

Yes

Benzovl

Benzyl

Butoxyethanol

n-Butyl

Yes

Yes

SK-BUWI

Yes

Ally1

Ten.-Butyl

Octanoic
Oleic 1 DO%
Oxalic 10%
Palmitic

MR
R
MR

Yes

Yes

Yes

NO

NO

NO

Cetvl

I-

MR
R
IR

NO
No

Cyclohaxanol

Yes

Yes

Oecyl

Diacetone

Yes

X
-

I 2.Ethoxvethanol
Ethyl (denatured)

I-

I-

-iXI

Ethyl Formula 30

MR

Y%S

Yes

Ethvl 95%

MR

Yes

(continued)

TABLE 1.59:

POLYSTYRENE,

SAN AND ABS PLASTICS-MONSANTO

Methylamyl

Yes

Nonyl

NO

WOCtYl

NO

NO

(continued)

Dlmethylformamade

1 x

Dlphenylawne

nl~thlrnrtrlmlne

I MR

Ix

IX

Yea

NO

Dlephenylemmine
(Carbazole)
Ethylenedaamme

MR

lsopropylamlne

Pel-WlFlm,ne

Twhopropanolamme

No

1 MR

Trlethylenetetramme

X
X

Cosmetics

No

Cyclohexane

Methylcyclohexane

No

Alcohol

5DA40

Yes

Perfume

MR

LallOlln

Cyclopsraffins
Alkalies
Ammonia

(aqueous)

Ammonia

Hydroxide

(cont.)

Yes

YeS

NO

(continued)

TABLE 1.59:

POLYSTYRENE,

SAN AND ABS PLASTICS-MONSANTO

(continued)

LUSTREXPOLVSlYRENE
Group

73.F

nut Rsducaa
Rssinsnsr

LUSTRAN
73-F

SAN

LUSTRAN

nut Rsdacss
Flaaistsnu

ABS

n-r

Foods
L

Black

Peooer

(fresh)

_r

Butter
Carrot

Juice

Catsup
C*la#., C*l*

Glycol
Dibutyl

Mono&hyl

Ether)

Phthalate

Ix

jx

Che...__

\~______I
Graw

fconc.l

Chicken

SVYr

,uv,vu.,

Cinnamon,

Ethyl

Chloroacetate

Ethyl

Lactate

Ethyl

Salicylate

Benzoate

lsoamyl

Acetate

Isopropyl

Acetate

Methyl

Acetate

Methyl

Benzoate

Methyl

Laurate

Foods

Fountam

Syrups

Chew,

Chocolate,

Orsnee,
Root Bear,
StraWbarrY,
Vanilla

ii

Oil

Fl

NO

MR

Yes

NO

Rt

Grapefruit

Grape

Gravy

Beer

(Over

m-0,

I,*irm

R
3.2%

alcohol)

R
-

Oil

Crirco

(Bourbon)

Beef

NO

Yes

R
Pt

NO

NO
-

Yes

I -

Ix

-I

Yes

Yes

MR

NO

MR

Yss

NO

1 MR

Yes

No

/hIA

1
I

No

1
I

Oil

Liver

Almond

Fat

Extract

Butter

Alcohol
Bacon

Yes

x
_

Ethyl

I-

Coca-Cola

Cod

NO

.__

Coca-Cola

Coconut

pwd.

_ _.. _.

Clove 011

Cocoa

NO

Chicken

Rt

Garlic

Salt

Gin
Ginger

Ale

Ginger

Ale
Juice

Extract
Juice

Yes

Yes

YeS

Rt

MR

NO

NO

MA

(continued)

TABLE 1.59:

POLYSTYRENE,

Yes

NO

MR

NO
-

No

(Curtis)
Lard
Lean Beef
Lemon Emulsion

Flavoring

SAN AND ABS PLASTICS-MONSANTO

Lemon Juice, Fresh

IMR

Lemon Oil and Peel

Ix

Ix

(continued)

R
-

1
I

Leaves, Caraway
Seed. Celery Seed.
Cinnamon

(Stick),

Coriander

(Whole).

Cumin Seed, Dill Seed,


Fennel Seed (Whole),
Marjoram.

[ Parsley Flakes

IRt

Mustard

0
4

s ::

ZtL,

t;
3

I
I

1
I

ILrclElLLILl

nflslll

IIIlIIIIIIIII

UC=

I I
I zP

I ==

Synthetic Resins and Polymers

zol

229

TABLE 1.59:

, SMP

POLYSTYRENE,

SAN AND ABS PLASTICS-MONSANTO

LUSTRAN

LllSYREX*

WLYSYYRENE

73-F

nm nducm
Raistanu

73F

SAN

Ihat Reduces
tksistanu

LUSTRAN
73-F

Chloroform

a-Chloronaphthalene

Ethanol

Chloropropane

o-Dichlorobenzene

P-Dichlorobenrene

Dethylene

Chloride

Ethyl Chlonde

ASS

Halogensted

Hydrocarbons.
Chlok

(continued)

(gas &

Acetophenetldm

NO

Adrenalin

Yes

Adrenalin
Aspwn,

Hydrochlonde
m 011
pwd.

Trichlorobenzene

Trichloroethane

Ttichloroeth,ylene

Gum Tragacanth

Tnchloropropene

Iodine

83%

Iodine

(T~ncfure

Katonas

8 Ethers

Gum Acacia,

pwd.

U.S.P.)

Acetone

Mentholatum

Acetophenone

Menthol

/x

Crystals

NO
NO

YES

Yes

1 -

IX
i-

(continued)

TABLE 1.59:

POLYSTYRENE,

LUSTREX
13-F

GWlp

SAN AND ABS PLASTICS-MONSANTO

LUSTRAN

POLYSTYRENE
Flea1 Reduces
Resistance

73-F

SAN

LUSTRAN

Hut Reduc@s
Resistance

ASS

Salts

Mercurochrome

MR

Ammomated
Merthiolate,
Novocain

Yes

Omtment.
tincture
(2%

Ml?

NO

MR

Yes

NO

Pectin, sat.

Yes

Penicillm

NO

Yes

Petroleum

and 4%)

G
Jelly

__ Jell
_ I,
,bolated
car
n..;uullline
rrra-hnin.
.,.,......
S,df.dia.inP
__ ___-. .^._ _..*
a,,, n1IIIIIITIII
P*trolaum

C..I..-

MR
R
R

1 MR
..aq

Yes

N
.._

I -

Yes

..

Nn

--

R
-

POLYSTYRENE,

73F

Haat Raducos
Resistance

/ -

Stearate

Calcwm

Elromlde

Calcium
Calc,,.-

Chloride
Y ..^^_ &.,^.,A^

me.

Calcium

nypocnlc ,rite

pwd

Calcium

Oxide

Calcwm

Sulfate
-

Copper

xloe

Copper

Sulphate

Cupric

Chloride

Cupnc

Sulfate

Cuprous

1
I
,1

R
L0

NO
Vnr

R
n
n

Yes
.1_
I

MR

No

iR

R
X

X
D.

25%
25%

Oxide

Ethylene Oxide
Ferric Amm__...-

_
NO

Oxide

Dlphenyl

1
: 73F

25% Sol

Ceslu

LUSTRAN

e..,...

Ferrous Sulfate

sag.
25%

Hydrogen
Ammonium

Salt.

Sulfide

Hydroqulnone.

sat.

Hydroqumone.

4%. sat

__AA.____._

LrdU

-r>er1015

Lead NItrate

Resistance

NO

NO
_

_
R
-

No
I.

I.

I?

,R

No

No

.I

i
1

&I^

R
-

I0

NO

V..*

NO

Ye5

Y8S

MH
..-

L.D..

lllll

/_

I0

j-

,_

L,.

Yes

I
j

NO

Magneswm

Carbonate

NO

No

No

I
1
I

_
-

5% ov,d

R
MR

Yes

IR

Yes

No

Bromide

Chloride

Magneswm

Mercury

ABS

73-F

,es

n.

Lead Acetate

LUSTRAN

Heat
Reduces,

MR

Ferrous Sulfite

Femc -
Ferrous ~n,or,qe.

SAN

Cadmium

1
I
/

!LUSTREX

CKIUP

73-F

Pharmaceuticals
Mercury

(continued)

(continued)

TABLE

1.59:

POLYSTYRENE,

SAN AND ABS PLASTICS-MONSANTO

LUSTRAN*

LUSTREX*POLYSlYRENE
73.F

Group

Haat Rldua
Resist*nu

73-F

SAN

Ifeat Reducn
Rasistanu

LUSTRAN

(continued)

ASS

73F

Salts
Potasswm
Sulfate.

Aluminum
sat.

Potaswm

Bxarbonate

Potasswm

Bwlfate,

sat.

Yes

No

NO

NO

MR

NO

NO

Chrome Alum.

Yes

Potawum

Ferricyamde

Yes

NO

Potassium

Iodide. sat

Yes

NO

Potassium
.zilt

Permanganate.
MR

NO

Yl?S

Potassum

Bromate

Potassium

Bromide 3%

Potassium

Chloride

Potassium

Sodwm

NItrate

R
MR

(continued)

TABLE 1.59:

POLYSTYRENE,

SAN AND ABS PLASTICS-MONSANTO

LUSTREXPOLVSNRENE
73f

GKIUP

Heat Rduca
Resirtuw.9

LUSTRAN
73F

SAN

Heat RDducDs
Rnistrncs

LUSTRAN
73F

Miscellaneous
Benzomtnle

Benzyl

Benzoate

(continued)

ABS

Group

73-F

Yes

Decahydronaphthalene

NO

Detergents

Rt

Ri

Fit

NO

Joy (5%)

1MR

NO
NO

Cresolic Compounds

MR

NN-Diethyl-M-Toluidine

DimethVl Sulfate

N,N-D~methylaniline

n,nrilnn

Distalled Water

Yes

No

NO

Flutd 4

R
-

Dow Cornmg Fluid 200

No

Dowtherm A

NO

MnO.
MR

3%. sat.

Ethylcellulose

MR

N-Ethvlaniline

Yes

1 -

Ix

Eugenol

IX

Flit, insecticide

1MR

Freon II

and N&Cl

I-

Elan (Photoa.)

Yes

Carbonate

D~v Cell Solution

ABS

73-F

Dow Corning

Ml7

LUSTBAN

DDT

Diethyl

MR

73-F

SAN

Heat Roducm
Resistmu

P-Cymene

Der0rn

Cottonseed Oil

HIat R#duces
Rnistancs

Miscellaneous

Detergent -

Colloidal Sulfur

LUSTRAN

LUSTREXaPOLVSNRENE

(continued)

TABLE 1.59:

POLYSTYRENE,

SAN AND ABS PLASTICS-MONSANTO

(continued)

USTRAN

L
I

73'F

TVdOl

Motor

Oil-Sunoco

lsobutyronitrile

Ivory Soap

Lactose, sat.

Yes

Lestoil

NO

/x

~1

X
-

/-

I-

m-Nitrotoluene

Nitrous Oxide

Yes

Nqol

Anise Seed

Clove

x
x
x
x
x
x
x

Lilac (Aflificlal)
Nutmeg
Peppermmt

Roses

Rose Geranium.

Mesityl

Oxide

Metalltc

Mercury

Metalltc

Sodium

dl-Methionine

(powder)

MR

Sandalwooc
Sassafras.
Spearmint. Sweet

Almond,
Oil-Light

Wrntergreen
Machme

Olive 011

Ozone (abs of light)

Moth Flakes

1 MR

Yes

IX

-X
WR
R

-- I1- -1
No
_

iR

IR

No

NO

WR

No

Paraff I

WR

Yes

No

NO

Para 011

4R

Pentasol

Phenol 5%
-

Palm Oil

Paraffl 011

Morpholine

Ix

Oil of

Nitromethene

Nitroglycerin

X
-

IIFI

clean
..-.-_____

MR

Nepnthslsne Base Gear


O+Telachron

Mr.

AB!

Phenylacetomtrlte
Phosohorous. White

HR
_
HR

Yes

Yes

NO

(continued)

TABLE 1.59:

POLYSTYRENE,

LUSTREX
73F

Group

SAN AND ABS PLASTICS-MONSANTO

LUSTRAN

POLVSTVRENE
flea1 R&ms
Resistmn

73-F

SAN

LUSTRAN

Heat Reduces
Rmsistanu

(continued)

AES

73-F

Miscellaneous
Pine

Needle

Oil
Ix

IX

Impact materials less resistant.


Impact materials not tested.
tTested under 2% constant strain.
ttComposition

(White

Spirits)

Sucrose
30%
Sulfur

Dioxide

(Moist)

Tenite

NO

Yes

Tetrehydrofuran

Tetralin

No

Texaco
3-In-One
Thmyl
Tobacco

Motor

Oil

Oil
Chloride
Tars

Triethanolamine

IR

NO

ii

may vary, each formulation should be checked individually.

corrosion Resistant Materials Handbook

236
TABLE

1.60:

POLYVINYL

CHLORIDE,

80F.

POLYPROPYLENE
KEY

to

the

temperature t~mta-

,,on 01 the material I cases


where chern~~al bolls belowth,s
IimItatIon. resistance 15 Intended to beshownuptothebolltng
pomt

RIGID PLASTIC

AND POLYETHYLENE

RECOMMENDED

CONDITIONAL
may be suit_
able but ConsuIt Atlas before
w3ng.

NOT
RECOMMENDED

FABRICATIONS-ATLAS

FABRICATIONS

CHCHCHCH

CHCHCHCH

Acetaldehyde

N;N

NC

N,C

Chlorrne

gas, wet

NlN

Acettc

acrd. up to 10%

R ,R

CiR

RR

Chlorrne

water

Acehc

acrd. glacral

R,R

R:R

R:R
R

Alum

Alumrnum

Chlorfde

R.R

Alummum

Nrtrate

RR

Alumrnum

Sulfate

RR

Ammonrum

Chlonde

RR

Ammonrum

Hydroxrde

Ammonium

Nitrate

Ammonrum

Sulfate

c . R i
-.
R

R;R

RIR

R:R

R.R

Amy1 Acetate

N:N

N~tN

Amy1 Alcohol

Anrline

Aqua Regra

RCNNNNN

Barrum Chlorrde

Barlum

Hydroxrde

Barrum

Nrtrate

Chloroacetic

acid

NON

N;N

R.N
C
C

N1.N
N/C

N
N

N-:C

Chlorobenzene

Chloroform

N.C

Chromic

R.R

acrd. up to 5% ~-

Chromrc

acrd. 10%

Chromic

actd. 20%

RR

Chromrc

acrd, 50% and over

N[C

NR

NR

N;R

N +_f4

RR

Crtrrc acid

RR

RR

Copper

Chlonde

R,R

R:R

Copper

Nnrate

RjR

RI-R----

Copper

Sulfates

RR

R-R

RiR

R,R.N

N./C

NN

Drchloroacehc

actd

R
N

Drch!orobenzene

NNNNNN

R:-R

R,R

Drethyl

R.R

R-R

RR

Ethyl Acetate

RIR

R,R

Ethyl Alcohol

Barrum Sulfide

C!R

CR

Ethyl Sulfate

N:C

Benzene

Ethylene

Chloride

N:

N.

Glycol

R;R_R

Benzene

sulfonrc

Benzorc

acrd. 10%

I~

-.

N.C

Ethylene

Formaldehyde

Formic

Gasoline

acrd

Fluosiltcic

Bone acid
Bromrne

water

NtN

Alcohol

N
-A

acrd

N,C

Butyl

Acetate

Butyl
Butync

ether

i
R;R

N,Ni

R!R

C;R

N.pmmt
N:N

Hexane

Cadmrum

Nrtrate

Hydrobromic

Cadmtum

Sulfate

NC

R.I__RJ I Rmc

~~_.. - ~_._.._._-R.-

acid

R ~. .-R,R
R
R
R:R
__---_-i_~-_i_---_-

Bwlfite

R
~.

Calcrum

Chlorrde

Hydrofluonc

acid, 3040%

Calcium

Hydroxtde

Hydrofluosrlicic

Nrtrate

Hydrogen

Peroxide,

Drsulfide

Hydrogen

Sulfide

50% _.
gas, dry

R
._
A

- R;R
.._--.
R
R

Tetrachlorrde

Hydrogen

Sulfide

gas, wet

Carbon

C
_~
C
R

acrd. 10%

Carbon

R -.._RsR
RIR
RIR
__
.T .___~_.___
7m-m
CR
~_
_____~~~ R - C.?.. N-_*- NI R/_.__...
R
acid, 20%

Hydrochlonc

Calcrum

N
N

R;R ~_~. CIR


C;R
_~__~_-____-_
R .j ~__
R
R/R
R/R
+ --it__..

Hydrocyanrc

Calcrum

~~ .~p-_~-_j ~~_.___.._.

Chlonde

N!N
-N:ti
N
m-i _ .___..~__.

R ~..
R
R_ ~R __.i
R
R_ .R
~_ _.~. R..~ __.
R
R
R
R
R
C
R
C~~
._~ R _N? R-- R, .R~
R
N
G

acrd

Cadmrum

.-

_. ~~~_
~_~__~~R-.__R
c-5

acrd

Glycerine
-~. --~
Gold Cyanide

_._

acid

RIR
I-_-

R/R
R/R
-mIm__t__-__

R
RIR
__c R~~ -_i_-__RIR
~__---t---~C;R

R;R

RiR

Iron Chlorides
Chlorrne

gas, dry

Iron Nitrates

(continued)

Synthetic Resins and Polymers


TABLE 1.60:

POLYVINYL

CHLORIDE,

POLYPROPYLENE

CHCHCHCH
Iron

Sulfates

AND POLYETHYLENE

Potassium

R,R

R
RiR
~~~~- 1. ~-R!R
CCR

Magnesium

Chloride

RR

RR

Magnesium

Hydroxide
.~~

R
R
~~._

Magnesrum

Nrtrate

RiR

Magnesium

Sultate

Lrnseed Oil

__~~~~

..-

Maleic acid

R:

R,R
~.~~ -__

Silver Nitrate

Sodium

Chlonde

R
R

RR

Rj_R__R

Sodlum

Hydroxide,

Sodium

Hypochlortte,

up to 3%

Sodium

Hypochlorrte.

15% and over R

Sodium

Nitrate

Sodium

Sulfate

Sodium

Sulftde

__..

R !R
.~~~_~
RIR

Sodium

~~ ~_~_F~~!?!

R
!R

R;R

R?R
-_R/R

RR

R ,R

1 RRI~R~_.RJ.

.._

RRRRRR

Methyl

Acetate

Methvl

Alcohol

Methyl

Ethyl Ketone

Acetate

Carbonate

R
RIR
~~
R/R

R
RR
CR
~_r ~~ _~.
__+_-R
1J--F,
R - .~_
RIR+._
R~~_-___
R
RR
R
N
N/N
NiN
N;N
N

Mercurrc

Acetate

Sodrum Brcarbonate

~~.__~~Sodium

RRRRRR
...~~~~~~.__

RRR

R
_._

- --

Nitrate

Isopropyl Ether
..__
__ NLC_._N~LC_~mNPotassium Sulfate
N + N
Kerosene _
R
RR
N:C
N
.._ ___.___
~
~_~~~_~~
mm_
~~_ RC
i.- ----+--_.
Lactrc acid, 25%
R
R; -R
R/R
R
_~ ~~______--_c
A-_iRIR ._._~~.
Salrcylrc acrd
Lead Acetate
R
R;R
R,R
RR
R
R

FABRICATIONS-

CHCHCHCH _____-

~-

~~~~~-R
N

Lead Nrtrate

237

R/R

RR

RIR

Sodium

Sulfite

Sodtum

Thiosulfate

30% and over

RIR

RR

N/N

R/R

Soya Oil
Nickel

Nitrate

R/R

_Nickel
_._._. Sulfate
Nirtic acid, up to 5%

Nitrtc acid, 20%

Nrtric actd. 40%


N!ric

acid, 50% and~~~


over ~
Nrtrobenzene

Steanc

RIR

Sulfur Dioxide __
gas,
____.-.
~__dry
Sulfur Droxide gas, wet

_~-------L--__--T~~~~~_

R:R

~+

R&_RRCR

Sulfur Trioxide

gas, dry

C
Sulfuric

acid

Perchloric

acid

R
N:RT _~_~_~
CCi
~,__R
..~ N
C mm-++
N
N ~~~..
NIC ~~ _ N : N
N
~~~~~~~~~~~._
N
NN
NIC
NIC
N

Oleic actd
Oxalic

R/R

acid. 10%

acid, over 93%

Phenol
Phosphonc

acrd

Phosphorous
Phosohorous
Phthalrc

actd
Trtchlonde
Tin Sulfate

actd

Toluene

Picrrc acrd
Potasstum

Brcarbonate

Potasswm

Carbonate

Trrchloroethylene
-..-

R
R;R
R!R
R/Rids ~~~
R
~__-_~,~~______~~~~~~_
~~
R
RIR
RJR
R
IR
A_ ___~_,
_-._
, -...-._R

Potassrum

Chloride

Potassium
Potassrum

Cyanide
_~. ___.~
FerncyanIde

Potasstum

Ferrocyanide

Potassium

Hydroxide.

UP to 30%

Potassium

Hydroxide,

30% and over R

RR$_ ___ R -;R_

R_i .R-_

f?

Trrsodtum
Tung 011
Urea

Phosphate

238

Corrosion Resistant tWaterials Handbook

TABLE 1.61:

VINYL,

SILICONE

AND FLUOROELASTOMER
MASTERFLEX

Legend:

N = Not satisfactory

Satisfactory

Use only after

testing

I
Fluld
ArrI<~ldehyde
/wetdIes IlOW mol WtI
?CCIIC acid [less Ihan
5%l

N
-

Cresol
:yClOhexane
>clohexanone

3acetone alcohol
3methyl
lormamrde
Essentral 011s

Acellc ;1Cld (more


than 5bl
AcetIc nrlhydrlae
Acrl0 ItrIle

pumped+

to be

TUBING-BARNANT

Tubing Compatibility
T

= TYGON

(vinyl)

Silicone

blng

tubing

Aolybdenum

N
N

X
X

.4onoerhanolarnme
daphtha

datural gas
Jrckel salts
dltrtc acrd (drluted)

dtsulftde

Ethers
Ethyl acetate

C
N

NC
C

.itrtone
Aceryl bromide

Ethyl alcohol
(Ethanol)

.Aceryl chlorrae

Ethyl bromtde
Ethyl chloride
Ethylarnme

x
x

N
N

N
-

X
N

chlorohydrln
dlchlonde
glycol

N
N
X

N
N

X
X

31s. vegetable
3lerc actd

3XdllC acid

oxrae

All
UWVJIS

Allphatlc
hydrocnrbon\
?~rn~num

Chl0rrae

Ethylene
Ethylene
Ethylene

Alum~nurn

sulphdte

Ethylene

Alurlls
.Ammonld (gas. IlquldJ
~\mmon~m acetxe
Ammorwm

carbonxe

?mmonwm

hyarOxlae

4n111rir h>arvchiorlae
4rlIlmon\ I&S

c
c
c
c
c

x
x
x

Farry acids
Femc chloride

Frrrrc sulrate
Ferrous chloride
Ferrous sulfate

X
X

Fluoborate

salts

Fluoborrc acrd
Flue-SI~ICIC acta

X
X

----

Formaldehyde

FormlC wd

Frron

X
N

N
C

Gdsolrne (nondromr)clcJ

Gasoline (hrgh
aromatlcrtyj
GlUCOSf?

N
X

x
x
-

x
x
x
x

x
x

?rorrlatlc
hydrocarbons

Hydr@bromlC

actd

N
N

X
X

Hydrochlonc acid
(rned concj

X
X

Berwldehyde
Benzene
~erizenwlon~c
Benzorc

dcla

aCla

Benlyl dliohol
Bleichlng Ilquors
Bow dcra
BrOlnle
Bullne

IBuwr 101)
HUlVllC dCld
Calcium

oxode

(alluteal
Cdlwm
salt5
C3rbon brsulfrae
Cdrbon arowde
Carbon tetrdchlorrae
Chlordceuc dcld
Chlorine

(wctj

Clllorlne (dry1
Chlorooenrene
C1110(obrornonlethdrle
Chlotolwm
Chlorosull0lc
acrri
Chromic

acra

Chrom8nl \dlts
Copper S&S

X
X
X
acid

Hydrochlorrc
(concJ

acrd

Hydrocyaw

acid

Hydrofluorlc
acid
Hyarogen peroxlde
Iail
Hydrogen
(COIILI
Hydrogen

peroxrde
sulfide

Hypochloroul
acid
I0rJlne so1ut10ns
Krrosrne

X
X
N

Krrones
Lacquer soIvents
Ldctrc acrd

N
N

Ledd acetate
Lrnseed 011
Lrthrum hydroxrde

acid

carbonate
chlorate

otaswm

hydroxide

Iodide

joap solutrons
jodrum
jordum

btcarbonate
blsullate

jodwm

brsulrite

jodrum

borate

SOdrUm carbonate
Sodrum
iodlum
Sodrum

chlorate
chlorrde
ferrocyantde

iodtum
Sodrum

hydrosulfite
hydroxrde

Id4

,Mercry salts
hlethdne

1Methyl

c
f-

x
xJ

C
C

x
X
N

X
I
X
X
;i
X

x
X

x
-

x
X
-

-X

X
-

X
X

X
X
N

X
X

Uquehd food producu

N
-

X
x

Ty9on
food

X
X

x
X
X

-C

_-X

hypochlorlte

srlrcate
sulhde
sulphrte

Steam Iup to 40 pstl


Stedrlc acid
Styrene
chlorrde
dloxrde
hexdlluorrde

C
X

x
X
X

-ii
X
-

X
X

1
x

ot maqnesra

X
X

-X

Sodrum hypochlorrte
Ibelow 5%)

Milk

X
-

Sulrur
Sulfur
Sullur

N
X

X
X

-X

Sodrum

Xylene (Xyloll
Zlrlc ihlorrde

X
-

Sodrum hydroxide
lconcj

Sodrum
Sodrum
Sodrum

X
X
-

C
X

X
-

/above 5%)
Sodlurn nrtrate

salrs

X
N

x
x
x
x
x
x

C
X

Sodrum hydrcxlde
(med concl

X
X

;i

-N

~tlrcone flurds
;&one
011
jllver nttrate

x
x
x
-

;i

x
C
N

Fluldto be pumped

hydroxide

rhlorlde
Mlxed dud (40%
slphrlc.
15%
rlllrlcJ

otasstum
(COCl
otasslum
pdlne

X
X

X
X
X

otasslum
otaswum

N
N

N
N
-

tubing

sod

iManganese

hosphonc
@rthol

chlorrde
sulldte

15%)
Magnewm
Maynewum
M&c dcld

erchloroethylene
henot

ru

(fluoroelastomer)

= No data available

r- v
-_- -

3xygen lgasl
erchlorlc acrd

(med concl

dcrd

Hydrochlorrc

311s. mmeral

olyglycol

hrsenlc
Bnwm

salts
\rllts

Jltrogen oxides
Qtrous acid
311s. animal

lattng solutrons

Glue
Glycerme
Hyarlourc

rlrtric sod [med cone)


\11trrcdcrd Iconc)
Qtrobenzene

hthallc

A4d regra (75%


hyarochlortc. 25%
llll dCldJ

V = VITON
-

IFluldto be pumper

--

Tables

tubing

hod

Uquclltd

producu

Beer
Butter
Coca co13 syrup
Coffee
Lard
hldzola

011

Orange peel 011


Orange syrup
Scotch whiskey
Spry shortenmg
Tdb concerltrdte
Tla Marla liqueur
Vegetable
Vlegar

011

z, JWeAlOd
>,,q&lu,ec(l

99 WAN
SH B d.9
W=W~bd
Odd PW
euelAlS

c-9

u_ a

wwaw

.-

me

aueldaH

<
0
0
0
0
_._

<

<

auazuag

pawluasuog

awwwaa
LLLWWLW

uo!lnlos ap!xoJpAq wntpos

3lJnw-s

(%OL) PI= 3JlN


(~~86) P9

3lJOlWOJp~~

waaw

wwwQwwww~www~ww~wwww~wwwcJwwQ-wQ-uwww~w

aw
0

ww

ww

LOW

aww
wuwaw

Resins and Polymers

waawwww
wwaw

Synthetic

239

240

TABLE

Corrosion

1.64:

Resistant

VARIOUS

Materials

Handbook

RESINS-GENERAL

Comparison

ELECTRIC

of Chemical

Resistance

of Six Plastics Resins


% tensile retaineda

NylonChemical

10% acetic
Glacial acetic
Acetic anhydride
Lactic
Benzene sulfonic
88% formic
10% WI
37% I-ICI
10% HNO,
30% H2S0,
85% H,PO,
10% chromic

30
0
74
22
0
0
0
0
0
0
0
67

15% NaOH
30% NaOH
28% NH,OH

69
89
85

HID

37
67
0
100
20
30
100
0
100
100
100
100

Phenolic

100
70
55
100
100
99
100
100
100
100
100
100

100
98
100
100
100
75
100
100
96
100
100
100

98
7
0

100
100
100

100
100
100

100
100
loo

CaWW

66
33
62
76
90
60
94
73
82
86
74
19
13
47
29

100
100
100
100
100
100
100
100
100
100
100
100
100
100
100

100
100
100
100
100
100
100
100
100
100
100
100
100
100
100

100
100
100
100
100
100
100
100
100
100
100
100
100
100
100

100
100
100
100
loo
100
loo
100
100
100
loo
loo
loo
100
loo

NaHC03
Na2C0,
Na2CriOj

76
80
57

100
100
100

100
100
100

100
100
100

100
100
100

KMnO,
NaOCl

100
100
48

100
100
92

loo
100
87

100
04
64

Brl
2-Aminoethanol
Amyl alcohol
Butyl alcohol
Cyclohexanol
Ethylene glycol

39
44
8
93
07
87
84
96

0
48
94
74
100

100
100
100
95
100

100
62
84
27
100

100
100
100
100
100

n-Butylamine
c Ethylenediamine
Aniline
Dimethylaniline
Morpholine
Pyridine

91
78
85
100
93
74

0
0
0
0
0
0

0
0
0
0
0
0

0
51
0
0
0
0

49
65
96
100
80
93

!
Bases
1
/

A12(S%)3
WW2S0,

Na2S0,
Na2SIO3
Na2S
NaCl
NH,CI
CaCI,
BaCI,

lnorgallic
aqueous solutlon

WCl2

AICI,
FeCI,
NH,NO,

Alcohols
I

Amlnes

Potycarbonate3

100
91
0
100
35
79
100
100
100
100
100
100

Acids

10%

616

Noryl
phenylene
Poly- oxide based Polyphenylsulfone4
resin2 ene sulfide5

98
4
83
13
73
63
99
100
-

85
loo
100
96
loo
100
(continued)

Synthetic

TABLE

1.64:

VARIOUS

RESINS-GENERAL

ELECTRIC

Resins and Polymers

241

(continued)
76 tensile retaineda

Chemical

Aldehydes. ketones 1

Chlorinated
organics

Esters
{

Nylon6/6

N&riles{
Nltro compounds

Phenolic6

0
100
0

0
0
0
0
100
0

100
99
100
84
100
100

0
0
0
0
0
0
42
0
0

0
0
17
0
0
0
0
0
0

0
0
0
0
53
0
57
0
0

100
100
100
100
100
07
100
74
72

88
95
90
89

46
0
46
0

0
32
63
0

0
0
19
0

100
100
100
100

100
81
96
87

61
78
0
0

100
0
0
0

0
47
0
0

100
89
88
76

90
84
07
80
86
90
88
100
89
76
91

75
100
100
99
100
100
100
99
0
0
0

99
100
100
100
100
100
100
100
0
0
0

0
36
36
0
0
100
100
100
0
0
0

100
91
100
100
100
100
100
100
100
96
100

100

;f;z;.;$;

93
88

25
0

0
0

69
0

96
100

100
-

Nitrobenzene
Nitro methane

100
57

0
0

0
0

0
66

100
71

100
100

0
0

0
0

0
0

0
0

100
100

a4
07
95
66
a4

0
0
0
62
16

0
0
0
55
77

93
100
-

100
97
100
100
100

87
07
07
98
77
81

0
100
0

Acetyl chloride
Benzyl chloride
Carbon tetrachloride
Chlorobenzene
2Chloroethanol
Chloroform
5% aq. chlorophenol
Epichlorohydrin
Ethylene chloride

0
80
76
73
12
57
41
a4
65

Amyl
Butyl
Butyl
Ethyl

acetate
acetate
phthalate
acetate

Cyclohexane
Heptane
Diesel fuel
Gasoline
Stoddard solvent
Mineral oil
Motor oil
Wesson oil
Dowtherm
Toluene
Xylene

m-cresol
Phenol

MibcdlalWOUS

0
0

Acetophenone
Cyclohexanone
Methyl ethyl ketone
Benzaldehyde
37% Formaldehyde
Furfural

Butyl ether
Cellosolve

Hydrocarbons

Poly-

1 carbonate3

Noryl
phenylene
Poly- oxide based Polyphenylsulfone*
resin 2 ene sullies

Dimethyl sulfoxide
Sulfolane
N.N-dimethylformamide
Cresyldiphenyl
phosphate
Triphenylphosphite
24-hr. l~powre at ZOOF.
1-Zytel
101, Du Ponc Co.
2-Noryl.
General Electric Co.
3-Lexan
141. General Electric Co.
CUdel.
Union Carbide Corp.
S-Ryton,
Phitlips Pelroleum CO.
G-Gcnal 4300. General Eleclric CO.

19
0

100
100
100
100
100
100
100
100
92
98
-

100
100
94
-

a--Alter

(Reprinted

from

Modern

Plastics)

242

Corrosion Resistant Materials Handbook

TABLE

1.65:

VARIOUS

KOROSEAL

RESINS

is an extruded,

ATLASTAFLEX

is a synthetic

CHLOROBUTYL

ELASTOMERS

polyvinyl

chloride

rubber-based

is a synthetic

3-PLY is a sheet lining


rubber.
Atlas PVDF

plasticized

is a polyvinyl

NEOPRENE

AND

rubber

consisting

FOR

chloride

laminated

LININGS

AND

MEMBRANES-ATLAS

sheet lining material.

sheet lining.

sheet lining.
lining material.

of a layer of hard natural

sheet lining is a polyvinylidene

rubber

sandwiched

between

two

layers of soft natural

fluoride.

ATLASTIC
31 is a hot-melt asphaltic compound with a ball-and-ring softening point of 200 to 225F (93 to 107C).
ATLASTIC
40 is a corrosion-resistant
membrane system consisting of a layer of ATLASTIC
40 textile in the center
of two layers of ATLASTIC
31. ATLASTIC
50 is a textile-reinforced,
hot-melt asphaltic membrane with a ball-andring softening point of 250 to 275OF (121 to 135OC).
CHEMPRUF
linings are a series of heavy-duty
monolithic
systems based on epoxy, furan, polyester, and vinyl ester
resins. The CHEMPRUF
1000 Series systems contain flake glass as filler and reinforcement.
The CHEMPRUF
2000
Series systems contain fabric reinforcement
which provides a lining with outstanding structural integrity and chemical resistance in broad thermal ranges.
Flake Glass Systems
CHEMPRUF
CHEMPRUF
CHEMPRUF
CHEMPRUF
CHEMPRUF

Resin Binder

1100
1200
1300
1301
1400

Fabric Reinforced

Furan

CHEMPRUF
CYEMPRUF
CHEMPRUF
CHEMPRUF
CHEMPRUF

Epow
Polyester
Polyester
Vinyl Ester

Chemical
R:
N:
A:
C:
X:

Resistance

Systems

Resin Binder

2100
2200
2300
2301
2400

Furan
Epoxy
Polyester
Polyester
Vinyl Ester

Chart

Recommended
Not recommended
Silica filler will be attacked. Sealing the surface may prolong
Conditional;
may be suitable but consult Atlas before using
Does not apply

life

2
=0

5
=
4:
-

C H

Ct. I
-

Acetaldehyde

NN

Hh I
-

Acetic acad. up lo 10%

CN

RR I
-

Acetlc acid. glaClal

NN

RN I

C Room Temn

ti 150F

Alum
Alumwwm

Chlortde

RR

Alummum

Nitrate

RR

Alummum

Sulfate

Ft
_

i-i
-

9R I

Ti
- I P
3R

Ammomum

Chloride

RR

El
-

Ammomum

Hydroxide

NRC

3A
-

IRR

(continued)

Synthetic

TABLE 1.65:

VARIOUS

RESINS AND ELASTOMERS

1t
1
-

FOR LININGS

7-

AND MEMBRANES-ATLAS

=E
a

C Room Temp.

, Ammomum
~Ammontum
Amvl

H 150F

CH
-

Nltrale

RP

SuItate

RR
-

Acetale

~ Amy1 Alcohol

, Aqua

CH
3N

3C
JN

RR
-

4N

Rh
- I

Regba

j Barwm

r4N

I F3R
I F1R
RR
i-i
- I F1R
IR
RR I F
UN I P
JN

Chlortde

RR

Barwm

Hydroxide

Barurn

NltraIe

Barium

Sulfide

BeMerle

-.

/ Benzene

sulfon~c

I Etromme

acid.

4N
RR
__
cl FIC
i-i FIR

10%

z
-

wear

~ Bulyl

Acetate

1 Butyl

Alcohol

Nh I

NhI r4N

I Amhne

h1ri

rJN

RR
- I rJN

MNI P4N
1 F3R
RR

G
UN
UN
UN
-

CH
RR
RR
NN
RC
_
NN

UN

YN

G
-

RR

3R

RR

G
UN

(:n

-7i-c

i-i
-

rUN
f UN
-

t UN
rUN
f i-i
-

RR

FIR
PIN
4N
-

RR

RR

IUN
-

RR

in4N
-

IUN

n1N

IUN

FIR
-

2
%
-6

-6 -6

[
(

c:n

RI R

hIN

i-i
-

4C

RC

hIN

NN

nIN
-

JN

NN

hIN

NN

nIN
-

JN

CN

hIN

I9R

RR

RIR
-

4R

RR

R R

FIR

I9C

RR

RIR

JN

AC

A R

:C
-

cc

Cz
-

tR

RR

C.i

IaC

RR

RIR
-

3N

RC

R R

RINI

1N
-

L1N
RIA
-

IU Nj

AC

4N

NN

NIN

h IN
-

RR

RIA
-

;k

RR

R R

I1C
I3R
IU N!

RR

RIR
-

IR

RR

R R

RIR

RR

RI-

RR

RIA
-

1-i

R R

R R

RIA

RR

AR
-

NN

NIN
-

IC

NN

NIN

N IN
-

RR

h IN

1N

CN

NIN

N IN

RR

C:H
-

IC

RN

C N

Ac

RR

IN

AC

RIC

RR

N Ni

Rc

RC

h IN
RIC

IR

RR

RIR

I- RR

C C

R 77

cc

Cz
-

IA

C C

RR

A C

R Y-

RIR
-

JN
UN
UN
-

PIN
-

UN

1N

nIN
nIN
I!IN
hIN
RIR

JN
JN
-

9R

F4A

3R

-7

1R

RIR
-

1R

RR

RIC
-

IR

RR

RIR
-

IR

RR

R
t-R R R
RR

R R

I- RR

n R

II r,

.-

hiIN

hlNiRR

C.N

NIN
-

NIN

RIR
A -G
-;
R A

RR

RR

Calcium

Chloride

RR

9R

FIR

FIA

RII4
-_

*R

RR

IR

IR

RR

RIR

Gi
-

3R
-

F,R

3R

FE
-

RIA
-

1R

RR

IA
-

IN

RC

A:R

9fi

FIR

h4N

RIA
t il. . ..-

4C

IH

RR

NIN
NIN
NIN
-

IN
-

#A
-IN
-

N IN
N IN

IN I-

CN

.N

C N

IN 6
-

NN

c
-

C d

/ !4 N

IN
-

NIN
-

IN
-

Carbon

Tetrachlorlde

NN

IN
-

IN
-

ICC

IR
-

N N
N N
-

IN
-

IN
P hIN
JN
NIN
4N
-

Chlorine

gas.

dry

RC

IN
-

N N
-

IN
-

4N
-

NIN
-

,Chlorme

gas. wet

RC

IN
-

N N

IN

IN

NIN
-

/Chlorme

water

AC

IR

c
-

Rc
-

c
-

CN

N N
-

IN
-

IR
IN

R R
N IN
-

IN
-

N N
-

IN
-

IN

N N
N N
N N

Chlorobenzene

N N;

Chloroform

N U

Chromic

acid.

up to 5%

,Chromlc

acid.

10%

/Otric
j Copper

acld
Chloride

/R

Ri

R R;

IRRIRR

-ii.

-F
T
-i-

N IN
-

N N

i NN
N N

Rc
1 C N
N N
L
7
4
f
NI

AC

JNI RR

IN
k
:N
-

IC

NN

R/RR/

:N
IN
-

2
R
z

C N

C N
-

N N

N
-A C;NN

N N

C N

R NiNN

N N

N NiNN

N Ni

NN

N N

RR

R R R

CR
RR

NN

;;7

NN

iN

NN

RR
-

K
N
t

h IN
-

IN i
c
IN ;N

A RR
_-_I

JN:NN
-

R Y-

RR

N N
A
N
R

NN

.N f
-

N Ni

NIN
R R

1C

1R

Dlsulllde

R R
-

RE
-

RI ?
-_

Carbon

Rx
R C

--I

FK
-

10%

Rc

PIR
-

G
-

acid.

6 IR

Fz

F1N

I
,Chloroacellc

IN

FIR
-

Gi
-

solution

NIN
-

F1R
-

RR

water

NIN

Rz
-

B~sulftte

Dloxlde.

1
RIR
-

Calctum

Chlorme

:I4
RIR
-

RI R

RR

RIR
-

FtR(RR

NN

FIR
-

G
-

i
Ii
ii

JN

( 72
-

L-i
-

l7

3R

G
-

IR

IN

r JN

G
-

Ei

-6

c:n
Fii

I 3R
-

fE
FIC
PiN

RR
- I F,R

1
0

:li
3C

Nh

8
;;
i
t

-:nz
i-z
-

z z yr

t-3

Is
;i;
2

-z

$
?

(contd)

54

243

Resins and Polymers

;~
-

N N
i #N N

A CI,,RRr;;;;j
C

(continued)

244

Corrosion Resistant Materials Handbook

TABLE 1.65:

VARIOUS

RESINS AND ELASTOMERS

FOR LININGS

AND MEMBRANES-ATLAS

--r

0:
5
z
i C Room
; Copper

H 150F

Ntlrale

Dlethyl
Ethyl

Temp.

Glycol

Ethylene

-6

CM

CH

cc

cc

5-i

RR

RR

RR

( :n

RR

UN I
__

FtR

tc

UN /

FIR

tR

UN

c1N

t
JN:NN

UN

c4N

JN

NN

UN

h1N

dN/NN

I NN I-NN

UN
-~

hIN

:N

C:N

RR

JN

hIN

RR

JN

hIN

AC

tC

RIC

tC

RR

RR

~HlCH

z
-

E
al
6
:ti

E6
-

!
(

RR

I ii

NN

r4N

,YNlRR

RR

UN
-

NN

I JN
-

IVNjRR

hIN
-

UN
-

RR

UN
-

VN

rJN

IVN;RR

rrlN

h IN
-

4N

3R

?R

FIN

I3C,RR

F1R

RIR
-

E
-

NN

3N

FK
-

(,NIRR

EJN

RIN
-

:N
-

NN

VN

PJN

rqN/RC

rJN

1N
-

?R

FG
-

F3RRR

F1R

NIN
A R
-

AIA

UN

r.IN
-

rrl

P4N

RIR
-

RR

h IN

?R

FIN
FIC
-

FIAlAR

FtR

r.,N

Rc

FIC

AR

N;RR

63R!RR

FIC

R Tt
-

C r- RR
RlRR

N / RR

JN

hIN

3C

RR

4N

C:c

3R

FIN
-

Glycsrme

RR

RR

tC

hIN

3R

Gold

RR

RR

tFt

RIA

7R

FIC
PIR
-

NN

RR

JN

RIN

2R

RIN
-

F1R

RR

IC

NIN

?C

RIR
-

RR

IC

NIN

3R

RR

IC

R C

3R

acld

RC

Hydrocyanlc

rcad

RR

Pwortdr

Hydrogwt

Sulhd,

R R
RR
-

N r- RR

FIC/NN

C:N

R C
-

R:RC

RIA
-

FtR

RR

RIC

R R
-

RIR
-

FtR

t RR

RIC

R A
-

4N

h IN
-

c1 N

NIN

JN

NIN
-

F1N

RR

RR

IN

A N

3C

RIN
-

RR

IN

R R

IR

JN

RIA

JN

h IN

:c

R1R

4N
4N

C: c

RIC

hIN

R -c

FIClNN

C.C

Rc

RIC
-

FlR:RA

R A

AR

RIC
-

FlR;RR

RI

RR

1R

RIR
-

FIRIRR

nIC

IR

FtR

RIR

3R

NIN
_~

Ir

4 Ni
IQ

RIA
RIA
IN
__..
X
-

ININNIRCINN

:c

tR

INj-&&lNIR~R

I R

--+
NR

:c

-4
R!

ARIAA

tR

ccb

IR

RRT-

IN

/ Magnesium

Chloride

Magnesvdm

Hydroxide

~RRIRR
RR

RR

: Magneswn

Nitrate

RR

RR

CN

A
kf
p

IR
IRRR
I

RC
t- RC

IFtR]RR

HIC

r.4NlRR
I, ,
cIRIRR

hIN
..

T
R

F
F

R R
R R
N N

:i

:N

IA

R
N

t- RR

IC

IC

R RlRR

IC

__ +
3RtNN

FfI RC

R R
-

RR

!F 1C /R d
c J
W /R R
R
IR
-

C:c.

CC

IC,RC

FIC

NIN

IN

R R

FIR

1N

Jr4

tR
-

RR

:c

RR

3N
-

RR

RR

gas. dry

FtR

RR

Hydrogan

RR

RC

4N
-

UN
-

NN

Hydrochloric

hIN
-

3R
-

RR

NN

Gasolme

3R
-

RN

RC

FIR
FIR
FIN
-

I3NIRR

CN

acld

-6
CH
-_

t1, c:k
-

I i-i

Formx

IiydrObrOmlC

a8

RN

JN

nex*ne

ri:

UN
-

RR

RR

RR

Cyrnlde

2
%

6
-

Ii-ii

Formaldehyde

.~

tt 1
t

RR

aad

:!

FIUOSIIICIC acld

RR

z
t

CH

CM I

NN

Acetate

2
i

2!

; CH

/ CM
\RR

Ether

5
i

_.-

6
2

8
t

bntd)

IR -

-E
R
R5

Req,,es

Synthetic
(continued)

Fabric

Synthetic

TABLE

1.65:

VARIOUS

RESINS AND ELASTOMERS

FOR LININGS

Resins and Polymers

AND MEMBRANES-ATLAS

I?

It.

245

(contd)

cy
-,i
i
c

[
C Room
Mercuric

Temp.

cl.41 CHjCH

Acetate

Methyl

Acetate

Methyl

Alcohol

Methyl

Ethyl

Methyl

Sulfate

___-

H 150F

Ketone

NN--*- NN

NN

I---NN

NN/NN

NN

NN

-_-~

CN

MIneral

011

MIneral

Splrlts

Murlatlc

acid

CN

NN

-t

cnicn
-NN
RR!RC
i---NN
C
NN
CN
RC+NG
NNICN
NN
-NNIRC
NN
NNiRR.NNCNICN;
-i--7
NN
CCNNICN!
RRIRRiRR

CC

NN

NN

RRtCN

RRJCN

FE~CNIAR;NNJCN

ii IN

NN.NN

RR

NN

NNF

RR

I- NN

RR

RC

FIR

RR

RR

t RC

RIC

RC

R!R

t RR

KilRRIRRR
[

Rta

Nickel

Chloride

Nickel

NItrate

Nickel

Sullate

F~F~RRIRR;C/RR

N,lrtcac,d.20%1Nltrlc

acld.

+--RRINNlNN

,RC

+-

NNICN

NN

N N/ C N

RC,RC

NN

t-NN

30%

YN

NN

acid

Oxalic

acid

Perchlorx

RR

GR
acid

Phenol
Phosphoric

acfd

Phosphorous

acid

Phosphorous

Trlchlorlde

Phthallc

?G~RR

NN NN

iRR

._i

acld

--I

/RR

RR

RC

NNlNN

Potasswm

Carbonate

Potawum

Chloride

R
-4

RR
-.I

!RRIRR/

NN

t- NN

N NI

NN

I-

N N!

NN/RR
Olelc

NN

I
GJRR~NN

I-

RR

NN
t

NN

NN

CN

CN

RRiRR

RR,C

RR

RC

;;;;;R

RR:C

RR

c RC

R R

CN

i- NN

N;;;~NN~NN/GNI

RR

NN

NNR

I NN
NN

NN

NN

RC

NNI

---I H
RR

RR

_f---

RC,RR

I-

RR

RR

t RR

Potasswm

Fetrtcyanlde

I,

Potasswm

Ferrocyamde

II

Potasswm
L-

Hydroxide.

Potassum

Norate

Potaswm

Sulfate

up to 30%

N N
salt

9R

RR

RC

AC

cc

ICC/cc
r--- c_
RRjRC

Bicarbonate

t-

RR

NN

R RRR
R C

Sodium

CN

R RiRR

Pyrldlne
Rochelle

CN

-RR

iA

Ad

1.
R R

RR

R R
.R C
1~

RR
RR

(continued)

Corrosion Resistant Materials Handbook

246

TABLE 1.65:

VARIOUS

I-

RESINS AND ELASTOMERS

FOR LININGS

AND MEMBRANES-ATLAS

kontd)

I i

2
2

n
A
C Room Temp.

H 150F

CniCnlcHlcnlcn

t;
c

cn cn
i-i
-

Sodium

Carbonate

Sodium

Chloride

1?R
-

Sodlum

Cyamde

Sodium

Hydroxide.

up to 30%

I3R

j Sodium

Hydroxide.

30% and

IG
-

Sodium

cn

cn

CH

I3R
-

Hypochlonle.

over

up to 3%

IGN
-

r4N
-

Sodium

RCIRCIRR/RRRAI

F3R
I 3R
-

Sulfate

I 3R
I *R

i Sodlum

Thwxulfafe

i Stearlc

fG
14N
9R/RRti-Nm

acid

I 1N
-

/ Sulfur

Dioxide

gas. dry

n4N

1 Sulfur

Dloxlde

gas. wet

n1N

1 Sullur

Trloxlde

gas. dry

n1N

i Sulfur

Trloxlde

gas. wet

?R!RCjRCk
CN

Sulfut~c
, Sulfurx

up to 50%

FIR
-

acid.

80%

hIN
hIN
hIN
hIN
h IN
h IN
NIN
~RRHCN~RRR

Tin-

:N
-

Toluene

IN
-

Trxhloroelhylene
Trlsodwm
Tung

Phosphate

011

Urea
xylene
Ant

C:N
-

IN
R
lk
R
N

Chloride

Zinc

Nitrate

Ztnc

Sulfate

NN
NN

hIN
-

acid.

Tin Chlortde

NN
CN
NN
NN
NN

Synthetic

TABLE 1.66:

VARIOUS

RESINS AND METALS-PHILLIPS


CORROSION

2fvf

MEDIA

RYTOf

2wF

2wF
KINAR

247

CHEMICAL

RESISTANCE

ENTO,

Resins and Polymers

GUIDE

2wF
MtBOI
STEEL

lEFLOh

AIL.
M,NM

wm)

I
A
A

Acctaldehyde
Acettc Acids
Acetac Anhydride

Ac,d

Acetlc Acid, Glacial


Acetone
Acetonitrile
Acetophenone

NR

NR

NR

A/Q

NR

NR

NR

A
A

NR

A/NR
-

NR

Alcohol,

Amyl

Alcohol,
Alcohol,

Butyl
2.Aminoethanol

A
A
A
A
A
A

AI-

Chlorohydroxlde

(wet)

Ammonia, anhydrous
Ammonium Chlortde
Ammonium

Hydroxide

Ammomum

Nitrate

Ammonium

Sulfate

Amyl Acetate
Aniline
Asphalt

Emulsions

Barium

Hydrorlde
Sulfate

Benzene
Benzaldehyde
Benzene

NR/C

Sulfonic Acid

Benzonitrile
Benzyl

Chloride

Borax
Bromine

A
A
A
A
A
A
A
A
A
A
A

Bar&urn Chloride
Barium

Al-

A
A
A
A

WQ

(wet)

Butadiene

A
A
A

Butylene
Butyl Acetate
Butyl Amme

A/Q

Butyl Phthalate

NR

NR

NR

A
A

A
A

NR

NR
-

NR

NR

NR

NR

NR

NR

NR

A
-

NR
NR

A/Q
AlQ
A/Q

A
A

NR

h
4

Q
Q

NR

A
NR

:
A
A

Q
A

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR
-

NR
-

NR
-

NR

NR

NR

NR

NR

A
A

A
A

NR

Q
NR

NR
-

A
A

NR
NR

P
NR

A
-

A
-

A
A
A

NR

A
A

Q
NR
-

A
AjNR

A
NR

NR

NR

NR

NR

NR

A
A
A

A
A

A
NR

NR
-

NR
NR
A

A
A

A
A

A
NR

A
-

A
A
A
A
A

NR

NR

A
A

NR
A

NR

NR

NR

NR

A
NR

NR

A
A

NR
A

NR

NR

NR

NR

NR

NR
NR

Q
-

NR
-

A
-

A
-

NR

Q
Q

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

Q
-

Q
NR
A

NR

:
A

NR

P
I\

A
A
pi

A
A

NR

NR

NR

NR

NR

NR

Cycloherane

A
-

NR

NR

NR
-

Copper Sulfate

NR

t
Q

A/Q

).

NR

NR

NR

A
A
A

NR

NR
A
-

NR

Crude Oil

NR
:

NR

m-Crew1 (crude)
Cresyldiphenyl
Phosphate

NR

A
A

NR

A
A
A

NR

A
-

Chromic Acid
Cottonseed Oil

A
A

NR

Chlorme(dry)

NR

A
NR

NR

A
-

NR

5% Aqueous
Acid

A
A

Chlorophenol,
Chlorosulfonic

NR

A
A
A

Chloroform

A
A
-

A/Q

(dry)

Tetrschloride
Chlorobenzene
2-Chloroethanol

Q
Q

NR

NR

Cellosolves

(wet)

A
A
A

NR

NR

NR

NR
-

A
A

AlA

Sulfate

Q
Q

NR

Calcium

Carbon D&oxide

NR

NR
-

Dlsulftde

Chloride
NItrate

NR

A
A
A
A
A

Calcium
Calcium

A
Nfl

Al-

A
A

Butyl Ether

NR

Al-

Butane

NR
A

Acetylene

Chloride (dry)
Sulfate

NR

Acetyl Chloride (dry)


Acid Mane Water

Alummum
Aluminum

Cyclohexanol

P
9

Cyclohexanone

NR

Detergents

Dtesel Fuel

A
4

NR

A
(continued)

248

Corrosion Resistant Materials Handbook

TABLE

1.66:

VARIOUS

RESINS AND METALS-PHILLIPS


m
WF
ENYD, Y

m
MOF

MOF

20s F

KYNAR

TEFLDf

POLY
LFOf

NYLON

1W F

Diisobutylene
Dimethyl Aniline

Dimethyl

Formamide

A/Q

Dimethyl

Phthalate

Dlmethyl

Sulfoxide

Diphenyl

Ether

Phthalate

p-Diorane

Dowtherm

NR
-

Dioctyl

Eplchlorohydrin
Ethanolamine

(dry)

NR

NR

Q
Q

Ethylene

(wet)

Chloride

Ethylene

Dlamine

Ethylene

Dichloride

Q
AIQ

Ethylene

Glycol

FC-77 (Cyclic Fluormated


Ferric Chloride
Ferrous Chloride
Flo-Cool lSO(SilicateEster)
Fluorosilicic Acid, 25%
Formaldehyde.
Formic Acid

37%

Ethe

NR

NR
-

NR
-

A
-

NR

A
-

NR

Q
A

NR

NR

NR

NR

NR

A
A

NR
-

NR

NR

NR

NR

NR
-

NR

NR

NR

Q
Q
Q
Q

A
A

A
A

NR

NR

NR

NR

NR

NR
-

A
A

A
A

A
A

AiA
-

NR

FlWlll
Furfural

AIQ
A/Q

A
A

Freon (dry)
Fuel Oil

Q
A

Q
Q

A
A
A

A/Q

NR

A/NA

ALMlNUM
(3cQI)

m
-

NR

STEEI

NR

NR

XROC

NR

NR

ZWF
P&E:I

NR

NR

NR

Lthyl Acetate
Ethyl Chloride

(continued)

A
-

Ethers

CHEMICAL

NR

NR

NR
-

NR

A
A

A
A
-

NR
NR

NR
NR
-

NR

NR

NR
NR

NR
A

:/NR
NR

NR

NR

NR

CaSOllne

NR

NR

A
-

Glycohc Acid

A
-

Heptane

Q
Q

Hexane

NR
-

A
-

A
A

NR

NR

NR

Hydrochloric

Acid, 20%

NRIF

Hydrochloric
Hydrufluoric

Acid, 37%
Acid, 5.75%

NR/Q
A

A
A

Hydrogen

Gas

Hydrogen

Peroxide,

HydroSen

Sulfide (wet)

30%

:
A

Q
Q

NR

NR

Lactic Acid

A
A

NR
A

NR

A
-

Oil

Chloride

Magnesium

Hydroxide

:
-

NR

NR
NR

A
A

NR

NR

Q
-

NR
A

&IQ
k

Morphofme
C9tor

Oil

Naphtha
Naphthalene
Nitric

Acid, 10%
35%
(Cont.)

Nitrobenzene
Nitrogen
Nitromethane

n
h
WQ
VQ
1
VQ
\
VQ

NR

NR
-

NR

NR

NR
A

NR

NR

A
A

A
A

NR

NR

Lubricating

A
A
A

A
A

Magnesium

Ketone

Ethyl Ketone

Methyl

NR

JP Fuels
Ketones

MethylenaChloride

:
A

Methyl lsobutyl
Mmeral Oil

KWOSel-le

LPC

NR

A
A

A
-

NR
-

A
A

NR
A

NR

A
A

Q
A

NR

A
A

iI

)I

NR

NR

VQ
9

/4

YR

NR

NR

NR

NR

YR

(continued)

Synthetic

TABLE 1.66:

VARIOUS

RESINS AND METALS-PHILLIPS

CHEMICAL

m
MEDIA

MO-r

2W F

RYTON

PENTON

m
Perchloroethylene
Phenol

(dry)

Acid

Phosphorus

Trnchloride (dry:

A
A

AIQ
A

A
A

NR

A
-

NR
A

NR
A

NR

NR

A
A

A/NR

NR

A
A

A
A

A
-

Sodturn Chloride

Sodaurn Chromate

A
A

Q
A

NR

NR

NR

A
A

A
A

Q
A

Q
NR

A
A

NR

Q
NR
A

NR
Q

Q
NR
A
-

A
A
A
A

A
A
A

z
A
NR

P
A

:
A
A

A
A

A
A

Q
A

A
-

Sulfuric

And. 30%

Q
A

Sulfuric

Acid, 50%

Sulfuric

Acid. 98%

A/Q *

NR

Q
NR

A
A
Al2
A

NR

NR

:
A
_
A
-

NR

NR
-

NR

NR

NR

NR

Q
A

NR
-

:
NR
A

NR

NR

NR

NR

NR

A
-

A
A
NR

A
A

A
A

vmegar

Sea

Tap

Xykfle

NR

Zmc Chloride

NR
-

than indicated.

polyphenylene
sulfide
poly-3,3-bis(chloromethyl)oxacyclobutane
polyvinylidene
fluoride
polytetrafluoroethylene
phenylene oxide-based polymer

NR

NR

P
NR

Q
NR
A

A
A
A
NR

A
Deionized

NR

Turpentme(dry)

RYTON
PENTON
KYNAR
TEFLON
NORYL

reslstant

NA

A
A

Ryton grades c~nta~nlng glass fiber


and/or mineral
fillers will be less chemically

NR

Q
NR

NR
-

Water,

NR

NR

A
AjNR

NR

NR

QINR
A
-

A
A

A
-

A
A
A

Q
NR

A
A

Phosphite
Phosphate

NR

Sulfur

Trlphenyl
Trlsodlum

Actd

Q
A

NR

P
A

A
A

SlfolUle

Phosphate

Trlethyl

Stoddard Solvent
Sulllnol

Trxhlorrcetic

A
A
A

Tomato JUG
Tnchlorethylene

NR
A

A
A

Tetrahydrofuran
Toluene

NR

Sodturn Carbonate

Dmxide

NR

AIQ
A

Sodium Thlosulfate
Steam-&IV
F

Chlorohydrin

Sodium Sulfate
Sodwm Sulttde

Propylene
Pyrldlne

Soln.

NR

Sodturn Hypochlorlte

ALU-

STEELYINUY
oca1)

NR

Permanpanate

15%
3D%

:ARBON

NR

Polarslum

50%

wF
NYLON

Nil

Hydroxide,

Sodium Hydroxide,
Sodium Hydroxide.

Chloride

Sodium Hydroxide.

NORlL

Polarslum

Sodium Bicarbonate

ZWF

2wf

POL.
ULFONI

Potassium

So%

IWF
TEFLON

kontinued)

Phosphoric

2M F
KYNAR

Resins and Polymers

NR

Q
NR
A
Q

249

250

TABLE

Corrosion Resistant Materials Handbook

1.67:

VARIOUS

RESINS FOR MEMBRANE

LININGS-WATERSAVER

WATERSAVER MEMBRANE LININGS

HYPALON
(Chlorosulfonated

OR CPE R
Polyethylene)

(Reinforced

. ..provides
excellent
resistance
to weathering
and
chemical
attack.
Hypalon
is available
only as a rein.
forced
membrane
and does not require a protective
cover for most applicatrons.
Hypalon
is approved
for
potable water containment.

PVC (Polyvihyl

Chlorinated

Polyethylene)

. ..specifically
formulated
for resistance to oils. Offers all
of the desirable characteristics
of Watersaver
CPE and
in addition,
provides greater strength and resistance
to
creep, sagging, and puncture
where conditions
of use
are severe, such as steep slopes or other high stress applications.

Chloride)
EPDM

. ..membrane
offers good chemical resistance,
sealability, and serviceability
in unexposed
applications.
It has
performed satisfactorily
as a liner for recreational
lakes,
canals,
evaporation
ponds,
sewage
lagoons,
brine
ponds, etc. It is recommended
that an earthen cover be
provided for PVC to maximize
its service life as a fluid
barrier.

OR CPE (Chlorinated

(Ethylene

EPDM

OIL RESISTANT

R (Reinforced

POLWINYL

ISOBUTYLENE

EPDM)

CllLORlDE

ISDPRENE

(ORPVC)

(BUTYL)

(IIR)
1

POLYCHLOROPRENE

ETHYLENE

PROPYLENE

DIENE

(NEOPRENE)

MONOMER

(EPDY)

CHLOROSULFONATED

POLYETHYLENE

CHLORINATED
POLWINYL

EXPOSED

BURIED
ACID

(HYPALON)

POLYETHYLENE
CHLORIDE

SIDE SLOPE

LINER

LINERS

RESISTANCE

ALKALINE
PETROLEUM

DH 2 to 7

RESISTANCE

(PVC1

II

DOMESTIC
ROOFING

RECOMMENDED

RR

III

IYR
UR

NR

RR

RR

ii

RR

II

II

II

RR

YR

UR

1R
I

pH&VOW
I

PRODUCTS
1 NR

WATER
WASTE
MEMBRANE

II.

RECOMMENDED

(CSMI

POTABLE

(CR)

(CPE)

NR

LINER

EXPOSED

Monomer)

. ..has the superior


weathering
characteristics
of the
non-reinforced
EPDM with additional
strength and tear
resistance
required by some applications.
Many potable
water
reservoirs
are rehabilitated
with EPDM R or
Hypalon.

. ..specifically
formulated
for resistance
to oils. Membrane
features
excellent
weatherability,
sealability,
chemical resistance
and long term durability.
CPE does
not require a cover material for most applications.

I.

Diene

. ..he. ,sen used for roofing and lining applications


for
many
years.
Superior
weathering
and
elongation
characteristics
have made EPDM the most widely used
single ply roofing membrane
in the U.S.A.

Polyethylene)

Propylene

1 RR

RR

NR

NR

i
-

ONLY WITH REINFORCING

iii

YR _ NOT RECDMYENDED

TABLE 1.68:

VARIOUS

RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW

DOW plastic lined pipe, fittings, and valves are designed and manufactured
specifically for safety with long service life and process integrity in handling
corrosive media, either liquids or gases,
The variety of lining materials in the line of DOW piping
engineer designing a piping system to select components
particular service. The complete line includes:
SL piping products lined with SARAN* polyvinylidene
PPL piping products lined with polypropylene
resin.
KL piping products lined with KYNAR** polyvinylidene
PTFE piping products lined with polytetrafluoroethylene
Trademark
**Trademark

products allows the


best suited for that
chloride

of The Dow Chemical Company


of Pennwalt Corporation

Ratings of serviceability
of DOW plastic
lined pipe, in terms of resistance to corrosive
attack by process media and maximum
operating temperatures,
are shown in the
following
table.
Unless otherwise noted:
Solutions of inorganic materials
appearing in the listing are saturated
solutions.
Where concentration
percentages are
indicated, the percentages are by
weight.

fluoride
resin.

resin.
resin.

CHEMICAL

Maximum Tsmperaturs-nF

PC)

252

:
-

:
-

Corrosion Resistant Materials Handbook

i
:d
-

#$
-

:
-

9
2
g
.
t
._

E
-

f
i

1
-

64
-

6
-

Sd
-

Eh
-

s
-

iA
-

2ci
-

k
-

E
-

d
-

s z

zl

- -

-E

-E -; -E
0

e
i

5
._

g
i

J2
3
f
5
._

!i E

d
-

d
-

;:
0
.-

11

5
x

; E
g
I
i

E E

h
.t
3

-E

e
I

-ir
.
.i
.I
i

TABLE 1.68:

VARIOUS

RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW

CHEMICAL

(continued)
Maximum

Cormsiw

Strsrm

*ls
11361

=
llnl

110

llm

ml

?m

Calciumchlwin

Pm

IL

19
El

11

Calcium chlorid*(rmunmdl

Temperature--7(T)

as

PPt

St
IL

PPt

St

04

Not
Recom
mended

ti

i;
.

i
-

Zd
-

;ris
:
-

e
-

$0
-

,
:
-

6d

id

ih
i
-

$
-

--

7,

E i
- -

-E

ij
?s
m

2
:

il: -i

i;
-

ii
-

id
-

-E

i
-

i;
-

i
-

:
-

-iz
m
5

-E
-E -E

e
_O

.r
d

f
1
f

.Y

I
i
f

i
0

i;

L
:
-

D
6

=
f
0

r;
If
2
-

-E -E

a
I
8

d
-

-E

Corrosion Resistant Materials Handbook

.Y

;
.

TABLE 1.68:

VARIOUS

RESINS FOR PLASTK

LINED PIPING PRODUCTS-DOW

CHEMICAL

z
KL

SL

PPL

PPL

i
IL

SL

KL
PPL

SL

PR

SL

SL

It

KL

PPL

St

PPL

St

IL

-t

KL
PPL
St

KL

(continued)

L
-

6
-

iti
-

$c4
-

$
-

*
-

Handbook

Materials

Resistant

ti
=

Corrosion

i:
=

ii

i;
=

E
f

.Y

F
-

$
f
P

5
E

E E
- -

c c
- i h
- -

b t

ii
-

f
-

i;
-

c
ii
-

i
-

iti
-

2
ii
-

ii

= =

8
i

::

$s

i i

ij
f d

.Y

.5

-1 -E

.Y

-E -E

-is -k
- - -

ii

=
=
=
-E -E -E

.
I f: I:
;
2
f j B

-r

ii
=

-E

j
i

G;

E
t:
t
E

2
a!

iit

;
-

:
-

D
f

3
:
:
,

TABLE 1.68:

VARIOUS

RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW

CHEMICAL

(continued)
Maximum

Tempcrahln-*F

PC)

IL

(continued)

TABLE 1.68:

VARIOUS

RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW

CHEMICAL

(continued)

(continued)

TABLE 1.68:

VARIOUS

RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW


Maximum

Temperature--F

CHEMICAL

(continued)

PCI

Maximum
(60
11311

sodium uh

I =* II

St
PPL

m
11351

lull
250

m
Ilull

Temper&m-*F

El

IC)
:n:

El

tzI
ISI

n
WI

NOt
Recom
mended

TABLE 1.68:

VARIOUS

Pnoriun

chbrat

llSWOPll

nff

RESINS FOR PLASTIC LINED PIPING PRODUCTS-DOW

II

II

Pm

nrf

I(t

nffll

WL

PPL

PPLi

KL

PPt

I St-3I

PrR

KL

Pauaium

nrf

Kt

?Pt

nR

IL

PPL-

nfi

IL

PPL

St

nfi

lu

PPt

St

Pmubm

Pamssbm

dide

whl

Iwfll
Pm

Kt

al
n

SL

I
St

It

PlFf

St

nrf

pwchbrn*

Pmauium pwmangan.a

I
St

Pmusium chbrida
shmmtie ImIk~lin*~

SL

wt

SL

PPt

I M I sl* I
PPL

SL

CHEMICAL

(continued)

A
-

f
L

+I

s
=

Synthetic

:
-

Resins and Polymers

%
-

:L
-

ti

i:
-

5
-

I
-

itI

E
-

ti
-

2
-

22
-

:;:
-

:
-

-E

I
I

ZZ

lz

s
-

g i$ g
; x .u
.g 2H .g

LYI

i
-

il
=

-.

I
._

::

5
%

2
._
fi

fs
3

,x

z
;

B
f

e
;

*
=

-E

E E
- -

i
t

L
-

z
;:
=

5
,;
i

rcs :i
-

&l

e
%

:
-

Z?

z
- c
- -

?I

c _E
_

E -E
_

zrE!!?E

-E

kg
-

z s
- -

e
1

i
-

ti
-

E
_

E
t

1
F
.

z
2

-t

i
-

- -

- -

b
=

c.

E E
-E - .
I

5
1

E
I

I
i

= =

5
I

5
s
::

-E

3
s

E
-E -

;
x
=

E
4
:

OL
2

I
d

5
t

5
3

1.

i
,

i;
-

;
I

E E
- =
k
6 z
H
i
P
.a

ep

1
t

P
i I
3 3

261

TABLE 1.68:

VARIOUS

RESINS FOR PLASTIC LINED


Msximum

Comasire

Stream

Temperature--7

fTI

PIPING PRODUCTS-DOW

CHEMICAL

(continued)

Maximum

Synthetic Resins and Polymers

TABLE

1.69:

VARIOUS

THERMOPLASTIC

AND ELASTOMERIC

PIPING MATERIALS-NlBCO

Chemical Resistanceof
Industrial lhetmoplastics

140F

NR

NR

R
R

R
R

R
R
R
NR

R
NR
NR
NR

ACetOne
Acetophenone
Acetyl Chloride
Acetylene

NR

NR

Acetyl Nltrlle
Acrylac Acad. Ethyl
Acrylonltrlle
Adlplc
105 Acid

NR
NR
NR
R

NR
NR
NR
R

A
NR
NR
R

NR
NR
NR
R

Acetaldehyde
Acetamlde
Acetic Acid,
Acetic Acid.
Acebc
Acebc
Acettc
Acebc

10%
20%

Acid. 50%
Ackd. 80%
Acid. Glacial
AnhydrIde

Ester

7 3F

185F

R
R

NR

R
NR

NR
NR
NR

NR

NR

NR
R

NR
R

NR

Ally!
Amy1
Benzyl
Butyl. Pnmary

NR

Alcohol
Alcohol.
Alcohol.
Alcohol

Butyl. Secondary
Dlacetone
Ethyl
Hexyl

NR

NR

R
R

R
R

AICOhOl.
Alconol
AlcnOl
AlOtwl

Isopropyl
Methyl
Propargyl
Propyl

R
R
R
R

R
R
R
R

NR
R
R
R

NR
R
R
R

Alum. Potassium
Alurmnum
Chloride
Alumnum
Fluoride
Aluminum
Hydroxide

R
R
R
R

R
A
NR
R

Alum,num
Alum,num
Alum,num
Ammoma

Nitrate
Oxychlonde
Sulfate
Gas

R
R
R
R

R
R
R
R

Ammonia
Ammonia.
Ammonwm
Ammon,m

Aqua
10%
Llquld
Acetate
Blfluorlde

R
NR
R
R

R
NR
R
R

Ammonum
Ammon,um
Ammonwm
Ammomum

Blsulflde
Carbonate
Chloride
Olchromate

A
R
R
R

R
R
R

Ammon!um
Ammomum
Ammonium
Ammonium

Fluoride.
10%
Fluoride.
25%
Hydrwde
Metaphosphate

R
A
R
R

R
NR
R
R

Ammohlum
Ammonwm
Ammonwm
Ammonum

Nitrate
Persulphate
Phosphate
Sulfate

R
A
R
R

R
R
R
R

Ammonum
Sulfide
Ammonwm
Thmcyanate
Amyl Acetate
Amyl Chlorlde

R
NR
NR

R
NR
NR

An,l,ne
An,lme Chlorohyarate
An,l,ne Hydrochloride
Anthraqumone

NR
NR
NR
R

NR
NR
NR
R

12OF

R
R
R
R

15OF

VITON

PVDF
18OF

3-F

15OF

23OF

2BOF

to 210F

NR
NR
NR
NR

UR
UR
UR
UR

NR
NR
NR
NR

UR
UR
R
R

14OF

210F

R
A
R
R

R
R
R
R

R
NR
NR

NR
NR
NR
NR

R
R
R
UR

R
R
R
NR

NR
NR
NR
NR

NR
NR
R
R

NR
NR
R
R

UR
R

NR
R

NR
R

UR

NR

NR

UR

NR

NR

UR

NR

iR

UR

NR

NR

R
UR
R
R

R
NR
R
R

R
NR
R
R

R
R
R
R

NR
R
R
R

NR
R

NR

NR

R
R

R
NR

NR
NR

NR

NR
NR

R
R

NR
NR
R

NR
NR
R

NR
NR

NR
NR

NR

NR

R
R
R

R
R
R

R
R
R

R
R
R

R
NR
R

R
NR
R

R
NR
R

R
UR
UR
R

R
NR
NR
R

R
NR
NR
R

R
R
R
UR

R
R
R
NR

R
R
R
NR

R
R

NR
R

NR
R

R
UR

R
NR

R
NR

R
R

R
R

R
R

A
R
R

NR
R
R

R
R
R
R

NR
R
R
R

NR
R
R
R

R
R

R
R

R
R

R
R
A
R

R
R
R
R

R
R
R
R

R
R
R

R
R
R

R
R
R

R
UR
R
UR

R
NR
R
NR

R
NR
R
NR

A
R

R
NR

UR
UR
R

NR
NR
NR

NR
NR
NR

R
R
R

R
R

R.

A
R
R
R
R
R

R
NR
R
R

R
R
R
R

R
R
R
R

R
R

NR
R

R
R
A

R
R
R

R
R
R

R
R

R
R

R
A

NR

R
R
R

R
R

R
R
R

R
R

R
R

R
R
A

R
R
R

R
R

R
R

R
R

R
R

R
R

R
R

R
R

RS

R
R
R
R

R
R

R
R
R

R
R

R
R

R
R

R
R
R
R
R
R
R

R
R

R
NR

R
R

R
R

R
R

R
R

R
R

R
R

R
R

NR
NR
NR
NR

NR

UR
UR
UR
UR

7:3F

R
R

NR

185F

R
R

14OF

.R
R

EPDM

3F

.R
R

R
R

Polyvmyl
Chlorrde.
Type 1. Grade
: $hlonnated
Polyvmyl
Chloride
R Recommended

3F

Alcohol
Alcohol
Alcohol,
Alcohol.

Ally, Chloride
Alum
Alum
Ammon,m
Alum
Chrome

R = Recommended
NR = Not Recommended
= No Data Available

POLYPROPYLENE

CPVC

PVC

3F

263

R
R

R
A

A
R

NR
R

NR
R

UR

NR

NR

R
UR

R
NR

R
NR

NR
R
NR
R

NR
R
NR
A

R
UR

R
NR

R
N

UR

NR

Nk

NR

R
R

R
R

NR
R

NR
R

UR
R
UR
R

NR

NR

NR

UR

NR

NR

NH

R
R

R
R

R
R

Data tp 210F

for other

chemxals

presently

not awlable

Corrosion Resistant Materials Handbook

264

TABLE 1.69:

VARIOUS

THERMOPLASTIC

CHEMICAL

PVC

Slfonlc
Ant,mony
Trlchloride
Aqua Aegla
Arsenic Acid
Aryl Sullon~c Acld
Anfhraq4one

ACld

AND ELASTOMERIC

POLYPROPYLENE

CPVC

3F

140F

R
R
NR
R
R

R
R
NR
R
R

R
R
R

R
R
R

R
R
R
R

R
R
A

3F

185F

3F
R

R
R

120F

150F

R
NR
NR

NR
R
A
R

NR
R
R
R

VR

NR

R
R
R
R

R
R
R
R

R
R

R
R

R
R
R
NR

A
NR

R
R
NR
NR

R
R
NR
NR

R
R
NR
R

R
R
NR
A

NR
R
R

NR
R

NR
R

NR
R

R
R

NR

NR

NR

NR

NR

NR

NR

NR

R
NR
R

NR
R

NR
R

NR
R

R
NR
NR

3F

150F

230F

R
NR

R
R
R

NR
NR

R
R
R
R

NR
R
R

R
R

R
R
A
R

R
R
R

Carbon
Carbon
Carbon
Carbon

Oloxlde
Dry
Otsulllde
Monoxide
Tetrachlorlde

NR

NR

NR

R
R
R

R
R
R

R
R
R

140F

210F

R
NR
R

NR
R

NR
R

NR
NR
NR

NR
NR
NR

NR
NR
NR

R
R
R

R
R
R

R
R
R

R
R
R

R
R

R
R

R
R

R
R

R
R

NR
NR

NA
NR

NR
NR

R
R
R

R
NR
R

NR
NR
R

NR
NR

R
R
R
R

R
R
R
R

R
R
R
R

NR
R
R
R

NR
R
R
R

NR
NR
NR
R

R
R
R
R

R
R
R
R

R
R

R
R
R
NR

R
R
R
NR

R
R
NR
NR

R
R

R
R

NR
NR
NR

NR
NR
NR

NR
NR
NR

R
R
R
R

R
R
NR
R

R
R
NR
R

R
R

R
R

R
R

NR
R

R
R
NR
NR

R
R
NR
NR

R
R
NR
NR

NR
NR
R
R

NR
NR
R
R

NR
NR
NR
R

NR
NR
R

NR
NR
R

NR

NR
R
R

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR
R

NR
R

NR
R

R
NR

R
A

R
R

R
R

R
R

R
R
R

R
R
R

R
R
R

R
R
R

R
R
R

R
R
NR

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R

R
R
R

R
R
R

R
R
R

R
R

NR
R

NR
R

R
R

R
NR
R
R

R
NR
R
NR

R
NR

R
NR

R
NR

NR

R
R

NR

NR

NR

NR

R
R

R
NR

R
NR

R
R

R
R

NR

NR

R
R
R
R

NR
R
R
R

NR
R
R
R

R
NR
R
NR

R
NR
R
NR

R
NR
R
NR

Polyvmyl
Chloride
Type 1. Grade
Chlorinated
Polyvmyl
Chloride
+ For dratnage apphcat~on
only
R Recommended
lo 210F - Data to 210DF

R
R
R
R
R

7 3F

R
R
R

R
R

EPDM
185F

R
R
R
R
R

140F

R
R
R
R
R

R
R
R
cane sugar Liquors
Carbltol
Capryllc
Acid
Carbon Oloxlde
Wet

7 3F

280F

R
R
R

(continued)

VITON

PVDF
18OF

NR
R

R
R
NR
R

R
R

PIPING MATERIALS-NIBCO

for other

chemocals

presently

not avatlable

(continued)

Synthetic

TABLE 1.69:

VARIOUS

THERMOPLASTIC

CHEMICAL

PVC

CPVC

3F

140F

R
R
R
R

R
R
R
NR

155F

R
R
R

R
A
R

R
R

R
R
NR
NR

R
NR
NR
NR

Water Saturated
Chioracetlc
Acld
Chloroacetyl
Chiorlde
Chlorobenzene

R
R
R
NR

R
R
NR

Chlorobenzyl
Chloroform
Chlorop,cr,
Chlorosulfonlc

Acid

NR
NR
NR
A

NR
NR
NR
NR

10%
30%
40%
50%

R
R
R
NR

R
A
R
NR

C~tr,c Acid
Coconr
011
Coke Oven Gas
Copper Carbonate

R
R
R
R

A
R
R
R

Cooper
Copper
Copper
Copper

R
R
R
R

R
R
R
R

A
R

R
R

R
R
R
NR

R
R
R
NR

R
NR
R
R

R
NR
R
R

R
A
NR
NR
NR

R
R
NR
NR
NR

UR

NR

R
R
R

R
R

R
R

A
R

R
R
R
NR

R
R
R
NR

NR
R
NR
NR

NR
NR
NR
NR

R
NR

R
NR

Chlmne

Chrome
Chromic
CHromfc
Chromfc

Chloride

Ac,d
Acld
Acld
Acid

Chloride
Cyantde
Fluoride
Nitrate

copper Sulfate
Corn syrup
011

Cottonseed
CISOl
Cresylx
Croton

Aad

50%

Aldehyde

e
II

3F

120F

NR
NR
UR

NR

NR

R
UR

NR

NR
NR

NR

PVDF
180Ft

3F

150F

R
R
R
R

NR
NR

NR

NR
NR

NR

R
R
R
A

VITON

EPDM

7 3-F

14OF

185F

3F

140F

R
R
NR
NR

R
R
NR
NR

R
R
NR
NR

R
R

R
NR

R
NR

NR

NR
NR
NR

NR
NR
NR

R
R

R
NR

NR
NR

210F

NR
NR
NR

R
R
A

R
R
A

R
R
R

R
R
R

A
R
R

NR
NR
NR

NR
NR
NR

NR
NR
NR

R
R

R
R

R
NR

R
NR

R
NR

R
R

NR

NR

NR

NR

NR

NR

NR

R
R

R
R

R
R

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

NR
R

R
R
R
R

NR
NR
NR
NR

NR
NR
NR
NR

R
R
R
R

R
R
R
R

R
R
A
A

R
R
R
R

R
R
R

R
R
R

R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
NR
NR
R

R
NR
NR
R

R
NR
NR
R

R
R
R
R

R
R
R
A

R
R
A
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
A
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
NR

R
R
R
NR

R
R
R

R
R
R

R
R
R

NR
NR

NR
NR

NR
NR

R
R
R
R

R
NR
R
R

NR
NR
R
R

NR
NR
R
R

NR

NR

NR

NR
R

NR
R

NR
R

R
NR
NR

R
NR
NR

R
R
R
A
NR

R
R
NR

R
R
R
R
NR

R
R
R

R
R
A
R
NR

NR
NR
R

NR
NR
NR

NR
PUR
NR

R
R

R
R

R
R

R
R

R
R

R
R

NR

NR

NR

NR

NR

NR

R
R

R
R

R
R
NR
NR

NR
NR
NR
NR

NR
NR
NR
NR

R
NR

R
NR

NR
R
NR
NR

NR
NR
NR
NR

NR
NR
NR
NR

NR

NR

NR

R
R
R
R

R
R
R

R
R

R
NR
R

R
R

NR
R
NR

NR
NR
NR

R
R

R
R

NR
NR

R
R

R
R

NR

Poiyv~nyl Chloride
Type 1 Grade 1
2 Chlonnated
Polywnyl
Chlotlde
+ For dramage
appl~caf~o only
R Recommended
10 2:OF
- Data lo 21OF

R
R
R
R

280F

(continued)

NR

UR

230F

265

NR

NR

NR
R
R
NR
NR

150F

R
R
R
NR
NR

PIPING MATERIALS-NIBCO

POLYPROPYLENE

7 3F

R
R
R
R

Chloracerlc
Acid
Chloral Hydrate

AND ELASTOMERIC

Resins and Polymers

NR

lor other

NR

NR

NR

NR

NR

R
R

chemicals

R
R

presently

R
R
R
R

R
NR
R
NR

R
NR
R
NR

R
NR
R
NR

NR

NR

NR

R
UR
UR
UR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

not available

(continued)

266

Corrosion Resistant Materials Handbook

TABLE

1.69:

VARIOUS

THERMOPLASTIC

PVC

CHEMICAL

AND ELASTOMERIC

CPVC

POLYPROPYLENE

3F

140F

r3OF

185F

3F

120F

D~octyl Phthalate
Dloxane
D~oxane. 1. 4
Dlsodlum
Phosphate
Dwmylbenzene

NR
NR
NR
R

NR
NR
NR
R

NR

NR

NR
R

NR
NR

Epsom Salt
Ethvl Acetate
Eth;l Acetoacetate

R
NR
NR

NR
NR

Ethyl
Ethyl
Ethyl
Ethyl

NR
NR
NR
NR

NR
NR
NR
NR

NR
NR
NR

NR
NR
NR

Ethylene

Bromide
Chloride
Chlorohydrln
Dlamme

Ethylene
Ethylene
Ethylene

Dxhlorlde
Glycol
Oxide

NR
R
NR

NR
R
NR

Fatty Acids
Ferrac Acetate
Fernc Chloride
Ferrac Hydroxxde
Ferric NItrate

R
R
R
R
R

R
NR
R
R
R

Ferrac Sulfate
Ferrous Chloride
Ferrous Hydroxkde
Ferrous NItrate

R
R
R
R

R
R

Ferrous Sulfate
Fish Solubles
Fluorine Gas Wet
Fluoborlc
Acld

A
R
R
R

Formaldehyde.
Formaldehyde.
Formaldehyde.

Acrylate
Chloride
Chloroacetate
Ether

Ethylene
Ethvlene
Eth;lene

Formrc Ac,d
Formic Acld
Freon F-11
Freon F-12
Freon
Freon
Freon
Freon

35%
37%
50%

NR
NR
NR
R

NR
NR
NR
R

NR
NR
NR
R

R
NR
NR

NR
NR
NR

NR
NR
NR

R
UR
R

R
NR
NR

R
NR
NR

R
NR
NR

NR
NR

NR
NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

R
R
R
UR

R
R
NR
NR

R
R
NR
NR

R
R
NR
NR

R
R
NR

R
R
NR

R
R
NR

NR
NR
R
R

NR
NR
NR
R

NR
NR
NR
R

R
R

R
NR

R
R
NR

R
R
NR

R
R
NR

NR
R
R

NR
R
R

NR
R
R

NR

NR

NR

R.

R.

R.

R
R

R
A

NR

Nk

Nk

YR
R

NR
R

NR
NR

NR
R

NR

NR
YR
R
R

NR
NR
R
R

R
R
YR

R
R
NR

R
R

R
R

R
R

R
R

d
R

R
R

R
R

R
R

R
R
R

R
R
R

R.

R..

Nk

NR

NR

R
NR
NR
NR

NR
NR
NR
NR

NR
NR
NR
NR

R
R

R
R

R
NR
NR
NR

::

::

R
R
R
R

NR
NR
R
R

NR
NR
NR
R

NR
NR
NR
R

NR
R
NR
R

NR
R
NR
R

NR
R
NR
R

R
R
NR

R
R
NR

R
NR

NR
NR

NR
NR

NR

UR

NR

NR

NR

R
R
NR

NR

NR

NR
NR

NR
NR

NR
NR

NR
R
R
R
R

R
R
R
R
R

R
R
R
R
R

R
R
R
R
R

NR

ik

NR
R
R
R
R

NR

NR

NR
R
R
R
R

idi

R
R
R
R
R

NR
NR
NR

NR
NR
NR

NR
NR
NR

R
R

R
R

R
R

A
R

R
R

R
R

R
R

R
R

R
R

A
R

R
R

ri

::
R
R
R

:
R
R
R

NR
NR
R
R
NR

NR
NR
NR
NR
NR

UR

NR
R

A
R

NR

NR
R

NR

R
R

R
NR
NR

NR

R
R

R
NR
R

R
NR
NR

NR

NR

NR
NR

NR

R
R

NR
R

NR
R

NR
NR
NR
NR

R
R
R

NR
R

NR

R
R
R

NR
NR

NR
R

R
R
R
R

R
R

210F

NR
NR

NR
R

R
R

140F

R
R

NR
R

R
R
R
R

R
R

R.
R

tik

i&l

NR
R
UR
UR
UR

UR
R
R
R
R

1 Polyvmyl Chloride. Type 1. Grade 1


2 Chlorinated
Polyvinyl Chlonde
t For dramage application
only
R Recommended
to 21OF - Data to 210F.

UR
UR
UR
R

EPDM

7 3F

NR

R
R
A
R

185F

NR

R
R

37%

140F

NR

73F

Acld. 20%
Acud. 5wb
Acld. Cont.

ZIJOF

NR

R
R
NR
R

Hydrobromoc
Hydrobromx
Hydrochloric

230F

NR

GeMIn
Glfl
GlUCOSe
Glycerme.

neptane

150F

R
R
R
R
R

Glycohc Acld
Glycols
Grape Sugar

NR
NR

VITON

PVDF

7 3F

(continued)

R
R

Gall~c Acld
Gas. Natural
Gasoline.
Leaded
Gasolme,
Unleaded
Gasolme. Sour

Glycerol

NR
NR

tI

(Anhydrous)

F-21
F-22
F-l 13
F-114

150F lEOoF

PIPING MATERIALS-NIBCO

NR
NR
R

NR
NR

NR
NR

kI
R

for other chemicals

.R
R

R
R

R
R

R
R

R
R

NR
R

NR
R

NR
R

:
R
R
R

presently

E
R
R
R

NR
NR
R
R
R

not avaalable

(continued)

Synthetic Resins and Polymers

TABLE 1.69:

VARIOUS

THERMOPLASTIC

CHEMICAL

PVC

Hvdrocvanc
H;droc;an,c
Hvdrofluorlc
Hydroflurac

Acld
Aad. 10%
Acid. Dalute
Acod. 30%

Hydrofluorlc
Aad. 40%
Hydrofluonc
Acid. 50%
Hydrofluos~l~ac
Acid
Hydrogen
Hydrogen
Hydrogen
Hydrogen
Hydrogen

Cyamde
Fluor!de.
PeroxIde
PeroxIde.

Hydrogen
Hydrogen
Hydrogen
Hydrogen

PeroxIde. 90%
Phosphrde
Sulfide. Dry
Sulfide. Aqueous

Hydroqumone
Hydroxylamme
Hypochlorous
Hydrazme

Anhydrous
50%

Sulfate
Ac!d

lodIne
Iodine Solutton.
Isopropyl
Ether
1sooctane

10%

So

CPVC

WF

14OF

R
R
R
R

R
R
NR
N9

R
A
R
R

NR
NR
R
R

R
NR

R
NR

3F

NR
NR

R
R

R
R

R.

NR

NR

R.
R
R

R
R

R
R

F
13F

230F

R
R
R

R
R
R
R

NR
NR
R
R

R
R

R
R
R

R
R

R
R
R
NR

R
R
R
NR

NR
NR

NR
NR

R
A

R
R

R
R

R
A

R
R
R
R

R
R
R

Lauryl Chlonde
Lead Acetate
Lead Chloride
Lead Nitrate

R
R
R
R

R
A
R
R

Lead Sulfate
Lemon 011
Llgrolne
Lime Sulfur

L~noletc
Llnolelc
Linseed
Linseed

R
R
R

R
R
R

R
R
R
R
R

R
R
R
R
R

MachIne 011
Magnesium
Carbonate
Magnesium
Chloride

A
R
R

R
R
R

Magnesium
Magnesium
Magnesium
Magneswm

R
R
R
R

R
R
R
A

Manganese
Sulfate
Male% Acid
Mal~c Acid
Mercurtc Chloride

R
R
R
R

R
A
R
R

Cyamde
Mercuric Sulfate
Mercurous
Nitrate
Mercury

R
R
R
R

R
R
R
R

.A

NR

iR

NR

NR

R
R

R
R

R
R

UR
R
R

NR
R

NR

.R

NR

NR

25OF

R
R
R
A

R
R
R
R

NR

NR
NR
R
R

NR
NR
R
R

NR
NR
R
R

Uk
R
R

NR
R
R

NR
R
R

UR
UR

NR
NR

NR
NR

NR

NR

UR
UR

NR
NR

NR
NR

UR
R
R
R

R
R

NR

UR
R
R

NR

R
R
A
NR
R

R
R
NR
R

R
R
NR
R

R
R
NR
NR

NR
A
NR
NR

NR
NR

R
R

R
R

R
R

NR
NR

NR
NR

NR
NR

R
NR

NA

NR

NR

R
R
R
R

NR
NR
R
A

NR
NR
R
R

NR
NR
R

R
R
R

R
R
R

R
R
R

R
R
NR

NR
NR
NR

NR
NR
NR

R
R

R
R

R
R

NR

NR

NR

R
R

R
R

R
R

NR
R

NR
R

NR
R

R
R
R
A

R
NR
R
R

NR
NR
R
R

NR

NR

NR

NR

NR

NR

R
R
R

R
R
R

R
R
R

R
R
.R

R
R
R
R

A
A
R
R

R
R
R
R

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
R
R

NR
R
R

NR
R
R

R
R
R
R

R
R
R
R

9
R
R
R

R
R
R

R
R
R

R
R
R

NR
NR
A

NR
NR
R

NR
NR
R

R
R

R
R

R
R

R
R

R
R

R
R

R
R

A
R
R

R
R
R

R
R
R

R
R
R

A
R
R

R
R
R

R
R
R

R
R
R

A
R

R
R

R
A

NR
R

R
R
R

R
R
R

R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

Presently

NR
NR
A
R

210F

NR

ChemlCalS

R
R
NR
NR

for other

NR
NR

14OF

NR

Polyvmyl
Chloride.
Type 1. Grade 1
2 Chlonnated
Polyvmyl
Chloride
+ For dramage
applfcatlon
Only
R Recommended
to 210F - Data to 210F

R
R
NR
NR

R.

R
R
NR
NR

3-F

155F

R
R

EPDM

140F

R
R

7 3F

R
R

(continued)

VlTON

PVDF

1SOF

R
R
R
R

R
R

dt
UP
113

15OFj

Kerosene
Kraff L,quor

Acld
011
011
011 Blue

ISOF

R.

25%
80%

IZOF

PIPING MATERIALS-NIBCO

R
R

MB,CU,IC

NR
NR

R
R
R
R

NR

R
R

Catrate
Hydroxide
NItrate
Sulfate

3F

R
R

Llqers
LIthum
Bromide
Lubr,cat,ng
011. ASTM
Lubr!cat,nq
011. ASTM
Lubncatm~
011. ASTM

POLYPROPYLENE

155OF

NR
NR

Jet Fuel JP-4


Jet Fuel. JP-5

Lactic Acid
Lactic Aad.
Lard 011
Launc Acid

AND ELASTOMERIC

267

not avaIlable

(continued)

268

Corrosion

TABLE

1.69:

Resistant

VARIOUS

Materials

Handbook

THERMOPLASTIC

PVC

CHEMICAL

AND ELASTOMERIC

140F

~efhylene

ik

R
NR

Methylamlne

R
NR

NR

Methyl
Methyl
Methyl
Methyl

NR
NR
NR
NR

NR
NR
NR
NR

NR
NR
A
R

NR
NR

R
NR
NR
NR
R
R
R
NR
R

R
R
R
NR
R

R
R

R
NR
R
R
R
A

R
NA
R

R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
NR

R
R
R
R

R
R
NR
NR

R
R
R
NR

R
NR
NR
NR

NR
NR
NR

NR
NR
NR
A

NR
NR
NR
NR

NR
R

NR
NR

NR

NR

Nitrous Ox,de
Nltroglycol

R
NR

NR
NR

0,lsVegetable
Ole,cAcld

R
R

A
R

R
R

R
R

NR
R
R
R
R

NR
R
R
R
R

R
R
R

NR
R
R
R

R
R

R
NR

R
R

R
R
R
R

R
NR
NR
NR

R
R

R
R
R
NR

R
R
NR

NR
NR
NR
R

NR
NR
NR
NR

Methane
Cplcrobromlde
Methoxyethyl Oleate
Bromide
Cellosolve
Chloride
Chloroform

Oleum
Oxalic Actd
Oxalic Acid 50%
Oxygen
Gas
OZOfl.5
Pai,f,c
Palmittc
Palm,,,
Paraflln
Peracervz
Perchlorlc
Perchlo,,

Ac,d
Acid
Ac,d

10%
70%

Acid 40%
Acid
10%
Acid 70%

Perphosphate
Petroleum
011s Sow

Phenylhydrazme
Phenylhydranne
Hydrochloride
Phosgene
Ltquld
Phosgene
Gas

7 3F

POLYPROPYLENE

CPVC

BF

185F 13F

120F

150F

PIPING MATERIALS-NIBCO

PVDF

18OFi I 7 3F

150F

IR

VITON

230F

R
R
R
R

R
R
R
R

R
R
R

NR
NR

NR
NR

NR

R
NR
NR
NR

R
NR
NR
NR

NR
NR

280F

13-F

140F

R
R

NR
NR

NR

NR

R
R
R

140F

NR

NR

21OF
NR

R
R
R

R
NR
R

R
NR
R

R
NR
R

NR
R
NR

NR
NR
NR

NR
NR
NR

NR
NR

NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

R
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR

NR

NR
NR

NR
NR

NR
NR

R
R

R
R

R
R

R
R
R

R
R
A

R
R
R

R
NR
R

R
NR
R

R
NR
R

NR

NR

NR

NR

R
R

R
R

R
R

R
NR

NR
NR

NR
NR

R
R

R
R

R
NR

R
NR

R
R

R
R

R
R

R
R

R
R
R
NR
R
R

R
R
R
NR
R
R

A
R
R
NR
R
R

NR
NR
NR
R
R
R

NR
NR
NR
R
R
R

NR
NR
NR
R
R
R

R
R
R
R

R
NR
R
R

R
NR
R
NR

R
NR

NR

NR

NR

NR
NR
NR

R
R
R
R

R
R
R
NR

NR
NR
NR
NR

NR
NR
NR
NR

R
R
R
R

R
R
R
R

R
NR
NR
NR

NR
NR
NR
NR

NR
NR
NR
NR

NR
NR

NR
NR

NR
R

NR
NR

NR
NR

NR
NR

NR
NR

NR
NR

NR
NR

NR
NR

NR
NR

NR

NR

R
R

R
NR

R
NR

NR
NR

NR
NR

NR
NR

R
R
R
R
R

R
R
R
R
R

R
R
R
R
R

NR
R
R
NR
R

NR
R
R
NR
R

NR
R
R
NR
R

R
R
R

R
R
R

R
R
R

R
R

NR
NR

NR
NR

A
R

R
R

R
R

R
R

R
R

R
R
R

R
R
R

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR

NR

NR

NR
NR

NR
NR

R
R

NR
NR

NR
NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

R
R

R
R

R
R
R

R
R
R

R
R
R

NR

NR

NR

NR
R
R
R
R

NR
NR
NR
R
R

NR
NR
NR
R
R

A
R

R
R

R
R

R
R

NR

NR
NR
NR
A
R

NR

R
NR
NR

for other

73F

Polyvmyl
Chloride.
Type 1 Grade 1
2 Chlor,nated
Polyvinyl
Chlortde
+ For dratnage appkatmn
only
R Recommended
to 210F - Data to 210F

EPDM

185F

NR
NR

bntinued

chemxals

presently

not wallable

(continued)

Synthetic

TABLE 1.69:

VARIOUS

THERMOPLASTIC

PVC
13F

CPVC

140F

R
R
R
R
R
NA
R

7 3F
R

POLYPROPYLENE

185F

3F

(20F

150F

PVDF
18OFi

3F

150F

230F

NR

NR

NR

R
R

280F
R
NR

13F

(continued)

VITON
140F

269

EPDM
185F

3F

140F

210F

NR
R

R
R

NR
A
R

NR

R
R

R
R

R
R

A
R

R
R

R
A

R
R

R
R

NR

R
R
R

R
R

NR

R
R

A
R

R
R

R
R

R
R

NR
R

R
R

A
R

R
R

R
R

R
R

R
R

R
R

R
R

R
R

R
R

R
R

R
R

Polyvinyl
: Chlonnated

PIPING MATERIALS-NIBCO

R
R

AND ELASTOMERIC

Resins and Polymers

NR

NR

NR

R
R

NR

R
R

R
R

R
R
NR

NR

NR

NR

NR

NR

NR
R

NR

NR

NR

NR

NR

NR

R
R

NR

NR

NR
NR

NR
NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR

NR
R

NR

NR

NR

R
R

NR

Chloride
Type
1 Grade
Polywnyl
Chlortde

R
R

R
R

R
R
R

R
R
R

(continued)

270

Corrosion Resistant Materials Handbook

TABLE

1.69:

VARIOUS

THERMOPLASTIC

CHEMICAL

PVC
73F

soaps
Sodaurn
Sodwm
Sodlum

AND ELASTOMERIC

CPVC

140F

3F

POLYPROPYLENE

185F

R
Acetate
Alum
Benzoate

R
R

* 7 3F

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
NR

R
R
R

R
R
R

R
R
R

NR

NR

R
R
R
R

NR
NR
NR
R

NR
NR
NR
R

R
R

R
R

R
R

R
NR

R
NR

R
R
R

R
R
R

R
R
R

R
NR
R
R

R
R
R
R

R
R

R
R

Sodium
Sodturn
Sodium
Sod,,

Ferrlcyanlde
Ferrocyanide
Fluoride
Hydrox!de

R
R
R
R

R
R
R
R

Sodium
Sodium
Sodium
Sodwm

Hydroxide
Hydroxide
Hydroxide
Hypochlorw

R
R
R
R

R
R
R

Sodturn
Sodium
Sodium
Sod,um

lodlde
Metaphosphate
Nitrate
Nitrite

R
R

R
R

Sodlum
Sodium
Sodium
Sodium

Palmttate
Perborate
Perchlorate
PeroxIde

R
R
R

R
R
R

Sodium
Sodium
Sodium
Sodium

Phosphate
Phosphate
Phosphate
Silicate

Sodium
Sodium
Sodium
Sodium

Sulfate
Suillde
Suif~te
Thlosullate

R
R
R
R

R
R
R
R

Sour Crude 011


Stannlc
Chloride
Stannous
Chloride
Starch

R
R
R
R

R
R
R
R

Stearlc
Acid
Stoddard
s Solvent
SUCCIIC
Acid
Sul+amtc Acid. 20%

R
NR
R
R

R
NR
R
R

Sulfated
Detergents
sui1ate Liquors
Sulfite Liquor
Sulfur

R
R

R
R

R
R
R
R

R
R
R
NR

R
R
R
NR

R
R

R
R

R
R

R
R

R
R

R
R
R

R
R
R

R
R
R

1
R
R

R
R

R
R
R
R

R
R
R
R
R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R

R
R
A
R

R
R
R
R

R
R
R
R

R
R
A
R

R
R
R
R

R
R
R
R

R
R
R

R
R
R

R
R
R

R
R
R

VR
R
R
R

NR
R
R
R

NR
R
R
A

UR
R
R
R

NR
R
R
R

NR
R
R
R

R
R

R
R

R
R

UR
UR

NR
NR

NR
NR

R
UR

R
NR

R
NR

R
UR
UR
A

R
NR
NR
R

A
NR
NR
R

R
R
A
R
R
R
R
R

R
R
R

R
R

\1R

NR

NR

NR

rlR
R
R

NR

NR

NR

R
R
R
NR

R
A
NR

NR

NR

NR
R
R
R

NR
R
A
R

NR
R
R
R

NR

NR

R
R
R
R

R
R
R
R

R
R
R
R

R
NR
NR
NR

NR
NR
NR
NR

R
R
R
R

R
R
R

NR
NR

R
R
R

R
NR
R

Sulfur Trloxlde
Gas
Suilur~c Acid
10%
Sulfuric
Acld. 30%
Sullurlc
Ac,d. 50%

R
H
R
R

R
R
R
R

R
R
R

R
R
R

R
R
R

R
R
R

R
R
NR

Sulfuric
Sulfuric
Sulfuric
Sulfuric

R
R
R
R

R
R
R
NR

R
R
R
NR

R
R
R
rlR

R
R
NR
NR

R
NR
NR
NR

NR
NR
NR

1 Polyvmyl
Chloride.
Type 1. Grade
1
2 Chlonnated
Polyvinyl
Chloride
t For dra,age
appllcatlo
Only
R Recommended
to 21OF
- Data to 21OF

R
R
R
R

R
R

R
NR
R
R

60%
70%
80%
90%

210F

Chiorlde
Chior~te
Cyanide
Dlchromate

Acid,
Acid.
Acld.
Aad.

R
R
R
R

Nk i

140F

R
R

Sodium
Sod,Sodlum
Sodium

R
R
R
R

R
R

R
R

R
R

R
R

R
R

R
R

R
R
R
R

R
R

R
R
R

7 3F

R
R

R
R
R

185F

R
R

Alkaline
Acld
Neutral

EPDM

140F

R
R

5%

VITON

7 3F

Dry
Wet

280F :

Chlotlde
Dloxlde.
Dloxlde
Tr,ox,de

230F

R
R
NR

Sullur
Sulfur
Sulfur
Sulfur

150F

ik

UF

(continued)

ik

R
R
R

Solur~an

18OF

PVDF

150F

Borate
Bromide
Carbonate
Chlorate

30%
50%
70%

120F

Sodium
Sodium
Sodium
Sodium

154.

PIPING MATERIALS-NIBCO

for 3fher

chemicals

presently

UR
R
R

NR
R
R

NR
R
A

A
R
R
R

R
R
R

R
R
R

R
R
R
R

R
R
UR
UR

R
R
NR
NR

NR
NR

not wallable

(continued)

Synthetic

TABLE

1.69:

VARIOUS

F
PVC

CHEMICAL

Sulfuric
Sulfuric
Suifur~c
Sulfuric

THERMOPLASTIC

Actd
Acid
Acid
Acid

93%
94%
95%
96%

I 3-F

140F

NR

NR
NR
NR
NR

NR
NR
NR

NR
NR
NR

R
R
R

R
R
R

NR
NR

Sulfuric Ac,d 98%


Sulfuric Acid 100%
Sulfurous
Ac,d
Tall Oil
Tann~c Acid
Tanning
Liquors
TX
Tartarlc Acid

Tetraethyl
iead
Tetrahydrodurane
Tetrahydrofuran
Tetra Sodium Pyrophosphafe

R
NR
NR
A

NR
NR
NR
R

Thwnyl
Chloride
Thread Ctittlng 011s
TlrplKl
T,tan,m
Te,rachlor,de

NR
R
NR
NR

NR

Toluene
Toluol
Tomato Juice
Transformer
011
Transformer
011 CITE/30

NR

NR

Trlbutyl
Phosphate
Tributyl
Citrate
Trvzhloroacetec
Ac,d
Trichloroethylene

NR
R
R
NR

NR

Tr~efhanoiam~ne
Trtefhyiamlne
Trimethyipiopane
Trlsodlum
Phosphate
Turpentine

POLYPROPYLENE

CPVC

7 3F

185-F

R
R
R
R

NR

R
UR

NR
NR

R
R

NR
NR

NR

R
R

7 3F

120F

150F

UR
UR
UR
UR

NR
NR
NR
NR

NR
NR
NR
NR

UR
UR
R

NR
NR
R

NR
NR
R

NR

UR

ELASTOMERIC

NR

UR

R.

NR

lBOF1

PIPING

1
7 3F

230F

28OF

7: 3F

R
R
R
NR

NR
NR
NR
NR

NR
NR
NR
NR

R
R
R
R

NR

NR

NR

R
R

R
R

R
R

NR

R
NR
NR

R
NR
NR

R
NR
NR

NR

R
NR

UR

UR

NR

NR

UR
R
R

R
UR

NR
R
R

NR
A
NR

R
NR

R
NR

NR

R
R
R
R
R

R
R
R
R
R

R
R
R
R.
R

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R
R

R
R

A
R

R
R

NR
R

NR
R

NR

NR

NR
R
NR

NR

R
UR

R
NR

R
NR

NR

R
R

R
R

R
R

R
R

R
R
R

A
R
R

R
R
R

NR

R
A
R

R
R

R
R

210F

NR
NR
NR
NR

NR
NR
NR
NR

R
R
R

NR
NR
NR

NR
NR
NR

NR
NR
NR

R
R
R

NR
NR

NR
NR

NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR
NR
NR

NR

NR

NR

NR
NR

NR
NR

NR
NR

A
NR
NR

R
R

NR

NR

NR

4R

NR

NR

NR

NR

NR
R

NR
R

4R
R

NR
R

NR
R

R
NR

NR
NR

NR
NR

R
R

NR
NR

NR
NR

NR
NR

4R
R

NR
R

NR
fi

NR

NR

R
R

R
R

R
R

R
R

R
R

R
R

R
R

NR

NR

NR

R
R

R
R

R
R

R
R

H
R

R
H

R
R
R

R
R
R

R
R
R

R
R

R
R

R
R

NR
R
R
R

NR
R
R

NR
R
a

R
R
R
R

R
R
R
R

R
R
R
R

R
R
R
R
R

R
R
R
R
R

R
R
R
R
R

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R
R
R
R

R
R
R

NR

NR

NR

R
R
R

R
R
R

R
R
R

R
R
R

R
R
R

R
R
R

UR

NR

VR

NR

NR

NR

R
R
R

R
R
R

chemicals

presently

fluoride-hexafluoropropylene

R
R
R

NR

R
R
R

for other

NR

NR
R

NR

I Polywnyl
Chlorlde
Type 1 Grade 1
7 Chlonnated
Polywnyl
Chloride
t For dramage applatlon
oniy
R Recommended
lo 210F - Data to 210F

NR

NR

R
R
R

name for vinylidene

140F

NR
NR
NR
NR

R
R

NR

trade

7 3F

,xylol,

VITON:

EPDM
185F

R
R

R
R

140F

271

(continued)

VITON

PVDF

150F

ZIC Chiorlde
Zinc N~trale
zinc Sulfate

xyiene

MATERIALS-NIBCO

NR
NR

NR
R
NR
R
R

water
Salt
water
Sea
water
sewage
Whiskey
White Liquor
w,nes

AND

Resins and Polymers

not available

copolymer.

R
R
R

R
R
R

272

Corrosion Resistant Materials Handbook

TABLE

1.70:

VARIOUS

THERMOPLASTIO

POLYMERS

Stock Type

Composition

Plasticized

Polyamide Resins (Nylon 610)

Polyester Elastomer

Ethylene Vinyl Acetate

Polyurethane

cl

Special Material

1 Excellent Rcstrtance - This fluid is expected


minor or no effect on the polymer.

to have

polymer should give reasonably


2 Good Rerirtrnce -This
satisfactory service. Due to the nature of this chemical
and under prolonged continuous exposure, the stock
may exhibit minor to moderate deterioration and/or
solution discoloration. Environmental changes such as
concentration,
etc.,
temperature,
may
promote
increased degradation.
x Not Recommended
- The stock is unsatisfactory
this chemical and should not be used.
- (Darh) - Insufficient or no data is available
material. Testing is advised.

RUBBER

Polyvinyl Chloride

i!

GATES CHEMICAL

Note

FOR HOSE STOCKS-GATES

(Hytrel)
(EVA)

(Gates Tufflex Hose)

RATING SYSTEM
The amount of discoloration that can be tolerated is
usually established
by the user on the basis of
application. Obviously, products such as paint must be
conveyed
through
a hose
having
very good
nondiscoloring
characteristics.
If the product is not
visually affected, then the hose is satisfactory. For
some
products,
the discoloration
may not be
objectionable from a visual standpoint. However, the
amount
and makeup
of the particles
causing
discoloration may be objectionable if they affect the
final use of the product.

for
Some
of the more
discoloration are:

common

methods

of

checking

for this

1: The above ratings as applied to the Chemical


Resistance Tables are intended as guides only. They
are compiled from the best data available to us. Ratings
shown in the tables are based on a temperature of 70 F.
and 100% concentrated or saturated solutions unless
otherwise noted.

Note 2: If unusual conditions exist, a stock test in the fluid is


suggested.

Allowing the fluid to remain in a sample piece of hose


for a given period, and then inspecting visually for
discoloration.
Testing fluid as in No. 1 above and then passtng it
through filter paper to check foreign content.
A more refined test can be made with a soectroohotometer.
This instrument measures light transmission ihrough the
fluid before and after immersron tests with the stocks. This
ives a relative rating expressed in percent, the original
uid being rated as 100%.

Note 3: Where a chemical listed in the Resistance Tables is


soluble in a solvent other than water, the solvent should
also be checked for its suitability with the stock.
Note 4: Discoloration of fluids conveyed in hose-There
are
no generally accepted standard tests for measuring or
rating discoloration of fluids passing through a hose.

(continued)

Synthetic

TABLE 1.70:

VARIOUS

THERMOPLASTIC

POLYMERS
CHEMICAL

Resins and Polymers

FOR HOSE STOCKS-GATES

RESISTANCE

273

RUBBER (continued)

TABLE
HOSE POLYMER TYPES

CHEMICAL
A
Acetaldehyde ..................................
Acelamrde ....................................
Acellc Acrds ...................................
Acetone .......................................
Acetophenone .................................

2(;[2
-

Use Chemrcal Hoses


1
2
I
I

1
1

Use Weldmg Hoses


1
X
1
1

Atr, 150F .....................................


Air,1600F .....................................
Air. 200F. ....................................
Awcratt
Hyd 011 AA ...........................
Alcohol, Amy1 .................................

2
X
X
-

1
2
X
-

Alcohol, Sutyl .................................


Alcohol, Furlural ...............................
Alcohol.Ethyl .................................
Alcohol, Isopropyl .............................
Alcohol. Methyl (6%). ..........................

1
-

Acetylene .....................................
Acrylonttrlle ...................................
Aero-Safe 2?iOO................................
Aeroshell. 1A. 1AC. 4 ..........................
Air, Ambrenl.. .................................

Alcohol, Methyl (166%) ........................


,Alkazene ......................................
Chlonde............................
1alummum
1Alummum Fluortde ............................
..........................
1Mummum Hydroxrde

2
1
1
1

Nitrate ..............................
I kluminum Sulfate .............................
hIurn
........................................
1
1kmmonia. Anhydrous ..........................
14mmonia. Aqueous ............................

1
1
1

1
1

Acetate ............................
14mmonium Bicarbonate .......................
I4mmonwm Carbonate.. .......................
I4mmonium Chlonde ...........................
.........................
14mmoniumkydroxlde

1
1
1
1

Metaphosphate ......................
Nrtrate ............................
(Fertrlirer)
c\mmonium Nrtrite .............................
I Immonium Persulfate .........................

2
1

b4mmonwm Phosphate.. .......................


Abmmonium Sulfate ............................
Pbmmonium Bulfrde ............................
P\mmonwm Thiocyanate .......................
Armyl Acetate ..................................

1
1
1
X

Akmyl Borate ...................................


Armyl Chloride .................................
Aimyl Chloronaphthalene .......................
.............................
A,myl Naphthalene
Armyl Phenol ..................................

1Muminum

14mmonwm

14mmoma

14mmonium

Anathole ......................................
Aaniline .........................................
A&line Oils ....................................
A,rrimal Fats ...................................
A,nti-Fraaze (Glycol) ...........................
A ntimony Chlorrde (50%) ......................
A ntimony Baits ................................
A qua Regra ....................................
A rcq A T.F. Dexron ............................
Type2 ............................
A rco ATF
.................................
A rcqc-2.100
A roclqr, Monsanlo .............................
A rqmatx Hydrocarbons ........................
A raemic Baits..................................
Aakarel (Transformer 011) ......................

2
1
-

1
1

1
1
1

1
1

2
1

2
2
1

2
1

1
1

1
1

2
2

2
2

2
1
1

X
1
2
1

1
1

X
1

2
2

1
1

2
-

X
1
Use Chemical
1
1

x
-

X
1
-

X
X
1
2
2

Hoses
-

2
1

2
1

1
X

;
)

1
)

1
1
-

2
-

1
1

X
-

1
1
1
1
Use Chemical Hoses

X
X

CI

:
2
2

1
No Hose Available
1

2
2
2
-

2
X

1
1
1
1
1

1
1
-

X
(continued)

274

Corrosion

TABLE

1.70:

Resistant

VARIOUS

Materials

Handbook

THERMOPLASTIC

POLYMERS

FOR HOSE STOCKS-GATES

RUBBER bontinued)

HOSE POLVMER TYPES


G

CHEMICAL

A-Continued
Asphalt, 18OF ................................
ASTM O,l No 1.. ..............................
ASTM 011 No 2 ................................
ASTM 011 NO 3 ................................
ASTM Ref Fuel A .............................

2
X
X
2

ASTM Ref Fuel B .............................


ASTM Ref Fuel C .............................

B
BalticTypes

100 150. 200 300. 500 ............


Banvel. Concentrated ..........................
Barium Carbonate .............................
3arwm Chlonde ...............................

1
1
1

3arlum Hydroxide .............................


3arfumSulfate ................................
3arlum
Sulfide ................................
3aslc Copper Arsenate ........................
3aygon .......................................
3eer ..........................................
3eel Sugar Lquors ............................
3ellows.SO-20 Hydraulic Oil ...................
3enzaldehyde .................................
3enzene ......................................

Use Chenvcal Hoses


I
2
I

--

Use FDA Hoses

:
X

3enzoic Actid ..................................


3enzyl Alcohol ................................
$lack Sulfur LlquOr ............................
)orax (Sodium Borate) ........................
{ordeaur Mxture .............................

1
2

Use Chemical Hoses


2
2

1
1

1
1

2
-

Acld ....................................
iorlc Copper Sulfate ..........................
hake Flwd (Petroleum) ........................
lrake Flwd (Synthetic) ........................
lrme (Salt) ....................................

X
1
1
2
1

1
1
1
1
1

2
-

Elunker 011 ....................................


Elutane. Gas or Liquid ..........................
B#utter ..........................................
t ebutyl Acetate ...................................
0 ,utyl Alcohol (ButanOl) ........................

I
2
I
Use 20BHB Only
Use FDA Hoses
2
1

X
1

low

alcium Arsenate
alcium
al&m
alcium
alctum
slcium

1
1

...............................

Bisulfate ...............................
Bisutflde ...............................
..- ....................
Bisulftte ........
Carbonate .............................
Chlorite... .............................

Chloride. 1.. ...........................


Hydroxide (Cont.) .....................
Clklcium Hypochlorite (5%) .. ....................
Calcium HypochloftlO (15%). .._ . . . . ..__. .__._.. .
Calcium Nitrate _.. . . . . . .
..... .... .... . ..

ccslcium
ccllcium

Calcium Silicate . . . . . . . . _. . . . . . . . . . . _. . . . .
Calcium Sutflde . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cane Sugar Lquon
. . . ._.. . . . . . . . . . . . . . . . . . .
Carbohc Acid (Phenol) . . . . . . . . . . . . . . . . . . . . . . . . ,
Carbon Disufhdc . . . . . . . . . . . . . . . . . . . . . . . . . .
Carbon Dioxide (Dry) . .
......... ...........
Carbon Dloxicb (Wet) . . . . . . . . . _. . . . . . . . . _. _. . . :
Carbon Totnchloride . . . . . . .._. . . . . . . . . . . . . _...
Carbonic AIM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Carter MotorDt1................................

2
-

1
2
1

1
1
1

1
Use Chemical Hoses

2
1
1

1
1
1

2
1

1
2
1

1
Use Chemical

X
7
1
X
2

Hoses
2

1
1
1
1

Use Chemical H05en


1

1
1
X

1
X
2

Synthetic

TABLE 1.70:

VARIOUS

THERMOPLASTIC

POLYMERS

Resins and Polymers

FOR HOSE STOCKS-GATES

275

RUBBER (continued)

HOSE POLYMER TYPES


CHEMICAL

C-Continued
Caseln ........................................

CastorCM.....................................

Caustic Potash (30%) ..........................


Caustic Soda (20%) ............................
Cellosolve Ace!are.............................

1
1
I
Usd Chemical Ho;es
Use Chemical Hoses

c2

>

Cellosolve. Union Carbode .....................


Cellugard. Cellugard 200 .......................
Cellulube, 80. 150. 220. 300 ....................
550. 1000 22OA. ST220 A60 .................
Chlorine Water (25%) ..........................
Chlorme Gas ..................................
Chlorine Trrtluorlde ............................
Chlorobenzene ................................
ChlorobrOmO Methane .........................
Chlorodane ...................................

Chloroform ....................................
Chlorosulfonic Acfd ............................
ChlOrO!Ol~ne

Chlorox..
ChOcOlale

.................................

.....................................
Syrup ...............................

Chrome Alum .................................


Chromic Acid .................................
Chromium Salts ...............................
Cider .........................................
Citpo A.T.F. Type F. Dexron ....................
Crroo
Citgo
Citgo
Citgo
Cttgo

X
X
X
2

2
1

.,

~tlonaead
Oils ................................
Creosote .......................................
Creoaol (Cresylic Acid) .........................
Crude Petroleum Oil ............................
Cyclohexane
. . . . . . . . . . . . . . . . . . . _. . . . . .

2
2
2
2
2

1
1
1
1
1

1
1
X
-

2
-

X
1
1

1
2
2
1
1

2
X

1
X

2
2

1
X
:hemicel l-l
1
1

--

1
1
1
1
1
1
1
1
2

US

..................................
Cycloheunone.................................
Cymene ........................................

Daaco. FR160: FR200. FRZOOB.


FR310 ........................................
Daaco IFR ......................................
DC 200. 510. 550. 560.. .........................
DDT Weed Killer (DIL.) .........................

2
2
2
2

Developing Solutions ...........................


Dexron .........................................
Dextrin .........................................
Dtacetone Alcohol ..............................
Diammonium Phosphate ........................

-c
HlOs(

1
1

Cyclohexanol

Docalm . . . . . . . . . . . . . . . .._.................._...
Deionized Water ................................
Decrol R 6 0 Oils ..............................
Denatured Alcohol ..............................
Datergant Solutions .............................

Zhemxal
1
1
1

:
2

Copper Chloride ...............................


Copper Cyanide ...............................
Copper Nitrate .................................
Copper Sulfate .................................
CornOils
......................................

FJOIHose Available
UI ;e IZhernlcal l-lost
2
1
UI

FR Fluids. . . _.. . . . . . . . . . . ._. . . . . .


Glycol FFMOXD .........................
Pacemaker ..............................
Sentry ...................................
Tractor Hyd Fluids ......................

Citric Acid ....................................


CoalGas ......................................
CoalTar
......................................
CokeOven Gas ................................
Condor Oils. 1WO. 1002. 1004 .................
1006.1008.1010, 1012, 1014. 1016

1
1

No Hose Available

:
-

t
2
1
1

2
ltact Gate:

1
2
1

X
X
!s
-

X
X
-

2
2

1
2
1
1

1
1
2
2

:ontlnued)

276

Corrosion

TABLE

1.70:

Resistant

VARIOUS

Materials

Handbook

THERMOPLASTIC

POLYMERS

FOR HOSE STOCKS-GATES

RUBBER (continued)

HOSE POLYMER TYPES


c

CHEMICAL

D-Continued
Drazmon. Drlute ................................
Dlbutyl Phrhalate ...............................
...............................
Dtchlorobenzene
Drchloroethylene ...............................
.....................................
DreselOrl

2
X
X
-

2
2
2
1

2
1
X
2
1

2
X
X
X

2
X
1

D@thanolamlne (20%) .......................


Dlelhylamtne ...................................
Drethyl Ether.. .................................
Drelhyl Glycol ..................................
Droctyl Phosphate ..............................

2
1
2
1
X

2
-

2
-

1
-

2
2
2
1
2

2
1

2
1
X
1

X
X
-

Dtoxane ........................................
Dow General Weed Killer (~~0)
Dowtherm A ...................................
Duro FR-HD., .................................
Duro OrIs .....................................
DP 47. 200 FluId (Dow)

.................

;
X
X
2

.........................

2
1
2

1
-

E
Enamels.......................................

Energol HL66 ..................................


Energol HLPC66 ................................
EP Hydraulrc Orb.. Chevron ......................
Essential Oils ...................................
Ethanolamrne ..................................

2
2
2

1
1
-

1
1
1

1
-

Ethers .........................................
.......................
Ethyl Acetate ...........
Ethyl Alcohol (Ethanol) .........................
ithyl Chlorrde.. ................................
EthylEther ....................................

2
X
2
X
X

X
1
1
-

2
2
1
X
2

1
1
-

2
2
2
X
-

................................
Ilhyl MerCaptan
..............
Ethylene Chlorrde ...............
Ethylene Chlorohydrin ..........................
ilhylene Glycol ................................

X
X
X

1
1

X
X
1

I
)

X
X
1

errous Sulfate .................................

1
1

1
1

1
2
1

...............
we Resistant ktyd Fluid (TeXaco)
king Solutron (Photo) .........................
.................................
luorborickid
luorine Liquid .................................
._. .........
tuoailicic Acid ....................

ormaldehydc (37%). ...........................


ormic Acid ....................................
R Fluid D .....................................
R Hydraulic Fluid ..............................
FtM ...........................................

won (all tym) ................................


_. . _. ...............
wit Juices ...............
nloil........................................
. ............................
rmaric Acid ......
rran (Furturan). ..............................
rrtural (Ant Oil) ...............................
._........
rrguard 150, 200. 226 .................
nquel go. 16Q22Q 300. sx). tooo.
...............
16RA0.22oA40.55oR&0..

....................................
....................................
arrrc Chlorrde .................................
_..............
erric Sultate ....................
errous Chloride ...............................
errous Nitrate .................................

:actovis 52
:atty Acids

1
1
2
1
1
-

1
1
1
1

>
i
2
2
2

Use Chemical Hoses


No HoseAvailable
UseChemical tioaes

3
-

X
-

2
I
lha Chemical Hoses
1
1
1
Special Hose Raqurrad
1
1
I
I
Use Chemical Hosas

2
1

1
1

(continued)

Synthetic

TABLE 1.70:

VARIOUS

THERMOPLASTIC

POLYMERS

Resins and Polymers

FOR HOSE STOCKS-GATES

RUBBER (continued)

HOSE POLYMER TYPES


CHEMICAL

Galllc Ac8d ..................................


..........
Gas, Natural ..................
Gasoline. Regular Unlealed...............
Gasolme, Regular. Leadec .....................

Use
X
X

II

ChemicalHoses

Contacl

Gasoline. Premium ..........................


Gasohol .......................................
Gelatin. ......................................

Gates
X

1
1

X
X

1
1
2

1
1
1

1
1
1

1
1
1

1
1
1

1
-

1
-

1
1

1
1

X
X

X
X

1
1

X
-

X
X

1
1
1

Glucose ......................................
.........................................

Glycerine (Glycerol) ........................


Glycol FR Flulds ...............................
Grease.......................

Glue

277

..................

FR FluId G-ZOO ..........................


t
Gult FR Flutd P37. P40. P43. P45. P47 ..........

Gulf

1
1
1
-

1
1
1

H
Heptachlor

(m

Petroleum) ......................
Heptane .......................................
Hexane ....................................
Houghto-Safe
271.416 .........................
520 526. 616. 620
625 640

2
2
2
-

Houghto-Safe 5046. 5046W ...................


Hy-Chock 011 ................................
Hydra Fluld. AZR (L 0. A. 0. AA. C .............
Hydra FluId 760 ...............................
HydraSol A ....................................

Hydraultc
Hydraulic
Hydraulic
Hydraulic
Hydraulic

Flwd
FluId
Flwd
FluId
Flutd

HF-31 .........................
HF-16. HF-20 ...................
(Std Petroleum). ...............
(Phosphate Ester) ..............
(Waler Glycol) .................

Hydra&c FluId (Texaco Safely 200. 300).


Hydraulic 011s (Shell) ..........................
Hydrazme .....................................
Hydrobromlc Acid .............................
Hydrochloric Acld .............................

.......

Chloride ............................
Fluoride .............................
Peroxide (lo). ......................
Peroxide (Over 10%). ............
Sulhde ..............................

Hydrolubric 011(Houghton) ............


Hydrolube (Water Glycol) .......................
Hypochlorous Acid ..... _. _. ....................

2
1
1
1

2
2

2
2

1
1

2
-

2
2
2
1

:
-

Use Chemical Hoses


Use Chermcal Hoses

Hydrocyamc Acld .............................


Hydro-drme 011.. .............................
Hydrofluoric Acid ........ __....................
Hydrofluosllicx Acld ...........................
Hydrogen ....................................
Hydrogen
Hydrogen
Hydrogen
Hydrogen
Hydrogen

--

Use Chemical Hoses


2

Use Chemical Hoses


Use Chemical Hoses
Contact Gates

Use Chemical Hoses

Use Chemical Hoses


Contact Gates

_. ..
2
2

1
1

._... _..

I
Imd. Imd 5150. 5220.5300. 5500 ................
lnduatron .....................................
.._ ...................
Ink. Printers.. ............
lnrulating Oil, Transformer ......................

1
1
1

1
1
1
Use LPG Hoaea Only

IklIne ..........................................
Iodine. in Alcohol ...............................
lrut Fluid 902 ..................................
, .. ., ........
lrusFluid BOS ......................
lrobutane.. ...................................
aobutyl Alcohol ................................
..__....._
...................
soOctane..
......
__. ..................
a0 Ropyl Acetate .........
so Ropyl Alcohol (Iroproprnol) ................

moPropylEthw ............

., ..................

1
2
2

(continued)

278

Corrosion

TABLE 1.70:

Resistant

VARIOUS

Materials

Handbook

THERMOPLASTIC

POLYMERS

FOR HOSE STOCKS-GATES

RUBBER (continued)

HOSE POLYMER TYPES


0

CMEYICAL

I-Continued

_. _. _.

I.50Cyanate

_.
J

,e,FuelJP-3...................................
let Fuel

JP-4

_.

let Fuel JP-5...................................


let Fuel

JP-6

_. .

let Fuel

JP-X

_..

2
2
2

_.

_. _.

_,

.__

.._.

._.

_.

_.

._._.

ttar0 Syrup .....................................


t(erosene .......................................
t(etones ........................................

(Toluene Of-lsocyanate)

X
X

--

2
2
-

1
-

L
L.acquers
L acquer

.......................................

L ead.

Acetate ...................................
Arsenate ..................................
Sullate ....................................
Telraethyl ................................
Tetramethyl ..............................

L me

...........................................

L ead
L ead
L ead
L ead.

Llubrtcattng

011s

1
2
2
-

(Orester)

M
achrne 011 ....................................
M agnestum Carbonate ..........................
Chlorrde ............................
U agnesturn
U agnesrum Hydroxide ..........................

2
1
1

agneswm NItrate . . . . .
. . . . . . . . . .._._.
a&3eswm Sulfate .............................
U agnus-Light .................................
...............................
U agnus-Medw'n
hl alarhron (Ag. Spray C on C) ...................
U

1
1
1

:
1

,yonn.rsc ....................................
*Iamine Varnish ..............................
Mcwuric Chloride ..............................
Mcwcuric Cyanide ...............................
MCwcurous Nitrate ..............................

2
2
-

Mercury ........................................
Marcury Slttr ..................................
Metallic Soaps ..................................
Meaityt Oxide ..................................
Mathcne .......................................

1
1
1
X

Methoxychlor

&elate
UethylAcrylrt.

Why1

WhyI

(Inaectici6a)

. .. . . .. . . . . . . . . . . . . . . . 1

.................................
.................................

Alcohol (h40thW~M) ......................


.............

X
1
-

1
1

X
-

2
X

1
1
1
Use Chemical Hoses

X
1

1
1

1
1
1
1
2

1
1
1
1

MImlathion (Ag Spray Dilute). ....................


Ml8licAcid .....................................
Ul sngancae Satts ...............................
Mlsnganeae Sulfnte .............................
Mcsximut (Hyd. Fluid) ...........................

1
-

1
2
1
2
1

2
X

.......................

1
1
1

2
1
1

:
2
2
-

............................

1
2
1
1
1
2

1
-

L iqutd Soap ....................................


011s ................................
Llubrlcatmg

I
I

1
1
2

Bleach ....................................
L rme Sulfur .....................................
L mdane (Ag Spray). ...........................
L tnseed Cake
011 (Bolled)

Use Chemical Hoses

L rme

L maeed

X
X

Solvents ...............................
_,..............
L actrc Acld ...................
L asso (Ag Spray) ...............................

1
-

1
Use Chemical Hoaea
1

1
-

2
2
2
-

2
1
2
2
2
2
2
-

1
1

_I
2

X
2

(continued)

Synthetic

TABLE 1.70:

VARIOUS

THERMOPLASTIC

POLYMERS

Resins and Polymers

FOR HOSE STOCKS-GATES

279

RUBBER (continued)

HOSE POLYMER TYPES


G

CHEMICAL

M-Continued
Me!hyl

Methyl
Melhyl
Methyl
Methyl

AmIne (60%) ...........................


...........................
Amlne (9%)
Amy1 Carbmol.. ........................
Bromide ...............................
Butyl Ketone (MBK) ....................

Methyl
Methyl
Methyl
Methyl
Methyl

Cellosolve ..............................
Chlonde ...............................
Ethyl Ketone (MEK) .....................
Formate ................................
lsobutyl Ketone (MIBK).................

2
X
2

Methyl isopropyl Ketone .......................


Methyl Methacrylate ...........................
Methyl Salrcylate ..............................
Methyl Sulfate. ................................
Methvlene Chlonde............................

X
-

X
-

1
X

Methylene Dlchlonde
.
.
Milk ...........................................
MIneral 011 ....................................
MIneral Spirits .................................
Mobile Hydrauhc Oils ..........................

X
1
1
-

I
I

Mobilmet S 122..
. .. .. . . .. . . .
Molasses ......................................
Monochlorobenzene
...........................
Motor 011s
....................................
...................
Munatx Acid (Hydrochlonc)

1
1
1

2
2
X
2

1
1
X
1

X
X
-

X
-

1
1
-

X
1
1
-

1
X

2
1
X
2

2
2
X
2

1
2
-

1
1
X
1
Chemical Hoses

U!

X
-

X
1
1
-

(Mustard.......................................

1
X

1
X
-

X
X
-

2
-

N
I

Naphtha (Low Aromatic Content)

. .. ........ .

/
Contact Gates

Naphthalene ...................................
Natural Gas ...................................
Nickel Acetate .................................
Nickel Chloride ................................
Nickel Nitrate .................................

Nickel Salts ...................................


Nickel Platmg Solution .........................
..:. ....................
Nxkel Sulfate .........
Nwzotine .......................................
Niter Cake (Sodium Bisulfatel ...................
Nitric Acid . . . . . . .

1
1
1
X

__.

1
1

......

~~

2
2

Nyvac20 (WG) 30 (WG) ........................


n-Octane .......................................

Ctctyl Alcohol ..................................


Oil (SAE) ......................................
Oil of TurPwttine ...............................
Oila. Animal..
.......... ... .... ....... .......

. . . . . . . . . . . . . . . . . . . . . . . .._.

Nitrogen Oxide up to 50% . . . . .._. _.._..

2
2
1

Use Chemical
1
I
1
1

Use Chemical t
X
I

-4
1
1

ies
1

1
1

X
-

1
-

1
-

X
X

ms

1
1

2
2
Use Chemical F

les

1
1

1
1
1
U

-f
1
2
2

X
-

:~

2
1
2
x
2

1
1
1
Chemiul
2

1
1
1

_I
X

2
2
2
2

(continued)

280

Corrosion Resistant Materials Handbook

TABLE

1.70:

VARIOUS

THERMOPLASTIC

POLYMERS

FOR HOSE STOCKS-GATES

RUBBER (contimed)

HOSE POLYMER TYPES


G

CHEMICAL

O-Continued
OS 45

Hydrauhc Flu&d .........................


(Sd0cate Ester Base)
Oxakc Acid ....................................
Oxygen .......................................
Ozone ........................................

UseChemcalI
-

es
1

P
Pacemaker Types 15OT. 300T
SC0T (Citgo) ................................
Pamt ..........................................
Pam1 Solvents (Oil Base). ......................
Pamts (011 Base) ..............................

Palm 011 ......................................


Palmmc Acid ..................................
Paraffm (Petroleum) ...........................
Paralormaldehyde .............................
Peanut 011 ....................................

X
-

1
-

Pennant Motor
OfIS ............................
Pentachlorophenol m 011. ......................
Pentane .......................................
Perchlortc Acid ................................
Perchloroethylene
_.
.

Use 20BHB C
Use Chemrcal t

es

2
-

Pentasol ......................................
Petroleum 011s .................................
Petroleum 011s (Sour). .................
._. ......
Pelroleum 011s (Refmed)
........................
Phenol (Carbohc Acid). .........................

2
2
Use Chemical t

Phenolates .....................................
Phorone .......................................
Phosphate Esters (to 150F) .....................
Phosphate Esters (above 15oF). ................
Phosphorrc Acid. ...............................

2
Use Chemmal Hoses

Photographrc. Developers .......................


Photographrc. Emulsions .......................
Photographic. Fuung Solutrons..................
Phthahc Acrd ...................................
PICNICAcid (Water Solution). ....................
RneOil........................................
Pmene .........................................
Prperarme Hydrochlonde Solution

Use Chemical Hoses

...............

0-w
X

Prtch ...........................................
Platmg Solution (Chrome) ......................
Polyester Resin .................................
Polyurethane (to 125F) .........................
Potassium Acetate ..............................
Potassium Bromrde.............................
Potassium Bmarbonate . . . . . . . . . . . . . . . . .
Potassium
Potassium
Potassium
Potassium
Potassium

Brsulphrte ...........................
&ornate .............................
Carbonate ...........................
Chlorate ............................
Chromate.. .........................

Potassium
Potasrium
Potassium
Potarsium
Potassium

Chloride .............................
Cuprocyantde ........................

Dichromate..........................

Ferrocyanlde .........................
Fluoride .............................

Potarrium Hydroxide
Potassium Hydroxide
Potassium Hydroxide

1
1
1

.... ...

.I

1
1

2
1
1

1
1
1
1

1
1

2
2

2
1
1
1

1
-

(low) .....................
@Mb) .....................
(50%) .....................

Uae Chamial Hoses


Use Chamical Hoses

..............................
...............................

1
1

Permanganate .......................
Permanganate (5%) .................
Panuttate. ..........................
Phosphate ...........................
Sulfate ..............................

X
X
1
1

Potasswm Iodide
Potassium Nttrate
Potassium
Potassium
Potassium
Potassium
Potassium

Use Chemical Hoses


2

(continued)

Synthetic

TABLE 1.70:

VARIOUS

THERMOPLASTIC

POLYMERS

Resins and Polymers

FOR HOSE STOCKS-GATES

281

RUBBER (continued)

HOSE POLYMER TYPES


0

CHEMICAL

p-continued
potassium Sulhde ..............................
p0ta~sw-n
Sulfite ...............................

potassr~rh Throsullate ..........................


.......
Powerlube (Carter) .....................
:Prrmatol A. S. P (Agrrc Spray). ..................

:
-

Purrna Insectrcrcte ....................


Puropale RX 011s ...............................
Pydraul F-9 .....................................
Pydraul SCIE ....................................
Pydraul150 ....................................

1
2

2
-

.........

Use 2OBHB Only


u! se Chemical Hoses
1
2

1; / z

propaneGas

...................................
P,op,onrc Acrd .................................
Propyl Acetate .................................
Propyl Alcohol (PrOpanOl) ......................
Propylene Glycol ...............................

,
,
,
,

2
-

2
-

2
2
2
2

(
(

2
1
2
1
2

2
X
X
X
X
X
X
X

X
2
1
X
2

X
2
1
X
2

X
2
2
;

X
X
1
X

1
1

2
-

X
2
X
X

2
-

1
-

2
1
-

Ramrod (Ag Spray) ............................


RandoOrls ....................................
Rape Seed 011. .................................
Red 011 (Comm Olerc Acrd). ....................

1
1
2
1

2
1
1

Retrned Wax (Petroleum). ......................


Regal 011s (R 6 0). .............................
Rrtchlreld A Weed Keller.......................
Rosm (Lrghl) ...................................
Rubrlene 011s.. .................................

2
2
2
2

1
1
1
1

1
1
2
1
1

jalrcylrc Acrd ...................................


jail Water (Sea Water). .........................
jantosafe W-Gl5. W-G20. W-G30 ...............

1
2

1
1

X
X
1
1

jauerkraut .....................................
;CC 7204 (Strutter) ............................
ievin ..........................................
*wage..
......................................
;FR Flurd B (Shell) .............................

2
-

Pvdraul
Pydraul
Pydraul
Pydraul
Pydraul

A-200
_.
260
_, _. _.
312
_..
540
__. _.
625
_. _. _.

_._.
_.

_.

_._. _.

_. _.

_.

_.

.
_, _. _._. _._. ._. _.
.._.

Pydraul 10E 23E LT. 30E. 65E ll-SE..


Pydraul. 135..
._. __. ..__.___.
Pyrene (Carbon Telrachlorrde)
Pyrethrum......................................
Pyrrdrne (50%).
_. _. _. _._. _.

_._._.
_. _.
_. _.

Pvrooard 51. 53 55..


.._.___. _.
F+ogard 160 230 630 ..........................
PyrogardC.0
..................................
Pyronal (Transtormer 011) .......................

jafetytex 215

...........

........................

:
1
2

:
-

:
2

1
1
1

2
1
1
1

1
1
1
-

1
2
-

1
1
1
1
1

:
1
1
1

................................
odwm Benzoate. ..............................

1
1
1
1
1

1
1
1

1
1
1

1
1
1

1
1
1

1
1

1
1
1
1
1

1
1
1
1
1

2
X
1
1
1

1
1
1
1
1

(
>

2
2
-

iilwr Nitrate ...................................


ikydrol 500 A.1 7OW.. .........................
hap Solutrons .................................
ada Ash (Sodium Carbonate) .................
0da Water .....................................

odrum Btcarbonate ............................


odrum Brsultate (Nrter Cdke)...................
odwmBrsulfrte ................................

2
-

odrum Acetate

2
-

;FR Fluid C (Shell) ............................


ihellac .........................................
iiticone Grease .................................
iilicone OrIs ...................................
iilw! Cyanide ..................................

2
2
1

2
2
2
-

2
X
1
1
1

1
1
1

_A
:
1
1

2
1
1
1

,
continued)

282

Corrosion Resistant Materials Handbook

TABLE

1.70:

VARIOUS

THERMOPLASTIC

POLYMERS

FOR HOSE STOCKS-GATES

RUBBER (continued)

HOSE POLYMER TYPES


CHEMICAL

S-Continued
Sodrum
Sodium
Sodrum
Sodjum

............................
D,ch,o;ate
Ferr8cyanrde .........................
Ferrocyanide ..........................
Fluorrde (70%). .........................
Hydrosulfrde ...........................

Sod!um

HydroSUlflle............................

Sodrum
Sodiwn
Sodrum
Sodrum

Hydroxrde
Hydroxide
Hydroxrde
Hydroxrde

Sodmum

(10%). ......................
(40%). ......................
(50% 115F). ................
(50% 160F). ................

jodjum HypochlOrlte (20%) .....................


Sodwm HypoSuffate ............................

..... ._..................
SodlurnMetaphosphate
.................................
Sodaurn
Ndrate

................................
................................
Sod#m!&lflle .................................
Sochum
Throsulfate (HPO) .....................
jodrum Trrpolyphosphate (STPP) ...............
Solns011s
.....................................
Solvac1535 G ..................................
jodrum Sulfate

So&urn

!julfde

ES

Use Chemrcaf 1
2
1

ES

1
1
1
1
-

1
1
1
1
-

SlannousChlorrde..............................

1
1
1
2
1

No 15. 16. 25, 31. 35. 51 ................


.........................................
FR .....................................
Acrd ............................
........................................

1
1
1
1
1

joybean DIG....................................
jtannrc Chlorrde. ..............................

jtanorl
Starch
jtaysol
jtearrc
jtearin

jtoddard Solvent ...............................


jtrarght Synlheuc OrIs .......................
(phosphate ester. phosphate ester base )
jtyrene (Monomer) ............................

.......
2
1

__

.................................

T
allOil .........................................
IIIOW .........................................
uvrrc Acid (10%) ..............................
u (Bituminous) ...............................
vOrl.........................................
rrlaric Acid.. .................................
dlus Oils .....................................
rnol Oil8 ......................................
*pinwl
......................................

ES
es

es
1
-

X
X
-

1
1
1

X
1

Use Chemrcal HOSeS


1

1
2
1

julfur Droxrde (Lrqurd). .........................


jullur Dfoxrde (Moist) ..........................
_.
.,
julfur Hexaflounde (Gas)
................
julfur Trroxfde (Dry). ..............................
julfurlc Acid ...................................

untac WR Oils

Use Chemrcaf k

.................
julfamrc Acrd ...............
julfate Liquors .................................
jurfur (2OO%F) .................................
julfur Chlorrde .................................
julfur Droxrde (Dry) ............................

.....................
unvisOils (700.6@3.900)
uper Hydraulic Oils ...........................
33 Fluid (ConooO) .............................
ynthetic oil (Citgo). ...........................

1
+
+
k

1
1
1
1

CheTrcal
Chemical
Chemrcal
Chemrcal

1
1
1

Perborate ..............................
Peroxrde ...............................
Phosphates. ...........................
.jrlrcate .................................

2
2
2
Use
Use
Use
Use

Sodun Hydrorrde (60%) .......................


Sodtun Hypochlonte (5%) .....................

jodrum
jodrum
Sodrum
jodrum

X
X
2
1
Use Chemical Hoses
2
2
2
2

2
x
2
2
1

2
1
2
2

Chemtcal
1
1
1
I
1
1
1
1

sses

Synthetic

TABLE 1.70:

VARIOUS

THERMOPLASTIC

POLYMERS

Resins and Polymers

FOR HOSE STOCKS-GATES

283

RUBBER (continued)

HOSE POLYMER TYPES


0

T-Continued

Terresstlc ..............................
Telraethyllead (TEL). ...................
TefrahydrOfurNl
(THF). .................
Tetralm ................................
Th,open................................
Toluene (Toluol)..
Toluene Dllsocyanate..
Transformer 011 (Petroleum Type)
Transformer 011 (Askarel Types).
Transmission FluId (Type A)
Trlbutoxyethyl Phosphate..
Trlbutyl Phosphate
Trtchloroethylene..
_. .
Trlcresyl Phosphate (Skydrol)
Tne:banolamine ITEA)

. .

._ .

. .
_.. _.
_. . _, _,
. . . _. _._. .
.
. .
. .
._ _.
_._. ._.

Ucon MI .......................................
Ucon Hydrolube Types 15OCP. 2DOCP. 275CP.
3OOCP. 550CP. 900CP. 150DB. 275DB.
150LT. POOLT. 275LT. 300LT.
2OONM. 300NM

2
-

:
-

1
2

Water
Water
Water
White
Wood

1
1
1

:
1

X
.. .. .. .. . .. . ... ... . . . ... . ... ... . .

1
1

zenc ...........................................
ZmcAcetsle...................................

Zinc Chloride Solutions ........................


Zmc Hvdrate ...................................

:
1

Zmc Oxide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Zinc Sulfate Solutions . . . . . . . . . . . . . . . . . . . . . . . . .

-i-

I r

2
2
1
-

ntact Gate

(Distilled) ................................
Glycols .................................
in Oil Emulsions ..........................
6 Bagley No. 2190 Cutting Oil .............
Oil .......................................

X
2

1
1
1

FDA Hoses Rwuired

Hoses

A?(:hemlcal Hcse

Water ..........................................
Water (Potable) ................................
Water(Brine) ...................................
Water (Demineralized)
.........................

I
I

2
2

Vmyl Acetate. ..................................


Vmyl Chloride (Monomer). ......................
Vltrea Oils ......................................

(XyW)

Use Chemical
2

2
2
1

xykme

2
I
Use Chemical Hoses

2
2

:
2

...

Umon Hydrauhc Tractor Flwd ...................


Urea Solubon .................................

Use Chemical Hoses

2
2
2
2
2

C-2 Flwd ................................


C-P 011 ..................................
ATF Dexron .............................
ATF Type F ..............................
Hydraulic Oil AW .........................

1
2

2
-

Tnpolyphosphate (STPP) .......................


Tung 011 .......................................
Turpentme.....................................
Tycol Avalon 50. 51. 60 .........................
Tycol A Turblo 37. 50. 58. 60 ....................

Umon
Union
Unton
Union
Union

2
-

Rubbers and Elastomers

TABLE

2.1:

ACRYLIC

ELASTOMER-AMERICAN

CYANAMID

CYANACRYL
is especially
noted for its ability to withstand
most lubricating
oils at 350F
(176C).
including
those sulfur modified
lubricants, essential in the performance
of hot running modern cars. Other petroleum
based
oils, such as high and low aniline point lubricating aliphatic hydrocarbons
offer opportunities
for outstanding
performance
by CYANACRYL.
Resistance to chlorinated
hydrocarbons,
degreasers, LP gases, fuel oils, animal and
vegetable oils and silicate esters is very good. Aromatic
hydrocarbons,
such as toluol, have some moderate to severe
effects but ketones, some alcohols and oxgenated
solvents can cause severe swelling. Nonpetroleum
based brake
fluid, phosphate ester, and diester synthetic lubricants can have a severe effect so CYANACRYL
should be tested
in these environments
before using. CYANACRYL
shows fair resistance to dilute and concentrated
acids and
bases. Therefore,
caution or a test first method is suggested when considering it for this type of application.
Fluid

Resistance

Data for CYANACRYL

Room Temo.
Fluid
Ethyl Acetate
Amyl Acetate
MEK
Varsol
Toluene
Kerosene
Naphtha
Acetone
Trichlorethylene
Perchlorethylene
Reference Fuel A
Reference Fuel B
Reference Fuel C
Leaded gasoline
Lead free gasoline
Water
Freon # 12
# 2 Diesel Fuel
Silicone Fluids
Ethylene glycol
Elco # 28 Oil (SAE 140)
Texaco TL 3450 (ATF)
Wheel Bearing Grease
Regular SAE # 20 Oil
Premium SAE # 20 Oil
Premium 1OW - 30 Oil
Premium Outboard
Motor
ATF - Type A
ATF - Type C
Hydraulic
Fluid
Mil O-6081
Hytran Tractor Fluid
ATF Chrysler MS4228
Anti-Freeze
Lubrizol G L-5 (SAE 140)
Jet II Hydrocarbon
Fluid
NOTE:

118

193

110
1.8
!12
0.85;
5.9

I
I
1

Ii

167
3.3

45
80
28
332

Elastomer

7 hrs

1 wk

I-

(Volume

Change, %)

250F(1210C)

212F(1000C)

1wk

24 hrs

Acrylic

2wks

70

--

lwk

I
1

I
I
I
I
f
I

I
I

1
f
;7 to 14

27

I
I

I 8.0
21.9
)o to -5.1

I
I
1
I

26
10
12
1

I
1.2
1.2

I
I

1.5
1.7

I
Oi

I
I

2.3
2.0
0.5

1
; 2:;
1 3.0

I
I

All values in this tab le i Ire (+) unless ot

-1.5

13.0
8.6
6.7

28

75

3.0
2.0

Rubbers

TABLE

2.2:

FLUOROELASTOMER-ELKHART

and Elastomers

285

RUBBER

In many applications,
AFLAS
outperforms
other elastomers
because of the following
characteristics:
(1) High temperature
resistance
(400F long term; 55O+F shorter term);
(2) Resistance to a wide range of chemicals
(including
acids, bases, steam, sour (H2S) oil and gas with amine corrosion
inhibitors,
oils and lubricants,
hydraulic
fluids of
all types,
brake fluids,
bleaches,
oxidizing
agents, alcohol,
etc.); (3) Durable
physical
properties;
(4) Excellent
electrical
resistance-Dielectric
constant
at 60 Hz of 2.5.
There are three grades of AFLAS.
All provide
essentially
the same heat and chemical
resistance but they differ
in
molecular
weight (which can affect processing and physical properties).
AFLAS
150E is the lowest molecularweight,
AFLAS
150P is intermediate
weight,
and AFLAS
IOOH is the highest molecular
weight.
AFLAS
100H is generally
recommended
for optimal
extrusion,
gas blistering,
and compression
set resistance.
The following
chart provides
an indication
of the chemical resistance of AFLAS.
Since temperature,
concentrations,
mixtures,
and elastomer
compound
selection
can affect
performance,
this chart provides
guidelines
only. Unless
otherwise
noted, the tests were run on a 75 Shore A carbon black filled AFLAS
150P formulation
with the following properties:
Orlglnal Pro~wtl*r of le.1 Formulation
Shon A Hardness

Tensile Strength (pal)

Elongation @ Break

2500

120%

75

Where available,
the chart shows the change in hardness (in Shore A points) and volume as well as the percentage
of
original
tensile strength
and elongation
retained
after immersion
in the test fluid under the time and temperature
conditions denoted. In other instances, volume change only is shown.
MEDIA

RESISTANCE

OUIDELINES
Amlnes .................................................
G to E
011s and Lubricants (Incl. synthetics.
SF CD, etc.) .................................. G to E
OXidlZlnQAQenlS ................................. G to E
Sour (H2S) 011 and Gas with
Conoslon lnhlbltors .................... G to E
Benzene, Xylene, etc. .......................... F to G
Fuels ..................................................... F to G
Ketones ........................................................ F
Chloroform ................................................... P

E
Animal and VeQetable Oils ......................... E
Bases ............................................................ E
Brake Fluids ................................................. E
Hydraulic Flulds (lncl. phosphate
esters, Mil-H-5806, water/Qlycol, etc.) ........ E
BteamrWaterlBrine ...................................... E
Radiation ...................................................... E
WeatherlnQ/Ozone ....................................... E
Alcohol ................................................. G to E
Adds

.............................................................

E. Excellent

Property
Retention
After Test

Test
Condition

CHEMICAL

G. Good

F - Falr

P - Poor

CHEMICAL

Property Retention
After Test

Test
Condition
rime
lays

AcetIc Acid
Acetrc acrd/lO%
Sodium chlonte
Acetone
Acetyl acetone
Aeroshell Grease 67
Amrne Corroston
lnhrbrtors (see Oilfield Media)
Ammonia (28%)
Ammonium
(28%)

Aniline
ASTM Oil I1

73

1.0

ASTM Oil 13

212
73
73
176

!4.0

7
3
2

io.0

Benzene
Benzene/Methanol

i4.0

8.0

Bl~;;~nq,

30/X
501%
powder 10%

Bromine
158
73

3.2
1 .o

hydroxide
;:
158
73
212
350

7
180
3
7
Z

1.0
2.5
3.2
.7
1.8
4.1

Bromine 32%/
Hydrochlonc acid
1B%/Sulfunc acrd
25 %
Calcium hypochlorite
10 %
Caproic acid
Carbon tetrachloride
Castro1 325

7.9
i3.0

212
350
73

3
3
7

3:

212
73

7
7

212

6.0

212
73
73
176

7
7
7
2

0
6.8
16.0
6.0

Il.0
12.0
!l.O
89
36

0.0
6.2

(continued)

286

Corrosion

TABLE 2.2:

Resistant

Materials

Handbook

FLUOROELASTOMER-ELKHART

RUBBER (continued)

--

Test
Condition

CHEMICAL

Chlorine solution
(saturated)
Chlorine solution (Sat.),
35% Sodium chlonde
10% Sodium
hypochlonte
Chloroform
Chromrc acid (62%)
Chromic acid (46%)/
Sulfurtc acid (25%)
Cyclohexane
Cyclohexanone
Diesel Fuel #2
95 Shore A Compcurw
Diethyl ether
D~octyl Cebacate
Dloxane
Dowtherm 209
Ethyl acetate
Ethyl benzene
Ethyl benzoate
Ethylene Chlorohydrrn
Ethylene glycolMlater/
Nalcool 2000 50/5C
4 oz. per gallon
Exxon Caloria HT43
Freon TF
Fuel B
Gasoline
Hydrochloric acid (37%

Hydrochloric
Hydrofluoric

acid (20%
acid (50%

Hydrogen peroxide (30%


lsoamyl alcohol
Iso-Octane
Kerosene
KFlHF (111.8)
Lacquer thinner
Light oil
Lithium Bromrde (58%)
Lithium chromate
Methyl alcohol
Methyl cellosolve
Methyl chloroform
Methyl ether ketone
Mil-H-5606
Mil-L-7808
Mobil 1 5W-30
Mobil Super lOW-40
n .hexane
Naphtha
Nitiic acid fuming
Nitric acrd (98%)
Nitric acid (60%)

Property
Retentron
After Test

Test
Condition

CHEMICAL

Property
Retention
After Test

Nitric acid (20%)

212
73
73

2.5
7
7

69

78

-9

90

98

-2

73
73
73
212
302
73
212
350
73
212
73
73
73
73

7
7
7

15

117

-1

;
1
3
3
3
3
7
7
7
7

75
70

103
121

-18
-5

5.9
12.0
1.7
2.6
13.0
22.0
9.0
29.2
42.0
8.8
20.0
57 0
6.3
88.0
22.0
26.7
0.0

Nitrobenzene
OILFIELD MEDIA
Amine corrosion inhibitors (mtnerallblack
filled compound)
1 % KW44 in water
10% KW44 in water
1% NACE A In water
Sour gas, wet (35% H2S.
50% CH,, 15% COz.
10 ml Hd))
Sour oil. wet with 5%
NICE B corrosion
Inhibitor
(47.5% ASTM %l oil.
47.5% HzQ, 5% NACE
6: Mixed gas 35% HzS
15% COz. 50% CHI
under pressure)
Skydrol 500
Skydrol 5008
Skydrol 500 84

73
I 7I I I I 5fi

NOTE Afhs rerrared

etastcmenc and dzl not

-1

150
144
194

-4
-4

;.i

66

86

-3

3.0

350

40

111

-15

8.6

176
212
176

2
3
2

9c

212
212
324

14

400

77

14.6
14.0
17.2

100 HI 15OP blend comoound

324
500
73
73
73
73
158
158
3:
212
73
73
73
185
73
73
320
392
73
73
73
73
212
212
400
400
73
73
73
73
73
5:
158

14
4

106
50

I
7
7
7

SOIVC

180
3
3
7
180
7
7
7
7
3
7
7
11
11
7
7
7
7
3
3
3
3
7
7
7
I80
30
7
I80
3

100

106
+;
164
-E
\flas 15OP

107

-1

57
58
63

112
85
117

-2
-6
+1

105

99

94

106
99

111

106
1lC

82
84

111
107

42

126

94

95

44

107

03

+1
+1

-6
-6

1.1
11.0
58.0
25.0
.2
4.5
7.0
7.4
1.5
4.1
-1.1
0.0
19.0
2.0
.4
53.3
5.0
-0.3
-0.3
0.2
1.4
25.0
58.0
12.0
6.0
8.4
10.1
24.0
4.0
19.0
15.0
21.0
0.0
5.1
IO.0

Sodium chloride (35%)/


Sodium hypochlorite
(10%) Saturated
chlonne solution
Sodium chlorite (10%)
Sodium hydroxrde 50%

212
212
2:;

Sodium

hydroxide

20%
2::

Sodium hypochlorite
(10 % )
Sour (HzS) gas and oil
(See Oilfield Media)
Stauffer 7700
Steam (93 Shore A cmpd)

Sulfur dioxide (5%)


Sulfuric acid fuming
Sulfunc

acrd (96%)

Sulfunc

acid (60%)

Sulfunc

acrd (20%)

rho

-9
-12
+2
-1
1;

5.9
22.0
1.2
1.1
-0.3
2.0

too

95

-1

1.0

350
320
392
392
550
104
73
73
73

3
7

80
91

-10
-3

;z
65
69
76

120
84
97
100
145
84
98

98

99

-3

99

-3
-1

:;
02
99

101
98
104
105
98

87
89

120
117

18.0
4.6
16
1.3
1.6
78
4.2
7.4
0.4
2.3
4.4
0.1
0.4
0.5
04
41.0
95.0
49.0
9.0
1 1
30 0

;:
4

2
7
180
7
I80
3

2:;

2::
73
73
73
300
212
73

;
7
7
7
3
3
7

/nfot?muo/l was
technical literature.

above

publlshbd

78
93
116
116
104
117

212

2:;

Toluene
Tnchloroethylene
Tnchlorotrlfluoroethane
Wagner 218 brake fluid
Water
Xylene

69
80
108
101
85
95

obtained

from

::
-1
.4
-2

fl
1;

-8
0

TABLE 2.3:
FL,D

FLUOROSILICONE

RESISTANCE

OF SILASTIC

RUBBERS-DOW

LS-S3U FLUOROSILICONE

lmmersron
Condrtrons

Nu,ds
ASTM

Reference

Fuel B

ASTM

Reference

Fuel C

10% Methanol/SO%
10% Ethanol,90%

_.

No-Lead
No-Lead

1
1
4
1
1
4
1
1
1
1
1

Gas
Gas..

_. ._....
....................
......................

ASTM NO 1 Oil
ASTM No 3 Oil
Jet Fuel. JP-l
Jet Fuel, JP-6 _.

_.

day/23 C (73 F)
we&f23 C (73 F,
weeks/23 C (73 F,
day123 C (73 F,
week/23 C (73 F)
weeks123 C (73 F,
day/&flux
day123 C (73 F,
week/23 C (73 F,
day123 C (73 F,
week/23 C (73 F,

70 hrdl50
C (302 F)
70 hrs/lSO C (302 F)
70 hrs123 C (73 FI
1 day123 C (;3 F;
1 week123 C (73 F,
70 hrs1135 C (275 F,
70 hrs/150 C (302 F)

_.

MIL-H-5606 (PO4226).
MIL-L-7806F (Brayco 660 G,
DI-P-ethylhexyl
sebacate
with 0.5% phenothwlne
Skydrolt
5OOA..
_, _. _.

46 hrs/l50 C (302 F)
70 hrs1121 C (250 F)

CORNING
FLUID RESISTANCE

RUBBER

Durometer.
Pants
Change
-9
-9
-6
-10

-11
-6
-11
-12
-13
-11
-11
4
-6
-5
-7
-7
-7
-14

TenSlIe
srrengm
Percent
Change

0
-30
-35
-9
-7
-13
-33
-70

-26

-90

-3
-5
-

+22
l22
+22
+25
+25
l25
+29
+26
+25
+23
+22
0
+4
+12
+6
+7
+tO
+13

+6

-36
-36
-36
-36
36
-36
-44
-49
-36
-31
-33
-

42
-37
-39
-43
-36
36
-42
57
-57
-IQ
46

-7

tWlJIe
s we//,
PerCef
Change

Elongation,
PWCet
Change

OF SILASTIC

LS-70 FLUOROSILICONE

RUBBER

Volume

TeSh?

ImmerS!on
Cond!trons

Flwds
ASTM Reference

Fuel B

ASTM Reference

Fuel C

10% Methanol/SO%
1wb Ethanol/SO%

No-Lead
No-Lead

Jet Fuel. JP-6

Gas
Gas..

_.

_.

Duromefer.
POllS
Change

Strength.
Percent
Change

Elongarion.
PerCent
Change

SbVe11.
Parren,

_ __

Change

1
1
4
1
1

day1123 C 173 F,
week/23 C (73 F)
weeks/23 C (73 F)
day/23 C (73 F,
week123 C 173 F)

-12
-12
-10
-10
-13

-12
-13
-16
-16
-16

-10
-10
-14
-14
-14

+17
+17
lla
117
-30

4
1
1
1
1
1
1
1

weeks123 C(73 i)
day/Reflux
day/23 C (73 F,
week/23 C (73 FJ
day123 C (73 F,
week/23 C (73 F,
day123 C (73 F,
week123 C (73 F,

-15
-10
-19
-17
-16
-15
-5
-4

-20
-29
-42
-41
-37
-35
-4
-2

-19
-33
-33
-19
-19
-14
-0
110

+20
+27
+22
+21
+16
+17
+3
+5

I=

Obtained by add,9 1 0 phr arox to SILASTIC LS-70 l~~r~~~l~c~ne rubber Slabs 0 075 mch truck were press cured 10 m,~?,,
(340 F, and post cured 4 hrsQc0 C ,392 F) prmr to testmg

+2a

1.O

*Obtam& by addIn
phr Varox to SfLASTlC LS-53 fluorosillcone rubber Slabs 0 075 inch tluck were press cured
10 mm,,71 C (340 F) and post cured 4 hrs/2@3 C (392 FJ war to testw
+Skydro, IS B rqstered trademark 01 Monsanto lndustrlal Chemu.1 Company
FLUlD
FLUID RESISTANCE

OF SILASTIC

LS-SSU FLUORDSILICONE

lmmersron
Conddrons

Fluids
ASTM Reference

Fuel B

ASTM

Fuel C

Reference

10% Methanol/90%
10% Ethanol/90%

No-Lead
ND-Lead

ASTM NO. 1 Oil


ASTM NO 3 Oil .,_.,
Jet Fuel, JP4
Jet Fuel. JP-6 _.

_.

1
1
4
1
1
4
1
1
1

Gas
Gas..

_._.

,_. _.
_, _. _. _.
_.

MIL-H-5606 (PO4226).
MIL-L-7606G (Stauffer
Skydrolt 500A..

Jet 1,.

_.

_.
_.
_.

day/23 C (73 F,
week123 C (73 F,
weeks123 C (73 F,
day/23 C (73 F,
week/23 C (73 F,
weeks123 C (73 F,
day/Reflux
day/23 C (73 F)
week/23 C 173 F,

1 day/23 C (73 F)
1 week/23 C (73 F)
70 hrs/150 C (302 F)
70 hrs/l50 C (302 F)
70 h&23 C (73 F,
1 day123 C (73 F)
1 week/23 C (73 F,
70 h&135 C (275 F,
70 hrsIl50 C (302 F,
70 hrs/70 C (1% F,

RESISTANCE

OF SILASTIC

LS-2249U

FLUOROSILICONE

RUBBER

RUBBER

Duromefer,
PO!tS
Change
-14
-13
-14
-16
-16
-13
-14
-19
-19
-16
-16
+1
-4
-6
-9
-9
-7
-10
-15

TenslIe
Sfrengfh.
PerCef
Change
-17
-21
-17
-23
-27
-20
-23
-47
49
-37
-37
-3
-27
-25
-6
-13
+5
-25
-22

*Dbta,ned by .,,.,in~ , 0 p,,, ,,ror (0 SILASTIC LS-SW ,,orosll,coe


rubber Slabs 0 075 I&
(340 F) ,nd port cured 4 hn/2OO C (392 F) prior to test!9
+Skydrol II a rq,s,ered trademark 01 Monsanto ldstrlal Chem,cals Compr~

Elogeflon,
PWCL?f
Change
-10
-13
-13
-16
-19
-16
-33
-35
-26
-19
-16
-10
-13
-20
a
d
-10
-25
-7

thick IOre press curti

VOlUl.9
SW/l,
Percent
Change
+16
+20
+20
+22
+22
+22
+27
+2.3
+26
+22
+21
l1
+4
+10
+4
+5
+7
+10
+16
10 ml/171 C

,lmerS,O
Condrfrons

Flurds
ASTM

ASTM

Reference

Reference

10% Methanol/W%
10% Ethanol/SO%
ASTM NO 1 Oil
ASTM No 3 011
Jet Fuel, JP-4
Jet Fuel. JP-6

Fuel B

Fuel C

No-Lead
No-Lead

Gas
Gas..

_.
_.

MIL-H-5=
(Unwist J-43)
MIL-L-7606 (Turbo 011 NO 15)
DI-?-ethylhexyl
sebacate
wth 0.5% phenoth,az,e

_.

Duromefer.
POllS
Change

TenSlIe
Strength.
Percent
Change

Elongarron.
Percent
Change

Volume
SbWll.
Percent
Change
4-Z
.e

1 day123 C (73 F1
1 v&k/23
d (73 k)
4 weeks123 C (73 F,
1 day/23 C (73 F)
1 week/23 C (73 F,
4 weeks123 C (73 F,
1 day/Reflux
1 day/23 C (73 F,
1 week/23 C (73 F,
1 day123 C (73 F)
1 week123 C (73 F,
70 h&l50
C (302 F)
70 hrs/lbO C (302 F,
70 hrs/23 C (73 F,
1 day123 C (73 F,
1 week/23 C (73 F,
70 ha1135 C (275 F)
70 hrz.1177 C (350 F)

-17
-15
-16
-16
-16
-15
-16
-23
-20
-16
-17
-1
-62
-10
-6
-9
-6
-19

-29
-29
-29
-33
-40
-37
-53
-63
-54
-54
-45
-0
-26
-9
-6
-6
-11
-60

-19
-19
-19
-20
-20
-20
-41
-37
-24
-30
-20
-2
-22
-0
-0
-7
-11
-22

+t4
+15
+17
+16
+15
20
+26
20
+19
+14
+0
+3
+6
+3
+4
9
+12

46 hrs/l50

-12

-14

-16

b
w
a
m
$
h
s
8
3
3

C (302 F)

Ob,a,ned by add,9 1 0 phr arox to SILASTIC LS-2249 luoros~lwzonerubber Slabs0075 &ch thuck were presscured 10 ma/171 C
(340 F, and post cured 4 hrsQc0 c (392 F) pnor to test!9
+Unws IS B reg,stered trademark of Humble 011and R&m9 Company

(continued)

h>

TABLE 2.3:

FLUOROSILICONE

FLUID RESISTANCE

OF SILASTIC

LS-2311U

RUBBERS-DOW
FLUOROSILICONE

Duromerer,
FluIds
ASTM Reference Fuel B

ASTM Reference Fuel C

10% Methanol/W%

_.

No-Lead Gas

10% Ethanol/SO% No-Lead Gas..

_.
_._.
......................

ASTM NO. 1 011


ASTM NO 3 011
Jet Fuel. JP4
Jet Fuel. JP-6 ......................

_.

MIL-H-5606 (Un,v,s+ J43)


MIL-H-7606 (Turbo Oil No. 15)
DI-P-ethylhexyl SebaCBte
wth 0.5% phenothoazlne
Skydrol SOOA

_.

CORNING

(continued)
FLUID RESISTANCE

RUBBER
TenslIe
svengm
Percent
Change

Elongation.
PBICBf
Change

Volume
SWII,
Percent
Change

Immersmn
Codr,roS

POllS
Change

1 day123 C (73 Fl
1 we&23
d (73 F)
4 weeku23 C (73 F)
1 day123 C (73 F)
1 week/23 C (73 F)
4 weekJ/23 C (73 F)
1 day/Reflux
1 d&23
C (73 F)
1 weeW23 C (73 F)
1 day123 C (73 F)
1 we&V23 C (73 F)
70 h&l50
C (302 F)
70 hrdl50 C (302 F)
70 h&23 C (73 F)
1 dav123 C 173 F)
1 we&/23 d (73 F)
70 hn/l37 C (275 F)
70 hrs/l77 C (350 F)

-12
-11
-9
-12
-13
-10
-15
-15
-17
-12
-13
-2
-2
-10
-4
-7
-5
-6

-14
-14
-16
-15
-17
-15
-15
-40
-45
-31
-29
+2
+5
-10
-10
-13
+10
-9

-7
-14
-21
-7
-0
-14
-7
-29
-29
-0
-0
-6
-17
-17
+7
+7
-17
-17

+14
l14
114
+17
+17
+17
+20
20
+20
+16
+17
+1
+3
+7
+2
+3
+7
+7

46 hrsl50
70 hrsIl21

-5
-39

+4
-74

-6
-17

+6
17

C (302 F)
C (250 F)

Obtmmd by add,9 1 0 ph, arox 10 SILASTIC LS-2311 ,,~r~s~l~c~e rubber Slabs 0 075 mch thick were press cured
10 rnIl171 C (340 F) and post CURCI4 hW?w c (392 F) pnclr to teStIn
+Unw~r I) a repwwd trademark ot Humble 011and Refmmg Company
Skydrol 1sa rsp~rteredtrademark 01 Monsanto lndusinal Chemicals Company
FLUID RESISTANCE

OF SILASTIC

LS-2323 FLUOROSILICONE

lmmersron
Cond!tions

Fluids

_.

ASTM Reference Fuel B

ASTM Reference Fuel C

10% Methanol/SO% No-Lead Gas


10% Ethanol/QO% No-Lead Gas..

_.
_,_.

_. _.
_.

ASTM NO 1 011
ASTM NO 3 011
Jet Fuel, JP-4 _........_...._.._....
Jet Fuel. JP-6
_.

MIL-H-5606 (Univist J-43)


_MIL-H-7606 (Turbo 011 No. 15)
Dt-P-ethylhexyl sebacate
wth 0.5% phenothlazme
Skydrol 5WA..
._

..

_.

1day123

C (73 F)
1 week123 C (73 F)
4 weeks123 C (73 F)
1 day/23 C (73 F)
1 week/23 C (73 F)
4 weeks/23 C (73 F)
1 daylReflux
1 day/23 C (73 F)
1 week/23 C (73 F)
1 day/23 C (73 F)
1 week/23 C (73 F)
70 h&l50
C (302 F)
70 hrsllS0 C (302 F)
70 hrs123 C (73 F)
1 day/23 C (73 F)
1 week/23 C (73 F)
70 hrs/135 C (275 F)
70 hrs1177 C (350 F)

TeSlle
Strength.
Percenl
Chanoe
-14
-14
-16
-15
-17
-15
-15
-40
-45
-31
-29
+2
+5
-10
-10
-13
+10
-9

ElOWfl0.
percent
Chanoe
-7
-14
-21
-7

Volume
Swell.
Percent
Change
+14
+14
+14
117
+17
+17
+20
+20
20
+I6
+17
+I
+3
+7
+2
+3
+7
+7

Fluds
ASTM Reference Fuel B

ASTM Reletence

Fuel C

10% Methanol/QO% No-Lead Gas


10% Ethanol/W%

No-Lead

Gas

ASTMNo
1011
ASTM No 3 011
Jet Fuel. JP-t
Jet Fuel. JP-6

_.

._
_._. _.

_.

MIL-H-5606 (Unwist J-43)


MIL-L-7606 (Turbo 011 NO 15)
CV-2-ethylhexyl sebacate
wth 0.5% phenothiazme

C (302 F)
C (250 F)

+6
+7

FLUOROSILICONE

_.

RUBBER

Duromerer.
Pomts
Change

TeS,le
Svenglh
PerCef
Change

Elongarro.
percent
Change

Volume
SbVe,,
P.YCet
Change

1 day23 C (73 F)
1 week123 C (73 F)
4 weeks/23 C (73 F)
1 day123 C (73 F)
1 week23 C (73 F)
4 weeks/23 C (73 F)
1 day:Reflux
1 day/23 C (73 F)
1 weeW23 C (73 F)
1 day/23 C (73 F)
1 week/23 C (73 F)
70hrs/l50C(302F)
70 h&l50
C 1302 F1
70 h&23 C (73 F)
1 day/23 C (73 F)
1 week/23 C (73 F)
70 h&57 C (135 F)
70 hrsI150 C (302 F)

-19
-19
-16
-21
-20
-20
-22
-23
-26
-21
-21
-0
a
-6
-6
-11
4
-12

-3
-2
-1
-3
4
-4
-33
-27
-29
-10
-10
_

-2
-2
-6
-2
d
-2
-22
-11
-3
-2
-5
_
-

-0
-2
-

l5
+3
_

110
3
l4
+a
+6

46 h&150

-1

+Q

C (302 F)

+17
+17
+17
+19
+16
16
+25
+21
+20
+17
+16
+0
+4

Obtafned by addq t 0 phr a,.. to SILASTIC LS-2332 l~r~~~i~c~nerubber Slabs 0 075 mch thxk were press cured
IO mm/l71 C ,340 F) and post cured 4 hrsr200 C (392 F) prior to tesl,nQ
+nws IS a regfrtered traclemark01 Humble 011and R&lQ Company

OF SILASTIC

Flurds
ASTM Reference Fuel B

ASTM Reference Fuel C

10% Melhaol/QO%
10% Ethanol/O%

No-Lead Gas
No-Lead Gas..

ASTM NO 1 011
ASTM NO 3 011
Jet Fuel, JP4
Jet Fuel, JP-9 _.

_. _.

_.

_.

_.

MIL--5606
(P04226)
MIL-L-7606G (Stauffer Jet 1).
MIL-L-23699 (Mobil Jet II)
ATF-Dextron (AMOCO).
Crude Oil API 315
* Otame*

LS-23SOU FLUOROSILICONE

,mrerSiO
Condlbons

_.

46 hrsfl50
70 h&l21

LS-2332U

lmmersmn
Cod,hos

FLUID RESISTANCE

BASE

Duromeler.
Points
Chanoe

OF SILASTIC

RUBBER

Duometer.
POifS
Chanoe

1 day123 C (73 F)
1 week123 C (73 F)
4 weeks123 C (73 F)
1 day123 C (73 F)
1 week/23 C (73 F)
4 weeks/23 C (73 F)
1 day/Reflux
1 day/23 C (73 F)
1 week123 C (73 F)
1 day123 C (73 F)
1 week/23 C (73 F)
70 hrs/l50 C (302 F)
70 hrs/l50 C (302 F)
70 hrs/23 C (73 F)
1 day/23 C (73 F)
1 week/23 C (73 F)
70 h&150 C (302 F)
70 hrs/l50 C (302 F)
70 hrs/150 C (302 F)
70 h&150 C (302 F)
70 hrsi135 C (275 F)

-11
-10
-9
-11
-11
-10
-12
-14
-15
-11
-10
+1
-1
-7
-6
-6
-7
-6
-9
+1
4

TeS!le
SWenglh.
percent
Chanoe
-16
-16
-14
-23
-22
-16
-26
46
-59
-37
-37
-1
-16
-14
+2
+1
-16
-29
-39
4
-26

Elongation,
percent
Chanoe
-16
-16
-24
-24
-16
-24
-29
-41
41
-16
-16
+I6
-13
-9
-6
-0
-17
-25
-29
-21
-29

Volume
.%e/i.
Percent
C.k3noe
+15
+15
+14
+17
rlR
+17
+21
+21
+19
+12
+15
+I
+4
l7
+3
I?
+I3
+a
9
+I
+6

_.
10phrarortoSlLASTlC
LS-2380
flOrO*lllCOe
rubber
Slabs
0075-4ch-thlck
wsre
press
Cured

by a&j,np
F) and post cured 4 hrs 200 C (392 F) prior to test,9

10m,nilllC(2~0

(continued)

3
a
3

2
_.
x
s

5
s
G
>
x
3
g
8
h

TABLE 2.3:

FLUOROSlLiCONE

FL,DRESISTANCE

OF SILASTIC

RUBBERS-DOW

Ls-2640 FLUOROSILICONE

CORNING

(continued)
RESISTANCE

RUBBER

OF SILASTIC

*125lJ

SILICONE RUBBER

TO IMMERSION

IN SOLVENTS

Tensde

Change

Ekmgabon,
P6XY?nf
Change

-13
-13
-13
-13
-19
-14
-14
-13
-12
+1
0
-6
-5
-13
-19

-40
-40
-43
-42
-57
-53
-50
-42
-36
-7
-27
-20
-16
-64
-55

-27
-23
-26
-27
-39
-29
-27
-21
-17
- 13
-22
-6
-11
-62
-23

POlfll

-Floids
ASTM Reference Fuel B
ASTM Relerence Fuel C

10% MethanolM%
10% E!hanol90%

No-Lead Gas
No-Lead Gas

....................
..................
...................
.............
......
....................

ASTM No. 1 oil


ASTM NO. 3 011
Fuel. JP-4
MIL-H-5606 (PO-4226).
ML-L-76M)G (Slaulfer Jet 1).
Skydrol* 500A.

Jet

1 day23 C 173 F)
, weeW23 C (73 FI
1 day/23 C (73 F)
1 weeW23 C (73 F)
1 day:Reflux
1 day/23 C (73 F)
1 week/23 C (73 F)
1 day/23 C (73 F)
1 week/23 C (73 F)
70 hrs/l50 C (302 F)
70 hrsl50 C (302 F)
70 hrsi23 C (73 F)
70 hrsil50 C (302 F)
70 hrsIl5C C (302 F)
70 h&i70 C (156 F)

FOODS

Prop&lest

Strength,
Percent
Change

Durometer,

AND LIQUID

SWdl,
PWX?lll

m
+16
+ 16
+20
+21
+26
+19
+22
+16
+17
+1
+3
+11
+9
+6
+23

Immersmn
Llqwd

Test
Condrtions

Water
Detergent. 3% m water.

Steari ___....._....,..__.,_....
coffee

.................
.........................
.......................
.....................

Vegetable 011..
Lard.
Whiskey
Cola Syrup
Vinegar ........................

Durorneter
Hardness,
Shore A-2,
pornts change

TBnSlle
Strength.
percent
change

Elongation,
percent
change

Volume.
percent
change

14 days/l00 C (212 F)
14 days/62 C (160 F)
3 days/20psi
7 dew/62 C il60 FI

+3
t2
+5
+3

+a
+2
-4
I-III

+7
-9
-9
-2

l1
-1
nil
+2

7 da&l50
7 days/150
14 days/23
14 days/23
7 days123

+2
+2
-2
-1
-1

-24
-29
+6
-10
-3

-35
-41
+10
-6
-2

+1
+1
+1
nil
nil

C(302 ;)
C (302 F)
C (73 F)
C (73 F)
C (73 F)

10w.Rs
Cadox
TSSO
per1Wharts
rubber
bwm,h,.
wess

~cm-rens lcanued wth


molded onto0.075-m-,h,ck
ASTM slabs (1 Slmm) tar 5 mmuter/llS C (240 F), and oven cured for 4 houroi200 k (392 F)
torlgmal !&WI duromster hardness - 54 pomts. twslle rtrsngti- - 1200 p.c,slongatlo - 580 percant

290

Corrosion Resistant Materials Handbook

TABLE

2.4:

POLYSULFIDE

RUBBER-MORTON

THIOKOL

ST polysulfide
rubber is a millable gum elastomer prepared from bis (2chloroethyl)
formal and
sodium polysulfide.
Vulcanizates
exhibit outstanding
resistance to a broac spectrum of oils and
solvents, to gas permeability,
low temperature,
ozone and weathering.
Typical uses include gas
meter diaphragms, rollers, printing blankets, o-rings, and many specialty molded items.

All of the solvent Immersion

tests were run with the following

Ingredients
ST polysulfide
Stearic acid

recipe:

Parts by weight
rubber

100
1

Sterling S
Zinc peroxide
Calcium hydroxide

60
5
1
167

Cure 30 minutes at 310F

SOLVENT

RESISTANCE

AT ELEVATED

Volume
1 week

Solvent
Xylene
Iso-octane
Butyl acetate
Methyl isobutyl ketone
Water

RESISTANCE

Tensile, psi
Elongation, 96

TO WATER

45
6
46
37
21

140F

Swell, %
1 month
58
6
46
67
41

(DISTILLED

AND

SALT)

Original
Properties

Distilled Water

4% NaCl Water

Distilled Water

4% NaCl Water

1090

1065

1100

665

1050

215

215

215

150

215

73

71

72

67

70

12

Hardness, Shore A
Volume Swell, %

TEMPERATURE,

Immersed 14 days at 80F

Immersed 14 days at 158F

(continued)

Rubbers

TABLE 2.4:

POLYSULFIDE

RUBBER-MORTON

THIOKOL

and Elastomers

291

(continued)

SOLVENT RESISTANCE
(30-Day Immersion at 80F - ASTM-D471-66, Method B)
SOLVENT

VOLUME
INCREASE,

CONDITION

Aliphatic and
Aromatic Hydrocarbons
Mineral oil
Benzene
Toluene
Xylene

-2
110
70
41

OK
Tender
Swollen but OK
OK

Halogenated Hydrocarbons
Carbon tetrachloride
Ethylene dichloride
Trichloroethylene
Perchlorethylene
Dowtherm A
Monochlorobenzene

46
230
159
28
127
161

OK
Very tender
Tender
OK
Tender
Tender

Aliphatic and
Aromatic Fuels,
Oils and Solvents
SR-6 (60% diisobutylene,
40% aromatics)
SR-10 (diisobutylene)
ASTM Reference Fuel Afa)
ASTM Reference Fuel Bfb
73 octane gasoline
100 octane gasoline
ASTM oil No. 1
ASTM oil No. 3
Turpentine
Motor oil (Esso)
Circa light process oil
Diesel oil
Circosol 2XH
Paint thinner (Duco)
Drip oil
Gulf motor oil
Pydraul F-9
Skydrol
Sovaloid C
Sovaloid N
Sundex 53
Tetrahydrofuran
JP-3
JP-4
Houghto-Safe No. 271

14
1
2
10
3
2
-4
-2
4
0
-2
3
-2
23
62
-3
37
24
30
2
-1
175
-2
1
2

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
Slightly tender
OK
OK
OK
OK
OK
OK
Very tender
OK
OK
OK

Organic Acids
10% acetic acid
50% acetic acid
Glacial acetic acid
Cresylic acid

9
26
18
123

OK
OK
OK
Tender

37
35
24

OK
OK
OK

Ketones
Acetone
Methyl ethyl ketone
Methyl isobutyl ketone
la7 Reference Fuel A has the same composition
fbl Reference

Fuel 8 has the same composibon

SOLVENT

VOLUME
INCREASE,

CONDITION
%

Esters
Ethyl.acetate
Butyl acetate
Tributoxy ethyl phosphate
Dibutyl phthalate
Plasticizer SC
TP-SOB Plasticizer
TP-95@ Plasticizer
Dibutyl sebacate
Dioctyl phthalate
Flexol 3 G 0
Tricresyl phosphate
Adipol BCA

35
30
4
10
6
12
28
2
-2
1
7
20

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

Ethers
Cellosolve Solvent
Bun/l Cellosolve
Dibenzyl ether
Butyl Carbitol

14
11
30
13

OK
OK
Very tender
OK

Vegetable and Wood Oils


Linseed oil
Cottonseed oil
Castor oil
Corn oil
White pine oil
Crude soya bean oil

-2
-2
-3
-4
14
4

OK
OK
OK
OK
OK
OK

Hydroxy Compounds
Ethyl alcohol (denatured)
Butyl alcohol
Isopropyl alcohol
Diacetone alcohol
Prestone
Methyl alcohol
Ethylene glycol
Gasohol
Glycerine
P-ethyl hexanol

2
2
0
18
3
6
0
5
1
1

OK
OK
OK
OK
OK
OK
OK
OK
OK
OK

Inorganic Compounds
10% Sulfuric acid
20% Sulfuric acid
50% Sulfuric acid
100% Sulfuric acid
10% Nitric acid
50% Nitric acid
10% Hydrochloric acid
50% Hydrochloric acid
100% Hydrochloric acid
10% Sodium hydroxide
20% Sodium hydroxide
3% Sodium chluide sdution
10% Sodium chloride
10% Copper sulfate
10% Zinc chloride
Water

2
-2
3
3
_
2
2
3
3
5
2
5

OK
Slightly soft
Deteriorated 2 wks
Deteriorated 1 day
Deteriorated 2 wks
Deteriorated 1 day
OK
Tender
Deteriorated 1 day
OK
OK
OK
OK
OK
OK
OK
-

as Type I te?sffluid in Mil-H-3136


119501, i.e., fuel is 100% iso-octane.
as Type III msf fluid in MY-H-3136
11950). i.e.. fuel is 70% iso-octane, 30% toluene (by volume/.

(continued)

292

Corrosion Resistant Materials Handbook

TABLE 2.4:

POLYSULFIDE

RUBBER-MORTON

THIOKOL

(continued)

EFFECTOFHALOGENATEDHYDROCARBONS
VS
OriginalPhysical

Properties

Dichloromethane
1 week
1 month

1100

950

240

70

285
260

1180

930

240

72

1200

910

290

71

328

1110
1100

820
620

270
320

84
63

VS

307

1.1.2.2.Tetrachloroethane
1 week
1 month

950

240

70

153
156

1210
1290

920
960

270
290

69
70

1 week

34

1180

920

250

68

1 month

32

1085

850

250

68

25
26

990
1040

820
1000

230
230

67
68

306
-

800
840

570
360

300
400

53
54

1 week
1 month

Decomposed

1.2.3.Trichloropropane
318

1160
1200

810
850

280
280

68
65

1020
1000

950
740

220
250

64
64

240

1100
1140

800
810

250
260

67
65

285

410

120

67

1 week

135

300

295

730

200

69

1 month

146

600

340
N.A.

1030
1010

800
750

260
280

64
61

32
32

1050
1110

900
1000

320

1 week
1 month
Chlorobenzene

54
54

1 week

159

1200

1000

250

70

1 month

164

1150

950

280

67

1 week

159

1100

880

250

67

1 month

166

950

750

250

58

160

48

180

50

250
235

70
70

1.2.Dichlorobenzene
235

1,1,2-Trichloroethane
1 week
1 month

1100

2-Chloropropane
Decomposed

1.2.Dichloroethane
1 week
1 month

Proparties

1 week
1 month

Tetrachloromethane
1 week
1 month

Tetrachloroethylene

1 month

1 month

Trichloroethylene

Diiodomethane
1 week

Trichloromethane
1 week

OriginalPhysical

Dibromomethane
1 week
1 month

1.2.4.Trichlorobenzene

1-Chlorobutane

Pentachloroethane
1 week
1 month

1 week
1 month

Decomposed
Decomposed

VS-

volume swell

T-

tensile strength, psi

E- Elongation, %

H-

Hardness, Shore A

M- 200% modulus, PSI


N.A.- not available

RESISTANCE TO KEROSENE AND BUNKER C FUEL OIL


Original
Properties

Immersed 1 weak at 80F


Kerosene
Bunker C

Immersed 1 weak at 158F


Kerosene
Bunker C

100% Modulus, psi

420

420

420

260

410

200% Modulus, psi

890

860

880

590

870

1200

1140

1180

790

1120

280

270

270

260

260

72

71

69

67

69

Tensile, psi
Elongation, %
Hardness, Shore A
Volume Swell, %

1.2

4.0

4.0

4.8

Rubbers

TABLE

2.5:

STDNLAST

POLYSULFIDE

SYNTHETIC

is a heavy-duty,

ing materials currently


flexibility

allows

those properties

the

RUBBER

and Elastomers

293

SEALANT-STONHARD

two-component

synthetic rubber sealant. It adheres tenaciously to just about all buildby exposure to water or most corrosive gases. STONLASTs
great
and contract to compensate for movement,
vibration,
etc., and it retains

in use, and is unaffected


material

to expand

over a wide range of temperatures

(-65O to +215F).

The purpose of this guide is to aid in determining


the potential
to the damaging effects of erosive chemical spillages.

value

of Stonlast

sealant

when

exposed

The test procedure


used was to totally immerse cured samples of Stonlast in the chemrcals listed for a
period of 30 days at normal room temperature
per ASTM 0471.62T.
Method B. (This is an exceptionally
severe test, since n-lost areas subject to chemical spillages such as these are flushed down periodically
with water as part of the normal maintenance
operation
)
The resultant resistance of Stonlast to the various chemicals
(It is assumed that normal good housekeeping
procedures
with clean water.)
RATING

is related
are used,

CODE

E -

Excellent

Fatr

G -

Good

NR

Not Recommended

The (number)

which

appears

next to each rattng

IS the percent

ALKALIES

ACIDS
E
(1 %)
E
(6%)
NR
NR
NR

Hydrochloric
- 10%.
Hydrochloric
- 30%.
Hydrochloric
- 37%.
Nitric - 10%
Nitric - 50%
Sulfuric - 10%
Sulfuric - 20%.
Sulfuric - 50%.
Sulfuric - 100%.

Hydrocarbons)

Benzene.
Toluene.
Xylene.

NR (314%)
NR (138%)
G ( 61%)

(Halogenated

Hydrocarbons)

Carbon Tetrachloride.
Ethylene Dichloride.
Monochlorobenzene.
Perchloroethylene.
Trichloroethylene.
(Hydroxy

F
( 78%)
NR (605%)
NR (474%)
E
( 43%)
NR (401%)

Copper
Copper
Sodium
Sodium
Sodium
Sodium
Sodium
Sodrum

E
(1%)
.E
(1%)
NR
NR

SOLVENTS
(Aromatic

AND

OTHER

(Aliphatic and Aromatic


Oils and Solvent)
ASTM Oil No. 1
ASTM Oil No. 2
ASTM Reference
ASTM Reference
JP-5..
Motor Oil.
Skydroltv.
SR-6.
SR-10.
Turpentine.

AND

(Esters

E
E
E
E
E
E

(-2%)
(10%)

E
E
E
E

E
E
: : : : : ::G
E
E
E

(
(
(
(
(
(

2%)
1%)
4%)
1%)

2%)
3%)

(Ketones

( 1%)
(12%)
(-1%)
(12%)
( 2%)
(-1%)
(59%)

(21%)
(11%)
(11%)

and Ethers)

Acetone.
Butyl CarbitolM.
Butyl Cellosolve~.
Dibutyl Ether
Ethyl Cellosolve?
Methyl Ethyl Ketone.
Methyl lsobutyl Ketone

SALTS
E (3%)

E (5%)
E
E
E
E
E

(1%)
(1%)
(1%)
(0%)
(1%)

E (1%)

and Plasticizers)

Butyl Acetate
Butyl Cellosolve
Adipate
Dibutyl Phthalate
Dibutyl Sebacate
Dioctyl Adipate
Dioctyl Phthalate
Ethyl Acetate
Propylene Glycol Ricinoleate
TP-SOB Plasticizer
TP-95% Plasticizer
Tributoxy Ethyl Phosphate
(Vegetable

E
E

swell.

CHEMICALS

Fuels,

:
Fuel A
Fuel B

volume

Sulfate - 10%
Sulfate - 14%
Chloride 3%
Chloride - 10%
Chloride - 36%
Hydroxrde
- 10%
Hydroxtde
- 20%
Hydroxide
- 50%

Compounds)

Butyl Alcohol.
Diacetone
Alcohol
Ethyl Alcohol
(denatured).
2-Ethyl Hexanol
Ethylene Glycol
Glycerol
Isopropyl Alcohol
Methyl Alcohol.

using the symbols listed below.


includtng a daily flushing down

Castor
G
.E

( 50%)

( 19%)
( 8%)

E
NR (605%)
E
( 28%)
F
( 87%)
E
( 36%)

and Wood

( 48%)
( 36%)

G
E

( 55%)
( 8%)

( 0%)
( 33%)

: :E
G
E

( 64%)
( 5%)
( 26%)

G
E

( 51%)
( 17%)

( -2%)

:E

Oils)

Oil

Corn Oil.
Cottonseed
Gil:
Linseed Oil
Soya Bean Oil..
White Pine Oil.

G
E

: ::: :::::

E
E
E
E
E

(4%)

( -3%)
(

0%)

( 0%)
( 17%)

294

Corrosion

TABLE 2.6:

Resistant

SILICONE

CORROSION

Materials

ELASTOMER

Handbook

LININGS-HURON

RESISTANCE DATA FOR SlLlGL4S~

Concentration

CHEMICALS

LTD

LININGS*
Temperature
Conditions [Cl

Test Duration

Pwl

Corrosive
Effect Noted

Acids
Hydrochloric
(HCl]

Acid

200

68

30 %

200

28
40

Nitric Acid
(HN031

7%
25%
50%
Reagent Grade

200
200
200
28

68
40
40
40

Sulphuric
(H2504I

10%
50%
50%
50%

200
200
600
85O

5%

Acid

Phosphoric

Acid

1.2%
1.2%

90-1000

.4 mils/yr
loss
.04% weight gain
24 mils/yr loss

.2
1.3
10
4.4

mils/yr
mils/yr
mils/yr
mils/yr

loss
loss
loss
loss

68
30
45
24

1 mil/yr
2 mils/yr
18 mils/yr
15 mils/yr

loss
loss
loss
loss

85O

48

Smils/yr

loss

10%
Reagent Grade

85O
60~

48
45

4% weight gain
1.18% weight gain

50%

85O

48

(H2PO3)

Bases
Ammonium

Hydroxide

(NH4W

Potassium
(KOH]

Hydroxide

Sodium Hydroxide

( NaOH)

10%
10%
20%
30%
50%

200
90-1000
6oQ
RT
RT

42
28
45
40
42

33 mils/yr

1.4
11.6
15
5

mils/yr
mils/yr
mils/yr
mils/yr
17 mils/yr

loss

loss
loss
loss
loss
loss

(continued)

Rubbers and Elastomers

TABLE 2.6: SILICONE ELASTOMER LININGS-HURON

Concentration

295

CHEMICALS LTD (continued)

Temperature
Conditions [Cl

[Days1

Corrosive
Effect Noted

30

10 mils/yr loss

Test Duration

Salt Solutions
Potassium Chloride
(KC11

Sodium Chloride
( NaCL)

100 gpl

65O

30 gpl

68

1 mil/yr loss
.I% weight gain

9Czo
200
90-1000

z
40

900

700+

85O

48

Hypotower Simulation
(No over-chlorination)
pH- 14+ 10

20-500

147

Hypotower Simulation
(50 over-chlorinations)
pH- 14+ 5

2@800

70

200
600

42
45

30 gpl
300 gpl
300 gpl

.5 mil/yr loss
.I&% weight gain

Oxidizing Environments
Electrolytic Sodium
Chlorate Production
Cell
NaCI, 50-250 gpl
NaC103, lOO-600 gpl
NaOCI, 1.5-2.Ogpl
pH=7

4 mils/yr loss

Hydrogen Peroxide
5%

(H202)

Sodium Hypochlorite
(NaOCI-6%)
pH 13
NOTE: lmil=

.OOl inches.

* SiIigIas lining material is a silicone elastomer on a glass fiber backing.

.2% weight gain

2 mils/yr

7 mi Is/yr

2 mi Is/yr
7 mi Is/yr

296

TABLE

Corrosion

2.7:

Resistant Materials Handbook

URETHANE-AMERICAN

CYANAMID

CYANAPRENE
A-8
CYANASET
M 90%
Shore A
% V.C.
. . . . . Acids . . . . . . .
Acetic acid 5%
Hydrochloric
10%
Nitric acid 10%
Sulfuric acid 3%
Sulfuric acid 30%

-3
0
-

6.25
4.9
-

-5
-3

3.7
3.3
-

-1
0

6.9
0.3

-2
-2

5.7
0.8

. . . . . Alkalies
Ammonium
hydroxide
10%
Detergent heavy duty
Sodium carbonate 2%
Sodium carbonate 20%
Sodium hydroxide
1%
Sodium hydroxide
10%
Soap solution 1%
. . . . . . . . . . . . . . . . . . .

0.75
0
4.2
3.6
0
-1.2
3.4

. . . . . . . . . . . Solvents

-4
0

2.5
-0.25

-3
-5
-4
-2
-3

A.:
0:3
-0.4
1.5

. . . . . . . .. . . . . . . . . . . . . . . . . . . . . .

-29
-13
-7
-

105.2
76.4
27.5

-15
-3
0
-7
-2
0

. . . . . . . . . . . . . . . . . . .
ASTM #I
ASTM #3
Heptane
lsooctane
Kerosine
Mineral oil
Toluene
Transformer

. . . .. .. . . . .. . . . . . . . . . . . . . . . . . .

-3
-1
+9
+7
-8
-4
-2

Acetone
Benzene
Carbon tetrachloride
Dimethyl
formamide
Ethyl acetate
Ethyl alcohol
Methyl alcohol
Toluene
Turpentine
Water

CYANAPRENE
D-5
CYANASET M 90%
Shore A
% v.c.*
. . . . . . . . . . . . . . . . . . . . . . . .

40.4
17.8
11.4
37.8
3.2
1.4

-20
-11
0
-9
-5
0
-5
-2
-1

67.4
45.25
-0.25
31.4
13.9
14.6
21.3
0.3
1.3

. . . . . . . . . . Oils, Fuels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
0
0
+3
0
-7
+2

oil

1.7
1.7
0.9
0.5
37.8
-0.3

-2
-3
-1
0
-5
0

0.3
1.3
1.0
0.5
21.3
-1.0

. . . . . . . . . . . . . . . . . . . . . . . . . . . . Other Media . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Aniline
Ethylene dichloride
Hydrogen peroxide 28%
Sodium chloride 10%
*% volume

change. ASTM

-38
-30
0
-3
Test Method:

ASTM

367.9
109
5.9
-0.04
D-543-60T

-35
-14
-3
0

239.5
53.9
3.8
1.3

297

Rubbers and Elastomers

TABLE 2.8:

URETHANE-DEVCON

Devcon FLEXANE
is a two-component
room-temperature
curing urethane for forming abrasion resistant linings,
repairing rubber parts or equipment, and forming flexible molds and parts. FLEXANE
is available in putty and
liquid form in two durometers. A FLEXANE flexibilizer
can be used to produce urethane of any desired durometer.

Chemical Resistance of Aexane-ImllWSiOn

SampleSize:Yz~x% xl Cure:7 Days@ Roomlemperoture Immersion:30 m

$g
-D

Flexone 80
(Llquld &Puny)

VG

Rezone 94
(Llquld & RQ)

VG

Aerone High
Petiormonce Pully
Flexone Brushable
Urelhone
1Rexone BIW

TABLE 2.9:

_a?2

,Ps

ProductNome

l3Y
F

V:

1 VG

1 VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

VG

URETHANE

VG

VG

VG

MEMBRANE-STERNSON

LIMITED

LIQUATHANE
is a high performance elastomeric urethane rubber membrane. Applied as a liquid, LIQUATHANE
is
designed to protect concrete and steel from corrosive attack as well as exhibiting excellent resistance when used as a
waterproofing/liquidproofing
or between slab membrane.

CHEMICAL

RESISTANCE

Exposure
Acids

GUIDELINES

Resistance
Good resistance

to common

industrial

strength acids

(0% to 15%), such as sulphuric. hydrochloric,


phoric, lactic, dilute oxidizing
agents.
Alkalis

Good

resistance

to common

industrial

phosstrength

caustics (0% to 15%), such as sodium hydroxide,


many chloride,
sulfate and nitrate salts, saturated
salt solutions.
Fresh Water/
Sea Water

Excellent

resistance

298

Corrosion Resistant Materials Handbook

TABLE 2.10:

VARIOUS

ELASTOMERS-AMERICAN

CYANAMID

Test Formulas
CYANACRYLO
J-c

-R
CYANACRYL R Polyacrylate
CYANACRYL L Polyacrylate
c Polyacrylate
cuwRn
Chgn&um HR 665
vamac B-124
General Elecnic SE-3724
N-550 (FEF) Carbon Black
N-990 (MT) Carbon Black
Hi-Sil 215 Precipitated Silica
Maglite D
Hercoflex 600
Dioctyl Sebacate
~araplex G-25
silane A-189
zinc Oxide
stearic Acid
TE-80 Petrolatrrm
Armeen
18-D
NPS Red Oil Soap
curative c-50
Spider Sulfur
CYUFAM@DS
Horfax
Disk No. 1
DPG
Total Parts

Imersion

100

124
100
60

55

40

60
15
40
10
5

10
5

3.5

3.5

0.3

0.3

0.4
3
1
2

2
0.5

-160.8

8
0.3

0.3
2
1.2

165.8 170.3

179.7

186.7

100.0

in Synthetic Fluids for 168 Hours at 3OO'F


CYANACRYL@
-!L
L

NBR
-

-EA8

-SI

-5
-8
+7

+10
-67
-49
+1

-2
-21
-33
+12

-16
-20
-12
+28

-6
-35
-41
+11

-2
-12
-11
+10

+16
-78
-86
+1

-5
-27
-36
+18

-13
-15
-4
+25

-14
-52
+7

-4
-21
-52
+10

-3
-12
-12
+10

+12
-71
-53
+2

-7
-14
-20
+15

-15
-24
-12
+28

-7
-6
-25
+13

-13
-30
-35
+20

-12
-22
-2
+19

+8
-77
-62
+6

-20
-39
-41
+42

-16
-25
-18
+28

-9
-8
-12
+18

-17
-24
-15
+28

-16
-34
-3
f26

+13
-80
-100
+8

-19
-50
-49
+69

-16
-29
-13
+24

+1
-28
-45
+5

-2
-36
-47
+7

Mobil 1 (LAOO)
Hardness Channe. points
Tensile Chang;,~%Elongation Change, %
Volume Change. X

-3
-31
40
+9

Polar Start DN-600 (LAB)


Hardness Change, points
Tensile Change. X
ElongationChange, X
Volume Change, X
Chenlube (DAE)
Eardness Change, points
Tensile Chang;. X
Elongation Change. X
X

Ultra E-11 (DAE)


Hardness Change, points
Tensile Change. X
Elongation Change. X
Volume Change. x
L

100

Valvoline ESP (Blend)


Hardness Change. points
Tensile Change, X
Elongation Change. X
Volme Change. x

CYANACRY
NBR
EAE
SI

100

-R

Volume Change.

-NBR

acrylic elastomer
nitrile polymer
ethylene acrylic
silicone

LAO0
LAB
DAE

I inear alpha olefin oligomer


linear alkylated benzene
dibasic acid ester

Rubbers

TABLE 2.11:

VARIOUS

ELASTOMERS

AND RUBBERS-DU

Chemical
GATlNG KEY

A-Flurd
B-Flurd
C-Flurd

and Elastomers

PONT

Resistance *
T-No
X-No

has kttle or no effect


has mmor to moderate effect
has severe effect

data-kkely
to be compatible
data-not
likely to be compahble
VlTW@

chemical
Acetaldehyde
Acetic acid. 20%
Acetic acid. 30%
Acetic acrd. glacial
Acebc acid. glacial
Acetic anhydride
Acetone
Acetylene
Alummum chloride solubons
Alummum sulfate solutions
Ammoma. anhydrous
Ammonium chlonde soluhons
Ammomum hydroxrde solutrons
Ammonium sulfate solubons
Amy1 acetate
Amyl alcohol
AmIme
Anrlme
Annme
ASTM 011 xl
ASTM 011x3
ASTM reference fuel A
ASTM reference fuel B
ASTM reference fuel C
ASTM reference fuel C
Asphalt
Banum hydroxide solutrons
Beer
Benzaldehyde
Benzene
Benzoyl chlonde
Borax solutions
Borrc acrd solutions
Bromme, anhydrous lrqurd
Butane
Butyl acetate
Butyraldehyde
Butync acrd
Calcium brsulfite solubons
Calcium chlonde solutions
Calcrum hydroxide solubons
Calcium hypochlonte, 5%
Calcrum hypochlonte. 20%
Carbon btsulfrde
Carbon dioxrde
Carbon monoxrde
Carbon tetrachlonde
Castor 011
Chlorme gas, dry
Chlonne gas, wet
Chloroacehc acid
Chlorobenzene
Chloroform
Chlorosulfonrc acrd
Chromtc acrd, lo-50%
Citrrc acrd solutrons
Copper chloride soluhons
Copper sulfate soluhons
Cottonseed 011
Creosote 011
Cyclohexane
Drbutyl phthalate
&ethyl sebacate
Droctyl phthalate
DOWTHERM A
DOWTHERM A
Eprchlorohydnn
Ethyl acetate
Ethyl acetate
Ethyl alcohol
Ethyl chlonde
Ethyl ether

299

;:

C
C

t
B (100F)
1

B
0

(2:UF)
5t
A

:
1
1

(ZO(PF)
A (200F)
A (2;VF)
c,toBw,

::
B
A
C

;;
i
A&F)
:
A (15BF)
A (1WF)
A(t$F)
-

r
A
A
A
A
L
A
A
A
AAB
-

A
B (:PF
Ii
B (l&F,

A (ZL,
A (200F)

A
A

:
C

:
B

;:;
A (2OODF)
A (Z&F,
A (2:BF)

x
A
A

T
A

;;
T
A
-

:
A
A
A
:
T
C
6
X

B
A
X
C

:
X
C

A (&F,
A
A
A
A

;
A
A
A
A-B

x
B

A (25F)
!

7
C

A (4pF)
::
:

X
C
X
T

A (l&F)
C
C

B (&F)
A
B
C

A
* ,1LF,
B
A
A
B (2l;PF)
A
C
C
T
A
A
A

r
T

B (t:bF)

A (4&V,

x
-

A (t:BF)

x
C
-

A (2:TF)
:
A
A
C
A
A
A
A (3:1pF)
A (212F)
A
B
B

B
c

C
A
A
A
C
A
A
A

A
8-C
C

:
A
8
:

A (2!2F)
A-B
B(lWF)
C (300F)
A (300F)
A (350F)
A
A
A

B-C
X

A(&

(2t;F)

:
C
B

;
C
:
B
X

7
A
A
A
-

:
C

A (2:EPF)
A (200F)

1;:;

:I:%
A (15bF)
A (15BF)

8
A (200F)
A

c
X (15kF)
:
B

A (2:,F)
B (4OBF)
C (12PF)
C

A
C

(continued)

300

Corrosion

TABLE 2.11:

Resistant

VARIOUS

Materials

Handbook

ELASTOMERS

AND RUBBERS-DU

PONT

Chemical

Neoprene

Ethylene dichlonde
Ethylene glycol
Ethylene oxide
Exxon 2380 turbo oil (lubncant)
Ferw chloride solutions
Fluos~lw acid
formaldehyde, 40%
Formaldehyde. 40%
Formic acrd
FREON*-11
FREON-l 1
FREON-12
FREON-12
FREON-22
FREON-22
FREON-l 13
FREON-113
FREON-1 14
FREON-l 14
Furfural
Fyrquel.220 (hydraulic fluld)
Gasoline
Glue
Glycertn
n-Hexane
Hydrazme
Hydrochlow acid, 20%
Hydrochloric acid, 20%
Hydrochlonc acid, 37%
Hydrochloric acid. 37%
Hydrochloric acid. 37%
Hydrocyanic acid
Hydrofluoric acid. 46%
Hydrofluonc acid. 75%
Hydrofluonc acid. anhydrous
Hydrogen
Hydrogen peroxtde. 90%
Hydrogen peroxrde. 90%
Hydrogen sulfide
lsooctane
Isopropyl alcohol
Isopropyl ether
JP-4
JP-5
JP-6
JP-6
Kerosene
Kerosene
Lacquer solvents
Lactic acid
Lmseed oil
Lubrlcabng oils
Magnesium chloride solutions
Magnesium hydroxide solubons
Mercunc chlonde solubons
Mercury
Methyl alcohol
Methyl ethyl ketone
Methylene chlonde
Mineral oil
Mobrl XRM 206A (aircraft
eng. lube)
Naphtha
Naphthalene
NWc acid. - 10%
Nitnc actd. 30%
Nitric acid. 30%
Ndnc acid. 60%
Ndnc acid. 70%
NW acid.
70%
NW acid. red fummg
Nitric acid. red fummg
Nitrobenzene
Olelc acid
Oleum. 20-25%
PalnWc actd
Perchloroethylene
Phenol
Phenol
Phosphonc acid. 20%
Phosphoric acid. 60%

C(lZoT,
A (1rFt

(continued)

7
A(lyFI
c Y
A-0
I (13U'F)
A&F,
A
A(l3VF)
A(&F)
r&q
B
B
A(lWF)
AWW
A
A

VAMAC

A(2:IF)
X

i
1
r
0
ks
c
a
c
E-c
i
7
-

VITOY'
A-B(lZU'F)
A(25O'F)
C(l5c'F)
A(39FF)
A
T

i
C,l;F)
A-B
T(lJ(PF)
A.8
B(l3U'F)
C
X(lWF)
T&F,
B
C&F)
A(2lPF)
A
A
A(2WF)
z
A
A(23fTF)
A(l5PF)
B(2jg"F)
A
k&F,
A
A
A
C(27U'F)
B(27BF)
A
A

a
;;

A&F)
A(4OU'F)
A(lOVF)
C(S5U'F)
:::z;
C
A
A,lAF)
A
A
;1
B
S&F,
A(3k-l
A(158T)
A(l76F)
A
A
A

x
x
x
x
x
X
r

,lAF,

C(&F,
B

A(2:Z'F)
A(2lPF)
B(3WF)
A(2:FF)
(continuec

301

Rubbers and Elastomers


TABLE

2.11:

VARIOUS

ELASTOMERS

HYPALOW@

Chemical
Phosphonc actd. 70%
Phosphoric acid. 65%
Ptckkng solubon
(20% nttnc actd. 4% HF)
Pickling solution
(17% nitric acid, 4% HF)
Pickling solution
(17% nitric acid, 4% HF)
Picric acid
Potassium dichromate solutions
Potassium hydroxide.
dilute solutions
Pydraul312C
Pyridine
OFl-2023 (silicone brake fluid)
SAE#lOoil
Sea water
Shell turbine oil 307
Silicone grease
SKYDROL 500
SKYLUBE 450
Soap solubons
Sodium chloride solutions
Sodium dichromate. 20%
Sodium hydroxide, 20%
Sodium hydroxide, 46th%
Sodium hydroxide, 46h%
Sodium hydroxide, 50%
Sodium hydroxide, 73%
Sodium hypochlorde. 5%
Sodium hypochlorite. 20%
Sodium peroxide solutions
Soybean oil
Stannic chlonde
Stannous chloride. 15%
Steam (see water)
Steam
Steanc acid
Styrene
Sulfur, molten
Sulfur dioxide, gas
Sulfur dioxide, liquid
Sulfur tnoxtde
Sulfuric acid, up to 5%
Sulfuric actd. 5-10%
Sulfuric actd. 1 O-50%
Sulfuric acid, 50-60%
Sulfurtc acid, 60%
Sulfuric actd. 90%
Sulfuric acid, 95%
Sulfuric acid. 95%
Sulfuric acid, fuming (20% oleum)
Sulfurous acid
Sunoco XS-620 (EP lubricant)
Tanntc actd. 10%
Tartaric acid
Tetrahydrofuran
Toluene
Tributyl phosphate
Trichloroethylene
Trichloroethylene
Tricresyl phosphate
Triethanolamine
Tnsodium phosphate solutions
Tung oil
Turpentine
Water
Water
Xylene
Xylene
Zinc chloride solutions

Doless

AND RUBBERS-DU

otherwise

noted,

HYPALON
HYTREL
NEOPRENE

(continued)
NOADEV

Wcoprcnc
::

A
A

A(150F)

_;
A (26@v

;;
A

7
A
A

c
A

F
;:

:
C

A (2:lPF)

A (20aF)

A (21zF)

A (2&
A (2OpF)
A

;
;

:I:%

A
A

A(&
A (2WF)
A

:
A
C

A (2$F)
A

B
A (350F)

rT
A(21tF)

I) (1GFj

A (2&
A (1FF)
A
B (:;BpF)
A ,&

t
C

A
A
A-0
X
X

;;

A&F)
A (2;rTF)

polyethylene

NORDEL
VAMAC
VITON

All

A
T

A(2:pF

ore saturated.

BWV
AW=-l

:
A(15CF)

solutions

A (2:QF)
A (1yF-f

A (&F,

A (2;F)

;7
A

A (2;F)
A
A
C

::

z
C

c
A(l52F)

A (2&)
T

T
T

:
C

A (250F)
A

z
A

A
A (2mF)
C

of aqueous

:
A
A
B
A
A

:
C
A

chlorosulfinated
polyethylene
polychloroprene

VAMAC'

A (269v
A (200F)

A (2rF)

concentration

PONT

::

A(IWF)

A ,&

A (lSi?Ff

A (2:PF
a (15IpFf
A

ratings

are at room

temperature

synthetic
rubber
ethylene
acrylic
fluoroelastomer

unless

speciflod

302

TABLE

Corrosion Resistant Materials Handbook

2.12:

VARIOUS

ELASTOMERS

AND

RUBBERS-EXXON

CHEMICALS

Exxon butyl rubber and its chlorinated


analog, chlorobutyl
rubber are isobutylene-isoprene
basically
inert, nonpolar,
stable elastomers
which exhibit
outstanding
resistance to attack
ent chemicals.

copolymers.
They are
by a great many differ-

VISTALON
elastomers
are classified
generically
as either ethylene-propylene
copolymers
(EPM) or ethylene-propylene terpolymers
(EPDM).
All grades of VISTALON
EPM have a completely
saturated
hydrocarbon
chain which
makes them highly
resistant
to attack
by chemical
agents such as oxygen,
ozone, acids, and the like that seek to
react at the site of a double bond.
Exxon
elastomers
offer good resistance to water, inorganic
glycol
base antifreeze
formulations,
and to most inorganic
elastomers
show good resistance to attack by acids, amines,
ethers, and ketones.
Resistance
to detergents
and soaps is
or in 1% solutions which approximate
the concentrations
cations.

salt solutions,
bases, synthetic
hydraulic
fluids, ethylene
acids. When immersed
in organic compounds,
Exxon
and oxygenated
compounds-alcohols,
aldehydes,
esters,
excellent
whether
in concentrated
form (as purchased)
of these materials commonly
used in household appli-

Exxon elastomers display good resistance to attack by animal or vegetable oils. However, they are like other petroleum derived synthetic
polymers
in that their resistance to the attack of hydrocarbons,
oils, and other petroleum
based chemicals
is low. Only VISTALON
6505 blends with
nitrile
and polychloroprene
rubbers
maintain
good
physical properties
after prolonged
exposure
to these materials.

CHEMICAL

RESISTANCE

OF COMPOUND

BASED ON INTERMEDIATE

UNSATURATION

BUl-YL RUBBER

72 Hours Immersion at 212OF


VOlUnW
change n
WATER
Distilled Water
Sea Water--Atlantic
Sea Water-Pacifu

Tensik stmngth
Retained %

+0.78
+0.56
+1.04

95.8
98.8
95.8

INORGANIC ACIDS
Boric Acid (10%)
Chlorosulfanic Acid (10%)
Chromic Acid (10%)
Chromic Acid (Cont.)

+0.93
Disintegrated
+6.60
+19.6

103.0

Hydrochloric Acid (10%)


Hydrochloric Acid (Cone.)
Hydrofluoric Acid (Cont.)
Nitric Acid (10%)

+3.70
+15.9
-1.94
+9.09

fl0llgdfOll
Retained %

Hardness
Change Pts.

surface
Condition

81.8
90.2
88.8

+1
+2
+2

Unchanged
Unchanged
Unchanged

94.1

+1

Unchanged

83.1
63.9

75.1
68.6

-2
-3

Unchanged
V. Brittle

96.4
81.9
89.0
-

78.4
109.8
58.2

-2
-8
-3
-

Sl. Tacky
Unchanged
Unchanged
-

Nitric Acid (Cow.)

Disintegrated

Phosphoric Acid (Cont.)


Sulfuric Acid (10%)
Sulfuric Acid (Cont.)

-0.46
+0.24
Disintegrated

102.4
94.0

93.5
82.4

+1
+2

Unchanged
Unchanged

+1.89
+1.88
-0.45
+1.16

958
105.4
98.8
97.0

86.3
96.1
86.9
82.4

-1
-3
+2
0

Unchanged
SI. Tacky
Unchanged
Unchanned

+2.85
+1.92

98.2
101.8

88.2
91.2

-2
-2

Unchanged
St. Tacky
Unchanged

-2
+1
+1
0
f2

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

INORGANIC BASES
Ammonium Hydroxide (10%)
Ammonium Hydroxide (Gnu.)
Barium Hydroxide (Cont.)
Calcium Hvdmxide (10%)
Potassium Hydroxide (10%)
Sodium Hydroxide (10%)
Sodium Hydroxide (Cont.)
INDRGANIC SALTS (25% Sofutiona)
Aluminum Chloride
Aluminum Sulfate
Ammonium Chloride
Ammonium Nitrate
Ammonium Phosphate

+0.11

99.4

88.2

+0.50
+0.51
+0.13
+0.21
+0.57

89.2
97.0
94.0
95.2
96.4

78.4
83.7
83.7
85.0
82.4

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

303

(continued)

72 Hours Immersion at 212F


VdumC
Change K

Tensik Strengtfr
Retained SC

Efongatifm
Retained %

Banum Chloride
Barium Sulfide
Calcium Chloride
Calcium Hypochlorite

+0.17
+0.39
-0.46
+0.69

95.8
94.0
89.8
98.8

82.4
82.9
77.1
80.4

+1
0
0
-2

Unchanged
Unchanged
Unchanged
Unchanged

Cupric Chloride
Cupric Sulfate
Ferric Chloride
Ferric Nitrate

+0.48
+0.94
+1.50
+3.65

98.2
91.6
95.2
97.6

Ferrous Sulfate

+0.48

92.8

84.9
80.4
76.5
93.0
81.8

+1
+1
0
-4
+1

Unchanged
Unchanged
Unchanged
V. Tacky
SI. Tacky

Magnesium Chloride
Magnesium Sulfate
Nickel Sulfate
Potassium Chloride
Potassium Permanganate

+0.31
+0.82
+0.79
-0.07
+0.58

94.6
94.0
94.0
90.4
93.4

84.3
81.0
84.3
82.4
84.3

+2
+1
+1
+1
-6

SI. Tacky
SI. Tacky
SI. Tacky
Unchanged
SI. Brittle

Potassium Bisulfite
Potassium Dichromate
Sodium Borate (Borax)

+1.41
+0.61
+0.34

Sodium Bicarbonate
Sodium Chloride
Zinc Chloride
Zinc Nitrate

+0.52
0.00
io.73
+0.24

92.8
91.6
94.6
94.6
100.0
94.0
94.6

83.3
77.1
84.9
84.3
82.4
80.4
80.9

Citric Acid (10%)


Formic Acid (10%)
tactic Acid (10%)
Oleic Acid (100%)

+10.9
+ 14.7
+9.w
+0.69
+12.3
+6.12
+B22

88.0
79.5
86.7
97.0
86.0
90.4
28.3

73.9
67.2
72.0
85.7
68.6
74.5
50.4

-6
-3
-3
+2
-4
0
-38

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanged
Unchanged
Unchanged

Oxalic Acid (10%)


Phenol (10%)
Phenol (100%)
Picric Acid (10%)
Stearic Acid (100%)
Tannic Acid (10%)
Tartaric Acid (10%)

+2.36
+2.82
-7.54
+ 14.6
+92.8
-0.76
+1.u

97.6
103.6
116.3
78.3
111.5
96.4
97.0

81.8
94.1
110.4
61.4
105.3
86.3
88.2

+1
-4
-7
-5
-4
0
+2

Unchanged
SI. Tacky
SI. Tacky
Unchanged
Unchanged
SI. Tacky
Unchanged

+3.19
+2.04
+2.44
+0.63
+0.36

106.6
91.0
89.8
98.2
loo.0

98.0
82.9
91.6
91.6
84.9

-9
-3
-3
+2
+2

Unchanged
Unchanged
SI. Tacky
SI. Tacky
Unchanged

Gfycerol
1 Hexand
Resorcind

-0.52
+17.B
+0.50

98.8
95.8
103.6

86.3
104.6
91.6

+2
-23
+3

Unchanged
Sf. Tacky
Unchanged

ALDEHYDES
Benuldehyde
Butyraldehyde
Furfural

+12.3
+24.9
+4.37

94.6
69.9
108.4

102.0
90.2
101.4

-19
-25
-8

Unchanged
Sf. Tacky
SI. Tacky

AYINES
Aniline
Triethanolamine
UDMH

+7.97
-11.1
+13.7

98.2
100.6
54.2

109.2
88.8
79.8

-15
+2
-18

Unchanged
Tacky
Unchanged

+67.2
+43.7
+22.5
+14.7
+1.80

31.3
51.2
88.0
60.2
112.1

46.5
78.4
83.7
67.3
103.3

-35
-33
-22
-17
-6

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

ORGANfC ACIDS
Acetic Acid (10%)
Acetic Acid (Glacial)
Chloracetic Acid (10%)

ALcoHoLs
Benzyl Alcohol
Ethyl Alcohol
Isopropyl Alcohol
Methyl Alcohol
Ethylene Glycol

Hardness
Change Pts.

0
0
-1
+1
-1
0
+2

Surface
Condition

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanged
Unchanged
Unchanged

ESTERS
Amy1 Acetate
Dibutyl Sebacate
Dioctyi Phthalate
Ethyl Acetate
Tricresyl Phosphate

(continued)

304

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

72 Hours Im-ion
TdkStNn#l
RJtJinedw

ETHERS
Dibenryl Ether
Diethylene Glycd Monobutyl Ether
Ethyl Ether
Ethylene Glycol Monoethyl Ether

(continued)

at 212*F

Ehngation
RJunedY

HarlhleJJ
ChJnrPts.

suhce
con&ion

99.4
110.8
28.9
W.0

111.8
104.9
30.0
89.6

-25
-12
-34
-12

Unchanged
Sl. Tacky
SI. Tacky
Unchanged

+125.6
+243.5
+190.2

19.9
18.1
15.7

24.1
17.7
26.1

-37
-37
-43

SI. Tacky
Sf. Tacky
Unchanged

+144.1
+94.4
+108.8
+198.0
+206.8

15.7
22.3
83.1
10.2
16.3

22.2
22.2
75.9
26.1
25.5

-35
-32
+12
-51
-45

Unchanged
Sl. Tacky
Sl. Tacky
Unchanged
Unchanged

20.2
21.6
45.7
17.1

-38
-32
-24
-46

Unchanged
St. Tacky
SI. Tacky
Tacky

+20.6
+4.89
+54.8
+5.01

HYDRDCARBONS
BelueM

Cyclohexane
Ethylbenzene
Heptane
HexJnJ

Naphthalane
Toluene
Xylem
HALDGENATED HYDROCARBONS
8enzyl Chloride
Bromobenzene
Carbon Tetrachloride
Chloroform
Ethylene Dichloride
Perchlorathvlene
OTHER SUBSTITUTED
HYDROCARBONS
Carbon Disulfide
Nitrobanzene

+225.8
+85.2
-I-37.9
+194.3

Disintegrated
Disintegrated
18.1
21.1
39.8
12.7

+ 144.9
+11.9

21.7
101.2

21.0
106.9

-30
-20

SI. Tacky
Unchanged

KETONES
Acetone
Methyl Ethyl Ketone
Methyl lsobutyl Ketone

+7.92
+15.7
+61.4

85.5
48.8
35.5

88.8
53.5
49.0

-11
-18
-32

SI. Tacky
Unchanged
SI. Tacky

DETERGENTS&OTHER
CLEANING PRODUCTS
Calgonite (1%)
Clorox (1%)
Clorox (Cont.)
Joy (1%)
Joy (Cont.)

+1.76
+1.13
+1.20
+2.08
-0.13

102.4
103.0
103.0
102.4
100.0

92.2
88.8
88.2
91.6
90.2

+1
+1
Cl1
+1
+1

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Lestoil (1%)
Lux Flakes (1%)
Rinse Dry (1%)
Rinse Dry (Cow)
Tide (1%)

+2.94
+1.78
+1.18
+1.34
+1.38

100.6
105.4
101.8
95.2
100.0

96.1
96.7
88.8
86.3
93.1

-1
0
+2
+2
-1

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

NATURAL FATS 6 OILS


Butter
Castor Oil
Cottonseed Oil
Lard
Oleomargarine
Olive Oil
White Mineral Oil

+23.1
-1.25
+19.2
t28.9
+ 15.3
+24.8
t 100.6

66.9
89.8
71.1
75.9
81.9
71.1
28.9

97.7
86.9
94.1
104.5
102.6
99.4
31.4

-18
-22
-17
-21
-33

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

OILS 6 FUELS
A.S.T.M. No. 1 Oil
A.S.T.M. No. 2 Oil
A.S.T.M. No. 3 Oil
A.S.T.M. Fuel A
A.S.T.M. Fuel B
A.S.T.M. Fuel C
Heating Fuel Oil
Jet Aircraft Engine Oil
Kerosine

+64.3
+88.2
+ 173.4
+ 159.0
+199.5
+232.7
+224.1
+92.3
t262.0

38.0
33.1
16.3
18.1
13.3
13.3
13.3

56.3
59.4
40.6
25.5
22.9
21.0
22.9

-34
-36
-46
-40
-45
-47
-45

SI. Tacky
SI. Tacky
Unchanged
Unchanged
SI. Tacky
SI. Tacky
Unchanged

13.3

22.2

-47

Unchanged

-21
0

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

and Elastomers

305

(continued)

72 Hours Immersion at 212OF


Volume
Changa K

Tensik Strength
Retained K

Elongation
Retained K

Hardness
Change Pts.

Sur(acC
Condition

AUTOMOTIVE PRODUCTS
Chassis Grease
Motor Oil (lOW.30)
Gasohnc (RON 94)
Gasohne (RON 99)
Gasohne (RON 102)
Gasolme: unleaded

+44.8
+157.6
+200.8
+181.9
+202.5
+ 162.0

40.0
17.5
15.7
15.7
14.5
12.7

45.7
30.8
21.6
20.2
20.2
18.2

-35
-56
-43
-39
-43
-43

SI. Tacky
Unchanged
Unchanged
Unchanged
Unchanged

-15
-26
-18
-24
-22

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

HYDRAULK FLUlDS
Dronite
Pydraul
Pydraul
Skydrol
Skydrol

8200
F-9
60
500

MfSCELLANEDUS
Gelatin (sat. soln.)
Glucose (sat. soln.)
Tincture of Iodine

+13.4
+27.7
+9.79
+14.1
+12.3

69.9
74.7
98.2
92.2
88.6

79.9
102.0
103.9
107.3
103.3

+2.39
+0.12
+1.11
-0.23
-0.12

100.6
101.9
101.2
97.0
93.4

VOIU~
Chmge %

TensUe Strength
Retained %

Elongation
Retained%

-0.11
+0.32
+0.25

100.0
102.4
97.6

97.5
100.6
94.1

+3
+3
+3

Unchanged
SI. Tacky
SI. Tackv

lNORGANlC AClDS
Boric Acid (10%)
Chlorosulfonic Acid (10%)
Chromic Acid (10%)
Chromic Acid (Cont.)

-0.11
Disintegrated
+0.93
+43.7

103.0

98.6

-l-3

3. Tacky

99.4
10.2

100.6
86.9

+3
-34

SI. Tacky
Tacky

Hydrochloric Acid (10%)


Hydrochloric Acid (Cont.)
Hydrofluoric &id (Cont.)
Nitric Acid (10%)
Nitric Acid (Cont.)

-0.65
+2.67
+0.62
+0.63
+14.8

98.8
98.2
98.8
103.0
28.9

95.5
110.4
98.6
97.5
103.9

+4
0
+1
+1
-28

SI. Tacky
SI. Tacky
Tacky
SI. Tacky
V. Tacky

-0.33
-1.22
Disinteerated

98.8
98.2

99.4
99.4

+3
+3

Sl. Tacky
SI. Tacky

102.0
102.0
96.7
102.0

+2
-3
+3
+3

Unchanged
Unchanged
Unchanged
Unchanged

Prestonc antifreeze
Dowgard antifreeze

85.7
86.9
88.8
88.2
82.4

+2
+2
+2
-1
+3

Unchanged
Tacky
Unchanged
Unchanged
Unchanged

One Month Immersion at 7S 2 5OF

WATER
Distilled Water
Sea Water-Atlantic
Sea Water-Pacific

Phosphoric Acid (Cont.)


Sulfuric Acid (10%)
Sulfuric Acid (Cont.)

Hardness
Change Pts.

Surface
Condition

INORGANICBASES
Ammonium Hydroxide (10%)
Ammonium Hydroxide (Cont.)
8arium Hydroxide (Cow)
Calcium hydroxide (10%)

+0.69
-l-o.75
+0.13
+0.35

103.6
103.6
99.4
101.2

Potassium Hydroxide (10%)


Sodium Hydroxide (10%)
Sodium Hydroxide (Cont.)

+0.11
+0.23
+0.11

97.0
94.6
106.0

93.5
88.8
98.0

+3
+3
+2

SI. Tacky
Unchanged
Unchanged

INDRGANIC SALTS (25% Sotutions)


Aluminum Chloride
Aluminum Sulfate
Ammonium Chloride
Ammonium Nitrate
Ammonium Phosphate

+0.34
+o.SD
-0.48
+0.42
+0.26

100.0
99.4
97.0
96.4
101.8

91.6
95.5
94.7
96.1
99.4

+3
+3
+4
+3
+3

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Ranum Chloride
Barium Sulfide
Calcium Chloride
Cakium Hypochlorite

-0.83
-1.29
+1.43
+0.73

97.6
98.8
101.2
100.0

97.5
98.0
99.4
95.5

+3
+3
+3
+2

Unchanged
Unchanged
Unchanged
Unchanged

(continued)

306

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

One Month Immersion at 75O 2 SF


Volume
Change X

Tensik strength
Retained %

Elongation
Retained K

Cupric Chloride
Cupric Sulfate
Ferric Chloride
Ferric Nitrate
Ferrous Sulfate

-1.00
+0.48
-0.11
+0.68
+0.70

98.8
95.8
98.8
101.2
89.2

93.5
96.1
97.5
101.4
93.5

+3
+2
+3
+2
+2

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Magnesium Chloride
Magnesium Sulfate
Nickel Sulfate
Potassium Chlorida
Potassium Permanganate

+1.66
-0.12
0.00
-0.56
+4.09

98.8
97.6
96.4
95.8
83.1

97.5
93.5
97.5
94.7
78.4

+2
+2
+2
+3
+2

Unchanged
Unchanged
Unchanged
Unchanged
Brittle

Potassium Bisulfite
Potassium Dichromate

+0.23
+0.63
+0.37
+0.25
-0.37
-0.12
0.00

101.2
98.8
97.6
95.2
100.0
96.4
96.4

loo.0
97.5
98.0
93.5
100.0
93.5
96.7

+2
+3
+3
i-3
+3
+3
f4

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

+1.88
+3.90
+1.24
-1.28
+0.38
0.00
+43.7

105.4
97.6
105.4
97.0
96.4
98.2
69.3

105.3
102.5
105.9
97.5
94.7
95.5
81.0

+3
-2
+3
+4
f3
+4
-16

Tacky
St. Tacky
St. Tacky
St. Tacky
SI. Tacky
SI. Tacky
Unchanged

+0.23
+0.94
+0.59
+0.46
+6.14
-0.13
-0.36

98.8
109.7
105.4
105.4
106.6
96.4
98.8

98.0
108.4
108.4
102.6
109.8
92.8
96.1

+3
fl
-2
+2
-1
+3
f5

SI. Tacky
SI. Tacky
Sl. Tacky
St. Tacky
Unchanged
Unchanged
St. Tacky

Benryl Alcohol
Ethyl Alcohol
Isopropyl Alcohol
Methyl Alcohol
Ethylane Glycol

+0.36
+0.39
G.00
+0.25
0.00

103.0
94.6
94.6
100.0
85.5

100.6
99.4
98.0
102.6
85.7

-1
-8
fl
-1
+3

Tacky
SI. Tacky
SI. Tacky
SI. Tacky
SI. Tacky

Glycerdl
1 .Hesarul
ResorcinU

-1.04
+3.39
+0.32

98.8
101.2
100.0

99.4
io3.3
98.0

+3
-3
+3

Tacky
SJ. Tacky
SI. Tacky

ALMHYMS
Renraldchyde
Butyraldehyde
Furfuraf

+10.4
+21.6
+0.11

102.4
66.3
106.6

106.9
81.4
106.5

-15
-20
-5

SI. Tacky
SI. Tacky
Tacky

AYINES
Aniline
Triethandamine
UDMH

+5.07
+0.13
+10.5

110.8
101.2
59.0

108.4
100.0
82.4

-6
+4
-13

SI. Tacky
SI. Tacky
Unchanged

ESTERS
Amy1 Acetate
Dlbutyl Sebacate
Oioctyl Phthalate
Ethyl Acetate
Tr~~resyl Phosphate

+46.4
+22.8
+1.85
-l-24.2
-0.13

39.2
80.1
101.2
95.3
101.2

45.1
96.1
103.9
86.9
103.9

-23
-17
-1
-13
f2

Unchanged
SI. Tacky
St. Tacky
Tacky
Tacky

+12.1
+1.32
-t-58.7
+1.29

loo.6
102.4
30.7
103.0

106.5
107.8
65.5
105.3

-16
-2
-24
-2

Unchanged
Tacky
Tacky
Tacky

Sodium Borate (8oru)


Sodium Bicarbonate
Sodium Chloride
Zinc Chloride
Zinc Nitrate
ORGANIC ACIDS
AcetIc Acid (10%)
Acetic Acid (Glacial)
Chloracetic Acid (10%)
Citric Acid (10%)
Fornw Acid (10%)
Lactic Acid (10%)
Oleic Acid (100%)
Oxahc Acid (10%)
Phenol (10%)
Phenol (100%)
Plcric Acid (10%)
Steanc Acid (100%)
Tanruc Acid (10%)
Tartarlc Actd (10%)

Hardness
Change Pts.

surface!
Condition

SI

ALCOHOLS

ETHERS
O~benryl Ether
Diethytene Glycd Monobutyt Ether
Ethyl Ether
Ethylene Glycol Monoethyl Ether

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

and Elastomers

307

(continued)

One Month Immersion at 75 * 5-F


Vdwnt
ww

Tensilt Strangth
Rttaintd w

Elongation
Retained%

Hardntss
Change Pts.

Surfact
Condition

HYDROCARBONS

Btnztnt

Cyclohtxant
Ethylbenzene

+71.4
+206.3
+167.4

26.5
22.9
24.7

27.5
18.2
23.5

-27
-28
-31

Unchanged
Sl. Tacky
SI. Tacky

Htptant
Hcxane
Naphthaltnt

+136.6
+160.8
+75.5

22.9
23.5
92.8

21.0
21.0
82.9

-27
-27
-13

SI Tacky
SI. Tacky
Sl. Tacky

Tolutnt
Xyltnt

+123.6
+182.0

23.5
22.3

22.9
20.2

-29
-30

Tacky
SI. Tacky

HALOGENATEO HYDROCARBONS
Btnryl Chloride
Bromobenzene
Carbon Tetrachloride
Chloroform

+12.8
+123.1
+192.0
+158.1

57.2
24.9
22.9
21.7

77.5
26.1
18.2
19.7

-20
-31
-29
-30

+25.6

50.0

62.8

-18

Per;hloroe!hyltt

+207.3

19.9

15.7

-32

Tacky
SI. Tacky
Unchanged
SI. Tacky
SI. Tacky
SI. Tacky

OTHER SUBSTITUTED
HYDROCARBONS
Carbon Dlsulflde
Nltrobenzene

+123.5
+7.64

23.5
105.4

21.0
105.3

-28
-13

SI. Tacky
SI. Tacky

+6.07
+10.2
+23.3

88.0
82.5
67.8

93.5
87.7
74.5

-10
-13
-18

SI. Tacky
SI. Tacky
SI. Tack;

-0.38
+0.64
+2.09
+0.13
-11.1

101.1
104.2
102.4
98.8
101.8

102.5
103.9
101.0
98.6
99.4

+3
+3
+2
+3
+4

Unchanged
Tacky
Tacky
Tacky
Tacky

+1.55
+0.35
+0.36
0.00
+0.26

131.8
137.2
100.0
95.8
100.0

104.5
106.5
97.5
93.5
101.4

+2
+3
+3
+3
+2

St.
Unchanged
Tacky

+2.12
-0.39
-I-2.49
+3.77
+2.51
+2.38
+13.1

97.0
98.2
99.4
95.2
104.2
101.2
54.2

102.6
98.0
102.6
103.3
105.9
106.5
58.8

-3
-I-4
+1
-3
-3
-1
-13

Unchanged
Tacky
SI. Tacky
Unchanged
Unchanged
SI. Tacky
Unchanged

Ethylene

Oachlorlde

KETONES
Acetone

Mcthvl
Methyl

Ketone
lsobutyl
Ketone
EIhvl

DETERGENTS &OTHER
CLUNING PRODUCTS
Calgon1te (1%)
C1orox (1%)
Clorox (Cont.)
Joy (1%)
JOY (Cone )
LestoIl (1 a)
Lux Flakes (1%)
Rlnst Dry (1%)
Rinse Dry (Cont.)
Tide (1%)
NATURAL FATS L OILS
Buntr
Castor 011
Cononsetd 011
Lard
Oltomargarint
Olwt 011
Whltt Mmtral 011

Tacky

OILS
FUELS
A.S.T.M.
1 011
No. 2
A.S.T.M. No. 011
A T.M. Fuel
A.S.T.M Fuel
A.S.T.M. Fuel
Heating Fuel
Jet Aircraft
Oil
Ktrosmt

+9.10
+9.88
+39.4
+84.2
+ 143.8
+155.6
+59.6
+ 17.2
+163.0

83.1
81.9
47.0
27.1
22.3
21.7
25.3
86.1
25.9

88.8
84.3
44.5
23.5
20.2
19.0
23.0
100.6
21.6

-5
-6
-19
-27
-31
-31
-31
-13
-32

SI. Tacky
SI. Tacky
Unchanged
Unchanged
Unchangtd
Unchanged
Unchangtd
SI. Tacky
Unchanged

AUTOMOTIVE PRODUCTS
Chassis Grease
Motor 011 ( 1OW 30)
Gasohne (RON 94)
Gasoltnt (RON 99)
Gasollnt (RON 102)
Gasolvw. unleaded

+13.3
+21.8
+137.9
+145.7
+15B.4
+181.6

75.9
50.6
23.5
21.1
22.3
23.5

77.8
51.0
19.6
19.6
21.0
20.2

-7
-18
-31
-31
-31
-31

Sl. Tacky
Unchanged
Unchanged
Unchanged
Unchangtd
Unchanged

(continued)

308

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

One Month lmmcrsion at 75O -C 5OF


volume
Chanrm %

TensileStrength Elongation
Retained K

Ratained K

Hardness
Chanee Pts.

Surface
Condition

HYDRAULIC FLUIDS

Oron1tc
8200
Pydraul F.9
Pydraul 60

+2.81
+3.97
-3.04

101.8
103.0
105.4

loo.0
103.3
104.5

-1
-1
+2

Unchanged
SI. Tacky
SI. Tacky

Skydrol

+1.01

112.1

111.2

-2

St. Tacky

Skydrol 500

+0.54

107.2

108.4

-2

Sf. Tacky

+1.24
+0.23
+6.44
+o.!X
+0.73

99.4
96.4
93.4
98.8
98.2

96.7
96.1
85.7
100.0
97.5

+3
+2
+1
+3
+4

SI. Tacky
SI. Tacky
SI. Tacky
SI. Tacky
Unchanged

MISCELLANEOUS
Gelatin (sat. soln.)
Glucose (sat. soln.)
Tincture of Iodine
Prestonc antifreeze
Dowgard antifreeze

Three Months lmmcrsion at 7S = 5OF

WATER
Distilled Water
Saa Water--Atlantic
Sea Water-Pacific

volume
Challm n

Tensfle strength
Retained %

Elongatfm
Retained %

+0.11
.+0.32
i-o.37

103.0
102.4
98.8

loo.0
101.4
96.1

+3
+3
+2

SI. Tacky
Unchanged
SI. Tacky
SI. Tacky

Hardness
Change Pts.

Surface
Condition

INORGANIC ACIDS
Boric Acid (10%)
Chlorosulfonic Acid (10%)
Chromic Acid (10%)
Chromic Acid (Cow.)

-0.11
Disintegrated
+6.52
i-47.4

94.0.

93.5

+2

80.7
1.8

88.8
13.5

-2
-33

Hydrochloric Acid (10%)


Hydrochloric Acid (Cont.)
Hydrofluoric Acid (Cont.)
Nitric Acid (10%)
Nitric Acid (Cont.)

-0.65
+11.8
+1.42
+0.88
Disintegrated

95.2
77.7
98.8
96.4

97.5
115.7
98.6
95.5

+3
-3
-2
0

SI. Tacky
Sl. Tacky
Unchanged
Tacky

100.0

99.4

+3

SI. Tacky

98.2

96.1

+4

SI. Tacky

-l-2.42
i-2.88
+1.21
+0.93

108.4
109.0
98.8
101.2

102.0
102.6
93.5
101.4

+3
-2
f4
+3

SI. Tacky
SI. Tacky
Unchanged
Unchanned

0.00
+0.23
+0.55

102.4
98.8
104.2

99.4
95.5
98.6

+3
+2
-2

Unchanged
Unchanged
Unchanged

Aluminum Chloride
Aluminum Sulfate
Ammonium Chloride
Ammonium Nitrate
Ammonium Phosphate

-0.12
+0.13
-0.24
-0.13
-0.13

99.4
102.4
98.2
98.8
96.4

94.1
101.4
98.0
101.4
98.6

+3
+3
+4
+3
+5

Sf. Tacky
Unchanged
Unchanged
Sf. Tacky
St. Tacky

Barium Chloride
Barium Sulfide
Calcium Chloride
Calcium Hypochlorite

-1.30
-0.91
+0.36
+1.09

97.0
99.4
98.8
98.8

96.1
96.1
96.1
98.0

+4
+3
+4
+3

Unchanged
Unchanged
Unchanged
Unchanged

Cupric Chloride
Cupric Sulfate
Ferric Chloride
Ferric Nitrate
Ferrous Sulfate

-1.13
+0.24
0.00
+0.68
+0.93

104.8
loo.0
97.6
102.4
97.6

102.5
101.4
96.1
100.6
96.1

+4
i-4
+6
+4
+3

Sf. Tacky
Unchanged
Sf. Tacky
Sl. Tacky
Unchanged

Magnesium Chloride
Magnesium Sulfate
Nickel Sulfate
Potassium Chloride
Potassium Permanganate

-0.26
+0.46
+0.33
-0.32
+2.90

97.6
103.0
103.6
98.8
78.9

97.5
94.7
103.3
99.4
77.1

i-4
+3
+4
+5
-3

Unchanged
Unchanged
Unchanged
Unchanged
Brittfe

Phosphoric Acid (Cont.)


Sulfuric Acid (10%)
Sulfuric Acid (Cont.)
INORGANIC BASES
Ammonium Hydroxide (10%)
Ammonium Hydroxide (Cow)
Barium Hydroxide (Cont.)
Calcium Hydroxide (10%)
Potassium Hydroxide (10%)
Sodium Hydroxide (10%)
Sodium Hydroxide (Cow.)

+0.11
+0.74
Disintegrated

Unchanged
V. Tacky

INORGANIC SALTS (25% Solutions)

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

Three
Vdume
Change
Potassium

Elsulflte

Potassium

Dlchromate

+2.29
0.00

(Borax)

Tensik
x

Strength

Retained

CHEMICALS

Months

immersion

(continued)

at 75O -

Elongation
Retained

and Elastomers

5F

Hardness
%

Change

Surface
Pts.

Condition

106.6

107.8

+1

Unchanged

101.2

100.0

+4

Unchanged

Sodium

Borate

97.5

+4

Unchanged

Sodium

Bicarbonate

-0.12

loo.0

98.0

+4

Unchanged

Sodturn

Chlwde

-0.49

100.0

98.6

+5

Unchanged

-0.12

97.0

98.0

+5

St. Tacky

97.6

96.7

+5

St. Tacky

0.00

21nc ChlorvJe
210~ NItrate

0.00

ORGANIC

96.4

ACIDS

AcetIc

Acid (10%)

+2.58

99.4

102.6

AcetIc

Acld (Glacial)

+8.20

89.2

101.0

-9

SI. Tacky

+3.34

107.8

99.4

+2

SI. Tacky
SI. Tacky

Chloracetlc
Citric

Acid (10%)

Acid (10%)

Formic

0.00

Acid (10%)

Lactic

Acld (10%)

Ole~c Actid (100%)


Oxalic

98.8

100.0

+3

103.0

loo.0

+3

SI

+0.68

100.0

+3

SI. Tacky

98.0

48.8

59.4

101.2

98.0

+3

SI. Tacky
SI

+2.97

107.8

111.2

-3

Phenol

(100%)

+8.26

104.2

119.0

-17

Acid (10%)

+0.81

Acid (100%)

Tanmc

Acid (10%)

Tartax

+13.9
0.00

Acld (10%)

97.6

94.7

Unchanged

-26

(10%)

Steanc

Tacky

+0.35

Phenol

PWXIC

SI. Tacky

+I.76
+90.3

Acid (10%)

Tacky

SI. Tacky

+1

St. Tacky

106.6

107.8

-2

Unchanged

102.4

101.4

+2

St. Tacky

-0.12

93.4

90.2

+3

SI. Tacky

-0.96

100.0

98.6

-4

SI. Tacky

97.6

100.6

-1

SI. Tacky

+0.36

97.6

100.0

-1

-0.36

92.7

90.8

-0.37

92.8

94.1

-0.25
+7.24
+0.76

100.0
86.8
loo.7

94.1
97.5
98.6

+9.66

91.6

100.9

-17

SI. Tacky

57.8

78.4

-18

SI. Tacky

105.4

103.9

-7

SI. Tackv

95.2

101.9

ALCOHOLS
Benryl

Alcohol

Ethyl

Alcohol

Isopropyl
Methyl

0.00

Alcohol
Alcohol

Ethylene

Glycol

Glycerol
1 -Hexanol
ReSoWlnOl

St. Tacky
0

+3

+5
-11
+3

Sl. Tacky
St. Tacky

Sl. Tacky
Tacky

Sl. Tacky

ALDEHYDES
Benzaldehyde
Butyraldehyde

+21.7

Furfural

-l-2.57

AMINES
Aniline

+11.8

-13

Sl. Tacky

Trlethanolamine

+0.57

101.2

99.4

UDMH

+7.90

57.2

74.5

-12

UnChanRed

-l-47.2
+23.5
+5.36
+10.9
+0.75

40.4
89.8
106.0
78.9
102.4

103.3

+11.6
+2.56
+57.4

103.0

107.8

-13

107.8

113.1

-7

St. Tacky

30.1

32.8

-25

Unchanged

97.0

98.0

-5

s1. Tacky

+3

Unchanged

ESTERS
Amy1 Acetate
Dlbutyl

Sebacate

Dwtyl

Phthalate

Ethyl

Acetate

Tricresyl

Phosphate

47.7

-22

Unchanged

103.3

-17

Unchanged

107.8

-3

SI. Tacky

88.2

-12

St. Tacky

+3

Sl. Tacky

ETHERS
Dibenzyl

Ether

Ditthyltne
Ethvl

Glycd

Monobutyl

Ether

Ether

Ethilent

Glycol

Monoethyl

Ether

+2.05

Unchanged

HYDROCARBONS
Benztne

+101.9

25.9

25.5

-28

Unchanged

Cvclohtxant

+230.2

21.7

17.7

-28

Unchanged

Ethylbenzene

+176.0

19.3

20.2

-31

g.

Heptone

+178.0

23.5

20.9

-28

Sl. Trky

Htxtnt

+169.0

Tacky

22.9

22.6

-27

+50.4

89.8

00.4

-7

SI. Tacky

Toluenc

+114.8

23.5

22.9

-29

SI. Tacky

Xylenc

+154.5

22.3

21.0

-30

St. Tacky

Naphthaltne

Y.

Tacky

(continued)

309

310

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Three Montlta Immersion at 75O 2 5OF

1-w
R8tdlled%

-w~InedW

Hardness
Chan8a Fts.

surface
Condition

HALDGENATED HYDROCARBONS
Benzyl Chloride
Bromobcnrtnt
Carbon Tttrachloridt
Chloroform
Ethylene Dwzhloridt
Ptrchlorotthyltnt

+25.1
+114.4
+199.5
+137.7
+25.2
+212.4

57.8
24.7
20.5
la7
48.8
la7

79.8
25.5
17.7
20.2
60.2
15.7

-20
-32
-31
-30
-18
-30

SI. Tacky
SI. Tacky
Unchanged
SI: Tacky
SI. Tacky
SI. Tacky

OTHER SUBSTITUTED
HYDROCARBONS
Carbon Dmlfedt
Nmobtnztnt

+183.4
-l-4.77

19.3
86.1

20.2
98.6

-30
-12

SI. Tacky
SI. Tacky

KETONES
Acetone
Methyl Ethyl Ketone
Methyl lsobutyl Ketone

+6.14
+19.7
+22.2

89.2
86.8
56.0

97.5
94.1
70.0

-9
-12
-17

SI. Tacky
Unchanged
SI. Tacky

DETERGENTSaOTHER
CLEANING PRODUCTS
Calgonltt (1%)

+0.50

98.8

+1.28
+1.48
+0.63
-11.32

101.2
106.0
96.7
98.8

103.3
103.9
103.9
98.0
102.6

+3
+2
-1
+3
fl

Unchanged
SI. Tacky
Tacky
SI. Tacky
Tacky

+2.74
+0.71
+0.72
-0.36
+0.65

102.4
98.8
95.2
93.4
101.2

105.9
97.5
96.6
96.6
103.3

-1
+2
+2
+3
-2

SI. Tacky
Unchanged
SI. Tacky
SI. Tacky
SI. Tacky

+8.92
-0.65
+5.18
+7.OO
+6.52
+7.87
+53.6

101.2
95.2
95.8
97.0
106.6
94.8
41.0

102.0
94.1
100.6
103.3
106.5
100.6
42.6

-7
-4
-6
-4
-3
-7
-26

Unchanged
SI. Tacky
SI. Tacky
Unchanged
SI. Tacky
SI. Tacky
Unchanged

Clorox (1%)
Cloror (COOC.)
JOY (1%)
Joy (Cone )
LestoIl (1%)
Lux Flakes (1%)
Ruvt Dry (1%)
Rinse Dry (Cont.)
Tide (1%)
NATURAL FATS & OILS
Butter
Castor OrI

Cononsetd011
Lard
Oltomargarine

Olwt 011
White Mmtral Ott
OILS & FUELS
A.S.T.M. No. 1 Oil
A.S.T.M. No. 2 011
A.S.T.M. No. 3 011
A.S.T.M. Fuel A
A S.T M. Fuel B
A.S.T M. Futl C
Htatmg Fuel 011
Jet Awcraft Engine Oil
Ktrosint

+20.0
+lB.9
+ 103.2
+162.9
+185.5
+ 197.8
+190.0
+27.0
+ 197.2

74.1
74.1
34.9
25.9
22.3
22.3
22.9
66.9
22.3

82.9
78.4
33.9
24.2
21.6
21.6
22.2
88.2
21.6

-8
-9
-27
-28
-29
-30
-32
-19
-31

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged
Sl. Tacky
Unchanged
Unchanged
Unchanged

AUTOMOTIVE PRODUCTS
Chassis Grease
Motor 011 (low 30)
Gasohnt (RON 94)
Gasoline (RON 99)
Gasolmt (RON 102)
Gasoline.* unltsdtd

+19.8
+93.0
+189.0
+ 182.4
+189.6
+ 196.9

54.4
37.8
21.7
21.1
19.9
20.5

59.4
39.2
20.2
22.2
21.0
20.2

-13
-37
-31
-31
-32
-32

SI. Tacky
Unchanged
Sl. Tacky
SI. Tacky
SI. Tacky
Sl. Tacks

-2
-4
-3
-3
-3

Unchanged
SI. Tacky
SI. Tacky
SI. Tacky
Si. Tackv

HYDRAULIC FLUIDS
Oronttt 8200
Pydraul F-9
Pydraul 60
Skydrol
Skvdrol 500

+4.56
+6.08
+1.39
+4.32
+1.67

97.0
107.8
106.0
1102
112.0

99.4
112.3
105.9
105.3
109.8

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMlCALS

311

(continued)

Three Months Immersion Jt X0 2 5iF


Vdwm
CftJrrwx
MISCELLANEOUS
GJlJtln (SJt Soln.)
Glucose (sat soln.)
Tincture of Iodine
Prestone antifreeze
DOwgIrd JntifrJJZJ

TJmitJSbmngth
R~bined K

DJngJtknl
Retained%

101.2
100.0
78.9
101.2
97.6

104.9
95.5
66.1
loo.0
95.5

0.00
+0.23
+12.5
+1.44
+1.33

fbrdncss
ChJnp PLs.
+3
+3
-2
-1
+3

SUrfJcJ
bnditkm
Si. TJCky
Sf. TJCb
Unchanged
St. TJcky
UnChJngJd

Six Months Immersion at 75O 2 IoF


Vdume
Charwe%

fJ"SilJ Stmgth

HJrdness
Change Pts.

SWfJcC
Ccmdition

Retained K

ElcwlgJtion
RJtainJd SC

101.2
105.4
105.4

102.6
104.5
100.6

+4
+4
+3

Unchsnged
UnchJnged
Unchanged

98.8

103.3

+2

SI. Tacky

Chromic Acid (10%)


Chromic Acld (Cont.)

-0.23
Disintegrated
+12.4
+4a.3

66.9
2.41

77.8
9.8

-6
-27

Tacky
V. Tacky

Hydrochloric Acid (10%)


Hydrochloric Acid (Cont.)
Hydrofluoric Acld (Cont.)
Nitric Acid (10%)
Nitric Acid (Cont.)

-0.52
+8.52
+2.36
+1.13
Disintenrated

97.6
54.8
87.4
95.8

96.7
103.9
80.4
93.5

+2
-8
-2
+1

SI. Tacky
SI. Tacky
SI. Tacky
V. Tacky

Phosphoric Acid (Cont.)


Sulfuric Acid (10%)
Sulfuric Acld (Cont.)

+0.11
+0.61
DisintJgrJted

102.4
99.4

100.6
101.4

+3
+4

TJcky
Tacky

WATER
Distilled WJtJr
!$ZJ Water-AttJntlC
Sea Water-Pacific

+0.90
+0.32
+0.25

INORGANIC ACIDS
Boric Acid (10%)
Chlorosulfonic Acid (10%)

INORGANIC BASES
Ammonium Hydroxide (10%)
Ammomum Hydroxide (Cont.)
Barium Hydroxide (Cont.)
CJlcium Hydroxide (10%)

+4.61
+5.14
+0.89
+0.82

111.5
108.4
101.2
101.2

103.9
96.7
97.5
95.5

+2
-3
+4
+4

Unchanged
St. Tacky
Unchanged
Unchanged

Potrsswm Hydroxide (10%)


Sodium Hydroxide (10%)
Sodium Hydroxide (Cont.)

+0.68
+0.35
+1.33

101.2
109.6
106.6

96.7
97.5
100.6

+3
+3
-2

Unchanged
Unchanged
Unchanged

Aluminum SulfJte
Ammonium Chloride
Ammonium NitrJtJ
Ammonium Phosphate

+0.81
+1.21
-0.61
0.00
0.00

96.4
95.8
94.0
96.4
98.2

90.2
83.7
92.8
95.5
98.0

+2
+2
+3
+2
+3

Sl. TJcky
UnchJngJd
SI. Tacky
St. TJcky
St. TJC~~

SJrium Chloride
Barium Sulfide
CJlcium Chloride
CJlcium Hypochlorite

+0.47
+0.26
+1.45
+1.58

88.6
97.6
95.8
110.8

86.9
95.5
96.7
103.9

+3
+2
+2
-2

Unchrnged
UnChJngJd
UnchJngJd
St. TJC~~

Cupric Chlortdr
Cupric S,,ffJtJ
FJrric Chloride

-f-o.37
+0.84
+0.22

96.4
94.6
100.6

96.1
92.8
101.4

+2
+3
-l-3

St. Trky
UnChJngJd
UtWhJngJd

Ferric NitrJtJ
Ferrous SulfJtJ

+1.23
+1.16

100.0
98.8

99.4
96.1

+1
+2

T-=b
UnchJnged

MJgnJsium Chloride
MJgnesium Sulfite
Nickel SulfJte
PotJssium Chloride
PotJssium PermangJnJte

+0.26
+1.0)
+0.66
+oz?
+-a47

96.4
101.8
100.0
94.6
85.5

96.1
94.7
101.4
94.7
88.2

+3
+2
+2
+1
-2

UnchJnged
UrKhJngcd
UnchJngJd
Sl. Tacky
Brittle

PotJsswm Bisulflte
PotJsslum Dichromrte
Sodium Borate (8orrx)
SJdlUm 8iCJrbonJtJ
Sodwm Chlonde
Zmc Chlorde
2IK NltrJtJ

+5.51
+1.02
+0.85
i6.76
+D.25
+0.47
+0.36

111.5
96.4
94.0
96.4
94.6
94.6
101.8

108.4
95.5
96.1
93.5
95.5
92.2
103.3

-3
+3
+2
+2
+2
+3
+4

Unchrnged
UnChJngJd
UnchJngad
UtKhJngJd
St. Tacky
Sf. Trky
SI. Tuky

INORGANIC SALTS (25% Solutions)


Aluminum Chloride

(continued)

312

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

Six Months Immersion


VdunW
ww

ORGANIC ACIDS
Acetic Acid (10%)
Acetic Acid (Glacial)
Chloracetic Acid (10%)
Citric Acid (10%)
Formic Acid (10%)
Lactic Acid (10%)
Oleic Acid (100%)
Oxalic Acid (10%)
Phenol (10%)
Phenol (100%)

Robined%

RetahdW

2 VF
Hldll8SS

ChangePts.

surfra

Condition

101.4
96.1
103.9
92.2
101.4
99.4
57.5

+1
-9
+2
+5
+3
+3
-26

Sl. Tacky
Sl. Tacky
Sl. Tacky
SI. Tacky
SL Tacky
Sl. Tacky
Unchanged

101.2
108.4
105.4
106.0
101.8
100.6
98.8

102.6
109.8
113.7
104.5
101.4
97.5
98.0

+3
-7
-15
+2
-2
+3
+3

SI. Tacky
SI. Tacky
Sl. Tacky
Sl. Tacky
Unchanged
Sl. Tacky
Sl. Tacky

+1.19
-0.24

104.8
89.8
89.2
97.0
92.8

103.9
96.7
90.8
loo.0
90.2

-6
-2
-6
-1
+4

SI. Tacky
St. Tacky
SI. Tacky
SI. Tacky
Sl. Tacky

0.00

Unchanged

+4.00
+0.38
+3.14
+0.68
+93.9
+1.15
+5.69
+6.16
+3.34
+17.9

Tannic Acid (10%)


Tartaric Acid (10%)

+0.65
+0.60

Glycerol

at 7S

Elongation

104.2
07.4
114.5
98.2
103.0
101.8
43.4

+4.58
+a.44

Picric Acid (10%)


Stearic Acid (100%)

ALCOHOLS
Bcnzyl Alcohol
Ethyl Alcohol
Isopropyl Alcohol
Methyl Alcohol
Ethylene Glycd

TensileStrength

(continued)

+3.70
+0.51
+1.23

95.8

89.6

+3

+6.92
+2.46

91.6
97.0

102.0
93.5

-10
+2

Tacky
St. Tacky

Bsnzaldehyde
Butyraldehyde
Fur(ural

+7.10
+21.6
+2.83

86.1
99.4
108.4

94.1
103.9
106.5

-13
-18
-8

SI. Tacky
Unchanged
TsClcy

AMINES
Aniline
Triethanolamine
UOMH

+10.6
+2.38
+4.89

98.8
97.0
51.2

103.9
88.2
66.7

-14
+3
-9

Sl. Tacky
St. Tacky
Sl. Tacky

ESTERS
Amy1 Acetate
Dibutyl Ssbacate
Dioctyl Phthalate
Ethyl Acetate

+45.6
+21.6
+6.14
+11.8

42.2
93.4
109.6
81.3

51.6
lD4.5
117.6
90.8

-23
-18
-7
-12

Unchanged
Unchanged
Si. Tacky
Unchanged

+0.87

105.4

104.5

+2

+9.92
+3.71
+52.6
-l-3.33

108.4
102.4
29.5
101.2

101.1
105.3
33.9
101.4

-13
-9
-35
-7

Unchanged
Unchanged
Unchanged
9. Tacky

27.1
22.3
20.4

29.4
17.7
21.6

-30
-31
-31

Unchanged
St. Tacky
Unchanged

l-Hexand
Rcsorcinol
ALOEHYDES

Tricresyl Phosphatr
EIHERS
Olbenzyl Ether
Diethylena Glycoi Monobutyl Ether
Ethyl Ether
Ethylene Glycol Monoethyl Ether
HYDROCARBONS
8eruene
Cyclohexane
Ethylbenzene

+112.2
+205.9
+140.0

Tacky

Heptane

+141.2

25.3

22.9

-28

Sl. TIJly

Hexarm
Naphthalene

+129.3
+41.8

21.7
81.3

21.0
77.1

-28
+2

Tacky
SI. Tacky

Tduene
XylWN

+139.5
+1642

21.7
21.7

22.2
21.0

-32
-31

Tacky
Sl. Tacky

HALOGENATEO WYOROCAR8ONS
Eenzyl Chloride
Bromobeozene
Carbon Tetrachloride
Chloroform
Ethylene Dxhloride
Perchloroethylene

+27.3
+115.6
+213.3
+170.1
+26.7
+220.0

57.3
24.7
21.7
19.9
56.0
19.9

78.4
26.1
19.0
21.0
70.6
18.2

-21
-32
-31
-32
-18
-33

Tacky
SJ. Tacky
Unchanged
Sk Tacky
SI. Tacky
Unchanged

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

313

(continued)

Six Months Immersion Jt 75 = 5F


lmsile Stnmgth
RetJined SC

Elongation
Retained K

+118.D
+4.59

21.7
103.0

20.2
104.5

-30
-9

St. TJCky
Tacky

Methit lsobutyl Ketone

+5.29
+9.22
+22.4

84.3
82.5
59.6

89.6
86.9
74.5

-8
-11
-16

Unchanged
St. Tacky
SI. Tacky

DETERGENTS&OTHER
CLUNING PRODUCTS
Calgonlte (1%)
Cloror (1%)
Cloror (Cow)
JO 11%)
Joy (Cone )

i-O.88
+2.43
+1.85
+1.79
-11.3

106.6
107.2
108.4
104.2
98.8

105.9
100.6
105.3
104.5
98.0

+5
+3
+2

+2.86
+1.30
+1.20
-0.50
+0.92

104.2
104.2
95.2
100.0
97.6

102.5
102.5
95.5
96.1
96.7

+2
+3
+3
+3
+3

SI. Tacky
Unchanged
SI. TJcky
Si. Tacky
SI. Tacky

+ 12.6
-D.92
+6.41
+11.8
+8.06
+12.0
+95.1

105.4
96.4
106.6
106.6
107.8
99.4
36.8

104.5
95.5
107.8
109.2
107.8
105.9
33.3

-12
+3
-4
-11
-7
-12
-26

Unchanged
Tacky
SI. Tacky
Unchanged
Unchanged
SI Tacky
SI. Tacky

56.0
54.2
30.1
23.5
20.5
19.9
20.5
60.8
22.3

67.3
63.3
28.8
23.5
21.6
21.6
21.0
84.3
21.6

-16
-17
-30
-28
-33
-32
-32
-21
-32

Unchanged
Unchanged
Unchanged
Unchanged
SI. Tacky
SI. Tacky
Unchanged
Unchanged

50.0
31.9
19.9
18.7
16.9
21.1

52.0
32.8
21.6
21.6
20.2
21.0

-21
-31
-32
-33
-33
-32

SI. Tacky
Unchanged
SI. Tacky
SI. Tacky
SI. Tacky
SI. Tacky

VOlUmC
ChJnmu
OTHfR

HJblJJJ

Ch~nnJ Pts.

SWfJCJ

Condition

SU8STITUTEo

HYORDCARBONS

Carbon Dlsulflde
Nllrobenzcne
KETONES
Acctonc
Methyl Ethyl Ketone

LestoIl (1X)
Lux Flakes (1%)
Rlnre Dry (1%)
Rlnre Dry (Cow )
Tide (1%)
NATURAL FATS L OILS
Butter
CJStOr 011
CoItonsud 011
Lard
Oleomargarine
OIIVC 011
White MlnerJl 011
OILS L FUELS
A.S.T.M No. 1 Oil
A S T.M No. 2 011
A S T.M No. 3 011
ASTM
FuelA
A.5 T.M. Fuel 8
A.S T.M Fuel C
Heating Fuel 011
Jet Atfcr~fi Engcne 011
Kcros~ne
AUTOMDTIVC PRODUCTS
Chassrs Grease
Motor 011 (lOW.30)

t30.8

+34.6
t 146.5
t-161.5
t189.7
t200.9
t 195.0
t41.7
t211.2

t38.0

t3

+3

SI.
SI.
Sl.
SI.
Sl.

Tacky
Tacky
Tacky
Tacky
Tack;

Unchanged

(RON 102)
GJsohne:* unleaded

t118.4
+192.5
+1?6.9
+192.0
+201.9

HYDRAULIC FLUIDS
Orontite 8200
edrJul F.9
Fydraul 60
Skydrol
Skvdrol 500

+11.6
+7.89
t2.01
+4.98
+3.24

99.4
112.7
101.2
106.0
103.6

104.5
115.1
103.3
108.4
105.9

-7
-7
-3
-8
-6

Unchanged
SI. Tacky
SI. Tacky
SI. Tacky
SI. Tacky

MISCELIANEOUS
Gelatin (sat. soln.)
Glucose (sat. soln.)
Tincture of Iodine
Prestone Jntitreeze
Dowgard Jntifreeze

+1.86
+0.23
+16.2
+I.67
to.39

98.8
98.8
53.6
99.4
94.8

96.1
94.1
40.6
100.0
92.8

+2
+3
-5
0

St. TJC@
Tacky
Unchanged
Unchanged
Unchanged

GJSOIWW

(RON

94)

GJSO~IIW

(RON

99)

GJSO~IW

t3

(continued)

314

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

12 Months Immersion at 7S = 5F
volume
Chena K
WATER
Distilled Water
Sea Wlter-Atlantic
Sea Water-Pecifii

-l-O.78
+0.43
-0.25

INORGANIC ACIDS
Boric Acid (10%)
Chlorosulfonic Acid (10%)
Chromic Acid (10%)
Chromic Acid (Cont.)

-1.95
Disintegrated
+20.2
f49.6

Hydrochloric Acid (10%)


Hydrochloric Acid (Cont.)
Hydrofluoric Acid (Cont.)
Nitric Acld (10%)
Nitric Acid (Co&)

+0.37
+11.2
+2.18
+1.6f
Disintegrated

Phosphoric Acid (Cont.)


Sulfuric Acid (10%)
Sulfuric Acid (Cont.)

+0.11
-0.12
Disintegrated

Elongatii
Retained%

95.2
100.6
98.8

96.1
102.5
96.1

+3
+4
+4

Unchanged
Unchanged
Unchanged

106.5

+3

Tacky

98.8
56.6
5.42
104.8
56.0
90.4
101.2
98.8
95.2

Hardness
ChannePts.

Surface
Condition

Tensik sbmgth
Retained w

-10
-21

Tacky
V. Tacky

102.0
88.8
67.2
101.4

+2
-11
0
0

Tacky
SI. Tacky
SI. Tacky
V. Tackv

101.4
95.5

+3
+4

Tacky
Tacky

77.8
12.3

INORGANIC BASES
Ammomum Hydroxbdc (10%)
Ammomum Hydroxide (Cope.)
Barwm Hydroxide (Cont.)
Calcium Hydroxide (10%)

-l-5.88
+7.39
+1.02
+1.05

106.0
101.2
100.6
96.4

96.1
89.6
99.4
98.6

-1
-3
i-3
f3

Unchanged
SI. Tacky
Unchanged
Unchanned

Potassium Hydroxide (10%)


Sodium Hydroxide (10%)
Sodium Hydroxide (Cont.)

+0.23
+0.93
+1.77

100.0
104.8
104.8

96.1
99.4
101.4

+3
+1
-4

Unchanged
Unchanged
Unchanged

Aluminum Sulfate
Ammomum Chloride
Ammonium N&rate
Ammomum Phosphate

+0.34
+1.34
+0.12
+0.13
+1.03

98.2
103.6
95.2
98.2
101.8

97.5
105.3
99.4
99.4
103.9

+2
+3
+3
+3
+3

St. Tacky
Unchanged
SI. Tacky
SI. Tacky
Sl. Tacky

Barwm Chloride
Barium Sulfide
Calcium Chloride
Calcwm Hypochlorite

+0.47
+0.51
+1.55
+1.82

104.8
98.2
95.8
107.8

105.9
91.6
94.1
107.8

+4
+2
+1
-1

Unchanged
Unchanged
Unchanged
Sl. Tacky

Cupric Chloride
Cupric Sulfate
Ferric Chloride
Ferric Nitrate
Ferrous Sulfate

+0.13
+1.80
+0.44
+1.25
+0.81

94.0
96.4
98.8
93.4
97.0

96.1
99.4
98.0
98.0
95.5

+4
+4
+3
+1
+3

St. Tacky
Unchanged
Unchanged
Tacky
Unchanged

Magnesium Chloride
Magnesium Sulfate
Nickel Sulfate
Potassium Chloride
Potassium Permanganate

+0.38
+0.69
+0.11
+0.56
+a.34

94.0
94.6
94.6
98.8
80.7

96.7
96.7
99.4
100.0
87.7

+3
+4
+3
+1
-3

Unchanged
Unchanged
Unchanged
Unchanged
Brittle

Potassium Bisulfite
Potassium Dichromrte
Sodium Borate (Borax)
Sodium Bicarbonate
Sodwm Chloride
Zinc Chlor&
Zinc Nitrate

+7.80
+0.63
+0.73
+0.12
-0.99
+0.23
+0.24

102.0
99.4
103.9
100.0
96.7
100.0
94.7

-4
+3
+3
+2
+3
+3
+4

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged
St. Tacky
St. Tacky

ORGANIC ACIDS
Acetic Acid (10%)
Acetlc Acid (Glacial)
Chloracetlc Acid (10%)
Citric Acid (10%)
Fonmc Acid (10%)
Lactic Acid (10%)
Olelc Acid (100%)

+5.63
+10.7
+5.45
+0.38
+4.15
+0.45
+95.7

103.9
92.2
99.0
101.4
105.9
100.0
59.4

-1
-9
-1
+3
+2
+2
-27

SI. Tacky
SI Tacky
Sl. Tacky
SI. Tacky
Sf. Tacky
Sl. Tacky
Unchanged

INDRCANIC SALTS (25% Solutions)


Alummum Chloride

113.3
98.8
100.6
98.8
93.4
98.2
93.4

103.0
88.6
133.1
98.8
107.2
98.8
45.8

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

315

(continued)

12 Months immersion at 75O 2 5F


Hardness
ChanPcPts.

surface
Condition

VolUmC
charwe x

TenaifeSbangth
Retained K

Elongation
Retained%

+0.12
+7.35
+4.50
+2.07
+18.6
+1.05
+1.08

105.4
115.1
98.8
101.2
108.4
100.0
100.6

104.9
112.4
109.8
99.4
108.4
96.1
103.9

+4
-11
-14
+2
+2
-1
+3

Sl Tacky
SI. Tacky
Sl. Tacky
SI. Tacky
Unchanged
Sl Tacky
Tacky

+2.79
+0.89
+1.53
+1.64
-0.36

104.8
94.0
92.2
97.6
94.6

103.9
96.1
96.1
96.1
92.2

-8
-2
-2
-2
f4

SJ. Tacky
Si. Tacky
SI. Tacky
SI. Tacky
SI. Taccky

Rtsorclool

+1.26
+6.60
+12.0

95.2
84.3
108.4

89.6
96.7
99.4

+2
-11
+1

Unchanged
Sl. Tacky
SI Tacky

ALDLHYDES
Benzaldthyde
Butyraldchydt
Furfural

+7.28
+17.4
+5.34

92.2
91.6
103.6

98.6
102.6
103.3

-13
-18
-9

SI. Tacky
Unchanged
Tacky

98.8
94.0
58.4

103.9
90.2
77.8

-13
+3
-9

Unchanged
SI. Tacky
Unchanged

Oxalc Acld (10%)


Phenol (10%)
Phenol (100%)
PICNICAcid (10%)
Stcarx Acid (100%)
Tannx Acid (10%)
Tartarlc Actd (10%)
ALCOHOLS
&nzyl Alcohol
Ethyl Alcohol
lsoprowl Alcohol
Methyl Alcohol
Ethylene Glycol
Glyctrd

1 -Htranol

AMINES
Antlmt
Trwthanolammt
UDMH

-l-7.33
-l-o.77
+7.00

ESTERS
Amy1 Acetate
Dlbutyl Sabacate
01octyl Phthalatt
Ethyl Acetate
Tricrtsyl Phosphate

+45.7
+19.3
+9.13
+8.75
+0.49

39.8
85.5
104.8
78.3
101.8

48.4
103.3
109.2
88.2
102.6

-24
-17
-12
-12
+2

Unchanged
Unchanged
SI. Tacky
Unchanged
Tacky

nlims
D~btnryl Ether
D+tthyltnt Glycol Monobutyl Ether
Ethyl Ether
Ethylene Glycol Monoethyl Ether

+9.56
+3.85
+60.2
+4.35

106.6
96.4
31.3
101.2

103.9
106.5
35.3
103.9

-13
-10
-27
-7

Unchanged
Unchanged
Unchanged
SI. Tacky

+84.0
+218.5
-f-142.9

20.5
16.3
21.7

26.9
17.1
24.9

-30
-32
-32

Unchanged
Sl Tacky
Unchanced

Xyltnt

+142.0
+125.5
+41.9
+128.5
+142.5

19.3
21.1
89.2
18.7
19.9

21.0
23.5
79.0
26.1
21.6

-30
-28
+2
-31
-31

HALDGENATED HYDROCARBONS
Btnryl Chlonde
Bromobenrcne
Carbon Tttrachloridt
Chloroform
Ethylene D&chloride
Pcrchlorotthvltne

+26.1
+118.0
+207.1
+169.5
+25.8
+200.5

56.0
22.9
19.9
19.3
52.4
16.3

79.8
26.1
19.6
22.2
62.7
18.2

-21
-32
-32
-33
-18
-33

T=ky
St. Tacky
Unchanged
!X Tacky
SI. Tacky
Unchanged

HYDRDCARBDNS
8tnzent
Cyclohcxant
Ethvlbtnztnt
Htptant
Htrant
Naphthalane
Tdutnt

!X
Sl.
St.
Sl.
Sl.

Tacky
Tacky
Tacky
Tacky
Tacky

OTHER SUBSTITUTED
HYDRDCAR8ONS
Carbon Disulfidt
Nltrobtnrene

+87.0
+3.36

16.9
94.6

21.0
101.4

-31
-11

Sl. Tacky
TabV

KETONES
Acetone
Methyl Ethyl Ketone
Methyl lsobutvl Ketone

+6.07
+8.60
+22.0

86.7
83.1
56.6

90.8
88.8
75.1

-8
-11
-17

SI. Tacky
Sl. Tacky
SI. Tacky

(continued)

316

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

12 Months Immersion at 75 2 SF
vohuna

liardness
ChangaPts.

+0.63
+2.30
+1.85
+1.41
-10.6

102.4
106.0
109.6
98.2
97.0

103.9
103.9
107.8
105.3
98.0

+3
+2
+1
+2
+3

SI. Tacky
Unchanged
Unchanged
Sl. Tacky
SI. Tacky

+3.34
+1.53
+0.96
-0.74
+1.77

101.2
101.8
98.8
97.6
100.7

105.3
100.6
105.3
98.0
99.0

-1
+3
+3
+4
+3

SI. Tacky
Unchanged
Unchanged
St. Tack-y
TaCkY

+28.4
-1.31
+11.1
+17.8
+27.9
+18.3
+108.5

88.6
98.2
116.9
99.4
101.2
101.2
34.3

100.0
103.3
115.1
109.2
105.3
107.8
38.6

-16
+3
-13
-13
-16
-14
-33

SI. Tacky
Tacky
SI. Tacky
Unchanged
Unchanged
Sl. Tacky
Sl. Tacky

Heatmg Fuel Oil


Jet Awcraft Engine Oil
Kerosmc

+45.8
+5D.6
+151.8
+128.4
+156.1
+ 140.0
+176.0
-l-44.7
+139.8

43.4
50.0
31.3
22.9
13.9
18.1
20.5
w.2
18.1

56.9
54.3
30.0
24.2
22.9
21.0
22.9
77.8
20.2

-23
-22
-32
-29
-32
-33
-33
-23
-32

Unchanged
Si. Tacky
Unchanged
Unchanged
St. Tacky
SL Tacky
Unchanged
Unchanged
Unchanged

AUTOMOTIVE PRODUCTS
Chassis Grease
Motor 011 (lOW.30)
Gasolmc (RON 94)
Gasolmc (RON 99)
Gasol~nc* (RON 102)
Gasoline. unleaded

+53.6
+ 149.8
+16D.9
+183.4
-l-203.7
+151.7

38.6
32.5
17.5
18.7
17.5
18.1

43.1
38.6
21.0
21.6
21.0
19.6

-26
-33
-34
-31
-36
-33

Unchanged
Unchanged
SI. Tacky
Sl. Tacky
SI. Tacky
Sl. Taskv

LestoIl (1%)
Lur Flakes (1%)
Rmre Dry (1%)
Rmse Dry (Cont.)
Tide (1%)
NATURAL FATS 6 OILS
Butter
Castor 011

Cononsced011
Lard
Oleomargarme
Olwe 011
While Mineral 011

sbwtgth

surfaa

Retained%

DETERGENTSLDTHER
CLEANING PRODUCTS
Calgonltc (1%)
Clorox (1%)
Clorox (COrlC.)
Joy (1%)
Joy (Cone )

Tamlk

Elongation

Ratainad
n

W%

ConditM

OILS 6 FUELS
A.S.T.M.
A S.T.M.
A.S.T M.
A S.T M.
A.S.T.M.
A.S T.M.

No. 1 011
No. 2 011
No. 3 011
Fuel A
Fuel 8
Fuel C

HYDRAULIC FLUIDS
Oronite 8200
Pydraul F.9
Pydraul 60
Skydrol
Skydrol 500

+13.7
+11.2
+6.70
+7.30
+3.37

101.8
103.0
104.8
106.6
110.2

104.5
110.4
106.5
110.4
110.4

-9
-10
-6
-7
-10

Unchanged
Tacky
Tacky
SI. Tacky
SI. Tackv

0.00

95.8

96.1

+2

+1.99
+19.4
+1.47
-0.79

98.8
53.0
96.4
94.0

94.7
41.2
99.4
97.5

MISCELLANEOUS
Gelatin (sat. soln.)
Glucose (sat. soln.)
Tincture of Iodine
Preston8 antifreeze
Dowgard antifreeze

lConvcntmnel motor fuels contaming tetraethyl lead eddihve. Approximab


**Motor fuel of premium grade containing no tatmethyl lead.

0
-5
-1
+3

Si. Tack-y
T=ky
Unchanged
St. Tacky
Unchanged

Research Octane Numbers Ind,ceted.

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS
CHEMICAL

ELASTOMERS
RESISTANCE

AND RUBBERS-EXXON

OF COMPOUND

CHEMICALS

317

(continued)

BASED ON LOW UNSATURATION

BU-I-YL RUBBER

72 Hours Immersion at 212OF


Hardness
Chanee Pts.

vulume
channc n

Tensite Strength
Retained K

Elongation
Retained K

+6.62
+11.0
+20.9
+1.20
+1.46

97.0
103.8
97.8
96.8
90.3

99.4
94.6
98.6
88.1
88.7

-14
-21
-27
+2
-3

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Ethyl Ether
Hexane
Hydrochloric Acid (10%)
Lard
Methyl Ethyl Ketone

+56.7
+147.9
+4.57
+36.2
+134

28.0
16.7
102.2
87.1
82.8

46.3
24.1
80.6
100.0
87.3

-28
-36
-4
-32
-20

SI. Tacky
SI. Tacky
Tacky
Unchanged
Unchanged

Perchloroethylene
Potassium Permanganate (25%)
Skydrol 500
Sudwm Chloride (25%)
Sodium Hydroxide (10%)

+339.1
+1.47
+13.8
+0.12
+2.67

64.5
94.1
86.6
101.1
102.7

17.7
79.9
96.2
87.0
94.1

-48
+2
-27
-1
-8

Tacky
Unchanged
Unchanged
Unchanged
Tacky

Toluene
Tide (1%)

+3D9.3
+1.27

69.9
90.9

26.9
87.3

-53

Unchanged
SI. Tacky

Aniline
Benraldchyde
Dioctyl Phthalate
Distilled Water
Ethyl Alcohol

Slll-faCe
Condition

One Month Immersion at 75O -C 5OF


vuhmn
Change K

Tensile Strength
Retained K

Elongation
Retained K

+10.0
+6.22
+3.09
-0.71
+0.36

112.9
110.2
104.8
95.2
90.3

103.3
110.8
103.7
94.3
96.2

-13
-17
-1
+4
+2

Ethyl Ether
Hexane
Hydrochloric Acid (10%)
Lard
Methyl Ethyl Ketone

+61.4
$166.9
-0.38
+4.02
+10.1

26.9
21.0
105.9
105.4
91.4

51.9
27.9
99.4
105.7
93.8

-29
-33
+3
-4
-16

Perchloroethylene
Potassrum Permanganate (25%)
Skydrol 500
Sodium Chlorrde (25%)
Sodwm Hydroxrdc (10%)

+251.5
+0.38
+1.89
-0.12
-0.12

14.5
88.7
104.3
98.4
184.3

18.4
84.9
99.4
95.2
96.6

-37
+5
-4
+2
+5

Tacky
Brittle
SI. Tacky
Unchanged
Unchanged

Tduenc
Trde (1%)

+171.6
0.00

16.1
99.5

25.5
99.0

-36
+6

TKky
T=ky

Anilme
Benxaldehyde
Dioctyl Phthalate
Distilled Water
Ethyl Alcohol

Hardness
Change PCs.

Surtace
Cundiiiun
Tacky
Tacky
Tacky
Unchanged
Tacky
SI.
SI.
SI.
Sl.
SI.

Tacky
Tacky
Tacky
Tacky
Tacky

Three Months immersion at 75O f IoF


VOtUme
Ct=W%
Aniline
Benraldehyde
Dioctyl Phthalatc
Distilled Water
Ethyl Alcohol

+9.00
+6.74
+5.06
-0.83
+0.11

Tensile Stmngttt
Retainad %

Elongation
Retained%

98.4
103.8
100.0
109.7
90.3

101.4
97.2
99.0
99.0
97.2

-12
-17
-7
+5
-1

SI. Tacky
Tacky
Tacky
Unchanged
Unchanged

Hardness
ChangePts.

Swface
Condition

Ethyl Ether
Hexane
Hydr&hloric Acid (10%)
Lard
Methyl Ethyl Ketone

+57.5
+X2.4
+0.38
+9.72
+7.55

31.2
18.3
98.4
111.3
93.6

50.5
25.9
97.6
103.3
94.3

-27
-32
+2
-8
-14

Unchanged
Sl. Tacky
Unchanged
Unchanged
St. Tacky

Perchloroethylene
Potasswm Permanganate (25%)
Skydrd 500
Sodium Chloride (25%)
Sodium Hydroxrde (10%)

+264.2
+4.30
+4.40
-0.97
+1.16

14.0
95.7
lM.8
101.1
97.3

19.4
89.1
101.4
94.8
96.6

-38
+5
-12
+6
+4

St. Tacky
Unchanged
Unchanged
Unchanged
Unchanged

Toluene
Trde (1%)

+187.4
0.00

17.2
102.2

27.3
98.6

-37
+2

T=ky
SI. Tacky

(continued)

318

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Six Months Immersion at 75O _C5OF


vokune
Change K

Tensile Strength
Retained K

Elongation
Retainad %

+4.15
+1.87
+8.42
-0.71
-0.24

103.8
97.9
102.2
101.1
89.3

100.0
99.4
99.4
96.2
97.6

-12
-15
-9
+4
-2

SI. Tacky
Tacky
Tacky
Unchanged
SI. Tackv

Aniline
Benzaldehyde
Dioctyl Phthalate
Distilled Water
Ethyl Alcohol

Hardness
Change PM.

Surface
Condition

Ethyl Ether
Hexane
Hydrochloric Acid (10%)
Lard
Methyl Ethyl Ketone

+54.5
+162.5
+0.38
+12.0
+8.65

33.3
18.8
100.0
116.1
91.9

48.5
26.9
88.7
101.8
91.5

-28
-36
+3
-16
-13

Unchanged
Tacky
Unchanged
SI. Tacky
SI. Tacky

Perchloroethylene
Potassium Permanganate (25%)
Skydrol 500
Sodium Chloride (25%)
Sodwm Hydroxide (10%)

+256.5
+7.06
+5.73
-!-0.24
+0.58

14.5
96.2
101.1
97.3
103.2

20.2
88.7
99.0
96.6
95.8

-39
-3
-13
+5
+4

Tacky
SI. Enttle
Unchanged
Unchanged
Unchanged

Toluene
Tide (1%)

+166.3
+0.37

18.3
103.8

-37
+3

T=ky
SI. Tacky

28.7
104.2

12 Months Immersion at 75 2 5OF


votume
Change W

Tensile Strength
Retained K

+6.00
+4.65
+11.6
+0.12
-I-o.97

96.2
97.9
102.7
102.2
93.6

100.4
98.6
112.7
99.7
100.0

-12
-15
-18
f3
-2

SI. Tacky
SI. Tacky
Tacky
Unchanged
St. Tacky

Andme
Benraldehyde
Omctyl Phthalate
Olstllled Water
Ethyl Alcohol

Elongation
Retained %

Hardness
Chanee Pts.

Surface
Condition

Ethyl Ether
Hexane
Hydrochloric Acld (10%)
Lard
Methyl
Ethyl Ketone

+48.8
+123.2
-0.13
+21.8
+7.93

29.0
15.1
104.3
111.3
100.5

46.3
28.7
97.6
103.3
92.9

-31
-37
+1
-23
-12

Unchanged
SI. Tacky
Unchanged
SI. Tacky
SI. Tackv

Perchloroethylene
Potaswum Permanganate (25%)

+262.1
+7.95
+4.81
-l-O.48
+0.81

15.1
89.3
101.6
96.8
100.0

18.8
87.7
99.4
97.2
94.8

-41
+4
-12
+2
+5

Tacky
SI. Brittle
Unchanged
Unchanged
Unchanged

i-131.9
+1.73

13.4
103.8

28.7
98.6

-38
+5

TafkV
SI. Tacky

Skydrol 500
Sodwm Chloride (25%)
Sodturn Hydroxide (10%)
--__
Toluene
Tide (1%)

CHEMICAL

RESISTANCE

OF CHLOROBUTYL

1066 COMPOUND

72 Hours Immersion at 212F


Vdume
Change W

Tensile Sbemzth
Retained 4

qongation
Ret&d
K

Hardness
Change Pts.

Surface
Condition

Aniline
A.S.T.M. No. 1 Oil
A.S.T.M. No. 3 Oil
Benzaldehyde
Oioctyl Phthalate

-l-7.86
+78.8
+168.1
+50.8
+29.0

95.0
47.0
28.3
67.2
75.3

93.4
62.8
51.1
57.2
68.9

-3
-27
-34
-14
-16

Unchanged
SI. Tacky
Sl. Tacky
SI. Tacky
Unchanged

Distilled Water
Ethyl Alcohol
Ethyl Ether
Cesoline (RON 99)
Hexane

+6.96
+4.92
+62.6
+167.1
+129.0

98.0
92.4
38.9
21.7
29.8

74.6
72.9
40.7
28.9
28.9

0
-1
-20
-34
-25

SI. Tacky
Unchanged
SI. Tacky
Unchanged
Unchanged

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganatu (25%)

+4.07
i-27.2
+19.9
+262.4
+2.59

102.0
78.3
61.6
18.7
97.0

84.0
67.5
61.2
21.9
72.9

fl
-16
-14
-33
+1

SI. Tacky
Unchanged
Unchanged
Unchanged
Unchanged

(continued)

Rubbws

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

and Elastomers

319

(continued)

72 Hours Immersion at 212OF


VOlUtVW

Shydml500
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Tolutnc
Tide (1%)
UDMH

Elongation

surface

Hardness
Change Fts.

Qunp%

Tonsik sb-tngm
Ret&W K

Retained W

+19.4
+0.96
-Il.92
+238.2
+5.94

74.8
104.5
102.0
17.7
99.5

74.6
76.0
64.7
29.9
76.0

-15
+1
+1
-41
-2

Unchanged
Unchanged
SI. Tacky
Unchanged
SI. Twkv

+18.6

84.9

45.7

-14

Unchanged

Condiitm

One Month Immersion at 75O t IoF


VdUmC
Change K

Andme

Tensile Strength
Retained K

Elongation
Retained%

Hardness
Change-.

Surface
Condii

A.S.T.M. No 1 011
ASTM
No. 3 Oil
Benzaldehyde
Dioctyl Phlhalatt

+4.89
+11.1
+39.5
+21.9
+2.71

91.9
84.3
53.5
71.7
95.5

87.1
75.3
49.4
62.8
85.4

+1
-4
-13
-9
+2

Tacky
SI. Tacky
Unchanged
Tacky
SI. Tacky

Distilled Water
Ethyl Alcohol
Ethyl Ether
Gasoltnt (RON 99)
Hexane

Lo.11
+1.78
+w.4
+158.2
+ 138.4

102.0
99.0
34.9
25.8
28.3

91.8
91.1
35.3
23.5
25.2

+2
+3
-20
-23
-21

Unchanged
Tacky
SI. Tacky
Unchanged
SI Tackv

Hydrochloric Acld (10%)


Lard
Methyl Ethyl Ketone
Perchlorotthyltnt
Potasswm Pennanganatt (25%)

+0.68
+3.75
+16.7
+ 170.0
+0.69

103.5
90.9
77.3
24.2
102.5

93.4
64.7
66.6
21.2
84.7

+3
-4
-10
-23
i-4

Unchanged
51. Tacky
Sl. Tacky
SI. Tackv
Unchangid

Skydrol500
Sodium Chloride (25%)
Sodwn Hydroxide (10%)
Tolutnt
Tide (1%)

+2.45
-0.12
0.00
+179.9
+1.01

101.5
104.5
102.5
29.3
101.5

91.1
91.8
92.5
28.2
92.5

+2
+2
+4
-22
d-4

SI Tacky
Unchanged
Unchanged
SI. Tacky
Unchanned

77.6

-11

Unchanged

Three Months Immersion at 75O * 5OF


Vdume
Chanm K

TmsikStren#h
Retained X

Ekmgation
Retained%

Hardness
Chanfp Pts.

Surface
Conditb

Amline
A.S T.M. No. 1 Oil
A.S.T.M. No. 3 011
Btnzaldehydt
Dioctyl Phthalatc

+6.64
+21.8
+114.s
+31.7
+6.32

94.4
77.8
46.0
63.1
97.0

90.1
65.9
37.5
54.1
65.4

0
-9
-21
-10
-1

SI. Tacky
Unchanged
Unchanged
Tacky
SI. Tackv

Distilled Water
Ethyl Alcohol
Ethyl Ether
Gasoline (RON 99)
Htxant

+0.58
+1.46
+62.8
+193.2
+156.3

104.0
93.9
33.8
30.3
30.8

91.8
m.0
36.9
27.5
25.9

+4
-3
-20
-22
-21

Unchanged
Sl. Tacky
Unchanged
Unchanged
St. Tacky

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Ptrchloroethyltnt
Potassium Ptrmanganatt

+0.63
+8.20
+15.6
+220.0

98.0
96.0
74.2
22.2

+2.41

100.5

87.8
87.1
64.2
19.5
86.4

-l-3
-5
-9
-23
+4

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanged

+2.80
0.00

99.5
103.0
99.0
29.3
100.0

65.4
88.7
64.0
27.5
87.8

+1
i-4
+2
-21
+1

SI. Tacky
Unchanged
Unchanged
Unchanged
Unchanged

72.7

68.9

-11

Unchanged

Skydrol500
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Tolutnt
Tide (1%)
UDMH

(25%)

-f-O.46
+182.5
+1.13
+17.0

(continued)

320

Corrosion

TABLE 2.12:

Resistant

VARIOUS

Materials

Handbook

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Six Months Immersion at 75O 2 5OF


Vdurm
W%

Tansik Strength
Ret&ad %

Elongation
Hardness
Retained SC ChangePts.

Surtaca
Condition

Amline
ASTM
No. 1 oil
A.S.T.M. No. 3 Dil
Senraldehyde
Dioctyl Phthalata

+4.05
+43.7
+157.0
+36.5
+9.38

96.5
66.2
43.4
54.0
93.4

91.8
55.8
33.6
48.7
82.4

-15
-25
-11
-4

Distilled Water
Ethyl Alcohol

+1.97
+1.43
+59.8
+189.0
+131.6

loo.5
100.0
37.4
24.8
31.8

81.7
88.2
36.9
26.6
26.6

+2
+1
-21
-25
-21

Unchanged
SI. Tacky
Unchanged
SI. Tacky
Sl. Tacky

Lard
Methyl Ethyl Ketona
Perchlomethyltna
Potassium Pcrmanganate (25%)

+0.89
+14.7
+14.7
+213.4
+4.59

100.0
90.9
77.8
24.2
106.1

87.1
76.0
64.2
20.5
86.4

+4
-9
-9
-23
+4

Unchanged
St. Tacky
Unchanged
Unchanged
SI. Brittle

Skydrd 500
Sodium Chlorida (25%)
Sodium Hydroxida (10%)
Toluene
Tide (1%)

+4.79
+0.12
+0.23
+191.3
+2.27

98.5
97.0
112.5
31.3
100.0

87.1
84.0
87.8
26.6
83.1

0
+4
+4
-23
fl

Sl. Tacky
Unchanged
Unchanged
SI. Tacky
Unchanged

+14.5

73.7

71.3

-9

Sl. Tacky

Ethyl Ether
Gasoline (RON 99)
Herant
Hydrahloric

Acid (10%)

UDMH

Tacky
Sl. Tacky
Unchanged
T=ky
Sl. Tacky

12 Months Immersion at 75O 2 5F


VOlUnW
Changa n

Tensile Stigth
Retaimd W

Elongation
Retained%

Hardness
ChangePtm

Surfaa
Condition

Aniline
A.S.T.M. No. 1 Oil
A.S.T.M. No. 3 011
Btnzaldehyde
Dioctyl Phthalate

+7.58
+52.8
+ 135.0
+44.5
+12.8

89.9
63.6
39.9
49.5
96.0

92.5
54.1
33.7
46.4
82.4

-3
-20
-21
-13
-6

Tacky
St. Tacky
Unchanged
Tacky
Sl. Tackv

Distilled Water
Ethyl Alcohol
Ethyl Ether
Gasoline (RON 99)
Htxant

f2.56
+2.82
+70.0
+ 155.0
+110.4

101.5
99.0
34.3
25.8
25.8

88.7
82.4
37.6
25.2
29.9

+4
+2
-22
-26
-28

Unchanged
Sl. Tacky
Unchanged
Sl. Tacky
Sl. Tacky

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchlorotthyltnt
Potassium Ptmanganatt (25%)

+1.90
+19.9
+14.1
+220.0
+6.64

101.5
87.4
75.3
21.7
98.0

80.7
81.2
66.6
22.3
77.6

+5
-11
-8
-25
+4

Unchanged
Sl. Tacky

Skydrol500
Sodium Chloride (25%)
Sodium Hydroxide (10%)

i-5.27
+0.25
+0.80
+127.5
f4.03

97.0
98.0
100.5
25.8
102.0

88.7
86.4
84.0
27.5
87.4

-1
+4
+2
-22
+4

SI. Tack-y
Unchanged
Unchanged
Sl. Tackv
Sl. Ta&

72.2

72.2

-10

Unchanged

Tolutnt
Tide (1%)
UOMH

+13.5

CHEMICAL

RESISTANCE

OF VISTALON

Sl. Tacky
SL Brittle

404 COMPOUND

72 Hours Immersion at 212OF


Volume
Changa K
Anlllnt
A S.T.M. No. 1011
A.S.T.M. No. 3 011
Benraldehyde
Dtoctyl Phthalate

f560
* 129.2
+216.4
126.4
139.6

Tensile Strangth
Retained K

Elongation
Retainad K

105.0
53 3
38.9
85.0
88.5

114 0
46 2
33.3
80.3
82.8

Hardness
Change Pts.
-3
-34
-35
-13
-18

Sutfaw
Condition
SI. Tacky
Swollen
Swollen
SI. Tacky
Unchanged

(continued)

Rubbers and Elastomers


TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

72 Hours

volume
Change W
DIstIlled
Ethyl
Ethyl

Water

Alcohol
Ether

Gasolme

(RON

99)

Hexane
Hydrochloric
Hydrochloric
Lard

Acid
Aud

(10%)
(Cow.)

Methyl
Ethyl Ketone
Perchloroethylene
Potassium
Permanganate
Skydrol
500
Sodturn

Chloride

Sodium
Sulfuric

Hydroxide
(10%)
Acid (Cont.)

(25%)

(25%)

ltde
(1%)
Toluene
UDMH

106.1

102.2

+2

Unchanged

105.0
36.5

-4
-28

Unchanged
Unchanged

+ 187.8

38.4

35.2

-37

Swollen

+177.6

36.9

30.2

-30

SI. Brittle

+5.80
+37.7
+64.0

100.0

88.0

80.5
69.2

72.6
66.7

-10
-26

Unchanged
Swollen

+ 16.3
+207.1

83.0
23.6

78 3
40.4

-12
-40

Unchanged
Unchanged

+0.84
+9.54

103.7
99.8

+0.93

111.5

+0.40

107.0

Dtstllled
Ethyl
Ethyl

Water

Gasoline
Herane

(RON

99)

Hydrochloric

Acid

Hydrochlow

Aced (Cone

(10%)
)

Lard
Methyl
Ethyl Ketone
Perchloroethylene
Potassium
Permanganate
Skydrol
500
Sodturn
Chloride
f25%)
Sodpum

Hydroxide

Sulfuric

Aced (Cone

(25%)

(10%)

( I ?P,
)

-4

Unchanged
Unchanged

0
+3

Unchanged
Unchanged

136

Cracked

102.7
22.6

100.0
30.2

+1
-35

Swollen
Unchanged

86.4

97.5

-11

Unchanged

Month

Immersion

Tensile Strength
Retained SC

at 75O 2

YF

Elongation
Hardness
Retained SC Change Pts.
109.5

-2

57.2
46.8

47.2
34.0

-23
-29

79.8
103.6

76.8
94.0

-8
-4

Unchanged
Unchanged

Unchanged

-0.10

109.3

105

101.9

102.5

36.9

38.5

-27

+166.8

40.8

33.3

-30

+ 190.9

36.4

28.9

-32

+0.94

114.4

110.1

+7.53

101.6

116

+23.9
+8.59
+93.3

93.2
92.7
45.8

+1.04

SUliWX

Condiiion

103.8

+0.12
+99.9

94.5

Swollen
SI Brlttle

SI. Tacky

83 8

SI

Unchanged
Unchanged
Unchanged

-8

Unchanged
Unchanged
Unchanged

+0.14

103.6

99.5

+3

74.4
107.1

+4

3
.: 6

Unchanged
Unchanged

.6

28.9
99.3

Tacky

-13
-8
-29

103.8
103.8

112.3
34.0
93.7

Sl. Tacky
Si. Tacky

-I 3

83.6
83.6
44.3

lacky

Swollen
Swollen

15
7

104.3
107.8

61.1

St

.h 1

+1.08
+0.02

+0.43
+182.9
+7.68

I de
Toluene
UDMH

+5

Brittle

+10.1

94.3

101.0

+0.91
+218.1

+15.9
+9.08

Alcohol
Ether

Unchanged

+57.9

+70.1
+214.4

Benzaldehyde
Dloctyl
Phthalate

+1

101.8
91.0
Brittle

+2.14
1 011
3 011

Surface
Condition

107.7
41.5

One

M No
M. No

Hardness
Change Pts.

+0.65

volume
Chanp SC
Anlllne

Elongation
Retained W

-1.31
+97.0

+16.5

A ST
A ST

(continued)

at 212OF

Immersion

Tensile Strength
Retained w

321

-31
-4

Sl

Tacky

Unchanged
Unchanged

Three Months Immersion at 75O f 5*F


VOlUllW
Change K
+2.26

Andme
A S.T.M

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

103.8

110.8

1011

+ 108.4

51.7

44.8

-27

3 Oil

+218.4

39.4

32.7

-31

+27.3

77.8

74.4

-8

Unchanged

No.

A S.T M. No.
Benraldehyde

Tensile Strength
Retained W

Unchanged
Swollen

Swollen

Dloctyl

Phthalate

+9.92

103.7

101.0

-3

Unchanged

Dlst!lled

Water

+0.44

106.9

106.5

- 5

Unchanged

+0.25
+94.4

97.2
40.8

104.5
42.8

-. 4
-28

Unchanged
Unchanged

43.4
32.5

35.8
32.7

Ethyl
Ethyl

Alcohol
Ether

Gasoline
Hexane

LRON

99)

+183.5
+175.8

Hydrochloric

Actid (10%)

Hydrochlonc
Lard

Acid

Methyl
Ethyl Ketone
Perchioroethylene

(Cow

t1.02
)

105

106

-33
-30
5

+11.0

95.5

1130

+20.9

85.2

92.8

-14

+8.54
188
1

98.5
41.8

93.7
46 8

-5
-27

-2

Swollen
Swollen
SI

Tacky

Unchanged
Unchanged
Sl. Tacky
Swollen

(continued)

322

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Three Months Immersion at 75O f 5OF


Volume
Chane %
POtaSslUm Permanganate
500

Skydrol
Sodium

Chiorlde

Sodfum
T!de

(10%)
)

aa 5
105 1

2 0.15
20 28

;07 a
103.7

106
101

5
a

-3
~ 7

39 9

48

-1

100

a7 a

102

-0.56

Toluene

Six Months immersion


Tensile

Vdumr

Change %
Anlllne
A S T M. No.

1 011

A S T M. No.

3 011

-199
1130.0
1213.5

aewaldehyde

+3a

Dmctyl

J-10

Phthalate

Ethyl
Ethyl

--0.66

Water

Distilled

Gasoline

(RON

99)

Hexane
Hydrochlow

Acid (1046)

Hydrochlorfic
Lard
Methyl
Ethvl

Acfd

(Cont.)

Ketone

500
Chloride

Sodturn

Hydroxfde

Sulfurtc

Acjd

Tide

Unchanged
Unchanged

107

-6

103

104

-6

Unchanged

101 a
410

-3

Unchanged

99 a
39 4

105
103

103

1018

1 011

f144

A ST

3 011

+211

M. No

103

+10

10 55
-0.06
+107.5

Olstllled
Water
Ethyl Alcohol
Ethyl Ether
Gasoline

(RON

99)

Hexane
Hydrochloric
Hydrochlorx
Lard

Acid (10%)
Aced (Cow

Potassium

Sodturn

Hydroxide

Sulfuric

Acid

Tide

(1%)

Toluene
UDMH

(Cow

(25%)

(10%)
)

Unchanged
Unchanged
SI Tackv

-26

swoiler!:

-3

-2
-4

Unchanged
Unchanged

-4

Unchanged

-2

Unchanged

30.4
91.7

-4

32.5
96 a

-27
-3

103

SI

Tacky

Swollen
Unchanged

Months Immersion at 75O 2 5OF

Tensile Strength
Retained %
4

53.2
42.8
108

Elongation
Retained %
108.3

-1

44.2

-29

75 0

107 9
107.4
38 5

Swollen
SI

-12

-6

108 9
108 2
40.3

-3
-2
-25

104

Surface
Condition
Unchanged
Swollen

-29

34.1
9

Hardness
Change Pts.

Tacky

Unchanged
Unchanged
Unchanged
Unchanged
Swollen

42.8

34 6

-30

32.5

30 a

-28

Swolfen

108 2
82 7
79 4

-2
-4
-16

SI. Tacky

98.6
424

96.9
49 4

-6
-30

98.8
1104

99 3
103 3

-1

Unchanged

A3
-1

Unchanged
Unchanged

-3

Unchanged

+2.50
+1.01

(25%)

-18
-6

+193.5

+103
1038

Permanganate
500
Chloride

SWOilen
Swollen
SI Tacky

f179.4

fl54
123
3
132.1

Methyl
Ethyl Ketone
Perchloroethyiene

Skydrol
Sodium

2
2

Unchanged

-30
-27
-4
-3

28 3

81.3

+31.3

Phthalate

Dloctyl

23 4

105

1.90

A S 1 M. No
Benraldehyde

32.5
108 2
98 2

106 5
99 a

12

Anllloe

-25

37 a

-1.05
007

Volume
Change %

Swollen

105

94 3

+I564
19 74

Toluene
UDMH

Surface

Condition

-27
-10

40.3

Hardness

Change ph.

37 6
74 4

93.7

- 0 53

(1%)

Retained %

-2.65

- 0 33

Unchanged

at 75O t 5OF

Elongation

a5 5
90 4
45 7

142

Unctiangod
SWOlll?fl

414
77 4

a6 a
a3 0
94 0

(10%)

(Cow.)

-7
-31
-3

Unchanged
Swoller!

+14
a
+34
a
+a.09

(25%)

Unchanged
l$hanged

-1
-25

32 3
97 2

Skydrol
Sodaurn

Unchanged
Unchanged

103.2
44 a

1167 3
-1.63

98.5
51 2

42.8

(25s6)

Permannanate

Retained %

1-181.6

+a6

Perchloroeihylene
Potassium

28
5

-0
187

Alcohol
Ether

Strength

32 7
100 0

31.1
93.7

+169.9
a.98

UDMH

surface
Condition

Hardness
Change Pk.

104.3

i 32.2

(I?,,)

U0tlgG3tihl

Retained K

2.67
11.15

125%)

Hydroxide
Acid (Cow

Sulfurrc

(25%)

Tensile Strength
Retained %

+o 01
LO.19
767
1O
+178.6
i12.4

69

110.2
75 a
83.8

103.2
101 9
10.3

100 0
102 5
52

109.8

106

37 9
102 4

32 a
98 2

Unchanged
Unchanged
SI. Tacky
SWOllell
0

-2
-30
-a

SI

Tacky

Swollen
Unchanged

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

CHEMICAL

AND RUBBE:RS-EXXON

RESISTANCE

CHEMICALS

72 HOWSimmersion
chnp%
+1.72

Anlllne

(continued)

BASED ON HIGH MOONEY EPDM

OF COMPOUND

VdUlIla

Tamilc stnmgm
Rabinad %

at 212OF

Elongation
Ratainad W

Hardnasa
Changa Pts.

Surface
Condition

98.5

87.6

No.

1011

t83.1

51.7

49.5

-25

SWOllen

A.S.T.M.
No
Senzaldehyde

3 Oil

+119.9
+12.8

35.9
77.0

37.2
72.4

-28
-10

Swollen
Unchanged

83.0

73.0

-11

A.S.T.M

Dloctyl

Phthalate

Dlstllled

+24.7

+1.10

Water

Ethyl

Alcohol

Ethyl

Ether

Gasoline

-3.47

(RON

99)

Hexane

104.7

-1

85 0

SI. Tacky

Unchanged

95.6

83.6

+62.6

36.0

36.3

-16

+121.8

35.5

38.0

-25

+93.4

28.1

25.8

-18

Unchanged

+1

Unchanged
Unchanged
Swollen
Unchanged

Hydrochloric

Acid

(10%)

+14.6

74.8

60.0

Hydrochloric

Acid

(Cont.)

+32.3

70.7

60.9

-8

Unchanged

+38.9
+5.15

65.0
72.1

63.7
73.5

-19
-7

Unchanged
Unchanged

-27

Lard
Methyl

Ethyl

Ketone

Perchloroethylene

+109.7

Potasswm
Permanganate
Skydrol
500
Sodium

Chloride

Sodurn

Hydroxide

Sulfuric
(Acid
Tide (1%)

(25%)

(25%)
(10%)

(Cow.)

Toluene

Unchanged

20.7

31.4

99.5
104.4

78.0
89.5

+2.69

94.7

73.5

Unchanged

+0.43

98.8

74.3

44.7

t29

Unchanged
Cracked

88.6

77.2

t1

Unchanged

23.0

30.6

-25

Unchanged

70.1

66.5

-1

Unchanged

t150.2

UDMH

+1.65
+2.08

t66.9
t1.63
+5.22

323

Unchanged
Unchanged
Unchanged

+1
-1

Ona Month Immersion at 75O -C SF


VOIUIIN
USC
AnNlIne
A S T.M

No

1 011

A S.1 M No
Senraldehyde

3 011

Dloclyl

Elongation
Ratainad%

Hardnass
ChangaPls.

sulfaca
Condition

93.4

90.7

-1

56.7

48.5

-13

Swollen

44.7
75.4

35.9
71.4

-16
-4

Swollen
SI. Tacky

SI. Tacky

Phthalate

+3.35

91.2

87.7

-2

Unchanged

Water

to.37

104.5

94.4

i2

Unchanged

-0.65
+61.6

97.5
33.3

89.5
36.3

-~ 1
-12

SI. Tacky
SI. Tacky

t 106.9

42.8

363

+119.2

32.7

25.8

-17
-13

Dlstllled
Ethyl
Ethyl

t 5.05
t53.1
t 128.6
+3.00

Tans& Srw#h
Ratained n

Alcohol
Ether

Gasoltne

(RON

99)

Herane
Hydrochlonc

Acld

(10%)

Hydrochloric
Lard

Acid

(Cont.)

Methyl

Ketone

Ethyl

Perchloroethylene

Sodium
Sodium

Chloride
(25%)
tivdroxlde
(10%)

Sulfuric

(Acid

Trde (1%)
Tolue&
UDMH

+1.22

104.2

94.4

t4.37
t20.8

102.4
77.7

92.3

1
+2

76.3

-8

Unchanged
Unchanged

+0.28

76.5

77.2

-1

Unchanged

37.4

36.3

-17

+0.59
-5.99

105.4
102.4

96.3

+0.04
+0.45

102.2
104.5

93.5

+73.5

Potassium
Permanganate
Skydrol
500

(25%)

(Cont.)

t7.81
t 1.61
+121.1
t1.65

T_sbryth
bt&md%

c
t4.97

Months

Unchanged
Unchanged
Unchanged

12
t2

95.2
37.8

52.3

Unchanged

-t2

97.2

100.8
28.5
75.2

lhroa

AnlIme

Swollen
Unchanged

Unchanged
Unchanged
Unchanged

*2
6

94.4

+3

26.6
60.8

-16
-c2

SI. Tacky
Unchanged
Unchanged

Immanion at 7b0 2 So*


w

Hafdnesf

Retainad

Surfaa?
--

Change

RI.

Conditkw

90.8

89.5

-1

A.S T.M

No.

1 011

+75.0

51.7

46.7

-17

A S.T.M

No. 3 011

+128.4

36.5

30.6

-17

t7.30
+3.52

83.8
99.5

80.8
97.2

-4
-2

Unchanged
Unchanged

+0.69

106.0

97.2

-2

Unchangeg

-0.67

95.8

91.5

Unchanged

39.6

40.8

-13

Sl. Tacky

+111.1

43.8

400

-18

Swollen

+111.4

30.4

31.5

-15

Swollen

Senzaldehyde
Ouoctyl Phthalate
Dbstllled

Water

Ethyl

Alcohol

Ethyl

Ether

Gasolmc
Hexane

(RON

t63.7
99)

Unchanged
Swollen
Swollen

(continued)

324

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

Three Months
Vdume
chanm

Hydrochlonc
Hydrochloric

Acld (10%)
Acid (Cont.)

Lard
Methyl

Ketone

Ethvl

Perchloroeihylene
Potassium

Permannanate
-

Skydrol

500

Sodwm
Sodlum

Chloride
(25%)
Hydroxide
(10%)

Sulfuric

(Acid

(25%)

(Cont.)

Tide (1%)
Toluene
UDMH

Tensile Strength
K

Retained

ASTM
No
Benzaldehyde

-1

+0.23
+0.26

103.8
99.5

97.8
93.5

i- 1
+3

Unchanged

+32.1

35.5

22.8

-9

Unchanged

+1.90
+117.3

102.2
26.1

97.2
29.4

-2
-16

89 5

71.8

Ketone

Perchloroethylene
Potasswm

Permanganatc

Skydrol
Sodwm

500
Chloride

Sodium
Sulfuric

Hvdroxidc
(10%)
(Aced (Con; )

Tide

(25%)

(25%)

(1%)

Toluene
UDMH

Dloctyl

Phthalate

Dlstllled
Water
Ethyl Alcohol
Ethyl Ether
Gasolme
(RON

99)

Hexane
Hydrochloric

Acid (10%)

Hydrochloric
Lard

Acid

(Cont.)

Methyl Ethyl Ketone


Perchloroethylenc
Potasswm
Permanganatc
Skydrol
500
Sodium
Sodwm

Chloride
(25%)
Hydroxldc
(10%)

Sulfuric

(Acid

Tide (1%)
Toluene
UDMH

(Cont.)

(25%)

5F

Hardness
Chance Pts.

Sur(aa
Condition

48.5

-15

-1

Unchanaed
SwolleG

+129.7
+9.90

41.8
87.8

37.8
80.0

-15
-3

SWOlle
Unchanged

-2

Unchanged

95 3

94 4

96.4
104

93.2

100 0
87.7

38.9
35.5

40.0
37.8

.1

Unchanged

-1

Unchanged

-11
-17

Sl. Tacky
Swollen

-14

Swollen

30.4

31.5

+2.00

97.5

89

+12.5
-l-27.0
+0.36

92.6
72.8
76.0

808
74.3
77.2

-2
-10

f73.2

37.3

39 2

-15

f1.88

95.0

89 5

-3

-5.73
+0.20

91.7
98.8

91.5
95.2

-2
-2

Unchanged
Unchanged

+0.26
+45.2

100.9

93.5

23.8

11.4

-1
-8

Unchanged
Unchanged

+1.82
+115.3
+4.30

104.9
26.3

98.0
28.6

SI. Tacky

70.0

56.3

-14
+2

Unchanged

12 Months

Aniline

Unchanged

50.7

Vdunw
Change K
A S T M No. 1011
A S.T M No 3 011
Eenraldehyde

at 75O t

Elongation
Retained W

Unchanged
Swollen

93.9

+ 103.0
Acld (Cont.)

TenslIe strsllgth
Retained %

Unchanged

58.7

Immersion

Unchanged

+4.55

+59.4
f110.5

Hydrochlortc
Lard
Methyl
Ethyl

-2

96.3

-0.51

Acid (10%)

Tackv

swon;n

91.7

+0.93

Hexane

SI

101.8

i-3.72

Hydrochloric

Unchanged

-0.91

Water

99)

-9
-1

-5.95

Phthalate

Ethyl Ether
Gasolme
(RON

Condition

-17

37.8

Dloctyl

Alcohol

Surface

Pts.

41.4

61.7
85.7

-l-72.8

Dlstllled
Ethyl

Change

62.0
85.7

+25.5
+0.62

+85.0

3011

Hardness
%

SI Tacky
Unchanged

83.6
91.5

Vdume
C)unm n
S T M. No. 1 011

75 + W

-1
-1

90.8
97.5

+3.13

AntlIne

at

Elongation
Retained

+1.30
+9.43

Six Months

Immersion

(continued)

Tan80 Strom@
Retained %

-2

SI

Tacky

Unchanged
Unchanged
SI. Tacky
Swollen

Swollen

at 75O 2 5OF

Immersion

Elongation
Retained%

Hardness
ChangePb.

Surtaw
Cat&ion

+6.53

95.0

95.2

-3

Unchanged

+9D.9
+144.4
+7.63

47.8
42.8
87.9

43.7
36.3
80.0

-18
-22
-4

Swollen
Swollen
Unchanged

+4.02

110.3

964

-3

+1.92
+0.33
+69.4
+1104

103.6
100.3
35.3
38.7

94.3
93.5
23.6
36.3

-10
-18

+ 128.3

30.4

29.5

-13

+3.86

88.0

80.0

fl

+18.3
+27.2

79.7
69 2

66.5
69.5

-9

+2.04
+75.9

74.6
32.7

73.5
31 5

+2.46
-5.47

101.8
100.8

93.4
92.3

-0.14
+0.29
+55.8

96.7
100.8
Broken

87.7
90.6
Broken

+19

+2.83
+114.6

105.0
39.9

93.5
30.5

-1
-16

+21.9

61.3

43

Unchanged
0
0

Swollen
SI. Tacky
0

-1
-14
+2
Al

+2
0

-3

Unchanged
Unchanged
SI. Tacky
Swollen

Unchangid
Unchanged
Sl. Tacky
Swollen
Unchanged
Unchanged
Unchanged
Si. EMtIe
SI. Tacky
Swollen
Unchanged

(continued)

Rubbers

TABLE 2.12:

VARIOUS
CHEMICAL

ELASTOMERS
RESISTANCE

AND RUBBERS-EXXON

OF HIGHLY LOADED COMPOUND

72 Hours

Vdume
Change SC
Anlllne
A.S T.M
A S T.M

No
No

-10.7
f57.1
+103.3

1011

3 011

Tensile Strength
Retained SC

CHEMICALS

and Elastomers

(continued)

BASED ON HIGH MOONEY

EPDM

Immersion at 212-F
Elongation
Retained K

Hardness
Change Pts.

116.0
108.0
65.2

81.9
89.3
68 0

+10
-31
-39

Sur(ace
Condition
Unchanged
Swollen

Swollen

Benzaldchyde

-5.26

102.3

68 0

+4

Dloctyl

Phthalate

+3.11

112.3

84.0

-2

Water

+0.66

117.3

87.1

-16.4
+21.9

110.2
83.8

85.6
68.0

,+12
-20

+85.6

69.5

68.0

-35

+59.8

58.7

48.2

-28

Unchanged

+9.35
+25.2

121.0
109.5

87.1
90.9

-4
-13

Unchanged
Unchanged

+19.4
-8.71
+68.5

116.0
76.5
60.8

85.6
64.1
60.5

-15
-348

Unchanged
Unchanged
Brittle

+3.13
-9.89
-0.18

134.0
114.5
123.0

92.5
69.5
89.3

+2
+9
-3

Unchanged

Sodium Hydroxide
(10%)
Sulfuric Acid (Cont.)
Ttde (1%)

+0.76
+74.2

126.0
65.0

89.3
-

+2

Unchanged
Broken

119.5

85.6

Toluene
UDMH

+96.9
-10.6

Distilled
Ethyl
Ethyl

Alcohol
Ether

Gasoline

(RON

99)

Hexane
Hydrochlow
Hydrochloric

Acid (10%)
Acid (Cont.)

Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium
Permanganate
Skydrol 500
Sodwm Chloride
(25%)

(25%)

+1.55

42.2
99.5

One

votume
Cm%
Anilme

-5.40

A S T.M No. 1011


AS T.M No 3 Oil
Benraldehydc

+29.3

+a1.1

48.2
69.5

Unchanged
Unchanged
0

Unchanged
Unchanged
Unchanged
Swollen

Unchanged
Unchanged

+I6

+1

Unchanged

-38
+7

SI. Brittle
Unchanged

Month Immersion at 75 5 5OF

Tensite Strength
Retained K

Elongation
Retained K

Hardness
Change Pts.

105.7

94.7

116.2
::t

90.8

-19

642

-26

-5.76

+5

Surface
Condition
Unchanged

85.5

14

Swollen
Swollen
Unchanged

Dloctyl

Phthalatc

-5.18

97.7

89.5

-42

Unchanged

Dlstllled

Water

+0.16

115.8

94.4

t2

Unchanged

-6.77
+27.5

102.8
86.4

92.6
73.2

16
-16

Unchanged
Unchanged

77.8
61.4

64.2
44.3

-28
-25

Swollen
Unchanged

+0.49

121.4

+4.31
+7.99

126.3
104.2

97.8
94.7
92.6

Ethyl
Ethyl

Alcohol
Ether

Gasolme
Hexane

(RON

99)

Hydrochloric

Acid (10%)

Hydrochlow
Lard

Acid (Cow

Methyl

Ketone

Ethyl

+69.8
+70.8

-7.73

Perchhxoethylene
Polasswm
Permanganate
Skydrol 500
Sodwm Chloride
(25%)
Sodwm
Sulfuric

(25%)

Hydrorlde
(10%)
Actid (Cone )

Tide (1%)
Tolene
UDMh

325

SI.Tacky

t2
+2
-8

Unchanged
Unchanged

+6

Unchanged

95.8

85.5

+39.3

100.0

85.5

+0.64
-11.8
+0.05

117.2
94.3
117.8

97.8
87.2
97.8

+2
+8

+0.08
+15.5

119.8
64.4

100.0
26.7

t2
-3

+0.21
i72.9

117.2
60.7

97.8
54.5

+1
-25

SI. Tacky
SI. Brittle

-8.76

110.7

58.5

+7

Unchanged

Vdw

Tanslle~

-24

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Unchanged

Three Months Immersion at 75* 2 5F

c-w%
Anlllne
A.S T.M.

-5.43
No.

1011

+48.7

A.S.T.M.
No. 3 Oil
Benzaldehvde
Dw~~tyl Phihalate
Dlstllled

+85.1
-6.19
-5.21

Water

Gasolme
Hcxane

(RON

--

Hardness
Change Pts.

Surface
Condition

103.5

105.3

97.7

83.9

-24

Swollen

72.8
103.5

60.5
89.5

-29
+4

Swollen
Unchaneed

16

Unchanged

97.8

-i4

Unchanged

123.0

105.3

-+2

Unchanaed

110.7
86.4

101.5
81.9

+71.6

80.0

69.5

-28

Swollen

+62.i

63.5

53 8

-23

Swollen

-6.98
+28.1
99)

Elongation
Retained%

100.0

+0.35

Ethyl Alcohol
Ethyl Ether

Retained K

13
-18

Unchanged
Unchanged

(continued)

326

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

VOlUlllO
Change K
Hydrochlorx

Actd (10%)

Hydrbchlorlc

Acid (Cow)

-I 0.39
+6.24

Lard
Methyl Ethyl Ketone
Perchloroethylene
(25%)

Potassium
Permanganate
Skydrol
500
Sodwm

Chlonde

(25%)

Sobum
Sulrur~c

Hydroxide
A&d (Co&)

(10%)

Tensile strength
Retained K

UDMH

117.2

Anlllne
No
No

1 011
3 011

Benzaldehyde
Dfoctyl
Phthalate
Dlsttlled
Ethyl

Water

Alcohol

Hexane
Acfd (1046)
Acid (Cone

Unchanged

-6
-24

Unchanged
Swollen

+1.08
-11.5

84.5
92.2

81.9
85.5

-4

Unchanged

+0.10
+1.12

122.2
121.4

105.3

-2

Unchanged

+0.31
+64.6

117.2
62.2

100.0
55 0

-7.84

113.5

62.6

VOIUIIW
Change W

Tensile Strength
Retained %

Potassium

Permanganate
500
Chlortde
(25%)
Hydroxide
(10%)

Sulfurtc

Acid

(Cone

(250,)

Tide (1%)
Toluene
UDMH

Months Immersion at 79
Elongation
Retained W
89.5

-24

+85.9
-7.03
-5.15

74.4
103.7
102.3

65 8
85.6 5
92

-28
-5

Unchanged

Unchanged

12

Unchanged

-2

Unchanged
Unchanged

96 3
94.7

81.5
75.0

74 8

-4
-13

Unchanged

74.8
57.3

-29
-28

Swollen

63.5

Swollen

1185

101.5

-2

Sl. Tacky

124 2
108.5
96.5

100.0
97.8
83.9

-3
-13
5

Unchanged
Unchanged

91 8

80.2

-21

+2.79

102.8

87.1

99.4
106.3
113.5
Broken

90 9
92.3
97.3
Broken

+0.90

111.5

97.8

+68.1
-7.22

58.5
119.2

55.0
65.8

Tamik Strength
RetBirmdn
109.2

Elongation
Retained%
97 8

91.5
77.9

80.2
67.8

Unchanged
Swollen

Unchanged
Unchanged
0

-3
-1
+6

Unchanged

2 SF
Hardness
ChangePts.

Surfaa
Condii

T3

Unchanged
Swollen
Swollen

-28
-29

-7.94

106

73.2

-5.18

108.5

89 3

-4

+o 68
-5.64

107.0
116.3

92.3
96.3

Ethyl Ether
Gasolme
(RON
Hexane
Hydrochlor,c
Hydrochlorx
Lard
Methvl

Ethyl

+31.1
+75.2
+70.9

99)
Acid
Acld

(lo?&.)
(Cone )

Ketone

Perchloroethylene
Potassium
Permanganate
Skydrol
500
Sodurn
Sodturn
Sulfuric

Chloride
(25%)
Hydroxide
( IOn.)
Acid (Cone )

Tide (1%)
Toluene
UDMH

(25%)

82.2
75 7
64.3

Unchanged
Unchanged
SI.Tacky
Swollen

-27

Dloctyl

0
f8
-2

Eenzaldehyde
Dtstllled
Water
Ethyl Alcohol

Surface
Condition
Unchanged
Swollen
Swollen

15

Phthalate

Swollen

108.0
103 5

-11.5
-0 01
-0.08
f410

+59.3
f88
0

1011
3 011

f7

-4

96.3

-4.31

AnlIme

Unchanged

Hardness
Change pt*

93.7

Vdunw
Change %

t2
-26

k SF

101.3

12 Months Immersion at 79

A ST M. No
A S.T M No

-5.43
f55.6

Unchanged
Unchanged

i2

9.4

+32.1

Skydrol
Sodturn
Sodium

105

42.2

+8.58
+12.0
-7.77

Methyl
Ethyl Ketone
Perchloroethylene

SI. Tacky
Unchanged

-11

+0.26
)

-1
-1

85.5

A-61

Hydrochloric
Hydrochlorx
Lard

100 0
96 3

SUrfaCt
Condition

89.5
81.9

+44.1
+73.0

99)

Hardness
Change Pts.

87.2
97.2
97.7

+0.32
-6.56

Ethyl Ether
Gasoline
(RON

(continued)

+10.0
-7.55
+34.5

Six

A S T M
A S T.M.

Elongation
Retained ?4

122.2

+33.9

ride
(1%)
Toluent

CHEMICALS

69 5
71.2
53.5

Tacky

Unchanged

-1
5
-20
-29
-22

SI

Unchanged
Unchanged
Unchanged
Swollen
Swollen

10.39
+12
2

1165
122.0

92.5
90 8

1
-4

SI Tacky
Unchanged

+I0
6
-7.48

100.0
93.5

89 3
74 8

-9
i3

Unchanged
Unchanged

+36.8

100

71 2

-19

+4.56
-11.2
-0.34
+o.os
+44.1

104.5
99.3

87.1

+10

87.1

1115

96 3

110.7

92

Broken

Swollen

-2

Broken

Unchanged

Al
18

+0.51
-l-77.0

112.9
59.4

loo.0
53.5

-1
-28

+9.78

124.3

58.8

-5

Unchanged
Unchanged
SI

Brittle

SI. Tacky
Swollen
Unchanged

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS
CHEMICAL

AND RUBBERS-EXXON

RESISTANCE

OF NATURAL

CHEMICALS

327

(continued)

RUBBER COMPOUND

72 Hwrs Immersion at 212OF


VobM
~w.W

Tensile Strength
RaMled

Elongatii
Ret8hd

SC

Aniline
ASTM
No. 1 Oil
A.S.T.M. No. 3 Oil
Benzsldehyde
Dioctyl Phthalate

+32.1
+77.6
+143.9
+244.8
+147.7

30.2
38.7
11.2
4.3
10.2

45.5
70.0

Distilled Water
Ethyl Alcohol
Ethyl Ether
Heune
Hydrochloric Acid (10%)

+6.14
+2.35
+84.6
+io8.a
+11.2

Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganate (25%)
Skydrol500

+BO.9
+47.2
-l-465.4
+3.15
+48.6

Sodium Chloride (25%)


Sodium Hydroxide (10%)
Toluene
Tida (1%)

-0.36
+2.96
Disinbgmted
+5.89

SUlfXZ

Hardness
Change Pts.

Condiiion

16.2
27.7

-19
-34
-35
-25
-30

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

89.2
78.4
34.a
26.2
61.0

78.5
58.4
34.6
28.4
49.2

-3
0
-15
-20
-4

Unchanged
Unchanged
Unchanged
Unchanged
SI. Tacky

36.7
44.6
3.6
54-4
22.6

42.3
51.5
17.8
49.2
65.4

-20
-21
-43
-1
-41

Unchanged
Unchanged
Unchanged
Si. Brittle
Unchanged

89.5
94.8

83.1
83.1

-3
-5

Unchanged
SI. Tacky

86.9

75.5

-3

Unchanged

50.8

One Month Immersion at 75O i BF


Vuhnlle

-m%

Tmsile Sbwwth
Reteined 2

Elonnation
Hardness
Retakd
SC ChanpPts.

Surface
condition

Amline
A.S T.M. No. 1 011
A.S 7.M No. 3 Oil
Benzaldehyde
Dtoctvl Phthalate

+a.90
+24.6
+107.3
+7a.3
+64.3

94.4
88.2
42.0
34.4
54.4

90.1
82.5
38.6
38. i
53.1

-5
-10
-20
-15

SI Tacky
Unchanged
Unchanged
Unchanged
Unchanned

Drstilled Water
Ethyl Alcohol
Ethyl Ether
Heune
Hydrochloric Acid (10%)

+1.32
+1.85
+95.5
+107.4
+2.17

102.6
88.9
28.2
31.5
96.1

100.9
73.2
32.3
31.6
91.7

0
-4
-17
-16
-1

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Lsrd
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganate(25%)
Skvdrol 600

+51.3
+46.a
+219.7
+4.19
+25.8

63.6
53.4
23.0
84.3
89.2

60.1
56.1
22.4
81.5
88.5

-15
-15
-20
-3
-11

Unchanged
Unchanged
Unchanged
Brittle
Unchanged

Sodium Chloride (25%)


Sodium Hydroxide (10%)
Toluene
Tide (1%)

-0.83
+0.72
+206.1
+1.92

97.7
97.7
20.8
94.7

-1
-1
-20
0

Unchanged
Unchanged
Unchanged
Unchanged

105.3
102.3
20.7
97.1

-18

Three Months immersion at 75 2 5OF


VOIUITIO
Channn

Tmsile Stmngth
Retained %

Elongation
Retained%

Hardness
ChanrgaPte.

Suliace
Condiiion

Aniline
A.S.T.M. No. 1 Oil
A.S.T.M. No. 3 Oil
Benzaldehyde
Droctyl Phthalate

+ii.a
+41.8
+102.2
+87.0
+78.4

89.8
79.3
41.0
20.7
57.4

88.5
74.6
38.6
30.7
55.4

-7
-10
-15
-24
-19

SI Tacky
Unchanged
Unchenged
SI. Tacky
Unchanged

Drstilled Water
Ethyl Alcohol
Ethyl Ether
Hexane
Hydrochloric Acid (10%)

+2.98
+2.15
+119.3
+107.3
+3.61

103.0
79.7
24.3
28.9
84.0

98.6
78.5
31.6
30.7
79.2

0
-3
-21
-18
-2

UnchanIyd
Unchanged
Unchanged
Unchanged
Unchanged

(continued)

328

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

Thrn
Vdume
change K

CHEMICALS

(continued)

Months Immersion at 75O t 5OF

Tensile Strength
Retained K

Etongatbl
Retained%

Hardness
Change ph

Lard
Methyl Ethyl Ketone
Perchloroethylcne
Potassium Permanganate(25W)
Skydrol 500

+65.4
+4a.o
+229.4
-1.29
+27.4

56.4
31.8
22.6
71.2
76.4

53.1
44.6
21.5
68.6
77.8

-17
-20
-23

Sodium Chloride (25%)

+0.71
+2.41
+2122
+3.28

98.0
84.3
21.0
97.1

91.7
77.2
23.1
91.7

+2

Sodium Hydroxide (10%)


Toluene
Tide (1%)

0
-10

0
-23
-1

surface
Condition
Unchanged
St. Tacky
Unchanged
Brittle
Unchanged
Unchanged
Unchanged
St. Tacky
St. Tacky

Six Months Immersion at 75O I?I5OF


Surface
Condition

Tensile Strength
Retained W

AST M. No. 1 Oil


A.S.T.M. No. 3 011
Benzaldehyde
Dmctyl Phthalate

+lO.B
-I-47.9
+125.8
+91.6
+B2.9

89.5
71.8
35.4
11.5
44.9

87.1
67.7
34.0
23.1
45.5

-8
-15
-20
-29
-20

SI. Tacky
Unchanged
Unchanged
SI. Tacky
Unchanged

Distilled Water
Ethyl Alcohd
Ethyl Ether
Hexane
Hydrochloric Acid (10%)

+3.34
+1.81
+106.B
+104.5
+4.22

97.7
76.7
21.6
30.2
79.3

91.7
73.9
27.0
30.0
69.3

0
-5
-23
-18
0

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganate(25K)
Skvdrol5OD

+68.8
+50.8
+255.0
+0.65
+29.5

51.5
24.6
19.0
61.0
57.1

50.1
38.6
20.8
53.1
67.0

-16
-23
-25
-3
-18

Unchanged
SI. Tacky
Unchanged
Brittle
Unchanged

Sodium Chloride (25%)


Sodium Hydroxide (10%)
Toluene
Tide (1%)

+1.31
+3.49
+246.8
+4.75

87.5
74.1
16.4
98.0

81.5
67.0
20.8
92.4

0
-1
-26
0

Unchanged
Unchanged
Tacky
SI. Tacky

Anlllne

Ebngation
Retained %

Hardness
Chanae Fts.

Vdume
chanee w

12 Months Immersion at 75k 2 5OF


Vdume
Change K

Tensile Strength
Ratained %

Etongatien
Retained W

Hardness
Change Pts.

surface
Cendition

Aniline
A.S.T M. No. 1 Oil
A.S.T.M. No. 3 011
Benzaldchyde
Dioctyl Phthalate

f14.1
+48.1
+ 128.8
+ 106.8
+90.0

83.6
68.9
33.4
4.3
32.8

84.8
67.7
34.6
19.2
39.9

-7
-20
-23
-36
-24

SI. Tacky
Unchanged
Unchanged
SI. Tacky
Unchanged

Distilled Water
Ethyl Alcohol
Ethyl Ether
Hcune
Hydrochloric Acid (10%)

+4.54
+3.59
+111.5
+81.7
+5.06

92.1
74.8
16.7
25.3
67.2

84.8
68.6
27.7
30.0
60.1

+4
-2
-29
-20
+2

Unchanged
Unchanged
Unchanged
SI. Tacky
SI. Tacky

Lard
Methyl Ethyl Ketone
Perchloruethylene
Potassium Pennanganate(25%)
Slwdrol 500

+74.8
+57.0
+211.4
+1.29
+32.4

40.0
13.4
13.1
71.2
37.4

44.6
32.3
19.2
67.0
53.8

-24
-3D
-30
-3
-25

Unchanged
SI. Tacky
Unchanged
Brittle
Unchansed

Sodium Chloride (25%)


Sodium Hydruxide (10%)
Tduene
Tide (1%)

-0.24
+7.34
+ 187.6
+6.44

84.3
57.1
12.5
90.2

76.2
50.8
20.8
76.2

+3
0
-22
+2

Unchanged
Unchanged
St. Tacky
St. Tacky

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICAL

RESISTANCE

CHEMICALS

329

(continued)

OF SBR COMPOUND
72 Hnurs Immersion at 212OF

VOlUn
CRawa%
Aniline
A.S.T.M. No. 1 Oil
ASTM
No. 3 Oil
8enzaldchydc
Dioctvl Phthalatc

Tmiksbwhgul
R&abed%

ElongM
Retained%

Wardness
change Pls.

Surface
Condii

+71.1
+24.9
+ 103.9
+150.6
+%.2

25.8
84.4
37.7
22.5
41.8

34.0
66.0
55.8
25.5
40.5

-26
-13
-26
-27
-22

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

+5.17
-0.12
+68.7
+61.6
+12.5

98.8
70.9
29.5
31.2
95.1

62.3
47.3
28.3
32.0
59.5

+2
+3
-17
-17
-2

Unchanged
Unchanged
Unchanged
Unchanged
SI. Tacky

Lard
Methyl Ethyl Ketone
Perchloroethytene
Potassium Permanganate (25%)
Stwdrol 500

+45.8
+52.4
+208.3
+3.74
+97.2

64.3
29.9
13.9
78.7
20.1

51.8
33.1
16.2
51.0
38.8

-17
-17
-28
-37

Unchanged
Unchanged
Unchanged
V. Brittle
Unchanged

Sodium Chloride (25%)


Sodium Hydroxide (10%)
Toluene
Tide (1%)

-0.11
+1.86
+255.7
+4.03

102.5
99.6
11.1
107.8

65.2
70.8
18.4
70.0

+3
0
-38
+2

Unchanged
Unchanged
Unchanged
Unchanged

Distilled Water
Ethyl Alcohol
Ethyl Ether
Huane
HydrochloricAcid (10%)

One Month Immersion at 75O * 5OF


Volume
CKawa%
Aniline
ASTM
No. 1 oil
ASTM
No. 3 Dil
Bcnzaldehyde
Duxtyl Phthalate
Distilled Water
Ethyl Alcohol
Ethyl Ether
Huane
Hydrochloric Acid (10%)

TeMikSbulgth
Retained%

gKJr.rgattafr
Retainad%

Hardness
ChangaPts.

Surface
Condition

+x).3
+5.21
+58.0
+105.8
+53.3

67.2
lM.9
53.3
28.3
53.3

58.1
92.6
45.3
26.4
47.3

-11
-3
-18
-19
-16

SI. Tacky
Unchanged
Unchanged
Unchanged
Unchanged

+1.35
+0.79
+74.8
+92.5
+2.04

111.9
99.2
29.5
32.0
109.8

96.3
85.8
29.2
30.3
92.6

0
-1
-17
-16
+1

Unchanged
Unchanged
SI. Tacky
SI. Tacky
Unchanged

Lard
Methyl Ethyl Ketone
Perchloroethylcne
Potasswm Permanganate (25%)
Skydrol 500

+16.2
+47.5
+190.5
+7.42
+46.6

70.5
34.4
24.6
109.0
56.5

61.5
34.8
19.8
88.7
53.0

-14
-16
-20
-2
-17

Unchanged
St. Tacky
SI. Tacky
V. Brittle
Unchanged

Sodwm Chloride (25%)


wium
Hydroxide (10%)
Tduene
Tide (1%)

+0.21
+0.71
+ 196.4
+2.16

109.0
108.2
25.0
107.8

90.7
90.7
19.8
96.3

+1
+3
-19
+1

Unchanged
Unchanged
SI. Tacky
Unchanged

mrs0 Months Im-ton

f-8-m
Rat&led%

-WI*
btaimd%

at 75 * SF
Hardness
ChanlQPk

SurtKc
CondRhn

Aniline
A.S.T.M. No. 1 oil
ASTM
No. 3 Oil
8anzaldehyde
Dioctyl Phthalate

+22.1
+9.m
+91.8
+104.8
+75.9

a.8
98.4
56.2
21.7
50.4

50.1
84.1
45.3
22.7
43.3

-9
+6
-17
-21
-16

St. Tacky
Unchanged
Unchanged
St. Tacky
Unchanged

Distilled Water
Ethyl Alcohol
Ethyl Ether
Huane
Hvdrochlaric Acid llOX\

+2.93
+0.45
+110.0
+93.0
+3.95

117.6
94.3
29.9
31.9
109.4

93.5
77.3
28.3
32.0
87.8

+3
0
-17
-15
+3

Unchanged
Unchanged
Unchanged
St. Tacky
Unchanned

(continued)

330

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Three Months Immersion at 750 ? 5oF


Vdume
change Y

Tensile Strength
Retained K

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

Skydrol SD0

+54.7
+53.1
+189.6
+9.10
+45.3

68.0
32.4
22.9
101.2
53.7

60.3
31.1
17.9
79.3
50.1

-16
-15
-20
-1
-12

Unchanged
Unchanged
SI. Tacky
Brittle
Unchanged

Sodium Chloride (25%)


Sodium Hydroxide (10%)
Toluene
Tide (1%)

+0.52
+1.74
+189.1
+3.67

113.9
107.0
23.8
109.8

94.3
85.0
17.1
89.8

+3
+1
-19
+2

Unchanged
Unchanged
Sf. Tacky
Unchanged

Lard
Methyl Ethyl Ketone
Perchloroethylcne
Potasswm Pwmanganate (25%)

Six Months Immersion at 75* 2 SF


Tansife sbength
Retained%

Elongation
Retained W

57.4
101.6
52.5
24.6
54.9

47.3
85.0
41.6
23.6
44.5

-5
-6
-19
-22
-17

SI. Tacky
Unchanged
Unchanged
SI. Tacky
Unchanged

+4.28
+1.26
+73.7
+58.4
+3.49

109.4
89.8
28.7
32.8
107.8

83.0
71.7
27.5
31.2
77.3

+3
0
-18
-15
0

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanged

+46.3
+52.9
+ 195.9
+9.31
+45.8

75.5
37.3
21.7
91.4
54.5

66.0
34.0
17.0
70.0
50.1

-16
-16
-17
-2
-18

Unchanged
Unchanged
SI. Tacky
Brittle
Unchanged

+1.25
+2.84

108.6
92.6
18.4
107.8

85.0
70.0
16.2
82.2

+3
f3
-20
+3

Unchanged
Unchanged
Sl. Tacky
Sf. Tacky

c
+19.6
+13.5
+88.2
+100.8
+a3.4

Aniline
A.S.T.M. No. 1 Oil
A.S.T.M. No. 3 011
Benzaldehyde
Dioctyl Phthalate
Distilled Water
Ethyl Alcohol
Ethyl Ether
Huane
Hydrochloric Acid (10%)
Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Pwmanganate
Skydrol 500

(25%)

Sodwm Chloride (25%)


Sodwm Hydroxide (10%)
Toluene
lade (1%)

+201.8
+4.75

Hardness
ChangePts.

Surface
Conditii

12 Months Immersion at 75* 2 SF


Vdume
Change%
Aniline
A.S.T.M. No. 1 Oil
A.S.T.M. No. 3 Oil
Benraldehydc
Dtoctyl Phthalate
Distilled Water
Ethyl Alcohd
Ethyl Ether
Hwane
Hydrochloric Acid (10%)

+26.5
+14.9
+87.8
+110.0
+78.3
+6.08
-l-O.42
+82.8
+52.7
+6.09

Lard
Methyl Ethyl Ketone
Perchloroethylene
Potasswm Permanganate (25%)
Skvdrol 500

+36.2
+57.3
+204.2
+11.2
+46.4

Sodaurn Chloride (25%)


Sodwm Hydroxide (10%)
Toluene
Tide (1%)

+0.11
+4.06
+166.6
+6.48

Tensile Sbength
ReteimdK

Elongatien
Ret&ted%

Hardness
Change&

Surface
CendRfen

57.4
96.7
53.3
16.0
49.2

56.7
82.2
45.3
21.8
41.7

-6
-7
-19
-21
-17

Y. Tacky
Unchanged
Unchanged
Y. Tacky
Unchanged

111.9
94.7
26.2
29.5
106.6

76.5
72.8
27.5
33.1
72.8

+4
+2
-17
-16
+3

Unchanged
Unchanged
Unchanged
Si. Tacky
Unchanged

62.7
25.4
21.7
77.9
47.5

64.7
27.5
19.8
55.8
47.3

-17
-16
-22
-4
-17

Unchanged
Unchanged
Unchanged
Brittle
Unchanacd

109.0
85.7
13.9
110.7

83.0
61.5
17.9
78.5

+4
+1
-21
+4

Unchanged
Unchanged
Sl. Tacky
St. Tacky

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS
CHEMICAL

AND RUBBERS-EXXON

RESISTANCE

CHEMICALS

331

(continued)

OF NITRILE RUBBER COMPOUND


72 Hours immersion at 212OF
Surface
Condition

Hardness
Change Pts.

Tensite strength
Retained K

Elongation
Ratainad K

17.8
118.6
104.4
20.6
60.1

21.7
79.4
83.0
19.9
55.2

-34
-1
-7
-28
-19

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

+7.16
+22.3
-t-33.5
+29.1
+9.71

117.4
52.6
53.0
62.9
66.4

97.5
49.8
51.6
62.9
57.8

-5
-10
-14
-16
-9

Unchanged
Unchanged
SI. Tacky
Unchanged
Unchanged

Hydrochloric Acid (10%)


Lard
Mathvl Ethvl Ketone
Pe~rchloroe~hylenc
Potassium Permanganate (25%)

+11.8
+0.41
+108.8
+51.4
-5.87

92.1
108.3
25.7
43.5
83.0

75.8
85.6
24.2
48.0
57.8

-4
-2
-24
-22
+1

Unchanged
Unchanged
Unchanged
Unchanged
V. Brittle

Skydrol 500
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Tolwne
Tide (1%)

+154.2
+1.09
+1.22
+124.8
$7.54

24.5
109.9
101.2
10.7
106.3

33.6
84.8
86.6
17.0
86.6

-34
-3
-5
-31
-5

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Vdume
Aniline
A.S.T.M. No. 1 Oil
A.S.T.M. No. 3 Oil
Benzaldehyde
Dioctyl Phthalate
Distilled Water
Ethyl Alcohol
Ethyl Ether
Gasoline (RON 99)
Hexane

chrne%
+250.9
-1.17
+11.3
+229.5
+54.1

One Month Immersion at 75 * SF


Surface
Condition

Ckarw%

Tarstic Sbwgth
Ratainad %

Elongation
Retaii
W

Amllne
A S.T.M No. 1 Oil
A.S.T.M. No. 3 Oil
Eenzaldehyde
Dioctyl Phthalate

+204.2
+2.69
+4.30
+198.2
+15.7

24.5
104.0
105.1
26.1
79.8

20.6
93.9
97.5
22.7
74.7

-23
-4
-7
-23
-10

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Drstilled Water
Ethyl Alcohol
Ethyl Ether
Gasoboe (RON 99)
Hexane

+2.51
+11.0
+21.8
+35.9
+11.0

109.5
86.2
53.8
80.2
85.4

103.6
82.0
55.2
78.3
83.0

-4
-11
-15
-13
-9

Unchanged
Unchanged
SI. Tacky
Unchanged
SI. Tacky

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganate (25%)

+1.44
+5.52
+128.2
+43.2
+1.68

102.8
105.5
26.1
60.5
110.3

97.5
100.0
24.2
60.3
109.4

-3
-3
-23
-18
-7

Unchanged
Unchanged
Unchanged
SI. Tacky
V. Brittle

Skydrol 500
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Tolwne
Tide (1%)

+X34.2
+0.71
+1.11
+112.4
+2.54

37.9
111.5
111.1
29.3
101.2

35.0
101.1
100.0
28.9
93.9

-24
-2
-2
-23
-3

Unchanged
Unchanged
Unchanged
St. Tacky
St. Tacky

Vduma

mree Months

TdkStmr@h
WnadW

Anihne
ASTM
No. 1 Oil
A.S.T.M. No. 3 Oil
Benzaldehyde
Dmctyl Phthalate

+211.8
-1.24
+4.54
+202.8
+37.4

29.6
110.7
109.1
M.6
71.2

Distilled Water
Ethyl Alcohol
Ethyl Ether
Gasolme (RON 99)
Hexane

+3.88
+10.6
+19.4
+18.6
+9.36

110.7
80.8
52.6
75.5
80.6

Hardness
Change Fts.

lmmarskrn at 75O 2 5*F


RoRgatim
lkwnad%

Rardness
Change Pts.

Surface
Condition

21.7
97.5
97.5
19.1
63.9

-22
-3
-3
-23
-18

Unchanged
Unchanged
Unchanged
SI. Tacky
St. Tacky

101.1
78.3
54.2
75.8
78.3

-3
-10
-16
-13
-8

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanged

(continued)

332

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Three Months Immersion at 75O % 5OF


Vdume
-_-___~.-Hydrochloric Acld (10%)
Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanaanate (25%)
Skydrol 500
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Toluene
Tide (1%)

Ch=w%

Tensile strength
Retained w

Elongation
Hardness
Retained SC ChangePts.

SlllfaCe
Condiion

+1.92
+1.02
+ 126.0
+55.8
+1.56

99.6
111.1
24.9
53.8
98.8

91.3
102.2
28.7
54.2
98.6

-4
+1
-22
-17
-4

Unchanged
Unchanged
Unchanged
Unchanged
Brittle

+150.9
+0.48
+1.73
+119.5
+3.55

36.4
114.2
96.8
28.9
1028

32.5
108.3
86.6
30.7
96.4

-23
0
-4
A23
-4

Unchanged
Unchanged
Unchanged
Unchanged
5l. Tacky

Six Months immersion at 75* 2 5F


volume
change %

Tensile Strength
Reteined W

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

An,t,fle
A S 1 M No 1 011
A S T M No 3 011
Benzaldehyde
Dmctyl Phthalate

+220.0
-0.21
-f-6.87
+191.0
+56.3

21.0
111.9
116.6
19.8
64.0

19.1
95.0
74.7
20.6
55.2

-25
-1
-4
-24
-18

Unchanged
Unchanged
Unchanged
Sl. Tacky
Unchanged

Dlstllled Water
Ethyl Alcohol
Ethyl Ether
Casolbne (RON 99)
Hexane

+5.44
+10.0
+34.5
+22.3
+9.20

105.9
84.2
49.8
77.1
79.1

93.9
77.6
49.5
75.8
72.2

-4
-10
-15
-Xi
-6

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanged

Hydrochloric Actd (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganate (25%)

+2.88
-0.71
+154.6
+43.6
+2.63

104.0
115.9
24.9
46.3
98.0

93.9
101.1
25.3
49.5
98.6

-3
+1
-24
-18
-6

Unchanged
Unchanged
Unchanged
Unchanged
Brittle

Skydrol 500
Sodium Chloride (25%)
Sodwm Hydroxide (10%)
Toluene
Tide (1%)

+142.6
+1.90
+1.60
+127.4
+5.79

35.6
107.9
94.9
27.7
104.7

35.0
90.3
79.4
27.8
93.9

-24
-3
-4
-23
-4

Unchanged
Unchanged
Unchanged
Sl. Tacky
Sl. Tacky

12 Months Immersion at 75O 2 5OF


volume
Change SC
Afl,ltIW

Tensile Strength
Retained %

Elongation
Retained K

Hardness
Change Pts.

5urlace
Condition

+230.1
-0.70
+9.00
+216.3
+53.0

17.4
105.9
94.1
20.6
64.8

22.7
87.7
79.4
24.2
57.8

-28

ASTM
No 1011
AS TM No 3011
Benraldehyde
Dtoclyl Phthalate

0
-5
-23
-18

Unchanged
Unchanged
Unchanged
SJ. Tacky
Unchanged

DMllled Water
Ethyl Alcohol
Ethyl Ether
Gasoline (RON 99)
Hexane

+6.92
+14.2
+38.0
+27.6
+26.9

108.3
81.8
55.3
72.7
85.8

92.8
75.8
55.2
72.2
76.9

-3
-9
-16
-14
-7

Unchanged
Unchanged
Unchanged
Y. Tacky
Unchanned

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganate (25%)

+3.25
+12.3
+151.6
+59.6
+ 1.92

106.3
107.1
24.9
57.7
97.2

86.6
92.8
25.3
55.2
89.2

-3
-2
-24
-18
-6

Unchanged
Unchanged
Unchanged
Unchanged
Brittle

Skydrol SO0
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Toluene
Tide (1%)

+ 147.7
+0.71
+7.04
+110.2
+8.02

33.6
111.1
89.7
24.5
102.0

35.0
97.5
73.3
28.9
89.2

-24
-1
-4
-24
-5

Unchanged
Unchanged
Unchanged
Unchanged
St. Tacky

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS
CHEMICAL

AND RUBBERS-EXXON

RESISTANCE

CHEMICALS

OF POLYCHLOROPRENE

and Elastomers

333

(continued)

COMPOUND

72 Hours Immersion at 212OF


Vduma
CharIRe K

Tensile Strength
Retained SC

Elongation
Retained X

Hardness
Change PM.

Surface
Condition

A.S.T.M. No. I 011


AS T.M. No. 3 011
8enzaldehyde
Diuctyl Phthalate

+ 143.3
+5.74
+61.7
+61.3
+116.6

22.9
100.0
46.1
25.0
39.1

58.3
88.3
67.3
40.4
61.4

-45
-4
-24
-35
-34

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Distilled Water
Ethyl Alcohol
Ethyl Ether
Gasoline (RON 99)
Hcxane

+9.34
+2.92
+49.5
+69.6
+24.5

97.2
85.6
44.7
41.2
78.5

85.2
79.4
53.8
58.3
80.7

-4
-4
-20
-28
-15

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

93.3
95.4
32.4
22.9
89.1

76.2
89.7
52.5
42.6
71.8

-8
-15
-28
-38
+2

Unchanged
Unchanged
Unchanged
Unchanged
V. Brittle

57.0
76.2
89.7
37.2
74.9

-45
+5
+1
-44
-9

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Andme

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanaanate (25%)

+15.1
+20.0
+72.3
i242.9
+3.07

Skydrol 500
Sodium Chloride (25%)
Sodaurn Hydroxide (10%)
Toluene
Tide (1%)

+151.0
+1.20
iO.24
+2D9.1
+11.6

17.3
95.8
101.4
15.9
91.6

One Month Immersion at 75O 2 5F


Elongation
Retained %

+67.3
+0.57
+19.5
+132.0
+77.1

63.0
110.9
91.9
30.6
56.7

76.2
100.0
85.2
40.4
58.3

-13
-25
-24

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanned

+3.67
+3.26
+49.8
+45.8
+19.4

112.7
97.5
41.2
57.8
86.3

106.3
91.0
52.5
62.8
80.7

0
-4
-20
-17
-13

Unchanged
Unchanged
Unchanged
Unchanaed
Unchanged

Lard
Methyl Elhyl Ketone
Perchloroethylene
Potassium Permanaanate (25%)

+2.65
+7.08
+70.6
+132.6
+4.16

107.8
104.2
32.4
31.0
108.8

95.5
98.7
52.5
37.2
97.3

+1
-8
-30
-23
-1

Unchanged
Unchanged
Unchanged
Unchanged
V. Brittle

Shydrol 500
Sodium Chlonde (25%)
Sodium Hydrorlde (10%)
Toluene
Tide (1%)

+115.6
+2.3G
+1.41
+141.5
+3.78

30.7
112.7
104.6
29.9
109.2

-31

Unchanged
Unchanged
Unchanged
Sf. Tacky
Unchanged

Amllne
A.S.T M No. 1011
A S T M No. 3 011
Benzaldehyde
Dmctyl Phthalate
Dlstllled
Water
Ethyl Alcohol
Ethyl Ether
Gasolme (RON 99)
Herane
Hydrochlonc

Acld

(10%)

Hardness
Changa Pts.

Surface
Condition

Tensile Strength
Retainad W

Vduma
challm K

53.8
97.3
94.2
35.9
100.0

-28
0

0
0
-24
$1

Three Months Immersion at 75O 2 5OF


Vdume
m%
Aniline
A.S.T.M. No. 1 Oil
A.S TM. No. 3 Oil
Benzaldehyde
Dtoctvl Phthalate

+67.8
+o.S4
+37.5
+146.2
+108.7

Dlstdled Water
Ethyl Alcohol
Ethyl Ether
Gasoline (RON 99)
Hexane

+6.35
+2.44
+54.8
+48.9
+21.1

Taleik stremglh
Rat&ad
50.0
108.1
87.0
24.7
46.1
114.4
94.0
46.8
60.9
70.1

Elmlgation
Retained%

Hardness
Change PM.

Surface
Condition

70.4
98.7
80.7
35.9
49.3

-27
+1
-15
-29
-25

Sf. Tacky
Unchanged
Unchanged
Sf. Tacky
Unchanned

94.2
86.6
60.5
68.6
77.6

0
-4
-23
-19
-12

Unchanged
Unchanged
Unchanged
Unchanaed
~
Unchanged

(continued)

334

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Three Months Immersion at 75O 5 SF


Volume
Change K

Tensile strength
Retained %

Elongation
Retained W

Hardness
Change Pts.

Surface
Condition

Hydrochlortc Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylcne
Potasswm Permanaanate (25%)

+4.09
+14.4
+85.5
+132.5
+7.22

108.8
110.9
29.5
32.8
112.0

95.5
103.1
51.6
37.2
95.5

+1
-10
-30
-24
0

Unchanged
Unchanged
Unchanged
Unchanged
SI. Brittle

Skydrol 5DO
Sodwm Chloride (25%)
Sodium Hydroxtde (10%)
Toluene
Tide (1%)

+X30.6
+2.53
+3.17
+166.5
+5.99

32.0
116.2
103.5
28.9
107.0

53.8
97.3
92.8
35.9
94.2

-35
+1
-5
-25
0

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Six Months Immersion at 75* 2 5OF


VdUtlW
Change K

Tensile Sb-ength
Retained W

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

AnlIme
A S.T.M No. 1 011
A.S.T M No 3 011
Etenzaldehyde
D~octyl Phthalate

+62.7
+1.20
+44.2
+156.4
+114.4

51.4
112.3
91.9
20.1
48.6

77.6
101.8
83.0
39.0
50.7

-29
+1
-20
-35
-26

SI. Tacky
Unchanged
Unchanged
Unchanged
Unchanged

Dlstllled Water
Ethyl Alcohol
Ethyl Ether
Gasolme (RON 99)
Hexane

+10.5
+2.48
+51.9
+50.7
+20.3

94.7
90.1
38.4
50.7
75.7

80.7
69.7
57.0
64.1
73.1

-4
-5
-25
-20
-12

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Hydrochlcr!c Actid(10%)
Lard
Methyl Ethyl Ketone
Perchloroethylene
Potasswm Permanganate (25%)

+5.77
+15.5
+92.8
+ 142.9
i9.72

102.1
107.4
23.2
26.8
106.7

85.2
94.2
49.3
31.4
83.9

-1
-14
-34
-29
-2

Unchanged
Unchanged
Unchanged
Unchanged
Sl. Brittle

Skydrol 500
Sodwm Chlorlde (25%)
Sodwm Hydrorlde (10%)
Toluene
Tide (1%)

+142.3
+3.02
+3.87
+204.2
+9.42

25.0
112.3
95.8
23.2
91.2

53.8
94.2
86.6
31.4
77.6

-40
+2
0
-28
-3

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

12 Months Immersion at 75O 2 5OF


Vduma
Change K

Tensile strength
Retained %

Elongation
Rabined%

HarW
Chanp
-38

Pts.

sulfaa
Condition

Aniline
A.S.T ht. No. 1 011
A.S T M. No. 3 011
Benzaldehyde
D~octvl Phthalate

+65.9
+1.10
+43.8
+190.0
+125.5

28.2
96.9
70.5
7.4
38.7

67.3
94.2
79.4
35.9
49.3

-19
-51
-29

SI Tacky
Unchanged
Unchanged
SI. Tacky
Unchanged

Dtstllled Water
Ethyl Alcohol
Ethyl Ether
Gasolme (RON 99)
Hexane

+ia7
+6.05
+56.8
+54.6
+20.8

79.6
89.8
34.5
47.9
65.1

70.4
86.6
59.6
67.3
70.4

-8
-4
-29
-23
-13

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylene
Potassium Permanganate (25%)

+9.13
+17.5
+94.4
+147.5
+ 13.0

95.8
94.0
21.5
25.0
90.5

73.1
95.5
55.2
37.2
70.4

0
-14
-38
-31
-4

Unchanged
Unchanged
Unchanged
Unchanged
SI. Brittle

Skydrol 500
Sodium Chlonde (25%)
Sodaurn Hydrorlde (10%)
Toluene
T#de (1%)

+156.7
+1.81
+3.99
+171.5
+12.3

la7
104.6
816
20.4
84.2

57.0
83.9
73.1
35.9
64.1

-43
-7
+1
-34
0

Unchanged
Unchanged
Unchanged
SI. Tacky
Unchanged

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

CHEMICAL

RESISTANCE

AND RUBBERS-EXXON

CHEMICALS

(continued)

OF CHLOROSULFONATED

POLYETHYLENE

COMPOUND

72 Hours Immersion
VdUmC

change K

335

at 212-F

Tensile Strength
Retainad K

Elogatio
Retained K

Hardness
Change Pts.

Surface
Condition

Aniline
A.S.T.M. No. 1 011
A.S.T.M. No. 3 011
Benraldehyde
Duxtyl Phthalate

+ 147.4
+6.59
+66.9
+40.4
+ 125.3

86.4
73.3
49.6
20.1
28.4

73.9
35.3
114.5
29.0
49.8

-54
+4
-21
-30
-29

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Distilled Water
Ethyl Alcohol
Ethyl Ether
Basoltne (RON 99)
Hexane

+9.43
+4.80
+44.9
+104.7
+24.7

97.2
81.1
34.5
25.4
49.3

80.7
82.1
48.3
53.1
62.8

-4
-6
-17
-30
-14

SI. Brittle
Unchanged
Unchanged
Unchanged
Unchanged

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Penhloroethylene
Potassium Pennanganate (25%)

+4.25
+20.3
+61.2
+150.2
+7.74

103.9
76.3
27.3
22.3
100.8

88.4
77.3
40.1
37.2
80.7

-1
-11
-24
-30
-5

Unchanged
Unchanged
Unchanged
Unchanged
SI. Brittle

Skydrol5DO
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Toluene
Tide (1%)

+108.7
+1.14
+1.07
+171.1
+8.65

23.1
99.7
96.1
17.8
85.0

44.9
83.6
78.7
36.2
73.9

-32
-1

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

0
-37
-5

One kkmth Immersion at 75 5 5OF


Vdume
Ctwv%

Tensile strength
Retained 54

Elongation
Retained %

Hardness
Change Pk.

Surface
Condition

AmIme
A S 1 M. No 1 011
A S T.M No 3 011
Benraldehyde
D~octyl Phthalate

+63.1
+0.59
+B.O2
+117.4
+40.3

47.6
104.7
82.5
28.4
56.6

67.6
101.5
82.1
33.8
61.4

-18
-3
-16
-21

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

DMllled Water
Ethyl Alcohol
Ethyl Ether
GasdIne (RON 99)
Hexane

+1.17
+2.51
+43.0
+48.4
+22.1

104.5
97.5
28.7
37.8
57.7

x30.0
98.1
46.9
51.7
67.6

+1
-4
-18
-20
-11

Unchanged
St. Tacky
SI. Tacky
Tacky
Unchanged

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroethylene
Potasswm Pennanganate (25%)

+1.80
+5.04
+70.0
+112.7
+2.50

109.8
81.9
32.3
27.6
109.8

102.9
85.5
43.5
37.2
101.5

+3
-2
-16
-6
0

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Skydrol 500
Sodwm Chloride (25%)
Sodium Hydroxide (10%)
Tolucne
Tide (1%)

+88.0
-0.23
+0.58
+128.8
+1.98

40.4
109.2
109.5
25.6
108.1

44.9
98.1
114.5
33.8
100.0

-19
+1
+2
-18
+2

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Three Months
Vdunm
ChrnOls%

T-=-m
RM8MW

knmerrion

&nation
Rabined%

at 75

!TF

Hardms
Chanm Pk.

Surface
Condiin

AmIme
A.S.T.M. No. 1011
A.ST.M No 3011
Benzaldehyde
Dmctvl Phthalate

+64.1
+0.34
+1a.2
+115.2
+115.5

38.7
108.6
74.9
25.4
43.7

61.4
96.7
75.7
33.8
42.0

-20
+2
-9
-19
-16

sl. T8cky
Unchanged
Unchanged
Unchanged
Unchanned

Olstllled Water
Ethyl Alcohol
Ethyl Ether
Gasoirne (RON 99)

+2.45
+5.50
+45.6
+51.7
+23.6

109.6
94.4
35.1
37.9
47.6

88.4
90.3
51.7
53.1
59.4

+2
-2
-16
-19
-11

Unchanged
Unchanged
V. Tacky
Tackv
Unchanged

Herane

(continued)

336

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Three Months Immersion at 75 * 5OF


volume
Change W

Tenrite Strength
Retained <

Elongation
Retried %

Hardness
Change Pts.

Surfs

Condiiien

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Parchloroathvtene
Potassium Pennanganatc (25%)

+2.36
+7.56
+68.4
+125.5
+4.17

108.6
96.1
28.1
281
115.9

98.1
90.3
40.1
33.8
98.1

+2
-4
-16
-18
+4

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

Skydrol 500
Sodium Chloride (25%)
Sodium Hydroxide (10%)
Toluenc
Tide (1%)

+87.8
l Fo.23
l Fo.93
i-135.4
+3.95

42.1
116.4
99.7
23.7
107.8

44.9
99.0
90.3
32.4
96.7

-17
+5
0
-18
+1

Unchanged
Unchanged
Unchanged
Unchanged
SJ. Tacky

volume
Chenge W

Tensik Strengtft
Retained W

Elongation
Retained K

35.1
109.8
77.7
28.4
41.0

62.8
93.2
82.1
37.2
42.0

-22
+2
-10
-20
-17

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

113.9
98.6
33.7
35.1
60.2

91.8
91.8
51.7
58.0
62.8

0
-3
-18
-20
-11

Unchanged
SI. Tacky
Tacky
Tacky
Unchanged

Six Months Immersion at 75O 2 5OF

Anlllnt
A ST M No. I 011
A S 1 M No 3 011
Benraldehyde
D~octyl Phthalatc
Dtst~llcd

Water

Ethyl Alcohol
Ethyl Ether
Gasoline (RON 99)
Hexanc

+62.0
+0.44
+3G.3
+103.8
+ 122.8
+5.13
+6.54
-t-46.0
+51.1
+23.6

Hardness
Change Pts.

surface
Condition

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Perchloroathylene
Potasswm Permanganate (25%)

+3.27
+16.4
+68.4
+1G9.0
+6.80

108.1
86.6
29.5
25.1
111.4

95.2
84.5
42.0
30.4
90.3

+2
-7
-17
-19
+1

Unchanged
Unchanged
Unchanged
Unchanged
SI. Brittle

Skydrol 500
Sodium Chloride (25%)
So&urn Hydroxide (1.0%)
Toluana
Tide (1%)

+ 102.2
+0.46
+1.28
+143.6
+5.16

40.1
113.9
107.0
26.7
104.2

48.3
95.2
90.3
33.8
88.4

-19
+3
+2
-18
+2

Unchanged
Unchanged
Unchanged
Unchanged
SI. Tacky

12 Months Immersion at 75O -C 5OF


Tensite Strength
Retained K

Elongation
Rtiained K

+71.8
+0.59
+40.3
+119.8
+110.5

26.2
108.6
72.4
24.5
39.8

64.3
95.2
75.9
37.2
43.5

-29
+2
-12
-21
-20

Unchanged
Unchanged
Unchanged
Unchanged
Unchanged

+6.86
+5.53

116.2
101.7

87.0
91.8

0
-11

Unchanged
Si. Tacky

+47.8
+51.8
+25.0

33.9
32.3
54.6

58.0
51.7
66.2

-19
-19
-11

Tacky
Tacky
Unchanged

Hydrochloric Acid (10%)


Lard
Methyl Ethyl Ketone
Parchloroathylcne
Potaswm Permanganata (25%)

+16.1
+24.9
+86.0
+105.7
+8.83

114.2
75.2
28.1
24.5
114.2

90.3
78.7
42.0
37.2
87.0

+4
-10
-20
-20
+1

Unchanged
Unchangad
Unchanged
Unchanged
St. Brittle

Skydrol 500
Sodwm Chloride (25%)
Sodium Hydroxtde (10%)
Tolucne
Tide (1%)

+88.6
+1.03
+X52
+188.0
+9.11

32.9
115.9
110.3
24.5
112.3

48.3
93.2
90.3
35.3
82.1

-19
+4
-l-4
-2G
0

Unchanged
Unchanged
Unchanged
St. Tacky
Unchanged

Volume
Change K
AflhW

A S 1 M No. 1 011
ASTM
No 3011
Benraldehydc
Dwtvl Phthalatc
Dlstdled Water
Ethyl Alcohol
Ethyl Ether
Gasolme (RON 99)
Hexane

Hardness
Change Pts.

Surface
Condition

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

CHEMICAL

AND RUBBERS-EXXON

RESISTANCE

OF V&TALON

CHEMICALS

Tensile Strength
Retained %

(continued)

6505 COMPOUND

72 Hours
Volume
Change X

and Elastomers

Immersion

at 2 12F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A.S.T.t.4

No. 1011

+ 129.3

30.8

45.9

-37

SI. Tacky

A.S.T.M.

No. 3 011

+ 222.4

20.9

29.5

-44

SI. Tacky

A.S.T.M.

Fuel B

Unchanged

+ 171.9

14.1

21.3

-11

Dtistllled Water

+0.5

93.2

77.0

+l

Unchanged

Ethyl Alcohol

-4.6

87.5

82.0

+3

Unchanged

Unchanged

Hexane

+69.0

18.6

24.6

+2

Hydrochloric Acid (10%)

+ 10.4

66.9

57.4

-2

Unchanged

Methyl Ethyl Ketone

+ 10.7

62.7

70.5

-9

Unchanged

Olive Oil

+41.6

55.1

65.6

-27

SI. Tacky

Skydrol 500

+5.5

98.1

88.5

-9

SI. Tacky

Sodium Chloride (25%)

+2.8

88.6

75.4

+l

Sodium Hydroxide (lD%)

-0.4

93.9

75.7

Trde (1%)

+0.6

89.7

75.4

One Month
Volume
Change %

Tensile Stmngth
Retained %

immersion

0
-1

Unchanged
Unchanged
Unchanged

at 79 2 5F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

1011

+42.8

40.3

49.2

-18

Unchanged

A S 1 M No 3 Oti

+ 162.3

25.5

24.6

-29

Unchanged

ASTM

+ 168.7

ASTM

No

Fuel B

Drstllled Water

+ 1.25

Ethyl Alcohol

+1.9

19.0

23.0

-27

Unchanged

111.0

96.7

-2

Unchanged

98.9

95.1

-5

Unchanged

+159.9

20.2

23.0

-26

Unchanged

+1.2

107.2

101.6

-2

Unchanged

+3.1

82.9

90.2

-10

White Res.

14.6

81.0

85.3

-9

Unchanged

-1.8

103.0

101.6

-4

V. Tacky

Sodrum Chlonde (25%)

+0.6

97.3

loo.0

-2

White Res.

Sodwm Hydroxtde (10%)

+O.l

95.8

95.1

-3

Unchanged

Tide (1%)

+0.7

92.0

95.1

Hexane
Hydrochlonc Acid (10%)
Methyl Ethyl Ketone
Olive 011
Skydrol 5DO

Unchanged

337

338

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND

RUBBERS-EXXON

CHEMICALS

(continued)

Three Months Immersion at 75 2 5F


Volume
Change K
ASTM

No

1011

Tensile Strength
Retained %

Elosgation
Retained %

Hardness
Change Pts.

Surface
Condition

t83.7

36.1

42.6

-26

A S T M. No. 3 011

t 175.0

24.3

26.2

-27

Unchanged

A S T M. Fuel El

7183.3

17.9

16.4

-30

Uuchange?d

Drstrlled Water

-0.9

98.1

96.7

Ethyl Alcohol

+i.2

88.9

93.4

-4

Unchanged

Unchanged

Hexane

+ 152.6

Hydrochlonc

Actd (10%)

Methyl Ethyl Ketone


Olrve 011
Skydrol 500

Sodrum Hydroxide (10~)


Tide

( 1%)

Unchanged

20.5

22.9

-29

t1.7

108.4

95.1

cl

+2.7

77.6

83.6

+25.4

76.8

85.2

-16

Unchanged

104.2

96.8

-2

Unchanged

-2.2

Sodwm Chlonde (25.)

Unchanged

Unchanged
7

Unchanged

91.2

88.5

-0

Unchanged

-0.2

98.5

96.7

+l

Unchanged

+0.2

85.2

90.2

Unchanged

Six Months Immersion at 75 + 5F


Volume
Change %
S TM

No

AS TM

No

3011

Oil

A S 1 M Fuel 8

Tensile Strength
Retained K

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

+115.3

36.1

42.0

-27

Unchanged

t 198.9

27.8

27.9

-31

Unchanged
Unchanged

+211.0

18.6

18.0

-31

Dlstrlled Water

-0.5

98.5

98.4

+I

Unchanged

Ethyl Alcohol

+1.25

82.1

88.5

-2

Unchanged

Hexane
Hydrochlonc

Acrd (100.)

Methyl Ethyl Ketone


Olive Oil

+192.1

19.4

23.0

-28

+0.6

98.9

95.1

+l

Unchanged

t2.8

82.5

86.9

-5

Unchanged

+29.0

Skydrol 500

(25%)

Sodrum Hydroxrde

I ~WC.)

Trde (1%)

CHEMICAL

73.8

83.6

-15

Unchanged

100.0

95.1

-2

Unchanged

-0.2

94.3

91.8

+2

Unchanged

98.5

93.4

+l

Unchanged

+0.4

92.8

93.4

Unchanged

-2.6

Sodium.Chlonde

RESISTANCE

Unchanged

OF 30 VISTALON

6505170

BUTYL

RUBBER

BLEND

COMPOUND

72 Hours Immersion at 212f


Volume
Change X

Tensile Strength
Retained X

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1 Oil

+ 68.2

57.6

57.1

-25

SI. Tacky

A.S.T.M.

No. 3 011

+ 136.9

36.6

35.7

-28

SI. Tacky

A.S.T.M.

Fuel 8

+ 133.7

-27

30.2

35.7

Dishtled Water

+2.2

98.8

92.9

Etnyl Akohol

-2.0

91.9

78.6

Unchanged
0

+l

Unchanged
Unchanged
(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

72 Hours
Volume
Change %
Hexane

Tensile Strength
Retained %

CHEMICALS

Elongation
Retained %

35.5

35.7

+7.1

88.4

75.0

Methyl Ethyl Ketone

+12.8

68.0

Olwe 011

+28.1

71.5

Skydrol 500

+a.5

Sodium Chlonde (25%)


Sodwm Hydroxide (10%)
Tide (1%)

A S 1 h4 No

1 011

No 3011

A.S 1 M Fuel 8

Hardness
Change Pts.
-5

Surface
Condition
Unchanged
Unchanged

71.4

- 12

Unchanged

78.6

-20

SI. Tacky

84.3

85.7

-12

SI. Tacky

+0.8

100.6

85.7

+l

Unchanged

-0.1

95.9

85.7

-1

Unchanged

+0.9

92.4

82.1

-2

Unchanged

at 75

One Month Immersion

AS TM

(continued)

z SF
Surface
Condition

Tensile Strength
Retained %

Elongation
Retained %

+15.1

73.8

71.4

-8

Unchanged

+67.9

49.4

50.0

-16

Unahanged

Volume
Change %

Hardness
Change Pts.

+117.2

34.9

32.1

-19

Unchanged

DIstilled Water

+2.5

98.3

92.9

-1

Unchanged

Etnyl Alcohol

+2.5

94.2

92.9

-2

Unchanged

+ 104.6

33.1

32.1

-18

Unchanged

+0.2

101.7

96.4

Methyl Ethyl Ketone

+5.7

74.4

78.6

-8

White Res.

Olwe 011

+5.3

93.6

92.9

-5

Unchanged

Skydrol 500

+0.4

94.8

?07.1

-2

V. Tacky

Herane
Hydrochloric

Aild (10%)

Unchanged

Sodurn Chloride (25:0)

+O.l

95.3

96.4

-1

White Res.

Sodium Hydrorlde

+0.2

102.3

100.0

-2

Unchanged

+0.2

100.5

100.0

Volume
Change %

Tensile Strength
Retained %

Elongation
Retained %

+29.0

Tide

(1OQ

I looI

339

Immersion
at 212F

+51.9

Hydrochlonc Acid (10%)

and Elastomers

Unchanged

Three Months Immersion at 75 II sF

1 011

A.S.7.M

No.

A.S.1.M

No. 3 011

A S.T.M. fuel 8

Hardness
Change Pts.

Surface
Condition

66.9

64.3

-12

+ 108.6

45.4

42.9

-17

Unchanged

+ 132.3

34.3

32.1

-21

Unchanged

Unchanged

DistIlled Water

-0.4

100.0

96.4

+l

Unchanged

Ethyl Alcohol

-1.8

91.9

89.3

-2

Unchanged

Unchanged

Herane

+117.3

37.8

35.7

-18

Hydrochlortc Acld (10%)

+0.5

95.9

96.4

+l

Unchanged

Methyl Ethyl Ketone

+6.5

75.0

82.1

-7

Unchanged

Olwe 011

+ 10.6

85.5

89.3

-8

Unchanged

Skydrol 5DO

io.4

97.7

96.4

-3

Unchanged

Sodwm Chloride (25%)

-0.11

97.1

78.6

92.4

89.3

+0.3

94.8

85.7

Sodurn Hydroxide (10%)


Tide (lo.1

Unchanged

+l

Unchanged

Unchanged

(continued)

340

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

Sir Months Immersion


Volume
Change %

Tensile Strength
Retained %

at 75

Elongation
Retained %

(continued)

z SF
Hardness
Change Pts.

Surface
Condition

A.S T.M. No. 1011

+45.2

59.9

60.7

-17

Unchanged

A S T.M. No. 3 011

+ 118.0

45.3

39.3

-20

Unchanged

A.S.1.M

+151.1

33.7

28.6

-19

Unchanged

-0.1

97.7

100.0

+1.7

89.0

85.7

Fuel 8

Dlstllled

Water

Etnyl Alcohol

Hexane
Hydrochlonc
Methyl

Acid CIOO~l

Elhyl Ketone

Olwe 011
Skydrol

500

Sodwm

Chlonde

(2!X.)

Sodaurn Hydroxide
Tide

(I@41

(1%)

CHEMICAL

RESISTANCE

+l

37.8

32.1

-18

Unchanged

+0.5

98.9

92.9

-8

Unchanged

+5.9

79.7

82.1

-7

Unchanged

+15.8

87.2

92.9

-9

Unchanged

+o. 1

94.2

92.9

-3

Unchanged

-0.3

98.8

92.9

+3

Unchanged

93.0

89.3

+2

Unchanged

+0.3

97.7

96.4

+l

Unchanged

OF 30 VISTALON

6505170 VISTALON

2504 BLEND COMPOUND

72 Hours Immersion

No. 1011

Unchanged

+159.0

Volume
Change %
A.S.T.M.

Whrte Res.

at 2 12F

Tensile Strength
Retained %

Elongation
Retained %

HarrJness
Change Pts.

Surface
Condition

c94.7

59.6

63.0

-27

SI. Tacky

A.S.T M. No. 3 011

+ 141.0

37.3

40.7

-32

SI. Tacky

A.S.T M Fuel 8

+ 138.0

bstllled

Water

Ethyl Alcohol

Hexane
Hydrochloric
Methyl

Acid (10%)

Ethyl Ketone

Okve 011
Skydrol

500

Sodium Chlonde

(25%)

Sodium Hydroxide

(10%)

Tide (1%)

32.4

33.3

-12

Unchanged

-13.0

105.9

92.6

-1

Unchanged

-2.7

94.5

85.2

+49.8

40.5

37.0

-2

+12.2

89.3

74.1

-4

Unchanged

+11.9

73.0

77.8

-10

Unchanged

+34.9

68.6

74.1

-22

SI. Tacky

+8.4

91.9

96.3

-10

SI. Tacky

+1.7

106.5

88.9

+0.3

105.4

107.4

+l

Unchanged

co.2

98.8

88.9

-2

Unchanged

One Month
Volume
Change %

Tensile Strength
Retained %

immersion

Unchanged

Unchanged

Unchanged

at 75 2 5F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A S 1 M No

I 011

+42.3

68.1

66.7

-15

Unchanged

AS

3011

+114.0

47.0

40.7

-21

Unchanged

+126.5

30.8

29.6

-21

Unchanged

+l.l

105.9

107.4

-1

Unchanged

+1.9

101.6

96.3

-4

Unchanged

TM

No

A S T M Fuel I3
Dlstllled

Water

Ethyl Alcohol

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

One Month
Volume
Change %
Hexane

+115.7

Hydrochior,c
Methyl

Acjd (IO,)

Ethyl Ketone

Olive 011
Skydrol

500

Sodturn Chloride

(250,)

(10.)

Sodaurn Hydroxtde
Tide Cl,)

CHEMICALS

Elongation
Retained %

37.8

+0.5

011

85.4

96.3

-9

Unchanged

+0.6

101.6

103.7

-4

V. Tacky

104.3

107.4

-2

White Res.

+0.2

104.3

100.0

-2

Unchanged

+0.4

101.1

100.0

-1

Unchanged

+69.5

+o. 1
+1.2

t 121.9

Herane

Methyl

Acid

I lo.)

Ethyl Ketone

Olive 011
Skydrol

500

Sodbum Chloride (25%)

(lO.l

Sodium Hydroxide
Tide (loo)

White Res.

+0.3

+135.6

Hydrochloric

Unchanged

+ 14.9

A S 1 M Fuel B

Ethyl Alcohol

-3
-8

+ 123.9

Waler

Unchanged

111.1
100.0

A S I M No 3 011

Dlst!lled

Surface
Condition

89.1

Three Months

No

2 5F
Hardness
Change pts.
-18

29.6

107.0

(continued)

+5.6

Volume
Change %
A !, 1 M

at 75

Immersion

Tensile Strength
Retained %

and Elastomers

Tensile Strength
Retained %

Immersion
Elongation
Retained %

at 75 2 5F
Hardness
Channe Pts.

Surface
Condition

64.2

62.9

-19

Unchanged

47.0

40.7

- 19

Unchanged

-22

White Res.

33.5

25.9

106.5

103.7

97.3

92.6

-2

33.3

-20

42.2
102.7

96.3

Unchanged
Unchanged

White Res.
Unchanged

88.7

85.2

-7

Unchanged

t23.9

82.7

92.6

-13

Unchanged

-0.6

101.6

100.0

-3

Unchanged

+O.l

98.4

81.5

Unchanged

+O.?

98.9

92.6

Unchanged

+0.08

103.8

100.0

+7.0

Six Months
Volume
Change %

Tensile Strength
Retained %

immersion

-1

Unchanged

at 75 + 5F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

I 011

t 100.6

58.9

55.6

-20

Unchanged

A S 1 M No 3 011

t 122.1

46.5

37.0

-23

Unchanged

A S T M Fuel B

+156.8

34.6

29.6

-22

White Res.

+0.4

103.8

103.7

White Res.

+2.4

101.6

100.0

Unchanged

+157.3

42.2

37.0

+0.5

99.5

85.2

Unchanged

A !z, T M No

Dwllled

Waler

Ethyl Alcohol

Hexane
Hydrochlonc
Methyl

Acid (lo,)

Ethyl Ketone

Olive DII
Skydrol

500

Sodlum Chlonde (25%


Sodwm

Hydroxide

Tide (1%)

(:O%)

-20

White Res.

+5.6

88.1

85.2

-8

Unchanged

t26.2

86.5

81.5

-13

Unchanged

-0.2

102.2

100.0

-3

Unchanged

+l

White Res.

-0.3

104.3

100.0

+0.3

105.4

100.0

Unchanged

+0.9

103.2

96.3

Unchanged
(continued)

341

342

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS
RESISTANCE

AND

RUBBERS-EXXON

OF 30 VISTALON

CHEMICALS

NATURAL

6505170

RUBBER BLEND COMPOUND

72 Hours lmmersron
Volume
Change %
A.S.1 M No

1011

Tensile Strength
Retained %

(continued)

at 212F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

+ 121.5

42.3

54.0

-37

SI. Tacky

A.S T M. No. 3 011

b232.4

12.6

25.8

-45

SI. Tacky

A S.T.M. Fuel 8

+ 155.9

18.1

22.6

-38

Unchanged

+3.5

101.5

93.5

- 1.2

104.8

96.8

+l

Unchanged

Unchanged

D,stllled

Water

Ethyl Alcohol

Hexane

Unchanged

+39.5

31.8

38.7

-4

+ 16.4

74.1

67.7

-4

Unchanged

+37.8

59.4

67.7

+3

Unchanged

Olrve 011

+ 76.6

48.8

61.3

-31

SI. Tacky

Skydrol

+35.7

55.4

90.3

-28

SI. Tacky

Hydrochlonc
Methyl

Acid (lo.)

Ethyl Ketone

500

Sodium Chloride
Sodwm
Tide

(25%)

Hydroxide

(10%)

(1%)

+0.2

107.6

93.5

+l

Unchanged

co.9

98.8

90.3

-1

Unchanged

+3.1

109.2

97.8

-2

Unchanged

One Month Immersion at 75 = 5F


Volume
Change %

Tensile Strength
Retainrd %

A.S T M No. 1011

+37.2

61.5

64.5

-7

Unchanged

A.S.T M No. 3 011

+ 141.8

41.2

41.9

-25

Unchanged

A S.T.M.

+178.9

18.1

16.1

-2

Unchanged

+1.7

111.4

100.0

-1

Unchanged

+3.1

105.9

103.2

-6

Unchanged

Fuel B

Dlstrlled

Water

Ethyl Alcohol

Hexane

Elongation
Retained %

Hardness
Change Rts.

Surface
Condition

+ 131.4

32.4

38.7

-24

Unchanged

+l.l

110.3

106.5

-1

Unchanged

+34.0

47.2

58.1

-17

White Res.

Olwe 011

+45.4

65.9

64.5

-14

Unchanged

Skydrol

500

+ 13.9

77.9

83.9

-4

Sodwm

Chloride

+O.l

105.9

106.5

+2

White Res.

Sodlum

Hydroxide

116.9

112.9

-2

Unchanged

+0.9

107.0

103.2

Hydrochlorrc
Methyl

Acid (10%)

Ethyl Ketone

(25%)

Trde (1%)

(10%)

Three Months
Volume
Charwe %

Tensile Strength
Retained %

V. Tacky

Unchanged

Immersion at 75 z 5F
Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1011

+64.3

60.4

61.3

-20

A.S.T.M.

No. 3 Ori

+157.1

39.0

38.7

-25

Unchanged

A.S.T.M.

Fuel 6

+ 193.5

23.1

29.0

-32

Unchanged

Drstrlled Water

+I.5

114.7

106.5

Ethyl Alcohol

+2.4

84.5

96.8

Unchanged

0
-4

Unchanged
Unchanged

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

and Elastomers

(continued

Three Months Immersion at 75 2 5F


Volume
Change %

Hexane

t141.3

Hydrochloric Acid (10%)


Methyl Ethyl Ketone

Tensile Strength
Retained %

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

31.3

35.5

--20

+1.4

100.4

96.8

+l

Unchanged
Unchanged

+35.1

52.7

74.2

-21

Unchanged

Olive 011

+63.4

53.2

54.8

-23

Unchanged

Shydrol 500

+16.5

65.9

77.4

-13

Unchanged

+l

Unchanged

Sodwm Chlorrde (25~~~)

-0.1

104.3

80.7

( 10o)

+0.5

104.8

93.6

Unchanged

+1.7

104.8

100.0

Unchanged

Sodrum Hydroxide
Tide

1loa)

Six Months Immersion at 75 + 5F


Volume
Change %

Tensile Strength
Retained X

Elongation
Retained %

Hardness
Change Pk.

Surface
Condition

ASTM

No 1011

+79.0

57.6

58.1

-25

Unchanged

AS TM

No 3011

+ 161.8

41.2

41.9

-29

Unchanged

AS TM

Fuel 8

-258.2

19.2

29.0

-33

Unchanged

Dtstllled Water

+1.9

107.0

Ethyl Alcohol

+2.4

Hexane

+ 189.9

Hydrochlonc

Acrd (10%)

Methyl Ethyl Ketone

100 0

Al

Unchanged

58.7

74.2

-3

Unchanged

24.1

29.0

-29

Unchanged
Unchanged

+1.8

103.2

96.8

+l

+41.1

24.7

54.8

-25

Unchanged
Unchanged
Unchanged

Ohve 011

+72.7

65.9

61.3

-23

Skydrol 500

+21.8

39.5

64.5

-17

Sodrum Chlonde (25%)

-0.3

101.0

90.3

+2

Sodrum Hydroxrde (10%)

+0.7

98.2

87.1

42

Unchanged

Trde (1%)

+2.2

110.3

100.0

+l

Unchanged

CHEMICAL

Unchanged

RESISTANCE OF 30 VISTALON 6505170 SBR BLEND COMPOUND


72 Hours Immersion at 212F
Volume
Channe %

Tensile Strength
Retained %

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1 011

+ 41.8

74.9

66.7

-17

SI. Tacky

A.S.T.M.

No. 3 011

+ 107.0

50.7

42.9

-22

Sl. Tacky

A.S.T.M.

Fuel B

+115.1

16.8

28.6

-23

Unchanged

Drstilled Water

+5.3

97.7

95.2

-1

Unchanged

Ethyl Alcohol

-2.1

87.5

81.0

-1

Unchanged

Unchanged

Hexane

+ 28.8

39.6

42.9

-2

Hydrochloric Acid (10%)

+ 12.8

94.9

76.2

-2

Unchanged

+4

Unchanged

Metnyl Ethyl Ketone

+30.6

55.4

57.1

Olrve 011

+39.4

67.0

61.9

-18

SI. Tacky

Skydrol 500

+37.7

64.7

66.7

-19

SI. Tacky

Sodrum Chlonde (25%)

+2.7

102.4

85.7

Unchanged

Sodrum Hydroxtde (10%)

+0.6

104.2

85.7

Unchanged

Trde (1%)

+5.3

101.9

85.7

-1

Unchanged
(continued)

344

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

One Month

AS 1 M No

1011

A S 1 M No 3 011
ASTM

Fuel 8

Dlstllled
Ethyl

Water

Hydrochloric
Methyl

Acld (10%)

Ethyl Ketone

at 75 z 5F

Elongation
Retained %

Hardness
Change Pts.

surtrcc
Condition

Tensile Strength
Retained K

+13.1

91.2

90.5

+84.9

53.1

47.6

-17

Unchanged

+ 105.8

34.4

38.1

-17

Unchkged

105.6

95.2

-2

Unchanged

94.9

90.1

-3

Unchanged

+2.8

Hexane

Immersion

(continued)

Vdume
Change X

+2.86

Alcohol

CHEMICALS

-7

Unchanged

+75.7

40.9

33.3

-16

Unchanged

+1.8

106.6

109.5

-2

Unchanged

+31.9

53.5

57.1

-12

Olwe 011

+22.5

81.9

76.2

-8

Unchanged

Skydrol

500

+21.9

77.7

76.2

-8

V. Tacky

Sodun

Chloride

+0.5

103.7

100.0

-2

White Res.

Sodium

Hydroxide

+1.2

106.9

109.5

-2

Unchanged

+1.3

93.0

95.2

(25%)

L10%)

Tide (1%)

ihrea

AS

1 M

Month

Volume
Change X

Tensile Strength
Retained K

White Res.

Immersion
Elongation
Retained X

Unchanged

at 75 : SF
Hardness
Change Pts.

Surface
Condition

No

1011

+23.4

77.7

71.4

-11

Unchanged

A S 1 M No

3 011

+98.2

54.9

47.6

-16

Unchanged

+ 108.7

36.8

33.3

-18

+2.6

100.1

95.2

+3.1

94.5

100.0

-3

Unchanged

+82.9

42.8

38.1

-16

Unchanged

~2.8

102.4

95.2

+l

Unchanged

+32.7

61.4

61.9

-13

Unchanged

Olbve 011

i24.3

74.5

76.2

-13

Unchanged

Skydrol

+ 19.9

76.8

71.4

-10

Unchanged

+0.6

99.1

76.2

Unchanged

+2.0

98.7

95.2

Unchanged

+2.5

99.6

104.8

Unchanged

A.S 1 M Fuel 8
Dlstllled

Water

Ethyl Alcohol

Herane
Hydrochloric
Methyl

Acld (10%)

Ethyl Ketone

500

Sodbum Chlonde
Sodwm

(25%)

Hydroxtde

Tide (1%)

(10%)

Six Months
Volume
Change X

Tensile Strength
Retainrd X

fmmersion

Yellow Res.

Unchanged

at 75 + 5F

Elongation
Retained K

Hardness
ChanRr Pts.

Surface
Condition

A S T M No

1 011

+31.0

82.8

76.2

-13

Unchanged

A S 1 M

3 011

+99.0

64.4

47.6

-18

Unchanged

AS

No

1 M Fuel B

Dlstllled

Water

Ethyl Alcohol

+126.1

39.1

38.1

- 16

+3.7

102.8

90.5

+l

Unchanged

Yellow Res.

+1.3

90.7

85.7

-1

Restdue

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON
Six Months
Volume
Change X

neaane
H,drochlor~c

Acid

Methyl

Ketone

(lo,1

Tensile Strength
Retained X

CHEMICALS
Immersion

at 75

Elongation
Retained X

+116.3

44.7

42.8

+3.7

85.6

61.9

and Elastomers

(continued)

+ 5F
HIrdIleSS

Change Pts.
-16

Sllr(NLe

Condition
Yellow Res.

+l

Unchanged

+31.7

57.7

52.4

-11

Yellow Res.

Oilde 011

+39.3

72.1

61.9

-12

Unchanged

Skydrol 500

+ 19.6

79.1

71.4

- 10

Unchanged

Ethyl

Sodium Chloride (250-i

+0.5

104.7

90.5

+l

Unchanged

Sodium Hydroxide ;lO%)

+2.8

96.3

85.7

+l

Unchanged

Tide (10.)

+3.3

105.6

90.5

+l

Unchanged

CHEMICAL

RESISTANCE

OF 30 VISTALON

6505170

NITRILE

RUBBER BLEND COMPOUND

72 Hours Immersion
Volume
Change K

Tensile Strength
Retained X

at 212F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A.S T M. No. 1011

+19.4

77.5

56.3

-7

A.S T.M

+63.5

62.0

50.0

-22

SI. Tacky

+84.4

37.1

40.6

-24

Unchanged

Dlstllled Water

+7.8

106.6

81.3

-1

Unchanged

Ethyl Alcohol

+9.3

83.6

71.9

-6

Unchanged

-3

Unchanged

No. 3 011

A.S T.M. Fuel B

Hexane

+27.8

53.5

50.0

Hydrochloric Acid (10%)

+ 10.7

98.6

65.6

Methyl Ethyl Ketone

+60.5

31.9

37.5

SI. Tacky

0
-29

Unchanged
Unchanged

Olwe Oil

+ 10.6

80.3

65.6

-7

Sl. Tacky

Skydrol 5OO

+73.5

23.9

34.4

-37

SI. Tacky

Sodium Chlonde (25%)

+0.9

93.9

71.9

+l

Unchanged

Sodlum Hydroxtde (10%)

-0.5

98.1

75.0

-1

Unchanged

Tide (1%)

+7.6

100.0

75.0

-2

Unchanged

One Month
Volume
change x
A S T M. No. 1 011

+6.0

A S T.M. No. 3 011

+28.2

A S.T.M. Fuel 8

Tonsila Strength
Retainrd
K

Immersion

at 75 d 5F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

95.3

87.5

-4

Unchanged

65.7

62.5

-17

Unchanged

+79.9

42.7

40.6

-24

Unchanged

Dlsttilled Water

+2.1

97.6

87.5

-4

Unchanged

Ethyl Alcohol

+6.9

83.5

81.3

-10

Unchanged

+45.4

49.3

46.9

-20

Unchanged

98.6

87.5

-2

Unchanged

+99.9

40.9

37.5

-22

+1.6

103.3

93.8

-1

Unchanged

+96.9

46.9

43.8

-17

V. Tacky

Hexane
Hydrochlonc Acid (lo/,)
Methyl Ethyl Ketone
Olive 011
Skydrol 500

Sodium Chlonde (25O.I


Sodium Hydrorlde
Tide

( 1%)

(lo.)

+1.83

+O.J

345

White Res.

99.5

93.5

-3

White Res.

+0.8

101.9

96.9

-4

Unchanged

+l.O

93.9

87.5

Unchanged
(continued)

346

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

Immersion

Three Months

volume
Channe

Retained

at 75 = 5F

Elongation
Retained X

Tensile Strength
K

kontinued)

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1011

+8.9

86.9

78.1

-4

A.S.T.M.

No. 3 011

+50.2

63.4

59.4

- 18

Unchanged

A.S.T.M.

Fuel B

+87.3

41.3

40.6

-23

Unchanged

+3.2

92.0

84.4

i5.5

82.6

78.2

-8

Unchanged

+48.9

54.9

50.0

-18

Unchanged

+2.3

96.7

87.5

+l

Unchanged

42.2

43.8

-25

Unchanged

DIstIlled

Water

Ethyl Alcohol

Hexane
Hydrochlonc
Methyl

Acid (10%)

Ethyl Ketone

+ 110.8

Ohve 011
Skydrol

500

Sodturn Chlonde
Sodium

(25%)

Hydroxtde

(10%)

Tide (1%)

Unchanged

+3.5

93.0

84.4

-2

Unchanged

+ 100.7

41.3

40.6

-23

Unchanged

+l

+0.5

95.8

78.1

+0.9

94.4

81.3

Unchanged

c2.2

98.6

87.5

Unchanged

Six Months
Volume
Change %
A S.T M. No.

Unchanged

immersion

Tensile Strength
Retained X

Unchanged

at 75 + 5F

Elongation
Retained %

Hardness.
Change Fts.

Surface
Condition

1 011

+ 16.6

81.7

75.0

-5

A S T M. No. 3 011

+54.3

68.5

65.6

- 19

Unchanged

+ 103.5

43.2

34 4

-22

Unchanged

A.S.T M. Fuel B
Distilled

Water

Ethyl Alcohol

Hexane
Hydrochlonc
Acid (10%)
Methyl Ethyl Ketone
Olive Oil
Skydrol

500

Sodium

Chlonde

Sodturn Hydroxide
Ttde (1%)

CHEMICAL

(25%)
(10%)

RESISTANCE

OF

+4.2

101.9

87.5

+2

Unchanged

+4.6

b9.7

78.1

-6

Unchanged

+90.4

53.1

46.9

- 18

Unchanged

c2.0

99.1

84.4

+2

Unchanged

+ 124.3

35.2

34.4

-23

Unchanged

+5.1

100.0

84.4

-2

Unchanged

+ 103.5

36.6

37.5

-24

Unchanged

+0.4

96.2

84.4

73

Unchanged

to.8

91.6

75.0

+2

Unchanged

+3.1

96.2

81.3

+l

Unchanged

50 VISTALON

6505150

NITRILE

RUBBER

72 Hours Immersion
Volume
Change %
A.S.T M. No. 1011
A.S.T.M.
A.S.T.M.
Dsttlled

Unchanged

Tensile Strength
Retained K

BLEND

COMPOUND

at 2 12F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

+43.9

64.0

53.6

-15

SI. Tacky

No. 3 011

+ 100.3

45.7

39.3

-29

SI. Tacky

Fuel El

+263.3

Water

Ethyl Alcohol

+ 13.2
t5.0

34.9

28.6

-33

Unchanged

100.5

71.4

tl

Unchanged

96.8

78.6

-4

Unchanged

(continued)

Rubbers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

and Elastomers

347

(continued9

72 Hours lmmerston at 212F

Hexane
Hydrochlorrc
Methyl

Acrd (10%)

Ethyl Ketone

Elongation
Retained %

Hardness
Change Pts.

Surtace
Condition

Volume
Change %

Tensile Strength
Retained %

+33.3

48.9

42.9

-3

t11.1

91.9

60.7

-3

Unchanged

+35.7

52.7

50.0

-23

Unchanged

Unchanged

Olrve 011

+18.7

83.3

64.3

-12

SI. Tacky

Skydrol

+76.5

42.5

50.0

-31

SI. Tacky

+ 1.3

101.6

71.4

+2

Unchanged

-0.3

101.1

75.0

-1

Unchanged

+4.4

98.5

75.0

-3

Unchanged

500

Sodrum Chloride

(25%)

Sodrum Hydroxrde

(1046)

Tide (1%)

One Month Immersion at 75 + 5F


Volume
Change %
AS 1 M No

1011

A 5 1 M No 3 011

Tensile Strength
Retained $6

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

+16.3

87.6

71.4

-10

Unchanged

+69.8

58.1

50.0

-23

Unchanged,
Unchanged

A S 1 M Fuel B

+95.4

42.5

39.3

-26

Drstrlled Water

+ 4.8

103.2

92.7

-4

Unchanged

E!hyl Alcohol

+ 4.3

96.2

89.3

-10

Unchanged

Hexane
Acrd (10,)

Hydrochlonc
Methyl

Ethyl Ketone

Olrve Oil
Skydrol

500

Sodrum Chlonde

+64.9

47.9

46.4

-22

Unchanged

+1.7

104.8

100.0

-2

Unchanged

+61.7

53.7

50.0

-. 20

+5.3

98.4

89.3

-5

Unchanged

+37.9

65.6

60.7

-15

V. Tacky

White Res.

(25?0)

+0.2

104.8

92.6

-3

White Res.

Sodrum Hydroxrde(lO%)

+0.2

106.5

92.6

-4

Unchanged

+1.2

101.1

89.3

-1

Unchanged

Trde

(loo)

Three Months Immersion


Volume
Change %

Tensile Strength
Retained %

at 75 + 5F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

ASTM

No

1011

+29.0

79.0

71.4

-15

Unchanged

AS TM

No 3011

+81.1

61.3

50.0

-23

Unchanged

ASTM

FuelB

+99.7

42.5

32.1

-27

Unchanged

Drstrlled Water

+0.3

104.8

85.7

-1

Unchanged

E!hyl Alcohol

+3.3

82.3

82.1

-8

Unchanged

+74.5

48.4

42.9

-23

Unchanged

+1.4

101.1

82.1

+62.9

61.8

53.6

-21

Unchanged

+9.5

94.6

78.6

-6

Unchanged

+54.6

61.8

53.6

-20

rlnchanged

-1

Hexane
Hydrochlonc
Methyl

Acrd tlO.)

Ethyl Ketone

Olrve 011
Skydrol

500

Sodrum Chlorrde
Sodrum Hydroxrde
Trde (lTO)

(25%)
(lo.)

+0.3

96.8

75.0

+0.4

99.5

89.3

+4.3

102.2

89.3

0
-1

Unchanged

Unchanged
Unchanged
Unchanged

(continued9

348

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

Six Months Immersion


Volume
Change ?4
A S T M No

Tensile Strength
Retained %

(continued)

at 75 = 5F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

I 011

+41.2

67.7

60.7

-15

Unchanged

A S 1 M No 3 011

+83.9

61.3

46.4

-24

Unchanged
Unchanged

ASTM

+114.4

FuelB

Dlstllled

Water

Ethyl Alcohol

Herane

33.9

32.1

-24

+O.9

99.5

82.1

+l

Unchanged

+2.5

85.5

78.6

-6

Unchanged

-21

Unchanged

+ 104.6

50.0

42.9

98.4

85.7

+63.0

53.8

46.4

-19

Olive 011

+12.6

89.8

71.4

-6

Unchanged

Skydrol

500

+56.6

56.5

53.6

-21

Unchanged

Sodium

Chlonde

+0.4

96.2

85.7

+2

Unchanged

Sodium

Hydroxide

93.0

75.0

+2

Unchanged

+2.8

99.5

82.1

+l

Unchanged

Aod (10%)

Hydrochlonc
Methyl

Tide

Ethyl Ketone

(25%)
(10%)

(1%)

+ 1.9

+2

Unchanged
White Res.

CHEMICAL RESISTANCE OF 70 VISTALON 6505130 NITRILE RUBBER BLEND COMPOUND


72 HoursImmersion at 212F
Volume
Change K

Tensile Strength
Retained K

Elongation
Retained X

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1 011

+70.0

53.9

51.7

-25

A.S.T.M.

No. 3 Oil

+ 130.9

43.9

37.9

-32

SI. Tacky

A.S.T.M.

Fuel 8

+224.0

33.9

27.6

-34

Unchanged

+2.2

100.6

75.8

+l

Unchanged

- 12.7

97.8

86.2

-8

Unchanged

Distilled Water
Ethyl Alcohol

Hexane
Hydrochloric
Methyl

Acid (loo/.)

Ethyl Ketone

SI. Tacky

+27.4

45.0

34.5

-2

Unchangqd

+ 12.6

94.4

65.5

-1

Unchanged

+32.6

67.2

62.1

-1

Unchanged

+26.3

71.1

65.5

-16

SI. Tacky

+38.3

65.6

72.4

-25

Sl. Tacky

+0.7

97.2

72.4

+2

Unchanged

-0.3

98.9

79.3

-1

Unchanged

+2.4

97.2

72.4

-1

Unchanged

Volume
Cheq. x

Tensile Strength
Retained K

Elongation
Retained K

011

+26.6

80.6

68.9

-13

Unchanged

A S T M No 3 011

+98.1

62.7

44.8

-23

Unchanged

Olive Oil
Skydrol

500

Sodium Chlonde
Sodwn

(25%)

Hydroxide

(10%)

Tide (1%)

One Month Immersion at 75 + 5F

A S 1 M No

Hardness
Change Pb.

Surface
Condition

+114.9

42.8

34.5

-25

Destilled Water

+1.9

98.9

93.1

-3

Unchanged

Ethyl Alcohol

+3.1

95.0

93.1

-7

Unchanged

AS TM

Fuel 8

Unchanged

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

One Month Immersion


Volume

change
HeXan.?
Acid

Hydtochlorlc

f IO,)

Ethyl Ketone

Methyl

Olive Ott
Skydrol 500

Sodturn Chloride (2Ya)


Sodium Hydroxide

(IO.1

(loo)

Ttde

Tensile Strength
Retained c

(continued)

at 75 r 5F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

+66.6

45.0

37.9

-22

Unchanged

+1.2

104.4

100.0

-2

Unchanged

+29.9

73.3

75.9

-17

+7.6

93.3

86.2

-7

Unchanged

+2l.l

71.1

89.7

-12

V. Tacky

White Res.

103.3

100.0

-3

White Res.

+0.3

98.9

96.6

-3

Unchanged

+0.6

96.7

93.0

-1

Unchanged

Three Months Immersion


Voluma

Tensile Strength

Change K

Retained X

Elongation
Uetained K

at 75 : 5F
Hardness
Change Pts.
18

Surface
Condition
Unchanged

AS 1 M No

1011

+49.1

67.8

55.2

AS 1 M

3011

+ 106.3

51.1

41.4

-23

Unchanged

+115.6

44.4

34.5

-26

Unchanged

No

AS 1 M Fuel B
Dlstlllcd

Water

Alcohol

Ethyl

tiexatle
Hydrochlorw

Acid IlO.)

+0.3

98.9

89.7

-1

Unchanged

+1.8

93.9

86.2

-6

Unchanged

+98.6

47.8

34.5

-23

Unchanged

+l

Unchanged

io.73

98.3

86.2

+31.1

77.2

72.4

-19

Gray Res.

Olwe 011

+16.1

86.1

79.3

-10

Unchanged

Skydrol 500

+22.2

86.1

75.9

-14

Unchanged

+0.2

105.0

86.2

+l

Unchanged

+0.3

94.4

82.8

Unchanged

+l.l

97.2

93.1

Unchanged

Methyl

Ethyl Ketone

Chloride

Sodaurn

(25O.1

(lo,)

Sodium t-lydroxlde
lldt

11-c)

Six Months Immersion

Volume
Change K
A.S T.M. No

Tensile Strength
Retained X

at 75 ? SF

Elongation
Retained X

Hardness
Channe Ptr.

Surface
Condition

1011

+ 61.8

65.6

55.2

-19

Unchanged

No 3 Oil

+ 109.8

51.7

44.8

-25

Unchanged

+138.1

35.4

31.0

-24

Dlstdled Water

+0.8

98.9

93.1

+1

Unchanged

Ethyl Alcohol

+ 1.6

93.3

86.2

-4

Unchanged

-22

A.S.T.M.

A S T M. Fuel 8

Hexane

+ 137.6

Hydrochloric
Methyl

Acid (lo.)

Ethyl Ketone

+l.l

52.2

44.8

100.0

86.2

+1

Unchanged

Unchanged
Unchanged

+30.3

71.7

69.0

-16

White Res.

Olwe 011

+ 18.9

88.9

79.3

-10

Unchanged

Skydrol SO0

+23.2

77.2

75.9

-14

Unchanged

Sodwm Chlonde
Sodwm

Hydroalde

Tide (1%)

(25J
(1o0)

349

+0.2

100.0

93.1

+2

Unchanged

+0.2

96.1

82.8

+1

Unchanged

+l.l

97.2

86.2

Unchanged

(continued)

350

Corrosion

TABLE 2.12:

Resistant

VARIOUS

Materials

Handbook

ELASTOMERS

CHEMICAL

RESISTANCE

OF

AND RUBBERS-EXXON

30 VISTALON

6505170

CHEMICALS

POLYCHLOROPRENE

BLEND

72 Hours Immersion
Volume
Change %

Tensile Strength
Retained %

(continued)

COMPOUND

at 212F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1 Oil

+25.1

86.8

73.9

- 10

SI. Tacky

A.S.T.M.

No. 3 011

+99.8

46.2

65.3

-27

SI. Tacky

A.S.T.M.

Fuel B

Distilled

Water

Etnyl Alcohol

Hexane
Hydrochloric
Methyl

Acid (lD?/J

Ethyl Ketone

Olive Oil
Skydrol

500

Sodium

Chloride

Sodium

Hydroxide

(2596)
(10%)

Tide (1%)

+92.3

33.8

47.8

-25

Unchanged

+10.9

96.6

78.3

-1

Unchanged

-0.1

91.9

87.0

+2

Unchanged

+27.9

53.8

60.9

+3

Unchanged

+7.1

88.4

75.0

+28.5

50.9

65.2

A S.T M No. 1011

AS TM
Dlstllled

+32.0

71.4

73.9

-17

SI. Tacky

40.6

65.2

-33

SI. Tacky

to.2

100.4

73.9

+6

Unchanged

+2.0

89.3

78.3

-3

Unchanged

96.6

82.6

-1

Unchanged

Tensile Strength
Retained %

Surtace
Condition

91.3

-4

Unchanged

~55.8

60.8

-16

Unchanged

Fuel 8

+a4.4

38.9

47.8

-19

Unchanged

+3.5

103.0

95.7

-1

Unchanged

+8.1

88.5

86.9

-6

Unchanged

+51.9
Actd (10%)

Ethyl Ketone

Olive 011
500

Sodlum Chloride

(25,)

Hydroxide

1lo01

I lo.1

72.3
t40.0

51.3

60.9

-15

Unchanged

105.9

108.7

-1

Unchanged

52.6

73.9

-16

+9.4

92.3

83.3

-5

+50.3

56.8

69.6

-14

+I.2

101.3

100.0

+3.1

101.3

91.3

+0.3

105.6

100.0

Volume
Change %

Tensile Stmngth
Retained %

Three Months Immersion

A S T M

Hardness
Change Pts.

59.0

Hydrochloric

Sodium

Elongation
Retained %

95.7

Water

Skydrol

at 75 + 5F

+7.6

Hexane

Tide

Vdume
Change %

Immersion

No. 3011

Ethyl Alcohol

Methyl

Unchanged
Unchanged

+73.3

One Month

AST.M

-18

No. 1 011

Elongation
Retained %

White Res.
Unchanged
V. Tacky

0
-2
0

White Res.
Unchanged
Unchanged

at 75 z 5F
Hardness
Change fb.

Surface
Condition

+ 13.8

85.9

78.3

-6

A S.T M No. 3 011

+72.8

55.9

56.5

-17

Unchanged

A S.1.M

+89.4

40.2

43.5

-22

Unchanged

+6.2

104.7

95.7

-1

Unchanged

+ 10.6

79.1

82.6

-6

Unchanged

Dlstllled

Fuel 8
Water

Ethyl Alcohol

Unchanged

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

351

(continued)

Three Months Immersion et 75 = 5OF


Volume
Change %
Hexane

Tensile Strength
Retained %

Elongation
Retained %

Hardness
Chanp
Pts.

Surface
Condition

+54.8

49.6

52.2

-15

Unchanged

+4.3

100.4

87.0

+l

Unchanged

Methyl Ethyl Ketone

+41.0

57.7

69.6

-17

Unchanged

Olive Oil

+19.5

84.6

82.6

-11

Unchanged

Skydrol 500

+53.9

49.2

69.6

-21

Unchanged

Sodturn Chloride (25%)

+1.5

100.0

75.9

+l

Sodium Hydroxldc (lC?o)

+5.0

95.7

87.0

+5.8

97.9

87.0

Hydrochloric Acid (10%)

Tide

1I,)

Unchanged

Unchanged

-1

Unchanged

Six Months Immersion at 75 r 5F


Volume
Change %
1 011

Tensile Strength
Retained %

Elongation
Retained $6

Hardness
Change Pts.

Surface
Condition

+20.7

80.3

78.3

-8

Unchanged

AS 1 M No 3011

+76.9

57.7

56.5

-21

Unchanged

A S 1 M Fuel B

+87.4

-20

Unchanged

A S 1 M No

39.3

47.8

+8.5

99.6

87.0

-1

Unchanged

+11.2

79.9

87.0

-4

Residue

+54.2

46.6

52.2

-15

+5.7

93.6

82.6

+l

Unchanged

+41.6

48.7

65.2

-17

Unchanged

+23.3

83.8

78.3

-12

Unchanged

+57.8

44.4

52.2

-23

Unchanged

Sodium Chlonde (25%)

+1.9

102.1

87.0

+2

Unchanged

Sodwm Hydroxide (10%)

+6.3

86.8

78.3

+l

Unchanged

Tide (l/.)

+8.4

102.6

87.0

+l

Unchanged

Dtstllled Water
Ethyl Alcohol
Heaane
Hydrochloric Acid

(lo.)

Methyl Ethyl Ketone


Olive 011
Skydrol 500

CHEMICAL

RESISTANCE

OF 50 V&TALON

6505150

POLYCHLOROPRENE
72 Hours

Volume
Change %

Tensile Strength
Retained X

Immersion

Unchanged

BLEND

COMPOUND

at 2 12F

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. I Oil

+46.4

70.8

68.0

-21

SI. Tacky

A.S.T.M.

No. 3 011

+114.0

42.7

48.0

-30

SI. Tacky

A.S.T.M.

Fuel B

+118.4

37.1

48.0

-27

Unchanged

Distilled Water

+6.7

98.1

80.0

-1

Unchanged

Ethyl Alcohol

-2.3

88.3

80.0

+2

Unchanged

Hexane

+33.3

46.5

48.0

+2

Unchanged

Hydrochloric Acid (10%)

+15.0

84.0

64.0

-2

Unchanged

Methyl Ethyl Ketone

+21.2

59.3

72.0

-16

Unchanged

Olwe Oil

+33.4

72.5

72.0

-22

SI. Tacky

Skydrol

+43.4

53.5

80.0

-28

SI. Tacky

500

Sodturn Chloride (25%)


Sodwm Hydroxide (10%)
Tide (1%)

95.1

76.0

+3

Unchanged

+ 14.6

87.5

72.0

Unchanged

+6.2

97.3

84.0

+O.Ol

-2

Unchanged

(continued)

352

Corrosion Resistant Materials Handbook

TABLE 2.12: VARIOUS ELASTOMERS AND RUBBERS-EXXON

CHEMICALS

(continued)

One Month Immersion at 75 + 5F


Volume
Change lb

Tensile Strength
Retained X

Elongation
Retained X

Hardness

Surfwe

Change Pts.

Condition

A.S 1 M. No. 1011

+17.5

82.3

76.0

-9

Unchanged

A.S.1 M. No. 3 011

+81.3

47.4

48.0

-21

Unchanged

A.S.T.M.

+99.0

39.7

44.0

-23

Unchanged

Dlstllled Water

+2.7

104.5

96.0

-2

Unchanged

Ethyl Alcohol

+5.2

88.7

84.0

-7

Unchanged

Fuel I3

+73.6

40.5

48.0

-18

Unchanged

+2.5

102.8

100.0

-2

Unchanged

Methyl Ethyl Ketone

+27.8

62.3

76.0

-16

Okve 011

+ll.O

88.7

84.0

-8

Skydrol 500

+29.6

77.2

84.0

-13

Hexane
Hydrochlonc Actd (10%)

White Res.
Unchanged
V. Tacky

Sodium Chloride (250,~)

+2.0

98.1

96.0

-3

White Res.

Sodium Hydrorlde (10%)

+2.2

101.1

96.0

-3

Unchanged

+2.1

98.1

.%.O

-1

Unchanged

lode

(1%)

Three Months immersion at 75 : 5t


Volume
Change X
A S T M No
AS TM

011

No 3011

A S 1 M Fuel 8

Tensile Strength
Retained X

Elongation
Retained K

Hardness
Change Fts.

Surfacr
Condlion

+32.1

72.5

76.0

-14

93.3

50.3

52.0

-21

Unchanged

38.4

40.0

-25

Unchanged

+110.5

Unchanged

+4.0

101.5

96.0

-1

Unchanged

+10.6

86.2

88.0

-6

Unchanged

+81.6

44.8

48.0

-21

Unchanged

+3.1

97.3

92.0

Methyl Ethyl Ketone

+28.8

68.3

76.0

Olive 011

+20.8

84.5

Shydrol 500

+30.2

72.5

Dlstllled Water
Etnyl Alcohol

Hexane
Hydrochlonc Aild

t 10-o)

Sodwm Chloride (2fP01


Sod~urn Hydroxide

(IO.)

ltd.? II"ab

Unchanged

-17

Unchanged

84.0

-14

Unchanged

80.0

-18

Unchanged

+0.6

97.7

72.0

+2.7

97.7

92.0

-1

Unchanged

+3.8

98.1

92.0

-1

Unchanged

Unchanged

Six Months Immersion at 75 = 5F


VdlUllO
Chrngo X

Tonsil0 Strength
Retained X

Elongation
Retainrd X

HlrdMSS

Change Pts.

Surface

Condition

A.S.T.M.

No. 1011

+41.6

67.8

72.0

-16

A.S.T.M.

No. 3 011

+95.8

46.9

52.0

-25

Unchanged
Unchanged

A.S.T.M.

Fuel B

+ 130.3

36.7

44.0

-24

Unchanged

Dtstllled Water

~6.3

101.5

92.0

-1

Unchanged

Ethyl Alcohol

+6.1

85.8

88.0

-5

Unchanged

(continued)

Rubbers and Elastomers

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

353

(continued)

Six Months Immersion at 75 r 5F


Volume
Change K
Hexane

Tantile Strength
Retainad K

+ 114.7

Hydrochlonc

Acrd (10%)

Elongation
Retained X

Hardnass
Change Pts.

42.7

44.0

-20

+4.6

90.0

76.0

-1

Surtrce
Condition
Residue
Unchanged

Methyl Ethyl Ketone

+28.5

60.6

72.0

-16

Unchanged

Olbve 011

+23.6

80.2

76.0

-14

Unchanged

Skydrol 500

+31.5

68.3

94.0

-19

Unchanged

Sodrum Chlonde (25%)

+1.2

99.8

88.0

+l

Sodium Hydroxrde (10%)

+4.3

93.0

84.0

Tide (1%)

+5.8

99.8

88.0

CHEMICAL

RESISTANCE

OF 70 VISTALON

6505130

POLYCHLOROPRENE

Unchanged

Unchanged

-1
BLEND

Unchanged
COMPOUND

72 Hours Immersion at 212F


Volume
Change X

Tensile Strength
Retained $6

Elongation
Retained K

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1 011

+66.4

61.0

62.5

-24

St. Tacky

A.S.T.M

No. 3 Oil

+ 130.9

39.5

45.8

-32

SI. Tacky

A.S.T.M.

Fuel 8

+ 137.4

-27

29.5

37.5

Dlstrlled Water

+4.0

101.5

87.5

Unchanged

Unchanged

Ethyl Alcohol

-1.5

91.5

83.3

+3

Unchanged

Unchanged

Hexane

+47.4

41.5

45.8

-1

Hydrochlonc Acrd (10%)

+ 12.3

91.0

75.0

-1

Unchanged

Methyl Ethyl Ketone

+ 15.5

64.0

_ 79.2

-14

Unchanged

Olive 011

+ 37.0

72.5

75.0

-21

SI. Tacky

Skydrol 500

+25.6

72.0

87.5

-21

SI. Tacky

Sodium Chloride (25%)

+0.8

108.C

83.3

+2

Unchanged

Sodium Hydroxide (10%)

+0.6

95.0

79.3

-1

Unchanged

Tide (1%)

+3.6

91.5

83.3

-1

Unchanged

One Month Immersion at 75 + 5F


Volume
Change K

Tensile Strength
Retained K

Elongation
Retained %

Hardness
Change Pts.

Surface
Condition

+ 27.0

79.0

75.0

-11

Unchanged

A S 1 M No 3 011

+ 102.2

50.0

45.8

-21

Unchanged

A S T M Fuel B

+115.3

-23

Unchanged

-2

Unchanged

AS TM

No

1011

29.5

33.3

Drstrlled Water

+ 2.5

108.0

100.0

Ethyl Alcohol

+*3.8

98.0

95.8

Hexane
Hydrochlonc Actd (lo.1

Unchanged

+81.5

35.5

37.5

-21

Unchanged

+2.3

109.5

108.3

-2

Unchanged

Methyl Ethyl Ketone

+15.5

61.5

75.0

-12

Olrve 011

+ 14.4

90.5

91.7

-9

Skydrol 500

+15.3

89.5

91.8

-10

Sodrum Chlonde (.25.)

+O.?

101.5

100.0

-2

White Res.

Sodrum Hydroxide (lO.J

+ 1.2

95.5

87.5

-2

Unchanged

100.0

100.0

-1

Unchanged

Trde

(I,)

+1.4

White Res.
Unchanged
V. Tacky

(continued)

354

Corrosion Resistant Materials Handbook

TABLE 2.12:

VARIOUS

ELASTOMERS

AND RUBBERS-EXXON

CHEMICALS

(continued)

Three Months Immersion at 75 2 5F


Volume
Change X

Tensile Strength
Retained K

Elongation
Retained %

Hardness
Cnange pts.

Surface
Condition

A.S 1 M No

1011

+47.6

67.5

70.8

-15

Unchanged

AS TM

3011

+112.4

45.5

45.8

-21

Unchanged

-23

Unchanged

No

A S.1 M. Fuel 8
Dlstllled

Water

Ethyl Alcohol

+ 128.5

37.0

37.5

+3.1

103.5

100.0

+4.5

93.5

91.7

-4

Unchanged

-21

Unchanged

Unchanged

+ 105.4

43.0

41.7

+2.3

100.0

91.7

+17.1

79.0

87.5

-13

Unchanged

Olwe 011

+25.3

80.5

79.2

-14

Unchanged

Skydrbl

500

+14.3

83.5

95.8

-12

Unchanged

Sodwm

Chlonde

-1

Sodium

Hydroafde

Hexane
Hydrochlonc
Methyl

Acid (l(P,)

Ethyl Ketone

(25.)
(1P.l

Tide (1%)

+0.6

104.0

83.3

+1.8

100.0

95.8

~2.4

107.5

95.8

0
-2

Unchanged

Unchanged
Unchanged
Unchanged

Six Months Immersion at 75 2 5F


Volume
Channe K

Tensile Strength
Retained K

Elongation
Retained K

Hardness
Change Pts.

Surface
Condition

A.S.T.M.

No. 1011

+60.9

66.0

70.8

-19

Unchanged

A.S.T.M.

No. 3 011

~116.1

51.5

50.0

-23

Unchanged

Fuel 8

+ 155.6

36.0

37.5

-23

Unchanged

+4.5

104.5

95.8

+3.2

95.0

87.5

-2

-20

A.S.T.M.
Dlsttlled

Water

Ethyl Alcohol

Hexane

Methyl

Acid (10%)

Ethyl Ketone

Unchanged
Residue

39.5

41.7

c3.4

102.0

95.8

c17.7

67.5

75.0

-12

Unchanged

+ 147.3

Hydrochlonc

Unchanged
0

Unchanged

Olwe 011

~28.0

86.0

83.3

-14

Unchanged

Skydrol

500

+ 14.9

85.0

95.8

-13

Unchanged

Sodwm

Chlonde

Sodturn

Hydroxide

Tide (1%)

(25%)
(lD%)

+0.7

104.0

95.8

+l

Unchanged

+2.2

99.0

87.5

cl

Unchanged

+4.0

102.5

91.7

Unchanged

Rubbers

TABLE 2.13:

VARIOUS

ELASTOMERS

AND RUBBERS-MINOR

CHEMICAL

COMPATIBILITY

and Elastomers

355

RUBBER CO.

CHARTS

(continued)

356

Corrosion Resistant Materials Handbook

TABLE 2.13:

glcium
C.lClrn

Carbonat*
ChlowJ.

VARIOUS

ELASTOMERS

AND RUBBERS-MINOR

AIAIAIAlAl

RUBBER CO. kontinued)

lAl*IClJI*I

~I~I~I~I~l~I~l~l~l~l~l

(continued)

Rubbers and Elastomers

TABLE 2.13:

VARIOUS

ELASTOMERS

AND RUBBERS-MINOR

RUBBER CO. (continued)

357

358

Corrosion Resistant Materials Handbook

TABLE 2.13:

VARIOUS

ELASTOMERS

AND RUBBERS-MINOR

RUBBER CO. (continued)

LEGEND

A
A

u
u

B
B

u
u

B
B

u
u
u
u

c
c

u
n

llllCl

U
U

c
A
B
_

IB

B
B

A
A
A

B
A

A
B
B
B

u
B

n
u

lvlele

u
u

B
B

I
B
B

B
B

u
n
n
B
A

n
c

u
c

it-.

u
u

A
B

u
u

fi

B
A
A
A

B
A
A
A

!.-_
u

u
B

U
B

C
A

B
B

6
A

A
A

A -.

,
_~

u
A
A
A

B
A
4

B
A

AL
c

C
B

B Ilclllsiclclcle

B
B
U

A
._A
A

d--4

(continued)

Rubbers and Elastomers

TABLE 2.13:

VARIOUS

ELASTOMERS

AND RUBBERS-MINOR

ICI

ui~l~l~l

iI
B

iI

359

RUBBER CO. (continued)

6 I

IAlA

6 I

IAl

Lg

I-

g;

a__

(continued)

360

Corrosion

TABLE 2.13:

Resistant

VARIOUS
LEGEND

Materials

Handbook

ELASTOMERS
/

AND RUBBERS-MINOR
/

RUBBER CO. (continued)


/

362

Corrosion

TABLE 2.13:

Resistant

VARIOUS

Materials

Handbook

ELASTOMERS

AND RUBBERS-MINOR

RUBBER CO. (continued)

-+

-+

-+

--i

-5

A
A

-z--z-

--&

-+-

+_

_-!A

-&

---Ti--E-

Rubbers

TABLE 2.13:

VARIOUS

ELASTOMERS

AND RUBBERS-MINOR

and Elastomers

363

RUBBER CO. (continued)

LEGEND

(continued)

364

Corrosion

TABLE 2.13:

Resistant

VARIOUS

Materials

Handbook

ELASTOMERS

AND RUBBERS-MINOR

RUBBER CO. (continued)

LEGEND

ikelly. solent
ikdrol500

B. c. E

:Lydrol7000
hap Sofwm*
$cow Mobtk

Type A

km Vacuum
AMAC781
,Gmsw,
bconv Vacuum PD959B
ia& Ash

UI

ulul

U
u
A

u
u
A

u
u
A

_:

VI

Al

A
A
A

181
A

B
B
A

UI

U
B
A

l
B
A

A
U

u l
u
U
A

B
B

A
A
A

_::

tinued)

Rubbers

TABLE 2.13:

VARIOUS

ELASTOMERS

AND RUBBERS-MINOR

and Elastomers

RUBBER CO. (continued)

_!I-_

u-

I,

II

---_

--t-

365

-4

-+

-2

(continued)

366

Corrosion Resistant Materials Handbook

TABLE 2.13:

VARIOUS

ELASTOMERS
-

AND RUBBERS-MINOR

RUBBER CO. (continued)

Rubbers

TABLE 2.14:

VARIOUS

RUBBER AND ELASTOMERIC

TANK

367

and Elastomers

LININGS-ACME-FISHER

Linings Recommended to Resist Various Chemicals


LININGS.
A - Abrasron Resistant
B - Soft Natural
C - Semi-Hard
Natural

CHEMICALS
INORGANIC ACIDS
Arsenic
Battery Acid (Sulphuric)
Carbonic
Chlorine Water
Cupric Acid (Copper Sulrate)
Fluoboric
Fluosilicic
Hydrobromic
Hydrochloric
Hydrofluoric
Hydrofluoric
Max. Cont.
Hydrogen
Sulfide Water
Nitric
Nitric
Perchloric
Phosphoric
Sulfonic Acid
Sulphuric
Sulfurous
SALTS a ALKALIES
Abrasive Solutions
Aluminum
Salts
Alums
Ammonium
Hydroxide
Ammonium
Persulfate
Other Ammonium
Salts
Barium Salts
Barium Sulfide
Calcium Bisulfite
Bleach Lrquor
Calcium Hydrochlorite
Other Calcium Salts
Copper Salts
Iron Salts
Lead Salts
Mercuric Chloride
Nickel Acetate
Potassium Hydroxide
Potassium Drchromate
Other Potassium Salts
Sodium Hydroxide
Sodium Bisulfite
Sodium Hydrochlorite
Sodium Hypochlorite
Other Sodium Salts
Sulphur Chloride
Silver Nitrate
Tin Salts
Zinc Salts

D - Hard Natural
E - Neoprene
F - Polyvinyl
Chloride

Natural

CONCENTRATION

G - Chloro-Butyl
H - Ethylene
Propylene
NR - Not Recommended

(Koroseal)

TEMPERATURE

LINING

OF

175

Any
To Saturation
To Saturation
Any
Any
Any
Any
To 50%
To Saturation
10%
25%
To Saturation
To 85%
To 50%
To Saturation

To
To
To
To
To
To

Saturation
Saturation
Saturation
Saturation
Saturation
Saturation

To
To
To
To
To
To
To

Saturation
Saturation
Saturation
Saturation
Saturation
Saturation
Saturatron

To Saturation
To Saturation
To Saturation
To Saturation
To Saturation
To Saturation
To Saturation
16%
To Saturation
To Saturation
Any
To Saturahon

High Bake Phenolic


175
125
140
175
175
175
186
175
225
160
90
70
120
180
180
160
160
OF
180
175
175
160
175
175
175
180
175
140
175
175
175
175
175
180
160
175
160
180
160
160
150
225
180
NR
175
175
175

DB
DB
D-H
F
DB
DBE
DB
DB
DB
G
DB
DEF
F
DF
EDB
DB
DB
D

A
DB
DB
D
DB
DB
DB
DB
DB
D
D
DB
DE
DB
DB
D
DE
DB
DF
DBE
DB
DF
D
G-H
DBE
D-B
DE
DE

(continued)

368

Corrosion Resistant Materials Handbook

TABLE 2.14:

VARIOUS

CHEMICALS

RUBBER AND ELASTOMERIC

TANK

CONCENTRATION

Brass
Cadmium
Chromium
Copper
Gold
Lead
Nrckel
Silver
Tin
Zinc

Trace to Any
Any
To 25%
Any
Any

To Saturation
Any
40%
Any

To Saturation
Any
Any
Any
Any
To Saturation

Any
To Saturation
Any

The temperatures
given are somewhat conservative;
however
should be conducted
to satisfy users particular problem.

(continued)
LINING

TEMPERATURE

PLATING SOLUTIONS

ORGANIC
MATERIALS
Acetate Solvents
Alrphatic Solvents
Acetic Acid
Acetic Anhydride
Acetone
Alcohols
Castor Oil
Citric Acrd
Coconut Oil
Cottonseed
Oil
Dye Stuffs
Citric Acid
Ethylene Glycol
Formaldehyde
Formic Acrd
Fumaric Acid
Furfural
Gallic Acid
Glucose
Glue
Glycerine
Lactic Acid
Malic Acid
Minerals Oils
Oxalic Acid
Soaps
Tannic Acid
Triethanolmine
Vinegar

LININGS-ACME-FISHER

If higher

OF
140

F-B-D

OF
NR
160
160
150
150
175
150
160
150
150
150
160
160
100
100
180
100
160
175
175
175
160
150
160
160
175
175
175
150

E
D
D
DB
DB
D
DF
D
D
D
F
DB
D
D
BDF
D
DB
DB
DB
DB
D
DB
ED
D
DB
DB
DB
DF

operating

temperatures

are anticipated,

tests

Cements, Mortars, and Asphalt

TABLE 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD


STONCLAD is a three-component, epoxy-base floor surfacing system. It was specifically designed for surfacing and
patching industrial floors exposed t o corrosive spillages and abrasive, wheeled traffic. STONCLAD-HT i s a threecomponent, epoxy-base floor surfacing system. It was specifically designed for surfacing and Fatching industrial
but less
floors exposed t o corrosive spillages and abrasives, wheeled traffic a t temperatures above 140 F (60C),
than 250F (122C).
The test procedure used was to totally immerse cured samples of STONCLAD in the chemicals listed
for a period of 90 days at normal room temperatures. (This is a n exceptionally severe test, since most
floors subject t o chemical spillages such as these are "flushed down" periodically with water as part of
the normal floor maintenance operation.)
The resultant resistance of STONCLAD t o the various chemicals is rated using the symbols listed
below. (It is assumed that normal "good housekeeping procedures" are used, including a daily flushing
down with clean water.)
RATING CODE

E - Excellent
G - Good
F - Fair
NR - Not Recommended

OS - Suitable for use


where "occasional spillages"
occur, when followed by
immediate water flushing.

Chemical Resistance Guide for STONCLAD


ACIDS
CHEMICAL

RATING

Acetic - 5%. . . . . . . .
Acetic - 10%. . .
Acetic - 20%. . .
Acetic - Glacial. .

CH EM1CAL

RATING

Heptanoic.. . . . . . . . . . . . . . . . . . . . .
OS
Hydrochloric
15%. . . . . . . . . . . . . E
Hydrochloric - 37%. . . . . . . . . . . . . G
Hydrofluoric - 5%. . . . . . . . . . . . . . G
Hydrofluoric - 10%. . . . . . . . . . . . . F
Hydrofluoric - 15%. . . . . . . . . . . . . OS
Hypochlorous - 5%. . . . . . . . . . . . . E

. . . . . . . . os

Benzoic - Sat. 3%.. . . . . . . . . . . . . . E


Boric - Sat. 30%. . . . . . . . . . . . . . . E
Butyric - 10%. . . . . . . . . . . . . . . . . . F

Lactic
Lactic

Chromic - 10%. . . . . . . . . . . . . . . . .G
Chromic - 15%. ..
Chromic - 20%. . .
Citric - 50%. . . . . . . . . . . . . . . . . . .E
Cresylic. . . . . . . . . . . . . . . . . . . . . . .
OS

- up t o 20%. . . .
- over 25%. . . .

Maleic - 30%. . . . . . . . . . . . . . . . . .G
Maleic - 40%. . . . . . . . . . . . . . . . . .F
Maleic - 60%. . . . . . . . . . . . . . . . . .OS
Malic - 50%. . . . . . . . . . . . . . . . . . .E
Monochloroacetic -5%. . . . . . . . . . . F
Monochloroacetic
10%. . . . . . . . . OS

. . . . . . . . . . . . . . . . . . .G

Fatty . . . . . . . . . . . . . . . . . . . . . . . . . .
G
Formic - up t o 10%. . . . . . . . . . . . .OS
Formic - over 10%.. . . . . . . . . . . . . NR
Fluoboric. .....................
G

Nitric - 10%. . . . . . . . . . . . . . . . . . . E

................G
. . . . . . . . . . . . . . . .F
. . . . . . . . . . . .NR
Nitric - over 40%

369

(continued)

370

Corrosion Resistant Materials Handbook

T A B L E 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD

(continued)

ACIDS (continued)
CHEMICAL
Oleic. . . . . . . . . .
Oxalic - Sat.. . .

RATING

CHEMICAL

.............E
. . . . . . . . . . . . .E

Phthalic..

RATING

......................

Succinic - Sat.. . . . . . . . . . . . . . . . .E
Sulfuric - 20%. . . . . . . . . . . . . . . . . E
Sulfuric - 50%. . . . . . . . . . . . . . . . . G
Sulfuric - 70%. . . . . . . . . . . . . . . . . F
Sulfuric - 98%. . . . . . . . . . . . . . . . . NR

Pelargonic. . . . . . . . . . . . . . . . . . . . .
OS
Perchloric - 35%. . . . . . . . . . . . . . . F
Phosphoric - u p t o 50%. . . . . . . . . i F
Phosphoric - 70%. . . . . . . . . . . . . .os
Phosphoric - Conc. 85%. . . . . . . . . NR
Picric - Sat.. . . . . . . . . . . . . . . . . . . E

Tannic - Sat.. . . . . . . . . . . . . . . . . . . E
Tartaric - Sat.. . . . . . . . . .
....E
ALKALIES AND SALTS

CHEMICAL

RATING

Aluminum Chloride - 50%. . . . . . . . E


Ammonium Chloride - 50%. . . . . . . E
Ammonium Hydroxide - up t o 20%. E
Ammonium Hydroxide - 409b.. . . . . G
Ammonium Nitrate - Sat.. . . . . . . . . E
Ammonium Persulfate . . . . . . . . . . . .E
Ammonium Sulfate - Sat.. . . . . . . . . E
Calcium Chloride - 50%
Calcium Hydroxide - Sa
Calcium Hypochlorite - up t o 15%. . G
Copper Fluoroborate
Ferric Chloride.. . . . . . . . . . . . . . . . . G
Ferrous Sulfate.. . . . . . . . . . . . . . . . . G
Potassium Hydroxide

- up to 40%. . E

CHEMICAL

RATING

Sodium Benzoate. . . . . . . . . . . . . . .. E
Sodium Carbonate (Soda Ash)-Sat.. E
Sodium Bicarbonate - Sat.. . . . . . . . E
Sodium Bisulfate - Sat.. . . . . . . . . . E
Sodium Bisulfite - Sat.. . . . . . . . . . . E
Sodium Chloride (Salt) . . . . . . . . . . . .E
Sodium Glutamate.. . . . . . . . . . . . . ..E
Sodium Hydroxide - up t o 5 0 % . . . .E
Sodium Hypochlorite - up t o 10%.. .G
Sodium Propionate.. . . . . . . . . . . . . .E
Sodium Sulfate - Sat.. . . . . . . . . . . . E
Sodium Sulfide - Sat.. . . . . . . . . . . . E
Trisodium Phosphate - Sat . . . . . . . E
Zinc Nitrate..

. . . . . . . . . . . . . . . . . . .G

SOLVENTS AND OTHER CHEMICALS


SU B STAN CE

RATING

Acetone, . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . os
Aniline, . . . . . . . . . . . . . . . .

Alcohol (Methyl). . . . . . . . . . . . . . . . . 0 s
Alcohol (Ethyl, Propyl.
Isopropyl, Butyl). . . . . . . . . . G
Amyl Acetate.. . . . . . . . . . . . . . . . . . E
Beer . . . . . . . . . . . . . . . . . . . . . . . . . .

Diacetone Alcohol. . . . . . . . . . . . . . . E
Diethyl Phthalate. . . . . . . . .
Dimethyl Phthalate. . . . . . . .
Ethyl Acetate. . . . . . . . . . . . . . . . . . . OS
Ethylene Glycol. . . . . . . . . . . . . . . . . E
Ether. . . . . . . . . . . . . . . . . . . . . . . . .
OS
Ethylene Dichloride. . . . . . . . . . . . . . .NR

. . . . . . . . . . . . . . . . . . . os
Butyl Acetate. . . . . . . .
........G

RATING

SUBSTANCE

Formaldehyde.

. . . . . . . . . . . . . . . . .E

Butyl Lactate. . . . . . . . . . . . . . . . . . . G
Bromine. . . . . . . . . . . . . . . . . . . . . . .
NR

Gasoline.. . . . . . . . . . . . . . . . . . . . . .
Glycerine. . . . . . . . . . . . . . . . . . . . . . .
Glyoxal .......................

Carbon Disulfide.. . . . . . . . . . . . . . . .
Carbon Tetrachloride. . . . . . . . . . . . .
Chlorobenzene. . . . . . . .
Corn Oil. . . . . . . . . . . . . . . . . . . . . . .
Cyclohexane. . . . . . . . . . . . . . . . . . . .
Cyclohexanol. . . . . . . . . . . . . . . . . . .
Cyclohexanone. . . . . . . . . . . . . . . . . .
Chloroform. . . . . . . . . . . . . . . . . . . . .

Hydrogen Peroxide

NR
E

E
E
E
OS
NR

E
E
E

- 10%.. . . . . . . E

JP5 Jet Fuel.. . . . . . . . . . . . . . . . . . . E


Juices - Fruit. . . . . . . . . . . . . . . . . . E
Juices - Vegetable. . . . . . . . . . . . . .E
Kerosene

......................

OS
(continued)

371

Cements, Mortars, and Asphalt


TABLE 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD

(continued)

SOLVENTS AND OTHER CHEMICALS (Continued)


SUBSTANCE

RATING

SUB STANCE

Lanolin. . . . . . . . . . .
Lard. . . . . . . . . . . . . . . . . . . . .
Linseed Oil.. . . . . . .

RATING

.............E
. . . . . . . . . . . . .F
Phenol - 5%. . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . NR
Mayonnaise. . . . . . . . . . . . . . . . . . . . G
Methyl Ethyl Ke
. . . . . . NR
Methyl Isobutyl
. . . . . . . . . . . . NR
Methyl Salicylate - 50% in
Toluene. . . . . . . . . . . . . . .
Methylene Chloride. . . . . . . . . . .
Muriatic Acid
(See Hydrochloric Acid)
Mustard. . . . . . . . . . . . . . . . . . . . . . .

Naphtha. . . . . . . . . . . . . . . . . . . . . . .

Skydrol .......................
Sucrose - Sat. (Sugar). . . .

. . . . . . . . . . . . . . .E

Trichloroethane. . .
Trichloroethylene. .
Triethanolamine. . .
Triethylene Glyco I.

Vinegar

. . . . . . . . . . . . . . . .E
(Household). . . . . . . .

Water. . . . . . . . . . . . . . . . . . .
Wine. . . . . . . . . . . .
. . . . . . .E
Oils - Mineral. . . . .
Oils - Vegetable. . .

Xylene. . . . . . . . . . . . . . . . . . . . . . . .

Chemical Resistance Guide for STONCLAD HT


ACIDS
CHEMICAL

RATING

Acetic - 5%. . . . . .
Acetic - 10%.. . . .
Acetic - 3 0 % . . , . ,
Acetic - Glacial.. . . . .

RATING

Lactic - u p to 20%. . . . . . . . . . . . . . F
Lactic - over 25%. . . . . . . . . . . . . . OS
Maleic
Maleic
Maleic
Maleic

Benzoic - Sat . . . . . . . . .
Boric - Sat . . . . . . . . . . . . . . .
Chromic - 10%.. . .
Chromic - 150h.. . . . . .
Chromic - 30%. . . .
Citric - Sat . . . . . . . . . . . . . . . . . . .E
Cresylic. . . . . . . . . . . . . . . . . . .
. os
Diglycolic. . . . . . . . . . . . . . . . . . . . . .

CHEMICAL

Fatty.. . . . . . . . . . . . . . . . . . . . . . . . .
E
.F
Formic - u p to 10%.. . . . . . . .
Formic - over 10% . . . . . . . . . . . NR
Fluoboric. . . . . . . . . . . . . . . . . . . . . .
G

. . . . . . . . . . . . . os
. . . . . . . . . . . . .E
Hydrochloric - 37%. . . . . . . . . . . . . G

Hydrofluoric - 5%. . . . . . . . . .
Hydrofluoric - 10%.. . . . . . . . . . . . G
Hydrofluoric - 15%. . .
Hypochlorous - 5%. . . . . . . . . . . . . E

- 10%.. . . . . .
. . . . . . .E
- 30%. . . . . . . . . . . . . . . . . .G
- 40%.. . . . . . . . . . . . . . . . . F
- Sat . . . . . . . .

Mr,nochloroacetic
Mmochloroacetic

-1
- 20%. . . . . . . . . 0s

Nitric - 20%. . . . . . . . . . . . . . . . . . . E
Nitric - 30%
.........
G
Nitric - over
. . . . . . . . . . . . . . . NR

Oleic.. . . . . . . . . . . . . . . . . . . . . . .
E
Oxalic - S a t . . . . . . . . . .
....E
Pelargonic. . . . . . . . . .

. . . . . . . .os

Phosphoric - 70%. . .
Picric - Sat.. . .
Phthalic.. . . . . . . . . . . . . . . . . . . . . . .
Succinic -Sat

....

..E
(continued)

372

Corrosion Resistant Materials Handbook

T A B L E 3.1: EPOXY-BASE FLOOR SURFACING SYSTEMS-STONHARD

(continued)

ACIDS (continued)
CHEMICAL

Sulfuric

RATING

CHEMICAL

. . . . . . . . . . . . . .E
. . . . . . . . . . . . . .F
- 98%. . . . . . . . . . . . . . . . .NR

Tannic - Sat..

..............

RATING

Tartaric - S a t . . . . . . . . . . . . . . . . . . E
Trichloroacetic - 5?6 . . . . . . . . . . , G
Trichloroacetic - 10% . . . . . . . . . . .F
Trichloroacetic - 20% . . . . . . . . . .os

.E
ALKALIES A N D SALTS

CHEMICAL

RATING

CHEMICAL

Aluminum Chloride - 50%. . . . . . . . E


Ammonium Chloride - Sat . . . . . . . E
Ammonium Hydroxide - u p t o 20%. E
Ammonium Hydroxide - u p t o 40%.G
Ammonium Nitrate . . . . . . . . . . . . . . . E
Ammonium Sulfate - Sat.. . . . . . . . . E

RATING

Potassium Hydroxide

- up t o 40%. . E

Sodium Carbonate (Soda Ash)-Sat.. E


Sodium Bicarbonate - Sat.. . . . . . . . E
Sodium Bisulfate - Sat.. . . . . . . . . . E
Sodium Bisulfite - Sat.. . . . . . . . . . . E
Sodium Chloride (Salt). . . . . . . . . . . .E
Sodium Hydroxide - u p t o 50%. . . . E
Sodium Hypochlorite - u p t o 10%.. . G
Sodium Sulfate - Sat.
Sodium Sulfide - S a t . . . . . . . . . . . . E

Calcium Chloride - Sat . . . . . . . . . . E


Calcium Hypochlorite - up t o 15%. . G
Copper Fluoroborate. . . . . . . . . . . . . E
Ferric Chloride - Sat.. . . . .
Ferrous Sulfate. . . . . . . . . . .

Trisodium Phosphate - Sat..


Zinc Nitrate..

......E

. . . . . . . . . . . . . . . . . . .G

SOLVENTS AND OTHER CHEMICALS


SUBSTANCE
RATING
Acetone. . . . . . . . . . . . . . .OS
Acrylonitrile. . . . . . . . . . . .OS
Aniline. . . . . . . .
Isopropyl. Butyl). . G
Amyl Acetate. . . . . . . . . . . E
Beer.. . . . . . . . . . . . . . . . . E
Butyl Lactate. . . . . . . . . . . G
Bromine. . . . . . . . . . . . . . . NR
Carbon Disulfide.
Carbon Tetrachlo
Chlorobenzene. . . . . . . . . . E
Corn Oil. . . . . . . . . . . . . . . E
Cyclohexane. . . . . . . . . . . . E

Chloroform.

. . . . . . . . . . . . NR

Diacetone Alcohol. . . . . . . E
Diethyl Phthalate., . . . . . . E
Dimethyl Phthalate. . . . . . . E
Ethyl Acetate. . . . . . . . . . . 0 s
Ethylene Glycol. . . . . . . . . E
Ether. . . . . . . . . . . . . . . . . 0s
Ethylene Dichloride. . . . . . . NR

SUBSTANCE
Formaldehyde..

RAT ING

. . . . . . . . . . . . . .E

Gasoline.. . . . . . . . . . . . . . . . . . . . E
Glycerine. . . . . . . . . . . . . . . . . . . . E
Glyoxal. . . . . . . . . . . . . . . . . . . . .
.E
Hydrogen Peroxide - 10%.. . . . . E

S U B STANC E
RATING
Naphtha.. . . . . . . . . . . . . . E
Naphthalene . . . . . . . . . . . . G
oils - Cutting.. . . . . . . . . E
Oils - Mineral. . . . . . . . . . E
Oils - Vegetable. . . . . . . . G

JP5 Jet Fuel.. . . . . . . . . . . . . . . . . E


E
Juices - Fruit. . . . . .
Juices - Vegetable..
...... E

Peanut Butter.. . . . . . . . . . E
Perchloroethylene. . . . . . . E
Phenol - 5%. . . . . . . . . . . NR
Pyridine.. . . . . . . . . . . . . . NR

Kerosene . . . . . . . . . . . . . . .G

Sucrose

Lard.

. . . . . . . . . . . . . . . . .E
..........
.........F
................ E

Methanol . . . . . . . . . . . . . . . . . . .NR
Mayonnaise. . . . . . . . . . . . . . . . . . G
Methyl Ethyl Ketone.. . . . . . . . . . .OS
Methyl Isobutyl Ketone.. . . . . . . . . OS
Methyl Salicylate - 50% in
Toluene. . . . . . . . . . . . . . . . NR
Methylene Chloride. . . . . . . . . . . . NR
Milk.. . . . . . . . . . . . . . . . . . . . . .
.E
Mineral Spirits. . . . . . . . . . . . . . . .E
Muriatic Acid
(See Hydrochloric Acid)
. . . .E
Mustard. . . . . . . . .

- Sat. (Sugar). .. E

Toluene . . . . . . . . . . . . . . . . G
Triacetin.. . . . . . .
....E
Trichloroethane. .
. . ..G
Trichtoroethylene. . . . . . . . G
Triethanolamine.
....... E
Triethylene Glycol. . . . . . . E
Urea

. . . . . . . . . . . . .E

Vinegar (Household).
... E

Cements, Mortars, and Asphalt

373

TABLE 3.2: EPOXY FLOORING COMPOUNDS-ATLAS


REZKLAD C IS a monolithic overlay designed specifically for use in applications where hydrofluoric acid and high
concentrations of sodium hydroxide are encountered. REZKLAD C has been formulated to incorporate toughness,
ability t o tolerate temperature cycling and good physical strength.Thls material IS installed dlrectly on the concrete
slab t o give a durable, corrosion-resistant topping.
CHEMICAL RESISTANCE OF REZKLAD C FLOORING COMPOUND

_____

RT

140'F
___

-~

-_

Acetic A c i d b e l o w 5 %

5% to 10%
Acetic Actd
- _______

-__

Acetic
i d 10% t o 50%
- A c~Acetone
_ ~~
_ -

Lux L i q u i d

N
_

-~

R
A l u m or A l u m i n_u _
m_ Sulfate
_
A m r.r ~-i i u-n i-- C hl o r i d e Nitrate
Sulfate
50% R
__._
__

R
R

Benzene S u l f o n i c Acid 10%

- ~ _ _

Benzoic Acid
-

___

Black Liquor - - - -_ _ _ _
Bicachinq Liquor below 2%

R
R

N
~

_ _--

R
N

E t h_y k_n-e Dichloride


_-Ethylene -G l y_____
col
F i~-~
t t i Acids.___Ferric C h l o- r i d__
e Nitrate- Sulfate
_ _ _
Fluosilicic A c i d

_ _R _ _
-

-___

- -.-

N
R

N
R

___

Hydrofluoric Acid
~
_

20% t o 70%

H y d r o g e n Peroxide

Phosphoric
_ - _ _Acid
_ _to 25%
___ __Phosphoric Acid
25% Io 50%
_~
-~

_ - ~CR

R-~
C
N
__-N

Phosphoric
A c i d above 50%
__________

__

Pycric Acid to 5%
Potassium
C h l o r i d e Nitrate
Sulfate
- -- __ __-___
Potassium H y d r o x i d e
-____-_

_ N_ _

below 25%

R-~
C
R ____
R

R
R
____

Potassium
H y d r o x i d_
e 25%
to 50%
_ - ~._

____C

Sodium
Bicarbonate Carbondre
___
______
_
_
Sodium
Nitrate Phosphate
_ _ ~ Chloride
- Sodium_
Sulfate Sulfide
_
-__
Sodium H y d r o x i d e t o 25%
________-

R
R

R
R

R
R

Sodium
-

H y d r o x i d e 25% t o 50%

R-____
C
C
N

S o d i u m Hypochlorite below 6 %

S o-______
d i u m Hypochlorite 16%

N
- -~

N__
C
--_-R
R
N
____

Stannic C h l o r i d e
Stearic Acid
Sugar Salt Solution

Sulfuric
c i d_
below
_ _ _A_
_ 40%
Sulfuric
_ Acid
_ _50%
-

____-

_R_ _ _C _

__

C -N
---

R ~ _
_ _ _ _ -_R _ _

Tpmato Juice
____

R
___

Trichloroethylene

Trisodium
_-

~~

-~

-R-CR
C

__

Phosphate

~
Turpentine
_ _

Vegetable O i l

~C

Vinegar
-~

R
R

C
R

R
R
C

N
N
N

Lactic A c i d 5% to 10%

Urine
~-

Water Distilled
_ _ _
_
Water a n d Sewage
_______
Xylene

~~

Water Fresh
~-

R
R_ _
_____

Urea, t o 20%
-____

_ - - _ _ _c

__

~~

t o 5%
Jet Fuel
Kerosene
Lactic A c i d b e l o w 5%

Petroleum
--__
_ ~ - _
Phenol below 5%
~
~

_H_y p o c h l o r o u s & i d

R____
N

Perchloroethylene
- _ _ ___

_____
t l y d r i x hl o r-i c ALid
---__20% to .36%~ C _ N_ _ -_
___

_R_ _

H y d r o f l u o r i c A c i d t o 2Ooh

- ___

Toluene Sulfonic A c i d
-

- - - _ _ - _

__

H y d r o b r o m i c A c i d 20%
.
-Hydrochli;ic
A c i d t o 20%
_

S u l f u r o u s Acid below
10% -Toluene
-

___.

or washed off the


surface

__

Grape Juice
~ _ _

- - --- -

______

Formic A_c i d
_90%
____~
~

N
C
N
N

__.

i_
illu
50%
_ r i_c ALid
_ _ ~above
~ ~-

_ _ _ _R_ ~ C

Formaldehyde
below 37%
_____

----

be s e r v i c e a b l e i f t h e
c o n t a m i n a n t is i m m e d i a t e l y removed

_-_~

N_
R
N
N

~~

R
C
_____

Oxalic
Acid
- __
__

- -_____

C - C o n~
d i t i o n a l M a y~

R
-~

Mineral
_
_Oil_ _ _ _ _ _ R_ R~ ~

_ ~ - _ __

~~

E t h y l_ Acetate
- - -__
E t h y l Alcohol_ _

-Magnesium C h l o r i d e Nitrate Sulfate


Maleic A c i d 25%
_
_
_ _

N - Not Recommended

C ~N
Nitric
A c i d b e l o w 5%
_____
t o_
10%
C
N
N
Nitric A c i d -5%._
. _- -- ~
_ - - ~
R
Oils _Vegeldble
c c __
_
_____ ----- ~~Oleic _Acid
N ___
N
R
_ _ ~ _ _ _
_____

Ether

c _ _c _ _

R
_

N i c k e l C h l o r i d e Nitrate Sulfate

R
R

~-

N
N

Milk

N
N
___________
Boric Acid R
__ _ _ _
______ R
Butyl Acetate
N
N
___ - _
t3ulyl AILotloI
R __
C_
- _
_ _____
Uutyric Acid
N
_____ N
I o ri d e N iI rat e Su IIat e
C d I L i u in C h
R
_ _ -~ - _ -R ____
Cnlci u ni~H y d r o x i d e_
R
_ _ _ - _ ~- R
CdlClUm H y- p o-c h l_
o r i t_
e
N
_ _ _ _ _ C -___
Ctilorine Dry
C
N
______
Chlorine Wet - ~
c
~c
Ctiloririe Wdlcr
___ - __- C - N___
ClllOlOdLellC
Acid_ _10%
_~
_____
~ N~ N _
Chloroform
_
_ R _ _~C_ N
C h r o m-~
i c A c i d 5%
_-____C
C h r o i n i c A c i d 5% to 10%
N
N
- -__ _ _ _ _ _ ___
R
N__
Citric Acid 10%
- - ~ _ _ _______
-

N
N

Methyl Ethyl Ketone

Copper
Nitrate Sulfate
_ _ _Chloride
_
- -

R - Recommended

-~
I? __
T
1400F
- -.

~-_

Methylene C h l o r i d e
-

_
_
~N
f l d r i u_m~ Chloride
Sulfate
R
________
Beer
~ _ __
~
~R
Benzene
__ - - -_ _ _ _
- _ _ _N_
Aqua Regia

Methyl
A_
lcohol ~
-

A m m o n i u m H y---__
d r o x i d e 10%
R
R
___________
Amrnonium
R
C
_ _ H _y d_ r_o x i d e 30%
Aniline
-~

Lactic A c i d above 10%


Lard

~
.

Z i n c C h l o r i d e Nitrate Sulfate

R
R

C
______
~

R
R

N
~

(cont Inued )

374

Corrosion Resistant Materials Handbook

TABLE 3.2: EPOXY FLOORING COMPOUNDS-ATLAS

(continued)

REZKLAD 250 i s the trowelable counterpart to sprayable REZKLAD 125s. REZKLAD 250 utilizes a room temperature curing, aromatic amine hardening system, thus the reason for i t s outstanding chemical resistance. In addition, this material has been formulated t o incorporate outstanding physical properties. REZKLAD 250 upgrades t h e
surface of existing concrete floors and provides positive protection a t a reasonable cost. Rezklad 250 complies with
ASTM C722, Specification for Chemical-Resistant Monolithic Surfacings.
CHEMICAL RESISTANCE OF REZKLAD 250

- .___
__..-

H e i k i a d 250
R l 15O'F

.-

Rezklaa 250

--.

~_ _ ~ _ _ ..~_.

R - Recommended

R T~
._.__
150F
~

Lactic
Acid. 5% t o 10%
R
R
Acelic A c i d~~-~
. below
_
_5%~ ~ _ ~ ~ - ~ _ _ _ R~ _R_ ~ __
_ . _ _ _ _ _ ~
AceGc Acid. 5% t o 10%
R -._
R
Lactic Acid, above 10%
R__.._
C
- .-. .. ... -~
_-_.
_______
Acetic A c i d , 10% t o 50h
R
C
Lard
R
R
.-..
..___
~~-~
- ___________
._____
Ace ton
e .....~.. _ _ ...-. .___._C
NR
Lux L i q u i d
R
R
~-.
__._
..__________
~

__

~~

~~~~

Magnesium
Chloride.
Nitrate. Sullate
R
R- ~ ___._
_
________.___

Methylene C h l o r i d e

_.

____-___

. ..__

Mineral C i I

__
N~i c k
el~
C h l o r_
i d e , Nitrate Sulfate ._~~
~~__--______

5"/.___

black Liquor
~ ~ .
____..__~.____
i l e a c h i n g Liquor. below 2%
. . _-._
- .~_____
___-Bleaching
L i q u o r . ~c _
on
.. ._._._-___
_c_ _ _ _ _ _ _ _ _

R
R

NR NR

Oleic A c i d
~~~~~
~
~
_
Oxalic A c i d
_ _ _ _- -~
._.
-- ~ - Perchloroethylene
.___._._

Boric Acid

R-~
R

Petroleum

..
. _ _ . ..__--

B u t y l Acetate
- __.. .._ ... .Butyl Alcohol
__ - ~_
Butyric Acid

RR

~~~

--

NR

CalL I u n i C h l o r i d e . Nit r dte, Sullat e

Cdlcium Hydroxide

~~

___

~~

__..__.--~__

. ..

-_

._--_

~ _ ~ _.____
_ _~

~~

C t i Iu f olor ni~
~~

_ _

_ _ _ _ c_
R

._._.

C t i Ior oac et i c Ac -........._._


i d , be l o w 1 0%
_~
. .

C_

Phenol,
~_~~
_ ~ below
_ ~ _.__._.
_5%
_
.__-_
_ _ _ _ _c_.___
~ -Phosphoric
Acid,
to
25%
R
B RB
_~______
-.
~
_
_
_
Phosphoric A c i d , 25% to 50%
CB N
R
~~.
-~_ _ _ _ _ .. __._
- _ ~ . . _ ~ . _ ~ ___._.
_
Phosphoric Acid. above 50%
NR --.
__
- - ~ - - - ~

_.....__

NR

R
_

Potassium
y d r.o x i d e_
, below
25%
-_ _ ~ H
. -.__._
_
_____
~
Potassium
ydro
x i_
d_
e_
, 25%
to ~50%
_ _ _ _ _ ~H_
_
~
--.
__

--

--

c-

S o d i u m Bicarbona;e,
Carbonate
-~
_s o _d i u_m _Chloride.
_ ~ - Nitrate. Phosphate

R
R
R
R

R
R
R
R

_ _ _ R_ R_ . ~

_ _ _ _ R ~ --_

S o d i u m Sulfate.--__
Sulfide

S o d.
i u.___
m H y ___..~
d r o x i d e , t o 25%
-.--. ~
----_-___
~ _ _ R_ c
_ _ _
. .~~
Cllrornic Acid. 5% Io 10%
c
NR
S o d i u m Hydroxide. 25% t o 50%
.
-.- _ _ ~ _ __ ~ - ~ _ _ _ _ ~ _ _ _ ~
Citric Acid, to 40%
S__._
odium
Hypochlorite. below
6%
______
~.. .
- - . ~ ~_
- ~
_~_ . _ _ _ _ __R R

_ _ _ _ _

C h r o m i c Acid. below 5%
.

__._

Picric Acid.
t o 5%
_._.__ _ _ _ _ _ _ _ _ _ _ _ ~
Potassium Chloride,
Nitrate. Sulfate
_-

~~

C h l o r i n e , Wet
. .. .
-C h l o r i n e Water

.R

. _ _ _
-.---..~-

__.__

~~

~~~

_-....- .

R. R-

~_~

_ _ . . . _ _ __._..___

R
R
c
Calci
~.
um
-.
~..
H y p _o c_
h l~
o r i_
t e_ _ _ _ _ _ _ _ _ _ _ _
Chlorine. D r y
c -~.
~________
~

surface
filler will be
a-t t a c k e d . Sealing
t h e surface may
prolong
t h e life.
-

....-.- ~~_

. -.

removed

or washed of1 the

mediately

B - May c o n t a i n t r a c e s
c c
of hydrofluoric acid
c
or acid fluorides.
--..---. c
c c_
Silica filler may be
_
__ . _ _
_
.
R
R
attacked. See "A".

_._.____-

--

..-

--

R~ R ~
R
R

- ~

. _ ~ _ _

__..____
_ _ ~ _ _ _ _ _ ~

__._

NR

R
~

_.-~

__._

.~
__.___...

--

~~~

Benzene
NR
N't.'L%A2d~be!5""
~ ~ _
.__.__
. - .___.__
~- R
Benzene
~ S
~ u_
l f o ~n i c~ A c~ i d~, 10%
- - _ .- -_._____R
R
Nitric Acid, 5% t o 10%
Benzoic A c i d
R
R
Oils. Vegetable

May
be s e r v i c e a b l e i t t h e
c o i l l a m i n a n t is im-

Conditional

-'---:
- ~
Silica
_

_~_
. ._~

Ethyl Ketone

_ _
_ - ~
~ -_
- -_
~ -_ _ _ .

R_ R ~

~ Milk

,e;

._.__._
~.

Methyl
.~

~ ~ _ ~ ~ ~ _ - _ _

_~_______

_______

_Methyl~A l c o h o l

R
R
_ _ _

R~ R_

Maleic
Acid ~
_ ~ _ -__._.__
_____

~~

B a r l u m Chloride. Sullate

C-

_______

m Sullate
R
R
-Alurn
...-. or A l u m i.n u_
~ .
_ _ ~_______
A m m o n i u m C h l o r i d e , nitrate sulfate. 50% R
R
- _ _ - . _._._
.-.
__._._ -..R
R~
A m m o n i u m H y d r o x i d e , 10%
_
. . .~
_._
~- ..
_
__
-~_~______
A mm o_n i u m H y d r o x i d
30%. _ _~ . _R _
_
~e. _
~C_
Aniline
C ..--NR
_ ~ _..___._.._
_-.
______~.
A q~~~_~
u a Regia
__...._-._
~
~
_______
_ NR _NR
~

NR - Not Recommended

NR

~ _ _ ~____
__~

Cuppal Chloride, Nitrate, Sullate


.-.

- ~ .

S o d i u m Hypochlorite. 16%

~___

_ -._-._.__

--_ ~ - _ _ ~
-Ethyl A l c o h o l
~
~ ~ _ __-_ _ _~N R -Ethylene D i c h l o r i d e
. __ _ _ _ _ _ ______
a

Ether
.. . _________

~~

Sugar, Salt Solution


Sulfuric Acid. t o 80%
--Sulfuric Acid. above 80%

_ _ __

Ethylene
~
~ G l y_c o l

Fatty
Acids~
~ . -.~

~
~~_ _.-~

Fluosilicic
Acid.
30%____-_______ A
. ~. __..
~ _ _

Formic
_ _Acid.
_ _ .90%
. ~

. -

~~~

t i y d r o c h i o r i c Acid. t o 20%

- -._~
~_ _
~ ~ ~

~H y d-r o c h_l o r i_c Acid. 20% t o 36%


H y d r o l l u~.
o r i c. Acid.
t o 20%
...___.
_
__.._
~
~-~~

R
R

~___

H y d r o l l u o r i c Acid. 20% to7OUh

-~

~ __

~~

Jet
Fuel
-.~
Kerosene

__---

Toluene
~- Sulfonic A
~c_i d _ _ _ ~ _ _ _ _
Tomato
Juice
__-.-___.._________.__
~~

_ _ _ _ _ _ _ _ ~ . ._____

--

R __
R

R
R

R
NR

R
R

C
R

. ..____

-____

~~

_ _ ~ ~ _ _ _ ~ _ _ R_ _-- _ _
__________________ R R

Turpentine
~-~
.__-.
~

Urea, t o 20%

-~~ ~

NR
_
~ _ _ _A~____
_
R _
-- _
_ _ _

R
C
_-~_________
R
--____
.~

Lactic Acid, below


5%
_______

Trichloroethylene
C
NR
_____-__
_ _ _ _ _ _ __
Trisodium
R
R
~ _ Phosphate
_ ~ ~ _ _ _______.-__~

_ _ _ _A_ _A-

___._._

H y d r o g e n Peroxide
____-~~_
H y p o c h l o r o u s Acid. t o 5%
.__..___._.

__.___

~~

R
_ _R

Grdpe
Juice
.~
- ~.
. .
__.__~
H y d r o b r o m i c A c i d . 20%

__~

Acid. b
e l o w 10%
~

Toluene

R
R
___

Forrndldehyde.
b e l o w 37%
. ~ -. ~ _ ~~ _ ~ _
..-.

Sullurous
___
.

c~
__ c
._..__

Ferric~
Chloride.
Nitrate.
Sullate
~
___.._..___
_
~
.
_

R
NR
___
R
R
-~
R
R
R
R
C NR

Stannic C h l o r i d e
__
Acid
_Stearic
__

c
c

E t h_
y l Acetate
_ ~

Urine
Vegetable O i l

~~~

__~___

Water.
Distilled
-.___
___

R
_ _ _ - ~ RR_ R
_ _.__ ~~-~

Water and Sewage


....

C
-

R
R
--~~
.___.__..._

Vinegar
_ _ ~~
_ _
Water, Fresh
~~~

R
-

~ _ ~R _ R_ _

_ _ _ _ _ ~ . _ _ _._.___..._

xylene

-~-___
- _._._.
__.

Zinc
C h l o r i d-e , Nitrate.
Sulfate
.
.-..
~

NR
-R
_~--.~

._______~

KEY:

Resistant to 160'F (71'C)

The highest temperature tested, may and/or could be revised


basis of further test.

Resistant to 90F (32OC)

Not Resistant

* * Resistant to 70'F (21'C)

Carbon filled

376

Corrosion Resistant Materials Handbook

TABLE 3.3: EPOXY MORTAR AND FLOOR TOPPINGS-PENNWALT


Calcium hypochlorite. . .
Calcium nitrate, saturated
Calcium sulfate.

............
.............
..................

..................
Carbon disulfide . . . . . . . . . . . . . . .
Carbon monoxide . . . . . . . . . . .
Carbon tetrachloride . . . . . . . . . . . . .
Carbon dioxide.

Caustic (see Sodium hydroxide) . . . .


Chlorinated lime. . . . . . . . . . . . .

. . .
...

. . . . . . . . . . . . .
..
........
Chlorine water . . . . . . . . . . . . . . . . .
Chloroacetic acid 100% . . . . . . . .
Chloracetic acid 10% . . . . . . . . . .
Chloronaphthalene . . . . . . . . . . . . . .
Chloronitrobenzene . . . . .
. . . .
Chromic acid 5 % . . . . . . . . . . . . . .

Ferric chloride, below 50%

Furfural.

...........................
......................

Furfuryl alcohol

Chlorine (wet) 500 ppm

Gallic acid

Coolant brines . . . . . .
Copper acetate, saturated

..

Household ammonia (see ammonium hydroxide).

Crude oil . . . .
Cyclohexane. .

.................
..................
Cyclohexanone . . . . . . . . . . . . . . . . . .
Dichloroethylene. . . . . . . . . . . . . . .
Diesel fuel . . . . . . . . . . .
. . . .
..

Dimethyla(1inoethanoI .
Dimethyl formamide
Diphenyl or diphenyl oxide
Ether
Ethyl alcohol

..................
. . . . . . . . . . . . . . . . . .

Ethylamine, 40% aq sol..


Ethyl chloride.

.............

..................

.................
Ethylene glycol. . . . . . . . . . . . . . . . . . . .
Fatty acids . . . . . . . . . . . . . . . . . . . . . .
Ethylene dichloride

Glycolic acid

Hydrochloric acid, any. . . . .


Hydrochloric acid, below 10%
Hydrochloric acid

...........

...........
10-32%. . . . . . . . . . . . . . . .

.................
...............
Hydrofluoric acid 20.70%. . . . . . . . . . . . . .
Hydrogen peroxide 50% . . . . . . . . . . . . . .
Hydrogen sulfide. . . . . . . . . . . . . . . . . . .
Hydroquinone . . . . . . . . . . . . . . . . . . . . . .
Hydrosilicofluoric acid. . . . . . . . . . . . . . . . .
Hypochlorous acid. . . . . . . . . . . . . . . . . . . . .
Hydrofluoboric acid

Hydrofluoric acid 10.20%

Iron sulfate, saturated . . . . . . . . . . . . . . . .


Jetfuel . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Kerosene . . . . . . . . . . . . . . . . . . . . . . . . . .

..

.....................
Lard . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Magnesium bisulfite. . . . . . . . . . . . . . . . . . .
Lactic acid 85%.

D in i tr o be n ze ne

Ethyl acetate

Glycerine. . . . . . . . . . . . . . . . . . . . . . . . . .
Glycol. . . . . . . . . . . . . . . . . . . . . . . . .
Glycol acetate. . . . . . . . . . . . . . . . . . . . . . . .

. . .

............

. . . . .

Gasoline

..........................
........................

......................
Heptanoic acid, any. . . . . . . . . . . . . . . . . . .
Hexachlorocyclopentadiene. . . . . . . . . . . . . . .

. . . . . . . . . .
Copper chloride, nitrate, sulfate . . . . . .
Cottage cheese . . . . . . . . . . . . . . . . .
Cottonseed oil . . . . . . . . . . . . . . . . . . .
Cresols . . . . . . . . . . . . . . . . . . . . . .

Diethylene glycol
DiethylenetrLamine

..............

...............
...............
Fluorine up t o approx. 50%. . . . . . . . . . . . . . .
Fluosilicic acid 30%. . . . . . . . . . . . . . . . . . .
Formaldehyde, below 37% . . . . . . . . . . . . . . .
Formic acid 90%. . . . . . . . . . . . . . . . . . . . . .
Fumaric acid . . . . . . . . . . . . . . . . . . . . . . . .
Ferric chloride, anhydrous
Ferric nitrate or sulfate. . .

Chlorine (dry). .

Chromicacid 5-10o. . . . .
.
Citric acid 406 . . . . . . . . . . .

(contlnuedl

Magnesium chloride, saturated


Magnesium sulfate, saturated

............

Maleic acid, below 40%.


Maleic acid 40%
Maleic anhydride

...........
. . . . . . . . . .

. . . . . . . . . . . . . . . . . .
. . . . . . . .

. .
. . . . .
..
. . . . . . . . . . . . . .

Mercuric chloride, saturated


Mercury
Methacrylic acid

...

....

Cements, Mortars, and Asphalt

TABLE 3.3: EPOXY MORTAR AND FLOOR TOPPINGS-PENNWALT


Methyl a c e t a t e . . . . . . . . . . . . . . . . . . . .

....................
Methyl amine 40%. . . . . . . . . . . . . . . . . .
Methyl "Cellosolve". . . . . . . . . . . . . . . . .
Methyl chloride. . . . . . . . . . . . . . . . . . . .
Methy cyclohexanol. . . . . . . . . . . . . . . . .
Methyl alcohol

................
................
Methylene chloride . . . . . . . . . . . . . . . . .
Milk . . . . . . . . . . . . . . . . . . . . . . . . . . .
Mineral o i l . . . . . . . . . . . . . . . . . . . . . . .
Miscible oil. . . . . . . . . . . . . . . . . . . . . . .
Monochlorobenzene. . . . . . . . . . . . . . . . .
Motor oil (see Crude o i l ) . . . . . . . . . . . . . .

(continued)

Po:assium chloride, nitrate or sulfate. . . . . . . . .


Potassium cyanide, saturated . . . . . . . . . . . . . .
Potassium ferricyanide, saturated . . . . . . . . . . .
Potassium hydroxide 50%. . . . . . . . . . . . . . . .
Potassium nitrate, saturated. . . . . . . . . . . . . . .
Potassium permanganate, below 5% . . . . . . . . .

Methyl ethyl ketone

Potassium peroxide 5%. . . . . . . . . . . . . . . . . .

Methyl naphthalene.

Potassium persulfate, saturated . . . . . . . . . . . .

Muriatic acid (see Hydrochloric acid)


Naphthalene.

.....

.....................

Nickel chlorate, nitrate or sulfate . . . . . . . .

....................
Nitric acid 70%. . . . . . . . . . . . . . . . . . . .
Nitric oxide gases . . . . . . . . . . . . . . . . . .
N it r o be nze ne . . . . . . . . . . . . . . . . . . . . .
Nitrosylsulfuric acid. . . . . . . . . . . . . . . . .
Nitropropane . . . . . . . . . . . . . . . . . . . . .
Oils (saponifiable) . . . . . . . . . . . . . . . . . .
Oleic acid. . . . . . . . . . . . . . . . . . . . . . . .
Oleum . . . . . . . . . . . . . . . . . . . . . . . . . .
Nitric acid 5%.

......................
.........................

Oxalic acid.
Oxygen

.......
........................
Perchloric acid . . . . . . . . . . . . . . . . . . . .
Perchloroethylene . . . . . . . . . . . . . . . . . .
Petargonic acid . . . . . . . . . . . . . . . . . . . .
Petroleum . . . . . . . . . . . . . . . . . . . . . . .
Phenol, below 5% . . . . . . . . . . . . . . . . . .
Paradimethylaminobenzophenone

Paraffin.

Phosgene . . . . . . . . . . . . . . . . . . . . . . . .
Phosphoric acid 85%

................

Phosphorous chlorides

...............

.................
Picric acid 5%. . . . . . . . . . . . . . . . . . . . .
Picric acid 50%. . . . . . . . . . . . . . . . . . . .
Potassium bromide, saturated . . . . . . . . . .
Potassium carbonate, saturated . . . . . . . . .
Potassium chlorate, 50%. . . . . . . . . . . . . .
Phthalic anhydride.

Po?assiurnsulfate saruratsd . . . . . . . . . . . . . . .

.....................
.........................

Potassium sulfide.
Prussic acid

Pyridine. . . . . . . . . . . . . . . . . . . . . . . . . . . .

.....................
....................
Salicylic acid . . . . . . . . . . . . . . . . . . . . . . . .
Salt, saturated. . . . . . . . . . . . . . . . . . . . . . . .
Sodium acetate, saturated. . . . . . . . . . . . . . . .
Sodium bichromate . . . . . . . . . . . . . . . . . . . .
Quinoline sulfate.

Saccharin solutions

Sodium c h lor ide, carbonate, bicarbonate,


phosphate, nitrate, sulfate or chlorate
Sodium hydroxide 50%

....

.................

........
...............
Sodium peroxide 5% . . . . . . . . . . . . . . . . . . .
Stannic chloride . . . . . . . . . . . . . . . . . . . . . .
Steam . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Stearic acid, any . . . . . . . . . . . . . . . . . . . . . .
Sugar, saturated . . . . . . . . . . . . . . . . . . . . . .
Sulfur chloride . . . . . . . . . . . . . . . . . . . . . . .
Sulfur dioxide. . . . . . . . . . . . . . . . . . . . . . . .
Sodium hypochlorite, below 6% C12.

Sodium hypochlorite 2 7%.

Sulfuric acid 80% . . . . . . . . . . . . . . . . . . . . .


Sulfuric acid 98%

.....................
...............

Sulfurous acid, below 10%

...................
.....................
............................

Sulfur monochloride
Sulfuryl chloride.
Tannin

Tar, tar oils . . . . . . . . . . . . . . . . . . . . . . . . .


Tartaric acid, cold saturated . . . . . . . . . . . . . .

.....................
Tetrachloromethane. . . . . . . . . . . . . . . . . . . .
Tetrahydrofuran . . . . . . . . . . . . . . . . . . . . . .
Toluene. . . . . . . . . . . . . . . . . . . . . . . . . . . .
To Iuenesu If on ic acid . . . . . . . . . . . . . . . . . . .
Tetrachloroethane

377

378

Corrosion Resistant Materials Handbook

TABLE 3.3: EPOXY MORTAR AND FLOOR TOPPINGS-PENNWALT

........................
Trichloroacetic acid . . . . . . . . . . . . . . . . .
Trichloroethylene . . . . . . . . . . . . . . . . . .
Triethanolamine . . . . . . . . . . . . . . . . . . .
Towngas

................
......................

(continued)

Urine . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Vegetable oil . . . . . . . . . . . . . . . . . . . . . . .
Vinegar . . . . . . . . . . . . . . . . . . . . . . . . . . .
Water, fresh . . . . . . . . . . . . . . . . . . . . . . . .

Trisodium phosphate

Water, dis;illed . . . . . . . . . . . . . . . . . . . . .

Turpentine.

Xylene . . . . . . . . . . . . . . . . . . . . . . . . .

Urea 20%. . . . . . . . . . . . . . . . . . . . . . . .

Zinc chlo: de 5096 . . . . . . . . . . . . . . . . . .

Solutions Common to the Plating Industry


Floor and Wall Service (Not for Immersion;
Acidcopper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
AcidZinc . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Aluminum bright dip +? 41 Phosphoric acid heat

Bath alumabrite
Concentrate # 41

.........................................
D.S.. . . . . . . . . . . . . . . . . . . . . . . . .

Aluminum Pickle - Northwest AI, Alume

Aluminum Pickling, Enthone Nitric acid with Enthone actane ii 70

............................
Alkaline t i n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Anodizing Electrolyte - 15 - 1806 sulfuric acid . . . . . . . . . . . . . . . . . . . . . . . . .
Brass bright dip - 50% nitric, 50% sulfuric . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cadmium bright d i p . with nitric acid with Kenvert conversion additive.

........

.........................................
................................
Chrome plating bath - approx. 4502 CR t o gallon 4502 sulfuric . . . . . . . . . . . . . .
Chromium . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Copper F luoroborate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Copper Lume, Copper cyanide. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Copper plating bath - cyanide with #625 Allied Research additive . . . . . . . . . . . .
Copper plating bath -straight cyanide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Enthone stripper. SI8 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Iron Chloride . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Cadmium plating bath

Calolume L. Cadmium cyanide bath

Rochelle salt, Copper cyanide

....................................

Udylite bright nickel # 425. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

...............................................
.......................................
Delchem946 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Enthone Stripper. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Watt's nickel.

Zincalume, Cyanide zinc.

.......................................
.............................................

Nuvite Take-off Stripper.

A-29-S Stripper.

Note: Top service temperature for continuous service is 14OoF (6OOC). Exposures to
16OoF (71OC) acceptable for not more than 20 minutes.

recommended t o 71OC. Contact Sternson Limited f o r


h i g h e r t e m p e r a t u r e recommendations.

u s e Talychem C

32
30%
50%

* NR D

highest temperature t e s t e d .
further tests.

May be r e v i s e d w i t h

s p e c i f i c chemical t e s t e d .
may d i s c o l o u r s u r f a c e , w i l l n o t l o s e p r o p e r t i e s .
c o n t a c t S t e r n s o n Limited f o r recommendation.
n o t recommended.

380

Corrosion Resistant Materials Handbook

TAB LE 3.4: EPOXY SUR FACl NG CEMENTS-STE R NSON Iconttnued)

Calcium s u l p h a t e
Carbon Dioxide
Carbon d i s u l p h i d e
Carbon monoxjde
Carbon T e t r a c h l o r i d e
C a u s t i c ( S e e Sodiun, Hydroxide)
C h 1o r i n a t e d 1i m e
Chlorine (Dry)
C h l o r i n e (Wet) 5000 ppm
C h l o r i n e Water
C h l o r o a c e t i c a c i d , 100%
('hloroacetic.
10%
Chloroform
Chloronaphthalin
C h l o r o n i t r o b e n z ene
Chronic a c i d , below 5%
Chrorric a c i d , 5%
Chromic a c i d , 5 t o 10%
C i t r i c Acid, below 5%
C i t r i c Acid, 5-402
Coolant b r i n e s
Copper a c e t a t e , s a t u r a t e d
Copper c h l o r i d e , n i t r a t e o r
sulphate
C o t t a g e Cheese
Cottonseed O i l
Cresols
Crude O i l
Cyclohexane
Cyclohexanone
D i c h l o r o e t hylene
Diegel Fuel
D i e t h y l e n e Glycol
Diethylenetriamine
Dimet hylaminoethanol
Dimethyl Formamide
Dinitro-benzene
Diphenyl o r d i p h e n y l o x i d e
Ether
Ethyl Acetate
E t h y l Alcohol
Ethylamine, 40% aqueous s o l .
Ethyl chloride
Ethylene d i c h l o r i d e
Ethylene g l y c o l
Fatty acids
F e r r i c c h l o r i d e , below 50%
F e r r i c c h l o r i d e , anhydrous
Ferric n i t r a t e o r sulphate
F l u o r i n e up t o approx. 50%

RD
R
32
R
32
R
R
R

R
NR
32
R
32
32
R

R
32

R
R
32
R
R

R
R
NR
R

*
R

R
R

R
R
32
R
R
R

R
32
NR
NR
RD
32
R
R
R

NR

F l u o s i l i c i c Acid, 30%
Formaldehyde, below 37%
Formic a c i d , 90%
Fumaric a c i d , any
Furfural
Furfuryl alcohol
Gallic acid
Gasoline
Glycerine
Glycol
Glycol a c e t a t e
G l y c o l i c Acid
Heptanoic Acid, any
Hex ac h 1o r oc yc 1opent a d i ene
Household ammonia ( S e e Ammonium
hydroxide)
Hydrobromic a c i d , any
Hydrochloric a c i d , below 10%
Hydrochloric a c i d , 1 0 t o 32%
Hydrofluoboric a c i d
H y d r o f l u o r i c a c i d , below 10%
H y d r o f l u o r i c a c i d , 10 t o 20%
H y d r o f l u o r i c a c i d , 20 t o 70%
Hydrogen p e r o x i d e , 50%
Hydrogen sulphid'e
Hydroquinone
H y d r o s i l i co f l u o r i c a c i d
Hypochlorous a c i d
Iron sulphate, saturated
J e t Fuel
Kerosene
L a c t i c Acid, below 20%
L a c t i c Acid, 20 t o 85%
Lard
Lead A c e t a t e , 25%
Lead C h l o r i d e , s a t u r a t e d
Magnesium b i s u l p h i t e
Magnesium c h l o r i d e , s a t u r a t e d
Magnesium s u l p h a t e , s a t u r a t e d
Maleic a c i d , below 40%
Maleic a c i d , 40%
Maleic a n h y d r i d e
Mercuric c h l o r i d e , s a t u r a t e d
Mercury
Methanol
Methyl a c e t a t e
Methyl a l c o h o l
Methyl amine, 40%
Methyl "Cellosolve"
Methyl c h l o r i d e

RC
R
NF
32
R
32
R

R
32
32
NR

NR

RD
R
RD
RC
RC
RC
32C
RD
R
R
32C

R
R
R
RD
RD
R
RD
RD
R
RD
RD
RD
32D
R

NR
R
4

32
R
R
R

NR

(continued)

Cements, Mortars, and Asphalt

TABLE 3.4: EPOXY SURFACING CEMENTS-STERNSON

Methylcyclohexanol
Methyl e t h y l k e t o n e
Methyl n a p h t h a l e n e
Methylene c h l o r i d e
Milk
Milk o f l i m e
Mineral O i l
Miscible O i l
Molybdic Acid, s a t u r a t e d
Monochlorobenzene
Motor O i l (see Crude O i l )
M u r i a t i c a c i d (see Hydrochloric
Acid)
Naphthalin
Nickel C h l o r i d e , n i t r a t e o r
sulphate
N i t r i c a c i d , below 2 1/2%
N i t r i c a c i d , 2 1/2 t o 5%
N i t r i c a c i d , 70% ( c o n e . )
N i t r i c oxide gases
Nitrobenzene
Nitrosylsulphuric, acid
N i t r opropzne
O i l s ( saponifiable )
O l e i c a c i d , any
Oleum
Oxalic a c i d , any
Oxygen
Paradimethyl-amino-benzophenone
Paraffin
P e r c h l o r i c a c i d , any
Perchloroethylene
P e l a r g o n i c a c i d , any
Petroleum
Phenol, below 5%
Phosgene
Phosphoric a c i d , below 2%
Phosphoric a c i d , 2 t o 5%
Phosphoric a c i d , 5 t o 50%
Phosphoric a c i d , 50 t o 85%
Phosphorus c h l o r i d e s
P h t h a l i c anhydride
P i c r i c a c i d , 50%
P i c r i c a c i d , 5%
Potassium bromide, s a t u r a t e d
Potassium c a r b o n a t e , s a t u r a t e d
Potassium c h l o r a t e , 50%
Potassium c h l o r i d e , n i t r a t e o r
sulphate
Potassium cyanide , s a t u r a t e d
Potassium f e r r i c y a n i d e , s a t u r a t e d

*
R

NR
R
R
R
R

RD
32

R
RD
R
R
NR

m
*
NR
32
R
R
NR
R

K
32
R

*
R
R
R

21*
32
RD
RC

RC
RC
R

32
R
R
32

R
R
R

381

(continued)

Potassium hydroxide, below 25%


R
Potassium hydroxide, 25 t o 50%
R
Potassium n i t r a t e , s a t u r a t e d
R
Potassium permanganate, below 5%
RD
Potassium p e r o x i d e , 5%
R
Potassium p e r s u l p h a t e , s a t u r a t e d
R
Potassium s u l p h a t e , s a t u r a t e d
R
Pot as s i um s u l p h i de
R
R
Prussic acid
Pyridine
32
Quinoline s u l p h a t e
R
Red O i l
*
Rochelle S a l t , 25%
R
Saccharin s o l u t i o n s
R
Salicylic acid
32
Salt, saturated solution
R
Sodium a c e t a t e , s a t u r a t e d
R
Sodium bichromate
*D
Sodium c h l o r i d e , c a r b o n a t e , b i c a r b o n a t e , phosphate, n i t r a t e , s u l p h a t e ,
sulphide o r chlorate
R
Sodium hydroxide, below 25%
R
Sodium hydroxide, 25 t o 50%.
R
Sodium H y p o c h l o r i t e , 50 ppm C12
R
Sodium H y p o c h l o r i t e , 5000 ppm C12
R
Sodium H y p o c h l o r i t e , below 6% C12
R
Sodium H y p o c h l o r i t e , 27%
32D
Sodium H y p o c h l o r i t e , 16%
32D
Sodium p e r o x i d e , 5%
32
Stannic chloride
32
Steam
R
S t e a r i c a c i d , any
R
Sugar, s a t u r a t e d s o l u t i o n
R
Sulphur c h l o r i d e
NR
Sulphur d i o x i d e
R
S u l p h u r i c a c i d , below 10%
R
S u l p h u r i c a c i d , 10 t o 20%
R
S u l p h u r i c a c i d , 20 t o 40%
RD
S u l p h u r i c a c i d , 40 t o 50%
RD
S u l p h u r i c a c i d , 50 t o 60%
RD
S u l p h u r i c a c i d , 60 t o 70%
RD
Sulphurous a c i d , below 1 0 %
RD
Sulphur monochloride
32
Sulfuryl chloride
32
Tannin
R
Tar, tar o i l s
32
Tartaric acid, cold saturated
R
Tetrachloroethane
NR
Tetrachloromethane
NR
Tet rahy d r o f u r an
32

(continued)

nuosllicic acid
Acetic acid glacial
Alum
Alurmnum Sulfate
Ammomum Hydroxide
- Ammal
~ _ _olls
_ _ _ _
Bakely Roducls
.- _
~
_
Beer
Benzoic acid
_ Bonc
_ acid
_ _ _ ~
Butter
Butync acid
_
______
Calcium Chlonde
~

~~~

Formaldehyde
Formc acid

Horse R a b h
_

~~

Jams % Jellies

Calcium Hydronde

p_

______

____-

Cheese all
chloGGWatZp
~
~
_
Chloroacetic acid 10%
. -~
__.____Cider
.~_ _ _
____
acid
Maleic acid
_ _Cilnc_____
___
Fmts
. Citrus
Coffee
_______~ _ _ _ _ _
Corn Syrup
Methyl Alcohol
.~ _ _ _
_
~
Yolk
_ ~ ~ _ _ _
- Egg
- _______Ethyl Alcohol
.
.__.__
__
Ethylene Glycol
Mmeral 011
_

c n
s o l u m Hypochlonte up to 3%

___-_

S o l u m Nitrate

S o l u m Sulfite

~S o l u m mosulfate

._________

Soft Dnnks _ _ _ _
__
Soft Dnnk Concentrates
soups
~_Soya
_ _ _ 011
__~~_
Steanc acid
- _ ~ _ _ ~ _ _ _
Sugar ~
_
_
- - - Sulfunc acid up_lo 50% ~ - sulfunc acid 80%
__-___
_ _ _ Sulfunc acid 93%

___

. _ _ _

~~

S~P----T a M i C acid
___
Tartanc acid

_Tea
_

-~

___

________

_____
Tnchloroethylene
_
____
-~~

__
~
_ _ _ ~

_S_o_l u_m_Sulfate
__

_______

Mmeral Spints
id
- Munatic a c ~
_ _
Molasses
Mustard
_ ~ _ _ _ _
Nitnc acid
Oleic acid
1
1
Olive 0
TxzCacid
Pectin
Phenol
_
_________
-_
Phosphoric Acid
~
_
_
_
Plckels
-~~
PIcnc acid
~ _ _ _ _ _ _ _ _
_ Potassium
_ ~ _ Bicarbonate
_ _
_
_
_
~
Potassium Carbonate
_
_ ~-_
_
Potassium Hydronde up lo 30%
~
_ ___ _ ______
Potavlum Hydronde 33% and over
_ Salad Oils
~
Sahcylic acid
Shortemng
_______
~Silver Nitrate
~
_
_
_ Smokehouse
_ _ _ _ _ Resicues
__.-- _~
Sodium Bicarbonate
S o l u m Carbonate
%&um Chlonde
-___
__
___
S o l u m Hydroxide up to 20%
~
_
Sodlum Hydronde 30%and over
p~

._______-

-~

c n

C H

C H

Tnsolum Phosphate
-~~_~~

~_ Tung Oil_

~~

urea

UMe
_______-Vinegar
~ _ _
Yeast

Solution

14 Days

90 Days

355 Days

Appearance Change

Concentrated Ammonium Hydroxide


10% Ammonium Hydroxide
10% Sulphuric Acid
Concentrated Nitric Acid
10% Nitric Acid
Concentrated Hydrochloric Acid
10% Hydrochloric Acid
2 5 % Aqueous Calcium Chloride
Distilled Water
Brake Fluid
Gasoline
Toluene
Methyl Alcohol
Motor Oil

None
None
None
None
None
None
None
None
None
0.1%
None
<0.1%
0.5%
0.4%

1.1%
0.5%
0.2%
1.8%
0.6%
0.7%
1.1%
0.4%
0.5%
0.6%
0.4%
1.1%
0.5%
0.7%

Very Slightly Darker


Very Slightly Darker
Very Slightly Darker
Slightly Yellow
None
Slightly Darker
None
Very Slightly Darker
None
None
None
Slightly Darker
None
Very Slightly Darker

3%
None

0.2%
<0.1?6

0.4%
0.5%
0.5%
<0.1%
0.396
0.2%
0.7%

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Cements, Mortars, and Asphalt

387

TABLE 3.9: URETHANE ASPHALT MEMBRANE-PENNWALT


PENNGUARD Adhesive/Membrane is a twocomponent urethane asphalt composition used in the installation of the
PENNGUARD Block Lining System. As an adhesive, it serves t o bond the PENNGUARD Block to a prepared substrate, and as a membrane, it serves as a moisture and chemical-resistant barrier. TUFCHEM I 1 Membrane i s an improved, two component, urethane asphalt based membrane system, that can be used, within i t s limitations, to protect concrete and steel surfaces from chemical attack and abrasion.

CHFlUlTCAL RESISTAWE OF
URFTHANE ASPYALT MEXBFA!!S

PENNCSWIB Adhesivefidrane
TUFCE3B I1 Membrane

Xey:

NR
C

- Resistant
N o t Resistant
- Conditional
-

A c e t i c Acid 25%

chromic Acid 35%


Citric Acid 35%
Hydrochloric Acid 35%
N i t r i c Acid 35%
O l e i c Acid
Phosphoric Acid 35%
S u l f u r i c Acid 35%
Acetone
Benzene
Carbon Tetrachloride
Ethyl A c e t a t e
Ethylene Glycol
bkthyl Chloride
Methanol
Prapanol
Toluene
Xylene
Water

NR
R

NR
NR
NR
R

NR
NR
NR
NR

Aluminum Hydroxide
Calcium Hydroxide, sat.
sodium Hydroxide 35%
Aluminum Chloride 35%
Calcium Chloride 35%
Calcium Sulfate, sat.
Magnesium Chloride 35%
Potassium Chr-te
35%
sodium CarbOMtE 35%
Sodium Chloride, sat.
Sodium Phosphate, sat.
Sodium Sulfate, sat.
B r ~ ~ ~ n i Nitrate
urn

m
R

m
R
R

NR
NR
R

Chemical r e s i s t a n c e was determined by imnersion in a solution


of the listed chemicals for one year at 132% (55.5oC).

m
R

R
C
R
R
R
R

R
R
R
R
R

388

Corrosion Resistant Materials Handbook

TABLE 3.10: POLYESTER AND EPOXY FLOORING COMPOUNDS-ATLAS


The REZKLAD epoxy-based system consists of a Concrete Primer and Flooring Compound, plus an Expansion
Joint Compound and Surface Sealer available for use where necessary. The CLADKOTE Flooring Compound i s a
modified polyester, resin-based monolithic overlay for concrete. The composite of resins and siliceous reinforcing
material cures t o a tough, chemical resistant topping. CLADKOTE C utilizes a 100% carbon filler specifically designed for service in hydrofluoric acid and fluoride salts.

CHEMICAL RESISTANCE OF

Rezklad*"FLOORING MATERIALS

.Clrdkob C Rcomnnnded

KHV
C 80F.

0 RECOMMENDED

Up to the temperature limilation of the material. In cafes


where chemical boils below
this limitation. resistance is
intended to be shown up to
the boiling point.

CONDITIONAL. may
b. suitable but conSult A t l a s b e f o r e
using.

I!&MMENDED

Cements, Mortars, and Asphalt

TABLE 3.11: VARIOUS CEMENTS-ATLAS

Corrosion Resistance of Various Cements

389

390

Corrosion Resistant Materials Handbook

TABLE 3.11: VARIOUS CEMENTS-ATLAS

(continued)

H = Recommended.

fl= Conditional, may be suitable.


0= Not recommended.
3 = Carbon-filled variation must be used.
= Possible failure through crystalline growth

Sodium Hypochlorite, up to

3%

Sodium Hypochlorite, 15% and over

H = Up to the temperature limitation of the


cement. In cases where chemical boils
below this limitation, resistance is
intended t o be shown up to the boiling
point.

Cements, Mortars, and Asphalt

391

TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING

CORROSION-PROOF MORTARS

PERMANITE" Resin Mortar:

RESIBOND HF Mortar:

An all-purpose furan resin mortar. Satisfactory for


non-oxidizing acids, alkalies, and organic solvents.
Available in quick setting or slow setting type to suit
the installation.

A selected polyester resin mortar with excellent


adhesion to ceramics and metals. Satisfactory for
dilute acids including those that contain fluorides,
mild alkalies and many organic solvents.

AClDSlL Mortar:

CORESITE Mortar:

An improved sodium silicate type mortar with


greater water resistance and higher physical strength.
Resistant to crystallization cracking, and vitrification
to 1900F.

An especially compounded hydraulic type mortar.


Resistant to chemical attack by acids, alkalies, salt
solutions, and organic solvents. Not recommended for
handling strong acids or concentrated alkalies.

AClDSll K Mortar:

EPllOC Mortar:

An improved potassium silicate type mortar with


greater water resistance and higher physical strength.
Resistant to crystallization cracking and vitrification
to 1900F.

A selected epoxy mortar with excellent adhesion to


metal surfaces. Resistant to many nonoxidizing acids,
alkalies, salts, and organic solvents.

AClDSll HK Mortar:

KNIGHTBOND C e m e n t :

An alumina calcine mortar with great water


resistance a n d bearing strength. Resistant to
crystallization cracking, and vitrification to 2700F.

A plasticized sulfur cement. Satisfactory for all


acids and many solvents. Set immediately upon cooling. Available with either silica or carbon filler.

RESIBOND Mortar:

KABO:

A selected polyester resin mortar with excellent


adhesion to ceramics and metals. Satisfactory for
dilute acids, alkalies, and oxidizing agents. Recommended for chlorine, chrome chlorine, dioxide and
peroxide.

An improved phenolic resin mortar. Resistant to


non-oxidizing acids, weak alkalies, and most organic
solvents. Supplied with either silica or carbon filler.

CH EMlCA L RESISTANCE
ACID
PH

NEUTRAL

ALKALI
8

1(1

11

12

13

14

CCRMANITE RESIN MORTAR

ACIDSIL MORTAR
~

KABO RESIN MORTAR

(continued)

Cements, Mortars, and Asphalt

393

TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (contlnud)


Chemical Resistance of AClDSlL and AClDSlL HK Mortars
(Meets ASTM specification 267 f o r chemical-resistant mortar)
Acetaldehyde . . . . . . . . . . . .
R
R
Acetic Acid . . . . . . . . . . . . . . .
Acetic Anhydride . . . . . . . . .
R
..............
R
Acetone
R
Alcohol, Amyl . . . . . . . . . . . . . . . . .
R
Alcohol, Butyl . . . . . . . . . . . . . . . .
R
. . . . . . . .
Alcohol, Ethyl
Alcohol. Iso-Propyl . . . . .
R
Alcohol. Methyl . . . . . . . . . . . . . . .
R
R
Allyl Chloride . . . . . . . . . . . . . . . . .
Aluminum Bromide ..............
R
R
Aluminum Chloride ...............
Aluminum Fluoride ............... NR
R
Alulnlnum Sulfate ..................
Amnionla . . . . . . . . . . . . . . . . . . . . . . .
NR
Ammonium Bicarbonate .......
R
R
Ammonium Bromide .............
R
Ammonium Carbonate .........
Ammonium Chloride .............
R
Ammonium Fluoride .............. N R
Ammonium N i t r a t e ................
R
Ammonium Phosphate ..........
R
Ammonium Sulphate ..............
R
Amy1 Acetate ......................
R
Amyl Chloride ........................
R
Aniline
...............................
**
Antimony Oxychloride . . . . . . . .
R
Antimony Trichloride ...........
R
Aqua Regia ............................
R
Arsenic Acid ............................
R
Barium Carbonate ..................
R
Barium Chloride ......................
R
Barium Hydroxide ..................
**
Benzaldehyde ............................
R
Benzene .....................................
R
...........................
Benzoic Acid
R
Bismuth Carbonate ................
R
Boric Acid ................................
R
Bromine ....................................
R
Butyl Acetate ........................
R
Butyric Acid ............................
R
Calcium Chlorate ....................
R
Calcium Chloride ....................
R
Calcium Hydroxide ................ N R
Calcium H)-pochlorite ............ N R
Calcium N i t r a t e ......................
R
Calcium Sulfate ...._............
R
Carbon Bisulphide .............
R
Carbon Tetrachloride ............
R
Carbonic Acid ..........................
R
Chloracetic Acid ...........
R
Chloral .............................
R
Chlorine ...........................
R
............. R
Chlorine Dioxide ._....
Chlorobenzene ..........................
R
Chloroform ................................
R
Chlorosulfonic Acid ................
R
Chromic Acid ..........................
R
Chromic Chloride . ..............
R
Citric Acid ..._........._
..__.............. R
Copper Acetate ........................
R
Copper Chloride ......................
R
Copper Cyanide ......................
R
Copper N i t r a t e _...___
.................
R
Copper Sulfate ..............:_._
......
R
Creosote _.....__._
....__._......
..... ..... R
R
Cresylic Acid ............................
Dibutyl P h t h a l a t e ..................
R
E t h e r ..........................................
R
Ethyl Acetate ........................
R
~

__

R - Resistant.

Ethyl Bromide
R
Ethyl Chloride
R
Ethylene Chlorhgdrin . . .
R
Ethylene Dichloride . . . . .
R
Ethylene Glycol . . . . . . . . .
R
Ethylene Oxide . . . . . . . . . . . . . . .
R
F a t t y Acids . . . . . . . . . . .
R
Ferric Chloride . . . . . . . . .
R
Ferric Nitrate . . . . . . . . . . . . . . .
R
.........
R
Ferric Sulfate
Ferrous Chloride . . . . . . . . . . .
R
Ferrous Sulfate . . . . . . . . . .
R
Fluorine . . . . . . . . . . . .
NR
.*
Fluosilicic Acid . . . . . . . . . . . . . .
Formaldehyde . . . . . . . . . . . . . . .
R
Formic Acid . . . . . . . . . . . . . . . . .
R
Furfural . . . . . . . . . . . . . . . . . . . . .
R
Gasoline . . . . . . . . . . . . . . . . . .
R
Glycerine . . . . . . . . . . . . . . . .
R
Hydriodic Acid . . . . . . . . . . . . .
R
Hydrobromic . . . . . . . . . . . . . . . . .
R
Hydrochloric Acid . . . . . . . . . . .
R
Hydrocyanic Acid . . . . . . . . .
R
Hydrofluoric Acld . . . . . . . . . N R
Hydrogen Peroxide . . . . . . . .
R
Hvdrogen Sulphide
R
. . . .
Hypochlorous Acid . . . . .
R
Iodine ..............................
R
Lactic Acid ......................
R
Lead Acetate . . . . . . . . . . . . . . . . . .
R
Lead Chloride ..........................
R
Lead Nitrate ..........................
R
Linseed 011 ..............................
R
Magnesium Carbonate ...........
R
Magnesium Chloride .............
R
........
Magnesium Hydroxide
**
Magnesium Nitrate ................
R
Magnesium Sulfate ...............
R
Maleic Acid ...........................
R
Manganese Chloride ..............
R
Manganese Sulfate ................
R
Mercuric Chloride ....................
R
Mercuric Cyanide ....................
R
Mercurous Nitrate ..................
R
Mercury ...................................
R
Methyl Acetate ........................
R
Methyl Chloride ......................
R
Methyl Ethyl Ketone ............
R
Methylene Chloride ................
R
Mineral Oil ..............................
R
Mixed Acids ............................
R
Naphtha ......................................
R
Naphthalene ............................
R
Naphthenic Acid ....................
R
Nickel Chloride ........................
R
Nickel N i t r a t e ........................
R
Nickel Sulfate ........................
R
Nitric Acid ................................
R
Nitrobenzene ......................
R
Nitroglycerine ..........................
R
Nitrophenol ..............................
R
Nitrous Acid ............................
R
Nitrosyl Chloride .......__........._. R
Oleic Acid ..................................
R
Oxalic Acid ..............._.....
.........
R
P a r a m n ......................................
R
Perchloric Acid ........................
R
Phenol ...............................
............
R
Phosgene ..................................
**
Phosphoric Acid ( t o 70% ) ....
R

NR - Not Resistant

Phosphoric Acid (above TO',: )


Phosphorous Bromide
Phosphorous Chloride .
.
Phosphol,ous Oxlchloride
Phthalic Anhydride
..
Picric Acid
Potassium Bicarbonate
Potassium Bromide
Potassium Carbonate
Potassium Chloi.ate
Potassium Chloride . . . . .
potassium Cyanide
poiassiuni Fei rocyanide
Potassium Dichromate
Potassium Fluoride
Potassium Hydroxide . . .
Potassium Nitrate
. . . .
potassiuni Oxalate
...
Potassium Permanganate . .
. . . . .
Potassium Peroxide
Potassiuni Sulfate . . . . . . . .
Potassium Sulphide
..
Propylene Dichloride
Pyridine . . . . . . .
Salicylic Acid . . . . . . . . . .
Silver Nitrate . . . . . . . . . .
Sodium Acetate . . . . . . . . . .
Sodium Bicarbonate . . . . . . .
Sodium Bisulfate . . . . . . . . . .
Sodium Bisulphite . . . . . . . . . . .
Sodium Bromide . . . . . . . . . . .
Sodium Carbonate ...............
Sodium Chlorate . . . . . . . . . . . . . .
Sodium Chloride . . . . . . . . . . . .
Sodium Chromate . . . . . . . . . . . . . .
Sodium Cyanide . . . . . . . . . . . . . .
Sodium Dichromate ..............
Sodium Ferricyanide ..............
Sodiuni Fluoride ....................
Sodium Hydroxide ...............
Sodium Hypochlorite ............
Sodium Nitrate ........................
Sodium Nitrite ......................
Sodium Oxalate ...................
Sodium Peroxide ..................
Sodium Sulfate .......................
Sodium Sulphide ................
Sodium Sulphite ...................
Sodium Thiosulfate . . . . . . . . . . .
Steam ...................................
Sulphur ..................................
Sulphur Chloride ...................
Sulphur Dioxide ....................
Sulphur Trioxide ....................
Sulphuric Acid ......................
Oleum ........................................
Sulphurous Acid ....................
Tannic Acid ............................
Tartaric Acid ..........................
Tin Chloride ............................
Tin Sulfate ................................
Toluene ......................................
Trichloracetic Acid ................
Trichloroethylene ....................
Trisodium Phosphate ............
Vegetable Oils ........................
W a t e r ........................................
Xylene ........................................
Zinc Chloride ............................
Zinc Sulfate .............................

"Consult M.A. Knight for specific recommendation.

**
R
R
R
R
R
R
R
NR
R
R

NR
R
R
NR
NR
R
R
R
NR
R
NR
R

**

R
R
R
R
R
R
R
NR
R
R
R
NR
R
R
NR
NR
NR
R
R
R
NR
R
NR

**

R
*
R
R
R
R
R
R
R
R
R
R

R
R
R
NR
R
R
R
R
R

(continued )

394

Corrosion Resistant Materials Handbook

TAB LE 3.12: V A R IO US MOR T A RS-KOCH ENGINEER I N G (continuedJ


Chemical Resistance of RESIBOND Mortar
(Meets ASTM specification 267 for chemical-resistant mortar)

E - Excellenr resisrance, all concentrations and temperarures to 250F


G - Good resisrance. most concentrations and remperatures to 165F
F - Fdir resistance. ddute concentrations and temperatures to 9 0 F
NR - Not recommended for this s e n ice under most conditions
Aceric Acid ( t o 5 0 5 )
E
Hydrofluoric Acid
G
Hydrogen Peroxide ( 3 0 5 )
Aceric Acid (Glacial)
NR
Magnesium Chloride
Ace r on e
E
Magnesium Hydroxide
Aluminum Chloride
E
Methyl Alcohol
A 1um in u r n Su 1fare
E
Methyl
Ethyl Ketone
Ammon i um Car bonare
E
Naphtha ( V M 8( P )
Ammonium Chloride
G
Nickel Chloride
Ammonium Hydroxide ( t o 755 )
r
\
;
~
Nickel
Sulfate
Ammonium Hydroxide (conc )
E
Nitric Acid ( t o 207: )
Ammonium Nitrate
E
Nitric
Acid ( t o 40% )
Ammonium Sulfate
Aniline
Barium Hydroxide
Bcnzene
Benzoic Acid
Boric Acid
Calcium Chloride
Calcium Hydroxide
Calcium Hypochlorite
Carbon Disulfide
Carbon Tetrachloride
Chloroform
Chlorine Dioxlde Bleach
Chlorine Gas
Chlorine Water
Chrome Plating Solution
Citric Acid
Copper Sulfate
Ethyl Acetate
Erhyl Alcohol
Erhyl Ether
Ethylene Dichloride
Ethylene Glycol
Ferric Chloride
Ferric Nitrate
Ferric Sulfare
Formaldehyde ( 37% )
Furfural
Glycerine
Hydrochloric Acid
*Consult M.A. K n i g h t for specific recommendation.

L
L
E
L
NR
G
E

I:
E
G

F
G
F

Nitric Acid (conc )


Oxalic Acid
Perchloric Acid ( 20% )

NR
E
E

E
E

NR
E
p.
E

E
E
F
E

Phenol
Phosphoric Acid
Potassium Chloride
Potassium Cyanide
Potassium Hydroxide (dilute)
Potassium Hydroxide (conc )
Pyridine
Sodium Bicarbonate
Sodium Carbonate
Sodium Chloride
Sodium Hydroxide (dilute)
Sodium Hydroxide (conc )
Sodium Hypochlorite (under 12 p H )
Sodium Hypochlorite (over 12 p H )
Sulfur Dioxide
Sulfuric Acid ( t o 70% )

E
NR
E

Sulfuric Acid (conc )


Sulfurous Acid
Toluene

NR
E
F

E
E
E
E

Trichlorethylene
Triethanolamine
Trisodium Phosphate
Water

NR
E
G
E

NR
E
E

Xylene
Zinc Chloride
Zinc Sulfate

E
E
E
F
G
G
E
G
E
G

NR
F
E

E
E
#

NR
G
NR

E
E

F
E
E
(continued)

Cements, Mortars, and Asphalt

395

TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued)


Chemical Resistance of RESIBOND HF Mortar
(Meets ASTM specification 267 for chemical-resistant mortar)

E - Excellenr resistance, all concentrations and temperatures to 250F.


G - Good resistance, most concentrations and temperatures to 165F
F - Fair resistance, dilute concentrations and temperatures to 9 0 F
N R - Nor recommended for this Service under most conditions
E
Hydrofluoric Acid
Acetic Acid ( to 50% )
G
Hydrogen Peroxide ( 30% )
Acetic Acid (Glacial)
N
R
Magnesium
Chloride
Acetone
E
Magnesium
Hydroxide
Alum in um Chloride
E
Methyl Alcohol
Aluminum Sulfare
Ammonium Carbonate
E
Methyl Ethyl Ketone
E
Naphtha ( V M & P )
Ammonium Chloride
G
Nickel Chloride
Ammonium Hydroxide ( t o 7 % )
NR
Nickel Sulfate
Ammonium Hydroxide (conc )
E
Nitric Acid (to 205%)
Ammonium Nitrate
E
Nitric Acid (to 40% )
Ammonium Sulfate
Aniline
F
Nitric Acid (conc )
G
Oxalic Acid
Barium Hydroxide
F
Perchloric Acid ( 20% )
Benzene
E
Phenol
Benzoic Acid
E
Phosphoric
Acid
Boric Acid
E
Potassium Chloride
Calcium Chloride
E
Potassium Cyanide
Calcium Hydroxide
E
Potassium
Hydroxide (dilute)
Calcium Hypochlorite
F
Potassium Hydroxide (conc.)
Carbon Disulfide
G
Pyridine
Carbon Tetrachloride
G
Sodium
Bicarbonate
Chloroform
E
Sodium Carbonate
Chlorine Dioxide Bleach
G
Sodium Chloride
Chlorine Gas
E
Sodium Hydroxide (dilute)
Chlorine Water
G
Sodium Hydroxide (conc.)
Chrome Plating Solution
E
Sodium Hypochlorite (under 12 pH)
Citric Acid
E
Sodium Hypochlorite (over 12 pH)
Copper Sulfate
F
Sulfur Dioxide
Ethyl Acetate
E
Sulfuric Acid (to 70% )
Ethyl Alcohol
Ethyl Ether
E
Sulfuric Acid (conc.)
NR
Sulfurous Acid
Ethylene Dichloride
E
Toluene
Ethylene Glycol
E
Trichlorethylene
Ferric Chloride
E
Triethanolamine
Ferric Nitrate
E
Trisodium Phosphate
Ferric Sulfate
E
Water
Formaldehyde ( 37% )
NR
Xylene
Furfural
E
Zinc Chloride
Glycerine
E
Zinc Sulfate
Hydrochloric Acid
'Consult M.A. Knight for specific recommendation.

E
E

E
E
E
NR
G
E
E
E
G
NR
E
E
NR
E
E
E
+
NR
F
E
E
E
#

NR
G
NR
E
E
NR
E
F
NR
E
G
E
F
E
E
(continued1

396

Corrosion Resistant Materials Handbook

TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued)


Chemical Resistance of CORESITE Mortar

Acids:
Acetic . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . .*
Arsenic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R
...............................
R
Boric
Carbonic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R
Chloride Dioxide Water . . . . . . . . . . . . . . . . . R
Chromic (Dilute) . . . . . . . . . . . . . . . . . . . . . . . . R
R
Citric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R
Formic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
NR
Hydrochloric.. . . . . . . . . . . . . . . . . . . . . . . . .
Hydrofluoric . . . . . . . . . . . . . . . . . . . . . . . . . .
NR
........... R
Hydrogen Peroxide . . . . . .
Hydrogen Sulfide Water. .
Hypochlorous (C12 water). . . . . . . . . . . . . . . R
R
Lactic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
NR
Nitric. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Oxalic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . *
Phosphoric . . . . . . . . . . . . . . . . . . . . . . . . . . .
NR
NR
Sulfuric.. .............................
Sulfurous (SO2 water) . . . . . . . . . . . . . . . . . . . *
R
Tannic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Tartaric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
R

Alkalies:
Ammonium Hydroxide . . . . . . . . . . . . . . . . . . .*
Calcium Hydroxide .....................
R
Calcium Hypochlorite . . . . . . . . . . . . . . . . . . . R
Magnesium Hydroxide . . . . . . . . . . . . . . . . . . R
Potassium Hydroxide (15%). . . . . . . . . . . . . R
Potassium Hydroxide (Conc.) . . . . . . . . . . . *R
Sodium Hydroxide (15%) . . . . . . . . . . . . . . . . R
Sodium Hydroxide (Conc.) . . . . . . . . . . . . . *R
Sodium Hypochlorite. . . . . . . . . . . . . . . . . . . . R
Sodium Peroxide ........................
R

Salts:
Aluminum Sulfate . . . . . . . . . . . . . . . . . . . . . .
R
Ammonium Chloride. . . . . . . . . . . . . . . . . . . . R
R
Ammonium Nitrate .....................
Ammonium Sulfate .....................
R

Borax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . R
Calcium Bisulfite . .
.................. R
Calcium Chloride . . . . . . . . . .
Calcium Hypochlorite.. . . . .

Potassium Nitrate . . . . . . . . . . .
Sodium Bicarbonate
Sodium Carbonate . . . . . . . . . . . . . . . . . . . . . .
Sodium Chloride . . . . . . . . . . . . . .
Sodium Sulfate . . . . . . . . . . . . . . .
Sodium Sulfide
......................
Sodium Sulfite . . . . . . . . . . . . . . . . . . . . . . . . . .
Trisodium Phosphate . . . . . . . . . . . . . . . . . . .
.............
Zinc Sulfate . . . . . .

R
R
R
R
R

Organic Materials:
Alcohol . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
..........................
m ........................
Ethylene Glycol. . . . . . . . . . . . . . . . . . . . . .
Formaldehyde . . . . . . . . . . . . . . . . . . . . . . . . . .
Gasoline . . . . . . . . . . . . . . . . .
Glucose . . . . . . . . . . . . . . . . . .
.........................
.................
Milk . . . . . . . . . . . . . . . . . . . . .
Mineral Oils . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Molasses . . . . . . . . . . . . . . . . . . . .
Phenol. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Soaps . . . . . . . . . .
....................
Starch . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Sugar Syrup . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Triethanolamine . . . . . . . . . . . . . . . . . . . . . . . . .
Vegetable Oils . . . . . . . . . . . . . . . . . . . . . . . . . .

R
R
R
R
R
R
R
R
R
R

'Consult M.A. Knight for specific recommendation.

R - Resistant
NR - Not Resistant

(continued)

Cements, Mortars, and Asphalt

397

TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued)


Chemical Resistance of KNIGHTBOND No. 6 Mortar
(Meets ASTM specification 267 for chemical-resistant mortar)
CHEMICAL
MAX. CONC.
MAX.TEMP. CHEMICAL
MAX. CONC.
MAX.TEMP.
Yc by w t .
o F.
7 a by wt.
O F .
50
Acetaldehyde . . . . .
70
Hydrocyanic Acid ...............
10
70
Acetic Acid . . . . . .
100
70
**Hydrofluoric Acid .............
Any
200
Acetic Anhydride
NR
Any
Hydrogen Peroxide ............
30
70
Acetone . . . . . . . . . . . . . . . . .
50
70
Hypochlorous Acid . . . . . . . . . . .
NR
70
NR
Any
Alcohol, Amyl . . . . . .
Lactic Acid ........................
25
200
50
70
Alcohol, Ethyl
Lead Acetate ..................
Any
200
50
70
Alcohol. Isopropyl . . . . . .
Magnesium Chloride .........
Any
200
75
70
Magnesium N i t r a t e . . . . . . .
Any
Alcohol. Methyl . . . . .
200
Any
200
**Aluminuni Fluoride . . .
Magnesium Sulphate . . . . . . .
Any
200
Any
200
Mercurir Chloride . . . . . . . . . . .
Any
200
Aluminum Sulphate . . . . . .
NR
70
Mercuric Cyanide . . . .
Any
200
Ammonia
. . . . . . . . . . .
Any
70
Mercurous Nitrate
...
Any
200
Ammonium Cai.bonate . . . .
25
200
MEK . . . . . . . . . . . . . . . . . . . . . . . . .
15
160
Ammonium Chloride . . . . . . .
25
200
Mixed Acids . . . . .
.....
55
70
Ammonium Nitrate . . .
25
200
Naphtha . . . . . . . . . . .
.
NR
70
Ammonium Sulphate . . . . .
Nickel Chloride
....
Any
200
Aniline
. . . . . . . . . .
NR
70
200
Nickel Nitrate
Any
200
Arsenic Acid . . . . . . . . .
Any
.............
200
Nickel
Sulphate
Any
200
Barium Chloride
Any
Nitric Acid . . . . . .
50
70
Barium Hydroxide ............
NR
70
Barium Sulphide ...............
NR
70
Nitric Acid
..
25
160
Benzene .............................
7o
Nitrous Acid
NR
70
NR
. . . .
.................
NR
7o
Oxalic Acid
Any
200
Bi.omine
7o
Perchloric Acid . .
. .
25
70
Butyl Acetate ...................
NR
........................
2oo
Phenol
50
70
Calcium Chlorate _ ............
Any
85
200
200
Phosphoric Acid
Calcium Chloride ..............
Any
Calcium Hydroxide .............
NR
7o
Phthalic Anhydride
Any
200
7o
Potassium Bicarbonate . . .
10
70
Calcium Hypochlorite .......
NR
2oo
Potassium
Bromide
......
Any
200
Any
Calcium Sulphate ..............
Potassium Chlorate . . . . . . .
~ n y
200
Carbonic Acid ......................
5
Potassium
Dichromate
....
Any
200
Carbon Bisulfide . . . . . . . . . .
NR
7o
Potassium
Ferrocyanlde
....
25
70
Carbon Tetrachloride ..........
NR
Potassium Permanganate
Any
200
Chloracetic Acid ..................
Any
70
Potassium Sulphate ..........
Any
200
Chlorine .............................
NR
70
Silver N i t r a t e
............
15
200
Chloroform ......................
NR
70
Sodium Acetate . . . . . . . . . . . .
Any
200
Chromic Acid . . . . . . . . . . . . . . . . .
35
70
Sodium Bisulphate . . . .
Any
200
Chromic Acid . . . . . . . . . . . . . . . .
10
160
Sodium Bisulphite . . . . . . . . .
Any
200
Copper Chloride ...............
Any
.........
2oo
Sodium Carbonate
25
70
Copper Cyanide . . . . . . . .
Any
Zoo
Sodium Chloride . . . . . . . . .
Any
200
Copper N i t r a t e . . . . . . . . . . . .
Any
2oo
Sodium Cyanide . . . . . . . . . . .
25
70

i:2

Copper Sulphate . . . . . . . . . . . .
Cresylic Acid . . . . . . . . . . .
Ether . . . . . . . . . . . . . . . . .
Ethyl Acetate . . . . . . . . . . . . . . . .
Ethylene Dichloride ..........
Ethylene Glycol . . . . . . . . . . . . . . .

NR

Sodium Ferricyanlde . . . . .
25
70
**Sodium Fluoride ..................
Any
200
Sodium Hydroxide . . . . . . . . . . .
NR
70
Sodium Hypochlorite ........
NR
70
Sodium N i t r a t e . . . . . . . . . . . . . . . .
Any
200
Sodium Nitrite ..................
25
70
F a t t y Acids .......................
NR
70
Sodium Sulphite ...............
10
70
Ferric Chloride ...................
Any
200
Sodium Sulphide ..............
NR
70
Ferric N i t r a t e .....................
Any
200
Stannic Chloride .................
Any
130
Ferric Sulphate ................
Any
200
Stannous Chloride . . . . . . . . . .
Any
200
Ferrous Chloride ...............
Any
200
Sulphur Dioxide .................
Any
200
Ferrous Sulphate ..............
Any
200
Sulphur Trioxide ..................
NR
70
70
NR
Fluorine ................................
Sulphuric Acid ....................
85
100
40
200
**Fluosilicic Acid ...................
Sulphuric Acid ..................
60
200
35
150
Sulphurous Acid .................
Formaldehyde .....................
10
70
Formic Acid ..........................
70
100
Trichloroethylene ..............
NR
70
F u r f u r a l .........................
50
70
Trisodium Phosphate . . . . .
10
70
40
200
Zinc Chloride .....................
Any
200
Hydrobromic Acid . . . . . . . . . .
Zinc Sulphate ..... ......~
.......
Any
200
Hydrochloric Acid . . . . . . . . . .
30
200
**Use KNIGHTBOND # 7 Sulphur-Carbon Cement because hydrofluoric acid and fluorides a t t a c k fillers
containing silica.
Not Recommended for this service under most conditions.
NR
(continued)
NR
NR
NR
NR
50

70
70
70
70
140

398

Corrosion Resistant Materials Handbook

TABLE 3.12: VARIOUS MORTARS-KOCH ENGINEERING (continued)


Chemical Resistance of KABO Resin Mortar with Carbon Filler
CHEMICAL
RESISTANCE
E
Acetaldehyde . . . . . . . .
E
Acetic Acid
. . . .
Acetic Anhydride
C
E
Acetone
c
Alcohol. Amyl
E
Alcohol. Ethyl .
.
Alcohol, Is0 PropyJ
E
E
Alcohol. Methyl . . . . .
E
Aluminum Chloride' ...
E
Aluminum Hydroxide
A I uni i num SUIpha t e
E
Ammonia _ _ . .
NR
Ammonium Bicarbonate
F
Ammonium Carbonate ..
F
Ammonium Chloride . . .
E
Ammonium Fluoride
E
E
Ammonium N i t r a t e . . .
Ammonium Sulphate . . . .
E
Amyl Acetate . . . . . . . . . .
F
Aniline . . . .
F
Antimony TrichloriPe
E
Arsenic Acid . . . . . . . . . . . . .
E
B a n u m Chrhonate . . . . . .
E
E
Barium Chloride . . . . . .
F
Barium Hydroxide
E
Barium Sulphide . . . . .
E
Benzaldehyde . . . . . . .
E
Benzene . . . . . . . . . .
Benzenesulfonic Acid
E
Benzoic Acid . . . . . . . . . . . . .
E
Bismuth Carbonate
....
E
Boric Acid ................
E
Bromine .....................
NR
Butyl Acetate . . . . . . . . .
F
Butyric Acid . . . . . . . . . . . . .
G
Calcium Chlorate . . . . .
E
Calcium Chloride _ _
.
E
Calcium Hydroxide ...
NR
Calcium Hypochlorite ......
F
Calcium Sulphate . . . . . . . . . . .
E
....................
Camphor
E
E
Carbonic Acid . . . . . . . . . . . . . .
Carbon Bisulphide ...........
E
Carbon Tetrachloride ......
E
G
Chioracetic chi id ..............
Chlorine ............................
G
E
Chlorobenzene ...................
.....................
Chloroform
E
Chromic Acid . . . . . . . . . . . . .
F
E
Citric Acid . . . . . . . . . . . . . . . . .
Copper Chloride . . . . . . . . . . . .
E
Copper Cyanide ..............
E

CHEMICAL
RESISTANCE
Copper N i t r a t e . . . . . . . . .
E
Copper Sulphate .....
E
E
Creosote .........................
E t h e r ..............................
E
Ethyl Acetate . . . . . . . . . . .
E
Ethyl Chloride ...........
E
Ethylene Chlorhydrin
G
Ethylene Glycol .........
E
F a t t y Acids .................
E
Ferric Chloride ..........
E
E
Ferric N i t r a t e ...............
E
F e m c Sulphate ...........
Ferrous Chloride .........
E
Ferrous Sulphate ........
E
Fluorine .........................
NR
Fluosilicic Acid ............
E
Formaldehyde ...............
E
Formic Acid .................
E
Furfural ........................
F
Hydrochloric Acid .......
E
Hydrofluoric Acid .........
E
Hydrogen Peroxide ....
F
Wydrogen Strlphide
E
Hypochlorous Acid . . . .
G
Iodine .............................
NR
Lactic Acid ................
E
Lead Acetate . . . . .
E
Linseed Oil . .
E
Magnesium Carbonate
E
Magnesium Chloride ...
E
Magnesium Hydroxide
F
Ma@esium Nitrate . .
E
Magnesium Sulphate . .
E
Maleic Acid
G
Mercuric Chloride
E
Mercuric Cyanide . .
E
Mercurous N i t r a t e
E
Methyl Chloride
E
MEK . . . . . . . . . . . . . . . . . . . . .
E
Mixed Acids . . . . . . . . . . NR
Naphtha . . . . . . . .
. . . . .
Naphthalene
E
Nickel Chloride
E
Nickel N i t r a t e .
.
Nicke] Sulohate . . .
E
F
Nitric Acid ( D i l u t e )
Nitric Acid (Conc.) .
NR
. .
E
Nitrobenzene
NR
Nitrous Acid
NR
Nitrosyl Chloride
Oleic Acid . . . . . . . .
E
Oxalic Acid ..
E

CHEMICAL
RESISTANCE
Perchloric Acid . . . . .
. . .
F
Phenol . . . . . . . .
. . . . .
G
Phosphoric Acid
E
. . . . . . . . . .
Phthalic Anhydride . . .
E
Picric Acid - Alcoholic . . . . .
E
Potassium Bromide . . . . . . . . . .
E
Potassium Carbonate (Dilute) .
C
Potassium Carbonate tconc.) .
F
Potassium Chlorate . . . . . . . . . .
E
Potassium Dichromate .
.
.
E
Potassium Ferrocyanide
E
Potassium Hydroxide ..............
NR
Potassium Permanganate
....
c
Silver N i t r a t e
.............
E
Sodium Acetate . . . . . . . . .
E
Sodium Bicarbonate . . . . . . . . .
E
Sodium Bisulphate . . . . . . . . . . .
E
Sodium Bisulphite . . . . . . . . . . . . . . .
E
Sodium Carbonate (Dilute) ......
G
Sodium Carbonate (Conc.) . . . . .
F
Sodium Chloride . . . . . . . . . . . . . . . .
E
Sodium Cyanide . . . . . . . . . . . .
E
Sodium Ferricyanide . . . . . . . .
E
Sodium Fluoride . . . . . . . . . . . . . . .
E
Sodium Hydroxide
. . . . . . . . .
NR
Sodium Hypochlorite . . . . . . . . .
NR
S o d i u m N i t r a t e .........................
E
S o d i u m N i t r i t e .......................
E
Sodium Sulphate
..................
E
Sodium Sulphite . . . . . . . . . . . . . . . . . .
E
Sodium Sulphide .......................
NR
Sulphur ..............................
F.
Sulphur Chloride .......................
NR
Sulphur Dioxide ...........................
E
Sulphur Trioxide .........................
NR
Sulphuric Acid ( t o 6 0 % ) ...........
E
Sulphuric Acid ( 6 0 - 8 5 g ) ........_
G
Sulphuric Acid (Conc.) ...............
F
Oleum ............................................
NR
Sulphurous Acid ...........................
E
Tannic Acid ...................................
E
T a r t a r i c Acid ..............................
E
Tin Chloride ..............................
E
Toluene ..........................................
E
Trichloroethylene .........................
C
Trisodium Phosphate (Dilute)
C
Trisodium Phosphate tConc.) ...
F
Zinc Chloride .............................
E
Zinc Sulphate ..............................

E - h t c e l l e n t resistance; ~ u i t a b l efor general serviceall concentrations and temperatures.

F - Fair resistance; suitable for some senrIces-dilute


concentrations and temperatures t o 90" F .
G - Good resistance; suitable for most s e r v i c e k m o s t
concentrations and temperatures to 212' F.

NR-Not
recommended
conditions.

for this service under most

KEY

a
0
a
a
0

Resistant

TYPE
MORTAR

Not Recommended
Limited Resistance
Conairional Test
Required
Not Testeo

RESIN"
SILICA & SILICATE

PENNWALT
NAME

FURAN

-0

rn

" p

v)
~

MODIFIED
PHENOLlC PHENOLIC

e z ~ p
n>
z

v,

ncnno

v)

T)

-g

u30T,ul=1,

?a:=
D

ID
r

ZD

-06

(? ? ?
?
!

r
--1

r
a'

o
<

o
z

m=

c_@
e3

m e
-0

e=
2

a i 5
Cl

SULFUR

F
=.
c

o
2

g
3

p
5

KEY

TYPE
MORTAR

0 Ressiant

0 Not Recommended

fl Conamonal

Llmltea Reststance
Requlred
NOI Tesieo

Test

PENNWALT
NAME

SILICA 8 SILICATE

r
O

0
0

6 ?
4

RESIN
MoDFED PHENOLIC

FURAN

(n-nc7T-n

v)

gngz .2a>z

- $5 n 6
? 52
2

SULFUR

PHENOLIC

D
D W D O p
g gEg; =
c
: =%w-3 6 2 5

r
!

<

s
a

2
s
a

E;

Cements, Mortars, and Asphalt

40 1

TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued)

L!miled Reslsiance

a Conaitional.
Test
Required

Not Tested

(continued )

402

Corrosion Resistant Materials Handbook

TABLE 3.13: VARIOUS MORTARS- PENNWALT

a Not Recommended

Llfnited Resisrance

Conditional Test
Required

(contrnued)

Cements, Mortars, and Asphalt

403

TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued)

0 Not Recornmended
Limited Resistance

a Conditional.
Test
Required

(continued)

404

Corrosion Resistant Materials Handbook

TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued)


KEY

TYPE

RES'N"
SILICA 8 SILICATE

Llmited Resistance
Conditional Test
Required

Zmc Chloride Nllrale Sulfate

(continued)

Cements, Mortars, and Asphalt

405

TABLE 3.13: VARIOUS MORTARS- PENNWALT (continued)

Same cheqical resigtance with reduced physical strength


above 750 F. (399 C)
SeeTable 3.3 for epoxy mortars
* * * Pennwalt K 1 4 8 Mortar has similar chemical resistances
to CORLOK@ B Mortar and HB@ Mortar with some
exceptions. Check with your Pennwalt representative for
specific chemical resistances.
t PENCHLOR@andCORLOK 6 Mortars should be tested
for resistance in 1% range. All Mortars resistant in 10%
and 25% range.
@ Resistant up to 40% at 16OoF (71OC). Test higher
concentrations and temperatures.
S Up to 2% concentration.
Q Limited resistance a t 48% concentration.
Resistant t o 100F (38OC). Test for higher temperatures.
A Strong oxidizers must not be added because elemental
bromine would be freed that would make the rating of all
resin mortars Not Resistant.
Polyester Mortar probably resistant to boiling point in
all three concentrations. Epoxy toppings may be considered up t o 10% but verify by test.
H.E.S.@and HB@ Mortars will resist some concentrations.
See Addenda.
# Attack is slow a t 1% or less.
Resistant to 20% at 100cF. (38OC)
c

+
+

++

& Resistant intermittent t o 1OO:F. (38zC)


0 Resistant ittermitt,nt t o 160 F. (71 C)
;= Up t o 302 F. ( 1 50-C)

ADDENDA
H.E.S. and HB Mortars differ from other siliceous, silicate, or silica mortars in resisting exposures between pH 0.0
and pH 8.0 with the exception of acid fluorides and HF acid. In addition, they can be used in glycol acetate,
potassium sulfate or persulfate, sodium sulfide and trisodium phosphate, all of which will damage other siliceous
mortars.
"Use this reference information as a guide only. The information given in the resistance chart is believed t o be
reliable, but no guarantee i s made nor can we assume liability in connection with their use. Please contact the
Corrosion Engineering Department for specific recommendations."

406

Corrosion Resistant Materials Handbook

TABLE 3.14: VARIOUS MORTARS-STERNSON


IN 0 BOND C is a high-purity quartz colloidal silicate mortar for use with all sizes of acid brick and i s especially
suited for stack or chimney linings as in sewage treatment operations and other, and as a mortar for process linings.
IN 0 BOND P is a potassium silicate based inorganic brick mortar formulated for use with all sizes of acid brick and
i s especially suited for chimney, stack or vessel linings where an easy t o use mortar will facilitate quick installation.
IN 0 BOND S is a sodium silicate based mortar designed for use with all sizes of acid brick.

FURABOND and FURASET are furan based cements that resist a wide range of strong corrosive solutions and severe mechanical abuse. They are formulated t o be used with all sizes of acid brick for protection of concrete and
steel surfaces such as trenches, floors, piers, pump bases, supporting foundations, sumps, batching and pickling
tanks, process vessels. They are especially suited for alternating alkali/acid conditions.
STERNCHEM Polyester Mortar is formulated t o provide superior service for acid brick constructions in the chemical process, pulp and paper, plating, textile, fertilizer, and metal refining industries. They are especially suited for
chlorine dioxide towers, bleaching vats, trenches, sumps, pits, bleaching solutions of sodium hypochlorite, oxidizing
solutions of nitric and chromic acids t o 20% concentrations, hydrobromic acid, potassium and sodium dichromates,
bromine water, s a l t solutions t o pH 11.
STERNCHEM Phenolic Mortar is formulated t o provide superior service for acid brick constructions requiring the
chemical resistance of carbon/resinous phenolic systems.

STERNCHEM CHEMICAL RESISTANCE GUIDE

R - Resistant
NR - Not Resistant
U - Untestcd
2'7OC - Maximum Temperature Tested
30% - Resistant To All Concentrations Up To 30%
- In 0 Bond Series Not Recommended For
Frequent Or Continual Concentrations Below 10%
- Talychem Epoxy Mortar - Refer To Talychem
Chemical Resistance Guide (Table 3.4)
EXPOSURE

Acetaldehyde
Acetic Acid, under 10%
Acetic Acid, Glacial
Acetic Anhydride
Acetone
Acetone Oil
Acetyl-Bromide
Acetyl-Chloride
Acetylene-Dichloride
Acetyl Salicylic Acid
Aluminum Bromide
Aluminum Chloride,
Sulphate & Alums

IN 0 BOND SERIES
llO0OC
P - goooc
S - 4OO0C

c-

FURABOND
FURASET
175OC

STERNCHEM SERIES
POLYESTER
PHENOLIC
120%

NR

175OC

R
R
R
NR
3OoC
R
NR
R
R
R
NR

NR
NR
U
NR
NR
U
U

NR
R
R
R
NR
NR
NR
NR
NR
R
NR

R
R

R
R
NR
R
R
R
R

3OoC
NR

(continued)

407

Cements, Mortars, and Asphalt

TABLE 3.14: VARIOUS MORTARS-STERNSON

(continued)

I N 0 BOND SERIES
llO0OC
P
goooc

EXPOSURE

c-

Aluminum
Alum
Rmmonium
Ammonium
Ammonium
Ammonium
Ammonium
Ammonium

Fluoride

Bromide
Carbonate
Chloride , Sulphate
Fluoride
Hydroxide
Nitrate
(Neutral S o l u t i o n s )
Ammonium P e r s u l p h a t e
Ammonium Phosphates
Ammonium Sulphide
Ammonium Tungstate
Amyl Acetate , Alcohol
Aniline
Aniline Hydrochloride
Antimony Chloride
Ant imo ny Oxych l o r i de
Antimony Potassium T a r t r a t e
Aqua Regia
Arsenic Compounds,
Neutral o r Acid
B a r i u m Chloride
B a r i u m Hydroxi de
Barium N i t r a t e
Barium Sulphide
Benzaldehyde - Neutral o r Acid
Benzene (Bensol )
Benzene Sulphonic A c i d ,
( o r Chloride)
Benzoic Acid
Benzyl Acetate
Benzyl Alcohol
Benzyl Chloride
Boric Acid
Bromine
Bromine Water, S a t u r a t e d
Butanol
Butyl Acetate
Butyl C a r b i t o l
Butyric Acid
Cadmium Chloride
Cadmium N i t r a t e
Calcium Chloride
Calcium Hydroxide
Calcium Hypochlorite
Calcium N i t r a t e ( N e u t r a l S o l u t i o n s )
Calcium Sulphate
Carbon Bisulphide

4OO0C

FURABOND
FURASET
175OC

NR
R
R
R
R
NR
NR

R
R
NR
R
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
R

NR
R

NR
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

NR
R
R
R
R

STERNCHEM SERIES
POLYESTER
PHENOLIC
12oOc

175OC

R
U
R
R
U
35OC

NR
R
NR
R
R
R
NR

R
R
R
R
R
R

R
U
U
R
U

R
R
U
R
U

NR

NR

R
R
R
R
NR

NR

NR
NR
R
R
R
NR

R
R
R
R
R
R
R

R
U
U

NR
U
R
R
R
3OoC

NR
NR

R
R
R
R
NR
NR
NR

R
R

U
R

NR
NR

U
U

U
NR

NR

R
R

R
R

NR
NR
R
R
R
R
R
R
R
R
R
R
R
R

NR

R
R

NR

3OoC

U
NR
U

NR
NR
NR

3OoC
R
70C
R
3OoC
R
R
R
R

R
R
R
R
NR
U
R
R
R
(continued)

408

Corrosion Resistant Materials Handbook

TAB LE 3.14: VAR 10US MORTAR S-STE R NSON (continued)

EXPOSURE

I N 0 BOND SERIES
llO0OC
P - 9oooc
S - 400C

c -

Carbon Dioxide
Carbon Oxychloride
( Phosgene )
Carbon T e t r a c h l o r i d e
C a u s t i c Soda & P o t a s h
C h l o r o a c e t i c Acid
Chloral (Trichloroacetic
aldehyde)
Chlorbenzene
C h l o r i n e D i o x i d e , Water
Solution
Chlorine, Liquid
C h l o r i n e , Gas
C h l o r i n e Water, S a t u r a t e d
Chloroform
Chloronaphthalene
C h l o r o s u l p h o n i c Acid
Chromic Acid 10%
Chromic Acid
Chromic C h l o r i d e
Chromium Potassium S u l p h a t e
C i t r i c Acid
Copper A c e t a t e ,
Chlorides & Sulphate
Copper Nitrate ( N e u t r a l
Solutions)
Cresol
Ether
Ethyl Acetate
E t h y l Alcohol
E t h y l a m i ne
E t h y l Bromide
Ethyl Chloride &
Ethylene Dichloride
E t h y l e n e D i s u l p h o n i c Acid
E t h y l e n e Oxide
Ethyl Ether
Ethyl Sulphate
E t h y l S u l p h u r i c Acid
F a t t y Acids
F e r r i c C h l o r i d e , Nitrate,
Sulphate
F e r r i - & Ferrocyanides
F l u o b o r i c Acid
F l u o r i n e Gas
F l u o s i l i c i c Acid
Fo rmal d e hyde
Formic Acid & Compounds, n o t a l l
Furfural

FURABOND
FURASET
175OC

STERNCHEN SERIES
POLYESTER
PHENOLIC
120oc

175OC

R
R

U
30C
U
N

R
R
R
R

R
R

R
R

NR
N

NR

NR

8OoC
35oc
35OC
20%
N
U
U

NR
NR
NR

NR

NR
R

3OoC

R
R
R
R
R
R
R
R
R
R
R
R

NR
NR
R
R
R

NR

3OoC
NR
NR
U
NR

U
U
R

U
R
R

R
R
R
R
R
R
R

R
R
R
R
R

R
U
U
N
8OoC
U
NR

R
NR
R
3OoC
30oC
NR
NR

R
R
R
R
R
R
R

R
R
R
R
R
R
R

R
R
NR

R
R
R

NR
NR

NR
R
R
R

3OoC
R
R

25Oc

NR

R
R
U

NR
NR
R
R
R

NR

NR
NR

6ooc

3OoC

NR

3OoC

U
U
25oc
3OoC

R
U

R
3OoC

3OoC
R
3OoC

R
R

NR

NR

NR

NR
R
R
R
NR
(continued)

409

Cements, Mortars, and Asphalt


TABLE 3.14: VARIOUS MORTARS-STERNSON

EXPOSURE

(continued)

I N 0 BOND SERIES
llO0OC
P
goooc
S
400OC

c -

G a l l i c Acid
Gasoline
Glycerine
Glycol Monoacetate
Hydrazine S u l p h a t e
Hydriodic Acid
Hydrobromic Acid
Hexane
Hydrochloric Acid
Hydrocyanic Acid
H y d r o f l u o r i c Acid
Hydrogen P e r o x i d e
1%
Hydrogen P e r o x i d e 10%
Hydrogen P e r o x i d e 25%
H y d r o f l u o s i l i c i c Acid
Hydrogen P e r o x i d e 30%
Hydrogen S u l p h i d e
Hypochlorous Acid
Iodine
I r o n Chlorides
I r o n Nitrates
Iron Sulphates
Isopropyl Ether
Iodoform
Kerosene
L a c t i c Acid & Compounds
Lead C h l o r i d e
Lead Nitrate ( N e u t r a l Solufuions)
Magnesium C h l o r i d e , N i t r a t e ,
Sulphate
Maleic Acid & Compounds
Manganese C h l o r i d e , Oxides
& Sulphates
Mercuric C h l o r i d e
Methanol (Methyl A l c o h o l )
Methyl A c e t a t e
M e t h y l b u t y l e n e g l y c o l Acetate
Methyl Cyclohexanol '
Methylene C h l o r i d e
Methyl S u l p h a t e
Methyl Sulphonic Acid
Mineral O i l
ivlolybdenum Acids & Oxides
Naphthalene ( S u l p h o n a t e d )
Naphthalenesulphonic Acid
Naphtholsulphonic Acid
Nickel C h l o r i d e & S u l p h a t e

F'URABOND
FURASET

175OC

STERNCHEM SERIES
POLYESTER
PHENOLlC
12oOc

175OC

U
25OC
70C

R
R
R
NR
NR
NR
NR
R
R
R
R
NR
NR
NR
R
NR
R
NR
NR
R
R
R
U
NR
R
R
R
R

R
R
R
NR
R
R
R
R
R
R
NR
R
R
R

R
R
R
R
R
NR
NR
R
R
R
R

NR

NR
R
R
R
R
R
R
R
R
R
R
R
R

NR

R
NR
R
R
R
R
R
R
R

NR
R
7OoC
R
25OC
NR
25OC
R
R
R

R
R

R
R

R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

R
R
3OoC
R

R
R
3OoC
R

U
U
U

NR
U

NR
NR

NR
R
NR

NR

U
U
NR
3OoC
25OC
R
R
NR

3OoC
3OoC
3OoC
NR
25OC
R

U
R
U

R
R
U
R
U

R
(continued)

4 10

Corrosion Resistant Materials Handbook

TABLE 3.14: VARIOUS MORTARS-STERNSON (continued)

EXPOSURE

I N 0 BOND SERIES

c P
S

N i t r i c Acid 5%
N i t r i c Acid 20%
N i t r i c Acid 40%
Nitrobenzene
Nitrogen Oxides
Nitroglycerine
Nitrophenol
Nitrotoluene
O i l s - V e g e t a b l e , M i n e r a l , Animal
O l e i c Acids & Compounds ( E s t e r s )
Oxalic Acids & Compounds

Paradimethylaminobenzophenone
P a r a f f i n Wax
P e r c h l o r i c Acid
Phenol ( 2 0 % S o l u t i o n )
Phenol S u l f o a c i d s
Phosphoric Acid
Phosphorous Bromide
Phosphorous C h l o r i d e &
Oxychloride
P h t h a l i c Acid
P i c r i c Acid
Potassium Bichromate
Potassium Bromide
Potassium Carbonate
Potassium C h l o r a t e
Potassium C h l o r i d e , Nitrate,
Sulphate
Potassium Cyanide
Potassium F e r r i & F e r r o Cyanide
Potassium Hydroxide
Potassium Oxalate
Potassium Permanganate
Potassium P e r s u l p h a t e & S u l p h a t e
Potassium Peroxide
Pyridine
S a l i c y l i c Acid
Selenium Compounds Acid o r N e u t r a l
Silicon Tetrachloride
S i l v e r Nitrate
Sodium A c e t a t e
Sodium B i c a r b o n a t e
Sodium Bichromate
Sodium B i s u l p h a t e , B i s u l p h i t e
Sodium Carbonate
Sodium C h l o r i d e , Nitrate
Sodium Chromate
Sodium C h l o r o s u l p h o n a t e
Sodium Cyanide

llO0OC
goooc
40OoC

FURABOND
FURASET

175OC

STERNCHEM SERIES
POLYESTER
PHENOLIC
120%

175OC

7OoC

U
NR
NR

NR
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

NR
NR
NR
R
NR
NR
NR
NR
R
R
R
R
R
NR
R
R
R
NR

R
R
R
R
R

R
R
NR
R

NR

R
R

R
R
R
R
R

R
U

3OoC

8OoC

8ooc
6ooc

30OC
NR
U
R
R
NR
NR
R

R
R
NR
R

NR
R
R
R

NR
R
R
R
R
R
R

NR
R
R

NR
R
R
R

NR

NR

R
NR
80C
R
R
R
U
R
R

R
R
R
R
R
R
R

25OC
NR
NR
NR
NR
U

u
R
R
R

U
R

NR
NR
U

R
NR
U
R
NR
R
U

U
U

R
NR
R
U
U

7OoC
R
R
R
R
U
R
R
U
U

3OoC
NR
NR
NR
NR
R
R
R
U
R
NR
NR
U
R

NR
U
R

NR
R
NR
3OoC
R

3OoC

U
U
R
R
R
R
R

3OoC
R
R
U
25OC
(continued)

41 1

Cements, Mortars, and Asphalt

TAB LE 3.14: VARIOUS MORTARS-STE R NSON (continuedJ

EXPOSURE

I N 0 BOND SERIES

c -llO0OC
P
S
Sodium Hydroxide
Sodium H y p o c h l o r i t e
Sodium O x a l a t e
Sodium P e r o x i d e
Sodium S u l p h a t e
Sodium S u l p h i d e
Sodium S u l p h i t e
Sodium T a r t r a t e
Sbdium T h i o s u l p h a t e , T h i o s u l p h i t e
Soya O i l
S t e a r i c Acid
S u l p h u r i c Acid 5%
S u l p h u r i c Acid 50%
S u l p h u r i c Acid 80%
S u l p h u r i c Acid 93%
Sulphur C h l o r i d e
Sulphur Molten
Sulpnurous Acid
Sulphur Oxides
Sulphur Dioxide (Wet o r Dry)
S u l p h u r i c Acid, Fuming
Sulphur T r i o x i d e (Wet)
S u l f u r y l Chloride (Sulphur
Oxychloride )
Tannic Acid
T a r t a r i c Acid & Compounds
Tetrachloroethane
Tin Chlorides
Tin Sulphates
Titanium C h l o r i d e s , S u l p h a t e
Toluene ( T o l u o l )
Toluenesulphonic Acid
T r i c h l o r o a c e t i c Acid
Trichloroethylene
Trisodium Phosphate
Tung O i l
Urea
U r i c Acid
Xylene ( XyIol)
Zinc C h l o r i d e , Nitrate, S u l p h a t e
Zinc Nitrate

- goooc

NR
NR

R
NR
R

NR
R
R
R
R
R

NR
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R

NR
R
R
R
R
R
R

40OoC

F'URABOND
FURASET

175OC
R
NR
R

NR
R
R
R
R
R
R
R
R
R
NR
NR
NR
R
R
R
R
NR

NR

STERNCHEM SERIES
POLYESTER
PHENOLIC
120%

175OC

NR
R

NR
NR

U
U

R
R
R
NR
NR

NR
R
NR
R
R
R
R
R
R
R
25OC
25OC

R
R
R
R

R
E
R
R
NR
25OC

3OoC
R
R
R

NR
NR

NR

NR

R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
R
125OC

R
R
U
R
R

R
80oc

U
NR

U
3OoC
R

3OoC
U
30OC
R
R

NR
R
R
U
R
R
R
NR

U
U
U
NR
R
R

U
U
R
R

Ferrous Alloys

TABLE 4.1:

AUSTENITIC

ALLOY-ALLEGHENY

LUDLUM

AL-6X is an austenitic chromium, nickel, molybdenum-containing


alloy developed for service in chloride and other pitting or crevice
corrosion environments such as sea water. The 20% chromium
and 6% molybdenum contained in the alloy produces outstanding
resistance to pitting and crevice attack in chloride-containing
solutions. The high nickel (24%) and molybdenum provide good
resistance to stress corrosion cracking. The alloy content of the
material produces excellent general corrosion resistance in a
number of media.
The alloy is readily welded by the inert gas processes. AL-6X
possesses good ductility and high impact strength.
AL-6X is available as welded tubing, sheet and strip.

Typical Analysis

Carbon
Manganese
Phosphorus
Sulfur
Silicon
Chromium
Nickel
Molybdenum

.025
1.50
.025
.Ol0
2d.E
24.50
6.25

The following table illustrates the corrosion resistance of AL-6X


in various solutions in comparison to AISI stainless steel grades.
Tests were performed in boiling acid (concentrations in weight
percent) for five 46-hour periods. The listed values are corrosion
rates in IPM (inches per month):

45% Formic Acid


20% Acetic Acid
10% Oxalic Acid
10% Sodium Bisulfate
10% Sulfuric Acid
65% Nitric Acid
(ASTM A-262
Practice C)

AL-6X

12.0

.143
.025
947
.230
1.36

943
9002
906
,014
.07f

9005
.OOOl
.0009
.OOll
,010

.0007

9507

.0009

JO26

.61
9000

Alloy

Crevices On Samples
0.45 Gram Weight Loss
Severe Crevice Attack

0.45 Gram Weight Loss


Severe Pitting

316

0.40 Gram Weight Loss


Severe Crevice Attack

0.03 Gram Weight Loss


Some Pitting, especially on
sample edges

AL-6X

No Weight change to
0.000 Grams
No Attack

Samples initially

weighed about 10 g,

No Weight change to
0.000 Grams
No Attack

316

Corrosion Rate, IPM

Concentrations
of H,SO,
Weight %

15VF

175F

2OfYF

AL-6X
316

904
.003

904
.007

905
.012

10

AL-6X
316

.CQ6
907

.004
.013

,007
.016

20

AL-6X
316

.009
.016

905
.070

.013
.146

40

AL-6X
316

907
536

.OlO
1.646

.019
3.023

95

AL-6X
316

.031
905

.043
907

.056
.026

No Crevices On Samples

304

304

Data, including the boiling acid tests above, show that AL-6X is
generally more corrosion resistant than Type 316. In environments
such as sulfuric acid, concentrations and temperatures have a
marked influence on corrosion rate, and specific conditions should
be carefully determined. The following data determined for 2-hour
coupon tests are illustrative:

Temperatures

TyPical Weiaht Changes and Sample Conditions Resuking


Fibm 10 Per&t Fe& Chloride tixposure Tests72 Hours 70 F (21 C)

We

Type

Type
446

Solution

Ferrous Alloys

TABLE 4.2:

AUSTENITIC

STAINLESS

STEELS-JESSOP

413

STEEL

Jessop Steels corrosion


resistant engineering
alloys, JS700 and JS777,
less steels. These alloys are proven problem-solvers
in many applications

are high-alloy,
fully austenitic,
super stainwhere corrosive
conditions
are too severe
for the standard
grades of stainless steel. They have also provided
cost-effective
alternatives
to more expensive
nickel-base
and titanium-base
alloys. JS700 and JS777 are much more highly alloyed
than the standard
stainless
steels. These grades contain nominally
25% nickel, 20% chromium
and 4.5% molybdenum.
The combination
of the
three major alloying
elements gives JS700 and JS777 a high degree of resistance to stress corrosion
cracking.
Neither
alloy is completely
immune to this type of corrosion
failure,
as can be shown by such severe tests as stressed exposure to boiling magnesium
chloride
solutions.

Corrosion

Data

(48 Hr. Laboratory

Tests-All

concentrations

are by weight

%I.
Corrosion

Environment

Temperature

OF
JS700

20% Phosphoric
Acid
54% Phosphoric
Acid
60% Phosphoric
Acid
85% Phosphoric
Acid
Sensitized
Material
25% Phosphoric
2% HF

Boiling
250
Boiling
Boiling
Boiling
167

Point

60% Acetic Acid


1.1 Acetic AcidIAnhydride

Boiling
Boiling

Point
Point

co.002
0.001

5% Nitric Acid + 3% HF
25% Nitric Acid
65% Nitric Acid (Huey)

155
Boiling
Boiling

Point
Point

<0.002
co.002
co.020

5% Hydrochloric
Acid
10% Hydrochloric
Acid
10% Hydrochloric
Acid
10% Hydrochloric
Acid
10% HCI in EDA (1 I

Boiling Point
Room Temp.
140
Boiling Point
Boiling Point

30% Sulfuric Acid


Sensitized
Material
50% Sulfuric Acid
50% Sulfuric Acid + %% HCI
70% Sulfuric Acid

Boiling
Boiling
Boiling
Boiling
Boiling

co.002
0.0024
0.059
0.122
0.124
0.008

Point
Pomt
Point

J8777

0.012
0.067
0.080

0.150
0.160
0.247
0.880
57.6

0.036
0.031
0.102
0.298
27.6

Butyl Acetate Mixture (2)


Boiling Point
Boiling Point
Stretcher Test (3)
(I) 1 Volume cone I-ICI in 9 volumes Ethylene Diamine.

0.264
0.096

Chemical

Nickel
Chromium
Molybdenum
Columbium
Carbon, max
Slllcon. max
Manganese,
max
Phosphorus,
max
Sulfur, max
Copper

Water-0.3%

HPSO~.

Composition

0.294

1 454

1.691

2.37

(4)

(4)

0.962

0.540

(3) 50% Sulfuric Actd + 0.6% Fe+) as ferrtc sulfate InhIbItor.


(4) Dissolved COmPletelY in 48 hours.

[IIOtninai

an&SiS)

JS700

JS777

24.0-26.0%
190-230
43- 50
6 x carbon mm-O.40 max
.04
1 .oo
2 00
.04
03
50 max

24 O-26 0%
19 O-23.0
43- 50
8 x carbon mm-80 40 max
04
1 00
2 00
04
03
1.90-2.50

The copper added to JS777 markedly


Improves resistance to general corrosion
in strongly acid environments. As shown
In the tabulated corrosion test results,
copper improves performance not only
in oxidtzmg acids (e.g. sulfuric) but in
media generally considered reducing
(hydrochlorIcI as well However, m more
nearly neutral media, where failure is by

0 196

co.002

Point
Point
Point
Point
Point

Acetic Acid-4%

317L
co.002

co.002

0.962

1% Butanol-10%

317L Plus

co.002

1.491
0.018
0.150
4.51
<O.OOl

(2) 75% Ester-l

Rate

IPY

localized corrosion, copper seems to be


actually detrimental to performance.
Field exposure tests (e.g. the TAPPI program
IIT pulp bleach washers) and electrochemical
current decay tests show pits to propagate
more rapldly in JS777. JS700 is therefore
the recommended alloy where pitting or
crevice corrosion IS the primary concern.

Ferrous

TABLE

4.3:

FERRITIC

STAINLESS

STEELS-ALLEGHENY

AL 29-4-2
Critical Pitting Potentials in Saturated Sodium
Chloride Brine at 38C (lOOF)

Data

pH 10

PH6

pH2

+990
+ 400

+ 990
+420

+ 860
+430

(continued)

from

one

year

field

corrosion

tests

paper

mill

bleach

Results

---__~_~~___.~~i

Ic

I
t

Mill
-~__

,I

C (72h.)

Numbers

in paranlherer

indicale

described

L--C_(250h.)

in ASTM

1 C (4%72hd

II

II

II ~ II
11 / Ill
II Ill

III
Ill
Ill

Ii
Ill
Ill

AL 29-4-2
Titanium
Monel400
E-BRITE
~ 316L

.._
22C (72F)
.00N3)
.OON
.OON
JJON
OON

(1) One

Year Exposure
Chlorides: Up lo 4100 ppm
: As low as 1.2
PH
Temperature:
Up to74C (lS*F)

the test duration.

Weight Loss, mg/cmz


1 sOC(14OF)

j 107C (224F)

/
;
I

.OON
.OON
.08c
.12 c
.Ol c

.OON
.OOC
.29 c
cl6C

.I. .I. Oeirler. R. H. Heahy


and
L. L Edwards. %onorion Resistance of Alloys 10 Bleach Plan,
Enwonmene.
TAPPI, Nov. 1979. Vol. 62. No. 11, pp. 4%5l.

.oic

/
Performance of AL 29-4-2 and Other Alloys
in Boiling 65% Nitric Acid

Crevice Corrosion Tests in Boiling Brine with


Sodium Carbonate
Alloy
Al 29-4-2
E-BRITE
Titanium
Monel400

Weight Loss, mg/cm2


0.00

0.00
0.00
1.05

Alloy

Visual Appearance

No Corrosion
NoCorrosion
No Corrosion
Crevice Corrosion

/
/
:/

(1)S&waled

NaCl brine conlaining


10% N&CO,,
pH 11. 72.hour
test,
abnospheric
pressure. wewces wdh rubber bands and tellon spacers.

(2) Corrosion Classdicabon:


I O-9 mil pit depth and4
mpy general corrosion rate
II S-20 mil pll depth o,>l lo IO mpy general corrosion rate
111 > 20 mil pit depth or>10 mpy general corrosion rate

Source: A. I, Tuthill, J. D. R6hlo.

I1 ) PH 7.0.72-ho,
test. crevices with rubber band and teflon soacers
(2; brine composition
(wt. %): 25% NaCI; 38% Na,SO.; .lS% &Cl,;
.03% MgCI,
No Corrosion; C Crevice Corrosion.
(3) Visual appearance
rating: N

II
Ill
Ill
Ill

A692).

Crevice Corrosion Test) in Synthetic Brine


__.__
Alloy

_---..-..-

I/

(1) 1500 ppm Cl as NaCl (Procedure


(Z)NC
No Cracks: C Cracks.

pulp

are shown

plants

TAPPI (0 Stage),) Corrosion


Stress COrrOSiOn Cracking in Various NaCl Tests

/___
T&304

at nine

below. In this
program,
nine different
pulp mills exposed corrosion
test spools for one year. The AL 29-4-2 alloy was
among
those
demonstrating
the highest
degree of
corrosion
resistance.

MillivoltsVs. Saturated Calomel Electrode


AL 29-4-2
E-BRITE

415

Alloy (contd)

and

Alloy

LUDLUM

Alloys

boiling

at

Corn&n

AL 29-4-2
1 E-BRITE
Type 304
Type 347
Type 316
-- Type-._430
-.......
(1) ASTM

I
I
I
.._.__

A 262. Practice

i -.-

._

C. Five who,

. .._

Rate, mm/a (MPY)

.05-.08 (2-3)
.lO-.13 (4-51
.20-.61 (8-24)
.25-.41 (10-16)
.28-.89 (1 l-35)
.51-.9l _...(2036)
--.__.
.._._.

_ ^._..

periods.

Corrosion of AL 29-4-2 and Other Alloys in Hot


Geothermal Fluid)
Corrosion of AL 29-4-2 and Other Alloys in
50% Nitric Acid Containing Chlorides and
Fluorides at 79C (175F)
i_!?lp(i~~!~---.

~-..-;

_-..

--

~-

.-__-

Corrosion Rate(?),mm/a (MPY)


F.RRIT E1TVIX 3W [ %nium
I.211.Ol; (0.6) 091 (3.6)
,117
025
,079 (3.1)
(l.O), 1 .305
,102 (4.0) i ,914
,241 (9.5) i 1.115

AL 29-4-2

(1) 133C (271F)


cl-776 ppm
pH 7.23
lice;
S4 ppm
Nonaerated
so: SO ppm
109 Day Exporure H,S 0.1 ppm
(2) Penetrabon rate calculated from maximm
(3) P-Present
but not measured
N-Not
observed
SO,Ce:

(l,Chlo,ides
(2) Corrosion

addedasH,&
fluoride as HF.
rate is the average 01 two 48-ho,

(4.6)
(12.0)
(36.0)
(43.9) __I

periods.

pit o, crevice depth.

D. W.~DeSe,,,.
P. F EM nd
C. C. Thomas. Malenals
Setec,ion Guidelines (0, Geothermal power Syrlemr~, FM
Ed.. Rad,w Cotp., lo, U. S. Dept. of Energy. Contract NO.
EC-77-C-M-3904.
Septembe,. 1978.

(continued)

Corrosion Resistant Materials Handbook

416

(contrnued)

AL 29-4-2 Alloy (contd)


Other Alloys in Boiling Organic

Acids

<O.Ol

AL 29-4-2
E-BRITE

/m_Fm_._

--

(1) Average 01 five 48.hour

(2)
0.5
(18)
0.01 (0.4)

~-

periods

A. I, Asphahani. P. E. Manning, W. L. Silence. F. G. Hedge.


Highly Alloyed Stainless Materials lor Seawater Applica-

Source:

lions,
Illinois.

Presented
at NACE.
March 3-7. 1980.

CORROSION/80.

Chicago,

Intergranular
Alloy

Corrosion of AL 29-4-2 and Other Alloys in


Boiling Dilute Sulfuric Acid Solutions
Corresion
_I--__-..
I

t
Alloy625

/ NA

IE-BRITE
I

A
NA
A
NA

/Type 316

1 A

I% H2sOI
.005(0.2)

.07 (2.6)
.07 (2.8)
.06 i2.2j
.02 (0.7)
13.7
(541)
.55 (21 7)
66 (25.8)

Desulfurization

[ Corrosion Rate, mm/a (MPY)


I
Samole
I

.03
.27
.32
.23
.36
77
2.49
2.71

(1.3)
(10 7)
(12.7)
(8 9)
(14)
(3020)3
(98.2)
(107)

.02
.46
.52

Ferric
ASTM
) Bolting
~ ASTM

Weight Loss (mglcmr)


-Test

AL 29-4-2
Alloy 625
i Alloy 625
/Type316
,Type316
!Allov G
i~lio;C-276

/
1

72h
24h
72h
24h
72h
72h
72h

8.73

L- ASTM A763

(344)

.HSOJ: 3 OI o Cl.

7
I

---I
0.2 N
-

20.6 C
I Wt. % CuCI.. 1 WI. %

F&t>

.14 (5.6)

.13 (5.0)

None

Practice

Corrosion of AL 29-4-2 Alloy in Laboratory


Caustic Solutions

4.2 C
-

(2),sualexam,nat,an.N NoCorrosion
C CrertceCorrosion

Sulfate-50%
HzSO~
A763. Practice X
65% HNOI
A262. Practm C

rot (158F)
c

I
I

Plain Containing
Grain
Sample
Weld
Dropping

Test

(0.8)
(18.2)
(20.6)

Environmentn)

Corrosion Tests on AL 29-4-2

em-mm/a (M
____~_
5% Ihso,

Crevice Corrosion of AL 29-4-2 Alloy and


Other Metals In Simulated Flue Gas

(1)7VCl

(0.1)

0.01(0.4)

Compesitior

=-----I

I_._

Temperature IIuration.

Other
-t- -

C (F)
Boiling
Boding
Boiling

1
-

Na&O.,

149
(300)
Bng
177 (350)
Boilmg
Boiling
177 (350)

Rate

mm/a

Days

1 WPv)

5
4
4
4
4

j o.m(o I)*
j 0.02 (0 8)

4
4

Corrosion

4
4

0.10 (3.8)

i 0.00(0.0)
I 0.04 (1 5)
/ 0.19 (7.4)
j 0.00(0.0)
0.00(00)
0.14

(5.6)

I
.L

(continued)

417

Ferrous A llo ys
TABLE 4.3:

FERRITIC

STAINLESS

STEELS-ALLEGHENY

LUDLUM

(contmwd)

The E-BRITE
alloy is a high-purity
specialty
ferritic
stainless steel which combines excellent
resistance to corrosion
with good fabrication
characteristics.
It offers outstanding
resistance to stress corrosion
cracking along with superior
Pitting
and crevice corrosion
resistance,
compared
to conventional
ferritic
and austenitic
stainless steels. General
corrosion
resistance
is usually
better than that provided
by these standard
materials
and
in some cases is even
better than that of some nickel-base
alloys. The E-BRITE
alloy also is designed to provide
excellent
resisiance to
intergranular
corrosion.
Added to all this corrosion
resistance are unique ductility
characteristics,
particularly
when
compared
E-BRITE

to other ferritic
Alloy Analysis
__-

j,,,,

stainless steels.
Crevice Corrosion Tests
10% Ferric Chloride
~_..~..__
-.._- ___. -. ._ _.__~____.._
.._~___~_
..

__-___-

~~~W%!!!!J!Jz!_!_;I.~~

Chromrum
Molybdenum
Nrckel
Copper
Manganese
Phosphorus

26 0
10
15
02
05
01
01
20
002
,010
10

Suf:1r
SIlIEOfl

Carbon
Nrtrogen
Columbrum

/
1

250
-27 5
0 75 - 1 50
50 max
20 max
40 max
02 max
02 max
40 max
010 max
015 max
005
-020

._ _
___#Weight Loss, mg/cm 1
-____
RT _ -.
_ 38C.11 DOF)m

L----_A110y.

,
j

E-BRITE
T37L
T316

03
50
11 5

~QX2QCt&_

(1)72

hour

__--.

exposure.

ASTM

_.___.._21..~__
G-48

i_AtlOY__ _-Weight
Chloride Stress Corrosion
Annealed Sheet
/r-----i
Boiling
I Solution

j
T304

J2OuMgCI,
c300 LIC
26Oc NaCl
(II

F NF -

Resistance

Time to Failure (Hours)


_._______-..
E-BRITE
T316
:
-~

F (81
F (22,

F 1241
F 1221
F (221)

F (J-31

Slress Corroston
No Fatlure

NF (2001
NF (500,
NF (loot

Falure

Critical Pitting Potentials


at 38C (1OOF)

(1) 96.hour

Crevice
Sodium

I
i_AhY.

Saturate

8ampleAppearance
No Corrosron
Crevice Attack

05
95
~~t21)Crevj~e&tack_.

exposure

Corrosion
Carbonate

Tests in Boiling Brine with

--.---

_-__

--_!--WeightLoss.

brine

containmg

..-.

No Corroston
No Corrosron

0 00
0 00
105
N&l

-__-.-

mgkmf-VisualAppearance-

NaCl Brine

,I)

at i1C (160F)
--.--

Loss,mg/cm*_

E-BRITE
Titanium

in Saturated

~_~._
_ _38.3-

-.

Procedures

Crevice Corrosion Tests


5.25% Sodium Hypochlorite

E-BRITE
Type 316
lyp&?Q__

76
27.0
32 2

-Crevice=

10% N&O,.

pH 11. 72.hour

lest. boiling

at

Urrosion
Rate
/-Temperature_.
Duration
_#1B.-Days
_-mm~.___UkWT)

kt?NaOH-/--CKMnOd-NaCI

75

Pitting Tests

102

Resistance
Containing

(215)

0 000

(220)

0 001

(230)
(240)
1290)
1315)

7
5
5
4

0 000
0 001
0 003
0 084
QZZ0
381

of E-BRITE Alloy to Caustic


NaCl and NaC103

(0 01,
to 04)
to oi 1
10 05)
(0 111
13 3)
16-151_

Solutions

!ld!Lal~~,,3
1
(1) 2%
(2) F

20
45
50
KMnO.-24

N&I.

Failure
by pottmg

no crev,ces

(pH 7.5)

10
5
-5
5
5___.
5

50

50
i.SL 50
_

!
~

01
0;
02

~~~~

143
143
152
152
152

(290)
(305)
(290)
13051
13051
(305)

/ 0041
(1 6)
003
li
0 076
(3
to 01
0 069
(2 71
_OLd28__
0 028
~il~li
11 11

~~_

(continued)

Corrosion Resistant Materials Handbook

418

TABLE

4.3:

FERRITIC

STAINLESS

STEELS-ALLEGHENY
E-BRITE

Corrosion of E-BRITE
In Pulp Liquors

and Austenitic

Alloys

Alloy

(contmued)

(co&d)

Performance
of E-BRITE Alloy and Other
Stainless Steels in Huey Test

Corrosion Rate, mm/y (MPY)


ik---------

LUDLUM

2 Parts White Liauor to 1 Part

I
/

I
/
1

i FcBpXZ
Type347
Type316
Type430

010-013
0.20-O 61
0.25-041
028-O 89
0 51-o 91
_____

(1)ASTMA262.

Pracltce C. Bollmg 65O~ HNO,.

Influence
Corrosion

I---

Fwe 4%hour

and Austenitic Alloys


Conditions of Heat Flux

300

50%
~ 50%

300

!-

1000

Corros,on

Corrosion

rate

0005
0010
0025
0041
0089

I ; 20
/ 20
'100
IS average

of two 48.hour

added as HCI. lluorlde

in Boiling.

______ _-

Rate, mm/y (MPY)

35

permds

Dilute Sulfuric

___~.j_

Activated

Alloy

1138)

Acid Solutions
(MPY)
5% lizSO
NonActivated

Activated

___I

(3 6)
(4 61
1120)
(360)
14391

as HF

Non-

(0 2)

Titanium

106)
0091
('0)'0117
(31),0305
(40) 0914
(95) 1115

(02)
0015
(04) 0025
(1 0) 0079
(16) 0102
(35),0241

1% H2S04

Alloy
005-005

periods

Type304

Corrosion Rate, mm/y

,E-BRITE
Type316Tt
,Type317L

~~_.

5000
5Ow

(2, Chloride

Corrosion of E-BRITE
In White Liquor Under

(8-22:)
(10-16)
(11-Z)
(20-261
~____

of Chloride And/Or Fluoride On


In 50% Nitric Acid at 79C (175F)

__-..--.

snD/o

(A-51

/I
/

Corrosion
Solution
.__. .
c_______-_
_. ..__.
E-BRITE
PPM F -IHNO,
_
_----- PPM Cl

(I,

/
1
I

Corrosion Rate, mm/y (MPY)

Alloy

Activated

(1) Sample kept al 160C (32OF) immersed in while liquor at BOC (176F).
(2) Sample temperature 160C (32OF). whde liquor jet at 8OC (176F) projected
against sample.

Corrosion

In-Plant Corrosion Tests of E-BRITE


Other Alloys in White Liquor

Corra
E-BRITE
NI-CrAlloy600
Type329StamlessSteel
Type310StalnlessSteel
NI-Fe-CrAlloy800
NI-'hAlloy400
NI-Fe-CrAlloy825
Type304StadessSteei
NI-CrAlloy625
Type316StamlessSteel
CarbonSteel

Boilin

Or

anic Acids

~~

and

___

Alloy

3n
Rate
__.___/

mm/y

WY)

0 000
0 005
0 008
0010
0020
0023
0 041
0168
0173
0 516
0886

(0 0)

(1) While Liquor:


260 (NaOH+Na,S).
7.8% NaCI. 1 5% NarCO,.
Temperature: 127C (261F)
Duratlon~
154 Days
(2) SCC - Slress Corroston Cracking Observed

IO 21
10 31
(0 4)
(0 81
ro 91

I
1

Comparison
of E-BRITE and Other Alloys
Boiling 88% Formic and 99% Acetic Acids

1
E-BRITE
NI-Cr-MoAlloy276
Nt-Fe-CrAlloyG
Nl-Fe-Cr Alloy825

NdZrAlloy600

Type304 StaInless
Type 3:6 Stainless

Rate. mm/v

88% Formic

<o 01

(-'O
1)

005
0 10

(1 8)

0 08
0 23
0 33
0 38
2 44

NJ-Cr Alloy 625


NI Alloy200
3OoNa.SO,

Corrosion

in

0.23

99% Acetic

0 01
001
004
005
001
010
020

(4 0)

(3
(9
(13
(15

0)
0)
0)
0)
(96 0)
(9oj

IMPY)

046
005

(0 5)
(04)
(1.6)
(20)
(04)
(40)
(80)

(180)
(20)

Ferrous Alloys

TABLE

4.3:

FERRITIC

STAINLESS

STEELS-ALLEGHENY

LUDLIJM

419

(continued)

Allegheny
Ludlum Stainless Steel Type 439, a titanium stabilized, 18% chromium alloy, also known as ASTM XM-8
and by the IJNS designation S43035,
is a ferritic stainless steel designed to resist corrosion in a variety of oxidizing
environments
from fresh water to boiling acids. It may be used either annealed, cold formed or as welded in many
applications
where other stainless steel alloys such as Type 304, Type 410, Type 409 and Type 430 are used. Type
439 may also be used in many oxidizing environments
where Type 304 is considered adequate in terms of general
corrosion resistance but is considered subject to chloride stress corrosion cracking.

TYPICAL

Tvpical
General Corrosion Data
_.

ANALYSIS
Standard Grade

Corrosion Rates in Inches Per Month


and Millimeters Per Annum ( )

,025
.40
.025
,003
.50
16.00
.30
.60
______ ,025

Medium

MSR Grade

.018
.40
,025
,003
.50
18.00
.30
.50
,014

10% Oxalic Acid


Boiling
___-

Corrosion Resistance

Stress Corrosion Cracking

Type 439 is resistant to attack by potable water and


many mildly or moderately corrosive chemical
environments which are oxidizing in nature. In various
chloride solutions, study has shown pitting resistance
of Type 439 superior to that of Type 304. In addition,
Type 439 is not subject to stress corrosion cracking
which may cause premature failure of austenitic
steels in chloride bearing environments such as hot
waters used in heat exchangers.

One of the most important corrosion properties of


Type 439 is resistance to chloride stress corrosion
cracking beyond the capabilltles of ConventIonal
austenitic grades. This resistance is provided by the
ferritic structure and low nickel content of Type 439.
Results are equivalent for annealed, U-bent and
autogenously welded Type 439.

MF-1 is the designation


for a corrosion resisting steel developed by Allegheny
Ludlum originally
for automotive
exhaust system applications.
An 11% chromium
alloy, MF-1 is a functional
corrosion resistant material that has
served outstandingly
in strong acid condensates that form in automobile
mufflers ard tailpipes.
The functional
uses of MF-1 as a corrosion resistant material for many other special applications
can be equally attractive; suetas replacement
for carbon steels, to avoid painting or other maintenance,
or for galvanized steels under severe
corrosive conditions.
Corrosion

Resistance

TYPICAL

of MF-1

jRates in Inches Penetration/Month


Medium

.--~__

r-

; Carbon

_----

25% Boiling Nitric Acid


20% Boiling
Phosphoric Acid
60% Boiling
Acetic Acid
50% Potassium
Hydroxide at 240F
75% Potassium
Hydroxide at 410F

--.-_______
Welded

samples

show

: Steel
.__..____ _

I
j
j

1
MF-1

50.0

; .0150

30.0

I .048
I
I .159

20.0

j Type 304 I
-/
I
1 .0002
1
I
1 / .0002

.0050

; .00055*
/

~ .00055

,221

I .085*

no preferential

corrosion.

/
I
i
I

,045

ANALYSIS
Cr

11.0

Ti

Fe

.50

Bal.

420

Corrosion Resistant Materials Handbook

TABLE 4.4:

FERRITIC-AUSTENITIC

STAINLESS

FERRALIUM
alloy 255 is a patented,
ferritic-austenitic
nickel,
2% copper
and 3.3% molybdenum.
It combines
tance to corrosion
and erosion.

STEEL-CABOT

WROUGHT

stainless
steel
high mechanical

containing
strength,

PRODUCTS

26%chromium,5%
hardness
with

approximately
ductility
and

resis-

Comparative Aqueous Corrosion Data

Media
Acetic Acid

Concentration,
percent by
$yt$mp.,
0
weioht

Average Corrosion Rate, mils (mm) per year


FERRALIUM
Type 317L
allov 255
Stainless Steel

10

Borhng

0.2 (<O.Ol)

0.2 (10.01

50

Borlrnq

NII

0.2 (<O.Ol)

Glacial

Borlrna

0.7 f<O.Ol)

2.9 10.071

Citric Acid

50

Borhng

NII

0.2 (<O.Ol)

formic Acid

20

Bowling

0.4 (0.01)

8.5 (0.22)

40

Bollinn

0.4 (0.01)

17 (0.43)

60

Boihna

0.1 (<O.Ol)

22 10.56)

88

Bowling

18 (0.46)

9.2 (0.23)

Room

Nil

NII

2.5

Room

Nil

11 (0.28)

10

Borhng

1.9 (0.48)

65

Borhng

8.0 (0.20)

Hydrochloric

Acid

Nitric Acid

Phosphoric Acid

10

150 (66)

Ntl

Nil

10

Bollma

NII

NII

30

150 (66)

0.1 (<O.Ol)

Nil

30

Bowling

0.2 (<O.Ol)

6.7 (0.17)
0.1 (<O.Ol)

55

150 (66)

Nil

55

Boihna

0.1 (<O.Ol)

1.2 (0.03)

85

150 (66)

0.1 (<O.Ol)

0.2 (<O.Ol)

Sodium Chloride

Bothng

0.4 (0.01)

Sodium Chloride plus


200 ppm Cu

Room

0.4 (0.01)

Sodium Chloride plus


0.5% Acetic Acid

0.8

Boding

0.2 (<O.Ol)

0.3 (<O.Ol)

Sodium Chloride plus


0.5% Citric Acid

0.8

Boiling

1.2 (0.03)

31 (0.79)

Sodium Chloride plus


0.5% Oxalic Acid

0.8

Boiling

0.5 (<0.02)

22 (0.56)

Sodium Chloride plus


0.5 % Ammonium Chloride

0.8

Boiling

Nil

NII

Sodium Chloride plus


0.5% Phosphoric Acid

0.8

Boiling

Nil

0.1 (<O.Ol)

Sodium Chloride plus


0.1 N Sulfuric Acid

Boiling

1 .o (CO.03)

148 (3.8)

Sodium Hydroxide

50

Borhng

1.8 (0.05)

29 (0.74)

Sulfuric Acid

150 (66)

NII

NII

Boiling

12 (0.30)

200 (5.1)

10

150 (66)

Nil

8.9 (0.23)

10

Boihnq

4OLl.O)

490 (12)

20

150 (66)

NII

50 (1.3)

(continued)

Ferrous

TABLE

4.4:

FERRITIC-AUSTENITIC

STAINLESS
Average

STEEL-CABOT

Corrosion

Data in Mixed

WROUGHT

PRODUCTS

Acids and Salts

Average Corrosion Rate, per year


mils
mm

286 (141)

0.1

co.01

212 (100)

8.4

0.21

212 (100)

0.3

co.01

212 (100)

0.2

<O.Ol

Stearic Acid DIUS 3% NaCl

212 (100)

0.3

-co.01

Stearic Acid plus 1% H2s0.1

212 (100)

8.3

0.21

Stearic Acid plus 1% H2S04 and 3% NaCl

212 (100)

0.4

0.01

44% Sulfuric Acid plus 6% HN03

86

0.2

co.01

5%

Citric Acid plus

Patmitic Acid

plus

8%

1%

NaCl
H2S04

Palmitic Acid plus 3% NaCl


Palmitic Acid

PIUS

1%

H2S04 and

3%

NaCl

(30)

Corrosion
Test Temp.
F
C

Media
ASTM Synthetic
Seawater*

ASTM Synthetic Seawater


Saturated with Chlorine Gas*

ASTM Synthetic Seawater


Saturated with SO2 Gas
Averageofdupbcale, smooth specimens.

Data in Seawater

Average Corrosion Rate,


mils (mm) per year

68

20

Nil

95

35

Nil

122

50

0.1 (<O.Ol)

149

65

0.1 (<O.Ol)

176

80

Nil

194

90

Nil

68

20

2 (0.05)

95

35

0.8 (0.02)

149

65

7 (0.18)

150

66

Nil

96.hr. exposure.

+*lnltla1lon

of ptts

Data in Natural

Crevice-Corrosion

Maximum Depth of
Attack, mm

14

co.01

57

14

81

1.2

30

86

30

1.6

co.08

30

86

30

28

1.9

30

86

30

76

1.9

30

86

30

97

1.1

30

86

30

41

3.1

30

126

52

0.8

<O.Ol

30

126

52

28

0.10

FERRALIUM
alloy 255
Type 316
Stainless Steel

29

57

29

FERRALIUM
alloy 255
Type 316
Stainless Steel
Type 317
Stainless Steel
Type 317LM
Stainless Steel
20 Cb-3Alloy
FERRALIUM
alloy 255
Type 316
Stainless Steel
.

Number of
Crewas
lmtmted
Number of Crewces
Powble
(120)

Seawater
Percent Crevices
Initiated*

Test Duration,
Days

Alloy

Trademark

of Carpenter

Technology

421

(continued)

Test
Temp.,
F (C)

Media

Alloys

Temp., C

Corporation

(continued)

422

Corrosion Resistant Materials Handbook

TABLE 4.4:

FERRITIC-AUSTENITIC
Crevice-Corrosion

STAINLESS

STEEL-CABOT

Data in 10% Ferric Chloride

WROUGHT

at Room

PRODUCTS

Temperature

for 10 Days

Maximum Depth
of Penetration,

Alloy

Number of
Attacked
Crevices*

mils

mm

FERRALIUM alloy 255

Type 317LM Stainless Steel

20

12

0.30

Allov No. 904L

23

19

0.48

Type 317L Stainless Steel

16

77

2.0

20 Cb-3 allov

24

76

1.9

Tvpe 316 Stainless Steel

24

76

1.9 (Perforated)

Maxamum

poswble

number

01 crewces

fcontmuedf

was 24

Crevice-Corrosion

Tests in Simulated

SO2 Scrubber

Environment*

Allov

Corrosion Rate
per year
mm
mils

Number of
Attacked
Crevices**

Maximum Depth of
Crevice Attack,
mils
mm

FERRALIUM alloy 255

0.4

0.01

Alloy No. 904L

57

1.4

24

0.15

Tvpe 317LM Stainless Steel

179

4.5

24

10

0.25

Allov No. 825

216

5.5

24

10

0.25

45.000
Maxnwm
0.003%

ppmCl-,

150F WCI.
ptf 2. SOz/O, I1 11 bubbled through solutmn.
possible number of cw~ces
was 24.
F&h, 0.11% KCI, 0.5% MgCIz. 1.1% Cat&, 5.6% N&I. 0.02% CaFz and 2OOg11CaSO1.2fi10.

Comparative

Localized

Allov

Corrosion

Temperature

Data in Oxidizing

Pitting
Temperature,
C
F

Crevice-Corrosion
Temperature,
C
F

FERRALIUM allov 255

50

122

35

95

Allov No. 904L

45

113

20

68

Tvoe 317LM Stainless Steel

35

95

15

59

Tvoe 317L Stainless Steel

25

77

10

54
523

CABOT allov No. 825

25

77

s-5

20 Cb-3 alloy

20

68

s-5

523

Type 316 Stainless Steel

20

68

1-5

523

4% NaCl

NaCI-HCI

Solution*

+ O.OlM HCI + 0.1% Fez ISO,) 3.

Comparative

Stress-Corrosion

Cracking

Data

Time to Failure, hrs.


Media

Test Temp.,
F
C

FERRALIUM
alloy 255

Type 316L
Stainless Steel

Type 317L
Stainless Steel

50% NaOH
with NaCl

Saturated

290

143

NC

NC

NC

70% NaOH
with NaCl

Saturated

350

177

NC

200,648

1031.1031

NC-No

fadure in 1000 hours. All tests were

run on dupbcate

specmxens.

(continued)

Ferrous Alloys

TABLE

4.4:

FERRITIC-AUSTENITIC

STAINLESS
Comparative

Media

Stress-Corrosion

Temp.,C

Pt

WROUGHT

STEEL-CABOT

Cracking

PRODUCTS

Data

TYpe 316
Stainless Steel

FERRALIUM
alloy 255

ASTM Synthetic Seawater

176

80

NC*

NC

0.8% NaCl + 0.5% Oxalic Acid*

286

141

NC

NC

0.8% NaCl + 0.5% Acetic Acid*

286

141

NC

0.8% NaCl + 0.5% Citric Acid*

286

141

NC

Modified Wick TestXb

212

100

NC

25% NaCl***

393

200

C
-

30% NaCI

Boiling

0.8% NaCl + COz*

286
Boiling

0.8% NaCl + 0.2% HaPOa*

286

45% Magnesium

Boiling

Chloride

NC
NC

NC

141

4% NaCl + 1% HIPO~*

(continued)

141

NC

*U-bend specimen. 30.day exposure


U-bend
spewne,
100-day exposure
U-bend
specmxn,
5OGhr. exposure
NC-No Cracks
C-Cracked
-Not
tested
Localued attack
blOOO ppm Cl (as NaCll and 500 pp FeCh

Average

Aqueous

Corrosion

Resistance

of Weldments*

Average Corrosion Rate Per Year, mils (mm)


Media

Test Temp.,
F (Cl

Base
Metal

% in. (12.7mm)
Plate, SMAW

l/B in. (3.2mm)


Plate, GTAW

% in. (12.7mm)
Plate, GTAW

75% Acetic Acid

Bolllng

0.1 (<O.Ol)

Ntl

0.2 (<O.Ol)

0.2 (<O.Ol)

2.5% Hydrochloric Acid

Room

0.1 (<O.Ol)

NII

1.7 (<0.05)

Nil

10% Ferric Chloride

86F (30C)

0 2 (<O.Ol)

0.6 (<0.02)

0.7 (cO.02)

6% Ferric Chloride
(With Crevice)

Room

NII

NII

Nil

Nil

65% Nitric Acid

Boiling

4.7 (0.12)

8.3 (0.21)

7.6 (0.19)

11 (0.28)

10% Nitric Acid + 3%


Hydrofluoric Acid

Room

2.3 (0.06)

6.8 (0.17)

55% Phosphoric Acid

Boihng

1.4 (0.04)

1.6 (0.04)

4.1 (0 IO)

1.3 (<0.04)

10% Sulfuric Acid

Bolllng

37 (0.94)

73 (I .9)

49 (I .2)

66 (I .7)

50% Sulfuric Acid +


42 g/l of Ferric Sulfate

Boiling

13 (0.33)

19 (0.48)

18 (0.46)

23 (0.58)

FERRALIUM
allay255lo ltsell
Comparative
Test
Temp.,

Alloy

1;

Stress-Corrosion

Cracking

Data*

Calcium Chloride**
250

121

300

149

Sodium Chloride**

350

400

250

300

177

204

121

149

350

400

177

204

FERRALIUM alloy 255

NC

NC

NC

NC

NC

NC

Alloy No. 904L

NC

NC

NC

NC

20Cb-3 illov

NC

NC

NC

NC

NC

*l-week
exposure. C-shaped spewnens.
like alloy holder.
Compositions
were selected to provide the same chloride
NC-No cracks
C-Cracked

content

as a 25% NaCl solutmn.

423

424

TABLE

Corrosion Resistant Materials Handbook

4.5:

IRON

ALLOY-CABOT

WROUGHT

PRODUCTS

MULTIMET
alloy is an iron-base alloy for use in applications
involving high stresses at temperatures
(816 C), and moderate stresses at up to 2000F
(1093C).
It has good oxidation
resistance, ductility
fabricated.
Its high-temperature
properties are inherent and are not dependent upon age hardening.

CORROSION

RESISTANCE

OF

MULTIMET@

up to 15OOF
and is readily

ALLOY

All results are expressed in mils (mm) penetration


per year. Acid strengths
are given in percent by weight. In some instances, no measurable penetration
could be observed. These instances are noted by the word, Nil. All data are
steady-state
as calculated
from a minimum
of five 24-hr. test periods.
All data were obtained using corrosion
solution
heat-treated
sheet.

TYPICAL

PENETRATION

RATES

ACETIC

specimens

IN CORROSIVE

ACID

CHROMIC
99%

2%

10%

20%

Room

Nil

Nil

Nil

Nil

Nil

Nil

150 deg. F
(66 deg. C)

Nil

Nil

Nil

Ni

(&S)

(2%)

1 356

1 >lOOO

0.1

(<O.Ol)

0.1
(~0.01)

0.1
(cO.01)

1 6.0
(0.15)

(9.09)

FORMIC

ACID

50%

from 12-gage,

Mils (mm) Per Year

MEDIA,

10%

Boiling

prepared

20%

I 30%

40%

60%

Nif

(<oo:bl)

0.1
(CO.01)

(<t-k!Ol)

Nif

(<%)

10%

1 4.0

(>25.4)

ACID

(0.10)

6.0
(0.15)

Nil

1_

69%
Nil

Nil

(<YOl)

1 (;;oo,

1 (zf5,

) (X0,

*Rate is for the fifth (24-hour) test period, not steady state rate.

CUPRIC

2%
Room

Nil

150 deg. F
(66 deg. C)

Boiling

5%

2% +
NaCl

CHLORIDE

FERRIC

5% +
10% NaCl

10%

10% +
10% NaCl

2%

2% +
5% NaCl

5% +
10% NaCl

10%

Nil

Nil

Nil

160
(4.06)

Nil

Nil

193
(4.90)

(725.4)

(725.4)

919
(23.3)

71000

Room
150 deg. F
(66 deg. C)
Boiling

0.1
(<O.Ol)

2%

(co67.01)

71000

71000

(>25.4)

HYDROCHLORIC
1%

CHLORIDE

WET
CHLORINE

ACID

5%

10%

150/o

20%

25%

37%

(E3,

(fE3)

$8)

(EO)

(K5)

(A!28)

687
(17.4)

>lOOO
(B25.4)

Nil

Nil

343
(8.71)

572
(14.5)

431
(10.9)

424
(10.8)

370
(9.40)

934
(22.7)

.>lOOO
(725.4)

>lOOO
(725.4)

71000
(725.4)

71000
(725.4)

180
(4.57)

(continued)

Ferrous Alloys
TABLE 4.5:

IRON ALLOY-CABOT

WROUGHT

PRODUCTS

425

(continued)

NITRIC ACID
10%

20%

30%

40%

50%

60%

Room

Nil

Nil

Nil

Nil

Nil

Nil

Nil

150 deg. F
(66 deg. C)

Nil

Nil

Nil

0.1
(<O.Ol)

0.3
(CO.01)

0.4
(0.01)

0.8
(0.02)

(<od%l)

0.8
(0.02)

2.0
(0.05)

4.0
(0.10)

6.0
(0.15)

(O!&

Boiling

PHOSPHORIC
ACID
10%

30%

50%

65%

Nil

150 deg. F
(66 deg. C)

Nil

I (CYOl,
I (<oo:bl,
I

Boiling

(<KY)

TABLE 4.6:

IRON ALLOYS-CABOT

Nil

Nil

(&Ol)

0.3
(CO.01)

3.0
(0.08)

STELLITE

(01320)

HYDROFLUORIC
ACID

Room

Nil

65%

303
(7.70)

25%

5%

1 &?3,

1(iii[z

70%

$6)

SODIUM
HYDROXIDE

45%

DIVISION

The TRISTELLE
alloys were designed to resist corrosion and all forms of wear. In particular, they were developed
to withstand galling, the gross damage commonly
encountered
in metal-to-metal
sliding systems. By virtue of their
excellent resistance to cavitation erosion, they are particularly
recommended
for valve service.

Compositions

Fe

Cr

Ni

co

Si

30

10

12

TRISTELLE

alloy TS-1

Bal

TRISTELLE

alloy TS-2

Bal

TRISTELLE

alloy TS-3

Bal

Resistance to Corrosion
The following
immersion
test results relate to multilayer
undiluted
gas tungsten arc deposits.
N/L represents an initial corrosion rate of greater than 50 mpy (1.27 mm/year)
and a steady state
corrosion rate of less than 5 mpy (0.13 mm/year).

30%CH&OOH
Boilina

50%H,POd
66C

65%HNOs
66C

5%H2SOd
66C

TRISTELLE

alloy TS-1

TRISTELLE

alloy TS-2

N/L

TRISTELLE

alloy TS-3

STELLITE

alloy No. 1

STELLITE

alloy No. 6

E = < 5 mpy (-c 0.13 mm/year)


G = 5-20 mpy (0.13 - 0.51 mm/year)

S = 20-50 mpy (0.51 - 1.27 mm/year)


U = > 50 mpy (> 1.27 mm/year)

426

Corrosion Resistant Materials Handbook

TABLE

4.7:

IRON-

AND

NICKEL-BASE

ALLOYS-STAINLESS

Corrosion

Specialty
Alloy

CFBM

Erosion-Corrosion

(Alloy

316

CFEM (316)

20)
Alloy

Modified

ILLIUM

PD _._._______,,..___
Fe Base Cr-Ni-Co

Alloy

ILLIUM

ILLIUM

98 .._.....___.,,__. Ni Base Cr-Mo-Cu

Alloy

CN-7M

Hardwood

Spent

Sulfite

Typical
Specific

Gravity

(25C)

liquor

from

..... . ............

................................................

4.52%
0.18%

Total

Sulfur

..........................

5.95%

Acid

......................................

6.37%

Formic Acid

......................................

1.26%

................................................. 8.74%

.25.00%

4.60%

Reducing

Sugars

Sulfonic

.............................

1 % Sl ......................

Sulfur

on Solids

Corrosion
Acid

Nitric

A 65%

solution of boiling nitric acid test revealed

to attack

Tests:

316

(S-20)

Erosion-Corrosion
IRok
Factor1

30.3646

0.65

32.1459

32.1437

0.57

29.7435

29.7420

0.41

31.4510

31.4491

0.37

ILLIUM

PD

29.8805

29.8793

0.31

IltlUM

98

32.5120

32.5109

0.27

Erosion-Corrosion

in

Hardwood

Spent

Sulfite

Liquors

Metal Losr Due To


Specimen
All0y

Weight

fgmsl

Erosion-Corrosion

After

Before

IRate

Fadorl

ILLIUM

98

32.2792

ILLIUM

PD

29.8990

29.8944

0.82

32.1 B 17

32.1722

1.73

Modified

CN-7M

32.2789

0.51

(Alloy 20)

PD

Food Acids:

PD is up to 10 times more resistant

than

CN-7M

Resistance of ILLIUM

Boiling

that ILLIUM

30.3667

fgmsl
After

1 .048

................................................

OCH

Weight

.2.3 - 3.0

MgO

Acetic

Liquor

Digester

Co0

Sl

Causticized

Analysis

pH ...................................................

( '/.

Specimen
Before

Alloy

Alloy

P ,_..______.________.
Fe Base Cr-Ni-Cu

IlllUM

in

Metal Lolr Due To

Description

,...,.__.,..,___.._._ ..Cast
CN-7M

& ENGINEERING

in Pulp and Paper Industry

Alloys

Designation

Modified

FOUNDRY

stainless

steel

Test

results

Tests

conducted

in boiling

vinegar

naise demonstrate

that ILLIUM

cellent

to attack

resistance

and

mayon-

PD exhibits

ex-

from food products.

were:
ILLIUM
CF-8M

PD

1 to 1.8 mills per year

(316)

11.7 mills per year


Fluosilicic

ILLIUM

PD passes the ASTM

Sea water corrosion

U. S. Navy at Portsmouth
of corrosive
to 75,000

attack

B117

salt spray

tests conducted
resulted

on specimens

psi for a period

Food processcrs

are becoming

severe corrosive

nature of cleaning

disinfectants.

Sea Water and Salt Spray:

test.

Acid:

for the

in no evidence

stressed at 55,000

corrosive

Fluosilicic

agents.

mills

per year.

corrosion

solution

CF-8M

ILLIUM

rate of 0.25

chemicals

acid is typical

A 25%

acid at 125 F corrodes

more aware of the

PD

and

of these

of fluosilicic

at a rate of 500
has a measured

mills per year.

of six months.
(continued)

Ferrous

TABLE

4.7:

IRON-

AND

NICKEL-BASE

ALLOYS-STAINLESS

Corrosion

Analysis

in Phosphoric

of Discharge

Phosphoric

Acid

Product

MATERIAL

Fluorine
Sulfuric

Acid

81 ENGINEERING

Industry

from

Reactor
Amount

Phosphoric

FOUNDRY

Present (percent

by weight)

AVERAGE

Acid

RANGE

48%

Compounds

47-49%

1%

Acid

1-2

l-2%

to

Solids

to

Measured
Reactor

Corrosion
Product

Rate of Alloys

at 180

in

CORROSION

98

0.5

lnconel

625

1.2

ILLIUM

1.9

ILLIUM

2.9

lnconel825

Alloy

RATE

ILLIUM

Durimet

Performance

MPY

9.1
20

10.1

20

53.7

in Phosphoric

(71% Phosphoric

MATERIAL

5%
40%

MATERIAL

Carpenter

Acid

Evaporator

Acid at 44OF)

MEASURED

CORROSION
IPY

ILLIUM

98

.0066

ILLIUM

.0109

ILLIUM

.028

316

(sensitized)

.067

317

(3.3 MO)

,079

316

(2.6 MO)

,131

316L

(2.2 MO)

,160

RATE

Alloys

(continued)

427

428

Corrosion Resistant Materials Handbook

TABLE 4.8:

STAINLESS

STEEL-ARMCO

STAINLESS

STEEL PRODUCTS

Armco NITRONIC 50 Stainless Steel provides a combination


of corrosion resistance and strength. This austenitic
stainless steel has corrosion resistance greater than that provided by Types 316, 316L, 317 and even 317L. plus
approximately
twice the yield strength at room temperature.
In addition, Armco NITRONIC 50 has very good
mechanical properties at both elevated and sub-zero temperatures.
This is the material for equipment requiring excellent corrosion resistance-including
that in which Types 316 and
316L stainless steels are marginal. NITRONIC 50 is an effective material for the petroleum, petrochemical, chemical,
pulp and paper, textile, food processing and marine industries. Components using the combination of excellent corrosion resistance and high strength currently include pumps, valves and fittings; fasteners, cables, chains, screens and
wire cloth; marine hardware, boat shafting, heat exchanger parts, springs and photographic equipment. A wide range
of additional applications is made possible by high strength and toughness at sub-zero temperatures, low magnetic
permeability
even after severe cold working or exposure to sub-zero temperatures, and excellent mechanical properties at temperatures up to 1200 F (649C).

Composition

%
.06 max
4.00/6.00
0.040 max
0.030 max
1 .OOmax
20.50/23.50

Carbon
Manganese
Phosphorus
Sulfur
Silicon
Chromium

%
Nickel
Molybdenum
Nitrogen
Columbium
Vanadium

11.50/13.50
1.50/3.00
.20/.40
.l o/.30
.l o/.30

CorrosionResistance
Corrosion Rates in Inches per Year (IPY) Unless Otherwise Indicatedu)
NITRONIC 50 Bar
Test Medium

Annealed 1950 F
(1066 C)

NITRONIC 50 Bar
Annealed 2050 F
(1121 C)

NITRONIC 50
High-Strength
(HS) Bar

10% FeCls, 25 C-plain(*)


10% FeCls, 25 C-creviced(*)

<.OOl g/in*
<.OOl g/in*

<.OOl g/in*
<.OOl g/in*

<.OOl g/in*
<.OOl g/in*

1%
2%
5%
10%
20%

<.OOl
<.OOl
<.OOl
-

<.OOl
<.OOl
<.OOl
0.028
0.133

<.OOl
<.OOl
<.OOl

1%
2%
5%
10%
20%

H2S04,
H2S04,
H2S04,
H2S04,
H2S04,
HzS04,
HaS04,
HzS04,
HzS04,
HaS04,

80
80
80
80
80

C
C
C
C
C

Boiling
Boiling
Boiling
Boiling
Boiling

1% HCI,35C
2% HCI, 35 C
1% HCI,80C
2% HCI,80C

.194

<.OOl
0.024
-

0.027
0.064
0.131
0.356
1.64

0.296
-

Types 316 &


316L
Annealed Bar

.Oll g/in*
.186 g/in*

Types 317 &


317L
Annealed Bar
-

0.002
0.011
0.060
0.10
0.48

<.OOl
<.OOl
0.036
0.049
0.155

0.12
0.26
0.73
2.20

0.013
0.027
0.093
0.465
1.30

<.OOl
<.OOl

<.OOl
0.027

0.012
0.021

0.002
0.023

<.OOl
0.439

0.239
0.452

0.148
0.263

65% HNOs, Boiling

0.010

0.012

0.012

70% HsP04, Boiling

0.203

0.202

0.201

33% Acetic Acid, Boiling

<.OOl

<.OOl

<.OOl

20% Formic Acid, Boiling


40% Formic Acid, Boiling
10% HN03 + 1% HF, 35 C
10% HNOs + 1% HF,80C

0.027
0.034

0.064
0.442

ft)lmmersion
tests performed on W dia. x % (15.9 x 15.9 mm) long machined cylinders.
Results are average of five 48-hour periods.
Specimens tested at 35 C and 813 C were intentionally
activated for third, fourth, and fifth periods. Where both active and passive
conditions occurred, only active rates are shown.
MExposure
for 50 hours with rubber bands on some specimens to produce crevices.

Ferrous

TABLE 4.9:

VARIOUS

DUPLEX

AND AUSTENITIC

STAINLESS

STEELS-CLIMAX

429

Alloys

MOLYBDENUM

Chemlcsl Analyses of Stainless Steels Studied. wt X


Stainless Steel
Type

Si

Mll

Cr

Ni

Ho

CU

Others

SK?

0.004

0.018

0.24

0.34

0.005

0.012 25.51

10.93

1.89

Ti-0.54

s13

0.004

0.011

0.30

0.35

0.005

0.014 25.18

10.35

2.91

1.04

Ti-0.48

DP-3

0.018

0.12*

0.43

0.88

0.015

0.012 25.02

6.91

3.07

0.64

w-o.11

SAF 2205

0.012

0.14

0.34

0.65

0.017 '-0.003 22.13

5.70

3.05

__

26.00*

5.52*

3.33*

1.73*

--

26

3.7

2.3

9.25

0.24

FBRRALIDI@ alloy 255


VEW A905

0.019* 0.20*

0.034* 0.36*

5.8

T304

0.068

0.52

1.07

0.007

0.014 18.29

T316

0.03

0.052

0.43

1.58

0.017

0.014 17.2

11.2

2.2

55700

0.036

0.032

0.32

1.77

0.020

0.005 20.5

25.10

4.40

<0.1*

__

0.16

__

__

0.28

Nb-0.32

* Analyzed at Climax Research Laboratory


FERRALIDM is a rqistered trademark of Bonar Langley Alloys, Ltd.
VBW A905 Is a trademark of Vereinlgte Edelstahlwerke
SAF 2205 is a trademark of Sandvikens Jeroverks Aktiebolag
DP-3 is s trademark of Sumitomo Metal Industries. Ltd.
X700 is a trademark of Jessop Steel Company
512 and 513 ere trademarks of Nisshio Steel Co., Ltd.

Critical Crevice Corrosion Temperature for the


Duplex and some Austenitlc Stainless Steels in 10% FeClj.6H20 (pH 1)"
Highest Temperature
of No Crevice Corrosion
'C

Stainless Steel
TYPO

Lowest Temperature
of crevice Corrosion
QC

s12

2.5, 2.5

7.5, 7.5

s13

0, 0, 2.5

2.5

DP-3

10, 10

12.5. 12.5

SAF 2205

17.5, 17.5

20, 20

VEW A905

17.5, 17.5

20, 20

22.5, 22.5

25, 25

FEP..RALI& alloy 255


T304

-_

-2.5, -2.5

T316

__

-2.5, -2.5

10, 10

JS700
*Based on oneday

exposure tests.

12.5, 12.5
(continued)

430

Corrosion Resistant Materials Handbook

TABLE 4.9:

VARIOUS

DUPLEX

AND AUSTENITIC

STAINLESS

STEELS-CLIMAX

MOLYBDENUM

(contd)

Corrosion Rates and Deepest Penetration In the Creviced Area for Duplex and
Austenitic T304, T316 end JS700 Stainless Steels in Dilute Chloride
(600 pprcCl-, 5 ppm Cu++, 02) Solution at 90C (194'F), One Week Exposure

Stainless Steel
TYPO

Corrosion Rate
rngdm-=/day
0.0, 0.1

NAB, 47

some etched
E.pots

513

4.1, 1.9

49, NMPb

pits, rust
spots

DP-3

0.0, 0.0

NA, NA

SAF 2205

0.2, 0.3

28. 39

etched spots,
small pits

VEW A905

0.8,

39, 32

small pits,
discoloration

0.9

T304

33, 28

206, 77

numerollspits,
etched spots

T316

7.7, 0.9

175, NMP

pits. etched
spots, rust
spots

JS700

0.1, 0.1

NA, NA

no attack

bNMP-

__

s13

0.120, 0.120

__

VEW A905

FERRALIlJt@
alloy 255

no measurable penetration

EDX Analysis of Austenitic and


Ferritic Phases of the Duplex Stainless Steels

pitting Potential Volts


50C
60C
0.100, 0.100

SAF 2205

__

NA, NA

s12

DP-3

0.1, 0.1

Pitting Potentials for the


Duplex Stainless Steels and T316 and 55700 in M NaCl
Stainless Steel
Type

Remarks

s12

FERRALIti alloy 255

NA

Deepest Penetration
in Creviced Area,
microns

0.320, 0.280, 0.240


Average 0.280
0.360, 0.320
Average 0.340
0.400, 0.340
Average 0.370

No pitting

T316

0.060, 0.060

55700

No pitting

SegregationRatio
Stainless Steel
TYPO

% in Ferrite/% in Austenite
CT
Ni
MO
Other

s12

1.41

0.56

1.03

--

s13

1.42

0.50

2.34

__

DP-3

1.29

0.43

2.39

--

SAF 2205

1.22

0.52

1.86

--

VEW A905

1.11

0.6

2.53

0.8 (Mn)

1.17

0.65

2.61

0.54 (Cu)

--

-_

__

0.080, 0.140
Average 0.110
__
FERRALIIJM@alloy 255
0.420

Ferrous

TABLE 4.10:

Relative

VARIOUS

Corrosion

304N
305
306
309
309s
310
310s
314
316
316F
316L
316N
317
317L
321
329
330
347
346
364
403
405
409
410
414
416
416 Se
420
420F
422
429
430
430F
430F Se
431
434
436
440A
4408
44oc
442
446

The X nolallons

Stainless

Steels
Chemical

Atmospheric
industrial

IRON AND STEEL INSTITUTE

Salt
Water

Marine

Mild

Oxidizing

x
x
x

x
x

Reducing

x
x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x

x
x
x
x
x

x
x
x
x
x
x

x
x
x

x
x

x
x

lndlcale that a speck

Manual

STEELS-AMERICAN

of AISI Stainless

Mild Atmospheric and


Fresh Water

(S20100)
(S20200)
(S20500)
(S30100)
(S30200)
(S30215)
(S30300)
(S.30323)
(S30400)
(530403)
(530430)
(S30451)
(S30500)
(s30800)
(530900)
(S30908)
(S31000)
(S31006)
(S31400)
(S31600)
(S31620)
(531603)
(S31651)
(S31700)
(531703)
(S32100)
(S32900)
(N06330)
(S34700)
(S34800)
(538400)
(540300)
(S40500)
(S40900)
(S41000)
(541400)
(541600)
(S41623)
(S42000)
(542020)
(S42200)
(S42900)
(S43000)
(S43020)
(S43023)
(543100)
(543400)
(S43600)
(544002)
(S44003)
(S44004)
(S44200)
(S44600)
(S13800)
(S15500)
(S17400)
(Sl7700)

201
202
205
301
302
3028
303
303 Se
304
304L

Products

Resistance

UNS
Number

TYPE
Number

*Steel

STAINLESS

431

Alloys

x
x

x
x

x
x

x
x

statnless steel type may be considered as reslstant to the corroswe enwonment

and Heat Resisting

Steels,

December

1974,

American

Iron and Steel

Institute,

categories.
Washington,D.C.

(continued)

432

Corrosion Resistant Materials Handbook

TABLE 4.10: VARIOUS STAINLESS STEELS-AMERICAN


Relative

Corrosion

Resistance

of AlSl Stainless

Acids
Hydrochloric acid

Nitric acid

Type 304L or 430 is used.

Phosphoricacid

Type 304 is satisfactory for storing cold phosphoric


acid up to 85% and for handling concentrations up
to 5% in some unit processes of manufacture. Type
316 is more resistant and is generally used for storing and manufacture if the fluorine content is not
too high. Type 317 is somewhat more resistant than
Type 316. At concentrations up to 85%, the metal
temperature should not exceed 212 F I100 Cl with
Type 316 and slightly higher with Type 317. Oxidizing ions inhibit attack and other inlubitors such as
arsenic may be added.

Sulfuric acid

Type 304 may be subject to pitting, particularly if


some sulfuric acid is present. Type 316 is usable at
moderate concentrations and temperatures.

Bases
Ammonium hydroxide, sodnrm
hydroxide, caustic:
solutions

Steels in the 300 series generally have good corrosion resrstance at virtually all concentrations and
temperatures in weak bases, such as ammonium
hydroxide. In stronger bases, such as sodium hy
droxide, there may be some attack, cracking or
etching in more concentrated solutions and at high.
er temperatures. Commercial purdy caustic solutions may contain chlorides, which will accentuate
any attack and may cause pitting of Type 316 as
well Type 304.
Acetic acid is seldom pure in chemical plants but
generally includes numerous and varied minor constituents. Type 304 is used for a wade variety of
equipment including stills, base heaters, holding
tanks, heat exchangers, pipelines, valves and pumps
for concentrations up to 99% at temperatures up to
about 120 F (50 0. Type 304 is also satisfactory for
contact with 100% acetic acid vapors, and-if
small amounts of turbidity or color prckup can be
tolerated-for
room temperature storage of glacial
acetic acid. Types 316 and 317 have the broadest
range of usefulness, especially if formic acid is also
present or if solutions are unaerated. Type 316 is

Steel

and the

CORROSION

Chemical

Industry,

RATES OF STAINLESS

Climax

*Pitted

specimens-average
White,

Materials

pit depth.
Protection,

2 (1963).

t Specimens
47.

Are Used*

Aldehydes

Type 304 is generally satisfactory.

Amines

Type 316 is usually preferred to Type 304.

Cellulose acetate

Type 304 is satisfactory for low temperatures, but


Type 316 or Type 317 is needed for high tempera.
tures.

Citric, formic and


tartaric acids

Type 304 is generally acceptable at moderate temperatures, but Type 316 is resistant to all concen.
trations at temperatures up to boding.

Esters

From the corrosion standpoint, esters are cornpar.


able with organic acids.

Fatty acids

Up to about 300 F (150 C), Type 304 is resistant to


fats and fatty acids, but Type 316 is needed at 300
to 500 F (150 to 260 C) and Type 317 at higher
temperatures.

Paint vehicles

Type 316 may be needed if exact color and lack of


contamination are important.

Phthalic anhydride

Type 316 is usually used for reactors, fractionating


columns, traps, baffles, caps and piping.

Soaps

Type 304 is used for parts such as spray towers, but


Type 316 may be preferred for spray nozzles and
flake-drying belts to minimize offcolor product.

Synthetic
detergents

Type 316 is used for preheat, piping, pumps and


reactors in catalytic hydrogenation of fatty acids to
give salts of sulfonated high molecular alcohols.

Tail oil ipulp and


paper industry)

Type 304 has only limited usage in tall-oil distillation service. High.rosin-acid streams can be handled by Type 316L with a minimum molybdenum content of 2.75%. Type 316 can also be used in the
more corrosive high-fattyacid streams at temperatures up to 475 (245 Cl, but Type 317 will probably
be required at higher temperatures.

Tar

Tar distillation equipment is almost all Type 316


because coal tar has a high chloride content; Type
304 does not have adequate resistance to pittmg.

Urea

Type 316L is generally required.

Pharma
ceuticals

Molybdenum

Type 316 is usually selected for all parts in contact


with the product because of its inherent corrosion
resistance and greater assurance of product purity.
Company,

STEELS IN FLUE GASES

~~~

l*W.F.

Grades

used for fractionating equipment, for 30 to 99%


concentrations where Type 304 cannot be used, for
storage vessels, pumps and process equipment
handling glacial acetic acid, which would be drscolored by Type 304. Type 316 is likewise applicable
for parts having temperatures above 120 F (50 Cl,
for dilute vapors and high pressures. Type 317 has
somewhat greater corrosion resrstance than Type
316 under severely corrosive conditions. None of
the stainless steels has adequate corrosion resistante to glacial acetic act@ at the boding temperature or at superheated vapor temperatures.

Type 304 can be used at room temperature for concentrations over 80%. Type 316 can be used in
contact with sulfuric acid up to 10% at temperatures up to 120 F (50 C) if the solutions are aerated:
the attack is greater in airfree solutions. Type 317
may be used at temperatures as high as 150 F (65 Cl
with up to 5% concentration. The presence of other
materials may markedly change the corrosion rate.
As lrttle as 500 to 2000 ppm of cupric ions make it
possible to use Type 304 in hot solutions of moderate concentration. Other additives may have the op
posite effect.

Sulfurous acid

Different

(continued)

Grades

Stainless generally is not recommended except


when solutcons are very dilute and at room
temperature.
There is usually no appreciable attack on Type 304
or 316 as long as sufficient nitric acid is present.

*Stainless

Where

Environment

Mixed acids

Organics
Acetic acid

Steels

Grades

Envrronment

IRON AND STEEL INSTITUTE

destroyed.

1966,

Greenwich,

(EXPOSURE

CT.

3 MONTHS)**

Ferrous

TABLE 4.11:

VARIOUS

STAINLESS

STEELS-CARPENTER

CORROSION

of inhibiting
or accelerating
contaminants.
of recirculation,
solids in suspension,
velocity,
of use, and equipment
design. The corrosion

RESISTANCE

TABLE

CODE

infredata

for all grades except Carpenter 20Cb3 are reprinted from


Corrosion Data Survey, 1967 and 1974 Editions, published
by the National Association of Corrosion Engineers. The
corrosion rates for Carpenter 20Cb-3 stainless represent a
composite of the NACE Corrosion Data Survey and more
current
data
developed
in
Carpenters
Corrosion
Laboratory.

350

250

175
150---

fluence on corrosion,
the conditions
greatly.

125

When

reviewing

these

the following in mind

corrosion

tables,

per year

Corrosion RON less than 0.020

per ycor

Corrosion Rote lrom 0.020 to 0.050

Corrosion RON greotcr than 0.050 par year

662

20

40

per year

80

60

100

462

347

affect
257

it is good to keep

100 212 _-------____


_.__
_.__._
____
_-_-_____
____.
______
______.___________

Stainless Type 410 is resistant

to mild atmospheres.
75

Stainless
Type
mospheres.

Corrosion Rote less than 0.002

212----

seldom found that will be free of all contaminants.


However, the majority of these contaminants have no inthat do generally

300---

The influence
of contaminants
is probably
the most important from a commercial
standpoint.
Corrosive
solutions
are

but the ones

433

TECHNOLOGY

This table shows the resistance of a number of materials to


the more common chemicals. Many factors influence the
resistance of materials lo various solutions. Factors which
must be given consideration
for service in corrosive environments are: temperature, concentration,
aeration, influence
fluence
quency

Alto ys

430

is

resistant

to

industrial

at-

to food processing

and

167

50---

Stainless
Type 304 is resistant
mild corrodents.

Stainless Type 316 is resistant to chemicals.

25

77

20

40

Percent Concentration

1ou

in Water

20Cb-3 stainless is resistant to severe corrodents.

Footnotes
1
2
3
4
5
6
7
a
9
10
11
12
13
14
15
16
17
16
19
20
21
22
23
24

for Corrosives

Toxic
Explosrve
Flammable
lhgestlon p&on
Inhalant poison
Attacks skm
lrntant
Vaoor harmful
lgmtes orgamcs
Fummg liquid
Hygroscoplc
Ltberates I-ICI in water
Narcotic
Volatrle
Hazardous under pressure
lgmtes combustrbles
Fire hazard
Exolosrve over 70%
lgnrtes m morst arr at 30C
Exothermrc m water
Dust explodes
Explosve dust
Exothermic with water

Footnotes for
Data Squares
1
2
3
4
5

No water
No arr. oxygen
Low arr. oxygen
Pits
Stress cracks

6
7
6
9
10
11
12
13
14
15
16
17
16
19
20
21
22
23
24
25
26
27
26
29
30
31
32
33
34
35
36
37
36
39
40

Stress corrosion
Drscolors
Crevrce attack
Intergranular attack
No chlorides
May discolor
May catalyze
May prl
May stress crack
Transgranular attack
Vapor
Aerated
Catalyzes
Static
Agitated
-7 pH
<7 pH
>7 pi-i
No HCI. H&O+ NaCl
No ferric chloride
-0.1% acetic acid
Also sludge
No iron salts
No sulfuric acid
Explosive
With HzSO4
With steam
No sulfur
No stress
No ammonia
300 psi
Stress relieved
No HCI. Cu. Ni ions
No Cu, Fe ions
Over 70% air

41
42
43
44
46
46
47
46
49
50
51
52
53
54
65
56
67
56
59
60
61
62
63
64
65
66
67
66
69
70
71
72
73
74

20-70% air, 530 psi


With sulfur, <340X=x
<IO mgil
No HzSOI
~60 psi
No sulfides
<20% zmc
Trace HCI
pH2t03.5
Annealed, immersed
>2.25% MO
Erratrc
With NaCl
With NaCI. HCI. Hz02
No Fe, Cl
With +-0.051% HaPOd or
HISOI
+SOz or HCOOH
<RC 22. 60.000
Annealed
No cold work
No HnS
Permeable to HZ
Unsulfaled
With or without
240 psi
Cold worked
X30% copper
>20% sulfuric, bat nitric acid
No MO; low C
Red fummg
Pits in chlorides
Over 400C
Steam and air
75-100% concentration

76
76
77
76
79
60
61
62
63
84
65
66
67
66
69
99
91
92
93
94

Low NaCl
Wrth HCI
<17% zmc
~0.23%. 200 psi
300 psi
No SO3
No NaCl
High pressure
75-120 psi
No sodium sulfite
+ammonia
Avoid hydroxides
Saturated
Not wood
No free acid
Passivated
<0.03% water
Attacks stress zones near weld
pH>12
>15 psig

:: :.oS??d pH
97 >200 ppm water
:g ;t3sp;hen wet

(continued)

434

Corrosion Resistant Materials Handbook

TABLE 4.11:

VARIOUS

STAINLESS

STEELS-CARPENTER

TECHNOLOGY

(continued)

Acetic
Acld
vapor

Acelic
AnhydrIde
In Acebc
Acid
4.7 9

Aluminum
Chloride

Ammonium
Carbonate

I I

I ,

I I

(continued)

Ferrous

TABLE 4.11:

VARIOUS

STAINLESS

STEELS-CARPENTER

TECHNOLOGY

Alloys

(contmued)

Formic
Acld

GCilllC
Acid

(continued)

Corrosion Resistant Materials Handbook

436

TABLE 4.11:

VARIOUS

STAINLESS

STEELS-CARPENTER

TECHNOLOGY

(continued)

iydrogen
Peroxide

iydrogen
Sulfide Dry
1.4
Lactic
Acid

(continued)

Ferrous Alloys
TABLE 4.11:

VARIOUS

STAINLESS

STEELS-CARPENTER

TECHNOLOGY

437

(continued

Phthalic
inhydride

I I I
Potassium
Carbonate

! ! ! I

Nitrous
Acids

Perchloric
Acid

Perchloroethylene

Phenol

(continued)

438

Corrosion Resistant Materials Handbook

TABLE 4.11:

VARIOUS

STAINLESS

STEELS-CARPENTER

TECHNOLOGY

(continued)

olassium
kmanganate
4. 10

eroxide

Dtassium
Sullate

Pyridme

#ichroma

P-u
e _._ _L
0

5
Sodium
Bisulfate

-7

El33
71

-t-.

Ferrous

TABLE 4.11:

VARIOUS

STAINLESS

STEELS-CARPENTER

TECHNOLOGY

1
c

T
L

T
ml

T
I

T
I

(contmucd)

A llo ys

439

440

Corrosion Resistant Materials Handbook

TABLE 4.12:

VARIOUS

STAINLESS

STEELS-CYCLOPS

UNILOY
Type 410:
hardenable martensitic stainless steel
UN I LOY Type 430:
nonhardenable
ferritic stainless steel
UN I LOY Type 304 and 316: austenitic stainless steel
CORROSION
MEDIA

Acetic

CONCENTRATION

Acid

Acetic Anhydride

II

IV

II

10%

Boiling

IV

II

60%

60

IV

III

60%

Boilmg

IV

Ill

II

100%

70

IV

III

100%

Boiling

IV

III

II

70

III

III

II

II

Boiling

IV

IV

IV

II

70

70

II

II

70

II

II

20%

70

II

II

II

20%

Boiling
-___

II

II

II

5%

70

IV

IV

IV

III

25%

70

IV

IV

IV

III

5%

70

IV

IV

IV

IV

10%

70

III

III

II

II

10%

Boiling

IV

IV

II

II

Methyl
--~_~~__

Chloride

Aluminum

Fluoride

Aluminum
Sulphate

Potassium
(Alum)

Aluminum

Sulphate

Carbonate
_

Ammonium

Chloride

Ammonium

Hydroxide

Ammonium

Nitrate

-__

IV

70

1%

70

II

II

5%

70

II

II

Boiling
___.

10%

--

IV
~___

IV

II

70
All concentrations

____

IV

70
-___

10%

Ammonia
Ammonium

70

IV

II
_
I

Ammonium

Perchlorate

Sulphate
_

Ammonium

70

II

II

II

II

10%

Boiling

IV

IV

II

II

10%

70

III

III

II

II

10%

Boiling

IV

IV

II

II

70

IV
-___

IV

III

II

70

II

II

II

II

70

III

II

II

II

70

III

III

70

II

II

II

70

Concentrated

Barium

Chloride

10%

Beer
Benzoic

Acid

10%

Blood
Boric

Acid

10%
Saturated

Buttermilk
I-Very

Good

II-Good

~-

10%

Sulphite

Aniline

-___
Ammonium

TYPE
316

304

70

Ethyl

Aluminum

TYPE

70

Acetylene

Acetate

TYPE
430

5% Aerated

90%

Aluminum

TYPE
410

10% Aerated

90% Anhydride

Alcohol

OP.

DATA

Ill-Fair

-.__

70

II

II

Boiling

III

III

II

70

IV-Poor

(continued)

Ferrous

TABLE 4.12:

VARIOUS

STAINLESS

MEDIA

STEELS-CYCLOPS

OF.

C ONCENTRATION
--

Hutyric

Acid

Calcium

Carbonate

Calcium

Chloride

Cane

Juice

~~ ~~___~~~

Carbolic

Acid

Carbon

Dioxide

Carbonic

Chromic

Citric

Copper

Chloride

(Cupric
Copper

(Cupric

III

III

II

II

III

III

II

II

10%

70

II

10%

70

II

III

II

II

Sugar Cane

70

II

II

C.P.

70

II

II

II

II

Sulphate)

Cottonseed

II

II

IV

IV

70

III

II

II

II

70

IV

IV

II

II

10%

70

II

II

II

II

10%

Boiling

IV

III

II

II

50%

70

III

II

II

II

50%

Boiling

IV

-T,- IV

IV

II

10%

70

IV

IV I IV

10%

70

II

II

.__

10%

70

II

10%

Boiling

III

70

70

IV

10%
Sulphate)

Acids

Ferric

Chloride

Ferric

Nitrate

Acid

II

II
+w

II

10%

70

IV

IV

IV

II

II

II

II

II

II

II

II

10%

70

50%

70

10%

70

II

50%

70

II

~.

II

II

II

II

II

II

II

II

70

II

--.--- III

70

IV

70

Ill

70

Dry

70

.__

40%
_

70

10%
50%
HIS

_._

.-__

Acid

All concentrations

70

IV

Hydrochloric

Acid

All concentrations

70

IV

II-Good

-;I_

Ill-Fair

IV

IV

~_

Hydrobromic

Good

I
I

70

Refined

I-Very

I
I

100%

Containing

Glue

I
I

100%
.__

IV

70

Sulphate

Formaldehyde

--

All concentrations

_ ._

(Gas)

___

Glycol

Fatty

Formic

II
IV

10% C.P.

Salt

Fluorine

II
IV

50% C.P.

Oil

(Magnesium

Ferric

70
70

Sulphate

Ethylene

70

Nitrate)

(Cupric

Epsom

TYPE
3t6

Chloride)

Nitrate

Copper

TYPE
304

70

All concentrations

Acid

TYPE
430

Bolllng

_~_

Acid

TVPE
4to

10%

(Dry)

Acid

(continued)

10%

Acid

Chlor:wetic

441

Alloys

---!

II

IV-Poor

(continued)

442

Corrosion Resistant Materials Handbook

TABLE 4.12:

VARIOUS

STAINLESS

MEDIA

Hydrogen
Lactic

STEELS-CYCLOPS

CONCENTRATION

Peroxide

Acid

(continued)

OF.

TYPE
430

TYPE
410

TYPE
304

10%

70

II

II

10%

70

IV

IV

II

TVPE
316

.._

II

Magnesium

Carbonate

10%

70

II

II

II

Magnesium

Chloride

10%

70

Ill

II

III

II

Magnesium

Sulphate

10%
10%
10%

70

IV

70

II

II

Boiling

IV

IV

70

II

II

Molasses
Nitric

Acid

Acid

Phosphoric

70

II

II

Boiling

I J

II

20%

70

II

II

20%

Boiling

IV

II

II

II

40%

70

II

II

40%

Bohg

IV

II

II

II

90%

70

IV

II

100%

70

IV

III

Boiling

IV

IV

IV

IV

70

IV

II

II

II

Picric

10%
Acid

-____

10% Aerated

70

II

II

II

10%

70

IV

IV

II

II

70

II

II

II

II

70

II

II

II

II

70

II

II

II

II

II

Air Free

All concentrations

Acid

II

10%
10%

100%
__~___
Oxalic

.__

Potassium

Bichromate

10%

Potassium

Chloride

10%

Potassium

Dichromate

10%

70

Potassium

Permanganat

10%
10%

70

II

II

Boiling

IV

IV

II

II

II

II

II

iooyr

Propane
Silver

.___

Nitrate

70

10%
10%

Boihng

Bisulphate

10%

70

Sodium

Hydroxide

10%

70

Sodium

Nitrite

10%

70

II

II

II

Sodium

Phosphate

10%

70
_~____

II

II

II

Sodium

Sulphate

10%

70

III

II

II

Tannic

Acid

10%

70

II

II

II

10%

Sodium
_~.

-___

I
I

--

II

70

II

II

II

Turpentine

70

Uric Acid

70

II

II

Tartaric

Acid

Vegetable

I -Very

Good

70

Oils

II-Good

Ill-Fair

IV-Poor

___

II
I

~~

Ferrous A llo ys

TABLE 4.12:

VARIOUS STAINLESS STEELS-CYCLOPS


UNILOY

TYPE

(continued)

410

NO.
c
;

COMPOSITION

430

*I5 =&
;d;o;~x*so

Si 1100 r&

Wt. per cent

P
s

443

*040m==*
.030 mar.

c .12 max
Cr 14.00/1i).00
Mn 1.00
Si 1.00
P
.040
S
*o3o

max.
max.
max
max

304
c .QImar.
cr iS.m/zo.m

Ni S.m/io.m
t4n 2.m 111.1.
Si 1.00 max.
P
.045 max.
5
.a30 111.

316
c

cr

.I mar.

16.w~w.m

Hi 11l.W~r4.m

Mn
Si
P
s
mo

2.m 1111,.
1.m mar.
.M5 mu.
.030 Ina.
2.m/3.m

UNILOY 13-8 Martensitic Stainless Steel


UNILOY 13-8, a precipitation hardening, martensitic stainless steel, has high strength, ductility and
toughness
in large cross sections in both longitudinal and transverse
directions.
TYPICAL

ANALYSIS

(in weight

percent)

Carbon . . . . . . . . . . . . . . . . . . . . . . 0.05 Max.


Manganese..
. . . . . . . . . . . . . . 0.10 Max.
Silicon.. . . . . . . . . . . . . . . . . . . . 0.10 Max.
Max.
Sulfur..
. . . . . . . . . . . . . . . . . . ...0.008
Phosphorus.. . . . . . . . . . . . . . . .O.OlO Max.
Chromium . . . . . . . . . . . . . . . . . . . . 12.25-13.25
Nickel . . . . . . . . . . . . . . . . . . . / . . . . 7.50- 8.50
Molybdenum.. . . . . . . . . . . . . . 2.00- 2.50
1.35
Aluminum.. . . . . . . . . . . . . . . . . . 0.90-

UNI LOY

15-5 Martensitic

UNILOY@ 15-5, a precipitation


hardening stainless
steel, offers a broad range of mechanical properties
for a variety of applications,
particularly
those
that require high transverse strength and toughness.
TYPICAL ANALYSIS (inweight percent)
Max.
Carbon . . . . . . . . . . . . . . . . . . . . . . . 0.07
Manganese..
. . . . . . . . . . . . . . . . . 1 .OO Max.
Silicon . . . . . . . . . . . . . . . . . . . . . . . . 1.00 Max.
Max.
Sulfur.. . . . . . . . . . . . . . . . . . . . . . . . 0.03
Phosphorus.. . . . . . . . . . . . . . . . . . 0.04 Max.
Chromium.. . . . . . . . . . . . . . . . . . . 14.00-15.50
Nickel . . . . . . . . . . . . . . . . . . . . . . . . 3.50-5.50
Copper.. . . . . . . . . . . . . . . . . . . . . . 2.50 - 4.50
Columbium plus Tantalum.. . . 0.15 - 0.45

UNI LOY

The general corrosion resistance


of Uniloy 13-8 is
superior
to the standard
martensitic
stainless
grades. Much like Uniloy@ 17-4 and Uniloy@ 15-5,
this alloys corrosion resistance
approaches
that
of Type 304 stainless steel. The general corrosion
resistance is greatest in the fully hardened condition
(H 950) and decreases slightly as the aging temperature increases.
Uniloy 13-8, the most resistant to stress corrosion cracking of any of the precipitation
hardening
stainless
steels, attains highest resistance
at the
higher aging temperatures.

Stainless Steel

Uniloy 15-5 exhibits lower corrosion


resistance
but higher stress-corrosion
cracking resistance.
When hardened at H 1025 condition and tested in
boiling 65% nitric acid, the corrosion rate is 0.127
inches per year (3.2 mm/year); in 1% hydrochloric
acid at 100F (38C) the rate is 0.083 inches per
year (2.1 mm/year);
exposure
in 5% salt fog at
95F (35C) for 10 days results in 0 to 5% rust.

17-4 Martensitic

UNILOY 17-4 is a unique stainless steel. It is martensitic and magnetic, capable of precipitation
or
age hardening to various levels of hardness and
strength. It is normally purchased in the annealed
condition and because of its great stability, it can
be machined very near finished dimensions prior
to heat treatment (900 to 1150).

Stainless Steel

Uniloy 17-4 has a high resistance to corrosion. It


stands up to corrosive attack better than any of
the hardenable stainless steels ( martensitic) and
is comparable to Type 304. It is used regularly in
such industries as chemical processing, dairy, petroleum, food processing, paper and marine.

YYPE ANALYSIS

Carbon ...............
Manganese. ...........
Silicon ...............
Sulphur. ..............

PhorphonJr.
...........
Chrome. ..............
Nickel ................
Columbium Plus Tantalum.
Capper ...............

..

0.07 Msx.
1.00 Max.
. . . . 1.00 Max.
. . . . 0.03 Max.
. . . . 0.04 Max.
. . . . 15.00-17.50
. 3.00- 5.00
. . . 0.15. 0.45
. . 3.00- 5.00
..

444

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

Stress Corrosion

STEELS

Cracking

AND

HIGH

NICKEL

Time to Failure,

hrs

Weight

Ref
Solution

Type 304
Type 316

8
48

MOLYBDENUM

Crevice Corrosion in Oxygen Saturated


Chloride Solutions, 90 C

of

Stainless Steels U Bends in Boiling 42% MgClz


Alloy

ALLOYS-CLIMAX

2
2

Loss, (mg/dm2/dayl

434

304

316

18Cr-2Mo

41.0

15.0

2.6

0.2

241 .O

11.8

3.5

0.8

200 ppm Cl-,


1 ppm Cu*

Type 430
Type 434

624 NF
1800 NF

2
3

18Cr-2Mo

1704

NF

260-l

MO

1200

NF

260-1

Mo-Ti

516 NF()

600 ppm Cl-,

l
Grwald,R.

F. TAPPI,

ZlCr-3Mo-Tic)

2000

NF

28Cr-4Mo

2400

NF()

8
Corrosion

()Specimen
()Nominal

was a stressed bolt


45% MgCl2

Solution

Steels

Exposure)

No Activation

Pitting of Stainless Steels in Oxygen-Saturated


Solutions-90

Rates for Stainless

(24-hour

NF = No Failure

N&l

Vol. 56, p. 129 (1973).

C During 30-Day Exposure

430

Weight Loss lmg/dm2/day)


434
304
316
18Cr.2Mo

3% N&l
(18.200 ppm Cl-)

46

0.4

0.1% NaCl
(609 ppm Cl-,
partial
immersionl

48

,o

1200 ppm Cl-,


400 ppm Cu *

SW

400

187

183

180 ppm Cl-,


60 ppm Cu *

40

6OOppmCI-.
1 ppm Cu*,
5ppmZn

4.7

600 ppm Cl-.


5 ppm Cu*

24.3

6OOppm Cl-.
20 ppm Cu *

* Steigerwald,

R. F. TAPPI,

Corrosive Medium

TUlIp.

20% Acetlc Acid


80% Acetic Acid
20% Citric Acid
30% Formic Acid
45% Formic Acid
20% Lactic Acid
40% Nitric Acid
1% Oxalic Acid
3% Oxalic Acid
10% Oxalic Acid
50% Phosphoric Acid
2% Sulfuric Acid
25% Sodium Hydroxide
35% Sodium Hydroxide
50% Sodium Hydroxide

Boiling
Boiling
Boiling
Boiling
Boiling
Boiling

Lizlovs,

E. A. Climax

communication
14

82.5

0.9

6.1

0.4

1.4

3.3

14
84.4

9.0

(1) Activebssive

Boiling
Boiling
Boiling
30 c
100 c
1ooc
100 c
Molybdenum

30
-

0.2
0.2
0.3
34
212
0.2
2.3
20
57(l)
2340
4.4
400
7.6
20
24

0.3
-

0.4
81

0.5
29

73
2.4
-

0.1
2.2
-

110
74
785
1.3
1 .l
2.2
3.0

57
47
7.5
0
1.9
1.6
2.7

Co. of Michigan,

personal

(1973).
behavior

Pitting

Corrosion

in 10%

- 6H2 O at Room Temperature*

FeC13

6.0

Corrosion Rate (mpy)


18Cr-2Mo
T316
T304

Alloy

Weight-loss

(mg/dm2/day)

Vol. 56, p. 129 (1973).


18Cr-ZMo-Ti

Bond,

1250

Type 304

485

Type 316

97

22Cr-2Mo

260-l

M&

26Cr-1 Mo-Ti

28Cr4Mo

A. P., Marshall,

Philadelphia,

J. 0.. Dundas, Ii. J. STP No. 425 ASTM,

p. 116 (1948).
(continued)

Ferrous

TABLE 4.13:

VARIOUS

STEELS AND HIGH NICKEL

STAINLESS

ALLOYS-CLIMAX

Crevice Corrosion in 10%

MOLYBDENUM

Ferralium

Alloy and Type 316 Stainless Steel*


Corrosion

Result

C
C
R
R

R
R

28Cr4Mo-2Ni
Titanium

20Cb3

lnconel 600
lnconel 625
Hastelloy
260-l

Alloy C

MO

28Cr4Mo

10% Acetoc Acid

Bollmg

0.1

Bolhng

3.1

Acid

10% Oxalic

Acid

M. A. Corrosion,

C = Crevice Corrosion

1N Sulfuric

Acid

Boiling
Room

3% NaCl
3% N&l+

20 ppm Cu-

*Ferralium

Alloy,

2600

46

640

25
0.4

Room

1 .o

0.4

Kokomo,

Data

Sheet,

Stellite

Division,

Indiana.

Stainless Steel*

M~terlal
Conditions

Application
Desaltmg

Crude

011

BOO-900

3RE60

Failed

ppm CI-

Type
c

P*rf0rlnalU*

304

5 years,

Falled by

no attack

RreSSCO~rOSlO
Air Cooler
Desulfurizauon

Pitting Potentials
C
V vs

6.5
235

Service Performance of an Austenitic-Ferritic

Pitting Potential,

0.4

0.2

Preliminary

Cabot Corporation,

R = Resists Crevice Corrosion

Alloy

Alloy

Boilung

Vol. 30, p. 77 (1974).

1M NaCI-25

(mpyl

Ferralium

39

Boilong

pH = 6.7, 75.195

* Streicher,

Rate

316

20% Formic

10% FeCll

Carpenter

Type

50 c

C
C

Type 316

Temperature

Solution

Room Temp.

Type 304

bntd)

Comparison of Corrosion Behavior of

FeC13 - 6H20

Alloy

445

Alloys

5 ppm Cl -, 1000 ppm


HIS, 10 ppm NH3

Type 316Ti
stresscorroslon

60.140

6 mo.

4 years.
no corrosion

wasteWater

5OOOppmH~S.15ppm

Type316

3.5 years

Treatment

Cl-

Falled by

no corrosion

SCE

pH=8.30-80

90 ppm mercaptan

stress-corrosion.
6 mo.

Tvpe 304

-0.030

Type 316

0.315

Type 216

NP

Armco

NP

22-13-5

Heat Exchanger,

3BO-409

Town

570 psi

Gas

Type 321

18 mo.,

stres*cOrro*lO

no attack

6-12 mo.

JS700

NP

Heat Exchanger

River water

Type

Alloy 6X

NP

Chemical

3M)-500

str,arscorroslon

Industry

ppm cl-

321

1 year,
no attack

6 mo.

* Lizlovs,

E. A. Climax

communication

Molybdenum

Co. of Michigan.
_

personal
Coolina

(1973).

Coils

Type 316T1

1 war

300-500

stresscorrosKl

no attack

ppm Cl -

6.12
l

Carlen, J. C.,

River water

NP = No Pitting
Helmer,

C. NACE

mo.

CORROSION173,

paper

No.

13.

Crevice Corrosion in 10% FeCIa - 6H20


Solution (pH=l)

Comparative Corrosion Rates for High Alloys*

at 25 C
Corrosion

Corrosion Rate
Material
Alloy 6X

0
0

Armco

50% H2S04
41.29/l

50.8

Type 316

207

Type 304

376

Solution

E. A. Climax

communication

MP35N

Alloy

Boiling

37

440

23

Bolling

14

190

20

Molybdenum

Alloy

625

Fe2(S04)3HZ0

Some crevice corrosion


Crevice corrosion

10% HzS04

Boiling

38

21

Severe crevice corrosion,

5% HCI

Soiling

610

120

790

Boiling

185

22

140

1.08%

some pitting

* Lizlovs,

IWWn#l

Tamperature

65% HN03

1.4

22-13-5

Type 216

Remarks

mgldmiday

JS-700

Rate Impvl

Hast~loy

HCI

Severe crevice corrosion,

10% Oxalic
10% FeC&

some pitting

+ 0.1 N HCI

Co. of Michigan,

personal

(1973).

[The tables above have been reprinted

* Bond,

A.

P. Climax

communication

from Materials

Performance,

Boiling
90 c

Acid
6H20

Vol.

Molybdenum

9.9
0

7.9

8.5
0

8.8
-

Co. of

Michigan,

Private

(1974)

September.]

(1970).

13, No. 9, pp. 9-16

(continued)

446

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

bntd)

symbols used in the following table to denote


type of test, aeration and agitation during test, specific details
of material samples tested and modes of corrosion.

KEY to special

Type of lest

L
Temperature

Aeration

Agitation

Type 304

field or pilot plant

I laboratory

test

: room temperature

B.P.

I boiling

sensitized

; slight to moderate

xx

: strong

low carbon grade (0.03%

none

slight

xx

rapid

Type

welded

Lower-case
Iv..ters
after corros+onrate frgures
refer
to observed
mode
of corrosion
where
the attach was
not uniform

to moderate

302 or Type 304 with


the standard maximum

Wrought
castings

carbon

Alloy

825

Note:

Test
conditions

slight pitting (maximum


incipient to 0.005 in.)

moderate
pitting (maximum
from 0.005 to 0.010 in.)

severe pitting
0.010 in.)

crevice attack
cell corrosion)

stress

Huntington

Alloy

Company,

material is Carpenter 20;


correspond to ACI CN-7M

Corrosion mediums

The compositions
the cooperating

remamder

99%.
water l%,
phosphates trace,

acldlty
pH 2.3

99%,

ethylene

oxide 1%

99%.

ethylene

oxide 0.85%

99.01%
0.07%.

as acetlc

methyl

ethylene
oxrde 1.92%
krotonaldehyde
0 0%

98%.

low boilers

2%

98%.

methyl

formate

2%

95%.

methyl

formate

3%.

85%.

low borlers

12%.

(secondary

methyl

acetic

acid

0.014%.

Rayon

142

414

Rayon

150

234

Chemical

150

609

Rayon

133

1645

0001

rlll

144

a37

ml

carbon

dloxlde

Chemrcal

150

147

rut

93%.
carbon dwde
6%,
dlmethyl
methyl formate 4%. butane 2%

<o

Chemical
(dlstlllatmni

actd 3%
ether

5%,

depth

of pits

of pits over

to concentration-

Division.The

International

Nickel

are those given by


total 100%.

Chemical

135

623

Chemical

140

805

Chemical

170

75

Rayon

142

1158

7PE

TWE

317

20

ALLOY
825

0 0001
<o

0001

<o

0001

nil

<0.0001

Chemical

2%

depth

cracking

316

nil

0.15%

acetate

of pits from

Average corrosion rates (spy)

formate

oxrdatron)

(tendency

of corrosion
media reported
companies
and do not always

lPE

water

(maximum

corrosion

Products

depth

Inc.

304
--P-P

98.97%.

C max)

cast

none

Over

20

Rates

Capital
letters
in
front of corrosionrate figures
refer
to condrtion
of the
material
tested

R.T.

Corrosion

test

0001

ml

<0.0001

<0.0001
fill

ml

0.0001
<0.0001

<0.0001

<0.0001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

Alto ys

MOLYBDENUM

447

hmtd)

Average corrosion rates (ipy)

TPE

304
P-PAcefaldshyda

mixtures

80%. acetic
rematnder

acid

acetate

8%.

lormlc

acid

0.3%.

20%.

acetlc

acid 5%

75%.

wyl

75%,
water

methyl
0.3%.

formate
l4%, methyl
acetlc acid 0.2%

70%,
0.5%

acetic

acid

14.5%,

water

15%,

701,
acetx
remamder

acid

14.3%,

lormlc

acid

70X,
acetlc
mamder

acid

8%.

low

acetate

boilers

water

220

357

xx

Rayon

239

664

-~

xx

Chemical

158

805

acid

Chemical

210.
215

xx

0.0001

water

Chemical

245

169

xx

0.0046a

0.0007

Chemical

220

100

WI

0 0001

Chemical

158

133

formic

3%.

water

re-

O 0006

<o

0001

70%. methyl
formate
10%. methyl
acetone 7%, wnyl acetate 5%

acetate

8%,

Chemical

190

610

nd

alcohols

and

Chemical

160

349

xx

IllI

246

higher

50%. acetic
remamder

acid

12%.

low

boders

3%.

water

Chemical

198

50%. acetlc
remamder

acid

10%.

low

bodets

3%,

water

Chemical

198

81

SO%, combmed
organxs
45% ketone.
methanol,
trlmethylene
oxide.
etcl,
sodurn
acetate
1000
ppm approximately.
formaldehyde
500 ppm approximately.
some resmous
matter,
water 5%

Chemical

195.
200

265

4.5%,
4.5%

acetaldol

40%,

water

42%.
water 30%.
IndIrect
acid 4%, acetic acid 0.5%
40%. acetone,
together
60%

methanol,

10.15%.

acidtty

water

and

boilers

Chemical

80

1025

23%.

formic

Chemical

216

510

ethyl

alcohol

Chemvzal

176

456

176

542

40%. combmed
orgamcs 40% k~cetone, methanol.
oxldes
etch. lormaldehyde
2000
ppm
approw
nlately
sodwm
acetate
1000 ppm approximately.
pii 5560

Chelnlcal

230

265

37%. acetone.
together
600

acetone.
methanol
lormaldehyde
2000

water,

and glycol
ppm max

methanol

36.92%.
water 62%. lormlc
ene oxtde 0.01%
PH 2.3

and

acid

high

Research

40%.
60,.

together

50.

ethyl

alcohol

Chemical

1.07%.

propyl.

Chemical

boders
methyl

Rayoll

35%.
water 40%.
acetic
acid 6%
low
5,
(methyl
formate
20.60%.
methanol,
acetate and acetone),
formic acid 1%

0.0002
ml

8%,

acetone.
methanol,
water 2%

methyl

84.5

<0.0001

70%. acetone
10%. methyl
formate
acetate 7X, vmyl acetate 5%

70%.
oxldes.

TIM

317

Chemical

10.5%.

0.3%,

TWL

316

<0.0001

<0.0001

<0.0001

rlll

rlll

<0.0001

<o 0001

xx

176

456

195

II6

--

xx

II7

335

xx

0 0002
rlll

IllI

llll

<0.0001

IllI

nd a

IllI

._ 0 0001

<0.0001

~-00001

\o

0 28

<0.0001

illI

xx

ALLOY
a25

<0.0001

ml

20

0001

0011

0000l1

0 0001

(continued)

448

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL ALLOYS-CLIMAX

Test
conditions

Corrosion mediums

TPE

TPS

304
--P-P

316

317

TIPE

Chemlcat

35%. water 38%. crotonaldehyde 24%. phos-Chemical


phoric acid, sodium phosphate and unidentified 3% :
30% approximately. water 67%, formic acid I Chemical
I ll%, methyl lormate and propylene oxide
:

225

183

xx

ml

nil

410

147

nil

nil

0.13

0.003

210

220

11.6

449

xx i

29.5%. water 45.4%, crotonaldehyde 21.9%. hexadlene aldehyde 1.3%, butyl butyrate <1.3%,
butyric acid <0.6%

i
:

Chemical

20%. acetone 22%. r.butanol 20%, ethanol 15%,


isopropanol 10%. water 6%, acetals 3%. acidity
0.5%. n-proponal 0.3%, carbonyls 0.2%

Chemical

jF

150.
230

508

xx

Chemical

140.
142

174

xx

Chemical

126.
140

508

xx

xx

245

756

20%. low boilers 3% (methyl


lormate. etc), water remainder

acetate,

methyl

5%. r-butanol 29%, ethanol 21.9%. isopropanol


17.1%. water 12.6%. carbonyls 4.1%. acetone
3 94%. methanol 3.7%, n.propanol 1.3%, acetals
1%. acidity 0.36%, formic and acetlc acids traces

:
i

100%

100.80%

! Chemical
j
i lsolvenlsl
:

100.80% lhalf Immersed)

Rayon

hntd)

Average corrosion rates (ipy)


r

35%. water 38%, crotonaldehyde and aldol 24%,


phosphoric acid, sodium phosphate

MOLYBDENUM

;F
F

B.P.

3.5

<0.0001

0.0013c

;
I

O.OOOla

0.0001

<0.0001

0.00016d
0.012

<0.0001

0.0048

<0.0001

Chemical
(solvents)

:F

BP.

3.5

100.80% (vapors)

Chemical
kolventsl

:F

B.P.

3.5

99.98%. water 0.017%

Chemical

224

71

0.0042

99.98%. water 0.017%

Chemical

224

71

x:

0.0024

99.9%, C.P. glacial acetic acid

Research

BP.

5.6

0.0009

99.9%. water <I%

Chemical

222

40

xx

0.0004

glacial acetlc acid

Research

BP.

0.027

glacial acetlc acid (column)

Chemical
~d~st~llat~onl

8.P

11

0.012
0.023

0.00084

glacial acetic acid

Research

BP.

CO.0064

CO.00036

glacial acetlc acid

Research

B.P.

0.0027

glactal acetlc acid (vapors)

Synthetic
Rubber

932

xx

99.7%

Research

249

261

xx

99.7%

Chemical

244

L0.0009

10.00075

99.7%

Chemical

293

LO.0556

0.270
10.0142

,_

0.0076

0.002

825

<0.0001

0.0001

<O.OOOla

ALLOY
20

<0.0001

0.00015
0.00018
<0.0001

0.0003

0.0003

0.0002

c0.0001

L IllI
III
0.032

(continued)

Ferrous

TABLE 4.13:

VARIOUS

STAINLESS

Test
conditions

Corrosion mediums

*ca*,c

*cd

99.5%

approximately

STEELS AND HlGH NICKEL ALLOYS-CLIMAX

Icolumn)

MOLYBDENUM

11PE

TYPE

IYPE

304

316

317

20

0 0005

Chemical
idlstdlation)

266

51

0 003

0 004

water

0 2%

Chemical

222

28

0.0009a

0 00046

99.43%,

water

0.03%

Chemical

222

23

0.0012

0.00021

RayOIl

235

266

xx

0.0004

0.0004

Chemical
Isolvents)

212.
249

a2

Chemical

244

625

Plastlc

73.
112

157

Chemical

128

51

0 0074

Chemical
(dlstdlatlon)

250

51

0 042

Chemical

240

216

LX

Chemical
(dlstdlatlon)

240

51

Chemical
Isolvents)

R.T.

13.8

75%

Research

B.P.

75%

Research

285

Research

340

75%

Research

355

75%

Research

395

70%

Research

B.P.

Rayon

212

377

50%

Jewelry

223

50%

Research

B.P.

0.25

50%

Research

B.P.

50%

Research

BP.

35%

Chemrzal

190

30%

Chemical

330

30%

Research

230

water

99%

Ivaporsl

1%

99.99%

99%.

water

2%

99%

bntd)

Average corrosion rates (ipy)

99.43%,

99%.

449

Alloys

xx
x

0.066c

0.0025

0 Ol8a

0.0003

ml

-;0.0001
.-!I 006

0.0004

0 0003

0 0001

00012

0 002

0.016

0001

0 008

0.055

0012

0 009

0 004

0.002
so 004

ALLOY
825

/
97%

approximately

(column)

95%

93%

approximately

90%.
commercially
storage tank)

pure

acetic

acld

(bottom

of

75%

67%,

kolumnl

water

33%

0 066

<0.0001
<0.0001

0.005

0.0001

0.033

c<0.0001

CO.006
co.001
CO.860
co.007

;xx

0.002

0.001

0.0015

0.0011
-

0.17

0.210
0.20

ml
co 0002

0.0004
0.0001

0.0001
ml

36.5
C<O.OOl

CO 0018

co.001

(continued)

450

Corrosion Resistant Materials Handbook

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

mediums

ALLOYS-CLIMAX

Average corrosion

--Acetic

hntd)

rates (ipy)

TYPE

TYPE

TYPE

304

316

317

ALLOY
--

20

825

acid

30%

Research

330

co.010

co.003

30%

Research

350

co.140

co.020

30%

Research

370

CO 160

co.210

20%

Chemical

213

LO.0018
s0.0001

LO.0035
s0.0002

10%

Chemical

B.P.

10%

Research

B.P.

15

10%

Research

B.P.

10%

Research

B.P.

10%

Research

B.P.

--.

232

51

Chemical

213

Chemical

224

25

10%

MOLYBDENUM

Chemical
fdlstillatlon)

fcolumnl

5%

ACET,C.AC,D
MlXTURES
ANHYDRIDE

.,..a

see

MMTURES

WITH
FORMlC
MIXTURES
WI

:
xx

nil

:
-

0.0699

0.0002

c0.0001

0.049
LO.053
0.0002
SO.00036

LO.0016

0.0003

0.004

LO.0009

ACETIC-ACID

ACID
and
ACETICACETIC
ACID

99.98%, water 0.017%, sulfur trioxide

trace

xx

0.0033

0.0013

0.0039a

0.0024a

0.0013

0.001

99.9X,
dichromate
water <O.l%

added

over one 24.hour

permd,

Chemical

222

18

99.9%, dlchromate
water <O.l%

added

over one 24.hour

period.

Chemical

222

13

xx

99.9%.

dichromate

and permanganate

Chemical

251

31

99.9%.

prop~oruc

acid and water

traces

Chem!cal

245

36

99.8%,

prop~oruc

acid aMwater

traces

Chemical

245

50

99.9%.

prop~on~c

actd and water

traces

Chemical

245

93

99.7%.

water

2%

manganese

acetate

0.1%

Chemical

253

29

(x

0.001

0.0026

0.0008

99.7%.

water

2%,

manganese

acetate

0.1%

Chenwal

248

40

xx

0 0008

0.0002

0.0007

n-butync

Chemical

255

21

xx

0.02%,

Chemical

216

106

xx

Pharmaceu
tlcal

234

42.5

xx

xx

99.7%.
prop+omc
acid.
acids traces (column)
99.6%.
water
some chromate
99.5%.
vapors1

waler

isobutyrk

03.0.4%.
added
0 45%.

added

and

acetaldehyde

sallcylates

0 05%

(column,

0.04%.

mineral

acid

trace,

no

Chemical

211

25

99.49%.
water
0.04%,
sullur trloxkde. chromate

mineral
added

acid

trace,

no

Chemical

215

71

99.49%.
water
sulfur trloxlde

xx

0.5a

0.02

0.06r

O.OOBr

0.004

0.03

0 025

:
0.082

0.0058

0 005*

0.03r

0.0005

0 0005

0.00032

0.0001

0.0041

0 003

0.0055b

0.001 la

0.0036b

0.0006a

00022

(continued)

451

Ferrous A /loys

TABLE

4.13:

Corrosion

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion
*
-

(amtd)

MOLYBDENUM

rates (ipy)

.
-

1VPE

,VPE

VVPE

304

3f6

317

20

ALLOY
825

Acetic-acid mixtures

0.0043b

0.00052a

xx

0.0038

0.0023

..

O.OW79a

0.00036

71

xx

0.0003

230

aa

..

0.00067

0.00043

215

25

xx

0.0038a

0.0023

O.WO41a

99.49%. water 0.04%. mineral acid trace, no


sulfur trioxlde

Chemical

: .

211

71

99.43%. water 0.04%. mineral acid trace

Chemical

215

25

99.43%. water 0.04%. mineral acid trace

Chemical

215

71

99.43%. water 0.04%.


mate added

mineral acid trace, chro.

chemical

220

99.43%. water 0.04%,


mate 35 lb/day

mineral acid trace, chro.

99.43%. water 0.04%,


trloxtde trace

mineral acid trace, sulfur

f
x

<0.0001

99%. high boilers 1.2%. water 0.05%

Chemical

:F

228

28

xx

0.0024a

99%, high boilers. 0.5%, water 0.5%, carbon deposit on all specimens, pressure 40 psig

Chemical

!F

311

171

0.0027d
L0.00108d

0.00108d

99%, acetic anhydride 1%. pressure 2 psig

Chemical

iF

250

638

0.00071

0.00062a

99%. heavy ends remainder

Chemical

;F

248

833

SS%, water I%, acetic anhydride trace

Rayon

:F

235

720

xx

0.0016

9499%,

high boilers l-2%, water 0.017%

Chemical

iF

228

23

0.00084

0.00053

9999%. high boilers 1.2%. water 0.017%. dichromate 35 lb/day

Chemical

235

00

0.0019a

0.00092

9C99%.

Chemical

:F

228

40

xx

0.0004

0.0002

Chemical

229

75

0.0007

0.0006

228

13

xx

0.0017

0.0026

0.0073b

0.0065b

high boilers 1-296. water <0.1X

99.99%, high boilers l-2%,


chromate 50 lb/day

water <O.l%,

di-

9&99X. high boilers l-2%,


chromate 100 lb/day

water <O.l%,

di-

0.04c

0.016a

9S%, acetic anhydride 2%

Chemical

250

638

99%, high boilers, water trace

Chemical

253

473

xx

99%. high boilers festers) 2%

Chemical

250

72

xx

0.0048a

O.W21a

99%. esters, high and low boilers, propionic acid


trace

Chemical

:F

240

72

xx

0.002a

0.002a

SE%, glycol diacetate 1.9%. water O.l%, dichromate trace

Chemical

252

43

xx

0.0001

o.WO4

99%. sahcylates 1.5%. water 0.5%


vapors)

Pharmaceu
tical
(evaporation)

265

O.OQl1

0.0009

0.002

0.0009

0.008

0.0006

fevaporator

99%. light ends, esters, etc together 2%

Chemical

235

73

~9.4%~ propionic acid 3.1%,


0.5%

Chemical

248

50

170
284

54

acetic anhydride

99%. propionic acid 3.1%, butyric acid 1%. nitric


acid 1%

Chemical

<0.0001

xx

0.017

xx
;
u

o.ooo2

0.0012

O.Wlla

o.OW2

0.0002

O.WOl

0.0024

.. .
o.w4

0.0004

0.0004

(continued)

452

Corrosion Resistant Materials Handbook

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

Average corrosion

TVPE

INDUSIRV

(PROCESS)

304
P-P-P

MOLYBDENUM

ALLOYS-CLIMAX

bntd)

rates (ipy)

TYPE

TVPL

316

317

20

ALLOY
625

Acetic-acid mixtures

95%, propionic acid 5%

Chemical

176.
284

125

xx i

0.05

0.004

0.001

95%. propionic acid 5%

Chemical

252

36

0.02r

0.002r

0.0016

95%, propionic acid 5%

Chemical

252

50

0.0025

0.002

95%, propionic acid 5%

Chemical

252

93

95.95% Ibottom of column1

: Chemical
; (distillation)

250

30

94%. acetic anhydride 6%

Chemical

265

638

Pharmaceutical

246

58

xxx;

91.96%, water 6.69%,


naphtha 0.5% (vapors)

salicylic

acid OS%,

91.60%, water 7.46%, salicylic acid (vapors)

Pharmaceutical

250

37

9t%, Propionic acid 6.596, acetic anhydride 1.5%,


water 1%

i Chemical

248

36

9C66%, salicylic acid 8.4% (nozzle between exit


of calandria and base section of still column)

f PharmaceuF
i tical

260

37

90%. propionic acid 10% (variable)

: f

275

137

90%, manganese acetate lo%, water 0.5%. man.


ganese dioxide 0.15%. permanganate added

j Rayon

259

96

90%. manganese acetate 1056, water 0.5X,


ganese dioxide 0.15%, permanganate added

man-

Rayon

I F

259

90%. manganese acetate 10%. water 0.5%, man.


ganese dioxide 0.15%, permanganate added

ftayon

;F

90%. manganese acetate 10%. water 0.5%, manganese dioxide 0.15%. permanganate added

Rayon

; f

90%, water remainder, high boilers trace

Chemical

;
.

67%. acetic anhydride 1396, pressure 4 psig


65%. acetaldehyde 2%, diacetyl 1%. glycol diacetate, oxygen trace
65%. acetaldehyde 2%, diacetyl I%,
acetate. oxygen trace

glycol di.

,.

:
;

0.033

...

0.006

x..:

0.01

xx

xx

0.002

0.0007

0.0005

0.021

0.014

0.005

0.005

0.009

0.0012

0.0011

0.001

,.

O.O65r

0.007r

0.001

xx

0.137

0.034

0.011

0.103

O.Ola

0.006r

C0.002a

xx ;

0.0004

0.0002

0.0003

75

xx

72

xx

0.0024

0.0016

0.0015

259

72

xx

o.OOO3
O.OOl

0.0002
0.0007

0.0004

300.
310

23

xx

0.0047

i
:f
: Chemical
: Chemical ; F

270

638

0.00073a

O.OOQ36

240

12

xxx;

0.0006

0.0002

i Chemical i

240

12

xx

0.0002

0.0004

Chemical

0.0006

0.0003

co.002

65%. acetaldehyde 2%. diacetyl 1%. glycol diacetate 1%. dichromate 0.1%. water remainder,
pH 1.4-1.6

i
f

Chamrcal

235

xx

0.0005

0.0011

65%. acetaldehyde 2% diacetyl l%, glycol di.


acetate 1%. dichromate 0.1%. water remainder,
pH 1.4-1.6

i
f

Chemical

235

xx

0.0033

o.Om3

65%. acetaldehyde 2%. glycol dlacetate I%, diacetyl l%, unknown reducmg agent trace (passlbly sulfur dioxide). waler remainder. pH 1.2

i
:
i

Chemical

240

35

xx

corr

0.312

0.117

65%, acetic anhydride 10%. water 5%. acetone,


acetonitrlle. ammes. etc (vapor line, column)

Chemical

239

875

xx

0.0036

0.0008

0.0007

,,,

.. .

0.0004

0.0003

(continued)

Ferrous Alloys
TABLE

4.13:

VARIOUS

STAINLESS

STEELS AND

HIGH NICKEL ALLOYS-CLIMAX

Test
conditions

Corrosion mediums

.
xx

194

35

75%. glycol diacetate 16%, water 9%, acetatdehyde 1.6%, diacetyl 0.8%. sodium sulfate and
acetate 0.6%. unknown reducing agent trace

300

15

xxx:

75%. glycol diacetate 16%. water 9%. acatafdehyde 1.6%. diacetyl O.E%, sodium sulfate and
acetate 0.6%, unknown reducing agent trace

300

12

xxx:

x !

74.68%. water 24.97%, naphtha l%, salicylic acid


0.27% (vapors)

Pharmaceutical
fdistillation)

226

57.5

x I

74.66%. water 24.97%. naphtha 1%. salicylic acid


0.27% (vapors)

Pharmaceu
tical
Idistillation)

226

45

x :

74.66%, water 24.97%, naphtha l%, salicylic acid


0.27% (vapors)

Pharmaceutical
fdistillationl

226

28

72%, glycol diacetate 16%, water 9%, diacetyl


0.8%, sodium acetate and sulfate 0.6%. unknown
reducing agent trace

Chemical

300

35

300

26

72%. glycol diacetate 16%. water 9%, acetaldehyde 1.6%. diacetyr I%, sodium acetate and
sulfate 0.6%

xx

xx :

67%, propionic acid 33%

Chemical

273

93

66X, water 30%, light ends 5%

Chemical

225

32

Chemical

.F

179

32

Metal
fcleaningl

110

61

217

381

xx j

Chemical

i F

25F
275

718

xx

carbon

Chemical

: F

356

300

xx i

sulfuric acid

Chemical

75

xx ;

; F

12:

jF

104

74

_:

X 1

water 1.6%, nitrogen

64%, nitric acid 25%. water 11%


60%. water 35%,
acid 1%

propionic acid 4%,

butyric

69%. acetic anhydride 40%

60%. hydrocarbons 18%.


monoxide 8%, water 5%
Sg-tO%.
0.25.4%

esters

acetic anhydride l-40%,

9%,

Rayon

57.5%. sulfuric acid 30.3%. water 12.3% (liquid


line1

Plastic

55.5%. water 43.48%, naphtha 1%. salicylic acid


0.016%

Pharmaceutical

219

57.5

55%. glycol diacetate 40%. sludge (manganese


acetate and resin) 4.g%, steam injection, water
0.1.0.2%

Chemical

310

97

51%. propionic acid 29.5%. acetic


11.5%, propiooic anhydride 7.5%

Chemical

275

97

anhydride

ALLOY
825

0.0013
0.0014

0.0003
0.0018

0.0003

o.OW2

0.0019

0.386

0.0358

..

xx

corr

0.016a

0.0002
s0.0003
10.0003

<O.OOOl
s0.0001

0.032

0.01

0.01

0.0004

0.0004

0.0004

0.128a

0.0528a

0.077

<O.OWl

0.W22a
0.007

0.0025
0.0004

0.0003

0.001

0.0009

0.009

0.004

<0.0001

<0.0001

...

<O.OOOl

<O.OWl

<0.0001

0.025

0.032

0.0005

<0.0001

1<0.0001

O.WOl

0.01

...

0.0001

0.0001

xx :

O.W35a

0.0002d

corr

x;

corr

.F

64.6%. nitric acid 33.2%,


tetroxide 0.6%

20

>0.105

Chemicpl

!
:

,PE

317

304
p-p--

Chemical

TYPE

316

1VPE

-..
(bottom of

bntd)

Average corrosion rates (ipy)

INDUSIRY
(PROCESS)

85%. water 5%. acetaldehyde 12%


oxidizer)

MOLYBDENUM

453

0.0016

0.0013

0.W5a

O.Wl7a

0.014r

...

o.ow2

nil

0.0017

...

(continued)

454

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

NICKEL

HIGH

Test
conditions

Corrosion mediums

51%.

hwd)

Average corrosion rates (ipy)

INDUSlIV
Acetic-acid

MOLYBDENUM

ALLOYS-CLIMAX

(PROCESS)

lYPE

TIPS

TYPE

304

316

317

0.01

0.007

p-p--

ALLOY
20

825

mixtures

propmnlc

acid

29.5%.
acetic
7.5%

anhydride

Chemical

275

co.007

11.5%, proptomc anhydride


50%.
lo%,

water 20%,
hydrocarbons

esters
5%

12%.

carbon

monoxide

Chemrcal

:F

356

258

xx

xx

0.002

0.001

50%.
lo%,

water 20%,
hydrocarbons

esters
8%

12%,

carbon

monoxide

Chemical

356

300

xx

YX

0.0004

0.0003

50%,

vinyl acetate

50%

Chemical

266

133

50%,

vmyl acetate

50%

Chemical

194

150

:F

water
25%,
ethyl acetate
7%,
various
ketones and alcohols together?%,
methyl
acetate 5%.
methylethyl
ketone 4%, acetone 2%

i
:
i

Chemical

131

360

50%.

Chemical

125

108

I
:
i

Chemical
ffractionation)

228

140

220

609

50%.
esters,

water

25%,

carbonyls

50%, acetic anhydride


and ethyhdene acetate

45%, vinyl acetate


tic anhydrrde 2%,
45%.

high boilers

and esters

25%

50%. some peracetic


(column, liquid header)

acid

40%, acetaldehyde
12%, aceChemical
light ends I%,
acetone trace :
55%

40%.
butane 20%,
acid 6%,
pentane

ethyl acetate
8%, propionic
5%, methylethyl
ketone 5%,

0.002

0.001

0.0003
0.0005

0.0002

<0.0001

x-

nil
xx

<0.0001

nil
0.0005

nil

nil

Chemical

310

300

I
j

Chemical

356

220

Chemrcal

347

216

xx

Chemrcal

347

216

xx

0014

0.0013

194

150

0.06

0.0015

212

52

xx

0.0004a

0.0002a

0.0624~

0.0071h
so.oo92c

xx

0.03

II

<0.0001

0.0016

0.0057

0.007

..

other esters and ketones


40%.
butane 20%.
ethyl acetate
8%, propmnic
acid 6%,
pentane 5%, methylethyl
ketone 5%.
other esters and ketones
40%.
butane 20%.
ethyl acetate
8%, propiomc
aud 6%.
pentane 5%. methylethyl
ketone 5%,
other esters and ketones together 16%

0.003

0 002

ace.

Chemical

16 days,
during 36

:
:

Chemical

Chenucal

345

108

35%, r..-butyl
acetate 40%,
Serbutanol
7%, .-propanol
uene sulfonic acid 0.25%

n-propyl acetate 8%.


Chemical
7%, water 3%. tol- :

235.
245

75

35%. r.c-butyl acetate 40%,


r.c-butanol
7%.
.-propanol
uene sulfonic acid 0.25%

n-propyl acetate
7%, water 3%,

Chemical

235.
245

92

I Chemical

110

129

<0.0001

<O.OOOl

<0.0001

100

129

<0.0001

<0.0001

<0.0001

xx

0.051

0.0009

0.1735c

0.0512~

40%. vmyl acetate


tic anhydride
40%,
water
days

ethyl
95%

40%,
water

butane
5%

40%,

propionate
and mixed

25%.

acetaldehyde

3%.

30X,

acetaldehyde

0.5%,

30%.

light ends 20%,

15%,

60%
during
alcohols
5%

esters

30%,

30%.
r.c-butyl
n.propyl acetate
toluene sulfonic

acetaldehyde

15%.

15%,

water

8%,
tol-

remainder

water

water

carbonyls

remainder

remainder

acetate
42%.
.-propanol
18%,
9%, se<-butanol 7%. water 4%.
and sulfuric acid traces

.F

Chemical

Chemical

185

321

Chemrcal

230

52

-F

xx

0.0912c
0.0519c

0.0207

0 0092

0.0312~
0.0083c

0.0152~
0.0067a

0.002

0.0002

(continued)

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test

Corrosion mediums

ALLOYS-CLIMAX

Average corrosion

conditions

,YPE
tNoSra
(PROCESS)

kontd)

rates (ipy)

WPE

TlPE

316

317

Chemical

280

28

0.025

0.00043

Chemical

280

12

x:

0.0031a

0.00025

Acetic-acid

304
p--p-

MOLYBDENUM

455

20

ALLOY
625

mixtures

27%. high boilers 70%. water 3%, sulfuric acid


used in hydrolysis, &chromate 28 lb/&y and soda
12 lb/day added

27%. high boilers 70%, water 3%, phosphoric


acid used in hydrolysis. no dichromate or soda
added
25X, organic esters 75%

Chemical

68.
la5

15

24% approrimatrly tcolumnl

Chemical
hi~stillationl

231

51

95

115

212

57.5

320

42

171.
208

24%. water 74%. lormaldehyde trace


23.44%. water 75.56%. naphtha 1%. salicylic acid
0.01 I % (column. vapors)

i Pastic
j Pharmaceu: tIcal

20%. glycol dracetate 78%. sodium sulfate and


acetate 1.2%. sohds trace, drchromate trace

Chernlcal

: f

20%. water 78%. benzene 2%

Chemrcal

:
:

20%. water 30%. acelaldehyde remainder

Chenucal

9.7%. high boilers 89.8%. water 0.5%

i Chemical

5%, sulfuric acid 1%

: Pulpand
i Paper

5X, butyric acid

<0.0001
-

corr

x-

<O.owI

nil
0.0027
<0.0001

0.0027
<0.0001

0.042

0 0007

0.0012

xx

0.0477c

0.007a

0.006a

214

0.0008

210

112

0.0026

335

72

70.
250

20

xx
<O.OOOla
<O.OOOla

(0.0001

0.0002

...

0.0007

0.0002

0.016

0.0032

<0.0001

0.004

0.0017

0.001

Chemical

:
:

239.
284

54

4%. butane 56%. other organics 27%. nitrogen i Chemical


lo%, water 2%, carbon dioxide 1%
.(

356

220

xx

0.001

0.0006

.. .

4%, butane 56%. other organics 27%. nitrogen


lo%, water 2%, carbon dioxide 1%

Chemical

347

220

xx

0.0007c

0.0004c

...

...

;e:S.j.75%,

(vapors and conden-

Chemical

F
j

208.
220

132

._

0.0001

O.OQOl

0.0001

0.0001

2.2%. methyl acetate 60%. water 18%. acetaldehyde 5%. methyl acetate 4-5%, methanol 4%, acetone 2.5%, ethyl acetate 1.5%

Chemical
(distillation,

223

45

xx

0.031

0.0077

0.01

furfural 0.5-l%

0.001

0.0001

: secondary
oxidation)

2.1%, ethylrdene diacetate 25.50%, acetic acid


2.4%. vinyl acetate 1.2%. toluene sulfonic acid
0.2%

Chemical

f <300

14

1%. water 98%, carbonyls 1%

Chemical

212

29

1%. water 98.4%, sulfuric acid 0.8%

!
;

Chemical
(distillation1

224

87

99.9%, water <O.l%,


acetaldehyde 0.02%, for.
mic acid <0.01X,
dichromate added over one
24.hour period

_ Chenucal
:

216

18.3

99.9%. water <O.l%,


acetaldehyde 0.02%,
mic acid <O.Ol%, no dichromate added

Chermcal

216

40

for-

xx

0.0003

xx

0.0001

0.0002

xx

0.0132

xx

0.0033a
L0.0027a

xx

0.0005

0.0003

.. .
0.0032

O.OOlla

0.0021b

0.0004

0.0003

0.0041

0.0002

(continued)

456

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX


Test
conditigns

Corrosion mediums

7PE

lormrc acid <O.Ol%

Chemical

248

296

TPE

TYPE

316

317

0.0007

0.0003

ALLOY
625

20

99.9%. formic acid <O.Ol%

Chemical

: F

216

15

0.0035a

0.0021a

0.0027a

S9.S7%, formic acid trace

Rayon

;F

244

243

xx

0.00023
0.00019

0.00017
0.00015

o.OQO34

99.9%, waler 1.6%, permanganate 0.3%, formic


acid 0.3%

Chemical

248

40

xx

0.0018

; F

255

75

xx

0.0025

Chemical

266

56

Chemical
tdistdlatron.
secondary
oxidation)

248

152

244

244

Chemical
tfractionation.
secondary
oxidatron)

Chemical
(evaporatlonl

272

20

99.6X, formrc acid <O.Ol%

Chemrcal

j F

216

23

99.6%, acetaldehyde 0.02%, formic acid <O.Ol%,


dichromate added 40 lb/day

Chemical

: F

216

29

xx

0.00076a

0.00015a

99.6%, glycol dracetate O.l%, water <O.l%.


formic acid. high boders and aldehydes remainder

Chemrcal

290

436

xx

0.0015

0.0015

99%. lormic acid 0.5%. waler 0.5%

Chemical

255

116

0.0017

99%. water 0.6%, formic acid 0.2%, formaldehyde 0.1%. propionic acid 0.1%

Rayon

250

253

99.7X, propiomc acid 04%, lormic acid 0.3%,


high boders. manganese dioxide, butyric acid trace

Rayon

243

91.5%. water O.l%,


boders remainder

Chemical

99.2%. propionic acid 0.6%, water 0.4%, high


boilers 0.3%. lormic acld 0.2%. butvric acid
0.1 sb. some manganese droxide

Rayon

98%. formic acid 0.2%, remainder unknown

99.8X, formic acid 0.02%,


no water

permanganate trace. i Rayon

99.9-9096, formic and propionic acids in Water,


areotropic solution

99.736, formic acid 0.02%, permanganate 0.03%

99.7%.
<O.Ol%

permanganate

<0.02%.

99.6%, formic acid 0.3%.


circulahon evaporator)

formic

water 0.1%

(natural

formic acid 0.01%.

99%, proplonic acid 1%. water 0.7%,


acid 0.2%. formaldehyde 0.1%

acid

high

formic

bntd)

Average corrosion rates (ipy)

304
p--p99.9%.

MOLYBDENUM

0.0016

0.0028

xx

0.0355

0.0124

0.005

0.0004
10.0004

0.0005

0.0011

0.001

0.0001

0.0001

0.0011

ml

0.0058

0.03b

0.0023

xx

0.028

0.013

243

xx

0.011
0.0046

0.00043
0.00031

275

75

xx

0 0027
10.0022

248

243

xx

0.0024
0.0021

Chemical

212.
252

Rayon

257

253

255

262

<0.0001
<0.0001

xx
-

xx

W-96.5%, formic acid 1.5%, waler l-1.5%

Rayon

97%. water 1%. formic acrd 2%

Chemical

240.
284

291

xx

97%. water 1%. formic acid 2%

Chemtcal

226

54

xx

0.07

0.0019

0.0022

0.0044

0.0046

0.0002

0.002
0.0018

<0.0001
0.0002

0.0004
0.0001

0.006

0.015
0.0053c

0.0017

0.0003
0.0023

0.01

0.006

0.0028

0.0021

0.0002

(continued)

457

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TYPE

wth

formic

bontd)

Average corrosion rates (ipy)

304
--P-P
@,cet~c~~wJ mmture*

MOLYBDENUM

TIPE

1IPE

316

317

"20"

ALLOY
825

aad

346

692

0.0021

0.0026

Rayon

225

362

xx

0.0069

0.0004

0.0006

97%. lormrc acid 1%. heavy esters 0.5%. water


0.2%. methylethyl ketone. elhyl acetate and hen-

Rayon

246

382

xx

0.0035

0.0025

0.0015

97%. waler 0.7%.


hyde 0. I Sh

Rayon

262

253

xx

Rayon

342

76

-.

xx

j F

250

337

:F

336

315

xx :

239

243

xx

: F

235

266

97%. lormrc acid 1.5%. water 1.5%

Chemrcal

97%. lormic acid 1.3%. propionic acid


heavy esters 0.5%. water 0.2%

I%,

me traces

formic acrd 0.2%.

lormalde.

9796%. water 3%. lormrc acid 0.5%


965X,

formrc acid 1.5%. esters l%,carbonyls 1%

Chemical

96%, formic acid 1.5%

I Rayon

96%, water 4%, formic acid trace, propionic acid


trace, permanganate injected at tray

95.4%. water
acid 0.1%

15%.

formic acid 0.69%, propionic

Rayon

Chemrcal

230.
291

formic acid 1%. high boilers

Rayon

;f

311

567

95%. water, lormrc acid trace, high boilers re.


mainder

Chemical

290

43

94%. water 3.4%,


acrd trace

Rayon

226

243

94%. high boilers 5%. formic acid 1%

Rayon

257

465

91.5%. water 6%, formic acid 2.5%

_Chemrcal

230

54

90.1%, water 6%, formic acid 1.75%

Rayon

: F

235

SO%, acetaldehyde 7%. water 3%, formic acid 1%

Chemical

90%. water 8%. ethyl acetate 0.5%. unsaturates


0.5%. methylethyl ketone 0.4%. propionic acid,
formic acrd trace, biacetyl trace

Rayon

; f

95%. formic acid 1.5.3%.


remainder unknown
95%, water 4%,
trace

permanganate 0.5%.

formic acid 2.3%.

propionic

Chemrcal

69%. acetaldehyde 7%, water 3%. formic acid 1%

x ;

0.03

0.0001

0 055

0.005

0.04

0.009

0.006

0.016
0.003

0.008
0.0029

0.013
0.0015

0.0001

0.0001

0.0098

0.0002

xx ;

0.0027

xx

0.0025
0.0032
0.012

0.0024

O.OQ58

0.0015

0.0019
0.0089

0.0001

<O.OOOl

xx

0.00049

<0.0001

xx

0.003
0.006

0.001
0.001

0.0007
0.0015

xx

0.0028

0.0005

0.0031

266

xx ;

0.0002

0.0001

211

511

xx

<O.OOOld

<O.OOOld

225

243

xx

250

511

248

382

xx

0.031

0.0001

0.0025

0.0004

.. .

0.0009
0.00078

0.00051
0.00031

Rayon

66.1%. water 10%. ethyl acetate 0.5%. unsaturates 0.5%. methylethyl ketone 0.5%, biacetyls
0.196, formic acid trace, propionic acid trace

I
:
i

Rayon

IF

221

243

xx

67%, acetaldehyde 7%, formic acid 1X, low and


hrgh boders. water remainder

Rayon

:F

252

756

xx

0.0027d

96.565%.
butyric and propionic acids together
9%, formic acid 3%. water 15.3%. pressure 3

!
:

Chemrcal

: F

244

166

0.0068~

<0.0001

10.0026

0.006cd

99%. lormrc acid 1%. propionic and butyric acids

0.011

xx i

<O.OOOld

0.00074

<O.OOOl
.
0.00051

<0.0001

0.001

wig
(continued)

458

Corrosion Resistant Materials Handbook

TABLE

4.13:

Corrosion

VARIOUS

STAINLESS

STEELS

AND

W,,h

ALLOYS-CLIMAX

Average corrosion

E =p

INOUSlRV

mlXfreS

NICKEL

Test
conditions

mediums

ACettC-aCId

HIGH

(PROCESS)
.

----

MOLYBDENUM

rates (ipy)

,PE

1TPE

TYPE

304

316

317

8%, low boilers 2%. formic


boilers O.l%,
water remainder

i
:

Chemical

260

0.0004

85%.
acetaldehyde
acid 0 75%,
high

8%. low boilers 2%. formic


boilers 0.1%.
water remamder

i
i

Chemtcal

235

0.0003

0.0002

85%,acetaldehyde

8%. low boders 2%, formic


hollers 0.1%.
water remainder

Chemical

250

0.0011

0.0006

high

85%.
acetaldehyde
acid 0.759b,
high

8%. low boders 2%. formic


boilers O.l%,
water remainder

! Chemical
1

545

300

ml

acetate

Rayon

221

756

xx

0.00011
0 00013

1.96%.

Chemical

240

I35

xx

Chemtcal

245

558

Chemical

230

113

0.75%.

85%, acetaldehyde
7% water 5%.
and formate 2%
formic acid 0.5%
71.28%,
acetaldehyde
water and low boilers

formic

methyl

7.37%,
formic
remamder

65%.
acetaldehyde
15%
hollers 196, water remainder
65.60%.

formic

acid 2-2.5S;,

acid

acid

water

3%.

low

remamder

0 0001

0 0001

0.0004a
L0.0046a

0 004a

xx

0.0085

0 0001

0.0018

o.opo3

235

179

1.5%,

low

Chemical

235

300

xx

acetaldehyde
20%. water 12%. methyl
and acetate 6%. formic acid 2%

for-

Rayon

221

756

xx

Chemical

221

315

Rayon

226

536

xx

Chemrcal

220.
240

57

xx

Chemical

217

511

x-

55.50%,
formic acid 0.5%,
esters, ketones. altohols. aidehydes. butane, pentane. nitrogen, carbon
monoxide and carbon dioxide remainder

Rayon

365.
383

359

55.50%.
formic acid 0.5%.
esters, ketones, alcw
hols, aldehydes, butane, pentane. nitrogen, carbon
monoxide and carbon dioxide remainder

Rayon

356.
378

360

221

452

525

62%.
acetaldehyde
18%, formic
boilers and water remamder

60%.
60%.

i%.

water

formic
water

60-509/o,
direct

formic

acid

water 35%. propionic


butyric acid 1%

60.55%.
0.5%.

38%,

2%

acid 4%,

l-1.6%.

formic

methyl

acid

acetate

iF

remainder

water

acidity

acid

acid

25.30%.
3.4%,

acetaldehyde

formic

10.1596,

in-

12

acid

>o

xx

Chemrcal

18%.
formic
remamder

<0.0001

0 0009

low

60%.
mate

625

0 0001

0.0268

3%

62%.
acetaldehyde
bollers I%, water

ALLOY
20

formic acvd

85%,
acetaldehyde
acid 0.75%.
high

acid

(mntdb

<O.OOl

<o

0 0001

0018
0.002

001

0.008

0.004

0.0007

0.0005

0.085
LO.076

0.0003

_,

C0.05b

<0.0001

acid 3%

50.9%.
water 43.2%.
propionic acid 1.7%,
acid 1.7%, butyrlc acid 0.5%, high boilers
50%.
water 28%. ethyl acetate
ketone 4%. propiomc acid 3%,
methyl ketone l%, acetaldehyde
mate 1%. formic acid 0.5%

formic

4%. methylethyl
alcohols 3%. di196, methyl for-

50.30%.
formic acid 2.10%.
methyl
acetaldehyde.
methyl acetate,
ethyl
tone. methanol,
water remainder

formate
acetate,

5%,
ace-

Chemical

!
:
f

Rayon

208

Chemical

223

99

0.006

0.0008

xx

O.Olc

0.0035

xx
-

xx

0.009
LO.0108
<0.0001

<0.0001

0 0089

0.015

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

-..
mlxtre*

NICKEL

ALLOYS-CLIMAX

water 24%.

acetaldehyde 8%, formic acid 2%

40%, formic acid 1.5.2%. acetaldehyde


boilers trace, water remainder

l%,

low

40%, formic acid l-1.3%, water remainder

INDUSTRY
(PROCESS)

200

380

TlPE

TIPS

1lPE

304

316

317

: Chemical

230

511

Chemical

;f

110

81

xx

! Chemrcal

; F

242

277

Chemical

: F

256

247

xx

0.0003
10.0008

0.0009

<O.OOOl

xx
XX

40%. butane 20%. esters and ketones 16%, ethyl


acetate 8%, pentane 5%, methylethyl ketone 5%,
formic acid 0.5%

1Rayon
:

: F

338.
374

358

40%. butane 20%. esters and ketones 16%, ethyl


acetate 8%. pentane 5%, methylethyl ketone 5%,
formic acid 0.5%

Rayon

338.
374

359

xx

40.35X, formic acid 5.2%

Chemical

230

131

Chemrcal

220

112

: F

220

106

xx

40.30%. formic acid 4.1096, methyl acetate 0.5.


196, water remainder

40.30%. formic acid 1.1.5%

: Chemrcal
: fdrstrllation
I secondary
: oxidation)

35%. acetaldehyde 3%, formic acid 1%

; Chemical

100

81

35%. formic acid 0.9.1.2%, water remainder

Chemical

256

300

35%. formic acrd 0.9.1.2%. water remamder

Chemical

256

35%. formic acid 0.9.1.2%. water remainder

Chemical

:F

0.023~

xx

<0.0001
0.031

0.011

0.006

0.002

0.018

0.0006

0.019

0.0001

xx

0.0001

0.0007

256

81

xx

0.0079c

0.0038a

262

433

0.026

0 0058

255

511

0.003d

0.002
0.0001

270

246

xx

0.0001

33%, formic acid 1.5%, water

Chemical

270

246

xx

O.OOOld

30%, formic acid 8%, water remainder

Chemical
Uractiona-

70%.

formic

acid

1%.

water

proptonic

0.0002

150

l%,

0.013

0.0023

_Chemical

acetaldehyde

0.0006

0.0089

33%. formrc acid 1.5%. water

30%, formic acid 1.2.1.6%. water remainder

nil

xx

Chemical

5%, formrc acid 4%. water

0.0088b

water remainder

0.0001

<O.OLlol

33%. formic acid 66%, water

28%. water
acid 1%

ALLOY
825

<0.0001

xx

Rayon

30%. formic acrd l%,


remainder

20

0.0001

0.0046

formic acrd 0.&1.5%,

30%. acetaldehyde
remainder

bntd)

Average corrosion rates (iPY)

Chemical

40X, formrc acid 0.9.1.2%, water remainder

35.25%,

MOLYBDENUM

formic acid

wttl

45%, high and low boilers 29.5%.


formic acid 1.5%
40%, water50%,

HIGH

Test
conditions

Corrosion mediums

Acetcacld

AND

459

A llo ys

<0.0001

c0.0001

275

112

0.0045

0.0018

I tron.
1 secondary
: oxidation)
j Chemical

245

300

0.0001

0.0001

Chemtcal

265

172

xx

0.0202c

0.0065b

Chemtcal

72

511

Rayon

208

382

xx

<O.oOOl

0.003

<0.0001

<O.OOOl

(continued)

460

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

2536,

formrc

acid

4%,

low

boilers

1%.

25%.

formic

acrd

IS%,

low

boilers

1%.

220

117

Chemrcal
tdrstrllatron.
secondary
oxidation)

220

129

Chemical

220

Chemrcal

Chemical

Chemical

water

25%. formic
remamder

acid

1.5%.

25%.

water

73 5%,

21%,

water

78%,

18%.

water

II%,

water

81%,

low

tormrc

acrd

formrc

water

1%

acid

formic

1%.

1.5%

acid

formrc

82%.

boders

l%,

acid

pressure

1 psig

1%

:
remainder

INDUSTRY
,PRUCESS,

Chemical
(drstillation,
secondary
oxidation)

water

remainder

TIPE

1VPE

304
P-P-

316

317

>0.059

0 0033

0.002

0.001

0 0003

0093

xx

129

xx

0 0093

0001

0 002

212

315

0 008c

0.002

0001

239

229

0.026

0.012

: f

208

167

0.0145

0.0076

Chenucal

210

436

0.0018
10.0007

0.0007

xx

O.lc

32%,

low boilers

Chemrcal

235

213

xx

0.018

0.01

18%, ethyl acetate 35%. benzene 32%,


9.5%. formic acid 0.39%. water 1.5%

low borlers

: Chemrcal

194

696

xx

0.0099

0.0024

methyl
acetate
water remainder

Chemical

265

169

xx

0.0001

0.0001

18%, ethyl acetate 35%,


9.5%, formic acid 6.7%

1512%.
<0.2%,

formrc
methyl

benzene

acid 0.3.0.4%.
formate
<O 2%,

12%.

formic

acid

E-4%,

water

remainder

Chermcal

250

355

0.014

0.0023

12X,

formrc

acid

M-3%.

water

remainder

Chewal

246

355

0.0006

0.0001

12%,

formic

acid 0.5%.

Chemical

280

169

xx

0.014

0.0001

12X,

formrc

acrd 0.4%.

Chemical

280

169

xx

0.0001

217

382

240

227

water

remainder

water

remamder

10%. ethyl acetate 36%, methylethyl


ketone 27%.
benzene
18%. water 6%. propionate
esters 2%.
lormrc acid 0.5%, propIonic
aud 0 5%

Rayon

8%. water 87%. methanol


methyl acetate, acetone

Chemical

4%,

formic

acrd

I%,

xx

0.034
0.006

0.02c

xx

7.2%.
0.3X,

i Rayon

158

585

xx

0.0003

00001

7%.
waler
65%.
methanol
7%.
acetone
methyl acetate 3%. ethanol 2%. acelaldehyde
tormrc aud 0.5%

7%.
2%.

Rayon

191

706

xx

0.005c

0 0007

208

511

257

756

7.5%.

water

91%.

Indirect

6%.
low
remamder

boders

8%. methyl acetate


mic acid 0 5-O 75%,
8%. methyl acetate
mic acid 0.5.0.75%,

acidrty

1596,

formic

Chemical

I%,

water

Rayon

20

ALLOY
825

0.0001

0.009
0.0001

0.0001

7.5%,
water
65%. methanol
8%. esters
acetaldehyde
2%. ethanol
l%, formrc acrd
propronrc acid 0.2%

acid 1%. acetaldehyde

(-ntd)

Average corrosion rates (iPY)

TlPE
-,.

MOLYBDENUM

<o

0001

0 006b

<0.0001

0.5%
2%,

formic

acid

6%, methyl formate


water remamder
6%.
water

methyl formate
remainder

xx

0.00029d

0.0002ld

0.00014
0.00013
0.0021

1%.

for-

Chemical

250

95

xx

0.0061a

l%,

for-

Chemical

230.
240

95

xx

0.002a
~0 OOOla

0.0034a

(continued)

461

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL ALLOYS-CLIMAX

TIPI

304
--P
mixtures

wth

formic

TWE

7PE

316

317

1%.

for-

Chemical

175

179

xx

<o 0001

6.4%. methyl acetate 6% methyl formate


mic acid 0.5-0.7596,
water remamder

l%,

for-

Chemical

150

81

<o 0001

<o 0001

4%. formic

acid 0 25%.

water

remainder

Chemical

222

63

xx

0.0002

0.0004

4%. formtc

acid 0 25%, water

remamder

Chemical

217

417

0.0013

0.00012

4%,

acid 0.25%,

vapor

Chemwl

222

63

xx

0.0002

0 0004

Chemical

210.

63

xx

216

436

formic

water

4%. methyl acetate 7%


0 25%
water remamder
0.5%.
3.5%

acetaldehyde

0.4%.

formx

methanol

35%.

3%.

formic

acid

water

formic

acid

remamdel

230

40

xx

ml

0 0107

230

1025

dlchlorlde,

water

Pulp and
Paper

161

31

butyrlc

Petrochemical

650

63

of acetlc,
hydrogen.

Chemical

R.T.
212

75

xx

xx

Chemical

205

880

xx

xx

Textde

212

35

xx

Textde

210

10

xx

100%

Chemical

277

571

100%

Rayon

273

287

xx

Chemical

283

suds,

solvent

ethylene

mostly
suds

acetic

orgamc
formic.
carbon

acids effluent
cor;!ammg
butyrlc,
propiomc
suds.
dmxlde and ash

acetlc
formic

acid, ethanol,
acid trace

acetlc

and formic

acetlc

acid, toluene

ACETIC

acetlc

formic,

propionic

ethyl

acids,

and

vapors
steam,

acetate,

acetaldehyde,

water

2 g/l,

formic

acid

0 0021d
L0.0037d

Chemical

Chemical

acid.

ml

0.006
0.0015

water

and formic

04%,

20%,

trace,

acetlc

acid

--

825

ml

215

acid 1 6596, water

0 3%. formic
remamder

ALLOY

20

acid

6%, methyl formate


water remamder

methyl acetate
mlc aud 050.75%.
6%,

(amtd)

Average corrosion rates (ipy)

Corrosion mediums

Acetic.acsd

MOLYBDENUM

0.019

0.003

0.0031d

0.0031d

0.0057

0.0049

0.0009
0.02

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001

<O.OOOl

<0.0001

<o 0001

<0.0001

<0.0001

ANHYDRlDE

anyhdrlde

65%, ethybdene
dkwetate
33%, acetlc
durmg
186 days, washed
with water
mamder
unknown, durmg 68 days
55%,

ethyhdene

dmcetate

50%.

acetIc

10%.

50%.
sollds

ethyhdene
5%

actd

40%.

acetlc

acid
98%.

2%
re-

Chemical

244.
323

254

acid

5%

Chemical

302

150

Chemical

237

369

Chemical

302

150

esters

dlacetate

40%.

acetlc

acid

5%,

0.012

0.005

0.003

0 0001
LO.0003
LO.0002

10.0003
LO.0007

xx

0.0003

0.0001

xx

0.0003

0.0002

0.0001

0.0001

0.0001

0 0001

0.0003

0.0002

0.0001

(continued)

462

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

AND

STEELS

HIGH NICKEL

ALLOYS-CLIMAX

TYPE

TYPE

316

317

0 0001

<0.0001

...

...

xx ;

0.0002

<0.0001

...

...

0 002c

...

...

TYPE

304
p-p--

20

ALLOY
825

mtxture*

30%. ethyhdene dlacetate 65%. acetlc acid 5%

Chemical

15X, ethylldene dlacetate 65%. solids 20%

acetic anhydrIde, acetlc acid, acetaldehyde, vmyl


acetate

: Won

ACETIC-ANHYDRIDE
*cE*Ic

bntd)

Average corrosion rates (ipy)

Corrosion mediums

AcetK.ahydnde

MOLYBDENUM

MIXTURES

Chemical

158

150

167

150

302

888

xx

F
IF

0.0001

WITH

KID

nil

99%. acetlc acid 1%

Chemical

310

637

xx

99%. acetIc acid 1%

Chemical

230.
248

165

xx

0.009

0.001

99X, acetIc aud 2%

Chemical

280.
291

718

xx

0.002

0.0008

0.0004

Chemical

250.
270

718

xx

0.014

0.002

0.001

93%. acetic acid 1%

Chemical

300

637

0.00011

97%. acetlc acid 13%

Chewcal

295

637

0.0005

0.0003

Chemical

268

571

0.009

0.0006

0.0004

Chemical

273.
280

718

xx

0.004

0.0008

0.0005

160

207

xx

0.0001

0.0001

0.00048

0.00028

99%. acetlc aud 2%. petmanganate


lb/day

90%. acetic acid 20%


70%, acetlc acid 30%

6536, acetlc acid 35%

added 150

: Rayon

<0.0001

<0.0001

<0.0001

63%, acetic acid 37%

Chemical

290

637

60%, acetlc acid 40%

Chemical

284

1183

60%. acetIc acid 407 0

Chemical

266.
277

718

xx

60X, acetIc acid 40%

Chemwal

262

571

60%. acetic acid 40%

Chemical

ia4

375

xx

55%. acetlc acid 45%

Chemical

280

104

0 0002

0.0001

...

...

55%. acetlc acid 45%

Chemical

280

104

0 0007

0.0002

...

...

50%. acetIc acid 50%

Chenwal

284

150

xx

0.002

0.0009

...

...

50%. acetic aud 50%

Chewcal

262.
282

718

xx

0 007

0.001

0.0007

44%. acetic acid 56%

Chemical

285

637

0 0004 I

0.00023

219

735

0 004

0 0024

acetlc anhydrIde. acetIc acid

xx

<o 0001
L ml
0.005b

0 0008

0 0006

0.02

0.001

0 0004

<0.0001

acetlc anhydrlde. crude acetIc acid

Research

246

II4

00711

0 0134

crude a&c

Research

230

114

0 0485

0.0174

anhydride. acetlc acid

llll

\0.0001

(continued)

Alloys

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

mxturer

Acetoc-anhydride

40%.
acetlc
15 psrg
acetlc

acid

anhydrtde.

ACETONE

98%.

withacetic

34%.

glacral

water

acetlc

oxide,

SO%, dlacetane

(PROCESS)

7PE

TIPE

TWE

304
P-P--

316

317

0 0009a

0 0021
0 0006

0.0019
0 0004

20

ALLOY
825

acid

20%.

pressure

acrd. catalyst

added

approximately,
half Immersed1

83%,

fatty

acrds

60%. methyl
5.0-6.0

dlbutyl

alcohol,

Chemrcal

1166.
1184

Chemrcal

1250

water

olerc

lmolelc

remainder

acetate

45%. methanol
2%. acetrc sod

30%,

38%.
0.1%

acid

(separator

remamder

tank1

acetaldehyde

methyl

10%.

acetate

15%,

acetone
vapors from drstilhng
a 40%
water hn vapor llne from top of column)
40%, water
charge Imet
water

alcohol

SO%
Istill,

60%

Icolumn,

10 bottom

60%.

methanol

13%,

58

ethanol, ethyl acetate


wth BP. 60.100 C

20X, water 80%


tone 2%. caustrc

water

pump

durrng 480 days, water


1% during 100 days

xx

~~

77

Soap
(solvent
recovery)

145

Soap
(solvent

32.
72

131

176

210

210

Chemrcal

135

133

59

dis-

Plastrc
ldistillatronl

145

59

Chemrcal

190

583

138

naphtha

ace-

000011

onnol

rlll.
0.0001

00001

<0.0001

Plastic
tdrstdlatmnr

Rayon

xx

0 0001

:
:

acetate

97%,

181

in

12%, acetal1%. methyl-

and solvent

137

RayOn

pH

solutmn

methyl

16%, methanol
16%. methyl acetate
dehyde 3%, ethyl acetate 1%. ethanol
ethyl ketone
acetone,
mixture

(amtd)

00042a

c0.0001

MIXTURES

mesltyl

26%.
1%

MOLYBDENUM

Average corrosion rates (ipy)

twos7*

ALLOYS-CLIMAX

463

0 0003

xx

0000l

,..

<0.0001

0.00038

rlll

nil

<0.0001

<0.0001

<0.0001

<0.0001

<o 0001

<o 0001

rlll

294

xx

<0.0001

<O.OOOl

940

xx

xx

<O.OOOlb
<O.OOOlb

<OOOOlb

580

0.0026

0.0016

0 595

0.765

<0.0001

Textile

70.
86

Chemrcal

165.
225

Petroleum

192

Phenol

302

276

xx

0.0003

Chemrcal

60.
60

22

0.0446

0.0442

Chemrcal

17.5

O.Olc

0.0085~

.,.

ACETONlTRlLE

4%.

Isopropyl-chlorrde

solutmn

l--

ACETOPHENONE

66X,

phenol

ACETVLENE

33%

<0.0001

<0.0001

TETRACHLORIDE

acetylene

tetrachlorlde

acetylene

tetrachloride

(liquid

and vapors)

205

(continued)

464

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

bntd)

Average corrosion rates bpy)

Corrosionmediums

YYPI

304
--P-P

TYPE

317

"20"

625

..

...

...

...

...

0.00083b

0.0049b

0.0026~

0.0018~

0.0028~

0.0012b

0.016

0.005

0.005c

0.004c

82

crude
acetylene
telrachlorrde,
chlorme
excess
IO-21 g/l, drssofved won 0.15-1.65
g/l, acrdity as
hydrochlorrc acrd 0.7-6.6 gi

Chemrcal

108.
120

acetylene
tetrachloride,
aqueous hme

trichloroethylene

vapors,

Chemrcal

185.
202

30

acetylene
tetrachloride,
aqueous hme

trichloroethylene

vapors,

Chemrcal

202.
220

30

15%. methylethyl
ketone 77%. water 8%. hydrachloric acrd trace fresrdue in evaporator
consists
of aconltic acid 50% and water 50%)

Sugar By.
product

190

15%. methylethyl
ketone 77%, water 8%, hydrachloric acid trace (residue rn evaporator
consists
of aconitic acid 50% and water 50%)

Sugar 8yproduct
(extractloo)

100

8.5

15X,
methylethyl
ketone 77% water 8%. hydrachlorrc acrd trace (residue m evaporator
consists
of acomtic acid 50% and water 50%1

Sugar

70.
100

0.5X,
calcrum chlorrde 12%, methylethyl
8%, hydrochloric acid l%, water remamder

Sugar Byproduct
fexfractronl

80

mother lrquor obtained alter one crystallization


of
the organic acid followed by removal of the acid
crystals by centrrlugation

Sugar

80.
100

96%.

methyl

Rayon

45%,

acetrc acrd 452,

30%.

acetlc actd 30%,

ALLOY

TYPE

316

ether hydroqumone
water

ketone

1000 ppm

IevaporatIon)

:F

Rayon

10%

15.9 -

77

116

150

20
3

_ xx

xx

(0.0001

0.0003d

0.0002
0.0001

<0.0001
0.002

<0.0001

00004d

<O.ooOI

<0.0001
0.0009

Rayon

250

Rayon

122

Research

266

20

0.0142

0.0045

Research

248

20

0.0917

0.0043

Metal

212

31

Chemrcaf

70

27

alkyl phenol

Metal
Idrstdlat&on)

401

45

0.0008

alkyl phenol [vapors)

Metal
fdistillatron)

401

45

0.0002

water remainder

acryhc acrd

AMYL

0.0026
LO.0021

xx

rlll

orI

Al.DEYDE

crude alkyl aldehyde


crude alkyl aldehyde

*LKL

0.002

(vapors)

AMlNES

alkyl amines mtxed (hqurd and vapors)


alkyl amlnes.
nol, water

caustfc

soda, sodwm

nitrrte,

metha-

nrl

xx

LO.0045

nil
0.0012

orI

c0.0007

0.003

(continued)

Ferrous

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL


Test

Corrosion mediums

ALLOYS-CLIMAX

465

A/lo ys

MOLYBDENUM

(contd)

Average corrosion rates (ipy)

conditions

TVPl

TYPE

VVPF

304

316

317

20

ALLOY
825

201

0.032

0.047

0.008

0.006

201

x..:

0.021

0.011

0.004

0.003

Chemical

jF

113.
195

30

xx

0.011

0.004

0.005

5%. ammonium chloride 5%, pH 2

Chemical

78

08

xx

xx

0.0023~

0.00015a

aluminum chloride, dust, solvent fumes (mainly


benzene)

Chemical

R.T.

30

xx

xx

0.0067b
0.0006b

0.0004b

aluminum-chloride dust, rulfurrc acid and bromine


vapors, mixture of many fumes (fan scroll1

Chemical
lventrlatronl

R.T.

30

xx

xx

0.004c

0.02c

aluminum chloride, some hydrochloric acid, possibly some moisture, tar residue from isomerization unit with heavy hydrocarbons (immersed in tar
at bottom of vessel)

Petroleum

225
250

44

xx

0.0945a

0.111

alummum chloride and hydrochlorrc acid, ethyl


benzene. ethylene benzene (bottom of reactor)

Chemical

240

35

corr

corr

alummum-fluorosulfate concentrated water solu


tron, solids 1535%, pH 1.52

Chemical
fevaporatron)

190

xx

0.016

0.011

0.0017

15% approximately. water solution, pH 2.3

Chemical

75

49

0.0095

0.0016

0.0002

90

15

Atomic
Energy

176

alkyl phenol-boron-trifluorrde

complex (vapors)

Chemical

alkyl phenol-boron-trrfluoride

complex

Chemical

aluminum chloride, water, oil

Al.MrNM

*LMINM

CHLORIDE

Energy
12.7%. water solution, free nitric acid 3.OM

lO%, water solutron, ferric nitrate


nitric acid 2-lo%, pressure 300 psi

2.5

*,

xx

0 168

0.0003

__I

IO%,

free

Chemical

400

10X, water solution, ferrrc rutrate 10%.


nitric acrd 2.10%. pressure 300 psi

free

Chemical

400

xx

60.20%

Chemical

244

36

60.20%

Chemical

244

36

Chemical

225
235

50.40%

Research

190

>6

40.30%

Research

175

>6

30%

Research

220

5550%,

0.00024~

FLOROSLFATE

47.6%, water solution, free nitric acid 0.12M

ALUUlNUM

0.078

0.182

0.36

0.545

xx

0.03

0.009

xx

0.005

0.0004

xx

0.634~

0.196

0.058
0.023

0.0003

nil

0.0002

SULFATE

pH 2.3

xx

0.09

0.0006

0.0001

(continued)

466

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

ALLOYS-CLIMAX

MOLYBDENUM

(cmtd)

Test

Corrosion mediums

conditions

Average corrosion rates (by)

ru,rats

Alrnlrn

NICKEL

.
-

TPE

lPE

WPE

304

316

317

20

ALLOY
825

Research

220

Research

160

>6

30.20%

Research

B.P.

>6

30.20%

Research

B.P.

>6

28.2%
Inltlally, 51.1%
fInally. ferrous lo <o 2%,
ferric bon <O.l%,
chromrc oxide trace mrtially,
alummum oxrde trace hnally

Chemical

225

44

xx

0001

0 0008

28.2%
ferric

Chemical

215

44

xx

0 0009

0 0007

30%
SO%,

manganousacid

mrtkslty. 57.7% finally, ferrous Ion <0.2%.


40 ~0.1%.
chromic oxide trace initially,

aluminum

oxrde trace

Research

219

21.8%

Petroleum

:F
:

120.
150

Research

218

Pulp and
Paper

110

45

160

129

15%

4%.

sulfuric

acid 25 g/l,

sulfuric

acid

3%,

iron 0.002%
potassium

chromium

sul-

Research

1L

Petroleum

;F

late
aluminum-sulfate
sulfur trioxide

saturated
trace

aluminum

oxide,

sulfuric

aluminum

sulfate

(vapors)

aluminum-sulfate

x
-

<00001

0.0001
0 0005

0.324
0 0015

IllI
0.0009

0.110
0 0005

finally

28%

6.1%.

xx

0.0005

hquor.

acid,

slurry, sulfuric

some

crystals,

Chemical

water

acid 50%

7590

.:
60

xx

60

: L

212

14

j F

220.
250

21

\F

154
247

90

xx

Research

: 1

260

i
:

Petroleum
Imethylamine
manufacture)

iF

260.
268

41

-.-.I

98

>6

<0.0001

<0.0001

<o 0001

<0.0001

00015

0.0005

xx

0.0001

<o

0001

x I

0.0031

0.0018

x:

0.007

0.003

<0.0001

LO.006

0.005

x :

<0.0001

0.002

0.014

xx

xx :

c ml

0.022

0.0002

0.008

nil

AMINES

amines in water, sodium chloride,


sodium hydroxide 2%. organic chlorides and polymer,
pressure
50 psig Ireboiler kettle)

aryl amines,
Iautoclave)

hydroqumone,

ferrous

100%

aminoethyl

ethanolamine,

100%

aminoethyl

ethanolamine

chloride

pressure

0.0004

<0.0001

0.37%.

Chemrcal

320

10 psig

Research

240

llll

ml

Research

240

0.0013

0 0009

I.

<0.0001

ammoethyl

ethanolamme,

pressure

35 psig

Research

285

IllI

20%

aminoethyl

ethanolamine,

pressure

10 psig

Research

240

0.001

20%
oxide

ammoethyl

Research

240

0.001

water,

carbon

di-

0.0003

20%

ethanolamme,

0.0003

<0.0001

nrl
0 0068

(continued)

Ferrous Alloys
TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

467

kontd)

Average corrosion rates (ipy)

h
f

$
-

0
.

$
.

TWX

7PE

TIPL

304

316

317

0.0021

ALLOY
20

825

*miner

20%
ammoethyl
hydrogen sulfide
20%

ammoethyl

ethanolamine,

ethanolamine,

19% amme hydrochlorides,


12%. sodwm chloride 3%,

carbon

hydrogen

dmxide.

sulfide

water 65%. ammoma


ammonium
chloride
1%

Research

240

Research

240

Chemical

250

14

ml
0.29

XX

10%
ammoethyl
ethanolamme,
with carbon dloxlde

water

saturated

Research

240

nil

0.0002

10%
ammoethyl
ethanolamme.
with carbon dioxide

water

saturated

Research

285

0001

0.0044

0.0002

10% ammoethyl

ethanolamine.

water

(autoclave)

Research

240

10%

ethanolamine.

water

(autoclave)

Research

285

ammoethyl

IllI

ml
nil

polyethylene
ammes
cleanmg
kettles)

and

fatty

acids

tcaustlc

for

Chemical

510.
555

33

xx

0 0003

0.0003

polyethylene
ammes
cleanmg
kettles)

and

fatty

actds

tcaustlc

for

Chemtcal

510.

39

xx

0 007

0 0004

XX

0.0007

0.0009

0.0035

0.0001c

0.0001

0 0001

555
Chemical
(oxlmation)

105

Plastic

221

30

Metal
tdlstdlationl

180

65

Petrochemical
tsynthettcurea
manufacture)

150

300

20%,
water
solution
of orgamc
acids,
methyl
acrylates,
ammonium
carbonate.
pressure
1000 PSI

Chemical

302.
320

300

20%. water, low carbon dioxide (ammonia


vapors below liquid trapout tray)

desorber,

Petrochemical
(syntheticurea
manufacture)

215

250

20%.
liqwd

water, low carbon dloxlde


and vapors above trapout

desorber,

Petrochemical
kynthetlcurea
manufacture)

150

20%.
trate,

carbon
pressure

Petrochemical
lsyntheticurea
manufacture)

Chemtcal

oxlme IintermedIate
in preparation
of a monomer),
hydroxylamine
sulfate 10%. sulfuric acid 7%

AMYONIA

90% gaseous mixture


bon dioxide and water
26% ammoma
remamder
lstill

wth

hydrogen

cyanide,

vapor. carbon dioxide


overhead
line)

22%. water 71%, carbon dloxlde


mtrate
trace,
pressure
29 pslg
vessel, bottom)

14%.

car-

water

7%, ammonium
(ammonia
surge

(ammoma
tray)

dloxlde
5%. water,
ammomum
65 ps~g (absorber
bottom)

20% approximately,
amme l-2%, ammoma

water
vapor

solutlon,

monoethanol.

ni-

xx

<0.0001

0.0003
SO.0076

0.0001
0.0002

0.0033
so.0039

0.0006
SO.0006

250

0.011
so.019

0.0016
so.003

270

300

<O.OOOl
s<0.0001

<0.0001
s<0.0001

207

36

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001
s<0.0001

0.0001

0.0004

<0.0001

0.0002

00002

0.015a

<0.0001

<0.0001

(continued)

468

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS AND

HIGH NICKEL

Test

MOLYBDENUM

bmd)

Average corrosion rates (iPY)

conditions

Corrosion mediums

ALLOYS-CLIMAX

TPL

304
-----

TWL

316

TWX

317

20

ALLOY
625

Ammonia

12%. carbon
Immersed1

dmxide

7%.

water

remamder

(half

85

16

xx

175

33

xx

xx

(0.0001
s<0.0001

<0.0001
s<0.0001

170

30

xx

0.001
so 001

0.001
so.002

Mmmg

175

33

xx

0.0001
s<0.0001

<0.0001
s0.00015

Metal

170.
180

III

xx

(0 0001
so 0001

<0.0001
s0.0001

Metal

175.
180

107

xx

xx

<0.0001

<0.0001

Chewcal

: lurea

0.078
LO.151

0.019

0.015

manufacture)
12-10x.
oxygen
8%. merts.
(second-stage
leach autoclave.

pressure
vapors1

100

pug

10-B%, first stage of ammoma


leaching
01 nickel
concentrates,
nickel,
cobalt,
copper
and ammomum sulfates;
water solutmn.
iron hydroxide
and
sulfide
pulp. some sulfur
sesquioxide
and sulfur
p-trloxlde,
pressure
100 ps~g
10.8%.
second
stage
of ammoma
mckel
concentrates,
mckel,
cobalt.
ammomum
sulfates.
water solution.

leaching
copper
pressure

of
and
100

Mmmg

: Mmng

Pslg
9%.
oxygen
14%
mtrogen
remamder

saturated
wth
(leach autoclave.

8%
approximately,
ammomum
sulfates.
clave)
8.4%.
fates,

water
vapor.
vapors)

mckel,
cobalt,
copper
and
water solution
150 g/l (auto-

mckel.
cobalt,
water solution.

copper and ammomum


solids as copper sulfide

sol2%

Mlnmg

207

22

--

xx

0.0002
SO.OOSb

0.0001
so.0002

E-4%, mckel,
cobalt.
fates, water solutlon,
(copper boil rebodet)

copper and ammomum


solids as copper sulfide

sol2%

Mmmg

215.

34

xx

0.0001
so.005

S0.007b

225

0.4%.
mckel,
cobalt,
copper and ammomum
sulfates, water soluhon,
solids as copper sulhde 2%.
vapors of ammoma
4.5% and water vapor (copper
boll reboilerl

Metal

5%. oxygen 9%. saturated wth water vapor,

Metal

170.
180

Metal

Mining

xx

_0.0001

107

xx

xx

10 0001
s<o 0001

\o 0001
s<0.0001

200.
204

100

xx

<O.OOOl
s<0.0001

<O.Lml
s<o.O001

:F

214

23

xx

<0.0001
so.002

<O.OOOl
so.003

155.
175

63

<O.OOOl

<O.OOOl

Coal By
product

75

318

xx :

0.5% fixed ammonia,


ammoma
still liquor, steam,
calcium chloride,
calcium
sulfide, calcium
cyanide,
no free ammonia

Coal By
product

230

144

ammoma.
and cupric

Chemlcaf

420

36

170

13.5

mtrogen

remamdet

(leach

3.5%
approximately.
ammonium
sulfates,
2.1%.
pmg

water

cobalt,
(stripping

pressure

copper
and
autoclave1

lo-15 psig

(strip-

215

autoclave)

1%. ammoma
liquor.
coal gas (tar decanter)
1% approximately,

ammonium
chloride

hydrogen

sulfide,

trace

of

Coal Byproduct

ammonia

hquor

chloride,

ammoma
stdl
waste,
calcium
acid,
manganese
sulfate
l-4
ammonium
chloride
traces, pfi

cuprous

chloride

<:0.0001

225

autoclave)

nickel,
pH 10.2

vapor.

95

0.0001

xx

nil

0.0001c

<0.0001

<0.0001c

0.0002

(ammonolysis)
chloride.
sulfuric
g/t,
organics
and
l-2.5

Coat By

product

.F

xx

(continued)

469

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Corrosion mediums

MOLYBDENUM

bntd)

Average corrosion rates (ipy)

ammonia
liquor. steam, ammonium
chloride,
cyanlde and thiocyanate,
hydrogen
sulfide,
calcium
chlorrde, phenol. complex iron cyanide compounds
(bottom of free still)

Coal By
product

ammoma vapors. hydrogen sulfide. carbon droxrde,


phenols, hydrogen
cyanide and steam (ammonia
stdl. vapor outlet1

Coal Byproduct

220

1200

Research

483

or-

Petroleum

190

90

932

64

AMMONIA

ALLOYS-CLIMAX

240

144

xx

TPl

TIPE

304

316

<O.OOOla

<O.OOOla

<o 0001

<0.0001

1.06

0.014

0.002c

0.0006~

TIPE

317
---

"20"

ALLOY
a25

ANHOROS

lrquld ammoma,

ammonuon

acetate,

pressure

0.2

PW
liquid ammonia,
ganic chlorides,
99.1X,

inerts

saturated
ammonia
ammonia
vapors1

amines.
polymer,
0.9%

ammonium
chloride,
pressure 850 psig

iF

(line)

ammonium-bromide

anhydrous.

trace

liquid

(column.

Chemical

xx i

:L

68.
80

.F

95

102

xx :

185

61

xx

bicarbonate

AMMONIUM

ammonium

amine

in

--

0.0995
nil

>0.52
nil

0.0001

0.0001

0.0007b

0.022
O.OOOla

0.0001

0.0001

nil

BICARBONATE

AMYONWM

ammonium

ethyl

solution

CARBONATE

carbonate,

ammonia,

pH 9-10

.Chemical

85.

41

115
AMMONIUM

CHLORlOE

water,

sodrum

chloride,

ptf

Chemical

120

183

0.0006~
SO.OOOBb

isopropanol.
water,
(transfer line)

sodium

chloride,

pH

Chemical

120

12

0.0003
s0.0007

0.0002
s0.0004

75%.
rsopropanol.
water, saturated
with sodium
chloride. some hydrochlorrc
acid. some free salt,
pH 6.8 (top cover of filter tank.1

Chemrcal
tfiltratlonl

120

13.5

0.0003a
S0.0009a

75%, rsopropanol, water, excess of sodium


Ide crystals, pH 5.7.5 (transfer line1

Chemical

140

41

xx

140

33

__I

Chemical

86.
176

68

14.11%.
water,
some hydrogen sulfide, mercap
tans and a nonabrasive solid (Texas reactor)

Rubber

194

11.5

xx

0.0005c
0.0076

0.0002

0.25%.
recirculated
water
free sulfurrc acid 0 2.0.43%.

Chemrcal

120

8.5

xx

xx

0.0006

0.0004

120

xx

xx

0.0004
<O.OOOl

75%.
isoptopanol.
6.5.8 5
75%.
658.5

33%.

water

34%.

lS%,
sodium
ammoma 2%.

zmc chloride

chloride
8%,
water (tubular

0.25%.
recuculated
free
sulfurrc
acrd
scrubber)

chlor.

33%

carbon dioxide
gas cooler)

3%.

for scrubbing
gases,
pH 1.6.10 (pipe line)

water for
0.2.0.43%.

scrubbing
gases,
pH 1.6.10
(gas

11

<O.OOOlbd

<O.OOOlbd

0.0003

0.0002

0.0001

O.OOOla
S0.0002a

0.0002a

0.0001

0.0001

0.0005ad
S0.0008ad

0.0003ad
S0.0005ad

0.0003d

0.0002d

0.0013c

0.0001c

<0.0001

<O.OOOlb
S0.0005a

<0.0001c

<O.OOOl

<0.0001

<0.0001

0.0004

co.0015

(continued)

470

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

chlorrde,

sodum

ammonium

chlorrde,

sodrum

sulhle

sulirte

lvaparsl

140.
147

30

<O OOOla

<O.OOOla

Chemical

140.
147

30

<OOOOlb

<0.0001

crys.
(vacuum

Chemrcal

150

96

50% to anhydrous
fled ore

ammonrum

unidenti-

Metal

80.
390

IO

Mmmg

230.
260

suspended
ferrous
(batch digester)

titanate,

bung

concen-

,PE

316

slurry,
sodrum-chlorrde
and other ammoacids

45%,
trated

TYPL

304
-----

Chemical

ammonrumxhlorrde
tals, glutamcc
acrd
crystalluerl

brfluorrde.

0 127

165
0 177

0.04

0.018

0 0018

Mmmg

R T.

Chermcal

125

94

xx

Glass

45.
80

30

0 0108
0.0082

0.0067

77

61

0011

0.0095

200

0.150

0 140

excess.

pli moderately

10%.
glass-fortrfyq
solutron.
hydrofluoric
acrd
total
8.75%.
sodrum
floorosdicate
8.55%..
free
hydrofluorrc
acid 4 9%, combined
ammonia
4 6%
10%.

water

6%.water

solubon
Research

solution

ammonwm.brfluor~de
sulfuric
acid and
to highly alkaline

iron

solutron.
traces,

66%.

free ammonia

17%.

65%.

free ammonra

21.7%.

hydrofluorrc
acid,
pH from hrghly acid

water
water

17%
13.3%

R.1:
il P.

Chemrcal

Petroleum

R.T.

Research

128

290

20X,
water and carbon dloxrde
traces,
pressure
30 psrg (bottom of ammonra desorber, vapors)

Petrochemical
Isynthetrc.
urea
manufacture1

ammonun

Petro.
chenucal

nrtrate.

24% approximately.
perchlorate
7 6%.
Icrystalhzer)

free

ammoma

sodrum chlorrde 23%,


sodium chlorate 0.2%.

sodium
pH 4.8

Chemrcal

30

>6

<0.0001

0001

00071

0 077

0.047

715

<o 0001

<0.0001

14.
20
300

138

0 0284
0.0127
<0.0001
s<0.0001

IllI

xx

<O.OoOI

<0.0001

28

89

175

0011

20%. trtanwm

hydroxrde

ALLOY
825

LO 101

60

ammorwm

0005c

CO 0096

15%.
basrc

20

xx

Glass

8%

TPl

317

0.0025b

34.5%.
glass-etchmg
solutron,
total
hydrofluoric
acrd 30%. free hydrofluorrc
acid 24.8%. combmed
ammoma
12 5%. sodrum fluorosdrcate
11 5%
fluorrde

bmd)

MOLYBDENUM

Average corrosion rates (ipy)

2 G
: g
. .
ammonrum

ALLOYS-CLIMAX

0.0013

0.0005

(0.0001

0.0286

ml

<0.0001
s<0.0001

<0.0001

<O.OQol

<0.0001

<0.0001

nil

c-0 0001

(continued)

471

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL ALLOYS-CLIMAX

Test
conditions

Corrosion mediums

MOLYBDENUM

(contd)

Average corrosion rates (ipy)

TWE

WPE

,.E

304

316

317

"20"

ALLOY
825

ammonium monophosphate, saturated water solu


tion

Chemtcal

82

150

<O.OOm

<0.0001

40% rpproxbrtely.

Chemical

140

22

<0.0001

<O.OoOl

ammonium phosphate, water. sulfuric acid 3%

Chemical

122.
158

30

xx

0.006

0.001

ammonium phosphate traces in steam; ammonia,


ammonium sulfate, fluorine compounds and silica
traces present (agitator)

Chemtcal

212.
250

12

xx

0.03la

0.001

ammonium silicofluoride,
monia

Chemical

110.
130

28

<O.OOOl

<O.wol

ammonium monophosphate

alkalme

solution, am.

Coal By
product

IOO116

33

ammomum sulfate, saturated water solutton. sulfuric acid 5%, some crystals tcrystallizer)

Coal By
product

IOO116

33

40% approximately, hydrogen sulfide, free ammonia trace tautoclave. vapors)

Muting

140.
160

--

30% apprOXimately. sulfuric actd 0.75%. ammonia


added with the acid, and 20% ammonium sulftde
2 gal/600 gal approximately of reacted solution

Chemtcal

150.
200

xx

0.339.c
0.75c

0.024

36%, sulfuric acid IO%, sulfur droxrde 0.3%

Chemrcal

180

25

0.0075c

0.0014

6% apprOXimately. ruconium-hydroxrde slurry 0 3


lb/gal, pH 8 (vacuum drum hlter)

Chemrcal

135

50

<o 0001

150

50

xx

<0.0001

6% approxheately. zirconium-hydroxide slurry 0.3


lb/gal, pH 8 (vacuum drum filter)

Chemical

3.2%, pH 5

Research

;1

105

128

1.01 sb, pH 8

Research

;L

105

101

ammonium sulfate, sulfuric acid (vapors)

:
i Chemica
i Chemical
i
:

ammonium sulfate, sulfuric acid (filter)

ammonium sulfate, sulfuric acid tcrystallixer)

i Chemical ::

ammonium sulfate, sulfuric acid (crystallizer)

Chemical

ammonium sulfate, sulfuric acid, ammonia

Chemical

ammonium-sulfate
ammonia

Coal By
product

slurry, sulfuric acid 412%,

ammomum-sulfate slurry, sulfuric acid 1.4%

Chemical

;F

>230

xx

-xx!

<o 0001
ml

0.0001

.,.

<0.0001

ammonium sulfate, saturated water solution, sul(uric acid 5%

0.03b
S0.24b

<OOOOl

S0.03b

nil

C nil

0.027

0.0068

0.002

O.oool

0.0001

0.0001

0.002

0.0035a

0.00014

0.0007

C<O.WOl

corr

125.
145

77

xx

145.
165

77

0.032

0.004

<0.0001

155.
175

77

0.002

0.001

0.001

C<O.OWl

xx

0.0003

0.0005
0.042
wo.01

0.001

c0.0004

221

15

0.04

0.045

CO.008

212

36

xx

.>230

<0.0001

<O.OoOl

0.0016

c<0.0001

<0.0001

(continued)

472

Corrosion Resistant Materials Handbook

TABLE

4.13: VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

bmd)

Average corrosion rates (iPY)

r-

TIPE

304
-----

#
.

mlxlures
of dilute or saturated
free sulfuric acid 1 5%

55% approximately.

35%.
lbotler)

ammoma

31%

ammonium

sulfate,

tap water
0.5%.

ammonium

sulfide

0.1%

approximately

30%.

ammoma

5%. ammomum

30%, ammonwm.thlocyanate
proximately
(outlet from

sulhde

vapors.
evaporator)

20%
approximately.
thiocyanate
scrubber)

coke-oven

10.7%

approximately.

tap water

6.2%.

water

gas

1%
pli

5 7 ap-

tammonlum-

:F

221

13

Agriculture

120

2-6

xx

Chemical

230

31

Coal Byproduct

RI

27

<0.0001

<o 0001

Chemical

70

31

<0.0001

<o 0001

Coal By.
product

154

17

00001

to

Coal By-

118.
133

61

0 0006

<0.0001

Agriculture

120

2.6

0.004

<0.0001

Coal By

63.
90

14

--

<0.0001

<0.0001

xx

product
ammomum
toluene

17%

thlocyanate,

approximately,

hydrocarbons,

up to

saturation

water

vapor.

(evaporator)

,PL

317

Chemical

product

solutlon

TYPE
316

Coal Byproduct

212

16

Metal
tevaporatlon)

220

Chemical

Chemical

xx

xx

0.0008

0.0005

0.0022

<0.0001

xx

0.0002

<0.0001

0001

xx

0 044c
O.OOlc

0.0002a

30

xx

OOOlb

0 OOOlb

340

154

00001

00001

175

!20

00001

0 0001

Chemvzal

R.T.

50

xx

Chemical

R.T.

50

xx

AYYL ALCOHOL

12X, sodrum oleate 58%. water 189,, amyl chlorides 10%. amylene
2% durmg 77 days, sodwm
oleate
58%.
sodwm
chloride
25%.
sodwm
hydroxide
19, and water during 77 days fslde near
bottom of dIgester)

AMYL CLORlDE

amyl.chlorlde
brme.
iamylene
column)

sodium

amyl chlorides
mrxed, sodrum
hydrochloric
actd. ferric chloride
amyl chlorides
ferric chloride

AML

amyl

0 35,

chloride.
traces
and water tplpel

mlxed. traces of hydrochtorlc


and water [pump discharge)

CINNAMK

cmnamlc

hydroxide

of

acid,

<00001

0.0044

<0.0001

0 0032

ALOEHIOE

aldehyde

Chemical

30

ml

OOOOla

20

ALLOY
625

TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX


Test
conditions

Corrosion mediums

amyf chlorrde

trace

lvaporsl

473

MOLYBDENUM

(am4

Average corrosron rates (ipy)

*WE

,PE

,PL

304

316

317

-----

amylene.

Ferrous Alloys

175

23

Chemrcal
ldrstrllationl

212

69

amyl mercaptan.
sodrum
hydrosulfrde,
amyl chlorrde. ethanol,
water,
sodrum
chlorrde.
pressure
250.300 psrg

Chemical

285

40

0.105
WO 161

0.061
wo 086

amyl
mercaptan.
ethanol,
brrne.
amyl
dramyl suffrde. hydrogen
sulfide trace

Chemrcal
fdrstrllationl

230

69

0.0001c
wo 0005

O.OOOlb
W0.0005a

amyl
mercaptan,
ethanol,
brrne.
amyl
chloride,
dramyl sulfide. hydrogen
sulfide trace fvapors)

Chemrcal
idrstrtlatron~

250

74

0 0005c
wo 0023

0 0004b
wo 0013

amyl
amyl

mercaptan,
dramyl
sulfide.
amyl
chlorrde.
alcohol, ethanol, water, hydrogen sulfide trace

Chemrcal
fdrstillatron)

322

78

0 OOISC
wo 0018

0.0005a
WO.0018

amyl
amyl

mercaptan,
dramyl
sulfide.
amyl
chlorrde,
alcohol, ethanol, water, hydrogen sulfide trace

Chemrcal
fdrstrllation~

285

78

0 0007a
woo019

0.0003
WO.0016

Chemrcal
fdrstdlatronl

390

50

Chemrcal
fdistdlationl

390

50

0.0001

0.0001

Chemrcal

195

106

co,,

CO,,

Chemical

195

106

0.0011

0.0009

...

Chemrcal
fdrstillation)

390

96

0.0001

0.0001

...

390

37

o.ooOa*a

0.0002a

. .

0.0022a

.. .

amyl phenol,
acid (vapors)

sulfurrc

acrd,

amyl phenol,
sulfonrc acid,

phenol.
sulfurrc

caustrc-neutralrzed
acrd trace

amyl
trace,

phenol,
phenolsulfonrc
acid.
lmely drvrded clay trace ttank

amyl phenol. phenol.


acrd trace (vapors)
amyl phenol

amyl

phenol,

phenol,

phenolsullonrc

hy-

chloride.

phenolsulfonrc

phenol.

sulfuric
bottom)
acrd,

acid

sullurrc

(vapors)

phospharrc

acrd 0.14%

Chemical

825

0.0001

Chemrcal

amyl mercaptan.
ethanol. water, amyl chlorrde.
drogen sufhde trace (top of column. vapors)

ALLOY
"20"

OOOla

0001

wo0009

<0.0001

coo095

<0.0001

...

0.0008a
amyl phenol,

phosphorrc

dramyl phenol,
still kettle)

potassium

acrd 0.14%

hydroxrde

fvaporsl

1.2%

andine.
carbon drsulhde,
hydrogen
drsullrde.
captobenzene,
thrazole etc lautoclave)

390

37

0.0031b
0.0027a

(batch

Coal Byproduct

230

15

0.00016

<0.0001

rner.

Chemrcal

390.
518

230

0.00015

0.00025

75

27

SO.OOOla
LO OOOlcd

nd a
L nd a

antibrotrc
fermentation
medra, neutral,
sometimes
hydrochloric
acrd acrdrfred.
once
sulfurrc
acrd
acidified
to pH 2 5, occasronally
sodrum hydroxide
alkalized to pH 10.5 (tank bottom head)

Pharmaceutrcal

.F

.. .

c0.0002

ml a

nil

nil

(continued)

474

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test

Corrosion mediums

r
t
2

(evaporator)

antlbrotlc

APF

(evaporator.

I
vapors)

x
s ss $f
. . .
r

TIPE

304
-----

Pharmaceutical

150.
180

25

ml ad

Pharmaceutical

125.
150

25

O.OOOld

antibloW
spent-beer
acetate
or acetone,
pH 7.5 average

solutlo,
water 90%,
Methahne
chloride

amyl
trace,

Pharma.
1 ceutical

antibIotIc
spent-beer
acetate
or acetone,
pH 7.3 average

solution.
water 90%.
Methaline
chloride

amyl
trace,

!
:

(mntd)

r
:
S

APf

MOLYBDENUM

Average corrosion rates (ipy)

conditions
$

antlbmtrc

ALLOYS-CLIMAX

TYPE

316

20

ALLOY
625

1 II

L ml

42

xx

<o

<0.0001

<0.0001

<O OOOla

<O.OOOl

0001

1PE

317

<0.0001

<0.0001

<0.0001

Pharma.
ceutical

172

42

--

Pharma.

390

61

Pharmaceutrcal
(fermenta.
tionl

75

60

penullm

Pharma.
ceutlcal
Ifermentatlonl

R.T.

144

penwllin

Pharma.
ceutlcal
(fermenta.
tlonl

75

42

Pharma.
ceutical
(lermentabon)

85

56

0.0001

0.0001

Pharma.
ceutlcal

RT.

46

00001

0.0001

antimony
chlorofluorides.
orgamc
chlorofluorides.
anhydrous hydrofluorlc
acid, hydrochloric
acid and
chlorme Ipressure vessel)

Chemical

200

35

0.0003

0.0002

antimony
chlorofluorldes.
orgamc chlorofluorldes.
anhydrous hydrolluoric
acid, hydrochloric
acid and
chlorme Ivaporsl

Chemical

200

35

0.0018

0.0012

antlrnony
<05%

organrc
lvacwm

preppratlo
evaporator)

penicdlm

contammg

ferric

IO. pH

7.0

...

...

ceutlcal

broth

streptomyon

media,

pH 6.2.8

streptomycm

media.

pti 2.0

II

0.0001

xx

<0.0001

II

...

...

...

<0.0001
10.0001

<0.0001

..

..

trlchlorlde.

some hydrochloric

acid, water

Chemical

212

12

xx

0 036

0.0002

0 0016
0 0025

0.001

0.0083
0.0089

antimony trlchlorlde.
i 0 5% (vapors1

some hydrochloric

acid. water

Chemical

2i2

12

xx

0.081
0.0054

0.0003

0.0027
0.0009

0.009
0.0029

0.0067

0.008

0.003

18

xx

0.0001*
0.0001

O.OOOld

antimony trlchlorlde
93%. alummum chloride
system blanketed wth hydrochloric acid

7%.

apple pomace mush, sodmm tetraphosphate


O.l%,
hydrochloric
acid 0.05%,
mahc acid 0.05%.
pH
7017

Petroleum

food

(continued)

Ferrous Alloys
TABLE 4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Corrosion mediums

37.5%.
sulfuric acid
corrosro
machrne)

6.24%.

waler

lcircular.path

37.5%.
sulfurrc
Immersed1

6.24%.

water

(beaker,

ascorbrc

hontd)

Average corrosion rates (ipy)

acrd

MOLYBDENUM

ALLOYS-CLIMAX

475

acrd itop 01 leed

half

hopper1

,wt

UPC

TIM

304

316

317

0 00018

Agrrculture

a5

xx

0 00018

Agrrculture

85

xx

0 0036

II

0 0001

0 0001

Chemrcal

65

Petroleum

IOO500

xx

xx

0.0245~

0.0109c

Petroleum

650.

xx

0.0016~
0 0005c

0.0001

ALLOY
20

a25

ASPN.I

asphalt
converter,
overhead
au blow,
hydrocar.
bans. other
organrcs,
salt water
(enters
top at
35 fl. oxygen, sulfur dmxrde, mercaptans
(asphaltplant

0059c

0.0196c

0.0105c

0.0001

0 0001

gas scrubber)

heavy asphalt, crude 011 contarnmg


naphthenic
(vacuum-drstrllatmn
tower, flash section1

acrd

750

atmosphere

at Bayonne,

N 1. (sheltered)

RI.

4340

xx

atmosphere

at Bayonne,

N. J (exposed)

R.T.

4340

xx -

exhaust
humrdrty

mme air,
100%

damp sullur-laden
tunnel at Tuelto,
locomotrve

sulfuric

acid

atmosphere,
w Va.)

flue gases

and steam

0.14%.

relative

Mrnrng

60.
65

70

xx

(Kmgwood

radroad

Rarlroad

R 7.

407

xx

Radroad

RT.

1775

ttunneh

xx i

<O.OOOlb

II

II

II

IllI

II

O.OOOld
0 OOOld

<0.0001

O.OOOlbd
O.OOOlcd

<OOOOlb

0 0006
0.0024b

<0.0001

an. at Baton
industrral

to

Rouge. La., chlorides


pollutron
(Braun-Esso

and sulfates
compressor)

due

RT

30

xx

<o 0001

<.00001

arr, at Baton
to industrral

Rouge, La., chlorrdes


pollutron
(Braun-Esso

and sullates
compressor)

due

RT

158

xx

xi

<0.0001

<:0.0001

au saturated

wrth water,

Kure

small

Beach,

amounts

N. C.,

of dust

800

ft

Mrnrng

from

61

31

R T

5474

xx

xx

atmosphere
ocean

at

atmosphere

at Shore

Rack

and Kure

Beach,

N. C.

Research

jF

R.T.

36C

xx

xx ;

atmosphere

at Shore

Rack

and

Beach,

N. C.

Research

:F

R.T.

1700

xx

xx

atmosphere

at Wdmrngton.

Marine

:F

R.T.

200

xx

xx :

N. C.

Kure

<0.0001

~:ooool

<O.OBOl

. ..

...

<0.0001

<O.OWl

. ..

.. .

<0.0001

<0.0001

.. .

nil

(continued)

476

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL


Test

Corrosion mediums

I
u
.

TIPL

TPE

304
1

----

316

Marine

R.T.

160

xx

Marme

R.T.

270

xx

Powel

R.I.

184

air, occasionally solvents and water

Rayon

70.
125

105

xx -

hot air saturated with water vapor. pH of condensate 1.2 (paper drler)

Pulp and
Paper

120

330

xx

ozonated air, oxygen 5 mgll, nitrogen pentoxide


0.1 mgil approximately (ozone generator)

Samtary

R.T.

60

xx

x I

air saturated with chlorine, chlorine 0.013 vol %

Pulp and
Paper

63

35

--

air saturated with water, some sulfur dtoxide


(economizer)

Pulp and
Paper

110

35

hot moist au (paper machines)

Pulp and
Paper

120

189

xx

Metal

40.
110

t 2&l

xx

au. some vapors of hydrogen sulfide and carbon


disulfide (rayon-spmnm&room roof)

Rayon

R.T.

152

xx

0.0001

air. humldlty high, probably sulfur compounds as


sulfur dloxlde

TextlIe
(wool1

175

56

xx

xx :

0.0008
0 0007

0.0004

atmosphere, humldtty high. fumes and vapors of


vinyhdme chloride. methylethyl ketone

Celloohane

225

95

xx

0.0001

0.0001

air, humidity htgh durmg 34 days, and air, humldlty


high. ddute acetIc_acid vapors durmg 20 days
(tilt drier)

Synthetic
Rubber

240

54

xx

ml

ml

atmosphere. humldlty 100%. in which salt dust


and steam flow periodlcally

Salt

75.
140

365

xx

<O.OOOld

air, humldlty high. lacquer residuals

Pulp and
Paper

MO200

28

xx

xx

batwm chlbrlde. saturated water solution

Chemical

R.I.

2.4

30%. solution repeatedly evaporated

Chemtcal

212

2-4

Chemical

95

Coal Byproduct

176

atmosphere of coast just south of San Francisco,


Calif.

ATUOSPHLRE.

bntd)

atmosphere at Passamaquoddy Dam. Maine

MOLYBDENUM

Average corrosion rates (ipy)

conditions

atmosphere at Wdmington, N. C.

ALLOYS-CLIMAX

<0.0001

E"PE

317

<0.0001

...

ml

<0.0001

...

<0.0001

<0.0001

...

20

ALLOY
825

PLANT INTERIOR

av. caustic fumes. ammoma fumes 0.005%.


mldlty 100%

25%. water solutton. free chlorine, pH

hw

20%, hydrochloric acid excess. sulfide trace, pH


2-3

0.0001

0.0001
<0.0001

...

0.124~

0.118~

...

nil

...

0.0001

.. .

11

xx

28

<O.OoOl

0.0001

0.0004

0.0001
0.0001
:

..

0.0001
0.0003

<0.0001

xx

<0.0001

<0.0001

O.OOOld

...

...

0.0001

0.0001

<0.0001

.. .

0.0001

...

0.25~

.. .

0.042cd

(continued)

Ferrous

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

VVPE

304
P--P-

MOLYBDENUM

kontd)

rates (by)

ALLOY

VW1

VVPE

316

317

barwm ltrate

Chemical

85

xx

spent beer. orgamc actids and their salts, lactic


acid 0.5%. dtcarboxylic acids. olyacids. tnccs 01
lormlc. acetic, prop~omc and bulyric acids

Brewing
~d~stdlalionl

212

105

beer. water 5%. alcohol. orgamc acids. ptt 3.4-3.7

Btewm9
idlstlllailonl

212

87

beer tlermenter, vapors. hqudi

Brewmg

45.
55

beer ifermenter)

Brewmg

R.T.

40

beer topen fermenter)

Brewmg

ale

Brewing

R.I.

70

beer l8eaudelot cooler1

Brewmg

coot

32

Chemical

200.
220

13

xx

0.0012

o.Ocul7

170

275

xx

O.OOOI

0.0001

0.0668cd
co,,

co,,

477

Alloys

20

825

0 005c

<0.0001

<O.oooI

<O.OOOld

<o.ooo1

nil

<O.oOOl

nil

75
-

<o.oM1
. .

...

II

.. .

<O.O!MI

BENZENE

98.5%. methytaldehyde 0.5%. lornuc acid ~~0.5%.


formaldehyde cO.5%. methyl tormate. ek
99.3%. water 1.5%. acetic acid 0.04%.
posdlon gases 0.02%

decom.

95% approximately. sullur~c acld 45%.


lies from crude benzene lwasherl

Impuri-

Coal By
product

122.
140

44

xx

90%. hydrochloric acid 5%. water 5%. chlorinated


benzene

Chemical

80

60

benzene, water

Pharma-

70

42

50%. chlormated benzene JO?.. hydrochloric acld


5%. water 5%

Chemtcal

80

60

x-

benzene. oleum, probably some sullur dooxide and


trloxide tvapori during first 12 hours)

Chemical

365

220

275

benzene. furnace vapors. water. acetic anhydride,


decomposition gases
Coal ByDroduct

113

27

benzene. toluene. xylene, some ammonia and solfur dioxide Icondenser. condensate)

Coal By
product
(tar distillation)

181
250

74

benwe. totuene. xylene. hydrogen sulfide, thiophene, sulfur dioxide, sulfur, oxygen, steam (light.
oil condenser, condensate)

Coal By-

53.
155

28

product
tlractionationt

<O.ODOla

0.0001

0.05 I

0.054

xx

0.47
0.43

0.77
0.73

xx

0.0019
0.0021

0.0011
0.001

0.0007bd

0.0005

xx

0.0061~

0.0012a

0.0002bd

0.0001

1.5

benzene, toluene. xylene. thiophene, condensed


vapors. hydrogen sulfide, sulfur dioxide, oxygen,
water

0.014cd

0.02lcd

1.

.. .

.. .

. .
(continued)

Corrosion Resistant Materials Handbook

478

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

Average corrosion

Corrosion mediums

TIPE

304
----benzene.
toluene.
xylene.
crude
steam tlrght-ml strrpper, vapors)

light

oil

and

benzene. toluene. xylene, thiophene,


hydrogen sulfide. oxygen. water,
sulfur flight-oil
condenser,
vapors1

benzene, totuene, xylene. throphene. hydrogen sulfide. oxygen, water,


sulfur llight-orl
condenser,
vapors)
benzene,

vmyt acttale.

BENZENE

some water

:
:

Coal Byproduct

190.
210

Coal By
product
ffractronationl

115.
257

28

Coal Byproduct

95
220

27

--.

Plastrc

85.
105

156

<0.0001

x--

TIPE

TIPS

316

317

20

ALLOY
a25

<0.0001

0.0034bd

0.0003b

. .

0.0013bd

0.0005b

...

<0.0001

bntd)

rates (iPY)

<0.0001

<0.0001

HEXACHLOR,DE

90%.

methanol,

sodrum nrtrate

0.5%

Research

230

0 93

0 005

45%.

methanol,

sodrum ndrale

0.5%

Research

155

0.083

0.0047

25%.

methanol,

sodrum nrtrate

0.5%

Research

150

0.022

0.004

25%.

methanol

Research

150

1.6

0.12

Chemrcal

75

30

0 0042

0.003

Chemrcal

R.T.

14

0 0033bd

0.0008d

Chemrcal

302

_-

0.35
0.245

302

--

0.045

302

--

0.025

75

70

BLNZOYL

MOLYBDENUM

CHLORIDE

benzoyl chlorrde

fvaporsl

benzoyl chlorrde

q.ORlC AClD

10%
50%

Chemrcal

30%
15.7%

approximately

Research

2.5%

treboderf

bow

acrd. borax, sulfdes,

borrc acrd. solutron


borrc acrd, sublrmed,

sulfates.

saturated

mrxed hquor

with sulfur dioxide

impurrtres

99%. chlorine trace, dry except


whdn hydrochlorrc
and boric
formed by hydrolysis

durrng shutdowns,
acid traces
are

Chemrcal
rdrstrllatronl

195

Chemrcal
tborrc-acrd
manufacture)

130.
220

45

Chemrcal

140

31

xx-

Chemrcal

130.
220

45

xx

Chemrcal

55.4

45

<o

67

xx

xx

xx

xx :

0001

<0.0001
0.0002

0.0001

0 004gcd
O.OOlb

0.0001

x.0 OOOld

\O.OOOld

0 0047cd
0 002cd

0.0002a

0.0003

0.0007

(continued)

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

I
:

95%.
chlorme 5%. dry except during shutdowns.
Chemrcal
when
hydrochloric
and boric acid traces
are
formed by hydrolysis;
ferric chloride and alumi. i
nom chloride traces fcondenserl
boron trichloride,
chlorme. ferrrc
urn chlorrde, srhco tetrachlorrde

Chemrcal
(filtratro)

chlorrde. alumi.
(filter inlet1

j F

:F

53.6

158

24

xx

0.0019

0.0008

2.8

14%.

hydrofluorrc

acid 0.2%.

low pressure

Chemrcal
Idrstrllation)

212

1.7

xj

Coal Byproduct

203

15

xxx;

Chemrcal

77.
257

19

105

92

105
230

17.5

302

32

polymerrzed
reactor)

boron trifluortde.
some hydrofluorrc
denser)

hydrocarbon

oils,

pH 3.4-6.7

polymerized
hydrocarbon
and lluoroborrc acids, water

boron trrlluorrde trace, polymerized


hydrocarbon 011s (vessel bottom)

oils,
Icon-

and neutralized

Chemical
(distillatron)

IF

Chemrcal

boron trlfluorrde
ether1

anhydrous.

anrsole

boron trrfluorrde
canter)

anhydrous,

fluorides,

(methylphenyl

pH 4.7

(de-

Research

Chemical
idtstrllationl

77

154

Chemrcal

70.
135

42

bororvtrrfluorrde
etherate
m hydrocarbon
sibly shght hydrolysis of boron trifluoride

011. pos(vapors)

Chemrcal

70.
135

42

x--I

mrxtures

Chemrcal

178

15

-xxx;

hydrocarbons,

IhI

165

12

Chemtcal

185

150.5
waler

~01%.
O-O 08%

various

unsaturated

0.32

0.068

0.046

0.73

0.22

0.13

0.075

00013

0.0011

0.0012

0.0011

xx

0.024

0.012

<0.0001

xx

0.0029

<0.0001

0.0009

0.0003

011. pos-

varrous crude hydrocarbon

0.29

boron-trilluoride
etherate
I hydrocarbon
srbly slight hydrolyses of boron trrfluorrde

1.5 vol%.

825
0.0019

212

0.155%.
(Nevillac

ALLOY
"20"

0.0021d

trace

TIPS

317

Chemical
(drstillatronJ

water

TIPZ

316

xx

low pressure (vapors)

cresols.

TPE

304

acrd 0.2%.

solvents.

bntd)

60

hydrolluoric

aromatrc

MOLYBDENUM

Average corrosion rates (ipy)

14%.

<1.5%.

ALLOYS-CLIMAX

479

xx

xi

<0.0001

<0.0001

0.001
0.002

0.0005

0.0007
0.0003

0.0005

0.023

xxj

0:027*

0.009

II
0.0003

0.00015

0.005

0.009

BUTANE

90%.

rsobutane

1%. acetic

99%. acelrc acrd 1%.

sod

ketones.

0.5%.

esters.

water

water.

0.5%

car-

Rayon

66.
113

363

Chemical

125

108

Rayon

131.
156

360

347

210

bon droxrde
65%. acetrc acrd IO%,
water 3%

carbonyls

and esters

60%.
waler,
ethyl acetate,
methylethyl
methyl acetate, acetone, esters, ketones.
56%. varroos organrcs 27%. nrtrogen 10%.
acrd 4%. water 2%. carbon droxrde 1%

22%.

ketone.
alcohols
acetic

276

Chemrcal

xx

II

x-

xx

<0.0001

II

<0.0001

II

LII
x

xx

,OOOOl
0 0002

<0.0001

0.0001
0.0003

0.0003

0.0002

(continued)

480

Corrosion Resistant Materials Handbook

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

ALLOYS-CLIMAX

Average corrosion

mediums

TWE

304
----0.003c

20%. mlrogen 65%. acids hnainly rcelwt. esters


and water

Chemrcal

340

20%. mtrogen 75%. oxygen OS%, light hydrocarbons. acads and esters remamder

Chermcal

125

lo8

86.
113

363

20%, nrlrogen and carbon dioxrde. water. hetones.


esters, aldehydes trace

TIPE

WPE

316

311

o.owBa
SO.OO12b

nit

nit
1 ml

xx

0.0001

0.0001

butane. butylene. dibulyl suthle. sutlur~c acrd. waler


trace tDBS debutanwer bottom1

Petroleum

250

52

0.006b

0.002a

bulane. dry hydrochtorlc acrd. powbly some tar


rerldue arid morsture, pressure 250 psi (vapors)

Pelroleum

225.
250

44

XI

O.OScd

0.0487bd

butane. some sulfur &oxide and dibutyt sulfate llop


of separator, gas stream)

Petro.
chemical
tfractionalion)

115.
120

49

99%. carbonyts 0.3%. esters. heavy alcohols trace

Chemical

265

277

IX

o.wO35

97.96%. hydrochloric aud 3-496

Pharma.
ceuhcal

XI

0.0257a

62%. waler 8.59%.


l.l.S%

Chemical

<0.00016

bnt'd)

rates (by)

MOLYBDENUM

"20"

ALLOY
625

..

...

o.oow

RUYANOL

higher alcohols 8%. carbonyls

R.T.
f

18

250

243

xx

<O.OoOl

265

243

xs

<0.0001

0.014sbd

9%. tugher alcohols B%, carbonyts 0.5%

Chemrcal

5%. water 95%

Chewat

195

39

0.0018

0.003

5%. water SO%, melhyl and ethyl alcohol 5%

Chemical

IS5

39

000013

<O.oOoI

230

371

I70
380

44

140

60

--

Chemical

392

75

Chemical

130.
140

28

67

136

butanol. propanol Itogether 42.3%). waler 30%,


carbonyls 3.8%. acelals 0.9%. sodium formale and
acetate
Chemical
tdrstrttal~onl

bulanot. benzene. dlbulyl phthalate (vapor line1

BYYERYILK

see LACTIC

BUYYL ACEYYL

xx

nil

nil

(0.0001

<O.OOOI

ACID

RlClNOLEAYE

bulyt acelyt rrcmoteate. charcoal. acetu acrd trace


I)TL

0.002

0.0002

0.0003

0.0014

o.ow7

0.0001

<O.oool

PHENOL

paratertiary butyl phenol. formaldehyde, turpentine,


boron triflooride, oxahc acid

(DI-) BUTYL

0.0098

0.0004

TIN CHLORIDE

dibuiyl tin chloride, molten lhalf immersed)

06%. water 1.3%, botyric acid 0.7%

I-

<O.OOOl

nil

<0.0001

(continued)

481

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

Corrosionmediums

STEELS AND HlGH NICKEL

Test
conditions

ALLOYS-CLIMAX

Chemical

330

10

2520%. acetic acid 40.45%, propionic acid 510%,


formic acid 0.02%, sodium chloride 0.01.0.05%,
hydrochloric acid trace

Chemical

105

38

butyric acid, small amounts of manganese Sulfate,


magnasmm sulfate and water (vapors)

Chemical
(distillation)

212.
250

32

butyric acid, propionic and acetic acids together


97%, formic acid 2%, water 1%

Chemical

248

315

butyric acid, propionic and acetic acids together


20%. some sulfur dioxide, water remainder (vapors)

Chemical

105

33

3%, heavy ends 95%, propionic acid 1.5%. acetic


acid 0.05%

Chemical

284.
320

54

cacodyhc-acid solution, boiled once, pH 2

Chemical

R.T.

cacodylic-acid solution, boiled once, pH 10

Chemrcal

R.T.

3;;

0.26C

0.024

0.012

0.003

0.003

0.002

<0.0001

<0.0001

20

825

212

l-4

xx

xi

0.002

<0.0001
O.OWl

xx

0.015

0.003

0.0015

0.094

0.051

0.029

0.024

xx

0.009

0.0025

.. .

0.004

0.012

ACID

30% Ialternately immersed)

CALCWU

ALLOY

1WE

316

304
P-P--

AClD

60%. sulfuric acid lo%, remainder unknown

CACODILIC

bntd)

Average corrosion rates (by)

mr

NUTIRIC

MOLYBDENUM

<0.0001
0.0002

<0.0001
o.woz

O.WlX

NNclM1DE

37.97%. water 41.97%. lithium bromide 11.53%,


calcrum chloride 8.5846, specific gravdy 1.56 (under
spray nozzles)

Metal
fair dehumidification)

120

38

XX

XX

09009bd

58% approximately, sodium chloride 1.1.3%, calcium hydroxide 0.1% approximately favaporatorl

Chemical

330

31

xx

O.W2a

O.Wl7a

30% approximately, cooling brine

Dairy

10

355

<O.OWlbd

<O.OOOlbd

calcium-chloride cooling brme

Davy

10

372

O.OOOla

21.69%. calcmm-magnesiumxhloride bittern, mag


nesium chloride 8.69%. sodium chloride 1.06%.
specihc gravity 1.38 (alternately immersed)

Chemrcal

175

130

<O.OOOlbd <O.WOlbd

21.5%. sodrum bichromate 0.0017% as inhibrtor,


pH 7-8.5 hn brme-spray au stream, dehumidifier)

Food
(air coohngl

3-4

338

XX

XX

<OOWl

<0.0001

...

21.5%. sodnan brchromate 0.0017% as inhibitor,


pli 7-8.5 (boding tank, under spray chamber)

Food

90.
225

337

<O.OOOl

<0.0001

.. .

calcrum and magnesmm.chlorrde brme liquors, total


chlorides 50% (evaporator1

Chemrcal
fair condrtioning and
relrigerationl

8.P.

26

xx

xx

o.ow2a

O.Wl4cd

1..

0.0001

. .

0.0001a

(continued)

482

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TIPX

and

sodwm-chloride

brme

in

Chenucal
lair conditioning and
refrlgeration)

160

box)

Chemical

131

107

KX

fumes and condensate lrom boiling calwm-magnesium-chloride


concentrated
solution,
free hydrochlorlc acid 0.63%
in condensate

Chemical

212.

39

xx

calcium

chlotlde.

CALC,M

sodium

chloride.

pH 9.0 tweu

<O.OOOlbd

xx

TWX

TWX

316

317

~0 OOOlad

0.0004.d

20

solution,

sulfurrc

acid excess 3%

calcrum-hydroxide
slurry,
hydroxide and silica

some undissolved

calcium-hydroxide
so&urn sulfide

liquors,

O.OOOld
0.021c

x.

0 02c

220

hme

ammonia

carbonate,

195
212

Chemical

194

fumes,

sodwm

hy-

02

203

xx

0.062

<.0.0001

0 035

,..

< 0.0001

<:o0001

,.0.0001

e.0 0001

LO 0001

10

180

120

204

Chemical

139

46

Chemical

75

65

0.012cd

0 0033cd

Chemical

90.
100

31

0 006cd
OOlcd

0 023cd
0 029cd

6%

Chemical

97

0 0216

6%

Cherrucal

140

o.fMo2

6%

Chemical

212

o.OGO5

0.0004

2%

Chemical

97

ml

0.0006

2%

Chemical

140

<0.0001

2%

Chemical

212

Pulp and
Paper

60.
100

30

Textde

65
100

31

(turbo gas absorber)

CALCIUM
15%

hydroxide. calcium
sodium sulhde

calcium

Sugar
(citric-acld
manufacture)

Pulp and
Paoer

U-7.4%

0001

YPOCLtJRlTE

approximately,

bleach

10%. bleach slurry, avadable


hme excess 20.30 g/I

calcwm
chlorine
chlorate,

ALLOY
825

CITRATE

calcium-citrate

calcium
droxlde.

kontd)

Average corrosion rates (ipy)

304
P---P
calcwm.
magnesium
28% concentratmn

MOLYBDENUM

chlorme

70.100

hypochlorlte
and hme sludge,
40 g/l, some calcium chloride,
calcwm carbonate and free hme

calclum.hypochlorlte
wne 2-3 gl I

bleach

hquor.

g/l,

avadable
calcium

avadable

chlo-

:t

0 0347

<O.oooI

<o.ooo1

0.0002

0017cd

xx

<o

0001

C0.022cd

0.0001

0.0037cd

<O.OOOld

<O.O001d

(continued)

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH

Test
conditions

Corrosion mediums

NICKEL

ALLOYS-CLIMAX

bntd)

Average corrosion rates (ipy)

TWE

304
P-P-P

CALClY

MOLYBDENUM

483

ALLOY

TWX

TIPE

316

317

20

825

LACTATE

5%. actwe carbon 0.5%

Dairy

140.
MO

2?

<o.lloo1

<o.w01

calcwm lactate, lactic acrd. organic acids, calcium


carbonate. pH 4-5.5, initially 6.5-7.5

food
Ilermenta.

125

303

<O.oool
W<O.OOOl

<O.OOOl
W<O.OOOI
LW<O.OoOI

<O.OOOl

IlOd

ClLElY

<O.Owl

PHOSPHATE

12X, calcrum monophorphale. solids 7.5%. phosphorrc acid 3X, fluorides 0.02%, pit I.2 texlraclion
tank bottom)

Chemical

02

18

calcium phosphale. ran exchanged inosrtol. converler liquor. some protein

Corn
Products

75

36

Mming
(ore
processlog

1520

63

Pulp and
Paper

200

68

<0.0001
<0.0001

<0.0001

<O.OOOld

<O.OOOld

CALCIUM

nil

SULFATE

10%. roaster calcme. sodrum vanadate 5.8%.


sodrum chlorrde 3.7%. silrcates. hydrochlorrc acid
and chlorme gases Ibetween roaster discharge and
baker cooler)-

CALCIUM

ml

O.lWllI

0.021

..

0.028

SULFITE

19.3%. calcwm-sulhte hquor. milk-of-lime solution


I lb/gal, sulfur droxlde 10% lgas.absorbmg chamber, top)

CARSON

actwated carbon SXAC-1 adsorbing acetone,


methylene chlorrde trace

Chemical

57

actwaled carbon bed Norit Sorbonorrt Ill adsorbmg acetone containmg methylene chlorrde trace

Chemrcal

57

0.0002bdr

O.OOOlbdr

aclrvated carbon bed Lactol. petroleum solvent.

Prmtrng

70

O.OOOlcr

0.000lcr

Chemical

coal (coal chutes)

Power

R.T.

257

carbowblack
sludge. carbonates. chlorides. sulfates.
carbon dloxlde and sullur dloxlde (half Immersed in
water seal at cooler end of furnace)

Carbon
Black

160.
205

61

O.OQOEc

carbon-black slurry carbonates, chlorides. sulfates.


carbon droxrde and sulfur droxlde from coolmg water
at pli 7 (bottom of prrmary coolerl

Carbon

400.
900

42

O.Oilll

0.001

0.0007

carbowblack slurry. carbonates. chlorides, sullates.


carbon dioxide and sulfur dioxide from cooling water
at pli 7 (riser of primary cooler)

Carbon
Black

900.
1400

42

0.0005

O.KNE

0.0004

steam,

some unknown

carbon

froth,

water

chloride
from

source

coolers

(half

Immersed)

Black

:f

R.1:
230

28

<O.OOOld

0.0047

<O.OOOld

<O.OOOla

O.OOOla

O.OOOlb

<0.0001

0 OOOla

<0.0001c

<0.0001

0.0046

<O.OOOla

(continued)

484

Corrosion Resistant Materials Handbook

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

Average corrosion

:f

160

240

xx

XI

Carbon
: Black

If

170

21

carbon-black slurry, sulluric acid pH 2 Ileaching j Carbon


: Black
tank)

if

110

xx

IX

carbon black loose, entrained combustion gases,


water vapor, product occasionally on tire

:F

120

240

ss

120

324

XI

170

30

xx

178

30

152

carbon-black slurry and water intermittently, pH 7


approxrmately (water level 01 cooler seal, ret and
dry, air and slurry1

I
i

carbon-black slurry (half immersed)

Chemical

Chemical

carbon black loose, entrained combustion gases,


water vapor, product occasionally on fire

Chemical

cartnm~black slurry, water, total solids 7.2%. con.


centrated carbon black 6.94%. sulfates 6.63 g/gal.
lerric oxide 4.24 g/gal, nitrogen as ammonia 0.64
g/gal. chlorides 0.45 g/gal. reduction factor cquivalent to potassium permanganate 0.647 g/gal (half
immersed)

Carbon
Black

carbon black. hard water (fresh water 52 salt


grains/gal). steam talternately immersed)

Carbon
Black

carbon black. hard water ilresh water 52 salt


grains!gall. steam (half immersed)

Carbon
Black

carbon black, sullur. salt and water vapor. oxygen


laet scrubber unit)

Carbon
Black

20% carbon-black paste, water 80% (mixer)

Petroleum
Carbon
Black
Uiltration)

carbon black, hydrogen sulfide 46 grains I100 cu It,


steam 45.50 vol %. carbon dioxide and monoxide.
hydrogen, nitrogen and oxygen 0.2.0.3%

:
i

ALLOYS-CLIMAX

Chemical

26X, oxygen 6%. carbon monoxide 2%, sulfur


dioxide. nitrogen trace

I
i

Water
Purification

<0.0001
0.001 Ic
0.0004

<0.0001

<O.OOGl

<0.0001

<O.OOQl

XI

0.0021c
0.02&

o.lKm

O.oool

<0.0001

30

xx

xx

O.OMC

O.WO1

0.0001

<0.0001

420

I5

xx

0.0402

0.0002

0.0001

7s

28

O.ONlld

0.0001

220.
230

251

160.

52

235.
240

62

104.
113

75

180

.,

IX

<0.0001

0.0001

xx

<0.0001

0.002

36

XI

<O.oool

<o.ocm

10%. gas stream, carbon monoxide 2%. sullur dioxide 0.25%. some oxygen

Mming

150

73

xx

xx

<O.OOOla
<O.OOOla

<0.0001

carbon-dioxide and sodium-chloride brine mixture


teas contains carbon dioxide 33.40%. sulfur dioxide
~050.1%. air; brine contains sodium chloride 45.2
g/l, sodium sulfate 12.5 g/l, sodium carbonate 4.7
g/l and borax) (gas scrubber, center)

Chemical

356

xx

II

<0.0001bd

<O.GGOld

80

302.
392

198

xx

O.OlKt4a

<0.0001

0.0001

0.002c

0.0012c

110

132

O.OOOlb

<O.mOl

0.0043r

Petroleum

<0.0001d

0.0004

xx

<O.OOOl

0.0013

0.0003

a25

<0.0001

0.03lc

12%. nitrogen 88%, condensed water has iron ions j Petroleum


40 ppm. sulfuric and sulfurous acids 10 ppm, nitric :
and nitrous acids 3 ppm (pipe. gas stream1

carbon dioxrde and nitrogen, chlorine trace (gaseous


mixturel

20

<O.OOOl

o.Ow5

<0.0001

--

xx

;F

0.0003cd

ALLOY
;;

<0.0001c

-F

33.34%. water 66.66%. ethanolamine trace (vapor


line of Girdler reactivator)

NM

316

o.lKmc

: Carbon
! Black

1VPi

364

hontd)

rates (ipyl

0.0011c

:F

carbon black, laden with fuel gases

---

MOLYBDENUM

0.0022cd

<0.0001

0.002cd

<0.0001

0.0013cd

(continued)

485

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL ALLOYS-CLIMAX

dwde.

carbonated

CARBON

ammonia

68 pug iammonla

water.

0.2%.
water. urea trace.
stripper bottom)

pressure

5 pug

.
x

carbon drsulhde.

trace,

carbon drsullide.

absorbmg

or1 trace

water

carbon drsulhde, water. sultur


tur~c acid and hydrogen sulfide

<_0.0001

,FE

317

20

625

(0.0001
s<~0.0001

<0.0001

<0.0001

<0.0001
s<0.0001

<0.0001

<O.ODDI

Food

Chemrcal

93

110

Chemical

R.T.

240

xx

<O.OOOl

<0.0001

Chemrcal

60

76

<O.OOOlbd
<O.DOOlbd

<O.OODl

104

180

104

363

112

363

s0.0001

ALLOY

rwe

316

Petro.
chemical
Isynthetic.
urea manulacturel

c25%.

some

sul-

Chemrcal

sulfur 20%

carbon d~sulhde. sulfur

Chemrcal

carbon dwlhde.

Chemrcal

CARBON

sulfur Ivaporsl

II

CARBON

F
.F

xx

0.0006cd

0.0006cd

xx

0.0018cd

0.0017cd

xx

0.0008cd

0.0006cd

Chemical

OK

392

TETRACHLORIOE

Kolene

solvent.

Kolene

benzene

solvent,

87.5%.
water 129..
sod 0.1% lvaporsr

25.5%.
sultur chlorides
dlchlortde. thlocarbonyl

IOYb

benzene

chlorme

crude carbon tetrxhlorrde

CIRROTING

:f

<00001
s<0.0001

MONOXIDE

carbon monoxkde. hrgh pressure

90%.
StIllI

315

,FE

304
P-P-

DISULFIOE

carbon drsulhde, water


(condensate hqurd hnel

90%.

I
u
.
.

;
r

carbon

bntd)

Average corrosion rates (ipy)

Corrosion mediums

pressure

MOLYBDENUM

10%

04%.

Ibottom

01

hydrochloric

~columnl

75.95%
chloride

lsullur mono- and


etch lhqwd Ime)

< 0.0001

Dry Cleanmg

R 1.

40

Dry Cleanmg
ld~strllatronl

287

38

xx

Chemical

140.
185

1.57cd

Chemtcat
Irectlhca.
t1ont

176

133

xx

. 0.0001

Chemrcal
ldtstdlatlonl

125.
130

35.5

xx

47

0.0014ad

<;0.0001
00008ad

0.0014ad

0.0001

I .26cd

<O.OODlad

0.0001

SOLUTlON

cdrrotmg solotton. sullur~c


3%. hydrogen peroxide 3%.

acid 4%. chloric


water remainder

acid

Textde

R.T.

carroting solution. sulfurrc acid 4%. chloric


3%. hydrogen peroxide 3%. water remainder

acid

Textile

R.T.

Tanning

<0.0001

<O.OOOl

0.067~

<0.0001

.. .

CASEIN

case,, leather brushes. shellac, wax. various resrns.


both synthetrc and natural. slightly alkaline water
solution or line dispersron

180

0.0001

0.0001

(continued)

486

Corrosion Resistant Materials Handbook

TABLE 4.13:

STAINLESS

VARIOUS

STEELS AND HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TIPS

180

resms.
water

0.0001

TIPE

TWE

316

317

104

37

xx

cerrum-sulfate
liquor. sulfurrc
anhydrrde
I I%
sulfurrc acrd IO 66%.
phosphorus
pentoxrde
4 596.
hydrochlorrc
acid 0 25, approxrmately
dung
wash
cycle

Rare-Earths
Separatron
tflltratlon)

70

22

0.0015

0.0005

0.0004

cerum.sutfate
liquor. sulfurrc
anhydrrde
11% sulfurrc acrd 1066%
phosphorus
pentoxrde
4596.
hydrochlorrc
acid 0 25% approxrmately
durrng wash
cycle

Rare-Earths
Separatron

70

63

0.015

0 005

0 004

cerowchlorrde

Chemrcal
levaporat~on)

212.
275

30

0 0075cd

0 0087c

0 0073cd

66.
75

86

?
noprts

!
no pits

132.
160

193

0.0001

0.0001

CHERR

sprnrR

bath

solutron,

pfi 5 lopen

evaporator1

xx

20

ALLOY
825

0.0001

Rayon

cellophane

bntd)

Average corrosion rates (iPY)

304
P-Pcase,. leather fmrshes. shellac. wax. varros
both synthetrc
and natural.
slrghtly
alkalme
solution or fme drspersron

MOLYBDENUM

0 0039c

CO 005cd

JlCL

maraschmoxherry
benzoate 0 1%

syrup.
maraschmo

sucrose
flavor

maraschmo
cherrres.
hot procersmg,
600-1000 ppm rnrtrally

50%.

sodwm

Food

sulfur

dioxrde

Food

00001

CLOR,NE

chlorme.

dry

Research

600

0.06

0.03

chlorme.

dry

Research

650

0.12

0.06

...

Food
lflour
bleachmgl

80

82

0 044

0.022

...

Textrle
kottonl

63

OOOld

0 0007d

Pulp and
Paper

62

35

0 124~

O.ll&

Petroleum

RT.

184

xx

hydroxrde.
morst
arc

Chemrcal

l?O135

90

xx

xx

naphtha.

Chemrcal

330

52

ichlorr-

Chemrcal

68

Chemrcal

68

Chemrcal

5.5 VIII % chlorme.


above flour agitator)

arr mixture

0.114%

awlable

chlorme

0.013%

chlorme.

arr mrxture

chlorme

fumes

Irubber

m bleach

hose

hne

solutron

(exhaust

srde of fan)

(atmosphere)

chlorme.
sodrum
oxychlorrde,
rodrum
sodrum
chlorrde,
sodrum-oxrde
smoke,
latmospherrc
fumes from sodrum cells)
chlorine.
hydrochlorrc
lene chlorrde
(vapors1

acrd.

naphthalene.

chlorme,
natorl

hydrochloric

acrd.

propronrc

chlorme.

hydrochlorrc

chlorme.

saturated

acrd. propronrc
water

solutron

acrd

acrd

RI.

xx

xx

...
...

...

0 0005c
0 0002

0.0002

00013

0.0012a

0.0014

0.16

0.18

0 28

0.0075

0 0065

0 0064

0 527
0.0154

0.0005

0.0016

0 478
0ot5

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

487

Alloys

MOLYBDENUM

hmd)

Average corrosion rates (ipy)


t

CHLORINE

gas

Pulp and
Paper

chlorme-dwde

chforme
chlorate

180

45

WPE

304
p-p--

TWE

*WE

316

317

20

gas and condensed

dloxlde, sulfuric
32%. methanol

aud

6OW

solution

sodium

per-

Pulp and
Paper

.F

150

14.5

xx

xx

Pulp and
Paper

:F

135

14.5

xx

cou

0.33

0.29c

0.15c

>0.55

CO.027

0.0026b

approaboately.

saturated

water

solution

Pulp and
Paper

38

70

5.4%

approximately.

saturated

water

solution

Pulp and
Paper

36

14.5

xx

0.0051c

0.0001

co.0007

Pulp and
Paper

155

14.6

0.016~

0.0025

co.0011

0.013a

0.0002

chlorme-dloxlde
sodwm chlorate

spent hquor.
20 gil

CHLOROACETlC

sulfuric

acid

45%.

10.0052c

x ;

o.ooo9

0.0032

AClD

monochloroacetlc

aced

80% crude monochloroacetlc


(half Immersed1

acid,

water

solution

Chemral

66.
70

Chemical

RT.

31

122.
140

17

o.w97

50.
77

17

OOWld

78%

monochloroacetlc

aud.

water

22%

Chemical

:F
:

78%

monochtoroacetlc

acid. water

221

Chemical

jF

0.0014

monochloroacetlc
acid. dtchloroacetlc
acid
acetyl chloride 155. some acid crystals

15%.

Chemical

70

xx

0.018

monochloroacetlc
aud. dlchloroacetlc
aud
acetyl chloride 15%. some aud crystals

15%.

Chemical

70

xx

0.01 I

Chemical

105.

14

70%

mooochloroacetlc

25%.

acetic

48.5%

625

0.056
0.12

7.2%

100%

ALLOY

OlOXlDE

chlorme-dmxlde

10.8%

z
.

acid,

carbon

tetrachloride

acid 5%

technical

0.0025

<0.0001

0.002

<O.OOOld

0.0018

<0.0001

0.013

0.009

0.0084

CO.0088

125

grade

monochloroacetic

acid,

Chemical

chemicat

<0.0001

12

90

x :

140.
159

57

70.
105

90

Chemical

265

137

LO0001

Chemical

266

30

0.04c
0 09

water

<0.0001

<0.0001

<0.0001

CHlOROBENZENE

monochlorobenzene,

phenol, water

chlorinated

benzene.

chlorinated

benzene

hydrochloric

;F

trace

acid

i Chemical
:

0.0053c

0.0066c

...
CO.0132

0 0001

C,,LORO-DIPHENYLAMINE
20%

approximately

5 34%.
mamder

todme

3xhloro-diphenylamine.
0 r9%,

monochlorobenzene

sulfur
re-

0 059c
0.12

0.044c
0.077

Corrosion Resistant Materials Handbook

488

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

Chemical

MOLYBDENUM

(contd)

Average corrosion rates (ipy)

1. 2.dlchloroethane

ALLOYS-CLIMAX

j L

935.

1-.

--

VVPE

TVPE

304

316

VV,E

317
P-P

"20"

ALLOY
825

0.03

1035

tnLONOEvnYLENE

perchloroethylene

ItolvenWecovery

perchloroethylene

Ivsporsl

perchforoethylene

vapor. water

still)

Isolvent-recovery

still)

fextractorl

trtchloroethylene

Isolvent

trichloroethylene.

air twoof-drier

Irlchloroethylene.
duct of blowyrl

air

IwooLdrier

Dry Cleaning
fdlstillation)

vapors)

system,

exhaust

liquidl

305

64

260

<I90

<O.OOOla
.cO.OOOla

12.5

0.0003ad

Textile

115

Tertile

185

Chemical
(distillation)

trlchloroethylene
liquldl

crude. water (vapors and entrained

Chemical
Idistillation)

trlchloroethylene
hquid)

crude. water (vapors and entrained

0 0001

--

<0.0001
<0.0001
0.0004

<0.ooo1
0.0003

--

0.lmo4
0.0006

xx

212

230

xx

Chemical
fdistillationt

169.
198

228

xx

trlchloroethylene
crude. inhibited by controlled adP,%IJ;, of gaseous ammonia (vapors and entramed

Chemical
fdistillationl

163.
198

94

xx

trichloroethylene.

Textile

88

--

tri-

Chemical

176.
212

16.3

nttrobenzene
85%. copper
acid
596 during stripping

Chemical

212

2.5

chlorophenol.
phenol. chlorme.
hydrochloric-acid
gas, ferric chloride (vapors. liqwd)

Chemical

123.
140

19

dlchlorophenol

Chemical
tdistillation)

330.
350

34

.F

<-O.OOOla

<o 0001

228

<2.5%

<O.OOOla

<0.0001

163

wool grease

<O.OOOlad

crude (vapors and entrained

xx

64

Textile
(distillation)

trkchloroethylene

<O.OOOla

Corn
Products

recovery)

system,

Dry Cleaning
(distillation)

<O.OOOl

0.0003

0.0006

<OOOOl

.. .

0.0003b

..

<O.OOOl

<0.0001

. .

<0.0001

<:0.0001

.. .

<O.oool
<0.0001

<o.ooo1

~.O.ooOl

<O.oool

0.0007b

CLONOHDNlN

epichlorohydrm.
chloroethylene

caustic soda, Eis Phenol.


and sodium-chloride
brine

chloro./+methylquinone.
chlortde. hydrochlonc

(vapors)

xx

xx

xx

0.0027

0.0031d

0.0051d
0.0031d
0.0005d

xx

<O.OcOl

0.0006

0.0024d
0.0035d

<o.o001

0.0032

0 002!d
0.003d

<o.o001

0.0025

0.003
0.0018

O.oool

(continued)

489

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

kontd)

Average corrosion rates (by)

5
I
.
dhzhloraphenol pure (overhead still pot, vapors)

Chemical
(distillation1

250.
290

34

2.4.drchlorophenol kolumnl

Chemical
(distillation)

:F

265.
302

21

2
.

::
.

$ g

xx

ALLOY

7PC

,PE

TPE

304

316

317

0.0029

0.0007

0.009

0.004

0.0013

0.001

0.0028

0.0032

0.0009d

0.0006d

0.0007d

O.OOOld

0.0017

0.0015

p-p--

20

825

CHLOROPICRIN

chloropicrin. water. calcium hypochlorrte. Irme. calcium chloride 7.0%. calcium carbonate. pli IO.11

Chemical

203

chloroprcrm. sodium hypochlorile. sodium hydroxide,


chlorine, sodwm chlorate

Chemical

75

10

Chemical

70.
120

86

chromic aud (hguid Ime)

Automotive

120

60

33.33%. Cromodme. sodmm chloride remamder

Metal

170

33.33%. Cromodme. sodwm chlorrde remainder

Metal

170

30%. chromic sulfate 0.45% levaporationl

Metal
(plating)

B.P.

25%

Research

75

25%

Research

180

0.73

1.08

15%

Research

75

0.0003

o.ooo4

15%

Research

150

2.5

0.0098

0.0142~

15%

Research

150

0.0134

0.0258

15%

Research

180

0.056

0.018

15%

Research

212

2.5

0.0979

0.3916

15%

Research

212

0.1869

0.4272

10%

Research

75

0.0002

0.0001

0.0002

10%

Research

180

0.0059

0.012

0.036

5%

Research

75

nil

ml

5%

Research

180

0.0007

0.0029

R 1.

60

0.0002d

0.0002d

CHLOROTRlFLUOROETHYLENE

chlorotr~fluoroelhylene. hydrofluorrc and hydrochloric acids <- 1.0%. pressure 150 prig iprtrally
lwhedl

CROWC

0.0012

AClD

5% approximately. Cromodme. hydrochlorrc acid

Metal

0.0052
SO.0058

0.0128
SO.0190

xx

0.0011

0.0005

xx

o.LlOO2

xx

0.555

nil

.,

co.0071
CSO.0161

0.418

0.68

c0.0002

0.004l7

0.19
...
.

...

(continued)

Corrosion Resistant Materials Handbook

490

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

.
chromic
2 gal

chromx acid,
3% (develooer

ClTRlC

oxnde 10 oz. sodium

water
box)

solutmn,

sulfate

sulfuric

acid,

5 oz,

acidity

Printing

:f

R.T.

Textile

: f

140.
160

.
:

6.5

(amd)

xx

I:

ALLOY

TPl

*we

TIPS

304

316

317

<0.0001

0.0003d

<O.OOOla

0.0003d

"20"

825

..
.. .

ACID

Chemical

155

52

56%

Chemical

130

food

125

37.5

B.P.

45

Chemical

213

Chemical

125

approximately

51.6.42.6%
20%
10%

10%.

50

citric ac!d, pure. dry (drum drwl

10%.

MOLYBDENUM

Average corrosion rates (ipy)

Corrosion mediums

3.4%.
water

ALLOYS-CLIMAX

chlorides

0.2

x.x

xx

xx
1.

<0.0001
0.0086b
<0.0001

II

<0.0001
0.00082b
<0.0001
0.0002

xx
-

x.x

36

xx

0.0001

IX

xx

~~0.0001

0 0006

x:

xx

r00001

0 003

fermentatmn

sucrose

solution.

hydrochloric

Chemical

90

60

fermenlat!on

sucrose

solution.

hydrochloric

Chemical

90

50

Chemical

213

01

II:

Sugar

180.
213

0.3

Chemical

160

106

0.00062
0 00103

0.00047

0.0015

acid
10%.
acid
6%
cltrlc acid. pti 2 neutralwed
to ptl 7-8

wlh

calcium

acldlhed clay, sulfwc


acid eqwalent
hydroxide 4 mg iOorr thickener)
acldtfied
lthlckenefl

hydroxide

to polasswm

x-

0.003
0 006

0.008

0 0001

00001

clay

slurry.

sulfuric

acid

0 18-O 5396

Chemical

140

40

1.

0 0003d

0 0001

acldllled
clay
lOlIver Idleri

slurry,

sulfuric

actd

0 18-O 53%

Chenwal

150

40

xx

00001

0.0001

acldlfled
IthwAenerl

clay

slutry.

sulfwc

acid

0 26.0 97%

Chemical

140

40

I:

0 0008

0 0001

acidlbed
IthIckener)

clay

slurry,

sulfuric

acid

0.53-1.3%

Chemical

140

40

0.0005

0.0001

acldlfled
Ithlckenerl

clay

slurry,

sulfurit

acid

0.88.2.1%

Chemical

140

40

0.0004*

0.0001

acldtfied
(thickener)

clay

slurry.

l&3.5%

Chemical

140

40

0.0003

0.0001

0.0002

0.0001

0.0001

0.0001

0.00106d

0.00036d

sulfuric

acid

acidified
clay slurry, sulfuric acid equivalent
potassium hydroxide 60 mg Klorr thickener)
acidified
Ith&.ener)
acldlfied

clay

slurry.

clay suspension.

sullurlc

sulfuric

acid

3.5-&O%

acid 15.20%

to

IF

Chemical

125.
160

106

Chemical

140

40

Glass and
Ceramics

70.
205

4.5

I:

I:

0 0001

.. .
(continued)

491

Ferrous Alloys

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

TYPE

304
p--pacrdrfred
bentonrtrc
clay slurry. drlute solution
of
alummum
and iron sulfates.
free sulfuric
acid
0 15% IOhver lilted

COBALT

Chemical

126.
158

Chemrcal

227

Metal

95.
185

MOLYBDENUM

bmtd)

rates (ipy)

TYPE

TYPE

316

317

0.0003

0.001

<O.OOOld

<0.0001

ALLOY

20

825

ACETATE

cobaltacetate
fevaporatort

solution,

COBILTOUS

free

acetrc

22 g/l, copper
trace, ptf 3

6 g/l

acrd

trace

396

xx

xx

nil

185

23

xx

xx

0.003

ll-

25

xx

xx

104.
149

60

SULFATE

5.31X,
sodmm

mckel
fluoride

2.58%.

mckel

2.37%.

ruckel as sulfate

as sulfate

0.31%,
nickel
g/l as sulfates,

as sulfates,

(nickel
refining)

10 g/l.

pH 1.2

LOO g/l,

04 g/l, copper
sodium chloride

Metal
fnickel
refining)

ptf 2.0

Metal
fmckel
reflningt

02 g/l.
iron
trace, pH 2.5

15

nil

o.OC3

IllI

IllI

185

Metal
(cobalt
refmmgl

00031c

<0.0001

<00001

<0.0001

<0.0001

COFFEE
18%
tar)

soluble

coffee

extract

coffee,

liquid

coffee

extract

fevapora-

Food

120

38

.food

40

30

Mining

70

42

xx

Muting

70

42

xx

Food

Food

65.
70

162

food

70

--

Food

190

10

Food

195.
212

173

Jewelry

215

~.00001

<0.0001

c,.o0001

WI

COLUMBIUM
26%.

hydrofluoric

acid solution

dissolved
columbde
sulfurrc acrd 3.5N

ore,

3.2N

hydrofluorm

acid

4.5N,

0.036

0.002

00021

corr

0.033

0.03

CONDIMENTS
bean sauce, tomato
alcoholrc

menstrua

mustard,

ground

salad dressmg.
tron fcooler)

products
and vanilla

beans

fgrmdert

vmegar

4%,

sodrum-chlorrde

solu-

sauces used m cannmg various


types of dry-bean
packs. tomato puree, chdi pepper, vmegar, etc

COPPER

I55

--

0.0005
x

~:0.0001
c_0.0001'

<0.0001

ml

< 00001

< OOOOld
LS. 0 0001
--

xx

0.0001.d
O.OOOld

<0.0001

00001

CHCORIOE

10% cupric

chloride

2.1

(continued)

492

Corrosion Resistant Materials Handbook

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

mediums

STEELS AND HIGH NICKEL

Test
conditions

ALLOYS-CLIMAX

Average corrosion

f $
. .

10% cupric chloride

Research
felectrotysrs)

cupric chloride, cupric sulfate and sodium chloride

60.
60

233

78.
80

- -

78.
80

xx

--

1.66% cupric chloride, sodium chloride 226.7


g/2345.9 ml, pressure 6 in. of mercury

Chemical

7.66% cuprrc chloride, sodium chloride 226.7


g/2345.9 ml, pressure 6 in. of mercury

Chemical

cuprous chloride, ammonia, magnesium oxide fcarbowmonoxide absorption chamber)

Automotive

R.T.

44.5%. boric acid 4.07%

Chemical

120

130

44.5%

:L

---

TYPE

TYPE

,PL

304

316

317

0.174c

<O.OOOlcd

--

20

ALLOY
825

<O.OOOlb

ml
0.0017

nil
0.0002

..

0.0565~

0.0006
0.001
0.003
0.001
0.002

Chemical

75

XX

11.46%. boric acid 4.07%

Chemical

120

0.0008

120

0.0005

nil

copper nicotmate. water solution, sulfurrc acid,


Pf-f 1

Chemrcal

75

19

xx

0.0666c

0.02oc

65% approximately cupric sulfate, saturated solw


tion, sulfuric acid 0.4.0.8% (evaporator)

Metal

170.
220

30

xx

0.0002

0.0002

17.5.10% approximately cupric sulfate, neutral


leach, srlver ion 3-6 g/l as sulfate

Mining

160

32

xx

xx

16.511% approximately cupric sulfate, concentration 34Bc. total acrd 16.8%. copper ion 4.6%. free
acrd 3.6% before evaporation; and concentration
4866. total acrd 24 3%. coooer ion 6.6%. free acid

5.5% after evaporation

Metal
levaporatronl

215

675

xx

12.5% approximately cupric sulfate, nickel ion 5


g/I and cobalt ran 2 g/I as sulfate, pH 2

Metal
hnckel
refining)

36

xx

xx

10.6% approximately cuprrc sulfate, copper-refmery


electrolyte. sulfuric acid 200.235 g/l, nickel ion
20-22 gi I as sulfate, pressure

Metal

150

32.9

.,

<0.0001

<O.OOOl

6-4X approximately cupric sulfate, sulfuric acid


~0.3%. mining low-acrd leach, zinc ion 4.7 g/l,
silver ion 2.5 g/l and manganese ran 1-3 g/l as sulfates

Mining

140.
170

32

xx xx

<O.OOOld

<O.O001d

.<149

bntd)

rates (ipy)

39.9X, boric acid 4.07%

5.73%. acrd

MOLYBDENUM

<0.0001

0.0002ad

0.0001

<0.0001

<0.0001

nil

nil

<0.0001

(continued)

Ferrous

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TIPl

TPC

1VPE

304

316

317

20

<o 0001

<0.0001

Mining

140.
170

32

xx

xx

<O.OOOld

<O.OOOld

5% approximately
cupnc sulfate,
manganese dmxlde 9-10 g/I

Metal

158

63

xx

xx

<o 0001

<o 0001

68.
140

194

xx

<O OOOld

<O.OOOld

129

30

111

2.613%
acid 2.54
mersed)

approximately
5%.
sodbum

cupric-sulfate

solution

acid 10%.

MOLYBDENUM

hontd)

Average corrosion rates (ipy)

6.4%
approximately
cupric sulfate.
sulfuric acid
3.6%. high-acid leach. zinc ion 5-6 g/l. manganese
loo 2.3 gi I and solver loo l-4 g/I as sulfates
sulfunc

493

Alloys

ALLOY
825

<o 0001

(plating)

cupric
sulfate

sulfate,
sulfuric
~2%
(half Im-

Oacolyte

Metal

Metal
~platmg)

cuprnc sulfate and hydroxide.


nnc. cadmium,
sew
calcwm sulfates and hydroxides. pH 6

ar-

xx

nil

Metal
lelectrorefinmg)

185

Cosmetic

RI

30

<0.0001

Cosmetic

Rl

30

<0.0001
<0.0001

ammonia

Cosmetic

R.T.

30

(0.0001
<0.0001

phosphoric

Cosmetic

R.T.

30

<0.0001
<0.0001

Cosmetic

R.T.

0.0002

Lumber

190

41

<0.0001

<o

0001

<0.0001

nil

<o 0001

<O.OoOl

<0.0001

COSMETICS

cream hawdress

emulsion

0 0004
cold permanent-waving
ammoma l%, mmeral
machme-wavmg
l%, pli 10

solution.
oil

lotton.

thioglycolate,

sodium

sulbte.

hair-waving
liquid neutralizing
solution,
acid and hydrogen peroxide, pli 2
glycerme

lotnon, alcohol,

alkaline

free

detergent

CREOSOTE

creosote

and steam

<0.0001

(0.0001

CRESOL
p and m-cresol
mersedl

mw.ture,

techmcal

(alternately

,m-

Chemtcal

R.T.

11

<00001

P- and mcresol
mersed)

mixture.

techmcal

(alternately

Im-

Chemical

160

11

<00001

Chemtcal

300

60

Rayon

350

55

CRESYLfC

cresyllc
66%,

..,

ACID

acid. water 0 5% Ireboiler)

sulfuric

acid 2%

xx
-

xx

O.OOOla

0.0001

0.007a

0.005b
0 Ola

0.02b
crude cresybc acid,
orgamc compounds

water

and

hydrogen

sulbde.

Rayon

350

135

xx

0.0008
0.0001

cresylic

acid, water,

sodmm hydroxide

Rayon

100

220

0.009c

cresylic

acid, water,

sodium hydroxide

Rayon

100

105

0.02b

Rayon

350

94

crude cresyhc acid, sulfur 4%. water


powder, caustic, ethylene dichloride

2.4%,

zinc

xx

0.0001

0.0002r

O.OOOlr

(continued)

494

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

90.89%.
cresol
chlorx
acid

acid 2%. organic


dlsulflde.
water

8.10%.

partial

esters

sulfurous

2-E%,

hydra-

xx

0.039cr
0 032cr

0.015a

Rayon

R.T.

360

0.013b

O.OOEb

B.P.

179

90.88%.
cresyllc
acid 5%, thiophenols
neswm chloride
1%. hydrochloric
acid
chlorides
trace;
residual
tar, tricresyl
and magnewm
chloride

5%, magand organic


phosphate

Rayon

700

306

xx

90.88%,
cresyllc
acid 5%, thlophenols
nes~um chloride
I%, hydrochloric
acid
chlorides
trace;
residual
tar, trlcresyl
and magnewm
chloride

5%. magand organic


phosphate

Rayon

700

140

xx

90.88%,
cresyhc
acid 5%. thlophenols
nesium chloride
1%. hydrochloric
acid
chlorides
trace;
residual
tar, tricresyl
and magnewm
chlortde

5%. mag
and organic
phosphate

Rayon

700

74

xx

90.88%.
cresyllc
acid 5% thiophenols
5%. magnewm
chloride
l%, hydrochloric
acid and orgamc
chlorides
trace;
rwdual
tar, tricresyl
phosphate
and magneswm
chloride

Rayon

700

36

--

90.88%.
cresyllc
acid 5%. thlophenols
nesium chloride
I%
hydrochloric
acid
chlorides
trace,
residual
tar, trlcresyl
and magnewn
chloride

Rayon

700

22

Rayon

212.
240

4.5

Rayon

176

544

crude

trlcresyl

phosphate,

trlcresyl-phosphate
scum,
orgamc sulfur compounds.

cresyl~c

acid trace

sulfuric
acid 2 ~01%.
water. hydrogen
sulfide

0 004a

xx

0 0006a

0.001

xx

0.01
0.0006

0.0055
0.0003

xx

0.025

0.0003a

00003a

0.0025a

0.002

Rayon

:F

100

135

heavy

al-

Chemical

275

147

xx

83%, water 10%.


cohols, phosphortic

acetaldehyde
acid

0.75%.

heavy

al-

Chemical

275

43

xx

as

Cbemlcal

200

608

xx

IllI

nil

120

1094

n1l

rlll

crotonaldehyde.
acldlty as acetlc
21.9%.
butyrate

10%
acldlty
trace, pH 4 5

water
15%. acetaldehyde
10%
acid 0 33%. phosphates
trace

Chemical

water 45 4,.
acetaldehyde
29 5%
butyl
36. hexadlenal
1.3.. butyrlc acid 06;

Chemical

250

462

Chernlcal
ldlstdlatlon)

212

347

xx

xx

0 0003a

0.006

0 75%.

acetaldehyde
phosphates

O.OOOla

0.035

0.007

acetaldehyde
acid

water
15%.
acid 0 33%

825

0 005a
0 008

O.OOiar
0.024

83%. water 10%.


cohols, phosphoric

75%,
acettc

hontd)

ALLOY
20

traces
of dlaryl
phosphate,
and phosphoric
acid

TIPS

317

60

Rayon

phosphate,
phosphate

TIPS

316

350

5%. ma&
and organic
ohosohate

5X, mag_
and organic
phosphate

TIP6

304
Chemical

90.89%,
cresyhc
acid 5%. thlophenols
nmum
chloride
1%. hydtochlorlc
acid
chlorides
trace:
residual
tar. tricresvl
and magnewm
chloride

trlcresyl
monoaryl

MOLYBDENUM

Average corrosion rates (ipy)

Corrosion mediums

cresylic
acid, sulfuric
compounds.
hydrogen

ALLOYS-CLIMAX

WI

0.0001

IllI

0.0001

00002

.. .

0 0002

o.uoo5

CUMENE

75%.

cumene

hydroperoxlde

25,

0 0001

0.0001

0.0001

(continued)

Ferrous

4.13:

TABLE

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Corrosion mediums

ALLOYS-CLIMAX

495

Alloys

MOLYBDENUM

(contd)

Average corrosion rates iipy)

TPL

TPI

TWE

304

316

311

-----

ALLOY
"20"

825

alkyl benzene

sulfontc acid

S0ap

120

55

0.0063

0 0039

alkyl benzene

sulfomc

Soap

120

56

0.0022

0 0006

<o 0001
s<0.0001

-0 0001

acid

41.39%
ammonium
alkyl
39.40%,
ethanol
14 516%.
4.7%. pH 6.9.13

aryl sulfonate.
water
ammonium
sulfonate

Soap

62.
105

43

3028%
ammomum
46.5.49.5%,
ethanol
fonate 2.4%

aryl

Soap

65

90

Synthetic

150

392

<o 0001

85

95

<O.OOOld
S0.0002cd

alkyl

sulfonate.

17.5.19.5%. ammonium

57.53%
sulfate

sodium alkyl aryl sulfonate.


<3%,
water remamder

41-4936

sodrum alkyl aryl sulfonate

active,

water
sul-

sodium

<0.0001
s<0.0001

<00001

Soap

Synthetrc
Detergent

175

311

sul.

Soap

130.
180

70

<O.OOOld

drshwashing
compound,
mainly sodmm polyphosphates. sodium srhcates. sodium carbonates,
small
amounts of aniomc surfactants
SAAS type

Soap

140.
160

60

c,0.0001

non-ionic detergent
slurry, containing
water,
phosphates, soda ash and sodium siltcate

poly-

Chemical

140

cleanmg compound. soya fatty acid soaps 3%.


ionm detergents
2%. sodrum tripolyphosphate
water, pli 10-10.5

nonin

Soap

72

silicate

Soap

AI.

(half Immersed)

Soap

140

0.25

xx

O.ODol

Soap

140

0.25

xx

0.0001

Soap

R.T.

--

Soap

140

025

xx

DDT. sodium sulfate, dratomaceous


earth, traces
of sodrum, monochlorobenzene
and chloral. pH 6-7
lhlterl

Chemical

270

acrd dye solutron.


murm colors

Textile

90%
10%

Nytron synthetic
(half immersed)

0.2%

Nytron

0.2%

Tab

0.2%

Or

Tide

synthetic

synthetic

actwe.

detergent,

synthetrc

synthetic

60%

detergent

sodium

sodium

detergent
detergent

(hall immersed)

detergent

straight

acid,

<:o0001

Neolan

acid,

chro-

10% Calcosrd orange YtID in methyl Cellosolve


solution, acidrfied with acetrc acid 99.5% to pH 5.2

Wood
Staining

<0.0001
S<O

.;o 0001

\o 0001

OOOld

<o 0001

pyre16%.

24%
sodium alkyl aryl sulfonate,
sodium
phosphate
16%.
sodium
tripolyphosphate
nonyl phenol trace, water remainder, pH 9
alkyl aryl sulfonate slurry,
fate ~3%. pH S-8.5

<o 0001

Detergent

<0.0001

0.00012

<00001

rlll

nit

0.0001

xx

0.00124

BP.

1 nil

80

<:0.0001

0.0005d

O.OOOSd

<0.0001

O.ODLt5d

...
(continued)

Corrosion

496
TABLE

4.13:

Resistant

VARIOUS

Materials

Handbook

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

YWE

304
----chromrumxhlorrde
dye, 27% hydrochlorrc
acrd
lb. water 1000 lb, corn syrup 200 lb, sodium
chromate
725 lb added

1100

chromrum-chlorrde
dye, 21% hydrochloric
lb, water 1000 lb, corn syrup 200 lb,
chromate
725 lb added

1100

cotton dyeing and bleachrng


regular processrng
cycles

solutron.

acid
sodium

150.
216

68

Textile

150.
216

68

Textrle

160.
170

194

xx

11

xx

xx

1<0.0001

<0.0001

<0.0001

<0.0001

<o 0001

<O.OOOla

di-

no Textone.

fur washmg.
bleachrng.
dyer@ solutions,
alkalies,
orgaruc and rnorganrc
acrds, oxidation
and reducbon agents, concentrations
<1.5%

Fur

dyemg solutrons.
hydrochlorrc
acid and acetrc acid
during 2 5 days, acetrc acid and sodium dichromate
durrng 1.7 days, sulfurrc
acrd during 1.5 days, and
sodrum perborate
during 0.7 days

Textile

50.
130

dye solutron.
water, sulfurrc
acrd,
drum drchromate.
cuprrc
sulfate,
scouring
sodrum hydroxrde
0.5.7%

Textrle

ff.1:
O.P

180

Textde

B.P.

400

x
-xxx!

wool

dyemg

water

Palatine

dyes

solutron

soluble

varrous

solution,

dyes, tallow

70.
100

25

<O.OOOlcd

O.OOOla

xx

00001

212

21

Tanning

100

100

O.OOZcd

<O.OOOlcd

0.0001

<O.OOOld

<O.OOOl

.. .

Textde

45.
202

30

Chemrcal

150.
220

194

acetrc
propyl

Chemrcal

200

92

xx

SC2%.

Chemrcal

190

52

xx

Chemical

171

17

boilers

Chemrcal

316

490

3%,

Chemal

226

17

Chemical

158

39

x:

0.0001
0.0001

;
-

a25

0.0002

dye hquors

0.002c

ALLOY
20

0.02

6.4

Textde
and wool grease

0.005cd

rrrr
317

Textile

acetic acrd. socolors,


caustic
(9 P.)

TWL

316

T&de

di-

dyestuffs
and developrng
baths durrng 250 hours,
sodrum hydrosulfrte
and caustrc during 5 hours

acrd dyemg

kontd)

Average corrosion rates (iPY)

Corrosion mediums

sulfurrc

MOLYBDENUM

<0.0001

<0.0001

.. .

ERlTnRrTclL
commercral

erythrdol

99% set-butyl
acetate, propyl acetate 15%.
acrd 15%. set-butyl
alcohol 8%. water 2%,
alcohol 0 5% toluene sulfonrc acid trace
55% set-butyl
acetate,
propyl acetate
butyl alcohol
6%
propyl alcohol
4%,
acetrc acrd 001%

ESTERS.
100%

ETHYL

33%.
water

ethyl

<0.0001

0.0001

0.0005

<0.0001

0.0001

nil

LOOOOla

ACETATE

ethyl acetate

99.92%

0.0009b
10.0028b

--.

acetate,

ethanol

O-7%,

high

xx

xx

0.0002
<0.0001

0.0003
nil

<I%

85%
ethyl

ethyl acetate, ethanol


propronate
2%. water

90%

ethyl

acetate,

methylethyl

9%,
1%

heavy esters

ketone

20%

xx

0.0024

0.001

0.0002

0.0001

<0.0001

(continued)

497

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

Corrosion mediums

STEELS

AND

HIGH

Test
conditions

NICKEL

ALLOYS-CLIMAX

TPl

Chemical

70% ethyl acetate. benzene 23%. water 7%. acetic ~ Rayon


acld 0.04%

(amtd)

Average corrosion rates (ipy)

304
P-P76% ethyl acetale. ethyl propionate 14%. acetic
aud 5%. heavy eslers 5%

MOLYBDENUM

O.oool

176

17

177

246

177

50

0.0002r

177

34

O.OOOlr

:f

,PI

,PL

316

317

ALLOY
20

625

o.ooo2

0.owlr

0.0001

ml r

nil r

c0.0001

...

...

<O.OoOlr

...

...

0.06r

0.006

...

...

807

ml

oil

158.
221

180

0.002
00013

0.0025
0.0018

0.001
0.0009

0.0015
0.0014

170.
240

318

0.0002

<O.OOOl

<O.OOOl

<O.OoOl

Rayon

284

63

0 04

LO.OO75c
0.0069

0 0055b
0 2c

60% methvl acetate. acetaldehvde 10%. water 5%.


acetic aclb2%, acetone and alcohols

Chemical
(fractiona.
IlOlll

223

131

0 0001

0.0001

20% methyl acetate, ethyl acetate 20%. methyl.


ethyl ketone 18%.acetone 15%,low boilers 14 4%.
water 6.5%. acetaldehyde 6%, acetic acid <1%

Chemical

144

390

18% methyl acetate, water 60%, acetone 16%.


acetaldehyde 4%. acetlc acid 05%. formic acid
0.1%

Rayon

199

1125

0.0004

14% methyl acetate, water 60%. acetaldehyde


13%. acetone 12%. acetlc acid 0.1%. tormlc acid
0.1%

Rayon

172

1158

<O 0001

propyl acetate, butyl acetate and isobutyl acetate


together 65%. water, propyl. butyl and tsobutyl
alcohol together 10%. acetlc acid 0 003.2%

Chemical

200

57

0 0002

propyl acetate, propyl alcohol, water, ethyl acetate,


ethanol, methyl amyl acetate, methyl lsobutyl car.
binol. isopropyl alcohol, isopropyl acetate, acetlc
acid

Chemical

167.
248

650

to 0001

70% ethyl acetate. benzene 30%. prop~omc and


acelrc acods0.02%

Chemical

70% ethyl acelate. benzene 30%. propiomc and


acelIe acids 0.02%. mangaoous acetate 10 lb/day

Chemical

61% ethyl acelate. benzene 26%. proplonic acid


11%. acellc acid 196. waler 1%. manganous acetate IO lb/day

Chemical

190

34

51% ethyl acelale. benzene 33%. acellc acid 10%.


water 6%

Chemical

120

ethyl acelale. esler~hcal~on. aceltic acid glacial


9500 gal. ethyl alcohol 9000 gal, sullunc acid
66Be 25 gal

Chemical

elhyl acelate. loluene. various volalde resms. plasIwers. waxes and lacquers

Solvent
Recovery

20% ethyl acrylate. phosphoric acld 70%. ethanol,


ethyl acetate and acetic acid together 10%

0.0001*

<0.0001
1<0.0001

0.0001

<0.0001

0.0017
0.0014

OOlb

<0.0001

0 0001

<0.0001

<o 0001

<0.0001

(continued)

498

Corrosion

TABLE

4.13:

Corrosion

Resistant

VARIOUS

Materials

STAINLESS

Handbook

STEELS

AND

HIGH

s
.

99% wnyl

acetate

Chemical

acetate

Plast,c

77

162

302

0 00001

254

Chemical

212.
293

vmyl-acetate

residues.

Plastic

220

56%. sollds
butyraldehyde

23%.
1%

water 15%. ethyl acetate


sulfuric
acid 0 5% (vapors)

5%,

56%. solids
butyraldehyde

23%.
1%

water 15%. ethyl acetate


sulfuric
actd 0 5%

5%.

Plastic

I67

56%, water
1% sulfurtc

15%. ethyl acetate


5%. acetic
acid 0.5%. butyrlc actd 0.1%

acid

Chemtcal

I67

acetate
acetlc

Plastic

167

41.42%. acetate polymer sohds 36% ethyl acetate


529,.
water 10% sulfwc
acid 1 3-2.5%.
acetlc
actd 0 2-2 3% (vapors)

Plastic

167

42%.
I 5,.

aud

PMlC
idlstltlatlon)

trace

Chemical
fdtstdlatlon)

acid

1%

47.42%. acetate polymer sollds 36%. ethyl


5 290,
water 10% sulfuric
acid 13.2.5%.
acid 0 2-2 3% (vapors1

water 53,.
ethyl acetate
suifurlc
acid 13%

9%. water 919,,


lcolumn
vapors)

sulfuric

monoethanolamme

pure

2 3%

and

acettc

95.90%

monoethanolamme.

water

95.90%

monoethanolamme.

water

water.

11% monoethanotamme.
water.
ptt IO-IO 5 frebader head)
15% monoethanolamme.
hydrogen sulfide (bottom

acetic

acids

carbon

water. carbon dloxtde


tray of absorber)

0015

0 OBC
0.m

132

II

<o 0001

< 00001

<0.0001

0.0007

0 042d

0.035d

<0.0001

<:0.0001

<0.0001

132

ALLOY
825

<o 0001

<o 0001
0 0002

\:o 0001
s<0.0001

<o 0001

0.0001

0 0004

so 001
0 0003
<o 0001*

0 0006

<o 0001

<0.0001
s<o 0001

0.0002

SO009ld
0 003.d

0.0009

0.0011
so 0017

0.0006

0.0004

I85

0 0061

0 0072

0 0068

188

0 0018

0 0005

0 0005

Chemical

212.
320

Chemical
(dlstdlation)

338

Petroleum

338.
374

36

Petroleum

230.
272

245

2%.

Petroleum

230.
240

and

Petroleum

230

dmxide

dloude

I67

<00001

20

so 0003

(vapors)

carbon

Plastic

TPE

317

I60

10% vmyl acetate,


acettc anhydrlde
50%
ethylldene dlacelate
30%. acetlc acid 10% durmg
186
days. and ethyl acetate.
methylethyl
ketone and
ethanol
together
40%.
water
remamder
during
68 days
sulfuw

TYPE

316

0 0001

(cantd)

rates (ipy)

TYPE

150

Chemical

MOLYBDENUM

304

176

80% vinyl acetate


vinyl propmnate
20% durmg
184 days and ethyl acetate
60%. other organ~cs
lO6. waler 30% during 118 days

28.5%
monoethanolamme.
and hydrogen sutflde

ALLOYS-CLIMAX

Average corrosion

mediums

100% wnyl

NICKEL

180

00001

0 0005

270

0.0004
0.0004

0016~
<o 0001
0.022.
<0.0001

O.Ol7c
<o 0001

<IO 0001

<o 0001
x,0 0001

(continued)

499

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

Test
conditions

Corrosion mediums

15% monoelhanolamme.
Irlethylamme
6%
d~ethanolamme,
mately Ivaparsl
dlethanolamlne.

STEELS AND HIGH NICKEL

ethanol

34%.

monoethanolamme

water

5%

25%.

approw

ALLOYS-CLIMAX

Average

corrosion

rates (ipy)

rwt

,PL

316

317

00001

0.0001

0 015

0 0032

<0.0001

<0.0001

<0 OOOld

<o 0001

xx

i 0.0001

c.0 0001

<0.0001
0 0002

<o

0001

<00001

(0

<o

0002

Chemical

325

102

xx

Chemical

410

30

P&ochemical

212

110

Petro-

200

110

-----

hydrogen

sulllde

hydrogen

sulfide

(heat-exchanger

chemical

30%
dlethanalamme.
voli vol water, pressure
irebolter)

water,
carbon
dtoxide
14
10 ps~g durmg 450 hours

Petroleum

100.
150

83

c.0 0001

30%
voiivol

water,
carbon
dmxlde
30
285 pug durmg 500 hours

Petroleum

IOO230

83

0 0001

0.0001

hydrochlow

Chemical

90.
200

153

0.0009b

0 0004a

Chemical
Idistillation)

338

35.5

0.0009

0.0005

Chemical
tdlstlllatianl

410

30

Chemical

123

102

Chemical

300

xx

24

xx

dlethanolamme,
water. prewre

mono-

ALLOY

TIPI

304

20

825

(dlstdlation)

dlethanolamlne.
bonnet1

trlethanolamme

(contd)

MOLYBDENUM

slurry.

dl- and trlethanolamme,

dl- and trlethanolamine.

acid

water

<O

5%

monoethanolamme

mono-. dl-. and trwthylamw


nol, pressure
175 ps,g

ammoma,

91% 2.ethyl
butanal,
acetals
from glycol and carbanyls
6%,

trace

water.

and ketals
water 3%

etha-

lormed

90% approrimat.?ly2-ethyl
butanol, carbonyls
butylene
glycol
3%. toluene
sulfonlc
acid
copper sulfate 0 09.0.6%

3.4%.
0 5%.

Chemical

300

90% approrimately2-ethyl
butanol. carbonyls
butylene
glycol
3%. toluene
sulfonlc
acid
copper sulfate 0 09-O 6%

3.4%,
0.5%.

Chemical

300

0.0052
0 0016

0.0012

xx

xx

0.017

0.0017
0.0002

0.005

<0.0001

0.0067

xx

0001

00001

0 0001

0 0002

0.0035

IllI

0.00066

0 0028

0 0023

ETHlLENE

ethylene,
cracked
gases
acid trace, hydrochloric
traces, pH 5 approximately

m quench
acid and

water,
carbon

organic
dwxlde

Petrochemical

160.
170

0 002a

0.0005b

ethylene.
cracked
gases
acid trace. hydrochloric
traces. pli 5 approximately

m quench
acld and

water,
carbon

organic
dloxlde

Petrochemical

160
170

0 019bdl

0 007adr

Petroleum

R.T.

0.0004

0.0003

ethylene

dlbromlde

(vapors)

60

_.

0.002

(continued)

500

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

,wt

TIPE

TIPE

304

316

317

2
.

0.021c

0.004c

:
dlbromlde

icolumnl

ethylene

dlbromide

fmlshed

ethylene

dlbromide

crude

fumes

Chemical
id~sttllationl

200.
212

Chemical

85

287

Chemical

80

287

011, steam,

hydrochlonc

Petrochemical

210.
240

79

ethylene dlchlorlde.
acid trace Ivapors)

Pella

oil. steam,

hydrochlortc

Petrochemical

100.
220

79

ethylene
hquld)

dlchlorlde.

dilute

acid (vapors,

Chemical
idlstdlation)

80

108

ethylene

glycol

Pharmaceutical

ethylene

glycol

Pharmaceutical

115

112

Chemlcai

500

42

Research

445

Chemical
Ldistillalionr

475

147

Pharma.
ceutical

221.
257

32

Chemical
(distillation)

212

43

0.108%
Z-ethyl suberlc acid. sebacic acid 0.10246,
diethyl
adipic
acid 0.024%.
heavy organic
acid
0 008%. ndecanolc
acid trace, remainder
water

stearic

acid

stearlc

and oleic acids

steartc

and palmitlc

crude fatty

acids,

acids vapors.

no air Ml

unit)

mixed

-----

<O.OOOlbd

ethylene dlchlorlde.
Pella
acid trace lo11 stripper)

hydrochloric

MOLYBDENUM

<o

-30

112

<:O.OOOld
0.0003ad
0.0003cd

0017

0.006ad

0.0055ad

0.002ad

0.0261

0.015

0.004ad

0 OOOlad
0001

0.0002ad
<0.000l

00001

0.0001

0 0001

0 0001

0015

0.0262

xx

0.0142cd

<0.0001

IIil
<O.OOOlad

<o

0 0086

0 0002
0001

0 0098

...

...

...

...

0.0213d

0.0049d

mixed

Research

230

1.7

0.0305

nil

...

...

soap tatty

acids.

mlxed

Research

250

1.25

0.0218

0.017

...

...

vegetable

latty

Chemical

365.
374

0.0021

0.0007

...

...

Chemical
ldistdlation)

490

42

xx

0.01

0.0001

.. .

..

Soap

530

50.5

0.0383~

<O.OOOlad

...

...

Chemical

170.
200

18

xx

...

...

cottonseed
crude
vacuum still)
cottonseed
vapors from
expeller)

tatty

fatly

live steam

acids

(top

vapor

outlet

of

actds

hot linseed

expeller

cake (Anderson

oil

<0.0001

0 0002a
<0.0001

0 0073

<0.0001

acids,

mixed,

ALLOY
825

0 0005ad
0.0005cd

xx

20

soap tatty

acids,

(contd)

Average corrosion rates (ipy)

ethylene

ALLOYS-CLIMAX

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

acid number

90%
approximately
from anlmal
foot.
vacuum column1

fatty-acids
vapor and
strlppmg
steam
20%

40%
ammal
fatty acids,
vacuum column bottom1
castor-od

fatty

castor-od

fatty-acld

and coconut

free

170

pitch

60%

Rubber

150

hquld
(high-

Soap
tdlstdlatlon)

420

163

xx

fhlgh-

Soap

440

163

acids

F r700

,wt

,,,I

TWE

304

316

317

<O.OOOlad
<O.OOOlad
0.0005
0 00022

<o

condensate

Chemical

75

<0.0001

fatty acids

Soap

Soap

fatty acids vapors from fish 011s

<o

135

1218

<0.0001

160.
200

553

Chemical
Mstdlatlon)

450.
500

210

90% fatty acids. sulfuric acid 5%. sebaclc acid 3%.


sodium sulfate, potasswm sulfate. water remamder

Chemical

220.
240

1:

fatty acids K,
acid 0 I-O 25%

Chemical
(dlstdlation.
estetlflca
tlon)

212

33 3

acid

Soap

215

30

water

Soap

215

57

Chermcal

250

21

acid

Soap

180

crude fatty acids and water alternately


ptt 3 due to sulfuric acid lrom previous

(water has
process)

Soap

60%

acid

I 17%

Soap

actd. sodwm

fatty

acids,

to C,.l,

mamly

primary

stearlc

ddute

alcohols,

acod. ddute

sutlurlc

stearlc

acid

fatty

palmltlc
ImeJ

acids.

acids.

washed,

water

40%.

6O*Be

sulfwc

ammal. vegetal and fish 011s. sulfuric


chloride and sodwm sulfate, pti l-10
fatty acids. nltrdes.
10 ps~g (vapors)
44.3%
mately.

fatty acids,
naphthalene

ammonia

sullur~c
14.3%

lsobutyl
isobutyl

sullur~c

and water,

acid 40 ~01%

and

sulfuric

sulfuric

stearlc and OICIC acids. their methyl and


esters. phosphoric acid, sodium methylate,
alcohol and methyl alcohol traces
stearlc
and
0 5% lllquld

20

ALLOY
825

0001

0 0015

119

stearlc
acid.
Icypress tub)

<o

<0.0001

xx

90% approximattly
5.15%

--

<O.OOOlad

0001

xx

anlmal and coconut


ole~c actds. ptl 3.6

kontd)

(dlstdlatlon)
Pamt and
Varnish
ldlstdlatwnl

ammal

MOLYBDENUM

501

Average corrosion rates (ipy)

--fatty acid Seedme.

Alloys

pressure

0001

<o 0001
<0.0001

0 0001

0 0001

0 0016a

0 00013ad

0 083c

0 256~

0 02

0 02

0017
0.0029

0.0018

II

0001
0 023
O.OC&

o.ooo2
ooao3

xx

oooo4

35

xx

<.OCKlOl

<0.0001

140

730

<0000I
WOtMl2

C.O.0001

212

21

xx

0 0049ad
0057

0.0007d
0.003lad

Soap

I30

I38

xx

0 0021

0.0006

0 0005

0 0006

Chemical

590

51

0071

0.03

0 0083

0 0062

115.
123

30

xx

0.0006

0001

0 0007

250

xx

0 125
0.016
0.039
0012

0.015
0 005

0.004
0 004

approxi.

20-0.02X
mixture of sebaclc, adlplc, stearlc acids
and phthallc anhydrlde, toluene sulfonic acid 0 5%
flwd.
vapors)

45

Chemical

xx

77

xx

0 0045

00016

0.0018

co.0002

<O.oool

(continued)

502

Corrosion

TABLE

Resistant Materials Handbook

VARIOUS

4.13:

~TAIIVIISS

STEELS

AND

Test
conditions

Corrosion mediums

20.0.02%
mWwz
01 sebaclc, adlplc. stear~c
and phthalic
anhydrlde,
toluene sulfonlc
acid
(Ilqutd. vapors)

suds
0 5%

Chumcal

saturated
acid 2%.

10X,

5%.

ammonia.

lernc.hydroxlde
ptl 3.5

cltrlc

waler

slurry,

approximately.

solution,

30%.
chlwc
(Iliter

orgamc
wasles
5%.
acid 0 5%. abrawe
pressl

16 5% approximately.
lead bon 0.07-2
mn 0 07 g/l as chlorides,
pti 1 2

62%.

water

77

61

corr

corr

216

106

Chemical

60

Metal
iplckhng)

170.
210

38

Chemical

65

32

xx

<o

Mlnmg

150.
168

?I

xx

c.0 OQOI

hydro-

Chemical

275

xx

0 0046

hydropH 1

Chemtcal

175

IO

xx

150

I 75 -

xx

Chemical

75

5 g/l,

tm

20

ALLOY
825

0 0007

0 0004d

xx

0001

275x

300.
570

340

xx

0.28%. catalysts
m reactton product
ketone and a dlamylamme.
pressure

01 an allphatlc

Chemical

300.
570

84

xx

0.28%.
ketone

of an ahphatlc

Chemical

300.
570

55

xx

Metal

90.
130

I6

xx

<.0 0001

0001

(0

<0.0001
<o

<0.0001

0001

c<0.0001
<o 0001
c<o 0001

0 0014cd

0 003b

0 0012cd

O.OOlcd

co.004
co.039

0.006
O.Oga

0.00015ad
0 00015ad

0001

0.0054

0.0017cd
SO 0029cd
L0.0017bd

<O OOOla
<O OOOla

(0

c nrl

OOOld

(evaporatmn)

(pIcklingI

corr

0 0005

0 001

pti 2 5 (evaporator.

,o

xx

Chemical

agents.

(mtd)

0 145

of an allphatic

of wettmg

0 0008

x-

0 28%. catalysts
m reactmn product
ketone and a dlamylamme.
pressure

24%. trace
crystalluerl

0 003
0001

solutmn

catalysts
m reactmn
product
and a dlamylamme.
pressure

0021
0 003

Chemical

ac!d 43 g/l

resorcmol
3%,
won restdue.

xx

sulfuric

solution,

,PE
317

AT.

mns present

saturated
ferrous-chlarlde
water
chlorlc acid 0 09% (evaporator)

46

,wt
316

water

sulfunc

250

,wt
304

Research

acid

acid 0 5%. copper

lerrnoxlde

1.4%

fatty

MOLYBDENUM

0 007
0 002

10%

chloride,

ALLOYS--CLIMAX

Average corrosion rates (ipy)

lerr~c

NICKEL

HIGH

0 003
OOOla

<O OOOla

<O OOOla

0 0003a

<o

O.OOOla

0 OOOld

OOOld

0 0001

(continued)

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion medrums

&
.

P
up

3
$

sg

<z

Metal

122158

20%. lelnc sullate


sodwm hypochlorlle
lcypress tank)

Chemical

203

18

Metal
tplckllng~

180.
210

Metal

120

10%.

sulfuric

ferrous

agents.

actd 5%

pH

2.5

hydrafluorlc

Ievaporator-

acid 5%

lerrous
PH

1.7

xx

TIPE

TWL

304
-----

316

317

5 12

11.5ad

xx

0.19c

0 07cd

xx

0 0006cd

0.0003d

xx

0 393

0.191

acid

waste

pickle

Ilquor,

Metal
lpxklmg)

140

67

sullale.

sullur~c

acid,

waste

pickle

hquor,

Metal
iptcklmgt

100

67

Pamt

162

27

xx

xx

ferric

sulfate

sulfuric

acid.

weak ferrous sulfate


solution
ferric sulfate and dllule sullur~c
sel. llqutd mterlacel

lme
Iton

I6

TPE

4
.

sultur~c

4%.

xx

sullale,

PH 1

lerrous
sullldes.
INme. pH 9

commercial

fertdlzer

rock

pH 2 5

possible
traces
of
aud (pressure
yes-

with

Swifts

0 03

5-10-5.

lb/ton

solu-

sometimes

(contd)

20%
sulfuric
acid 19 5%. lltanwm
dloxlde
10%
as sullale,
sohds 2-396. l~tanwm
(3) !on 1.7 g/I as
sullale,
hydrogen
sulflde trace (Oorr settling
tank)

wetl~ng

MOLYBDENUM

16.18;
sodurn chloride
10%
0 5-l 96. hydrochloric
actd trace

ALLOYS-CLtMAX

Average corrosion rates (ipy)

16%. some
crystalllrer~

NICKEL

503

Pamt and
Varnish
Icryslallua.
IlOll

450

33

0 0002cd
so 0007C
0.0002b
S0.0004b
LO 0008b

0 00018ad
so 00021

0.0005cd
s0.001*c
0.0005cd
S0.0007cd
LO.OOllbd

0.0004cd
50.0004b

0.017
0.017

0.0107

91

22

xx

xx

Agriculture

RT.

290

xx

Research

100

28

Agriculture

100

Agrulture

Agrwlture

Chemical

F (250

ALLOY
825

CO 05cd

0 0002

0 000 I3ad
SO 00015ad

0 0002cd
0 00025cd

0.0003

0.0006cd

0 0006

Mmlng

20

0 0003

0.0005

<O.OOOld

<O.OOOld

xx

0 0001

0.0001

14

xx

0.0001

135

28

xx

0 0001

135

28

xx

00122

00111
0 0206

damp
lert~l~rer,
waler
67 89%.
75%
phosphoric
II 16%. potasswm
chloride
9 7%. anhydrous
moma 2 45% lhall Immersed)

hquld

lertdtzer

fertduer.
16.74%.
ammoma

Nllrana

(half

acid
am-

immersed)

waler
65 05%.
15%
phasphow
acid
potassum
chloride
14 54%.
anhydrous
3 67%. pH 6 6 (half Immersed)

fertduer.
water
52 43%.
75%
18.6%
ammomum
mtrate 9.34%.
Ide 8.08%. urea 1.47%. anhydrous
DH 6 5 (half Immersed)

phosphonc
acid
ootassum
chlor&non~a
4 08%.

mued fertduer.
superphosphate,ammonum
sulfate,
potaswm
chloride,
sand, ammoma,
ammonium
mIrate and sulfuric
aud

56

<0.0001

0 0015cd

WI

0 0001

<o

0001

0 0002bd

(continued)

504

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TIPI

Agrlcufture

60.
80

Chemical

menhaden
fish sllckwater.
peptones.
ammoaclds.
gelatme-hke
materials,
sodwm
chloride,
calwm
and magneuum
salts, audIbed
with sullur~c acid to
pH 5 lsmgle eftect evaporator1

Agriculture

menhaden
fish stlckwater,
sohds 4 9596 acldlfled
to pH 4 5 wth sulfuric acid ItrIple etlect evaporator)
rdpurs
frow menhaden
llsh
4 95.,
sollds and acldlfled
pti 4 5

.
x

a4

90

105

185

30

Agriculture

212

28

Agrwlture

212

28

XX

llntreated
menhaden
llsh stickwater.
caustic bollout
15, washedwth
hydrochloric
acid S%tevaporatorl

Agriculture

200.
220

51

bsh stlckwater,
fural: acid 2%

Agrulture

124.
200

41

Agriculture

200

51

Chemical

RT

32

Metal

200

137

Chemical

75

30

24 1%

Research

175

IO

24 7%

Hesearch

175

Metal

95

137

Chemical

220.
250

013-

220
250

013xx

Metal

120

Chemical
ldlstdlatlon)

490

Uran

32,

condensed

fish solubles.

Feran

stackwater.

aLld to pti 5 3 (double

acid.

boric acid

1%. sol-

acIdtIled

eftect

alunwwm-hydrate

wth

sol-

/II organic

304
-----

TIE

TWE

316

317

LO

<0.0001

<0.0001

<0 OOOld

<0.0001

~.00001

00001

XX

<o

0001

<o 0001

xx

<o

0001

<0.0001

~<0.0001

O.OOOlbd

ALLOY
825

0001

LO 0001
<:o0001

xx

20

<0.0001

<0.0001

0.0001

<o 0001

evaporator1

slurry.

ptt

I 9 2

I 5%

lree hydlsfluorlc

1%. dispersed

0 99%.

8 30%.

chloride

bortc acid 7 099;

fluoborlc

3 84%.

sollds

stlckwater
contalnmg
wth
sullur~c
acid to

colltammg
sodwm
Itubular evaporator)

furlc

32%.

N~trana

pfi 4 2

fIsti

64.2%.

21.

(amd)

Average corrosion rates (ipy)

.
lerf~hzers

MOLYBDENUM

acid trdce

pti

I7I

medium

pH 3 2-3 4

fluosullomc
waste acld contammg
chlorme.
chlorine
oxldes and sulfuric
acid IO-25 ~01% added lstdl ootl

some
acid.

oxygen,
sulfwc

127

44

0 066

xx

xx

0 0016cd

CO.OOZcd

0.0044a

0.0037

co.0021

0 221

0 0472
wo 052
0 0309

xx

xx

xx
0 0053c

0.0023cd

wo 0475
0 0467

0 0003d

CO 0015d

00013

0.0008
c0.0006

0.0003d

0.0013

0.0055c

0 tic
SO 027~

0.29c

0 92c

0 0104cd

0.0009cd

0 43c

0 49c

0.029c

(continued)

Ferrous

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

Alloys

MOLYBDENUM

505

bntd)

Average corrosion ratesiipyi

TrT

304

9
.

I
f

9
.

TIM

TIPE

316

317

20

ALLOY
825

FLUX

25%

zmc.chlorlde

llux.

PH 4

soldermg-flux
solutmn.
zmc
chloride.
water [half ImmersedI

alummum
brazmg
ftuorlde
or sodun

FOOD

chloride.

ammonium

flux
llthwm
fluoride.
sodturn
chlonde
ialternately
immersed)

75.
80

56

Chemical

60

60

_-

Metal

800.
1300

Food

212

Food

175

Food

45

xx

>0

56

0.003

0 044c

0.018c

>0.56

BRINE

Prague pickle solution.


dun nltrlte 6%. sodurn
and glycerme

sodurn
mtrate

chlortde
889,,
so4%. some dextrose

vapors arwng
from Prague pickle solution.
chloride
88%. sodwm
mtrlte
6%, sodium
4%. some dextrose
and glycerme

meat-curlog
solution,
salt
4 lb, sugar
Prague curmg powder kontams
sodurn
trite and chtorldei
0 28 Ib,l gal water

brme solutmn,
<020
pH557

otwe

Metal

brme

90.80%.

sodwm

contammg

vacuum

04%

lnorzle

73%

(Paralorm

chloride

lactic

25.10

mercury

on side of Paraform

flrst.rtage

70.30%

formaldehyde
65.45%

acid.

2.3%.

sodurn
nitrate

0 24 lb and
nitrate,
I-

mallc

acid

salt and water

tParaform
evaporator1

evaporator)

rebollerl

evaporator)

0.0005cr

xx

0 0004

<<O 0001

<o OOOlr

.<o 0001,

<o

0 OOOld

0 OOOld

nil

rlll

43

Food

66.
75

95

Chemical

180

115

xx

Chermcai

190.
200

35

xx

0 0001

0.0001

Chemical

150

64

0 0001

0.0001

Chemical

130.
140

99

80

30

<0.0001
0.0003

xx

170

xx

37%

Synthetic
ReWl

75

41

20%

Chemical

275

71

xx

176

996

15%
tower)

0 0001

70

Chemical

10% lfractlonatmg

0 0001

Chemical

220

a7

xx

210

560

<0.0001

<0.0001

,.o 0001

c0.0001

nil

<0.0001
0.0002
<0.0001

0.0001
<O.OOOl

00001

<0.0001

0 0004

0.0006

<o 0001

0001

0 0001

<o 0001
0.0005

Rayon

6.7.1%

Chemical

283

xx xx

0.0004

0.0004

3.5%

Chemical

285

58 xx xx

0.0002

0.0001

nil

0.15%

Chemical

297

5.8

0001

0 0001

ml

<o

<00001

<0.0001

5%

x xx

<0.0001

OOOlr

Food

solution

(Paraform

0.0001

xx

(conbnued)

506

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

trmxane.

lormlc

65.50%.
fornuc
water remainder
65.50%.
water

sullurlc

W-SO%.
water

sullunc

60.40%
sullur~c

acid

acid

acld

lormaldehyde

Chemical

245.
265

125

0 0023

00183

15

xx

0 0982

0 0398

220.
225

10

2.4%.

formic

acid

l-3%,

Chemical

220.
225

18

Chemical

220.

0 03

20

0.0244~

Chemical

0.5-l%,

0 01

ALLOY

--

xx

2.4%.

acid

TtT

317

acid

formz

xx

nst

316

00313

sulfuric

2.4%,

TWL

304

xx

1%.

to

acid

0 01%

hmtd)

Average corrosion rates bpy)

---

99.5%
trace

MOLYBDENUM

825

00214

225
formaldehyde
acid 1.3%

vapors,

formic

t-4%.

Chemical

222

30

xx

0 024

0017

lormal.
05%.
acid as
2 8

Chemical

250

33

xx

0 0003

0 0007
0 0003

00001

Chemical

250

33

xx

0 0423

0 0023
0 0029

0 0023

Chemtcal

120

189

Rayon

245

556

acid trace

Chemical

437

859

acid trace,

Chemical

acid

57.5% approrlmately
tnoxane,
water 40%.
dehyde 2%. methyl
lormate
and methylal
total acldlty
as lor~mc acid 0 5%. mmeral
sullur dloxlde 0 002%
oxygen 6

I ppm.
pH

50.40%.
total acldlty as lormlc
4 8 ppm, mmeral
aud as sullur
water remamder.
pH 1.9
48.37%.
47 5%.
amount

methanol

aud 2 9%. oxygen


trioxlde
00001%.

8% max. lormlc

acidity
as
unsaturates.

46%. water 28%


lscrubbmg
column

acid, pti 3-5

lormlc
acid 0014%.
water remainder

methanol
bottom.

26%. lormlc
gas stream)

42%. water 38.. meLhanoI 20%


pH 3-3 5 irectkatlon
column)

form!c

23,, lormlc
bottom)

25.20%.
column1

remamder

water

167

xx

\ 00001

Chemical

acid trace

158

xx

<o ooota
L~.oooolc
s- OOGOI

00001

859

859

xx

c on001
L* 00001
s< 0 0001

tpurlbcatlon

37 5. water
22 8%
formaldehyde
gas, nitrogen
194%
methanol
IO 1%. hydrogen
8 3%. carbon
dloxlde
carbon monoxide
0.1%. formic
acid
trace iplpel

RayoIl

285

b21

Chemical

878

Chemlcat

Chemical

<o 0001
0 0002d

0 0032d

L<- 0 0001 d
So. 0 0001

40%. water 37% methanol


pH 3-3 5 lscrubbmg
column

011s and

small

-~

xx

63

xx

280

306

235

198

Chemical

225

Chemical

Chemical
Iconcentra.
IlOll)

00001

~.00001

L 00001

00001

L._0000l
I

00001

L. 00001
oooot

0001

co 0001

xx

0 0007d

<0 OOOld

0.00081r

<O.OOOld

198

WI

<O.OOOld

245

179

xx

275

27

xx

Chemical

264

114

xx

Chemical

140

444

xx

;o

I896.

22%.

lormx

acid C 076%.

20%.

water

80%.

20%.

water

80%.

tormlc
lormlc

water

remainder,

pH 3

acld 0 1%
acid 0.1%

nil
18%.

lormlc

15.12%.

14%.

aud

lormlc

water

formaldehyde.
denser Inlet

81%

0 1%. glycols

remamder

acid 2%

methanol

3.4%.

methanol.
tormlc
of gas stream1

pH 3 6
acid

iprlmary

con.

0 0002d

<O.OOOld

0.073

0 0006

0001
L~:0.0001
s<:o 0001
c.0

0 04

0001

<00001
L<00001

(continued)

507

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

Formaldehyde

water

MOLYBDENUM

bntd)

Ei

TYPE

TYPE

TlPE

304

316

311

00001

< 0000l

20

ALLOY
625

mt~tures

99%.

methanol

0 770

Rayon

4.6%
2%. lormaldehyde
water remamder

0 5-l 596. resins.


(tower)

1%. formaldehyde

1%

water

formic

acid

formaldehyde

larmlc

acid

hydrogen

0.2%.

water

99.696,

higher

remamder.

glycols.

338

Chemical

300

27

Rayon

298

Chenwal

220

160

90

koncentratmn1

pH 3

peroxlde

unknown

naphthalene

(column,

Chem!cal
Idlstdlatvxd

anthracene,
phenanthrene
creosote
residuals
(column,

Chemical
(dlstdlationl

lormlc

453.5%
Mural
vapors,
sollds 0 01-O 02%
traces
acid and acetaldehyde
4.5.3 5% furlural
sollds 0 01.0.04%.
and acetaldehyde
4.5-3 5% lurlural
sohds 0 01-O 04%.
and acetaldehyde

60
4.6

43

0 073c

0 063~

0 0184
woo113

0 004
woo113
L0.0007
wto 0004

0 0024

00001

, 00001

0016C

0 0002d
x.0 OOOld

0 0001

0 003c

00001

244

40

<o 0001

00001

Chemical

338

acetlc
aud
1.752.5%,
of lormlc
acid. sullur~c

Chemxal

330

70

0 002

00001

vapors,
traces

acetlc
acid 1 75-2 5%.
of sullur~c.
formic
acids

Chemical

330

82

0 0029
0 0002

vapors,
traces

acetlc
aced 1.75.2.5%.
al sullur~c,
larmlc
acids

Chemical

330

71

0 0044

4 5 3 5% lurfural
vapors.
acetlc
sollds 0 02-O 08%. sullur~c acid,
acid and acetaldehyde

acid.

acetlc

acid

1 75-2 5%

0 96

0 63

0 0001

0 000 1

0 0009
0 0001

0 0003
u 0001

0005
00001

0 0002
0 0001

corr
0051

0 0009
00017
0012

00012
00313
0 0088

0 0002
0 0036
0 0024

0 0002
00011
0 0009
0 0001
0.000 1

40

0001

Chemical

298

108

0 0018
0.0001

0 OOIR
0 0001

0 0004
0 0001

0 0004
00001

acetic
acetal-

Chemical

208.
220

132

0.0001

0.0001

0 0001

0.0001

0.0001

ktrlp-

Chemical

208.

132

0 0001

0.0001

0 0001

0.0001

0.0001

acid 1.752 5%.


traces of lormlc

vapors
and condensate,
traces 01 formic
acid and
column)

0.0004d

0.0001

\o 0001

levul~n~c

0 OOlrd

0 0003d

40

some

lurlural
restdue. sullur~c acid,
acid 33.. pressure
100 ps,g

lurlural
condensate.
pmg column bottom)

296

0 14c

226

mixture,

lurlural
water
mixture,
carbazole
and other
vapors)

4 5 3 5% Mural
acid
75-2 5%.
dehyde tstrlpplng

Chemical

lurlural-water
VapOrsI

266

Chemical

0 2%. pH 3 8 average

ALLOYS-CLIMAX

Average corrosion rates (ipy)


S

0.3%.

NICKEL

(continued)

508

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

(contd)

MOLYBDENUM

Test

Average corrosion rates (ipy)

conditions

Corrosion mediums

coke-oven
gas, leavmg sulfate
some sulfwc
acid tar trace
mixed
sullur

gases,
dloride

dlgester

air 86 5%
2% water

gas lrom

moisture,

hydrochlonc
lb.
sulfuric

dlgestlon

drier exhaust
air. wdtef
0 06vz sodturn Iluosllxate
acid a!r remamder

saturator,

acid
acid

of rnllk waste

3 19%. hydrochloric
acid
with 0 369; hydrochloric

gases contatnlng
caibon
dloxlde,
water,
volatlles
and spray rondensate
contammg
acid as fluorine compounds

GAS.

tlue

10%.
0 5%

fluorine
2%

Coal Byproduct

140.
158

I33

xx

0 0005cd
0.0008cd

0 0002

Chemical

150.
550

42

xx

xx

0.092cd

0.03bd

oa1ry

100.
II0

79

O.OOOlcd

Chemlcdl

F 100

26

xx

xx

0.015
0 013.a

0014a

Chemical

175

52

xx

xx

16

0.057r

Chemical

a50

30

xx

0.14

0.054

Research

ao400

oooo2

0.ooo1

Chemical

335

60

0.0097

0.0009a

Power

340

<0

<0.0001

0.0037

FLUE

gas, dry

llue gas.
luel gas

sullur

25 grams

1000

llue gas. nitrogen.


oxygen.
dloxlde.
sullur lrmxlde
lheat

cu II of lOOO~BTlJ

carbon
monorlde
exchanger1

and

flue gas and condensate.


sulfur dloxlde
0.1 ~1%.
sullur~c acid 50-75 lb/ hour. sobd fme ash 20 lb/ hour

250

240

xx

xx

xx

xx

<o.Giw

<O.oool

o.oao7

<0.0001

0.0022a

<0.ooo1

O.W21a

<0.ooo1

Mler)

flue gas. carbon dmxlde


14%.
acid trace. remamder
nitrogen.

oxygen 2%, sulfuric


some moisture.
soot

Chemical

100

138

flue gas. carbon dmnde


actid trace. nttrlc
acid
some moisture.
soot

oxygen 2%. sullur~c


remamder
nitrogen.

Chemical

90.
I30

140

Bunker C luel-011 combustmn


condensate,
sullur~c.
sulfurous
acads and anhydrldes,
other combustion
products,
no adddIve
used

Power

flue gases from kiln burnmg


water, some vanadates
lbollerl

water

Power

flue gas lram


boder
bred gas contaming
sulfur
dloxlde and trwde.
water and some vanadates

Power

llue gases from kiln burnmg


Bunker
vapor lrom wet dlatomaceous
earth
wth lmpurltles
lrom raw sugar Ilquor.
chamber)

Sugar

Pulp and
Paper

14%.
trace,

Bunker

C ml.

C 011, water
Impregnated
pH 5-6 (dust

flue gas. nitrogen


78%. carbon dloxlde
18%. oxynen 2%. sulfur dloxlde
1%. sulfur trmxlde
trace
hydrogen
sulbde
trace,
chlorides
0 05%
some
magneswm-oxide
ash suspended.
and solution
con.
tammg
sullur
trmxlde
1%. sullur
dwde
combmed wth magneswm
oxide 0 5%. pH 5-5 5. but
3.3 5 durmg 60 days

91

xx

xx

<0.ooo1

0.004c

<0.0001

0.004c

<O.OOOl

0 027cd
0.027cd

0.03lcd

0.006

0.043
0.051

0.0246
0.0333

0 0027
0.0029

158

xx

330

158

xx

60.
130

31

xx

500

<oOOolc

0.01 Ic

xx

360

535

0.013c

xx

<00001

0.0002c

<0.0001

<0.0001

0.0042cd
0.003acd
0.0027cd
0 0036cd
CO 0012cd

0.015c

<C.oOOl

<00001

0 0019cd
0 0024cd
0 0016cd
0 0049cd

<0.0001

0 0031bd

0 0026bd

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

509

Alto ys

MOLYBDENUM

(contd)

Average corrosion rates (ipy)

IL

2
;

TIM

TIPS

TPl

304

316

317

ALLOY
20

625

combustmn
gases from
natural
gas and sulfurbearing 011. water vapor 50% approximately
karbonblack bag collector)

Chemical

460

240

rombustlon
gases from
natural
gas and sulfurbearmg 011. water vapor 50% approximately
karbonblack bag collector)

Chemtcal

410

224

combustion
gases
from
natural
gas and sulfurbearmg 011. water vapor 50% approximately
tcarbonblack bag collector)

Chemical

340

271

tlue gases, products


ot combustion
of sultwc-aciddlgested
corn cobs, sulfur
trloxlde.
sulfuric
acid.
carbon monoxtde,
carbon dloxlde.
ndrogen,
oxygen,
water (heat exchanger1

Chemical

400.
450

73

xx

0.007bd

0 0078cd

0 0068cd

0 009cd

0 0075cd

llue gases, products


ot combustion
of sulfwc-aciddlgested
co, cobs. sultur
trloxlde,
sulturlc
acid,
carbon monoxide,
carbon dloxlde.
nitrogen.
oxygen,
water (heat exchanger1

Chemical

250.
215

71

xx

0.0072a

0 0063cd

0 0054bd

0 0071cd

0 0051cd

flue gases, products


of combustion
of sulfurlc-aciddlgested
corn cobs, sulfur
trIoride,
sullur~c
acid,
carbon monoxide,
carbon dtoxlde,
mttogen.
oxygen,
water iheat exchanger1

Chemical

300

71

xx

0 0008

<0.0001

~0.0001

<0.0001

<0.0001

flue gases. products


of combustion
ot sulfuruaclddlgested
corn cobs, sulfur
trloxlde.
sulfuric
acid,
carbon monoxide,
carbon dloxlde,
ndrogen.
oxygen,
water (heat exchanger1

Chemical

300.
400

71

xx

0 0004

<o

<o

<o

<o

llue gas from combustion


ot Ohlo strip-mme
coal.
BTUfb
12800,ash
129b.sulfur
2 5-4 5% (au heater1

Power

240

197

xx

xx

0 0022

0 0021

flue gas from combustion


of Ohlo strip-mme
coal,
BfLl lb 12800, ash 12%
sulfur
2 5.4.5%,
sulfur
dloxlde
0 18-O 25 voloO. flyash 1% m the gas IN
heater1

Power

195

270

xx

0.001

0 0014

flue gas contammg


sulfur
dloxlde.
combustion
products
of destructwe
dlstlllatlon
of furlural
restdue. llquld
runnmg
down the mst
ellmmatur
has
ptt 2 torganlc waste mcmeratorl

Chemical

500

50

xx

xx

tuel-od combustion
products,
carbonate.
calcmed
alumina
scrubber1

Chemical

200.
425

20

xx

xx

0.0002bd

Publtc
Works

21

xx

xx

0 006

0.005

Chemical

200

30

xx

0 029

0013

Chemical

120

30

xx

0 043

0011

Fertduer

131

58

xx

xx

0 0001

0 0001

0.0001
c0.0001

00001

Mmmg

170

180

0 0001

0 OWI

0.0001

0 0001

wet flue gases, carbon dloxlde


14%. oxygen 2%.
sulturous
acid trace, nltrlc acid trace, soot trace,
nttrogen remamder

Gas
purlflca.
t1on

90.
130

65

xx

0.022c

0.003c

alummum
Soderberg-pot
gases and water scrubbing
sprays. some tfuorme and sulfur dloxlde. pH 3

Chemical

120

57

xx

0 003
0 0014a

0.001
0.0008

tlue gases (from

tlue gas, water

mcmerator)

sprayed

tlue gas, m spent


kdn

sulfur dloxlde. sodturn


m suspension
tgas

scrubber

gas saturated

wth

water
water

vapor

irotatmg

water

vapor.

sulfur

disc

_-

,_,o 0002a

c OOOOla

OOOOla

<o

0001

<O.OOOld

<o

<o

OOOla

<o.o001a

,O

0001

0.003
0 020

~.0000la

<00001a

0001

(0

<0.0001

0001

<0.0001

0001

saturated

wlh

dloxlde

0001

<0.0001

0001

0 0003

0 0003

0.0005

0 003
0 017

0 003
0 018bd

0 002
0013

0 005

0.007

<O.OOOlad

type scrubber1
hot gases
2.4%

0001

0.0001c

0 OOlc

(continued)

510

Corrosion

TABLE

Resistant

VARIOUS

4.13:

Materials

STAINLESS

Handbook

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

NICKEL

MOLYBDENUM

ALLOYS-CLIMAX

bntd)

Average corrosron rates (ipy)

TYPE

304
-----

Twt

TIPE

316

317

ALLOY
20

825

Petroleum

100

487

traces

Petroleum

100

400

I 0000l

hydro

Petroleum

100

250

0 001

0001

0 0007

hydroxide

Petroleum

270

28

0 085~

007lc

0 0023a

alkylate.
butane and Ilghter.
sulfur dmrlde
and trioxode. water, pressure 200 PSI bpors,
hquld)

Petroleum

128

384

cracked
reduced
pawer

Petroleum

300.
350

123

Petroleum
llractmnat1on1

270

330

sulva.

Petroleum

F ~720

psi

Petroleum

325

Petroleum

Petroleum

hydrocarbon
gases C, to C.. catalytic
cracked gasolme and water 50 gpm, carbon dloxlde
~01%. carban monoxlde
hydrogen
sulfide 0 2 vol%
oxygen \ 0 05 vol%

hydrocarbon

mixture.

hydrofluorlc

95 Iso feed lo alkylation


of condensate

reactor

86% lsobutane
r,-butane
fluorlc acld 2.3%

9%.

011 contalmng
solution
3%

hydrofluorlc

acid 2.6%
contammg

propane

acid,

2%.

sodwm

gasolme
distdlate,
from
crude cracklog,
pressure
teboderl

both gas od and


100 PSI (depro-

process
stream
through
fluId
catalytic
umt. hydrogen sulfide 1 mol% m vapors

hydrocarbon.
some organx
Ilde. pressure
(150
PSI
pars. Ilquld)

cracking

acid and hydrogen


(evaporator
tower.

0 0004cd

L<O

<0

53

<O.OOOla
to 0001

0 0005

c.0 0001

0 002

318

0 OOlcd

0 0002cd

150

318

0 0002cd

105

441

Petroleum

110

317

<0.0001

<o

hydrocarbons.
water.
hydrogen
<l 5%. hydrogen
sulfide
mtrogen,
carbon monoxide
and dnxlde.
together <:I%
Ivapors)

Petroleum
ilractlonatlon)

270

640

<o

<0.0001c

100%
tray1

Petroleum
(fractIonaIIon)

760

252

Petroleum

780.
785

Petroleum

Petroleum

Petroleum

gas condensate
stabtllzerl
hydrocarbon.

lor

water.

gasolme.

reflux.

pressure

pressure

hydrochloric

100 PSI (crude

acid,

chlorides

I ~0196,

crackedod

vapor,

decomposttmn
products
tor tower bottom)
restdue
grawty

sulfur

05%

01 cracked

from cracked
gas 011 and
9 API. sullur 1% Ievaporator

hot lopped
crude
lbottom
of hot.od

011. sullur
separator)

gasolme.
speck
gravity
hydrogen
sulfide
00029
stbly some ammoma

105

05%

(tower

top

gas od tevapora.

vapor.
tower

speclflc
bottom1

approximately

82 API, sulfur
0.021%,
Ibibbl.
waler trace. pos-

WLO 0016c

OOOlc

co0001

<o 0001

(0 0001

0001

stabdlzed
slralght-run
(crude stabdlzer)

<co 0001

s-0 0001

0001

OOOld

0 0003ad

0 0004bd

<o

OOOlc

0.0075c
WO.0203~
0001

0 0027

0 0006

58

0 001

0.0014

780

74

0 001

0.0009

725

100

0 0013

0 0008

225.
250

359

0.0012cd

0.0005cd

<o

0001

co

0001

,.

(continued)

Ferrous

TABLE

Corrosion

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

TVPE

vapors from
ge
sulfide.
chloride

Petroleum

300

Petroleum

245

258

hydrogen

Petroleum

60

305

and chlorrdes

Petroleum

390

167

Petroleum

240

prunary drstrllalron
of crude od. hydra
hydrochlorrc
acrd and amrnmonrm

mrd contment
crude
ammonrum
compounds
Hop of tower1

011, chlorrdes
concentratron

and sulfides.
0 05N. pH 7-9

gas 011. specrfrc gravrty 40.45


sulfide. carbon droxrde trace

API,

sour naphtha,

sulftde

water.

hydrogen

gasohne
vapors
treated
It/hour
ltop of tower1

wtth

some

ammoma

46

hydrocarbon
vapors, water, hydrogen
sulfide
pprn hydrochlorrc
acrd <I 3 ppm (between
stages
rn overhead
condenser
from
crude
tlonatorl
crude oil. superheated
some naphthenic
acrds

hydrocarbon
hqurd and vapors
trllatron
of crude od. chlorides
sulfide 5-10 glbbl (top tray)

strarght-run
gasohne
lrqurd reflux)

WPE

317

xx

0 0032bd

0 0016bd

0 0004cd

< 00001

0 oolxc

<0.0001c

355

--

xx

0 0064~

~ OOOOfd

drstdlate

Petroleum

285

430

am
ttop

Petroleum

334

411

<20
two
frac-

Petroleum

180

137

Petroleum

690

175

Petroleum
fdistrllation)

300

329

Petroleum

195.
219

156

II3

130 ppm. phenols


column.
reflux dts-

strarght-run
gasolme.
water,
sulhde and hydrochlorrc
acrd

reduced
redwater
sulfur compounds,

TIPE

316
O.OOOZbd

Icontd)

rates (ipy)

0 0004cd

MOLYBDENUM

511

20

ALLOY
825

c.00001

0 0056~

245

hydrocarbon
stream,
chlorrdes
45 ppm. sulhdes
trace lprrmary
trrbutor
above top tray1
high end pomt
mow
hydrogen
01 tower1

304
-----

Alloys

steam,

m atmospherrc
drs10 gibbl,
hydrogen

hop of tower,

vapors,

x-

0.0002

O.OOOSbd

xx

<0.0001

-10 OOOld

<o 0001

tO.OOO1

0.0002ad

<0.0001

0.004a

0.003a

xx

0 0056b
0 Ollc

0.005c
0.0093c

O.OOla
0 OOla

0.0009a
0.0006a

<O.OOOl

hydrocarbon,
concentratron

short charn, hydrogen


chloride
(tower. condensate
receiver)

rn low

Chemrcal
lfractronatlonl

85

hydrocarbon,
concentration

short chant. hydrogen


chlorrde
(tower. reboder sectron)

rn low

Chemical
lfractionabon)

355

113

xx

<o

0001

<0.0001

<0.0001

hydrocarbon,
cancentratron

short charn. hydrogen


chlorrde
(lower, reborler sectronl

rn low

Chemrcal
tfractronatlonf

470

I13

xx

<o

0001

<0.0001

<0.0001

Petroleum

270

I68

0 0003a

0.0002a

crude

or1

0.0007a
0.0004a

drstrllates.
water, hydrogen
acrd traces, pfi 6 5-7

sulfide

and hydrochlorrc

Petroleum

250

412

xx

0 0002a

0 OOOla

0.0002a

drstrllates.
water, hydrogen
acid traces, pH 6 5-7

sulfide

and hydrochlorrc

Petroleum

175

412

0 OOOla

0 0001

0 OOOla

hydrogen

Petroleum

190

I28

xx

0.0004ad

00002ad

0 0003a

overhead from crude-on


fade, hydrochlorrc
acrd

fractronahon,

sul-

(continued)

512

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TYPE

1VPE

,PE

316

317

strarghtrun
gasohne liqurd and vapor, gravity 61
API. water, hydrogen sulfide. some ammonium chlorrde. pH of condensmg water 8 (heat exchanger1

Petroleum

260

165

xx

0.0004b

0.0003

Stralght-run
average

API

Petroleum

240.
375

76

xx

O.OlZcd

0.006gcd

acrd and

Petroleum

250.
260

116

xx

0.0034a

0.0012a

Petroleum

342.
352

132

-.

xx

0 007ad

O.OOOlad

sul.

Petroleum

268.
378

189

0.003lc

0.0022c

36 API average,. pH 7-9

Petroleum

245

315

xx

0.0009cd

0 0003cd

crude or1 from varrous sources, hydrogen sulfide and


hydrochforrc acrd rn various concentratrons,
not desalled:mhrbdors
added flop tray of fractionator)

Petroleum

150.
270

330

0 002

0002

butane, propane, ethane, hydrogen sulkde.


ammoma. cyanrde (overhead condenser)

Petroleum

130

160

xx

Petroleum

ZOO375

116

xx

0.018r

0.009r

Petroleum

140.

116

xx

0.0016cd

0.0008bd

216

xx

106

xx

xx

malsture,

strarght-run
gasolme,
hydrogen sulfide

some

gravdy

35.5

hydrochlarrc

crackmg
of Wyommg
sour crude
hydrogen sulhde 0 106%. mercaptan
total sulfur 0.27% (top of tower)

or1 containing
sulfur 0 066%.

condensmg vapors contarnmg waler, hydrogen


fide. mercaptan sulfur and fixed gases
mrd-contment
(top of tower)

hrgh-end-pomt

low-end.pomt

crude, gravdy

gasolrne,

gasoltne.

hydrochlorcc

hydrochlorrc

water,

acrd

acrd

(amtd)

Average corrosion rates (ipy)

304
-P--P

gasolme,

MOLYBDENUM

<0.0001

20

ALLOY
825

<0.0001

255
low-end-pomt

gasolme.

gasohne. wdh normal


top of tower)

hydrochlorrc

hydrocarbon

acrd

fractmns

Petroleum

Petroleum

Petroleum

115

640

xx

bot-

Petroleum

370

165

55,

Petroleum

200

68

sec-

Petroleum

700

750

(vapors.

hydrocarbons,
water, hydrogen < 1.5%.
hydrogen
sulfide,
nrtrogen.
carbon monoxide
and droxide
together ~1%
loutlet from main fractionator
con-

130

<O.OOOlad

0.0002ad

<0.0001c

<0.0001
<O.OOOlad

<0.0001

densers)

lrght strarght-run

gasohne.

mercaptans

(tower

0.0005cd

<0.0001c

tom)
C,-poly gasolme,
C, 5%,
water ~1%.
pressure 225 psrg fdepropanrzer
reboiled
crude resrdue fvacuum
tlonl

lower

bottom,

pH

slrlpping

0.0028

0.0003

0.0002

hqurd hydrocarbons and hydrogen


fur 1.2.1.7%
m liqurd. hydrogen
ammonia 1% in gas

recycle
sulfide

gas, sul3% and

Petroleum

600.
650

221

xx

0.0004

0.0005

hqurd hydrocarbons and hydrogen


fur 1.2.1.7%
in Irqurd. hydrogen
.^I
ammorua 1% rn gas

recycle
sulfide

gas, sul3% and

Petroleum

730.
775

221

xx

0.002

0002

co.0014

0.0061

(continued)

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

IWDUS~RV
(PROCESS)

ALLOYS-CLIMAX

513

MOLYBDENUM

bntd)

Average corrosion rates (ipy)

TIPI

TIPE

TIPI

304

316

317

ALLOY
20

825

<O.orml

<O.OOOl

of

Petroleum

600

xx

0 275cd

0.0189cd

steam d~stdlat~on of petroleum


treatment
wth 66BC sulfuric
cewer too)

lubrlcatmg
011 after
acid ldlstlllation
re-

Petroleum

600

10

xx

00011

00014

steam dlstlllatlon
of petroleum
treatment
wdh 66ElO sulfwc
cewer top1

lubrlcatmg
011 after
acid (dlstlllatlon
re-

Petroleum

600

30

xx

0 0004

00005

some

Petroleum

170

98

0.0002bd

0 00015ad

0.1%

ap-

Petroleum

150.
I60

158

salt

3-5

Petroleum

750

238

xx

0.0025cd
0.0048cd

<0.0001cd

column1

Petroleum

750

357

<O.OOOl

<o.o001

gasoline and salt water. total acid ~1%


calculated
as sulfuric acid, hydrochloric
acid trace (bottom
of Rock tower)

Petroleum

90

93

salt water under sour 011. chlorides 5850 ppm. so.


dlum 4225 ppm. sulfates
2500 ppm. bicarbonate
2072 ppm. hydrogen sulfide
1714 ppm. calcium
835 ppm. magnewm
310 ppm. pti 7.8

Petroleum

80

360

sour water contammg


some hght flashed
and hydrogen sullide (vacuum flasher)

Petroleum

130

309

50.

Petroleum

220

71

XX

naphthenm

acids

Petroleum

725

35

0.0003cd

01 hydrocarbons.

pres.

Petroleum

100

258

0001

sulhde

Petroleum

875.
975

258

<o 0001

reactor eflluent flash gas, hydrocarbons.


sulhde 0 02-O 03%. pressure 460 pstg

hydrogen

Petroleum

100

258

0.0009

0.0006

0.0012

naphtha

520 pslg

Petroleum

600.
750

258

0.0002

0.0002

0.0006

0.0003

770.
790

112

xx

0.0006

0.0005

Petroleum

625

102

xx

0.0004a

0 0003a

Petroleum

700

vapors III
crankcase

top of flash
oil. sulfuric

tank used III the re-rehning


acid 1 5%. pressure

hght flashed dlstdlates


and sour water
hydrochloric acid (vacuum flasher)

wth

West Texas crude. being desalted, sulfur


prorlmately,
pH l-8 (condenser, vapors)
mmed
Louwana
crude.
sulfur
lb/ 1000 bbl (vacuum flasher)
tar.

grawty

13 API (bottom

0.26%.

of Vitbreaker

10% phenohc water vapor contammg


1320 ppm (phenol recovery tower)

24 API gas 011. hydrogen


Msbreaker
bubble tower)

condensed
reactor
sure 460 pug

etfluent

sulhde.

relormet
etfluent.
hydrocarbons.
0.02.0 03%. hydrogen, pressure

leed, sulfur 0 01-O 02%.

testdue from cracked


0 6-0.7% (evaporator
hydrocarbon

vapors.

gas atmosphere,
hydrogen sulhde

distdlate

chlorides

hydrogen
500 psig

pressure

gas oil and vapor. total sulfur


tower bottom)
hydrogen.

sulfur 0 053%

hydrogen
60%.
2% (vapors1

methane

38%.

<O.OOOl

<0.0001

0.031c

O.Olc

<O.OQOl

<0.0001

O.OOOlcd

0.0001c

0.004r
0.03c
0 02c

0.004r
0.007

<0.0001

co.0012

<O.cnMl

0.004r
0.0009

<O.OOOl

0.0011

0.0007

<0.0001

<OOOill

<o

0001

<o

0001

0006

0.0016

(continued)

514

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TYPE

,PE

TPE

304

316

317

9
.

900

0.025

0 027

0 086

0.108

60%.

methane

38%.

hy-

Petroleum

gas atmosphere.
hydrogen 60%,
drogen sulfide 2% (vapors)

methane

38%.

hy-

Petroleum

II00

hydrogen
hydrogen

65-55 mol%.
sulfide 12.20

hydrocarbons
35.45 mol%.
grams/ 100 SCF (vapors)

Petroleum

640

130

0 0008

0 0007

hydrogen
hydrogen

65-55 mol%,
hydrocarbons
35-45 mol%,
sulfide 12-20 grams/ 100 SCF ivapors)

Petroleum

800

130

0 0013

00012

Petroleum

650

130

0 0003

0 0004

hydrocarbons
70-60 mot%,
hydrogen 30-40 mol%,
hydrogen sulfide 0 07-0.09 mol%. pressure 400 ps+g
(vapors)

Petroleum

650

291

hydrocarbons
70.60 mol%.
hydrogen 30-40 mol%,
hydrogen sulfide 0 07-O 09 mol%, pressure 400 ps~g
ivaporsl

Petroleum

555

130

regeneralmn
gas and overflow
waler.
carbon dl
oxide. oxygen. sulfur dloxlde tract?, chlorme trace
ammoma trace, pressure 300 PSI

Petruleum

IOO500

regeneratwn
gas and overflow
water, carbon dioxide, oxygen, sulfur dioxide trace, chlorme trace,
ammonia trace. pressure 300 psi

Petroleum

wgm
naphtha feed, hydrogen solflde 5 grams;
co 11 average, recycle gas IS 35% of charge
contams 79 mol% hydrogen, pressure 310 PSI

Petroleum

hydrocarbons
70.60 mol%.
hydrogen solfade 0 03-0.04

unleaded

gasolme

hydrogen 60-40
mol% (vapors)

mol%,

100
and

(vapors)

hntd)

Average corrosion rates (ipy)

3
f

gas atmosphere.
hydrogen
drogen sulhde 2% k~ors)

MOLYBDENUM

\o

0001

00001

57

0.0197c
00651

0012lr
0.0178r
0 028r
0 067r

IOO900

47

100114c
WLO Ol9c

910

90

0 0024

Petroleum

R.1

365

Food

II0

100

Food

130.
150

55

food

173

27

food

55

Chemical

IIOI50

.,o

0001

<0.0001

Chemical

140.
150

..o

0001

\0.0001

0001

825

<0.0001

00001

<o

ALLOY
20

0 0012a

0.0065~
WO 0067~

0.0025

<0.0001

CLLATlNC

evaporated
gelatme
solutmn
contammg
20.30%
gelatme,
salts 0 75%.
actdlhed wth hydrochloric
aud to pH 3

gelatme Ilquor.
pH 3 8-4 8

gelatme

gelatme,

50%

acldlfled

solutmn.

sohds 4.20%.

hydrochloric

approximately.

wth

actd (0

hydrochloric

aud

to

pH 3.8-6.8

6%

pH 2 (evaporator,

llqwd

level)

0 0004d

00001

<0

OOOld

<0

OOOld

00001

<0.0001

0.0003
0.0003

0.0002

(continued)

Ferrous

TABLE

VARIOUS

4.13:

Corrosion

STAINLESS

STEELS

AND

HIGH NICKEL

ALLOYS-CLIMAX

conditions

Average corrosion

IWE

WUE
gum.arabrc
adheswe
solution.
lb/SO gal fhqurd levell

acrd.

sulfur

ptf 5.6 Mash

glulamrc acrd. saturated


rde. ptl 3.2 lcrystallrzerl

MOLYBDENUM

bmd)

Test

mediums

crude glutamrc
Ilquorl

515

Alloys

solution

droxide

chamber

of sodurm

1.5

above

chlor-

304
-----

Ink

R.T.

79

xx

Food
Ievaporation)

158

36

xx

Food

ml c

000013ad

rates (ipy)

ll?E

IVR

316

317

20

ALLOY
825

nil

<O.OOOl

0.00024ad
77

28

xx

0.0021c.d

xx

_.

O.OOllcd

O.OOlBcd

glutamrc

acrd crude,

hydrogen

peroxIde.

pff 3.2

glulamrc

acrd crude, hydrogen

peroxIde,

pH

Food

176

Food

176

some

soap
Idrstdlat~onl

BP.

27

300

89

I8

xx

0.0092cd

0.0012ad

xx

0.0019cd

O.OOOB4ad

0 0027

0.0020

xx

0.00042ad

0.00029ad

xx

0.0079ad

0.007Bbd

0.0003cd

O.OOOlad

0.0036ad

GLYCERlNE
concenlrated
glycerme
Iall 1 suspe*lon

saturaled

coocentraled
glycerme
crystals Ivapors)

saturated

wcth

salt.

salt

Soap
fdrstrllationl

concenlraled
crystals

saturaled

wrth

salt.

salt

Soap
fdrstdlatron)

F <320

Soap

140.
220

91

30%
half-crude
glycerme.
sodrum chlnrrde 20%.
lree bufyrrc acrd trace. water remarnder. pH 4

Soap
levaporafront

210

I2

O.CfJl3cd

IO%, purrhed
acrd. pH 6

cellulose

Food

I30

61

0.0004cd

GRAPEFRUIT

JUICE

Food

36

wool grease bemg rehned. dtlute sulfurrc and hydrochlorrc acrds. alcoholrc caustic solution. hydrogenperoxide bleach, strong sodium-hypochlorite
bleach,
2-6 batch cycle

Chemical

F <210

105

xx

wool grease being rehned. drlute sulfurrc and hydrochlortc acrds, alcoholic caustic solutron. hydrogen-peroxrde
bleach,
strong
sodrum.hypochlorrte
bleach, 2.6 batch cycle ltank bottom)

Chemical

F <210

123

76% anrmal
mamder

Leather

100

Metal

115

glycerme

110.15%
glycerme
Sanger evaporator)

85%

grapelrurt

saturated

wrth

sausage

turce. orange

wrlh

salt

salt.

Ilooster-

casting strip. acehc

furce 15%

72

124

xx

--

._.

<O.OOOld

<O.OOOld

0.003ad

<O.OOOld

<0.0001

<0.0001

09014
0.0001

0.0001

0 0024
0.0014

0.0035

0.0004
0.0004

o.OOG9

_.

GREASE

grease,

sullurrc

acid 22.1%.

water

re-

halmum hydroxide suspensron m ammomum-sulfate


and ammonurm.hydrorrde
solution. pH 758.5
IftIter
press, hall Immersed)

3.3

58

x-1

xx

<o 0001

0.00013
CO.BQOl

00006
c0.0007

<O.OOOl

<0.0001

(continued)

Corrosion Resistant Materials Handbook

516

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

hmtd)

Average corrosion rates (ipy)

--

ALLOY

WPE

IWE

TWE

304

316

317

20

---

825

HLXAYINE

90% horrmme slurry, ammonia 0.1%. lormaldehyde


0.01%

Chemical

: F

I40

32

43% heramme mother hquor, lormaldehyde 0.2%.


ammonia 0. I %

Chemical

!F

125

28

25%. lormaldehyde 40%.


monia 0.3%

am.

Chemical

150

32

hrrane vapor. lowboiliq vapor horn lall oil, sullur


dioxide 0.3%. waler5%

Chemical

257

250

methanot 17%.

II

II

<o.ooo1

<0.0801

...

...

XI

<O.OOOl

<0.0001

...

...

ss

<0.0001

<09001

<0.0001ad

<09001

<0.0001

1)

I1

NVWINE

Research

hydrasine, various concentrations

nvDnoBnoYIC

.L

OK

I)

(1

ACID

......

0.0274bd

o.ctos8w

......

0.18

0.067

0.00&Z

o.C@71c

0.153
0.179

0.049

200.
212

37

Chemical
tdistdlation)

168

55

Metal
lplatm~

124

hydrochloric-acid lumes lrom tank contaming hydra.


chloric acid 19% approximately

Metat
(pickling)

166
180

41

15% (hall immersed)

Water
Treatment

R.T.

10%

Research

150

0.00388

:.

o.mi66

nYDRocHLoaIc

s**

.I0

0.0035cd

hydrobromic acid, hydrochloric acid, crude ethylene


dibromide

O.OlRcd

Chemical
idistillation)

hydrobromic acid. variws concentrations, decomposition products 01 ethylene dibromide

ACID

HYDROOEN

CnLORloE

28%

1.2

xx

xx

10%

Research

75

10%

Plastic

75

12

75

105

xn

95

xc

dilute

: Rubber

IF

5%

Research

3.52%

Research

;L

77

70

1%

: Researdl :L

95

xx

O.OOlad

O.OW2d
0.9017cd

O.lOOld
0.00126

Research

jL

140

II

0.5%

Research

IL

95

xs

0.0966a

0.LlOO6ad

0.0059C

O.OLKI8a

54.1
1.4

1%

(1 = Molybdenum content above 0.5% catalyses decomposition 01 hydrarme

O.OOla

0.036

.. .

.. .

0.16
81.4
0.14

517

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

Test
conditions

Corrosion mediums

Hydrochloric

STEELS AND HIGH NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

hntd)

Average corrosion rates (ipy)

TYPE

,PE

TIPE

304

316

317

ALLOY
20

825

ld

0.36%

Research

0.036%

Research

water conlaming
chloric acid

small

moist au containing

amounts

hydrogen

or traces

of hydro-

1
:L
F

Metal
(pickling)

1.4

77

70

160.

41

2.0
x

0.0016

0.0007

0.003cd

O.Ml4cd

180
:

chloride

77

R.T.

137

0.0022

0.001

0.0033

0.003

0.0029

0.656

0.485~

0.414c

DRocLclR,C-ACID
YIXTURES-*.*
aus0
NITRIC-ACID
MlXTURES
WITH HYDROCnLORlC
ACID

20%.

sulfuric

1X%,

acid 5%.

non-ronrc
0.125%.

hibitor

nitric acid 5%

detergent
0.188%.
water remainder

amine-type

in-

1%.

bow

acid

0 1%.

free chlorme

chlorme

hydrochlorrc

low but varying


Ihydrogenxhloride

acrd. chlorme.

waler.

Soap

120

12

72

90

bow

Petroleum

L5.23

0.003c

--

100

77

87

xx

xx

Chemrcal

Pulp and
Paper

ppm.

Heatmg
Water

140

concentration
fume scrub.

Rubber

45.
70

Chemical

77

<IO0

ppm.

water

0.02 g/l

waler,
mmeral
acids approxlmateiy
70.80
ptf 2.8.3.5. pressure 5 psig (heat exchanger)

wash water. usually


of hydrogen chloride
berl

3.28

0.003c

6% approximately. Polyrad
I1 1Oa aminetype
in.
hrbitor 0.5%. some ferric chloride and cupric chloride

0.015X,

Chemical
(pickling1

acid

68

88

xx

xx

xx

xx

xx

O.D003d

O.OWd
nil

<OOOOl
<0.0001

90

210

0.437c
0.437.c

<O.wol

0.0001c

<O.OOOl

<0.0001

<O.ooOl

0.0001 b

o.oa66c

>O.l

0.02c
hydrochlorrc

acrd. lactic acrd. pfi 4.5

prolem
hydrolysate
some sulfur dioxide,

HlDROClNlC
hydrocyamc

mixture.
pH 1.5

hydrochlortc

actd fhqwd)

WIDROFLUORK

A,tlD
grade

commercial

12 vol%, waler vapor


~019~. lluos~hc~c acid
densate)

17 ~01%.

sulfuric

I ~01%
(vapors

65-60X.
nydrolluorthcrc
acla 1.5.2.5%.
acid. 1.2%. won 10 0.01~0.03T 0
sullwc

170

60

xx

food

110

84

Chemical

45

<0.0001

0.0015cd
O.OO~Scd

0.0001

<0.0001
0.0001

O.cKlOl

0.0001

0.49

0.15

0.14

0.24
>0.38

co.43

ACID

70%

50%.

acid,

Dairy

acld 50%

Mining

,F

acid 10
and con-

Chemical

sulfuric

Chemical

Glass

169

<O.oOOl

70

42

x.

350

14

xx

corr

30.
80

28

corr

R.1:

<O.OOOl

corr

0.99c

0.026

140

(continued)

518

Corrosion Resistant Materials Handbook

TABLE

VARIOUS

4.13:

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

Average corrosion rates

TVPE

lNUUSVRV
,PROCESS,

50%. au 30%
on tetrafluorlde

waler 12%. sullur~c


1% (vapors)

46.5 approximately.
top vapors)

lsobutane

acid

7%.

SI~I-

tregeneratcorAower

TIPI

317

350

0 133
0.139

0.163
0 113

Petroleum

210.
220

0 0634~

0.001

Petroleum

230

37%. glass.etchmg
solutlon.
amm~nu~m
blfluorlde
9%. water durmg 200 hours, and 49% hydrofluorlc
acid. ammonium
blfluorlde
1500 sulfuric acid. water
durmg 24 hours

Glass

167

29%. glass-etchmg
solution.
ammonia
14% as ammon~um blfluorlde
water durmg 72 hours, and 40%
hydrofluorlc.
ammonia
15% as ammonium blttuo.
ride. ammonw~
fluosillcate
4% water durmg I76
hours

Glass

140

12%.

Chemical

I82

10%

Metal
lplcklmgl

10.1%

Petroleum

acid 0 2%

VVPE

20

ALLOY
625

co 081

corr
2.oc
COlr

lO3-

7.2

xx

30

--;

250

49

50.
70

bntd)

(ipy)

316

Chemical

38%

hydrofluosllw

304
-----

MOLYBDENUM

0 140

0.1

0 160~

0 7Olc

0 00038

--

<o

0001

0 0359
0 0446

0.0015

0017

0013

co 0066
0 0064

0 008
0 025

0 0034
0.0086

co001

8%. some fluosdlclc

acid letchmg

of tubes)

Televwon
Tube
Manulacture

RT

120

xx

8%.

acid tetchmg

of tubes1

Televwon
lube
Manufacture

RT

120

xx

xx

Petroleum

215

Metal
(pickling)

120

Fertihrer

R.T.

I41

Petroleum

I28

226

00008

0.0004

O.CHlO6

Petroleum

250

226

0.0013ad

0.0014

0.001

23.1.9.1x

Chemical

145

90

0.03gc

0.005

22%

Chemical

I45

94

xx

20%

Chemical

I35

38

xx

xx

LO.OQS

0 005

0.003a

0.005

Chemical

I75

I6

xx

xx

LO.021

0.003
0.015

0.0007

0.005
0.001

Chemical

120

62

sorne fluosllwc

6%. organic

fluorides

71%.

5%. lerrous
sulfate
nately Immersed1
3%. fluorme

Ilquor,

IO%,

sulfwc

benzene
sulfuric

19%
acid

5%

acid 0 5%

1%. regenerated
hydroftuow
acid. lsobutane
n-butane
9 6%. propane 2 4% tdepropanlzer.
top tray beslde feed Inlet)
regenerated
hydrofluorlc
~zer accumulator
bottom)

20%.

16%,
0 3%

phosphoric

water

acid

83%.

acid.

l5%,

s~hca

taller-

propane

sulfunc

05%.

aci!I

07%.
above

ldepropan-

i%

phosphoric

acid

226
I 8

0012c

0012b

xx

xx

0.393

0.191

0001
co 002
0 002

00041

0.008C

0.023

x.

0.002cd

0.02c

0.016~

0.003

_.

0.0025
0.013

(continued)

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

HydrOrlYoSdICIC

(contd)

Average corrosion rates (ipy)

TIPS
-

MOLYBDENUM

519

INDUSTIIY
,PlOCESS~

304
-P-P-

ALLOY

TYPE

,PE

316

317

20

825

0.24

0.13

0.025

0.116

aad

10%. some hydrofluoric and phosphoric acids

Chemical

: f

140

19

xx

96%, sodrum-Ruosilicate crystals with 1012%


crystal water

Chemical

;F

100

163

xx

xx:

0.0017bd

8.5%, electrolytic-lead solution, lead ftuosilicate,


msoluble anode slimes, lead 80 g/l, total acid
149 111

Metal
(lead
refiningl

176

60

0.023

hydrofluosihcic acid, water, fluorine 0.2% approximately as hydrofluosilicic acid (gas scrubbing tower
base)

Chemical

:F

85

22

--:

spray water and gas containmg low concentrations


of hydrofluorrc acid, sulfur dioxide, and sillcon
tetrafluorrde (gas scrubbing tower)

Chemical

122

22

xx

moist gas having a low content of hydrofluoric acid,


sullur dioxide and silicon tetrafluoride (gas scrubbing)

Chemical

122

22

xx

60% approaimately. hydrocarbons 20% approximately, hydrogen sulfide 2.10 graMlOG cu ft during 1 week, then 2 grains/ 100 cu 11 average, hydrogen chlorrde trace

Petroleum

950

250

hydrogen chlorrde. dry, pressure

Petroleum

180

234

hydrogen chlorrde. dry

Research

4w

xx

hydrogen chlorrde. dry

Research

1 <900

xx

OK

OK

hydrogen chlorrde. dry

Research

1 >900

xx

NC

NG

hydrogen chlorrde. dry

Atomic
Energy

930

hydrogen chlorrde, dry

Research

1OQO

95%. dry, acetyl chlorrde 3%. acetrc acrd 2%

Chemical

52

OROGEN
CHLORIDE
see a110 DROCHLORIC

XI

0 018
0.018

0.001

.. .

0.003

0.0018

0.0014

0.085

0 052

00086

0.0012

0.0013

0 0008

nil

<0.0001

ACID

0.0075
<0.005

LOO11

21

0.17
0.14
14

xx

0.196

hydrogen chlorrde. dry dry chlorine, orgamc materral

Chemical

302.
527

26

hydrogen chlorrde, dry caustrc soda (autoclave,


vapors)

Rubber

573

60

L<O.OOOla
<O OOOla

hydrogen chlorrde, dry, caustrc soda lautoclave,


vapors)

Rubber

573

60

LO.OOOla
0.0004a

hydrogen-chlorrde vapors from vent system and absorber

Ravon

RT

hydrogen chlorrde, au
hydrogen chloride, hydrogen, Zucex process, hot
cycle only

A 1.
Atomrc
Energy

1112

<0.005

3.3

135

0.139

0.042

0.0012

I:

O.OOOla

0.0002a

0.015r

0 0032cd
LO.025
LOO21

0 0044cd
0.0077

0.06*(continued)

520

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

Average corrosion rates (ipy)

----

TYPE

,PS

,PE

304

316

317

20

hydrogen

chlorrde.

dry, hrghboiling

ether

Research

R.1

0.0064

0.0017

...

...

hydrogen

chlorrde,

wet. high-borhng

ether

Research

R.T.

0 0068

0.0035

...

...

hydrogen

chlorrde.

purge. high.borlmg

212

0.005

0.0046

...

...

0 0065ad

0.0036ad

0.0086c

0.0071c

O.Olc

0.0082~

0.01

0.008

0.007c

0.013c

ether

hydrogen chloride made by volatthzmg


acrd solution
31.5%
(shaft leadmg
carbonize0

hydrogenchlorrde
chlorrc acid 19%

10%

au 90%.

hydrochloricto woolrag

fumes from tank contarnmg


approxrmately

some chlorme

hydra-

Textrle

220

Metal

160.
180

41

xx

R1.

92

xx

xx

92

xx

iplcklmg)

and water

hydrogen

chloride.

chlorme.

moist au

R.T.

hydrogen

chlorrde.

chlorme,

moist au

RT

118

184

hydrogenchloride

fumes m atmosphere

Petroleum

R.T.

IOX,
acetrc acid, cationic resin, acetylrted
castor
oil during 8 hours; and athaline wash, water wash,
sodium sulfate during 6 hours tepoxydation
reactor)

Chemical

212

86%.

Chemical

85

Cosmetic

R.T.

: Cosmetic

R.T.

Chemical

Petroleum

90

188

xx

Chemical

176.
302

166

Chemical

100.
170

3-17 mall.
carbon dioxide
of chlorrdes. cyanides and

Petroleum

260

288

hydrogen sullide. traces of ammoma.


carbon dioxide and hydrocarbon, diethanolamine.
water tvaporsl

Petroleum

215

396

725

242

220.
230

xx

HVORWEN

0.0086a

xx

XI

xx

xx

<o.Mut1

30

<0.0081

30

<0.0001

._

<0.6001

<o.Lm

<O.OOCIld

<O.OOOla

<O.@Mlad

<O.OOOlad

<O.oOala

OMtO1

<0.0001

ALLOY
625

0.0059c

0.0057b

lLROIUOE

stabdrzed

6.1%.

kamtd)

with sulfuric

stabilized

with

acid

acetandrde

and

phosphoric

0.027d

0.008d
so.059d

acrd

3%.stabdized
MWEN

hydrogen
86%.

with retanilide

SULFIDE

sulfide (generator.

vapors)

air, nitrogen

hydrogen

sulhde.

hydrogensulhde

water teatraction

gas saturated

8566 oaf%.
ammonia
7.12%.
small amounts
hydrocarbons fvaporst

unitt

with water

vapor

hydrogen sulfide, mercaptans.


acidrc moisture, pres
sure 25 psr (Cotter bubble tower, bottom head)
hydrogen
ndrogen.
ILyagfdter

sulhde.
carbon monoxrde
and droxide.
oxygen trace,
some carbon-black
dust
plenum chamber floor)

Carbon
Black

56

64

93

x
-

<0.mo1
<0.ooo1

x ;

<O.oOol
<0.0001

nit

10.0003

10.0003

xx

<o.O001c
<0.0001c

. ..
0.9002ad

<09001

<0.cQO1c

00001

<o.ooo1

< O.owI

(continued)

Ferrous Alloys

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

IKSUSTRV
(NIOCESS)
,-

VWE

180
220

304
----O.WO8cd

hydrogen sulhde, hydrochloric acid from breakdown


of chlorides and sulfur compounds in crude oil (top
tray of fractronator)

Petroleum
tfractionatroll)

1.5 vat% hydrogen, hydrogen partial pressure 485


psC

Petroleum

750

25

1.5 valX hydrogen, hydrogen partial pressure 405


psig

Petroleum

975

41

hydrogan sulfide, sour water, light hydrocarbons

Petroleum

100

568

--

water contaminatad with hydrogen sulfide, mow


ethanolamine trace (vertical condenser)

PetrochemiCal
Idrstillationl

72

106

32 ppm hydrogensulfide gas, orygen 1X, saturated


with water vapor

Petrdeum

85

Synthetic
Rubber

90

2.5% pH 3.6.2.9 (circular-path currosion machme)

Rubber

120

IO

xx

2.5%. ptf 3.5 hank bottom)

Synlhetrc
Rubber

54

25

10%

Research

B.P.

prinhng ink, blue (half immersed)

Ink

R.T.

_.

TWE

VWE

316

317

20

ALLOY
825

0.0003cd

0.0112
co.01 13
10.0119
LCO.0052

0.0239
wO.0171
co.0154
10.0250
LW.0212
LCO.0123

0.0208
CO.0220
10.0240
LCO.0117

<0.0001

<0.0001

nil

(amtd)

rates (ipy)

0.0122
WO.0083
CO.0084
LO.0104
1w0.0078
LCO.0057

O.WOlad

xx

MOLYBDENUM

521

0.0001ad

<0.0001
O.ooOlad

<O.OOflId

nil

NVDRDQUINDNE
IX.

sodrum-sulfite Inhibitor 0.033%. pH 6 5

NVDDXVACETIC

0.00011
<0.0001

<0.0001

xx

<O.MMl

<0.9001

xv

nil
nil

nil

ACID

--

79

a-

0.38

nil

nil

nil

IODINE

--

0.12

0.081

80

--

0.002
0.002

0.9003

0.0002

O.Ooal

72

xx

0.0071
0.0071

0.0023

0.0073

0.0039

410

276

xx

ml

nil

iodme, pressure 400mm mercury

Research

842

10%. non-romc datergent 90%. some hydrochloric


acid

Soap

72

8.3%. isopropyl alcohol 11%. hydrochloric acid


2%, nonronrc detergent remainder

Soap

Chemical

KLROSLNL
as%

(continued)

522

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

bntd)

Average corrosion rates (ipy)

g
.

TIP6

304
-----

NPE

316

TIPS

317

20

ALLOY
825

I(srorsne

94%.
trace

butane

5%.

acetrc

acrd 0.7%.

roohng felt stock from rags, small


sene, paper, sawdust. consrstency
proximately
lcylmder machine)

organrc

acids

amount of kero0.5%.
pH 7 ap-

Chemrcal

122

276

Construction

60

100

xx

Rayon

68

200

<o

0001

<O.OOOl

KETENES

25%. carbon droxrde II%,


acetrc acrd ll%,
butadwne
lene 1%. acetrc anhydrrde

carbon monoxrde 12%.


10%. allene IO%, ethy1%

c ---.
LC

xx

0.0001

hrgh.borlmg

ketone

Research
(distillation)

264

0.0134

0.002

high-borlmg

ketone (vapors)

Research
Idistillation)

266

0.0026

0.0003

ketone
0.1%.

Chemical

175

60%
methyl+sopropyl
ketone,
ethyl-vmyl
ketone
15%
VI~YI-ISOD~~~VI
ketone
0.5%.
dimer
4%.
methylethyl
ketone 0 1%. alcohols
0.1%.
water
remamder

Chemrcal

190

60

44%
3%.
I%.

drmer
ketone

Chemrcal

230

50%,
2%

Chemical

60%.
drmer
ketone 1%.

Chemrcal

2 8% methyl-Isopropyl
ketone, 4.hydroxy 3-methyl
2-butanone
3%
ethylwnyl
ketone 0 6%,
phosphortc acrd O-6%, formaldehyde
04%.
water temamder

Chemrcal

94%
methyl-rsopropyl
ketone,
ethyl-wnyl
3%.
methylethyl
ketone
0.1%.
alcohols
hydroquinone 25 ppm. water remainder

ketone, water 50%,


l%,
vmyl-rsopropyl

3-methyl
2-butanone.
water
ketone 10%. formaldehyde

1% methyl.rsopropyl
ketone,
water
10%. formaldehyde
1%. vmyl-rsopropyl
alcohols li 0

LACTK

<o

0001

<0.0001

<o 0001

x :

<o

0001

<0.0001

<0.0001

60

225

125

225

60

0 00013

0.00016

<o 0001

220

17

0.0001

0.0001

0.0001

BP

6
6.5

.,

methyl-Isopropyl
phosphorrc
acrd
alcohols 1%

36% 4.hydroxy
methyl-Isopropyl

reduced

60%. sofutron
100 ppm

pressure

saturated

tstlll pot, Irqurd)

wrth calcium

60.30%
lactrc-acrd vapor. vacuum
lcontmuous evaporator)

45%

<0.0001

0.0021

00013

0.0006

<0.0001

0.0002

ACID

65%
>BO%.

0.0025a

taccelerated

corrosron

test)

sulfate.

won

26 in. of mercury

xx

0.036

Chemrcal
tdrstdlationl

330.
355

Dairy

110

15

0.0039cd
0.0027cd

0.0005cd

Corn
Products

115

42

xx

0.0026cd
0.003cd

<O.OOOlad
0.0003ad
W0.002d

Chemical

R.T.

14

xx

xx

0.0005

<O.cHIOl

0 0006

<O.OOOld

<0.0001

(continued)

523

Ferrous Alloys
TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

Average corrosion

I
g

blue

0 01%.

possibly

cupric

loos

Pulp and
Paper

70

90

0
f

&

9
.
1%. methylene
ftank bottom1

ALLOYS-CLIMAX

P
.

xx

TPl

304
----<o 0001

<0.0001
S<O.OOOlad

MOLYBDENUM

(contd)

rates (ipy)

ALLOY

TPE

TPl

316

317

20

625

<0.0001
s<0.0001
L<O.OOOla

<0.0001

<0.0001

<0.0001
s<0.0001

L<0.0001
polylactlc

acid.

mdetmtte

Chemical

180

38

xx

<0.0001

<0.0001

Dairy

132

15

xx

<0.0001

<0.0001

Metal
(lead
refmmg)

117

25

Chemical

BP

I23

LACTOSE
mdk-sugar solutlon,
lvacuum evaporator)

LEAD

hydrochlortc

acid 0.0150.03%

FWOSlLlCATE

lead-fluosdlcate
electrolyte,
total hydrofluosdicic
acld 13 32%. free hydrofluosllw
acid 6 49%. lead
6 9% as lead lluosdlcate.
pH <O (pump tank)

LEAD

0.0072

0.0063

0.0062

0 0065

OXlDE

oxldes. carbonates
antImany.
aqueous
pan1

LEAD-PLATING

and chlorides
of lead. tm and
slurry tdlrect-ttred
evaporation

lead, tm and antimony

lemon lwe,

0 0007

xx

0001

0 0001

SOLUTION
platmg

solution.

mainly

fluo-

berates

pH 2 5

pure levuhmc

acid (vapors)

levulmtc

acid (vapor head of acid still)

levuluwacld
vapors. hydrochloric
acid
rmc acid 2.5% (evaporator.
vacuum)

ldhlum bromide (vapors


durmg 600 hours above
600 hours below 212 f)

durmg 4M)
212 F. then

Metal
(plating)

-F

70

59

--

Chemical

:L

70

71

xx

260

38

xx ;

100

57

corn
Products
tdlstillation)

98%

crude

3.5%.

for-

hours, llquld
hquld during

0.0003

<0.0001
s<0.0001
<o.OOa*

0.0003

0.0009

<0.0001

0.034cd

0.043bd

corn
Products

iF

corn
Products
(distillation1

I F 225
;
:

0.0009d
0.0008d

0.0003

29

0.0133cd
0.0124cd

0.0038bd

0.2cd
0.19cd
con
corr

0.061cd

Corn
Products

140

10

Metal

205
217

67

0.0007cd

0.0006bd

0 003bd

(continued)

524

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

Average corrosion

EWE

304
----Illhum
bromide lhqud
durmg 1000
212 F. then 600 hours below 212 Fl

30%

hours

above

levaporatorl

Metal

205
217

Al,

240

xx

172

x.

(contd)

rates (ipy)

TWE

EWE

316

317

<O.OOOla

40

MOLYBDENUM

<O.OOOlr

<0.OOOlr

<0.0001

<0.0001

ALLOY
20

625

<O.OOOld

<O.OOOld

Conditioning
30% during 26 days. calcium chloride
146 days, vacuum (bottom of columnt
vapors from a bodmg
(evaporator)

48%

(boll-down

42%

(evaporator)

lithium-chloride

during

Chemical
(dehydration)

solution

Al,
Conditioning

240

40

Chemtcal
(evaporation)

330

55

xx

Chemical

312

35

xx

Metal

160

31

131

20

160

235

25%

30%

kettle)

36.353,
sodium chloride 0.8%.
calcwm
chloride
0.4%. traces of won, copper, mckel. manganese and
sulfates. pH 5-6 (heating cod)

7%. magnewm
chlorate
nesum hydroxide 0.25-l%,
sorption tower)

3%. chlorme
pfi 6.2-6.4

magneswm
oxide. carbon dloxlde,
sulfur d!oxlde (type N Rota-Clone
clpltatorl

3%. magitop of ab-

motsture.
hydrostatic

some
pre-

Chemical

20.
68

40%

Research

125

20.18%

Chemical

95

Coal By
products

10%

Research

5%

0.0043

0.0032r

0.000lcr
x

0 0002ad

>0.28
corr

xx

0.0069cr

xx

0.0001
OOOOlb
0 OOOlc
0.001 lc
0 0014c

O.OOOZad

>0.29
corr

C0.445cd

0.0001
0.0001
O.OOOla
0.0002c
0.0001c

XI

0.147

nil

253

xx

<0.0001

<0.0001

c<0.0001

36

27

xx

<0.0001

<0.0001

c<0.0001

125

xx

0.16

nil

Research

125

xx

0.0005

nil

2.7.2.1%.
concentrated
apple julce. soluble sohds
72% (mostly sugars). pH 3.3-3.45 (Maloonier vacuum
pan)

Food

135

42

xx

<o.ow1

<O.OoOl

0X1-0.33%.
apple
sauce.
soluble
solids
21%
(mostly sugars). rodwm chloride trace, pH 3.4-3.7,
temperature
216 F initially

Food

RT.

57

<0.0001

<0.0001

0.45.0.35%.
14% lmostly

Food

42

xx

l&IO%.
phthallc

small
acid

amounts

of

naphthoqumone

and

fresh apple puce. soluble solids 12.


sugars). pli 3 55-3 65 (tank bottom)

50.
05

car,.,

<o 0001

(continued)

525

Ferrous Alloys

4.13:

TABLE

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

3
$

xx

<0.0001

<O.ooal

xx

<o.Ooot

<o.o001

xx

0.033

65

morslure and sullur lumes lrom kiln drying of green


malt lexhausl venlrlator slacW

Srawing

65

223

Chemical

220

19

xx

Ievaporation)
Chemical

168

75

manganese-sullale
solution,
specrhc gravrty 1.25.
1.35. sulfur droxrde 0 5 g/l. mostly pH 4-5 ltrrpod
leg 01 hrst effect evaporator body)

M1nrng
kvaporatron)

235

II

manganese-sulfate
solutron.
suspended
15%, sullurrc and sulfurous acids, pH 1-2

Mllg

140

Chemrcal
levaporatron)

212

24

Mrning

60.
145

23

ALLOY
825

20

CHLORIDE

37%
neutral
Immersed1

manganouschlorrde

manganese-chlorida

manganese
copper

TIE

317

88

Food

6.67.5%,

TWX

316

hard elder, alcohol


pH 3 553.65

TWX

304

.
acetic

9.3%

bmtd)

:
I
u
.
.

YANGANLSE

MOLYBDENUM

Average corrosion rates (ipy)

Corrosion mediums

O.lS-0.35%.
acrd 0.264%.

ALLOYS-CLIMAX

sullale,

traces

manganese
sulfate, sulfurrc
varyrng concentrahons

solutron.

solution

Shall

pH 3

of calcrum.

solids

5.

rron. srlrcon.

acrd, sulfurous

acrd of

0.0002d

xx

rx

0.026

0 0005*bd

0.0003a

corr

0.0029

0 008~

0.0009

0.0001d

0.0001

c<o

0.0002
0001

0% approximately.
neutral leachmg solutron from
leachmg 01 reduced manganese ore, ammonmm sullate 130 g/l, ferrous sulfate 20 g/l. ptl 6.5.7.5

Mlnlng

80

91

xx

xx

0.0001

0.0001

manganese-sullate
solutron oblamed
wrth manganese droxrde and oxrde ore and sullurrc acrd 5%
approxrmately

Chemical

180

245

xx

xx

0.0006

0.0005

0.0033
LO.0045

0 0022
LO.0018

ml

0.0087
LO 0087

0.0058
LO.0069

00016

0.013
to 011

0.016
LOOII

0.0051

o.oOC5

0.0001d

0 0005

o.clwJ5

MERCIPSOL

25.5SC
19 3%.

mercapsol
solution.
naphthenrc acrd 15%.

sodrum
hydroxide
cresols 10%. water

zo230

3.1

xx

25.581
19 3%.

mercapsol
solutron.
naphlhemc
acrd 15%.

sodium
hydroxide
cresols 10%. water

220.
230

24

XI

25 5S&
mercapsol
soluhon.
I9 3%. naphlhemc
acrd 15%.

sodrum
hydroxrde
cresols 10%. water

zzo230

24

xx

xx

25.586
I9 3%.

mercapsol
solutron,
naphlhenrc acrd 15%.

sodrum
hydroxrde
cresols 10%. water

220.
230

12

xx

xx

0 0006

0.0002

25 5Se
mercapsol
solution,
19 3%. naphlhenrc acrd 15%.

sodturn
hydroxrde
cresols 10%. water

220.
230

165

xx

xx

0 0006

0.0002

MERCURIC

.,

CHLORIDE

mercurrc-chlorrde

solution

Tanning

:F

180

0.0001

0.0001

(continued)

526

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

lest
conditions

Corrosion mediums

ALLOYS-CLIMAX

TIPE

95.15%.
captans,

ammonra.
hydrogen
sulfide,
l-10
water and au together

various

mer-

g/I (vapors)

60%. acetone
23%. methyl
acetate
15%.
2%. acetlc acid 0 03%. pressure
16 psig
50%. acetone
35%,
methyl
acetate
3%,
tone I%, water 1%

2. Pdlmethoxy
ethanol
2%.

330

water

propane
methylethyl

8%.
ke-

Chemrcal

77

Paper
tdrstdlation)

Chemical

Rayon

304
p---p

180

762

165

355

158

473

xx

xx

TYPE

TWE

316

317

<0.0001

<O.OOOl

<O.OOOld

<O.OOOl

<0.0001

nil

<0.0001

<0.0001

methyl
acetate
water 3%

38%.

methylethyl

ketone

Chenwal

149

150

xx

36%.
33%.

methyl
acetate
water 3%

38%.

methylethyl

ketone

Chemical

104

417

<0.0001

<0.0001

Rayon

144

707

1x

<0.0001

<0.0001

22%. water 55%. acetone


20%. methylethyl
ketone 1%. ethanol
19.. traces of esters and ammo.
Norm hydroxide

Rayon

180

435

xx

<0.0001

19%.
water
60%.
acetone
16%.
ethanol
1%.
methylethyl
ketone 0 5% ethyl acetate
trace, sodun hydrorlde
mjecled.
pti 12

Rayon

223

294

xx

(0

10.5%

acid

Chemical

200

52

xx

0.0001

<O.OOOl

1.15%. amme salt 12%. sodrum chlor-

Chemrcal

85

20

xx

0 0001

LO.0002

Chemrcal

210.
220

52

xx

Chemrcal

225

37.4

Metal

266

48

95.92%

Chemical

120

0.02%

Chemical

212

390

methanol

and carbon
g%,

and methylal.

droxrde,

caustic

acetate

water

traces

20%.

acetalde-

of formic

ALLOY
20

825

<O.OOOl

nil

nil

36%.
33%

35%, acetone 25%. methyl


hyde 12%. water 5Y 0

(amtdl

Average corrosion rates (ipy)

melhacryhc
acid. methyl
methacrylate
during
days, and au during 110 days lcrackmg unlt)

MOLYBDENUM

<o

0001

0001

<0.0001

0.0001

<o 0001

remamder

rde 1%
5.3%

methanol

and melhylal.

water

0.5%.
water 98.99%,
xcbutanol
ethyl ketone trace, formaldehyde

dlmethorybutane

crude

thqud)

95.98%

0.5%,
trace

methyl-

<0.0001

<0.0001

0.00027

0.00018

0.0002

0.0002

0.00021a

0.00038

YE,LAt.DEHDE

x.

<0.0001

<O.OOOl

<0.0001

<0.0001

dlmelhyl

chloracetyl

Chemrcal
lchlorina110)

32

25

xx

&methyl

chloracetyl

Chemrcal
..,

212

17

xx

0 0006

0.0005

(contikd)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion medrums

ALLOYS-CLIMAX

I
u
.

NPI

304
-----

TIM

WPE

316

317

methyl-chloride
atmosphere,
latty amme 75% solutmn m ~sopropanol,
amme
hydrochloride,
qualernary ammomum
chlorides.
some free hvdtochlorlc
acid, pH 3-8

Chemtcal

99.3%. methanol
0 5%, acldlly as hydrochloric
acid
0 000756, chlorme
5.4 ppm, copper ton 5 ppm, ran
eon I ppm tactwated
carbon solvent recovery)

Texlde

75.
100

methylene
and water

chloride,

tormaldehyde,

traces

of

011s

Rayon

140

628

<0.0001

<00001

ethylene
and water

chlortde,

formaldehyde,

traces

of

011s

Rayon

185

628

<0.0001

<0.0001

Rayon

100

22

70

59

70

57

:F

100

59

: F

100.
248

56

Rayon

IF

100

22

Chemical

jF

65.
85

400

175

60

Textile
Mvent
recovery)

IOO140

53

xx

x.

to

Textile
(solvent
recovery)

100.
250

51

xx

0 0008r

0.000lr

0 2%.

Chemical

75.
85

396

0.0001

0.0001

I%, acldlty as hydromn 12 ppm, chlorme

TextlIe
fsolvent
recovery)

75.
85

560

formic

acid, methylaldehyde

ethylene
chloride
wet,
acid and other ~O~JSI~~S

traces

of

hydrochlonc

Plastlc
(solvent
recovery)

ethylene
chloride
wet, bung dried in a calcwm
chloride
bed, calcwm chloride
concentrated
solutton m regeneratmg
cycle idrler)

Plastic
(solvent
recovery)

methylene-chloride
vapors.
water
vapor,
possibly
traces of hydrochloric
acid and other couos~ves
(top of column)

Plastic
kolvent
recovery,
dlstdlationl

methylene
chloride.
pyrldme.
chlorlc acid trace (vapors1

90%.

methylaldehyde

90%.

methanol

water. acetone, hydro

10%.

acetone

0 3%. acldlty as hydrochlouc


bon dloxlde removal

0 5.1%. water
1 ppm after

75%. methanol
condenser)

22.5%. water 75%.


adsorber cook0

2.5%.
acldlty

methanol

2.5%

2 5%

car-

of hydrafreboder)

thquid

(vapor

water 95%. methanol


2.5%. acetone
as hydrochloric
acid O-IO ppm

0.5X,
water 98.5%. methanol
chlorlc
acid 0.007%.
copper
IO 6 ppm. MO IO 2.5 ppm

0.2.

acid

40%. acetone
50%. water 10%. traces
chlorlc
acid and phenollc-type
products
22.5%.
water
from adsorber

.F

tdtstdlation)

10%

outlet

inlet

Plastlc

(contd)

chloride,

MOLYBDENUM

527

Average corrosion rates (ipy)

methylene

Alloys

190

55

56

SO 0004ad

0.0002ad
S0.0002ad

ml a

nil

xx

--

x
--

0 00016

x
<o

0001

<0.0001

<0.0001

<0.0001

<0.0001

0001

O.OOOlad

0.0001

.,

<0.0001

<O.OOol

<o

0 0002

ALLOY
625

0.00016

<O.OOOl

0.0001 I
0.00018

0.0002ad

20

<0.0001

<o 0001

<0.0001

<0.0001

0.00011

<0.0001

O.OOOlad

nil

O.OOOld

O.OOOld

tdtstdlatmn)
nil

IllI

nil

nil

(continued)

Corrosion Resistant Materials Handbook

528

4.13:

TABLE

Corrosion

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

--

TPS

TIPS

304

316

Chemical

303

100

90%.

Chemical

I67

390

trace

Sugar Etyproduct

190

trace

Chemical

180

38-

Chemical

167

Chemical

160

125

6%

Chemical

162

42

nil

10%

Chemical

176

25

xx

<O.OOOl

Chemical

162

29

xx

O.OOOla

0.0001

Chemical

167

29

xx

0.0001

0.0002

20%.
methyl
acetate
20%.
ethyl acetate
15%,
acetone
15%. acetaldehyde
10%. waler 7%, alcohols 5%. methyl formate 4%

Rayon

140

535

xx

0.012a

0 0007

18%. water 80%.


alcohols
1%. formaldehyde
trace

Chemical

200

0.00021

0.00019

Chemical

176

39

0.0003

0.0002

Chemical

181

29

XI

0.0005

O.O@M

0.00022

ethyl

acetate

5%.

90%. water vapor


Ievaporator.
VaporsI
82%,

water

water

10%.

5%

hydrochloric

14%. methanol

trace,

acid

ret-butanol

80.1%.
pentane
9 1% water 9%
ethyl
0 6% tertiary
butyl alcohol 0 3%. methyl
0 2%
73%. water
formaldehyde

15%.
Z-3%,

57%.

ethyl

acetate

50%.

ethyl

acetate

44%.
14%.

ethyl acetate
water 7%

25%, water
ketones

15%.

75%.

water

70%,

13%, ethanol
ketones 22%,

methyl
alcohols
47%.

water

40%.

water

37%,

other

ethyl

ethyl

isopropyl
2%

ketone

esters

acetate,

acetate

4%.

and ketones

other

1%.

acetate
acetate

esters

and

trlethanolamine

15%

35%. water 18%.


butanol
12%

other

esters

and

3.8

<O.OOOla

0.0002

0.00017

xx

O.llOc

0 007d

0 00028

0.00013

xx

0 0002

0 0002

. 0 0001

<:o0001

<O.OOOl

nil

water

95%

Chemical

190

39

0.0002

1%.

water

99%

Chemical

210

39

0.00015

300

106

0 0001

IllI

135

xx

0.0001

0.0001

255

241

xx

llll

145

28

8.7%.
boders

high hollers

50%

ethyl
acetate
2 45%. water

Chemical

84%,
light
remamder

turnethyl
phosphate,
hght
aud 0.31 g/l, pti 4 8

ends,

ends

audlty

and

htgh

Chemical

as acetic

T"Pl
---

317

20

ALLOY
825

<o 0001

0.00012

WI

0.0002

5%.

50%.

kontd)

rates (ipy)

hexamethylene
tettamme,
an alkyl chloride
durmg
90 days. and ammoma.
aryl.alkyl
chlonde
during 10
days lautoclavel

MOLYBDENUM

<O.OOOl

<0.0001

0.00015
<0.0001

nil

MILK

mdk

Dairy

0.00017

(continued)

Ferrous

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

ALLOYS-CLIMAX

TIPS

304
----mdk whey

oxtdued
sludge effluent
lram
waste, total sohds 1000-1500
oxldlzed
of mdk
taeratmn

hqwds

from

I 57,
0 pH 7.2

dlgester
sludge lexcess oxldlzed
total solads 1.7%. pH 4 5-7 5

190

Dairy

80

c.0 0001

<:00001

D.alry

82

<00001

< 0 0001

waste,

Dairy

104

79

,00001

<o 0001

and whey),

Dairy

105

79

--.

dIgestIon
supernalant
liquor
mdk waste, total soltds 3000

Dairy

98

79

<:o 0001

<O.ODDl

<0 0001

01 mdk

sludge

lram
ppm.

the dlgestmn
pti 7.5

of

OOOOlad

cOOOD1

dlgester

gas from

dlgestmn

of mdk waste

Dairy

95

79

<O.OOlcd

dIgester

gas lrom

dIgestIon

of mdk waste

Davy

105

79

0 OOOlcd

Dairy

110

79

Explosives

212.
215

12.5

150

7.2

2.4

dlgester
gas
from heater

60% Sulfuric
lnltrocellulose

from

dlgestmn

acid. mtrlc
bodmg tub)

01 mdk

acid

waste,

20%,

steam

water

20%

59%

Sulfuric

acod. nitric

acid 22%,

water

19%

Chemical

59%

sullur~c

acid,

acid 22%.

water

19%

Chemul

181

40%

rullur~c

acid. ntitrlc acid 20%,

water

remamder

Research

150

nltrlc

ac!d

Metal
(plcklmg)

150

Sugar

195.
210

Food

RT:
150

33

Petroleum
tdlstdlatwd

100

400

naphtha. IBP 257 F. EP 400 F, speclflc grawty 47 3,


sulfur
00089,.
small
amounts
of dissolved
am.
monla. traces 01 water and hydrogen
sulfide (sump
of top tray 01 column1

Petroleum
Idlstdlatton)

320

538

heavy naphtha
lrom West Texas crude
sulfur 04.
0 5% hydrogen sulhde. traces ol hydrochlarlc
acid,
carbon dloxlde and water

Petroleum
Idlstdlatmn)

85

156

mtrlc

23% approximately
sullwc
acid.
appronmately,
water remainder

TIPS

317

the dIgestIon
of milk
ppm, pH 7 5 tclarlfler)

dtgestlon

TlPE

316

Dairy

sludge and mwed liquor trom the dIgestIon


waste.
total
sohds 0 8.1.2%.
oti 5-7 7
tank1

sludge and
total sollds

MOLYBDENUM

bntd)

Average corrosion rates (ipy)

Corrosion mediums

dealbumlmzed

529

Alloys

26%

.,.

<D.OOOl

<D.OOOl

~0

0.0006

0001

0.0003

DO013

0 0005

0.0065

825

<OOOOl

<O.OOOlbd

31

ALLOY
"20"

0.0043

0.004

0.0046

0.0012

D.ODO13

0.00011

c0.00014

00019

0.0015

MOLASSES
molasses
acldllled
wth
sulfwc
small amounts of phasphonc
acid.
fumes
acetlc

lrom
acid.

acid contammg
pti 6.6 5 Icooker)

molasses
mwng
tank.
calcium chlortde lbluwerl

sulfur

dloxlde.

IX

;DDODlbd

<OOOOlad

<:o0001

<0.0001

<O.OOOlb

<o.Ocma

.,O

<O.OOOld

NlPTl
naphtha
400 API, some hydrogen
sulhde
and
phatic acids alter vapor.phase
clay treatment

all-

OOOld

<O.DOOl

<O.ODOl

<o 0001

(continued)

Corrosion Resistant Materials Handbook

530

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Corrosion mediums

ALLOYS-CLIMAX

lqht

naphtha

naphtha.

cracked

(top ot tower.

tqht naphtha. ammoma.


chlorides trace. pressure

96%
solvent
slbly evolved

(cmtd)

Average corrosion rates (ipy)

TIPf

tqht petroleum
tower1

MOLYBDENUM

llop tray al bubble

vapors1

hydrogen
45 pug

suthde.

naphtha, some mtrogen


Ml
column, vapors)

water.

oxides

Petroleum
tfractlonaIIon)

.
-

215

Petroleum

200.
300

750

Petroleum

100

369

170

35

pos-

304

Petroleum

576

150

polymerlred
naphtha,
fluoride etherate 5%

tri-

Coal By
product (tar
distillation)

123.
195

66

coal tar oils

Coal By
product (tar
fraclionalion)

440

naphthalene

Chemical
(distillation)

naphthalene,
naphthalene
sulfonic
acid, sulfuric
acid 66BC and 50&
(conical washer bottom)

Coal Byproduct

naphthalene,
sulfuric acid 6OB& caustic wash lo%,
water wash, cychc operation (washer bottom1

TlPE

TlPE

316

317

0 0167cd
0 0133cd

0.0186cd

.,

O.OOOlbd

0.0004ad

xx

1 ml

L nil

s<o

vlrgm naphtha stock, hydrogen 24 ~01%. hydrogen


sulhde 0 21 ~01%. hydrocarbons
remamder.
small
amounts of amrnonla and hydrochloric acid

--

0 0003
0001
0.0014

xx

0.04

65

xx

<0.0001

185

36

190

45

XI

xx

corr
corr*

corr

Chemical

199

12

xx

corr

corr

washmg naphthalene.
sulfuric acid 66BC
1.1-1.3
~01%. water washmg and neutralizing
wth
10%
caustic soda 8.16 ~01%

Coal Byproduct

ZOO210

20

xx

xx

0.0672

65% naphthalene,
tar acids 19%, ammonium
ride 0.7 lb/ 1000 gal. pti 5 5 (column)

Coal Byproduct (tar


fractlonalion)

380

60

chlortde.

Chemical

300.
360

63

and man-

Paint and
Varnish

R T:

382

Chemical

450

15

Petroleum

500

174

Petroleum

554

59

resin

distillate.

boron

ALLOY
825

<O.OOOla

00001

<0.0001
so 0002

xx

--

20

0012

0.015

<:o 0001

0 0075

NAPHTAl_ENE

crude naphthalene,
associated
K.P. 200-300 C) Icolumn)

neutral

naphthalene,
chloronaphthalene,
calcrum
calcium owde, hydrochloric
acid trace

chlo-

xx

nit

<0.0001

<0

0 56

0 34

0 0003

0 0002

0.141

Illl

OOOlcd

<O.OOOld

--

0 0005
0.0002

0 0004
WO 0006
0.0002

NAPHTHANATES

naphthanates
ganese

and thallates

naphthenlc

acid

naphthenlc
petroleum.

acid I dlstdlates
sulfur 2.4%

of lead. cobalt

from

naphthemc
acid m heavy dlstlllate
Amer~canpetroleum,sullurcontentolgasolme

South

American

from

South
1.7%

<o 0001

<o

OOO!

<0.0001

350

x
-

xx

0.057

<0.0001

0.0236

0.0003

0.0002

0.0003

<0.0001

0.0002

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

heavy dIstIllate
from
Lagumllas
naphthenlc
acids, neutralization
hydroxide
2 5 mgig thigh vacuum

luel
value
tower)

contammg
potassum

NICKEL

ALLOYS-CLIMAX

TIPI

TWE

TWE

304

316

317

"20"

0 0365
LO 0187

0.0011

0 0002

00003

Chemical

450

15

0 057
0.057

0 0003

oxy-

Mming

300

11

s0.0004

so0009

24.3% approximately.
nlckel.ammonlum-sulfate
vapars.freeammO"la 30 g/l. oxygen partial pressure
<300
pslg

Mwng

300

11

so 0001

s0.0002

21.7% approximately,
free ammoma
gen partial
pressure
375.400
ps,g.
500 psrg Ivapors, Ilquld)

Mining

300

so.02
so 007

so.003
so 004

Metal
lplatmgl

200

26

punbed
nickel-plating
electrolyte,
mckel
42 8%.
sodwm sulfate
31 6%. boric acid 21 5%. calcium
sulfate
121%.
chlorme
lo 0053%.
copper
IO
0 001%. IlO lo 0001%.
pH 5.2

Metal
Iplating)

116.
120

121

<O.OOOld

mckel-platmg
phosphate
3.3 5

Metal
iplatIng)

135

42

0.0007

Mining

191

232

Metal
IplatIng)

160

176

0005lcd

0.0005cd

Agriculture
flnsectludes)

high

31

0.0146

0.00233

Chemical

535

0.31

0.45

Chemical

90

90

WO.026

99%

Chemical

110

90

WO.048

99%

Chemical

130

90

wo.05

98.5%

Explosive

86

30

NICKEL

acid tllquld

AMMONlUM

NICHEL

tree ammoma
<300 ps,g

solution

NICKEL.PLITING

(contd)

107

ALLOY
825

SULFATE

24.3%
approximately.
gen partGil pressure

nickel-chlonde

I~ne)

MOLYBDENUM

531

Average corrosion rates (ipy)

Petroleum
lgasollne
condensing)

naphthenlc

Alloys

bung

30 g!l.

30 g/l, hydrototal pressure

evaporated

to 0015a

0 0013ad

SOLUTION

12

bath, nlckef chloride


27 ozigal. nickel
ozigal.
borx
acid 5.5 ozigal,
pH

<0.0001

0.0005

.sLfITE

39 1.23%.

copper

1 O-0.751.

0.0015-0.02

hydrachlonc

acid,

g/I

(evaporator)

pti 3.3.5

<0.0001

<0.0001
<0

OOOld

<O.OOOld

NlCOTlNE
nlcotlne

solution

NlCOTlNlC

A.cILl

mcotmlc
acid.
phate, ammonta

NITRIC
99%

n~acene

amme.

dtammonlum

phos-

AClD

:L
F

0.09

0.074

0.203

0.042

(continued)

Corrosion Resistant Materials Handbook

532

TABLE

VARIOUS

4.13:

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

niT

98.5%

304
--p-p

1PE

,wt

316

317

(vapors1

86

30

97%

Chemical

90

90

97%

Chemical

:1

110

90

97%

Chemical

:L

130

90

--:

white fuming

0.058

-_:
-.

0.059

825

...

WO 027

...

...
...

WO 025
WO.024

and

;L

160

lunung nltrlc acid

Aircraft
Missile

and

R.T.

30

A.T.

10

--:

0.0008

0.0008

122

10

--:

0.045

0.05

160

10

__1

0.16

0.2

90

90

-:

water

3.5

Aircraft
Missile

and

95.694.5X
white fuming nitric
3.9%. nitrogen dioxide 0.94-1.6796

acid,

water

3.5.

Aircraft
Missile

and

!1

95.M4.5%
white fuming nitric
3.9%, nitrogen dioxide 0.94.1.67%

acid,

water

3.5.

Aircraft
Missile

and

95%

Chemical

95%

: Chemical

:L

110

90

95%

Chemical

:1

130

90

--

:
:

R.T.

30

white fuming

mtrlc acid, inhibited

Aircraft
Missile

and

white turning nitric acid, inhibited

Aircraft
Missile

and

160

LO.15

0.043

LO.0045

O.OCQ5

wo.OQO7
wo.0014
wo.001

LO.OQO2

o.OOil2

LO.001

0.0067

nitric

acid, mtrogen

dmxlde

Alrctaft
and Mtsslle

R.T.

10 __j

0 0006

0.0008

92.8-92.3X
red fuming
4 9% water 2 3-2 9%

nitric

acid. nitrogen

dmxide

Arcraft
and Mssile

122

10

--I

0.065

0.075

92.8.92.3%
red fummg
4.9%
water 2 3-2 9%

nltrlc acid, nitrogen

dioxide

Alwalt
and hksile

160

10

--:

0.17

0.26

Chemical

R.T.

-.

0.3

1551.59,

nltrlc

acid.

nitrogen

dloxlde

6.5%.

Research

250.
300

red tummg
water 2.3%

&tic

acid,

nitrogen

dloxlde

6.5%,

Research

50.
80

--

98

xx

0.016

0.016

0.0051

0.0045

co.0102

CO.0148

Research

-L

65%

Research

65%
65%

E.P.

Research

251

Research

251

co.05

0.0004

red lummg
water 2-396

co.05

wo.0012

92.8.92.3%
red fummg
4 9% water 2 3-2 9%

red fummg mtrlc acid. speclflc gravity


nitrogen dloxtde 13.18%,
water 2.5%

0.02

...

Aircraft
Missile

acid,

0.064
0.017

WO.0125

nitrfc acid

95.&S4.5%
white fuming nitric
3.9%. nitrogen dmxlde 0.94.1.67%

69.5%

ALLOY
20

acid

Explosive

white

bmtd)

Average corrosion rates (ipy)

.
Nafric

MOLYBDENUM

12

2.5

0.0006
0 0004

0.0007

0004

...

...

...

...

(continued)

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

533

hmtd)

Average corrosiQn rates (iPY)

Corrosion mediums

--

TWE

TWE

304

316

ALLOY

TYPE

---

317

20

825

Research

251

XXI

0.011

Research

251

xx

0.011

65%

Research

251

10

xx

0.017

65%

Research

251

--

60%

Research

210

60%

Research

98

xx

509.

Research

98

xx

42%

Research

200

40%

Research

98

xx

<0.0001

30%

Research

98

xx

<0.0001

25%

Research

130

20%

Research

98

xx

<o 0001

10%

Research

98

xx

<0.0001

10%

Research

212

xx

10%

Chemtcal

BP.

30

10%

Research

10%

Research

10%

0.0193
0.0034
0.0002
<0.0001
0 0033

0.0002

0.0042

0.0001

0.0002
0.0003

75

<0.0001

150

<o 0001

M1fWlg

120

70

6%

Research

210

5%

Research

98

5%

Research

212

5%

Metal

86

5%

Metal

5%

Metal

xx

<0.0001

<0.0001
IllI

xx

<0.0001

xx

0 0002

14

xx

xx

<0.0001
L,0.0001

140

14

xx

xx

,.0.0001
LL.0 0001

195

14

xx

xx

,O 0001
L< 00001

NITRIC-ACID
MlXTURES
DROCHLORlC
ACID

WITH

70%. hydrochloric

acid 2%. water

Chemical

70

70%.

hydrochloric

acid 2%. waler

Chemical

200

67%.

hydrochloric

acid 0.1%.

water

Chemical

El.P

0.0094
0 0091

67%.

hydrochloric

acid 0.1%.

water

Chemical

B.P.

0.0088

65%.

hydrochlonc

acid 0 1%. water

Chemical

B.P.

0.0079
0.0083

0.0001

(continued)

Corrosion Resistant Materials Handbook

534
TABLE

4.13:

Corrosion

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

TYPE

304
65%.

hydrochloric

65.46%,

acid 0 1%. water

z~rconyl

nltrate

Chemical

11.13%. chloride

ion

ppm.
water
60%.

hydrochloric

acid 40%,

55%.

hydrochloric

aud

water

1%.

65%,

hydrochloric

hydrofluorlc

50.25%.
36 75%
20%

acld

acid

acid

hydrofluorlc

10

0 063~
LO.12

500-1000
concentra.

Mllg
banurn
reflnlng)

F <175

solution,
chlorides
hquld.
concentrator

Mllg
(uranwm
teflnlng)

F 1175

lplcklmg

tank)

trace

water

3%

12-b%, sulfuw
acid 5.8%
hydrofluorlc
12%
phosphoric
aud <I%.
Virgo

0.007

212

200

320

acid 1.1.
salt deter.

rates (iPY)

TIPE

TIPE

316

317

20

ALLOY
825

0.16

0 049

0 026

xx

0 0049
0.045
0.015
10.0063

0 0004

0.0005
0.0007

0 0004a

00005

0 OOlad
0 002d

0 0009
0.0003

Metal

R 1:
160

Metal

251

xx

75

--

Metal
fplckhngf

120

>2.7
>2.7

0.95

Metal
(pIcklingI

130

1.8

>5.9

LO 193

Metal
fplckfmg)

100

Metal
(pickling)

70

Research

176

Metal

bmd)

65.4

>2

101

0 0004

0001
0 0004

1.64d

74cd

LO 006
LO.06
0 038
0.058

fplcklmg)

3%

aud

258

Chemical

plckllng
solutton
for alummum.
hydrofluorlc
acid 13 7%

hydrofluorlc

20.15%.

10%

0.0078
0 0077

5%. water

rafhnate
(vapors.

Metal

X1-20%.
raffmate
solutlo.
chlorides
ppm. fluorides
50 ppm (vapors,
Ilqud,
tar column)

30%
approximately.
885 ppm average
column)

BP.

MOLYBDENUM

0.002

xx

CO.172

0.06

0.0001
0.0014

0218

0.0004
s<0.0001

0.151

0.185

0.161

0 203

0.0001

0.0005

gent
ll.lO%,
sulfuric
09-l 1%

acid

10%.

acid 3%

hydrofluorlc

ll-15%.

hydrofluorlc

acid

3.3

03

1.65

1.29c

xx

3.78

xx

aa

L62.2
W 5.12

65%.

potaswm

dlchromate

1%

Research

ff P.

--

1.97

3.19

65%,

potasswm

dlchromate

5%

Research

B P.

--

7.65

9.37

Chemical

165

0 002

0.0023
OK

concentrated
nttrtc acid.
saccharlc
acids, mtrogen
corn starch

organic
dlowe

acids as glucomc,
and oxide, water,

0 0033

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TIPS

8Cld

rmxtures

smelter

slag

60%.

onreacted

59.5X,

water

slag

39%,

chromic

acid

1%

Mining

Mining

Rubber

235

68.

70

xx

11

--

42

xx

xx :

62
Research

112

15

ion 5 ppm

Chemical

:F

258

10.3

xx

45.40%.
zirconyl
mtrate
0.8M, sulfate
ion O.OV.4,
van loo 0.003M (concentrator
column. vapors above
reboller
pot)

Chemical
Ifractionation)

190

44.7

245

34

56.5%,
1.5%

phosphonc

56X,
based

metal mtrates
on nrcorwm

45.35%.

saturated

4135%,
Mate

44%.

11.13%.

metal mtrates
ion 3-20 ppm

40%. mtrogen
sorption
tower)

chloride

of 10.35%
nrconylvapors, hquid)

zirconium)

nitrous

nitrate

dioxide

mtrate

(mainly

tetronde,

potassum

nitrogen

with zirconyl

saturated
solutmn
crystals
(evaporator.

45.35%.
chloride

36%,

acid

30%

acid,

lo-20%,

water

approximately,

xx

,.

Chemical

245

29

xx

Chemical

250

21

--Ix;

15

xx

-xxi

0.00296

0.00242

0.0061
0.0061

10.0113
0.013

0.063~
LO.lZc

0.16~

xx :

0.049

Chemical

Pharmaceutlcal

F <415

79

xx

0.0044
S0.0069a
0.0088
LO 0052b
0 0091
s>o 073
L 0017

Chemical

240

33

xx

001

Mmmg

215

70

xx

xx

0.002

Chemical

617

xx

0
0
LO
Ll

Atomic
Energy

160.
190

xx

XI

00013
so.04c

xx :

0.0001
s0.0001
0.0004
SO.0025

35.25%,

mtrous

30%,

largely

30%.

mcotlmc

29.26%.
mtrates
fluoride
rator)

aud

reacted
acid,

traces

(concentrator

column)

slag
methyl

ethyl

pyrldme

free acid 20% approximately,


remamder
of iron, magnewm,
lead and alummum,
ion 3%. sulfate
ton 2% (rattmate
evapo-

13

52

0.049c

0.026

0.0022

0.0008

0.047
0.042

0.026
0.021

0.029
0.017

0.0058
0.013

0.086

0.049
0.043c

nil
10.0001

0.0014

0062
39
39
4

ALLOY
825

0.0116

0.027
0.026

0.016
0.01
10.033
LO.027~

"20"

0.0016

some

ethyl

0.0076

0.012

Chemical

165

TIPE

317

0.002

tab-

95

TIPS

316

0.0015

sodium
mtrate,
won, calcium
and magnewm
nitrates
and sulfates,
imall
amount
of chlorides,
water remainder
(evaporator1
mtrlc
acid. mtrogen
oxldes
..36%,
methyl
pyrldme,
macm. pressure (Ilqwd.
vapors)

hontd)

304
-p--p
NltrlC

MOLYBDENUM

535

Average corrosion rates (ipy)


6

60%.

Alloys

Ilil

0.0015

0.0006
c0.0007

0.0005

0.021
0.017

0.002
0.43
12

00012
so 03c

25%.

potaswm

dlchromate

2.5%

Research

130

00018

0.0026

25%.

potaswm

dlchromate

5%

Research

130

0 0043

0 0069

0 0009

(continued)

Corrosion Resistant Materials Handbook

536

TABLE

4.13:

Corrosion

mediums

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

Average corrosion

1lPE

304
--p-p
21.2%.
chloride

metal
nltrates
02.25%.
sullate
lo 3-13 ppm based on zirconium

20%.

2.5.dtalkyl

pyrldlne.

nlac,

20%.

2.5.dlaikyl

pyrldme,

macm

20%

approximately,

18%.

terephthallc

18%.

lormlc

IS%.

terephthallc

trace,

Chemical

222.
265

0.0052

MOLYBDENUM

rates (ipy)

TYPE

TPE

316

317

0.012

365.
315

0031

0 039

Chemical

365.
375

0 063

0071

Mmmg

0 00014

0.00016

Chemical

303

0 025
0041

0019

Chemical

350

0 064

0.056

Chemtcal

390

05

0 32

18% approximately
untreated
nltrlc acid. rallmate
contammg
lree nltrlc
acld 3N. combmed
rutrates
of won. copper.
calcwm,
cobalt 2 7N. some phasphates and arsenates
of these metals, calcwm
sol.
fate 20 g/l, chloride
mn 50 ppm

Mmmg

195

IO

0 0005

0 0002

nltnc-acid
Ilquor,
high co,wentratmns
other morgantcs
Ievaporator.
vapors)

Mmmg

212

60

0.0045

0 004

14% apprwmately
raffmate.
lree nltnc
acid 4N.
sullates
01 van. copper, cobalt, caluum
16N. phasphates and arsenates
01 these metals, chloride
ion
50 ppm approximately

Metal

210

57

001

0.003

ralfmate
treated
wth sulfuric
acid. lree nltrtc acid
4 6N. free sullur~c
aud 0 4N. sulfates
01 capper,
iron. cobalt and calctum,
phosphates
and arsenates
of these metals, chlonde
non 50 ppm

Metal

250

84

0 0175ad

0 02

13.25%.
chloride

Z~rcexsolut~ons,
0 4M ivapors)

hydrogen

Ato,,,,c

BP

0 13

2.16

13 25%.
chloride

Z~rcex solutmns.
0 4M Ivapors)

hydrogen

13.25%.
chloride

Zlrcex
solutions.
0 4M Ivapors-hqud

hydrogen mn 3M. uranyl


Interphase1

Atomic

13.25%.
chloride

Zrcex
solutions,
hydrogen aon 3M. uranyl
0 4M Ivapors
llqud
Interphase)

Atomic
Energy

BP

reacted
aud

slag

6%. former

acld 0 2%

acid 0 296

acid 6%. lormlc

acid 0 2%

of lfon

(on 3M

and

uranyl

ALLOY
20

625

0 0074

0 0046

LO 0098

Chemical

tvaporsl

11

0 043

0.00015

0.0004

0013

0 026

Energy
bon 3M. uranyl

Atomic

BP

00012
SO 0006

28

Energy
BP

0 I3

29 2

Energy
0.0042
so 0057

28

13 25%. Zlrcex
chloride
0 4M

solutions.

hydrogen

tan 3M, uranyl

Atomic
Energy

BP

13.25%.
chloride

Zlrcex
0.4M

sotutmns.

hydrogen

ion 3M, uranyt

Atomic
Energy

BP

2.65%.
(vapors)

Ztrcex

salutmns.

uranyl

chlonde

0.4M

Atomlc
Energy

BP

00081
SO.0098

2.65%.
Zlrcex
solutmns.
(vapors--llqwd
Interphase1

uranyl

chloride

0 4M

, Atomic
Energy

BP

0.543
so 333

Atomic
Energy

BP.

2.65%.

Z~rcex

solutions.

bntd)

uranyl

chloride

0.4M

0 13

2 13

0.0045
so013

28

0.17

7 28

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

Kid

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

NltrlL

STEELS

ALLOYS-CLIMAX

537

MOLYBDENUM

bmd)

Average corrosion rates (ipy)

m,r,res

B.P

068
so a45

2.65%. Zwcex solutions.


uranylchlonde 0 4U

Atomic
Energy

90%. carbon dmxlde 6%. carbon monoxide 1%.


traces of butanes, penlanes, water and atdehydes

Rayon

86.
131

o&betd crude 011lvaporsl

Petroleum

60

399

crude o11, sodwm chloride 67 lb/l000 bbl. sulfur


0.342% as sulfides (top of crude flash tower1

Petroleum
(dlstillatmnl

230

43

xx

o+fwld

Petroleum

60.
130

399

<0.0001

<O.Oool

lllmo~s crude ml, API gravity 37, salt 100 lb11000


bbl, sulfur 0 4% (vacuum pipe stdll

Petroleum

250.
350

463

<0.0001

<O.ooOl

sweet crude, small amount of hydrogen sulfide (flash


towert

Petroleum

R25

73

0 0006

0 0008

light fuel 011, some water, ethylene dichloride and


hydrochloric acid

Petroleum

225

45

xx

0 02cd

0045c

hghl fuel ml, some water, ethylene dlchlonde and


hydrochlwc acid

Petroleum

150

45

xx

0 004ad

000%

diesel ml. pentachlorphenol

Chemul

225.
232

46

--

IueM washmg. aud wash wth 6686 sulfwc acid


4 lbibbl durmg 4 hriday. and caustic wash wth
Ioak sodurn hydroxide 1~1%

Petroleum

ao105

56

xx

combuslmn products of gases horn 011burners, sullur dmxlde, sulfur trwxlde. selentum dioxide (uptake
from shmes roastmgl

Chemical

1100

42

xx

lube OIIL, azeotraplc salutmn of water and phenol


10% Ialternately Immersed)

Petroleum

210.
230

230

sour lube 011. hydrocarbons 58%. water 40%. WI.


lur~c acid 2% (heavy 011agitator bottom)

Petroleum

100

IS

lubrlcatlng 011s.sulfurvz acid. total acldlty 25%

Petroleum

220

10

lube-ml frachan of heavy crude prmr to neutraluatlon. naphthenlc acads. orgamc sulltdes. some strippmg steam (vacuum tower, vapors)

Petroleum
Mstdlahon)

620

I83

OIL.

Alloys

ii78

x~

<.0000l

0 0001

CRUDE

crude 011.salt water

<0.0001c
0.01 I 'cd
0 008Cd

<0.0001
0 005cd

0 0006

0008

00015

0 008

0.006

OIL. FUEL

5%

<o 0001

<00001

xx

0 018b

ooiaa

0 007b

0.007a

xx

0 0002

00002

0 ooaad
0 019ad

0006a

0 566

056

xx

0 0016cd

00001

0017.3

co 0001

00016'cd

(continued)

538

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

,wt

ml, water

2%,

caustic

added at reflux

TIPE

7PE

316

317

26

Rayon

392.
401

1168

<0.0001

Rayon

131.
158

1168

<OOoOl

hght 011 washmg wth sullur!c actd concentrated


and
sodlum hydroxide 20%. carbon disulhde. hydrogen
sulhde. water 5% tliqwd level1

coat Byproduct

52.
140

189

0.002d

O.OO3d

O.Wl4
CO.OW6

light 011 Ibenzene.


toluene.
sulfuric
acid 92.98%
and
VOI %

Coal Byproduct

115

30

0.02cd
0.051c
0 OOSa

0.017
0.048
0 005a

co.025
co.033
co.004

crude benzol washed wth sultur~c acid 93%. dduted


to 50%
actd m cycle, lotlowed
by neutralizatmn
wlh mdk 01 hme

Coal Byproduct

110

41

0 073c
0.02
0 077c

0.09c

0017
0.012
0.002

non-conderwble
ml. condensed

Petroleum

90.
120

50

Chemical

110

57

<0.0001

<OolNl

Chemical

120

57

<O.OOOlb

<O.ooolc

Chemtcal
Icoal)

284.
320

Petroleum

760

tray

Petroleum
Ifractmnatlon)

715

116

strlpper 011. Jlmonene


95%. lighter alcohol, esters
and other components
durmg 7 days. and alcohol
65.60%.
water during 239 days (freezer)

Beverage

-30

246

xx

xx

<0.0001

<0.0001

vapors and droplets of peroxldes. aldehydes,


lem. fatty acids. 011 traces. all suspended
(fume box at base of venturi scrubber)

Chemical

30.
200

253

xx

xx

<o

<0.0001

Chemical

125

25

Metal
(pIcklIngI

180

80% absorptmn od. butane and pentane 18%.


bon monorlde and dmwde 2%. water trace

hydrocarbon
trahzed wth

aylene) warhmg
wth
wth
caustic soda 16

gases and condensate of hght gas


steam Ivacuum-stdl
condensate
Imel

011. small amount of sulfuric acid, new


caustic solutmn 10% (vapotsl

hydrocarbon od. small amount ot sutfwc


tralwed wth caustic solution IO%

hght 011. steam dlstdled


Itop. bottom ol stdlt

wth

actd. new

creosote

cracked
petroleum
gas
od.
<
27C.. mercaptans.
orgaw
stage tar separator)

combmed

gas 011 lram


of tower)

0 5%

50.20%.
sollds

car-

crude charge.

sulfuric

acid

sullur

1.5.3%,

sulbdes

011

rullu~

0.00067ad

ALLOY
625

0.0002

<0.ooo1

0.087
0.015

<O.OOOl

nil
0.0002

175

xx

0.0042

0.0037

II

0 0005

0.0005

(second

(bottom

suspended

oxaltc acid, Oakde solution, sodium


known wettmg agent 2% approximately

wash

kontd

Average corrosion rates (ipy)

304
-----

98% mmeral
200 lb/day

MOLYBDENUM

acrom air

crystals,

bisullate,

un-

xx

--

0001

0.0003d

0.0002
0 068

0 0004

<o

c0.00044

0001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

NICKEL

ALLOYS-CLIMAX

539

Alloys

MOLYBDENUM

bmtdl

Average corrosion rates (ipy)

TPt

TPl

TYPE

304

316

317

--

ALLOY
--

20

825

OZONE

0.23%
ozone
approximately

ozonated

III air,

nitrogen

pentoxlde

0.1

mg/l

Water
Treatment

tap water

ester gum. drymg

Chemlcat

011s fvapors,

hquid)

R.T.

60

0 0004

35.
70

\o 0001

Pant and
Varnrsh

550.
600

20

0 0001
0 0001

Plastic

122

73

<o 0001

<o 0001

palm 011

Metal

350.
450

30

<0.0001

c.0 0001

palm 011

Metal

300

sulfite-dlgester
hquor, free sullur
dloxfde 7.02%.
combmed
sullur dloxlde
1 21% ImU
composltlon
average).
cookmg
acid has sulfur
dloxlde
7.42%
total. pH 1.32, pressure
65.70 psig

Pulp and
Paper

131

55

<0.0001

<0.0001

sulhte
sullur

Pulp and
Paper

172

51

0 0001

0 0001

Pulp and
Paper

260

96

co 0002

0 0004
0 0025~
c0.0002

0 0007
0 0005

dloxlde

Pulp and
Paper

79

172

to 0001

0 0001

0 0001

sulfur

Pulp and
Paper

180

17

0 0002b

00001

Pulp and
Paper

65

109

neutralized
varmsh, acetlc acid 63 7%, water 16%.
methyl acetate 2 5%. ammonium
sulfate 2 2%. lormaldehyde
7%. ammonwn
acetate 0.3%

PALM

OIL

Ilquor,
droxade

lree

I 2%

sulfur

dloxlde

sulllte cookmg acid, total sullur


bmed sulfur dloxlde 1% tat start

calcium-blsulhte
4 4%. combmed
sulbte
dloxlde

paper

pulpmg

stock,

cookmg tlquor,
sulfur dloxrde
vapors.

weakly

large

6 3%,

combmed

dloxlde
6%.
of cookmgl

free

I 1%

amount

acid to pH 5 (flow

sulfur

of wet

com-

box)

approxamately,

sul-

Pulp and
Paper

84

76

water suspension
of sulhte fiber 0 4%. sulhte
liquor trace. pH 6 Illat screen header)

waste

Pulp and
Paper

35

48

Pulp and
Paper

103

paper stock. corwstency


lurrc acid 4 mgil

3%

PAPER.

SPENT

sulllteblsulflte
pti 6.2 (top at packmg

.NI~OIWI

3x,

A,CID PULPING.

0 0005bd

<o

0.00014cd

<0

OOOlad

0001

10

0001

n1l

nil

0 0001

n1l

wUOR

solutlon,
sullur
dioxide
m absorption
tower)

0 0002

0 Ml03

(continued)

Corrosion

540

TABLE

4.13:

Corrosion

Resistant Materials Handbook

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

TYPE

Pawr.

ace* pulptng.

II:

xx

304
-----

Pulp and
Paper

107

dlgester
hquor,
sulfite 3 4%

bl-

Pulp and
Paper

70

faa

O.SZ%,
dtis.
screen head

Pulp and
Paper

45

97

Pulp and
Paper

51

Pulp and
Paper

Pulp and
Paper

Pulp and
Paper

sulfur

dloxlde

4 7.5%.

calcium

2.2

0 0003

106

xx

I):

60

140

..o

a4

140

xx

265

132

Pulp and
Paper

190

180

Pulp and
Paper

228

sodwm
hydronde
II 5% expressed
as sodtium oxIde. sodwm carbonate
and sulfide etc
5%. cookmg Western
red cedar tblow end cone of rotatmg
dlgesterl

Pulp and
Paper

F <350

sodium hydronde
II 5% expressed
as sodwm oxIde. sodwm carbonate
and sulfide etc 1 5%. cookmg hemlocks
90% and spruce 10% (blow end cone
of rotatmg
dlgesterl

Pulp and
Paper

ktaft pulp stock,


chme, flow boxI

ma-

pulp suspension.
sollds 1500-2000

consistency
ppm IsulfIte

sulfite pulp consistency


so screen head box)

0 25-O 6%.

wash
Dll)

stock.

water

from

wash water
seal box)

sulfite

from

sulfite

sulfite

waste

Ilquor.

sulfde

waste

liquor

rates (ipy)

*WE

TlPE

316

317

20

0 0004

0 0004

0.0004

0 0001

0 0001

0.0001

pH 4 5-6 (Johns.

pH 5 75 fsulflte

stock.

seal

pH 5 twhlte-water

pH 3 5

1:

(0.0001

I:

0.0001

0001

00001

0.0001

<o

0001

c<o 0001

x.0

0001

c~ooool

0 OOOlad

0 OOOlad

IX

0 0001

0 0001

0 0001

0 0001

31

0 0002

0 0006

F ~350

31

0 0002

0.0006

Pulp and
Paper

90

43

flue gas from kraft black.hquor


recovery
furnace.
sodium
sulfate,
sodium
carbonate.
sulfur
dioxide.
sulfur
trloxlde.
hydrogen
sulfide.
methyl
mercaptan, water, orgamc oxtdatlon
products.
sodium compounds
as sodturn
sulfate
1.7 lblmin
(venturi
scrubber1

Pulp and
Paper

160.
200

66

0 012cd

flue gas from kraft black-hquor


recovery
furnace,
sodwm
sulfate,
sodium
carbonate,
sulfur dioxide.
sulfur trloxlde,
hydrogen sutflde, methyl mercaptan.
water. organic
oxldatlon
compounds,
sodium
compounds
as sodium
sulfate
10 Ib/min
(venturi
scrubber)

Pulp and
Paper

400.
435

66

0 OOOlad

sodlum
bonate

Pulp and
Paper

iao

204

<OOOOl

<O.OOOl

450

25

0.021

0 047

wth orgamc sulfide, remainder


sodwmhquor recovery.
pH 4 5 (evaporator,

47.43%

alum

wed,

carbonate.
sodwm
(mud thlckenerf

black

hquor

ALLOY
825

<0.0001

II

water vapor
base sulfite
VaporsJ

(contd)

spent ,,quo,

ammonium
sulf~le~btsulf~te
solutlan.
sulfur
dioxide
3%. pti 6 2 (top of packmg I absorption
tower)

sulfite
solved
box1

MOLYBDENUM

pH 6 5-7 (paper

sulflde.

calcium

car-

Pulp and
Paper

64

<0.0001

<0

00001

00001

0.0001

0001

0 0006

OOOld

0.0002cd

<O.OOOlad

O.OOOlbd

<O.OOOlad

O.OOOlbd

<O.OOOlad

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

s
.
black

Caustic

IllIrate.

lrquar

Pulp and
Paper

pH 9 5

60

.
--

450

TYPE

,PE

,PL

304
-p--p

316

317

0 028

0 049

140

45

xx

Pulp and
Paper

70.
85

a7

<OOOOld

vat)

Pulp and
Paper

139

209

0 0001

0.0001

chlo-

Pulp and
Paper

68.
78

31

xx

0 002cd

O.OOlcd

chlarrne

Pulp and
Paper

60.
90

83

chlorme-droxrde
water, chtorme-droxrde
gas, hydra.
chlorrc acrd 0 2 gl I, pH 3.5 thltratron box)

Pulp and
Paper

160

45

Pulp and
Paper

95

17

150 g/l

Pulp and
Paper

85

17

40 g/l

Pulp and
Paper

95

Pulp and
Paper

Pulp and

zmc-hydrosulhte

bleach,

after last washrng


fwhrte-water
flume

pH 4.2 (Oliver

bleached sulfate pulp contammg


rme ffuststage
bleach washer)
waste
0.0350

water
from
07 gi I

washer

some resrdual

chlormatron

washer,

bleachrng

solutron,

sodrum hypochlorrte

bleachmg

solutron.

sodrum hypochlorrte

bleachrng

solutron.

calcrum

40 gl

hypochlorrte

hypochlorde
solutron, calcrum chloride 1.5 g/l.
crum hypochlorrte
0.1 g/l. pH 7.2 (washer)
Pratt pulp stock wrth resrdual
bleach, pH 6 5 (head box)

Cal-

chlorrne-droxide

xx

L.

OOOOld

<O.OOOld

L<O

0001

<o

0001

<0

LO 0008
0.0006

0 0003c

0 0003

--

0.0014

0.0003c

17

--

0 0062~

0.0428~

120

68

xx

xx

L0.0004bd

10.0002a

155

14

xx

0.0003a

O.OOOla

0 0001

0 0001

Pulp and
Paper

97

169

xx

xx

groundwood
crdes, pH 5

300 ppm, shmr-

Pulp and
Paper

120.
127

161

< 0.0001

<o

6-8

Pulp and
Paper

130

152

xx

i 0 0001

<00001

Pulp and
Paper

125

161

xx

<0.0001

<00001

alum

groundwood
stock
au dry alum
4 4-4 1 ientrdnce to bull screenL
300

ppm,

groundwood
pulp stock. sulfurrc
droxrde pH 4 2-4 4 Wourdrrnrer)

lb/tan,

pH

consfstency

sulfur

Pulp and
Paper

87

210

xx

(washer

flume

Pulp and
Paper

140

163

<O OOOld

(0

fan)

Pulp and
Paper

91.
130

189

<o

<0.0001

sultur droxrde. being absorbed m sodrum-carbonate


solutron. sulturrc and sulfurous acrd, carbon drox!de.
tree sulfur I the gas Itan rnletl

Pulp and
Paper

160

45

pulp, consistency

vapors from groundwood

<o 0001
<0.0001

0 0007d

0 0004ad

0.0003ad

0 0002b

0.0002

0.0003

0 0003

<o

0001

0.0003

0.0093a

0.0003a

co.0002

O.tXKfla

0.0001

acid

0001

and

groundwood
bottom)

<00001

ALLOY
825

Paper

groundwood
teed.
alum
0 469,, slrmrcrdes. pH 5

0 OOOld

20

OOCIld

paper-mrll
head-box stock, groundwood
and sulfite
pulp 0 5-O 6%, chlorme
ppm, pH 5 2-6
pulp to deckers,

(contd)

c
y2 Q

Pulp and
Paper

bleached
sulhte whrte water
stage of calcrum hypochlorrte
from deck&

MOLYBDENUM

541

Average corrosion rates (ipy)

41.43%

ALLOYS-CLIMAX

Alloys

3.4%

pulp grmders

(exhaust

00001

0001

0 0001

0 0001

0001

0001

0 0007

0.0007

(continued)

Corrosion Resistant Materials Handbook

542

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TYPE

TYPE

TYPE

304
-----

316

317

neutral sulhle serm chemrcal


coohmg hquor. spew
me I sulfur-dmrlde
gas durmg 52 days, I hquor
wlhout
sulfur bm~~de durmg 81 days. sodwm
sul.
hte 14 Ibcu 11 and sodwm carbonate
3 5 Ib:cu 11
I hnrshed hquor (absorplmn
towerl

Pulp and
Paper

140

neutral
washer

stock

Pulp and
Paper

176

125

xi

xx

0.0001

0.0001

levapo.

Pulp and
Paper

131.

56

0 0001

00001

0002

spent
ratorl

neutral

semr-chemrcal

sulhle

pulp

lvacuum

semi-chemrcal

hquor

0.0001

c0.0002

0 0001

0 0001

0 0006

co 0003

xx

0 038~

0 0089

0.0062

0 0001

0 0001

0.0001

0 0022

00001

0.0002

tevapo-

Pulp and
Paper

131.
216

spent
rator)

sulhle

semi-chemical

hquor

levapo-

Pulp and
Paper

131.
233

water, steam, carbon dmxrde. sadrum carbonate


and
sulfate,
sulfur
droxrde
and trmxrde
(exhaust
gas
from tower, bemg absorbed
m soda-ash salutronl

Pulp and
Paper

212

95

sodrum-sulfite
Me, thtosulfate
evaporator)

Irquor.
and

sadturn sul10 (vacuum

Pulp and
Paper

212

6.4 -

sodwm-sulhte
Me. thmsulfate

hquor, sodwm
and polysulhde,

sulhde,
fodwm
sutpti 10 tevaporatorl

Pulp and
Paper

212

--

bller stock contammg


waste paper 75%. top lmer
stock 25% tmlxture
of sulhte. soda and kraft pulps
wth envelope cuttings).
alum treated to ptt 4.3

Pulp and
Paper

75

140

xx

<o 0001

<0.0001

waste
paper
pulp
tcyhnder mold1

0.25%.

sodium

chlortde

1%

Pulp and
Paper

115

180

xx

xx

<0.0001

<0.0001

waste
paper
pulp
tcylmder mold1

025%,

sodrum

chloride

1%

Pulp and
Paper

115

180

xx

xx

Pulp and
Paper

60

88

Pulpand
Paper

65

53

solution.

parchmentlzmg
cwm sultate

solutmn,

sulfuric

parchmentwng

sotutmn.

sullur~c

acrd 35.40%

Pulp and
Paper

65

50

xx

parchmentwng

solutmn.

sulturrc

acrd 35.40%

Pulp and
Paper

60

53

Pulp and
Paper

70

88

Pulp and
Paper

70

53

nrtrrc

solutmn,

sulfurrc

acrd

65 5-68 5%

110

parchmentlzmg
nrtrrc acid

parchmenlwng

sulfuric

acid

54%.

acrd

acid

parchmentwng

salutron,

sulfuric

acrd 5.8%

cal-

35.38%.

c0.0001

0.0004

lrquar

ALLOY
825

0 0001

semrxhemrcal

20

0 0001

sulhte

sodrum
sulhde,
polysulhde.
pH

0 0001

216

spent neutral
rator. vapors)
neutral

(amtd)

Average corrosion rates (ipy)

.2
.

sulhte.
vat)

MOLYBDENUM

0.0012cd

<0.0001

<o 0001

:o 0001

<o 0001

0 0001

0 0001

0 0001

0 0001

xx

0.0001

0.0001

0.0001

0.0001

00001

00001

0.0001

O.COOl

<0.0001

<o 0001
x

0.0001

<o

0001

0.0001

00001

0 0001

<o

0001

0 0001

(continued)

Ferrous A l/o ys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

NICKEL

Test
conditions

Corrosion mediums

we. ptt 5-6 durmg 7.7 days, and


small amount of zmc sulfate dur-

ALLOYS-CLIMAX

TYPE

TYPE

TWE

304

316

317

0.0001a

0.0001a

0001

0.0001

----

Pulp and
Paper

140

sulhte
drssalvmg
pulp,
and 55.5 during 83 days

Pulp and
Paper

60

250

xx

xx

whrte water. consrstency


0.25%.
sulfites
38 ppm,
thmsulhtes
22 ppm. ptt 3.8-5 (paper machme
wire

Pulp and
Paper

118

100

<~0.0001

<0.0001

paper-machme
whrte water. hber 0.07%, alum. suihte waste hquor.
phenyl rnercuw
acetate
trace,
pti 4.3 (canal from suctron box)

Pulp and
Paper

83

35

xx

xx

<o OCOl

<0.0001

sulhte
whtte waler,
alum.
some pulp lpump box)

droxlde.

Pulp and
Paper

70

79

xx

xx

<o 0001~

<o 0001

shower

Pulp and
Paper

88.
118

231

xx

xx

0.0001

<0.0001

0.06%

Pulp and
Paper

108

295

xx

xx

<o 0001

<o 0001

groundwood
white water. total acrdrty as calcwm
carbonate
534 ppm. pH 42 average (groundwood
screen shower pond1

Pulp and
Paper

123.
136

134

xx

\0.0001

<0.0001

groundwood
5 3 average

Pulp and
Paper

108

141

xx

<0.0001

<o 0001

Pulp and
Paper

110

Pulp and
Paper

Pulp and
Paper

newsprmt
whrte water, groundwood
and sulfite furrush. small amounts
residual
wood acrd. sulfurous
acrd. calcium bwlhte.
bleach hquor (paper machmel

Pulp and
Paper

paper-machme
white water, total acvAty as calcium
carbonate
37.3 ppm average. pH 4.3 average
paper-machme

white
water from bleach
pH 3 7-4 durmg 167 days,

MOLYBDENUM

bmtd)

Average corrosion rates (ipy)

.
glue alum paper
starch alum we.
mg 1 3 days

HIGH

543

20

<0.0001

ALLOY
825

<0.0001

prtl

groundwood
pond)
groundwood
lgroundwood

white

water

wtute
screen

whrte

senwchemrcal

neutral

papevmachme

whrte

we.

(groundwood

screen

water.
consistency
shower pond)

water.

consrstency

sulhte

water

hquor,

whrte

006%.

pH

pH 7.2

krffler)

paper-machme
whrte water.
sulhte
18.22%,
consrstency
pH 4.4 approximately

0 01%,

trtanrum

water.

groundwood
78.82%.
0.3% approximately.

consistency

0.002.

pH 5 trltfler)

paper-machme
white water, aluminum
hydroxrde.
pH 5.2 average Ifourdrinierl

sulfate

and

80.

82

to 0001

0001

231

xx

xx

<00001

<0.0001

66

150

xx

<00001
<0.0001

<o 0001

95

186

xx

xx

< 0.0001

<o 0001

Pulp and
Paper

87.
107

140

xx

xx

. 00001

~.00001

Pulp and
Paper

32

974

Pulp and
Paper

60.
85

185

<o 0001

<0.0001a

0.0001

0 0001

106

llll

0.0001

00001

WI

0.0001

(continued)

Corrosion Resistant Materials Handbook

544

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

INDUSlIV
IPIIOCESSI
WnlTE

WATER.

PAPER

MOLYBDENUM

(contd)

Average corrosion rates (ipy)


E
r
t;
P
r
i-5 3
8
oc UyI
-9s
f
et2
L

-.
PAPER.

ALLOYS-CLIMAX

s
c

1VPE

t
.

4
.

304
-----

1VPE

TPE

316

317

20

ALLOY
625

BOARD.

WASTE

rrch whrte water from hardboard manufacture, ptl


4.346

Pulp and
Paper

110

275

<O.OOOl

<O.OOOl

Pulp and
Paper

60

32

<0.0001

<0.0001

kraft and semrxhemrcal whrte water, pH 6-g flog


shucmg)

Pulp and
Paper

45.
a5

222

<0.0001

<0.ooo1

kraft whrte water. sulfate 0.045 g/l. sulfide 0.025


g/l. chlorrde 102 ppm, pH 7.3-g 2 (fog sluicing)

Pulp and
Paper

45.
a5

98

0.0001

Parco compound solutron. phosphorrc-acrd base

Metal

30

0.0bo1
O.OM)l

Parco Lubrrte

Metal

200

30

Bonderrte K solutron. sodmm 0.62%. chlorate


0.51%. phosphate 0.251%. ndrate 0.25-l%, chlorrde 0 l-l%, zmc 025-O 75%, phosphorrc acid
0 25.0 5%. copper 0 005~0.01%. pH 2-2.5

Metal

150.
160

33

0.0006d

BondeWe 0 180 solutron

Metal

30

<O.OOOl

<O.OOill

Eonderrte 160 so1uI1on

Metal

30

<O.OOOl

<O.OOOl

Food

<0.0001
<0.0001

<0.0001

<O.OOOld

<o.ooo1

PAPER.

WlTE

WATER.

SODA

soda-pulp whrte water

PAPER.

WHITE
WATER.

PARKERIZING

SVLFATE

0.0001

SOLUTION

<0.0001
<0.0001

<O.oooI

0.0001

0.004

PECTlll

thin pectm hquor. lactic acid 0.26%.


0 05%. carbon 0.03%. pH 3.8

malic acid

3.8

xx

XI

1E

thin pectm liquor, malic acrd 0.2%. sulfur dioxide


0.065%. pH 2.7

Food

120

30

xx

2% pectin extract from apple pomace. saturated


with sulfur dioxide

Food

70.
190

39

<O.OOOld

<O.OOOl

2% pectm extract from apple pomace. saturated


wrth sulfur dioxide Ivapors)

Food

120

39

<O.OGOld

<O.OOol

175

56

xx

0.026~

0.027~

40.
100

346

xx

<0.OGO1

<0.ooo1

PENTANE

pentane vapors (compressor drschargef

0.02ac

PESTICIDES

pestrcide solulron for spraymg vegetable crops.


Orthane emulsron New Green. Malathion.
20-20-20 soluble fertilizer, ziw, copper. Aldrin.
sulfur fspray tank bottom)

Agriculture

(continued)

Ferrous Alloys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

545

hmtd)

Test
Corrosion

Average corrosion

mediums

f
fs $.

. .

rates (ipy)

TYPE

IYPf

1VPL

304

316

317

nil

<O.OoOl

20

varrely of pestrcrdes. Ovatran,


ON dry mix, sulfur, copper sulfate,
zinc copper 011. zmc copper
sulfur mrxture. or1 emulsron

AgrlCultUre

60.
120

230

hydrated hme, copper sullate. lead arsenate, Para.


thron. Mrcrohne,
Raped Grow soluble fertitrrer

Agrrculture

90

277

xx

<O.OOOl

<0.0001

DOT
SIO

emut.

Agrrculture

90

277

xx

<0.0001

<0.0001

heptachlor
emulsron.
copper sulfate,
magnesmm
sulfate, Zrram wettable powder, Zrreb wettable
powder.
Parathron
emulsron.
Parathron
wet.
table powder,
DOT emulsron.
TOE emulsron,
Toxaphen emulsron. 1020-10
lrqurd fertrlrzer

Agrmulture

70.
85

258

xx

<o 0001
<0.0001'

<0.0001

Drathane
2 qt/lDO
gal, New Green 1 ptl100
pal. Malathron
lb1100 aal. water-soluble
olant
rood 20-20.20
5 lb/ 100 &.zinc
0.5 lb/ 106 gal,
cobalt, water

Agrrculture

40.
100

xx

<O.OOol

<o.OOo1

pesticide
solutfons for spraying
late wettable powder, Panate
trrbasrc copper sulfate, Zerlate

Agriculture

60.
100

420

xx

0.0001

0.0001

Chemical

140.
203

13

xx

0.197

0.138

O.OOlcd

0.0006cd

C0.0005r

0.0008a

0.00056

co.Ooo3

powder,

wettable

sulfur,

Malathion

2.4.dichlorophenoxyacetrc
hol (top of still, vapors)

tomatoes,
Marwettable powder,
wettable
powder

acrd ester

of butyl

alco-

151

xx

monochtorobenzene.

sulfur droxrde. water

Chemical

65

157

chloral.

acrd

Chemical

70

156

Bordeaux
mrxture. wettable
sulfur, copper salts,
nicotine sulfate. summer.oil
emulsions,
separately
and in combmations
(spray tank bottom)

Agrfcutture

60.
75

3.2

xx

xx

0.0002

Bordeaux mixture, wettable sulfur and Irmesulfur,


separately and in combmations
(spray tank bottom)

Agrrculture

76

1.3

xx

xx

ODD06
0.0074

pesticide solution for spraying crtrus fruit, sullur.


time sulfur, zinc. copper, iron, manganese,
borax,
molybdate, 011, magnesmm.
0.N , Ovatron.
Sistax, Parathion,
Malathion,
2-4-D

Agrrculture

40.
100

266

xx

mrxture of acetone, phenol,


ptf 5.8.8Icondenser)

Pharmaceutrcal

70.
150

42

Pharmaceutrcal

Pharmaceutrcal

hydrochlorrc

water,

alcohol

slop from lrver extractron

alcohol

slop horn pharmaceutrcal

alcohol

stop from msulm

lrver compounds.

extractron

extractron

alcohol recovered from msulm extractron,


rcrds trace, orgamc acrds trace, sodium
monium salts trace Icolumn)

salrcylrc.
anhydrrde

acetrc

and

acetylsaticylrc

acrds.

mmeral
and am

acetic

<0.0001

0.0003

nil

0001

91

\o

0001

91

<O.DOOl

<O.OOOl

Pharmaceutrcat

91

<O.OOOld

<0.0001

Pharmaceutical
ffractiona
tront

91

O.OOlcd
<00001

<O.OWcd
<O.oOol

Pharmaceutical

33

0.0008ad

0085

<O.ocGl

(0

140

ALLOY
825

<0.0001

<o.Ooo1

<o.oOo1

0.0006

(continued)

546

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TYPE

TWE

TIPE

304

316

317

Pharmaceut1cal

249

10%

Pharmaceutical

RT.

20

Pharmaceutrcal

70

62

Cbemrcal

590

--

Chemrcal
ldrstillationl

311

276

<0.0001

Chemical
llractmnaIron)

302

125

xx

00217

Chemtcat

590

--

80.70%.
,,-methyl
styrene. acetophenone
and mesttyl oxide 5%. water 1.3%. pH 4-5 (top of head of
vertical reborler of cracking still)

Petrochemical
tdistdlation)

435

3.5

0.1

0.002

phenol,

Chemical

378

--

0.037

0.023

phenol,
hydrocarbon
alkylation.
phosphorus
trrchloride 1%. boron trifluoride
0.796, hydrochloric
acid, possibly hydrofluoric
acid liberated

Chemical
lalkylatronl

175

12

pure phenol,

Chemical

590

germrcide.

pH 10 3 inrtially

intravenous
solutmn. dextrose
IO-50%.
water, sodrum chlorrde 09%.
calcwm
chloride,
potassum
chlorrde. ddute crtric acid, sodrum crtrate, sodrum
lactate, extremely
drlute vrtamm solutions, pH 4-7

bmtd)

Average corrosion rate: (ipy)

15% sulfuric acrd and sugar lrom the digestion of


tuber Barbasco. neutrahzation
wrth lime at end of
run lautoclavel
Roccal

MOLYBDENUM

<0.0001

<0.0001

(0.0001

<o 0001

625

0.051
co 051

O.lcr

ALLOY
20

PHENOL

phenol,
95%.

pure
acetophenone

phenol (bottom

5%

(bottom

of wlumn.

used plant phenol,

vapors)

some sulfur

hydrochloric

of column)

compounds

acid 0.26%

sulfur 0.5%

as butyt disullide

IllI

IllI

0.0034

0001

amylene

Chemical

113

25

xx

0.0288
0.0004a

phenol, amyl phenol, some sulfuric acid,


sulfurous acid (digester, vapors. liqwdl

amylene.

Chemical

230

17

0.0191r
0.153

0.0124ar
0.0506

ltower,

Petroleum

220

43

0.0029
0.0117
O.OQ184

0.0025
0.0168

ppm ltower.

Petroleum

220

71

xx

0.004r
0.004r

0.004r

217

xx

o.Om

xx

0.0003

10% phenolic
vapors, liqurdl

10% phenolic
vapors)

water,

water,

some

sulfuric

chlorides

chlorides

1320

ppm

lo-1320

phenol, acetone, cumene.


ldecomposer
drum bottom)

sulfur

dioxide

100

ppm

Chemical

150

phenol, acetone,
curnene,
(decomoorer
drum1

sulfur

dioxide

100

ppm

Chemical

150

16

0.0009

0.0055
<0.0001

<0.0001

0.00015

phenol. curnene, ,t.methyt styrene. water,


very mildly acid (bottom of column)

neutral

or

Chemical
(distillation)

304

109

<0.0001

<o.cQO1

phenol, cumene. +melhyl


very mildly acid (bottom

neutral

or

Chemical
ldistillationl

304

52

<0.0001

<O.OOQl

styrene. water,
of column1

0.0007

0.001

acid,

phenol, amyl phenol,


(vapors, liquid)

<o COOI

<O.OOOl

0.0008
so.0015

0.002

l--

nil

0.004r

<o.OOm

<0.0001

0.00014

<O.OOOI

0.00014

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

Alto ys

MOLYBDENUM

a
05

TVCE

304
--p-p

TV?E

TIPE

316

311

phenol, ,B-methyl rtyrene.


trace, neutral or very mildly

acetophenone.
cumene
acid lbottom of column1

Chemical
ffractionationf

304

54

<o 0001

phenol, ,,-methyl
styrene.
trace, neutral or very mildly

acetophenone.
cumene
acid (bottom of column)

Chemical
ffractionationl

304

40

<0.0001

Pharmaceutical

214

28

Chemrcal

390

18

Coal Byproduct

212.
221

14

xx

0 064

0 0004

Chemrcal
khstnfatronl

240.
260

xx

0 0018

0 0009

81%
approximately
phenyldrchlorarsme.
drphenyl.
arsme 17 5%. trrphenylarsme
5%. some tar

Chemrcal
ldn.tdlation)

180.
185

xx

0 0039

0.0067

55% phenyldrchlorarsme,
prsenrc trrchlorrde 32%.
drphenylarsme
12%, trrphenylarsme
1%. some tar

Chemrcal
tdrstdlatronf

I95
202

xx

0.0178

0.0018

mrxture of arsenrc trichlorrde,


drphenylarsme.
triphenylarsme,

Chemical
tdrstdlation)

195.
520

3.3

XI

0.0012

0.0009

Chemical

380

0 182
0.196

0 087
0.089

Rubber

75.
85

0.0001

0.0001

Research

450.
485

0.98

0.18

Research

2m

0 13

0.0005

PENl.ACETlC

phenylacetrc
organrcs

,Ol.,

PHEWL

zmc chloride,
liquid1

small

bntd)

Average corrosion rates (ipy)


E

phthahc
anhydride.
phenol,
amount sulfurrc acrd Ivapors.

547

0.11
0.0047

20

<0.0001

<OOoOl

0.0001

<O.OoOl

0.027
0.0057

ALLOY
626

co.017
0.0048

ACID

acrd.

some

chlorrdes.

possrbly

other

0.033

AMINE

molten mixture of drphenylamme


part, rodme 05%
approxrmately.
thiazme and hydrogen-sulhde
gas

3 parts, sulfur 1
to form phena-

PHEWLARSINE

92% rpprorimatsly
__.
u%. some tar

dtphenylarsme,

trrphenylarsme

MM., PENl_

SIX.

phenol

trrphenyl

CAR.ONATE

I I%,alummum

phosphate.

lfJS.1~103.6%

phenyldrchlorarsme.
some tar

chlorrde

technrcal

superphosphorrc

acrd

complex

1%

92%

plant phosphorrc

acrd

Research

358

92%

plant phorphorrc

acrd

Research

358

IO

>6

XI

II

--

xx

corr

0.0001

c00001

corr
corr

(continued)

Corrosion Resistant Materials Handbook

548

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

mediums

STEELS AND HIGH NICKEL

Test
conditions

Average corrosion

5 5
. .

Pliosphor,s

a.z,d

phosphoric acld

ALLOYS-CLIMAX

TYPE

TYPE

rwt

316

317

260

90%

Research

210

90%

Research

280

Chemical

190.
215

81.02%

Research

I90215

95%

Research

125

co.05
co2

85%

Research

175

co.05
co.2

95%

Research

200

85%

Research

1208

99%

Research

99%

Research

15%

Dlanl

3142.2%.

tmpwtles. lower uwdes of phosphorus

>6

xx

xx

bntd)

rates (ipy)

304
--p-p

Research

90%

MOLYBDENUM

0.015

ALLOY

20

625

0 01
co.02
co.05

xx

xx

xx

0.015

0 024

0579

0.021

0 005

0 58
NG

0.021

0.005

0.0054

xx

00012

xx

0.002

208

0.28

235

xx

0.005
o.Lxl3

Research

235

0.05
0.023

96%

Research

255

xx

0.013
0.01
0.018

95%

Research

255

0.11

290

0 14
0093

95%

Research

95%

Research

1290

DSX

Research

300

XI

95%

Research

300

B5X

Research

1320

85%

Research

95%

Research

85%

Research

95% plant phosphoric acid

Research

1208

15% plant phosphoric acid

Research

0.012
0.025
0.1

II

0.3
0.4
0.24

0 12
0 27
0.3
0.29
0.5
c>o.2

325
245.

c>o.2

410
B.P.

MB

--

1.17

33.6

85.5
69.2
xx

0.001

0.004
0.005

0.002

(continued)

Ferrous

TABLE

4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX
Average corrosion

549

A l/o ys

MOLYBDENUM

hcmtd)

rates (ipy)

r
8
z

s
::
.

5
::
.

---

TYPE

Twf

rrrr.

304

316

317

ALLOY

--

20

825

85% plant phosphonc acid

Research

235

xx

0 004
0.008

85% plant phosphoric acid

Re:earch

235

0.018

85% plant phosphoric acid

Research

255

xx

0.015
0.03

...

...

85% plant phosphoric acid

Research

255

0.051
0.11

...

...

...

85% plant phosphor&cacid

Research

280

xx

0.07
0.12

...

...

...

85% plant phosphoric acid

Research

280

0.24
0.47

85% plant phosphoric acid

Research

300

xx

0.063
0.12

85% plant phosphoric acid

Research

300

0.3

tracer of lead.

Petroleum

430

167

0.0181

0.007

66%. chlor&s. sulfates. mtrates. traces of lead.


iron and arsenic

Petroleum

430

121

0.0187
0.0007
0.0029d
0.0015

0.0028d
0.0006
0.0014

85%. chlorides. sullates. ndnles.


MO and arsemc

traces of lead,

Perdcum

430

117

O.WO8
0.0065
0.0033b

0.0005
0.0034
0.0013a

85%. chlorldts. sulfates, Mates.


iron and arsemc

traces of lead,

Petroleum

430

46

0.0261a

0.0074a

85-78X

Research

R.T.

0.0001

0.0001

8578%

Research

220.
240

0.23

0.005

84%

Research

320

82%. pressure

Research

235

co.02
co.05

82%. pressute

Research

290

co.05
co.2

86%

Chemical

R.T.

10%

Research

75

80%

Chemical

175

80%

Research

255

80% plant phosphoric acld

Research

150

>6

xx

0.0009

80% plant phosphoric acid

Research

200

>6

xx

o.OOfJ2

80% plant phorphorlc acld

Research

200

>6

II

xx

85%. chlorides. sullates. mtnter.


lron and arsenu

0.0092

O.Olc

c>o.2

C,O.O001

o.ow1

<-0ooOl

co.05
co 2
< 0.0001

0 0006

CO.05
co.2
<WWl
0.0004

0.0032

(continued)

Corrosion Resistant Materials Handbook

550

TABLE 4.13: VARIOUS STAINLESS STEELS AND HIGH NICKEL ALLOYS-CLIMAX

MOLYBDENUM

bntd)

Test
Corrosion mediums

Average corrosion rates (ipy)

s ak

PhDLPhcmC

. .

acK!

WPE

1VPE

316

304
-P-P-

80%

plant phosphoric

acid

Research

200

xx

0 0033

80%

plant phosphonc

acid

Research

200

0 0004

80%

plant phospharlc

acid

Research

240

>6

xx

xx

80%

plant phosphoric

acid

Research

294

>6

xx

xx

Research

167

.,

Research

185
212

Research

75
210

Chemical

122

60

xx

Chemical

153

328

xx

75%

Chemical

158

23

xx

15%

Chemical

158

39

xx

15%

Chemical

158

45

xx

75%

Chemical

159

13

15%

Chemical

171

12

xx

15%

Chemical

175

13

0.0088
wo.0033
10.0106
WLO 0079

75%

Chemical

175

21

xx

0 0026
wo.0023
to 0003
WLO 0004

75%

Chemical

190

12

xx

0.0006
LO.0021

75%

Chemical

199

xx

WO.0083
WLO.0056

75%

Chemical

210

xx

0.0031
LO.0301

80.75%
B&70%,

small amount

of floorme

80.10%

75%

75%

compounds

(top of absorber)

TWE

317

20

O.OJJOla
0 0002a

0.0001

ALLOY
625

<0.004
NC

NG

0.0006

0 0035

0.66

0.112

coJm5
co.02

>6

12

0.0005c
so Oowa

00001
0 096

corr

0.0001

00001

0.0005
w0.0004

0.0003

0 0004

0.0002

0.0003
wo 0005

0 0001

c0.0001
0 0001

IllI

0.0016
wo 0023
LO 0024
WLO 0022
0.0032
10.0005

75%.

pressure

Research

310

75%,

pressure

Research

240.
435

75%

commercial

phosphoric

aud

Chemical

172

<O.ool
w<o.o01

75%

commercial

phosphoric

acid

Chemical

194

0015
wo.0015

0.0034

c0.0002

00013

c0.0003

00188

c0.0074

c>o.2
c>o.2

<O.OOi

<OOOl

<OOOl

0.001
WOOOl

<o

<O.OOl

001

(continued)

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Pholphorl

MOLYBDENUM

(contd)

Average corrosion rates (ipy)

Corrosion mediums

15%

ALLOYS-CLIMAX

551

TWL

TWE

,PE

304

316

311

ALLOY
20

625

aLd

commercial

phosphonc

acid

Chemwal

208

<O.OOl

w>o 001
75%

commerclsl

75%

approximately

phosphoric

70%

acid

Chewcal

221

Chemical

250

Research

255

< 0001

0 0007

30

xx

0.0074

xx

~0001

<o 001

wo001 I

0.0099

0 0009
<0.0001

0.0013
0.0039

co.05
co.2

70%

Research

BP.

12

xx

70%

Research

BP.

xx

15

Research

260

>6

xx

<4.45

65%

Chemical

R.T.

<0.0001

0.00013

<0.0401

65%

Chemical

175

<0.0001

0.00068

<0.0001

66%

Research

175

60%

Research

200

66%

Research

245

60%

Research

245

60%

Research

BP.

70%

plant phosphoric

acid

0.022
0 42
SO.42
0.78
<098

co.005
co.02
0.003
co 05
co.2
co.005
co.02
I

xx

0.012

0.022

60%

plant phosphoric

acid

Research

200

60%

plant phosphoric

acid

Research

200

50%

Research

AT

<0.0001

50%

Research

175

<O.OOOl

66%

Research

240

50%

Research

BP.

66-10%

Research

125.
210

co.005
co.02

504%

Research

75

co.005
co.02

45%

Agrw_dture
(fertilizer)

170

40%

Research

200

xx

0.006

40%

Research

200

0.001

40%

Research

B.P.

Research

200

40%

plant phosphoric

acid

0 003

xx

0.001
<0.0001
0.00041

<O.OooI
0.00044

co.02
co.05

xx

46

0.0071

0.0027ad

xx

0.0031

xx

0.0071

O.OLW

o.ooo7

0.0051
0.0004

(continued)

552

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

bntd)

Average corrosion rates (ipy)

&
i

r*DUs7

(PROCESS1
*

I
.

5
2

$
.

---

ALLOY

lWE

TWE

TWE

304

316

317

20

825

40% plant phosphorrc acid

Research

200

.
-

35%

Research

R.T.

<O.OWl

35%

Research

175

<0.0001

30%

Research

217

30%. pressure

Research

230.
390

30%. pressure

Research

235

co.02
co.05

30%. pressure

Research

280

co.05
co.2

Research

300

Research

B.P.

Metal
kleaning)

190

12

Resaarch

200

xx

o.OW2

...

...

20%

Research

200

0.001

...

...

20%

Research

B.P.

0.0004

...

...

20% plant phosphoric acid

Research

200

xx

o.Wo2

...

...

20% plant phosphoric acid

Research

200

0.002

...

...

10%

Chemical

R.T.

...

...

Research

125.
210

...

...

10%

Research

175

10%

Research

B.P.

3.3%

Research

77

3.3%

Research

77

70

<1%

Research

80.
100

O.Wl
0.0002

nil

95.85%. small amounts of fluorine compounds

Research

212.
239

0.045

0.036

95.85%. small amounts of fluormc compounds

Research

165.
185

0.0028

0.0032

_.

190

0.0041
S>O.O63

0.003
s>o.o99
LO.W41

O.W24

203.
230

Phorphc.rlc

8Cld

w4.

pressure

30x,

pressure

22%. p~~khng solution

20%

10%

PWOSPHcJRICACrD

--

0.002

CSO.008

<o.W01
0.0008

<o.Wo1
o.W4l2

cso.w3

co.2
c>o.2

c >0.2

xx

0.0019

0.001

0.0001

OS001
WOSMOl

0.0004

<0.0001

<O.Wcll

o.Wa13

nil

co.W5
co.02
o.WO12

xx

<o.W04

<o.WO1

o.ow4

...

o.OW12

<o.Wo4

o.Wo2
<O.WOl

...

...

...

...

...

...

...

...

YlX1UlE.s

81%. water 16%. nitrrc acid 3%

80.70%. small amounts 01 fluorine compounds

. Metal

Research

89

0.0096

O.Wll

0.0032
90.027

0.007

(continued)

Ferrous

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

<O.OOOl
so.015
1<0.0001

<0.0001

xx

<0.0001

<O.OOOl

310

58.2%. nowomc detergent 10%. amine-type inhrbilor 230. water. pH 0 2

Soap

72

90

6045%. lluos~l~c~c acid 2.4%.


gypsum holatmg lilter drum)

some suspended

Chemical

176

41%. Phoscalord. vegetable


8.10%

protem material

Waler
Treatment

130

43X, Phoscalold. vegetable material 8.10%

Waler
Treatment

130

43%. Phoscalmd. vegetable material 8.lOb

Water
Treatment

130

2.8

IO%, sulfuric aud 5%. Ac~trol mhlbltor 0 05%.


Lntomerse wettmg agent 0.25% Mop 01 Permubl
P regeneratmg column)

Metal
Icleanmg)

120

40%. sulfuric acid 5%. Acitrol inhibitor 0.05%.


Lntomerse
wetlmg agent 0 25%

Metal
lcleanmgl

33.5-33X.

Chemical

31.41%. calcium sollate hydrate and silica Jo%.


sullurr acid 1.84%. fluosilicic acid 1.48%. hydrafluoric acrd 0.12% Ifilterl
30.75%. water 25%. iodine 3.85%, non-ionic detergent remainder

18%. waler 86.8%.


mdine 1.75%

xx

0.837

0.0018

xx

xx

0.00 I 7

0.0004

xx

0.291

0.001

82

.,o 0001

<O.OOOl

<:o0001

200

62

xx

00001

0.0001

0.0002

170

33

xx

0 006gcd

0.0016

0.0009

Chemical

127

SW

72

90

:
:

Metal
~cleaningl

190.
210

lpickliogl

195

Mdal

:F

I Metal
I (treatingI

i
I

Chemical

xx

<O.OoOl
O.Mml
SO.0388

<O.Llool
LO.mol
1X1.0325

xx

<O.oOOl

<O.oiMl

83

xx

._

<O.owl

<O.OOOl
m).lnXll

81

<0.0001

<O.OoOl

80

--

<0.0001

<O.oaol

<O.wOl

<O.ooLIl

8.4

73

90

--

230

81

O.OOLl4

15.2%. water 85%. organics remainder

Chemrcal

200

14.5%. nrlrlc acid 0.381%. pH 0.62

Agriculture
Uertilizerl

158

32

10%. waler. mesityl oxide

Rayon

218

149

10%. water. mesltyl oxide, diacetone alcohol

Rayon

221

10%. water, mesrtyl oxide, dracelone alcohol

Rayon

10%. water. mes~lyl oxrde. dracetone alcohol

Rayon

20

0.0002

0.0004

nowionic detergent 15.75%. i Soap

18.10X, 4hydroxy 3.methyl 2Manone 15%. poly


mer 5%. methyl.isopropyl ketone 3%. formaldehyde 1%. water remainder

0.0001

Ruosrltc~c acid 3-3 5% (thIckenerI

SOlutiOn

TV,e

317

75

No. 171

1YPE

316

18%. Deoxidrin

YWf

304

.
Chemical

22%. pickling solution

MOLYBDENUM

553

kmtd)

Average corrosion rates (ipy)

70%, electrwfurnace technical grade

22%. and Luck wash and regeneration with sulfuric


acid 30% (Permutit unit)

ALLOYS-CLIMAX

Alloys

<0.0001

0.0004

<O.OtMl

<O.oool

0.00013

0.0001

<o.wo1

0.001

0.0005

o.OOa9

0.0001

0.0001

0.0001

149

218

181

xx

0.00022

o.lm43

216

149

0.003

o.ooo7

.. .

0.0225

0.0001

<0.0001

0.0002

o.ooo12

0.0001

<O.OLKll

0.0002

0.0001

xx

ALLOY
825

o.olw
c0.0001

<O.OcQl

0.0012
0.mO1

0.012d

(continued)

554

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

NICKEL

ALLOYS-CLIMAX

0
.

TVPE

TVPE

,VPE

304

316

317

90

4.2%. sollds 15%. gypsum slurry, sulfuric acid 1%.


soluble fluorme compounds 0 2%. pH 1.9 (pump box)

Chemical

90

3.86%.
fluosdw
water, ptl

Chemical

123.
168

65

0.003cd

Chemical

133

13

0.0004

0.0002
w0.0001

Research

363

0 0009

0.0003

Metal
[treating)

165

Research

150

Research

80.
100

>6

Chemrcal

RT600

14

vapors contammg
phosphorus pentwde
0 07% approxrmatety.
oxygen 7.15%.
fluorine 264 ppm ap
proxlmatety

Research

129.
237

2.1%

Research

78

phosphorus

Research

149.
158

phosphorus

Chemrcal

140

185

phosphorus.
water,
hydrogen,
phosphine.
hydra
carbon, traces of carbon dioxide and carbon mok
oxtde. pH 3.6 (vapors. hquid)

Chemical
fdistillationi

176

112

buffered phossy water or tap water, small partrcles of phosphorus. adjusted with soda ash to pH 9

Chemical

140

185

<O.ooal

gas stream of phosphorus condenser.


carbon monoxide 90%, nitrogen 8%. carbon dioxide 2%. small
amounts
phosphoric
acid.
phasphine.
hydrogen
sulfide and fluosilicrc acid

Chemical

150.
175

56

0.021

0.0023

phosphorus oxychloride
and triethyl
form tetraethyl
pyrophosphate
and

Chemical

300

0.0085
0.0085

0.0081

Pharmb

54

4.6

O.OOOSad

0.0003d

acid

0 15%.

fluorine

0.38%,

2.9%.

water

contammg

1%.

sugar 5%.

a sludge

pressure

1% approximately.
oxrdrzmg agent

160 PSI

Cranodme.

~1%.

small amount

<I%.

acrd from

small

of phosphorous

weak

acrd

sump.

amount

of

acrd

pH

1 approxr-

mately

II 5%.

phosphorlc.acrd.type

catalyst,

organics

approximately

(cmtd)

Average corrosion rates (ipy)

0
f

I2

MOLYBDENUM

60

70

ALLOY
825

c<0.0001

<0.0001

,0.0001

20

0.002cd

<0.0001

0.002
0 003

00031

0 00015

nil

0017

0.02
0.018

0 032

0.19

0.0037

0.006

0.046

<0.0001

PHOSPHORUS

phosphate
to
ethyl-chloride

0.0001

co

0001

0.0031

0.0001

<0.0001
o.w29

0.0025

CO.cQ28

0.0024

<O.oool

gas

PHOSPHOTUNCSTIC

phosphotungstrc

ACID

acrd and hydrochloric

acid, pH 1.5

ceutical

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Corrosion mediums

ALLOYS-CLIMAX

phosphotungstrc
acrd and phosphomolybdic
used rn precrprtatron
of basic dyes

acid

Prgment

55
205

60

phosphotungstrc
acrd. slurrred
wrth water, and adlusted wrth hot barrum hydroxrde
to pH 8-12

Pharma.

77

fdm sensrtwng
acrds. solvents,
10%. pH I

dope,
alcohol

vapor,

phthalrc acid.
water 98%

xylene.

99%,

and malerc

benzorc

crude phthalrc
acrd and water

phthalrc

crude

water

propylene

inorganic
together

vapor

tolurc

acrds

and malerc

acid <O.Z%.

impurities

acids

Ivaporsl

Impurities

of malerc

Ivapors)

(vapors)

methyl

lrqurd phthalrc anyhdrrde,


amounts
of materc acrd.
acid. naphtha qumones

saturated
ammonra.

TYPE

NPE

304

316

0 OOOlad

<0.0001

0.0002

<o 0001

ceutrcal

ALLOY

TIPS

---

317

20

825

Photo-

37

0.0001

0.162a

0.0021d

0001

graphtc

phthalrde.

anhydrrde

phthalrc
anhydrrde,
ethyl phthalate

75%. potassrum
1 5%. bromme,

and

anhydrrde.
small amounts
ftop of column, vapors)

anyhdrrde

phthalic

ethylene

solutron,
organic
and
salts and dye components

7% phthahc-acrd

9695%.

(contd)

sOLTtONS

photographrc
fdm
chlorrdes
acetone,

benzorc

MOLYBDENUM

Average corrosion rates (ipy)

--

PHOTOGRAPHK

555

Alloys

Cellosolve.

drmethoxy

phthalrc acrd. water, small


malerc anhydrrde,
benroic

bromate 25%.
uon trace

potassrum.bromrde
pH 8-9 5 ffrlterl

Chemical

85

16

Chemrcal

356

40

Rayon

200

44

Chemical

536

25

Chemrcal

536

25

Chemrcal
tdrstillatronj

410

45

Chemical

435.
555

85

Coal Byproduct

320
545

59

Chemrcal

284

221

Chemrcal
fdistrllationl

329
518

70

potassrum

hydroxrde

Chemrcal

65

solutron,

dissolved

Chemical

185

20

Petroleum

240

74

17%. potassium
brcarbonate
13%. chromate
ion
2000 ppm. pressure 270 psrg (top of carbon-dioxrde
absorber)

xx

0.2843
SO.1523

nil
s0.0004

xx

0.0005

0.0009

xx

0.0001

xx

xx

0.0001

0.0002

0.0001

0.0002

0.0002

0.0002

0 0002

0.0002

0.0393

0.0007

0 0001

0 0092a

0.0006

xx

0.0002

0.0002

0 0001

0 0001

0.0085

0.0054

0.0032

0.0028

0 25

0 002d

3.4

0 0007
c0.0001

0001

>0.25

<o

0.034cd

0001

00014

0.008a

0.0057a

xx

<0.0001

<O.OOOl

xx

<O.OOol

<0.0001

0.0078b

<o

<0.0001

<0.0001

(continued)

556

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

Polasswm

WPE

TYPE

304

316

b
.

-,.

s
.

z
.

km4

----

WPE

311

20

ALLOY
825

0 0001

0.0001

carbonate

16%.
potaswm
blcarbanate
14%.
chromate
ion
2000 ppm, pressure 8 pug (bottom 01 carbon-dioxide
strIpper)

Petroleum

240

74

xx

<0.0001

<O.ODDl

10%.

Chemical

230

120

xx

<O.OOOl

<o 0001

221

120

xx

<0.0001

<O.ODDl

potassium
bicarbonate
vessel leedmg
to absorber1

ppm(storage

14%.
chromate
10
potassum
hydroxide

5%. potaswm
bkwbonate
21%. stripped carbondloxlde gas. water remamder
tventmg ott stripper)

Chemical

4%.
potasswm
bicarbonate
28%.
chromate
ion
2000 ppm, pressure 6 ps!g (top of carbon-dioxide
stripper)

Petroleum

240

74

~30%.
400-600
chloride
OH 5 3-8

Chemical

122

132

31.5%,
sodwm
sulfate
0.5%.
sodum
chloride
0 05%.
lead, copper, starch trace, pH 9-10 IDorr
clardlocculator.
overllow weir)

Chemical

180

65

0.0002c

0.0002

20%.
saturated
solution, potassium
hydroxide 2-l
g/l. potassium sulfate 2-3 g/l. potassium carbonate
1 g/l.
calcium
3 5 ppm, specific
grawty
1.18,
pti 135

Chemncal

150

215

<O.OOOlad

<O.OOOla

25%.

Chemical

70

64

xx

0.0002b

<O.ODDI

Chemical

122

29

xx

xx

0.0003d

<O.OOOld

Chemical

50.
122

46

--

0.057c

<O.ODOl

Metal

190.
212

potaswm-chlorate
slurry. sodwm chlorate
gl. potawum
chlor@e 20.500 g/l. sodurn
30-250 g/l. sodwm bichromate
Z-14 g/l.
7

POTASS,M

copper

POTASSWY

trace

CROYlC

45% potasuum-chrome-alum
acid 5% approximately

5 8.6

POTASSWY

xx

0.0001

0.0001

O.OOOla

CHLORIDE

25% approximately,
potaswm
ion 13.95%.
chloride ion 13.49%,
sodium ion 0.59X,
sulfate ion
0.5%. ferric oxide 0.29%,
calcwm ion 0.07%.
copper powder trace, amine acetate 210 ppm

9%. ptt

MOLYBDENUM

Average corrosion rates (ipy)

IHDUSTRV
(PROCESS)

ALLOYS-CLIMAX

C<O.OOOl

SULFATE

solution.

free

sulfwc

<0

OOOld

<O.DOOl

C<O.DOOl

<O.ODDl
c<o.Ow

OROXIDE

92.90%

Chemical

716

xx

0.35

0.25

co.092

80%

approximately

Chemical

B.P.

0.1

0.008

0.02

50%

approximately

Chemical

BP.

XX

0.13

0.12

015

(contikd)

557

Ferrous Alloys

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

Average corrosion

B
.

hydroxide

50%

<o 0001

F < 200

hy

Chemical

248

60

25.2%.
potassum
Isobulyrate
37 8%. potassium
sulbde
5 5%. potaswm
carbonate
Z.l%,
potassun mercaptldes
I 9% treboder)

Petroleum

282.
290

140

20%.
dww

Isopropanol

sotutlon

of hexachlorocyclopenta-

Chemical

176

146

xx

20%.
dlene

rsopropanol

solutlon

of hexachlorocyclopenta-

Chemical

176

90

20%. ~sopropanol
fvaporsl

solutmn

of hexachloropentadlene

Chemical

202

18

20%.

solutmn

of hexachloropentadlene

Chemwal

202

19

k troleum

360.
380

Chemical

122

Rubber

100

Synthetic
Rubber

R.T.

5%

Rubber

76

25

xx

5%

Synthetic
Rubber

:L

85.
100

Synthetic
Rubber

.f

90

13

--

sodwm
hydroxide
3% approumately

~sopropanol

21 6%. ammonwm
levaporator)

11.2%. alkyl phenolate


28X.
potasswm
19%, sulfide
08%.
mercaptans
04%
solut~zer
regenerator
tower)

POTASSIUY

lsobutyrate
(bottom
of

TlPE

316
----

TWE

317

20

ALLOY
625

xx

xx

0 0228
0.0222

<0.0001
0.0295
0.0292

COW
COW*

0.0002a

0 0001

00001

0 0004a

00003a

xx

0 0009a

0 0007a

276

xx

0 0023ad
0 0024ad

0.004lad

132

xx

xx

~~

xx

0002

PERCHLORATE

<30%.
potasstum-perchlorate
slurry.
sodium
perchlorate
600-900
g/l.
potasswm
chloride
O-500
g/t, sodum
chtorlde
O-250 g/l,
sodurn
chlorate
6-24 g!I. sodium dtchromate
2-8 g/l, pfi 8 7 5 3

POTASSWkl

30

--

Chemical

0.0001

0.0001

0 0001

PERSULFATE

8 7%
illally,

approximately
2 l-2 3 fmally

5.1%.

pH 3

4.8%,

TYPE

304

hydrorlde

sodum

32.4%,
droxlde

(contd)

rates (ipy)

2
.
50%.

MOLYBDENUM

g
g

po,ar,wm

ALLOYS-CLIMAX

saturated

salutlon,

ptl

I 9 I-

pH 3

00015

0.00035

ml

0.0001

<0.0001

<0.0001

nil
nil*

<0.0001

WI
ml*

<0.0001

<0.0001

<0.0001

<o 0001

4%

Synthetic
Rubber

R.T.

42

4%

Chemical

80

61

Soap

RT.

365

0.0001

Petroleum

110

262

xx

0.0001

PROPANE

propane.

fatty

acids

propane.

free sulfur

dionde,

sulfurous

acid (vapors)

0.0001

o.ooo1

(continued)

Corrosion Resistant Materials Handbook

558

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

kontd)

Average corrosion rates (ipy)

Corrosion mediums

z
g?

f
2

TPL

P
.

304

WPL

316
----

ALLOY

TIPS

317

20

a25

PROPlOLACTONE

100%

~propmlactone

176

200

xx

L0.0003

0.0001
L0.0001

L.0002

0.0001
L0.0002

85% fl.propmlactone,
acetic anhydrlde
13%, dloxymethylene
dlacetate
2 3%. aluminum
chloride
and
zmc chloride
together
0 2%. formaldehyde
trace

Rayon

95

200

100%

Rayon

293

200

xx

0.038

120

250

0.0005

99.5%,
butyrlc
acld 0.3%.
mg 219 days; and proplow
99 5% durmg 31 days

acetlc acid 0.2%


acid 0.5%. butyrtc

duracid

Chemical

sullurlc

acid

1%

Chemical

280

10

QQ%, sulfwc

actd

1%

Chemical

282

QQ%, sulfuric
acid 1%. butyric acid 0.5%, decomposdion
products
0.5%. durmg 12 days; and diverstfled operation
durmg 613 days

Chemical

302

96.2%. acetlc acid 3.4%, water


2500 ppm. copper eon 5-30 ppm

Chemical

291

50

96.2%.
water 0.1%. manganous
acetate
10 lb124
hours, iron ton 35-2500 ppm. copper ion 5-30 ppm

Chemical

291

34

95%. acetlc actd


p~onnc acld durmg

Rayon

292

246

Chemleal

284.
329

125

xx

decom-

Chemical

302

12

155 days,
acid 1%

Chemical

233.
284

193

Chemlcat

288

47

99%.

95%.

butyrlc

acid

5% during
46 days
2%.

94%. sullurlc
acid 5%.
posItIon products 0.5%
93%, acetlc acid 5%.
and acetlc acid 97%.
durmg 38 days
89-86.5. acetlc
and won loos

acid

esters
water

iron

200 days;

remamder

butyric

O.l%,

ion 35.

100%

pro-

unknown

acid

0.5%.

2% during
2%. formic

11.14%, water, traces of copper

0.012
<0.0001

<0.0001

0.02

0.0043

0.005

12

0.073a

0.011

0.014

625

0.0078c

0.0013

0.0004

0.0034

0.0016

0.001 lar

O.OOiX

0.0014

00003

0.047

0.0024

0.0012

0.0007

0.00027

0.00019

xx

0.006

0.0007

<0.0001

xx

0.01
0.003

0.006
0.0001

IllI

0 0086b

0.0013

O.OM)8

0.045

0.003

0.0035

xx

86%. domestlc
water lo%, butyrvz acid 3%. higher
esters
1% durmg 213 days; proplow
acid 75%,
butyrlc
acid 15%. acetlc acid 5%. higher esters
5% durmg
127 days, and propnow
aud 85%.
acetlc actd 6%. hlgher esters 6% dung
85 days

Chemlcat

212.
340

63%.

Chemical

280

during 7.4
12%, sulacid BO%,
3.2 days

Chemical

252.
286

0.16

0.011

0.0047

60%. butyric
acid 10%. sulfuric
acid 10% during
7.4 davs. butwc
aud 80%. oromomc
acid 10%.
sulluriE
acid iO% durmg
7.4da;s;
and proplonic
actd 70%. acetlc acid lo%,
nltnc acid 10%. onknown 10% dung
3.2 days

Chemical

: F

228.
275

0.16

0.021

0.0045

butyvc

acid

12%,

sulfwc

acid

5%

63%, butyrlc acid 12%. sulfuric


acid 5%
days, butyrlc
acid 63%. proplonic
acid
furlc acid 5% durmg 7.4 days; proplonic
acetlc acid 10%. nitric acid 10% during

425

co.003

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test

ALLOYS-CLIMAX

Alloys

MOLYBDENUM

559

(amtd)

Average corrosion rates (ipy)

Corrosion mediums

.?z.
;
TIP6

TYPE

316

317

0.12

0.012

0.005

0.025r

0 005r

0.004

TIPE

ia

304
-----

80%. sulfurrc
acrd 10%. decomposrtmn
products
10% durmg
7 4 days; butyrrc acrd 80%, sulfurrc
acrd 10%. decomposrtron
products
10% durrng 7.4
days, and propronrc
acrd 80%. sulfurrc
acrd 10%.
nitric acrd 5%, unknown 5% durmg 3 2 days

Chemrcal

310.
320

15%. proprow
anhydrrde
13%. acetrc acrd 12%.
and propronrc anhydrtde
98%. acetrc anhydrrde
and
rmpurrtres
together
2%

Chemrcal

275.
338

36

70%. glycol
acrd 1.5%

Chemical

314

566

0.017

0.0046a

0 003

Chemical

300

21

xx

0.012

0007

0.005

311

466

xx

0 027~

0 0061b

0 0039

esters

66%.
rsobutyrrc
small
amounts
400 mgi

16 5%. butyrrc

acid

12%. acetrc

acrd 17%. n.butyrrc


acrd
of acetrc
acrd. norvvolatrle

17%,
300.

20

ALLOY
625

0.0035

65.60%.
unknown

butyrrc
acrd
remamder

4.7%.

Chemrcal

50%. acetrc acrd 50%. propronrc acrd 54%. acetrc


acrd 2596, water 20%. unknown
1%. and proprow
acrd 97% acetic acrd 3%

Chemrcal

212.
284

125

xx

0018a

0.0025

0 0009

50%. butyrrc acrd 45%. heavy esters 5%


155 days, and acetrc acid 96%. non-volatrles
proplonrc acrd I%, water 1% durmg 38 days

dung
2%.

Chemrcal

251

193

xx

0 002

0 0007

0 0004

nitric

acid

Chemrcal

176.
284

250

xx

0.006

0.001

water

6%.

Chemical

199

25

xx

0.15

0.01

0 003

Chemical

324

167

0.0041
0.006r

0.002r

0.001

99.8%

Chemrcal

347

50

0.002

0.0003

0.0002

99.8%

Chemical

347

93

0.003

0.0007

0.006

25% rsopropanol.
water 57%, sodrum chloride
la%,
rsopropyl chlorrde bubbled through solution,
sodium
hydroxrde
adlurted
pH 10

Research

140

spent rsopropanol.
sugar solids
of sulfur droxide.
hydrochloric
phosphate,
pH 3.45

Food

100

Research

97

Chemical

260.
270

48%, butyrrc acrd l3%,


2%. other hrgher acrds
9%, ethyl acetate
acetrc acrd ~1%

PROPlONlC

99.9%,

50%

63%.

10-1296,

acetrc

acetrc acrd 8%.


remainder
benzene

21%,

acrd

lNYDR,DE

impurrtres

rsopropyl

chlorrde.

water

3%. small amounts


acid, sodrum tetra-

50%

(vapors)

42

37

4.2

51

xx

nil

nil

0.0001

0 0001

nil

II

0.0004

<0.0001

(continued)

560

Corrosion Resistant Materials Handbook

TABLE

VARIOUS

4.13:

STAINLESS

STEELS

AND

HIGH NICKEL

Corrosion mediums

6560%,
hydroxrde
66%.

glycol

drpropylene
and sodum

water

15%.

8%.

water

l%,

glycol
15%, salts
lormate
0.1%

unidentihed

orgamcs

sodwm

drpropylene
resms 5%

glycol

80%,

sohds

90.65%.
sodrum
methyl aldehyde
20-15%.
water
traces of lormrc

75.80%.
propylene
glycol
acrd and carbon droxrde

0.1%.
water

formtc
acid 1%. propylene
remamder.
sodrum hydroxrde

prune

processmg

water,

0.0001

xx

Chemrcal

360

123

xx

<0.0001

Chemical

194.
196

48

xx

0 0002

aide-

Chemical

300

51

xx

<o

0001

<0.0001

for-

Chemrcal

360

51

xx

<o

0001

<0.0001

of pro-

Chemical

275

xx

and

Chemical

llc140

51

<0.0001

<0.0001

Chemrcal

360

51

xx

<0.0001

<0.0001

Rayon

218

462

0.0001

Food

210

60

0 0001

0.0001

Plastrc

200

61

xx

<o

0001

<o 0001

<0.0001

O.lO%,

glycol
added

0 0001

461

remamder

methanol

--

7PL

317

385

as sodium

hydroxide
3.6%.
together
3.5%

*FL

316

as sodrum

propylene
glycol. formic acid, formrc esters
pylene glycol, traces of acetals and water

TWE

304

Rayon

30.20%.
water 60.70%.
methanol
and methyl
hyde 3%. formrc acrd O-I%. pH 3-3 5
15%,
mate.

MOLYBDENUM

kontd)

Average corrosion rates (ipy)

.
SO%, drpropylene
hydroxrde
0 04%

ALLOYS-CLIMAX

0.2%.

pH 3.8

3.5

0.023

---

20

ALLOY
825

<0.0001

0.0001

0.02

<0.0001

PlRlDlNE
56%.
Water
50%.
traces
of
methylene
chlorrde
and acetone
6%. sodum
water

chlorrdc

remamder

pyrrdme.
water,
tom of reboder)

pyrrdme

bases

4.5%.

(top

methyfene

acid,

(distdlatmn)
2%,

Plastlc
ldrstillatron)

100

52

xx

Lbot-

Plastic
(distillation)

230

56

xx

011 (VaporS.

Coal By
product
tdistdlationl

176.
212

chloride

of column)

acetone,

from

hydrochloric
(vapors)

tar

methylene

and

chloride

carbohc

liquid1

pyrrdme
densate
rectrfred
fate
unwashed
acrd 15%

sullate.
unrectified
hquor. sulfuric
acid,
pyrrdme

sulfate.

pyrrdme sulfate.
Icondensate)

pyridine
water

unrectified

carbohc

0.0001

0.025
0 079
10.024
10.072

0.0001

<0.0001
<0.0001

<0.0001

<0.0001

<0.0001

0.008

0.05

0.037

sulfate.

con-

Coal By
product

123

197

pyridine

sol-

Coal By
product

215

197

xx

xx

0.017c

0.014cd

Coal By
product

123

197

xx

0.0007cd

0.0003

oil and Sulfuric

<0.0001

II

0.0003

(continued)

Ferrous

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

pyrollgneous

bntd)

TPE

TIPE

304

316

<O.OOOlad

<O.OOOla

ALLOY

TWE

---

317

20

825

ACID

hquor

vapors.

pressure

125 PSI

53

xx

Chemical
fdlstillation)

27

14

acid,

12%
approximately
acid 2%. pressure

Ilquor.

sulfuric

Chemical

pyrol~gneous
30 psi

methanol,

Turpentine
ldlstillatmnl

wood-dMillatton
products,
acetic
lormlc acid etc. pressure 100 psi

275

0.00107

0.00029

0.00071

0.00063

pyrohgneous
hquor.
sulfwc
mately,
pressure
100 PSI

acid

10%

approxi-

Chemical

<335

xx

0.0098

0 00558

pyrohgneous
hquor,
sulfuric
mately, pressure
100 psi

acid

10%

approxi-

Chemical

F <335

18

xx

0.045

0.0304

orgamc vaternary
ammomum
nol solutlon.
possibly
product
carboxyhc
acid. pH 2.3

compound
in methaof lsonicotmate
and

Chemical

42

xx

0.012

0.005

condensate
formed when mwng
or bisulflting
quebracho extract
wth so&urn
blsulflte
3%; reaction
frees sulfur dloxlde and forms sulfurous
acid with
water vapors

Tannmg

<0.0001

<0.0001

coal
dme

Chemxat

110

Chemical

105.
122

15.6

rare-earth
sulfate soluhon,
sulfuric acid, phosphoric
acid. acldlty 0 9-l 1N. speclflc grawty
1.14-1.15

Chemical

A.T.

69

rare-earth
sulfate crystals,
sulfwc
acid 25%, phosphorlc acid 17%. conslderable
copper m solution

Chemlcat

50.
70

rare earths
0 8N. slurry

QUEBRACHO

195

0.0015

EXTRICT

tar base of qumolme


impurltles,

RARE-EARTH

MOLYBDENUM

561

Average corrosion rates (ipy)

-PYROLlONEOS

Alloys

type,

carbon

and dmcra-

JO-

50

206

185

0.0001

pH 8-9

0.0001

CHLORIOE

rare-earth.chlorlde
sand. tare earth
0.04-O 2N

solubon,
and thorturn.

residue
composed
of
free hydrochloric
acid

xx

0.046cd
0.087cd

xx

<O.OOOld

<O.OOOld

xx

0.0002
0.0004

0.0004

2.5

xx

0.29.d
0.19cd

0.31d

C0.2d

xx

0.012
0.008

0012

CO.008

xx

<o 0001

0.0001

coooo3

xx

IllI*
0.0004

0 0002

co.0003

CIIIC. cerlum,
and sulfuric
conlammg
sand and barium

acids
sulfate

05

Chemical

159

rare earths, cer~c, cewm


and sulfuric
0 EN. slurry contammg
sand and bawm

actds
sulfate

0 5

Chenucal

159

65

18.2096,

Chemical

55

23

salts,
sodwm
sulfate,
acids, acldlty
1 4.2N

Chemical

113

rare karth

sulfate

phosphoric

acid

slurry.

rare earth
phosphoric

double.sulfate
and sulfuric

sulfuric

acid

C0.03cd

c<0.0001

0.0004

16-1796

75

(continued)

562

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

15 5% coagulatmg
bath, sodwm
other ,norgalc
salts l-5%

sullut~c
acid 13%. rayon nwed
fate 249,
zinc sulfate
hydrogen sulfide, water remamder

acid.

sullur~
lwors

NICKEL

sol-

RayOIl

112

149

0 0122c

0 0106

Rayon

132.
138

60

xx

dwlbde

Rayon

200

39

xx

Rayon

120

425

bath

evaporator

TWE

317

0 016cd

dramage

hardemng

TIPE

316

0 056~
0 037c

acid 0.002 0 005%


staple
hber
sodium sullate
0 006-O 015%

lrom

,PE

30

vapors

MOLYBDENUM

304

112.
130

Rapll

vapors.
water 93%. carbon
hydrogen
sulbde 0 2%

ALLOYS-CLIMAX

aud 0 001 IO,.


dilute
coagulating
bath,
dlsulflde
and hydrogen sulfide O-500 porn

sullunc-acid
5.. a#r 2%

acid

HIGH

hntd)

Average corrosion rates (ipy)

sodlum
solamount
of

1536,small

sulfuric
carbon

AND

Test
conditions

Corrosion mediums

sulfurs
acld
late 15 259,.

STEELS

30

0.027
0.004
0.041
0 02
0017
r00001

0.0001
0 009
<O.OOOld

~0

<O

OOOlad

20

ALLOY
825

00111

0001

<O.OOOl

0 0012cd

0 00014

<0.0001

0 0029c

0 004c

0 0033c

rayon swng
penetrants,

bath, gelatme.
glycerme

vegetable

oil, softeners,

Rayon

155.
160

68

rayon swng
penetrants.

bath, gelatme,
glycerine

vegetable

011. softeners,

Rayon

160

208

RaytIll

170

78

38

wscose

rayon

spm bath

(evaporator)

rayon

bath,

III

<,0.0001*ad
<O.OOOlcd

<O.OOOl

<O.OOOld
<O.OOOlad

<0.0001

xx

xx

xx

xx

0.084
o.oOO2c
0.0001

0.0011c

0.0107cd
0 059cd

0.0061ad

0 013lc
0.0001

0 0001
0.02

sulfurs
acid
fate 10.12%

IO-12%.

sodwm

sul-

sulfurs
aud
fate 20.22%.

10.12%.
rayon spin bath, sodium
some zmc sulfate. *orne organics

soI.

Rayon

F <I20

30

sulfate
20 ppm

Rapll

119

60

Rayon

78

26

sulfuric
acid 8%. rayon spw bath, water
71%,
sodwm sulfate
14%. glucose 6X, zmc sulfate
l%,
traces 01 hydrogen sulbde and carbon dwlflde

Rayon

105

35

xx

OOIlcd

0 009d

sulfuric
acid 7-896. rayon spm bath, sodwm
13.15%.
some zmc sullate and orgamcs

sulfate

Rayon

F <II2

30

0 0062cd
0 0062cd

0.0035ad

sullur~c
acid 7 25%.
backchannel
sulfate 18.19%. nnc sulfate 0 75%,
1 22 at 30 C

hquor,
spec~bc

sodwm
gravity

Rayon

104.
II3

60

0 0076cd

0.0005

stretch

water

Rayon

167.
194

20

0.05cd

I I%, rayon

spin

sulfuric
acid
20 5% zinc sulfate
approximately

0.8%.

spm bath,
hydrogen

sulfuric

rayon

spm

ac!d 8 1%.

sulfuric
acid 1.3% apprwmately.
from rayon spmnmg
machine

sodium
sulfide

bath

0.00035a

<o

0.027

0.03

0.0061ad

co 0002c
c0.0002

0001

0.0035d

<0.0001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

304
-----

TWL

TWL

316

317

20

0.0054
<0.0001

0.0028
0.0191

sullwc
sulfate

actd 0 25%,
0 25%

spent

rayon

spin bath,

sodium

Rayon

180

102

xx

xx

. ..d

sullur~c
sulfate

acld 0 25%.

spent

rayon

spin bath,

sodium

Rayon

200

111

xx

xx

0.0001
0.0001

0.0001

Rayon

119

40

X -

0.0238cd
0 0320bd

0.0168
0.0025
0.0195
0 0026
0.0176
0.0023

Rayon

105

78

xx

0.0201

0.00025a

spm-

Rayon

117

40

0.03636

0 0136a

carbon

Rayon

R.T.

30

spin-bath

rayon

spmbath

drlppings

drlppmgs

spmbath
atmosphere,
bath dnppmgs

lumes from rayon


dlsulbde.
hydrogen

acid bath
fide

rayon

aud

fumes.

spm

lumes

hydrogen

spm bath,
sulfide

carbon

bath

sulfide.

sulfuric

dwlbde

and

acid,

and hydrogen

fumes

and water

vapor

from

rayon

spin bath

exhaust gases above spmnmg


hquors, free
and other gases from sodium-hypochlorde
mg, sulfur, other vapors

atmosphere,
stack

sol-

on roof

m wc~n~ty

of rayon

chlorme
bleach-

bath

fume

563

(contd)

Average corrosion rates (ipy)

TIPE

rayon

Alloys

xx

<O.OOOld

O.OOla
O.OOSc
0.005b

0.001
0 0014

xx

0.005
0.005

0.0006

0.0001c
0.0001

0.0001

Rayon

R.T.

30

Rayon

160

111

xx. xx

Raven

176.
195

20

x.x xx

Rayon

a4

60

I)

xx

Rayon

57

30

xx

<0.0001

<o 0001

Atomic
Energy

85

130

<o

0001

<0.0001

Atomic
fnergy

85

125

<o

0001

<o 0001

Atomic
Energy

85

125

<o

0001

<o 0001

Plastic

212

Synthetic
Resm

75

42

<0.0001
w<0.0001

Plastic

77

31

<0.0001

Synthetic

158.
180

179

185

23

<0.0001

ALLOY
625

co0001
c0.0003

<0.0001

0 035c
0 042~

O.Ollb

0.01

RESIN

Dowex

50

resm

saturated

wth

mtrlc

acid

Dowex

50

resw,

saturated

wth

oxalic

actd 5%

Oowex

50

resm

m dtstdled

water,

65% approximately
urea formaldehyde
formic acid, pti 4 5-5 2 (vapors)
urea-lormaldehyde
and
product. sohds 62%
urea-lormaldehyde
31% synthetic
dehyde 7 5%
23 5%
calcium
sodurn

zinc-chloride

6M

slurry

rests.

free

condensation

resm
resm
sulfuric

acetlc
aud 41 5%. formalacid 296, water remamder

wnyl-resin
sollds suspended
by agltatlon
m
chloride 0 33,
sodum Ih~osullateO
052%
hydroxide
0 026% solution

Resin
Plastic

I: xx

58

<O.OOOld
0 OOOld

<0.0001

0 00012

<o 0001

<0.0001

0.0001ld

0 00016d
wo 00011

0 0003cd

<0

0001

<0.0001
(continued)

Corrosion Resistant Materials Handbook

564
TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

Palot and
Varmsh

fumes
from
synthetwesm
varntsh manufacture.
phthahc anhydnde.
glycerine.
vegetable
011s and
sodurn hydrorlde
10% cleanmg
solutton

Pamt and
Varntsh

formaldehyde

loo.
500

40

1 oo500

40

Chemical

220

130

Plastic

40.
160

45

vapors from a phenol-formaldehyde


resm reaction
kettle.
contammg
phenol
6000 lb, formaldehyde
3000 lb, and sullur~c acid 95% 120 lb

Synthetic
Resin

212

phenol-formaldehyde
6000 lb, formaldehyde
acid 95% 120 lb

resm
obtamed
from phenol
37% 3000 lb, and sulfuric

Synthetic
Resin

phenol-formaldehyde
6000 lb, formaldehyde
95% 120 lb Ivapors)

renm
obtained
from phenol
37% 3000 lb, sulfwc
acid

Synthetic
Resin

Chemical

ohenola-resm
001%.
nltrate
ppm. no sulllte.

water

98%.

methyl

alcohol

slurry,
Mate
0 19%.
chlottne
and nltnte
12 5 ppm. mtrates
3
pH 3 5.7

rosm. orgamc
aclds. phenols.
aldehydes,
non.aqueous
resm media (autoclave)
60%
pdch

row
20%

acids.
(bottom

tall 011. prmclpally


outlet)

olewlmolelc
of tower\

tall-oil

acids

various

tall-oil

rosm

labove

Research

reboder

TIM

TIPE

316

317

0.0002

O.WOl

<0.0001

(contd)

0.0013

<o

0.0005

0001

<O.OoOl

63

0.0006bd

<O.OOOl

212

51

0.055lad
0.0845a

0.0535ad

212

51

0.0063a

0.0039ad

525

610

<o.c301

509

54

527

69

0.185

ALLOY
825

20

<0.0001

1<0.0001
L 0.0002
O.OOOla

0.0002

(fractlonation)

and slightly

rubber rec!almmg. alkalme, neutral and slightly


condltlons IdIgester, vapors, hquld)
latex

TIPE
304

0.0003

20%.

MOLYBDENUM

0.0006

c<0.0001

<0.0001
0002

ml

<o

0001

c<0.0001
co.0002
c ml

ifractlonation)

robber reclalmmg.
alkalme, neutral
condltlons
(digester,
vapors. Ilqwdl

I%?18

2%

ALLOYS-CLIMAX

Average corrosion rates (ipy)

synthetlc.rerm
varmsh base. phthahc anhydrldc and
glycerme. vegetable 011s and sodium hydronde
10%
cleanmg solutlon

resm.

NICKEL

COagU~atlOn, calcium chloride


1%.
days, and acetlc acid. pH 3 durmg

acid

Rubber

387

IO

0.0003
0.0002

0.0004
0.0002

acid

Robber

387

13

ml
0.0003

rlll
0.0001

200

107

200

53

90

12

pH 9 dur. synthetic
89 days

0 OOOld

nil d

Rubber

latex, calwm
chloride
2%. pH 9 durmg
and acetlc acid 1%. pH 3 durmg 19 days

34 days;

Synthetic
Rubber

mother
liquor from Oluer biters. sodwm
3%
approximately,
sullurlc
acid 0.1%
mately.
small amounts
of hydroquinom

chloride
approxiand car-

Synthetic

.F

Rubber

<O.OOOld

nd
nit*

nil d

<0.0001

bonates
treated
water used in Bona s synthetic-rubber
production, small amounts of styrene, pH 7.10

Synthetic
Robber

75

35

<0.0001

<0.0001

treated water for making up synthetic-rubber


emulwoo. hardness 0. turbidity 3, pti 6-8 (tank bottom)

Synthetic

135

26

<O.wol

<O.ooal

Rubber

0.0001

0 0002

0.0002

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosron mediums

ALLOYS-CLIMAX

A l/o ys

MOLYBDENUM

565

bntd)

Average corrosion rates (ipy)

TIPE

::
.

::
.

364
-----

TIPE

TWE

316

317

20

ALLOY
625

Rubber

synthetrc-rubber
crumb, water
30%,
salt 0.5%,
traces of coagulatron
hquor chemrcals.
combined
sodrum sulhde. blended trrphenyl phosphite ldrrerf

Synthetic
Rubber

180

15

xx

x*

<0.0001

<0.0001

actrvator
solutron used m cold rubber production,
glucose 18.4%.
sodwm pyrophosphate
4.4%,
fer
rous sulfate 0 7%

Rubber

80.
212

xl

I:

<0.0001

<0.0001

synthetic

Synthetic
Rubber

F <140

<0.0001
<0.0001

<0.0001

mrxed acrd serum horn synthetic-rubber


coagula
Iron, sodrum chlorrde 20% average.
sulfuric acid
0.08% average, acetlc acid 0.08% average. pH 3

Synthetic
Rubber

90

concentrated
coagulatmg
serum,
10%. pH 4-6 (serum evaporator)

Synthetrc
Rubber

coagulatmg
serum, strong sodrumchlorrde
concentratron. drlute sullur~c acrd. rubber lures and soao.
traces 01 auxrlrary solutron; rubber contarns carbon
black 30%
some carbon black suspended in soluIron, pH 3 5 average

Synthetrc
Rubber

ddute acid solutron lor coagulatmg


serum make-up.
sodwm chlorrde 4%. sulfuric acid 0.35%

recycle coagulatmg
serum, sodium
lute sulfurrc acrd, water, pH 4

xx

42

xx

0 0002ad

185

13

xx

xx

0.0035cd

0.0017ad

115

34

xx

xx

0.0025cd

0.00064bd

Synthetic
Rubber

100

41

II

xx

0.0168cd
0.01115cd

0.0004d

Synthetrc
Rubber

100

64

drlute mother lrquor used to coagulate


synthetrc
rubber, sodium chloride 4% approxnnately,
sodium
sulfate 0.3% approxunately,
pH 3.5 (tank bottom)

Synthetrc
Rubber

120

21

ddute creamrng and coagulating


solution for GR
S synthetrc rubber latex, sodmm chloride 3 9%.
sodrum sulfate
0.27%.
pH 3 55 Ialternately
im.
mersed)

Synthetic
Rubber

120

sodium chlorrde
iOorr dewatermg

Synthetic
Rubber

90

30

0.0007d

<0.0001

0 0002c
nil

<0.0001
nil

0.0011c

<0.0001

rubber

latex

3 3%. sulfuric
skrmmer)

sodrum

chloride

chloride

acid 0.01%

4%.

di-

solution

I(

<00001

nil

<O.OOOlad

0.00012ad <O.OOOl
<O.OOOlad
nil a

nil

nil

nil

sodmm chlorrde 3.06%.


sodium sulfate
bon. ddute sulfurtic acrd. pH 4 3

0.33%

solu

Rubber

86

12

sodwm chlorrde 3 06%. sodium sulfate


bon. drlute sulfurrc acrd. pH 4.3

0.33%

solw

Rubber

120

sodwm chlorrde 3.06%.


sodrum sulfate
bon, ddute sulfuric acid, pH 4.3

0.33%

solw

Rubber

120

12

sodrum chlorrde 2.68%.


sodium sulfate
bon. dilute sulfuric acid, pH 1.5

03%

solu-

Rubber

86

sodrum chlurrde 2 68%. sodmm sulfate


bon, drlute sulfuric acrd. pH 1.5

0 3%

solu,

Rubber

86

12

0.0324~

IllI

sodmm chlorrde 2.68%.


sodtum sulfate
bon. drlute suffurrc acid, pH 1.5

0 3%

sohr

Rubber

120

12

0.0427~
0.096

0 008
0.0005

<0.0001

0.0001

<0.0001

0.0072

(contmued)

Corrosion Resistant Materials Handbook

566

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

(amtd)

Average corrosion rates (ipy)

ALLOY

TIM

TWE

TIPC

304

316

317

20

825

Precious
Metal

200

0 28

0.135c

0.058c

0 083c

0.17c

Precious
Metal

130

004llc

0.061 lc

0 0564~

0 12llc

0 0506~

Prectous
Metal

0.029c

0.027~

0 022c

0 024~

0 029c

Metal

1280

48
8 48

7.02

moisture-laden
sewage gas from anaerobIc
dlgesbon of packlng house waste, carbon dioxide
63%.
methane
36%. hydrogen
sulfide
l%, pH 7.4 ap
proxtmately
(Nash vacuum pump)

Food
(meal1

90

90

settled

sewage
Itreatment)

75
80

34

selentous
scrubber)
fumes

aud,

of selemous

fumes of selemous
(box scrubber)

selenwm
charge,
chlorides
0 166,
per 0 094%

sewage,

sulfwc

and

acid.

sulfuric

acid.

nltrlc

acids

and nitric

sulfurtc

and

(gas

acids

rutnc

acids

sulfates
0.78%.
sulfur
0.34%.
won 0.13%, telluwm
0 11% cop-

hydrogen

sulfide

14.20

ppm.

pH 6-7

0.1189c
650

<o 0001

<o 0001

0 0003

0.0002

xx

<o 0001

<0.0001

<0.0001

flftrate
from dewatered
contams
ferric chloride.

elutrlated
sewage sludge,
pH 6 (vacuum flltratlon)

Sewage
fdlsposal)

70

110

xx

xx

CO OOOld

flltrate
from dewatered
contains lerr~c chloride,

elutrlated
sewage sludge,
pH 5 5 6 (vacuum fdtratlon)

Sewage
fdlsposal)

70

139

xx

xx

0 0002cd

Chemical

RT.

xx

0 001
0001

0 0006

0.0032

0.0031a

s~I~ceous ore pulp. soltds


ferric sulfate added, ferrtc

s~hcon

tetramdide,

free

50%. sulfuric
acid and
loo 2 g/l, mltlal ptf 0 5

lodme

2%

(hall

Immersed1

>40%
potash soap, derived
lrom edible
011. hand washmg
soap, fatty
acids
~0
9 59.8

coconut
5%. pH

Research

Soap

:f

293

<0

72

<O.OOOl

<0.0001

Soap

72

<o 0001

<0.0001

15% soap, made up from soya fatty acids 50%. tall


011 50%. wth sodlum sullate 1% and pine oil 1 5%.
floor cleaner, pH 10.6

Soap

72

<0.0001

<0.0001

12.5% soap made up from soya fatty


and tall 011 50%. wth
free trisodium
1%. floor cleaner.
pH 11-11 5

Soap

72

<0.0001

<O.OOol

Synthetic
Rubber

135

soap solutmn,

pH 10.3

IllI

<o 0001
00001

<0.0001
0 0001

0.0035

0.0029

OOOld

35% soap made up lrom coconut


fatty acids 50%
and soya fatty acids 50%. glycol 5%. hand-washing
soap, fatty acids (0 4%, pH 9.2-9.5

acids 50%
phosphate

3 19

llll

(continued)

Ferrous Alloys
TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

lPL

soap
2%

lye.

sodium

fats,

fatty

acids,

mixture,
10%

chloride

caustic

ll%,

soda

sodturn

hydroxide

Soap

200

sodlum

hydroxide

Soap

200

102

Soap

90

35

(bottom

of kettle1

(amtd)

Average corrosion rates (iPY)

304
----soap and wash-hquor
15%. sodturn chlonde

MOLYBDENUM

567

TPl

TWl

316

317

<o 0001

<0.0001

<o 0001

<o 0001

<0.0001

<0.0001

20

ALLOY
a25

217
soap, salts of alummum.
z,nc. pH 4-l

calcwm.

preclpltated

magnewm

and

soap and salt

Soap

100
190

35

<o 0001

co 0001

Soap

100

35

<o 0001

<0.0001

125
tallow,
stocks

acldulated
cottonseed
(tank bottom)

aclduiated
vegetable

cottowseed
oil
011 soap stock

and soybean

soap

stock

011 soap

and

mlxed

Chemical

Chemtcal

138

11

xx

<0.0001

<0.0001

147

62

xx

<0.0001

<0.0001

56

<0.0001

<0.0001

<0.0001

<o

ddute soap solutlon


of sodwm salt of sulfonated
011
of mdefmlte
composition,
sodurn
oleates.
paraffm
011s

Rayon

86

lo%,
hyde

Chemical

230

38

xx

Chemical

80
130

157

xx

Chemical

300

61

xx

xx

<0.0001

82

36

xx

<0.0001

280

xx

xx

5%,

5.2%.
0.1%.

organws.
1%. water
waler

bulyl
alcohols
5.10%.
remamder,
pH 4.5

remainder.

water 93%.
pH85-95

formalde-

pH 4-10

sodwm

formate

0.5.1%,

butane

96% crystallme
sodurn bicarbonate
and ammonun
chloride,
remainder
sodwm chloride,
ammomum
bicarbonate,
hydrogen
sulfide. water fliqwd);
and air,
sodurn-carbonate
dust, ammoma.
hydrogen
sulfide.
water Ivapors)

20%,
soda-ash
draw liquor.
ammonwm
chloride
15%. sodwm chlor,de 5%, dissolved
carbon dloxlde
2%. free ammoma
1.2%. solld ammonwm
blearbonate I%. sodum sulfide trace (carbonating
tower1

Chemical

85

condensate

Chemical

135

Chemical

84

3102

Chemical

81

90

from

sodium-bicarbonate
chlortde.
sodwm
tder lcarbonatmg

sodlum-bicarbonate

slurry
chloride,
tower)

slurry saturated
wth
carbonate.
ammonium
bonate. free ammoma
carbonatmg
tower)

mother

liquor

m solution
of ammonium
and free ammonia
35

sodum
chloride,
sodium
bichloride,
ammonium
bicarand free carbon dioxide
fbi-

0.0001

0.0004

0001

0 0001

<0.0001
w0.0001

0.0001

L nil

14.
28

<o 0001

0.0001

0 0001

0.00037

xx

0 0001

0.0001

xx

xx

0.0003ad

0.0004d

(continued)

Corrosion Resistant Materials Handbook

568

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

wet gas containmg


carbon dioxide and ammonia,
water 0.32 g/I ammonia
0.23 g/l;carbon
dioxide
0.135 g/l III vapors; ammonium
carbonate
IM, ammonwm hydrorlde
1.3M III condensate. some hydrogen sulhde III vapors (heat exchanger)

Chemical

ALLOYS-CLIMAX

bmd)

Average corrosion rates (ipy)

185

70

x.

O.OOOlb

0.0001

soda)

feeder Ilquor. sodwn


chloride 230 g/l. flxed ammoma 65 g/l, free ammonia 15 g/l, sulfide 0.04 g/l.
won 0 006 gi I (coke-packed section of strippar still)

Chemical

185

105

xx

0.0016~
0.0003c
s0.0014c
LSO.OO28c
sooolc

0.0001c
so.ooo2c

blcarbonale
lower slurry saturated wdh sodwm brcarbonate. ammomum bicarbonate.
sodium chloride,
ammomum
chloride,
free ammoma,
free carbon
dloxlde, some crystals of sodium bicarbonate

Chemical

75.
160

77

xx

O.OOZlad
0.0015ad

0.0015a

8%,

Chemical

150

60

xx

xx

0.016~

salt m suspension

Chemical

230

174

xx

00001

saturated
solution of sodium chlorate and sodium
chloride from which the chlorate is crystallized,
no
hypochlordes,
pH 6-7

Chemical

100

62

saturated
solution of sodium
chloride, sodrum hypochlorite
porr. pH 6-7

Chemical
tevaporatiord

165

13

xx

Research

127131

purlhed sodwm-chloride
slurry from vacuum pans,
brine 75% approximately,
salt crystals 25% approximately

Chemical

90.
100

saturated

sodrum-chloride

Chemical

160

saturated
materials

sodium-chloride
brine,
some oxidizing
lrom products of combustion of gas flame

Chemical

saturated
fdter)

sodlum.chlorlde

Chenwal

SOOIM

MOLYBDENUM

0.0001c
SO.OOOla

CNtBONATE

25.4%. sodwm
so&urn

sulfate

chloride
2 5%

8%,

sodium

borate

SOOWM
CHLORATE
55%. sodium chlorfde 7%. rohd
5%. pH 9-10 [vacuum evaporator)

sochum
water

chlorate,

sulfuric

chlorate
2-5 g/l.

acid,

chlorine

dioxide,

O.OOOlbd

c0.0001

O.OOOlbd

0.0005ad

10.0045
10.009
10.0156

10.0063
LO.0086

0.002

CHLORlOE

sootu

brme

solution

saturated to 15.3%
nate Immerslonl

sodium-chloride

vapors from bodmg


t10n Ievaporator)

saturated

25%.

and sodium
chlorine va-

00001

water

remamder

(Ohver

solution

sodlumxhlorlde

vacuum

lalter-

solu-

xx

204

180

52

0.0004cd
0.0007cd

0.0022cd

90

90

xx

0.0012cd

O.OOOla

Metal

60.
80

160

O.OOOld

Chewal

210

210

xx

0 OOOlcd <O.OOOlbd

Research

140

90

<O.OOOlad

<0.0001

<O.OOOld
C<O.OOOld

ml a

<O.OOOld

<O.OOOl

IllI

(continued)

Ferrous Alloys

TABLE

VARIOUS

4.13:

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

bntd)

Average corrosion rates (ipy)

1YPE

---SDdlrn

MOLYBDENUM

569

304

TYPE

316

WPE

317

20

ALLOY
825

Ehlorlde

nil a

140

Research

95

a4

Textile

150

AN
Conditioning

17

90

0.00015cd
LO.OOOlcd

<O.OOOlcd

Refugeration

17

90

0.00013cd
LO.OOOllcd

<O.OOOld

Research

195

Chemical

100

393

Chemical

400

27

~50%
sodium-chloride
brme, oxldlzmg
materials
from combustion
products
of gas flame (open evaporator)

Chemical

200

45.6%
sodurn-chtorlde
slurry.
calcium
chloride
17.6%. magneswm
chloride
3.2%. solid salt in suspension, pti 6 3 fIlmed); pH 5.3 hmllmed)

Chemlcat

129

26%
saturated
chloride
10 g/l.

Cherwcal

50

23.6%
approximately
sodwm-chloride
brme.
calcwm sulfate 3 g/l. sodum
chlorate
0 5 g/l, traces
of sodium hypochlorde
and mercury

Chemtcal

149

23.5% approximately
sodurn-chloride
sulfate
18 g/l. sodium
carbonate
hydroxide
I g/I

Brme
Product,on

R.T160

Chemical

48

<0.0001

21.2%
approximately
sodwm-chloride
solution.
free ammonia
39 g/l, llxed ammonia
as ammonwn
chloride
15 g/l. carbon dloxlde
19 g/l, hydrogen
sulfide 0 5 g/I tplpmg)

Chemical

145

<0.0001c

19% approximately
sodumxhlorlde
chlorate
30-50 g/l. iron 1-l 5 ppm,
ppm. sodwm hypochlorde
as chlorme

Chemical

waler

remamder

20%.

sodbum-chloride

Ivapors.

Ilqwd)

spray

10%
sodwm-chloride

solutmn.

sodwm-chloride

spray,

pH 8 5

pH 6 5

4%

saturated

salt brme. hydrogen

sulLde0.15gll.

50% sodwm
chloride.
sodium
hydroxide
dum chlorate
I%, ammonia
1%. water
lammanla
still1

sodurn-chloride
calcwm
sulfate

22%
approrlmately
dlum sulfate 60 g/l.
l1zer tank1

pH 6.7
8%. SD
remainder

solution,
calcium
2 g/l, pH 6.5

brme.
16 g/l.

sodium-chloride
sodium hydroxide

sodum
sodium

solutlon.
so7 g/I (crystal.

brine. sodurn
mercury
l-l 5
0.2%

45

ml a

Chemical

25%.

0.0007

<0.0001

<0.0001

0.0001c
0.004

0.0023

0 009bd
0215bd

0.041gbd

0.001 led

lJ.oOfJ~

ia0

0.002

0.003cd

aluminum

chloride

hydrate

S0ap

160

65

18%.
residual
0 25%

soap,

alumwm

chloride

hydrate

soap

165

65

SOi3P

165

65

0.0007

ml

225

soap,

sodwm oxide 0.03% apoxide 00003%


approxl.

<O.OOOla

0.0146b

16%.
restdual
0 25% (fdterl

ICI%, restdual soap, total


proximately,
free sodurn
mately

0 00036~

0.0001

0.0006cd

0.0002d

(continued)

570

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

jj
e

TYPE

TlPE

TlPE

0
.

2
.

4
.

304

316

317

18%. restdual
soap. total
pro:imately.
lree sodium
mately

sodium oxide 0.03% apoxide 0.0003%


approxi-

Soap

140

65

xx

xx

10%. alummum
mately. pressure

hydrate

0.25%

approxi-

Soap

165

65

XI

xx

hydrate

0.25%

approxi-

Soap

160

65

xx

xx

0.00064~

0.00036cd

soap

160

46

xx

xx

0.0004ad

0.00014

Soap

140

46

xx

xx

0.00084d

0.00038

15.3% approximately,
ammomum
perchlorate
240
g/l, sodturn perchlorate
78 g/l. sodwm chlorate
2
g/l, ammonium
chlonde
trace, pH 4 8

Chemical

155.
170

98

14% approximately
slum chloride
12%
center well1

slurry,
potasIOorr thickener,

Chemvzal

77

38

0.0003a

0.0003

14% approximately
sodium-chloride
bittern,
chlOr&de 10 5N. sulfate
ion 55 g/l. magnesium
ion 41
g/l, sodlum and potaswm
ions balance of catloos.
pH 2-5 (heat exchanger)

Chemical

170

90

xx

0.0036r

0.006~

12X, acldlfled
with sulfwc
acid, petroleum
added, pH 2 5 kheepskm
degreasmg
drum1

Tannmg

180

0 0001

0.0001

xx

xx

0.156cd

0.047cd

WO.OOlcd

18%.
mately

bmd)

Average corrosion rates (ipy)


c

chloride

MOLYBDENUM

0.0004d

<0.0001

20

ALLOY
825

0.0002

<0.0001

110 psi

aluminum

chloride

18%. total sodwm oxide 0 03% approximately.


sodwm oxide 0 003% approximately.
pressure

free

110

PSI
18%. total sodium oxide 0 03% approximately.
sodium oxide 0 003% approximately.
pressure

free
110

Psi

sodwm.chlorlde
approximately

solvent

Mmmg
kulfur)

112

sodwm chloride
and sodwm sulfate
13.16%.
glycenne 10.12%.
spent soap lye treated
wth ferric
chloride and sulfuric
acid to pH 4 5. mud and water

Soap

a5

I05

xx

WO OOlcd

sodwm
chloride
lye treated
wth
mud and water

Soap

a5

105

WO 006cd
wo 004c
WO.OOOlbd

10.5%.
acldlc salt strlppmg
solution.
chloride
70
g/l, sulfate
50 g/l. nitrate
20-25 g/l, thorwm
4.5
g/l. ferric ton 1 g/l. sulfuric
acid 0 IN; pH 0.5 ap_
proximately

Mmmg

86

21

7% approximately.
05%

12% approximately
waste brine, calcmm
g/l. hydrogen sulbde 250 ppm (line)

chloride

and sodturn sulfate


13.16%.
acid
alkali to pH 9. glycerine
lo-12%,

pickle

1% approximately,
pickle
0 5% (above hquor level1
5%,

potasswm

chloride

5-4%,

sodlum

hydroxide

4.7%.

hydrofluosdiclc

17

--

hquor,

sulfuric

actd 0 25.

Tanning

60.
70

180

Ilquor,

sulfuric

acid

Tanning

60.
70

180

Chemical

67

35

xx

Chemical

220

58

0 25.

4 5.

1% (bottom

01 column1

acid 3.5%

2%. plantwaste
elfluent.
sohds 4-5%, chlorides,
carbonates,
sullates.
sulfides
and organic
salts,
water remamder,
pH 10

Agriculture
(fertilizer)

a0

35

Chemical

60

105

0.018a

0.016cd

0.0022

0 0012

<o

0001

xx

<o

<o

0001

xx

<O.OOOld

<O.OOOld

0.0026cd

0.0007ad

0001

<0.0001

0 0038cd

W0.003cd
wo.003
W<O.OOOld

<0.0001

0.0001a 0OOOla

0.0002cd

0 005lad

0 0074ad

<O.OOOld

0 006cd

<O.OOOld

<0.0001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TlPE

304

316

0.0001c

0.0001c

---1.6% approximately,
spent brme mme water from
Frasch process,
calcwm
carbonate
500-1000
ppm,
hydrogen
sulllde
150.200 ppm, polysulfldes
75.100
ppm. thlosulfates
as hydrogen
sulfide
4-10 ppm.
ptl 6-6 8

Mming

120

67

xx

0.15%.
chlorides

Chemical

149

144

xx

xx

Chemical

130

45

xx

xx

Salt

228

ia

XX

brme,
bromme

calwm
and
04%,
pH 6

sodium

chloride,

potaswm

purllled
chlorlc

sodium-chloride
brme.
acid to pH 3 54.5

sodium

chloride,

water

sodwm-chloride

blttern

magnewm

chloride

3%.

acldlfled

ferrous

wth

chloride

(heatexchanger

sodium

chloride.

sodwm

sulfate

sodium
(vertical

chloride.
sodium
tube evaporator1

sulfate,

hydra.

Chemtcal

0 7%

head)

glycerme.

pH 6-10

MOLYBDENUM

571

(mntd)

Average corrosion rates (ipy)

VIPE

o+field
lo%,

Alloys

147

Chemtcal

Tannmg

Soap

169

168

xx

180
140

1235

xx

,PL

317

20

825

0.012c

0.016~

0.0022d

0.0022d

0.263

0 0002ad

0 OOOlad

0 0006cr

0 0006~

0.0002

0.0001

<O.OOOlcd

ALLOY

0.189

0 0002c

<O.OOOl

<0.0001

<O.OOOlad

<O.OOOld

<OOOOld

<0.0001

<0.0001

150

saturated
salt
erine 15.80%

solution of glycerine
and water. glyc(Wooster-Sanger
evaporator.
vaporsl

Soap

140
220

91

salt and crude


pH 79

glycerme.

soltds

7.25%,

water

vapor.

Soap

190

24

llll

salt and crude

gtycerme,

solids

725%.

water

vapor,

Soap

190

26

0.00012

Chemical

212

14

,.

XI

0.0047cd

Mmmg

77

84

xx

xx

0.0003ad

<O 0001

Chemical

0.004c
0.006cd

0.0001

0 0003cd

nil

<0.0001

pn 5.5-9
organic
sodium

maternal
contammg
unstated
chloride
and hydrochlow
acid

air. saturated

SODWM

5%.

wth

sodhum

amounts

of

chloride

0.0043cd

CHLORITE

pti 3 5 5

68

158
0.5%. during 34 hours, aeratmn
durmg 138 hours,
calcium
hypochlorlte
direct
chlorination
wth
added sulfuric
acid to pH 4.5 durmg
572 hours
(honzantal
Bellmer
bleach beater)

Pulp and
Paper

95

31

.x

xx

0.0002cd

0 OOOlad

0.2.0.1%.
mg, oxahc

Textile

160.
170

194

xx

0.0006~

0.0003c

0.1%. CF rayon bleach, 53% acetic acid 0 18%.


synthetic
detergent
0.1%.
0.035%
hydrogen
peroxide 100 vol, sodium
carbonate
0.03%

Chemical

210

05

xx

0 003

0.003

0 04%.
CF
textde
bleach,
synthetic
detergent
0.2%,
sodium
bicarbonate
0.15%,
free chlorine
as sodium hypochlorlte
0.15%.
soda ash 0.07%

Chemical

130

0.5

xx

0.001

0 002

0.02%.

Textone,

TextlIe

sodwm

cyamde

MIlllog

Textone
cotton
acid l-2 g/l

caustic

solutlon

dyemg

and

soda 1% lbleachmg

bleach-

klerl

215

a0

23

60

0 0001

<0.0001

<o

0 OOOlc

O.OOOla

0001

<0.0001

<0.0001

(continued)

Corrosion Resistant Materials Handbook

572

TABLE

4.13:

VARIOUS

STAINLESS

Corrosion mediums

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

Test
conditions

Average corrosion rateS (ipy)

304
-----

TVPE

SOdlrn

TlPE

WPE

316

317

cyanide

solution

Mmg

a5

111

%00001

sodium

cyanide

salut~on

Mmmg

75

98

0 0001

sodurn

cyamde

water

tvapors)

Mmng

70

111

00001

0 0001

sadlum

cyanide.

water

fvaporsl

Mmg

74

98

0 0001

0 0001

sodwm

cyanide

Chemical

1292

10

0.0377d
0 0464d

0 0279ad
0 043d

Metal

a7

63

Chemtcal

175

30

0 OSIC
0 Olc

0 043

Chemical

140.
180

IO

0 135

0 0562a

acid.fluoude

Chemical

50

30

0 0023

0.0013

acid

Chemical

130

0.153ad
0 116ad

0 055d

Chcmtcal

167

310

. OOOOlad

SDD,M

fused

ALLOY
20

625

FLOR,DE

sodum
lluorlde,
alummum
lluwde,
sodium
fate. sodturn carbonate,
sodwm
bicarbonate.
water. alummum
oxide. DH 9

SOOIlA

t*alw

itop

trough

sodturn
acid fluahydrogen
lluorlde

01 crystalluer)

3.7% approximately
s0lut10n. solne lree

SODlUU

sulaw.

00001

<o 0001

0 00011
0 00017

FLUORlOE

6.1%
approrlmately
saturated
ride solul~on.
crystals
30 g/l.
30 gl

saturated
Crvslals

sadwm

CO 032

FLOSIL1CATE

sodwm-fluosd~cate

SOOIVM

slurry.

hydrochloric

FORLlALOLHYDE

60.25%
lvacuum

5%

SULFOXILATE

sodlum.formaldehyde-sulfoxylale
evaporator)

monosodwn

glutamate,

saturated

l!quor

<0.0001

Food

86

28

Chemical

176

a4

<0.0001

<0.0001

Chemical

230

50

<0.0001
<O.OOOl
L<0.0001

<O.OOOl

Textile

85.
125

42

<o 0001

<0.0001

17.75% approximately

110

57

12.65%

90

58

sodurn chloride

0.00015ad <O.OOOla
0 0014bd

solutwn tcrystalluer)

SODIUM

HYDROSULFlDE

46.36%.

sodwm

12-5X.
ties

sodwm

SOOIUU

40%.

bntd)

cyanide

sodium

6%

MOLYBDENUM

sulfide

1%

sulhde

and polysullldes

as impuri-

<O.OOOl

<o 0001

HVDROSULFITE

some sullur

dmxlde,

approximately

zmc suspension

in water

0.002a

0.0001

0.0001

c0.0001

O.OOOlcd

0.0001

0.0001

c0.0001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

r::

TPE

TPE

TlPE

304
-----

316

317

nil

llll

0.005a
0 007a

0.007a

150

75%

Chemical

275

35

74% ltank car)

Chemical

265

88

73%

Chemical

248.
320

34

73%

Chemical

230

88

--

0 045
0 038

73%

Chemical

230

52

0.0093
0.0039

72%

Chemical

250

119

0.0037

70%

Chemical

194.
239

90

0.0268

51.49%

Chemical

150

30

0.0001

50%

Chemical

136

167

30%

Petroleum

68

30

22%

Chemical

131

133

Chemical

190

90

Chemical

200

119

0.0002

0.0002

Chembcal

240

24

0.001

0.0015

35%. chloride IO 3 ppm lvaporsl

Atomic
Energy

500

21

23% approxlmatety, salt 7.8%

Chemical

200

48

00004

0.0023

23% caustic soda lye, sodium chlonde IO-15%.


tallow, coconut 011. glycerme removed wth sodwm
chloride. sodium hydrosulllte 0.050.15% added m
alkatme solution

Soap

190

64

xx

<O.OOOlcd
;OOOOlcd
O.OOOlb
00001*a

<OOOOla
0 0003

22.18%. mercaptans. cresolates

Petroleum

100.
220

30

xx

0.0001
0.0001

0.0004

20%, potasswm hydroxide 2.7%. (stilt pot in crackmg column)

Plastic
tdistdlalion)

305

60

xx

<O.OOOl

140

196

xx

00014

HYDROXlDE

evaporat00

xx
-

0 0084
0.1 I3

0 105

0.0031

<0.0001
<0.0001

<O.OOOl
<0.0001
<0.0001

Scm,M-HYDROXIDEYlXTURES
50%. sodium chloride 10.15%
40.35% approximately.
(salt settler)

20% approrimately.
Ievaporator)

salt 6.7%

suspended

approximately

crystalline

salt

(amtd)

2
a

TextlIe

14% huttpte-ettect

MOLYBDENUM

573

Average corrosion rates (ipy)


2

SODlUH

Alloys

<0.0001

0.0036

20

ALLOY
625

574

Corrosion Resistant Materials Handbook

4.13:

TABLE

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

hmd)

Average corrosion rates (ipy)


E

----

NPE

TlPE

TWE

304

316

317

IS%,
naphthenrc
gravrty 22.28&),

acrd, cresols,
phenols
fresultrng
mercaptan
sulfur 0 04% (tower)

Petroleum

225

660

0.0001

0.0002

18%. naphthenrc
gravrty 22~28Bel,

acid, cresols.
phenols
Iresulting
mercaptan
sulfur 0 04% (tower)

Petroleum

225

564

0.0001

0 0001

20

ALLOY
825

17.2%,
chlarrde

organrc
salt 12%.
7% lliqurd Imet

methanol

8%.

sodrum

Chemical

85

37

xx

<o 0001
s0.0001

<0.0001
so 0001

<0.0001

<0.0001

17.2%,
chlorrde

organrc
7%

methanol

8%.

sodrum

Chemrcal

85

37

xx

<o 0001
so 0001

<0.0001
s0.0002

<0.0001

<0.0001

Chemrcal
fdrstrllation)

212

33

Chemrcal

85

20

xx

0 0001

Chemrcal

190

279

0 0002

Research

190

300

Petrocherlncal

80.
90

138

Chemrcal

125

104

Chemical

130.
140

99

130.
140

salt

12%.

15%. monochlorotoluene
saturated
wrth
2% and hydrochlarrc
acid 2% approxrmately
strll)

15.1.5%.
chloride

10%

amme
7%

caustrc

10.3%.

salt

cell

12%.

Imuor.

occasronalty

sodrum

hypochlorrte

2%.

sulfurrc

acrd 10%.

sodrum
solutron

sodrum
solution

hydroxrde.

hydroxrde,

salt

some

6%,

methanol

~1%

sulfur

sulfur

8%.

scud

(gas scrubber)

droxrde

dioxide,

droxide.

sodrum hydraxrde,
sodrum
fide. mtermrttent
exposure
gen sulfide (gas absorption

0 1%. pH 4 3
normally

normally

hydrosulfrde.
sodium sulto air, steam and hydrocolumnt

material,
sulfuric
of ro exchanger)

0.5%.

of butane

99 5%.

acid

0.0083

0 024cd

0 022cd

io

0001

<o

xx

<o

0001

<0.0001

99

xx

<0.0001

167

15

xx

167

30

275

0.0001

0.0001

II

nil

xx

Chemical

86.
248

75

Chemical

100

103

xx

5% (tank bottom)

Cellophane

65

39

2.94%

Textile

70

25

--

Petroleum

R.T.

37

6.3%.

sulluric

acrd 45%,

sulfate

0.52X-O%,
free sodrum hydroxide
chlorrde
2-25 g/l. sodium rrlicate
O-2 ml/l

turpentrne

oil

4-35 g/l. sodium


g/l. acid oils

<0.0001
0.0003

<o

0001
0 0003

0.0003d

O.OOOSbd

0.029cd
O.OOllcd

0.0001

<o 0001

<0.0001

0 0002d

0.0003d

<0.0001

0.0004

methanol,

formate.

CO 0006

0001

0.00015

320

sodrum

<0.0001

0.03a

0 018cd

to 0002

xx

Chemrcal

0 022cd

0.023cd

and kerosene

dilute
caustic
soda,
rtrogen
compounds

traces

acid

alkaline

sodrum
hydroxrde,
organic
and arsenious
acid fin resm

water

sodrum

12%

sulfurrc

sulfur

chlorine
[batch

0.0002d

<O.OOOl

0.0006d

0.000la

(continued)

Ferrous Alloys
TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

,PP

0.11%. sodium alummate 1200 ppm approximately

Beverage

70

0.1%

Chemical

140

0.042%-O%. sodrum chloride 3.21 g/l, free sodium


hydroxide 6-13 g/l. acid ads 02 ml/t during 13
days; and sodium chloride 7-15 g/t. free sodium
hydroxide 5.8 g/l during 42 days

Petroleum

R.T.

55

Cellophane

:F

212

69

30

94
1.3

x-

1VPE

317

<O.OOOld

<O.OOOlcd

0.0009d

0.00015d

O.OOl&

xx

<0.OOOlad

xx

o.ooa7c

xx

VIPE

316

<O.OOOlad

. ..

0.0006

Chemical

232

0.4-0.3X.

Textile

180

Coal Byproduct

248

50% sodium trrpolyphosphate and sodium tetrapolyphosphate solution (hydrator)

Chemical

165

2.5

xx

xx

0.0001

0.0004

so&urn phosphate, salts 54.55%. hydrochloric-acid


trace. ptl 6 9-7 (gas scrubbing, vapors, liquid)

Chemical

185

16.5

II

xx

nil

nil

10% dlsodium phosphate and sodium carbonate,


sodwm.phosphate solution. pH 9 (bottom of tower)

Chemical

150

123

xx

xx

0.0001
0.0001

0.0001

rhsodurm pyrophosphate during 38.6 days, disodium


phosphate durmg 7.3 days, monosodium phosphate
durmg 5.7 days, potassium phosphate during 4.3
days, potassrum pyrophosphate during 1.8 days,
monopotassium phosphate during 1 day (rotary drier)

Food

:F

60

59

xx

xx

0.0001

0.0001

0.0001

disodium pyrophosphate during 38.6 days, disodium


phosphate during 7.3 days, monosodium phosphate
durmg 5.7 days, potassium phosphate during 4.3
days, potassium pyrophosphate during 1.8 days,
monopotasswm phosphate during 1 day (rotary drier1

Food

70

59

xx

O.OOOla

0.0001

0.0001

sodwm phosphate, sodium chloride, pH 4

Research

230

55

Chemical

F <160

45

xx

xx

SODIUY

0.2

0.0056
10.0058

ALLOY
825

20

nil

6&12X approximately, crude sodium-nitrate sohrIron fevaporalor)

s&urn chloride 0.9%. diazoting bath

(contd)

Average corrosion rates (ipy)

304
-----

sodrum hypochlorite traces, sodium chloride <l%.


sulfur base dye

MOLYBDENUM

575

<O.ODOlad

o.ow6

0.0044

PHENOLATE

sodium phenolate, tar acids 20 WI% approximately.


total alkalinity 20% as sodium hydroxide (tower)

329

<O.OOOlcd

<o.o001

SODIUM PHOSPHATE

SODIUM

0.0012cdr

nil

0.0011c

0.0016cd

PROPIONATE

~0.2% sodium and calcium propronates and acetales, so&urn salts, pH8 approximately

<0.0001

(continued)

Corrosion Resistant Materials Handbook

576

VARIOUS

TABLE 4.13:

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

sodrum-sulfate

solution,

crystals

20%

304

TWX

316
-P-P

xx

0.0001

0.0001

0.0001

xx

0.0001

0.0001
w0.0001

0.0001

xx

xx

0 0006ad

0.0003d

0.0028cd

O.OOlcd

170

48

Chemical

230

193

Paper

158.
176

Pharmaceutrcal

125

20

xx

6.547%
approximately,
sodrum fluorrde 5.20 g/l,
sodrum carbonate 2.10 g/l, traces of sulfur dioxide
and hydrofluorrc
acrd, water remarnder
(Soderberg
gas scrubber)

Metal

68.
104

55

xx

xx

0.0004c
. ..0.0001

<0.0001

5-0.5X.
washmg

Chemical

150

28

xx

<O.OOOld

<0.0001

Textile

150

flll

Pulp and
Paper

190

179

Metal
fprckling)

160

71

x-

Chemrcal

340

26

Chemical

212.
355

81

xx

xx

Chemical

300

30

xx

0 092
0.114

Chemrcal

300

19

xx

0.084
0.23

Chemrcal

194

160

sulfate

25.20%.
top waters from organrc yellow
sodrum acetate 3%, sodrum chlorrde 16%
14.8%.
chlorrde ran 456,
ran 1%. pH l-2 5

1.5%

sulfurrc acid
of sdrca gel

sodrum sulfate

11%

ran 4%.

053%.

hydrate,

sodium sulfate. sodrum


water, solrds 55%

SOOIUY

ferrrc

wash

sulfuric

carbonate,

prgment.

phosphate

water

sodrum

4.1

xx

825

nil

<O.OOOl

<0.0001

<O.OOOla
s<0.0001

<0.0001
S nil

WLFlDE

Ifusron pot1

60-30X

sulfide.

7 5

20

,81-) SULFATE

60%
60%

from

acid 0.5%

approximately

SODIUM

l%,

ALLOY

,PL

317

.
F

sodrum.sulfrte
saturated
slurry. tmc
sodrum hydroxrde. pti 8 5-9 fevaporator)

bmtdl

Average corrosion rates (ipy)

,Pl

saturated

MOLYBDENUM

(tube evaporator

tray)

60.25%

>0.072

0.207

>0.3

fevaporator,

vapors)

Chemrcal

255

30

xx

0.0075
0.0118

0.019

15%

(evaporator,

vapors)

Chemrcal

185

30

xx

0.0001
0.0001

0.0001

10%

Ievaporator)

Chemrcal

185

21

xx

0.0005
0.0001

0.0001

10%

Chemical

R.T.

81

xx

0.0001

0.0001

0.4%

Rayon

108

43

Pulpand
Paper

65.

163

of tanti

100

0.0026

_,

co.11

30%

pH 6.5 (bottom

finally

CO.081

mrtrally.

solution,

45%

>0.073

0.038

40%

sodium-sulhde

sodrum hydrosulfrde

0.036

0.0039

0.0002
<0.0001
0.0001
<O.OOOl

<O.OOOl

<O.OOOl
<0.0001

<O.OOOl

0.0015

0.0005

CO.owI

(continued)

Ferrous A l/o ys

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL


Test

s -f
i pz $

,YOUSl

IPROCESS
L
i
.

0
.

. .

ll?E

1WE

1WE

304

316

317

0.0001

0.0001
0.0001

P--P-

Tanning

sodnrm sulfide, sulfonicacrd


derivatrves.
pH >8
11 any hqurd entrained
in vapors and noncondensable gases Ievaporator.
vapors)

Pulp and
Paper

140

84

xx

O.WOl

2% sodrum trwlfide.
sodium chloride 2%. sodium
hydroxrde 0.5%. traces of ethyl amine, thiosulfates
andsodmmmercapto-benzothlarole.
water remainder

Chemical

105

70

xx

0.0001

6.64%

Pulp and
Paper

75

28

Tanning

Rayon

sodrum-sulfide

solution.

approrimately.

3%. orgamc
false bottom

sodrum
0 12%.

sodium sulfhydrate

sodwm

bicarbonate,

pH 7.5

actds, sulfurous acrd. tannins


01 quebracho bisulhting
tank)

sulhte
alkalme

calculated
Antrchlor

as sodrum
solution

(under

hydroxrde

Pulp and
Paper

6%.

Tanning

Metal

16.4%
approximately.
drum chlorrde 3%

hydrochloric

acid

5%.

so-

I80

<0.0001

ALLOY
20

525

<0.0001

<O.OoOl

180

xx

108

56

150.

55

0.0901

0.0001

<0.0001
<0.0001
0 2038

<o

0001

nil

c rlll

200

20%. yandlm. treated under vacuum with sulfuric


acrd to drove off sulfur droxrde. solution decomposed
to sodrum sullate

acid, tannins

hntd)

nil

0.063%.
sulfates as sulfur trroxide 232 ppm, chlorrdes as chlorme 210 ppm. rron 28 ppm, nitrates as
mtrogen droxlde 15 ppm. free sulfur 2 ppm

organcc acrds. sulfurous

MOLYBDENUM

Average corrosion rates (ipy)

conditions

Corrosion mediums

ALLOYS-CLIMAX

577

180

116

180

125

30

0.0002

xx

xx

0.0001

corr

CO.0008

0.0001

0.069cd

0.065cd

0.188cd

SOYBEAN
au. steam,
Iexpeller)

vapors

from

hot,

moist

au steam, vapors
soybean meal

horn

hot. morst,

au steam. vapors
soybean meal

from

Agriculture

165

33

xx

xx

<O.OOOld

<O.OOOld

Agriculture

156

28

xx

xx

<0.0091

<O.OoOl

Agriculture

175

28

xx

xx

<O.OOOld

<O OOOlad

steam. n-hexane
vapors, some orgamc distillates
from soybean extracted meal, no chlorrdes (half embedded m carbon, vapors mlet of absorption tower)

Chemical

80.
250

55

0.0002

0.0004

vapors and condensate


from soybean and flaxseed
flmseed) cookmg (vapors mlet of condenser)

Food

100.
400

145

iO.OOOlcd
<O.OOOl

<0.0001

fumes from soybean


Ipressure cooker)

Food

450.
500

145

<0.0001

<0.0001

morst.

and flaxseed

soybean

meal

raw extracted

toasted

(Imseed)

extracted

cooking

(continued)

578

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

01 crushed soybeans
condltloner
ventdator)

(expeller

and

bntd)

oz

fumes frotn the heatmg

MOLYBDENUM

Average corrosion rates Lipy)

g
=

llaxseed

ALLOYS-CLIMAX

food

230.
240

39

Food

32@
340

68

Power

220

244

430

129

291

e
-

$
.

,PL

,WL

7PE

304

316

317

,.o 0001

<0.0001

ALLOY
20

a25

SiARCH

wheat starch, water, sulfur dioxide and Dowicide.


pH 2 Z-3.8 (drum drier, vapors during 35 days)

0.0002c
0.0002c

<0.0001

STEAM

steam

wrtually

devold

of all

solutes

fdeaerating

<o 0001

--

heater)

steam, occaswnal
tracer of ammoma.
sodium
droxlde. sodium chlorate and sodium chloride

hy

<0.0001
s<0.0001
w<o 0001
0.0006

c IllI

92.2%
approximately,
hydrogen
sulhde
7.63%,
mercaptans
0.17%
(overhead hne from sour-waler
stripper)

Research

ZOO230

geothermal
steam cnndensate,
carbon
drogen sulhde. iamonia.
pH 5.25

hy

Power

240

55

<0.0001

<0.0001

geothermal
steam and water, carbon dioxide, hy
drogen sulftde. ammoma,
pH 6.5 (steam and water
separator)

Power

180

60

<0.0001

<0.0001

steam from Dallas city water, after zeollte soltenmg. sodturn chloride 292 ppm average. hydroxides
0.42 ppm, carbonates
10-36 ppm, bicarbonates
O-6

Chemical

225

30

xx

Agrkxlture

190

112

up dur-

Textde
tprmtingl

F <,212

33%.
small amounts of sodium chromate.
pH 3-6
during 44 hours. pH I1 approximately
durmg 35
hours. pti l-2 durmg 9 hours

Chemical

160

Steffen Mate,
total dry substance 70%, tsucrose
IO%, aminoacids
IO%, potassium salts remainder),
pH 6.5 (evaporator)

Sugar

178

Steffan Wale,
total dry substance 40%, (sucrose
lo%, aminoacids
10%. potassium salts remainder).
pH 8.5 (evaporator)

Food

Steffen
filtrate. total
10%. aminoacids
10%.
pH 8.5 (evaporator)

Sugar

Food

dioxide,

IllI

0.0004c

xx

0.0003

IllI

<0.0001

ppm
steam, fumes
cooler1

lrom

feedstufts

and

steam and water and other reagents


mg vat agmg of printed goods

molasses (tap of

plcked

dry substance 4%. (sucrose


potassium salts remainder),

carbonated
Steffcn
filtrate
sludge. total solids
23%. (calcium carboMts
87%. sucrose 4%. aminoacids 4%. mostly potassium
salts remainder).
pH
8.5 (Dorr thickener)

268

c.0 0001

xx

<0.0001

O.OOOllad <O.OOOl

0.07bd

0.219ad
P.217bd

127

<O.OOOla
<0.0001

176

127

0.0001

o.lxM2

214

111

xx

OOOOla

D.DDOl

125

59

xx

O.OOOla

O.DDDl

3.7

<D.DDDl

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

TWE

304
p-p-carbonated
Steffen
filtrate, total solids 3%, fsuclose 10%.
aminoacids
10%.
calcmm
carbonate
6%.
mostly potasswm
salts remainder).
pH 8.5
tOorr thickener)

Food

125

0.0001

sulfate.

am-

Chemical

260

liquors,

dls-

Sugar

160

133

muriatlc

acid

Sugar

180

m solution
in suspen-

SUgal

176

105

Invert sucrose syrup. acidified


wth
hydrochloric
acid to pH 2.5-3. and neutrahzed
with lime to

Sugar

140

116

Sugar

170

56

bone
sugar

Sogal

160

61

pH 7.6

Sugal

160

228

Research

363

Sugar

ZOO1100

CalSW

Sugar

185

105

and

Sugar

170

74

Sugar
Irefmingl

ZOO700

50

vacuum

Sugar

160

59

trough)

Sugar

145

Food

Food

91.90%

sucrose.
solids

60%
3%

bntd)

ALLOY

TPL

TPE

316

317

20

825

0.0059

0.0015

00013

0.0001

CANE

sugv.
hydtochlorlc
acid,
momurn chloride.
pH 0.5,

solved

MOLYBDENUM

Average corrosion rates (ipyl

Corrosion mediums

SUOAR.

579

A llo ys

sugar

ammomum
pressure

sugar

syrups
pH 3.5-S

60X,
syrup.

caustic

and

soda 3%,

concentrated
Steffen
bltrate.
60%.
solids lmostly potassium
slon 5% fcalandrla evaporator)

sohds
salts)

xx

xx

xx

XX

0.037c

<0.0001c

<0.0001c

0014

0.006

IllI

0 0006

nil

0 OQo3

0.0001

pH 5-6
cane-sugar

hquors

(bone char filtratlon)

14.0.5%
sugar, sweetwater
from washmg
char after use as a blter ald for refmed
hquor (evaporator
charge tank)
11%.
5%.

lowpurlty
sulfuric

(75%)

sweet

acid 0.5%.

sugar fdter media,


ity fdter vessel)

water,

pressure

superheated

Steffen
fdtrate.
solids in
cium carbonate
precipitated
pewon
(Kelly falter)

fmal

160 psi

steam,

pH 6 fgrav-

solution
2.5%,
IX,
sohds in

waste water from bonexhat


biters.
inorgamc lmpuritles,
pH 6.7-7.3
steam, destructively
pH 6-7 ILIter)

dtstdled

vapors lrom lowgrade


sugar
27 in. of mercury (condenser)
vapors

from

SUGAR.

hot

CORN,

sugar

liquor

otganics

dilute

at

masseculte.

lchar

filter

800

F,

0.2

<0.0001

<0.0001

xx

<0.0001

<0.0001

<0.0001

<o

0.018

0.0033

xx

0.001

0.002

<O.OOOl

0001

0.003

<0.0001

<0.0001

<O.OfJOl

<0.0001

<o 0001

xx

<0.0001

<O.OOOl

<0.0001

xx

xx

<0.0001

<0.0001

56

<0.0001

<O.OOOl

16

xx

xx

<0.0001

<0.0001

xx

108

xx

x-

<O.OOOl

c.0 0001

<O.OOOl

<0.0001

CONVERSION

dextrose solution formed by washing


with recirculated
water. pH initially
each day (sugar scrubber)
dextrose.

orgamc

hydrochloric

dextrose dust
7. fmally 3.7

acid, pH 1.33

corn syrup being concentrated


from
80% solids (vacuum evaporator)

51%

solids

to

Corn
Products

:F

78.
88

214
90.

190

0.016d

<O.OOOld

0.0002

<0.OOOld

<O.OOOl
c<0.Oc41

(continued)

580

Corrosion Resistant Materials Handbook

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

lest
conditions

mediums

COUI

Products
Irefining)
95.50% rpprortmately. second sugar liquor, sodium
chlorrde 4.2%. pll 4.2 Miial evaporator)

Sugar

66% appruimrtrly. second sugar char liquor, pH


4.5 hmder surlace of carbon in column)

Sugar

50% approstmalely, second sugar liquor, sodium


chiorrde 2.7%. hydrochlorrc acid to ptt 4.4.4.6

Sugar

45% approximately. glucose liquor from corn, pH


4.45 tfilter~

ALLOYS-CLIMAX

Average corrosion

:f

200

I35

33

xx

xx :

-xxx:

<0.OOOlad

<O.OOOlad

O.OOW

0.0003

0.0005
42

135

30

x-

Food

170

100

xx

22% approximately.
refined dextrose solution, activated carbon suspension. sulfuric acid, pH 4

Corn
Products

145

52

99.9% starch. hydrochloric acid tO*Be remainder

Chemical

425

15

I,

0.0015a

0.0005a

93.9% starch, lO*Be hydrochloric acid 3.11%.


glacnl acetic acid 3.05%

Chemical

140

15

0.0003a

0.0002

aerated cornstarch lermentation liquor, pH >3.2.


pressure IS-18 psi

Food

77.
96

starch slurry, hydrochloric acid to 0.02N. specific


gravity 1.075. pH 1.8 ldextrose converter, vapors.
hqurdl

Corn
Products
(relining)

275

134.
217

starch slurry, sulfuric acid to O.O4N, chlorides


0.0022%. pH 1.62

Corn
Products

120

57

xx

xx

starch wash filtrates, sullur dioxide. pH 3.5

Corn
Preducts
beliiing~

11

125

44

xx

xx

Food

jF

60.
212

79

204

--

i
:
:

hontd)

rates (ipy)

70

ltashed steam, hydrochloric acid, sulfur dioxide,


various volatile decomposilton products from acid
hydrolysis of corn march, pH of liquor 1.5 (vapor
line)

MOLYBDENUM

.F

xx

xx

0.0002bd

<0.0001

xx

0.0003cd

<0.000I
w<0.0001

<0.0001
<0.0001

xx

xx :

<O.OOOl

<0.0001

<O.OOOl

<O.cml
w<0.0001

<0.0001

<O.MUtld
0.0006d

0.0002
0.0004d

0.0001
w<0.0001

w<o.O001

<0.0001

O.OOld

<0.0001

<O.OOOlcd

<O.OOOl

<0.0001

<0.0001

0.66

0.07

0.12

0.095

0.046

0.036

0.53

0.7

SULFONATCO COYfOUNOS
81.3%

99%
filly;

benzene

sullonic acid, sulfurs acid 3.8%

benzene sullonic acid, sulfuric acid 4%


sulfuric acid 66*Bi. benzene initially

: Chemical

86.1%benzene sulfonic acid. sulluric acid Xl%,


some water
9949% benzene sullonic acid, sulluric acid JO50%. benzene m~disullonic acid 0.15%. sullur
dioxide m vapors

:
:

50% od-soluble sulionic acid, solvent naphtha


45%. water 5%. sulluric acid lrace (bottom of still)
59% oilsoluble sullonic acid, solvent naphtha
45%. water 5%, sulfuric acid trace (vapors1

Chemical

jf

329

15

Chemical

:F

264

11

Chemical

98.
275

31

xx

xx

60.
250

3.8

1.451

0.93

0.346

0.316

60.
250

3.0

0.061

0.06

0.063

0.059

Chemical
Idistillation)

Chemical
(distillation)

x:

0.0017d

0.0011

(continued)

Ferrous Alloys

TABLE

4.13:

VARIOUS

STAINLESS

Corrosion mediums

STEELS

AND

HIGH

NICKEL

Test
conditions

ALLOYS-CLIMAX

MOLYBDENUM

581

bmtd)

Average corrosion rates (ipy)

$f

liquor saturated wth organic sutlonic acids, sodmm


sullate and sulfur dmxide. hydrochloric acid 2%.
some sulfuric acid. acetic acid trace, pH 1.5-2
(vacuum biter. alternately Immersed)

Chemical

98

Ilquor saturated with orgamc sullonic acids, sodturn


sullate and sulfur dioxide, hydrochloric acid 2%.
some sutlur~c acad. acetic acid trace, pH 15-2
(vacuum filter)

Chemccal

78.
98

80

lwE

304
p---p

1WE

7WE

316

317

corr

0.0002a

0.002

corr

0.0001

0.0001

20

ALLOY
825

66% ap~rextmataly dodecylbenzen sulfonic acid,


spent sulluric acid 33% approximately, sulfur dioxide and trioxide (bottom of sulfonator)

:F

155

22

xx

0.0714

D.055d

O&W

0.0102

0.M

66% qprnxtwlety
dodecylbenzene sullonic acid.
spent sulfuric acid 33% approximately, sulfur dioxide and trioxide kullonator, vapors1

-F

155

22

xx

0.0436

0.04d

0.03d

0.0036

0.007

33% appuiaalely
dodacylbenzene sulfonic acid,
hexane 64%. spent sulfuric acid 2.3% tbottom of
teotd

IF

80

22

X x :

0.0003

0.0009

0.0011

O.OOOE

0.0018

x :

<O.OOOl

33% a##rox*ataly dodecylbenzene sullonic acid,


hexane 64%, spent sulluric acid 2.3% (vapors)

Petroleum

80

22

dodecylknzeoe sullonic acid, from reaction of 20%


oleum I.32 parts and dodecylbenzene I part

Detergent

125

16

xx

D.Old
D.WJd

D.DD23d

0.0009

dodecylbenzene sulfonic acid, from reactiowol 20%


oleum 1.32 parts and dodecylbenzene 1 part, water
0.139 parts

Detergent

;1

125

16

xx j

O.WlSd

O.OD21d

O.Wll

dodecytbenzen sutfonate paste, neutralized with


mixture of alkali and alkaline metal hydroxidas

Detergent

:L

125

16

xx

sullonated kerosene. settling out of sulfuric acid


05%

Detergent

135

111

xx

O.OD5d

0.004

sutionated kerosene. in Jullurii acid 85% which


during aashmg ranges from 85% to neutral

Detergent

60
150

111

xx

xx

0.W2ad

O.WJad

naphthatern sullonic acid, solids 50%. pH 1

Chemical

122

xx

0.0395

0.0107

104.
284

100

xx

>O.D56c

>o.O61c

naphthalene sullonic acid, phenol condensates, pH


1-7 ibottom of tank1

3.3

30% phenol sutldnic acid, from reaction of phenol


and 98% sulfuric acid I248 F during 12 hours).
formaldehyde and water added, borax and ammonia
to pH 3

Chemical

158

40

22% p-chlorobenzene sulfonic acid, sulluric acid


74%. DOT 4%

Chemical

65

11

--

chlorosullooic acid, alkyl aryl organic. hydrochloric


acid. sullur dioxide

Chemical

140

20X, pyriime sulfonic acid, sulfuric acid I-S%.


calcium srllate, mercury sullate suspension trace
talternataty immersed)

Chemical

75

1510% calcium pyridine sutlonate. pyridine I%


approximately, calcium hydroxide 0.1%. pH 8 approximately Ialternately immerse@

Chemical

R.T.

calcium pyridme sullonate slurry, sulfuric acid


I?I%, small amount of mercury sullate probably in
mercurnc form (vacuum lilterl

Chemical

100.
150

4.2

37

4.7

16

nil

<0.0001

<O.OWl

<D.DDOl

nil

0.039c
0.073c

0.142

0.136

0.0003

0.001

0.002

XX

0.0087

O.DO8

0.0068

xx

<D.ODOl

<D.DODl

xx

0.0012

xx

<O.OOOl

<o.OOD1

0.013

CD.0084

0.0068

0.0014

<0.0001

(continued)

582

TABLE

Corrosion Resistant Materials Handbook


4.13: VARIOUS

Corrosion

STAINLESS

mediums

STEELS

AND

HIGH

NICKEL

Test
conditions

ALLOYS-CLIMAX

Average corrosion

---

MOLYBDENUM

rates (ipy)

TIPS

TIPS

TIPE

304

316

317

0.113ad

0.121

0.001

0.001

ALLOY
--

20

aconrlrc acrd. sodrum hydroxrde. solforrc acid, sodium m-brsulfrte (half Immersed)

Chemrcal

188.
195

sulfonated turpentme. from reactron of sulfurrc


actd 60% and turpentine in molar ratro 211

Chemical

32.
42

sulfonated alkylaled aromatrcs. sulfuric acid 96%


at 145.170 F, and 63% at 195.222 f

Chemical

145.
222

14

xx

0.21

sullonated alkylated aromatrcs. sulfurrc acrd 98%


at 145-170 f, and 63% at 195.222 F (vapors)

Chemrcal

145.
222

14

xx

0.0017

0.0013

sullonated waxes. sodrum chloride, water solutton,


pH 5-a

Rayon

132

162

xx

O.OOOlcd
O.OOOlad

0.0001

unspecrfred green sulfan~ acrds. unspecrhed car.


boxylrc acrds, medwm vrscosrty lube or1 stock, in
sulfuric acrd 3% solutron, neutralrzed wrth sodium
hydroxrde to sodum hydroxtde <6% concentratron
lb&w
steam cart, bottom of tank)

Petroleum

150.

60

0.045c

0.027~

0.0027

lrqurd sulfur. selenium

Metal
fdistrllation)

a50

0015

0.008

0.028

lrqurd sulfur. rron and alumrnrum chlorides 600 ppm


approxrmately. hydrochforrc acrd trace possible
lfrlterl

Chemical

275

a3

XI

0 0037cd
0.0035cd

0.0024

0.0033

co.004

ltqurd sulfur. small amounts of sulfurrc acrd and


won sulfate fair-sulfur interface1

Mlnlng

280

13

xx

xx

0.015
0015

0.018

0.017

0.015

lrquid sulfur. traces of morsture and hydrochloric


acid

Chemical

302

105

0.0048Cd

0.0033cd

liqurd sulfur. arr. small amounts of water, pH


1.5-3.5

Mrnrng

305

11

xx

xx

0.037
0.035

0.02la

lrqurd sulfur. water saturated. pressure 25 psig

Chemical

248

o.oaac

0.05ac

lrqurd sulfur. morsture during 10 days, and water


durmg 51 days

Mming
fsulfur)

330

61

xx

xx

0.005cd

lrqurd sulfur, nitrogen 55%. water vapor 27%, carbon droxide 9%, hydrogen sulfide 4%. sulfur di.
oxide 2% of gas (bottom of tower packmg support.
scrubbing of sulfur vapors)

Chemical

290

135

xx

0.0003cd

0.0001

sulfur. sulfurrc acrd. hydrogen sulhde, sulfur droxrde, sutfurous acrd trace, water vapor

Chemrcal

73.
284

ai

XX

0.004acd

O.OOlgbd

sulfur (vapors)

Metal
ldistillatmn)

a50

0.02

0.023

sulfur Ivapors)

Chemical

1060

54

xx

0.027

0.0311

sulfur. stagnant (vapors)

Research

1020

27

0.03
0.032

0.0022

sulfur. stagnant (vapors)

Research

1100

36

0.031
0.051

sulfur, stagnant (vapors)

Research

1250

28

0.047
0.014

iao

7.8

Isulfur)

a.5 -

7.8 -

bntd)

0.001

0005

0.122

0.048

0.0013

0.001

1125

0.019bd

0.0015bd

0.02

0.084

(continued)

Ferrous A llo ys

TABLE 4.13:

Corrosion

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

mediums

ALLOYS-CLIMAX

Average corrosion

stagnant Ivapors)

Research

1400

28

sulfur, traces of moisture and hydrochloric acid


Ivapors)

Chemical

305

105

6% sulfur, m acrd gates. nitrogen 55%. water


vapor 16%, carbon dioxide 15%, hydrogen sulfide
6%. sulfur dioxide 3%

Chemical

500.
600

163

3% sullur vapors, in acid gases, mtrogen 55%.


water vapor 27%. carbon droxide 9%, hydrogen
sulfide 4%. sulfur dioxide 2% [bottom of catalyst
support grad in converter)

Chemical

a00

135

2.5% sulfur vapors. in acid gases, nitrogen 59%.


water vapor 22%, carbon dioxide 15%. hydrogen

Chemical

500

276

sulfide

1%.

sulfur

dioxide

Rubber

290

hot water

Rubber

212

69

sulfur compounds in reduced crude vapors. pressure


75.mm mercury (tar pocket, vacuum tower)

Petroleum

750

369

96.3%.
carbon
chlorrde 0 01%

Chemical
frecbficaIlOrd

280

133

Chemical
frr;;ifica.

257

133

Chemical

60

Chemical

m steam
in water)

fvulcanization

sulfur compounds
leached
and steam or steam alone

SULFUR
60%.

horn

rubber,

tetrachlorrde
0.13%,
iron as ferrrc
lreboder for bubble cap column)

96% approrinately
cap column, vapors)

(below

bottom

plate

20%.

water

of bubble

vapor saturated

16X,
small amount of sulfur trioxide
lsulfur burner, discharge linof
morsture.

small

amount

10% approrimrtaly,
saturated
hquor contains sulfurrc acid
scrubber)

water 3090%.

and moisture

of sulfur

trioxide

with water, recycle


0.3.0.75%
(Peabody

10% approxknately,
saturated
wth
hquor contains sulfuric acid 0.725%
167X,

ALLOY

lPI

T"PS

TIPS

316

317

20

825

0.11
0.18

0.12

0.004cd

0.0023cd

0.0002

0.0901

0.002

0.002

0.0003

0.0002

0.9901

xx

<0.0001

0.0001

<O.OOOl
<O.OOOl

4.5

--

1<0.0001

<0.0001

<0.0601

xx

0.0002

LO.0601

xx

0.00078

0.0004

xx

0.00035

0.00035

94

xx

0.0001
0.00025

0.00025

SW
700

90

xx

xx

Pulp and
Paper

100

37

Sulfuric
Acid

85.
95

20

xx

xx

Sulfuric
Acid

125.
135

20

xx

XI

DlOXlOL

mtrogen

17.13%.
bower)

rates (iPY)

0.5%

autoclave,

sulfur vapors
half Immersed

kontd)

304

---sulfur,

MOLYBDENUM

583

sulfur trioxide

water,

recycle

Chemical

57%

180.

<O.OOOla
0.0003a

4.5

xx

200
5X,

ruckel-converter

5%

saturated

ps

fumes tram calcining

process,

oxy9en

11%. carbon droxida 8%. sulfur trioxide mist 1 cu 11

Metal

400

39

Metal

40.
130

34

0.0002

xx

<O.OOOl

0.0001

0.0001

0.0001

0.0001

<o 0901

0.002a
0.254a

0.052

0.006

0.003

0.002

0.02
0.037

0.021
LO 041

0.0056ad
O.OOO&
xx

<0.0901

0.02
0.0041
0.000&d

0.0046a
0.0007
<0.0001

<o 0001

<0.0001
c0.0001

(continued)

584

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELSAND

HIGH NICKEL

Test

----

5% rpproximatcl~.
air,

MOLYBDENUM

(=ntdI

Average corrosion rates (ipy)

conditions

Corrosion mediums

ALLOYS-CLIMAX

moisture 6%. sulfur tri-

425

68

11rE

ll?E

31s

317

_.

0.002

0.002

0.0042b
0.0015cd

0.0007

20

ALLOY
825

oxide 1%

Mining

200.
500

79

xx

xx

42%. water-vapor s&waled gases

Mining

170.
550

160

2.1.5X. oxygen and nitrogen remJinder

Ymiq

300
500

103

xx

0.2SX. moisturs

Food

31

62

Miniw

.F

185

13

xx

90

15

<5%.
125f

oxygen 15%. nitrogen remamder. dew pomt

sulfur.dioxi&-containin(

#Jr fspny tower1

sullur dioxide, sulfuric-Jcid mist. seknious acid,


nitrgan oxides from decompositkm of sodium niwe, wetrr vepor. ~Jses of wryin composition
fCottnll exit pxsl

Wrl

sulfur dioxide. sulfuric.rcid mist. selanious rid.


nitrogen oxides from decomposition of sodium ni.
We. water vepor, 2lras of verging composition
(Coftnll exit gases.1

Chemical

sulfur dffxide. moisture. urban diixide. lwtic acid.


or#Jnic-acid vapors

Corn

Products

100

90

100

a.8

<O.OOOl

<O.OOOl

<0.0001

<O.OOOla
o.axl2r

<O.OOUcd

<0.0001

<O.oOOl

<O.OOOl

xx

0.2

0.184

0.161

XI

o.OfJscd

0.035cd

0.032bd

II

0.15bd

O.W?bd

0.009bd

0.02lc

0.0002c
10.0001c

II

200
400

271

xx

0.094
0.035

0.051

<0.0001

<0.0001

O.Olbd

frefiningl
sulfur diosidr. sulfur mist smell mounts of orygen.
ukr vepor Jnd sulfuric rid Kottrefl prrcipitalor)

Mining

no450

suffur dioside. sulfur flowers added to burnin coke,


suffur trioside. urbo~ monoxide Jnd dioxide. uncerlrfn concentrations. possibly sulfuric and sulfurous
ecids

Brewing
(beer1

M)140

277

xx

xx

O.WMd
0.0003d

0.0001

~e,diixide.

RJilroed

R.T.

365.
620

xx

xx

o.mlJ

O.ooolJ

so90

55

xx

RISe*rCh

60

XI

0.013

nil

Research

100

0.06

0.0042

nil

104

xx

0.022

nil

0.15

0.059

0.064

0.138

0.0625

0.26

0.177

0.336

0.551

Ol.mRlC

trioside. cJrbon dioxide (locomotive

0.047

AClD

olcum (25%)

RosJarch

:L

Reserrch

150

0.08 x

Research

175

0.08 x

200

0.08

Reserrch

.L

Plastic

49
77

102

--;

(OK

bserrch

104

XI

wx

Research

60

es--j

0.0007

<O.aml

nil

0.017

nil

o.c#2

nil

0.0002

II

<O.oool

(continued)

585

Ferrous Alloys

TABLE 4.13:

VARIOUS

Corrosion mediums

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

ALLOYS-CLIMAX

MOLYBDENUM

Average corrosion rates (ipy)

l,E

rm

304

316

3;;

0.736

0.282

0.579

0.022

nil

00%

Research

100

0.08 x

10%

Research

104

IO%

Research

150

0.08 x -

1.26

0.572

1.12

(0%

Research

175

0.08 x -

2.1

1.2

3.35

10%

Research

200

0.08 x -

7.05

4.0

6.05

77.6%

Research

90

0.0001

0.0007

70%

Research

60

xx -

0.039

0.05

70%

Research

104

xx

0.0875

0.54

96%

Research

90

..

0.204

0.144

99%

Research

60

xx

0.306

0.43

90%

Research

104

xx

0.346

1.06

99%

Research

60

xx

0.15

0.258

90%

Research

90

,..

59%

Research

104

xx

4.4

6.5

40%

Research

60

xx

0.048

0.18

40%

Research

100

0.09

0.85

0.825

49%

Research

104

xx

0.9

6.5

40%

Research

150

0.09

13.0

6.4

R.T.

SlrlF

Xld

hmtd)

39%

xx

--..:

0.217

0.6

0.072

Research

60

xx

0.035

0.065

39%

Research

104

xx

0.474

0.665

30%

Metal
tcleaning)

130

62

xx

xx

O.wOl

<0.0003

26%

Research

60

xx

0053

25%

Research

104

xx

0.41

0.47

R.I.

0.13

0.009

20%

2.64

O.LMO4

nil

0.44

IllI

1.01

0.0745

xx

0.437

0.11

0.U

0.027

5.75

0.191

0.199

10.1

0.94

0.576

Research

60

20%

Research

100

0.06

20%

Research

104

20%

""""

104

20%

Research

150

0.09

29%

Research

175

0.09

0.22

xx

20%

ALLOY
125

cm

39%

20

0.024

(continued)

Corrosion Resistant Materials Handbook

586

TABLE 4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

(contd)

Average corrosion rates (ipy)

lY?E

Slrrlc

acod

20%

Research

20% approximalaly

Chemical

15%

200

304

TWE

311
1.06

0.08 x

21.0

1.77

F <IO4

8.5

xx

0.0002
0.0238
LO.OOu

0.0001

Research

60

xx

0.03

15%

Coal Byproduct

59.
86

212

xx

0.024~

0.0014

15%

Research

104

xx

0.292

nil

12% approximately

Metal
lplckling)

185.
195

14

xx

xx

0.0126

0.0027

R.T.

0.065

nil

ml

10%
10%

Research

60

10%

Research

100

0.08

10%

Research

104

104

1
1

10%

0.0175

0.39

0.0096

0.193

nit

0.17

0.0036

illI

0.09

Research

140

10%

Metal
lpicklmg)

120.
160

10%

Research

150

0.08

I83

0081

0.078

10%

Research

175

0.08

4.5

0.15

0.197

176

1
0.08 I

23

10%

Research

200

10%

Research

8.P.

10% approsimataly

Sugar

68.
152

97

Research

176

9.
10

Metal
tpickling)

130

47

8%
5%

I
104

5%

Textile

R.T.

5%

Research

60

5%

Textile

80

106

5%

Research

loo

0.08

104

104

5%
5x

Research

L nil

llll

ml

0013

0.18
-

7.0

--

R.T.

825

0.0012

10%

10%

20

niL

xx

xx -

ALLOY

TPE

316
-P-P

16.5

.,

0.0001

0.460

0.0001

0.0108
0.0504

0.0014

II -

0.013

nil

nil

nil

0.222

nil

0.058

nil

0.0875

nil

xx

0.0252

co.0059

<0.0001

<O.OOOl

<O.OOOl
0.025

nil

0.55

0.86

<O.OLlOl'
<0.ooo1
0.0007

0.047
xx

0.207

nil

(continued)

Ferrous

TABLE

4.13:

VARIOUS

Corrosion mediums

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

ALLOYS-CLIMAX

MOLYBDENUM

TWE

TWE

1PE

304

316

311

5%

Research

150

0.08 x

1.1

0.036

0.0038

5%

Research

175

0.08

1.63

0.74

0 09

5%

Research

2w

0.08 x

5.4

0 14

0.23

3%

Research

100

0.08

0.067

nil

nll

3%

Research

150

0.08 x

0.388

0.0082

nil

3%

Research

175

0.08

0.528

0.04

0 058

3%

Research

200

008

13

0 094

0.12

2.5%

R.T.

0.031

nil

2.5%

104

0.036

nil

2.5%

140

0.16

0.0036

2.5%

176

nil

R.T.

0.025

nil

100

0.0575

nil

1%

104

0 028

nrl

1%

140

0.074

ntl

1%
1%

Research

1%

Research

150

0.22

nil

1%

Research

175

0.38

nil

Research

200

0.79

nil

1%

Research

B.P.

0.3161

0.0489

0.5%

Research

100

0.037

nil

.,

104

0.025

nil

80
110

0.021
0.0056

0.5%
0.5%

Synthetic
Rubber

0.5%

nil

140

nil

O.Wl1

0.047

nil

0.5%

Research

150

0.08

0.0225

nil

nil

0.5%

Research

175

0.08

0.445

nil

nil

176

200

0.08

B.P.

0.5%
0.5%
0.5%

Research

ALLOY
825

0 14

8.P.

1%

20

nil

176

1%
1%

(contd)

0.036
nil

Pulp and
Paper

587

Average corrosion rates (ipy)

su,,ur,c ace*

2% apprnximataly

Alloys

nil
x

0.79

O.W38

nil

0.054

(continued)

588
TABLE

Corrosion Resistant Materials Handbook


4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Corrosion mediums

ALLOYS-CLIMAX

bntd)

Average corrosion rates (ipy)

1lPE

---slnc

MOLWDENUM

WPE

TPE

304

316

317

0.036

nil

20

ALLOY
825

acod

0.25%

140

0.25%

176

0.25%

9.P

,.

nil
0.0927

83.9% oleum 118%1. pyrrdrne 16 1%

Chemrcal

125.
152

0.0013

0.0016

66% ohm (65%l, pyrrdme 33% (bottom 01 sullonatron kettle)

Chemical

329.
347

0.123
0.111

0.07

oleum 140%). nrtrrc acrd 4%

Chemical

110

0.00018

O.OOCl

0ooo12

vapors over oleum (20%) and pyridine

Chemical

125.
152

0.0001

O.Owl

0.wo1

9999%. ferrrc sulfate, ferric chloride, hydrochloricacid saturated (pipe)

Chemical

75.
a2

167

xx

O.ooO27

0.ooo15

99%. rodrum naphthanate Z-3.86

Petre
chemical

2:;

90

xx

0.0185d
0.017cd

0.0136

99.90% sulfuric-acid sludge, pressure 15-18 psi


Isettling drum)

Petroleum

160

25

corr*

corr

930%. aluminium sulfate 3090%. hydrated aluminum oxide (underside 01 tank cover, vapors and
splash)

Chemical

4
270

165

99% acetic anhydride 9.1%. water remainder

Petroleum

65
105

42

99% acetic anhydride 9.1%. water remainder (vapars)

Petroleum

65.
105

42

XI

9920%.

Soap and
Fatty Acid

150.
2M)

110

_.

xx

19%. nitrogen oxides

Chemical

95

73

78% hydrogen peroxrde 3.5%, VariOUs iron, manganese, chromium and nickel salts

5oaP

100.
130

69%. reclaimed sulfuric acid, sodium sulfate 49


50 g/l, nickel 3-S (II. arsenic l-l.5 g/l. copper

Metal

100

33

Chemical

104
167

113

61%. mmor hydrocarbon contaminants

77.
122

113

63.41%, propylene

2:

tallow fat

II0

0.0909

<0.9001

0.0014

c<0.0001

co.053

C nil

omJ15

0.9959d

<0.9901

0.0002

O.WWd

<0.0001

c0.09011

<O.OWl

c<0.wo1

<0.0001

0.072

0.012

nil

nil

C nil

xx

0.0947

0.0082

0.14

o.ooo5

O.WB

IX

xx

0.075c

0.08c

0.0121

0.0059

II

xx

0.015

0.0015

O.Wlb

O.Wl4

63

xx

xx

0.099

0.099

0.033

0.0002

0.0002

O.oorll

xx

corr

0.014

0.0022

0.005

trace

97X, propane, propylene partially combined with


the acid

99% sulfurrc-acrd emulsion, manganese dioxide precioitated 40%

.Pharma.
ceutrcal

145

12

xx

6920%. copper 45 g/l.


11.7 111

Metal
lelectrorcliningt

B.P.

101

xx

nickel 20 g/l,

arsenic

0.01

0.0094

0.0094

0.0002

(continued)

Ferrous Alloys
TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

W?E

0.007a

Chemical

56%
sulfurrc~actd
sludge from light-oil
washing,
coal tar, saturated
and unsaturated
hydrocarbons,
sulfur trroxrde fumes. steam

Coal By
product

285

07

56%
sulfuric-acid
sludge from light-oil
washrng.
coal tar. saturated
and unsaturated
hydrocarbons,
sulfur trroxrde fumes, steam

Coal By
product

255

56%
sulfurrcacrd
sludge from light-or1 washrng,
coal tar. saturated
and unsaturated
hydrocarbons,
sulfur trroxide fumes, steam

Coal Byproduct

256.
285

77

56%
sulfuric-acid
sludge from Irght-oil washing,
coal tar. saturated
and unsaturated
hydrocarbons,
sulfur trroxide fumes, steam

Coal Byproduct

256.
285

50%.

Petroleum

200.
250

Soap and
Fatty Acid

selenrous

caustic

505%.

acid 80 g/l,

soda 20S

sodwm

sulfate

satu-

fneutralizer)

fats and orIs flop of tank)

45%, sodrum brchromate


chromrc sulfate 3%

0%.

sodwn

sulfate

g%,

0.06

0.011

0 006~

0.003c

0.0013c

0.15

0.08

0.033

48

0.065cd

0.02cd

160.
200

40

0.0056

0.0047

105

0 05

0041

0.0012
0.0004

0.001

0.121

0.059c

35.15%

sulfurrc-acid

sludge,

tar, oil

Petroleum

120.
200

19

35-15X
and or1

sulfurrc.acrd

sludge,

large

Petroleum

120.
200

29

35.10%.

ammoma,

Chemical

40.
110

53

Research

212

Chemrcal

175.
202

Metal

170.
180

Chemical

RT.
212

Arrcraft

150.
160

Metal

30%, clay
30%
approximately,
fonatorl

sodrum-sulfate

3920%.
copper sulfate 0.5.3.5%.
mud from electrolytic
copper-refmmg

25%.
phosphorrc acrd
hydrofluorrc acrd 0.3%.
25.22%,

fsul-

abrasrve anode
process

15%.
sodium sulfate
rare-earth fluorrdes

sodrum drchromate

24%.
tdanrum
ferrous sulfate
gravtty 1.485

solution

3%,

56%

droxrde as trtanrum
sulfate
12%.
9.6%.
ldanrum
13) 2 g/l, specific

22.16%,
copper sulfate 3545
g/l. nickel sulfate
20-30 g/l, chlorrdes as sodrum chloride 0.5 g/I

20%.

sodnon drchromate

4%

(stripping

tank)

Metal

>6
51

<0.0001

0.0028

0.0027

0.0034

0 045

co.017

0.482

co.157

,.

<0.0001

0.0001

0.0008

0 34

0.39

0.46

0.131

0.096

0.072

corr

625

<0.0001

0.2

RT

oxrde

hxmtd)

ALLOY
20

0.0903

ndrous

?WE

317

0.002

Chemical

of tar

TWE

316

0.005

35.6%.
phosphorrc acrd 13.3%.
aluminum and ferrrc oxrdes 3.4%.
hydrofluorrc
acid 1.396, copper
0.3%.
rare-earth
oxide
0.02%.
thorrum
oxide
0 01% (transport truck)

volumes

MOLYBDENUM

Average corrosion rates (ipy)

304
-P--P
56.5%.
rated

589

coo1

corr

0 021cr

0.01

66.
70

0.03

0.0024

130.
150

<0.0001

<0.0001
L<O.OCOl

150.

0.014

0.023

0.013

0.011

0.005

0.009

<O.OOOl

<0.0001

0.0064

0.019

(continued)

Corrosion Resistant Materials Handbook

590

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

aced

Metal
(pickling)

140

25

Metal
Ipickling)

170.
180

xx

TWE

TPl

"20"

304

316
P--P

317

0.188

0.014
wo.013

0.015

CO.0056

0.02la

0.0081

2O%.lerrous
and ferric
bottom of sump tank)

lcontmuous
plcklerl

won 2% tcontmuous

plckler,

<0.0001

chromic

acid 3%

(bottom

of tank1

Metal

180

86

0.0091
S0.03la
10.012

0.016
so.04
10.027a

18.5%.

chtomlc

acld 3%

(bottom

of tank)

Metal

180.
185

23

0.0051
SO.024

o.Oct7
so.014

Metal
(pickling)

170.
190

xx

0.53

0.21

0 17

0.11
CO.096

Metal
(pickling)

190.
210

19

xx

0.0004

0.0003

0.0004

0.0006
c0.0003

Electrow

160.
200

30

0.003a
0.002d

0.0015

0.0008

15.6.8.5X,
selemous acid 40-100 g/l. some selemum suspens!on. small amounts of sulfurous actd

Research

70.
80

0 0324~

0.0004d

C0.0003d

15%.

Metal

R.1:
1300

Metal
tcleanmg)

B.P.

720

xx

Petroleum

150.
200

22

chloride

3%

18%. tron 1% approximately,


added lcontmuous picklerl

17.5X,

chromic

anneal

15.10%.

67 mhlbltor

and spray pickle cycle (conveyor

copper

racks)

sulfate

manganese

10%. manganese
ganic acid

sludge.

large

amounts

of

sullate,

mangamc

oude.

water

Chemical

80.
210

30

dloxlde

9-10

some

perman-

Metal
(plating)

131.
208

76

Chemical
(filtration1

65.
70

Metal
(plating)

95.
122

Metal
(pIckhog)

90

Metal

IOO200

162

10%.

manganous

lo%,
cell)

manganese-dioxide

10%.

Rodme

acid 3.5%

15.10%
sulfuric-acid
sludge 011

13%

825

<O.OOOl

18.5%.

sodwm

ALLOY

mlxturel

20%. copper sullate


<5%

18%,

(amtd)

Average corrosion rates (ipy)

TWE

Slf,lC

MOLYBDENUM

actd 8%.

copper sulfate

slurry

sludge

2%

g/l.

(electrolytic

(spray pickling

zinc

machmel

3.8

60

7.3

xx

xx

0.007

0 005

0.0001
S corr
1 NG

0.00014

0.0001

xx

0.095
0 077

0.072

xx

0 034

0.031

0.0045

0 0047

0.012
10.014

<0.0001

<o

0.0053

0.005

0.004

0.0087

0.0069

0.0051

xx

xx

<0.0001
<O OOOla

<0.0001

xx

<0.0001
SNC

<o

0001
SNG

0.0001
SNG

copper

sulfate

0.25%

10.5%.

sodum

sulfate

25%,

hydrogen

sulbde

trace

Petroleum

IOO140

42

0 053cd

0 025cd

0 004cd

10.5%.

sodwm

sullate

25%.

hydrogen

sulfide

trace

Petroleum

100.
140

23

0.062cd

0.018cd

0.0033cd

62

0.015

0 007

Chemical

CO.046

0 03

10.5%.

9%. water 85 5%. sodium sulfate 3%. hydrofluonc


acid 1%. orthosdwc
acid 1%. sodwm fluosdicate
05%

nil d

0001

0.0083

0.0078

0.077

0.0038
SO.072

0.001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Corrosion mediums

Average corrosion

.
constituent.

ferroclean

8-7.5%.
alummum
sulfate
small amounts ot calcrum

8.7%.

sodrum nrlrate

prcklmg

3%. few
sulfate IX,
and magnewm
sulfates

0 8-O 3 oz.gal

5.5%. roasterxrubber
ous acrd 83.7 g/l.
0.8 g/l

solutron,
tellurum

5%.

zcrconyt sulfate

0.3-0.4

5%.

z~rconyl sulfate

3.4%

5%,

Acrtrol

5%.

rodrum drchromate

selenium as setew
as telluroos
acid

Metal

Chemrcal

200
210

Metal
lplcklmgl

155.
165

13

Pulp and
Paper

78

Chemrcat

lb/gal

inhibrtor

1.11 lb/gal

copper 0.5-0.56

or/gal

5.4%
sulfurrc-acrd
solutron settled from the acid
warhmg of oleic acid, during settling periods only
(bottom of lank1
large amounts

4.1%.
1015%

rates (ipy)

1wc

,lPE

TWL

304

316

317

ALLOY
20

825

ot sadwm

arnmonwrn

sulfate

20.25%.

sodium

sulfate

15

xx

xx

0 025

0 006a

xx

0.036d
0 053d

0 0001
00031

90

xx

< 00001

0 0007

<o 0001

150.
160

30

0 08cd

0 025cd

0 02cd

0 002cd

80.

15

xx

0.001

o.C.31

nit

90

I5

xx

IllI

0.001

0.001

rlll

57

xx

0 077

0.0048

0.0008

0.0003d

xx

0.0003d

xx

0 00016a

xx

0.0318cd

100

Metal

70.
85

30

Metal
lpticklmg)

175.
185

30

Chemical

180.
212

70.
82

30

Chemical

95.
104

970

chlotrde

rlll

0 0004
0 0005

xx

0.0001

Metal
(pickling)

150

2.7

0.0057c

0.0011

3%.

Cuprodme

powder

5 ozlgal

Metal
tprcklingl

150

2.7

xx

xx

0.071c

0.0021c

Chemrcal

200.
250

11

0.0725.

0 02

120.
128

30

0.0072ad

0.0059a

120.
180

259

430.
470

sodrum chloride

O.l%,

<I%,

ferrous

0.36%,
liquor
tbottom

vessel,

(tower)

saturated

1.61.0.027%.
chlorrdes
0.015%.
pH 1.1-8.1

ipressure

alcohols

and
hquid

as

lerrrc

chlorme

sulfates.

ion

pH

0.001.

1.8-4.5

interface)

some chlorides
from acid
used to dilute concentrated

brine mother
sulfuric
acid

Chemrcal

Paint and
Varnish
tcrystalliza.
tion)

Synthetic
Robber

70.

110

II

xx

xx

co 0005

0.0246ad

5 ozlgal

sulfate

0001

<O.OOOl

powder

copper

c<o

O.OOOld

Cuprodme

2.5%.

111
0 0022

<O.OOOld

3%.

2%.

(amtd)

Metal
(cleaning)

Ipickling)

4%.

MOLYBDENUM

591

ac,Ll mlXtre*

Su,rlC

8%.
oxrdrzmg
solution

5%.

ALLOYS-CLIMAX

Alloys

0.0001

0.0001
c0.0001

0.0001

<0.0001
0.0001

00188

0.0001

<0.0001
0.0002

<0.0001
0.0001

0.0163

0.0427

0.0301

<o.o001

0.0088d
0.0040d

0.026

<O.OOOld

of tank)

(continued)

592

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

ac,cl

mlxturer

0.20.02%.
Retrol
of diamylene.
amyl
chlorides (vapors1

clay, amylene. phenol, traces


chloride,
ferrrc and ferrous

bntd)

Average corrosion rates (ipy)

TYPE

SlWK

MOLyBDENuM

TWE

304

316

TWE

311

20

ALLOY
825

Chemical

125
305

52

xx

O.Olcdr

0.0055c

0.1%.
sulfur droxide 0.04X,
varying amounts of
carbon, pff 2 iPeabody scrubber, bottom tray strip
per section)

Chemical

164.
177

58

xx

XX

0.0023~

<O.OOOld

0.1%
approximately,
salts, pH 2-3 5

Chemical

170.
185

14

XX

0.147c

Petrochemical

210

57

<O.OOOlad

<0.OOOlad

<0.0001

0.0001

<O.OOOl

Petrochemical

130.
150

57

<O.O001d

<O.OOOld

<O.oool

0.0003

<O.oool

sulfurrc acrd concentrated


to very drlute. hydrochlorrc acrd, caushc soda, morganic chlorides, miscellaneous
anthraquinone
derivatives,
various sotvents, pH l-12

Sewage
Itreatment)

60.
1OC

35

xx

<0.0001
0.0006

<O.OOOl
0.0003

sulfurrc acrd, phosphorrc acrd. hydrofluorrc acrd and


fluosrlrcrc acrd mrrbrre, concentration
20% in water
(scrubber)

Chemrcal

225

30

xx

XX

sulfurrc

Chemrcal

125.
145

77

Metal
IrefuungJ

162.
178

tungsten

0.050.01%.
glycol 15%.
side of hydrator tankl

water

0.050.03%.
glycol
15%.
dome of hydrator tank)

acid, ammomum

and

molybdenum

remainder

water

(bottom

remainder

ftop

sulfate

sulfurrc acrd. ferrous sulfate,


1.5 (alternately
immersed)

some

sulfide

ion, pH

sulfuric and sulfurous


lclay dust washer)

acids,

pH 2.5 approximately

660.
690

sulfuric and sulfurous


(clay dust washer)

acids,

pH 2 5 approxrmately

660.
690

0.0016cd

<0.0001
0.093

0.005c

<O.OOOl

<09001d

0.0004

O.OOlad
O.OOlcd

0.0003
w<o.o061

<O.OOOld

8.2

xx

xx

0.24
so 43

0.0012
SO.OO25a
SO.001 la

8.3

xx

xx

S0.29cd
058cd

0.0014
SO.0018

281

<O.OOOlb

<0.0001

80

<O.M)Ola

<O.OOOl

O.CJxll

0.0005d

<O.OQOl

<O.OQOld

sulfurrc acrd. sulfurous acrd. sulfur droxrde.


carbon alkylate. pH of water 3 approxrmately
overhead column)

hydro(rerun

Petroleum

230

ddute sulfurrc acrd m plant process water,


acrd. sodrum hydroxrde. pH 3-14 fcollector

acetic
sewer

Chemrcal

60.
150

dilute sulfurrc acrd. neglrgrble amounts of sulfomc


and orgamc acrds (top of clay contact flash tower,

Petroleum

265

247

<0.0001

<0.0001

<O.OOOl

0.0001

c<0.0001

0.0001
c<0.0001

O.OOZad

<O.OOOl

sump)

vapors)
drlute sulfurrc and acetic acrds mixture
wrth sodium hydroxide 50% (sump)

neutralized

Plastrc

60.
160

216

<0.0001

<0.0001

dilute sulfuric
prckling

from

Metal
fpicklmg)

60

164

<0.0001

<0.0001

acid,

waste

acid

sewer

steel

<o 0001
0.0001

<0.0001
0.0002
0001

c<o
drlute sulfurrc
lsulfonatorl

acid,

sodium

sulfate

drlute sulfurrc
tmg tank1

acrd. pH 2.3 (vapors

water

solutron

from

fat split-

Chemrcal

SO105

Soap

70.
220

6.8

60

xx

0.0001
wo 002

O.OOZad

0.0001
WO.0025

O.OOla

0 0001

O.OOla

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test

SULFUROUS

Average corrosion

conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

ACID

0.00022

<O.OOOl
w<0.0001

l&9

660.
690

8.3

660.
690

8.1

Synthetic
Resin

127

41.5

chloride

Chemical

55

30

xx

xx

solution

Chemical

80

30

Synthetic
Resin

219

41.5

Power

150

2.4

tall 011

Chemical
lfractionationl

545

0.175

0.001
0.004

0.0005

tall 011

Chemical
tlractionatlonl

572

0.497

0.003
0.004

0.0008

tall 011

Chemtcal
(tractrowtion)

600

0.804

0 027
0.072

0021

Isulfur-dmxrde

Synthetrc
Resin

scrubber)

sulfurous and sulfuric


May dust washer)

acrds.

sulfurous

acids,

and sullur~c

pH 2.5 approximately

ptl 2.5 approximately

(clay dust washer)


2.6%

tsullur-droxide

2.05%
1.7%

scrubber)

approximately.

drlute

sulfurous

0.01%

apprasimately

sullurous
tratrons.
1.1-12.6

sea water,

acrd.

sodium

I propylene-glycol

acrd and caustrc soda rn varymg concenwater effluent 01 arc heater washmg, pH

xx

0.27d
S0.43d

xx

<O.OOOl

O.OOlSad

<0.0001
<0.0001

xx

0.0001

0.012d

so.011

0.00013d

<0.0001

500.
550

195

co,,

0.014

taILorI latty
fhrgh-vacuum

acrds lrom southern kralt-paper


mills
lractronating
still. top 01 tower, vapors1

Soap

470.
510

195

corr

<O.OOOl

Soap

560.
590

xx

0.048~

0.001

Chemrcal
lfractiona-.
tion)

455.
473

50

xx

xx

tall 011 and Its glyceryl esters, tall-or1 amides,


furrzed tall 011 lbottorn of tank)

WI-

Chemrcal

300.
550

17.5

tall 011 and Its glyceryl esters, taILorI


furred tall oil ltop of tank, vapors)

sul-

Chemrcal

300.
550

17.5

amrdes.

successrve
furuatrons

tall-orl

esterrfrcatrons.

amrdrzations.

sol-

Research

300.
550

18

successwe
luruatrons

taILorI esterrhcatrons.
[vapors)

amidizations.

sol-

Research

300.
550

18

_.

C<O.O001d

c<0.0001

<O.OOOl
w<0.0001

fatty acrds Ireboiler)

<O.OOOld

<0.0001

Soap

acids from kralt-pulp


manulacand abretrc acids fhigh.vacuum

C<O.OOOl

<O.OOOl
w<0.0001

acrds lrom southern kralt-paper


mdls
lractronating
still, bottMn of tower)

crude tall-or1 fatty


tore. olerc. lmolerc
lractionatmg
still)

co.ooo1

0.0054
so.0059

>l.O
S>l.O

tall-otl latty
Ihigh-vacuum

talLoil

(co&d)

rates (ipy)

90.3%

593

Alloys

0.0018

0.009

0.0014

<O.OOOlad

<O 0001

0.0002

0.0001

<0.0001

0.0006

0 0007

CO.0006

C<O.OOOl

0.009

0.0014

CO.0006

0.0001

0.0001

c0.0001

(continued)

594

Corrosion Resistant Materials Handbook


4.13:

TABLE

Corrosion

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

mediums

Average corrosion

.
tall-or1
oleate

methyl
esters,
rosr
acrds 46%.
and lrnoleate
44%. sterols
10%

methyl

TPl

317

20

0.008

0 0034

xx

00001

0 0001

123

xx

xx

0.000acd

0 OOOBcd

O.OOlcd

123

0 0001

0.0001

0.0001

200

30

0.185

0.089

CO.032

co,,

0.026

La

Chemrcal

250.
450

11

tanrung
solutron.
small amounts
01 lactrc.
acetrc
and organrc acrds. pH rnrtralfy 5.4, alter 8 days 4.2,
at end of l-day cycle 3 1

Leather

80

II3

chrome

tannrng

hquor

Leather

ao220

chrome

tannrng

lrquor

Leather

60.
90

Tanning

rosrn tvaporsf

TPl

316

xx

378

rodrne,

TIPE

304

----

hmd)

rates (ipy)

<o 0001

acrd,

MOLYBDENUM

<o 0001

OrIs and
Fats

fatty

ALLOYS-CLIMAX

ALLOY
825

00038
CO 0025

chrome-tannrng
mrum sulfate

sofutron,

concentrated

basrc

chro

55%
tank)

basrc

chrommum-sullate

solutron

(bottom

01

Chemrcal

200

20

50%
tank)

basrc

chromrnum-sullate

solutron

(bottom

01

Chemrcal

130

38

Leather

70.
212

Tannrng

140.
160

180

Tannrng

114.
126

21

vegetable
tan Irquor. chestnut
extract
40%. quebracho extract
30%. brsulhted
prevrously
wdh sodrum brsulfrte
3% and hemlock-bark
lrquor 30%

Leather

110

coal tar

Coal Byproduct (tar


drstillatronl

chrome-tannrng
150F durmg
at 212F
2 8. at 7OF
5%, at IOOF

18,

vegetable

run-off

solutrons
sulfurrc
acrd 16% at
16 hours, sulfonated
naphthalene,
pH
durrng 25 hours; chromic
sulfate,
pH
during
50 hours. sodrum
brcarbonate
durrng 25 hours

tan Irquor,

organrc

acrds,

lrquor

on leather
wrmger,
acrd 0.013%.
traces
and anrmal grease

I 5%.sulfurrc
bonate

tannrns

tannrng
lrquor
of sodrum car-

48

53

116

COll

0.0001

0.0008

<0.0001

<0.0001

xx

<0.0001

co

0001

xx

<0.0001

<o

0001

xx

<o

0001

<o

0001

xx

<o

0001

<o

0001

0 0009

<0.0001

<0.0001

coal tar, some chlorrdes

Icolumnl

Coal By
product
(distillation)

350.
420

60

0.065

0.023
SO.025
LO.021

0.012

oooa

coal tar, some chlorrdes

Icolumnl

Coal Eyproduct
fdrstillationl

350.
420

60

0.056

0.016
so.022
LO 0145

0.0085

0.0063

coal tar. some chlorrdes

(column)

Coal By
product
tdrstrllationl

350.
420

60

0.025

0.009
SO.008
LO.007

0.0033

0.002

coal tar, some chlorrdes

lcolumnl

Coal Byproduct
fdrstillation)

350.
420

60

0.023

0.012
so.01
LO.01

0.006

0.002

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

Corrosion mediums

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

Test
conditions

Average corrosion rates (ipy)

304
-P-P-

1VPE

1VPE

,PE

316

317

Coal By
product
fdrstillatronJ

450

306

0.013r

0.0035r

0.0002bd

595

Alloys

20

Icontd)

ALLOY
825

Tar

coal tar lreflux condenserl

coal tar. waler


column)

washed

la remove

chlorrdes

(top of

Coal Byproduct Itar fractlonatlon)

390

66

xx

O.Olcd

coal tar, water


column1

washed

to remove

chlorrdes

(top of

Coal Byproduct Oar fractlonatlon~

390

59

xx

0.002bd
0.005cd

nrl

<OOOOtd

nil

coal tar. water

washed

to remove

chlorrdes

kolumn)

Coal Byproduct (tar fractlonatmn)

515

66

xx

coal tar, water

washed

to remove

chlorides

Icolumn)

Coal Byproduct (tar fractronatron)

515

59

coal tar, water

washed

to remove

chforrdes

(column)

Coal Byproduct itar fractlonatlon~

500.
600

59

<o

coal tar. waler


of column)

washed

to remove

(bottom

Coal Byproduct (tar frac.


tlonatlonl

640

59

<0.0001

<0.0001

Coal By
product (tar
distdlation)

F <650

360

xx

<O.OOOl
w<0.0001

<0.0001

Coal By
product (tar
drstdlatmn)

390

81

xx

0.035

0.012
WO.008

Coal Byproduct (tar


drsttllatiord

515

81

xx

0.0025

0.001
WO.00023

Coal Byproduct ttar


drstillatmn)

640

81

xx

0 00016

Coal By
product (tar
drstdlatron)

Coal Byproduct (tar fractronation)

coal

tar kontmuous

stdl,

flash

chlorrdes

box, above

hqurd

level)

coal tar, chlorides

0 08%

coal tar. chlorides

0.08%

coal tar. chlorides

0 08%

coke-oven

tar Ivapors.

(top of still)

(bottom

of column)

lrqurdl

0 013c

<0.0001

0001

<0.0001

<0.0001
w<0.0001

180.
700

305

IOO145

48

Coal Byproduct (tar fractlonahon)

510

53

xx

0.0002c

0.0002

Chemrcal
Idrstilfatiord

430.
460

13.3

0.099c

0.052

tar acrds. tar bases, neutral coal-tar orI constrtuents, ammonium


chlorrde, pH 6 approxrmately
(top
of column, vapors)

Coal Byproduct

430.
460

97

hrgh borlmg

Chemical
(distillation)

356

188

coal-tar hydrocarbon
vapors. Irquid)

coal-tar 011.
naphthalene
chlorrdes as
pfi of feed 6

mrxture

Carbohc
40.50%.
ammonwn
(bottom of

wrth

steam

(column,

orI. tar acrds, tar bases,


water
l-3%,
neutral
011s.
chlorrde 4.17 lb/ 1000 gal.
columnl

tar acids. tar bases, neutral


ents, ammonwn
chloride,
(vapors)

coal-tar 011 constrtupH 5 approxrmately

tar acid (top of heating

bundle

in still)

xx

<o

0001
0.0003

<o

0.0001

<o

xx

0001

00003
0001

0.0089c
LO 007lc

<o

0001

c<0.0001

0.02c
0.0095c

0 0024

0 0015

0001

0 0002

0.0001

(distillation)
-

xx

COU

0.0066

(continued)

Corrosion Resistant Materials Handbook

596

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Corrosion mediums

ALLOYS-CLIMAX

Average corrosion rates

---

MOLYBDENUM

(ipyl

IVPE

IPE

TPE

304

316

317

tar acrds,

phenols,

cresolr,

xylenol.

sullur

corn

product
(distillation)

tar acrdi.

Coal By
product

phenol,

cresol,

xylenol

175.
375

547

xx

374

32

xx

<0.0001

<0.0001

Coal By-

ALLOY
--

Tar

pounds (vacuumstill. vapors outlet, liquid)

0.0002

(contd)

20

825

0.0002

(distillation1
tar acrds. sodium sulfate,
tres. ptl 6.8 (column)

sodium

carbonate

impuri-

Chemical
(drstillation)

212.
392

38

xx

<0.0001

<0.0001

xx

<o 0001

<0.0001

xx

0.0002

<0.0001

tar acrds. benzorc sod. phosphoric


sulfate. pli 4.5 (top of still pot)

acrd,

sodium

Chemical
(distillation)

212.
392

11.5

tar acrds. benzoic acid, phosphoric


sullate impurities (bottom of still)

acid,

sodium

Chemical

212.
392

11.5 -

Coal Byproduct tfractionatiord

350.
380

Coal By
product
tdistdlatron)

320

Coal By
product (tar
fractionabon)

Coal By.
product (tar
drstillationl

tar acrds. phenols, cresols,


spray of hquid possible)

xylenols

tdistrllatronl
(vapors,

some

0.0001

xx

<0.0001

<0.0001

21.4

xx

<o 0001

<o 0001

175

25

xx

0.0001

0.0001

400

306

0.018~

O.OlJcd

Coal By
product

250.
650

128

xx

<0.0001

10 0001

coal-tar vapors, phenol, naphthalene.


tar bases, cresylrc acrds. some chlorides ttop of column)

Coal By
product bar
distillatronl

190.
375

128

xx

<o 0001

<OOOOl

coabtar vapors. light oil

Coal By
product

230

24

<0.0001

<o 0001

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001

<0.0001

<O.OOOl

<0.0001

tar acrds. phenol,

coal tar,
vapors)

coal-tar

vacuum

cresol,

xytenol

(top

of

(vapors1

fractionating

column,

vapors (condenser)

coal-tar vapors. phenol, naphlhalene,


sylrc acrds. some chlorrdes

vapors.

tar bases, cre-

water

140

<0.0001

gases contarnrng constrtuents


commonly
coal-tar pitch, hydrofluorrc
acrd, traces
and carbon dioxide, air

found rn
of sulfur

Metal
(aluminum1

100

196

xx xx

gases containmg
constituents
commonly
coal-tar pitch, hydrofluorrc
acid, traces
and carbon droxide. air

found in
of sulfur

Metal
(aluminum)

100

196

xx xx

Chemical

395

xx

0.002

0.0045

00063

Chemrcal

395

xx

0.003

0.0006

0.001

Metal

21

xx

<O.OOOl

<0.0001

commercrakgrade
tartarrc acrd, decomposrtron
ucts, formrc and acetic acrds, etc
vapors over tartaric acid, decomposrtron
acetrc and lormrc acrds. etc

prod-

products,

O.OOOlcd

O.OOOJcd

TclRIM

thorrum traces, solvent extractron lrom ionexchange


barren
solutron: lerrous
ion 2-20 g/l. sulfuric
acrd 2-3 g/I, ferric ran 1 g/l. nitrate ion 0.5 g/I,
chlorrde ion 0.2 g/l. ptl 1.7; solvent. amine 5%
rn kerosene. chlorine 2 g/l (extractor)

68.
86

<0.0001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

597

MOLYBDENUM

(-ntd)

Average corrosion rates (ipy)


S

.$

TPE

304
p-p-TIN

Alloys

,PI

316

TPE

317

20

ALLOY
825

CHLORIDE

Im chlorrde.
sodrum chlorrde. zmc chlorrde.
so?
pended sohds. petroleum
solvent conlammg
small
amounts of water lautoclave)

Chemrcal

80.
370

18% approrimately stannous tluoborate.


free fluobow acid 200 g/l, gelatme 3 g/l. catechol 0.5 g/l.
a_naphtholO.5
g/l

Metal
tplatmgl

125

stannous-sulfate
saturated
solution.
4 or/gal. hydrofluorrc acid 1 ozlgal

acid

Metal

cresol

Metal

Petrochemi.
cal
Rayon

11.7% stannous sulfate.


sulfon~c acrd 3 9%

TOLWC

sulfuric

acrd 9.4%,

0.013

0 0056

0.0009

14

0.00135
LO.00133
0.00037
LO.00038

0.00626
0.00143

140

0.0149

0.0002

RT250

77

0001

<o 0001

330.
380

22 5

0 0002

0.0003

350.
370

22 5

0 0003

0.0005

290.
320

22 5

0.0005

0.0006

340.
350

44

0.001

0.0006

220

44

0.0005

0.0007

Petrochemrcal
Idlstrilalmnl

350.
525

34

0 029
0 033

0 0002

Pulp and
Paper

150.
200

97

0.0001

0.0001

365

0.0003d

0.0003

ACID

72.5%
mtolurc
acrd, p-tolurc
acrd 2.6%. benzorc acid 2.6%
55%.
rylene

sulfurs

0 067

16

acrd 22.3%.

o-tolurc

phthalrde
12%.
esters
12%.
water
5%. phthalrc acrd and anhydrrde 5%

50%.
phthalrde
15%. esters 15%.
and anhydrrde 10%. xylene 10%

phthalrc

40%.
xylene 20%.
phthalrde
15%,
phthahc acid 4%, water remamder

esters

40%.
xylene
phthalrc acid
mainder

20%.
4%.

lo%,

acid

10X,

phthalide
15%.
esters lo%,
cobalt acetate
1%. water re-

30%.
xylene
50%.
phthahde
8%,
water
phthahc acrd 3%. phthalic anhydride 3%

5%.

tolurc acrd. benzarc acrd. acetaphenone,


tolualdehyde. undetermmed
orgamc materlals
treborlq)

<o

<o 0001

0 0013

<o

0001

0001

TURPEIITIRE

turpentme
from kraft pulpmg.
small amounts
of
hydrogen sulhde. methyl mercaptan.
dimethyl
sulbde (decanter)

URANIUM

CHLORlOE

12%

approximately. water sotutmn

12%

approximately,

water

solution

12%

approximately,

water

solution

8.P.

6.8

LO.92

0.44

0.125

(half Immersed)

BP.

6.8

10.58

0.43

0.97

(vapors)

BP.

68

LO.012

0.018

0.0048

(continued)

598

Corrosion Resistant Materials Handbook

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

i!

sulfuric acid 50.60


oxide 1 g/l. chlo-

Mmng

103.
106

23

113.
118

60

xx

xx

lPl

304
P-P--

0.00015
<0.0001

,Pl

TIPS

316

317

Mmlg

118

41

pulped
ferrous

Mlnlng

104.
II6

42

xx

0.0009d

0.0013d

0 0002d

0.0001

xx

0.109c

0.066c

00001
<00001

0.0002d

acid 4%

M1nmg

103.
106

23

uranum-ore

pulp, sulfwc

acid 2%

Mmng

103.
106

23

103
106

12

;0.0001
< 00001~

<o.ooot

c.0 0001

Mmg

103.
106

23

(0 0001
<0.0001

<oOLlOt

<o 0001

uranwmore
leach pulp. sohds 68% approximately,
sulfur as sullate 10 13.2 g/l. ferrous ion 6.6 g/l.
ferric IO 2.7 g/l. fluoride ion 2.7 g/l. chloride ion
1.2 g/l, free sulfuric acid 0.1 g/I

Mmlg

75.
90

38

uramum ore tgranlte rock), sodurn-carbonate


pulp,
sohds 50%. sodwm sulfate 6%, sodium carbonate
5%, sodwm bicarbonate
1.596, pressure 85 psig
(half Immersed)

Mming

200.
215

44

xx

xx

wanurn
and other
tlon. from leachmg

solu-

Mming

100.
160

100

xx

xx

0.037
0.067

uramum and other metal salts m sulluric-acid


solutlon, from leaching of uranium ores, pH 0.9-1.4

Mmmg

R I:
100

100

<O.OOOl

uranylmtrdte
100% uranyl

M1nmg

BP

120

uranwm-ore

pulp, sulfuric

80%, water
of tank)

acid 0.5%

metal salts III suIturic-actd


of uramum ores. pH 0.4-I

water
Mate
solution.

solution. being concentrated


hexahydrate
(evaporator)
free nitric

sod

trace

to

(bottom

uranylmtrate
ratlmate solutlon, nitric acid 30.40%.
variable chlorides
~2000
ppm (concentrator
column. vapors. Ilqudl

OOOld

<o

0 0003
0001*

<o

0001

co 0001

<o

0001

<:0.0001

O.OOOld <0.0001

0.002
O.OOlcd

0.0001

0 028

pulp, sulfuric

pulp. sullur~c acid 1% approximately

<0

0002

uranwm-ore

uranium-ore

625

<o 0001

<0.0001

0.0019cd

ALLOY
20

L0.002d

pulped ranwn
ore. sollds 60%. sulfuric acid 28.
55 g/l, ferric ton 5-10 g/l, some lerrous MI. sodwm
chlorate 0 I% approximately
uranwm
ore kdlcatel.
sulfuric
acid 5%.
bon 6 g/l. ferric ton 0 5 g/l IOorr agItatorI

(=md)

Average corrosion rates (ipy)

0 s
f f

uranwm ore, sollds 70%. free


g/l. iron ton 5-6 g/l. uranwm
rate 0 3 g/I

MOLYBDENUM

O.OOOld

0.07

<0

OOOld

<O.OLlOl

0.0004
0004

0.0003

co 0005

c<0.0001

0 0002

<O.OOOl

LO

Mming

160.
215

36

0.0004ad

o.wo5
o.cOo3

0.0009
0.0004

0.001
0.0002

Mining

175

92

0.0011
0 0016

0.0011
0.0007

0.00095a

0.001

0.0006

0 0007

0.0001
0.0002

0.0002
0 0001

UREA
44%.
8%

ammoma

31%.

water

17%.

carbon

43%.
ammoma
32%.
carbon dloxtde
remamder
(heat-exchanger
head)

7%.

dooxide

water

Chemical

Chemical

90

90.
250

42

100

xx

<0.0001

<0.0001

0.0002

<0.0001

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

19%.

merts

32 2%.
0.3%

urea. ammonia

carbamate.

urea. ammon,a.
reboderl

carbon

urea, llquld
carbonate

WNYL

2
;

Urea

oxide

ammonia.

water

20.5%.

ammonia.
dloxlde.

carbon

Petrochemc
cal

dwde

Chemlcal

stwper

Chemical

ammon~m

Chemical

carbon

carbon

011 (urea

dloxlde.

dl-

MOLYBDENUM

599

bntd)

Average corrosion rates (ipy)

3
f2

28%. ammonia

ALLOYS-CLIMAX

Alloys

355.
360

150

300

300

xx

250.
310

56

xx

365.
375

125

xx

xx

rIPI

304
-----

TPl

TPI

316

317

<0.0001

<0.0001

SC0 0001

s<o 0001

ALLOY
20

825

<0.0001

<o.o001

CDll
0.028

0.0015

S>O.O68
LO0016

CO,,

0.027

00011
0.0089
so.0041
LO.0013
to 003

0.0013

00011

0.001 I

0.0004
0.0008
so 0007

0.0006

0.0002
0.0009

0.0001

CHLORIDE

vmyl chloride,
vmyt
peroxIde.
hydrochlortc

acetate,
acetlc acid, hydrogen
acid, pH 3 5.4 5 tpolymerizerl

Chemical

RI.
150

vmyl acetate,
methyl
acetate,
dlau and moisture
(vapors and resm

Chemical

60.
110

226

wnyl chlortde.
probably
contammg
unsettled
droplets of a sodurn-metablsulhte
solutlon
c 15% and
4-85 average

Chemical

60.
80

135

vmyl chloride,
probably
contammg
unsettled
drop.
lets of a sod~um~metab~sull~te
solutlon
< 15% and
4.8, average

Chemical

60.
80

135

vmy:.chloride
vapors
and polyvmyl
tramed m water vapor, pawbly
traces
and phosphates,
vacuum

Resin

110.
150

67

Resm

80.
150

117

xx

xx

<o 0001

Pulp and
Paper

188.
190

56

xx

<0.0001

boder.feed
water, sprayed
mto deaerating
heater.
carbon dloude 70 ppm, sulfuric acid 30 ppm. oxygen
10 ppm

Power

244

xx

<0.0001
<0.0001
<0 OOOldr S<O.OOOl
w<o 0001

vented gases from steam deaeratmg


dloxlde
~400
ppm. oxygen
(80
softened water vapor. pH 4

Power

210.
220

244

xx

<O.OOOld

brackish sea water, total sohds 1.8%. sulfur dioude


l-2 5% lspeclmen
removed
and allowed
to dry in
au durmg 10 seconds1

Chemical

60.
95

158

xx

xx

corr

Galveston

Chemical

112

130

xx

xx

0.0002

vmyl chloride,
methyl
acetal,
a!ternatelyl

20% polyvmylxhlorlde
phates 0 05%. pH 4.6

bodet-feed

water,

solutlon,

oxygen

0.01

chloride
en.
of peroxIdes

peroxldes.

ml/l.

phos-

pH 8.1 lecono-

mlzerl

Bay water

brackish
water,
denser box)

salt

heater.
ppm,

carbon
zeolite-

(condenser1

200-15000

brackish water. chlorides


icondenser
water box1

O-5000

100.

220

ppm.

pH 6-8 Icon-

Petroleum
ldistdlatlonl

90.
115

181

ppm.

sullur~c

Power

32.
85

400

acid

0.0004

<0.0001

O.OOllcd

<0.0001

<0.0001

<O.OOOld

<O.OOO!

<O.OOOl

<0.0001

<o 0001

<0.0001

<o 0001

co 0001

<O.OOOl

<0.0001

<0.0001

ml

<0.0001

<o 0001
w<0.0001

0.0003cd

O.OOOlad

0 0002d

<0.0001

<0.0001

<0.0001

xx

<:o 0001

<0.0001

<0.0001

(continued)

Corrosion Resistant Materials Handbook

600

4.13:

TABLE

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

IWoUs~aI
(PROCtSS,

r-

5s

WPE

*I

304
----P

Coal Byproduct

RT

water condensed trom gas stream inItrogen 88%,


carbon dwde
12% approxrmately),
rron 40 ppm,
sulfuric and sulfurous
actds IO ppm, nttrlc and
mtrous acids 3 ppm, pfi 6 approxrmately
[alternately
Immersed1

Petroleum

70
90

36

coohng water

Pharmaceutical

62

112

Soap

70.
110

360

tap water, brcarbonates


as calwm
carbonate
20
ppm. sulfates 21 ppm. chlorrdes 11 ppm. iron and
alumma 6 ppm. calcrum oxrde 5 ppm. sdica 2 ppm.
suspended matter, pH 5 6

food

42

30

New
then
every
each

Food

45
50

hmtd)

TlPE

rwt

316

317

20

ALLOY
625

braclush

carcadmg brackrsh water,


liquor coolmg cods)

WATER.

Everett,

Mass. fammonra.

63

00006cd

<OOOOlbd

0 0001

(0

CmiDENSA*E

(tower

water,

basin)

pH 4.5

York Crty water sprayed Into atmosphere


and
drawn through
arr washer;
wdter replaced
33 hours, pH inrtially 7. fmally 4.5-4.8 during
replacement
perrod frmmersed
and in spray)

0001

xx

<0.0001

<0.0001

xx

<0.0001
w<0.0001

<O.oOol

xx

xx

<0.0001

<0.0001

16

xx

xx

<O.OOOl

<o.Lloo1

xx

evaporator

tailprpe

water,

pH 7.14

Rayon

120

29

xx

<0.0001
<0.0001

<0.0001

evaporator

tadprpe

water,

pH 7.28

Rayon

120

36

xx

<O.OOOld
<O.OOOld

<O.OOOld

Pubhc Works

68.
72

42

xx

<0.0001

<0.0001

well water, chlorrdes 40 ppm. carbon droxrde 30


ppm. won 5 ppm. sulfur droxrde 2 ppm, total hardness 200 ppm, pH 7 48 (pump discharge)

Petroleum

71

63

xx

<o

<o.ooo1

fresh+vater

supply to pulp grmderr.

Pulp and
Paper

95.
99

140

well

hydrogen

Synthetrc
Resm

126

61

Water
Heatmg

160

1555

Chemrcal

F <212

89

xx

ppm.

Petroleum

212

164

1235 psi

Research

572

30

fresh water,

water,

domestrc

MOLYBDENUM

2
3

L
.

coolmg

ALLOYS-CLIMAX

Average corrosion rates (ipy)


c;

waler,

NICKEL

pH 7.3

hot-waler

sulfide

pH 7.6

58 ppm approximately

sopply

hot water

untreated

water,

salts as chlorides

300-4000

<0.0001

0001

xx

0 0003ad

CO OOOla

0001

<0.0001

<,o 0001

<0.0001

c0.0001

<O.OOOlad

<o

xx

<0.0001

<00001

<O.OOOl

<0.0001

<0.0001

pH 6 5-7.5

degassed

drstrlted

water,

pH 6.5, presrure

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

MOLYBDENUM

601

(amtd)

Average corrosion rates (iPY)

,PE

304
P-P-P

.
water.

Alloys

TlPE

VIPS

316

317

ALLOY
20

825

hrgh-purrty

hrgh-purely

water,

oxygen

catron-free

water,

pH 3 2

dewwed
water
water heater)

Frood rnme
durmg test)

20 ml/l.

and steam,

water,

720 pst

Research

teed.

Power

450

655

3 trmes

Mmmg

I lo120

14

total drssolved
pti 6.8, specrftc

Mmmg

86

Mmmg

changed

27.3 g/I
14 8 g/l.

rnme water from sulfide ore, ferrous


sulfate
2.567
g/l. total sulfate
ran 1.621 g/l. sulfurrc
acrd 0 265
g/l. free sulfate ran 0 259 g/I
coal-mme
water,
0 4 ppm, pH 7 85

sulfate

Ion

513

30

Research

pH 9 fdeaeratrng

pH 3 4, (water

mane water,
total sohds
solrds 26 6 g/l, chlorrdes
gravity
017

pressure

ppm,

ferric

ran

500
78.
a2

xx

200

xx

xx

xx

47

56

61

87

LC.0

00001

~OOOOl
L. 0.0001

< 00001

mme water from sulfide


ore, magnesrum
sulfate
5230 ppm, ferrous
sulfate
2599 ppm. calcrum
brsulfate 2285 ppm, acrdrty 200 pprn

0001

L<O

0001

nrl

<0.0001

<_0.0001

00001
0 0001

00001

00001

47

61

--

00001
00001

sulfide ore, calcrum


sulfate
1710
sulfate
663 ppm. ferrous
sulfate
150 ppm

Mmmg

47

61

0.0171d
0 0108d

<0.0001

rnme water from sulfide ore, ferrous


sulfate
2835
ppm. magnesrum
sulfate 2410 ppm. calcium
sulfate
1408 ppm. acidrty 82 ppm

Mmmg

47

61

xx

0.0095bd
0.0014d

<O.OOOl

mine water from sulfide ore. ferrous


sulfate
1060
ppm, rnagneswn
sulfate
1000 ppm. calcium
sulfate
923 ppm. acidrty 7: ppm

Mmmg

47

60

xx

<0.0001

<0.0001

mrne water from sulfide ore. calcium


ferrous
sulfate
1310 ppm. magnesium
ppm. acrdrty 52 ppm

sulfate
1361.
sulfate
054

Mming

47

60

xx

<O.OOOld
0 0006d

<O.OOOl

rmne water from sulfide


ore, calcium
sulfate
923
ppm. calcium chloride 638 ppm, magnesium
chloride
239 ppm, ferrous sulfate 61 ppm. acrdtty 23.5 ppm

Mining

47

60

xx

0 0003d
0 0002d

mme water,
copper as sulfate
0.102%.
available
sulfurrc
acrd as won sulfate
0 67% (water flows
from launder mto sump. spools exposed to air durmg 5.15 mmutes,
m water dung
26.5 minutes1

Mmmg
fcopper)

6061

xx

xx

<o 0001

<0.0001

mmeral sprmg water,


potassium
chloride
2584 4 ppm. talcrum
sulfide
2743
ppm.
calctum brcarbonate
113 2 ppm. alumma
carbon
aSoxIde 41

sodrum chlorrde
11190 5 ppm,
2614.9
ppm
sodwm
sulfate
sulfate
1263.8 ppm, hydrogen
calcrum
carbonate
273.2 ppm.
221 3 ppm, magneswm
sulfate
101 pprn. ferrrc oxide 93 ppm,
8 ppm, acrd, speclfrc
gravrty

Sanrtary

80.
212

47

<O.OOOla
<O.OOOlb

<o 0001

hot sulfur-spring
water, total solrds 269 pprn. calcrum carbonate
124 ppm, sulfates
23 8 ppm. chlorrdes 14 ppm, sulfides
12 ppm, pH 9.4 (Olymprc Na.
lional Park, Wash)

Samtarv

120

120

xx

<0.0001

<0.0001

mme water from


ppm, magnesrum
603 ppm, acrdrty

58

<0.0001

10169
nil

(continued)

602

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS AND HIGH NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

bntd)

Average corrosion rates (ipy)

Corrosion mediums

50.
70

90

TIPS

TIPE

TIPS

304

316

317

<o OOOlc

20

ALLOY
825

<0.0001

Arbuckle water, N. A. Hoffman 8 No. 6. Trapp


Freld Barton Countv. Kansas. total drssolved solids
33640 ppm. chlor&
ion 20165 ppm, sodium ran
10930 ppm, talcrum ran 2091 ppm. bicarbonate
ion
476 ppm. total alkalrnrty 390 ppm, sulfate ion 24.19
ppm. large amount of hydrogen sulfide, pH 695,
specrfrc grawty 1 0267

Petroleum

salt water from crude 011. pti 7 5 approxrmately


settler vessel1

(salt

Petroleum

170.
200

216

<O OOOla

<o 0001

chlorine

Petroleum

95

83

0 OOOld

<o 0001

Ncches River water, chlorine 0.2%.


chlorrdes 3030
ppm. hardness 340 ppm. methyl-orange
alkalinity
312 ppm. srlrca 50 ppm. pH 8.1 lcoolrng tower)

Power

8b
92

74

O.OC&d
0.0003d

O.@lO2d
<O.OOOld

0.0002d
<O.OOOld

<O.WOld

Neches River water, chlorme 0 2%. chlorides 3030


ppm. hardness
340 ppm. methyt.orange
alkalinity
312 ppm. srtrca 50 ppm. pH 8.1 (cooling tower)

Power

82.
97

74

OOOOld

<O.OOOld

<O.OOQl

<O.OOOld

cooling water from Passau Rrver, chloride ion 834


ppm, calcium carbonate
328 ppm. sulfate ion 160
ppm. brcarbonate
ran 46 ppm. sulfate/chtorrde
ratio
0.19, drssolved oxygen trace, pH 8.5

Power

65.
71

30

<O.OOOla

<0.OaO1

rover water, chtorrdcs 1300 ppm. sulfates as sulfur


75 ppm. sutfrdes as sulfur 20 ppm. pH 6.3 (travel.
hng bark screen)

Pulp and
Paper

45.
85

148

0.0001

0.0001

rwer water

from let condenser

Pulp and
Paper

R.T.

224

~O.Oooi

<O.OOOl

Mrssrssrppr

Rover water

Chemical

R 1.

90

c.00001

<O.oOOl

90

169

orl-field

brme.

chloride

ran

16950

ppm,

0.0042~

2 ppm

rover water,
tent chlorme

IPotomac

chlarrdes.
varrous organrcs. intermit.
(barometric
condenser tailpitl

Kelly Lake water

Hudson
Rwer water
contammated
waste from Poughkeepsie
Crty

WATER.

SEA

with

organic

Mmmg

72

35

<0.0001

Gas

100

60

<O.oOOl

70.
02

212

R.T.

160

(O.wOI

ml

nrl

nit

<O.OOOl

Manulacture

,IYYERSED,

sea water

sea water at Kure Beach, N. C.

sea water

nrl

O.LlOO2d

at Kure Beach, N. C.

Research

sea water at Wore Beach, N. C

Research

sea water at Kure Beach, N C

Research

<0.0001

60

R.T.

1645
(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

603

Alloys

MOLYBDENUM

(amtd)

Test

Average corrosion rates (ipy)

conditions

Corrosion mediums

TIPE

.
water

rea

sea waler

304
--p-p

TIPE

TIPE

316

317

ALLOY
20

625

,wnmersedl

at Kure Beach,

N C.

Research

R.T.

480

--

0 0002c

<o 0001

sea waler
al Curacao,
Netherlands
chlortdes
20000 ppm, pH 6 6 tpressure
casmgi

West Indies.
end of pump

Petroleum

79.
88

122

xx

xx

00001

sea water al Curacao.


Netherlands
chlorides
20000 ppm ptf 6 6 lsuctlon
casmgi

West IndIes,
end of pump

Petroleum

79.
88

44

xx

xx

0 OOOlad

0 OOOlad

sea water
at Curacao.
Netherlands
chlorides
20000 ppm. ptf 6 6 ipressure
CaslllgJ

West IndIes.
end of Pump

Petroleum

79.
88

I2

xx

xx

0 0005ad

0 0004ad

Research

86

84

xx

xx

<O.OOOla

<o

Research

RT.

359

xx

xx

<o

0001

<o 0001

Research

RT.

193

xx

xx

<o

0001

IllI

Research

R.T.

360

0.0007cd

<O.OOOld
<O.OOiIlad

Research

R.T.

I60

0.0001
0.0001*

0 0001

Food

68

I05

0 003c

0 0009c

Los Angeles
Harbor West Basm sea water,
total
sohds m suspension
2.5%. organic matter
m solotmn 2 0%. chloride
ton 18800 ppm. sodturn
loo
10478 ppm. sulfbte
loo 2724 ppm. magnewm
40
1245 ppm. calcwm
aon 451 ppm, potassium
non 374
ppm. bicarbonate
ton 165 ppm. bromme
loo 12 ppm,
SIIICP 6 ppm, phosphate
ton 5 ppm. borate loo 0 3
ppm. won loo 0 2 ppm, pH 7.5 (18 m. below water
level1

Petroleum

120.
140

350

0 0005cr

heated

sea water,

oxygen

I5 ppm. pH 6.2

Chemical

290

xx

00124

00131

heated

sea water,

oxygen

trace,

Chemical

180

xx

0.0091

0.0007

heated

sea water,

pH 7

Chemical

320

xx

0.0002

0.0002

evapora-

187

6.2

0.00013

0.0001 I

evapo-

174

6.2

0.00018
<0.0001

0.00031

<0.0001
0 0001

evapo-

174

6.2

<o

0.00021

<0.0001

artlliclal

sea water,

WATER.

SEA.

pH 7.7-8

AERATED

,IN

SPRA

0001

OR TIDAL

ZONE,

sea water

at Kure Beach,

N C [half-tide)

sea water

at Kure

N. C. (half-tide

WATER.

SE&

IN

Beach,

HARBORS

sea water

at Wllmmgton,

sea water

at Duxbury,

6.5 86 concentrated
clflc gravity
I 0469

in basin)

OMMERSEO)

N. P,

Mass.

seawater
(evaporation

brme, pH 28.
pond)

spe-

xx

0.0001

0 0004cd

0 0006cd

SEA. HEATED

WATER,

sea water,
tor)

salt

sea water,
rator)

salt 6 07%,

sea water,

salt

6.07%,

6 07%.

pH 6.7

pH 8.1 lflrst.stage

pH 8.1 (second-stage

pH 8.1

lthird.stage

XI

x
-

_.

0001

OOOla

0.0001

rator)

(continued)

Corrosion Resistant Materials Handbook

604

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

NICKEL

ALLOYS-CLIMAX

MOLYBDENUM

hontd)

Average corrosion rates (ipy)

Corrosion mediums

sea water, salt 5 95.6 13%.


pH 8 8 levaporator)

magneswm

hydroxide,

250

66.5

sea water. salt 5 95.6 13%,


pH 8 8 (evaporator, vapors1

magnewm

hydroxide.

250

66.5

TPl

TYPE

UPL

304

316

317

<O.OOOla

<O.OOOlar

0.0005c

ALLOY
20

825

<o 0001

0.0003at

<o 0001

sea-water
brme.
salt 13.1 4%,
carbon
dmxide
ppm. pti 8
(first effect, bottom of unit)

Marme
Idlstdtatlon)

267.
270

42

xx

00003

0 0002

sea water brme, salt


effect, bottom of unit)

Marme
tdlstdlatlon)

253.
256

42

xx

0.0002

0 0001

sea-water bIttern. Pachuca slurry, sodwm chloride


100 g/l, magneswm chlonde 75 g/l. calcium sulfate
50 g/l, talcum
chloride 25 g/l. pH 6.7.5 lspeclmens
covered wth crystals)

Chemical

127

107

xx

xx

0.0001

0.0001

sea-water
blttern,
sodum
chloride
100 g/I. magneswm chloride 73 g/l, talcum
chloride
25 g/l.
calcium sulfate 2 5 g/l lheatmg tank)

Chemical

95.
I26

84

xx

0.0004bd

0.0003ad

hot sea water,


mIxtureI

Marme

267.
270

42

xx

0.0004a

Marme

253.
256

4.2

xx

0 0004

above

Water
Treatment

65

210

xx

<00001

<00001

from amon and catwn

Water
Treatment

65

210

xx

<0.0001

<0.0001

Synthetic
Rubber

70

17

xx

<O.OGJl
oil*

<0.0001

Synthetic
Rubber

I50

--

zeohte softenmg of well water at SIOUX Falls, S. 0,


total hardness 23 2 g/gal,
calcium hardness
16 3
g/gal.
methyl-orange
alkalmlty
II 6 g/gal.
ma&
newm
hardness 6.9 einal.
chlorides
1.6 n/eal.
sulfates I.1 g/gal tall these expressed as calcwm
carbonatel.
sdIca 20 ppm. iron 0 4 ppm. pH 8.1

Water
Treatment

50.
60

365

xx

<0.0001

<0.0001

zeollte softenmg
of wer
water at Casper. Wyo,
sulfates 40 g/gal. compensated
hardness 29.1 g/gal,
total hardness 264 g/gal,
calcwm
hardness 21 E
gigal,
methyl.orange
alkalmlty
96
g/gal,
magnewm
hardness 4 g g/gal, chlorides 2 8 g/gal lall
these expressed
as talcum
carbonate),
silica 15
ppm, won 0 I ppm, pH 7.6

Water
Treatment

50.
60

365

xx

<0.0001

<0.0001

Corn
Products

150.
190

242

xx

0 0005
<. 0.0001

<0.0001

. .O.OOOl

corn
Products

127

44

xx

xx

<O.GQOld
wo.OQa3

<o.ooLN

<0.0001

hot sea water,


(vapors mIxtureI

carbon dloxlde

carbon

decatmrwed
water
mmeral bedl
demmeralued
exchangers

1.8.2.0%, pH 8 2 (second

I ppm. pH 6 2 lvapors

dioxide

I ppm,

ltop of catlon

water.

effluent

zeohte-softened

water

(screen.

zeollte-softened

water,

small

pH 6.3-6.7

exchanger,

treated

amount

water

of

line1

styrene,

OH 7

I.

WATER.

0.0002

<0.0001

<0.0001

__.

STEEP

10-4 Be steep water,

pH 4 (evaporator)

corn steep actid. acldlty at end of steeping cycle as


hvdtochlow
acid 0.56%.
sulfur dioxide
initiallv
OTl4%. fmally 0.018%.
pti 4 average fin liquor jui
above corn level)

WO.0006

(continued)

Ferrous

TABLE

4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH

Test
conditions

Corrosion mediums

NICKEL

ALLOYS-CLIMAX

Alloys

605

MOLYBDENUM

(amtd)

Average corrosion rates (ipy)

---

TIPI

TPl

TWE

304

316

311

ALLOY
--

20

625

<o 0001

<0.0001

wo 0013c

wo.0012

<o 0001
wo.ooo7c
wo 0022c

<0.0001
wo.001

80

<O.OOOld
0011

<0.0001
0.0019

150

40

<0.0001

<0.0001

130
190

24

<0.0001

<0.0001

Power

4w425

32

0 006
0.0055

0.0016

water saturated wth synthesis gas. hydrogen 38%.


carbon monoxide 32%. carbon dionde 8%. oxygen
0 2%. nitrogen remamder,
sulfur as hydrogen sulhde and organic sulfurs 300-500 grains/w
11

Chemical

150

30

0.0001

0 0002
0.0003

chlormated

Plastic

85
115

57

<o 0001

<0.0001

chlorinated
lresh water, ptl 1, raw water composltlon methyl orange alkalmlty
as caluum carbonate
212 ppm, total hardness as calcium carbonate 200
ppm, sulfate IO 32 ppm. chloride loo 24 ppm

Food
(fruItI

70.
90

32

c.0 0001

<o 0001

<o 0001

<0.0001

chlorinated
fresh
droxlde to pH 8.
orange alkahmty
total hardness as
fate bon 32 ppm.
spray1

water buffered wth sodwm hy


raw water cornposItIon,
methylas talcum
carbonate
212 ppm,
calcium carbonate 200 ppm. sulchloride ion 24 ppm Iwasher. m

food
tfrult)

70.
90

31

<o 0001

<o 0001

<o 0001

<o

chlormated
lresh
acid to ptt 6 9,
orange alkalmtty
total hardness as
late ton 32 ppm,
spray)

water acldlbed wth hydrochloric


raw water composltlon
methylas calcwm
carbonate
212 ppm,
calcium carbonate 200 ppm. solchloride loo 24 ppm (washer, in

Food
tfrult)

70.
90

32

<0.0001

<0.0001

<0.0001

<O.OOOl

Chemical

195

61

tower water from Syracuse water supply, treated


wth alglclde.
Oaklte
Samtlzer
No 1, pH 8-8 5
(tower slwe-way1

Pharmaceu
tlcal

45.

227

quench water, total sohds 0 64%. msoluble sollds


0 25%. ammonium chloride 0.1%. volatdes 0 09e%.
calck
chloride 0 066%.
calcwm sulfate 0.062%.
pH 6 5 (coke quenchmg tower, below spray header)

Coal

corn steep acid. acldlty at end of steepmg

cycle as
hydrochlonc
acid 0 56%,
sulfur dioxide
ntially
0 12%. imally 0 012%.
pH 4 1 average (below corn
level)

Corn
Products

corn steep acid, acldlty at end of steepmg cycle as


hydrochtorlc
actd 0 5296. sulfur dioxide
mltially
0.1 I%, fmally 0.011%.
pti 3 8 average (below corn
level)

corn
Products

steep water

Corn
Products

126.
130

Food

food

tap water saturated wth carbon dloxlde contammg


sullur dloude 0 008%
average and traces of dissolved a~. pressure

steep
0.05%.

from corn starch (evaporator)

water.
lack
acid 051%.
sullur dloxlde
PM 3.54 5 (alternately
vapors. lIquidI

vapors above steep water,


dlonde 0.05%.
pH 3.5-4.5

WATER.

lactic acid 0.5.1%.


(evaporator1

sulfur

130

130

31

39

<o 0001

<0.0001

w0.0014

TAP

water

water. small amounts of hydrochtorlc


we, pH 2 lbottom 01 condenser)

acid and chlo-

88

11.2

0 002lc
0.004c
0.0005

0 0042

<0.0001

0001

O.OOOZbd

0.0005bd

<0.0001
<0.0001

0 0018

<o

0001

0.0003
0.0002

0 0004
0.0003

0.0002

(continued)

606

Corrosion Resistant Materials Handbook

TABLE 4.13:

VARIOUS

STAINLESS

STEELS

AND

HIGH NICKEL

Test
conditions

Co rosion mediums

ALLOYS-CLIMAX

TIPE

Coal

waste-water
effluent.
hydrochloric
acid, sulfuric
acid. soda ash, caustic soda, chlormated
solvents,
organics, zmc sulfate. pH 2.10, generally acid (sump
pipe Imel

Chemical

waste water from fme-chemicals


manufacture,
drochforlc aud. sulfuric acid, or~an~cs.
pH 6 5

Chemical

(coke quenchmg

tower,

below

11.2

0 0013c
0.0093c
0 02lc
0 0084~

TPE

316

0.0002
0.0003

,PE

317

20

0.0002
0 0004

ALLOY
825

0 0001
0.0003
0 0002

spray header1

hy-

R.T.

68

80.

30

<0.0001

<o 0001

<o 0001

<0.0001

Chemical

55.
70

42

<o

waste-process
water. sodium sulfate, sodium chloride, sodium phosphate, ammonium sulfate, calcium
sulfate. magnesvxn sulfate, pH 3.5-5 (vacuum evaporator. vapors)

Chemical

90.
118

63

<0.0001

water.
chlorlc

Chemical

86.
99

147

0 0116

0.0111

Coal

RT212

I80

0 003c

0 0004c

and oxygen, resullur


dioxide,

Petroleum

IOO500

278

wash water, dissolved acid gases and oxygen, carbon dwnde.


sulfur dwxlde trace, chtorldes trace.
pressure 300 psb (bottom of tower1

Petroleum

125

211

electroplatmg
waste,
nickel,
salts, phosphates, pH 2

Metal
(plating)

70

105

Petroleum

160.
190

25

various orgamc
esters
acid trace, pH 2 Icooler)

and

waste water, for spray


just above spray pIpIngI

wash water. dissolved acid gases


generatmn
gas, carbon
dloxlde,
chlorides

aclds,

hydro-

quenchmg

chromium,

c<0.0001

<o 0001

100

waste
water
from
fme.chemlcals
manufacture.
acetlc acid. halogen suds, sullur~c acid, salts of
these acids, traces of organic solvents and greases,
pH Z-7.5, 6 5 average

ammonwstdl
coke flower,

(mntd)

Average corrosion rates (ipy)

304
----quench waler. total solids 0 64%.
msoluble sollds
0 25%. ammonium chloride 0.1%. volatdes 0.098%,
calcwm chloride 0 066%.
calcium sullate 0 062%,
Nalco No 161 mhlbltor added to coke sump feedmg at rate 01 50 ppmlgal
water returned to sump

MOLYBDENUM

of

sodwm

0001

LO 0003a
WLO 0003a

(0

0001

<o 0001

LO.OOOZa
WL0.0003a

<o 0001

<o 0001

0.0002a

<0.0001

WAX

wax, sulfuric
I8 psi
castor

wax,

acid 5%

approximately.

pressure

15.

0.02

0.014

sodium

hydroxide

SO%,

sulfuric acid

Chemical

180.
212

castor wax. sodwm

hydroxide

50%.

sulfuric

acid

Chemical

180.
212

lactic

acid,

Brewing
fwhiskyl

140.
185

<o.o001

Brewing

110.
240

<o.ooo1

25%

25%

thm stillage. sohds 4.5%.


succimc aud. pH 3 8
gram and water mixture.

acetic

acid,

pH 5.8 (cooker1

0.0008
<0.0001

<0.0001

o.ooo9

(continued)

Ferrous

TABLE

VARIOUS

4.13:

STAINLESS

STEELS AND HIGH NICKEL

Test
conditions

Corrosion mediums

ALLOYS-CLIMAX

TWE

P-P-_
acid, water, gram.
pti 3 1 average

Impurltles.

total

sohds

MOLYBDENUM

TIPE

TPl

316

317

20

Brewing

60.
160

146

xx

<0.0001

<0.0001

Brewing

175
212

146

<0.0001

<0.0001

Brewmg
td~stdlat~on)

208

87

xx

--

<o

<0.0001

vapors from drymg solld syrup 30%. moisture. a~.


traces of lack
acetic, formic, prop~omc acids Ide.
hydrator)

Brewmg

140.
180

151

vapors from evaporators


to condensers.
moisture.
traces of lactic, formtc. prop~orw acids (vapor Ime,
evaporator]

BleWlog

120.
200

146

Lumber

loo212

150

xx

Rayon

350

44

xx

xx

0.0006

0.0003

0.0007

fbpll

350

34

xx

xx

0.001

0.0008
0.0018d

0.001

mixed condensate of xylene and water, small amount


of acetlc acid. pH of aqueous phase 3 approximately

Lumber

70.
MO

150

IX

<0.0001

<O.OOOl

15%.

RayOn

60

22.5

<0.0001

0.001

Rayllll

350.
370

22.5

0.0016

0.0014

0.0004

0 0002

0 104c

00031

xx

0.0006

0.00045

0.148

0.00024

mixture
01 dlstdlers
drmd grams
syrup, sohds 40% 130% I syrup)
vapors ol alcohol,

orgamc

and

acids. water,

evaporator

pli 5

(amtd)

Average corrosion rates lipy)

304

lactic
14%.

607

Alloys

0001

O.OOOkd

<o

0001

ALLOY
825

<O.OOOlcd
<0.0001

<0.0001

XILENE

lwd
xylene. small
ph 3 appraxlmately

91.8%

amounts

0 xylene, aromatlcs

98%

o-xylene,

tolulc

of water,

acid.

1%

water

acetlc acid 2%.


acid remamder

75%. acetlc acad, toluic


dehyde together 25%
50%. water 22%.
ester 5%. phthahc

formic

acid 2%,

acid,

tolulc acid
acid 4%

formic

15%.

xylene. malelc acid I% as matelc


zene, water trace Icotumnl

azeotroplc

acetlc

mlxture

of xylene

water

and

acad. formal-

phthallde

5%.

Rayon

ZOO220

225.

anhydrtde,

ben-

Chemical
tdistdlation)

194.
302

14

Rayon

80

460

xx

Chemical
td~stdlatmn)

325.
350

70.
180

46

Chemical

160

27

Chemical

i1

140

33

140

144

and water

xylene toppmg of reactor ettluent (effluent


IS row
lure 01 wter.
acetic acid. benzolc acid. tolulc acad.
tolualdehyde.
acetophenone.
hydrocarbons).
vacuum
25 m. (column, vapors)

19.3%
zmc-carbonate
slurry,
sodlum
10%. sulbdes, sullur~c acid, ptt 3

33%.
5%

ammomum
apprarimataly.

chlorwk

33%.

water

sodium chromate

carbonate

remainder

Lumber
twwd
preserving)

a.7

<o 0001

0.0001
<0.0001

0 032cd

0.0013cd

<O.O001ad

0.0008

0 0074

0.0043

0.00043

00003

c.0 0001

0 032d
<O.OOOlcd
<0.0001ad

(continued)

Corrosion Resistant Materials Handbook

608
TABLE

VARIOUS

4.13:

STAINLESS

7JNC

HIGH NICKEL

fumes.

oil combustion

gases

ALLOYS-CLIMAX

MOLYBDENUM

(contdb

Average corrosion rates (ipy)

---

Pamt and
Varnish

210

Chemical

60.
80

lW116

22.4

4.5

*I

TYPE

NPE

,,PE

304

316

317

0.027a
0.027.a

0.013a

0.0024'a

09007

20

--

ALLOY
625

FLOSILICA,E

3&30X

rpprutmately.

free Ruosilicic

zinc fluosrlrcate
sdwc acrd l%,

concentrated
hydrochloric

zinc fluosdicate,
acrdO050.1%

varying

ZINC FORhsALDEHVOE
zinc formaldehyde
acid l-15%

saturated
44%

AND

Test
conditions

Corrosion mediums

zinc and leadchloride


(dust collector1

STEELS

solution,
acid 0.5-l%

concentration,

free

Ruo-

hydrochloric

xx

0.009c

co.012c
0.01 lc

106

33

xx

Textrle

115

25

xx

0.002

0.0904

Chemrcal

B.P.

34

xx

0.006

00011

solutron.

Chemrcal

212.
225

35

xx

bemg concentrated,
peroxrde and lead

Chemrcal

IOO180

48

xx

Chemical

220

Chemical

0.0011

0.001

0.0915

SLFOXLATE

zinc

dust,

sulfuric

solutron (evaporator)

approximately,
saturated
sulfurrc acrd trace

zmc-sulfate

36.30%
ZlnC-Sulfate
sdutmn
sodrum brchromate,
hydrogen
peraxrde (flash evaporator)
sullurrc

CryStalS.

36.5%.

IX

70

Chemrcal

sulfoxylate,

zincsulfate

acid 1%

acrd 66

Be Ievaporator)

36%. iron, sodrum. cadmium,


pH 5.2 (flash evaporator)

and copper impurrties.

corr*

0.026a

0.006

<0.0001

(0

0 0045

0.01
0.0097c

<O.OOOl

0001

<0.@301

C<O.OOCl

acid

2-3

Mining

90.
102

85

<0.0001

<0.0001

<0.0601
c<0.0001

0.4

g/l

Mining

90.
103

72

<06001d

<0.0001

<O.OoOl
c<0.0001

water

Chemical

61:
232

8.3

0.008lcd
0.008lcd

0.0047cd

approxi-

Chemical

219.
232

7.5

*I

0.0026cd
0.0026cd

0.0015bd

Metal
Iplating)

125
150

31

Metal

90102

317

rmc sulfate,
zmc chlorrde. ferrous sulfate,
ferric
sulfate, ferrrc chlorrde. chtorrde. water, in varying
concentratrons
(chlorinator)

Chemical

R.T.230

83

xx

xx

zmc-sulfate
solution, copper 10 mglt. iron hydroxrde. zmc ferrrte. lead sulfate, solids grab samples
showed pti 4 8 (Kelly filter)

Mming

113

48

xx

ztnc-sullate

Chemical

110

31

xl:

Chemical

60.
110

60

xx

25%
acrd zinc-sulfate
solution,
sulfuric
g/l. copper 2 g/l. ferrous ion 0.8 g/l
25%

neutral

zmcsullate

20%.

zmc chlorrde

8.8%.

20%
approsnnatcly.
mately. water
rmc~sullate

slrghtly

electrolyte,

acrd zuwsutfate

Z,RCON,U

solution.

ferrous

zmc

copper

sulfate

chtorrde

9%

1%.

pH 3

solutron,

copper

drrer fumes

I:

<O.OOOl

<O.OOOl

<O.OOOl

<O.OOOl

0.014cd

0.0033cd

O.ooOl

0.0001

0.0076bd
0.0068cd

0.0023ad
0.0004ad

0.0011

O.OOla

0.0046

CO.OOScd
C0.0082cd

TETRACHLORtDE

atmospherrc
fumes of ruconurm
drogen chlorrde. and chlorme gas

tetrachlorrde.

hy-

0.002

Nonferrous Metals and Alloys

TABLE 5.1:

ALUMINUM

ALLOY-ALCOA

Effect of

Hydrogen
Sulfide,
on Aluminum

Carbon
Dioxide
Alloys and Mild

Calculated

1 Aqueous

ALLOY
HYDROGEN

CARBON
2SH14
Aluminum..
3S-H14 Aluminum..
Mild Steel.. . . . . .

Dioxide

Volume of Metal bee


ln.~/in.~/yr.~

Solutions

SULFIDE-%

2SH14
Aluminum .................
3SH14
Aluminum .................
Mild Steel ........................

and Sulfur
Steel

1 Moist Vapors

HOURS

:i%:

:Ef

.0117

,.0204

DIOXIDE-96

HOURS

.. . .. . .. .. . ... .
. . . . . . ..; . . . . . . 1
... .. . ... .. . . . . .
SULFUR

DIOXIDE-32

2SH14
Aluminum .................
3S-H14 Aluminum .................
Mild Steel ........................

HOURS

:E
45.oooos

.0337
.0511
.5080

NOTES:
* Specimens
.064 x .36 r 1.2 exposed to distilled water saturated with gas and also the gas saturated
with moisture
at room temperature.
Daily cycle involved
bubbling
gas into water at 3 liters per hour for 8 hours
and sealing the system off for 16 hours:
s Test terminated
after one hour because of rapid attack of metal.
Resistance of Alumtnum Alloy 35 to Solid Chemicals
Under Conditions of Hlgh Humldlty

Non-Comoeire
Ammonium
dichromate
Ammonium
molybdate
Ammonium
nitrate
Ammonium
sulfate
Barium carbonate
Barium chloride
Barium nitrate
Borax
Boric acid
Calcium oxide
Chromium
trioxide
Aluminum

NOTES:

Citric acid
Potassium
thiocyanate
Sodium acetate
Sodium aluminum
fluoride
Sodium bicarbonate
Sodium chlorate
Sodium chloride
Sodium nitrate
Sodium sulfate
Triphenyl
phosphate

Border Line
Ammonium
chloride
Ammonium
fluoride
Copper sulfate
Ma rgt12
chloride
ox&

Gxroeive
Aluminum
chloride
Calcjum chlpride
Fom&ichlhlrlde
rmanganate
Sodium car E nate
Sodium fluoride

with 1.2% Mn.

I Shallow 2 diameter
impact extruded
containers
of aluminum
alloy 3s.
s Chemicals
placed in containers
as a thin (rf) layer and as scattered
aomll mounds.
s Containerr
exposed to an atmosphere
having a relative humidity
of approximately
100%
room temperature
for one month.

609

et

610

Corrosion Resistant Materials Handbook

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

ASSOCIATION

CORROSION RATE UNITS: The most commonly


accepted

unit for expressing

the rate of corrosion of a


mpy. One mil is

metal is mils per year, abbreviated

equal to 0.001.
Resistant = less than 1 mpy attack
Mild action = l-5 mpy attack
Moderate action = 5-20 mpy attack
Corrosive or corroded by = greater than 20 mpy

AL

ABIETIC ACID. Cz0H,,,02. Abietic acid has been


handled extensively in aluminum alloy equipment.
See also Ref: (1) p. 124, (2) p. 274, (3) p. 132,
(7) p. 3.
ACETALDEHYDE.
CH,.CHO.
In laboratory
tests, 1100 alloy was resistant to aqueous rolutions
of 0.1% to 100% acetaidehyde.
Acetaldehyde
has
been produced and handled in aluminum alloy tubing. heat exchangers, stills, tankage and shipping
drums. See also Ref: (I) p. 124. (2) p. I. (3) p. 120,
(4) p. 73. (7) p. 3.
ACETANILIDE.
CH,.CO.NH.C,H,.
Acetanilide
has been produced in aluminum alloyequipment including tanks. pipes, valves, pumps, refiux condensers, vapor lines, heating coils, evaporators and
reaction vessels. See also Ref: (I) p. 124. (3) p. 147.
(7) p. 3.
ACETIC ACID. CHJ.COOH.
The effect of acetic
acid on aluminum changes markedly with acid concentration and temperature.
The rate of corrosion is low when
exposed to acetic acid at all concentrations
up to anhydrous glacial acetic acid below 50C (IZZ?F); at
the boiling temperature
of the acetic acid, aluminum is corroded in solutions up to about 90% concentration of the acid. when the attack falls off rapidly to less than 5 mils per year and the rate remains
at that level until the anhydrous
condition
approaches. The corrosion rate of aluminum in glacial
acetlc acid. uhich normally contains 0. I to 0.2%
water. does not increase with temperature.
Boiling
anhydrous acetic acid is very corrosive to aluminum.
Removal of the last trace of water increases the corrosion rate one hundred fold, while conversely the
addition of 0.05% water stops the action. Aluminum has been used extensively in the manufacture
of acetic acid, in its storage and handling. and in
process equipment where acetic acid is one of the
raw materials. In the manufacture
of acetic acid
from wood. the following aluminum
alloys have
been used: for storage tanks. alloys 1100. 3003,
5083. SOSZ: for stills, alloys 3003. 5052, hU61: for
condensers. alloys 3003. 5052. 6061; for piping, alloys 1100. 3003. 6061; for ulves and fittings. alloys
356.0.
514.0;
and for manholes.
etc..
alloy
356.0. Alloys 1100.3003,5154,
and 5052 have been
the most commonly used for tanks and tank cars for
storage of pure glacial acetic acid solutions at normnl temperatures.
Aluminum alloys have been bed
extensively in the textile industry for itorape fxiltties for xstic acid solutions down to 80% ioncentrations. although they are not recommended
to
rtore acid of Ins than 90% concentratism.
Some
tank failures have been reported by the textile industry in the storage of 80-84% acetic acid rolutions. Susceptibility of aluminum alloys to corrosive
attack in acetic acid solutions is increased greatly by
inorganic halides or reducing acids and reducing or-

ganic acids, esters and aldehydes normally encountered in the production and use of acetic acid. The
presence of formic acid should be avoided. Potassium sulfate and bromide have no influence at ormal temperatures. but accelerate attack at elevated
temperatures.
Aluminum
acetylation
equtpment
has been used I the cellulose acetate iwintry.
Many large crornge tanks. tank can and shipping
drums have been tired for handling acetic acid.
See ~1s Ref: (I) p. 124. 12) pp. 3,
4. (3) pp. 21. 121. 136. 127. (4) pp. 22. 23. 24. 25,
27. 28. 29, 30. 31. 34. 61. h2. 64. 92, 1I I. (01 p. 20.
(7, p. 3.
ACETIC ANHYDRIDE.
(CH,,CO):O.
In limited
laboratory tests. acetic snhydride caused moderate
(I3 mpy) attack of 3003 alloy at IOOC (212F). in
other tests, acetic anhydride caused mild attack of
II00 alloy at ambient temperature
and at 50C
(122F). Acetic anhydride
had mild action (-5
mpy) at the boiling point.
Aluminum
and Its alloys have been used for heat exchangers,
reaction vessels, piping, storagetanks,
drums and
tank cars for handling
acetic anhydride.
Alloy
A356.0 valves have been used for handling acetic
anhydride. See also Ref: (I) p. 124. (2) p. 13. (3) p.
128, (7) p. 5.
ACETONE.
CH.CO.CHJ.
Aluminum and AI-.Mg
alloys are resistant to acetone in laboratory tests at
all temperatures.
Aluminum has been used with acetone for piping, (tills. heat exchangers and storage.
Mild corroGon has been reported in an aluminum
rtorage tJ.nk for redistilled
acetone. Alloy 356.0
va!~es have been used for handlmg acetone. See also
Ref: (I) p. 124. (2) p. 17. (3) pp. 121, 242. (7) p. 5.
ACETONITRILE.
CH,.CN. Alloy 3003 was resistant to acetonitrile at 100C (212F) in laboratory
beaker tests. See also Ref: (3) p. 142. (5) p. 9.
ACETOPHENONE,
ORTHOHYDROXY.
CH,COC,H,OH.
Limited laboratory tests indicated
that acetophenone was mildly corrosive to 3003 alloy
under refluxing or boiling and condensing conditions. See also Ref: (1) p. 124, (2) p. 20. (3) p. 121.
(7) p. 7.
p-ACETOTOLUIDIDE.
CH,CONHC,H&H,.
Acetotoluidide
has been distilled and handled in
aluminum alloy equipment. See also Ref: (3) p. 144.
(7) p. 7.
ACETYLSALICYLIC
ACID.
CH,.CO.OC,H,COOH.
In the production of acetylsalicylic acid, the raw materials, acetic anhydride
and salicylic acid, and the final product have been
handled in aluminum alloy storage tanks. piping
and reaction vessels. See also Ref: (2) p. 26, (3) p.
130. (5) p. 9. (7) p. 7.
ACONITIC ACID. C,H,(COOH),.
In limited laboratory tests, aqueous solutions of aconitic acid
(0.25% to 50%) caused moderate attack (-6 mpy)
of 3003 alloy at IOOC (212F). See also Ref: (10) p.
77.

alloy
Aluminum
ACROLEIN.
CH?: CHCHO.
equipment has been used in the manufacture
and
shipment of acrolein. See also Ref: (I) p. 124. (3) p.
120.
ACRYLIC ACID. CH?:CHCOOH.
Alloys 3003.
SOSZ. and 5454 were resistant to glacial acrylic acld
at ambient conditions. Glacial acrylic Acid has been
shipped in aluminum alloy drums. See also Ref: (I)
p. 124. (3) p. 128. (5) p. 9. (7) p. 7.
ACRYLONITRILE.
CH?:CHCN.
In laboratory
tests. alloy 3003 uu resistant to acrylonltrilr.
acrylonitrile saturated uith water and water raturated
with acrylonitrile at room temperature and u hen exposed to boiling acrylonitrile.
Aluminum alloy industrial equipment has been used for the prodoction and shipment
of acrylonitrile
and ~15 in
further transforming
it into acr)lonitr!le fiber. See
also Ref: (I, p. 124. (3) pp. 112. 233. (1 p. -.
ADIPIC ACID. HO,C(CHz)KO!H.
ln iclborntory
tests, adiplc acid in 20% nod SOW,>concentrations
caused mild attack of alloy 3003. The acid and its
salts have been piped, rhipped and stored m Jlumiurn. See also Ref: (3) p. 130. () p. 7.
AEROSOLS.
A generic term applied to pxkc of
various liquid products under pressure. .ilum~num
alloy cans have been used to package aerosol formulations. See also Ref: (3) pp. I IO. 239.
ALDOL. CH,.CH(OH).CH2.CH0.
In laboratory
rests. 3003 and 1100 alloys were resistanr to aldol at
100C (212F) but at the boiling point alloy 3003
was mildly attacked (4 mpy). Aldol has been handled and shipped in aluminum alloy containers. See
also Ref: (3) p. 121.
ALKALINE SOLUTIONS.
Alkaline solutions generally have some action on aluminum alloys. The
pH of these solutions alone is not a reliable indicator
of the performance
of aluminum alloys. Usually.
weak bases such as ammonium
hydroxide, hexamine, alkanolamines
and their aqueous solutions
can be handled in aluminum because a protective
film forms on aluminum after an initial period of
reaction. Solutions made alkaline by hydrolysis of
basic salts such as sodium carbonate form protective films on AI-Mg alloys containing 3.5% or more
magnesium. Strong bases such as sodium hydroxide
and potassium hydroxide dissolved in water are very
corrosive and should not be handled in aluminum.
See also Ref: (4) pp. 35. 37.
ALKYL SODIUM SULFATE.
RSO,Na. Alkyl sodium sulfates have been stored in aluminum alloy
containers. See also Ref: (3) p. 246.
ALLYL ALCOHOL.
CH>:CHCH?OH.
In laboratory tests under refluxing conditions. 3003 alloy was
resistant to ally1 alcohol. See also Ref: (3) pp. 22.
114. (5) p. 10. (7) p. 9.

(continued)

Nonferrous Metals and Alloys

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

ALLYL ISOTHIOCYANATE.
CH,:CHCH,NCS.
Aluminum alloy columns and condensers have been
used lo the production of all)1 isothiocyanate.
See
also Ref: (3) p. 138.
ALUMINA.
AI?O,. Alumina has been stored in
aluminum alloy containers and shipped in aluminum alloy railroad cars. See also Ref: (3) p, 77. (4)
p. 5.
ALUMINUM
ACETATE.
AI,C~H,OzlI. In limited
laboratory tests. aqueous solutions of aluminum acetate (0.2Svn to 25%) cauwd mild attack ( - 3 mpy)
of alloy 3003 at ambient temperature.
,Aluminum
alloy equipment has been used in the manufacture
of aluminum acetate. See also Ref: (I) p, 124, (3) p.
78. 15) p. IO. () p. 9.
ALUMINUM
AMMONIUM
SULFATE.
AINH,,SO,):. I2 H!O. Laboratory tests \howed that
dlloys 3003 md 5154 were re*i(tdnt to solId aluminum an?nwnlum \ulfare under conditions of 100%
relat~w humidity at amtvent temperature.
ALUMINUM
BORATE.
2 AI>O,.B,OJ.~
Laboratory tests showed that alloys 3003 and
were resistant to solid aluminum borate under
ditions of 100% relative humidity at ambient
perature.

HKJ.
5154
contem-

ALUMINUM CHLORIDE.
AICI,. Anhydrous aluminum chloride has been stored and transported in
aluminum alloy containers. Moist aluminum chloride and aluminum chloride solutions are vety COP
rosive to aluminum
alloys. The severity of attack depends upon the quantity of free hydrochloric acid
produced by hydrolysis and on the temperature. See
also Ref: (I) p. 125. (2) p. 37. (3) p. 77. (7) p. 11.
ALUMINUM FLUORIDE.
AIF,. Laboratory tests
showed that alloys 3003 and 5154 were reSiStant
to
solid aluminum fluoride under conditions of 100%
relative humidity at ambient temperature.
Aluminum fluoride solutions are corrosive to aluminum.
See also~Ref: (3) p. 77, (7) p. 1 I.
ALUMINUM
FORMATE.
AI(HC02),.
Laboratory tests indicated that 1% and IO% solutions of
aluminum formate caused highly localized attack of
alloy 1100 at ambient temperature.
However, aluminum equipment has been used successfully in the
production of aluminum formate. See also Ref: (I)
p. 125, (3) p. 78.
ALUMINUM
NITRATE.
AI(N0,),.9
H*O. Solid
aluminum nitrate was corrosive (50 mpy) to 3003
and 5154 alloys in laboratory tests conducted under
conditions of 100% relative humidity at ambient
temperature.
Aluminum
nitrate has been stored
and shipped in aluminum alloy containers. See also
Ref: (I) p. 125, (3) p. 78. (7) p. 11.
ALUMINUM OXALATE. AIJ(C?OJ),.H~O. Laboratory tests indicated that alloys 3003 and 5154 were
resistant to solid aluminum
oxalate under conditions of 100% relative humidity at ambient temperature.
ALUMINUM STEARATE. AI(C,,HJ5.02),.
Laboratory tests indicated that alloys 3003 and 5154 wre
resistant to solid aluminum
rtearate under conditions of 100% relative humidity at ambient temperature.
ALUMINUM SULFATE.
Al?(SO,),. 18 H>O. Laboratory tests showed that alloys 3003 and 5154 were
rewtant to solid aluminum sulfate under conditions
of 100% te!ative humidity at ambient temperature.
Laboratory tests made in aqueous solutions indi.
cated mild action on alloy 1100 by solutions of .Ol%
to 25% aluminum sulfate. Aluminum
piping has
been used fur aluminum sulfate solutions in the pa-

ASSOCIATION

611

(continued)

per industry. Alloy 356.0 valves have been used for


handling aluminum sulfate solutions. See also Ref:
(1) p. 125, (2) p. 42. (3) p. 77, (7) p. Il.
ALUMINUM TABTRATE.
AIJ(CIHIO,),.
Laboratory tests indicated that alloys 3003 and 5154 were
resistant to solid aluminum
tartrate under conditions of 100% relative humidity at ambient temperature.
2-AMINOETHANOL.
NHzCHICHzOH.
See monoethanolamine.
See also Ref: (3) p. 145.
AMINOETIIYLETHANOLAMINE.
NH,CH,CH~NHCH,CH,OH.
In laboratory
tests,
3003 alloy was resistant to aminoethylethanolamine
at temperatures from ambient to 204OC (40f~F). In
other laboratory tests under refluxing conditions,
aminoethylethanolamine
was very corrosive to alloy
3003. Aluminum alloy tanks have been used to store
aminoethylethanolamine.
See also Ref: (7) pp. 12,
13.
AMMONIA.
NH,. (See also ammonium hydroxide) In laboratory tests. 1100, 3003 and other copper free aluminum alloys have been found to be resistant to dry, gaseous ammonia even at elevated
temperatures. Alloys 1100 and 3003 were also resistant to pure anhydrous liquid ammonia but contaminants can result in pitting of the metal. In dilute
ammonia solutions (up to - 10%) the initial rate of
attack is controlled by diffusion of OH- ions to the
aluminum surface and is a function of pH. Passivation of the aluminum surface occurs when a critical
amount of corrosion product builds up at the aluminum surface forming a protective film. If solution
saturation of soluble corrosion product is relieved
before passivation. film formation may not occur. A
careful analysis of exposure conditions is required in
using aluminum alloys in dilute ammonia. Aluminum alloys have been used in refrigeration systems
handling liquid ammonia containing up to 5% water and in producing synthetic ammonia. Aluminum alloy compressors. heat exchangers. evaporators. condensers.
and piping have been used in
producing ammonia. Aluminum alloy pressure vessels have been used for storing and tranrponing
ammonia. Carbon dioxide and hydrogen sulfide have
been used to inhibit corrosion under condensing
conditions. See Ref: (1) p. 125. (2) p. 46, (3) pp. 43,
S8. 61. 223, (7) p. 14.
AMMONIUM
ACETATE. CH,COONH,.
Solid
ammonium acetate caused mild attack ( - 3 mpy) of
alloys 3003 and 5154 in laboratory tests conducted
under conditions of 100% relative hunvdiry at ambient temperature.
In other laboratory tests. I, 5
and 10% solutions of ammonium acetate at ambient temperature caused mild attack of 3003 alloy
while the alloy was resistant to concentrated
solutions. Dry ammonium acetate has been stored and
transported in aluminum alloy containers. See also
Ref: (1) p. 125, (3) p. 71. (5) p. 11. (7) p. 1.5.
AMMONIUM
BICARBONATE.
NH,HCO,. Aluminum alloy equipment has been used in the production of ammonium
bicarbonate.
See also Ref:
(1) p. 125. (3) p. 67. (5) p. 11. (7) p. 15.
AMMONIUM
CARBAMATE.
NHzCOO.NH,.
Ammonium
carbamate
has been produced
and
handled in aluminum alloy equipment,
including
tanks, piping and subliming equipment.
See also
Ref: (1) p. 125, (3) p. 68.
AMMONIUM
CARBONATE.
(NH,)&O,.
Solid
ammonium
carbonate
caused mild attack (-2
mpy) on 5154 alloy Hhile 3003 alloy was resistant to
solid ammonium carbonate in laboratory tests conducted under conditions of 100% relative humidity
at ambient temperature. Other laboratory tests in-

dicated that alloy 3003 was resistant to 1%. 5% and


50% aqueous solutions of ammonium
carbonate.
Aluminum alloy storage tanks and piping have been
used for handling ammonium carbonate. See also
Ref: (I) p. 125, (3) p. 67. (7) p. 15.
AMMONIUM CHLORIDE.
NH,CI. In laboratory
tests at ambient temperature, aqueous solutions (up
to 20%) of ammonium chloride caused mild attack
( - 3 mpy) on 1100 alloy with localized pitting occurring at all concentrations.
Solid ammonium chloride resulted in moderate attack ( - 6 mpy) on alloy
3003 in other laboratory tests under conditions of
100% relative humidity at ambient temperature.
Concentrated
solutions of ammonium
chloride at
the boiling point are very corrosive. See also Ref: (I)
p. 125. (2) p. 50. (3) p. 62. (7) p. 15.
AMMONIUM DICHROMATE.
(NH,)&r?O-.
Alloy 3003 was resistanr to solid ammonium dichromate in laboratory tests under conditions of 100%
relative humidity at ambient temperature.
Similar
results were obtained in other laboratory tests involving aqueous solutions (up to IO%) of ammonium dichromate at ambient :empcrature.
See alto
Ref: (I) p. 125. (3) p. 0. (71 p. 17.
AMMONIUM
FLUORIDE.
NH,F. In laboratory
tests, solid ammonium fluoride caused mild attack
(-3 mpg) of alloy 3003 under conditions of 100%
relative humidity at ambient temperature.
In other
laboratory tests. 505 solutions of ammonium fluoride uere very corrwi\e
co alloy 3003 dt 93C
(ZOOF), but at ambient temperature.
II00 alloy
was resistant to solutions of 10% to 25%. See also
Ref: (I) p. 125. (3) p. 63. (7) p. 17.
AMMONIUM
HYDROXIDE.
NH,OH. In laboratory tests, ammonium
hydroxide solutions have a
rapid initial reaction on aluminum alloys which decreased dramatically
as concentration
and pH increase. The rate of attack of dilute ammonium hy
droxide solutions was moderate ( - 6 mpy) for 1100
alloy but decreased to less than 1 mpy when the concentration
reached 10 N. Similarly, the rate was
mild (- 2 mpy) as the pH of the solutions reached
13. These decreases have been attributed to film formation on aluminum
alloys which has been promoted by pre-saturation
of the solution with aluminum. It has also been retarded or prevented by the
presence of precipitation
resulting from over saturation. Alumin~lm alloys have been used in processing
equipment. including pressure vessels, piping. storage tanks and tank cars. See also Ref: (I) p. 125. (3)
pp. 43, 58. 61. (4) pp. 34. 35. 36, 37. 69 (7) p. 17.
AMMONIUM IODIDE. NHJ. Solid ammonium
iodide caused mild attack (- 2 mpy) of 3003 alloy
and mild attack (-4 mpy) with blistering of alloy
5154 in laboratory tests conducted under conditions
of 100% relative hun idity at ambient temperature.
See also. Ref: (3) p. 63.
AMMONIUM LACTATE.
NH,C,HjO,.
In laboratory tests at amb;ent temperature.
30% and 30%
aqueous solutiors
of ammonium
lactate caused
mild attack ( - 5 mpy) on alloy 3003. while at boiling
temperature. 30% solutions were very corrosive. See
also Ref: (3) p. 71.
AMMONIUM
MOLYBDATE.
(NHJzMoO,.
Alloy 3003 was resistant to solid ammonium molybdate in laboratory tests conducted under conditions
of 100% relative humidity at ambient temperature.
See also Ref: (7) pp. 16, 17.
AMMONIUM NITRATE. NH,NO,. See also AMMONIUM NITRATE (AMMONIATED).
In laboratory tests. alloy 3003 was found to be resistant to

(continued)

Corrosion Resistant Materials Handbook

612

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

dry ammonium nitrate at ambient temperature and


to aqueous solutions of ammonium nitrate at ambiznt and elevated temperatures
(up to 18OF). Ammonium nitrate solutions used mainly for fertilizers,
have been produced. piped and stored in aluminum
alloy tank cars in concentrations
up to 83% by
weight and at rempcratures up to 12 I C (250F). In
the hot 83% solution. corrosion can be stimulated
particularly at welds by the presence of Free nitric
acid. To avoid this, the pH of the hot solution
should be maintained above 6 and rhe solutigln agitated to maintain d uniform pH. Welded 3003 alloy
is more tolerant of these acidic conditions and has
been used For tank bottoms and piping. Mercury
contamination can also be a serious problem in ammonium nitrate service and must be avoided. Roofing, siding, and prilling towers have been used in
ammonium nitrate plants. See also Ref: (1) p. 125.
(2) p. 55. (3) p. 66. (7) p. 17.
AMMONIUM NITRATE (AMMONIATED).
Ammoniated solutions of ammonium
nitrate have
been shipped, stored, and handled in aluminum alloyequipment.
See also Ref: (1) p. 125. (2) p. 55. (3)
p. 66.

ASSOCIATION

(continued)

alloys have been used For piping, coolers


and tanks with ammonium sulfide. See also Ref: (I)
p. 125. (3) p. 63. (7) p. 19.

Aluminum

AMMONIUM TH~OCYANATE. NH,SCN. AIIO~S


3003 and 5154 were resistant to solid ammonium
thiocyanate

in

conditions

of

temperature.

laboratory
100%

tests

relative

In other

conducted

humidity

laboratory

under

at ambient

Aluminum

used to handle
Ref: (I)

alloy

tanks

ammonium

and piping

have been

thiocyanate.

See also

A,MMONlUM PERSULFATE. (NH,),StOn. Alloys 3003 and 5154 were resistant to solid ammonium persulfate in laboratory tests conducted under
conditions of 100% relative humidity at ambient
temperature. See also Ref: (I) p. 125. (2) p. 58, (3)
p. b5. (7) p. 17.
AMMONlUM PHOSPHATE.
Monobasic NH,H,PO,. Dibasic (NH&HPO+
The
action of ammonium phosphates on aluminum is a
Function of both the concentration and the temperature. Solutions of the monobasic salt are less corrosive than are solutions of the dibasic salt and the
rate of attack decreases with time. Laboratory tests
showed that solutions of the monobasic salt up to
28% caused moderate attack (- 10 mpy) on alloy
3003. Solutions of the diammonium
talt are corrosive to aluminum alloys and should not be used with
aluminum
equipment
unless inhibitors
are employed. See also Ref: (I) p. 125. (2) p. 60.
AMMONIUM SULFAMATE. NH,SO,NHz. Laboratory tests indicated that II00 alloy was resistant
to aqueous solutions of ammonium
sulfamate at
ambient temperature. See also Ref: (7) pp. 17. 18.
AM,MONlUM SGLFATE. (NH&SO,.
In laboratory tests, alloy 3003 was resistant to solid ammonium sulfate under conditions of 100% relative humidity at ambient temperature.
Other laboratory
tests showed
45%

temperature.
handling

1100alloy

that

solutions

was resistant

of ammonium
Aluminum

ammonium

alloys
sulfate.

to 1% to

sulfate at ambient
have been used for
See also Ref:

FF) p.

125. (2) p. 62, (3) p. 64, (7) p. 19.

AMMONIUM
tests. 1100 alloy

SULFIDE. (NH,)*S. In laboratory


was resistant

tions of ammonium

sulfide

to 15%

at ambient

to 40%

AQUA REGlA. A mixture of nitric and hydrochloric acid. In laboratory tests, aqua regia was very
corrosive to all aluminum alloys. See aiso Ref: (2) p.
80, (3) p. 38.

p. 126, (2) p. 66. (3) p. 69, (7) p. 19.

THIOGLYCOLATE.
HSCH&OONHI.
Ammonium
thioglycolate
has
been handled and shipped in aluminum alloy containers. See also Ref: (3) p. 71.
AMMONIUM

AMMONIUM THIOSULFATE.
(NH,),S,O,.
Laboratory
tests showed that alloy
3003 was resistant to aqueous solutions of ammonium thiosulfate at ambient temperature. Aqueous
ammonium thiosulfate solutions have been shipped
in aluminum drums. See also Ref: (3) p. 65. (7) p.
19.

AMMONIUM
OXALATE.
(NH&C20,.Hz0.
Solid ammonium
oxalate caused mild attack ( - 2
mpy) of 3003 alloy in laboratory tests conducted un- AMYL ACETATE. CHJ(CH1)lOOCCH,.
In laboder conditions of 100% relative humidity at ambient
ratory tests, alloys 3003 and 5052 were resistant to
temperature. In other laboratory tests, 1% solution
amyl acetate at temperatures
up to 204C (4OOOF).
of ammonium
oxalate at ambient
temperature
In other laboratory tests, condensing amyl acetate
caused mild attack ( -3 mpy) and 4% solution was caused mild attack ( - 3 mpy) of alloy 3003. Pure
corrosive to alloy 3003; while at the boiling temperaamyl acetate has been stored in aluminum
alloy
ture. 1% solution was very corrosive. See also Ref: tanks. See also Ref: (1) p. 126, (2) p. 68. (3) p. 136.
(I) p. 125. (3) p. 71. (7) p. 17.
(7) p. 19.
AMMONIUM PERCHLORATE.
NH,CIO,. Aluminum alloy equipment has been used For producing and handling ammonium perchlorate. See also
Ref: (3) p. 63, (7) p. 17.

APPLE BRINE. Limited laboratory tests indicated


that 5052 alloy was resistant to apple brine at 100C
(212F).

tests, alloys 3003,

5052 and 6061 were resistant to 1. 25 and 50% solutions of ammonium


thiocyanate
at ambient temperature.

sol. (chlorophenoxy) acetic acid, copper oxychloride


(0.5% Max.) and calcium polysulfides.
In laboratory tests most insecticides were corrosive to aluminum alloys. See also Ref: (IO) p. 101.

AJMYL ALCOHOL. CH,(CH,),OH.


Limited laboratory tests indicated that alloy 3003 war resistant to
amyl alcohol at 100C (212F). Amyl alcohol war
very corrosive to 204C (JO03F) and at the boiling
point. Aluminum alloys have been used to handle
amyl alcohol. See also Ref: (2) p. 71, (3) p. 113, (7)
p. 21.
AMYL .MERCAPTAN. CH,(CH2),SH. Amyl mercaptan has been stored in aluminum alloy tanks.
See alu, Ref: (3) p. 133. (7) p. 21.
AMYL
Laboratory

VALERATE.
tests indicated

ant to concentrated

amyl

(CH,),CHCH2COOCsH,,.
that

ARGON. A. Aluminum alloys have been used For


pressure vessels and containers handling argon. See
also Ref: (3) p. 35.
ARSENIC ACID. H,AsO,. In limited laboratory
tests, concentrated arsenic acid *as very corrosive to
6061 alloy at ambient temperature.
See also Ref: (3)
p. 49, (7) p. 25.
ARSENIC TRIOXIDE. As,O,.
Alloys 3003 and
5154 were resistant to solid arsenic trioxide in laboratorv tests conducted under conditions of 100%
relative humidity at ambient temperature. See also
Ref: (3) p. 49. (7) p. 25.
ASBESTOS. Laboratory tests have shown that wet
asbestos will cause corrosion when in intimate contact with all aluminum alloys. This has been confirmed by service experience. Dry asbestos does not
cause corrosion of aluminum alloys. See also Ref:
(I) p. 126. (5) p. 12.
ASPARTIC ACID. HOOC.CH2CH(NHI).CDDH.
In limited laboratory tests, alloy 3003 was resistant
to aspanic acid at 204C (4M)F). See also Ref: (I)
p. 126. (3) p. 146, (7) p. 25.
ASPHALT. Bituminous
substances
From petroleum or purified tar. Aluminum alloy piping and
tankers have been used For handling asphalt. See
also Ref: (1) p. 126. (3) p. 221.
ASPIRIN. CH,COOC,H,COOH.
Aluminum
alloys have been used in reaction and crystallization
equipment for the preparation of aspirin. See also
Ref: (2) p. 26. (3) pp. 130. 239.

1100 alloy was resist-

valerate

at ambient

perature.
Amy1 valerate
is handled
containers.
See also Ref: (7) pp. 20.

tem-

in aluminum

21.

ANILINE. C,HsNH,.
Laboratory
tests indicated
that 1 LOOalloy was resistant to aniline vapors at ambient and 75C (167F) temperatures.
However,
concentrated solutions of aniline were corrosive to
1100 alloy at the boiling Point 184C (364OF). Aluminum alloy equipment has been used in procesru
involving aniline. See also Rcf: (1) p. 126. (2) p. 73,
(3) p. 144, (7) p. 21.
ANISE OIL. Aluminum alloy tanks have been used
for storing anise oil. See also Ref: (8) p. 12.5.
ANTIFREEZE SOLUTIONS. Water Solutions of
Methyl Alcohol, Glycerin or Glycol. Laboratory
tests have shown that alloys I100 and 3003 were resistant to many commercial antifreeze solutions. In
automotive
applications,
the antifreeze
solution
must be maintained at the proper concentration
in
order that sufficient inhibitor is present to prevent
deposition corrosion by heavy metal ions picked up
From dissimilar metals in the system. Aluminum alloys have been used for automotive radiators and
heat exchangers. See also Ref: (I) p. 126. (3) pp. 23.
114, 115. 136.240.

ATMOSPHERES. Most aluminum alloys have resisted atmospheric


weathering in laboratory controlled tests and have been widely used For architectural and structural purposes. The earliest known
example of aluminum exposed to the weather is the
cap piece on the well-known Washington
Monument erected in 1884. That 100 ounce casting was
examined in 1934 and again in 1964. Both examinations confirmed the resistance to weathering of the
cap, as evidenced by the legibility of the original engraved inscriptions. The earliest known use of aluminum sheet For a roof is Found on the St. Cioacchino church in Rome. Italy. Installed in 1897.
examination
after 70 years disclosed a measured
corrosion depth of 0.06 mm (2.5 mils) average. A
number of applications of aluminum For electrical
power cables began early in the present century and
continue in use today. An early stranded aluminum
power cable in service near Hartford, CT, For 51
years. exhibited
an average measured corrosion
depth of 0.109 mm (4.3 mils). Aluminum castings
have been used For thousands of spandrel panels on
many buildings such as those in the Radio City complex completed during 1432 in New York and the
Koppers Building completed during 1929 m Pittsburgh.
pleted

PA. The Empire


State Building
during
1929 in New York City

gZS.OW pounds of aluminum

applied

also comhad about

to its exterior.

SOlU-

temperature.

ANTIPESTICIDES, INSECTICIDES.

Dinitrocre-

(continued)

Nonferrous Metals and Alloys

TABLE 5.2:

ALUMINUM

The A. 0. Smith Bulldmg completed


Milwulkee.

Wisconsin.

ner of aluminum
niltmn

curtain

during 1930 m

may hdve been the forerunwall corwruction.

iu 1962 of a cast panel from

mg disclosed

ALLOYS-ALUMINUM

the Smith

ExamiButld-

average

measured depth of attack to


be 0.053 mm (2.1 mils) in the 6.35 mm (250 mils)
thick metal. Aluminum
residential
roof shingles
were marketed beginning in 1928 and examination
of such a roof after 30 years in an industrial atmosphere revealed an average depth of corrosion pmetration of 0.076 mm (3.0 mils) in the 0.508 mm (20
mils) thick 3003 alloy sheet. Since 1930. many applications of aluminum roofing and siding have been
made throughout the world. Alclad aluminum industrial roofing and siding have been used for many
years in a wide variety of highly industrial
atmospheres. Corrosion depth is arrested at the claddingcore interface under the effect of cathodic protection
by the 1% zinc-bearing
aluminum alloy cladding.
Port facilities throughout the nation have used large
quantities of those alclad aluminum sheet products
for transit sheds, storage buildings and the like. Literally hundreds of studies have been made on aluminum alloys after service for many years in industrial
and seacoast localities.

B
BARIUM CARBONATE.
BaCO,. Allo) 3003 uas
resistant to solid barium carbonate in laboratory
tests conducted under conditions of IOOYGrelative
humldity at amhient temperature.
See also Ref: (3)
p. 76, (7) p. 27.
BARIUM CHLORIDE.
B&I,.2
H20. Alloy 3003
was resistant to solid barium chloride in laboratory
tests conducted under conditions of 100% relative
humidity at ambient temperature.
In other laboratory tests. 1100 alloy was resistant to 0.001 to 0.4 N
solutions of barium chloride at ambient temperature. See also Rcf: (I) p. 127, (2) p. 84. (3) p. 73, (7)
p. 27.
BARIUM HYDROXIDE.
Ba(OH),.B
H,O. Laboratory tests have shown that aqueous solutions of
barium hydroxide are very corrosive to aluminum alloys. Aluminum alloys are not ordinarily used with
barium hydroxide solutions. See also Ref: (1) p. 127.
(3) p. 72, (7) p. 27.

ASSOCIATION

hminued)

num alloys have been used for fermenters, yeast tubs.


culture tanks, carbonating
tanks, coolers, storage
tanks. beer kegs and other containers. Aluminum alloys have also been used for wart receiving and settling vessels and filtering apparatus. Aluminum alloy
beer cans are coated internally. See also Ref: (I) p.
127. (3) p. 202. (4) pp. 94, 95, %. 97, 128, (6) p. 10.
BEESWAX. Conrainr about 8@G myricin. Beesuax
ha> been used as a prorecti\e coating for alummum
allo! strw corrouon cracking test fixtures. See also
Ref: (I) p. 127. (3) p. 225.
BENZALDEHYDE.
C,,H;CHO.
In laborator)
tests. alloys 3003. 5052 and 51.54 uere resistant to
benzaldeh\de
at 5OC (122F) and 2WC (400 F).
Under boiling and condensing conditions, benzaldehyde caused moderate attack u-lth localized pnting
(- 8 mpy). In other laboratory tests. the addition of
water to brnzaldehyde
caused moderate corrosion
with the maximum attack (- I2 mpy) of 1100 allo!
developing at about a IO?& mixture of benzaldehyde
in water. Aluminum alloy drums and tanks, dinillation columns. condensers and dephlegmators
have
been used to handle pure henzaldehyde. See also Ref:
(1) p. 127. (2) p. 87. (3) p. 120. (7) p. 27.
BENZENE. C,&,. In laboratory tests. alloys 3003.
5052,5l.S4 and 6&l were resistant to benzene at ambient and SOY (122F) temperatures. The addition
of moisture increases the corrosivity of benzene
towards aluminum alloy\. Aluminum equipment has
been used for stills, fractionators,
dephlegmators.
condensers. tanks and heat exchangers for benzene.
See also Ref: (I) p. 127. (2) p. 90. (3) pp. 104. 223.
242, (7) p. 31.
BENZENE HEXACHLORIDE.
C,H,CI,.
Aluminum allob equipment has been used in handling benzene hexachloride.
CAUTION:
see Halogenated
Hydrocarbons. See also Ref: (3) p. 110, (7) p. 31.
BENZ&
C,HrCOCOC,Hs.
In limited laboratory
tests. alloy 3003 was resistant to benzil at 204C
(400F). Localized pitting was evidenced on the
3003. See also Ref: (3) p. 121. (7) p. 31.
BENZOIC ACID. C,H:,COOH.
Alloys 3003 and
5154 were resistant to solid benzoic acid in laboratory
tests under conditions of 100% relative humidity at
ambient temperature. Aluminum alloy sublimating
equipment. hoppers and piping have been used in
the production of benzoic acid. See also Ref: (1) p.
127, (2) p. 96, (3) p. 132. (7) p. 29.

BARIUM NITRATE.
Ba(N0J2.
Alloy 3003 was
resistant to solid barium nitrate in laboratory tests
under conditions of 100% relative humidity at am- BENZOYI. CHLORIDE.
C,HJOCI.
Limited labbient temperature.
In other laboratory tests. 1100 oratory tests indicate that benzoyl chloride is cormalloy was resistant to dilute aqueous solution of sive to high purity aluminum at boiling temperature
barium nitrate at ambient temperature. See also Rel: 198C (388F). CAUTION:
See Halogenated Hy(3) p. 75, (7) p. 27.
drocarbons. See al5o Ref: (1) p. 127, (3) p. 133.
BmM
SULFIDE.
BaS. In limited laboratory
tests, a 10% aqueous solution of barium sulfide was
corrosive to 3003 alloy at ambient temperature and at
50C (122F). See also Ref: (3) p. 74. (7) p. 27.
BAUXITE. Ore of aluminum.
containing a high
content of hydrated aluminum oxide together with
lesser amounts of oxides of iron. silicon and titanium
and some minor impurities. Aluminum alloys have
been used for transporting bauxite and as building
components in bauxite plants. See also Ref: (8) pp.
loo. 190.
BEANS. Beans have been canned in coated aluminum alloy cans. See also Ref: (6) p. Il.
BEER. Laboratory tests have shown that beer causes
mild attack of most aluminum alloys and even less of
high purity aluminum. In the brewing of beer, alumi-

BENZYL ACETATE. C,H,CH,OOCCH,.


In laboratory tests, alloy 3003 was resistant to benzyl acetate at 1005C (212F) but was corroded under boiling
and condensing conditions.
BENZYL ALCOHOL. C,H,CH,OH.
In laboratory
tests. alloy 3003 was resistant to benzyl alcohol at
2O4C (4OOF) and under refluxing conditions. Benzyl alcohol has heen handled in aluminum alloy
tanks. See also Ref: (3) p. 113, (7) p. 33.
BENZYL CHLORIDE. C,H:,CHICI.
High purity
aluminum was resistant to benzyl chloride in lahoratory tests at ambient temperature.
Benzyl chloride
caused corrosion of other alloys, increasing as temperature increased. CAUTION: See Halogenated
Hydrocarbons. See also Ref: (2) p. 100. (3) p. I I I,
(7) p. 33.

BERYLLIUMCHLORIDE.

613

BeCl,. Aluminum

aIloy

contamers have been used for storing and transponing beryllium chloride. See also Ref: (2) p. 102. (3)
p. 73. (7) p. 35.
BISMUTH NITRATE.
Bi(NO,),S
H,O. Alloys
3003 and 5154 were resistant to solid bismuth nitrate
in laboratov tests conducted under conditions of
100% relative humidity at ambient temperature. See
also Ref: (8) p. 106.
BITUMINOUS
PAINT.
Laboratory
tests have
shown that bituminous paint is protective to aluminum alloys. See also Ref: (I) p. 127, (3) pp. 218.221.
(4) p. 141.
BLACKBERRY NICE. In laboratory tests. blackberry pomace and juice mixture was corrosive to 3003
alloy at 100C (212F). See also Ref: (4) pp. 88. 89.
BORDEAUX MIXTURE.
A mixture of cupric sulfate, calcium oxide. and water. Aluminum
alloy
equipment has been used to handle Bordeaux mixture. See also Ref: (1) p. 127.
BORIC ACID. H.,BO,. Alloys 3003 and 5154 were
resistant to solid boric acid in laboratory tests conducted under conditions of 100% relative humidity
at ambient temperature. In other laboratory tests, alloys 1100. 3003 and 6061 were resistant to aqueous
solutions (I-IS%) of boric acid at ambient temperature and at 60C (14OF). Aluminum alloy drying
kilns, trays, conveyors. hoods, tanks and valves have
been used for handling boric acid. See also Ref: (1) p.
127, (2) p. 108, (3) p. 51, (4) pp. 123, 124, 125. (7) p.
35.
BORON TIUFLUORIDE.
BF1. Aluminum
alloy
reactors have been used in the manufacture of naphthalene in which boron trifluoride is used as a catalyst. See also Ref: (1) p. 127, (3) p. 51, (7) p. 37.
BOROSILICATES. In laboratory tests. 3003 alloy
was resistant to borosilicate glass wool under conditions of 100% relative humidity al 52C (125F). See
also Ref: (10) pp. 29, 108.
BROMOFORM. CHBr,.
In limited
laboratory
tests, bromoform was corrosive to aluminum alloys
with the attack being accelerated as the temperature
increased. Inhibitors such as amines have promise of
reducing the attack to some degree. CAUTION: See
Halogenated
Hydrocarbons.
See also Ref: (1) p,
128. (3) pp. 23, 106. (7) p. 37.
BROMOMETHANE.
CH,Br. In limited laboratory
tests, bromomethane was very corrosive to high purity aluminum at 50C (122F). See also Ref: (3) p.
105.
BULK (DRY) MATERIALS.
Aluminum
alloys
have been used to handle a wide variety of materials
in bins. cars. drums and wrappings. Listed below are
some examples of these materials. See also Ref: (6)
pp. 10, 11. 12.
Flour
Sugar
Synthetic detergents
Soap flakes
Cocoa
Instant coffee

Phosphorus
Cement
Whiting
Ethycel
Salt

suspensions

IJ-BUTADIENE.
CHz:(CH)z:CH,.This
product
has been stored and transported in aluminum alloy
equipment. See also Ref: (3) p. 103.
BUTANE. CH,(CH,),CH,.
Aluminum
alloy pipe
and tube have been used to handle butane. See also
Ref: (I) p. 128. (3) p. 214. (7) p. 39.
BUTTER.

Aluminum

alloy equipment

has been

(continued)

614

Corrosion Resistant Materials Handbook

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

used to handle butter. Aiuminum foil has been used


for packaging butter. See also Ref: (1) p. 128. (3)
p. 205. (4) pp. 84. 100. 102. 103. 114. (6) p. 11.
BUTYL ACETATE CH,COO(CH,LCH,.
In laborator! tesw allo! 3003 was resistant to hutyl acetate
at ambwnt temperature
and at the boiling pomr.
Under refluxmg conditmns.
butyl acetate caused
mild attack ( - 3 mp!) of 3003 allo?. Aluminum allo?
storage tanks have been used for butyl acetate. See
also Ref: (1) p. 128. (2) p. 118. (3) p. 136. (7) p. 39.
BUTYL ALCOHOLS.
CH,.CH2.CH2.CH:.0H.
CH,.CH(OH).CH,.CH,.
(CH,),C.OH.
In laboratar) tests. allo) 3003 water cooled tube was resistant
to condensing vapors from n-butyl alcohol. In other
laboratory tests at 204C (400F). n-but!1 alcohol
containing as much as i 3% eaterwasverycorrosive
to 3003 alloy. but with 5% water. 3003 alloy was
resistant. At the same temperature.
alloy 3003 was
resistant to secondaq
and tertiary butyl alcohols
with 0.3% water. Aluminum alloy decanters, heat
exchangersand tanks have been used with pure butyl
alcohol or butyl alcohol-water
mixtures. See also
Ref: (1) p. 128. (2) p. 120. (3) p. 113. (7) p. 39.
BUI?LCELU)SOLVE.CH,OH
.CH,.O .C,I&. In
limited laborator) tests, commercial pure bury1 Cellosolve caused very severe corrosion of 3003 al101
under refluxing condltlons. This corrosion was eliminated in those tests by the addition of a small amount
of nitrobenzene.
BUTYL CELLOSOLVE
ACETYL RECINO.
LEATE. CI,H,O,.
This product has been manufactured and handled in aluminum alloy equipment.
BIJTYL LACTATE.
CHJH(OH)COOC,H,
I,,
laboratory tests, alloys 3003. 5052 and 5154 were re.
sistant to butyl lactate at temperatures from ambient
to 188C (370F). As condensing vapors, butyl lat.
tate caused mild attack ( - 2 mpy) of 3003 alloy.
Bury1 lactaw has been handled in drums. tank trucks
and tank can made from aluminum alloys. See also
Ref: (1 pp. 40. 41.
o-BUTYRALDEHYDE.
C2H,.CH,.CH0.
In labOratoIy tests, 1 IO0 alloy was resistant to solutions of
butyraldehyde
(l-100%)
at ambient temperature.
Corrosion increased at elevated temperatures,
particularly at lower concentrations
in the same tests.
Aluminum allo) still and condenser tubes, shipping
drums and tank cars have been used with n-butyraldehyde. See also Ref: (3) p. 120. (7) p. 41.
BUTYRIC ACID. CHd(CHJ> COOH. The effect
of butyric acid on aluminum is similar to that of acetic acid and propionic acid.
The corrosion rates pass through a minimum at 5%
acid and then increase again at approximately
70-80%. Above this concentration,
the corrosion
rates drop to low values for commercial strength
butyric acid containing about 0.2% water. Dehydrated acid. containing about 0.05% water corrodes
aluminum. Aluminum alloy storage tanks and shipping drums have been used. Heat exchangers made
of aluminum-manganese
alloys have proved to be
satisfactov. Alloy 356.0 valves are used for handling
buryric acid.
See also Ref: (1) p.
128. (2)~. 123,(3)p. i27, (4)pp. 24,29,30,31,(7)p.
41.
BUTYRIC ANHYDRIDE.
[CH, (CH,),COlzO.
In
laboratov tests, but@
anhydride and mixtures of
butyric anhydride and butyric acid at tempemtuEs
from ambient to boiling caused moderate attack (- 7
mpy) of 1100 alloy. In the same tests. a mixture of
dehydrated butyric acid and commercial strength
anhydride was corrosive to 1100 alloy. Aluminum
alloy storage tanks and shipping drums have been

ASSOCIATION

used for butyric anhydride.


p. 41.

(continued)

See Ref: (3) p. 128, (7)

C
CADMIUM
CHLORIDE. CdCI*.2 % HsO. Solid
cadmium chloride was very corrosive to 3003 and
5154 alloys in laboratory tests conducted under con.
ditions of 100% relative humidity at ambient temper.
attire. See also Ref: (3) p. 80, (7) p. 45.
CADMTUM SULFATE. CdSO,. Alloys 3GU3 and
5154 were resistant to solid cadmium sulfate in laborator tests conducted under conditions of 100%
relatwe humidity at ambient temperature. In other
labonto?_ tests, aqueous solution (l-IS%)
caused
mild attack of 3003 alloy at ambient temperature.
Aluminum alloy piping. filter press plates, and tanks
have been used to handle cadmium sulfate. See also
Ref: (3) p. 80. (7) p. 45.
CALCIUM CARBIDE. Cd,.
Solid calcium carbide caused mild attack of alloy 5154. while alloy
3003 was resistant in laboratory tests conducted
under conditions of 100% relative humidity at ambient temperature. See also Ref: (I) p. 128, (3) p. 76.
(7) p. 4s.
CALCIUM CARBONATE. CaCO,. In laboratory
tests, saturated solutions of calcium carbonate caused
mild attack (-2 mpy) on alloy 1100 at ambient
temperature. The rate decreared with time. Drv calcium carbonate had no effect. See also Ref: (1) p. 128,
(3) p. 76, (7) p. 45.
CALCIUM CHLORIDE. CaCl?.6H,O.
In laboratory tests, solid calcium chloride caused moderate attack (- 6 mpy) of alloys 3003. 5154, and 6061 under
conditions of 100% relative humidity at ambient
temperature.
Other laboratory
tests show that
aqueous solutions (up to 455%) caused mild attack at
ambient temperature with pitting in evidence. The
action of calcium chloride can be inhibited by the addition of sodium dichromate.
Inhibited
calcium
chloride refrigeration brines have been commonly
handled in aluminum alloy equipment. Alloy 356.0
valves have been used for handline calcium chloride
solutions. See also Ref: (I) p. 128.72) p. 129. (3) pp.
23, 73, 240, (7) p. 47.
CALCIUM CHROMATE. CaCrO,. Calcium chromate has been used as an inhibitive pigment in
organic coatings on aluminum alloys. See also Ref:
(7) p. 47.
CALCIUM GLUCONATE.
Ca(HO.CH,
(CH.OH),COOlx~HIO.
Aluminum
alloy tanks have been used in the production of calcium gluconate. See also Ref: (3) p. 77. (7) p. 47
CALCIUM
HYDROXIDE.
Ca(OH),.
In laboratory tests, calcium hydroxide solutions have rapid
etching action on aluminum alloys Hhich quickly
subsides as the result of the formation of protective
films on the aluminum surface. See also Ref: (1)p.
128. (2) p. 133. (3) p. 72. (4) p. 47.
CALCIUM HYPOCHLORITE. Ca(CIO),.Z H:O.
Solid calcium hypochlorite
was corrosive (- 27
mpy) to alloy 3003 and caused moderate attack
H- IO mpy) of alloy 5154 in laboratory tests under
coryditions of 100% relative humidity at ambient
temperature.
!n other laboratory tests, aqueous
solutions. except those at very low concentrations,
wem corrosive to 3003 alloy at ambient temperature. Aluminum baskets and rotary driers have
been used with calcium hypochlorite. See also Ref:
(1) p. 128. (2) p. 104, (3) pp. 73. 247, (7) p. 47.

CALCIUM
NITRATE. CalNO,)?.
In laboratory
tests. alloy 3003 was resistant to aqueous solutions
(l-50%) of calcium nitrate at ambient temperature.
See also Ref: (1) p. 128, (3) p. 75. (7) p. 47.
CALCIUM OXIDE. GO. Alloy 3003 was resistant
to solid calcium oxide in laboratory tests conducted
under conditions of 100% relative humidity at ambient temperature.
In the presence of liquid water.
calcium hydroxide is formed. leading to the formation of protective films on the aluminum surface
(see CALCIUM HYDROXIDE).
See also Ref: (1)
p. 128. (31 p. 72, (7) p. 49.
CALCIUM PROPIONATE.
Ca(CH,. CHz. COO)>.
Calcium propionate has been stored in aluminum
alloy tanks. See also Ref: (3) p, 77.
CALCIUM SILICATE.
Ca,SiO,(OR 3 CaO. SiO,).
Aluminum alloy driers have been used with calcium
silicate. See also Ref: (3) p. 76. (7) p. 49.
CAMPHOR. C,,H,,O. Aluminum alloy equipment
has been used to handle camphor. See also Ref: (1) p.
129. (3) pp. 104, 121. 226(7) p. 51.
CANE SUGAR LIQUORS.
Aluminum alloy equipment has been used in the processing and handling of
cane sugar liquors. See also Ref: (4) pp. 74. 90.
n-CAPROIC ACID. CH,.(CH!)q.COOH.
In laboratory tests, alloys 3003. 5154. and 6061 were resistant
to n-caproic acid at 50C (122F) and at the boiling
point. Under refluxing conditions,
n-caproic acid
was corrosive to aluminum alloys. This acid has been
stored in aluminum alloy containers. See also Ref: (2)
p. 24. (3) p. 127.
CAFROLACTAM. CHz(CH:),NHCO.
Laboratory
tests indicate that caprolactam is discolored by contact with nluminum alloys.
n-CAPRYLJC ACID.
CH,(CHJ),
COOH. In limited laboratory tats. alloys 3003 and 5052 \\\ttre resistant to caprylic acid at ambient temperaure.
This
aad has been shipped in aluminum alloy containers.
See also Ref: (2) p. 24. (3) p. l2i.
CARBOLIC ACID. C,H,OH.
See PHENOL.
also Ref: (2) p. 537. (3) p. 116.

See

CARBON. C. In laboratory tests, various aluminum


alloys were resistant to carbon when dry. When wet.
carbon acts as a cathode tocontacting aluminum and
causes corrosion as a result of galvanic action. Carbon black has been handled in aluminum alloy containers and hopper can. See also Ref: (1) p. 129, (2)
p. 50.
CARBON DIOXIDE. CO2 Carbon dioxide in liquid. solid orgaseous form has been handled in aluminum alloy equipment including pipe lines. See also
Ref: (1) p. 129, (2) p. 141. (3) pp. SO, 214, (4) pp. 43,
47, 48. 93.
CARBON DISULFlDE.
CS,. Alloy 1100 was resistant to carbon disulfide in laboratory tests conducted
at ambient temperature
and at the boiling point.
Aluminum
absorbers,
distillation
columns, condensers, and piping have been used in carbon disulfide recovery systems. Alloy 356.0 valves have
been used for handling carbon disulfide. See also
Ref: (1) p. 129, (2) p. 146. (3) p. 51 (7) p. 51.
CARBONIC ACID. HJO,.
Carbonated beverages
have been handled in aluminum alloy equipment.
SeealsoRef:(l)p.
129. (2)~. 141,(3)p. 22, (7)~. 51.

(contmued)

Nonferrous Metals and Alloys

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

CARBON TETRACHLORCDE.
CCIJ. In laboratory tests. alloys 3003. 5052 and 5154 were resistant
to carbon tetrachloride
at ambient temperature.
whereas. boiling carbon tetrachloride was corrosive
to these alloys as well as to many others. Two products of this reaction are aluminum chloride and hexachlomethane.
The reaction apparently
is electrochemical in nature and accelerated by anhydrous
aluminum chloride. The reaction decreases rapidly
as the temperature is dropped from boiling 177C
(170F)I to 50C (122F).
The rate increases
markedly on superheating.
The presence of water.
carbon disulfide or oxygen increases the action at
lower temperatures and decreases it at higher temperatures. The action can also be minimized by add~ng stabilizers. Aluminum powder in contact with
carbon tetrachloride should not be used as a milling
medium for comminuting
aluminum.
CAUTION:
See Halogenated Hydrocarbons.
See also Ref: (I)
p. 129. (2) p 153. (3) pp. 23. 106.
CELLULOSE.
(ChH,,,Or),. Aluminum alloy equipment has been wed to handle cellulose. See also Ref:
(I) p. 129. (31 pp. 124. 231.
CELLULOSE
ACETATE
BUTYRATE.
Aluminum alloy 5110s. piping. Jnd conveyors have been
used for handling cellulose acetate butyrate. See also
Ref: (3) p. 130. (7) p. 53.

ASSOCIATION

615

(continued)

ture. Similar results were obtained with 2% and 20%


solutions of chlordane in kerosene. However. the addition of as little as 0.2% distilled water to these colutions increased their corrotivity greatly. Aluminum
alloy containers have been used for the bulk rhipment of chlordane. CACiTl0.V. See Halogenated
Hydrocarbons. See also Ref: (3) p. 110. (7) p. 55.
CHLORINE. C12. In laboratory tests, aqueous soIu+
tions containing 25.50. and 100 ppm chlorine caused
moderate attack of I IO0 and 6061 alloys at ambient
temperature. Dry chlorine gas does not attack aluminum alloys. but in the presence of water is corrosive.
Aluminum alloy bus bar has been used in causticchlorine plants. Hot chlorine gar has been cooled in
aluminum alloy heat exchangen. See also Ref: (1) p.
129, (2) p. 167, (3) pp. 36, 247, (7) p. 57.
CHMROACETIC
ACID. CHICI COOH. Laboratory tests indicated that pure chloroacetic acid is very
corrosive to 3003 alloy at 204C (400F). CAUTION:
See Halogenated Hydrocarbons.
See also Ref: (7)
pp. 56, 57.
CHLOROBENZENE.
C,H&I. Laboratory tests indicated that alloy 3003 was resistant to chlorobenzene at 100C (212F) and refluxing temperatures.
Chlorobenzene has been shipped in aluminum alloy
tank trucks. CAUTION: See Halogenated Hydmcarbons. See also Ref: (2) p. 173. (3) p. 111. (7) p,
57.

CHROMIUM OXIDE. Cr,O,. Chromium oxide in


the dry state has been handled in aluminum alloy
equipment. See also Ref: (1) p. 130. (3) p. 82.
CHROMlUM
POTASSIUM
SULFATE.
CrK(S0,)~~12H10.
Alloys 3003 and 5154 were
resistant to solid chromium
potassium sulfate in
laboratory tests conducted
under conditions
of
100% relative humidity at ambient temperature.
See also Ref: (7) pp. 62, 63.
CHROMIUM SULFATE.
Cr,(SO,),
I5 H20.
Solid chromium sulfate was corrosive to 3003 alloy
in laboratory tests conducted
under conditions of
lOO% relative humidity at ambient temperature.
See also Ref: (1) p. 130. (3) p. 82, (7) p. 63.
CHROMIUM TRIOXIDE.
CrO,. Solid chromium
trioxide caused moderate attack ( - 17 mpy) of 3003
alloy in laboratory tests conducted under conditions
of 100% relative humidity at ambient temperature.
Alloy 356.0 valves have been used for handling
chromic acid solutions. See also Ref: (2) p. 194, (3)
p. 82. (7) p. 63.
CIDER. In laboratory tests, 5052 alloy was resistant to apple cider at 38C (IOOF). See also Rrf:
(1) p. 130. (3) p. 202. (4) pp. 78. 97. (6) p. IO.

(HOOC)CH,C.(OH)(COOH)
CITRIC ACID.
.CH:COOH.
In laboratory tests. II00 alloy uas
CELLULOSE
ACETATES.
Aluminum alloys have
resistant to aqueous solutions of citric acid at ambeen used in the preparation and storage of cellulose l-CHLOROBUTANE.
C,H,CI.
Laboratory
tests
blent remperarure.
While increased concentration
acetates. See also Ref: (I) p. 129. (3) pp. 136.232. (7) showed that 3003 alloy was resistant to I-chlorohad
little effect, increasing temperature cawed the
p. 53.
butane at ambient temperature and 50C (IZZF).
corrosivity of the solutions to increase subsrantlally.
At the reflux temperature I-chlorobutane was corroThe presence of chlorides or heavy metals mcreaws
CEMENT, PORTLAND.
While in the fluid state, sive to alloy 3003 and high purity aluminum. CAUthe corroshity of these solutions. Aluminum has no
Ponland cement causes etching of aluminum alloys TION: See Halogenated Hydrocarbons.
harmful action on the organisms used in rhe manuas indicated in laboratory tests and in service applicafacture of citric acid and is suitable for cc:uipment
tions. After the cement has set, no further corrosion 2XHLOROBUTANE.
CH,&HICHCICHJ.
In laboruch as fermenting
vats. crystallizers,
solution
occurs as a result of a protective film forming on the ratory tests. alloy 3003 was resistant to 2.chlorostorage \ats. and piping. Alloy 356.0 vahes have
aluminum. Galvanic corrosion will develop if alumi- butane at ambient temperature. At higher temperanum is coupled todissimilar metals in cement or con- tures, 2.chlorobutane
been used for handling citric acid solutions. See also
was corrosive to 3003 alloy.
crete to which chlorides have been added for high CAUTION: See Halogenated Hydrocarbons.
Ref: (I) p. 130. (2) p. 199. (3) pp. 131, 209. (4) pp.
early strength. Aluminum alloys have been used for
22, 25. 26, 27, 28, 29, 30. 31, 109. 110. 113. (7)
p. 6.5.
freight can. hopper can, and tote bins handling ce- 2XHLOROETHANOL.
CHzCICHIOH. In laborament. Aluminum has also been used successfully for tory tests, 3003 alloy was resistant to 2.chloroethanol
CITRUS FRUlT IUICES.
Laboratory tests indiracks and pallets in the concrete block industry,
at ambient temperature. Corrosion increased rignificated that alloys 3003. 5052. and 5086 were resistant
molds and forms. and terrazzo divider strips. See also cantly as temperature increased with 2.chloroethanol
to citrus fruit juices at ambient and refrigerated temRef: (I) p. 129. (2) p. 161. (3) p. 228.
being very corrosive at the boiling point. C4UTION:
peratures. See also Ref: (-I) p. 90. (6) p. IO. 13.
See Halogenated Hydrocarbons.
See also Ref: (3)
CEREALS. Aluminum alloy equipment
has been p. 133. (7) p. 87.
CLAY. Variable substance with a base of hydrous
used for handling and preparation of cereals.
aluminum silicate. Dry clay and clay slurries have
CHLOROFORM.
CHCI,. In laboratory tests, Ill!0
alloy was resistant to chloroform with a trace of water
been handled in aluminum alloy piping, fittings, and
CHEESE. Cheeses vary in their action on aluminum
valves.
See also Ref: (I) p. 130. (3) p, 228.
at
temperatures
up
to
the
boiling
point
6lC
(142F).
alloys. In laboratory tests, aluminum
alloys were
resistant to some cheeses, while other cheeses were In the same test. anbydrouc chloroform uas cop~oCOAL.. Mainly carbon. containing also many orcorrosive. When necessary. aluminum alloys can be sive. CAUTION: See Halogenated Hydrocarbons.
game compounds. A controlled field test indicated
protected readily. Aluminum vats and molds have See also Ref: (1) p. 130. (2) p. 179. (3) p. 106. t) p.
that aluminum alloys performed uell when contactbeen used for processing cheese. Aluminum wrap- 59.
ing various types of coal for 30 years. Aluminum
pings and containers have been used for cheese.
NO:C,H,CI.
In limalloys have been used for trucks, hopper cars. chutes,
Those have usually been protected. See also Ref: (I) CHLORONITROBENZE,NE.
skips, cages, trolleys. pit props, and hand tools in the
p. 129, (3) pp. 199. 205, (4) pp. 84, 102, 103. 114, ited laboratory tests, 3003 alloy was resistant to chloronitrobenzene
at ambient
temperature.
CrlUhandling of coal. Aluminum liners have given satis115. (6) pp. 9. II, 14, 15.
TIO,V: See Halogenated
hydrocarbons.
See also factory service in coal bunkers to assist in the flow of
CHERRIES.
In laboratory tests, cherries in brine Ref: (2) p. 185.
the coal. See also Ref: (1) p. 130, (3) pp. SO, 221.
caused moderate attack of 3003. %2.
and Alclad
Aluminum
alloy equipment
has COAL GAS. Containing hydrogen, methane, car3003 alloys at amblent temperature.
Alclad 3003 CHOCOLATE.
been used in the preparation
and manufacture of bon monoxide, ethane, carbon dioxide, oxygen, niwhen exposed at ambient temperature was resistant
foil has been used to trogen and volatile organic compounds. Limited labto Maraschino cherries in another laboratory test. chocolate candy. Aluminum
Fresh chemies in water have been carried by alumi- package chocolate products. See also Ref: (3) pp. oratory tests showed that 443.0 casting alloy was
200.203. (4) p. 115, (6) p. 12.
num alloy irrigation pipe to processing tanks.
resistant to coal gas at ambient temperature. See also
Ref: (3) p. 221, (7) p. 65.
CHROMIC
ACID.
H2Cr004.
In
laboratory
tests,
CHERRY MCE.
In laboratory tests, sweet red
cherry juice caused mild attack ( - 4 mpy) of 3003 1100 alloy was resistant to aqueous chromic acid COAL TAR. Containing benzene, toluene. naphup to 0.1 N at ambient
alloy at lOOC (212F) while black cherry juice caused solutions in concentrations
thalene.
anthracene.
xylene.
other
aromatics;
moderate attack ( - 8 mpy). See also Ref: (4) pp. 88, temperature. See also Ref: (1) p. 130, (2) p. 194. (3) phenol, cresol, other phenolics; ammonia. pyridene.
pp. 82, 236, (4) pp. 21, 121, (7) p. 63.
89, (6) p. IO.
other organic bases. thiophene.
Aluminum
alloy
equipment including distillation columns, condenCr. Chromium plated aluminum al- sers and piping have been used in the production of
CHLORDANE.
C,,H,CI,. In laboratory tests. 3003 CHROMIUM.
alloy was resistant to technical chlordane with ot loy products have been used. See also Ref: (3) p. 82, coal tar. See also Ref: (3) pp. 223, 224.
without 0.2% water additions at ambient tempera- (4) pp. 83. 134.

(continued)

616

Corrosion Resistant Materials Handbook

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

ASSOCIATION

(continued)

COBALT COMPOUNDS.
Solid cobaltous chloride tive films. Calcium chloride is often added to morwas very corrosive to alloys 3003 and 5154 in lab- tar and concrete to accelerate curing and to develop
oratory tests conducted under conditions of 100% high early strength. Sodium chloride may also be
relative humidity at ambient temperature. Solid cw present. as a contaminant of the water and sand. In
baltous nitrate caused mild attack ( - 3 mpy) of 3003 laboratory tests, the addition of appreciable amounts
alloy in the same tests. See also Ref: (3) p. 84, (5) p. of either calcium chloride or sodium chloride to concrete had little effect on the corrosivity of the con13.
crete to aluminum alloys. However. these rests and
COCA COLA* SYRUP. In laboratory tests, Coca service experience show that small amounts of
chlorides will aggravate corrosion of alloys and even
Cola syrup is corrosive to aluminum alloys. Unpro
cause deterioration of the concrete when the co_
tected aluminum is not ordinarily used with this pro
sion is of a galvanic nature. especially when the conduct.
crete is either intermittently
or continuously
wet
l&mcml tndrm.rt
after curing. While aluminum alloys perform well in
many applications
involving mortar and concrete.
COCONUT
OIL. Contains
Irimyristin.
trilaurin.
tripalmitin.
tristearin. other glycerides. Coconut oil definite benefits may be obtained by using protec.
tive
coatings
to
prevent
staining, eliminate crevice
has been stored in aluminum alloy tanks. See also
corrosion, minimize galvanic corrosion, and imRef: (7) p. 93.
prove adhesion by decreasing gas evolution at the
metal interface. See also Ref: (IO) p. 29.
COD LIVER OIL. A fixed oil containing vitamins
A and D. glycerides of palmitic. stearic. etc., acids,
COPAL. Contains
trachylolic
acid, isotrachylolic
cholesterol, butyl alcohol esters. Cod liver oil has acid, resene and volatile oil or contains dammaric
been processed and stored in aluminum alloy equipacid. dammaran
and a resin. Aluminum
alloy
ment. See also Ref: (I) p. 130, (2) p. 294. (3) p. 239.
equipment has been used for the production of var.
nishes made from copal resins. See also Ref: (1) p.
COFFEE. Coffee has been prepared in aluminum
131, (2) p. 210, (3) p. 226, (7) p. 65.
alloy cooking equipment and utensils. See also Ref:
(1) p. 130. (3) p. 211. (4) pp. 80. 84.97, (6) p. 12.
COPPER
COMPOUNDS.
In laboratory
tests,
COKE. (From destructive distillation of coal and
other carbonaceous materials.) The resistance of aluminum to coke has been reflected by its use for coke
conveyor buckets and as sprayed coatings to protect
steel can used for coke quenching. Aluminum alloy
equipment
has been used in many applications
handling coke oven gas. Deacidifien. pipes. heat exchangers, heating coils, regenerators, and absorbers
made of aluminum allovs have been in service om.
cessingcoke oven gas. S& also Ref: (1) p. 130, ($&.
210, 221, 223.
COKE OVEN GAS. Contains hydrogen, methane,
carbon dioxide and volatile organic compounds. Aluminum alloy deacidifiers. heat exchangers, and heating coils have been used in the Collins process for the
desulfurization
of coke oven gas. Condensation
of
moisture on surfaces contacting coke oven gas CM
accelerate cormsion on aluminum alloys as the result
of the formation of sulfurous acid. See also Ref: (1)p.
130. (2) p. 859.
COLLODION.
Pymxylin dissolved in alcohol and
ether. Laboratory tests showed that alloy 6053 was
Rsistant to collodion at ambient temperature.
Collodion has been stored in aluminum alloy containers.
See also Ref: (3) p. 124.
CONCRETE.
Aluminum alloys embedded in fresh
mortar or concrete have been used in many applications. As shown by laboratory tests, 5ome surface
attack occurs during the first few hours while the
concrete is still fluid. However, further attack is
substantially retarded because of the formation of
highly protective films on the aluminum. Measured
depths of the attack that take place during the setting period of concrete are generally less than 1 mil
while after 6 months or after 8 or 27 years in service
measured depths of attack have been found no
greater than S mils. Laboratory tests have demonstrated that the volume of concrete in contact
with aluminum as well as availability of external
moisture have no more than a minor effect on the
performance of aluminum alloys embedded in concrete. In many applications,
aluminum alloys embedded in concrete are coupled directly or indirectly
to reinforcing or structural steel. Laboratory tests
have shown that aluminum is anodic to steel in concrete. Nonetheless. when coupled electrically in the
laboratory to steel in concrete, aluminum
alloys
have been found less affected than when not coupled as the result of more rapid formation of protec-

tar. In laboratory tests. 1100 alloy was resistant to


l%, 3%. and 100% solutions of cresylic acid at ambient temperature. See also Ref: (2) p. 221, (7) p. 67.
CBYOIJTE.
(SODIUM
ALUMINUM
FLUORIDE). Alloy 3003 was resistant to solid cryolite in
laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
See also
Ref: (7) pp. 160. 161.
CUMENE. C,Hs CH(CH,),.
In limited laboratory
tests. 3003 alloy was resistant to cumene under
refluxing conditions. Cumene has been stored in
aluminum alloy containers. See also Ref: (7) p. 69.
CURRANTS(BLACK
AND RED). in limited laboratory tests, red currants were corrosive to 3003
alloy at 100C (212F). Aluminum equipment has
been used in processing and preparing currants. See
also Ref: (6) p. IO.
CYCLOHEXANE.
CJ&
In laboratory tests, 3003
alloy was resistant to cyclohexane under &axing
conditions. Aluminum alloy tank trucks have been
used to ship cyclohexane. See also Ref: (3) p. 104,
(7) p. 71.

CYMENE. C&I,.
In laboratory tests. 3003 alloy
was resistant to cymene under boiling and condensaqueous solutions of copper compounds were cot- ing conditions and under refluxing conditions. See
also Ref: (3) p. 104.
rosive to aluminum alloys causing localized pitting.
See also Ref: (1) p. 131. (3) p. 238.

CORK. The light, porous outer bark of the cork


oak. In laboratory tests, cork was corrosive to contacting 3003 alloy under conditions of 100% relative
humidity at 52C (125F) which caused wetting of
the cork. See also Ref: (10) p. 29.
CORN OIL. A refined oil expressed from grain of
Zea mays L. Corn oil has been stored in aluminum
alloy containers. See also Ref: (6) p. II.
CORN PRODUCTS.
In laboratory
tests, alloys
1100 and 3003 were resistant to many corn products tested. Aluminum
alloy equipment
has been
used in the production of corn products. Aluminum
alloy hoods. ducts. piping, and conveyors have been
used.
CORN SYRUP. A mixture of dextrose and dextrins
in water. Laboratory tests indicated that 6061 alloy
was resistant to corn syrup at ambient temperature.
Corn syrup has been stored in aluminum alloy containers. See also Ref: (2) p. 229. (6) p. IO.
COSMETICS.
In laboratory tests. many cosmetics
have been tested with variable results. Aluminum
alloy containers have been used for a variety of
creams, powders. lotions, and soaps. See also Ref:
(3) pp. 117. 239.
COTTONSEED
OIL. A refined oil expressed from
the seeds of Gossypium herboceun and other species
of Gossypium. In laboratory tests, 6061 alloy was
resistant to cottonseed oil at ambient temperature.
Aluminum alloy storage tanks have been used for
cottonseed oil. See also Ref: (2) p. 872.
CREAM. Aluminum
allovs have been used for
ream separators. See also kefz (3) p. 204. (4) pp. 26.
ICn, (6) p. 11.
XESOL
C,H,(OH)(CH,).
In laboratory
tests,
1100 alloy was resistant to 1%. 3%. and 100% solutions of cresol at ambient temperature. In other
aboratory tests. ctesol was very corrosive to I I00
alloy at the boiling point. See also Refz (1) p. 131. (2)
). 221. (3) p. 116, (7) p. 67.
XESYLIC

ACID.

A mixture of phenols from coal

2, 4-D. Cl,. C,H, 0. CH2. COOH. Limited laboratory tests indicate that dilute aqueous solutions of
2. 4-D caused mild attack of 3003 alloy at ambient
temperature. 2, 4-D has been handled in aluminum
alloy sprayers and piping. CAUTION: See Halo.
genated Hydrocarbons. See also Ref: (3) p. 127.
DAJRY PRODUCTS.
Aluminum alloys have been
used for milk pails, milk cans, storage tanks, truck
tankers. pasteurizers.
coolers. butter chums and
tubs. foil hoods, and powdered milk driers. See also
Ref: (3) p. 204. (6) p. 11.
DDT. (CIC,H&CHCCII.
Laboratory tests showed
that 3003 alloy was resistant to dry DDT and dilute
aqueous solutions of DDT at ambient temperature.
Aluminum alloy cans have been used for aerosol w
lotions of DDT. CAUTION: See Halogenated Hy
drocarbons. See also Ref: (2) p. 226. (3) pp. I Il.
241. (7) p. 75.
DETERGENTS.
Aluminum alloys perform in different ways in different detergents. When in solution. some detergents stain andFor corrode aluminum. Since general conclusions cannot be drawn,
detergents rhould be tested individually before use
with aluminum alloys. Aluminum bins, silos. piping,
and packages have been used for detergents. See alu,
Ref: (I) p. 131. (3) p. 243, (4) pp. 34, 72, 75. 76, 85,
86, 87, 96, 103.
DMCETONE ALCOHOL.
(CHJ,C(OH)CH,COCH,.
In limited
laboratory
tests. 3003. 5052. and 5454 alloys were resistant to
diacetone alcohol at ambient temperature
and at
54C (13OF). See also Ref: (3) p. 121.
DICHLOROACETIC
ACID. CHC&COOH. In limited laboratory tests, dichloroacetic acid was corive to 3003 alloy at 2OVC (400F). CAUTION: Set
Halogenated
Hydrocarbons.
See also Ret (3)
p. 127.
DICHMROBENZENE.
C&Cl,.
In laboratory
tests, alloys 3003 and 5154 were resistant to dichlorobenzene at 50C (122F). Dichkxobenzene
has been

(continued)

Nonferrous Metals and Alloys

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

handled in aluminum alloy tanks, filters, and heat


exchangers. CAUTION: See Halogenoted
Hydracarbons. See also Ref: (2) p. 173, (3) p. Ill, (7) p.
75.
DICYCLOPENTENYL
ALCOHOL.
In laboratory
tests, 3003 alloy was resistant to dicyclopentenyl alcohol at boiling temperature.
DIETHANOLAMINE.
HN(CHz CH*OH)*.
Laboratory tests showed that alloy 3003 was resistant to
diethanolamine
at ambient temperature.
However,
at the boiling temperaturn and under refluxing conditions diethanolamine
caused moderare attack.
While aluminum alloy heat exchangers have been
used to handle diethanolamine
solutions, tests under
the anticipated conditions should be made prior to
use in service. See also Ref: (3) p. 145.
DIETHYL4MlNE.
(CJH&NH.
Alloy 3003 was resistant to diethylamine in laboratory tests conducted
at elevated temperatures
of ICPC (212F) and
204C (400F). Aluminum alloy stills and condenser
tubes have been used in processing and handling diethylamine. See also Ref: (7) pp. 76. 77.
DIETHYLENE
GLYCOL.
HO. CH>. CH, .O-CIiZ CH:OH.
In
laboratory
tests. 3003 alloy was resistant to diethylene glycol
under refluxing conditions. See also Ref: (3) pp. 25.
135. (7) pp. 76, 77.
n-DIMETHYL
FORMAMIDE.
HCON(CH,)x.
In
laboratory tests, 3003 alloy was resistant to dimerhyl
formamide at ambient temperature and at the boiling point. Dimethyl formamide has been handled in
aluminum alloy tanks. piping, heat exchangers. and
distillation towers. See also Ref: (3) p. 147, (7) p. 81.
UNS-DIMETHYlBYDRAZlNE
(CH,),NNHz.
In
laboratory tests, alloys I 100, 3003 and SO52 were resistant to uns-dimethylhydrazine
when exposed at
30C (86F) and 63C (145F). Dimethylhydrazine
has been stored in aluminum alby containers. See
also Ref: (7) pp. 80. 81.
DIMETHYL SULFATE.
(CH,),SO,. Dimethyl sulfate has been stored in aluminum alloy containers.
See also Ref: (2) p. 233.
DIMETHYL TEREPHTHALATE.
C,H,(COOCH,,)I.
Aluminum alloy containen
been used for handling dimethyl terephthalate.

have

DIOCTYL PHTHALATE.
C&I,(COOCHzCH(C~Hs)C,H&.
Aluminum
alloy
tanks have been used to store dioctyl phthalate. See
also Ref: (7) p. 81.
DIPHENn
C,Hs.C,Hs.
Aluminum
alloy equip
ment has been used to handle diphenyl. See also Rel:
(2) p. 247. (3) p. 104. (7) p. 81.
DYES. Aluminum alloy equipment has been used in
some manufactuting
processes for dyes in some dyeing processes for dye kettles. dye sticks and drying
pans. See also Ref: (I) p. 131. (2) p. 212, (3) pp. 10%
119, 121. 132, 144. 145, 146. 23.5. (4)~. 73.
DYNAMITE. An explosive mixture containing nitroglycerin with other substances both inert and active. Aluminum alloys have been used for parts in
dynamite packing machines and for dynamite driers
and mixers. See also Ref: (I) p. 131. (3) p. I IS.

E
EGGS. Aluminum alloy equipment has been tised
for the preparation and dessicarion of egg powder.
Aluminum alloy trays have been used for drying egg
whites. Seealso Ref: (1)~. 131. (3, p. 198. (4)~. IIS.
(6)pp. 8. II.

ASSOCIATION

(continued)

ESSENTIAL OILS Volatile oils derived from plants


and usually taming
the esxnt~al odor or flavor of
the plant used. Aluminum
used m the preparation.

alloy equipment
storage.

sential oils. See also Ref: (I)


239.

has been

ond trxtsport

p. 131. (2) p. 2%.

of er(3) p,

ESTER GUMS. The glyce~l. methyl and eth!I esten of resin acids. Alummum alk>ys have been used
for piping ester gums.
ETHANOLAMINE.
H,N.CHlCH,.OH.
Limited
laboralor) tests under reflusing conditions indicate
that ethanolamine caused mild attack (-4 mp!) of
3003 alloy. Aluminum alloy heat exchangers have
been

used for

handling

617

a ethanolamine-dieth~lene

glycol mixture to remow CO:. H2S. and water from


natural gas. Aluminum allo! tanks have been used
to transport ethanolamine.
See also Ref: (I) p, 131.
ETHER. C?H,. 0 C:H,.
Laboratory
tests indicated that alloy 3003 uas resistant to ether at both
ambient and elevated temperatures. Aluminum processing. handling and degreasing equipment
have
been in use. Allo! 356.0 valves have been used for
handling ether. See also Ref: (2) p, 258, (3) p. 135,
(7) p; 77.
ETHYL ACETATE. CH, .COO.C,H,.
In laboratot tests. alloy 3003 was resistant to ethyl acetate
and its condensing vapors. Aluminum alloy heat exchangers. tank cars, etc.. have been used for handling ethyl acetate. See also Ref: (I) p. 132. (2) p. 2bO.
(31 p. 136. (7) p. 85.
ETHYL ALCOHOL. CIHIOH. In laboratop tests.
alloy 3003 was resistant to commercial (95%) ethyl
alcohol and its aqueous solutions. In other laboraton tests, anhydrous ethyl alcohol was corrosive to
aluminum alloys. Aluminum alloys have been used
commercially for stills, hear exchangers,
drums.
tanks, and piping in the processing of ethyl alcohol
and products employing ethyl alcohol in their manufacture See also Ref: (1) p. 132. (2) p. 28, (3) pp. 23,
112. (4) pp. 93. 97, 142. (7) p. ES.
a-ETHYL4NUINE
C:H,NHC,H,.
In laboratory
tens. alloy 3003 was resistant to n-ethylaniline at the
boiling temperature and under reflilsing conditions.
Erhylaniline has been stored in aluminum
alloy
containers.
ETHYLBENZENE.
C,Hs. CIH,. In laboratory
tests, alloy 3003 was resistant to ethylbenzene af the
boiling temperature
and at 204C (4CPF). Ethylbenzene has been handled in aluminum alloy heat
exchangers. See also Ref: (2) p. 263, (3) p. 104, (7)
p. 87.
ETHYLBUTYL ACETYLBICMOLEATE.
Aluminum alloy equipment has been used to produce
and handle ethylbutyl acetyhicinoleate.
ETHYL BUTYBATE. CH,.CHz.CH>.COOC,H,.
In laboratory tests, ethyl butyrate caused mild attack
(- 2 mpy) of 3003 alloy under boiling and condensing conditions and under refluxing conditions. Aluminum alloy equipment has been used in the production and handling of ethyl butyrate. See also Ref: (I)
p. 132, (3) p. 137, (7) p. 87.
ETHYLENE.
CH,:CHI. Ethylene has been handled
in aluminum alloy heat exchangers and tanks. See
also Ref: (3) p. 103, (7) p. 87.
ETHYLENEDIAMINE. NHz.CHI.CH,.NHz.
In
limited laboratory tests, 3003 alloy was resistant to
ethylenediamine
al 100C (212F) and 204C
(400F). See also Ref: (1) p. 132. (3) p. 145, (5) p. 9.
(7) p. 89.

ETHYLENE
DICHLORIDE.
CH2CI CHICI.
Limited laboratory tests indicate that 3003 alloy was
resistant to dry ethylene dichloride vapor at the boiling point. The presence of water causes increased
corrosion because of hydrochloric acid formed by hydrolysis. CAUTION:
See Halogenated
Hydrocarbons. See also Ref: (1) p. 132, (2) p. 268.
ETHYLENE GLYCOL. HO.CH,.CH,.OH.
Laboratory tests have indicated that 3003 alloy was
resistant to ethylene glycol at ambient temperature
and under refluxing and boiling and condensing conditions. Aluminum alloyequipment has been used in
the processing of ethylene glycol and for storage
tanks and pressure vessels. Inhibited ethylene glycolwater solutions have been used in automotive radiators and heat exchangers. Aluminum alloys should
not be used in applications with stagnant ethylene
glycol where very high temperatures
are involved
[2OPC (392F) and above]. Violent reactions are
possible under these condirions. See also Ref: (1) p.
132. (3) pp. 25. 114. (7) p. 89.
ETHYLENE
OXIDE. (CH,j20. Aluminum alloys
have beeh used to produce and handle ethylene oxide. Violent reactions are possible if aluminum chloride and aluminum oxide are present. See also Ref:
(1) p. 132, (3) p. 135, (7) p. 89.
ETHYL FORMATE.
HCOO.C,H,.
In laboratory
tests, alloy 3003 was resistant to erhyl formate at ambient temperature and at the boiling temperature. In
other laboratory tests. 3003 alloy was resistant to
ethyl formate ascondensingvapors.
See also, Ref: (1)
p. 132. (2) p. 136, (7) p. 91.
ETHYL LACTATE. CH,CH(OH)COOC,Hs.
In
laboratory tests at ambient temperature. alloy 6053
was resistant to ethyl lactate. See also Ref: (I) p. 132,
(3) p. 137.
ETHYL PROPIONATE.
CH,CH, COOGH,.
In
limited laboratory tests, alloy 3003 was resistant to
ethyl pmpionate under boiling and condensing conditions. Aluminum alloy stills and condenser tubes
have been used in the production of ethyl propionate.
See also Ref: (7) pp. 90, 91.
EUCALYPTUS
OIL. A volatile oil containing eucalyptol: vale& butyric. etc., aldehydcs: d-pinene.
Aluminum alloys have been used for handling eucalyptus oil. See also Ref: (1) p. 132.
Aluminum
EUGENOL. C,,H,IOz.
have been used to store and transport

alloy drums
eugend.

F
FATS. Aluminum alloy equipment has been used to
handle fats. See also Ref: (1) p. 132. (2) p. 271. (3) p.
198, (4) pp. 72, 78, (u, 84, 99. 100, 109. (7) p. 93.
FATTY ACIDS. RCOOH.
Laboratory tests have
shown that fatty acids cause mild attack of 1 IGil alloy
at ambient temperature. Anhydrous fatty acids were
found to be very corrosive to aluminum alloys at the
boiling point in other laboratory tests. Aluminum alloy storage tanks. separators. settling and receiving
tanks, condensers, vapor lines, and steam trace lines
have been used to process and handle fatty acids and
fatty acid derivatives. See also Ref: (1) p. 132, (2) p.
274, (3) pp. 125, 127, (4) pp. 25. 100, (7) p. 93.
FERRIC CHLORIDE. FeCIJ.6HI0.
Solid ferric
chloride was very corrosive (244 mpy) to 3003 alloy in
laboratory tests conducted under conditions of loO%
relative humidity at ambient temperatom.
Also in
laboratory tests, aqueous solutions of ferric chloride

(continued)

618

Corrosion

TABLE 5.2:

Resistant

ALUMINUM

Materials

ALLOYS-ALUMINUM

were very corrosive to aluminum alloys. See also Ref:


(I) p. 132. (2) p. 288, (3) p. 84, (7) p. 93.
FERRIC OXIDE. FQO,.
were resistant to solid ferric
conducted under conditions
ity at ambient temperature.

Alloys 3003 and 5154


oxide in laboratory tests
of 100% relative humidSee also Ref: (1) p. 132.

FERROUS SULFATE.
FeS0,.7Hz0.
Alloy 3003
was resistant to solid ferrous sulfate while 5154 alloy
suffered mild attack ( - 4 mpy) in laboratory tests
under conditions of 100% relative humidity at ambient temperature. In other laboratory tests at ambient temperature.
aqueous solutions (O.COOl-10%)
caused mild attack ( - 3 mpy) of 1100 alloy. Aluminum spray tanks and alloy A356.0 valves have been
used with ferrous sulfate solutions. At elevated temperature. ferrous sulfate oxidizes to ferric sulfate
which is aggressive to aluminum alloys. See also Ref:
(I) p. 133, (2) p. 291, (3) p. 84. (7) p. 93.
FERTILIZERS.
In laboratory tests. the corrosive effects of fertilizers on aluminum alloys vary greatly
with some being compatible and others very cormswe. Generally the solid and liquid nitrogen fertilizem have been the least corrosive while the complete
mix neutral fertilizers have been the most corrosive.
Aluminum alloy equipment
has been used in the
manufacture and handling of the nitrogen fertilizers.
See also Ref: (3) p. 64.
FLSB. Laboratory tests have shown that alloys 1100
and 3003 are resistant to most fish products at ambient temperature.
Aluminum
alloys have been
widely used in the construction of fish holds and linings of fishing vessels, fish boxes, trays, smoke racks,
and tables. Many fsh products can be preserved in
either protected or unprotected aluminum alloy containers. See also Ref: (1) p. 133. (3) pp. 198, 207.
208, (4) pp. 72. 78. (6) p. 12.
FLOUR. Aluminum
milling and handling
(6) p. IO.

Handbook

equipment
has been used in
flour. See also Ref: (3) p. 203,

FLUE GASES. The corrosivity of flue gases to aluminum alloys depends on the sulfur content of the
fuel being burned and if condensation
is present.
The sulfur content of fuels increases in the following
order: processed natural gas. fuel oil. hard coal. soft
coal. Aluminum alloys have been widely used for flue
linings and vent pipes serving domestic gas-fired appliances and has been specified by many gas companies and public utilities. Aluminum alloy flue liners
have been widely used for house chimneys. Generally, aluminum alloys will suffer some corrosion if
condensation is present in the flue. See also Ref: (1)
p. 133.
FLUOPHOSPHORK
ACIDS.
H,PO,F(or (HOhFOF); HPOlF, (or HOPOF>); HPF,.
Aluminum alloy reactors and tanks have been used
in the manufacture
and handling of fluophosphoric
acids. See alw, Ref: (3) p. 37.

ASSOCIATION

(continued)

FLY ASH. Laboratory tests have shown that alloy


3003 is resistant to dry fly ash at ambient temperature. The results of similar tests showed that wet fly
ash caused variable results depending upon the composition of the fly ash. particularly the pH. chloride
content and heavy metal content. Tests should be
conducted prior to using aluminum alloys in applications involving contact with fly ash.
FOOD. (SEE SPECIFIC FOODS).
The use of
aluminum alloy cooking utensils has been universal
for the preparation and cooking of foods. See also
Ref: (3) p. 197.
FORMALDEHYDE
GAS. HCHO. Aluminum alloy
equipment has been used for distillation. storage,
and shipment of formaldehyde.
Alloy 356.0 valves
have been used for handling formaldehyde. See also
Ref: (1) p. 133. (2) p. 307. (3) p. 119. (4) pp. 73, 86,
97, (7) p. 95.
FORhALIN.
A solution of formaldehyde gas in
water usually with methanol added. Laboratory tests
at ambient temperature
and at 38C (100F) indicated that 1100. 3003 and 5052 alloys were resistant
to 19% solution of formalin. At boiling conditions.
formalin (37% solution) caused substantial pitting
corrosion. Chlorides and copper salts increase pitting in formalin solutions. Aluminum alloy piping.
storage tanks, drums and tank trucks have been used
for handling formalin solutions. See also Ref: (1)P.
133, (3) p. 119, (7) p. 95.
MRMAMIDE.
H. CO. NH,. Alloy 1100 was resistant to aqueous solutions of formamide (LO-100%)
at ambient temperature and at 50C (122F) in laboratory tests. Similar solutions (greater than 10%) at
the boiling temperatures were very corrosive. See also
Ref: (3) pp. 143. 147. (7) p. 95.
FORMIC ACID. HCOOH.
Solutions
of formic
acid caused mild attack of 1100 alloy in laboratory
tests at ambient temperature.
In laboratory tests at
50C (122F). the formic acid was corrosive, and at
the boiling tempertore.
formic acid was very COROsive. Aluminum is not recommended for use with forSee
mic acid except in special cases.
also Ref: (1) p. 133. (2) p. 315. (3) pp. 22. 124, 125.
227. (7) p. 95.
FREON*. Agroupof halogenated hydwarbons
used
as refrigerants, propellants. blowing agents, fire extinguishing
agents, and solvents. Laboratory tests
have shown that 1100 alloy is resistant to most dry
Freons at elevated temperature
200C (392F). In
similar laboratory tests, the presence of moisture
permitted hydrolysis of the Freons and subsequent
corrosion of the aluminum. Aluminum alloy refrigeration and air conditioning equipment has been used
with Freons. See also Ref: (1) p. 133. (2) p. 239. (3) p.
107, (7) pp. 58, 60. 74.
lR.sllleRd TradeMlrk.

FLUORINATED
HYDROCARBONS.
Fluorinated
hydrocarbons are the most stable halogenated hydrocarbons and the most compatible with aluminum
alloys. They have been used as propellants and refrigerants in contact with aluminum alloys in many
applications. See Freon and Ha&mated
Hydracarbons.

FRUIT. Some of the acids in fruits have been found


to be corrosive to aluminum alloys in laboratop tests.
Because of the presence of denrose. proteins and
pectin in fruit. the corrosive action is inhibited in
many cases. Protected aluminum alloys have been
used for canning fruit and foil has been used for
wrapping and containers. See also Ref: (1) p. 133, (3)
p. 208, (4) pp. 72. 79. 80, 81. (6) p. 10.

FLUORINE.
F. In laboratory tests, II00 alloy was
resistant to fluorine at temperatures
up to 4SOC
(842F). In the presence of moisture. hydmfluoric
acid is formed which corrodes aluminum alloys. Dry
fluorine gas has been handled in aluminum
alloy
equipment. A durable protective coating is formed
on the aluminum surfaces contacting the gas. See
also Ref: (I) p. 133. (2) p. 297, (3) p. 35, (7) p. 95.

FRUIT JUICES. (See also Citrus Fruit Juices).


Fruit juices are processed and handled in aluminum
equipment. Orange squeezers have been made of
aluminum alloys. Fmzen juice cans have aluminum
alloy ends. Fruit juices are generally less corrosive to
aluminum alloys than are the corresponding
fruit
acids. See also Ref: (1) p. 133, (2) p. 321. (3) pp. 131.
201. (4) pp. 88. 89. 90. (6) p. 10, (7) p. 95.

FUDGE. In laboratory tests, alloy 3003 was resistant


to fudge at ambient temperature and 62C (143OF).
Milk chocolate
fudge has been processed
in
aluminum alloy equipment. See also Ref: (6) p. 12.
FUEL OIL. Fuel oil has been stored and transported in aluminum alloy equipment. See also Ref:
(I) p. 133. (3) p. 220.
FUELS, MISSILE. United States Defense Research
reports that aluminum is resistant to many oxidizers
and fuels used as missile propellants.
Aluminum
alloys are used with chlorine trifluoride. ethylene oxide, fluorine. hydrazine. unsymmetrical
dimethyl
hydrarine. hydrogen peroxide. liquid oxygen. nitrogen tetroxide tO.l% or IeCs moisture). fuming nitric
acid, n-propyl nitrate, liquid nitrogen. alkyl boranes. perchloryl fluoride (anhydrous) and liquid hydrogen. Ref: Titan 11 Storable Propellant Handbook-Bell
Aerospace Company. New York. Report
No. 81 II-933003
FURFURAL.. C,H,O?.
In laboratory tests. alloy
3003 was resistant to solutions of furfural at ambient
temperature and 200C t392F). Aluminum storage
tanks, evaporators. condensers. valves and pumps
have been used to handle gasoline-furfural
mixtures.
Aluminum bubble caps. trays and heat exchangers
have been used uhere furfural is used as the selective
wlvent.
Pure furfural for pharmaceuticals has been
stored in aluminum.
,Alloy 3jb.O valves have been
used for handling furfural. See also Ref: (I) p. 133.
I?) p. 325. (3) p. 148. (-1 p. 95.

G
GASOLINE. A minure of C, to C,! hydrocarbons:
also paraffins, olefins. naphthenes.
and aromatics:
traces of tetraethyl
lead. ethylene dibromide or
dichlonde
and proprietary
additives.
Laboratory
tests have shown that aluminum
alloys including
3003 were resistant to gasoline at room temperature.
Thev tests also showed that the sump water in gam
line tanks can be corrosive because of the accumulation of halogen and lead compounds. Gasoline has
been handled in aluminum alloy drums and tanks.
Aircraft fuel tanks have been fabricated from aluminum alloys. Alloys 3003, Alclad 3003, 5052, 6061,
and A356.0 have been used with gasoline. See also
Ref: (1) p. 133.
GELATIN. Gelatins are handled extensively in aluminum alloy equipment. Aluminum vats are used to
digest pork skins. calf skins, and animal bones at
66OC (150F) using dilute solutions of H&V,. HCI,
HNO,, H,SO,. or SOS depending on the final pH requirementsof thegelatin (pH range 3-7). Aluminum
alloys have also been used in evaporators,
piping.
tubing. tanks, pumps, drying tunnels. and convey
ors. Aluminun is one of the few metals in which edible gelatin can be produced to meet requirements of
the Pure Food and Drug Law. It is not recommended
as containers for finished gelatin solutions unless
protected because of the presence of salt. See also
Ref: (1) p. 133. (2) p. 328. (3) p. 210. (4) pp. 48. 73.
84. 100. (6) pp. 10. (7) p. 97.
GLASS WOOL. Fine filamentsof glass intermingled
like wool. In laboratory tests, 3003 alloy was resistant
to all dry glass wools, but when wet in 100% relative
humidity environments. soft glass wools were cormsive whereas, 3003 alloy was resistant to hard glass
(borosilicate type) wools. The binders used in glass
wools may be corrosive to aluminum alloys in some
cases. Glass wool has been used to insulate many aluminum alloy products. See also Ref: (10) pp. 29, 108.
GLUCONIC

ACID.

CIIHIzO,. Laboratory

tests indi-

(continued)

Nonferrous Metals and Alloys

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

cated that 1100 alloy was resistant to 10% solutions


of gluconic acid at ambient temperature. Increase in
temperature resulted in substantially
increased corAluminum alloy equipment has
rosion
been used to produce gluconic acid from sugars by
the fermentation process. Neutralization of gluconic
acid to produce calcium gluconate is carried out in
aluminum alloy equipment. See also Ref: (1) p. 133.
(2) p. 332. (3) p. 129. (7) p. 97.
GLUCOSE. C,H,>Oe H20. Glucose solutions have
been stored in alloy 6061 tanks. Alloy 356.0 valves
habe been used for handling glucose solutions. See
also Ref: (I) p. 133. (3) p. 12.3.
GLUE. Originally an impure form of gelatin. In
more modem times, glue is one of many types of adhesives uxd for bonding. In laboratory tests, most
adhesives were found to be either innocuous or pmrectne to aluminum
alloys. Houever. exceptions
\rere found and included the alkaline water base
latex adhesives, acetic anhydride
adhesives, and
adhesives that have been made electrically conductive by the addition of copper, silver. or carbon. Such
adhesives ihould be used with caution and with the
knowledge that corrosion could develop. Adhesives
are used with aluminum alloys in many applications.
See also Ref: (1) p. 133, (3) pp. 124. 199.231.2.33. (4)
pp. 107. 11.5. R. L. Patrick, Editor. Treatise of
Adhesion and Adhesives, Vol. 111. Marcel Dekker.
New York, 1973.

GLYCERIN.
CH,OH.CHOH.CH,OH.
Laboratory tests indicate that alloy 3003 is resistant to gly
cerin solutions at ambient and boiling temperatures.
Aluminum alloys have been used for still,. condensers. heat exchangers, storage tanks, and tank cars for
handling glycerin. Alloy 356.0 valves have also been
used. See also Ref: (1) p. 133. (2) p. 337. (3) pp. 115.
240. (7) p. 97.
GLYCEROPHOSPHATE.
H,O,IOCH~~CHOH~
CH@H. Glycerophosphate
has been shipped in ahminum alloy containers. See also Ref: (3) p. 137.
GLYCOLIC ACLD. HOCH&OOH
(Hydmxyacetic
Acid). In laboratoty tests, glycolic acid was corrosive
to 3003 and SlS4 alloys at IO0C (212). Glycolic
acid solutions have been stored and shipped in aluminum alloy containers. See also Ref: (1) p. 133. (3)
p. 129, (7) p. 105.
GRAPEFRUIT JUICE. Laboratory tests indicated
that 1100 alloy was resistant to grapefruit juice at ambient and refrigerated temperatures
(see Fruit and
Fruit Juices). See also Ref: (4) p. 90, (6) p. 10.
GRAPE JUICE. In laboratory tests. unfermented
grape juice caused mild attack (2 mpy) of llC0,3003.
and 3004 alloys at room temperature. Aluminum alloy equipment has been used for harvesting grapes
and grape juice has been transported in aluminum
alloy tank cars (see Fruit and Fruit Juices). See also
Ref: (4) pp. 88, 91. (6) p. IO.
GRAPHlTE.
Alloys 3003. SIM and 6061 were resistant to solid graphite in laboratory tests under conditions of 100% relative humidity at ambient temperature and 54C (130F). Other laboratory tests have
shown that graphite smears on aluminum are carmsive because of galvanic corrosion of the aluminum.
See also Ref: (3) p. 50, (5) p. 13.
GUM ARABIC. A dried gummy exudation from the
stems and branches of Acacia. Aluminum alloy containers have been used for storing gum arabic solutions. See also Ref: (1) p. 134, (3) p. 226.

ASSOCIATION

619

(continued)

H
HALOGENATED HYDROCARBONS. Aluminum
alloys are usually resistant to pure halogenated hydrocarbons and other organic chemicals containing
halogens under most conditions particularly at room
temperature or lower. Under certain conditions some
of these hydrocarbons may produce a rapid rate of
corrosion of aluminum or a violent reaction. Hence,
the service conditions to insure safety should be recognized or established before aluminum alloys are
used with any halogenated hydrocarbon.
Halogenated hydrocarbons may decompose by hy
dmlysis if water is present or by other processes to
yield mineral acids such as hydrochloric acid. These
acids corrode aluminum alloys because they destroy
the protective surface oxide fdm naturally present
that provides inherent resistance to corrosion. Cormsion of aluminum alloys by these acids may also
promote reactions of the hydrocarbons themselves
hecause aluminum halides formed bv corrosion are
catalysts for some of these reactions (e.g. AICI, for a
Fried&Crafts
reaction). In some instances. aluminum alkyls may be produced. Because of the rapid
rate of evolution of heat, corrosion of aluminum and
reaction of a halogenated hydrocarbon. once initiated, may tend to become autocatalytic.
The reactivity of aluminum alloys with halogenated hydrocarbons decreases generally in the order of
increasing chemical stability of these hydrocarbons,
which may be established precisely by themwdy
namic data whenever these data are available, or
qualitatively by the structural formulas of the hydracarbons and by the halogens they contain. Thus. aluminum is most resistant to hydrocarbons halogenatsd with fluorine followed in order of decreasing
resistance to those with chlorine. bromine and iodine. It is also resistant to highly polymerized halogenated hydrocarbons. reflecting the high degree of
chemical stability of these materials.
The behavior of aluminum alloys in a mixture of
halogenated hydrocarbons. or mixtunzs of these hydrocarbons with other organic compounds cannot be
predicted fmm its behavior with each of the compo.
nents. Some mixtures (e.g. of methyl alcohol and carbon tetrachloride) produce rapid corrosion of some
aluminum
alloys at ambient
temperature
even
though the components alone do not.
The resistance of aluminum alloys to halogenated
hydrocarbons tends to decrease as the temperature is
raised and the rate of corrosion in many liquid halw
genated hydrocarbons remains low until the boiling
point is reached; in some, it is low or non-existent
even at this temperature. Other factors that affect Rsistance include the presence of an inhibitor and the
purity of a halogenated hydrocarbon; amines or various heterocyclic compounds have been effectively
used as inhibitors in certain cases.
Aluminum in a finely divided form, as in a powder,
should not be exposed to a halogen&d
hydrocarbon.
The likelihood of creating a violent reaction that may
lead to an explosion is increased when aluminum
with a large surface area is exposed to a small volume
of a halogenated hydrocarbon,
and even more so
when this operation is carried out under pressure.
Specific entries in this book for fluorinated hydrocarbons such as Freons and inhibited halogenated hydrocarbons such as solvents for degreasing illustrate
applications with halogenated hydrocarbons.
In summary, the service conditions to insure safety
should be recognized or established before aluminum alloys are used with any halogenated hydrocarbon. With respect to aluminum and a specific halogenated hydrocarbon
under specific conditions.
aluminum producers may be able to submit useful
data.
HELIUM. He. Aluminum alloys have been used for
heat exchangers in the manufacture of helium and

for covering on lighter than air ships. See also Ref: (1)
p. 134. (3) p. 35.
HEPTYL ALDEHYDE. CH,(CHI)SCHO.
num alloy separators. rectifier tanks. and
tanks have been used with both crude and
heptyl aldehyde. See also Ref: (3) p. 120. (7)

Alumistorage
refined
p. 99.

n-HEX&NE. CH,.(CH2),CHI.
Aluminum alloy heat
exchangers have been used with n-hexane. See also
Ref: (7) pp. 98, 99.
HONEY. Contains mainly levulose and dextrose;
some sucrose. wax. pollen. and other organic matter.
Aluminum alloy equipment has been used for pasteurizing honey. Honey has been packed in aluminum containers. See also Ref: (I) p. 134, (3) p. 203,
(6) p. 10.
HYDRAZINE.
H2NNHI. In laboratory tests, hydrazinc caused mild attack of 3oQ3 and 5154 alloys at
ambient temperature.
The action of hydrazine on
aluminum alloys is increased by the presence of moisturn resulting in hydrolysis. See also Ref: (1) p. 134,
(2) p. 353. (3) p. 44, (7) p. 101.
HYDROARIETYL
ALCOHOL.
C,&CH,OH.
Aluminum alloys have been used for piping, full flow
filters, final condensers, and steam heated storage
tanks in the production of hydmabietyl alcohol. See
also Ref: (3) p. 115. (7) p. 101.
HYDROCARBONS.
Organic compounds containing hydrogen and carbon. In laboratory tests. alloy
1 I00 and 3003 were resistant to most hydrocarbons.
Aluminum alloys have been used to piping, pumps,
condensers,
*eat exchangers,
valves, impellers.
ducts, fan and blowers. storage tanks, and shipping
containers for handling hydrocarbons. See also Ref:
(3) p. 101.
HYDROCHLORIC ACID. HCI. Aluminum is carroded by hydrochloric acid. The rate of attack increases with acid concentration
and temperature.
Metal purity plays a significant role in the degree of
Inattack by hydrochloric acid.
creasing purity of the aluminum decreases the rate of
attack by hydrochloric acid significantly. Inhibitors
can be effective in reducing the corrosive effects of
hydrochloric acid, particularly in dilute (< 10%) solutions. Such inhibited acid has been used to clean
aluminum equipment and containers. See alw, Ref:
(1) p. 134, (2) p. 359. (3) pp. 22.37. 244, (4) pp. 15,
16, 17. 27, 29. 30. 31. 34. 73. 74, 97, 127, (7) p. 101.
HYDROCYANIC ACID. HCN. In laboratory tests,
alloys 3003. 5052. and 6053 were resinant to a 77%
solution of hydmcyanic acid at ambient temperature.
Hydrocyanic acid has been processed in aluminum
distillation towers. reflux condensers, final condensers. adsorption towen. heat exchangers. tankage,
shipping drums, and piping. See also Ref: (1) p. 134.
(2) p. 368, (3) p. 51. (7) p. 101.
HYDROFLUORIC ACID. HF. Aluminum alloys
are corroded by hydrofluoric acid. With most alloys,
the action is uniform and imparts a bright silvery appearance. This acid has been used as an etchant on
aluminum in preparing decorative patterns. See also
Rrf: (I) p. 134. (2) p. 372. (3) p. 36, (4) p. 86. (7) pp.
101, 103.
HYDROGEN.
Hz. Aluminum alloy equipment has
been used to produce and to store hydrogen. See also
Ref: (2) p. 379. (3) p. 35. (7) p. 103.
HYDROGEN CHLORJDE GAS. HCI (SEE HYDROCHLORIC
ACID). Aluminum alloys are COT-

(continued)

620

Corrosion Resistant Materials Handbook

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

ASSOCIATION

(continued)

mded by hydrogen chloride gas. The reaction becomes more rapid as temperature is increased. Aluminum equipment has been used with dry hydrogen
chloride gas at 288C (SWF). See also Ref: (2) p.
383. (3) p. 36, (7) p. 103.

[RON SULFIDE,
FeS. Dly iron sulfide has been
shipped in aluminum alloy containers. In laboratory
tests, iron sulfide accelerated corrosion of contacting
aluminum alloys as the result of galvanic action. See
also Ref: (3) p. 84.

HYDROGEN CYANIDE GAS. HCN (SEE ALSO


HYDROCYANIC
ACID. In laboratory tests, alloy
3003 was resistant to hydrogen cyanide gas at ambient temperature.
Aluminum alloy heat exchangers. reactor towers, tanks. and piping have been used
in the manufacture of hydrogen cyanide gas. See also
ReI: (2) p. 368, (3) p. 51.

ISOAMYL ACETATE.
(CH,COO .CH,. CH*CH(CH,),.
Laboratory tests
showed that 3003 and 5052 alloys were resistant to
isoamyl acetate at temperatures up to and including
the boiling temperature. See also Ref: (3) p. 136. (7)
p. 107.

HYDROGEN
PEROXIDE.
H,Oz. In laboratory
tests, alloys lC60. 5OS2 and 6063 were resistant to
chloride free hydrogen peroxide at ambient temperature. Aluminum alloy distillation towers, heat exchangers, storage tanks. piping. tank cars and shipping drums have been used with hydrogen peroxide.
Alloy 1060 has been preferred for long term storage,
whereas, the SXXX series alloys often have been used
for short term storage. Alloy 6063 has been used for
piping. See also Ref: (I) p. 134. (2) p. 391. (3) pp. 39,
234. (4) p. 55. (7) p. 103.
HYDROGEN SULFIDE.
H,S. In laboratory tests,
aqueous solutions of hydrogen sulfide and hydrogen
sulfide gas caused mild attack ( - 2 mpy) of alloys
II00 and 3003 at ambient temperature.
Aluminum
alloy storage tank roofs for sour crude oils, bubble
caps. dnd heat exchangers have been used in refinery
service handling hydrocarbon
liquids and vapors
containing hydrogen sulfide. See also Ref: (1) p. 134.
(2) p. 3%. (3) pp. 40. 214. 223. 234, (7) p. 103.

I
ICE. Aluminum alloy equipment has been used in
the manufacture of w and for refrigeration units.
See also Ref: (3) p. 28. (4) p, 49.
ICE CREAM. Aluminum alloy trays. molds, pans
.md freezer components hake been used to handle ice
cream. See also Ref: (4) pp. 102. I IS. (6) p, I I.
INK. Laboratory tests have indicated that inks vary
widely in their corrosivity to aluminum alloys. Generally. writing inks have been found to be corrosive,
while marking inks are not. However, in view of the
wide variability. it is desirable to conduct preliminary tests to establish the suitability of aluminum
alloys Hith a particular ink. Aluminum alloy tanks
have been used for transporting
printing ink. See
also Ref: (I) p. 134, (3) p. 199. 238.
(NVERT SUGAR. A mixture of about 50% dextrose and 50% levulose obtained by hydrolysis of sucrose. Aluminum alloy piping and tanks have been
used to handle invert sugar.
IODINE. I> In laboratory tests, alcohol solutions of
iodine were comxive to aluminum alloys. See also
Ref: (1) p. 134, (2) p. 406. (3) p. 36. (7) p. 107.
IODOFORM.
CHI,. Solid iodoform caused moderate attack ( - 7 mpy) of alloy 3003 in laboratory tests
conducted under conditions of 100% relative humidity at ambient temperature. CAUTION: See Halogenated Hydrocarbons.
See also Ref: (I) p. 135. (3)
p. 106. (7) p. 107.
IRON OXIDES.
FexO,,Fe,O,.
Alloys 3003 and
5154 were resistant to solid ferric oxide in laboratory
tests under conditions of 100% relative humidity at
ambient temperature. See also Ref: (1) p. 135, (3) p.
83.

ISOAMYL
ALCOHOL.
(CH,)lCHCHICHzOH.
Laboratory tests indicated that alloy 5154 was resistant to 85% isoamyl alcohol at 93C (2OOOF). See
also Ref: (3) p. 113.
ISOBUTYL ACETATE.
CH, COO. CHz. CH(CH&.
Aluminum alloy tank
cars have been used to transport isobutyl acetate. See
also Ref: (7) p. 107.

80%) caused mild attack ( - 3 mpy) of 3003 alloy. At


100C (212F). aqueous solution of lactic acid was
vety corrosive with the maximum attack occurring at
about 5% concentration. See also Ref: (1) p. 135, (2)
p. 417, (3) pp. 22, 129. (4) pp. 25. 26. 28. 29.30.31.
62. 92. 97. 102. (7) p. 111.
LARD OIL. Lard oil has been handled in aluminum
alloy equipment. See also Ref: (6) p. 12.
LATEX. Principally isoprene polymers. In laboratory tests, latex with pH 10 caused mild attack of
3003 alloy at ambient temperature. Aluminum alloy
tanks and steam-jacketed kettles have been used in
storing and processing latex. Aluminum alloy cups
have been used for collecting latex from rubber trees.
See also Ref: (3) pp. 103. 125, 227.
LEAD ACETATE.
Pb(C2H,0&.3Hz0.
Solid lead
acetate caused mild attack ( -4 mpy) of alloys 3003.
5154 and 6061 at ambient

temperature.

but was car-

rosive to the same alloys at WY


(130F)
tory tests conducted under conditions of

in labora-

ISOBUTYL
ALCOHOL.
(CH,)$H.CH,.OH.
Limited laboratory tests indicated that 3003 alloy
was resistant to isobutyl alcohol at ambient temperature, but is corrosive ( - 18 mpy) at elevated temperature 204C (4OOF). See also Ref: (3) p. 113.

100% relative humidity. In other laboratory tests. alloy 3003


was resistant to 0.1% aqueous solution of lead acetate, while 1.0% and 10% solutions were corrosive at
ambient temperature. See also Ref: (1) p. 135. (3) p.
81, (7) p. 111.

ISOBUTYRIC
ACID. (CH,), CH.COOH.
Isobutyric acid has been stored in aluminum alloy tanks
and handled in aluminum alloy piping. See also Ref:
The Corrosion of Light Metals (p. 14) Goddard, Jepson, Bothwell and Kane.

LEAD AZIDE. Pb(N,)> Aluminum alloy trays have


been used for drying lead azide at temperatures
not
exceeding WC (140F). See also Ref: (3) p. 81; H.
Kast and H. Heid. Z. Angew. Chem. 38; pp. 43-52
(1925).

ISOEUGENOL.
C,,,H,,02.
Isoeugenol has been
stored and shipped in aluminum alloy containers.
See also Ref: (3) p. 118.

LEAD MONOXIDE.
PbO. Alloys 3003 and 5154
were resistant to solid lead monoxide in laboratory
tests conducted under conditions of 100% relative
humidity at ambient temperature. See also Ref: (1)
p. 135.

ISOOCTMOIC
ACID. (CH,)zCH(CH1),COOH.
Aluminum alloy containers have been used for storage and handling of isooctanoic acid.
ISOPROPYL ALCOHOL. CH,CHOHCH,.
Laboratory tests showed that alloy 3003 was resistant to isopropyl alcohol at IWC (212F) and 204C (4WF).
See also Ref: (1) p. 135. (3) p. 113. (7) p. 109.
ITACONIC ACID. CH,C(COOH)CH&OOH.
Aluminum alloy pans have been used in the pmcessing of itaconic acid.

K
KEROSENE.
Kerosene has been processed and
handled in aluminum alloy equipment. Aluminum
alloys have also been used for vapor degreasing
equipment. See also Ref: (1) p. 135. (3) pp. 218, 219.
KIPPERS. Kippers have been packed in aluminum
alloy cans. See also Ref: (4) pp. 106, 108. (6) p. 12.

L
LACQUERS.
May contain nitmcellulose or a viscous liquid obtained from plants plus diluents. plasticizers. resins and pigments. Lacquers have been
used extensively for coating aluminum alloys. Aluminum alloys have been used for the production, handling, and storage of lacquers. See also Ref: (1) p. 135,
(3) p. 225. (4) pp. 48, 79. 95. %, 97, 103, 105, 109,
110, 114, 115. 117, 119, 137, 140, 141.

LEAD NITRATE. Pb(NO,)z. Solid lead nitrate was


very corrosive (more than 50 mpy) to 3003. 5lS4 and
6C61 alloys in laboratory tests under conditions of
100~0 relative humidity at ambient remperature. See
also Rrf: (31 p. 81. (7) p. 113.
LEAD OXIDE. Pb,O,. Alloys 3003.5154 and 6061
were resistant to solid lead oxide in laboratory tests
under conditions of 100% relative humidity at ambient temperature
and at 54C (13OOF). Priming
paints containing lead should not be used on aluminum alloys because of the possibility of accelerated
corrosion. See also Ref: (3) p. 238.
LEAD TETRAJ?THYL.
Pb(CzHs),.
Laboratory
tests showed that 3003 alloy was resistant to gasoline
containing lead tetraethyl at ambient temperature.
Aluminum alloy tank trucks and aircraft gasoline
tanks have been used to handle leaded gasoline. In
the presence of a separated water phase. some by
products of the lead tetraethyl, such as lead bromide.
accumulate in the water and cause corrosion. See
also Ref: (1) p. 135. (3) p. 218.
LEATHER. Aluminum alloy equipment
has been
used in handling leather. See also Ref: (9) pp. 42.43.
LEMON JUICE. In laboratory tests, alloy 3003 was
resistant to lemon juice at ambient and Rfrigerated
temperatures.
Domestic aluminum alloy juicers for
lemons have been used (see Fruits and Fruit Juices).
See also Ref: (1) p. 135, (4) pp. 88, 90. (6) p. 10.
LIME. CaO. Solid lime caused mild attack (- 1
mpy) of alloy 3003 in laboratory
tests conducted
under

conditions

bient

temperature.

133, (3) pp.

di-LACTIC ACID. CH,.CH(OH).COOH.


In labxatory tests, aqueous solutions of lactic acid 10.0.5 to

of 100%

relative

See also Ref:

humidity
(I)

p.

at am-

128. (2) p.

229, 242.

(continued)

Nonferrous Metals and Alloys


TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

LIME JUICE. Laboratory tests showed that alloys


3003. 5052 and 5086 were resistant to lime juice at
ambient and refrigerated
temperatures.
See also
Ref: (6) p. IO.
LIME MORTAR. Contains hydrated lime, sand.
Portland cement. coloring. During the period when
mortar is liquid. aluminum
alloys show etching
which ceases when the mortar dries because of the
formation of a protective film. It is good engineering
practice to protect aluminum alloys contacting mortar in a faying surface to minimize crevice corrosion.
See also Ref: (1) p. 129. (2) p. 161. (3) p. 72.
LIMESTONE.
CaCO,. .Aluminum alloy equipment
has been used in handling limestone. Aluminum
alloy building products have been used in contact
with limestone. See also Ref: (3) p. 76.
LINSEED
OIL.. Contains
glycerides of linoleic,
oleic. stearic. palmitlc and myrinic acids. In laboratory tests, alloy 3003 was resistant to linseed oil at
300. 350 and 380C (572, 662. and 716OF). In the
same tests, linseed oil vapors at these temperatures
were corrosive to 3003 alloy. Aluminum alloy vessels
have been used to heat linseed oil to 25OC (482F).
See also Ref: (1) p. 135. (2) p. 427, (3) p. 238, (7) p.
113.
LITHIUM CHLORIDE.
LiCI. Alloys 3003, 5154
and 6061 were resistant to solid lithium chloride in
laboratory tests conducted under conditions of 100%
relative humidity and at ambient temperature. In the
same tests conducted at 41C (130F). solid lithium
chloride caused mild attack of the same alloys. In I %
to 40% aqueous solutions. lithtum chloride caused
mild attack (- 3 mpy) of 3003, 252 and 6061 alloys
at ambient temperature and at joC (122F). Local
pitting was encountered in the solution tests. See also
Ref: (I) p. 135, (2) p. 429, (7) p. 113.
LITHOPONE.
A mixture of zinc sulfide. barium
sulfate and some zinc oxide. Solid lithopone caused
mild attack ( - 1 mpy) of 3003 and 5154 alloys in laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
Aluminum alloys have been used for pipe lines and driers in
the manufacture of lithopone. See alw, Ref: (1) p.
135. (2) p. 433. (3) p. 238. (7) p. 115.

ASSOCIATION

(continued)

MAGNESIUM
NITRATE.
Mg(NO& .6 H>O.
Alloys 3003. 515-I and 6061 were resistant to solid
magnesium nitrate at ambient temperature but suf.
fered mild attack ( - 2 mpy) at 54C (130F) in laboratory tests conducted
under conditions of 100%
relative humidity. In other laboratory tests, 3003
alloy was resistant to I%, 5% and 10% solutions at
ambient temperature. See also Ref: (I) p. 136. (3) p.
75, (7) p. 117.
MAGNESIUM
OXIDE. MgO. Alloys 3003. 5154
and 6061 were resistant to solid magnesium oxide in
laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature
and at
54C (130F). See also Ref: (3) pp. 72. 230.
MAGNESIUM
SILICATE.
MgSiO,. Alloys 3003.
5154 and 6061 were resistant to solid magnesium silicate in laboratory tests conducted under conditions
of 100% relative humidity at ambient temperature
and at 54C (130F). See also Ref: (3) p. 76.
MAGNESIUM
SULFATE.
MgSO,. 7H,O. In limired laboratory tests, 1100 alloy was resistant to aqueus solutions of magnesium
sulfate (O.ooOl% to
10%) at ambient temperature.
See also Rrf: (1) p.
136. (2) p. 440. (3) p. i5, (7) p. 117.
MALEIC ACID. HOOCCH: CHCOOH. Alloys 3003
and 5154 were resistant to solid maleic acid in laboratory tests conducted under conditions of 100% relative humidity and ambient temperature.
In other
laboratory tests, 30% aqueous solutions of maleic
acid caused mild attack ( -5 mpy) of I IO0 alloy It
52C (126F). Other laboratory tests conducted at
IOOC (212F) showed that maleic acid uas crwsi\e
to 1100 alloy
See also Ref: CI) p. 136.
(3) p. 131. (7) p. 117.
MALEIC ANHYDRIDE.
(CHCO)>O. Alloys JO03
and 5154 were resistant to solid m&ctc anhydride in
laboratory tests conducted under conditions of 100%
relative humidity at ambient tempemrure.
.Mlren
maleic anhydride has been stored in 3lumium alloy
tanks. See also Ref: (I) p. 136. (3) p. 131. I-) p. I Ii).
I-MALIC ACID. HOOCCH(OH) CH:COOH.
In
laboratory tests, aqueous solutions (up to 55%) of
malic acid caused mild attack ( - 2 mpy) of 1100 3110~
at ambient temperature.
In the same tests. these *
lotions were corrosive to 1100 alloy at 100C (212F).
See also Ref: (1) p. 136. (3) pp. 131. 209. (4) pp. 25,
26, 29, 30, (7) p. 119.

LUBRICATING
OILS. Laboratoty
tests indicate
that alloy 3003 was resistant to most lubricating oils
at ambient
temperature
and at 66C (150F).
Aluminum alloys generally do not accelerate oxidation of lubricating oils. Aluminum alloy tank trucks
and cans have been used for lubricating oils. Alloy
356.0 valves have been used for handling lubricating
oils. See also Ref: (1) p. 135. (3) p. 220.

MALONIC ACID. HOOC CH1. COOH.


Limited
laboratory tests indicated that 3003 alloy was resistant to malonic acid at ambient temperature.
See
also Ref: (1) p. 136, (3) p. 130. (7) p. 119.

MAPLE SYRUP. In laboratory tests, alloy 1100


syrup
at ambient
was resistant
to maple
temperature. Aluminum alloys have been used for
evaporators
and other equipment
in processing
maple syrup. See also Ref: (I) p. 136, (6) p. 10.

MAGNESIUM
CHLORIDE.
MgCIz. Alloy 3003
was resistant to solid magnesium chloride in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests. alloy 1100 was resistant to aqueous
solutions (up to 10%) of magnesium chloride at ambient temperature.
Localized pitting was encountered in the aqueous solution tests. See also Ref: (1)
p. 136. (2) p. 435. (3) pp. 73. 230. (7) p. 117.

MARGARINE.
A mixture of natural or hydrogenated animal or vegetable fats plus colonng and flavoring. In laboratory tests, alloy 3003 was resistant to
margarine at ambient and refrigerated
temperatures. Aluminum alloys have been used for storing
and packaging margarine. See also Ref: (3) p. 206.
(4) pp. loo. 103.

MAGNESIUM
HYDROXIDE.
Mg(OH)I.
Limited laboratory tests showed that magnesium hydroxide is corrosive to 1100 alloy at ambient temperature
and that the corrosion rate increases as the pH of the
solution increases. See also Ref: (1) p. 136. (7) p. 117.

621

MEAT. Aluminum alloy equipment has been used in


the meat industry for steam jacketed pans. cookers.
wagons. rods. racks, boilen and Taste barrels. Aluminum alloy foil has been used to wrap meat to be
frozen. See also Ref: (1) p. 136. (J) pp. 198, 206. (4)
pp. 72, 78. 80. 99. 106, 109. (6) p. 12.

MERCURY.
Hg. The actwn of metallic mercury on
aluminum is unique. It rends I amalgamate with
aluminum to produce 3 surface that corrodes at an
extraordinarv rate in the presence of moisture uith
the production of voluminous columnar corrosion
products. When that reaction is rtarted. the rxe of
corrosion is dependent upon reletne humidity. When
dry. metallic mercury reacts onl! nlth difficulty because of the oxide film on the aluminum surface.
Traces of acidity or halides on the surfax dive rire 10
raped attack. Solutions containing mercu~ ions tend
to cause rapid pitting of aluminum alloys because of
plating out of mercury in localized areas. Mercury
can be removed from aluminum wrf~es by treatment uith -0% nitric acid. Mercury can be distilled
away from 3 aluminum curf~e by trentmenr uirh
steam or hot a,r. See also Rrf: (I) p. 136. 12) p. 440.
(3) p. 80.
MERCURY SALTS. In laboratory tests. aqueous
solurions of mercury salts uere \ery corrosive to aluminum alloys. See also Ref: (1) p. 136. (2) p. 444. (3)
pp. <SO.132. 238.
METHANE. CH+ Aluminum alloys have been used
for pressure vessels in the storage and transport of
compressed methane gas. Aluminum alloy tanks and
pipe lines have been used extensively for handling
liquid methane at temperatures
as low as -1bOC
(-256F).
See also Ref: (I) p. 136, (3) pp. 103, 214,
(7) p. 121.
METHYL ALCOHOL.
CH,OH. Laboratory tests
showed that 1100 alloy was resistant to commercial
absolute methanol at ambient and boiling temperatures. In the same tests, aqueous solutions of methanol varied in their corrosivity with concentration.
Anhydrous methanol at the boiling point was cormsix. Alummum alloys have been used for drums.
tanks and piping for processing and handling methyl
alcohol. See also Ref: (1) p. 137. (2) p. 449, (3) p.
112. (7) p. 121.
METHYLAMINE.
CHINHZ. Aluminum alloyequipment has been used in refrigeration systems perating uith methylamine. See also Ref: (1) p. 137. (2) p,
452. (3) p. 143. (7) p. 123.
METHYL CHLORIDE.
CH,CI. Methyl chloride.
under certain conditions, reacts with aluminum alloys to form metallo-organic
compounds which are
spontaneously explosive up exposure to air. Aluminum is not recommended
for use with methyl
chloride. CAUTION:
See Hnlogenated Hydrocarbons. See also Ref: (I) p. 137. (2) p. 454. (3) p. 105.
(7) p. 123.
METHYLENE
CHLORIDE.
CH#:.
Limited laboratory tests indicated that alloy 3003 *as resistant to
methylene chloride at ambient temperature and at
the boiling point. Inhibited methylene chloride has
been shipped in aluminum alloy containers. CA.!/TION: See Halogenated
Hydrocarbons. See also
Ref: (1) p. 137. (2) p. 437. (3) p. 106, (7) p. 12.5.
METHYL ETHYL KETONE. CH,XO.CH>XH.,.
In lnboratoly tests, alloy 3003 was resistant to condensing vapors of methyl ethyl ketone. Methyl ethyl
ketone has been distilled and condensed in aluminum
alloy equipment. See also Ref: (1) p. 137. (3) p. 121,
(7) p. 125.
METHYL
laboratory
formate at
137. (3) p.

FORMATE.
HCOOCH,.
In limited
tests, 3003 alloy was resistant to methyl
ambient temperature. See also Ref: (I) p.
136. (5) p. IO. (7) p. 125.

METHYL. GLYCEROL.
CH,(OH)CH(OH)COOCH,.
Aluminum alloy pipe
and containers have been used for handling methyl
glycerol.

(continued)

622

Corrosion

TABLE 5.2:

Resistant

ALUMINUM

Materials

Handbook

ALLOYS-ALUMINUM

METHYL ISOBUTYL
KETONE.
(CHJzCHCHICOCH,.
In laboratory
tests, alloy
3003 was resistant to methyl iwbutyl ketone under
boiling and condensing conditions. Methyl isobutyl
ketone has been handled in aluminum alloy tanks
and piping. See also Ref: (7) pp. 124. 125.
METHYL METHACRYLATE.
CH2. C. CH, COO CH, Methyl methacrylate
has
been processed in aluminum alloy equipment
and
handled in aluminum alloy containers. See alw, Ref:
(3) p. 137.
METHYZ SALICYLATE.
C,H,OHCOOCH,.
Limited laboratory tests indicated that alloy 6061
was resistant to methyl salicylate at ambient temperature. Methyl salicylaw has been shipped in aluminum alloy containers. See also Ref: (3) p. 137.
MILK. In laboratory tests. alloys 1100 and 3003
were resistant to sweet milk at ambient and boiling
temperatures.
Aluminum alloys have not affected
the taste of milk. Aluminum alloy equipment
has
been used for handling whole milk and sweetened or
unsueetcned
condensed milk. Powdered milk has
been dried in aluminum alloy towers. Foil hoods have
been used to protect and seal bottles. Fresh milk has
been transported in aluminum alloy equipment. See
also Ref: (I) p. 137. (2) p. 463. (3) p. 204. (4) pp. 78.
84. 98. 100. 101. 102. 106. 109. (6) p. II. (7) p. 127.
MLVERAL OILS. A mixture of liquid hydrocarbons
from petroleum. Laboratory tests indicate that man?
mineral oils are protective fo aluminum alloys. Mineral oils have been stored and transported in aluminum alloy equipment. Alloy A356.0 valves have been
used for handbng mineral oils. See also Ref: (I) p.
137. (3) p. 102.
MOLASSES. Alloys 3003, 5052, 5086 and 6061 were
rerisfant to molasses in laboratory tens at ambient
and 46C (I 14F) temperatures. Copper from earlier
processing equipment can make molasses corrosive
to aluminum alloys. It is dewable to resf a source of
mulasses prior to handling in aluminum equipment.
Aluminum alloys hale been used for fermenting vats.
piping. containerc dnd tanks with molasses. See also
Ref: (1) p. 137. (2) p. 474. (6) p. 10. (7) p. 127.
MOLYBDENUM
DISULFIDE.
MO&. In laboratory tests. molybdenum diwlfide accelerated corxrlon of aluminum alloys in the presence of a conductive electrol~?e. See also Ref: (3) p. 82.

NH>CH>CH,OH (2 AMINOETHANOL).
In labow
rory tests. solutions of monoethanolamine
have rc
acted with aluminum alloys in much the same manner as ammonium hydroxide solutions. Solutions
containing up to 50% monoethanolamine
have an
initial rapid reaction, but the aluminum develops a
protective film that inhibits funher action. Medium
strength solutions (- 15%) cause more corrosion
while a film is forming than do either more dilute or
more concentrated solutions. In greater than SO%
solutions, initial cormsion is slight. The effects can
be accelerated by elevated temperature.
The presence of carbon dioxide or hydrogen sulfide in monoethanolamine solutions retards corrosion of aluminum alloys. Hence, aluminum alloy equipment has
been used in natural gas processing plants employing
monoethanolamine as an acid gas removal agent. See
also Ref: (3) p. 145. (7) p. 127.
MORTAR. In laboratory tests. conventional
mortars react with aluminum alloys in the same manner
as cement and concrete. While the mortar is liquid,
etching of aluminum alloys occurs; but the reaction
stops after the mortar sets. It is good engineering
practice to protect the aluminum from crevice corro-

ASSOCIATION

(Continued)

(1)p.

temperature and was corrosive at 54C (13OF). See


also Ref: (1) p. 137, (3) p. 84.

MUSTARD. Prepared mustard has been packaged


in protected aluminum alloys. See also Ref: (1) p.
137. (3) p. 211. (6) p. 12.

NICOTINE SULFATE.
(C,oH,,N?j2. HISO+
In laboratory tests. alloy 3003 was resistant to a 40%
solution of nicotine sulfate at 204C (400F). See
also Ref: (I) p. 137. (3) p. 149.

sion where contacting the mortar. See also Ref:


137. (2) p. 161, (3) p. 72.

MUSTARD OIL. (Constituents:


alkyl isothiocyanafe; carbon disulfide: alkyl cyanide). Mustard oil
has been handled in aluminum alloy columns and
condensers.

N
NAPHTHA. Limited laboratory tests indicated that
alloys 1100, 3003, 5052 and 6061 were resistant to
naphtha at ambient temperature. Naphtha has been
handled in aluminum alloy stills, fractionators.
dephlegmators,
heat exchangers,
condensers,
and
tanks. See also Ref: (7) pp. 128, 129.
NAPHTHAIJZNE.
C,,,&. Aluminum
alloy stills,
dephlegmators, fractionators, heat exchangers, and
condenseen have been used at temperatures
above
15oC (302F) in the production of naphthalene. Naphthalene has been stored in aluminum alloy tanks.
See also Ref: (3) p. 105, (7) p. 129.
NAPHTHEMC ACID. C;H,zOz. [n laboratory tests,
alloy 3003 was resistant to commercial naphthenic
acid at ambient temperature and 82C (18OF). Boiling naphthenic acid was very corrosive to 3003 alloy
in the same test. Naphthenic acid has been transported in aluminum alloy tank cars. Aluminum alloy
fractionating
columns, condensers,
receivers and
piping have been used in the production and handling of naphthenic acid. See also Ref: (1) p. 137. (7) p.
129.
NATURAL GAS. About 855 methane, 9% ethane.
3% propane, 2% nitrogen, 1% butane, occasionally
helium or more nitrogen plus other contaminanfs.
Natural gas has been handled in aluminum alloy
equipment including processing equipment, disrillalion apparatus and pipe lines. Alloy .A3_%,.0valves
have been used for handling natural gas. Large tanks
on ships have also been used to transport liquid natural gas. See also Ref: (I) p. 137. (3) p. 214,
NAVAL STORES. These include turpentine. rosin,
copal. pentene. dipentene and pinene. In laboratory
tests, alloy 3003 was resistant to products such as
these. Naval stores have been processed and handled
in aluminum alloy equipment including rosin kettles, evaporators, condensers. storage tanks, transfer
lines, distillation equipment,
piping and shipping
containers. See also Ref: (3) p. 226.
NEOPRENE. (CH,CCI:CHCH,)..
In laboratory
tests. various aluminum alloys were resistant to pure
neoprene. However, the amount and type of filler
materials were found to affect corrosion. See also
Ref: (3) pp. 104. 110. 228.
NICKEL COMPOUNDS.
In laboratory tests, aqueous solutions of nickel salts at ambient temperature
caused varying degrees (from less than I mpy to more
than 60 mpy) of attack of 1100 alloy depending upon
the concentration and the specific compound. Most
solutions of nickel compounds are inherently corrosive to aluminum alloys. In laboratory tests conducted under conditions of 100% relative humidity at
ambient and 54C (130F) temperatures, solid nickel
chloride was very corrosive to alloys 3003, 5154 and
6061 at both temperatures,
solid nickelous acetate
caused mild attack of these alloys at ambient temperature and was corrosive (- 40 mpy) at 54C (130F).
Solid nickelous nitrate caused mild attack at ambient

NITRIC ACID. HNO,. In laboratory tests. the action of nitric acid on aluminum alloys varies with
concentration and temperature
and is increased by agitation or the presence of nitrogen oxide. At ambient temperature.
the rate of attack of
I100 alloy
shows a maximum at 20%
concentration. Above 82%. the attack is between 0
and 5 mpy. Aluminum alloys have been widely ued
for storing and shipping fuming nitric acids. Red
fuming nitric acid Inhibited with hydrofluoric acid is
compatibile with all aluminum alloys to at least 71C
(160F). Solutions of the lower oxldes of nitrogen and
the gases themselves have mild corrosion effects on
aluminum alloys. As a rerulf. aluminum alloys have
been used for the catal}tlc oxidation of ammonia in
the production of nitric acid. Aluminum alloy equipmrnt used in this prwe\s has included piping for
wpplying ammonia dnd {oxygen to the oxidizing reactor. shwlumd yas mirrerc. refrigeration tanks for
srorirq raw matuuls.
principal parts of the autoCIZW.
refining columns,
intermediate
reservoin,
heat exchangers for cooling the nitric acid before
storage, tanks and drums for storage and transportationof rheconcentrated
acid. Seealso Ref: (1) p. 138.
(2) p. 480, (3) pp. 22, 45. 244, (4) pp. 19, 20, 21. 29,
30. 31. 34. 74. %, (7) p. 130.
NITRIC SULFURIC ACIDS. (MIXED ACID:
NITRATING
ACID). In laboratory tests. mixed
acids had varying corrosive effects on aluminum
alloys which were dependent upon the composition
of the mired acids. Mixed acid containing 85%
HNO,. 12% H2S0,. and 3% water caused mild attack ( - 2 mpy) of I IO0 alloy while an 80. IS. 5 mixture caused moderate attack (- 10 mpy) of alloy
IloO. Mixtures containing 60% HNO,. 38% H+O,.
and 2% H:O were corrosive while those containing
45% or less HNO, were very corrosive. Hydrofluoric
acid has been used as an inhibitor for the less cormsive mixed acids. Aluminum alloy tanks have been
used to handle mixed acids. See also Ref: (2) p. 466,
(7) p. 127.
NITROBENZENE.
C,Hs NO>. In laboratory tests,
alloys 3003, SO52 and 6061 were resistant to nitrobenzene at temperatures ranging from ambient to the
boiling point. See also Ref: (I) p. 138, (2) p. 488, (3)
p. 141, (7) p. 131.
2 NlTRO-I-BUTANOL.
CH,CH2CHNOlCH,OH.
Aluminum alloy equipment has been used to handle
2.nitro-I-butanol.
NITROCELLULOSE.
C,2H,eN,O,&EE
ALSO
CELLULOSE NITRATES). Nitrocellulose has been
produced and washed in aluminum alloy equipment.
Nitrocellulose lacquers and enamels have been used
on aluminum alloys. See also Ref: (1) p. 138. (2) p.
490, (3) pp. 124. U2. (4) pp. 95. 140. 141.
NITROETHANE.
tests, alloy 3003 was
(237F) and 204C
stored in aluminum
141.

CH, CH]. NO*. In laboratory


resistant to nitmethane at 114C
(400F). Nitmethane has been
alloy tanks. See also Ref: (3) p.

2-NITRO-2 ETHYL-I, 3 PROPANEDIOL.


CH,~OHC(C,H:,)NOJH,OH.
Aluminum
alloy
equipment has been used to handle 2-nitro-2 ethyl-l.
3 propanediol.
NITROGEN.

N. Liquid

nitrogen

has been

pro-

(Continued)

Nonferrous Metals and Alloys


TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

cessed and handled m aluminum alloy eqwpment.


See also Ref: (II p. 138. (3) pp. 43. 214.
NITROGEN TETROXLDE.
YIO,. Nitrogen tetroride is handled in aluminum .~lluy missile fuel tanks
under stringent moisture controlled conditions. See
also Ref: (7) pp. 132. 133: Titan I1 Storable Propellant Handbook-Bell
Aerospace Company. Buffalo,
New York. Repon No. 811 l-933003.
MTROGLYCERN.
CIH;(ONOz),.
Nitroglycerin
hJs been handled ,n aluminum alloy containerr. pipe
lines. Jnd tanks. See aiw Ref. (I 1 p. 138. (2) p. 497.
(3) pp. 115. 112. (7) p. 133.
NITRO~ETH.&~uYE. CH,NO!.
Nitromethane
has
bwn stored in ,&mmum ~110) tanks. See r1l$o Ref:
() pp. 132. 133.
MTROPm&FFLYS.
Organic compounds derived
from paraffin h!drwarbons
by replacement of one or
more h!droyen atoms b) rl nitro (NO?) group. Controlled field renice reqts bhoued that nitroparsffins
cduwd mdd atrack (If V03 a1lo.y. ,Nirroparalfins have
been rtured I dlumlnum .dlo? tanks.
MTROPHENOL.
NO&H,OH.
Alloy 3003 was r-esistant to solid p-nitmphenol in laboratory tests conducted under condirions of 100% relative humidity
at ambient temperature. See also Ref: (1) p. 138. (2)
p. 499, (3) p. 141. (7) p. 133.
NITRO PROPANES (I- AND 2-j.
CH,CHJHJN02.
(CH3),CHNOl.
In laboratory
tests, alloy 3003 was resistant to nitm propanes
under refluxing conditions and suffered mild attack
under boiling and condensing conditions. Nitm pmpanes have been handled in aluminum alloy equip
mew. See alw Ref: (7) pp. 132, 133.
NITRO TOLUENES
(0, m, p). NO&H,CH,.
In
laboratory tests, alloy 3003 was resistant to +nitm
toluene at boiling and refluning conditions. Aluminum alloy equipment has been used to handle nitm
toluenes. See also Ref: (2) p. 505, (3) p. 141. (7) p.
133.
NITROUS OXIDE. NzO. Aluminum alloy retorts
have been used in the manufacturing
of nitrous oxide. See also Ref: (1) p. 138, (3) p. 47, (7) p. 135.

ASSOCIATION

(continued)

was resistant to orange juice at ambient and refrigerated temperatures.


Aluminum alloy equipment has
been used for handling orange juice. Alummum alloy
squeezers for oranges have been used a.s have foil
closures for bottles of homogenized orange juice (see
Fruit and Fruit Juices). See also Ref: (I) p. 138, (6)
p. 10.

PARAFFIN.
A wax consisting of a mixture of louer
hydrocarbons
with a softening point about SOC
(122F) and having the general formula C.H,,,,.
Paraffin has been processed and stored in aluminum
alloy equipment. Block paraffin has been produced
in aluminum alloy molds. See also Ref: (1) p. 139. (3)
pp. 102.218,220.

ORES. Many ores have been handled in aluminum


alloy equipment.
e.g.. bauxite. Compocition and
physical characteristics of the ore generally govern its
suitability for use with aluminum alloys.

PARAFORMALDEHYDE.
(CH,O),.
Aluminum
allo! equipment has hew uwd ro handle paraformaldehbde. Seealso Ref: (1)~. 139. (2)~. 52. 13Jp. 119.
(71 p. 139.

ORLON. Acrylic fiber. a polymer containing at


leti
85% acrylonitrile
units (-CHzCH(CN)-).
Aluminum alloys have been used in the manufacture,
handling. storage. and shipment of orlon.
.ReymrrrdTradeMlrr

PARAL.DEHYDE.
C&O,.
Paraldehhde has been
procersed in aluminum allo! equipment and handled
in aluminum alloy drums. See also Ref: (1) p. 139. (3)
p. 120. (7) p. 139.

OxALlC ACID. HOOC.COOH.2


H>O. Solid oxa
lit arId ~a3 cormwe t - 20 mpy) to 3003 allo! in lab
oratoq tests conducted under conditions of 100%
relative humidit) at ambient temperature.
In other
laborator? tests. aqueous solutions (0.1 to 12oi) were
corrosive ( - 15 mpy) to 1100 alloy at ambient ten?perature. At 50cC (122F) and boiling temperatures.
those solutions were corrowe IO 1100 allot. Oxalic
acid has been handled in aluminum allot filter5 and
cnstallizers. because aluminum salt) do not discolor
the product. See also Ref: (1) p. 138. (2) p. 520. (3)
p. 130. (4)pp. 22. 28, 29,30. 120. 121, 122. 123, 124.
12.5. 126. 127. 128. (7) p. 137.
OXOGLUCOMC
ACID. C,H,OO.. Aluminum alloys have been uwd in the fermentation
process 01
oxoglucomc acid.
OXYGEN. O*. Aluminum
allo! equipment
ha\
been used in the manufacture and transportation of
liquid oxygen. Aluminum alloys are panicularly suitable for these apphcations since they retain mechanical properties at low temperatures.
Alloy A356.0
valves have been used for handling liquid oxygen. See
also Ref: (I) p. 138. (3) p. 38. (4) pp. 2. 117; Corrosion Effects of Liquid Fluorine and Liquid Oxygen
on Materials of Construction,
CORROSION,
17.
No. 2. 80-82 (1961 February).
OZONE. O1. Aluminum alloys have been used tn the
construction of oronizers. See also Ref: (I) p. 139, (2)
p. 524. (3) p. 38, (7) p. 137.

NYLON. [CO(CH3,CONH(CHJ~NH]..
Aluminum
alloys have been used for tanks. piping, bins. railroad cam and tank cars for handling nylon. See also
Ref: (3) p. 127.

PAINTS. In laboratory
tests, most paints were
found to be protective to all aluminum alloys. Exceptions were those containing mercury, lead or copper
compound pigments. These were corrosive. Aluminum alloy equipment has been used for process and
storage tanks, pipe. heat exchanger tube. condensers. and reaction vessels in the paint industry. See
also Ref: (1) p. 139, (3) p. 237, (4) pp. 95. 117, 119.
134. 137, 140.

OINTMENTS.
Aluminum
the packaging of ointments.

alloys have been used for


See also Ref: (10) p. 100.

OLEIC ACID. CH,KH,)CH:CH(CH1)~.COOH.


In laboratory tests, alloys 1100, 3003 and 6061 were
resistant to oleic acid at ambient temperature. Oleic
acid has been shipped in aluminum alloy tank cars.
See also Ref: (1) p. 138. (2) p. 510. (3) p. 129, (4)
p. 25. (7) p. 137.
OLIVE OIL. Mixed glycerides of oleic. palmitic,
linoleic. stearic and arachidic acids; squalene phytosteml. tocopherols. Olive oil has been processed and
handled in aluminum alloy equipment. See also Ref:
(I) p. 138. (2) p. 872. (3) pp. 129. 206. (6) p. Il.
OMON JUICE. In limited laboratory tests. alloys
1100. 3003 and 5052 were resistant to onion juice at
ambient temperature. See also Ref: (1) p. 138.
ORANGE

JUICE.

In laboratory

tests,

alloy 3003

623

PEANUT OIL. Aluminum


been used to handle peanut
p. 872.

alloy equipment
has
oil. See also Ref: (2)

PEMCtLLLI. CH(COOH).C(CH,),S.CH:
N.CO.CH.NHCOR.
Where R i, a side chain of
varying identity. Penicillin has been produced in
aluminum alloy equipment
and packaged in vials
with aluminum caps. See also Ref: (2) p. 529, (3)
p. 146.
PENTACHLOROETHANE.
CCli.CHC12. Limited
laboratory tests indtcated that alloys 3003. 5052 and
6061 were resistant to pentachlorwthane
at ambient
temperature
and at 50C (122F). At the boiling
temperature.
pentachloroethane
was vet corrosive
to all alloys. CAUTION:
See Halogenated Hydracarbons. See also Ref: (2) p. 530. (3) p. 109. (7)
p. 139.
PENTACHLOROPHENOL.
Q&OH.
Wood treated with pentachlorophenol
or its sodium
salt has been used in contact with aluminum alloy
products. CAUTION: See Halogen&d
Hydmcarbon
See also Ref: (3) pp. 133, 242. (7) p. 139.
PENTAERYTHRITOL.
CrH,20+ Aluminum alloy
filters have been used in the production of pentaerythritol. See also Ref: (3) p. 115. (7) p. 139.
PENTAERYTHRITYL
C5H eN40 1. Aluminum
used forpentaery?hrityl
pp. 115. 138. 142.

TETRANITRATE.
alloy containers have been
tetranitrate. See also Ref: (3)

PENTANE. CH,.(CH&.CH,.
In laboratory tests,
3003 alloy was resistant to pentane under reflurjng
conditions. See also Ref: (3) pp. 103, 214, (7) p. 139.
PEPPERMINT
OIL. Aluminum
alloy equipment
has been used for stills. piping. drums, tanks. and
condensers for handling peppermint oil.
PERACETIC ACID. CHJO~O~OH.
Peracetic acid
has been shipped in aluminum alloy drums. See also
Ref: (3) p. 126.

PALMlTIC
ACID. CH,.(CH,),,.COOH.
Palmitic
acid has been shipped in aluminum alloy containers.
See also Ref: (1) p. 139. (2) p. 274, (3) p. 127, (7)
p. 139.

PERCHLORK
ACID. HCIO,. In laboratory tests.
perchloric acid was very corrosive to aluminum alloys. See also Ref. (11 p. 139. (2) p. 533. (3) p. 37. (7)
p. 139.

PALM OIL. Containing palmitin, stearin. linolein.


Palm oil has been handled in aluminum alloy equipment. See also Ref: (2) p. 872.

PERCHLOROETHYLENE.
See TETRACHLOROETHYLENE. See also Ref: (7) p. 139.

PAPER. Mainly cellulose;


clay, starch.
fillers.
Laboratory tests indicated that the corrosive effects
of paper on aluminum alloys vary with composition of
the papers. Paper when wet can cause corrosion of
aluminum alloys by poultice action. Papers with controlled composition have been used to interleave aluminum alloy products. See also Ref: (10) p. 106.

PETROLEUM
OR CRUDE OIL. A mixture of hydrocarbons obtained from an oil well. Usually an oil
well also produces salt water brine. In general, these
brines are corrosive to merals. Some brines are corrosive to aluminum alloys while others can be handled
in aluminum alloy equipment. Tests are necessary

(continued)

624

Corrosion

TABLE 5.2:

Resistant

ALUMINUM

Materials

Handbook

ALLOYS-ALUMINUM

with the product of a specific oil field before using


aluminum alloy equipment to handle oil field brines.
The crude oil may also contain appreciable amounts
of sulfur compounds in which case it is designated as
sour. Sour crudes are more corrosive to metal than
are sweet crudes. Aluminum alloys have found increased use in the petroleum industry as a result of
their superior corrosion resistance compared to steel.
They have been used for pipe lines, distillation columns, heat exchangers, storage tanks, piping and
valves. A corrosion hazard to aluminum allovs is iron
sulfide scale that may be deposited on ah&nun
alloy equipment
from sour products previously in contact with steel equipment. See also Ref: (I) p. 139, (3)
pp. 102, 214. 216.
PETROLEUM
JELLY. Purified mixture of semisolid hydrocarbons. chiefly alkanes. Laboratory tests
showed that many petroleum jellies are protective to
aluminum alloys.
PHENETHYL
ALCOHOL. C,H&H,CH,OH.
In
limited laboratory tests, 1100 alloy was resistant to
phenethyl alcohol at the boiling point - 204C
(399F). See also Ref: (3) p. 114.
PHENOL.
C,H,.OH.
In laboratory
tests, alloy
3003 was resistant to anhydrous phenol at temperatures up to 50C (122F). Above that temperature,
phenol was very corrosive to aluminum
alloys.
Aqueous solutions of phenol caused mild attack ( - 5
mpy) of 1100 alloy at temperatures from ambient to
50C (122F). Aluminum alloy tubes and A3.56.0
valves have been used to handle phenol. Solid phenol
has been handled in aluminum alloy drums. See also
Ref: (1) p. 139. (2) p. 537, (3) p. 116, (7) p. 141.
PHENYL ETHER. CbHrOCIH%. In laboratory tests,
alloy 3003 was resistant to phenyl ether at refluxing
conditions and at 204C (400F). Phenyl ether has
been handled in aluminum alloy heat exchangers and
stored and shipped in aluminum alloy containers.
See also Ref: (2) p. 263, (3) p. 135.
PHOSPHATE ROCK. Aluminum allo! equipment
and hopper cars have been used for handling phosphate rock.
PHOSPHORIC
ACID. H;PO+ In laborator?_ tests,
aqueous solutions of phosphoric acid (S-85%) were
corrosive to 1100 allo! and the corrosion increased
with concentration at ambient temperature. The rate
of attack was - 100 mpy at 570 and - 1200 mpy at
85% concentration.
The action of phosphoric acid
can be reduced by the addition of inhibitors. Aqueous solutions containing phosphoric acid and chromium trioxide have been used as cleaning solutions and
as surface preparation
for painting of aluminum
alloys. See also Ref: (1) p. 139, (2) p. 566, (3) p. 132.
(4) pp. 21. 29, 30. 74. 86. 138, 139, (7) p. 143.
PHOSPHOR SUSPENSIONS.
Suspension of substances which will fluoresce under ultraviolet light.
Phosphor suspensions used in manufacturing
fluorescent lights are handled in aluminum alloy containers.
PHOSPHORUS.
P. In limited laboratory tests, alloy 1100 was resistant to solid and liquid white phosphorus at ambient temperature. Water cooled aluminum alloy pans have been used to handle molten
phosphorus. See also Ref: (1) p. 139, (3) p. 48.
PHOSPHORUS PENTASULFIDE.
P+s. Dry phos-,
phones pentasulfide has been handled in aluminim
alloy tote bins.
PHOSPHORUS
SESQUISULFIDE.
P,S,. Aluminum alloy equipment has been used in the manufac-

ture of phosphorus
p. 48.

ASSOCIATION
sesquisulfide.

(continued)

See also Ref: (3)

PHTHALIC ANHYDRIDE.
C,HI(CO):O.
Alumi.
num alloy condensers have been used in the produc.
tion of phthalic anhydride. Molten phthalic anhydride has been stored in the aluminum alloy tanks.
See also Ref: (1) p. 139, (2) p. 573, (3) p. 132. (7)
p. 143.
PICKLES. In laboratory tests. pickles were COTrosive to aluminum alloys. Sodium chloride and vinegar contribute to this cunosion. See also Ref: (1) p.
139, (4) pp. 78.92, (6) p. 11.
PICOLINES.
CsHINCH,.
In limited laboratory
tests, mixed picolines (alpha, beta. gamma) were carrosive to 3003 alloy at 66C (150F). Picolines have
been handled in aluminum alloy containers. See also
Ref: (3) p. 149.
PINEAPPLE NICE.
In laboratory tests, 1100 allo)
was resIstant to pineapple juice at ambient temperature. In another laboratory test. pineapple juice was
corrosive to 3003 alloy at 1oOC (212F). See also
Ref: (6) p. IO.
PINENE. C,,,H,,. Aluminum
alloy equipment
including stills, condensers, filters and tanks has been
used with pinene. See also Ref: (3) pp. 104. 226.
PiperaPIPERAZINE.
NHCH*CH>NHCH,CH,.
zinc has been handled in aluminum alloy piping and
stored in aluminum alloy tanks.
PLASTER. (CaSO&
H*O. In laboratov
tests,
plaster caused an initial reaction of contacting aluminum alloys while the plaster was liquid after which
comosion did not continue. Aluminum alloys have
been used for nails. corner strips. and expanded metal lath with plaster. See also Ref: (1) p. 139, (2) p.
161. (3) p. 228.
PLASTICIZERS.
(Non-volatile
organic liquids or
low melting solids, now especially phthalate,
adipate, and sebacate esters and aryl phosphate esters).
Plasticizers have been shipped in aluminum alloy
containers.
PLUMS. In limited laboratory tests, blue plum
pomace was corrosive to alloy 3003 at 38C (lOOoF)
while red plum pomace caused mild attack (- 5 mpy).
Coated aluminum alloys have been used for canning
plums. See also Ref: (6) p. 10.
POLYETHYLENE.
(CH,CH,)..
Polyethylene
has
been handled in aluminum
allo: equipment
including weighing bins, blending bms. storage bins.
and conveyor systems. Polyethylene has also been
used as a covering on aluminum electrical conductor
and in laminations with aluminum foil. See also Ref:
(3) p. 237, (7) p. 145.
POLYPROPYLENE.
(C,H,)..
Aluminum
allo)
silos. driers. and conveyor systems have been used to
handle polypropylene. See also Ref: (3) p. 237. (7)
p. 145.
POLYSTYRENE.
(C,H,CHCH,),.
In limited laboratory tests, alloys 3003 and 5154 were resistant to
solid polystryrene under conditions of 100% relative
humidity at ambient temperature.
Aluminum alloy
bins, hopper trucks, tanks, pipe lines and conveyors
have been used in handling polystyrene. See also Ref:
(3) p. 104. (7) p. 147.
POLYVINYL
ACETATE.
(CH+ZOCOCH,)..
In
limited laboratory tests, 3003 alloy was resistant to
polyvinyl acetate emulsions. Pol.yvinyl acetate has
been prepared in aluminum alloy equipment including condensers and piping.

POLYVIXYL
ALCOHOL. (-CH,CHOH-)..
A
colorless plastic made bb the acidic or basic hydrolysis of a polyvinyl ester. usually the acetates. Polyvinyl
alcohol ha2, been handled in aluminum alloy containers.
POLYVIXYL BUTYRAL RESINS. Synthetic resins. Aluminum alloy containers have been used in
handling polyvinyl butyral resins. See also Ref: (8)
pp. 19. 199.
POTASH ORE. Aluminum
alloy equipment
has
been used in handling and transporting potash ore. It
has also been used in many mine and mill building
applications. See also Ref: (9) p. 34.
POTASSIUM BITARTRATE.
KHC,&Ob. In limited laboratory tests, dilute aqueous solutions of po.
tassium bitartrate caused varied degrees of comxion
of 3003 alloy at ambient temperature.
0.25% solutions caused moderate attack (- 7 mpy) while 1.8%
solutions were corrosive. See also Ref: (3) p. 71.
POTASSIUM
BROMIDE.
KBr. Limited laboratory tests indicated that potassium bromide solutions
at ambient temperature have action on aluminum alloys similar to that of sodium chloride. See also Ref:
(1) p. 140. (2) p. 585. (3) p. 63, (7) p. 147.
POTASSIUM CHLORATE.
KCIOj. Aluminum alloy dtying pans have been used in the commercial
production of potassium chlorate. See also Ref: (1)
p. 140, (2) p. 592. (7) p. 14i.
POTASSIUM CHWRIDE.
KCI. Alloys 3003 and
5154 were resistant to solid potassium chloride in laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature. Granular
potassium chloride has been handled in aluminum
alloy hopper cars. See also Ref: (1) p. 140, (3) pp. 62,
63,214. (7) p. 147.
POTASSIUM
CHROMATE.
K@3,.
In laboratory tests, 3003 alloy was resistant to aqueous solutions (l-36%) of potassium chromate at ambient
temperature. Potassium chromate has been used as
an inhibitor in natural waters and chloride containing solutions carried in aluminum alloy piping and
equipment. See also Ref: (1) p. 140, (3) p. 70, (7)
p. 147.
POTASSIUhI CYANATE. KCNO. Potassium cyanate has been prepared in aluminum alloy reactors.
See also Ref: (3) p. 68, (7) p. 149.
POTASSIUM
DICHROMATE.
K,Cr,O-. Potassium dichromate has been a u&accepted
inhibitor
for use with aluminum alloys in natural and salt waten. It has been used to inhibit the corrosion of aluminum alloy piping and equipment exposed to such
waters. See also Ref: (1) p. 140. (2) p. 598, (3) p. 70.
(7) p. 149.
POTASSIUhI HYDROXIDE.
KOH. In laboratory
tests, potassium hydroxide was very corrosive to all
aluminum alloys. See also Ref: (1) p. 140, (2) p. 606,
(3) p. 61. (4) pp. 34, 35, 36, (7) p. 149.
POTASSIUM
IODIDE.
KI. Limited laboratory
tests indicated that potassium iodide solutions at ambient temperature have action on aluminum alloys
similar to that of sodium chloride. See also Ref: (1)
p. 140, (3) p. 63. (7) p. 149.
POTASSIUM
NITRATE.
KNO,. AIloys 3003 and
5154 were resistant to solid potassium nitrate in Iaboratory tests conducted at 100% relative humidity at
ambient temperature.
In similar tests conducted at
54C (130F). solid potassium nitrate was very con
sive to alloys 3003 and 5154. Aluminum alloy equip-

(continued)

Nonferrous Metals and Alloys


TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

ment has been used for producing and handling potassium nitrate. See also Ref: (1) p. 140, (2) p. 613.
(3) p. 66. (7) p. 151.
POTASSIUM PERMANGANATR.
KMnO,. Solid
potassium permanganate was corrosive to 3003 alloy
in laboratory tests under conditions of 100% relative
humidity at ambient temperature.
See also Ref: (I)
p. 141, (2) p. 617. (3) p. 70, (4) pp. 74, 75,17) p. 151.
POTASSIUM PERSULFATE.
K2S106. Aluminum
alloy equipment has been used for processing and
shipping potassium persulfate. See also Ref: (2) p.
622, (3) p. 65, (7) p. 151.
POTASSIUM
PYROSULFATE.
K1S201. Potassium pyrosulfate has been cast in aluminum alloy
molds and shipped in aluminum alloy containers to
avoid contamination.
See also Ref: (3) p. 65.
POTASSIUM SULFATE.
KZS04. Alloys 3003 and
5154 were n&ant
to solid potassium sulfate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature.
In similar
tests at 54OC (130F), potassium sulfate caused mild
attack ( - 3 mpy) of these alloys. See also Ref: (1)
p. 141, (2) p. 625, (3) p. 64, (7) p. 151.
POTASSIUM
TARTRATE.
C,H,O,K, h H,O.
Solid potassium tartrate caused moderate corrosion
of 3003 alloy (14 mpy) and was corrosive to 5154 alloy
in laboratory tests conducted under conditions of
100% relative humidity at,ambient temperature. See
also. Ref: (1) p. 141.
POTASSIUM
THIOCYANATE.
KSCN.
Alloy
3003 was resistant to solid potassium thiocyanate in
laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
In other
laboratory tests, 3003 alloy was resistant to aqueous
solutions (including saturated solutions) of potassium thiocyanate at ambient temperature.
See also
Ref: (I) p. 141, (3) p. 69, (7) p. 153.
PROPANE.
CH,CH&H,.
propane has been handled in aluminum alloy tube. See also Ref: (I) p. 111,
(3) pp. 103. 214. (i) p. 153.
PROPIONIC ACID. CH, CHI. COOH. In laboratory tests, alloy 1100 was resistant to aqueous solu(ions (0.5% to 100%) of propicnic acid at ambient
temperature. As the temperature increases, solutions
of propionic acid become aggressive. Completely
anhydrous propionic acid was very corrosive, but the
addition of a small amount of water reduced the attack significantly. Propionic acid has been handled.
stored and shipped in aluminum alloy tanks, drums
See also Ref: (1)
and tank cars.
p. 141, (2) p. 628, (3) p. 127. (4) p. 24.
PROPIONIC ALDEHYDE.
CH,CH,CHO. In lahoratory tests, 1100 alloy was resistant to aqueous solotions of propionic aldeh)de at ambient temperature.
At SOC (122F) and ICOC (ZIZOF), these solutions
caused moderate attack. Fropionic aldrhyde has been
produced in aluminum alloy equipment and has been
stored and shipped in aluminum alloy containers.
See also Rel: (3) p. 120. (7) p. 153.
PROPIONIC
ANHYDRIDE.
(CH,CHICO)zO.
In
laboratory tests, 1100 alloy was resistant to propionic anhydride at ambient temperature and at 50C
(122F). At the boiling point, propionic anhydride
was very corrosive. Propionic anhydride has been
handled in aluminum alloy storage tanks, drums and
See also Ref: (3) p. 128.
tank cars.
PROPYL ACETATE. CH3COOC,H7. In laboratory
tests. 3003 alloy was resistant to propyl acetate at the
boilinn temoerature.
Condensing vapors of propyl

ASSOCIATION

(continued)

acetate caused mild attack of 3003 alloy in the same


tests. See also Ref: (7) p. 153.
n-PROPYL ALCOHOL.
CH,. CH2. CH? OH. In
laboratory tests, n-propyl alcohol caused mild attack
( - 3 mpy) of 3003 alloy under boiling and condensing
conditions. See also Ref: (1) p. 141, (3) p. 113, (7)
p. 153.
PROPYLENE
GLYCOL. CH,C HOH CH*OH.
propylene glycol has been handled in aluminum alloy
stills, evaporators, and heat exchangers. See also
Ref: (31 p. 114.
PYRIDINB.
N: CHCH: CHCH: CH. In laboratory
tests, 1100 and 3003 alloys were resistant to pyridine
at ambient temperature. Aqueous solutions (1% and
5%) caused mild attack ( -5 mpy) of 3003 alloy at
ambient temperature.
Aluminum alloy condensers
and dephlegmators have been used with pyridine.
See also Ref: (1) p. 141, (2) p. 633, (3) p. 149, (4)
p. 73, (7) p. 155.

Q
QUEBRACHO
EXTRACT. Contains quebracho
alkaloids and tannen. In limited laboratory tests,
quebracho extract caused mild attack (- 4 mpy) of
3003 alloy at 204C (400F).
QUINOLINE.
C9H:N. Quinoline has been handled
in aluminum alloy containers. See also Ref: (1) p.
141. (2) p. 640, (3) p. 149, (7) p. 157.

num alloy pipe and $hipped in aluminum alloy tank


cars. Aluminum allo! equipment has been used in
the manufacture of paints and varnishes containing
rosin. See also Ref: (1) p. 141, (2) p. 866, (7) p. 159.
RUBBER. Mostly obtained from the coagulated
milky juice of Hevea 6rusiIknsti. Aluminum alloys
have been used on rubber plantations for cups, latex vats, pans, buckets. coagulating
tanks, and
drums. Aluminum alloy molds have been used for
the production of rubber articles and for vulcanizing. See also Ref: (1) p. 141, (3) pp. 103, 227.
RUM. In laboratory tests, rum was corrosive to
aluminum alloys usually in the form of localized pitting. See also Ref: (1) p. 141.

S
SALICYLALDEHYDE.
HOC&CHO.
In laboratory tests, aluminum alloys caused discoloration of
salicylaldehyde. Alloy 5052 caused less discoloration
than other alloys. See also Ref: (3) p. 121.
SALICYLIC ACID. HOC,H,COOH.
Alloys 3003
and 5154 were resistant to solid salicylic acid in
laboratoq
tests conducted
under conditions
of
100% relative humidity at ambient temperature.
Salicyclic acid has been handled in aluminum alloy
distillation columns. condensen,
pumps and piping. The sublimed acid has been condensed
in
aluminum-lined
chambers. In the preparation
of
aspirin. salicylic acid has been reacted with acetic
anhydride in aluminum alloy kettles. See also Ref:
(1) p. 142, (2) p. 644, (3) p. 130. (7) p. 161.
SARDINES. Coated aluminum
alloy cans have
been used to package sardines. See also Ref: (3) p.
208, (4) pp. 106, 108, 109, (6) p. 12.

RASPBERRY JUICE. In laboratory tests, alloys


1100, 3003, and alclad 6053 were resistant to black
raspberry juice at refrigerated
temperatures.
In
other laboratory tests, black and red raspberry
juices caused moderate attack of 3003 alloy at
100C (212F). See also Ref: (I) p. 141, (4) pp. 88,
89 (6) p. IO.
RAYON INDUSTRY.
Aluminum alloys have been
used in the rayon industry for spinning buckets and
bobbins, piping for viscose and wash water, filter
presses and guide holders, desulfurization
machines, ventilating and heater ducts, and blower
equipment. See also Ref: (1) p. 141. (3) pp. 124,
232.
RESORCNOL
FORMALDEHYDE.
C-H,O,. Resorcinol formaldehyde has been handled in aluminum alloy bulk containers.
RHUBARB.
In laboratory tests. rhubarb pomace
and rhubarb juice were corrosive to alloy 3003 at
100C (212F). See also Ref: (4) p. 80, (6) p. 11.
RICE. Aluminum alloy equipment has been used
to ptocess various rice products. See also Ref: (I)
p. 141.
RICNOLEIC
ACID.
CH~.(CH>)s.CHOH.CHICH:CH.(CHz),.COOH.
In limited laboratory tests, 3003 alloy was resistant
to ricinoleic acid at ambient temperature.
Ricinoleic acid has been processed in aluminum alloy distillation equipment, condensers and piping. It has
been stored in aluminum alloy tanks. See also Ref:
(2) p. 274, (3) p. 129.

SAUERKRAUT.
In limited laboratory tests, sauerkraut caused localized pitting of 3003 alloy. See also
Ref: (1) p. 142. (3) p. 209, (4) pp. 78, 80, 92, (6)
p. 11.
SEAWATER.
Many aluminum
alloys have been
shown to resist seawater in both laboratory controlled field tests and in service. These include
aluminum-magnesium
alloys 5052, 5154, 5083,
5086, and 5456 and aluminum-magnesium-silicon
alloys 6061 and 6063. The high strength aluminum
alloys 2219, 2024, and 7075 require protective
measures when used in seawater.
In Januac. 1936, an aluminum hull section of a
high speed boat was placed in the James Ri\er Estuary
of the Chesepeake Bay. The hull was fabricated of
5052.H32 plate. the framing of 6053 extrusions and
the assembly rivets of 6053.T4l. The outside of the
hull below the water line was painted except for a
small area that was left bare to ohsewe the effect of
the seawater on the hull plate. When inspected 42
years later, even the unpainted area had resisted
corrosion. The Alcoa Seaprobe was 244 feet long with
hull of 5456 aluminum painted with a coal tar epoxy.
When the vessel was decommissioned after 10 years
of service, examination disclosed the hull plates to
have resisted the effects of seawater. Aluminum
alloys have been used forrowboats, canoes, and other
pleasure craft; outboard motors; as well as naval and
commercial vessels. When immersed in seawater,
aluminum alloys, as most other metals, are protected
from marine fouling by organic coatings. These antifouling coatings should not contain mercury or cop
per compounds. See also Ref: (3) pp. 32, 62, (4) pp.
42.55356, 57.50, 59.
SEWAGE.

ROSIN.

625

Molten rosin has been carried

in alumi-

Aluminum

alloys have generally

per-

(continued)

626

Corrosion

TABLE 5.2:

Resistant

ALUMINUM

Materials

Handbook

ALLOYS-ALUMINUM

formed well when used with domestic and industrial


sewage and the decomposition
products
of the
sludges. including hydrogen sulfide. methane, carbon dioxide, and nitrogen. Aluminum alloys have
been used for filters. gratings. thickeners,
valves.
pipes, and sludge handling equipment in sewage disposal plants. See alw, Ref: (1) p. 142, (3) p. 243.
SHAVING CREAM. Many shaving creams have
been packaged in mllapsible aluminum alloy tubes.
See also Ref: (I) p. 142.
SHELLAC. A resinous excretion of the insect LncC+ &co. In laboratory tests. 3003 alloy was resistam to shellac at ambient temperature.
Aluminum
alloy storage tanks have been used for shellac. See
also Ref: (3) p. 226.
SHOE POLISH. Typically a mixture of hard waxes
(camauba.
etc.), paraffin,
ceresin of ozokerite,
solvents (naphtha and turpentine.
etc.) and dye.
Aluminum alloy containers have been used for shoe
polish. See also Ref: (9) p. 62.
SILVER COMPOUNDS.
In laboratoq
tests, solutions of silver compounds
were corrosive to all
aluminum alloys causing localized pitting atiack. See
also Ref: (1) p. 142, (3) p. 73.
SOAP. Salt of fatty acids. In laboratory tests, the action of soaps on aluminum alloys is variable. Many
soaps cause less than 1 mpy attack while others,
usually those more alkaline, are corrosive. Aluminum allo? screw conveyon. compactors. packaging equipment. and tote bins have been used in the
production of soap. Bar soap has been wrapped in
aluminum foil laminates. See also Ref: (1) p. 142.
(2) p 647. (3) pp. 117. 2.39. 245 (71 p. 160.
SODA ASH. See SODIUM CARBONATE.
SODA WATER. In limited laboratory tests. 3003
alloy was resistant to soda water at ambient temperature. When tap u ater is used. the amount of carroslon is dependent
upon the composition of the
water used. See also Ref: (9) p. 65. (10) pp. 46, 93.
SODIUM. Na. Sodium has been heated on aluminum allo) trays in the production of sodium p~ducts. See also Ref: (1) p. 142. (3) p. 58.
SODIUM
ACETATE.
CH,COONa.3H,O.
Alloy
3003 was resistant to solid sodium acetate in laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
In other
laboratory tests, 1100 alloy was resistant to aqueous
solutions of sodium acetate (0.1% to 36%) at ambient temperature.
See also Ref: (I) p. 142, (2) p.
650. (3) pp. 25, 71 (7) p. 161.
SODIUM
ALUMINATE.
NaAIOI. Solid sodium
aluminate was very corrosive to alloys 3003 and 5154
in laboratory tests conducted under conditions of
100% relative humidity at ambient temperature. See
also Ref: (3) p. 70. (7) p. 161.
SODIUM ARSENATE.
Na>HAsO,. Solid sodium
arsenate caused moderate attack (- 10 mpy) of 3003
and 5154 alloys in laboratory tests conducted under
conditions of 100% relative humidity at ambient
temperature. See also Ref: (1) p. 142, (7) p. 162.
SODIUM
ARSENITE.
NaAsO,.
Solid sodium
arsenite caused mild attack ( - 5 mpy) of alloy 3003
while 5154 alloy was resistant to solid sodium arsenite
in laboratory tests conducted under conditions of
100% relative humidity at ambient temperature.
Aluminum alloy tanks have been used to handle SDdium arsenite. See also Ref: (7) pp. 162, 163.
SODIUM BENZENESULFONATE.
C6H5S020Na. Aluminum alloy rotary driers, fume

ASSOCIATION

(continued)

hoods, and duct work have been used


manufacture of sodium benzenesulfonate.

in the

SODIUM BENZOATE. CJ+. COONa. Alloys 3003


and 5154 were resistant to solid sodium benzoate in
laboratory tests conducted under conditions of 100%
relativ: !tumidity at ambient temperature.
See also
Ref: (3) p. 71. (7) p. 163.
SODIUM
BISULFITE.
NaHSO?.
Solid sodium
bisulfite was corrosive to alloys 3003 and 5153 with
evidence of localized pitting in lahorato~ test, conducted under conditions of loOr relative humidit!
at ambient temperature.
In other laborator) tests.
aqueous solutions of sodium hisulfite t lob to 25b 1 at
ambient temperature
caused attack of alloy 3003
which increased with concentration
Solutions Of
10% or less caused mild attack ( - 2 mp) Hhile 25%~
solutions were slightly more corrosive t - 4 mpy). See
also Ref: (2) p. 657. (3) p. 64, (7) p. 163.
SODEM
CARBONATE.
Na:CO,.
Solid sodwm
carbonate
was vety corrosive to alloy 3003 in
laborator?, tests conducted under condllions of 100%
relative humidity at ambient temperarure. In other
laborarov tests, aqueous solutions of sodium carbonate (1% to 10%) were very corrosi\e to 1100 allo>
at ambient temperature. In the same tests. the action
of these aqueous solutions was eftectively inhibited
by the addition of silicates. Aluminum alloy hopper
cars have been used to transport sodium carbonate.
See also Ref: (1) p. 142. (2) p. 660. (3) pp. 23. 67. (4)
pp. 34.37.50, 76,86,%,
103.
SODIUM CHMRATE.
NaCIO,. Alloy 3003 was
resistant to solid sodium chlorate in laboratory tests
conducted under conditions of 100% relative humidityat ambient temperature. Sodiumchlorate
has been
dried in aluminum alloy equipment and shipped in
aluminum alloy tanks cars. See also Ref: (7) pp. 164.
165.
SODIUM CHLORIDE.
N&I. Alioy 3003 was resistant to solid sodium chloride in laboratoq tests conducted under conditions of 100% relative humidity
at ambient temperature.
In other laboratory tests.
aqueous solutions of sodium chloride (0.1 [POto 25%)
caused mild attack (- 2 mpy) of llo(l alloy at ambient temperature with some localized pitting. The
presence of heavy metals in these solutions accelerated attack. Sodium chloride has been the basic
ingredient in many standard accelerated corrosion
tests used in evaluating the resistance to corrosion
and stress corrosion cracking of aluminum alloys.
Aluminum alloy equipment has been used for hoppers. elevator buckets. drying towers and bins for
handling sodium chloride. Solid sodium chloride has
been shipped in aluminum
alloy railnay cars.
Sodium chloride brines have been carried
in
aluminum alloy refrigeration
systems.
See also Ref: (1) p. 143, (2) p. 665. (3) pp. 25261,
213, (7) p. 16.5.

SODIUM DICHROMATE.
Na,Cr,O-.ZH,O.
SC,dium dichromate has been wed as an mhibitur to retard corrosion of alummum alloys in chloride solutions and ethylene glycol. See also Rrf: (1) p. 143. (3,
p. 70.
SODIUM DISILICATE.
Na.Sis05. Sodium disiilcate has been used as an inhibiror of corrosion of ahminum alloys in alkaline solutions. See aJso Ref. (7,
p. 165.
SODIUM FLUORXDE. NaF. Solid sodium fluoride
was corrosive to alloy 3003 in laboratory tests conducted under conditions of 100% relative humidit!
at ambient temperature.
In other laboratory tests.
aqueous solutions of sodium fluoride (0.1% to 4%)
caused moderate attack ( - 10 mpy) of 1100 allo!
which varied ulth concentration.
See also Ref: (I) p
143. (3) p. 63, (7) p. 167.
SODIUM FLUOSILICATE.
Na,(SiF,). Alloys 3003
and 5154 were rwstant to solid sodium fluosilicate in
laboratory tests conducted under conditions of 100%
relative humidlry at ambient temperature.
See also
Ref: (2) p. 688. (3) p. 69.
SODIUM HYDROGEN SULFATE. NaHSO,. Solid
sodium hydrogen sulfate was very corrosiw fo alloys
3003 and 5154 in laborator? tests conducted under
conditions of 100% relative humidity at ambient
temperature. In other laboratory tests. aqueous sobtions of sodium hydrogen sulfate (l-25%) caused attack of 3003 alloy at ambient temperature which increased with concentration.
Alloy 3003 ~a5 reslstanr
to a I% solution. while a 2S% solution caused mild
attack (- 4 mpy). See also Ref: (1) p. 142. (2) p. 65.3.
(3) p. 64.
SODIUM
HYDROXIDE.
NaOH. In laboratop
tests, aqueous solutions of sodium hydroxide were
very corrosive to all aluminum alloys at all concentrations and temperatures.
Dilute solutions of sodium
hydroxide have been inhibited by the addition of inhibitors, including potassium dichromate.
ammonium metavanadate.
or ammonium persulfate. See
also Ref: (1) p. 143, (2) p. 693, (3) pp. 25. 60. (4) pp.
34.35. 36, 37, 49, 103. (7) p. 169.
SODIUM
HYPOCHLORITE.
N&IO.
In laboratory
tests.
aqueous
solutions
of sodium
hypochlorite cause corrosion which varies with concentration. Alloy 1100 was resistant to dilute solutions of sodium hypochlorite
at ambient temper.
atore. whereas. more concentrated
solutions HYIY
very corrosive. Silicates have been used as inhibitors
for corrosion of aluminum
alloys by sodium
hypochlorite. See also Ref: (1) p. 143, (2) p. 703. (3)
pp. 63. 247. (7) p. lb9.

somm

LACTATE.
CH, CHOHC. 00~~.
in
laboratov tests, 30% solution of sodium lactate was
coormsive to 1100 alloy at ambient temperature and at
1OOC (212F). In the same tests. 1100 alloy was reSODIUM CHROMATE.
Na,Cr0,.4
HIO. Alloys sistant to an 80% solution of sodium lactate at ambi3003 and Sl_S4 were resistant
to solid sodium ent temperature. See also Ref: (3) p. 71.
chromate in laboratory tests conducted under conditions of 100% relative humidity at ambient tem- SODIUM LAURYI. SULFATE.
perature. In other laboratory tests, 1100 alloy was CH,(CH,),,COONa
SOz. In controlled field tests.
resistant to aqueous solutions of sodium chromate
aqueous solutions of sodium lauryl sulfate were COT(up to SO%) at ambient temperature. Sodium chro- msive to alloy 3003.
mate has been used extensively as an inhibitor to
retard corrosion of aluminum alloys in many aqueous SODIUM MERCAPTOBENZQTHIAU)LE.
environments. See also Ref: (1) p. 143, (2) p. 678, (3) C,H,N:C(S). SNa. Sodium mercaptobenzothiazole
pp. 61, 62, 70, 73 (7) p. l&S.
has been used as an inhibitor to retard corrosion of
aluminum alloys in ethylene glycol sohnions. See also
SODIUM CYANIDE. N&N. In laboratory tests, Ref: (10) p. 30.
aqueous solutions of sodium cyanide at ambient
temperature caused attack of 3003 alloy which in- SODIUM NITRATE. NaNO,. Alloy 3003 was resiscreased with concentration.
At 0.1%. the sodium tant to solid sodium nitrate in laboratory tests concyanide solution caused mild attack (- 4 mpy) while ducted under conditions of 100% Hlative humidity
at 20%. it wasve~ corrosive. See also Ref: (1) p, 143,
(2) p. 682. (3) p. 68. (7) p. 165.
(continued)

Nonferrous Metals and Alloys


TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

at ambiel;t temperature.
In orher laboratow tests,
1100 allO\ was resistant to aqueous
solutionsof
sodium nitrate (0.1% to 43%) at ambienr temperature
Sodium nitrate has been used in combination uith sodium nitrite as an inhibitor to retard
the corrosion of aluminum alloys. See also Ref: (1)
p. 143. (2) p. 712. (3) p. 66, (7) p. 169.
SODIUM NITRITE.
NaNO,. Alloys 3003 and 5154
uere resistant to solid sodium nitrite in laborator)
tests under conditions of ICVb relative humidity at
ambient temperarure. See also Ref: (1) p, 143. (3) p,
66. (7) p 169.
SODIUM OXALATE. Na,CzO,. Alloys 3003 and
5154 UCK resistant to solid sodium onalate in lab.
oratov tests conducted under conditions of 100%
relative humidit! al ambient temperature.
In other
laborator) tests. 300.3 alloy was resistant to saturated
solutions of sodium oxalate at ambient remperature.
while dilute solurions of sodium oxalate (3.1%)
caused moderate attack ( - 7 mp)-) of 3003 alloy at
100C (212F). See also Ref: (I) p. 143.
SODIUM
PERBORATE.
NaBO,. 4H,O.
Alloys
3003 and 5154 were resistant to solid sodium perborate in laboratory tests conducred under conditions of 100% relative humidity at ambient temperature. In other laboram?
tests, 3003 alloy was
resistant in moist sodium perborate at ambient temperature. See also Ref: (2) p, 718. (7) p. 169.
SODlUM PERCARBONATE.
2 Na,CO,.3
H>O. Na:CO,.H?OI.l/>
H?O or
Na,C,O,. Sodium percarbonate has been prepared
in aluminum allo! reactors. See also Ref: (2) p. 720.
(3) p. 68. (7) p. 169.
SODIUM PEROXIDE.
NalOl. Solid sodium peroxide was very corrosive to alloys 3003 and 51-54 in
laboratoq tests under conditions of 100% relative
humidity at ambient temperature.
See also Rcf: (1)
p. 144. (2) p. 725. (3) p. 60. (7) p. 171.
SODILJM
PHOSPHATE,
DIBASIC. Na,HPO+
Alloys 3003 and 5154 were resistant to solid sodium
phosphate,
dibasic. in laboratory tests conducted
under conditions of 100% relative humidity at ambient temperature.
See also Ref: (1) p. 144.
SODIUM PHOSPHATE,
TIUBASIC.
Na,PO,. In
laboratory tests, aqueous solutions of sodium phosphate, tribasic, were very corrosive 10 1100 alloy at
ambient temperature.
Sodium silicate was found to
be an effective inhibitor for this compound. Cleaning
products containing this compound should be used
only with great caution on aluminum alloy products.
See also Ref: (1) p. 146, (2) p. 734, (3) p. 67. (4) pp.
34. 37, SO. 69, 75. 76. 86. 103. (7)~. 171.
SODIUM PROPIONATE. CH,CH$OONa.
Sodium propionate solutions have been handled in aluminum alloy tanks. See also Ref: (3) p. 71.
SODlUM
SILICATES.
SiO,(Na,O).
The resistance to corrosion of aluminum alloys by sodium
silicates depends on the weight ratio of SiO,/Na,O.
Commercial sodium silicates with a weight ratio of 2
have been used as inhibitors of corrosion of aluminum alloys in alkaline solutions. In laboratory
tests. sodium metasilicate with a weight ratioof 1 was
very corrosive to 1100 alloy at ambient temperature.
See also Ref: (1) p. 144. (2) p. 740, (3) p. 69, (4) pp.
37, 47, 76, 86, %. 103. 119. 12.3, 138, (7)~. 171.
SODIUM SULFATE.
Na,SO,. 10 HIO. In laboratory tests, alloy 3003 was resistant to solid sodium
sulfate under conditions of 100% relative humidity at
ambient temperature.
In other laboratory tests,
aqueous solutions of sodium sulfate (0.1 to 14%)

ASSOCIATION

627

(continued)

caused mild attack ( - 2 mpy) of 1100 alloy at am


bient temperature.
Aluminum alloy tote bins have
been used for handling sodium sulfate. See also Ref:
(l)p. 144,(2)p. 744(3)p.64,(7)p.
173.

perature. In other laboratory


stannous chloride (O.ooOl%
tack (-4 rnpy) of 1100 allo)
See also Ref: (1) p. 144. (3)

SODIUM SULFIDE.
NalS.9 H20. Solid sodium
sulfide was very corrosive to 3003 and 5154 alloys in
laboratory tests conducted under conditions of 100%
relatix humtdity at ambient temperature.
See also
Ref: (1) p. 144. (2) p. 748, (3) p. 63. (7) p. 173.

STARCH. Solid starch caused mild attack (-2


mpy) of alloy 3003, while 5154 alloy was resistant to
solid starch in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Aluminum alloy conveyors and piping have
been used in starch plants. See also Ref: (1) p. 144.
(2) pp. 123, 124, 231. (4) p. 73.

SODIUM SULFITE.
Na2S0,. 7 H>O. In laborato~
tests, 1100 alloy was resistant to aqueous solutions of
sodium sulfite (0.1 to 15%) at ambient temperature.
Alloys 3003 and 5154 were resistant to solid sodium
sulfhe in laboratory tests conducted under conditions
of 100% relative humidity at ambient temperature.
See also Ref: (I) p. 144. (2) p. 754, (3) p. 64, (7) p.
173.
SODIUM THIOCYANATE.
NaSCN. In laboratory
tests, 1100 alloy was resistant to aqueous solutions
(0.1 to 40%) of sodium thiocyanate
at ambient
temperarure. Aluminum alloy troughs. tanks. rolls,
piping and towers have been used to handle sodium
thiocyanate solutions. See also Ref: (1) p. 144, (2) p.
760. (3) p. 69, (7) p. 173.
SODIUM THIOSULFATE.
Na,S201.5 HzO.
Alloys 3003 and 5154 were resistant to solid sodium
thiosulfate in laboratory tests conducted under conditions of 100% relative humidity ar ambient temperature. In other laboratoty tests, 1100 alloy was
resistant to aqueous solutions of sodium thiosulfate
(0.5% to 40%) at ambient temperature.
Sodium
thiosulfate has been used as a deicing salt on aluminum alloy equipment. See also Ref: (1) p. 144. (2)
p. 763, (3) p. 65, (7) p. 173.
SOILS. Soils vary widely in their corrosivity towards
aluminum alloys. Soil composition,
the nature of
chemicals in the ground water, and the degree of wetness and aeration are factors in the cormsivity of soil;
but the corrosion of aluminum alloys in soil is so complex that even that information is not sufficient for
accurate prediction of performance in a given soil. It
is recommended that soil corneivity be evaluated for
each application
while still in the design stage.
Aluminum alloys buried in soi. are usually protected
by claddings, coatings, or wrappings. Cathodic protection is also used, sometimes in conjunction with
other protective measures. Alloys containing copper,
such as 2024, should not be used in soil. Aluminum
alloys have been used for oil pipe lines and culvert
pipe in soil. See also Ref: (1) p. 144.
SOBBITOL. C6Hl,0a. Sorbitol has been filtered in
aluminum alloy filter presses and transported in aluminum alloy tank cars and shipping drums. See also
Ref: (2) p. 766, (3) p. 115, (7) p. 173.
SORBOSE. C&i,*O,. Aluminum alloy equipment,
including r&dry fermenters and sterilizers, has been
used in the production of Sorbose. See also Ref: (2) p.
768. (3) p. 123, (7) p. 173.
SOYA OIL. Consists of glycerides of oleic. linoleic,
palmitic. stearic and linolenic acids. Aluminum alloy
weight tanks and kettles have been used in the pro.
duction of soya oil.
STWC
CHLORIDE.
SKI, Solid stannic chloride was very corrosive to alloys 3003 and 5154 in laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
See also
Ref: (1) p. 144, (2) p. 774, (3) p. 81. (7) p. 175.
STANNOIJS
CHLORIDE.
SKI,.2
H,O. Solid
stannous chloride was very corrosive to alloys 3003
and 5154 in laboratory tests conducted under conditions of lOLl% relative humidity at ambient tem-

tests. dilute solutions of


to 10%) caused mild arat ambient temperature.
p. 81. (7) p. 175.

STEAM. HZO. In laboratory tests under static conditions, alloy 3003 uas found to be resistant to pure
steam wer distilled water at temperatures
up to
268C (514F). In fact, aluminum alloys exposed to
steam at these temperatures had improved resistance
to corrosion by other environments because of the increased thickness of the oxide film on the surface. In
the same tests, steam at 268C (514F) was cormwe.
High prw.sure steam can erode aluminum alloys by
impingement
corrosion erosion, particularly
when
the jet of steam is perpendicular
to the surface.
Aluminum
alloy equipment
including
heat exchangers, dryers. steam jacketed kettles, piping have
been used to handle steam in the petroleum. chemical and food processing industries. See also Ref: (1)
p. 144, (2) p. 778, (4) p. 49, (7) p. 175.
STEABIC
ACID. CH,.(CH,),,.COOH.
Aluminum alloy equipment has been used for steam distillation, filtering and storing stearic acid. Alloys
3003 and 5154 were resistant to solid stearic acid
under conditions of 100% relative humidity at ambient temperature.
See also Ref: (1) p. 144, (2) p,
782, (3) p. 127, (4) p. 25. (7) p. 175.
STRAWBERRIES.
In limited
laboratory
tests,
fresh strawberries caused localized pitting of 5052
alloy. See also Ref: (4) pp. 106. 109.
STREPTOMYCIN.
C:,H,cNQl.
Aluminum allo)
media tanks. pre-seed ranks. absorption
tanks,
slurry tanks, pipe and fittings have been used in the
production of streptomycin.
See also Ref. (3) pp.
146. 239.
STROBANE*.
(Consrituents:
Terpene
polkchlorinates such as camphene, pinene and r&red compounds). In controlled field tests, 3003, 5052, and
5154 alloys were resiaant to Strobane at ambient
temperature.
Indcmrrl;
STYRENE. C,HsCH.CHz.
Aluminum
alloy heat
exchangers. bubble caps, tank trucks, conveyors.
piping, polymerization vessels and storage tanks have
been used in the styrene industry. See also Ref: (3)
pp. 104, 105. (7) p. 175.
SUCCINKACID.
HOOC.CH2.CH2
.COOH.
Alloys 3003 and 5154 were resistant to solid succinic
acid in laboratory tests conducted under conditions
of 100% relative humidity at ambient temperature.
In other laboratory tests, aqueous solutions of succinic acid (0.25% to 50%) caused attack of 1100 alloy
that increased with concentration and temperature.
At O.ZS% the attack was moderate ( - 6 mpy) while at
50% it was corrosive at 100C (212F).
See also Ref: (1) p. 145. (3) p. 130. (7) p. 175.
SUCROSE. CIZHnO,,. Alloy 3003 was resistant to
solid sucrose, while alloy 5154 showed mild attack
(- 2 mpy) in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. Aluminum alloy piping, crystallizers and storage
tank heaters have been used with sucrose. Dry sucrose
has been handled in aluminum alloy piping. See also
Ref: (1) p. 145, (2) p. 790. (3) p. 124. (6) p. 10.

(continued)

628

Corrosion Resistant Materials Handbook

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

SUGAR. C,zH,,O,,.
Aluminum
alloy equipment
for piping. tankage and transportation has been used
in the sugar industry. See also Ref: (1) p. 145 (2) p,
790. (3) pp. 123. 198,203,209, (4) pp. 73, 74,88,90,
91, 93,98, (7) p. 175.
SULXAMIC ACID. H,N .S02.0H.
In laboratory
tests, aqueous solutions of sulfamic acid (0.1% to
20%) caused attack of 1100 alloy which increased
with temperature.
At ambient temperature, the attack was moderate (- 10 mpy). while at 50C
(122F) and IOOC (212F). sulfamic acid solutions
were very corrosive. See also Ref: (I) p. 145. (3) pp.
42, 244, (4) p. 124.
SULFITE
WASTE
LIQUOR.
Aluminum
alloy
tank trucks have been used for handling dilute, unneutralized waste liquors. See also Ref: (2) p. 7%.
SULFUR.
S. In laboratory tests, 1100 and 3003
alloys were resistant to liquid sulfur al l35-154C
(275-310F). Aluminum alloy equipment has been
used for the recovers and ourification of sulfur. in
sulfur mining equipment.
buildings,
freight cars,
hoooer cars and convevors. See also Ref: f 1) o. 145.
(2;;. 800. (3) pp. 40. i27; James R. West,.S\lphu;
and Sulphides vs. Materials of Chemical Plant Con.
struction. Chemical Engineering, 1946 October.
I

SULFUR CHLORIDE.
SCI or S&I,. Sulfur chloride ha\ been shou n to be very corrosive to aluminum
alloys in laboratop tests. See also Ref: (7) pp. 176.
177.
SULFUR DIOXIDE. SO2 In laboratory tests. sulfur
dioxide sarurated with water was corrosive to all
aluminum alloys at ambient temperature. Aluminum
alloy equipment
has been used for refrigeration
systems containing sulfur dioxide, for vulcanizing
chambers, and petroleum refiiing
stills involving
sulfur dioxide, for heat exchangers in cooling sulfur
dioxide, and for reactors converting sulfur dioxide to
sulfur trioxide. See also Ref: (1) p. 145, (2) p. 806, (4)
p. 97 (7) p. 177.
SULFURIC ACID. HISO,. In laboratory tests, the
corrosion of aluminum alloys in sulfuric acid varies
with concentration of sulfuric acid.
The corrosion reaches a maximum at about 80% acid
concentration. Above that concentration.
attack decreases rapidly until at 98% it becomes mild, less
than 5 mpy. In other laboratory tests, fuming acids
containing 101. 103. 107 and 115% sulfuric acid
caused moderate attack of 3003 alloy at ambient temperature. Aluminum alloy heat exchangers, piping
and tanks have been used to handle sulfuric acid in
98% concentrations and at temperatures
as high as
200C (392F). See also Ref: (1) p. 145, (2) p. 811, (3)
pp. 22. 41. (4) pp. 18, 19, 29, 30, 31, 34, 74, %, 97,
(7) p. 177.
SULFUROUS
-40.
HzSO1. In laboratory tests,
dilute aqueous solutions of sulfurous acid caused corrosion of 1100 alloy which increased with concentration. At 0.1% sulfurous acid, the attack was mild
(-4 mpy). while at 8%. the attack was moderate
(- 12 mpy). Sulfurous acid condensed from gases
containing sulfur dioxide and moisture will cause
corrosion of aluminum alloys. See also Ref: (1) p.
145. (2) p. 841, (3) p. 22, (4) pp. 19,29,30, (7) p. 179.
SULFUR TRIOXIDE.
SO,. Aluminum alloy reactors have been used for converting SO1 to SO, (sulfur
trioxide). See also Ref: (3) p. 40.

TALL OIL. Tall oil has been handled

in aluminum

ASSOCIATION

(continued)

alloy tanks, pipe lies, and heat exchangers.


Ref: (7) pp. 180, 181.

See also

TANNlC ACID. CT~H~~O~. Solid tannic acid caused


mild attack (- 2 mpy) of alloys 3003 and 5154 in lab.
oratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
In other
laboratnn tests, 0.01% to 20%~ aqueous solutions
caused mild attack ( - 2 mpy) of 1100 alloy at ambient temperature and moderate attack (- 9 mpy) at
50C (12ZcF). These solunons were corrosive at IOOC
(212F). Aluminum allo! processing equipment has
been used in tanning plants. See also Ref: (1) p. 145.
(4) pp. 29. 30. (7) p. 181.
TAR. Aluminum coils and heat exchangers have
been used in tar distillation plants to condense hot
creosote vapors. Tar and tar products have been
handled in aluminum allo! tanks. See also Ref: (1) p.
145. (3) p. 223.
TARTARIC ACID. HOO.C(CHOH)>COOH.
Alloys 3003 and 5154 were resistant to solid tartaric
acid in laboratory tests conducted under conditions
of 100% relative humidlty at ambient temperature.
In other laboratory tests. 1100 alloy was resistant to
aqueoussolutions(O.l%
to55%) at ambient temperature, but these solutions were corrosive at SOC
(122F) and very corrosive at 100C(2120F). Tartaric
acid has been processed in aluminum alloy filters and
crystallizers and has been stored in aluminum alloy
See also Ref: (1) p. 145. (2)
tanks.
p. 848, (3) pp. I3 I, 209. (4) pp. 22, 25,26,27,28.29,
30. 88, (7) p. 181.

containers have been used for handling


porting pure. dry titanium sponge.

and trans.

TITANIUM
DIOXIDE.
Ti02. Titanium
dioxide
pigment has been dried in large aluminum-lined
steam tube driers. Aluminum alloy heat exchangers
have been used to condense titanium dioxide vapors.
See also Ref: (3) p. 78.
TITANIUM
TETRACHLORJDE.
TiCI,. In limited laboratory tests, titanium tetrachloride caused
mild attack ( - 5 mpy) of alloys .X)52 and 6061 under
refluxing conditions. See also Ref: (7) pp. 182. 183.
TOBACCO. In limited laboratory tests. moist tobacco caused localized pittmg of 3003 and SOS2
alloys at ambient temperature.
Aluminum
alloys
have been used for packaging tobacco products. See
also Ref: (I) p. 146.
TOLUENE.
C,H,.CH.,.
In laboratory tests, 3003
alloy was resistant to toluene at ambient temperature
and the boiling temperature.
Toluene has been
handled in aluminum allo) equipment. See also Ref:
(1) p. 146. (2) p. 855. (3) pp. 104. 223, (7) p. 183.
TOLUIDINES(m-,o-.andp-_).CH,C,I&.NH,.
Toluidines have been handled in aluminum alloy
steam heated stills. See also Ref: (1) p. 146. (3)
p. 144.

TERPENES. Cl&,.
(Polymers of lsoprene CrH&
Aluminum alloy tanks have been used for storing terpenes. See also Ref: (3) p. 104. (7) p. 181.

TOMATOES
AND TOMATO JUICE. In laboratory tests, 3003 and 5154 alloys were resistant to
tomato paste at ambient temperature.
In other laboratory tests. 3C03 alloy was resistant to tomato juice
at 1OOC (212F). Cooking and storage of tomatoes
in aluminum al(oT vessels has caused pitting on the
metal. TomatoJuIce has been processed in aluminum
alloy equipment. See also Ref: (I) p. 146. (3) p. 209.
(4) pp. 88. 91. 92. (6) p. Il.

TETRACHLOROETHANE.
CI,HC.CHCl2.
Limited laborat?
tests indicated that 3003 alloy
was resistant to tetrachloroethane
at ambient temperature but at boiling temperature
tetrachloroethane was corrosive. CAUTION: See Halogenated
Hydrocarbons. See also Ref: (3) p. 109.

TOOTHPASTE.
In lahoratoy tests, the corrosion
effects of toothpastes are variable. with most causing
little corrosion. Those contaming fluorides are corrosive IO aluminum
alloys. Toothpastes
hate been
packaged in collapsible aluminum tubes. See also
Ref: (I) p. 146. (3) p. 239.

TETRACHLOROETHYLENE. Cl&. Ccl,. In limited laboratory tests, high purity aluminum was resistant to tetrachloroethylene
at SOC (122F) and under refluxing conditions. In other laboratory tests.
tetrachloroethylene
caused mild attack ( - 5 mpy) of
3003 alloy under refluxing conditions. Aluminum alloy degreasing installations including stills and storage tanks have been used with tetrachloroethylene.
See also Ref: (1) p. 145. (3) p. 108.

TOXAPHENE. C,&,,Clh.
In limired laborato?
tests at ambient temperature and 52C (126F). toxaphenc solutions caused localized pitting of 3003 alloy. Aluminum allo! tanks have been used to store
and transpon toxaphene. CAUTIOS: See Halogenated Hydrocarbons. See also Ref: () pp. 182, 183.

TEA. Aluminum alloys have been used for packaging, storing, and brewing tea. See also Ref: (I) p.
145, (3) p. 211, (4) pp. 79,843 97.98. (6) p. 12.

THIOCARBANILLDE. CS(NHC,H&. In laboratory tests, thiocarbanilide


caused mild attack (-4
mpy) of alloy 3003 at 204C (400F). Aluminum
alloy drying trays have been used for handling thiocarbanilide at temperatures up to 88C (190F).
THIOGLYCOLIC
ACID. HS CH1. COOH. In laboratory tests. alloys 1 IO@. 3003 and 5052 were resistant to 7.2% aqueous solutions of thioglvcolic acid at
ambient temperature.
Aqueous solutibns of 45%
concenlr.xion were corrosive. Aluminum alloy tanks
and recehers have been used for thioglycolic acid.
See also Ref: (3) p. 133.
THIOPHENE.
SCH:CHCH:CH.
Limited laboratory tests indicated that 3003 alloy was resistant to
thiophene at 204C (400F). See also Ref: (3) p. 148.
TITANIUM. Ti. In laboratory tests, titanium was
found to cause corrosion of contacting aluminum
alloys in high chloride-containing
environments by
galvamc action. Hermetically sealed aluminum alloy

TRLXETIN.
(CHICOO)JCIHi.
Limited
laboratory tests indicated that 6053 alloy was resistant to
triacetin at ambient temperature.
Aluminum alloy
kettles and stills have been used in the production of
triacetin. See also Rrf: (IO) p. 81.
TRICHLOROBENZENE. C,H,CI,.
In laboratory
tests, 3003 alloy was resistant to trichlorobenzene at
ambient, SOC (122F). 100C (212F). and 204C
(400F) temperatures
and under refluxing conditions. Aluminum alloy tank cars have been used to
ship trichlorobenzene. CAUTION: See Halogenated
Hydrocarbons. See also Ref: (3) p. 111. (7) p. 185.
I,I,I-TRICHLOROETHANE.
CCI,CH,.
In limited laborator? tests. 3003 alloy was resistant to trichloroethane at ambient temperature and under refluxing conditions. CAUTION: See Halogenated
Hydrocarbons. See also Ref: (3) p. 109. (7) p. 18.5.
TRJCHLOROETHYLENE.
CICH:CCI,. In limited
laboratory tests. 3003 alloy was resistant to trichloroethylene in the dry condition at ambient temperature,
50C (122F) and under refluxing conditions. The

(continued)

Nonferrous Metals and Alloys

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

presence of water accelerates the corrosive effects of


trichloroethylene.
Aluminum alloy tank cars have
been used for transporting dry trichlonethylene.
Inhibited trichloroethylene
has been used for degreasing of aluminum alloy products. CAUTION:
See
Halogenated
Hydrocarbons.
See also Ref: (1) p.
146, (3) pp. 25. 108. 244. (7) p. 185.
TRIETHANOLAMlNE.
N(CHI. CH*. OH),. In laboratory tests, alloy 2017 was resistant to triethanolamine at ambient temperature while triethanolamine
was comosive to 3003 alloy at 204OC (400F) and
under refluxing conditions. Aqueous solutions were
vey corrosive to aluminum alloys at ambient temperature. Triethanolamine
has been stored and tram
ported in aluminum allo! tanks. See also Ref: (1) p.
146. (2) p. bb2.13) pp. 25. 145, (5) p. 14.
TRIETHYLAMINE.
(C?H,),N.
Laboratory
tests
indicated that 3003 allo!_ war resistant to triethylamine at 1OOC (212F) and 204C (400F).
TRIETHYLENEDIAMINE.
NH>(C,H&C>H,NH:.
Alummum allov steam tube has been used to handle
triethylenediamine.
I. 2,4 TR[METHYLBENZENE
(PSEUDOCUMENEI.
C,H,(CH,),.
Aluminum allo} stills have been used
for the distillation of trimethylbenzene.
See also Ref:
(7) p. 187.
2, 4, 6.TRINITROTOLUENE.
(NO&. CoH>. CH,.
Aluminum allo! kettles and heat exchangers have
been used in the manufacture
of trinitrotoluene.
Aluminum alloy vessels have been used for melting
trinitrotoluene.
TRI-o-CRESYL
PHOSPHATE.
(CH,.C,H,),PO,.
In laboratoq tests, 3003 alloy was resistant to tri-ocresjl phosphate at 204C (400F). Under refluxing
conditions tri-o-cresyl phosphate
was corrosive to
3003 alloy. Aluminum alloy tank trucks have been
used to transport tri-o-cresyl phosphate.
See also
Ref: (1) p. 146. (3) p. 138. (7) p. 18.5.
TUNA FISH. In laboratory tests, 3003 alloy was resistant to tuna fish at ambient temperature. See also
Ref: (6) p. 12.
TUNG OIL. In limited laboratory
was resistant to tong oil at ambient

tests, alloy 6061


temperature.

TURPENTINE.
(Usually contains mainly n and 4
pinene; also camphene, dipentene. other monocyclic
terpenes. p-cymene). In laboratory tests, 3003 alloy
was resistant to turpentine
at ambient temperature
and at the boiling temperature.
Production of turpentine has been carried out with aluminum alloy
distillation equipment, heat exchangers, and tanks.
Alloy A356.0 valves have been used for handling turpentine. See also Ref: (2) p. 866, (3) pp. 104, 226,
238. (7) p. 189.

U
UNDECYLENlC
ACID. CH,:CH .(CH&,.COOH.
Aluminum
allo) receivers and storage tanks have
been used for handling undecylenic acid.

UREA. H2N. CO. NH>. Alloy 3003 was resistant to


solid urea while 5154 alloy suffered mild attack in
laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
In other
laboratory tests, 3003 alloy was resistant to solutions
of urea at ambient temperature.
Aluminum
alloy
equipment.
including distillation columns, driers,
heat exchangers, storage tanks. and piping, has been
used for handling urea. See also Ref: (I) p. 146, (3) p.
147. (7) p. 191.

ASSOCIATION

(continued)

V
VALERIC ACID. CH,(CHJ3COOH. In laboratory tests, 3003 alloy was resistant to valeric acid at
IOOC (212F). See also Ref: (1) p. 146 (3) p. 127.
VANILLIN. CH,O(OH)C,H,CHO.
Aluminum equipment has been used to handle synthetic vanillin. See
also Ref: (8) p. 124.
VARNISH. A resinous solution or drying oil. Aluminum alloys have been used for varnish kettles. Lead
drying agents have caused pitting and failure in some
aluminum alloy varnish kettles. See also Ref: (1) p.
146. (2) p. 770, (3) pp. 131, 237.
VEGETABLES.
Vegetables have been prepared in
aluminum alloy kitchenware. The cooking periods
are relatively short, and even acidic vegetables have
negligible effect. Aluminum alloys have been used
for certain canned vegetables. See also Ref: (1) p.
146, (3) pp. 198.208, (4) pp. 78, 79, .%I.88, 106. 109,
115. (6) p. 11.
VINEGAR. In laboratory tests, 1100 alloy was resistant to various types of vinegar at ambient temperature. At SOC (122F), the corrosion was increased
and the attack was moderate (- 7 mpy). Aluminum
alloy distillation columns, tube, pipe and tanks have
been used in producing vinegar. Vinegar contaminated with chloride or heavy metal ions promotes pitting of aluminum alloys. See also Ref: (1) p. 146, (3)
pp. 126. 198, 210, (4) pp. 22, 24. 31, 84, 92.
VINYL ACETATE.
CHI. COO. CH CH?. Aluminum alloy equipment has been used for polymerization kettles, driers, containers and tank trucks in the
production and handling of vinyl acetate. See also
Ref: (3) p. 136. (7) p. 193.
VINYL CHLORIDE
MONOhER.
CH,:CHCI.
Aluminum alloy aerosol containers have been used to
handle vinyl chloride. Vinyl chloride slurries have
been handled in aluminum alloy pipe. CAUTION:
See Halogenated Hydrocarbons.
See also Ref: (2)
p. 875, (3) p. 108. (7) p. lc13.
VINYL CHLORIDE
CHLORIDE.

POLYMER.

629

Aluminum
alloys are well suited for handling
steam condensate. They are not adversely affected by
carbon dioxide and oxygen or by chemical agents
such as ammonia. hydrazine. morpholine.
filming
amines and sodium sulfite added to condensate in
the relatively small concentrations needed to protect
steel. Large aluminum tanks have been in use at
power plants for storage of alkaline condensate
(pH 9-9.5).
Laboratory tests indicate that the cwrosivity of
natural fresh waters is difficult to predict. When they
do cause corrosion. the attack is generally of the pitting type. The tendency of fresh natural water to promote pitting of aluminum depends upon the nature
and concentration of salts dissolved in them. Small
quantities of soluble chloride and heavv metal salts in
some natural water will promote pitting of aluminum. especially if the water pH is 6 or below, Alclad
alloys such as alclad 3003 and alclad 6061 are highly
resistant to the development of deep pits.
Waters that are handled in recirculating systems
are generally corrosive to aluminum unless a suitable
water treatment is used. Even if a water that in its
natural state has little action on aluminum is used.
the concentration
of dissolved solids builds up as
evaporation losses are made up or as contaminants
are picked up from the system or the air and the corrosivity of the water could increase. Expert advise on
suitable water treatments is available from a number
of water treating concerns. See also Ref: (7) pp. 251.
252.253. L54.
WAX. In laborator! tests. man) waxes were protective to aluminum alloys. Steam traced aluminum alloy piping has been used to handle liquid and molten
waxes. Molten waxes have been solidified in aluminum alloy pans. Aluminum allo! dip tanks have been
used to treat crude robber with molten wax. See also
Ref: (1) p. 147. (3) pp. 220, 225.
WETTING
AGENTS. (Alkyl and alkylaryl sulfonates in the form of their sodium salts). Aluminum
alloy containers have been used to handle these cornpounds. See also Ref: (IO) p. 100.
WHISKEY. In laboratory tests. alloys 1100 and 3003
were resistant to uhiske! at ambient temperature but
pronounced localized pttting occurred. The color of
the whiskey was also affected. See also Ref: (1) p.
147, (3) p. 203, (6) p. 10.

See POLYVINYL

WHITING.
CaCO,. (Naturally occurring calcium
carbonate about 98% pure). Aluminum allo) bins
VINYL RESINS. Vinyl resins have been shipped in and drums have been used for inter-plant and inaluminum alloy tanks and drums. Alumincnl alloy plant handling of whiting. See also Ref: (3) p. 76.
tanks, comeyors. and bins hake been used for inplant storage and handling of vinyl resins. See also WINES. In laborator) tests, the corrosion eftects of
Ref: (3) p. 233.
wines on aluminum alloys vary widely. Discoloration
of some wines contacting aluminum alloys wa$ also
\lTAMINS.
Aluminum alloy equipment has been encountered. Aluminum alloy equipment such as pipused to process and handle vitamins. See also Ref: (2) ing, fittings, containers for transferring grape juice,
p. 82. (3) pp. 104. 115. 124. 138. 198. 205.
unfermented
wine. fermented wine. and fortified
wine as well as grape pulp or must har been used in
the wine industry. Coated pure aluminum tanks have
been used for storage and shipment of u ines. Wine
has been packaged in coated aluminum alloy cans.
SeealsoRef:(l)p.
147, (3)~. 202.(4)pp. 93.94, 142.

WATER. HIO. Aluminum alloys have been used for


handling a wide variety of waters. In high purity
water, laboratory tests show that a slight reaction occurs originally between the aluminum alloys and distilled, deionized. and uncontaminated
rain water,
but after a few days it ceases and aluminum pick-up
by the water becomes negligible. Aluminum alloy
tanks and piping have been used for storage and distribution &fdistilled and deionized water. At elevated
temperature,
- 200C (392F) and above, both distilled and deionized water cause very severe corrosion
Of most aluminum alloys. Special aluminum alloys
containing iron and nickel as alloying elements have
been developed for use in high purity water up to
temperatures of 360C (680F).

WOOD. Wet wood has caused varying degrees of


corrosion of contacting aluminum alloys in laboratov tests. The degree of corrosion varied uith the
type of wood tested. It is good engineering practice to
apply protection where aluminum alloys will contact
wood which may become wet. Aluminum alloy nails,
screws. and bolts have been used in wood. See also
Ref: (1) p. 147. (3) p. 231.
WOOD CREOSOTE. (A mixture of phenols, chiefly
guaiacol and cresol.) In laboratory tests, wet wood
treated with creosote did not accelerate corrosion of

(continued)

630

Corrosion Resistant Materials Handbook

TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

ZINC BORATE. 3 ZnO 2 B*O,. Alloys 3003 and


5154 were resistant to solid zinc borate in laboratory
tests under conditions of 100% relative humidity at
ambient temperature. In other laboratory tests, 1100
alloy was resistant to dilute (up to 10%) solutions of
zinc borate at ambient temperature. See also Ref: (3)
p. 80.

WOOD PRESERVATIVES.
In laboratory tests,
wood preservatives were found to vav greatly in their
corrosivity to aluminum
alloys. Some caused less
than 1 mpy attack while others, particularly those
containing copper or mercury salts or zinc chloride,
were very corrosive. Creosote. zinc napthanate and
pentachlorophenol
were found to be most compatible with aluminum alloys. None of the wood presep
vatives was inhibitive.

ZINC CHLORIDE.
ZnC12. Solid zinc chloride was
corrosive to 3003 alloy in laboratory tests conducted
under conditions of 100% relative humidity at ambient temperature.
In other laborator) tests. dilute
(up to 10%) solutions of zinc chloride caused mild attack of 1100 alloy ( - 2 tnp! ) with evidence of localized
pitting at ambient temperature.
See also Ref: (1) p.
147. (2) p. 892. (3) p. 79, (7) p. 195.

X
XYLENE. C,H4(CH,)]. In limited laboratory tests,
3003 alloy was resistant to xylene at the boiling temperature. Xylene has been handled in aluminum alloy
piping. condensers. and pressure vessels. See also
Ref: (1) p. 147, (3) pp. 104. 223, (7) p. 193.

ZINC CHROMATE.
Zn,CrO&OH)2.H~0.
Alloys
3003 and 5154 were resistant to solid zinc chromate
in laborator) tests conducted under conditions of
100% relative humidity at ambient temperature.
Zinc chromate has been used as an inhibitive pigment in organic coatings used on aluminum alloys.
See also Ref: (3) p. 80, (4) pp. 95. 139, 141.

Z
Alloys
ZINC ACETATE.
Zn(CHICOO):.2H20.
3003 and 5154 uere resistant to solid zinc acetate in
laboratory tests conducted under conditions of 100%
relative humidity at ambient temperature.
In other
laborator) tests, 1 IO0 alloy uas resistant to dilute (up

Designations

(continued)

to 10%) solutions of zinc acetate at ambient temperature. See also Ref: (3) p. 80.

contacting 3003 alloy under conditions of 100% relative humidi


at SZOC (125F). Aluminum alloy equip
ment including coils, heat exchangers. and tanks has
been used to handle creosote. SeealsoRef:(l)
p.131,
(3) pp. 117, 223.

YEAST. Limited laboratory tests indicated that 11OC


alloy was resistant to yeast at ambient temperatuw
and 32C (90F). Production of yeast has been carried
out in aluminum alloy vessels. Aluminum alloy equipment for brewing and distillation of yeast has been
used. Yeast has been packaged in aluminum foil. See
also Ref. (I) p. 147. (2) p. 889, (3) p. 210, (7) p. 193.

ASSOCIATION

ZINC NAPHTHANATE.
Zn(C-H,,O,JJ. In laboratory tests. zinc naphthanate
preservative treatment
did not accelerate attack of aluminum alloys by contacting wet wood.

ZINC NITRATE. Zn(NO,),.6H,O.


Alloys 3003
and 5154 were resistant to solid zinc nitrate in laboratory tests conducted under conditions of 100% relative humidity at ambient temperature. In other laboratory tests, 1100 alloy was resistant to dilute aqueous
solutions of zinc nitrate at ambient temperature. See
also Ref: (1) p. 147. (3) p. 80.

ZINC OXIDE. ZnO. Alloys 3003 and 5154 were resistant to solid zinc oxide in laboratory tests conducted under conditions of 100% relative humidity
at ambient temperature.
See also Ref: (3) p. 79.

for Wrought Alloy Groups

ZLNC STEARATE.
A mixture of the zinc salts of
stearic and palmitic acids and usually uith some excess of zinc oxide. Allov 3003 and 5154 were resistant
to solid zinc stearare in laboratory tests conducted
under conditions of l&We relative humidity at ambient temperature

ZINC SULFATE. ZnSO,. 7 H20. Alloys 3003 and


5154 were resistant to solid zinc sulfate in laboratory
tests conducted under conditions of 1CWo relative
humidity at ambient temperature.
In other laboratoy tests. 1100 alloy was resistant to aqueous solutions (up to 10%) of zinc sulfate at ambient temperature. See also Ref: (1) p. 147, (2) p. 8%. (3) p. 79, (7)
p. 195.

References
Alloys-Struc1. Mondolfo. L. F.. Aluminum
Boston: Butteworth
&
ture and Properties.
Co., 1976 (reprinted in 1979).
New York:
2. Rabald. E., Corrosion Guide.
Else&r Publishing Co.. 1968.
P. and M. Sigxalt. Aluminum-Its
3. Joni&,
Applicatton
in the Chemical and Food lodustties, New York: Chemical Pubhshing Co.,
1964.
4. Br+n.
1. M.. Alummium
and Aluminium
Alloss in the Food Industn.
(Fw/
:,Iws~~~,I.
liorr. Spcid
Repurr.
No. So). London. His Majestys Stationery Office, 1948
5. Witt. C. A., A. Labenski and G. Gerken.
Resistance of Aluminlum
to Various Chemicals.Alumi~~r~n~, 1979. 55. (8). 526-532.
6. Kunz.
E.. Corrosivity
of Different
Food
Groups in Aluminum
Packaging Materials.
Edited version. Institute for Food Technoloa
and Packaging, 1974.
7. Hamner.
N. E.. Corrosion
Data SuwevMetals Section. Houston: National Assoclaiion
of Corrosion Engineers. 1974.
8. Das Chemische Verhalten van Aluminium.
Dusseldorf. Aluminium-Verlag.
1955.
9. Bohner. H. and H. Buschlinger, Survey of the
Behavior of Aluminium Toward Chemicals and
FoodProducts. Housrrirschrifr
(1931)
9 (II),
301.
10. Aluminium in the Chemical and Food Industries. London: British Aluminium Co.. 1959.

Designations

for Casting Alloy Groups

Alloy No.
Aluminum-99.00%

minimum and greater. .

lxxx

Alloy No.
Aluminum-99.00%

Major Alloying Element


Aluminum
alloys
grouped
by major
alloying
elements

Copper .....................
Manganese ..................
Silicon. .....................
Magnesium .................
Magnesium and Silicon .......
Zinc ........................
Other Element. ..............
Unused Series ...............

minimum and greater .

1xx.x

Major Alloying Element


2xXx
3xXx
4xxx
sxxx
6xxx
7xxx
8xXx
9xxx

Aluminum
alloys
grouped
by major
alloying
elements

-Copper . . . . . . . . . . . . . . . . . . . .
Silicon, with added Copper
and/or Magnesium . . . . . . . .
Silicon . . . . .1. ..............
Magnesium. . . ..............
Zinc . . . . . . . . . ..............
Tin . . . . . . . . . . ..............
Other Element ..............
-Unused Series ..............

2xx.x
3xx.x
4xx.x
5xx.x
7xx.x
8xx.x
6xx.x
9xx.x

(continued)

631

Nonferrous Metals and Alloys


TABLE 5.2:

ALUMINUM

ALLOYS-ALUMINUM

INHIBITORS

ASSOCIATION

An inhibitor is a substance which, when added (usually


in a small amount) to a liquid or chemical.
reduces or
prevents the corrosion of a metal which would otherwise
occur. Some of the common inhibitors for aluminum and
the media in which they have been used are:

INHIBITORS ARRANGED ACCORDING

Acid, hydrochloric,

..........

1N

Acid, hydrochloric,
Acid, hydrochloric

1 N.. . . . . . . .
0.25, 1 N (32F)

Acid, hydrochloric,
Acid, nitric, 2-S%

2 N ..........
..............

Acid, nitric,

10%

................

Acid, nitric,
Acid, nitric,

10%
20%

................
................

..............

Acid, nitric fuming

phosphoric,
20% ...........
phosphoric,
20-80% ........
sulfuric, cone ..............
sulfurous ...................
..........................

.............
Alcohol, anhydrous
Alcohol, (antifreeze)
(See also methyl and ethyl). .....
Alkaline solutions (mild) ........
Alkaline solutions, e.g. sodium
carbonate .....................
........
Alkaline. soda solutions
Alkalies ......................
Ally1 alcohol ..................
Ammonia, condensing
steam ....
Barium hydroxide ...............
Brines .........................
Bromoform;
Chloroform
Iodoform
Calcium

chloride.

sat.

Carbon tetrachloridc
Chlorinated
aromatics
Chlorine
Detergents
Ethanol,

water

............

...................

......................
commercial

Ethyl formate
Ethylene

glycol

.
glycol

.
.

...................
..................

Fruit and milk acids

....

Sodium nitrite and


sodium molybdate
Sodium disilicate
Agar
Sodium silicofluoride
Sodium chromate
Albumins
H,S; CO, + H,S
Sodium silicate
Sodium chromate
Amines. Butylamine

Silicates

.............

Ethanol. hot . .
Ethyl alcohol or ethylene

0.003 M aphenylacridine.
finaphthoquinone,
thiourea.
or 2-phenylquinoline
Tannic Acid or rosin
0.5 g/l acridine,
1.0 g/l
thiourea, or nicotinic acid
0.06% acridine
0.05% hexamethylene
tetramine
0.1% hexamethylene
tetramine
0.1% alkali chromate
0.5% hexamethylene
tetramine
0.6% ammonium
hexafluorophosphate
0.5% sodium chromate
1.0% sodium chromate
5.0% sodium chromate
Sodium metasilicate
Dibenzyl sulfonic acids;
phenyl quinoline
Trace of Hz0

Alkali silicates; sodium


chromate
0.2-0.5%
formamide
O.l-0.2%
nitrochlorobenzene
Sodium silicate

...........
..........

.. . . .

(1%)

0.03% alkali carbonates,


lactates, acetates or
borates
Potassium dichromate
1% (NaNOz + Na
molybdate),
1% (NaNO*
+ Na tungstate),
or 1%
(NaNo? + Na selemate)
Aconitic, formic or
malonic acids (0.5%)
Sodium tungstate
or
sodium molybdate;
Alkah
borates or phosphates;
O.Ol%-1.0%
sodium
nitrate
Albumins,

TO ENVIRONMENT

Inhibitor

Environment

Inhibitor

Environment

Acid,
Acid,
Acid,
Acid
Acids

(continued)

collagen

Glycol-water,

30 : 70

Hydrogen

peroxide

Hydrogen

peroxide,

. .

2% sodium cinnamate
+
0.1% sodium tetrasilicate
+ phosphoric
acid to pH
= 9.5

...............

Alkali metal nitrates;


Sodium metasilicate
Sodium silicate

.......

alkaline

Latex coagulation
................
Lead paint pigments or lead soaps

Methanol

or ethylene

...... .

glycol

Sodium fluosilicate
Linoleates,
laurates
ricinoleates

or

Methyl chloride.

O.Ol-2% benzotriazole
+
O.l-2% Na molybdate or
umenate or arsinite +
OS-2.5%
buffer to pH
7.5-10s
Sodium chlorate +
sodium nitrate
Water

Pineapple
Potassium

Sugar
Sodium

Methyl alcohol

juice
chloride

Seawater. .
Soap..............
Sodium acetate
Sodium carbonate.

Sodium
Sodium
Sodium
Sodium
Sodium
Sodium
Sodium

. .

carbonate,
dil
carbonate,
1%
carbonate,
10%
chloride, 3.5%
cyanide..
hydroxide,
1%
hydroxide,
1%

Sodium hydroxide,
Sodium hydroxide,
Sodium hydroxide,
Sodium hypochlorite
in bleaches.
.
Sodium phosphate,
Sodium sulfide
.
Sodium sulfide
.
Synthetic detergents

natural

. .
.
. _. .
. ... . . ..
.

.
.

dibasic,

.
. .

surface

Water recirculating
air conditioning.

4%
0.3 N (3X).
0.5 N
contained

tribasic

. .

.. .

Trichloroethylene
Water,

...

. ...

.
...,

chromate

0.75% sec. amyl stearate


Sodium silicate
Alkali silicates
Bone glue; vegetable glue;
chromate;
gelatin; gum
arabic
Sodium fluosilicate
0.25% sodium silicate
0.05% sodium silicate
1% sodium chromate
Sodium metasilicate
Alkali silicates
3-4% potassium
permanganate
18% glucose
0.4% tragacanth
gum
0.2% agar-agar
Sodium silicate
.SStfirm silicate

I % sodium metasilicate
Sodium silicate

...

0.02-0.05%

. .

Potassium chromate,
dichromate;
sodium
chromate,
dichromate

formamide

for

0.1% Na+O,,
pH =
7-9. or 0.1% Na
me&silicate
+ 0.1% Na

g<zyhphate.

pH =

632

TABLE

Corrosion

5.3:

Resistant

ALUMINUM

Materials

Handbook

BRONZES

AND

NICKEL-ALUMINUM

BRONZES-AMPCO

The AMPCO
alloys
recommended
for process
applications
are essentially
bronzes.
They
can be produced
in a wide range of forms-sand,
centrifugal
sheat and plate; extruded
and continuous
cast rod, tube and shapes.
Applicability

Acetate Solvents (Pure)


Crude
Acetic Acid
Crude
Vapors
Acetic Anhydride
Acetone
Acetylene (Wet)
Alcohols
Aluminum Fluoride
Aluminum Sulfate
Aluminum Hydroxide
Ammonia Gas
Drv

of AMPCO

Alloys

Carbon Tetrachloride
Chlorinated Hydrocarbon
Chlorine
Dry
Wet
Chloroacetic Acid
Chloroform
Chromic Acid
Citric Acid
Copper Sulfate
Corn Starch Slurry
Diesel Oil, Light
Esters
Ethers
Ethylene Glycol
Ethyl Sulfate
Fatty Acids
Ferric Chloride
Ferric Sulfate
Formaldehyde
Formic Acid
Freon
Furfural
Gasoline
Glucose
Glycerine
Hydrocarbon Gases
Hydrochloric Acid
to 15%
over 15%
Hydrocyanic Acid
Hydrofluoric Acid
Hydrogen Fluoride (Dry)
Hydrogen
Hydrogen Sulfide

Rx
R
R

wit

Ammonium Chloride
Ammonium Hydroxide
Ammonium Nitrate
Ammonium Phosphate
Ammonium Sulfate
Amy1 Chloride
Asphalt
Barium Chloride
Beer
Beet Sugar Liquors
Benzene or Benzol
Borax
Boric Acid
Brine
Butane, Butylene, Butadiene
Butyric Acid
Calcium Bisulfite
Calcium Hydroxide
Calcium Hvoochlorite
Carbon Dioxide
Dry
Wet
Carbon Disulfide

R
RF
::

zt
Hydrogen Peroxide

R!
RX

aluminum
and shell

Chemical

Ketones
Lacquer and Lacquer Solvents
La&c Acid
Magnesium Chloride
Magnesium Hydroxide
Magnesium Sulfate
Malt Beverages
Mercuric Chloride
Mine Water (Sulfate)
Molasses
Monochlorobenzene
Naptha
Natural Gas
Nickel Chloride
Nickel Sulfate
Nitric Acid
Nitrogen (Dry)
Oleic Acid
Oxygen
Paint Vehicles
(except Soya-Oil)
Palmitic Acid
Petroleum Oils
Sour
Refined
Phenol
Phosphoric Acid
Pickling Acid
(except Nitric Chromic)
Potassium Chloride
Potassium Cyanide
Potassium Hydroxide
Potassium Sulfate
Propane
Shellac
Soaps
Soda Ash
(Sodium Carbonate)

R
RRX

RX
R
NR

to Various

METAL
bronzes
and nickel-aluminum
mold castings;
forgings;
rolled

Agents

RX
R

Sodium Bicarbonate
Sodium Bisulfate
Sodium Chloride
Sodium Cyanide
Sodium Hydroxide
Sodium Nitrate
Sodium Perborate
Sodium Peroxide
Sodium Phosphate
Sodium Silicate
Sodium Sulfate
(Soda Cake)
Sodium Sulfide
Sulfur (Molten)
Sulfur Chloride (Wet)
Sulfur Dioxide
Dry

!i
;

NR
RX
R
RX
RX
R
RX

N;
R
R
RX

wet

Sulfuric Acid (to 50%)


Sulfurous Acid
Tannic Acid
Tartaric Acid
Toluene or Toluol
Tri-Chlorethylene
Tri-Sodium Phosphate
Turpentine
Varnish
Vegetable Oils
Water
Fresh
Salt (includes
Polluted Harbor)
Xylene
Zinc Chloride
Zinc Sulfate

RX
R
:;

RX

These ratings
may usually be
interpreted as follows:
R - Generally suitable. Corrosion rates less than 2 mpy.
RX-Generally
suitable however conditions such as aeration or temperature could restrict their use. Corrosion rates IeSS than 20 mPy.
NR - Generally not suitable. Corrosion rates over 20 mpy.
In evaluatmg this data, it should be understood that these are results of specific tests and are indicative of those conditions
under which the tests were run, thus are a basis for recommendation, but not for guarantee.

CORROSION
No aeration

IN BOILING
SULFURIC
ACID
no agitation except boiling
AVG.

/
I
I

MATER

SOLUTION
CORROSION

5% HSO,
102O c
(216 F)

I AL

RATE,

10% HSO,
105 c
(221
F)

INCHES

19% H,SO,
105C
(221
F)

23 hr. tests

!/ ALUMINUM
MONEL
400 BRONZE
ALLOY
NICKEL
200 ALLOY
CHEMICAL
LEAD

(10%

AL)

0.0019
0.0034
0.034
0.016

0.0002
0.0024
0.12
0.015

PER

___

YEAR

!
_-.

150% HISO.

1 123C
(253

F)

20 hr. tests

:
1

0.0012
0.0075

0.0079
0.65

0.11

3.4

0.042

1.2

Nonferrous Metals and Alloys


TABLE 5.4:

ALUMINUM

COATING-ALCOA

12-YEAR INSPECTION
TESTS ON METALLIZED

RESULTS

ALUMINUM

PANBLTYPB
BASE METAL
PREPARATION

TEST

OF SEAL COAT

SITB LOCATION

OHIO

EAS~TC&~GO,

KURE BEACH,
NORTH CAROLINA
( ao-ft la)

KURE BEACH,
NORTH CAROLINA
(800~fc lot)

Typa

of b.ue

NOM

0.003

0.003

0.006

WP+Av-1

WP+AV-2

NOlK

ENVIRONMENT
Base metal no( atracked.
Sprayed metal intact but
show a very faint yellOr
gray stain 00 front of
panels, ,witb a VT Ii&t
rryhmc
sod whne rust

Base men1 not attacked.


Sprayed meal intact
Vinyl seaI coat on from
of panels shows dull
gray blacba.
Vinyl saI
;sxo;to
of panels

URBAN

Base metal not attacked.


Sprayed metal on front
of panels shows many
pinpoint aodw and a
general dark gray deposit
stain. Back of
show a ,enerr::
gny sum.

Base metal not attacked.


Sprayed metal intact.
The vinyl seal coat
show L chin dark gray
deposit sain on both
the front and back
of pnel.s.

INDUSTRIAL

Base metal not attacked.


Sprayed metal on from
of panels shows many
pinpoint nodes and a
general dark
ay deposit
rain. Back o Y paneb
show a dark gtn,
deposit win.

%~%*$z%mt
of pan& shows a
general dark depceit
stain. Back shows a
thin deposit stain.

SamensType2.

Same u Type 1.

Bue metal not attacked.


Sprayed metal and vinyl
se-al coat unaffeaed on
both front and back of
pan&.

Base metal ax attacked.


Sprayed mm1 on front
and back of panels
shows many piapoinc
noder and L general
dark gray deposit stain

Base meal nor~rmcked.


Same a Type 2.

SEVERE
WE

Base meal not attacked.


Sprayed metal on front
of panels shows dull
blotches. Back of panels
are leu blotchy. Both
sides show some low
unbroken blisters.

Base men1 not arracked.


Sprayed meal intact_
Vinyl seal coat shows
&li,z:rs
og ;a$~
!&a
balalcJff~nels

SALT-AIR

Base meal not attacked.


s rayed metal on front
o P panels intact. Sprayed
metal on back shows
small to medium red
rust snias.

Base metal not attacked.


Sprayed metal intact.
Vinyl seal ccat shows
dull grr, blotch- 0~1
front side. Seal ccat on
back unaffected.

Base mm1 not attacked.


Sprayed metal on front
of panels shows many
pinpoior nodes and a
general gray deposit
stain. Sprayed mm1 on
back intact.

Base metal not attacked.


Sprayed metal inuct.
Vinyl seal coat on front
of panels is spotted
with medium sized gray
deposit stains. Seal cou
on back unaffected.

Base metal not attacked.


Sprayed metal intact.
wn~lsea~~coaf

Base metal nor attacked.


s rayed metal 00 front
o P panels shows P
general very light
stain over lo-25 ?z%
the surface, mostly near
the edges.

Base metal not xacked


Sprayed metal infact.
Vinyl seal coat 00 front
of panels shows light
gray blotches. Seal coat
00. back unaffected.

Base mm1 not amcked.


Sprayed metal inact.
Vinyl real ccut
unaffected.

INDUSTRIAL

POINT R?zYES.
CALIPOR?JIA

EXPOSURE

COATED CARBON STEEL PANEIS

0.003

SALT-AIR

coLuh4zBus.

OF ATMOSPH.ERK

ALUMINUM
COATING
THICKNESS, in&s
TYPE

633

SALT-AIR

mehal papaaior

1. Covse silica sand


2. Coarse silica and steel dash

* Types of II&
WP
AV
- 1
-2

Same as Type 2.

Same Y Type 2.

Base men1 not attacked.


Sprayed metal on both
from and back of panels
shows many pinpoint
nodes and a thick dark
deposit stain.

Same aa Type 1

Base metal not attacked.


Sprayed metal on from
and back of panels
intact.

Base metal not amcked


Sprayed metal on fronr
of panels shows many
pinpoint nodes and
general gray deposit
stain. Sprayed meal on
back of panels shows
gray deposit stains.

Same as Type 1.

cod

Wuh primer
Aluminum vinyl
One cca of specified seaI ccat
Two cop= of q&&d
ral cat

(continued)

634

Corrosion

TABLE

5.4:

Resistant

Materials

ALUMINUM

COATING-ALCOA

12-YEAR

RFiSULIIs

ALUMINUM

lYPB

BASE hfl?TAL
PREPARATION
NUMlMJM

(continued)

INSPECTION

TESTS ON METALLIZED
PANEL

Handbook

CARBON

STEEL PANEIS

bntd)

0.009

0.009

IYPB OF SEALCOAT

0.006

0.006

COATING

SITE LOCATION

COATED

EXPOSURE

THICIWESS.inches

TEST

OF ATMOSPHERIC

wp+Av--I

wp+.4v--I

WP+AV-2

ENVIRONMENT

sameOS
Type 1.

COLUMBUS.

OHIO

URBAN

%x

same*I
Type 2.

KURE BEACH.
NORTH
CAROLINA
( SO-fc la)

SEVERE
MARLXE

Same u Type 2.

KUKB BEACH,
NORTH CAROLINA
(800h
II_?%)

SALT-AIR

Same as Type 2.

NEW

YORK
AREA

CITY

Same ar
Type 2.

salnew
Type 4.

Same u
Type 2.

$x

INDUSTRLU
Same 0s
Typc4.

Types of bnrr m&l


1.
2.

Same a,
Type 4.

fwe,%rhw

Coarse silicasand
Coarse silica and steel Bash

Sameu
Type 5.

Trpm of md cod
WP
AV
- 1
-2

-Wash
primer
- Aluminum vinyl
-One
coat of specified seal coat
- Two coats of specified seal coat

(continued)

Nonferrous

TABLE

5.4:

ALUMINUM

COATING-ALCOA

12-YEAR

RE%JL.I-S OF ATMOSPHERIC

ALUMINUM

PANELTYPE
BASH METAL.
PREPARATION

OP SEAL COAT .*

TEST SITE LOCATION

COLUMBUS.

OHIO

COATED

WON

STEEL PANELS

kontd)

10

11

12

13

0.012

0.012

0.012

0.015

WP+AV-1

WP+AV-2

0.009

NOllC

wP+Av-2

NOtIe

ENVIRONMENT

NIX
Tatcd

UmAN

sameu

SEVERE
htNuNE

KUlU BEACH.
NORTH CAROLINA
( 800~fI lot)

SALT-AIR

NEW YORK CITY


AREA

INDUSTRIAL

Not
Tested

NOt
TCStCd

zd

Tlpc 2.

KURE BEACH.
NORTH CAROLINA
( 80-h la)

EXPOSURE

ALUMINUM COATING
THICKNESS. inches
TYPE

635

kontinued)

INSPECTION

TESTS ON METALLIZED

Metals and Alloys

sameu

Type 2.

sameu
Type 4.

Same aa
Type 2.

g?

SALT-AIR

* Trpa
WP
AV
-1
-2

of 14

cod

- Wash primer
- Aluminum vinyl
-One
cat of specified al cat
-Two
coat, of specified al am

(continued)

636

Corrosion

TABLE 5.4:

Resistant

Materials

ALUMINUM

Handbook

COATING-ALCOA

12-YEAR

INSPECTION

TESTS ON METALLIZED
PANEL

(continued)

ALUMINUM

TYPE

BASH METAL
PREPARATION

RESULTS OF SEA WATER


COATED

CARBON

TYPE OF SEAL COAT

l l

0.003

0.003

WP+CV-1

wP+CV-2

0.006

NOOe

red
CID3-5 % of the
md back of pm&.
Sprayed meml and vinyl
seal cca dissipaccd in
rbere area% Edges

Base metal mt atacked.


Sp? cd mm1 00 f1ont
& ck of panels
shows P for Mall
sawed
blisters and
red rust rmins. Edea
have been damaged
mechanically.

Base cat.41 shows

rw

front

TEXAS

TOTAL
IMMERSION

WR.IGHTSVILLE BEACH.
NORTH CAROLINA
( t&w-low-tide)

TOTAL
IMMERSION

Base mad not amckd.


Sprayed metal showa a
few small. unbroken
blistm on both sidn of
panels. Vinyl vnln
diuipDocd

TYPE

BASE MrrAL
PREPARATION

OP SEAL COAT

TJZST SlTB

PREEPORT.

wP+CV--1

TEXAS

WlUGMSVfLLB
BEACH.
NGRTH CAROLINA
( below-lowide)

WIUGHTSVILLE
BEACH,
NORtTTf_f$lNA

Panela missin&

SameasTypc

Base meal not rmcked.


Sprayed metal shows a
few medium. unbroken
blistersoa both sides
of panels.

1.

Base meal not amcked.


Sprayed metal intact on
both sides. Vinyl seal
coat una5med 00 both
rides. Edges have been
damaged mcchMiolly.

SamcaaTypcl.

0.009

0.009

0.009

NlJhUNUM
COATING
THxCKNE.SS. incbcr
TYPE

0.006

DMRONMENT

TEST SITE

PANEL

STEEL PANELS

PREEPORT.

EXPOSURE

0.006

WPs_CV-2

wp+CV--I

wP+CV-2

ENVIRONMENT

TOTAL
IMMERSION

SameuTypc4.

TOTN
IbfMERSION

SrmcUTlpcl.

SameasType

SameuTypel

3.
e;:

^rn%@

Base meal no( wackcd.


Sprayed metal shows P
few unbroken blinns.

SameuTypel.

Fkasc meal not ncmcked.


Sprayed metal shows P
few. unbroken blisrcrr.
Vinyl

Al-d&N?

ad

Coal diuipated.

SEA WATER
TY,W of bar mstd $wspar&m
2. Csilica sand and steel flub

Typa

WP
CV
- 1
- 2

of a.4

cod

- Wash prima
-Clew
vinyl
-One
ccac of specified seal coat
-Two
c-0 of specified seaI ccw

(contlnued)

Nonferrous

TABLE

5.4:

ALUMINUM

COATING-ALCOA

I2-YEAR

Metals and Alloys

637

(continued)

INSPECTION RE!XJLTS OF SEA WATER

EXPOSURE

TESTS ON METALLIZED ALUMINUM COATED CARBON STEEL PANELS kontd)


PANBL ZYPE

10

11

12

13

BASB METAL
PREPARATION

0.012

0.012

0.015

0.018

WP+CV-1

wp+CV-2

NofM

None

et:

SImc II
TYPC 3.

Type3.

ALUMINUM
COATING
THICKNBSS. incha
IYPB OF SW
TESTSITE

WRIGHTSVILLE BEACH,
NORTH CAROLJNA

( below-low-ride)

COAT

0.012

NOflC

l l

ENVlRONMBNT

TOTAL
IMMERSION

Same u
Type 1.

$x

sameu
Type 1.

COMFOSITION AND

Wash Primer

DESCRlPTION

OF SEAL COATS

Rain component:
Pigmmt: Insoluble type, inert,
zinc chmmate
Nawolatilc vehicle: Polyvinyl
l=vl
Volatile vehicle: Butyl md
isopropyl alcohol
Acid component:
phosphoric acid
Ethyl (or isopropyl) &Aol
plus water

8.2%

An air drying,
two-part, acid-zinc
chromate
wash
cc& primer

9.576
02.376
16.0%
BllUXC

Mi low puts ol the resin component rich oat put of she acid component to obmia 6ml prima
campoaitioa.
Aluminum Vinyl

Oar

Pigment: Non-leafing
aluminum flake
Nonvolatile vehicle: Vinyl
copolymer md plasticizer
Volatile vcbicle: Tolume
and ketone

Vinyl

Pi-:
None
Nonvolatile vehicle: Vinyl
dllori&-a
Resin
PlUti&Cl
Volatile v&hick: Ketones
Ammatic hydrocarbons
(Tolumc. benxol.

American

20%
70%

A clear. vinyl
copol~mcr.
rirdrying coating
IlUtcri~l

16%
1.4%
37.6%

45.0%

viol)
(0

A vinyl copolymrf
aluminum ah.
air-drying trp of
coating nut&l

10%

Welding

Society,

Inc.)

Same *I

638

Corrosion

TABLE 5.5:

Resistant

Materials

ALUMINUM-ZINC

Handbook

COATING-BETHLEHEM

STEEL

GALVALUME

is the trade name for a patented


sheet steel product
having a coating of corrosion-resistant
aluminumzinc alloy applied by a continuous
hot dipping
process. The alloy coating of aluminum
and zinc combines the best
properties
of both metals. It has the corrosion
resistance, high-temperature
oxidation
resistance, and heat reflectivity
characteristic
of aluminum
coatings,
with the formability
and galvanic protection
of cut edges characteristic
of zinc
coatings.
GALVALUME
sheet, both bare and painted,
is intended
for applications
where superior
corrosion
resistance is required,
as in roofing,
siding, pre-engineered
buildings,
appliances,
air conditioner
housings, and other uses.
GALVALUME
sheet is also used for applications
where resistance to oxidation
at elevated temperatures
is important, such as fireplaces,
toasters and automotive
exhaust systems.
Atmospheric
Corrosion
Resistance:
Based on 13-year
atmospheric
test results (see Figure I), it is estimated
that
GALVALUME
sheet will outlast
galvanized
by two to four times in marine, industrial
and rural atmospheres.
When
compared
to aluminum
coated sheet steel, GALVALUME
sheet has superior corrosion
resistance at sheared edges.
Salt Spray Corrosion
Resistance:
With cut edges protected,
the coating
on GALVALUME
sheet steel lasts five to
ten times longer than the coating
on galvanized
(see Figure 2). In salt spray tests conducted
with bare cut edges
exposed, the corrosion
resistance is typically
three to four times that of galvanized
(see Figure 2).

HOURS

OF EXPOSURE

TO

FIRST SIGNIFICANT
RUST
ASTM B117 Salt Fog Test

CORROSION
AFTER

LOSSES

OF GALVALUME

13 YEARS
(AVERAGE

CORROSION
LOSS (Mils)

0.1

EXPOSURE

AND

0.3

SHEETS

IN THE ATMOSPHERE.

TOP & BOTTOM

0.2

GALVANIZED

SURFACES)

GALVANIZED

0.4

0.5_

0.6

0.7

0.8

0.9

GALVALUME

KURE BEACH
(Sev;F_eTMalaye)

!OOO

KURE BEACH
(Marine)
800 FT LOT

BETHLEHEM
(Industrial)

SAYLORSBURG
(Rural)
Figure
Firat

1
Rust, 4 Years

l*Flnrt Rust, 10 Years

GNPR~TECTED
EDGES
Figure

PROTECTEI
EDGES
2

TABLE

5.6:

BERYLLIUM

COPPER

ALLOY-BRUSH

WELLMAN

Beryllium
copper
is the material
of choice in an array of designs demanding
corrosion
resistance.
From instrument
springs and bellows
exposed
to hostile
atmospheres,
to bushings and tubular
products
used in harsh oil field environments, beryllium
copper alloys are selected to solve corrosion
problems.
In combination
with corrosion
resistance, beryllium
copper alloys are considered
nonmagnetic and offer high electrical and thermal conductivity
with high strength.
BRUSH
ALLOY
25, a heat-treatable
beryllium
copper product
contains
1.80 to
2.00% beryllium.
BRUSH
ALLOY
25 is resistant to hydrogen
embrittlement,
and not susceptible
to either sulfide stress cracking
or chloride
stress cracking.
Moreover,
in marine
and certain
industrial
environments
this alloy
outperforms stainless steel, titanium,
and most copper based alloys. Beryllium
copper
is available
in a wide range of forms, including
strip, tube, rod, bar, extrusions,
casting and master alloy, and forging billet.

Corrosion Rorirtanco of Soryllium Copper in Soa Water

=
TEST
MEDIA

Acceptable
Atmosphere

Water

Gas (dry)

Organic
Compounds

Inorganic
Chemicals

-_
,

32-70

-.
Interrupted
alternate
immersior
in sea
water

i.91

-_
96 hours

-_ --

S~,Fg.~

7 weeks

2.36 in.

Not Recommended

S:;9,l.~39

Ammonium Hydroxide
Oxidizino acids/salts
chromic acid
nitric acid
ferric chloride
Mercury

2.5

2.0
2.2

O.CiUX
0.0034

3.5

2.2
2.3

O.WO4
O.OtW4

3 weeks

0
1.5

3.5

--

--

*Corrosion can be affected by temperature. concentration, velocity, and


the presence of other chemicals.

c,;as3;3~4

15 days
Y:%

0.394 in.

.- -Artificial
sea water

Strip

::3
9.96

::EZ

2.6
2.8

o.ooo5
O.GlXX

= in/yr

..

Electrolytic
copper.
H (cold rolled).
A quenched from 1480 F)
A 4 (quenched
from 14UJ
F and aged 3 hr. at 570 F)

..

2.P,

0.0005

2.8

__. _. ._.

_-Ascast,...........,....

I168 hours

= =

lmdd = mgldmlday;ipy

--

cast _,__.
cast..
cast..
cast..

::EE%

:::

--_
112.1
Annealed
H hr. at 1020 F
A (quenched from 1510 F)
;;U&
AT (quenched
from 1510
F and awl 3 hr. at 660 F)
100.2
A (quenched from 1510 F)
78.4
AT (wenched
from 1510
F and aged 3 hr. at 660 F)
150.7
A (quenched from 1510 F)
154.9
AT (quenched from 1510
F and aged 3 hr. at 660 F)
42.9
A (quenched from 1510 F)
AT (quenched
from 1510
51.5
F and aged 3 hr. at 660 F)

As
As
As
As

-I- 0.0035

;::

_-

2.36 in.

68

3.3

Annealed % hr. at 1020 F


A (quenched from 1510 F)
AT (quenched
from 1510
F and ared 3 hr. at 660 F)
A (quenched from 1510 F)
AT (quenched
from 1510
F and aged 3 hr. at 660 F)
A (quenched from 1510 F)
AT (quenched from 1510
F and aged 3 hr. at 660 F)
AT (quenched
from 1510
F and aged 3 hr. at 660 F)

2.5

Artiticial
sea water

3.9
7.8

irIG&

3.5
yyg.39

0.0037
0.0034
o.OOQ7
0.0014

2.3
4.3
3.4

2.0

Non-Oxidizinq Acids
acetic acid
hydrochloric acid
dilute sulfuric acid
phosphoric acid
Alkalies

O.WJ4

0
2.0

2.5

Pyridine

2.3

EE:

--

2.0

Alcohols
Chlorinated Solvents
Fuels
Lubricating/Hydraulic oils

0.0009
OSXW

-.

0
1.5

Acetylene

IPY

5.6
2.3

--

3 weeks

2.36 in.

Room

-I-

0
1.89
2.74
2.99

-_

3% NaCl
solution
saturated
with CuCl

mdd

96 hours

-_

Fresh
Brine
Softened
Sewage
Soil

-I-

-_

140

113

Ccmdltlon and
Heat Treatment
Phosphorus
deoxidized
copper................
AT (quenched from 1470
and ased 3 hr at 570 F)
HT (quenched from 1470
F. cold rolled and aged
2 hr. at 525 F)

Z*i%

Industrial
Marine
Rural

Chlorine
Oxygen/Ozone
Carbon Dioxide
Sulfur Dioxide
Ammonia
Fuel Gases

R
-_

CORROFON

n
-.

59

GUIDE TO ROOM TEMPERATURE USE OF BERYLLIUM COPPER*

zzz?

--

-I-

0.0180
%E:
I::;::
::k%
::E%

_- -/0.0052
F
/
/K%!
,
2
,X:EE
4
_t
16.9
15.7
fQ:Z

IE27
I3.0035

IKQ28

(continued)

TABLE 5.6:

BERYLLIUM

COPPER ALLOY-BRUSH

Effect of Immorslon in Bulfurir Acid on 2%

=-

WELLMAN

Alternatr
immerr;ion
in 10%
solution.
1% min. in
solution
and 1%
min.inair
-Interrupted
alternate
immersion
in IO%
solution
____
CntinUUs
immersion
in 10%
solution
~-Continuous
immersion
in 5% WI.
iuric acid

YE:
F.

__

Spedmen

_---

1Durntlon
0

_.

_~

96 hours

0
1.89

hotaaed...............

2.05

As

---

C~;;~;43;4

24 hours

_.-.

24 hours

Strip

_.---

Interrupted
alternate
immersion
$O%

140

O.Oli4

Cntinus
immersion
i; F3l%

Rwm

1240
1148

Strip

in

6 hours

2.1

24 hours

2.1

_.

-5% sulfuric
acid + 3%
potassium
dtchromatf c

_.

= =

Duratiot
0

sp&o;u
8 in.

2.0

--__
96 hours

24
27

Ip;O3I

9
2.0

7 days
___
2 days

2.36 in.

2.0

0.0054

2.5
-____
Continuous
immersion
i; &%

Room

-_
Strip. 0.039
x 1.18 x
2.36 in.

2.1
2.1

Same..

Same.,

_.

._.

. ..

_.

192340
18.600

~7 days

2.0

2.5

3.46
3.24
Continuous
immersion

6s

ht.

0.394

mdd

Phosphorus
deoxidized
copper
AT (quenched
from 1470
F and aged 3 hr. at 570 F)
HT fquenched
from 14iO
F. cold rolled. and aged
2 hr. at 525 F)
_______~

0
1.89

0.0952
o.wl4
0.0642
0.0047
-_-_

negligiljie
31

yipi

-_

mdd = mg/dmz/day;

0.073

332

0.058

332

0.058

147
182

0.024
0.03

-___

~-_______
Annealed..
1079
588
Annealed..
~-~~
-__
A fquenched
from 1470 F)
AT fwenched
from 1470
z:
F and aged at 660 F)
~______~_
A (quenched
from 1470 F)
AT (quenched
from 1470
2
F and aged at 660 F)
~__
____-A (quenched
from 1476 F)
402
656
AT (wenched
from 1470
F and aged at 660 F)
A fquenched
from 1470 F)
AT (quenched
from 1470
F and aged at 660 F)

2.05

As cast.

24 hours

2.05

As cnst..

IPY

-.

453

_~

Not aged..

__24 hours

x 0.394 x

0.174
0.099
0.110
0.123

0.070
0.115
--

36U
585

Z:Z

50

0.009

90

0.016

a.94 in.
iPY

;;,I%

= in/Vr

.-

Continuous
immersion
;;&O%
Continuous
immersion

(Lossin mdd)

I
CONDITIONS

Continuous
immersion
for 24 hours et 68 F
on cast specimens
(not age hardened)

5.05
2.05
9.96
Continuous
immersion
for 24 hours at
room temperature
on strip specimens
a, iollows:
Electrolytictopper..
Beryllium
copper:
H (cold rolled).
_. .
A (quenched
from 1480 F).
AT fguenched
from 1480 F)
andaged3hr.at570F)
..,__.__.,

_.

____-

Rnt

24 hours

1%

2.5%

4%

Fz
+?
g

......

:;
118

__
__5%--139
130
I21

7.5%

0
2.12

10.6
7.7

......

11.6

.
.

.
.

0.010
0.007

::
45

kX

Content In Varying Concentrations of Acetic Acid


(Lossin mdd)

::
30

.M

Electrolytic
copper.
H (cold rolled).
(quenched
from 1480 F)
AT (quenched
from 1480
F and aged 3 hr. at 570 F)

ipy = infyr

Infiue~nce of Beryllium

9.4

......
......

lmdd = mg/dm?day;

:::

____--E

16%

_.

__~__~

_-

itnp

z=zzz=z

CONCEhTRATION

I
content. --0.49
1.00

--~
3art. 0.394
x 0.394 x
3.94 in.

Zy.5%

Bervllium
Percent

68

.-

In~uonco of Bwyllium Contw~tin Varying Concantratlonsof Sodium Hydroxide

TEBT

Spedmen

--

Gmdltlon
and
Heat Treatment

-6 hours
24 hours

Strip

Room

ir:

COR&$l,ON

____
IO0

Electrolytic
copper..
H (cold rolled).
A (quenched
from 1480 F)
AT (quenched from 1480F
and aged 3 hr. at 570 F)
---~
Apparentiv
rolled. annealed and nged
Same..................

.-

0.199
0.19x

0.852

0
2.12

__

70.75

4840

cast..

_.___-.
Room

T:::TF
Alternate
immersion
1% min.
in solution
and I%
min. in
air in
10% HCI

0.609
0.X92

3.94 in.

immcrciun

bY

mm
.5 i 1J

~_~

____

strip

_~
68

AT

ture.

-_1

mdd

Phosphorus
deoxidized
copper.
(quenched
from 14iO
F and aged 3 hr. at 570 F)
IIT (quenchrd
from 14iO
F. cold rolled and aged
2 hr. at 525 F)

2.0

R in.

140

__

Condltlon
and
lieat
Treatment

S:~ip&Ox~

146

_.

Tempera-

coRp;l,,tN

COntiiWUS

10%
solution

Beryllium Copper

_.

----

Effect of Immersion in Hydrochloric on 2%

Beryllium Copper

TemTYPE
OF
TEST

(continued)

TEST CONDITIONS

?zcY
Percent

CONCEhTRATlON

~lz.s46I5.ow(~/~

.
I

(continued)

TABLE 5.6:

BERYLLIUM

COPPER ALLOY-BRUSH

WELLMAN

(continued)
hfluenca

of Beryllium Content in Varying Concentrarionr of Nitric Acid


(Loss in mdd)

TEST
InRuonca

of Bwylllum Content In VaryIns Concontrotlonr of

TEST

CONDITIONS*

Continuous
on cast

immrrsion
specimens

lI%l2.5%1

pzz::v

CONCENTRATION

-__

._

for 24 hours at 68 F
(not age hardened)

5.5%
-.

..
-Continuous
immersion
for 24 hours
at
r~)m temperatwe
n strip specimens
as
follows:J~
Electrolytic
copper..
Beryllium
copper:
H (cold rolled).
(Quenched
from 1480 F).
AT (quenched
from 1480 F and
aged 3 hr. at 570 F).

..

i:t;

..,

2.!2

5%

-.
-_--2.5% I

immersion
for 18 days
at ro0m temperature
on strip
specimens.
0.039 x 1.18 x 2.36 in..
in annealed
condition

__7.5%

1070 S
12
Sn
14 0 n Sn

I 10%

E
ii

88
%
:::
62

_-

1%

Continuous

Ammonium Hydroxide
(Less in mdd)
( I+rylllum

CONDITIONS

_-

-~

_.

. .
...
__..

-~
-.

_.

3
-.

_-

...
...
...
...

Continuous
immersion
for 24 hours
at 68 F on drawn specimens,
0.32
in. diam. x 0.60 in. long (not age
hardened)

170

100% cu
2.3% Be
10% Al

312
269
w5
2.53
Ii7
251
215
2.53
I89
lR4
226

..

-.

Rates in Phosphoric Acid and Vapor

Beryllium
Copper..
(2.02 Be, 0.21
Phos
hor Bronze-C.
(88
Sn).
.

Ni) .
.

.
.

mdd
iPY
mdd
ipY

Aluminum
Bronze
(57
Al).
High bass..
(35% Zn).
Cupro-Nickel..
(20% Ni. 5% Zn).

........

Silicon
Bronze
(3.19,
Si. 1.1% Mn)
Monel,
..............
(2.9%
Cu). ........
Mild Steel
(0.24%
C). ........

...........

_. . .

. .
..,

*E&l :::

4o:oca
__-

__
1070
3%

._

____

..,

...
...
...
...
...
...
...
...
...
...
...
...
.
. ..
-__
...
..,
.
..,
. ..
Ii0
1.50
r
2&L
94:500

210
110
120
31.5w
94x+

750
1210
11.580

1%
11.050

--.-_
.

--

1695
I681
li48
1928

.
. .

.
..,

5-95s HaPO 1
con~t&h;;g a1
Amount of
FlUO~lll~
Compounds
At 165-185F

Elemental

Phoephorue
in Store&z
At 149-158F

uanmy of
RMist
3PoI 88 P
and

Traces of
Fluorine
Compounds
At 185-212F

_-

12.6
0.0022
11.1

3368
0.5900
4950

O.b>

0.z8
0.0009

$jt$?
0.65&

515
o.OBo

0.1120

25.9
i?
O.CQ28
mdd
iPY
mdd
iPY
mdd
ipY

Phc phoric Acld

>uantlties of
FlUOlill~
Corn unds
in a c ist of
HsPOd
At 212-239F

Units

Itaining

5-95s HaPO
(~PPka)
ytt&y

HsPO
(DrqbpPW

D-80

MATERIAL TESTED

..
. .

_-

,.,
. .
.

10%

zz==z=crz

Corrosion

_.

270
370
8530

3:g

Continuous
immersion
for 24 hours
at room
temperature
on strip
specimens
as follows:
Electrolytic
copper..
Beryllium
copper:
H (cold rolled).
A (quenched
from 1480 F)
AT (quenched
from 1480 F
and aged 3 hr. at 570 F).

.__5%

3%

120
Jo

Continuous
immersion
for 24 hours
at 68 F on cast specimens
(not age
hardened)

...
...
...
...

CONCENTRATION

29.7
i??
.?O=
0.0310

+i

36.5

6.8

0izz4
0.0084
136.8
0.0220

+z312
0.0011
7.5
0.0012

118
0.0203
43.2
0.0070

4.1
0.0007
5.6
O.ooo9

32.7
0.0055
86.1
0.0140
45.500
8.3100

7.1
0.0012
4.9

263
0.0460
538
O.&z0
0.0640
1709
0.3000
318
0.0540

1451
0.2550

O.b%
48.4
o.Oa!30

0.980
4375
O.T100

O.bzO
148
0.0240

41.6
0.0070
369
0.0600
Excessive
Excessive

416
O.OioO

32.1
0.0054

...

yg$
.-2
3.422

O.gl
O.&l40
o.?zo
O.%O

o.zo

O.K?!O
274
O&45
197
0.0360

i??
0.0040
--

(continued)

642

Corrosion Resistant Materials Handbook

TABLE 5.6:

BERYLLIUM

COPPER ALLOY-BRUSH

Corrosion

WELLMAN

Resistance of Beryllium

(continued)

Copper

Summarized

Approximate Service Ratings (see note)


Good
Acetic acid, 0.1% (RT)
Alcohols
Alum
Ammonia, dry
Atmosphere,
rural
marine
industrial
Boric acid
Brines
Bromine, dry
Calcium chloride
Carbon dioxide, dry or moist
Carbon tetrachloride
Chloride, dry
Citric acid
Fluorine, dry
Freon
Fresh water
Gasoline
I Iydrocarbons
II,,,,,,n sulfide, dry
Mercury (RT-200 F)
Oxalic acid
Phosphorus
(150 F)
Potassium.
molten (up to 1112 F)
Sea water (RT)
Sodium chloride
Sodium, molten (up to 1112 F)
Sodium-potassium
alloys,
molten (up to 1112 F)
Steam
Sulfur dioxide, dry
Tannic acid
Trichlorethylene

Limited

Poor

Acetic acid, 2.5-10%


(RT)
Bromine, moist (RT)
Chlorine, moist (RT)
Fluorine, moist (RT)
Hydrochloric
acid, O-5$& (RT)
Mercury (200-700 F)
Mine water
Phosphoric acid, 3-95% (RT-212
Sea water (140 F)
Sodium chloride, 3y0 + copper
chloride
Sodium hydroxide,
l-10%
(RT)
Sulfur dioxide, moist
Sulfuric acid, O-10% (RT)
Zinc, molten

F)

Aluminum,
molten
Ammonia,
m.oist
Ammonium
hydroxide
Bismuth, molten
Bismuth-lead
eutectic, molten
Bromine, moist (ET)
Cadmium, molten
Chlorine. m_o_ist(ET)
Chromic acid
Ferric chloride
Fluorine, moist (ET)
Gallium, molten
Hydrochloric
acid, 10% (140 F)
Hydrochloric
acid, over 5y0 (RT)
Hydrogen sulfide, moist
Indium, molten
Lead, molten
Lithium. molten
Nitric acid
Sulfuric acid, 10% (140 F)
Sulfuric acid, 5% + potassium
dichromate,
3%
Thallium
molten
Tin, molten

RT-room

temperature
ET-elevated
temperature
These ratings, based upon laboratory
and field tests. are offered
only as a guide. since corrosion
rates are affected by agitation,
temperature,
aeration,
concentrations,
etc.
Ratings
based upon
laboratory
tests have the following significance:

Note:

Rating

Rate of attack, ipy

G_ood

less than 0.001


0.001 to 0.010
more than 0.010

zzed
-

CHEMICAL

COMPOSITION

Nonferrous

TABLE

5.7:

COBALT-BASE

ALLOYS-CABOT

STELLITE
Nominal

Cobalt-Base

Alloys

Co-0-W-C

Type

Chemical

Forms

Cr

Composition,
Ni

STELLITE

allov No. 1

A&F

30

12

2.5

STELLITE

alloy No. 4

33

14

1.0

STELLITE

alloy No. 6

All

28

1.1

STELLITE

alloy No. 12

All

29

1.3

STELLITE

alloy No. 20

AS

32

17

2.5

Co-Cr-WiMo-NilFe-C

643

Metals and Alloys

MO

Weight Percent
Fe

Si

Others

Type

STELLITE

alloy No. 21

A,B,C,F,G

27

0.2

STELLITE

allov No. 238

26

0.1

STELLITE

alloy No. 306

25

STELLITE

alloy No. 694

28

STELLITE

alloy No. 2006

A,BS

STELLITE

alloy No. 2012

STELLITE

alloy F

1.5

2.8

5
3

20

0.5

0.9

31

1.3

18

A,B,F

33

1.7

10

15

1.5

AS

25

2.0

22

19

12

5Nb, 1Mn
1v

Code:
A-Bare

Cast Rod

B-Covered

Comparative

Electrodes

Corrosion

C-Tube

Wire-(Sub-Arc)

D-Tube

Wire-(Open

Arc)

E-Tube
Wire (Gas Metal Arc)
F-Powder

G-Solid

Wire

Data*

Gas Tungsten Arc Deposits


Media

Alloy

Concentration
and
Temperature

Acetic
Acid

Formic
Acid

Nitric
Acid

Phosphoric
Acid

Sulfuric
Acid

30%
Boiling

80%
Boiling

65%,15OF
(66%)

50%,15OF
(66%)

5%,15OF
(66%)

STELLITE alloy No. 1

STELLITE alloy No. 4

STELLITE alloy No. 6

STELLITE alloy No. 12

STELLITE alloy No. 20

STELLITE alloy No. 21

STELLITE alloy No. 238

STELLITE alloy No. 694

STELLITE alloy No. 2006

STELLITE alloy No. 2012


STELLITE alloy F

STELLITE alloy No. 306

Five 24-hr. test periods. Determined in


laboratory tests. It is recommended that
samples be tested under actual plant
conditions.

Code:
E-Less
G-5

than 5 mpy (~0.13 mm/y)

mpy (0.13 mm/y) to 20 mpy (0.51 mm/y)

S-Over

20 mpy (>0.51 mm/y) to 50 mpy (1.27 mm/y)

U-More

than 50 mpy (11.27 mm/y)

644

Corrosion Resistant Materials Handbook

TABLE

5.8:

HAYNES
excellent

COBALT-BASE

ALLOY-CABOT

WROUGHT

PRODUCTS

alloy No. 25 is a cobalt-base alloy which combines


high-temperature
properties to 1900F (1038C).
CORROSION

RESISTANCE

good formability,

OF HAYNES

ALLOY

wear and corrosion

resistance with

NO. 25

All results are expressed in mils (mm) penetration


per year. Acid strengths are given in percent by
weight. In some instances, no measurable penetration could be observed. These instances are noted by
the word. Nil. All data are steadv-state as calculated from a minimum of five 24 hr test oeriods.
TYPICAL PENETRATION
RATES IN CORROSIVE MEDIA, Mlla (mm) Per Year

I
Room
15Odeg F
(66 deg. Cl
Bolllng

ACETIC
ACID

I
10%

50%

w%

Nil

NII

Nil

NII

NII

NII

,<?&

CHROMIC ACID

12%

Ilo%

20%

Nil

Nil

N8

Iml

Nil

,oP,,

FORMIC ACID

(0%)

!a%

IwYaI

,<%I,

Ntl

(cool)

I 2% I Se&I

l - I -

I -

Nil

0.1
,<O.Ol)

1%

2%

0.1
(CO.01)

0.1
(<O.Ol)

15Odeg F
(65 aw C)

NII

0.1
(C 0.01)

Nil

10%

0.5
(COO2)

6%
(02461,

I lx&

I -

0.1
(cool)

(059,

ZxCl

NII

ACID
2on

25%

37%

(02564,

,&,

6.0
(0.15)

(4oS0,

,0.05,

13.3% MNO, (tyehl)

CH:%.4E

15%

552
(14.0)

1 -

Nil

10%

NII

10%

HVDRDCHLDRIC
ll.&HC;,

&I,

NII

5c&I

NII

474
(12.0)

80%

FERRIC CHLORIDE

HVDRDCHLDRIC

Room

,<%I,

N,I

I 2%
I
I
I
I,AodTo,I
I - I NilI - I - I N

lQr&I

I Nil

Boiling

0%

(0%
CUPRIC CHLORIDE

166decl Cl

(<oobl,

Nil

(<%l,

150 dep. F

40%

266
I6 61)

66
(1731

,;z,

(<OOlOl
,
-

NITRIC ACID MIXTURES


15.2%_;2,+

17.2% HNOI (b&w~ht)

16Odeg F
(71 deg Cl

(0%)

19Odeg F
Wdeg
3
NITRIC ACID
10%

30%

1ow

lQlc

50%

ROOfll

Nil

Nil

NII

Nil

Nil

Nil

150 deg. F
(66 deQ. C)

Nil

NII

0.3
,<O.Ol)

0.5
(CO.02)

0.6
(0.02)

2.0
(0.05)

2.0
w5)

4.0
(0.10)

9.0
(0.23)

0.5
(CO.02)

Soiling

PHOSPHORIC

5m

$6,
HVDROFLUORIC

SULFURIC ACID

56%

7&
NII

,:.:7,

Nonferrous

TABLE 5.9:

COBALT-BASE

ALLOYS-WALL

Corrosive

RESISTANCE

Wallex No. 1 and Wallex No. 6, containing chromium


and tungsten, are virtually unaffected by the most
commonly used corrosive chemicals, and by atmospheric corrosion. Wallex Nos. 40 and 50, containing
chromium and tungsten, but also nickel and boron,
are slightly less corrosion-resistant,
but have the
advantage that they can be produced in powder form
for ease and efficiency of application,
using the
Colmonoy Spraywelder gun (or Fusewelder torch).

OF WALLEX

Concen-

Media

ALLOYS

PENETRATION

tration

Temp.

Acetic
Acid

10%
10%
50%
50%
50%

RT
Boil
FIT
15OF
Boil

Nil
Nil
0.2
0.2
2.0

Chromic
Acid

10%
10%
10%

RTo
150 F
Boil

Nil
1.0
Hiqh

Wallex No. 1

IN VARIOUS
RATE:

Wallex No. 6
Nil

MEDIA

Mils per year


Wallex 40 & 50

Nil
0.2
0.2
0.4

Nil
Nil
NR
1.0
NR

Nit
28.0
Hiqh

Nil
NR
NR

Chlorinated
Water

Sat.

RT

Nil

High

NR

Cupric
Chloride

2%
10%
10%

RT
RT
Boil

2.0
0.5
High

0.7
0.5.
Hiqh

Nil
NR
NR

Ferric
Chloride

2%
10%
10%

RT
RT
Boil

3.0
1.0
Hiqh

2.0
6.0
Hiqh

Nil
NR
NR

Nil
Nil

0.5

Nil
NR

Ferric
Sulphate

Hydrochloric
Acid

Nitric
Acid

Phosphoric
Acid

10%
10%
2%
2%
10%
10%
20%
Cont.

RT
Boil
RTo
150 F
RT
Boil
RT
Boil

10%
10%
40%
Cont.
Cont.
10%
10%
10%
40%

9.0
169.0
10.0
High
26.0
High

1.0
0.1
120.0
9.0
High
16.0
Hish

RT
Boil
RT
RT
Boil

Nil
0.1
0.1
0.2
Hiqh

Nil
Nil
Nil
0.1
High

3.0
NR
NR
NR
NR

RTo
150 F
Boil
Boil

Nil
0.2
0.6
High

Nil
Nil
Nil
0.1

Nil
Nil
63.0
NR
Nil

39.0
NR
NR
NR
NR
NR

Sodium

5%

Boil

10%

Boil

0.5
Hiqh

Nil

Hvdroxide

2.0

NR

2%

RT

0.1

0.1

157.0

2%
Sulfuric
Acid

NOTES:

645

COLMONOY

The name Wallex designates a line of cobalt-base


hard-surfacing
alloys. All of them resist corrosion
well, but they vary in their ability to resist abrasion
and impact, and in the way they can be applied.
Wallex alloys would seldom be recommended
for
protection
against corrosion alone. In most cases,
they are chosen for their ability to fight the twin
hazards of corrosion and abrasion. The specific alloy
choice depends on a careful analysis of the extent of
the problem presented by each hazard.
CORROSION

Metals and Alloys

150F

23.0

Nil

NR

10%

RT

Nil

Nil

NR

10%

Boil

High

High

NR

5096

RT

0.2

0.1

NR

90%

RT

0.3

Nil

NR

NR means either
Not
Recommended
or loot I?arsd (i.e. unknown).
RT means Room
Temperature.
Generally,
a corrosion
rate greater than 3.0 mils per year should call
for caution.
Whenever
possible, it is advisable to make individual
tests on specific
applications.

646

Corrosion

TABLE 5.10:

Resistant

Materials

Handbook

COLUMBIUM-CABOT

KBI
Corrosion

Resistance

of Columbium
S = normally

no attack

V = variable, depending

on purity

X = not resistant
Columbium
has good resistance to
many corrosive
media, such as sulfuric, nitric, and hydrochloric
acids,
within certain defined limits. The
accompanying
table summarizes
corrosion resistance of the metal.
The following
tests have been conducted with reagent grade chemicals,
actual field testing could differ
because of impurities.
Field testing is
htghly recommended.

Gases
Air
230 C (446 F) Reaction begins
388C (730 F) Accelerated
reaction begins
Nitrogen
300C (572OF) Reaction

begins

Hydrogen
204 C (400 F) Reaction

begins

Fluorine
Attacked
Chlorine
200 C (392 F) Reaction begins
Steam
399 C (750 F) Fair resistance
Metals -

molten

Lithium, magnesium, potassium,


982 C (1800 F) maximum
Aluminum
Attacked
Lead

sodium

Chemical

66F

Bismuth
538C (lOOO F) maximum

Temperature
20C 60C 1OOC
66 F 140 F 212 F

140F 212F

Acetic acid (10%)


Acetic acid
(Glac. and anh.)
Acetone
Acetylene
Alcohols (most)
Aliphatic esters
Aliphatic halogen
compoundschloroform
Alum
Aluminum chloride
Ammonia anhydrous
Ammonium chloride
Amyl acetate and
chloride
Aniline and
compounds
Aqua regia

S
S
S
S

S
S
S
S

S
S
S
S

S
S
S
S
S

S
S
S
S
S

S
S
S
S
S

S
V

S
X

S
X

Benzoic acid
Boric acid
Brines, saturated
Bromine, moist

S
S
S
S

S
S
S
S

S
S
S
V

Calcium chloride
Carbon disulfide
Carbonic acid
Chlorine, dry
Chlorine, wet
Chlorides of Na,
K. Mg
Chromic acid (80%)
Citric acid
Copper salts (most)
Cyclohexane

S
S
S
S
S

S
S
S
S
S

S
S
S
S
S

S
S
S
S
S

S
i
S
S

S
V
S
S
S

Detergent, synthetic

Emulsifiers
Ether

X
S

X
S

X
S

Fatty acids (C=C6)


Ferric chloride
Ferric sulfate
Fluorine
Formaldehyde
Formic acid

S
S
S
X
S

S
S
S

Glycerine
Glycols

S
S

S
S

Hexamine
Hydrochloric acid
(10%)
Hydrochloric acid
(cont.)
Hydrofluoric acid
Hydrogen peroxide
Hydrogen sulfide

V
X
V
S

X
X
X
S

X
X
X
S

Ketones

849C (156OF) maximum


Mercury
599C (111OF) maximum

Chemical
Temperature
2OC 60C 100C

S
S
ii

:
S

Lactic acid (100%)

Maleic acid
Mercuric chloride

S
V

Naphthalene
Nickel salts
Nitric acid (25%)
Nitric acid (50%)
Nitric acid (95%)

S
S
S
S
V

S
S
S
S
V

S
S
S
V
X

Oils, essential
Oils, mineral
Oils, vegetable and
animal
Oxalic acid
Oxygen

S
S

S
S

S
S

S
X
S

S
X
S

S
X
V

Perchloric acid
Phenol
Phosphoric acid
(25%)
Phosphoric acid
(50%)
Phosphoric acid
(95%)
Potassium hydroxide
Pyridine and
compounds

S
S

S
S

S
S

V
X

V
X

X
X

Seawater
Silicic acid
Silver nitrate
Sodium carbonate
Sodium hydroxide
Sodium hyprochlorite
Sodium silicate
Sodium sulfide
Starch
Sugar and syrups
Sulfates of Na, K,
Mg, Ca
Sulfites of Na. K,
Mg, Ca
Sulfonic acids
Sulfur
Sulfur dioxide, dry
Sulfur dioxide, wet
Sulfur trioxide
Sulfuric acid (20%)
Sulfuric acid (50%)
Sulfuric acid (70%)
Sulfuric acid (95%)

S
S
S
S
X
X
X
S
S
S

S
S
S
S
X
X
X
S
S
S

S
S
S
S
X
X
X
S
S
S

S
S
S
S
S
X
S
V
V
X

S
S
S
S
S
X
S
X
X
X

S
S
S
S
V
X
S
X
X
X

Tallow
Tannic acid (10%)
Tartaric acid

S
S
S

S
S
S

S
S
S

Vinegar

Yeast

Zinc chloride

Nonferrous

TABLE 5.11:

COLUMBIUM-TELEDYNE
Corrosion

Metals and Alloys

WAH CHANG ALBANY


Data for Columbium

in Aqueous

Media

Concentralion
(Weight %)

Temperature
(C)

Corrosion Rate
mm/y Ww) 4

15
15
30
30
30
37
37
37%
10%
10%
10%

bolltng
RT-60
100
35
60
100
RT
60
60
bolllng
bolllng
bollmg

fill
nil
0.025 (1 0)
0 025 (1 .O)
0 05 (2 0)
0 125 (50)
0 025 (1 0)
0 25 (10)
0 5 (20)
0 025 (1 0)
0 125 (501
0 05 (2 0)

RT
250
bollfng
RT
66
100
bolllng
66
botlmg
RT
RT
bowling
bolllng
boiling
boilmg
bolltng
bolllng
bollmg
50-60
boiling

nil
0 025 (1 0)
0 5 (20)
0.0025 (0 1)
0 05 (2 0)
0.125 (5 0)
3 75 (150)
0 025 (1 .O)
0.25 (10)
nil
Embrlltle
0.125 (5.0)
0.25 (10)
0 5 (20)
0 25 (10)
1.25 (50)
0.5 (20)
0 25 (10)
nil
0 25 (10)

5-99 7
10
37
10
1 O-65
10
20
50
99

boiling
boiling
b&ng
bolllng
b&ng
balling
RT-bolllng
bollfng
bolll!lQ

n1i
0 025 (1 0)
00025(01)
nil
0 025 (1 0)
1.25 (50)
nil
I-III
nil

l-40
l-10
5-40
1-5

RT
96
RT
kz

0 125 (5.0)
Embrlttle
Embrlttle
Embrlttle
nil

boiling
botlmg
bolltng
boiltng
boiilng
RT-boiling
boiling
RT
96
RT
bolllIlQ
boiling
RT
boiling
boiltng
50
RT
96
boiling
boiling
bollrIg

0.005 (0.2)
nil
011
IllI
nil
nil
0.0025 (0.1)
0.025 (1 .O)
EmbrIttle
0.025 (1 .O)
0 025 (1 .O)
0.025 (1 .O)
0 025 (1 0)
0 5 (20)
0 125 (5 0)
1.25 (50)
0.025 (1 .O)
Embmtle
0 025 (1 .O)
nil
nil

20
20
92

nil
0 025 (1 .O)
0.125 (5.0)

92

0 125 (5.0)

RT
bolllng

0.025 (1 .O)
0.5 (20)

Solutions
Acid Solutions
Hydrochlonc
Hydrochloric
Hydrochlortc
Hydrochlonc
Hydrochlonc
Hydrochlonc
Hydrochlonc
Hydrochlonc
Hydrochlotlc
Hydrochlonc
Hydrochlonc
Hydrochloric

Acid
Acld
Acid
Acid
Acid
Acid
Acrd
Acid
Acid
Acid
Acid
Acid

Nltrlc Acid
Nllric Acid
Phosphow
Acid
Phosphoric
Actd
Phosphonc
Acid
Phosphoric
Acid
Phosohoric
Actd
Phosbhorlc
Acid
Phosphoric
Acld
Sultur~c Acld
Sulfuric Acid
Sullur~c Acld
Sulfuric Acid
Sultur~c Acid
Sullur~c Acid
Sulfuric Acid
Sulfur!c Acid
Sulfunc
Acid
Sultunc
Acid
Sullur~c Acid

(aerated)
(aerated)
(aerated)
(aerated)
(aerated)

wth
wth
wtth
with
and

Cl,
0 1 % F&I,
0 6% F.&I,
35% FeCI,
2% FeCI,

65
70
60
65
65
65
65
t+/~
with 4% HNO,
40.50%
wth 5 ppm F
5-40
96
10
25
40
40% with 2% FeCI,
60
60% wth 0 l-l% FeCI.
20% with 7% HCI and-100
50% with 20% HNO,
50% with 20% HNO,

ppm

F-

Organic Acid
Acetic Acid
Cttric Acrd
Formaldehyde
Formic Actd
Lactic Acid
Oxalic Acid
Tarlarlc
Acid
Tnchloroacetkc
Tnchloroethylene

Alkaline
NaOH
NaOH
KOH
KOH
NH.OH

Salts
25
25
10
70
40
10

AICI,
AMSO.),
AIKW.),
C&I,
WNO,),
F&I,

saturated
l-10
1 O-20
10
47
saturated

HgCl,
KG&
K&O,
K,PO.
MQCI,
N&l,
Na,CO,
Na,CO,
Na,HSO,
NaOCl
Na,PO.

and

pH = 1

10
10
40
6
5-10
2.5
10

Na,PO.
NH,SO,H
Nti,

30
40-70

ZnCI,
Mlscellanaous

Bromme

liauid

Bromine
Chrome
Solution
Chrome
Solution

vapor

H,O,
Hz01

Plating
Plating

25% 00,.
H,O
17% 00,.
Hz0
30
30

12% H,SO.
2%

Na,.QF.. trace H&O,

647

648

Corrosion Resistant Materials Handbook

TABLE 5.12:

COPPER ALLOYS-REVERE

relative corrosion resistance of common copper alloys to various types of environments


COppW

ALLOV

Aluminum
Bronze
alley
Caeseo

Phosphor
BtVllZ9
llloy
CSlOao

Aluminum

Rod Brass
&l&Yw

Adminlty
$&

c:bxCl so00

BNU
alloy
Cwfoo

SIlkOn

Yuntr
Metal

Bma

&l&Y,

cotqw
Nickel llloye

t&80

CZ

Nlckal
SllvW
C?&ZO

CORROOENT
;r:
!%a

A
A

A
6

B-C
C

A-B
B-C
A-B

A-B
:I:

A-B
B-C
A-B

;:
C

BAC

A-B
B-C

cDD

c;D

::

CED

coD

CAD
D

lrwrgMlc ultr
NeutralBelts
Acid Salts
Abatine 6&s
DxktiringSalts
MercurySsns

A-B
B-C
A-B

A-B
B-C
A-B

A-B
B-C
A-B

?lD

cDD

coD

A-B
B-C
A-B
C-D
D

wide
Mineral
Drgenic

D
A.-B

BFC

B:C

BDC

ADB

*CDD

A-DB

6-DC

i?

::

i?i

I!

w&tynyd#
carboik

lllfw

P stem

compound*

w
Moist

lmmon*
Moist
AmmomumSalts

A=Albys givenan A rating hew a provenhrstoryof excellentperforma~* m these environments.


6=Albys whbh how a provenhistoryof goodconosbn resistancein the specific
snviroomant
Tends to dezmnc~ty.
use other alloys.

C=The alby hm fair resistanceto the specMcsnvkonmenl.


D=Tho alby is not w~able for use in thisenvimnment.

approximate composihon. per cent

trade name

alloy
no.

Oxygen Free (OF) n


Srlver SearingA
Red Brass. 85%

form

I Cl0200 I sheet
1tube
I
1Cl1400 1sheet
C23000

Cartndge Brass. 70%

density
lb.
per
cu in

uns

C26ooo

copper
cu

zinc
Zn

99.95 0
9995 0
99.900

fOd

99~0

sheet
tube

650

sheet
rod
tube

70.0
700
70.0

lo-15 oz. srlver per ton

650

hn
Sn

mckel
NI

lead
Pb

silicon
SI

0.323
0 322

150
150

0316

300
30.0

0306

I 300 I
1 40.0 1

I
I

I
I

Muntz Metal.1

C26000

sheet

Admiralty Metal (Arsenical)

c44309

tuba

60.0
71.0

Naval Brass

C46-400

sheet
rod

M).O
60.0

3925
3925

Free Cutting Naval Brass

c46500

rod

60.0

37.5

1.75

0 75

0305

Revalon (Aluminum Brass)

c66700

IUtxs

76.0

220

As005

Al 20

0301

C70600

sheet

Copper-Nickel,

10%

Copper-Nickel.

10%

Copper-Nrckel.

30%

Aluminum Bronze. 5%

1 28.0

As0.05

1.0

0303

I 033.2

0.75
0.75

0304

1c70600 1tube
1C71WO 1 sheet

95.0

95.0

0 Minimum
A Alloy numbersCllrX).
C11500andC11600arealsoavailable. Properties are approximatdy the same as shown
for Alloy Cl 1400.

l
*Leaded

As0.035

Muntz

5.0

Al50

Metal,

Revere

Alloy CS500.

0.40-0.9096 lead for improved machinability,


for plate applications.
n Available as 99.99% copper-Oxygen-Free
GradeAlloyClOlCG.

I
I
containing

is supplied
Electronic

0320
0.295

Nonferrous

TABLE 5.13:

COPPER AND COPPER ALLOYS-ARC0


typlcA1

INDUSTRlAl

METALS,

AMERICAN

Metals and AIIOYS

649

BRASS

USIS 01 COPPER AND COPPER ALLOYS

This section is not intended to cover all uses of copper


and
its alloys but is limited to the listing of a few typical applications where corrosion
res~~~~e
is important.
ROATS

AND SHIFS

BREWERIES

BUILDING

CONSTRUCTION

FIpimR
Brew Lettick
At(caprktd?
cdb
Lmter t.ba
&It .,d,
tmkk

COPPER,
COPPER,
COPPER,
COPPER,
COPPER,

bar.
Fluhinp
Gutters md dowmpodta
Fiinr
for r.ter.
lor-

:z;::
COPPER

>

RED BRASS
EVERDUR
655
CUPRO
NlCKEL.
EVERDUR
655
EVERDUR
655

lo%

705

~OEPDP~~*SS
EJ,,D,$

655,

COPPER,

CUPRO

NICKEL,

COPPER,
COMMERCIAL
BRONZE,
RED
BRASS,
MUNTZ
METAL,
ARCHITECTURAL
BRONZE,
NICKEL
SILVER
BRASS,
BRONZE,
NICKEL
SILVER
COPPER,
COMMERCIAL
BRONZE
DISlILlERIES

GAS

INDUSTRY

011

REFINERIES

OBGANIC

CHEMICALS

Condcnwr and he.,


rhax,Rer take.

pip line.

Coadcmer and he.1


chuSe+r cdkk

Stills

PLANTS

PAPER MILLS

ud

md hut
inks

es-

Waler @pin*
Stock Bnn
Wire kr Fmrdrinitr

mire

and Candrascn

ADMIRALTY

COPPER.

RED

BRASS

a-

eheecu

Winding

ADMIRALTY

COPPER,
ARSENICAL
ADMIRALTY,
CUPRO
NICKEL,
30% 115; 30% 710
LEADED
YUNTZ
METAL
355. NAVAL
BRASS
454. CUPRO
NICKEL,
30% 715.
AMBRALOY
614
COPPER,
EVERDUR
655

.scrnlu

SALT MANUFACTURE

ARSENICAL

ARSENICAL
ADMIRALTY,
CUPRO NICKEL.
SO% 716; 20% 710
AMBRALOY
687. RED BRASS
LEADED
MUNTZ
METAL
365, NAVAL
BRASS
464. CUPRO
NICKEL,
30% 715.
AMBRALOY
530, AMBRALOY
514
EVERDUR
551
MUNTZ
METAL,
NAVAL
BRASS
d64
RED BRASS
RED BRASS

Slotted ,c,ccn pl.trk


Paper mvhinr
roBa of
rkrions kin&
Cylinder rwb

SALINE WATER CONVERSION

BRASS

u-

rvkpomtora

Conden.cr
rhmpr

Tuk.

PULP AND

RED

COPPER
ARSENICAL

TmL. she&a

POWER

COPPER,
Es;:::
COPPER,

ARSENICAL
COPPER,
ARSENICAL
ADMIRALTY,
AMBRALOY
687, CUPRO
NICKEL,
10% 706: 20% 710; 30% 715
LEADED
HUNT2
METAL
365. NAVAL
BRASS
164. ARSENICAL
ADMIRALTY,
CUPRO
NICKEL,
IO% 706: 30% 715
AMBRALOY
614
CUPRO
NICKEL,
IO% 705; 30% ,I5
COPPER,
COPPER,

RED BRASS
EVERDUR
655

BRASS,
PHOSPHOR
BRONZE
PHOSPHOR
BRONZE,
AMBRALOY

612

RED BRASS
PHOSPHOR
BRONZE,
EVERDUR
655
COMMERCIAL
BRONZE
EVERDUR
651, PHOSPHOR
BRONZE

ARSENICAL
ADMIRALTY,
80% 716; 30% 710; 10%
AYBRALOY
687

CUPRO
706,

507

NICKEL,

Tube .hwt.

LEADED
MUNTi!
METAL
365, NAVAL
BRASS
154, ARSENICAL
ADMIRALTY.
CUPRO
NICKEL,
10% 706; 30% 715.
AMBRALOY
614

ShrlL

PHOSPHORIZED
COPPER
133. EVERDUR 655, CUPRO
NICKEL,
IO% 706
MUNTZ
METAL
330, NAVAL
BRASS
4.54.
ARSENICAL
ADMIRALTY,
CUPRO
NICKEL,
10% 706

COPPER,
ARSENICAL
ADMIRALTY,
CUPRO
NICKEL,
30% 715;
20% no;
10% 706

(continued)

650

Corrosion Resistant Materials Handbook

TABLE

5.13:

COPPER

AND COPPER ALLOYS-ARC0


SEWAGE

TREATMENT

METALS,

Piping
Slotted acreem
Electrical conduit
Anchor bolta ..,d
manhok steps
V&e md g.te stems

PLANTS

COPPER,
EVERDUR
EVERDUR

h~poraor

PROCESSING

tube8

COPPER,
RED
ADMIRALTY,

Cklandriu. syrnp
tanks, mire
ClysMizing
pana
Melting t&a
He.1 exchanger tmbw
Heat uchauer
tube mheeta

WATER

CORROSION
A--Th

e.metaI

6 -Qe

COPPER,
COPPER
EVERDUR

RED

COPPER,
EVERDUR

RED
555

piping
Screens md rken~
framea
Anchor bolt. md
m.nhole
nteps
Valve and g.tc stem.

WORKS

should

BRASS

BRASS

under most conditions of use.

with

other

resistance governs

D -1h

than corrosion
offers fair

e metal

is not suitable.

651
630, TOBlN
SlLlCON

CHARTS

iii place of a metal


0 metal

706

651

metal offers good corrosion resistance. It moy

C-lh

ARSENlCAL
NICKEL,
10%

EVERDUR
655. EVERDUR
EVERDUR
655, AMBRALOY
BRONZE
664,.
LEADED
BRASS
697

RATING

be suitable

BRASS,
CUPRO

651
630, TOBlN
SILICON

EVERDUR
666
COPPER
COPPER
ARSENICAL
ADMIRALTY
NAVAL
BRASS
664

piping
Printing rolb
Electrical conduit

TEXTILES

RED BRASS
655
651

EVERDUR
655, EVERDUR
EVERDUR
655, AMBRALOY
BRONZE
4641, LEADED
BRASS
691
EVERDUR
665
EVERDUR
655

Gates and gate fr.mea


Weirs
SUGAR

BRASS (continued)

AMERICAN

on A

corrosion

rating

when

be considered
some property

its use.

resistance.

COPtEKHIGH-ZINC
BRASS

LOW-ZINC
COWER

BRASS
CO*MIRCIAt
IROll2f 220

SPECIAL BRASS

CAPTPIOGf
BRASS 160

TOBIll
wloll2t

655

.,i

AIMBRALO266

1!

l1

6BBBDDDDCC;e
B
A

B
A

B
A

B
A

D
A

D
AA

Acetylene*

Alcohols

Alum

II

Alumina

A
B

A
B

A
B

A
B

Acetone

Aluminum
Aluminum

Chloride
Hydroxide

Aluminum
Ammonia,

Sulfate
absolutely

Ammonia,

moist

Ammonium

Hydroxide

Ammonium

Chloride

Ammonium

Nitrate

Ammonium

Sulfate

dry

Barium

Sulfide

Beer.
Beet Supar

Syrups

A
D

A
D

B
A

A
D

C
A

C
A

B
A

B
A

6
A

B
A

B
A

B
A

B
A

B
A

B
A

B
A

B
A

B
A

A
D

A
D

A
D

A
D

A
D

A
D

A
D

A
D

A
D

A
D

A
D

A
D

D
D
D

D
D
D

D
D

D
D

D
D

D
D

D
D

D
D

D
D

D
D

D
C

D
e

ll

D
D
D

D
B

Hydroxide

Sulfate

Barium

Barium

Carbonate
Chloride

Barium
Barium

Marine
Rural

Atmosphere,
Atmosphere,

Industrial

A
c

:ccccc
A
A

A
A
A

A
A
A

A
A
A

A
A
A

B
B
A

B
B
A

B
B
A

B
B
A

c
A

A
c

C
C

A
A
A

A
A
A

A
A
A

A
A
A

D-

A
A

C
A

:CCBBBBBI
A
A

e
B

D
A

cuno
IIICKtt.
30% 716

ffROUR
651
I

SItVtR
II% 152

B
A

Atmosphere.

630

B
A

Acetate

Asphalt

ICIfL.
109, 706

C
A

Alcohol
Dyes

10) 624

AMBRALO

.tUPRO

NICKEL
SILVER

C
A

Amy1
Aniline

;~wlo

CUPRO
NICKEL

D
A

Amy1

Aniline

SILICON
ALLOYS
CVIRDUR

,6,,

MUllI

230

Acid
Anhydride

ALUMINUM
BRONZE

CRCnlTECTURAL
/ lRSENlCAL
ADMIRALI
(13
BRONZl
385

RED lRASS

Acetic
Acetic

WOSPHOR
BRONZE

c
A

c
A

A
A

A
A

A
A

A
A

A
A

(continued)

Nonferrous

TABLE 5.13:

COPPER AND COPPER ALLOYS-ARC0

LOW-ZINC
BRASS

METALS, AMERICAN

IRASS

SPECIAL BRASS

CARTRIOOE

rznI
COMMEWlAl

PHOS?HOR
IRONZE

HlClLZlNC

BRASS

Metals and Alloys

bntinued
COPPERSILICON
ALLOYS

ALUMINUM
DRONZE

CUPRO
NICKEL

I-

CUIRO

TOIIN

KICKEL.
10% 106

BRASS 260

AKtUTECTURAL
BR0ll2E 3*5

651

ADIiRALTV

443

NICKEL
SILVER
NICKEL

SILVER.
10% 752

cum0
KICK&
30% 115
I

1 1 1
Benrine
A
A
A
A
AAAABBBBAAAA
Benzoic Acid
Ben1ol
A
A
A
A
block Liquor. Sulfate ProcessC
C
C
C
Bleaching Powder. Wet
B
B
B
B
BCWtJX

Bordeaux Mixture
Boric Acid
Brines
Bromine, Dry

A
A
A
B
A

A
A
A
B
A

A
A
A
B
A
B
A

A
A
A
8
A

Bromine, Moist
BlMolle
Butyl Alcohol
Butyric Acid
Calcium Bisultite

B
A

B
A

:
B

A
B

Calcium Chloride
Calcium Hydroxide
Calcium Hypochlorite
Cone Sugar Syrups
Carbolic Acid

B
B
B
B
A
A
A
A
B
B
B
B
AAAABBBBAAAA
B
B
B
B

Carbon Dioxide, Dry


Carbon Dioxide, Moist
Carbonated Water
Carbonated Beverages**
carbon Dirulfide

A
A
A
B
B
B
B
8
B
B
B
B
BBBBAAAAAAB:

carbon Tetrachloride, Dry


*
Carbon Tetrochlorida, MoisttB
Castor Oil
A
Chlorine, Dry
Chlorine, Moist
c
_Chloracetic Acid
B
Chloroform, Dry
A
<hromic Acid
D
Cider**
A
Citric Acid**
A

A
B
A
A
c
B
A
D
A
A

B
A
A
:ACCc*C::::
B
I)

A
D
0

A
D
D

A
D
D

A
D
D

A
D
0

A
C
B

A
C
B

A
0
B
D
A

A
B
B
D
A

A
B
B
D
A

A
B
B
C
A

A
A
A
B
A

A
A
A
S
A

D
A
A

D
A
A

D
A

D
A
A

C
A

0-B

D
B
D

D
B
D

D
8
D

C
B
D

B
A
B

A
A
A
c
B

A
A
A
c
B

A
A
A
c
B

A
A
A
B
B

A
A
A
c
8

A
A
A
B
A

A
A
A
A
A

A
A
A
0
A

A
A
A
B
A

A
A
A
B
A

A
A
A
A
A

A
A
A
A
A

A
A
A
A
A

C
A

B
A

B
A

B
A

B
A

B
A

B
A

B
A

B
A
A
A
B

:
B

:
B

r
B

A^
B

A
B

B
A
B

B
A
B

A
A
B

B
A
B
A
B

B
A
B
A
B

B
A
B
A

A
A
B
A
B

A
A
B
A
B

I)

A
A
B
A
B

A
B
B
B

A
c
C
C

A
c
C
C

A
c
C
C

A
c
C
C

A
B
B
B

A
B
B
B

A
B
B
B

A
B
B

A
B
B
B
B

A
B
B
B
B

A
B
B
B
B

A
B
B
B
B

A
8
B
a
B

A
B
B
B
8

A
B
A

A
B
A

A
D
A

A
B
A

A
B
A

A
B
A

A
D
L.

A
D
1

A
D
_

D
1

D
_

A
D
_

A
D
1

A0
A
A

c
B
A
0
A
A

A
B
A
A
c
B
A
0
A
A

A
B
._
A
A
t:
II
AA
D
A
A

o*
D

A
D
A
A
D
D

A
B
A

c
B

A
D
A
A
D
D

A
B
A

:
B

A
D
A
A
D
D

D
A
A

A
A
A
A
B
B
A
D
A
A

A
B
A
A
c
B
A
D

A
D
D
D
8

A
D
D
D
8

A
D
D
D
B

c
8
A

c
B
A

:
c
B
A

A
c
C
B_
A

:
A
B

B
c
A
B

A
D
1

A
D
1
-

c_off.o**
copper Chloride

COPP er

Nitrate
coppu Sulfot.
Corn Oil**

C
B
A

C
B
A

A
D
D
D
0

Cottonseed Oil**
Czr0tO
Crude Oil
E!hars
Ethyl Acetate

AAAABBBBAAAA
A
A
A
A
B
B
B
B
A
A
A
A
A
A
A
A

B
C
A
D

Ethyl Alcohol
Ethyl Chloride
Etitylone Glycol
F&c
_.. Chloride
Ferric
-___ Sulfate

A
A
A
a
B
B
AAAABBBBAAAA
D
D
D
D
D
D
D
D

Ferrous Chloride
F~rJOUI Sulfat.
Formaldehyde
Formic Acid

B
B
A
A

B
B
A
A

B
B
A
A

Fre0fl
Fruit Juicer**
--7
F_u.l 011
hrf&Ol
G~s_olin*

A
B
A
A
A

A
a
A
A
A

G*lotin***
Glucor.*
EIU.

A
A

C
B
A

A
C
0

A
A
A
C
B

C
B
A

A
*
c
B

C
B
A

C
8
A

C
B
A

C
B
A

C
B
A

A
C
c
B
A

:
A
B

A
B
A
A

A
B
A
A

A
B
A
A

A
B
A
A

A
A
B
A
A

A
A
B
A
A

A
A
B
A
A

A
A
8
A
A

A
A
A
A
A

A
A
B
A
A

A
a

A
n

A
B

A
B

A
B
A
D
D

A
B
A
D
D

A
B
A
D
D

A
B
A
D
D

A
B
A
D
D

A
B
A
D
D

D
D

D
0

D
D

D
D

0
D

D
D

D
D

0
D

B
6

D
D

D
D

D
D

D
b

B
B

Et
B

6
6

B
6

8
B
A
A

B
B
A
A

B
B
A
A

B
B
A
A

B
B
A
A

B
B
A
A

A
a
A
A
A

A
B
A

A
D

A
D

A
D
B
c

:
A
A

A
C
A
A

A
B
A
A

A
B
A
A

A
B
A
A
A

4
B
A
A
A

A
B
A
A
A

A
B
A
A
A

A
I>
A
A
A

_A.

A
B

A
B

A
B

Pi
B

A
A
A

A
A
A

A
A
A
A
A_A.L_A

A
A

*
A

A
A
A

AA
A
A

~AAAAAAAA

A
A
A
A
4

(continued)

652

Corrosion Resistant Materials Handbook

TABLE 5.13:

COPPER AND COPPER ALLOYS-ARC0


low-zIwc
BRASS

COttfR

:
B

Hydrogen
-~
Hydropal PTroxide
._ ___
_Hydrpge~_S+l+,Dry
Hydrop.nS*flde, ________~
MOWI
.--;
Kerosene

A-~__ A
A
B--iA_A_&A-AB
B
__-~
D_
D
A
A
A

Lacquers

~__=_~~~~~-.~-~_1_~_.~~~~~-.
~-AAAACCCCAAAA
__
~.
__
A_-.~~~_~+_B
A
c
c

Limp
&ne_Sulfur

--;-

~c

_~___D
c
B

:
B

: __
B

B~~~-____
B
B
%eed.pil
__ _.
Magnesium Ch!qrido
B
B
B
Magneiium HydrckidsAA--A-A-A
.____--__-~~~--A
Mog%&%~~Sulfate
A
A
A
M+ry
DDDDDDDDDDDD
_
-_
-Merwy
Salts
D
D
D
Methyl _Alc_ohol
Methyl Chloride, Dry
Mi .----p_-_-~.-.-

AAAAAAAAAAA
A
A
A

A.--_--_-_--_
A
C

D
A

C
A

C
A

A
D
D __
D .-D

D
D
D_
D

: ~~~__~
:
A.~--

c^
D
D-B

_-c^
D
D__
B

A
c^
c __
D
D
C__. C-------B
______BP

A
B

A
B-~

C
C
:
_____~._____
D~~. D
D-____.D

B
D
A
C

B-__ B
C
C
A__-.__A
A
A

B
B~.
A
A

D--D-___

A--

D-~

B
D_

A-__

A__-

-__- D

2 YYYY_

:
A
A

*A
A
A

c^
C
A

A
D

0 _@.-B_.LB.C
A
AA-A A
B
B
B>
A
A
A
B
B
B

P_o~&s~~m_~h_~~mote
~_____
PoJorrium Cyonid_e
Potosrium Dichromate, Acid
Potassium Hydroxide
Potassium Sulfate
Propane

A
D*
0
D
D
D
D
B
B
B
AAAABBBBAAAA
A
A
A

Ken ~~

Sea Water
SeW3ge
Silver Salts
Soap Solutions
Bkarbonate
~__~____
Bisulfote
Bisulftto --B-B-B
Corbonote
Chloride

Sodium Chromate

SodiUmCyanibe

--iSodwm Di&omote,
Acid
--Sodium Hydroxade
%&urn Hypochlorite
SXiuGiNhate

A-

__~.

B
D

8
D

A ______
B

~~~~-__~
A
B_

:~

jy~~~hn~&C>
Poralfin
Phosphoric Acid
%t&&~arbk.not~
%i&Chl&id~

A~____A

A
B

c^
.--:__:__:

B
D
:
A-~~ A
A
A
_A
A
A
A

NICREL SILVER

A-__

B
B

A
D

__-_c
s

-.-.A

A_-----ZA
A

AAAA-A

A
DD
D
6B
A
A

A
D
D
0
A
A

A
A

A
D
D
A
A
A

A
A
D_.D
D
..D
A_-;
A
A__!

4_..AA.A

c
A

A
D
D
B

A
D
D
C

A
.D
D
C

A__~ A
d
D
D
D
C
C

A
D
D
B

A
D
D
B

AA

A
D

A
D
D

A
D
D

::

:
B

:,
B

:
B

:
B

:
c
D
c

:
c
D
c

:
D
c

__ L

A
D
D
B

D
6

A
B

D-DO-

___
2

D
B

A
B

B.
A

A
D
D
B

:
B
LDDCBB

A
B

B
B5,.
A

B
A
B

B
A
B

cD
D
B-__
D

6
B
A
A

8
A
B

B
__:
A

c
D
D
B
D

AA ~-AA
A.A._A
--A__ :
A
A___
c

B
A
B

c
D
D__
B-D

:~
A

B
A
B._____
A
B

B
B
B__
A
B

B
B
A
A
A
A
D_-.D_.D.__
-----o
D
D
-_~

B
_____~_
:
A
A

B
B

A_~
:

A
B-B
A
C
A

A
A
A
A.-:-A

_B
B

A~
;L..-.-__
;----

:
B

A
A
A

B_
B

A
A
B____ 6
A--~
__--.
D
D
D
A
A
A~--

A
B

c^

A
A
A-A7

A
B
----A-A
._~__
_?

t D
0
B

A
A

A
A

:
B-B-B

A-_._ A__.
c_c -_
c*--~
D
D
D
c
c __--- c
_____.- B

--~

C
A

A-__
c-_

c
B
B----zA
A-.~

:-:-:-A
C
C
i
A

B
B
B
B
A
A
A
A
_D
D
D
D
AAAABBBBAAAA

BRASS (continued)

tHOStHOI ALUMlNUM SlLlCOW CUtRO NICKEL

WECIAL BRASS

--.

Mint
Nat;
&Ii.-i.

Sodium
Sodium
Sodium
Sodium
fodwm
__~

A.--~___
D
o^
DD~
D_
DD
D

AMERICAN

cottfu-

HICKZlWC
BRASS

Hydrocarbons, Pure
___
Hydk&l?%;-&id
Hyd!ocyanic A&- -___
Hydroftubfi<-A&d
Hydroflu&ilici~-Acid

METALS,

D___

;
C
:

~--D

B
6
B
B
B
B
A ___~__
A
BB

A
.-___ A
D-.
D
D
9
D
:
c
B

A
D
D
a
c
a

-A+

B ~__ B
A
A
D
D
A
A

A
A___-.
D__~_
A

A.~
A

B-_____
B
B
A
B

B
B
B
A
B

A-A
A
A
AA__A
A ___ A
A
A

A
D
D
B
c
0

A
D
D
B
C
B

A
D
B
D
c
B

B
6
B_B
A
B

B
6

:
B

_B_-_I)
A___A
B
B

A
A
D
A

A
D
D

B
B
B
A--B

A_~_____
A
D__p
D
D-B
A
c
c
S__A

A.
A

A
A
D
A

A
D
D
A
B
A

_A

A
A
A
A
A
A
D
D
A
B
A

(continued)

653

Nonferrous Metals and Alloys


TABLE 5.13:

COPPER AND COPPER ALLOYS-ARC0

LOW-ZINC
COwfR
-cLEcTnoLvlIc

Sodium
Sodium
Sodium
Sodium
Sodium

Peroxide
Phosphate
Silicate
-Sulfate
_
SultIde

BRASS
COYYLRClAl

C
C
C
C
A
A
A
A
AAAABBBBAAAA
AAAABBBBAA
C
C
C
C

METALS,

AMERICAN

corrfu-

HIGH-ZINC
BRASS

rHosrHOu
SILCIALBRASS BROHZf

C
A
A

I)
A
A
A

B
A
A
A

6
c
B
B
A
B

B
c
B
B
A
B

B
c
A

8-B
B_.B
A_e

B
C
A.~
B
A
B

A
B

A
A

A
kt
D
A

D
B

C
A

C
A

C
A

C
A

c^

A
c

Sodium Sulfite
Sodium
Thiosulfote
_.Steam
%:&Acid
Supor Solutions
SGtfu;7bry

B
D
::BBBBBBCC
9
c
A
A
A
A
C
B
B
B
B
C
AbiAABBBBAAAA
B
B
6
B
A

it

A __~ A
B ____-B

A
B

A
B

+lfur,
S&fur
Sulfur
Sulfvr
Sulfur

D
A
AA
B
A

Sulfuric Acidft
Sulfurous Acid
~annic Acid
Tar
lartoric Acid**
r_o!ce2e
~i<hJoroca(icAcid
lrichlorethylene.
Dry

Zinc Chloride
Zinc Sulfate

____-.

C
C

__~

B
A

D
A
A
B
A

D
A
A
B
A

D
A
A
D
A

D
A
A
D
A

D
A
A
D
A

D
A~A
D
A

D
A
A
B
A

D
A
A
B
A

D
A
A
B
A__

D
A
A
B
A

D
A
A
B
A

D
A
A
B
A

D
A
A
B
A

D
A
A
C
A

D
A
AA
C
A

B
8
A

B
0
A

8
0
A

B
B
A

D
D
0

D
D
B

D
D
B

D_
D
B

El
B
A

II
B
A

B
_B
A

B
C
A

B
C--C
A

AAAACCCCAAAA
A
A
A
A
B
B
B ____.B
A
A
A
A

A
D
A

A
d
A

A
D
A

A
D
A

A
C
A

A
C
A

A
B
A

A
B
A

A
A
A
B
A

A
A
A
B-7
A

A
A
A

A
A
A

A
A
A
B

D
C ~-a--A-~.-A-C
B
C..-A
~~ ~

4
A
A-.
E_
A

D
A

B fl-.-- B
A~_.~______~~~~
A
A

C_
___~
B

C
B-.

C
B

NlCKfl
SllVfR

C
A
A

D
B

Moist

ALLOYS

C
A
A

D
B

lrichlorethylene.
--- ..Turpentme
Varnish
OiGgkor**
w2GG--FGw
I

CUPRO
NlCKfl

SIllCOn

ALUMINUM
KRONZE

CARlIDlx

D
B

Moltfn
Chlortde,__Dry
Dioxide, Dry
Dioxide, Moist
Trioxide, Dry

BRASS (continued)

B _~...D
-A
C
D
B_____D

D
D~c~~~_.c
~.. .__~
D
D

___D -___D
C
D
B
._ D _____~_

C__
B

(I_
B

C
B

~~--I__
A

.__

..c __
B
~~

_B

A
A-&~__~~

B
A
A
A

C
A
B
A
_A
_A
A
B
-. A

B
A

B-_-A
A
A

A ._ P

a~__8
___B
A
A
A

B
A

c
-_B___

c _~_C
B___ B

B
A

c
B

*Copper and copper alloys are not attacked by dry gases at room temperature or lower. Acetylene forms an explosive compound
with copper when moist and alloys containing more than 65% copper should not be used with the wet gas under pressure. Moist
carbon dioxide is corrosive to brasses high in zinc but may be handled by other copper alloys. Tin coatings are highly resistant
to moist carbon dioxide. Moist chlorine gas is corrosive to all copper alloys. Sulfur dioxide and sulfur trioxide in the presence of
moisture form sulfurous and sulfuric acid, respectively. Copper, Red Brass, Everdur, Phosphor Bronze and Cupro Nickel, 30%
715 should be considered for handling these gases when moist.
**Copper
and its alloys are resistant to corrosion by most foods and beverages. However, consideration must be given to the possibility that such products handled in equipment made of copper or its alloys may dissolve traces of copper in amounts sufficient
to discolor the product or alter its taste. In such cases it is recommended that the metal be tin-coated.
TCopper alloys are resistant to most organic solvents such as the acetates, alcohols, aldehydes, ketones, petroleum solvents and
ether. Organic acids in aqueous solution may be handled by copper and most copper alloys but corrosion will be accelerated if
air is present. Binary copper-zinc alloys containing more than 15% zinc may be attacked by dezincification
corrosion. Copper
alloys may be definitely corroded by chloride hydrocarbons,
such as carbon tetrachloride
and trichloroethylene,
at the boiling
point in the presence of moisture unless the hydrocarbons are stabilized by a neutralizer.
Of the copper alloys, Cupro Nickel,
30% 715 and tin-coated metal offer the best resistance to moist chloride hydrocarbons.
ttCopper
and copper alloys are rapidly corroded by oxidizing acids such as nitric and chromic. Corrosion by other acids is generally
dependent on the presence of oxygen or some other oxidizing agent in the solution. Brasses containing not more than 15% zinc,
and special brasses, can be used with many acids, but, in general, high-zinc brasses should not be used with acids due to the danger of rapid corrosion by dezincification.
Copper, Red Brass, Phosphor Bronze, Everdur, Aluminum
Bronze and Cupro Nickel
offer good resistance to corrosion by hot and cold dilute sulfuric acid and to corrosion by cold concentrated sulfuric acid. Intermediate concentrations
of sulfuric acid sometimes are less corrosive to copper alloys than either concentrated
acid or dilute
acid. Concentrated
sulfuric acid may be corrosive at elevated temperatures due to breakdown of the acid with the formation of
metallic sulfides and sulfur dioxide gas causing localized pitting attack. Tests indicate that the copper alloys may be corroded by
pitting attack by 90 to 95% sulfuric acid at about 122OF (5OC). by 80% acid at about 16OF (71C) and by 60% acid at about
212F (1OOC).

(continued)

654

Corrosion

TABLE 5.13:

Resistant

Materials

Handbook

COPPER AND COPPER ALLOYS-ARC0

METALS,

AMERICAN

BRASS (continued)

RATINGS OF ALLOYS LISTED IN BRACKETSARE IDENTKAL WITH RATINGS


OF FOLLOWING LlSTlNGS IN CHART
Certified OFHC Copper 101
OFHC Copper 102
Boron Deoxidized Copper 109
Silver Bearing Copper 113
Silver Bearing Copper 114
Silver Bearing Copper 116
DLP Copper 120
Phosohorized Couoer 122
Phosphirized Arsenilal
Copper 142
Tellurium Copper 1452
OFHC Sulfur Copper 147
Amzirc (Zirconium Copper) 150
Hitenso 162
Hitenso 1622
Hitenso 165
Chromium Copper 182
Leaded Copper 187
Deoxidized Leaded Copper 1870
Anaconda Coooer 189
Gil&g
210
Phosphor Bronze 505
Phosnhor Bronze 507
Silicon Tin Bronze 5072
Calaun Bronze 607
Leaded Nickel Copper 7021

Commercial

Bronze 226

Leaded Commercial

Bronze 314

High Strength Commercial


Bronze 316
Ambronze 405
Ambronze

ne

Yellow Brass 274


High Leaded Brass 353
High Leaded Brass 3531
High Leaded Brass 3532
Extra High Leaded Brass 356
Free Cutting Brass 360
Leaded Muntz Metal 365
Free Cutting Muntz Metal 3711
Free Cutting Muntz Metal 3712
Free Cutting Muntz Metal 3713
Forging Brass 377

COPPER

Naval Brass
Naval Brass
Leaded Naval Brass
Leaded Naval Brass
Manganese Brass
Leaded Manganese Brass
Anaconda
(Low Fuming) Bronze

Cum

see

COMMERCIAL
BRONZE 220

413

Hardware Bronze 320


Ambronze 422
Ambronze 425
Ambronze 430
Trumpet Brass 435
Silicon Bed Brass 6941

*Slightly
**Slightly

less corrosion
less corrosion

resistant
resistant

Bronze (A)

we TOBIN
BRONZE 4641

681

Nickel, 5% 709

5090

>

see CUPRO
NICKEL, 10% 7~6

see

CUPRO
NICKEL, 30% 715

see

Bronze 544

PHOSPHOR
BRONZE, (A) 510

Phosphor Bronze (C) 521

sea PHOSPHOR
BRONZE, (D) 524

Free Cutting Phosphor


see RED BRASS 230

Leaded Silicon Brass 6942

Low Brass 240


Yellow Brass 268
Leaded Tube Brass 330
Leaded Tube Brass 3301
Leaded Tube Brass 331
Free Cutting Tube Brass 332
LOW Leaded Brass 335
Medium Leaded Brass 340
High Leaded Brass 342
Manganese Brass 667

462
464
482
485
675
676

Cupro Nickel, 20% 710**

Phosphor

we MUNTZ
METAL 280

Everdur 6421
Everdur 661

see CARTRIDGE
BRASS 260

than Nickel Silver, 18% 752.


than Cupro Nickel, 30% 715.

Nickel
Nickel
Nickel
Nickel
Nickel
Leaded Nickel

Silver,
Silver,
Silver,
Silver,
Silver,
Silver,

10%
12%
18%
12%
13%
10%

745*
757*
7641
770*
776*
796*

see EVERDUR 655

see NICKEL SILVER


18% 752

Nonferrous Metals and Alloys

TABLE 5.14:

Corrosion

LEAD AND LEAD ALLOYS-LEAD

of Chemical

in Phosphoric

Corrosion

rate-mpy

(corn I)

3.4

tcomil

4.9

40% &PO.

(c,nlI;

5.7

50?/. &PO,

(COrnl)

65% H,PO,

(coml)

16

6c?G H,PO.

(pure)

12.6

(a)

Chmniul
Solution

!T

64
(a) mils per year (= mdd x 0.127)

x 0 127)

per year (= mdd

m,,s

-r
Chemical
w

lead

(a)

5% Ha

+ 5% Fe Cl,

26

+ 5% Fe Cl,

tia

+ 5%

Fe Cl,

16

20

10% HCI

22

43
150

33

15%HCI

31

20% HCI

74

160

25% HCI

190

200

36% HCI (b)

350

540

-4

37

Chemvxl
Solution

76

avsilabk

10% H.SiF.
1% H,SiF,

6% antimonial

+ 1% H.SO.

77

14

64

115

66

76

+ 10% H,SO,

lead

mPY

53
+ 5% H,SO,

10% H,SIF,

160

lead

mPY

5% H,SiF.
5% H,SiF,

150

mdd x 0.127)

HCI commwcially

lead

mpy (0

ea

190

Corrosion of Chemical Lead


with Sulfuric-Nitric
Mixed Acids
Gxr1son
Solution

24

Effect of Sulfuric Acid on the Corrosion


of Lead by Fluosilicic Acid at 113F (45C)

6% antimonial

41

lead

mPY (8)

5% HCI

(a) milr per year (-

15% HCI

20%

6% antimonial

1% HCI

(b) concentrated

lO%HCJ

+ 5% Fe Cl,

lead

May (a)

Corrosion of Lead in
Hydrochloric Acid-Ferric
Chloride Mixtures at
75F (24C)

SOlUtiOll

Corrosion of Lead
in Hydrochloric
Acid at
75F (24C)

(a)
Solution

30% H.PO.

ASSOCIATION

Corrosion of Lead
in Nitric Acid

Acid at 70F (21C)

Solution

20% H,PO,

Lead

INDUSTRIES

655

rate-mpy

75F (24C)

Effect of Nitric Acid in Sulfuric Acid


on the Corrosion of Lead at 245F (IISC)

122F (WC)

70% k&SO. + 0% HNO,

76% H,SO.

+ 1% HNO,

12

76% H.SO.

+ 3.5% HNOa

3.6

16

70% H.SO,

+ 7.5% HNO,

35

Corrosion

of Lead in Hydrochloric
Chemical

Chsm#cal lead
Solution

Acid-Sulfuric

6% antimomal

lead

75F (24C)

lead

1 WF

(66C)

75F (24C)

15OF (66C)

1% HCI +

9% H,SO,
7% H,SO,

14

32

21

41

5% HCI +
7% HCI +

5% H.SO,
3% H.SO,

14
16

42
45

21
22

65
74

9% HCI +

1% H.SO,

16

47

30

64

5% HCI + 25% H,SO,

10

22

22

34

10% HCI + 20% H.SO.

17

42

60

56

15% HCI + 15% H.SO,

41

74

90

160

20% HCI + 10% H.SO,

12

66

120

110

180

5% H,SO,

140

160

150

210

5% HCI + 45% H&O.

62

53

10% HCI + 40% H,SO,

65

64

15% MCI + 35% l&SO.

66

120

20% HCI + 30% H,SO.

64

130

25% HCI + 25% H.SO,

120

210

(a) mile per year (= mdd x 0.127)

lead

mPY

mPY (a)

3% HCI +

25% HCI +

G%anlimonal

Acid Mixtures

mPY (a)
Solution

mpy

(continued)

656

Corrosion Resistant Materials Handbook

TABLE

5.14:

LEAD AND LEAD ALLOYS-LEAD


Corrosion

INDUSTRIES

ASSOCIATION

of Lead in Chemical

(continued)

Processes

I
Temperature
Sulfstfon

01 011, with 25% rulfurk

(6OC)

rate

mpy (6)
3
12

Olive

Cod liver

Neatsfoot

11

Fish

11

Vegetable

23
16

peanut
with 93% sulfurk

scld (66 6.0)

Naphthalene
Phenol
and Neutrsllzatlon

Sulfated

of Sulfated

and Sullonatod

vegetable oil + water wash-neutralized

Naphthalene

sulfomc

Storaae

tallow wth

acid + water wash-neutralized

2% by WI w

453

140

60

156

70

39

250

121

with caustic

Be sulfuric acid

of llauid alkvl deteroent

Storage of 50% chlorosulfonic


Mixing

166
120

with sodium

soda pH3
Washing

246
330
Compounds

hydroxide

Tallow

Washing

I
I

castor

Sulfonatlon

acid (66 Ee)-14OF

Corrosion

tank

and

acid-50%

sulfur trioxide

crystalhrer-saturated

ammonium

0.3

0.6

1 to 5

sulfate-S%

sulfuric acid soluhon

116

47

190

66

Splmlng
Olive oil and 0.5% sulfuric
of split fatty acids

Storage

of spht fatty acids

Extractton

acid (66 Be)

Storage

01 Atumlnlum

Liquid

Sulfate

level 12

from AlumInn

Bauxite

+ sulfuric acod-boiling

Liquid 16

Bauxite

+ sulfunc acid-boiling

vapor 5

Alum evaporator
alum paper mill

Tank for dluolvmg


Storage

240

116

120

49

16

of 24% alum solutlon

Dorr Settling

11
Liquid 0.6

0.6

Tank

19 5sulfuricacid.

ZO%ferrousslfate.

lC% titanwmoxidearTiS0,

156

70

10

Evaporator
Nickel sulfate solution

212

1w

Zinc sulfate solution

225

107

Ammonium

Solution-saturated

smmomum

sulfate + 5% sulfunc

acid

116

47

Mixmg tank 1

Solutton-saturated

ammonium

sultate + 5% sulfuric

acid

116

47

Crvstalllrer

Add Washha

Sulfate

with 25% sulfuric acid

Sludge oil + 15% sulfuric

acid-steam

Benzol (crude)-treatment

with3%slfricacid

neutralized

220

wth

140

with sodium

hydroxide
of sulfuric

25
20

washed with water,

25% sulfuric acid. wahed

Wet acid gases from regeneration

104

:reatment

with lime

Tar oil-treatment
neutraltzed

Lube oll-treatment

ProductIon

acid

60

with water.
170

250

121

24
6

Polym~rlz~tlon
Polymerization

of butener

with 72% rulfuric

acid

175

60

0.5

Polymerization

of butena

with 72% sulfuric

acid

175

60

14 pita

(continued)

658

Corrosion Resistant Materials Handbook

TABLE 5.14:

LEAD AND LEAD ALLOYS-LEAD

INDUSTRIES

ifz$?ff ~
I=
Corrosion

Rate of Lead in Chemical

ASSOCIATION

Environments

(continued)

(Continued)

CO"CS"- Corrosion

trstion

Alkyl naphthalen

SlfOiC

75

Coos-

ClssI

Temp T

65

75

Lltid

Ally1 sulfide

Aniline

sulfite

rsll0

carroslor
%

CISSS
A

10

75-212

I3

75-212

Anthrscsne

75-212

Anthrsqutnone

75-212

El

10-20
-

Anthrsquinone

75-212

10-30
-

O-10

sulfonic

Alummum

acetate

75-212

Aluminum

chlorate

75-212

Aluminum

chloride

90-100

Aluminum

ethylsto

75-212

Aluminum

fluoride

75-212

Alummum

fluorosulfste

50-70
-

Aluminum

fluosilicste

Aluminum

format0

Alummum

formste

AIUWW~

hydroxide

Aluminum

nitrate

75

75
75-212

chloride

AJItimOnv Dentschloride

potsssium

sulfate

potassium

sulfstfi

75-212

Azobenrene

75-212

scld

scid

B
e
D
B
D
B
B

IO-70

75-212

10

75-200

IO-30

Et

10

cl

acid

Ammonia

Ammonrum

acetate

Ammonium

szide

Ammomum

bicarbonate

Ammonium

blftuorlde

Ammonium

blsulflte

Ammonium

urbamate

Ammonium

carbonate

77
75

3.85
-

10

75-212
75

75-212

10
O-10
-

Ammonium

formate

Ammonium

hydroxide

Ammonium

hydroxylsmine

Ammonium

metaphosphste

Ammonium

nitrate

Ammonium

~~stst~

Ammonium

persulfate

Ammonium

phosphate

Ammonium

picrste

Ammonium

polysulfide

Ammonlum

sulfsmste

Ammonium

sulfate

Ammonium

sulfide

Ammonium

sulfite

Ammonium

thlocysnsts

Ammonium

tungststs

65-212

34

B
B

1
I

10-30
-

I--+
150
75-212

10

75-212

10

75-212

10

75

75-212

75-212

B
A

75
75

Amy1 scntste

75

Amvl chloride

75

Benzene

hexschloride

75

Benzene

sulfonic

scld

75

Benzene

sulfonic

acid

212

Benzldine

Benzllic

75-212

+ NH,OH

IO-100
-

I
I

212

Benzidine

dlsulfonic

acid 2.2

75-212

Benridine

3 sulfonlc

acid

75-212

scid

75-212

Ben~obenzolc

acid

Banzolc

acid

BsZOl

75-;12

BeZOPheOS

75-212

Benzotrtchloride

75-212

Benzotrifluorlde

75-212

Bsnzoyl

chloride

212

Benroyl

peroxlde

Benzvt acetate

75-212
75-212

Banzyl alcohol

75-212

Etenzylbutyl

75-212

EIezyl cetlulws

75-212

Benzyl chlortde

75-212

Benzyt ethyl anlllm)

75-212

Benwtphenol

75-212

phithslste

Ami1 bropionate

75

Benzonltrlle

Beryllium

75-212
75

Awl ohenol
75-212

75-212

Benzocathscol

Benzylphsol
Bezyfslfolllc

Amyl lsurste

B
10

75400

Bsrlum sulfide

10

75-125

e-

10

Aminophenol
Aminosslicylic

20

75

Ammoszobenzene
sulfonlc

10-20

10

Alummum

Aminobenzoic

Antimony

75

Aluminum

Amuwbenrens

acid

sslicylate
acid

chloride

B
cl
E
B
6
B
B

IO-100
-

B
D
B
B
B

10-100
-

B
B

loo
-

A
A
A
B
B
C
B
B
B
B
El
B
B
B

75-212
75-212

B
B

212

(continued)

Nonferrous Metals and Alloys

TABLE 5.14:

LEAD AND LEAD ALLOYS-LEAD


Corrosion

INDUSTRIES

Rate of Lead in Chemical

Environments

Carbon

Carbonic

Butyl

ASSOCIATION

659

(continued)

(Continued)

fluorides

acid

butyrate

Butyfic aldehydes

Calcium

benr

Calcium

blurbonate

Calcium

bromide

Calcium

chloride

(continued)

660

Corrosion

TABLE 5.14:

Resistant

Materials

Handbook

LEAD AND LEAD ALLOYS-LEAD

INDUSTRIES

Corrosion Rate of Lead in Chemical

ASSOCIATION

Environments

(continued)

(Continued)

Chloroxylols
Cholesterol

Diphenylamine

Chromic

acid

Chromic

chloride
Eplchlorohydrin

Ethyl auttate

Chromyl

chlorides

Ethyl cellulose

Cobalt sulfate

Ethyl formate

0 - creBsoI + 1wowater

Crolonaldehyde

Ferric ferrocyamde

Dwthylanlline

75-212

Dlethylene glycol
Odluoroethane

75-125
75-212

B
0

Dmthylsmme

Daglycollc

Olhydroxydiphenylsultone

75-212

Dllsobutyl

75-212

75-212

OloXalW

75-212

Olphenyl

75-212

Dunethyl

acld

75

ether

75

I_

(continua

Nonferrous

TABLE 5.14:

LEAD AND LEAD ALLOYS-LEAD

INDUSTRIES

Corrosion Rate of Lead in Chemical

ASSOCIATION

Environments

Metals and Alloys

(continued)

(Continued)

Oxalic ecld

Perchloroethylene

Qumme

blsullate

75-212

Qulnlne

tarirate

75-212

OllllllZFl~l~

75-212

OUl!lOllW

75-212

OWlOIl

75-212

10

0
10

(Continued)

662

Corrosion Resistant Materials Handbook

TABLE 5.14:

LEAD AND LEAD ALLOYS-LEAD

INDUSTRIES

Corrosion Rate of Lead in Chemical

ASSOCIATION

Environments

Chemlcel
stannlc

tetrachl0rla.3

Stannous

blsulfate

stannous

chlorlae

~UCCIIVC

acla

Sulfamlc

actid

sulfur

atoxlae

sulfur

trlorlae

(continued)

(Continued)

(dry)

Concen-

Temp F

class

100

10

10-50

cl

10-50

3-20

I3

75
75-212

75
75-212

Corrosion

tratlon %

72
75-400
75

90

90

Sulfurtic .3c+a (Sea figure)


sulfurous
SUlfUfyl

chlorlae

Tannma

matures

Tsnrw

ac8a

Tsrtar~c acla
Tetraphosphorlc

scla

chlonae

Thlophosphoryl

75

.3cla

Thmnyl

140

75

zo-loo

75
75

So-70

B
D

70

10-100
-

75-Km
chlorlae

Tetrachlorethene
Teamum

sulfate

Tewwm

tetrachlonae

Toluene

145

75-212

10-30

75
75-212

Toluene-sultochlorlae

75

75

Thnchloroethylene
Trlchloronltromethane
Trlathanolamme
Triphenyl
S&urn

percarbonate

75

sodium

peroxIde

75

Soalum

persulfate

75

Soawm

phosphate

Soalum

phosphate

Scdwm

whcate

75-212
(tri bsslc)

Turpentme

75

10

Vmyl chlonaa

75

10

zmc carbonate

75

70
75

SO-36
-

25

10-100
10-M

75

Zinc sulfate

95

75

Z-20
10-30

zmc chlonae

175

10-30
-

20

sulfate
suff0ae

75-212

sulfite

75-212

SoOlum tartrate

7j

stanmc

75

0.4

80

75

Soawm

chlorlae

140

zmc fluoslllcate
Zmc hyarosulflte

Sodium
Soalum

phosphlte

Corrosion

Rate of Lead in Sulfuric Acid

10

Nonferrous

TABLE

5.15:

MAGNESIUM-DOW

Metals and Alloys

663

CHEMICAL

In the table the concentration


of the chemical is shown in percent. Values of 100% refer to the pure substance in
dry or liquid form. Concentrations
less than 100% refer to water solutions of the chemical. The other column in the
table indicates whether or not a test under actual operating conditions is warranted. A Yes in this column means
that magnesium is basically resistant to the chemical or that laboratory tests have shown enough promise to warrant
testing under actual service conditions.

Suitability
Acelaldehyde
Acel~c
Acid

Any
Any

ACtlOllt
ACttykllt

Any

100

NO
NO
ves
ves

Alcohol Butyl
Alcohol.
Ethyl
Alcohol.
lso~ro~yl
Alcohc4. Methyl
Alcohol,
Propyl

100
100
100
1W
100

ver
Yes
ves
NO
ves

100

ves

Any
Any
100
100
Any

NO
ves

NO
ves
ves

Bow Actd
Brake buds (Most)
Bromides (Most)
Bromobenzene
Butter
BuFIIphenols

Any
100
Any
l-5
100
Any
100
100
100

NO
ves
NO
ves
NO
VCS

Calcrum Arsenate
Calcium Carbonate
C&rum ChlOrlde
Calcwm ttydroxlde
Camphor
Carbon BlWlphlde
Carbon Dloxlde (Dry)
Carbon Monoxrde

Any
100
Any
100
100
100
100
100

ves
ves
NO
Yes
VW
ver
ves
ver

100
Any
100

VBS
NO
ves

too
100
Any
100
100
100
Any
100
Any
Any
100
-

ver
ves
NO
NO
ver
ves
NO
ves
ves
VCS
ves
Yes

100
too
100
Any
100
100

ves
VCS
ves
ver

Ammomd
IGas or L~ouvJl
A~monnrm F;aRs
(Most)
Ammomum Hydrowle
AnlIme
Anthracene
Arsenates (Most)
Benlaldehyde
Benzene
Ebchramales

VCS

Yes
ves

Calben

Tetrachbrlde
Carbonaled Waler
Castor 011
Cement
Chlorides (Most)
Chlorme
Chlorobenzenes
Chlorolorm
Chlorophenols
Chlarophenylphenol
Chromates (Most)
Chromrc Acld
Citronella 011
Cod Lrver 011
(Crude)
Copale
Camarm
CreeDI
Cyamdes (Most)
Orchlorohydrm
Orchbrophenol
Orchromates
(See BlChromales)
Orelhanolamme
Orethyl Anlme
Orethyl Benzene
Olelhylene Glycol
Solutions

1W
100
100
Any

ver
Yes

ves
ves
YCS
Yes.

mayneed

OlPhenyl
O~phenykmme
Orphenylmethane
Olphenyl Oxrde
Orpropylene Glycol
Owylbenzene
Or, Cleanmg Flurds

100
100
100
100
100
100
100

mhrbrlors
Yes
Yes
Yes
Yes
Yes
YIP
Yes

Ethers
Ethanolamme (Mono)
Elhyl Acetate
Eth;l Benzene
Ethyl Bromrde
Ethylcellulose
Ethyl Chlorrde
Ethyl Sabcylale
Ethylene (Gas)
Ethylene Orbromrde

100
100
100
100
100
100
100
100
100
100

Yes
Yes
Yes
Ye1
NO
Yes
Yes
Yes
Yes
Yes

of Testing

Magnesium

Ethylene Glycol
SOlUllonS

in Various Substances

100

VCS,
need
Inhlbdors
Yes

Any
Any
Any
Any
Any

NO
NO
Yes
No
Yes

Any
100

NO
Yes
Yes.
II mhlblled
Yes.
11mhrbded

Any

may

Fats, Lhkmp
IAcId-tree)

Fatiy
Acids

Ferra Chlonde
Fluorrdes (Most)
Fluord~c~c Acrd
Formaldehyde
Fruit Juues
and Acrds
Fuel 011
Gasohol (l&b

Ethanol)

1W

Gasohol (lC%

MelhanoI)

100

GeSobne
(Lead-tree)

1W

Gasobne (leaded)

100

Gtkllllt
Glyccrme C.P
Grew (Acrd-tree)
Heavy Metal
Sdns (Most)
Heumme

Any
100
100

Yes.
II mhlbded
Yes.
II mhrbrted
VSS
Yes
YeS

Any
3

No
Yes

liydrochlonc Acrd
Hydrolluaru Acid
Hydrogen Peroxrde
Hydrogen Suiirde

Any
s-60
hY
100

No
Yes
NO
Yes

lodrdes
lodute Cr~rtals

Any
100

NO
YCS

100
100
Any
1W

Yes
Yes
NO

(Dry)
Isopropyl Acetate
lSopropYl Benzene
(sopropyl Bromrde
Kerosene
Lanolin
Lard
Lead Areeitale
Lead Oxrde
Lrnseed 011
Ma~newm Arsenate
Mapnesrum CarDonate
Mqnesrum Chlorrde
Mercury Salts
Methane (Gas)
Methyl Bromrde
Methfi Cellulose
Methyl Chlorrde
Methylene Chloride
Methyl Sabcykle
Mdk
(Fresh and Sour)
Muteral Acrds

100
1M)
Any
Any
1W
Any
1LlO
Any
Any
100
Any
100
100
100
100
100

Yes
Yes
Yes
Yes
NO
Yes
Yes
Yes
NO
NO
Yes
No
Yes
YCS
Ye5
VeS
NO
No

Monobromobenzene
Monochbrobenzene

Any
100
100

Yes
Ye5

Naphtha
Naphthalenc
N~colme Sulphale
N~lrsles (All)
Ndrous G&es
Nrtrrc Acrd
Nllro~~CGrln

100
1W
40
Any
100
Any
Any

Yes
VSS
Yes
NO
No
No
NO

Any

Yes

100

Yes

100
100
loo
Any

Yes
YCS
Yes
NO

100
100
100
100

NO
Yes
YCS
Yes

011. Anrmal - (Aad.


and Chloride-Iret)
011. Mmeral
(Chloride-free)
011. Vegetable
(Chlorrde-tree)
Olerc Acrd
Obve 011
Orgamc Acrds
lMos.11
Ocihochioraphenol
OrthodlChlorobenzene
Onhophenylphenol
oxygen

Paraphenylphenol
ParadrchlOrobenZene
Pentachloropheml
Perchloraelhylene
Permanpanales
(Most)
Phenol
Phenvl Elhvl
A&ate
Phenylphenols
Phosphates (Marl)
Phosphow Acrd
Polypropylene
Glvcols
P&rum
Ruorrde
Potasswm Hvdroxule
Folarsrum Nitrde
Pooswm
Permanpsnate

Propylene Glycol
u S.P.
Propylene Ox&de

tw

YCS
YCS
YCS
YCS
Yes

1w
loo
1w
Any
1w

Y.?S

100
loo

VCS

Any
Any

YCS

loo
Any
Any
Any

YCS

YLS

NO

Yes
YCS

NO
YCS

1w
100

YCS
Yes.
need
rh,b,tors
YCS

may

Pyrrdme
(Acti Free)

1W

Py&bl

AnY

NO

Rubber h Rubber
Cements

loo

YtS

Sea Water

100

No

Sodrum Bromale
Sodrum Ltromrde
Sodrum Carbonate
S&urn Chtorroe
Sodrum Cyamde
Sodrum Orhromale
Sodrum Fluonde
Sodium Hydrorrde
Sodrum Phosphale
(Tnbasr)
Sodrum Lluale

Any
Any
Any
Av
AnY
Any
Any
Any
Any

NO
No
Yes
No
Yes
YCS
Yes
Yes
Yes

Any
3
3

YCS
VCS

loo
1pD
loo
Any

ND
Yes
Yes
Yes

Any
100
1w

NO
Yes
Yes

Any
Any
Any
3
Any

NO
NO
No

1w
Any

Yes
No

1w

YCS

100
loo
loo
loo
1w
100
1w

YCS
Yes
Yes
VCS
Yes
Yes
YeS

1w

Yes

Any

Yes

Sodrum Sulhde
Sodwm Telraborale
Steam
Slurrc Actd (Dry)
Styrene Polymer
sugar Solullons
(Acrd-Free)
Sulphates (Most)
Sulphur
Sulphur Oioxrde (Dry)
Sulphur Chbrrde
Sulphwc Acrd
Sulphurous Acrd
Ttnmc kd
Tanrung Solutmns
Tar. Crude h
11sFrxtlons
Tarterr Acrd
Telrahydrowhlhskne
Triaruum
Tslnchlornle
Tolwne (Toluol)
Tnchbrathykne
Trrchbrophenol
1unp 011
TUrpsnhne

Yes

NO
NO

urea
urea m Aqueous
Sotuhon (Cold)
urea I Aqueous
Sohdron (Warm)

Any

NO

VUteQplr
Vmyhdme Chlorrde
VInyI 1oblenc

AnY
1w
1w

No
Yes
Yes

water.
Water.
water.
Waxes

1w
100
loo
loo

NO
VCS
Yes
Ye5

loo

Yes

XYIOI

BollnlQ
Drslrlkd
Raul
(Acrd-free)

664

Corrosion Resistant Materials Handbook

TABLE

Alloy
type

5.16:

Alloy

Nickct
pure

200

NICKEL

AND

ALLOYS-HUNTINGTON

HIGH-NICKEL

Nominal chemical
composition, %
(Maior elements)

Description

ALLOYS

A=Acceptable
C-E=Good
to excellent
gG=Not
ffecommended
X=Check
for specific

data

Corrosion resistance

COmmerCially
pure wrought nickel,
good mechanical
properties,
excellent resrstance
to many corrosives.

nickel

!PoljEL
so0

nickelcopper

!lf$EL
R-405

Hugh strength,
good weldability,
excellent
corrosron resistance
over
wide range of temperatures
and

Similar to MONEL allov 400. Controlled sulfur added for improved


machining
characteristics.

Age-hardened
version of MONEL
400 for increased
strength and
hardness.

alloy

NCONEL
llloy
ioo

Hugh nickel, hrgh chromium


content
for resistance
to oxidizing and
reducing environments;
for severely
corrosive
environments
at elevated
temperatures.

NCONEL
IllOY

Excellent
high-temperature
mooerties, resistance
to oxidizing,.
carburizing,
and sulfur-containmg
atmospheres.

io1

NCONEL
;y;y
NCONEL
IllOY
125

la 3.6

nickelchromiun

NCONEL
IllDY
890

LI(INfNEL
f-750
UNTlNGTOh
llloy G

IUNTINGTOI
If0y
IX

A hi h-chromium
modification
of
INCbEL
alloy 600. Good resistance
oxidizing chemicals
and sulfur-containing gases. High mechanical
properties.

to

Excellent
strength from -423
F to
1300 F (-253
C to 705 C). Age hardenable and may be welded in fully aged
condrtion.
Excellent
oxidation
resistance UP to 1800 F. (980 C).
Age-hardenable
alloy with good corrosion and oxidation
resistance.
Excellent
relaxation
resistance.

52.5

18.5

19.0

MO 3.1
Cb&
Ta 5.1

73.0

7.0

15.5

Ti 2.5

Excellent corrosion
resistance
in many
media. Resists pitting, crevice corrosion, and intergranular
corrosion.

44.0

19.5

22.2

:u, to
Ta 2.1

Excellent orrdabon resrstance and elevated


temperature strength.

MO 6.5

48

18.5

21.8

MO 9.0

t Nickel 201. low caroon version


recommended
for temperatures
above 600 F (315 C)
*Age

hardened

(continued)

Nonferrous Metals and Alloys

TABLE 5.16:

Alloy
type

NICKEL

Alloy

AND HIGH-NICKEL

ALLOYS-HUNTINGTON

INCOLOY

$0"'

Strong and resistant


to oxidation
and carburuation
at elevated
temperatures.
Resists sulfur attack.
internal oxidation,, scaling and corrosnon in wide varlety of atmospheres.

(continued)

toexcellent

=Acceptable
C-E=Cood
I=Not
Recommended

Nominal chemical
composition. %
(Major elements1

Description

ALLOYS

665

X=Check for specific

data

Corrosion resistance

G-E

G-E

G-E

G-E

G-E

G-E

G-E

G-E

G-E

46.0

INCOLOY
alloy

eooH

12.5

46.0

nickelironchromiu

G-E

21.5

G-E

G-E

G-E

Age hardenable alloy provides high


strength u to IOOOF (54OC) comparable
to alloy a2%0CO~~OS,O
reststance.

INCOLOl
:?!?

42

HUNTINGTOI
alloy
6041

G-E

32

G-E

G-E

G-E

G-E

G-E

G-E

G-E

G-E

G-E

G-E

G-E

G-E

25.5

45.0

G-E

G-E

G-E

G-E

_ _ _
A mckel-won
chromium
alloy with good
high-temperature
strength and corrosion resistance.
Provides good resistance to oxidation and carburization.

TABLE 5.17:
ALLCORR
ments.

It

characterized

NICKEL-BASE

is a

single

phase,

is a nickel-base
by the

alloy

following

ALLOY-TELEDYNE
non-age

ALLVAC

hardenable,

containing

G-E

corrosion

nominally

31%

alloy for service in highly


10% molybdenum,
and

resistant
chromium,

corrosive

2%

environ-

tungsten.

It

is

properties:
l high strength

high

resistance

to general

corrosion

high

resistance

to pitting

and crevice

high

resistance

to intergranular

l high

resistance

to stress corrosion

corrosion

corrosion
cracking

and ductility

l good

weldability

l good

hot

l good

machinability

and cold

workability

Corrosion rates in mils per year (micrometers per year)


S&lCtJ*

AUCORR

SY

YY

T:

ZY

CzEzNTER

,I6
STAINLESS

666

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

ALLOY CHARACTERISTICS
HASTELLOYe
alloy
B-2-An
improved
wrought
ersro of HASTELLOY
allov B Allov B-2 has the
fame excellent
corrosion
resistance as alloy S. but
with Improved
resistance
to kmfe-lme
and heatatfected.zone
attack This alloy resists the formation
of grain-boundarv
carbide preciprtates
in the weld
he&-affected
zonk, thus making it suitable for most
chemical process appl!cabons
m the as-welded condrtion. Alloy B-2 also has excellent resistance to pntmg and stress-corrosion
cracking
It is particularly
well
suited
for equipment
handlmg
hydrogen
chlonde gas, and hydrochloric,
sulfuric, acetic, and
phosphoric
acids.

anhydride.
sea water and brine solutions. It isone cf
the few matenals that resists the corrosive effects of
wet chlorme gas, hypochlorite
and chlorine dioxide
solutrons
Alloy C-276 resists the formation of grarnboundary
precipitates
in the weld
heat-affected
zone thus makina
it applicable
for most chemical
process uses in tiie as-welded
condition.
It has excellent
resistance
to pittmg and stress-corrosion
cracking

HASTELLOY
alloy
G-A
columbium-stabilrzed,
mckel-base
alloy with excellent
resistance
to hot
SulfurlCandphosphoricacrds
AlloyG will wlthstand
the Corrosive affects of both oxldizrng and reducing
agents
and can handle
both acid and alkaline
solutions
It resists pltttng and has exceptional
resistance to stress-corrosron
crackrng
HASTELLOY
alloy X-A
heat-resistant,
nickel-base
alloy rdeally suited for chemical plant equipment
It
has good high-temperature
strength
and exceptional resistance to oxidrzing atmospheres.

HASTELLOY
alloy C-4-A
new nickel-chromlummolydenum
alloy with improved
high-temperature
stability
as evidenced
by high ductility
and corrosion resistance even after long-time
aging in the
1200 to 1900 deg. F (649 to 1038 deg C) range. This
alloy
resists
the
formation
of gram-boundary
precipitates
in the weld heat-affected
zone. thus
making It suitable for most chemical
process applications in the as-welded
condition.
Alloy C-4also
has excellent
resistance to stress-corrosion
cracking and to oxidizing
atmospheres
up to 1900 deg. F
(1036 deg. C).

HASTELLOY
alloy C-27B-An
improved
wrought
version of HASTELLOY
alloy C with vastly improved
fabncabilrty.
It has outstanding
resistance to a wide
variety of chemical process envtronments
including
strong oxidizers. i.e., ferric andcupricchlorides.
hot
contaminated
mineral acids, solvents. chlorine and
chloride-contammated
media (organic
and morganic). dry chlorine, formic and acetic acids, acetic

CABOT6
alloy
No. 625 has hrgh strength
and
toughness
from cryogenic
temperatures
to 2000
deg F (1093 deg C). Its fatigue strength is excepbona1 This alloy derives its strength from the stiffening effect of molybdenum
and columbium
on Its
nickel-chromium
matrix.
In addnion
to good oxidation resistance, the alloy also reststscorrosiveattack by many other media; it is virtually immune to
chloride-ton,
stress-corrosion
cracking.

Aqueous Corrosion Data for CABOT Alloy No. 625

ed 1 hr 8, lKrOF1871Cl

-FnmllCAcid

NnncAd
PhOIPhWlC
Acid

40

Bolllng

73

0 19

Averagecl four 24hr perrods

88

BOlllng

93

0 24

Avera9.zof lour 24.hr pet~Js

25
25

N,l

NII

tOcMr lest

0.5

<o 02

1Whr test

25

472

12

tW_hr.test

34

0 86

Aer.?9eOf four 24-M tests

10

0.7

65

20

Bolbng

63

70

240!116,

12

70

300,,491

11

85

BWllQ

67

681201

NII

55

l50% HzSOa(weight
l*7% HISO,, 3% HCI
Nil-No

at 17oOF19270

measurable

95,351

Nd

122,501

01

1491651

176 1801

NII

194 190,

Nd

percentl
(volume

coo2
0.61

24hr te
Avera9eof f+ve48-h,

,
_.

.~

50
50

199 (93)
Bo,,m0

.~

sueunc
Acid

0.4
24

001
006

96-h, test
96hr test

10

Borlrng

37

094

Average cf lo, 24-h, per,&

30

Bodmg

231

59

Averageof f01lr24-h, perrods

50

Bodmg

960

Room
122,501

01
a1

21

48-h, ter,,

15800)

196

47

48-h, test

24

Average of four 24.hr ~er,ods

<o 003

4Bhr lest

and 42gil of ferric sulfate


percentagesl,

penetrabon

1%

CUCIIand 1% Fe Ch (weight percentages).

could be calculated.

COMPARATIVE

RESISTANCE

OF HASTELLOY

ALLOYS

TO VARIOUS

CORROSIVE

MEDIA

KEY
E

EXCellent

Lass than 2 mllr

Good

2 to 10 mllr

Satisfactory

Over 10 to 20 mlls (~0.25


per year

to 0.5lmm)

penetration

BorderlIne

Over 20 to 50 mlls (aO.51


per year

to 1.27mm)

penetration

Unsatisfactory

More

(0.05

than 50 mllr

(O.OSmm)

penetratlon

to 0.25mm)

(1.27mm)

per year

panetratlon

penetration

per year

per year

No Data

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

HASTELLOY~

PRODUCTS

G/G-2

Medic

Acetaldehyde
Acebc

98

Acid

Acetlc

Acid

Acetic

Acid

Acebc

Acid

Acetlc

Acid

2.5M

135

2.5M 1
3

57

212

385

196

1 -

4.5

347

175

10

75

38.60

1 immersed:

/ rack
wtmllymtmg
onbottom.

Acid

10

214

101

Acetlc

Acid

10

300

149

---

Acehc

Acid

12

250

121

A&c

Acid

Acetic

Acid

Acetic

Acid

Acetlc

Acid

Acehc

Ac!d

210

210

20

210

20.8
21

Acebc

Acid

Acetlc

Acid

234
24

Acebc

Actd

25

Acetic Actd

25

Acettc

I
1

99

I - I

E l-/-i

99

1 -

E
E

239

I
1

100

110

I-1

220
220

100
110

104

104

1 -

I -

plus

/ plus

plus

I starch

pwflcabon

conve,s~pn

and higher

l -

/ -

/ plus

--

acids.

1 5 to 4 percent

formic

1 percent

acid

formic

H,O.

balance

02 percent

chlwde

plus

1.5 percent

plus

4 percent

acetaldehyde

acid.

192.hr

test under
water

sahcyhc

formic

Allay

78 percent

actd.

contammabon
formic

13aO.hr

Alloy
acid.

C = 0 7 mpy

reflux
Alloy

99.129.day

test

acetaldehyde.
acetaldehyde,
formic

129.day
129.day

test, topolfractlanatlngcolumn
test at bottom of tower

Aud

30

275

135

--

plus

a percent

Acid

30-40

230

110

--

plus

5 2 percent

Acebc

Aud

30-50

220

104

--

plus Z-10 percent


Iormlc
aud and total 5 percent
acetaldehyde,
methyl acetate. ethyl acetate. acetone.
Allay C = 7 mpy

Acid

33

270

132

Acid

40

347

175

--

Acebc

Actd

44

212

100

--

15

percent

formic

acid,

(wolent

test m vapors

Acebc

Acetlc

C = a mpy

C = 0 6 mpy

Acebc

Acebc

011s

acid

plus0 Spercent
plus 3 percent

formic

tar creosote

test at top of tower

sallcylates

0 011 percent

some

3 percent
hardwood

2to

~mmetwn

acid

acetaldehyde.

plus 1 percent formic


agltatlon
of solution)

--

I - / -

aeration

purlflcabon

butane, 2 percent water. 10 percent mtrogen,


1 percent
27 percent other organ~cs
Alloy C ~0 I mpy

/ PIUS
50 percent

I-

lab test a 1 days.

to ptl of 2.0 I streptomycm

30 percent

j -

day test in top of tower

Immersed,
comparison
of heat transfer CoAdltlons
with slmple
test. Corrodent
renewed every 48 hrs.. total time 95 hrs

E
E

HCI

/ also
HCI

129

lab test 41 6 days

HCI to pH of 2 0 in streptomycin

plus prop!o~

1 - / -

aeratw

plus 56 percent
carbon dmxlde,
plus

115

230

--

99

B01lmg

212

plus

aolllng

Acid

material.

Acid

17

low bml~ng

___

2 percent

-E

Acetlc

20

Conditions
plus

___

E
E

Stnl

--

24

(continued)

Acebc

10

1 -

4.22

100-140

100

40-72

1 C/C-276

667

Trpr
316
Shinless

alloy
_

Corrosive

Metals and Alloys

aad.

Alloy

acid

5902

Alloy

C = 12 mpy
C = 0 5 mpy
methyl
methyl

formate.
alcohol

hrs.

plus 20 percent butane.


5 percent pentane.
a percent ethyl acetate. 5
percent
methyl
ethyl ketone.
6 percent
propu~mc
acid. esters. and
ketones
Alloy C = 0 7 mpy
plus 34 percent

amyl alcohol,

trace 01 chlorides

792.hr

test. Alloy C = 1 0

mPY

E
C
S
B
U

Less than 2 mpy (0.05 mm/y)


2 mpy (0 05 mm/y)
to 10 mpy (0 25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0 51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (127 mm/y)

M -

Molar

(continued)

668

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

Acebc Aad

51

ALLOYS-CABOT

275

WROUGHT

135

PRODUCTS

E 1 -

1 -

(continued)

/ plus30
percent

Acetlc Aad

55.5

104

Acehc Acld

57

100

38

1 -

E 1-1-I

60

B.P.

B.P.

Acebc Ac!d

219

--

plus

percent

proplow

I1 5 percent acebc anhydrlde.


Alloy C = 0.2 mpv

anhydrlde.

H?SO,.

12.3 percent

H,O.

1 percent

naphtha.

I PIUS 10 percent stbcvlates.

Acebc Acid

60

221

105

--

plus 2 percent format acid. 38 percent

Acebc Acid

60

356

180

--

plus 18 percent hydrocarbons.


water Alloy C = 2 mpy

Acebc Acld

67

212

100

--

Acetlc Actd

67

Acetkc Acld

273

134

E I -

Allov C = 0.7 mpv. 9504.hr

/ -

/ plus33percent

131

--

tests for selecbon of materul


acetaldehyde wt. 91 hrs.

Acebc Acld

75

258

126

--

DIM 20 oercent or~amcs

Acehc

80

195

Acebc Acid

Acebc Acid

85

167-257

85

237.273

89

251

I
Acebc Aud
I
Acebc Ac!d

89

IgllGIGI--I--I~
75.125

114-134

1 -

lz5

124

)
I

Acebc Aad

90

225

107

Acebc Acld

90

275

135

99.6

244

118

Acebc Acid

99 6.99 9
(anhydrous)

216

102

05 mm/y)
to 10 mpv (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/v)
mm/y) to 50 mpy (1.27 mm/y)
(127 mm/y)

BP

E
G
S
6
U

Less than 2 mpv (0


2 mpy (0.05 mm/v)
Over 10 mpy (0.25
Over 20 mpv (0 51
More than 50 mpy

for an acebc acid recovery column

and 5 oercent

water

lor an

Allov C = 0.3 mov

--

1 -

/ -

/ macebc

plus I1 percent man~anousacetate. 0 15 MnO,. 58 ppm Cl.. a trace 01


/ formic ac,d

manganese acetate = IO 73 percent. manganese dloxlde = 0 15 percent.


/ water = 006 oercent 50 ppm Cl-

I
1

E i-1-1
E
I - I -

percent

formic actd. 3-5 percent prop~on~c acld. ethvlacetate


small amount water (ethylacetateacetlc
acid azeotrope dlstlllabon
process) Alloy C = 4 0 mpy. 1126.hr test.
plus h percent acetaldehyde.
Alloy C = 1.4 mpy

--E

5 percent

water

Extenswe

aerabon.

anhydrlde pwbcabon.
Plus 10 percent acetic anhydnde. 5
percent water. acetone. acetondnde. ammes. etc. Alloy C = 0 1 mpy

plus 10 percent

I olus

10 percent

manganese
proo,onu

percent
sa Icy
Acebc Acid

9 percent esters, 8 percentC0.5

PIUS 2 3 percent

255

Allov C = 46 mpv

water. Alloy C = 1.2 mpy

test.

267

lhqud and vapor phase

prop~omc acid. Alloy C = 0.2 mpv

72

Acid

7.5

0.016 percent sal~cyl~c acad. 1380.hr test an vapors

plus 30.3 percent


I

propb~n~c acld.

acetate. Alloy C = 3 mpv


aad. Allov C = 1 mov

IC XI

Immersed. comparison 01 heat transfer condlbons wth slmple mm~err~on


test. Carrodent renewed every 48 hrs. total time 96 hrs
--

0 7 mpv, plus 60 ppm sodaurn dlchromate

Bodmg Pomt

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

Acebc Acid. Glacml

ALLOYS-CABOT

Acetlc Acid. Glacial

675

100

125.B.P.

52.8.P

50

297
1

Anhvdrlde

60

Acebc Anhydnde

95

A;eilc

357

1247

Acebc AnhydrIde

PRODUCTS

675
1

Acetlc Acld Vapor

WROUGHT

E
E

/
I

140

252

122

--

--

lb7

284

m vapors and catalyst during


1 pyrolysis Alloy C = 0 1 mpy

manufacture

plus 40 percent
acetlc acld

1
I

1 -

I - / olus40

ethylene

percent

dlamme

acebc anhydrlde.

266

130

--

KMnO, added for quahty control

Acebc Anhydnde

99

310

154

--

plus 1 percent

Acebc AnhydrIde

1M)

273

134

--

Alloy C = 0.04 mpy

Acebc AnhydrIde

All

to B.P

to BP

--

--

Acetone

60

Acetone

All

Acetomtrlte

176

1 toE.P

Acetophenone

67

Tetrachkwde

Acetylene

Tetrachlartde

376

302

Acetylene
1Crudel

80

toE.P. I
191

150

I isopropyl
1

methyl acetate,

chloride

1 plus 33 percent

74.80

Acombc

185.194

85.90

--

Aad

10 percent

acetaldehyde

Dissolved Fe=0

plus NaOH, H&O,.


sbghtly

and sodturn

metablsulllde

212

100

--

110

43

aerabon. saturated wth water and contammg


other organu compounds

180

82

Ca(OCI),, Cl, and Hz0 Durabon 01 test -

AI, and Steam

180

82

100
100

75
BP

fl2p4

Alcohol. Ethyl or Methyl

All

to B.P

to BP

l
Alkylammer

Alkylate, Butane
and LlRhter

Alkylbenzene

Sulfonate

Alkyl Benzene.
Sulfomc Acid
E
G
S
E
iJ

Less than 2 mpy (0


2 mpy (0.05 mm/y)
Over 10 mpy (0.25
Over 20 mpy IO 51
More than 50 mpy

200

128

71
-

140
100-130

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 mpy (127 mm/y)
(1.27 mm/y)

I
/

93

I
1

E
S

53

60

--u

38-54

BP

HCI

Alcohol, Ally1

15-l 65 grams/liter.

Column. m vapor and llquld

AI,, Exhaust

--E

pH 5.6

phenol

excess Cl, = IO-21 grams/lder


= 0.7-6.6 Rrams/bter

Acrybc Ac!d

chloride

rolubon.

at top and bottom 01 dlstlllabon

165.175

plus traces 01 methylene

--

4cld Pulpmg
lAmmonla Base1

Alloy C = m SPY

/ - I

---

42-49

acid and 10 percent

acetlc acid and violent agltabon

plus 30 percent

I -

tetra-acetlc

activated carbon used lor absorbmg


Allov C = 0 1 mpy

---

108.120

by

PIUS 5 pecent acebc acid

95

of .%et~c anhydrbde

vapor velocdy, 175 It/w,


1776.hr test Spool exposed m Inlet leg of
reactor cml I acetic anhydrade (99 percent acebc acid plus catalyst),
Alloy C = 0 1 mpy

Acebc Anhydnde

Acetone

669

(continued)

Metals and Alloys

Alloy C gamed wetght

H,SO,. acrybc aad reactor condenser


chlormated

solvents and

204 days

II

--

1-I

I
G(

--

alkyl ammes
pH 10.12

during petroleum
Allov C = 0

rellnmg

I mm

24 hrs
--

m aqueous

solubon

contammg

m depropanlzer

small

tower.

amounts

vapor

of CO,.

and lhquld

lab test (wgorous stlrrmg)

m settlmg tank and sullonabon


C=06mpy

tank durmg detergent manulacture

Alloy

Bodmg Pomt

(continued)

670

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

TYpr
316
Stain-

stwl

Conditions
I alkaylabon. mwng
AllOV c = 0 4 mov

and dlsbllabon

processes lhquld and vapor phase

plus phosphated alumma hydrate


hydrate, 75 percent H,POa

_
_
_
_
-

(60 Bk H,SOJ

LIF, N&I, NaF, specimens VW! alternately


over lO.day pernod
as m ethyl benzene productmn.

65 percent alumna

exposed to wand

!somerlzatlon.

Fwdel

molten flux

Crafts synthesis

plus HCI at 250 pr,

AICI, 85%. NaCl 12%. Al20] 3%. Fe& 700 ppm lnlbally
NaCl 8.9%. Al,01 30.55%. &Cl, 0.5.1 5% flnal
no

AICI, 35.60%

aeratton

AI>FJOd to pH = 2.3 Alloy C = 0 4 SPY


Alloy C = 24 mpy

_
_
_
-

*paper

makers alum

I cm descallng Plus 0.01 percent ferric and 0 03 percent lerrous 10s as


Fe,O,. trace Cr,Oj. Occasional exposure to NaOH cleanmg solution
E

30% Warn.

20% orgamc acld, pH 10.11, polymeruabon

kettle. 62 days

hot wash bquld Reacbon product of dlphenylamme


and acetone m HBR
catalyst after addlbon to 50% NaOH to yield pH of 12 14 Moderate
aeration
dissolved m isopropyl alcohol
73% NaOH to keep neutral
Agltabon vmlent, 251 days

Methyl chlonde added to MNTN pressand


Manulacture
01 fabric softener Au free

ammama
aeratmn

20%. water 50% Lwd

phase

ammoma

20%. water 50% Lwd

ammOls

20%. water 50%

smmoma

20%. water 40%. 4 days, agdatmn

ammonia

20%. water 40% Laqud phase

252

days. no agdabon

or

phase

J 4Wsec.

aerabon -

one

U
E

E
G
S
B
U

Less than 2 mpy IO.05 mm/y)


2 mpy 10.05 mm/y) to 10 mpy (0 25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y)
Mote than 50 mpy (127 mm/y)

BP

3 25% NaOCI. 2% NaOH. 10% NACL. 69% H,O, Balance inuts pH 14.
producbon of 3.Ammopyridme.
Agdaban - none. Air Iree. 74 days
plus 7 percent carbon dkwde
ll,Pl nlnnt

and water m ammoma wx~ery

strtpper m

6% CO,. 66% w&r vapor (all by WI I, 131 days. test m heat exchanger.
vapor zone Aerabon - shght. Aga:atlon - shght

carbon dwde

68. water vapor 66% air 0 5.l0.

all by volume

Bmlmg Pa~nl

(continued)

671

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

WP

Conotiw

316
Stain.
Iem
Stnl

_-

Media

Ammoma

Ammow

Ltquld

75
loo-BP

ti

;:

lOO:;.P.
75
loo-BP
to 8.P
to E.P.
to 600

:o
50

1;:

Ammonia,

Llquld

Ammomum

Blfluorlde

Ammomum

Blfluonde

Ammomum

Blfluorlde

Ammomum

Blsulfde

Ammonwm

Bromide

10

Ammonium

Carbonate

10
20
::

90

25
25.200

-I-

i
-

40
40
50
Ammomum

1
I

300

149

157-162

69-72
24

75
to B.P
to e P
to 175
to B P
to 175
BP
BP

to BP
to BP
to 80
to 8.P
to 80
0.P
BP

266

130

90

Chloride

6 22

Ammomum

Chloride

11-14

194

Ammomum

Chloride

14.1

86.176

Ammomum

Chloride

Ammomum

Chloride

Ammonium

Chloride

Ammomum

Chloride

Ammomum

I26.31

180

plus ammonium chloride.


Alloy C = 2.21 mpy

m outlet
chlorides

cuprous

chloride.

cupric

of methallymme
reactor contammg
plus polymer. Alloy C = 0 1 mpy

chloride.

ammes

NH&I.

Awfree

orgamc

Alloy C = 1.1 mpy


Alloy C = 8.4 mpy

fused, 40 days

pulping

S
S
E
S
S

-.

0.07% mckel chloride. 2 95% ammom. 5 55% ammonium carbonate. pH


= 10 8. recove,y of ammonw 24 hrs.

8% N&I:. 4 2% CO,. 131 days, agdatlon

flwng stsmless steel strip pnor to salderlng. Ourabon of test aerabon - moderate. agdatmn - 2-3 ft Isec

S
S
E
:
:

lkquor Alloy C = 0.3 mpy

plus H,S, mercapans

+i-+l-+

Ind non-abraswe

solfds I agdator
and aerabon -

skght
98 days.

77-216

75.102

m evaporabng

221-230

105-110

plus less than 0 5 percent NH,

35-50

to 225

to 107

plus 35 percent ZnCI, for 2 percent of pernod, tank contamed bakng


solubon of 50 percent NW
4 percent ZnCI,, 0 15 percent PbCI,
Alloy C = 0 1 mpy I both lhquld and vapor phases.

Chlotlde

to 40
All

to BP
to B.P

to BP
to BP

S
s

Ammomum

Chloride

147 g/l

167

75

Ammomum

Chloride

sole leather dye vat NH&I

Ammontum

Chloride

sodium sulfde mother IIOUOIS. Allov C = 0.003 mov m 336.hr

Ammomum

Chloride

plus sodwm

Ammomum

Chloride

plus HCI and hydrocarbons

28-40
35

79.103

tank

Alloy C = 0.02 mpy

sodaurn chloride 78 g/I, carbon dmxlde 42 g/l (combmed as NH,HCO,.


(NH,), COI, NaHCO,), ammoma 22 g/l (combmed as NH,HCOI. (NH& CO,
NH, OH Sulfide trace. organa
posrlble trace

rulflte

400 grams/bter

Chloride

Alloy C = 2 12 mpy

Ammomum

Chloride

350 grams/Met

Alloy C = 0 004 mpy

NH&

&hydrogen

Ammomum

Fluoride

plus excess NH,OH

Ammomum

Fluoride

plur8percentbtamum

Fluande

plus suspended

E
G
S
B
U

Less than 2 mpy (0


2 mpy (0 05 mm/y)
Over 10 mpy (0.25
Over 20 mpy (0 51
More than 50 mpy

16.93

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0.51 mm/y)
mm/y) to 50 mpy (1.27 mm/y)
(1 27 mm/y)

BP -

bubble tower Alloy C = 0.1

NH3

plus 1.2 grams/liter

free NH, Alloy C = 0 06 mpy

28

NH,CI plus 3-5 grams/kter

Ammomum
Phosphate

Ammomum

82

I refmery c&r

test

Chloride

Satr Soln

I water

mother Iutuor. Alloy C = 0.02 mpy

Ammomum

and enzymes dlsperseo

Ammomum

449

Alloy C = 0 014 mpy

I
S

fluwdem

theseparatlonoftltanlumfromttrore

fetrous tdanate IIlmenW

Bolllng Pomt

(continued)

672

Corrosion Resistant Materials Handbook

TABLE 5.18:

Ammomum

Fluos~l~cate

Ammomum

Hydroxade

Ammomum

Hydroxide

Ammomum

Hydrorlde

NICKEL-BASE

I
I

ALLOYS-CABOT

18.5

Ammomum Hydroxide
Mrxtures. Ammoma

248

32.43
120

Cone

572

300

150

66

Ammomum Hydroxide,
Ammoma. Carbamate

90-110

268.275

21

Ammomum

Ndrate

10

Ammonium

Nttrate

12

Ammomum
Ferbbzers

Notrate

13.38

Ammontum

Oxylate

Ammomum

Perchlorate

122.194
75
32-212

100

10

l5

All

to 160

WROUGHT

E*

PRODUCTS

(continued)

I - I - I plus1 percent free H,SIFG


I

--

131.135

50.90

--

24

I -

contamed 2 grams cupnc chlonde


test. no agrtatmn *Cracked

--

0.100

--

38

E.

24

--

to71

--

lSlqht

weight gam

I 210 hours, 8% NH]. 2% HrS, 2% CO, and 0 3% HCN

contams

aeration

(NH,),COI.

carbon dloxlde
aerabon

(NH&S.

NH&.

dwlfonate

Ammomum

Persulfate

10

75

24

--

Phosphate

75

24

--

Ammomum

Sulfate

s
S.

--

Ammomum

Sulfate

--

Ammomum

Sulfate

156

69

--

plus SO? and other sulfur compounds

Ammomum

Sulfde

103

39

--

plus ammomum

Ammomum

Sulfde

45.46

135

--

to B.P
190

to B.P
88

212.213

100

all by volume,

SO?. ammomum

shght

sulfates and

potaswm chloride 11.6to 301, cslclum phosphates, mono- and dl.. 1%


to 14%; water 20%. lnerts 12%. pH 4 5 to 7 0. moderate aerabon

Ammomum

All
45

159 hrs.. lab

NaCl

6%. water vapor 66%. au 0.5-l%.

plus ammomum hydroxylamme


nitrates Alloy C = 0.3 mpy
E

and sodbum sulfate/gal,

hquld

anhydrous

NH,. H,SO,, and (NH&S

m ddute and saturated NHSO,

added m process

plus 1 5 percent free H,SO, Alloy C = 0 7

mpy

Amyl Acetate

275

NH,HSO,.

Alloy C = 0 06 mpy

blsulflte, 3 percent total SO,, pH = 6 2 Alloy C = 0 1 mpy

pfi 5.0 to 6 0

durmg produchon

ol amyl acetate from amyl alcohol. glacial acetlc acid.

HSO,
Amy1 Alcohol

Amy1 Chlonde

104

40

--

plus 44 percent acebc acid, 34 percent amyl alcohol. 2 percent rulfunc


acad. balance water

75

24

--

plus traces 01 NaCI. NaOH, Fe&

Amyl Chlonde

84

86

30

--

plus 16 percent dry HCI Alloy C less than 0 3 mpy

and water

Alloy C less than 0 1 mpy

Amy1 Chloride

100
100

86
BP

30
BP

III

Amyl Mercaptan

230

110

-__

to 320

to 160

--

/ -

I-

I-1

plus trace of HCI and water

plustracesof ethanol, brme. amyl chloride. dlamyl sulllde and H,S 1656.
hr test

Amyl Mercaptan
-

Amyl Phenol

176

80

Amyl Phenol

392

200

AfUllW

100

75

24

AlUklle

~~~~~~
Amsole (Methyl Phenyl
Ether), Boron irdluorlde
Anodizmg
Alummum
E
G
S
B
U

Soluhon.

;:

302

180

Less than 2 mpy (0.05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy (0 25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy 10 51 mm/y) to 50 mpy (121 mm/y)
More than 50 mpy I1 27 mm/y)

200-270

392-518
1::

Amkne Sulfite

16
24
[

150

1 -

82

6 P -

E*

m lkqutd and vapors ol dlsbllabon column


pounds, water and a trace 01 H,S
E

varws orgamc syntheses. lerbary amyl phenol. amylene. ddertwy amyl


phenol, trace BF3.ether: t.nonyl mercaptan. sulfur. hydrogen sulfide
dlterhary
nonyl.polysulflde.
magnesm.
dlphenylamme.
monene.
nonyldlphenylamme.
styrene. trace 98% H,SO,. clay, vapor phase

, various organic synthesis tertiary amyl phenol. amylene. dltertlary amyl


phenol, trace BF,-ether. t.nonyl mercaptan. sulfur. hydrogen sulhde.
dlterbary
nonyl.polysulflde,
magnesia.
dlphenylamme.
nonene.
nonyld~phenylamme.
styrene. trace 988 H,SOI

--

plus CS,, H,S. mercaptobenzol.

j -

--

plus some other amyl com-

SO,

blown mto 10 percent

1anhydrous.
18 5 percent

thwole

and others

Alloy C = I 0 mpy

sn~lme 011 I water

32 days

HPO,

plus 3 percent

H,CrO,

m lead+ned

tank

Bolllng Pmnt

(continued)

673

Nonferrous Metals and Alloys

TABLE 5.18:

Conosiv~
Anbbmbc
Fermentation

NICKEL-BASE

COMSW
tntion.
ptrcmlt

Ydia

ALLOYS-CABOT

WROUGHT

Temprntun
dw.f

HASTELLOV~
G/G-2

d-C

PRODUCTS

(continued)

TYpr
316
Stain-

lky

WC-276

Ins

SW

Conditions

Media

habc halocarbons.

anhydrous

hydrogen

fluor,de and

Anhmqny

Salts

-58.212

.50-100

vapor over mlred anbmony fluorochlor,des [SbFxCl(S-xi].


refluxmg
condensate of ahphstlc halocarbons. anhydrous hydrogen fluoride and
hydrogen chlortde

Anhmony

Salts

212

100

mixed anbmony fluorochlorldes


[SbFxCI@x)]
and [ SbFyCI(%y)]. to
which IS alternately added anhydrous hydrogen fluoride and altphatlc
organic chlorides

Aaua iha

B.P

1 482

B P.

Aromabc

Tar

AromatIc

Tar

140

Bawm

Chlarlde

20.25

140.212

60-100

Bawm

Chlonde

to BP

to BP

Atwne

I
Banurn Chlortde
Barium

482

All
20
25
Saturated

Hydrwde

Beeswax Bleach
Soltlo

70
EiP
I500

220

Benzene

All
100

50

90

Benzene

a0

Benzene. Chlorinated

All

1
I

100

Benzene. Monochlor

I -

25 percent

--

I d,st,llabon

process, 167 hrs, welded samples

d,st,llaban

process. 264 hrs, welded samples

60

--

moderate

--

Allay C = 0 1 mpy

104

aerabon

1 E

1-

S
E

s
___

--

--

127iBIB

1-

1Alloy

C=Ol

mpy

160 lb H,PO,. 50 lb K,MnOa and 300 lb H,O per 1250 lb of crude


beeswax Alloy C = 0 19 mpy
I

/ plus 40 percent

1 E

1-

1-

vJ6.P

II

II

l-l-l
I

266

130

1 -

1 Alloy C = 0 1 rnpy

27

--

I DDT producho

140
284

1::

G
S

s
U

_
-1

plus 3 percent

process starts wdh 66 Bi H,SO, and benzene Ftnal product


percent benzene suI1on1c ac,d and 4 percent H~SO,

I65

--

Benzene Sullon~c Ac,d

913

284

140

--

PIUS 3 8 perCent

--

plus 5 percent

Benzo~c Ac,d
BlsmuthLead

269-554

86-95
10

75

200

1 32-2ag)

30-35
24

C
-

1 E

/ -

I -

--

--

43.47

450

232

m produchon

Bleach Liquor

100

lo 125

to 52

contalnlng

El P -

Alloy C = la mpy
acid and 3 percent

both Alloys B and C considered

Black Liquor

Less than 2 mpy (005 mm/y)


2 mpy IO 05 mm/y) to IO mpy (0 25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy 10 51 mm/y) to 50 mpy I1 27 mm/y)
More than 50 mpy (1.27 mm/y)

HISol
suIfur,c

IS 90

water

---

to 240

H,SO,

I still at three wlnts Alloy C = 0 2 ,py I lhquld 0 5 mpy I Ihquld-vapal


0 7 rnpy , vapor

to 464

plus SO,, Alloy C = 0 3 mpy

I Interface.

Eutechc

E
G
S
B
U

Alloy

392

H!O

Alloy B = 44

329

Benzene.Wet

benzene

16-27

90

Benzene Tetrachlor

HCI. 5 percent

60-80

Acid

benzene. 5 percent

I
I

Benzene Sulfonx

92

chlorinated

toBP

Ac,d

Acld

HCI

I -

250

21

HNO,. 75 nercent

Benzene Sulfonlc

Benzene Sulfamc

86

plus 5 percent HCI. 5 percent H,O and chlormated


/mpy,A11oyC=O2mpy

a0

I
Benzene

250

of d,methyl

rulflde

good for long hme use


from black lhquor

avadable chlanne

Bo1hng Point

(continued)

674

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

HWTELLOV~
Conoriw

B/B-Z

Media

IX-276

--

(continued)

TYpr
316
Stainless
Stnf

alloy

Bleach Solubon

PRODUCTS

Conditions
0.044 percent tree Cl,. 0 07 percent available Cl,, 0.025 petcentClO>
hr. test. Alloy C = 1 1 mpy

48.

Boric Acid

= 0 2 mpy (vapor), <o 1

Boron Trlfluorlde

Bracktsh

water

Brass Ptckllng
Solubon
BrarIng

100

140

Flux

Brtflo

1090-1140

2-9

Brtlle

Brme. Saturated

Brme. Saturated

Brme Solubon.
Waste Stream

60

j
I

125.150
140
240-245

--

contams 19 to 28 percent H,SO, and


4 percent CuSO&. Completely
Immersed m solubon m rubber-lmed tanks

--

alkali fluorides

--

plus glue and carbon black, H,SO, added to release fatty acid from soap
addlbon. ptl = 2.0-Z 9, Alloy C = 0 065 mpy

1 -

588-615

115-125

46.52

1
I

/
/

52.66
60
115-118

1to

-/

//

1I

1310

grams/liter

m commercial

dip brazmg furnace

NaC brine plus trace Cl,, pH = 104

--

aerabon

107

42

contammg 23 g/l total dlsolved sollds conststlng


4 4 g/l sulfate p&l. 90 days

contammg MgSO4,. H,SO,, KCI, N&I.


to extenwe
aerabon

also NaTSO,. KCI. N&I.


aeration

195

91

Brme Slurry
contammg MgSO,

196

92

MgCI,, trace of S. pti 7 7. moderate to extenswe

Dry

100

Gas

59

15

--

m eqwkbnum

wth

Bromme

Gas

59

15

--

m equihbrwm

wth Br lhquld Awelded

158

70

--

also 50 2% H,SO,. 21 3% water. synthebc

--

plus Isobutane.

Butane

28 5

Butane

225-250

107.121

Butanes
(Catalyst Cracked)

120.140

49-60

Calwm Carbonate

117

47

C&urn

Carbonate

80

27

Calcum

Chlorate

All

Calcwm

E
G
S
B
U

and

Bromme,

66.371
to 66

of 10 g/l chloride

MgCI,, trace of S, pH 7 7. moderate

Bromme

150.700
to 150

Alloy C = ml mpy

1-1-I

Brme Slurry

Alloy C = 5 6 mpy

11

10% Br water solubon

hydrogen

plus 0.02 percent

chloride

mercaptan

Awelded

samples

samples
butyl acetate lhquors

Alloy C = 10 mpy

sulfur

Bromide

to B P

Less than 2 mpy (0.05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy (0 25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0 51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (127 mm/y)

toBP
BP

calcium carbonate,
11% (by wt)

talcum

calcwm carbonate. calcium sulfate. calcium sulflte and Ily ash all
suspended as about 20% (by
) slurry. pH not speclfled. aerabon

--

slurry.
pH not

sulfate. calcium sulfde. all suspended


spec!fled, aerabon

as 6.

wt

Boakng Pomt

(continued)

675

Nonferrous lwetals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

bntinued

I QPJ I
Conoriw

Concmtntion.
wcrnt

Media

Calcwm

Chloride

Calwm

Chlortde

20

Calcium

Chlwde

29

Calcium Chloride

All
40-60

Tmwratun

dw

12

WC2

d-C

75.85

220

IUS

Conditions

stwl

--I

104

316
*in-

Jlloy

WC-276

24.29
I

HA6lELLOV~

--

E
E*

-_

I-

PIUS a percent methyl ethyl ketone. 1 percent HCI. 0.5 percent acombc
acid
10% KCI; concentrated

brme I potash ertracban

pllot plant.

plus 8 7 percent M&I,, 1 percent N.&l hall I vapor.


Bdtern Process Alloy C = 0 08 mpy

hall lhquld phase,

167.194

75-90

to B.P.
350

to E.P.
177
a2

zmc sulfate 40%. pH 2.8. 35% of ttme. alummum sulfate 3.30%. pH 3.


15% of bme: magnewm
sulfate 40%, PH 3. 10% of hme. zinc chlorkde
40%. pH 1.8. 5% 01 bme, moderate aerahon

21.93

5 solutions. each smgly calcium chloride. PH 2. 35% 01 time. zinc sulfate


40%. pH 1 8. 35% 01 bme, alummum sulfate. 3.30%. pH 3. 15% of bme.
magnesm
sulfate 40%. pH 3. 10% of time. zmc chloride 40%. pH
of bme Moderate aerahon

Calcium Chloride

40

ia0

Calctum Chloride

40

70.200

*shght gam m weight. Specimens

m pdot plant evaporator

i 8.5%

Calcium

Chloride

54

260

127

Calaum

Chloride

55

220

104

-__

Calwm

Chloride

58

329

165

Calwm

Chloride

62

73

Calcium Chloride
Calcium Chloride

Calcwm

Calaum

Chloride
Chloride

Calcwm Hypochlorde
(Lime Sludge)
Calcwm-Magnewm
Chloride Solubons

purlfled
N&I,

0.10 percent

___

partially

___

140 g/l C&I,,

-__

plus Na,S. Na,CO,. elemental

80.90

176.194

21
I

to B.P.

24
to 6.P

60.100

plus t&Cl,
I

purdled
80 g/l NaCI. 2 g/l Ca(OH),
sullur.

m sulfur separator

brme. pH = 5 0

durahon 01test - 204 days, *severe pdbng

I -

I -

I amounts

16-3a 1 -

free Cl = 40 gramslhter.

CaCI,. CaCIO,. CsCD, and lree lhme in small

--

plus free 0 63 percent

--

plus 1-5 percent H,SD, and a t:ace of HgSO,

46

Calcium sulfate. ctklum Carbonate, fly ash. all suspended as 30.50%


wt 1 slurry. pH not spec~bed

47

cakwm sulfate. ctlclum carbonate. fly ash. all suspended as 10.15% (by
wt.) slurry, pH not speclfti.
aerabon

Calcium Pyrldme
Sulfanate

100.150

38.66

Calcium Sulk

115

Calcwm

117

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy 10.25 mm/y)
Over 10 mpy (0.25 mm/y] to 20 mpy (0 51 mm/y)
Over 20 mpy (0 51 mm/y) to 50 mpy (127 mm/y)
More than 50 mpy (1.2.7 mm/y]

--

Alloy C = 2 1 mpy

120.138

CatOH),.

100-104

partially

79

212.220

E
G
S
B
U

plus 1.0-1.3 percent

177

Cone

Wide

--

175

to 50

154

hydrogen chloride recovery. pH about 3 to 4


Durahon of test - 305 hrs = 12 71 days
Aerabon - moderate
Agdatlon - 2-3 ft /xc

350

la.20
I

Hydroxide

310

248.266

Brme

Calcium Hydroxide

Calcwm

--

B.P. -

HCI m Londensate

Alloy C = 6 7 mpy

Alloy C = D 1 mpy

Eolhng Pomt

(continued)

(by

676

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

COOCSllComsiw
Calcium

trstion.
pwcsnt

Ysdis

Sulfate

Tsmpwstws
dw.F

10
-

Clurdeblla Wax

WROUGHXPRODUCTS

to BP

to B.P.

96.221

36-105

Captolactone
and Ammoma
Carbon Olchlotlde

65

I
10

12

C/C-276

SI

SI-

Irs

75

Conditions

6trl
-

--

plus N&IO,.
100.hr. test
G

I -

I - I HCI

&

24

1-

about 25 percent of total).

of caprolactum

plus 25 percent CU. 10 percent heavy organu chlorides saturated wtth


and CIT. about 20-30 ppm H,O. Alloy C = 0.05 mpy

H,SO, and HNO, laud content

664 hn.. producbon

150

CarbonSlurry

B/6-2

250

I
Carbon Dmxtdc

?I7

Stsin-

HAsTELLOv~ Slloy

dW.C

(continued)

m humtdlflcabon
process plus 0.2 percent
10, AlloyC=O.O2mpy

1 - 1plus

SO,, 2 percent CO and some

HCI to a pH of 1.5. Alloy C = 0.02 mpy

11-weektest

100

75
to 300

24
to 149

i
S

---

Carbon Tetrachlorlde

85-87

85.167

30.75

--

plus 13-15 percent chlormated high polymer. 0 08 percent chlorine. 0 1.


0.2 percent HCI Normally anhydrous Alloy C = 2.2 mpy

Carbon

a7 5

185

85

--

plus 12 percent H,O. 0.4 percent Cl,, 0.1 percent HCI Alloy C = 2 3 mpy

--

Ccl, carrwd

--

Carbon Tetrachlorlde

Tetrachlorlde

Carbon Tetrachlorlde
Carboac

932-1112

500.600

an au stream

Acid
I

Causbc (mdd)

0.6

Chestnut Wood Extract


Chloracebc

Acld

Chlotacebc

And

Chloracebc

Acid

4.100

80.90

27-32

---

2.17

60.110

16.43

--

plus 7 percent NaCI, 8 percent


water III neutrabratmn pvxess

150.200

66-93

--

plus orgamc and sulfurous

Caushc

Causbc

40.212

90

73

100

158

to 70
80
100

to B.P
75
to 356

plus tetra sodmm phosphate,


11.5 oercent acldl

ddute NaOCI. some lree Cl,. dilute HIS04

absnrpbon of Cl1 and acldlc matenat from reactor off.gases


tams 1 percent NaOCl maximum

Solubon con.

CHICOOH. 12 percent orgamc salt and


Alloy C = 0 1 mpy

acids and tannm

I23iEIEI-j-1

70

toB.P

E 1

E
s
E

1-1-I
---

24
to 180

T*
E*

20

--

plus 15 percent dlchloracetlc


~0 1 mpy

68

lmonochlotacebc

acid

Chloracebc
Mono

Acid.

Chloracehc
Mono

Acid.

160.180

71.82

--

Alloy C = 14 mpy

Chloracebc
Mono

bud.

ii

77
77
77
140

25
25
25
60

E
s

---

plus 30 percent acetu acid. 1 5 acetyl chloride. 0 5 percent H,S m


mother lhquor (1) no agdabon (2) slow agdatlon (3) fast agltatmn

Chloracebc Ackd.
Mono (Tech. Grade)

Chloracebc Acid.
Mono (Tech Grade)

100

ChloralphenoryAcetlc Aad. 2-4 DI

Chlorethylene.

--

process IS to dissolve 945 grams/liter


agdated wdh ao Alloy C = 0 2 mpy

60.70

16-21

--

Alloy C = ml mpy

250

121

--

producbon
of this acld from monochlorobenrene.
monochloracebc
and. NaOH and H,SO,

100

to BP

to B.P

--_

75

24

--

4 percent HISO,. 3 percent H,O, carotbng solution


day test

1M)
100

75
190

.$

::

51

97

50-180

10.82

--

Less than 2 mpy (0.05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0 51 mm/y] to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

BP

Trl

Chlarme

Water

Alloy C

11

30

Chlormated

(11
(2)
(3)
(1)

86

Chlorlc Acid

E
G
S
B
U

Ill
(21
(31
111

acid and 15 percent acetyl chloride

vapor and lbqud -

somebmes

sobd MCA m water

steam and ammoma

Solupon

dlchlorophenol

present

Alloy C = 0 1 mpy 47.

saturated

plus 3 percent Inert gas (CO? H,. etc


(50 deg F). 09 mpy (180 deg f)

Iwater

saturated

Alloy C = 0 07 mpy

Bollmg Pomt

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

COllCO~Corrosive

tntion.
prrcmt

Media

.18
Amblent

Amblent

Chlorme

677

(continued)

Stsin-

C/C-276

Ins
SW

--

B/B-Z

dq.C
0

Chlorme

PRODUCTS

HASTfLLOV~ alloy

T9mpmtun
dw.F

Chlorme

WROUGHT

Metals and Alloys

Conditions
durabon

of test -

chlorme

smff

plus
HCI and

139

days,

scrubber.

dry chlorine

gas

400 hrs

l-l-l

s*

B*

feed Cl, to dlchloropropene


at 5 ps,g, 672 hrs vapor
phase I Ihquld.
Alloy B = 30 mpy. Alloy C.276 = 13 mpy, Type 316 Stamless
Steel = 32

dry chlorme

--

49.57

140

60

--

w/entramed89

302

150

--

1000 ppm Cl, I vapor


1776.hr
test

75

24

--

60.200

16.93

I - I

68

20 I

Chlorme

76.86

24.30

Chlorine

77.90.

25.32

Chlorine

86

30

Chlorme

120.135

Lt*

organic

actd

mpy

Chlorme
Chlorme

Chlotme

(Wet)

100

Chlorme

IWetl

Chlorme

(Wet)

86 I

30

gas

chlormabon
system
culabng
loop, 3936
-

m alkylbenzene
hrs.

above sodum
cell I fumes
chlotlde.
sodum
oxide smoke
max pdbng
1%

sulfwc

und

contammg
sodaurn
and motst air Alloy

acad and

phase

orgamc

durmg

Alloy

C = 1 1 mpy.

104

40

--

Chlorme

(Wet)

122

50

--

plus hydrochloric
72 hrs

Chlorme

(Wet)

170

77

--

orgamc
test -

Chlorme

(Wet)

185

85

--

I vapor
chloride

Chlorme

(Wet1

190

88

--

condensed
lorated

Chlorme

(Wet)

190

88

--

durabon

01 test -

28 days,

perforated.

Chlorme

(Wet)

190

88

--

durabon

of test -

74 days.

severe

Chlorme

(Wet)

190.1

88

durabon

01 test -

18 days,

moderate

Chlorme

IWetl

I durabon

of test -

202 days.

Chlorme

(Wet)

Chlorme

(Wet1

20;

Chlorme

(Wet)

205 I

E
G
S
B
U

I -

190

I lgoI

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y]
to 10 mpy (0 25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0 51 mm/y)
to 50 mpy (1.27 mm/y)
More than 50 mpy (1 27 mm/y)

88

1-1-I
I

I -

l -

sea-water

and hydrochlorous

sokds. condensed
67 days
space

01 sulfur

separator

water and orga!c

durabon

01 test -

40 days.

durabon

01 test -

203

Alloy

C = 0 3 mpy

l-l-l
l-l-l

sokds.

chlormabon

of polyethylene.

attack under

Plus

H,O.

S. and

durabon

under

of

thlo and

203 days.

per-

spray

salt brme

attack

Duratmn

oqamc

of test -

salt brme

pdbng.

spacer.

spray
spacer

96

acld.

water. shght

condensed
moderate

lmpurabes

spray

I - I I- I- I
96 I

sodurn
0.001 I

67 8 hr test

(Wet)

oxychlorlde.
C = 0 1 mpy.

CII-

-[-I-~T

ntth some

m chloronator

dechlormabon

Chlorme

samples

perforated

water and orgamc sohds/spacer.


attack under soacer

days.

moderate
salt brme

durabon

pdtmg.

of test -

salt brme

18days

spray

spray

(continued)

678

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

kontinued)

Dioxide

SD

10

--

O-l 5 grams/W
CID, plus trace SD?, O-9 grams/Mer
percent H,SO, I spent bquor tank. Alloy C = 0.5 mpy

Chlorme Dmxlde

135

57

--

78 percent GO..
32 percent
flo. rate of 6b g.p.m :351-h,.

Chlorme

Chtorme Dioxide

150-170

60-77 I

E I -

I -

sodwm chlorate
test

Cl0 water and gas. plus 0.2 grams/lder

and methanol

HCI m water

I O.lZmpy

N&ID,,

18-38

aerabon.

ptl=3 5

Alloy C =

chlorate

m pulp

Chlorine

Dloxlde

155

68

--

spent gas m vent lhne of bleach tower. 338.hr

Chlorme

Dioxide

155

68

--

plus 45 percent
bleachmg.

Chlorme

Dlornde

155

68

--

pH q 6.5 spool exposed I headbox I No. 6 pulp washer Kraft pulpstock


plus residual CIO;

Chlorme

Dloxlde

79-85

--

at top of bleach retenbon

Chlorme

(Matures)

15.30

Chlorme

(Mwtures)

Chlorme

(Mixtures)

175-185

Chlorobenzene

60

Chlorobentene

I -

Chlorotenzene.
Mono

Chloro Ethyl Ether,


Ethylene Chlorohydnn

Chlorofluoromethanes

64

59.86

I-llJl

68-85

20.29

169.212

76-100

1 -

40.100

77.338

25.170

302

150

100.180

38.82

grams/liter

tower

cyanogen

chloride.

chlorme.

test
sodium

Alloy C = 0.7 mpy

water (all gas)

I cyanogen

chloride

(CNCI). chlorme.

water vapor (about 1000 ppm)

1 cyanogen

chloride

(CNCI) chlorme.

carbon tetrachlorlde.

I 4c48
I - I E I - I EI

,i

0.020

I 250I lzl I - I E I - I - I
1

t&SO,,

/ -

water (trace)

chloral 40% (tnchloro acetaldehyde).


water not over 0 5% hydrogen
chlortde trace. IpH of water extract 2 01
commerul
aerabon

trlchlorobenzene

vapor. amrnon~a and chlortdes.

11114.lb

ertensw

1 -

stdl system for crackmg DI (Zxhloroethyl)


acetal to vmyl 2.chloroethyl
ethers and ethylene chlorohydrm
Samples m kettle bquld. 300 hrs.

tnchloromonofluoromethane
and d~chlorod~fluoromethane.
hydrogen
chloride 20%. hydrogen fluoride IO%, carbon tetrachlorlde 1%. anbmony
pentachlorade. oxygen. mtrogen. total 5% (all approx water not over 200

3.chlorod~phenylamme,
311.lb
monochlorobenzene
Alloy C = 15 mpy

sulfur.

1 l-lb

lodme. 475gal

ppm
Chlorofluoromethanes

60

100.180

38-82

d!chloromonofluoromethane
and
monochlorodafluoromethane.
hydrogen chloride 20%. hydrogen fluoride 10% chloroform 5%. anbmony pentachlorade. oxygen. mtrogen. total 5% (approx water not over
200 ppm

Chloroform

loo

to B.P.

toB.P.

I -

Chlaromethylphenoxyacebc Acid

99

300

149

--

Chloromethylphenoryacebc Acid

99

315

157

Chloronaphthalenes

100
1W

300.360
300

149.182
149

122-140

SO-60

250

121

Chlorophenol

Chlorophenol.
Dlchlorophenol
E
G
S
B
U

Less than 2 mpy (0.05 mm/yj


2 mpy 10.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy ID.51 mm/y) to 50 mpy I1 27 mm/y)
More than 50 mpy (1.27 mm/y)

6 P -

I
S

I -

I
4.chloromethyfphenoxyacebc
sodurn chloride. water.

acid.

small

ants.

hydrogen

chloride,

4.chforomethylphenoxyacettc
sodum chloride. water

aad.

small

amts.

hydrogen

chloride.

vapor and lhquad m neutrakzabon


l*vaoar and bawd oh&es

;*.

--

m lkqwd and vapor phase dung


from HCI. H,S. F&I,

--

hydrogen

chloride

of free HCI wdh lame

chlormabon

of phenol

trace. water vapor trace. moderate

Contammabon

aersbon

Bollmg Pomt

(continued)

Nonferrous

TABLE 5.18:

Chlaro-Trlfluoro
Ethylene
Chromic

NICKEL-BASE

ALLOYS-CABOT

70.120

21.49

PRODUCTS

--

Aod

Bodmg

Bmbng

--

Chromtc Acid

10

Balkng

Bolllng

to 30
50

to BP
125

to BP
52

Chromic

Sulfate (Bane)

Chromwm
Chromwm

WROUGHT

Sulfate (Baste)

50

130

Sulfate (Baw)

55

150.250

s
S

(continued)

lhquefled plus 1 percent or less HCI and water m trace amounts

120 hr lab test


-

120 hr. lab test

---

--

Alloy C = 0.07 mpy, mdd agdabon

--

4BO.hr

54
66-121

parMy

10

to BP

to E.P

Cltrlc Acid

10

60.180

16-82

--

manufacture

Cltnc Acid

10

80-170

27.77

--

manufacture by acid by fermentabon


Allov C = 4 mov

Cltrlc Acid

10

Balling

Bodmg

--

Cltrlc Acid

to 58

130

--

All

to B.P

Cltrlc

Potaswm

Acid

spargmg

Alloy C = 0

with sucrse. made acld wth HCI

by bodmg sob&on from 15 to 30 Bk. 120.hr

concentrabon
=45mpy

I mpy

test, Alloy C

--

41

mIxed fermentabon tank effluent,


0.08 to 1.2% chloride, pH 5

180

82

clarlfw llqwd m mumclpal refuse mcmerator Water treated wth calverts


coagulant II and ammoma to nommtl pH of 6. moderate aeratmn

90

32

---

105

Clarlfw

Coagulation Soluban.
Synthebc Rubber

-a

to BP

by aerobic fetmentabon

Cdr!c And

Llquld

54

---

test

Chromium
Sulfate

679

Metals and Alloys

sme cltrlc acid salt. 5 to 65% sokds.

plus 0 01 percent H,SO,. 3.3 percent NaCI. pH


dewatermg sklmmer

3 3. m discharge wetr of

CookIng Liquor

13.2

115

46

aerabon

Cookmg Liquor

132

115

46

Ll*

u*

aerabon. specimen

Cookmg Liquor

13.2

300

149

aeration

Cookmg Liquor

13.2

300

149

tJ*

aerabon,

Copper Chlorides

455

234

cuprous
chlwde.
cuprous
pyrrahdone. p_cyanophenol

Capper Cyamde

170

77

--

105

41

coppet smelbng gas contammg 0 75-196 SOI and some sulfurlc acid mfst
(25-100 ppm). eatenwe aeratmn

135

57

copper smelter gas after cookngm a Hz0 spray tower Gas cntalns H20 at
2.5 pH plus sulfuric acld mist (25-100 ppm). extenwe
aeratton

100

30

copper smelter

12% Cu avg. 0.5% H,SO,. 90 days. copper refmmg.

Copper Smelbng

Gas

Copper Smetler

Gas

Copper Smelter

Gas

Copper Sulfate
copper Sulfate
E
G
S
B
U

45

190

BB

160

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy 1025 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy 10 51 mm/y) to 50 mpy (1.27 mm/yj
More than 50 mpy (1.27 mm/y)

00

71
BP

1 -

copper
copper
caushc
sodlum

*specimen

plabng
cyamde
soda =
cyamde

corroded

away 01 war lost

corroded

away or was lost


cyanide.

p.chloro

phenol

methyl

solubon
= 10 z /gal
4 oz /gal
= 2 oz./gal

gas and recycled cookng spray water (pH as low as 7


avg. 2 51 1.1 5% SO, m gas plus parbculate and SO,. eatenwe aeration

I E 112% rulfurtc

acad. 1 free copper

refmmg.

moderate

aetabon

113 days

Eolkng Pomt

(continued)

680

Corrosion

TABLE 5.18:

Resistant

Materials

NICKEL-BASE

Handbook

ALLOYS-CABOT

WROUGHT

CWtCantntinn.
percent

de8.f

dq.C

B/B-2

Copper Sulfate

All

to BP

bJ8P

copper

Sulfate

150

66

copper

Sulfate

160

71

Conoriva

Media

Temperature

HAnELLOr~

--

1 -

149

creosote or1

329

165

Cresvhc Acrd

All

I toBP

I
1

toBP
30-180

I
1

s
-

Acrd

100

I s
1 s

l-l-l
1 -

Conditions

electrolyte.

1cornstarch

194 g/l &SO,.

40-70 grams/hter

49 g/l cuso,.

CuSo,. 3-6 grams/hter

acrdrfied wdh HCI tooffof

1 g/l cao
AgrSO,

1.5.1.7.steam

1 plus 7 percent acebc acrd. 2-3 percent propronu

rmecbon at 150 osr


acrd and higher acrds

1 u 1 cresyhc

acrd, phosphorous oxychlorrde, trrcresyl phosphates. hydrogen


chlorrde, alummum chlorrde 1%. pyrrdmes less than 0.1%. Anhydrous.

--

Cresyhc Acrd

113-266

45-130

cresyhc acrd. phenol. lormaldehyde.


sulfurrc acrd. ethylenedramrne.
phosphorrc acrd. sodrum hydroxrde. carbon droxrde. ammoma. barrum
hydroxrde. Corrosrve medra varied from mtxed phenol and sulfurrc acrd at
266F to 20% sodrum hydroxrde at 212F (Batch-baas manufacture of
phenohc resms and varnrshes). moderate aerstron

Cresyhc Acrd

266

130

cresyhc acrd. phenol, formaldehyde,


sutfurrc acrd. ethylenedlamrne.
phosphorrc acrd. sodrum hydroxrde, barrum hydroxide. carbon droxrde.
ammama. aerabon

Cresyhc Acrd

284

140

phenol. phosphorus orychlorrde. trrcresyl phosphate. hydrogen chlorrde.


alummum chlorrde 0.5-l%, pyrrdrnes (1% Anhydrous

350

177

--

plus HrS. H,O and some organrcs I borlrng solubon

350

177

--

Alloy C = 0 04 mpv. some H,S

1 1 E

1 E
1 -

1 1 -

1 E 1wdh or1 field bnne contamrng


1 - 1Ib,
mrxed Lowslana crude, sulfur

Cresyhc Acrd
Cresybc Acrd (Crude)

Crude 011
Crude Or1

I
Crude Toluene

Cumeme

75

Cyanurrc Chlorrdc

Cyanurrc Chlorrde

750.780

1
)

339

145

Cumeme

38

Steel

300

Crwyhc

- less

86-356

15-1.7

WC-276

--

(continued)

TYpr
316
Stnin-

alloy

Corn Starch

Cresvhc Acrd

PRODUCTS

63
399.416

171

Cyanogen Chlorrde

Cyanurrc Chiorrde

Cytnogan
E
G
S
8
U

Chlorrde (Gas)

1 drmethylandme

Alloy C = 0.5 mpy

hydrochlorrde

15 ppm S

refmmg

60.71

---

plus phenol. acetone

207.221

97.106

_--

plus 25 percent cumene hydroperoxrde.


ohenol from cumene

60.160

16.71

50

77

25

176

80

I G I E I-lEl
-

E
E

In lhqurd phase Manufacture

of

toluene. dlchlorocyanurarropropamrde
(C,N,CI,NHCH
(CH,),). sodium
hvdroxrde. sodrum chlorrde 10%. DH 1 l-13. moderate aeration
6

chlorme

water yaw

chlorme.

carbon tetrachlorrde.

water (trace)

carbon

traces of chlorme.

water

221

105

59-86

15-30

chlorme,

8 P -

crude toluene; 235 hrs

m carbon tetrachlorrne or toluene. chlorrne 0 5%. cyanogen chlorrde


(CNCI) 0 3%. hydrogen chlorrde and phosgene (carbonyl chlorrde. COCI.)
traces. moderate aerabon

toluene.
water

Less than 2 mpv 10.05 mm/y)


2 mpv (0 05 mm/y) to 10 mpv (0 25 mm/y)
Over 10 mpv (0.25 mm/y) to 20 mpv (0.51 mm/y)
Over 20 mpv (0 51 mm/y) to 50 mpv (127 mm/y)
More than 50 mpv (1.27 mm/y)

Alloy C ~0 1 mpv

= 0.26 percent. salt content = 3-5 lb./ 1000

140.160

lo
Cyanogen Chlorrde

plus NaOH and water

(about 1000 ppm)

tetrachlorrde.

cvanogen

chlorrde.

Bo1hng Pomt

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

Detrose (Greens) Liquor


Dkbaslc Drgamc Acld
and Thmurea
DI-baac
Orgamc Acld
and
Thloutea
D~chlorethane

D~chloromonotluoromethane and monochlorodlfluoro-methane


Dachlorophenol

315.325

158.163

156

70

156

70

100

to 125

to52

1 -

0.04 N HCI.AlloyC 4.35 mpy


q

H,S In vapor phase


1 aeratmn.

l-l-l
_

4.5% hydrogen chloride. durabon of test - 53 days, lshght attack under


spacer

60

165

74

hydrogen chloride 20%: hydrogen fluoride 10%. chloroform 5%. anbmony pentachlorlde, oxygen. nttrogen. total 5% (all approx.): water not
over 200 ppm

100

250

121

trace 01 hydrogen chloride and water vapor


Durabon 01 test - 36 daqs
Aerabon - moderate
Agdabon - none
Process mvolved - dlchlorophenol

77.212

25.100

--

160.194

62.90

212

--

100

8
-

I 1 E

I -

I - I

1 -

S*

I E I E I EI

146

D!phenylamme

212

I -

145.165

70

I
1

63-74 I
21
1

150.
a

Alloy 8 pdted m Iwd.

tt$O, (small amt. probably) 153 hts

117 hrs. held test, aqueous DMA-HCI

63

Unsymmetrtcal
D~methylhydrazme

G I-lI
E
1 -

30

I
1

2 cycles. hqwd 72 hrs.. vapor 130 hfs, malonomtrde process (pllot plant
test)

E I
E
I

86

Electrolyte

--

E*

26

Dukes Mixtures

I
/

(continued)

Olethyl Sulfate

Dodecylbenzene
Sulfon~c Acld

PRODUCTS

160

D!methylamhne
Hydrochloride
Unsymmetrical
Dlmethylhydrazme

WROUGHT

681

355

Dlethyl Malonate

ALLOYS-CABOT

Metals and Alloys

E 1 tesbng rocket fuels, 26 days


tesbng rocket fuels, 7 days
E

hot wash Ihqud. reacbon product of dlphenylamme and acetone m H8r


catalyst atter adddlon of 50% NaOH to ywld pH 01 12.14. moderate
aeration
plus SOI SO, spent H SD, at bottom 01 sulfonator Alloy 8 = 27 mpy
IlWdl. j2 mby (apot;

S / mdustrlal waste. water. low but wdely varylog concentrations of


hydrochlow
hydrobromlc. sultur~c. sulturous acids. alcohols.
chlormated orgamc solvents pH about 1. moderate aerabon
194 g/l H,SO,. 49 g/l CuSO,. 1 g/l CaD *specimen corroded away or was
lost, llf free

Eplchlorhydrm

EGS8U-

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y] to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y]
More than 50 mpy (1.27 mm/y1

8.P - 8odlng Pomt

(continued)

682

Corrosion

Resistant

Materials

TABLE 5.18:

NICKEL-BASE

Corrosive

Conmltlatton.
Vet

Yedia

Ethyl Cvanoacetate
Ethylene.

Cracked

G%?S

/
I

ALLOYS-CABOT

deg. F

1
j

24
24

77.212

8-8.5

250.365

Ethylene Olamme
Tetra-acebc Acld

M-60

IUS

s
s
s
s

-----

G 1

1-

100.220

/ -

7177

toBP

1 -

1-1-I

121-185

84

38-104

/ lab

test. aaltatlon
acids. CO?, HCI. H,O ptl = 5 0 approx..

Some W@SK

Alloy C =

/ 0127mov

--

m 50 percent ammoma

--

plus 30.40 percent


16.800.hr test

/ -

1 -

1plus

solubon

anhydrlde

Alloy C = 5 7 mpv

O-20 perceot

water, pella (111.and occasional

wilds

traces 01 WI

Alloy C = ml mpy.

Allov C = 72 mpv

sodium hydronde d!ethylene glycol 80% tormmg sodturn dlethylene


glycolate Addlbon of dlmethylamme.
orgamc chloride. tormmg amide

Ethylene Glvcols

Ethylene.
Crude

Conditions

stool

contms

183

(continued)

TYP
316
Stain-

alloy

C/C-276

s
:

25.100

PRODUCTS

160.170

Ethylene Olamme
Hydrochloride

WE-2

2:

to B.P

dq.

75
75

100

Olchlonde

HASTELLOV~

::

Ethylene Olamme
Hvdrochlorlde

Ethylene

WROUGHT

Tompmtun

25
50
70
1Cil

Ethyl Chlorfde

Handbook

Trlchlor

Exhaust Air

156

69

170

77

E
_

--

plus gaseous ammoma

m dlstlllabon

process

Alloy C = 0 03 mpy

saturated wdh water vapor contammg chlorme (low concentration


suspended droplets). sodium hvdroxlde. chromate and chromic
(low concentrat~onl and chloride. extenswe aerabon

and m
wastes

entramed phosphortc acid. sulfuric acid vapor. sullur trtoxlde. mtrous


acid. s~hcon tetrafluorlde.
water vapor. sprayed wth water contalnmg
phosphorlc acid 0 1%. sulfuric acid 0 06%. combined Huortde 0 1% ex-

Exhoxylates
Fabrx sdteners
8 Manufacture

80.85

Fabw Softener
Rx Effluent

94

35

160

71

--

130

54

E
E

E
E

_
_

--

m d~sbllabon from tall 011

--

durw,

90

220.240

104.116

Fatty Aads

100
100

to 275
to 600

to135

Fatty Acads

210

Fatty Aads

455.473

Fatty Acids

I-.

Few

99
235.245

plus 5 percent H&O,.


K&O, and H,O

_
_

*Itquld

Nitrate

IO

75

24

--

2-4

160

71

235

113

E
G
S
B
U

Less than 2 mpv (0.05 mm/y)


2 mpy (0.05 mm/y] to 10 mpy (0.25 mm/y)
Over 10 mpv (0.25 mm/y) to 20 mpy (0.51 mm/y]
Over 20 mpy 10.51 mm/y) to 50 mpy I1 27 mm/y)
More than 50 mpy (1.27 mm/y)

BP

wth

quaternary salt of tallow m isopropyl alcohol wth 1.2% HCI to make


shghtly acld. 18 H,O and Cl Manufacture of fabric softener agltabon Ikhtenmg m!xet. total davs 235 0

Ferric Sullate

Ferric Sullate

of ethoxylates

secondary ammes of tallow dissolved m tsopropyl alcohol. methyl


chloride added to MNTN press and 73% NaOH to keep neutral

/
to 316

36 hrs, samples m c~rculttor i~ne Sulfonabon


chlorosulfonlc acld. HCI evolved

3 percent sebaclc aad. small amounts of Na,SOa.

and vapor phases

lracbonatlon

Allov C = 0 5 mov

ferrous sullate 0.2% sulluw


aeration
slurrv reacbon mature.

acid 0 5&n, pH 1 2. hydrogen peroxide trace.

lab test 68 7 davs. aerabon

Bodmg Pomt

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

683

(continued)

Fert~hzer. Slurry mu

wdh 121 ppm LN 12Oand pttadtustment

mcmerator scrubber. munulpal


mcmerabon. 85 days

E
G
S
B
U

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y)
More than 50 mpy (1.27 mm/y)

BP

53hng

sobd raste.excessoxygen

wdh NaOH.

added during

Pomt

(continued)

684

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

Flue Gas

ZOO-250

WROUGHT

93-121

PRODUCTS

aeration

(continued)

Flue Gas

212

100

etlluent (ram quench chamber mcmerabon


added durmg mcmeraban. 85 days

Flue Gas

300

149

mclnerator
cmerabon,

scrubber,
85 days

mumclpal

01 garbage, excess m an

sokd waste. excess (11 added durmg I-

305

152

water and water vapor. pH 2.0 to 4 0. aerabon

350

177

contammg sulfur oxtdes. nitrogen oxldes. CO, CO?. HCI. 0,. N, and Hy ash.
pti 4 5, e*cess au to support

370

188

400

204

Flue Gas

100.800

38.427

Flue Gas

1100

593

Flue Gas

flue Gas
Flue Gas

ALLOYS-CABOT

Flue Gas
Flue Gas

Flue Gas
~~~

Flue Gas

Fluegas. Power Plant

130.135

54-57

Fluegas. Power Plant

140

60

Acld

Fluoborlc

Acid

Fluobonc

Acid

Fluabonc

Acid

Fluorme

Fluorides.. Fused

750 ppm. CO> 0 7%. H,O 1.3%. bal au

carbon dwde
15%. oxygen 4 7%. ndrogen 804%. (all dry basls) water
vapor abaut 25%. suspended sohds

hot exhaustgases and steam from water sprays oft refuSe Incinerator.
tensw aeration

stack gas from fwtube


operation

32

__-

Flue Gas

Fluobonc

plus 1-5 percent

lrom munwal

1 from mumclpal

wth entralned

aeration

1 E 1 /
E
E

with entrained

149.176

65-80

90.100

32.38

lOQ.180

38.82

--

10 grams/hter

160-209

71-98

--

plus alummum

E.

--E

100
100
100

950

iz
510

G
-

1112

600

---

HCI by volume

burmng 114D ~(4%

sulfur content) m cyclic

reluse. aerabon

H,O and slurry (calcium sulfate. ctlcwm

scrubbmg

sulflte). aeratlan

Ihquor. serstlOn

bone acid

40 grams/lder H,BF, at pti 1 7 to 1 9 m gas washer Powble


Alloy C = 0 2 mpy

H,BF, at pH 3 2.3 4 m spent hquor tank Alloy C ~0 1 mpy


trthydrate

slurry at pH 1.9 to 2 1 Alloy C = 0 4 mpy

*furnace gas atter lhme water spray Penetrabon rate wed


from 0 7 to
2 6 mpy at lower temperatures
Alloy C galned wwght shghtly

NaF-ZrF,. lluorme
IO gal /hr

purge 63 hrs hehum purge 153 hrs fluorine flow rate

140.165

60-74

16

80.140

27-60

--

plus 0 3 percent H,PO.. 0 5 percent SIO,. 83 percent water


mpy

Fluos~l~c~c Acid

20

130.140

54.60

--

m fume scrubber

Fluos~kc~c Acid

25
50

75

24

S:

11

70
1

75
75

24
74

s
s

---

245

119

--

Formaldehyde

Il.13

traces of HF

Fluos~kc~c Acld

Fluos~kc~c Acid

wet process H,PD,.

lhquld phase, 49 days. extenswe

Less than 2 mpy (0


2 mpy 10 05 mm/y)
Over 10 mpy ID.25
Over 20 mpy (0 51
More than 50 mpy

aerabon
Alloy C = 2

Alloy C = 5 mpy

plus 0 2 percent lormlc acid. methanol. ketones and other aldehydes


138.day test wth agltahon

E
G
S
B
U

ex-

reluse mcmerator

plus I 5 percent
--

b&r

and CO,

and no aerabon

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 rnpy (127 mm/y)
(1.27 mm/y)

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

Formaldehyde
Formaldehyde

12-15

Formaldehyde

20
50
70
100

Formaldehyde
Formaldehyde

to
to
to
to

BP
B.P
BP
BP

--

--

;
s

11
--

--

S
s

135

plus traces of formic aud. calcwm formate. and glycols. 07.day test nn
battom of fractmnatmg tower 87.day test at center of tower
plus 2 percent lormlc acid, 2 percent ~arws alcohols, aldehydes and
resms. Alloy C = 7 mpy

plus lo-15 percent volatdes (ethanol. acrolem acetone) and 0 1 percent


formic acid. 71.day test wdh agdatlon and no aeratmn
plus 10 percent methanol and 0.01 percent formic acid. 2%day test wth
moderate agitation and aeration Alloy C = 0 04 mpy

E l-l-l

214

101

--

10

150

66

--

150
150
150

66

G
G
E

;
E
E

11
---

25

Formic Acid

a4

Formic Acid

88.90
25
100

BP.

217

GaseousStream

EGSBU-

to
to
to
to

--

20
40
6o
85

50

Gasolme

B.P.
BP
BP
B.P

(continued)

plus 0 5-l 5 percent formaldehyde, resms. higher glycols Alloy C = 0 4

FormvzAcid

.E

PRODUCTS

2 l 300l 14g
I - I E I - I - I mov
10

Furfural &due

135

5o

10

Furfural

275

122

Formic Acid

40

Formic Acid

FormvzAnd

104
117

275

Farmlc Acid

WROUGHT

220
243

20

I
Formic Acid

ALLOYS-CABOT

B.P

103

ii0 I

217

103

--S

BP
75

B.P
24

S
S

---

EI I

230

100

38

1 -

--B

Immersed, 96 hrs

I Alloy C = 8.1 mpy


Immersed. 96 hrs

-Immersed. 96 hrs
-

I -

I -

*plus one percent acetlc acid and one percent formic acid and I trace of
acetaldehyde and CO,

I plus 40 percent H,O. 3-4 percent H,SO,. traces acetic and formic actds

4 550% Oz. lo-12% P,OI, 3.15 0 H,O and (small

302

685

100

325

Less than 2 mpy (0 05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

163 I

E 1 -

I -

I straight run. crude, etc

in lhquldand wpor phases. 630 A P I 105 pslg

e P - EtodmgPomt

(continued)

686

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

bntinued)

bP

Cmcmtntion.
pmmt

Cmmsin Mdia

acF

100

GlYCerhle

75

B/B-?

w.C

24

1301

316
6th

alloy

C/C-276

E/ElG

25.30

140

60

--

Hexamme

:o
40
80

140
130
140

::
54
60

;
E
E

11
---

Coeditioes

I--Is1

Hexamme

80

ti
-

266

30.35

GlYOXd

HA6lEuOv.

rm

1%formic acid: 2% glycohc acrd: 3% formaldehyde: 10% ethylene glycol.


505 hrs.. lab test, glyoxal strlppmg system
plus 0.5 percent methanol, 0.5 to 2.0 percent formaldehyde. O-O.3
percent NH? ptl = 11. Alloy C = 0.02 mpy

Hexamme

Hexane Vapor

I -

I 257I 125I - I E I - I - I

Hexone

Herone

Room

Room

Hydrobromrc Acrd

48

Hydrocarbons.
Short-cham

Hydrochlorrc Acrd

Ddute

Hydrochlwrc Acrd

(1

Hydrochlorrc Acrd

<l

1
1

Hydrochlorrc Acrd
Hydrochlorrc Acid

140

Hydrochlorrc Acid

2M

Hydrochloru Acid

2M

B.P

60

Room

8.P.

90

32

50.90

10.32

O-150

Room

21.66

320

160

a0

27

1
I Bolllnfl I

aolllrll

1 -

--

I -

1 -

I -

low bodmg vapor from tall 011plus 0.3 percent S02, 5 percent H,O. Alloy C
CO.1mov

12mofr/hter

HCNS

wdh 2 mols/hter HCNS. prod&on

1-

--E

1 plus 0 1 percent formaldehyde, 0.1 percent NH? Alloy C = 0.3 mPy

ethylene methane. acetylene. ethane. propylene. propane. some butane


and hrgher h~~drocarbons:hydrogen. carbon monoxrde. carbon droxrde.
hydrogen sulfide; oxygen. ndrogen, water, heabngod. moderate aerabon

--

plus ammonm

sulfate III enzyme bath Allov C (0 1 mov

--

1
I

1 -

1-I

ILI

1 U* 1 drssolved. Lab test

plus
organrc acrd. phosphates. sulfur compounds in pepsm extraction

1 -1-I-i

of HF (Zr free), 2-5 days

plus Fe& and other salts pH = 3.5-5. Alloy C = ml mpy


Cl*. CO a CO?,22 days

--

contammg approximately 1 mol NH,CNS per hter


production of Hf (2, free)

Room

Room

--

Hydrochlortc Acrd

140.176

60.80

m ethanol. ethyl sdrcated reactor, 120 hrs.

Hydrochloric Acrd

150

66

U*

*drssolved. Lab test

Hydrochloric Acid

150

66

Hydrochloric Acid

200

93

--

tfydrochlorrc Acrd

200

93

I -

120 hrs.. lab test


aeratmn

1-

I ferric chlorrde. Iconc. not stated). consfderable wiltloo

Hydrochlorrc Acid

EGSBU-

Less than 2 mpy 10.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy ID.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

6.P - Bolllog Pomt


M - Molar

(continued)

Nonferrous

TABLE 5.18:

ttydrochlonc

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

Metals and Alloys

687

(continued

Acid

Hydrochloric

Acld

35

160.170

71-77

Hydrochloric

Acld

36

Ambent

Ambtent

Hydrochloric

Acld

Hydrochloric

Ac!d

Hydrochloric

Acid

Hydrochtorlc

Acld

40

76

25

Room

Amblent

Room

60-212

Ambent
16.100

I
Hydrochloric

Aad

lo4

4o

Hydrochloric

Acid

140

60

Hydrochloric

Aud

140

60

Hydrochloric

Acid

226

108

Hydrochloric

Acid

Hydrochloric

Acid

662

350

800.1000

40
45
55
:
All

427.538

120
Room
75

49
Room
24

110
90
to B P

43
32
to BP
Room

Hydroftuwc

Aud

Room

Hydrofluorlc

Acid

10

140

60

Hydratluarlc

Acid

14

115

46

Hydrofluonc

Acid

Hydrafluonc

Aud

Hydrofluarlc

Ackd

65

140

60

Hydrofluorlc

Acid

70

60.140

16.60

Hydrofluorlc

Acid

E
G
S
8
U

Room

Less than 2 mpy (0 05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy (0 25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy (0 51 mm/y\ to 50 mpy I1 27 mm/y\
More than 50 mpy (127 mm/y)

30%. sulfurx acid 10 to 40%. nltrtc acid 10 to 25%. sodturn hydroxide 1 to


40% sodwm carbonate. dlchlorobenrene
2 to 5%. pomalus acid and
fumarlc acid less than 5% mono- and dlnltrobenzenes and arMme. trace.

Room
BP

Bolllng Point

(continued)

688

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

COilCMlCorrosive
Hydrofluorlc

Media
Acid

WROUGHT

HASTELLOP

Temperature

tntion.
oerceot

deg. F

140.165

den. C

WE-2

60.74

PRODUCTS

Y*?

alloy

Stainless

1WC-276 1 G
G

(continued)

Steal

Conditions

Il.13% lluos~l~c~c
sod plus undescrlbed

phosphow
Hydrolluorlc
(Anhydrous)

Acad

.I0 to 300

Hydrolluorlc Acld Barnum Fluoride

_
-

68
248

Hydrofluorlc Acad [Boron


Trlfluonde Catalyst)

-6
68
176
248

.2l
20

G
B

1;:

--_
_

Boding

Bollmg

--

1-

Hydrofluorlc Acid,
Chemical oure

60

-23 to 149

o-100

Hydrolluorlc
Mixtures

Actd

40
-

.10 to 300

Hydrafluosdlclc

Aad

Hydrolluosdw

Acid

Hydrolfuosdxlc

I- mm-~Pim

10-11

Actd

120

I60

1 G 1 -

12-13

160

43

71

71

Hydrolluosdwx

Acid

30

100

38

Hydrofluosdnc

Acid

35

80

27

40% H&O,,

209b H,O moderate

(except HNO,-HF) anhydrous


100 to 0%

I G I concentration
1

E
G

plus

rest nitrogen

1spool

aerabon

hydrofluorlc

sod 0 to lOO$. suIfurIc

sod,

faded

lmpurdles

from wet process phosphaw

acid

lmpurltles

from wet process phosphoric

acid

plus 22 percent hydrolluorlc


acid producbon

(ortho-. para-. and melaxylene

(except HNOI.HF) polymernbon


of a proprietary orgamc man aromabc
solvent wdh a BF, catalyst. HF & possibly fluoborales present Open to
moisture and air. HF attacked glass m vapor area and glass has spalled
from surface during 350 hrs. ol actual exposure. extenwe
aerabon

---

hydrocarbons

hydrocarbons

1 - 130days

-23Ia14gI

B I -

aromabc

4 days, vapor phase purged wdh 1% oxygen.

l8

born wet process

100.0~

plus bquld aromabc


ethyl benzene)

65

-I---I -

~mpurmes
aeration

_
_

/(I
I GI-IsI

80

Acid

H,SO,,

HFBF,(ascalalysl)
plus hquld

Ambient
Amblent
Amblent

Hydrolluorlc
MlXtUreS

acad Llquld phase, extensive

acld and 0.06 percent H,SO, in fhydrolluorlc

plus 4 7 percent NaCl solubon becomes saturated wdh Na,, SIF, Alloy C =

--

32 mpy
Hvdrolluosdw

Acld

Hydrolluosdlclc

Aad

Hydrofluoslllclc
Fumes

Acld

Hydrogen
Hydrogen

Chloride

Hydrogen

Chloride

Hydrogen

Chlwde

Hydrogen

Chloride,

Hydrogen

Hydrcw

12.13%.

imounbes

lrom

wet orocess

ohosohorlc

acid.

some

10.11%. wth lmpurdtes


suspended, aeratmn

from

wet process

phosphoric

acid.

some

salt water (horn estuary), sdvxn tetrafluorlde.


to 2

95

I3

to 700

200.800

Hydrogen

74

55

100

Chloride

I65

to 371
1

93.426

0 to 50

-18 to IO

to4271

s
s*

wdh

phosphow

acid, a~. pH I

-1

1 -

1 HCI resulbng from the decomposdlon of all types 01 we


cludmg polyvlnylchlorlde-cooling
water spray

msulatmn.

in

plus 3 percent acetyl chloride and 2 percent acebc acid vapors Alloy C =

--

76mpy
P-r--~

100

I to800 I

289

143

572

300

Chloride

75

24

Chloride

110

Dry

43

E
-

l-l-l-l
E

--

plus causbc soda I plasbc synthesis.

--

moisture m gases evolved, concentrabon


atmosphere, considerable aerabon

I -

IGl vapor

600

316

--

Hydrogen Chloride and


other gase, and vapors,
umdenbfled

800

427

B = 1 6 mpy m

Alloy C = 0.01 mpy


low but not speclfred

(almost all HCI) leed to fracbonator IS normally


phosgene (COCI,) and 23.6% monochforobenzene

I-

and am~nes. Alloy

Hydrogen Chlorade and


other gases and vapors.
umdenbfied

E
G
S
B
U

plus anhydrous orgarwhlorosdanes


lhquld and 15 mpy m vapor.

--

lndustrlal

0 4% HCI 70%

Less than 2 mpy (0 05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy 10.25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0.51 mm/y]
Over 20 mpy 10 51 mm/y) to 50 mpy (I 27 mm/y)
More than 50 mpy (127 mm/y)

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

Metals and Alloys

689

(continued)

,r-

h-rosin

Yadia

COnCOiltntion.
pwnnt

kmpntun
F

dq.

HASlELLOr~
GIG-2

dw.C

316
Stain-

alloy

W-276

loss

Conditions

Stnl

Hydrogen Chloride and


other gases and vapors.
umdenbfled

800

427

Hydrogen Chlonde and


other gases and vapors,
umdenbfled

1300

704

--

Hydrogen Cyanide,
Hydrocyamc Acid

122
224

50
107

Hydrogen

100

to 1000

to 537

--

110-130

44.54

to 100

to 38

--

lodme

All

to B.P

to B.P

--

Moe

572

300

--

pressure of mdme 400 mm Hg

lodlne

a42

450

--lJ

572
842

300
450

E
--_

--

24 hrs
24 hrs

Fluortde

Hypochlorlte

Bleach

lnsul~n Extract

lodme YBPCM
1
Iron Ore Slnter.
Plant Flue Gas and
Scrubbmg Llquorr

105-180

HCN strlppmg

/S

41.82

still feed line and tads Ime. 372 days feed. 672 hrs tads

0.1 grams/ltter CaOCI. 1 5 grams/liter


Alloy C = 0 1 mpy

C&I,.

plus some Protem. fats, HCI. ammoma


0.04 mpy

pti = 7. extenwe

salts. H,SO, and NaCl Alloy C =

pressure of lodIne 400 mm Hg

aeratmn

Isopropyl

Alcohol

11

72

22

plus 9 3 percent mdme. 2 percent non-~omc detergent

Isopropyl

Chloride

50

95

35

811 bubbled through solution


lhquld

Isopropyl

Chloride

80

95

35

83

28

60.75

16.24

--

Bolllng

Ewmg

Kraft Flbers.
(Hardwood or Pme) at 1%
Consistency
La&

Acid

Lactic Acid

10

Lacbc Ac!d

17

Bolhng

Bolllng

Lacbc Acid

All
25.60

to BP
130

to B P
54

S
-

--f

--

E
G
S
B
U

Less than 2 mpy (0 05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy IO 25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (127 mm/y)
More than 50 mpy (127 mm/y)

8 P -

aeration

PIUS 20 percent
E

isopropyl

pH 5-6. low concentration


!de. moderate aeration

alcohol

10% ammomum
acid serwce

chloride

HCI bubbled

of chlorides

plus 0 01 percent melhylene


mpy

Alloy C 0 I mpy

Alloy B = 9 0 mpy m vapor and 32 Ompy m

through

blue and possible Cu

0 4% N&I.

lbquld

and sodium. trace chlorine dlox-

+ tons Alloy C 0 1

115 hrs. lab test. proposed lactic

Bolllng Pomt

(continued)

690

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

hpmtun
Conorivr

Yedia

Lachc Acrd

50

HAsTELLOr~

dw.F
1
Bohla
I
I

dq.

W-2

BolllnaI

PRODUCTS

TYpr
316
StainIUS

llloy

1 W-276
I c

I -

Lacbc Acrd

85

B01hng

Bollmg

--

Lactrc Acrd

90

Bolhng

Bolhng

--

--

-__

Lanol,n Bleach

Lead.B,smuth

Alloy

Lead. Lead Chlorrde

to 464

240

982.1000

526.537

95

LImestone

Slurry

Lrmestone Slurry

Lrmestone Slurry

Lrqurd leavrng bottom


ot Fractmnator

8
-

/
I

30

Lrthlum Chloride

d43

184

Lrmestone Slurry

Slurry

80-110

Lame Slurry
and Caustrc Soda

99

Eutecnc

Levulm~c Acrd

irmestone

210

120

89

107

lZ7

Strl
I G I orooosed
S

49

32

254

123

265

129

260

127

1
1 E

Lrthrum Chlarlde
Sulfate

90

I -

300

149

60.145

16-63

/E

24
to 8 P
79.B.P
to B P

E
E

::
Magnesrum

Chlorrde

30-40

273

134

--E.-

Magnesrum

Chlorrde

51

330

166

GEE

Magnewm

Chlorrde

15% solrds. CaCO plus CaSOl and a small amount of CaSOa pH 3 7-6 7
/ avg 5.6, mode,a;e aerabon

330-335

166.168

Magnesrum

Chlorrde

53

345

174

Magnesrum

Chlorrde

55

345

174

Magnewm

Chloride

85
IOU

266
334

130
168

310

154

Magnewm

Chlorrde

Chloride

Magnewm

Hydrqxrde

E
G
S
E
U

335.355

150

Less than 2 mpy (0.05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy 10 25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy (0 51 mm/y] to 50 mpy I1 27 mm/y)
More than 50 moy (127 mm/y)

168.179

66

8 P -

and monochlqrobenzene

one sample

bal H,O. 2000 hrs. LrCl productron

manganeseore
leach,ng(anax,deandsull,de)

I acrds

out of lour showed

plussullur~candsullurous

Alloy C = 0 1 mpy

1
_

wrth small amounts 01 MgSO,, NaCI. KCI. LICI. lraces of Br 3-48 salads 01
MgSO,. 1 25 H,O. extenwe
aeration
l? NaCl ll? KCI 2% tICI. vapor phase
moderate

120 hrs

aeratrqn and agltatron

I-

llOO hrs wrth MgCI: brine only 1% N&l I+ KCI. Zb* LrCl as cqncentrated from natural Banrwlle
brmes 01 33% solubles Llqurd phase exposure. moderate to considerable aeratran

I
1-

vapor phase above wrth 8.000 10.000 ppm HCI tn condensate

/_

wdh 1% N&I.
I% KCI. and 2% LrCl as concentrated
Bonneville brmes of 33% solubles

_
-1
/

from

I open-pan evaporator Cancentrat,on expressed as MgCl> 6H.0


= 0 1 mpy 165 percent1 0 3 mpy (100 PercentI

natural

Alloy C

in vapor phase - vapors over 508 MgCI, wth 500 to 4 000 ppm HCI ,n
condensate and 1 000 ppm MgCI. In lhqurd phase - 50+ MgCl, saiubon
plus IJn NaCl 1% KCI. 2% LICI Concentrat,on of natural Bonnev,lIe b,,ne
lrom 33% solubles to 508

53,>magnewm chloride wrth I+ NaCl I, KCI and 2q LiCl as cqncen


trated lrom natural Bonrwlle
brmes of 33% solubles moderate to cansrderable aerahon

absorptron
seratlon

lree of HCI mostly phosgene

I
Magnewm

lrqm power plant flue gas. 91 days

E
E

lhquor for SO, removal


aerahon

bal H?O. 2000 hrs, L!Cl productron.


shallow prnrng, 1 5 mds deep

--

1
~
1

I water. OH 63-79

flue gas contammg 2 Ibs /mm of SO, pH 3 5-6 3 avg 5 7 91 days


hquor Ior SO, removal from oowe, slant

wually

aeration

/ scrubblne

c:i

CaSO, and lly ash. pH 5 O-6 0. moderate

E
E

excess sullur~c acrd

! -

/I

to BP

75
to B.P
175.BP
to B P

contammg

/E

to B P

10
25

polymer

/ 15% C&O,

j-

10

Chlorrde

lead

I--lEl

Carbonate

Magnesrum

C&O,,

scrubbmg

lead chlorrde. bottom -

/ C&O,

/ E / E 1moderate

Magnewm

mrddle -

H,O, and strong NaOCl

lE

I--E

115 hrs, lab test

added to argamc

I-Ii1
1 E /
I E /

I
Manganese

proposed lactic acrd serwce.

1 -

115 hrs.. lab test

argon atmosphere Top-lead.


chlorrde upper phase

*5

53

Conditions
lactrc acrd serwce.

plus drlute H,SO&. HCI. alchollc caustic soIut,o.s.


bleaches Alloy C = 0 141 mpy

42

(continued)

lhqwd IO, SO. Generates brsulhte COOkl,,g ac,d w/pH

of 5 4

Bolllng Pomt

(continued)

Nonferrous

TABLE

5.18:

NICKEL-BASE

Mwha

COWerItrrtion.
percent

Magnewm

Oxide Slurry

Magnewm

Sulfate

CDrrorive

ALLOYS-CABOT

WROUGHT

T*mpmtre
dw.

25
50

dq.

120

49

to B.P
125.8 P

to B.P.
52.B.P

198

92

616-2

E
E

Magnesium Sulfate

Malac Actd

10
10
100

to 175
BP
to B.P.

to 79
B.P.
to B.P

lo-18

32.40

o-4

Male~c Ackd Liquor


1

Male~c AnhydrIde

Mercurtc

Chloride

10

I to175

326.398

Mercury

All
100

to 800
to 700

to 426
to 371

Methanol

All

to B.P

to B.P

Methanol

Bodmg

Bodmg

s
s

---

_
-

to 80

620-750

Chloride Vawrs

204-285

TYW
316
Stainless
St.&l

llue gas scrubbmg hquor lor SO? removal. 238 days, moderate aeratton

brme slurry contammg MgSO,, Na,SO,.


7.7. moderate to extenwe aerabon

/ t0144 1

60

to B P

Methyl Alcohol

60

165

Methyl Alcohol

95

203

blBP

100

95-113

Methyl Chlortde

95.113

Methyl Chlarlde

100

Methyl Ethyl Ketone

plus phthahc anhydrlde. 1090.hr


trav of fracbanabn~ column

--

1
1

35.45

35.45

210

1
)

---

99

1-

--

methanol

contawng
bubblmg

--

100 ppm hydrogen


through

230

110

---

plus 15 percent acombc

22 5

100.250

38.121

--

plus 2.5 percent

methanol

Methylene

Chloride

40

to BP

toBP

Methylene

Chloride

50

140.200

60.93

--

plus 50 percent

methanol

Methylene

Chlwde

70

120.140

49.60

--

plus 30 percent

methanol.

Methylene

Chloride

Methylene

Chloride

Methylene

Chloride

82.121

195-225

91-107

Methylenedlaxybenzene
Reaction Mixture

221.248

105.120

Ambtent

_
10
E
G
S
B
U

Less than 2 mpy (0


2 mpy (0.05 mm/y)
Over 10 mpy (025
Over 20 mpy (0 51
More than 50 mpy

Ambtent

38.100

180.250

Alloy C = 0 2 mpy

135

H,O. trace al TIC

Chloride

and 8 percent

plus percent phasphorlc acld. 3 percent dtamer. 1 percent vinyl ISOPrODl ketone.
DerCent alcohols

Methylene

Methyldlchlorophosphlne
(Anhydrous)

and 30 ppm water

Alloy C ~0.1 mpy

44

100-212

chlonde

water, 2 0 mpy I vapor phase, 3 0 I lhquld phase

Methyl lsopropanol
Ketone

90

1 G 1 B / HCI 20%.

Alloy C = nil mpy

H,O 5%. 27 days m vapor above solubon. moderate

plus 10 percent

methanol

contammated

CH,PCI, lower cancentrabons methorydlchlorophasphtne.


trlchlonde.
phosphorus
orychlorlde.
triethylphosphate.
aeratmn - one. agltatlon - rapld

aelatIOn

Amblent

Amblent

24

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 mpy (127 mm/y]
(1.27 mm/y)

BP

w/H,O.

contamng

trace Cl,. 195 days

aeration

Alloy C = ml mpy

75

acetic acid,

plus 4 Percent HCI, CH,CI bubbled through Vapor phase = 16mpy. lhqu!d
=55 mpy

H,O. 2 percent

1 - j phase
j E /

32.38

275

5 percent

plus 15 percent methyl acetate, 23 percent acetone. 0 03 percent acebc


acld Sllaht [lltbn~

90.100

recovery column stock solutions sent to lab for

wth 10 percent acetaldehyde.


traces of acetone and alcohols

77

75

at top

plus 20 percent ethyl acetate, 18 percent methyl ethyl ketone. 15 percent


acetone. 6 percent acetaldehyde.
14 percent low boders trace acetic
Iacid
AlloyC=OOlmpy

Methyl Ethyl Ketone

test I vapor veloc#y of 7 ft /set

N, atmosphere.

1 E 1 -

38

phthakc acid Alloy C =

air-free mtrogen atmosphere. Mercuric chlortde IS present as 10 percent


welghtpercentafvarylngamountsof
acbvsted carbon Alloy C= 1 1 mpy

1-j-1

qwnone.

--

E / E

74

plus small amounts of alpha naphtha


02mpy

l-l-l

--

E
_

-I

g5
Methyl Chlonde

KCI. N&I. MgCI,. trace of S-, pH

_
_

Methyl Acetate

Methyl Acetate

Conditions

Mercuric

400.545

WC-276

kontinued)

PRODUCTS

HA.SYELLOY~ alloy

691

Metals and Alloys

aerabon
phosphorus
76 days

Cl>, 166 days

Bo~lmg Pomt

(continued)

692

Corrosion

TABLE 5.18:

Corrosive
Molybdlc

Resistant

Materials

NICKEL-BASE

COnCOIltntion.
QWCU,t

Media

ALLOYS-CABOT

WROUGHT

T~mparatun
dq.

Aad

Handbook

HASTELLOV
dq.

300

149

B/B-Z

C/C-276

10

to B P

to B P

---

Monoethanalamlne
Hydrochloride

30

150

65

204

95

Monomer & Otmer


fattyAcids from Tall
011 Purlflcatlon

537.550

281.288

Morpholme
Mlxture

Reaction

_
-

156
392

125
200

Morphollne

Sulfate

374

190

170

77

Naphtha.

100

Naphtha

96

Solvent

Naphthalene

160

75
/

160-180

180

71

Naphthalene
Acid

Sulfonlc

180

82

6
u

--

--

43
200

G
B

1
82 1

110
392

potasswm,

m methanol,
1

or ammonium

72 hrs, lab test

1 N, atmosphere.

72 hrs., lab test

aelatIon

88 hrs, lab test

141 hrs.. lab test. valves for morphohne

/ E 1

j water
drammg

from marble scrubbmg.bed


plus direct spray of neutral
H?O pH = 2 0.3.5 Municipal garbage lncmerator flue gas scrubbing,
moderate agttatwn. extenwe
aeration 51 days

--1

/ in vapor space of still column

1 G / _ 1 s j organtc
condensabon

650-750

80

200

554

I 2go
/ u I a I - I I

93

E I -

I -

01 naphthalene

evolved

I vapor phase

crude 011 m flash sectlo ol

l-l-1
nickel chloride leed tubes to converters
unstressed spectmens
nickel carbonyl.

05 mm/y)
lo IO mpy (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 mpy Ii 27 mm/y)
(1 27 mm/y]

and HCI vapor

dlstlllatetower
from Al,Oy
heavy
contalmng
/ in
vacuum
c Iasphalt
ol mpY

Some mtrogen axldes powbly

product

lormaldehyde. condensation product 01. Ca(OHl,. NaOH CaSO,. Na?SO,


natural aeratwn through agltabon

25

343-m /

sulfate serwce

from secondary chamberafterpassmgthrough


scrubber marble bed plus
entraIned hquor at pH 3-4. extenwe
aerabon

productlon

Nickel Chloride

Less than 2 mpy (0


2 mpy 10 05 mm/y)
Over 10 mpy 10 25
Over 20 mpy 10 51
More than 50 mpy

71.02

_
_

Chloride

E
G
S
B
U

sodium,
--

24

Naphthalent?

Nickel Chloride

Conditions
formed by reaction of MC&. oxygen and 5% HNO, H,SOI ccmc goes to
20% Jacketed vessel allows heabwcaolml!
Extenstve aeration

Mumc~pal Garbage
lnclnerator flue Gas
Mumc~pal Garbage
lnclnerator Scrubbing
t1quor

(continued)

TYP
316
Staintws
SW

alloy

Mono Phosphates

Monoethanalamlne
Hydrochloride

PRODUCTS

nickel hexammlne

chlwde.

in an Amlnco
ammomum

bomb, pH 3 4.
carbonate.

am

BP - Bolllng Pomt
M - Molar

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

Nitric Acid

63

Nttrx

Acid

65

150

Ndc

Aud

65

Boding

Boding

Ndc

Acid

72

177-163

Nitw

Acid MM

25

177-183

120

Ndnc-Sultunc
Acid Mixtures
Nltc.Sulfuc
Aud Mxtures

Nitrldmg

Gases

WROUGHT

49

66

PRODUCTS

15% by wt. (20% by vol.) 40 Edor

120 hrs.. lab test

120 hrs.. lab test

81.84

6% H,SO,

81.84

25% phosphate

All

la5

B / -

1000

538 1

El

lWI

UIGI-l-l

RoomI

Et--I--I
plus chlora-beta methyl qunone. copper chloride, 5 percent HCI I stripp!g ltrobenzene from orgamc solubon Alloy C = 2 6 mpy

I -

of HCI. ndrous

oalde, and tsopropyl

c~rro~~~ rack test (m plant). balance O,, H1O. N2

dlnonylphenol
0 6%, water 0.1% mu, nonyl and dmonylphenol
rulflde
67.73% and process 01125%. hydrogen chloride a few percent (Corn.
poslttons of hquld phases)

75

24

contalnlngddutesulfurlc
acid (pfi 1.8) and possibly somecarbon
90 days, moderate aerabon

to B.P.

20
20

Oleum

20

40

Oleum

75.120

Orange Jwce
All

125.150
125.150
50.90

52.66

100.125

38.52

10

BolkP

20

110

1.32 parts to one part dodecyl


1

I -

to B.P.
29

--

43

pyrldlne

I detergent

6o

E I -

B.P.

B.P

--

Oxakc Acid

All

to B.P

to B.P

--

Oxahc Aud

Oxldlzlng

100

140

60

to 1600

to 982

--

285

141

1.5M

323

162

114

46

benzene and SO,

vaoors m sulfonatlo

of ovndme.

and 2.5 percent water I sulfonabon


manufacture.

of pyrldlne

Alloy C = 0.1 mpy

HNOl

25 to 98% HNOI. trace HF

wdh pecb

lhquor

to which II added 93% H,SO, (approx 10% when diluted). pH lesstha


plus calcium oxalate and calwm
sulfate, moderate aerabon

-1-I

Sat,. Sol.

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 mpy (127 mm/y)
(1.27 mm/y]

I - 1plus

--

Oxahc Acid

1 vaoors DIUS pwdlne

plus 4 percent
G

El--I--I
-

---

Bolllna

--

140

to 60

85

--1

B 1 -

IO-32

dfoxlde.

---

1
1

30.120

Oxakc Acid

45

52.66

to140

Oxakc Acid

Oxakc Acid

52

1
1

86-248

to B.P.

6.75

to 6.P.

125

1
1

25

Oleum

Less than 2 mpy (0


2 mpy (0.05 mm/y)
Over 10 mpy (025
Over 20 mpy (0.51
More than 50 mpy

productlo
from reacbon
Alloy C = 2.5 mpy

dung

I - I alcohol,

171

Oleum

Paper MeachIng

by vol of 50% tf$O,


50% HNO, added to H,O and heated to 200
deg. C for-18 hrs then cooled and exposed I 20% by vol of 50% HNO,.
50% HCIO, added to H,O and heated to 200 deg. C for 12 hrs

416

Oleum

E
G
S
B
U

.50%

20% by vol of 50% H&O,


HNO, added to Hz0 and heated to 200
I deg C for 18 hrs. the cooled and exposed I 16 5% NaOCl at 170 deg C

340

100

Paper, Alkakne Pulpmg


CookIng Liquor

4% HISOl

20% by vol 01 50% HrSO,


50% HNO, added to H,O and heated to 200
deg. C lor 18 hrs the cooled and later dried at 170 deg. C I 10% C102

780

Olelc Acid

Paper, Acid Pulping

(dehydrate)

10

Gases

dichromate

/ B / 20%

212

Room

Od-Water Emulslo

Orthoformyl Benrenesulfontc Acid

I B I

rock, 24% H,W,.

2% sodum

60.75

Natrous Oxide

Organic Chlorides

B I -

200

Oleum

Nonylphenol

392

I
Ndrosyl Chloride

la5 I

85

Nltrobenzene

I
365

(continued)

365

693

slurry

I E I modeiate

35% sulfuric
aeration

acid.

calctum

oxalate.

calwm

sulfate.

pH 1.

acid.

calcium

oxalate.

calcium

sulfate,

pfi

slurry, 35% sulfwc


moderate aeratlo

cookmg Ihquors: acid sulfate. sodwm

oxygenated

0 01% chlorme.

sodwm

1.

hydroxide

base; alkalme.

pulp dlgester

trace chlorme dloxlde

I,

Kraft

liquor, esterwe

aeraio

pH 5 5 to 6.0, moderate aeratlo

6 P - Elolllng Pomt
M - Molar

(continued)

694

Corrosion

TABLE 5.18:

Resistant

Materials

NICKEL-BASE

Paper Bleachmg

Paper aleachmg

I
I

Paper Pulp, Bleached

145

150

1.5

Paper Pulp, Bleached

135.165

/
I

Paper Pulp Slurry

ALLOYS-CABOT

Paper Stock

135-165

/ -

/ E I

I - I E I - I El
I 57-74
I - I E l - / El
66

57.74

1-

--

0.15 g/l HCI. 0.02 g/l free chlorme

--

Kraft pulp stock. pH 9 5.10. moderate aerabon. flow rate of 4500 g.p m
337.hr test

___

G /

to 52

1
I
1

21
to66
24.100

sulfonatmn of peanut and corn 011


plus traces of HCI. moisture and air Alloy C = 0 8 mpy

j-1-1

eXtraCtlooOf pepslo with one percent HCI and org.WWaCodS.pH 4 a-7 0

1-

--

I u I

302.320

150.160

125
125

380

193

_-_

Phenol Formaldehyde

212

100

Phenol Formaldehyde

265

129

260 /

Phenol D&&mate

Phenol, Paraterbary
Butyl

90

Chlorme - 01%. pH 5 5 to 6 0
Ourabon of test - 58 days
Aerabon - moderate
Agdabon - moderate
Type of test - field
Process mvolved - paper pulp bleachmg

j-j-1

30

extenswe

86

Phenol

5.5 to 6 0. 95 days. aerabon and @bon

95

calcium chloride 0 3%. residual chlorme dmxlde 002%. pH 5 5 to 6 0, ex


tenswe aerabon

121

Phenol

atmosphere over ( 1% slurry of paper pulp, 001% chlorme. trace


chlorme dwde, pH 5.2

1 1 5% CaCI. ptl

250

Perchloryl Ffuorlde

paper pulp 1% slurry, 0.01% chlorme. trace chlorme dloxlde. pH 5.2,


moderate aerabon

68

Perchlaroethylene Carbon Tetrachlorlde

24

to 125

72

75

1 70
I to150
I 75.212

155

Perchlone Acld

63

atmosphere over a 1% slurry of paper pulp; 0 05 chlorme. trace chlorme


dwde. pH 7 0. moderate aeration

Peanut 011

I - I E l-l EI

(continued)

46

Pew

PRODUCTS

114

Pacer Stock

Pentane

WROUGHT

56

132

Paper aleachmg

Handbook

HCI and Cl,, durabon of test - 47 days


E

519 hrs.. lab test. tank placed m air cabmet

___

plus 5 percent acetaphenone. mildly bolllog solution


chlorlnabon Process exposed 19 days I llquld phase
phase

/ z / 1 I ewwd19 days mvapor

plus I1 percent phenol and 1 percent AICll


sulfwc acid. phosphoric acid. Ikme. caustic. moderate aeration
~Durabon of test - 107 days
Aerabon - present
Agltatkm - present
Type of test - held
Process mvofved - phenokc resm
Remarks - vapors present mtermdtently dung operabog cycle.

500

I -

I -

plus formaldehyde turpenbne. boron trlfluorlde. and oxahc acid m kettle


AlloyC=OZmpy

Phenol Sulfomc Acid

Phosgene Vapor

122

50

Phosphow Acid

0.5

60

16

---

Phosphoric Acid

3-14

150

66

EGSBU-

984 hrs, lab test


H,PO, catalyst plus orgamcs

--

small amounts of fluorme compounds

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y] to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

m 3.4 hn. heatmg cycle

plus newsprmt

Phosphoruz Actd

35

350

177

Phosphoru

Acid

36

100.111

38.44

2 9 percent

Phosphoric

Acid

36

172

78

2.9 percent H,SO,. 350 ppm chloride.

Phasphonc

Acid

40

158

70

129% P,O,l. sulfuric acid 2.3%. slurrv contams 2.3% calcium sulfate
blhydraie (gypsum). 0.5% fluorine &pounds
as hydrofluosdlclc acid,
metalhc compounds

Phosphow

Acid

40.80

225

107

--

Phospharlc

Acid

45

Phosphoric

Acid

45

Phosphortc

Acid

Phosphoric

Acid

I
1

Phosphortc

Acid

Phosphonc

Acid

63.68

266

/
I

ZOO.300

145.155

45
50.55

1
I

230

50
52.5

25.130

77.266

1
/

695

Metals and Alloys

1 -

IEi-1
/ - 1 -

contamma
/ I wetvaoors

/ 1mmened96~hrs.

130

93.149

sulfuric

113
45

acid 45 percent.

G 1 -

-I

G lEIGl

some hydrofluosdwc

aud

some HF, 30 percent gypsum

plus lo-20 percent HNO,, lo-20 percent ZnO, 10.20 percent Na,CIOI, 5
oercent NaSO.. Allov C = 0.4 mov

/
I
1

1
I

11101

H2S0,. 350 ppm chloride.

1half

water 10 percent

m vaoors. half Immersed.

sulfuric

Allov C = 7.9 mov

acid 45%. water 10%


Hf. Allov C = 24 mov

H!PO, (P,O, eqwalent


35%). sulfunc aud 2.9%. chloride 400 ppm
hvdrofluoslhclc
sod trace. fernc phosphate trace, moderate aerabon
HISO,.

Acid

53

250

121

--

plus 1.2 percent

Phosphortc

Acid

54

260

127

--

m fume hood of defluormator

Phosphoric

Acid

54t

310.335

154-168

Phosphoric

Aud

55

175.185

79.85

sofne tluorldes.

Phosphoric

Acid

55

221.261

105.127

(40% P,Or). sulfurtc acid 3 0% (2 5% SO,). talcum sulfate (hemlhydrate)


slurry. fluorine compounds Llquld phase. gases contalnlng H,O and SF.
are evolved Foam dlstrlbutlon process

Phosphoric

Acld

55

221.261

105.127

Phosphwc

Acld

55

228

109

--

Phosphoric

Acld

55

228

109

Phosphorx

Acid

55

237

114

Phosphoric

Acid

562

72
22

Phosphoric

Ac!d

61

176

Phosphoric

Acid

69

Phosphoric

Acid

69

E
G
S
B
IJ

Less than 2 mpy (0


2 mpy (0 05 mm/y)
Over 10 mpy (0 25
Over 20 mpy (0 51
More than 50 mpy

14 percent.

4 3 percent
calcwm

1.2 to 1.5 percent

Alloy C = 5 mpy

Phosphoric

sulfate.

hvdrofluoslluc

reaaent nrade DIUS 0.8% hvdrofluonc


-

0.8 percent
U

and HF

hot wall

ackd

acid

HF

(40% P,O,l. sulfuric acid 3.0% (2.5% SO,). calcwm sulfate (hemthydrate)
slurry: fluorme compounds Llquld phase, gases contammg H,O and SIF,
are evolved

plus

I - I E l-l-l

mdme. nowomc
detergent (nonyl
IIYCOI). and water Alloy C ~0.1 mpv

(44% P,OI). filtered. contammg


hydrofluosdictc aud

81

27

(50% P,O&
hydrofluosdw

212

100

(50% P,OI). fdtered. contammg


hvdrofluosdwc
acld

percent

H2S0,.9F,.

sulfurtc acid 3.0 percent (2.5 percent SOJ. calcium sulfate (hemihydrate
slurry), fluorme compounds

t -

Hf

H,SO,. 48 hours exposure.

80

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy 10 51 rm/y)
mm/y) to 50 mpy (1 27 mm/y)
(1 27 mm/y)

plus 1 percent

phenyl

small concentrations

ether of polyethylene

of sulfunc ac!d and

sulfwc
acid 3.4%. ctlwm
sulfate 3.4%.
acad. alummum compounds. pH about 18
small concentratmns

traces

of sulfuric acid and

P,O5

(continued)

696

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

I
Corrosive

WROUGHT

PRODUCTS

I
COOCmb
tmtion.
pwcmlt

Media

ALLOYS-CABOT

I
lempwtun
d*.

HAslLLLw~
de6. C

G/G-Z

alloy

WC-276

Tva
,r316
Stain-

(continued)

191s

Conditlonr

stni

acid met (0 04. 35 grams 100% H,PO, per standard cubic footor 0 10
86 grams 100% HIPOl per cubic meter (STPII Chloride (20-30 ppm) in
cdy water used I scrubber liquor. extensive aerlt~on

Phosphortc

Acid

70.100

200-212

93.100

Phosphanc

Acid

75

68.212

20-100

Phosphoric

Acid

75

100

38

Phosphow

Acid

75

185

85

Phosphoric

Acid

75

194

90

30 days

Phosphoric

Acbd

75

203

95

30 days

Phosphoric

Ac\d

Phosphoric

Acid

75

Phosphoric

And

75

Phosphoric

Acid

75

75

I
j
I

212

100 I

105

G/--I--I

16-lz7

Acid

82-87

190-215

88.102

Phosphoric

Acid

85-95

165.185

74.05

Phosphortc

Acid

85-95

212.239

100.115

Phosohorrc

Actd

86

Phosphoric

Acid

87-90

176,230

Phosphoric

Acid

87-90

194

Phosporlc

Phosphoric

Acid

Acid

127
190.210

98

390.460

300

Acid

103

I___

101

Phosphoric

Acid

117

Phasphorlc

Acid

118

Phosphorfc

Acid

Phosphoric

Acid
75

Phosphoric Acid
Dehydrated
Phosphoric

Acid Fumes

Phosphow

Acid Mtst

Phosphorr

Acid M~rtures

90

260

Acid

75

39

ptl below 1,140 ppm ASlO, IS lmpwty


Furnace process to produce
phosphoric acid Moderate aerabon. total days - 375 agdatlon - 590
fpm velocdy

pH below 1.140 ppm As,Ol Impurdy.

--

30 days apptox..

I 6 1 -

300
140
1

485

small amounts

B
-

immersed

acid velocity

895 ft /mln

agitabon

acid velocity

895 ft /mm

hrs,

aatatm
-

acid Yelow

895 ft /mm

plus H,O plus S10,l. half I vapors.

present 1s mpr,bes

01 fluorme

compounds

m mnt

E
G
S
E
U

22

Alloy C = 21 mpy

96 hrs

lurnace process
agltatlon none

furnace process (63 to 65% P,O,). trace HCI and NaCl moderate swabon

vapor above phosphoric acid 93 58 167+ P,O,i. wet pwcess. contaNnIng


about 4 3% sullur~c acid and 4 4% won and aluminum oxldes Fluoride IS
oresent below 1 51. moderate aeratton

149

1 G I -

E
S

moderate.

102 days. trace NaCl and HCI erat~on

110

78
90
98
105

_
_
_
_

E
E
E
G

/ 171 percent P,OI) sulfurs acid 4-6 percent. iron and aluminum
trioxides. lluorme compounds 0 5 1 0 percent

/ solids

_
~

1 17 percent.

85 percent

2 8-3 0 ss

0 4 percent lluor~ne

H?PO, IS catalyst 10 polymenzabon


acid = 0 1

reaction

1000 hl$

mol estewmol

P,O,

gases conta,mng HF SIF,. SO,. wth entrained


HISO& 3 70 (3 0% SO,). ertenswe aelatIOn
75 105% bv wt
C
C
C
C

=
=
=
=

aerabon.

H,PO,

9gc- (7Z

P.0.)

126 davs

Alloy
Alloy
Alloy
Alloy

1 mpy
14 mpy
1 mpy
4 6 mpy

plus acrylic acid and betaproprlolactone


ryiate umt

some P.0, and HS

Alloy C = 5 mpy at top 01 dc

320

160

122

50

206

97

0 04. 35 grams lOOo H,PO, per standard cubic loot or 0 10 &grams


100* H,PO, per cubic meter (STPil Chlarlde 120 30 ppmi m city wster
used I scrubber Ihquor. extensw
aer&on

(28. P&i.
sullur~c acid 2, hydrottuoslllclc
and hydrolluorlc
trace amounts. total lluorlde eqwalent
about
2 suspended
30
weight Llquld phase moderate aerdbon

170.183

77.84

01suspensfon

Phosphoric Acid
Plcklmg Soiutlon

hall

172
194
208
221

hrs

230

hrs, @bon

16.343

acid velocdy 895 ft/mln

of lluor~ne compounds

small quanbbes

Ca (C&O,

lower oxides 01 phosphorous

--

60.650

726-793

HF. 30 percent
I immersed

199.238

251

days Apple,

aeration

60
/

appvx726-793
approx
726-793

moderate

hrs, agltatlon

164 hours

149

130

726.793

48 hours

80.110

375.410

Phosphonc

98

93s

Phosphoric

Phosphoric Acid
Commercial

208

93

Actd

240.260

Phosphoric

Phosphoric

--

100

212
221

180-200

Less than 2 mpy 10 05 mm/y)


2 mpy (0 05 mm/y) to 10 mpy IO 25 mm/y)
Over 10 mpy (0 25 mm/y) to 20 mpy (0 51 mm/y)
Over 20 mpy (0 51 mm/y) to 50 mpy I1 27 mm/y)
More than 50 mpy (1 27 mm/y)

a2 93

lor remwng

scale lrom parts to be bondewed

dc,ds in
gypsum

Alloy C = 2 5 mpy

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

Corrosive

NICKEL-BASE

COllCSlltrat1on.
pment

Media

WROUGHT

dq.

PRODUCTS

m-2

de.C

1X-276

Conditions

130

54

20

170.200

77-93

--

0.1

122.248

50-120

s~llcon tetralluorlde
approx 0 31-O 44 lb /IO00 cu It carbon dmxtde
approx 0 47-O 68 lb /IO00 cu ft P>Os equivalent 0 00033.0 00048
lb /IO0 cu ft Possibly very small amount H,PO, as spray. moderate
aerat,on

/
Phosphor!c

Actd Slurry

Phpsphwc Acid
and Sulfuw
Acid IO 4%)

Phasphorlc Acid
and Sulfuric
Actd (0 3%)

01

50.175

122.347

i dlgester dwng producbon 01 wet prpcess H,PO, Plus CaSO.. 40


percent H,O. 2 percent H,SO#.
percent fluorme Alloy C = 7 9 mpy

/
Phosphcmc Ac,d.
Wet Process

14 5

158

Phosphoric Acid.
wet Process

28

180.230

Phosphoric Aod.
wet Process

28

180.230

Phosphoric

And.

30t

Phosphoric Acid.
wet Process

30t

Phosphoric Acid.
Wet Process

30t

Phosphoric Acid.
Wet Process

WetProcess

(continued)

HAslELLOr~slloy

hmpnturs

Phospharlc Acid. Productton gases and vapors

ALLOYS-CABOT

697

82.110

82.110

70

a5

Ourabon
Aerabon
Agltatlon
Type of
Process
Remarks

01 test - 43 days (25 I HIPO,. 18 I H,SOaI


- a,, free
- extenswe
test - field
mvolved - syntheses of tertiary and secondary
- unwashed

plus 0 381 percent

42 days. 20-22~ H&O*.

;G

al test - 64 days (56 m H,PO,. 8 m H,SOJ


- 11, free
- extenwe
test - f,eld
mvolved - syntheses 01 tertiary and secondary
- unwashed

/ 185

Ouratmn
Aeratmn
Agltatmn
Type 01
Process
Remarks

P,OI 20+

rulfwc

2 percent

amylphenols

HNO, I acid Alloy C = 0 1 mpy

I I 5%fluoslllclc

acid 20.22% flurorlde


aeration

/ lluos~l~r~c
ac,d. moderate

amylphenols

f. 4 5 percent

H,SOI ill0

acid. aera,,on

about

modrrate

1! 5~

hours exposure).

probably

IS

lhquld

250

121

2 percent F 4 5 percent

185

85

2 4 percent F 3 percent HISO,. 1 2 percent ferrous oxldes


sollds (96 hours exposure) lhquld

1 1 percent

30t

250

121

2 4 percent F. 3 percent H,SO*. 1 2 percent ferrous oxides


solIds (96 hours exposure). hot wall

! 1 percent

Phosphartc Acid.
wet Process

36

104

40

sulfuric
acid 2 9% chlwde
P,Oi eqwalent
260
hydrolluostluc
and trace alummum phosphate trace few
trace moderate aerabon

350 ppm
phosphate

Phosphoric Ac,d.
Wet Process

36

172

78

77-84

77-84

a4

Phosphow Acid.
wet Process

/
~

I 3g I 170lE3

Phasphow Acid.
Wet Process

39

170.183

Phosphortc Acid.
wet Process

39

183

Phosphoric Acid.
Wet Process

538

Phosphortc Acld.
Wet Process

55

Phosphoric Acid.
Wet Process

Phosphoric Ac,d,
wet Process

~
I

121.149

49.65

180

82

55

232

111

56t

190-230

88-110I

I -

j E/

-I

1
!
1
~

I
j

H:SOA 1110 hours exposurej

hot wall

P>OI equwalent 26&o rulfurtc ac,d 2 9%. chloride 350 ppm hydrofluorlc
acid. trace water Suspended matter calcium sullate dehydrate 30a. of
SUSP~~S~O~wght.
calwm
phosphate 0 lk moderate ae,at,on
2 percent

HISO&. total fluorides

12 percent

gypsum

30 percent

96 days. hquld phase. 2% H,SO,. Hf and H,S,F. trace aeratmn moderate


agltatlon strong
28% P,O,. sulfurtc acid 2o. hydrofluosdw
and hydrofluor,c
Suspended gypsum 30h of suspenskw wetght. aeratmn

about

evaporation of HPPO, plus 162-I 70 f.


CaSO, m thickener Alloy C = 1 7 mpy

Go

H,POd (401
hydrofluoslluc

40% P,O, eqwlent.


contammg 3b sulfuric acid and suspended calcwm
sulfate. slurry Gases contammg water and fluonne compounds are
evolved at the exoosure a,ea

2 percent H:SOd. 1 percent F 1 5 percent ferrous and a!ummum


oercenl solids 148 hours exoosurel lhauld

oxIdes. 4

2 percent HSO,. 1 percent F 5 percent ferrous and aluminum


percent sohds (48 hours exposure). hot wall

ondes. 4

oxIdes. 4

-I

I E

P,OrJ. contalmng
acid

combined

1 5-2 5 H,SO,.

fluanne.

2 percent

talcum

Phosphoric And.
wet Process

56t

225.245

107-118

Phosphoric Acid.
wet Process

56t

300

149

2 percent H ,SO,. 1 percent F 1 5 percent ferrous and aluminum


percent wilds 148 hours exposure). ho1 wall

Phasphorlc Ac!d.
Wet Process

56t
66t
66t

330
325
340

166
163
171

small amounts 01 Co. MgO Fe. AI.O>. SIO, Na 0 Cl No lluondesor


present (4.3 how exposure). hot wall

69

490 to 550

Phosphoric Acid.
wet Process
E
G
S
B
U

Less than 2 mpy (0


2 mpy IO 05 mm/y)
Over 10 mpv (0 25
Over 20 mpy 10 51
More than 50 mpy

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy 10 51 mm/y)
mm/y) to 50 mpy (1 27 mm/y)
(127 mm/y)

-I

hlghlv concentrated.
t -

percent

I Zc

aerated aud

sullate.

H.SO,

69 P 0.. rtabc and agitated

P,O\

(continued)

698

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

30
40
E
G
S
8
U

ALLOYS-CABOT

to B P
BP

- Lessthan2 "py 1005 mm/y,


- 2 mpy IO05 mm/y) to IO rnr~y
(025 mm/y)
- Over IO mpy (025 mm/y) to20 mpy (051 mm/y)
-Over 20 mpy (051 mm/y) to 50 mpy (127 mm/y1
- Mare than50 mpy (127 mm/y,

to BP
BP

WROUGHT

PRODUCTS

(continued)

6 P - Bodmg POlfll

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

Chloride

Potaswm

Ferrocyanlde

75

24

---

Potaswm

Ferncyantde

30
IO

75

24

I-_

Potasswm

Hypochlwte

50

200

Potaswm

Hypochlortte

All

to B P

to B.P

--

Potaswm

Hydroxide

to BP
IO il P
to B P
IO BP
to El P
BP
to 125

to B P
to 5.P
to 8 P
to B.P
to E P
BP
to 52

S
S
:

s
s
S
s

---

::
40
50
60
90

;
S

11
---

20

203

95

E
C
S
B
U

Hydroilde

Less than 2 mpy (0


2 mpy (0 05 mm/y)
Over 10 mpy 10 25
Over 20 mpy 10 51
More than 50 mpy

manulature

of electrolytic

potarwm

hydroxide

sodium chloride 1% a&c


acid
Ourat~on ot test - 93 days
Aeratmn - extenswe
Agatatlon - extensive

lmpwtles

Potassium

699

(continued)

durmg

Potaswm

Metals and Alloys

10

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 mpy (127 mm/y)
(1.27 mm/y)

93

8 P -

M&O,.

plus 50 percent

CaSO,, MgCI,, 36 days

NaOH. Alloy C = 0 03 mpy

--

--

I ~sopropanol and ~sopropanol solutmn of hexachlorpentadlene


0 09 mpy

Alloy C =

Bolllng Pomt

(continued)

700

Corrosion Resistant Materials Handbook

TABLE 5.18:

Potassium

NICKEL-BASE

Permanganate

Potasswm

Persulfate

Potassium

Sulfate

Potasswm

Sulfite

ALLOYS-CABOT

WROUGHT

PRODUCTS

25

75

24

50
75

75

24

_-

II

75

24

---

10
20
-

15
to 125

24
to 52

s
_

140

60

(continued

--

catalyst for synthetic

rubber

productlo

Alloy C = 0

I mpy

potasswm bsulftte. about 50% water. ptf 6 O-5 0. sulfur dlorlde


gas, extensive aeratwl

Potassium

Sulfite

145

63

potassum

blsulfk?

about 50% water, ptf 5 9-l

Potassum

Sulfite

145

63

potasswm

blsulftte.

about 50% water. ptf 6 0.7 2

Potaswm

Sulfite

180

82

potaswm

bwlflte.

about 50% water. pH 5 9.7 2

Potassium

Sulfite

180

82

potassium b!sulflte,
gas. aerabo

about 50% water. pH 6 O-7 0. sulfur dloxlde

Potaswm

Sulfite

180

82

about 50% water. pH 6 0.7 2

Potaswm

Sulfde

230

110

2. moderate

I flue

aeration

potaswm

blsulflte,

potassium

b!sulfde. about 50% water. pH 6 5-5 0. sulfur dloxlde

m flue

m flue

gas
Sulfite

270

132

Potasstum

Sulfite

280

138

Potaswm

Sulfite

300

149

Potaswm

potassum

bwlflte.

potaswm

blsulfde, about 50% water. pH 6 5 to 5 0. sulfur dmxlde m flue

about 50% water, PH 6.8-5 5

potaswm

3% formic acid. balance water. 24 hrs lab test

--

gas

Propan

47

356

180

Propanal

110

43

155

Prop~on~c Acid

60-65

311

tl

100.170

120-160

Acid

64

500

260

Prop~onlc Acid

80

212.338

Prop~on~c Acid

90

248.320

Proplonlc

blsulfite.

about 50% water. pH 6 8 to 5.5

plus free SO; and H,SOa. pH = 2 5-5 Alloy C = 0 1 mpy


1

1 plus 10.12percet

butyrlcacld.

4.7 percent acebcacld

Alloy C ~0 1 mpy

35+ prop,on,c anhydrIde.


feed 2000 cc per hour

1% mckel acetate, 7 hrs, lab test, conbnuous

--

plus 2 5 percent butyrlc


aud Alloy C = 0 7 mpy

acid, 2 percent mtrlc acid. 0 1 percent acebc

--

plus 4 percent butyrvz acid.

if

I percent

nltrlc acid. scetlc ac!d Alloy C = 0 5

mpy
Prop~on~c Acid

94

85.356

30-180

1-

1 -

1plus 2 percent
dwng

Prop~on~c Aud

plus 3 percent

acebc acid

Alloy C = 0 07 mpy

288

142

--

Propuetary

Compounds

284

140

proprietary acid chlorides. toluol and VMP naphtha Also methanol


1.3% HCI durmg s cleanmg cycle, ~~~.ss~~nalf~ OMF also to clean

N.

Proprietary

Compounds

329

165

proprietary ac!d chlorides. toluol and VMP naphtha Also methanol


1 3c0 HCI dwng a cleaning cycle, OCC~SIO~~~~ DtiF also to clean

N.

100-115

38.46

plus HCI to pH of 1 5 and some SD, mwng


rn0

331

166

100.120

38.49

--

Protel

97

butyrlc aud. 3 percent bollhng esters, 1 percent acebc acid


mtrlc acid treatment
Alloy C = 0 1 mpy

Hydrolysate

2 Pthoxyethyl

Acetate

Pyrldlne

96

scetx anhydrlde
aeratlo
plus 5 percent N&I.
0

Pyrldlne

50

Pyndme

9M

E
G
S
tl
U

Less than 2 mpy (0


2 mpy (0 05 mm/y)
Over 10 mpy (0 25
Over 20 mpy 10 51
More than 50 mpy

0 4%. acetlc

dIgestIon

tank Alloy C = D 6

acid 0 2%, water unknown,

ertenswe

2 percent CH,CI,. 1 percent NaOH. and water Alloy C

Iw

80.100

27.38

--

plus traces of HCI CH,CI, and acetone I separatlon 01 pyrldlne


water Alloy C 0 I mpy At 200 deg F. alloy C 0 I mpy

572

300

--

plus IM ferric chloride. also il mixture 01 pyrldme.


and lerrlc chloride. 6 to 48 hrs, lab test

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 mpy (127 mm/y)
(1.27 mm/y)

pyrldme

from

hydrochloric

I3 P - Elolllng Point
M - Molar

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

Pyrogallic Acid

All

ALLOYS-CABOT

WROUGHT

PRODUCTS

701

(continued)

to B.P.

to B.P.

--

Rayon

122.167

50.75

rayon spin bath - 510% sulfuric acid: 1.6% zinc sulfate; 10.15%
sodium sulfate. Free carbon birulfide present and saturated wlh
hydrogen sulfide. Amines and ethylene oxide condensatmn produck
present to 1%.

Rayon

206

98

rayon cascade bath - 1.15% sulfunc actd: 1.3%zincsulfate; 10.15%


scdium Mate;
free carbon blsulfide present and saturated wth
hydrogen suifide.

Rayon Bleach

210

99

--

plus 0.1 percent sododlumchlorite, 0.03 percent sodwm carbonate, 0.1


percent synthetic detergent 0.035 percent lizOr. 0.07 percent acetic
acid. Alloy C = 3 mpy

Rayon Spin Bath

125

52

--

10 percent H,SO, phases.

extenrwe aeration.Alloy C = 4 mpy

Rayon Spin Bath

100.210

--

122

50

--

11 percent HISO,. 24 percent SO,. saturated rtth H2S

Rayon Spm Bath,


Dilute

Room

Room

--

in splash zone H,SO, 10 percent to less than 0.001 percent. From 0.500
ppm of CS, and H,S. Alloy C = 3 mpy

Rayon Spm Bath.


Spent

203

95

--

H&
= 0.25 percent Na,SG, = 0.25 percent m casbng machme. Alloy C
= 0.1 mpy

25

.4

1 -

--

Rosin and Rosin Oil

Rubber

572

72

Rubodium

100

77.256

36

Scrubbed Botler
Fluegas

120

Scrubkr

Effluent Gas

Scrubkr

Envuonment

120

I -

sodwm hydrorlde cleanmg solubons (6% ba~lmg). Various raw materials


mclude phthahc and malelc anhydrldes. tsopthabc acid. glycerol. pent.
acrythntol; hnseed. soy, castor and tall 011s.vmyltoluene. propylene and
ethylene and other glycols.

1in boiling

w&ion

at still bottom and m vapors. Alloy C = 0.1 mpy

elastomer dissolved in aliphabc solvent to rhlch bromine was added. pH


7.4, tested in absence of any light source, moderate aerahon.

25.126
3

XII
---

I--IEl

49

crackmg.

15OOTIGcrackmg. 1600f-no

crackmg
-

I ~mduction

of acid. pH varies from 12 to 2. Alloy c = 1.73 mpy

15% CO,. 3% O1. 400 ppm SOI. NOX and fly ash bemg scrubbed m slurry
of 7% CaSOs. 2% CaSO,. ,596 MO. pH 5. Scrubbmg of SO2 and fly ash
from power plant flue gas
Aerabon - moderate
Agltabon - 200.000 ACFM gas
Total days - 158

limestone slurry. 1750 ppm SOI. 2.3% fly ash. 3% CaW,, 2.3% CaSG,
plus CASO,. PH 6-6.4 2000.3000 ppm Cl. moderate aerabon

15% CO1. 3% 0,. less than 100 ppm S02. Llquld spray with some dissolved
sohds present. pH 6-7 Scrubbmg of SO, and fly ash from power plant flue
gas.
Aerabon - moderate
Ag!tabon - by gas flow
Total days - 156

190

a8

O-400 PPm S&. 10% water vapor, fly ash after limestone slurry scrub.
bing, moderate aeration

110.115

43.46

aeration

3w

Scrubber Environment

;
9

49

T-r
-

Scrubbed Boiler
Fluegas

lab test, 500 hrs.. 14Wf.lG

Salicylic Acid

Scrubbed Boiler
Fluegas

1 -

22

ii:
671

Salt Water. Clean

Boiler

300

1400

15w
1600

krubkd
fluepar

36.99

spinning bleach. hardening etc. Vapor and liqmd

Rayon Spm Bath

Resm (Alkyd. Poly


ester. Amine Types)

4w

I 14g
I - I E I EI E I

for municipal refuse incinerator. Hot. acid chtorlde enwronment,


range about l-6. extenwe aerabon

204 I

EI-l

-I

for mwwpal
refuse incinerator. Hot acid chtorlde envwonment
range about 1.6. extenswe aerabon

pH

pH

Sfrubbmg Liquor
Boikr Fluegas

120

49

4.4% CaSO,. 2.5% CaCO,. 0.5% fly ash. 0.1% CaSO,. pH 6-7. Scrubbmgof
SO2 and fly ash from power plant flue gas
Aeration - moderate
Agitation - by gas flow
Total days - 158

Scrubbing Liquor

1%

66

portable steam generator flue gases contammg SO?. NOX. N. CO, and 0,.
Liquor alkatme ott field H,O wth 5000 ppm Cl, 21 days

E
G
S
B
U

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy IO.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

B.P -

Boding Point

(continued)

702

Corrosion Resistant Materials Handbook

TABLE 5.18:

Power Plant

E
C
S
B
U

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

Fluegas

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mh/y)
to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y)
to 20 mpy (0.51
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27
More than 50 mpy (1.27 mm/y]

mm/y)
mm/y)

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

NC
63

703

colanon,

-i-

66177

80

Scrubbrnp liquor,
Power Plant fluegas

aeratmn

HrS sparged Into crtrrc acrd N&O, plus absorbed SO, sotubo to put
sullur. pH 4-5. Citrate process for sulfur dtoxrde removal (and sulfur
reCOVerYI

Aerabo - one
Agitation - vrolent
Total days - 91
Scrubbing Lrquor.
Power Plant Fluegas

176

80

176

80

240

116

Scrubbmg Liquors
Smoke and Fluegas

70

21

Scrubbing Lrquors
Smoke and Fluegas

117

47

Scrubbmg Liquors
Smoke and Fluegas
Scrubbing Liquors
Smoke and ftuegas

Scrubbing Lrquors
Smoke and Fluegas

krubbmg Liquors
Smoke and Fluegas

Scrubbing Lrquors
Smoke and Fluegas

SO2 bemg absorbed m sofubon of crtrrc acrd. 80 g/l Na,COs; pH 4.0-5.0.


Cltrated process for sulfur droxide removal (and sullur recovery)
Aerabon - moderate
Agdatro - by lrqurd flow
Total davs - 91

recycled and makeup 190 g/l crtrrc acrd. 80 g/l Na,COI. pH 4-5. C&ate
process for sulfur droxrde removal land sulfur recovery)
Aeratro - none
Agrtabon - agdated
Total days - 91

SO2 1600-2000 ppm. 14% C02. 3% Or. exposed to lrquor spray at pH 10


contarnmg sohds. Scrubbmg SO? and fly ash from povrer plant flue gas.
Aerabon - extensive
Agdabo - 5.10 ft./see.
Total days - 135.6

hydrochloric acrd. sulfuric acrd. sullurous acrd. hydrobromrc acid,


orgamc solvents, some chlorinated, pH appmx. 1. moderate aerabon

calcmm sulfite. &rum


sulfate. calcium carbonate. fly ash. at1suspended
as 10.15% fbv wt.1 slurrv. OH not specified

IL
-

57

60

164

73

170

77

175

79

175

79

135

280

93

54

93

Scrubbrng Lrquors
Smoke and Fluegas

130

71

krubbrnn Liauors
Smoke aid Fluegas

Scrubbing Lrquor.
Power Plant fluegas

Swbbrng
Lrquor.
Power Plant Fluegas

=I=
-I

Hue gas from mcmerator.

scrubbed

water from mcmerator scrubber. Chlorrdes 900-1000


pH 1.95.2.03. extensrve aerabon

ppm. rron 24 ppm.

flue gas conbmmg

flue gas contarnmg H20. SO?. SO,. HCI. HP and NaOH

--IE

-i

flue gas contamrng HrO. SO,. SOa. HCI. H2S and NaOH

H20, S02. SOs. HCI. HJ

and NaOH

flue gas. water-scrubbed, from combusbo of munrcrpal reluse: nearly


saturated wth water vapor. conrderable aeration

flue gas contaming sullur droxrde and sulfurtrroxrde. Canstderable liquid


water and water vapor, DH 2.0 to 4.0. entramed. extenswe aerabon

27

calcrum carbonate. calcium sulfate. calcrum sulfite. and fly ash alt
suspended as about 20% (by wt.1 slurry. PH not specdied. moderate
aerabon

38

4IL-

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

water scrubber: pH 2.53: chloride 175 ppm. sulfate 75 ppm. moderate


aerabon

138

34

32

E
G
S
B
U

flue gas scrubbmg liquor contaming ffy ash and drssolved chlorides.
sulfur oxrdes. drogen oxtdes. carbon dioxide and carbon monoxrde. pH
4.5. extensrve aeration
flue gas contarmng wetted fly ash. Scrubber liquor contammg rullurrc
acrd 0.19%. hydrochlocu actd 0.057%. pH 2 to 5. extensrve aerabo

-1

flue gas containmg sulfur dioxrde. Entramed potassium rulfrte-beulfate


solution, pH about 4.0. estenswe aeration
E

ti

limestone slurry 15% CaCOa in water. pH 6.3-7.9

5% H2S0, scrobbmg sdotion for smatter gas containing 2.10% Or. less
than 500 ppm sullur dioxide and 160 ppm chlorides. exhnsive aeratmn
copper smelter gas and recycled cwbng spray water (pH as low as 1.7
average 2.5) 1.1.52 SOr I gas pius particulate and SO>. extenuve
aeration

(continued)

704

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

comom-

tntia.
prr#nt

WROUGHT

tiA6lEUOV~
offoy

TwDumn

caflditioml

dq. C

6/6-Z

41

--

copper smelting gas contmning .75-l%


(25.100 ppml. extensive aerabo

Scrubbmg Liquors
Sulfur Dioxide

105

41

--

smefter gas in TCA scrubber and lhmestone slurry (15%. pfi 5.2.7) which
is converted to CaSOl and some CaSO, by SO2 I the gas, extenwe
aerabo

Scrubbing Lwors
Sulfur Dioxide

107

42

--

lhmestone slurry 15% sohds. CaCO, plus CaSOl and a small amount of
MO,.
pfi 3.7-6.7. ave. 5.6, moderate aerabo

115

46

1 WC-276 1 6

Tt

StJo-

105

Scrubbing bquors
Sulfur Dioxide

bntinued)

Scrubbing Liquors
Sulfur Dioxtde

faloalvo Ydl

&a F

PRODUCTS

9%

I-lEl

SO1 and some sulfuric acid mist

calcium sulfite, calcmm sulfate, calcium carbonate. fly ash, all suspended
as 30.50% (by wt.) slurry. pH not specified

Scrubbing Liquors
Sulfur Dioxide

117

47

calcium carbonate. calcium sulfate. calcwm sulLte. all suspended as 6.


11% (by wt.) slurry. ptl not speclfled. moderate aeratm

Scrubbmg Liquors
Sulfur Dioxide

117

47

flue gas contalnlng entraIned H1O and slurry (calcmm sulfate, calcwm
sulfde. calcmm carbonate). moderate aetabo

Scrubbing Liquors
Sulfur Dioxide
Scrubbing Liquors
Sulfur Dioxide

I - I
I - I
-

Scrubbing Liquors
Sulfur Dioxide

120

120

I 4gI - I E l-l-l
I 4gI - I E I-lEl

magnewm
oxode slurry scrubbmg lkquor for SO, removal from power
plant flue gas. moderate aerabo
bader flue gas. 0.400 ppm SO,. 10% water vapor. fly ash after lkmestone
slurry scrubbma. moderate aerabon

120

49

6% limestone slurry. CaCOx. CaSO,. CaSO, and fly ash. pH 5.0-6.0.


moderate aerabo

Scrubbing Liquors
Sulfur Dioxide

120

49

boder flue gas and hmestone slurry. 1750 ppm SO,. 2.3% fly ash .3%
CaCO,. 2.3% CaSOl plus CaSO,. pH 6~6.6.2000-3000
ppm CL moderate
aeration

Scrubbing Liquors
Sulfur Dloxlde

120

49

sodtum sulfate scrubber hquor. Gas from 011 fued sodlum sulfate flash
drymg system. Liquor contams dilute Na2S0,. H,SO,. pH 2.3. extenwe
aerabo

Scrubbing Liquors
Sulfur Dioxide

122

50

power plant flue gas scrubbmg lkquor 7% CaSO?. 2% CaSO,. 1% CaCOI. 1%


chloride. pH 5.8-6.1 Gas I 2000.24W
ppm SO, extenswe aerabo

Scrubbmg Lwors
Sulfur Dloxlde

122

50

power plant flue gas scrubbmg kquor 7% CaSO,. 2% CaSO,. 1% CaCOI. 1%


chloride. pH 5.8.6.1 Gas I 2000.2400 ppm SO2 extenwe aerahon

krubbmg Llquots
Sulfur Dloxlde

122

50

scrubbed power plant flue gas conta~nmg 300.500


H20. extenwve aerabon

Scrubbmg Ltquon
Sulfur Dioxide

125

52

SO, gas scrubbing. 800 ppm SO?. 15% H,O. 12% CO?. 68% N,. 5% Oz.
chlorides. 2000 porn fluotlde. some SO,. PH 3. moderate aerabon

Scrubbing Liquors
lb./ml.

Sulfur
lJoride

ppm SO2 and 15%

gas after lkmestone slurry scrubbmg contammg 0.1


of residual SO?. Effluent of absorber sechon of scrubber.

Scrubbmg Liquors
Sulfur Dloxlde

131

55

Scrubbmg Liquors
Sulfur Dioxide

135

57

--

copper smelbng gas after coohng m a H,O spray tower. Gascontalns H,O
at 2.5 pH plus sulfurtc acid mist (25.100 ppml. extenwe aerahon

Scrubbing Liquors
Sulfur Dloxlde

140

60

--

scrubbed roaster gas; SO1 100-2000 ppm. H,SO, 100.1500 ppm. balance
wet aw: heavy loadmg Hz0 droplets. contalmng Ca salts and ore dust

Scrubbang Llquots
Sulfur Diomde

Scrubbing Liquors
Sulfur Dioxlde

I - I

62

1 -

/ -

150

I a I - I E l-l EI

150

66

--

Scrubbing Lwors
Sulfur Dloxlde

160

71

---

krubblng Liquors
Sulfur DooxIde

167

75

--

Scrubbing Liquors
Sulfur Olorlde

176

80

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/)]
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy Il.27 mm/y)

SO2 scrubber gas. 5% SO,. 3% SOI. 7% 0,. balance N, saturated wdh H?O.
Powble splashmg wdh wlubon contammg 1.3 g/l Cu. pH 6

wet venturi scrubbmg stream removmg fly ash horn holler burnmg corn
N2, 360 ppm SO>. 80 ppm HISO,. Ash 6% Cl. extensw

143

Scrubbing Lwors
Sulfur Dioxide

E
G
S
6
U

1 E / ae,at,on
cobs. Gas 83%

scrubbng hquor for portable steam generator flue gases contamIng SO?.
NOX. N. CO,. and 0,. Llauor alkahne 011 field H,O wth 5000 oom Cl.
moderate a&abon
wet flue gas after Hz0 spray. wubber slurry (CaSOI mamly. alsoCa(OH),
or CaCOl plus CaSO,. pH 3.12) during upsets.

scrubbmg hquor for portable steam generator flue gases contalnmg S02.
NOX. N. CO,. and 0,. Liquor alkalme 011 held H,O wth 5000 ppm Cl,
moderate aerabo
dlmethylandlne

contalnmg SO, steam and sulfur dloxlde

SO7 scrubber gas. 5% SO?. 6.5% 0, and 88.5% N2 (dry basls) saturated
wdh water vapor. eatenwe aeratton

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

concen-

Trpnhn

tnth.
fhlldve rndl

Pm@nt

WROUGHT

acF

llA3nll6Y.

drcc

Vc2

PRODUCTS

Scrubbed Power Plant


Flueflas

(continued)

eoey

C/C-276

Scrubbing Liquors
Sulfur Dioxide
Scrubbing Llquorr
Sulfur Diorlde

705

power plant flue ger xrubbmg. Cdrate roluhon phareof sulfur decanter.
(Dilute and impure sodium cdrate)
370

115.125

108

46-52

--

Hue get from e metallurgEel roaster. typlCal 02 grmr/cu.


1500 ppm. SD, 750 ppm. CD? .7% H,D l-3%, bal. a,r
E

ft. dust, SD2

conteinmg droplets of dbl. alkak scrubbmg kquor. aerabon

Aerabon Agdation -

moderate
by gas flow

process black kquor


Aeration - ertenwe
Agdetion - 10.12 ft.&c.
Scrubber Fluegas,
lncmerabon of
Sewage Sludge
Scrubber Ltquor for
Recovery bier Flueps

20.5g/l Na,CD,, 21.5 g/l NtHCD~. 3.1 g/l chlonde sokds. 15% traces
Na2S~D3. Scrubbmg of recovery bode, flue gas ftrmg kraft process black

i_LL
1 l&l

E C S 6 IJ -

Less then 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Dyer 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Dyer 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y]
More then 50 mpy (1.27 mm/y)

days -

67.0

(continued)

706

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

WM

PRODUCTS

WC-276

143

Scrubber Water Effluent

:z

63

Conditions
E

gas from or1 fired sodrum sulfate flash drymg steam


ddule NarSO,, HrSO,. pH 2-3. extensrve aerabon

90% water saturated, downstream of scrubber and demrster pH 3-4.


Mumcrpal garbage incmeratorflue gaascrubbmg: agdatron hrgh. aerahon
extensrve; 51 days

gas 10% CO>. 13% Or, Bal Nr IHI0 Satd). Fly ash carryover. pH below 0.
Scrubbmg of SO, and fly ash from power plant flue gas.
Aeration - extensive
Agitabon - 5.10 IL/set.
Total davr - 135.6

defluormabon system. HF s&bon


SO,. pH 3.0, 92 days

from prequench chamber of mumcrpal refuse rncrnerator scrubber


about 1
hydrogen sulfide gas wdh mrst of de-aerated

93

!-j-q-f

240

116

196

91

Sea Water and Or&


Fuel Exhaust Products

Ambrent

Ambrent

5 months. flow rate -

Acrd

10

90.220

32.104

55-104

Sewage

65.95

29-35

240

116

100.160

38-71

Sewage (Scrubbed)
Sludge Incmerator
Fluegas

plus 0.05-2 percent max. HrSO,


balance. Alloy C = 0.4 may

in sbll. Alloy C = 0.4 mpy

municrpal garbage mcmerator flue gas from secondary chamber after


passing through scrubber. marble bed plus entramed lkquor at pH 3-4.
Agrtation moderate; aeration extenrrve. 51 days

66-72

19.22

G
E

Sewage Sludge Incinerator Fluegas

100-210

38.99

E
E

mumcipal refusa incinerator flue gas effluent after HrO scrubbmg. Environment should be mainly steam wdh entramed rmpunbes. extensrve
aeration

municrpal refuse incmerator water quenched flue gas, acrd chlorrde en


vironment. pH range about 1.6, extensrve aerahon

w,

19W20

I
7,,,.9,,0

371.46)

Srhcon Tetrachloride

100

140

60

Srkcon Tetrafluorrde

113

45

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) lo 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy Il.27 mm/y)
More than 50 mpy (1.27 mm/y)

B.P. -

127 days,

avg. comporrlion of brine: NH, 5 ppm. Cl 100 ppm. 8.0.0.


moderate aerabon. pH 6.0
E

200 mg/l.

aerabon

sewage sludge mcrnerator flue gas berng scrubbed by once thru water
plant effluent water, aeratron
E
E

E
E

--

--

I
G

&

sewage sludge incmerator flue gas bemg scrubbed by once thru water

in deacidification

I
-

sewage sludge mcmerator flue gas bemg scrubbed by once thru water
plant effluent water, aerahon

E
E

1.40% NaOH.

moisture laden gas from anaerobrc drgestron of packmg house waste. 63


percent COs. 36 percent CH, and 1 percent HrS. pH = 7 4 approx

E
E

HNO,.

6*-104
I :

530% HCI. 10.40% HrSO,. 10.25%


aeration and agdation moderate

150I & I - I E

Sewage Sludge Incrnerator Fluegas and


Scrubburn Lrquor

H;O

Sewage Sludge Incm


erator fluegas

K,SO,.

and traces of Na,SO,,

I 3.40
I I3 I E

E G S Et U -

sea water

5 aom

plus

Separate Water Solubons

Sewage, Raw
and Processed

pH

small amounts of H,SO,. NarSO, and K,SO*

Secondary Discharge
Effluent

Gas

0.6% as F, 2000 ppm PIO,. 700 ppm

contammg chlorrdes. sodrum. sulfur, carbon

Sebacrc Acrd

SeLwx

ash, aerahon

200

Seawater Matures

1plus fly

Lrquor conlams

Sea Water

(continued)

I
G

of silica by rotary kdn. Alloy C = 0 04 mpy

with dry HCI and Cl, bubbled through. In productron of hrgh punty srhca
of pigment. Alloy C = 0.1 mpy
acid spray of droplets containing phosphonc acrd. hydrolluosdw
phosphate rock dust, water.

acrd.

Bodmg Pond

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

707

(continued)

cowoafva

Coneenttetton.
pwunt

Ye&

c(yF

Silicon Tetrafluoride

Silicon Tetraiodide

I
I
I

10

I
I
I
1

Silver Chforrde

10

Silver Fines (wet, Grey)

167

285.300
75
75
212

VI-2

da9.G

131

Silicon Tetrafluoride

Silver Bromrde

HAmlloY.

Frnpntur

55

1
I
I
I
1

75

140-149

316
St&a-

a9oy

c/c-m

CmMtiom

z4

1 s

1 -

1 B 1acid

I plus z percent free iodine under reflux half immersed

I very dilute FeCI, bleaching powder and murabc acrd solubon. aerabon
none, agdabon by boiling. Alloy C - 12 days

24

-1-I-I

24

s l-l-l

100

spray containing phosphoric sod 169% HsPO,.


hydrofluosilicic acid, phmphate rock dust water

Silver Refnwrg

I - l 220I lo4l - l E I - I El

Sdver Refinmg

220

104

SW

Silver Salt

70

21 I

Slurry

I
1

4s

I
1

60

I
1

16 I

Soap Fat
Sodium Acetate

50%

Pro,).

acid leach slimes of silver refinery contammg Cu, Au. Ag. Se. le. Pt and
Pd. moderate aeration

1acid
Pd.

$s;mCoagulatlng
r

phosphoric acid, hydroffuosdicic

acid spray containing hydrofluoricacid,


acid

100.125

465.480

10

75

30-52

240249

I
I
/

241

E I - I E
1 E

--

leach slimes of silver refinery contammg Cu. Au. Ag, Se. le. Pt and
corroded WIW or was lost. aeration

lsDeEimen

1 E I possrbly mtrate. aqueous solubon: concentrabon unknown


I E I 100mesh and hner. 2% HrSO,. saturated with SO,, pH 1.0-1.5
1 - 1strong NaCl solution plus dilute HrS.O,. rubber, soap and traces

of aux.
diary solution. Rubber contains 30 percent carbon black pH = 3.5 avg.
Alloy C = 0.17 mpy m cowersron tank
steam, fatty acid, glycerol

I-I-1

liter of sodrum hypochlorde.

il. No hypochlorites present. pH = 6.7.

E
G
S
B
U

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy IO.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm&l
Over 20 mpy (0.51 mm/y) to SO mpy (1.27 mm/y)
More than 50 rnw (1.27 mm/y)

B.P. -

wing

Point

(continued)

708

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

gmll f&I,;

15-100 gm/l CaSO,; 0.2.

m chloride. sodium car.

E
C
S
B
U

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) lo 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

Sodium Chloride
me punficabon - salt productlon
rabon - 1.5 ppm 0,
dabon - 6 ft./set.

Sodium Chloride
Sodium Chlonde

Sodium Chloride

Sodium Chloride
Sodium Chlorde
Sadlum Dialkyl
Orthocarbonate
Sodium hrncyamde
Sodium flormaldehyde
sulfolylate Liquor
S&urn

preconcentrator.

Alloy C = 0.006 mpy

Fluonde

Sodium fluo5dicate
Dust
godly

Fluosdicate

Sodium Clutamata.

Mono

Sodium Glutamate.

Mono

Sodium Hydrosulfide
Sodium Hydrorlde
Pulp Dugester Liguor
Sodium Hydromde
Sodium Hydroxide

Mum

Hydroslde
Durabon Aerabon Agdabon Type of test

150 days
moderate
normal flow
- held

Sodium Hydroxide

Sodium Hydroxide

15

to230

to 110

--

Plusmonochlortoluene saturated wdh approx. 2 percent each of HCI and


Cl?. Alloy C = 23 mpy

Sodium Hydroxide

90

32

--

10 to 15% NaOH. NaCl and NarCO1. HCI. COCI,. moderate aeratton

Sodium Hydroxide

100

38

--

plus cresylu aad. Alloy C = 0.5 mpy

Sodium Hydroxide
Sodwm Hypochlorde

160

71

0.5

1::

;:

:I

0.5

212

100

--

Sodium Hypwhlorde

140

60

--

Sodium Hypochlorite

1.2

70

21

Sodium HypochlOrite

65

16

--

::

11

--

dilute, chromate and chromu wastes. chlorides. all low concentrabons


Dakms solubon. Alloy C = 0.1 mpy

Alloy C = 4.0 mpy


E

plus umdenbfmd

components.

bottom of bleach makup

pH near 7

tank. Alloy C ,O.l

mpy

Sodmm Hypochlorite
I
Sodium Hypochlorite
E
G
S
B
U

15

1::
66

Less than 2 mpy (0.05 Imm /VI


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm, Y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm. /Y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.2 7n Im/y)

,,

30
M -

plus 3 percent caustic soda. Alloy C 6amed iwght

shghtly

Molar

(continued)

710

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

ent sodurn

E
G
S
B
Ll

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy IO.51 mm/y) to 50 mpy (1.27 mm/y)
Mare than 50 mpy (1.27 mm/y)

B.P. -

hydride.

and 0.1 percent

sodurn

oleate

Alloy C = 0.2

Bodmg POW

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

Sulfated Detergent
E
C
S
B
U

NICKEL-BASE

ALLOYS-CABOT

125

Less than 2 rnIpy ID.05 mm/y)


2 mpy ID.05 mm/y) to ID mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy 11.27 mm/y)

52
B.P. -

WROUGHT

PRODUCTS

711

(continued)

Boding Pomt

(continued)

712

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

bontinued

TYw

COllC0II-

tntion.
prrcrnt

ConosiwIMa
Sulfated

W.F

011s

Sulfonabon
and 011s

Of Fats

98

Reacttons

Sulfonatlon

Acrd (Spent)

Sulfonabon

Acrd (Spent)

w-2

de8. C

316
sttin-

HA3lELLOV~ alloy
WC-276

3;

Condiiionr

52

---

70

21

sulfonatmns of castor, soya, sperm and red 011s. mmeral or1 and various
other fatty acrds. fats and 011swdh 96 Baume H&O,. pH 1-4. Moderate
aerabon, agdabon - 84 rpm turbme.

248

120

sulfurrc acrd 98%. ammoma anhydrous.


maldehyde, moderate aerabon

or sodrum hydrorrde

33%. for-

176.320

80-160

--

sulfuric acrd 98%. ammoma anhydrous.


maldehvde. moderate aershon

or sodturn hydroxrde

33%. for-

125

Suffonatlon

Sulfonabon

Tampontun

272

133

341

172

5 percent

111 days

H>SO,. NaCl and Na$O,

below lkawd level

8 days below hquld level

Sulfonabon

Aced (Spent)

392

200

10 days below lkqurd level

Sulfonatlon

Acid (Spent)

392

200

start - 25% pet. SO,. 6% HFSO3. 3% I?, 3% HI. 63% H,SO,. End HFSO,. 4% 12, 3% HIO, and 87% H$O,. 56.5 days

Sulfonatlon

Acrd (Spent)

Sulforuc

50

Acrd
-

Sulfur

Sulfur

Sulfur.

Molten

0.077

Sulfur OroxIde
Sulfur Ororrde

1.8

482

250

60.250

16.121

74.284

23.140

--

plus some HISO,. H2S. SO,. H2SOI and water vapor m melbngtank.
ple half I vapor. half I kqwd. Alloy C = 0.52 mpy

850

454

--

plus selenium. 11.7 day test, 7.8daysof


5.1 mpy (vapor)

775
300.315

412
149.157

:*

284.302
265.295

140.150
129.146

220

55

104

13

-_-

E
1

28 days below hqurd level


plus 45 percent solvent naphtha,
bonom of sbll

6%

5 percent water and trace of H,SO, at

Sam-

borlmg. Alloy C = 2.8 mpy (kqwd)

lvlus aerated water at pH of 1.5 to 3.5.ll.day test permd m surface pope


hoe between well and gathermg stabon. Alloy C = 0 9 mpy.
6.day test perrod
agrtated. plus au and unpurdresmcludmgsulfurlcac~d.
and ferrrc sulfate.
Tested up to 12 days
balance H,O. Alloy C = 0.19 mpy

--

m sea water plus 1.7 percent

1-1-I

N&I.

Alloy C

0.6 rnpy

Sulfur OroxIde

3.6

106.118

41.48

--

about one.half saturated wth spray water I scrubber tower. Alloy C = 0.2
wy

Sulfur Droxrde

4-5

185.200

85-93

--

plus selemous acrd mrst and some sulfunc


Alloy C = 0 9 mpy

Sulfur Drorrde

4.7-5.0
(by volume)

--

plus 3.4 percent calcium bwlfde


oltw

--

plus 15 percent O?. balance N, (dew pomt 125 percent)


wet wmdboa. Allov C = 0.8 mov

Sulfur Droxrde

Sulfur Drorrde

70

Sulfur Droxrde

200-500

400

18

500.700

260.371

OroxIde

Sullur

Dloarde

115.170

Sulfur Dlorlde

125

Sulfur Otorrde

E
G
S
B
U

Dlorrde
Less than 2 mpy (0
2 mpy 10.05 mm/y)
Over 10 mpy (0.25
Over 20 mpy (0.51
More than 50 mpy

16

46.77
52

54

130
-

Sulfur OroxIde

Sulfur

60

Drorrde
1

204
29.35
52.57

Dtorrde

Sulfur Ororrde

85-95
125-135

Sulfur

131

93.260

10

Sulfur

Sulfur

21

55

U
U

G
;

I -

I -

mckel
I an

convertor.

acrd m shmes bodmg kettle

m sulfde acrd senlmgtank

In gas ofnake

Alloy C = 2.6 mpy

saturated wth water m bonom of scrubber Recycle lkquor contammg


H,SO, m range of 0.30.0.75 percent. Alloy C = 0.1 mpy (90F). 3 mpy
(130F)

11

0,. trace SO, and mofisture. Allov C = 0.1 row

--

@US 3 percent

--

plus S,O, m compressor condensate


mpy wth less than 1.0 mrl pdtmg.

gas up to 1.5% SO? aerahon

1000 ppm chlorrde. 2000 ppm fluorrde. some SO, and pH 3. 800 ppm
SO,. 15ia H,O. 120 CO,. 68% N?. 5% O?. moderate aeration

1 s

/ -

1 u*

/ 8

for alkylabon

untt

in gas stream wth spray from coolma tower contammn

56

m flue gas from No 6 fuel 011. shale dust. water

140

60

SO, lW-2000
H.0 droolets.

140

60

m gas stream wth spray from coolmg tower contammg

Alloy C = 0 03

H,SO,. aeratron

specimen corroded away or was lost. aerabon. 5% SO,. 3% SO,, 7% 0,.


balance N, saturated wdh water Possrble splashmg wdh solubon con.
tammg 1.3 g/l Cu. pH 6

132

05 mm/y)
to 10 mpy (0.25 mm/y)
mm/y) to 20 mpy (0.51 mm/y)
mm/y) to 50 mpy (1.27 mm/y)
(I 27 mm/y)

Alloy C = 0 1

ppm. HISO, 100-500 ppm. balance wet au. heavy loadmg


contamma Ca salts and ore dust
H,SO,. aerabon

713

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

bv@

ColKmtmtion.
m

Cofrosiw redii

WF

Sulfur Dioxide

316
6th

HA6lEuOv~ all07

TIlaDmtum
drcC

W-2

145

63

1 C/C-276 1 6
E

conditions

&

burmng coal wth 3% S plus 940 ppm Cl, 19 days. fleld test, moderate
aerabon. vmlent agdabon

and MgD (scrubbmg produckofcombustionfrom


aeration

Sulfur Dloxlde

160

71

Sulfur Dloxldt

176

ED

tJ*

*specimen corroded away or was lost. extenwe aerabon. 5% SD?. 6.5%


0, and 88.5% N, Idw baslsl saturated wth water vaoor.

176

80

U*

swclmen corroded away or was lost extenwe aeratton. 5% SO?. 6.5%


O2 and 88.5% N2 (dry baas) saturated wth water vapor.

Sulfur DooxIde
-

Sulfur Dloxlde
Sulfur Dtioxlde

Sulfur Dioxide. Moist


Sulfur Oxldes (Oi 6 Tril

1
1

1
1

MgDrecoverysystem).

230

110

--

in hydrocarbon alkylate plus sulfut~c acid Alloy C = 0.01 mpy

300.350

148.177

--

elemental sulfur mist Oz. H,O and traces of sulfuru acid. In preclpdator
for recovery of sulfur from pyrde gas. Alloy C = 5.0 mpy

180
350

1
1

82
177

1 1 -

1
1

I occasIonat SPfaShlngof Na,SO,

1 -

1 E

ISD,

and H,SO+ Alloy C = 0.15 mpy

16.2%. SD, 1.8%. Hz0 2.0%. 0, 1.4%. moderate aeratmn

Sulfur substltutad
Amylphcnol

257

125

Sulfur Trloxlde

100

38

--

PIUS SOP. N,. CO, at top of Jennson towers m exhaust gas. Alloy C = 0.1
mpy

93

--

PIUS O-5 percent Na,SO,. 0.0.5 percent ZnSD,. O-D.2 percent CSI. trace of
H2S. Alloy C = 1.0 mpy

Sulfuric Acid

o-3

200

Sulfuric Acld

0.4

140

Sulfuric kid

0.1

kid

0.19

140

Sulfuric k#d

0.26

Room

Room

Sulfuric Acld

0.4-8.0

170.220

77.104

l-5

220

104

Sutfurlc

Sullur~c kid
Sulfunc Acld

164177

lto23

Sulfuric kid
Sulfwc

kid

I w 1-l

1
1

302

2.5

1
1

150

118.126
200.250

93.121

E
-

hydrochloric acid 0.057%. pH 2 to 5.2360


waste

hn.. mcmeratlon of muonpal

--

spent pukle s&tions. Cold wash water wth salts puked up m steel pck.
ling (0.097 percent ferrous. 0.003 percent few)
Alloy C = 0.05 mpy

--

plus copper sulfate to saturation. Alloy C = 0.6 mpy

--

1-1-1

plus vegetable, fats, greases. Alloy C = ml mpy


1

) as scrubbmg liquid. moderate aerabon

plus 0.04 percent SD1 and varying amounts of carbon on bottom tray of
SD? scrubber in tegenerabon of alkylabon acid. Alloy C = 0.8 mpy

--

Sulfuric Acid

2.8.9.3

83

28

Sutfunc Acid

70.85

21.29

--

---

max. pdting = 14 mpy. Saturated wth NaCl


plus 0.1 percent copper sulfate and some alcohols. Alloy C = 8.2 mpy
E

alummum sulfate 0.8&3%.


moderate aeration

potasswm chromium sulfate O-O 3%. water.

per 18 gal. Alloy C = 0.07 mpy

plus 20 oz. Na&rlO,

plus FeSD, and 0.05 percent li02 IO.008 percent vahds)

Sulfuric kid

90

32

Sulfunc kid

90

32

Sulfunc Acid

122

50

--

Sulfuru kid

137.153

58.67

Sulfuric Acid

175.185

80.85

--

plus 0.50 to 0.56 oz./gal. of copper. Alloy C = 1.9 mpy

82

--

plus ore contammg

plus 15.25 percent Na,SD,.

Sulfuric Acld
Sullur~c kid
Sulfuric Acnd

Sulfwc

kid

Sulfuric Acid
Sullwc

kid

Sulfuru Acld
E
G
S
B
U

180

5-15

113-131

5 to 150 g/1

160

6-9
7.8

and

hot sulfuric acld solubon (pH 3.0) contammg tungsten and molybdenum
salts wth 2-3 g/l fluorides. moderate aeration

--

48.52

HCI (pfi-21. unreacted chlorme amyl-phenol. sulfur monochlorlde


sulfur dioxide m trace quantities. extensive aeration

E I-ICI

60

73.81

3.4% zwconyl sulfate, 15 days


plus sulfate 011s. traca

of NaCl and Na,SO,.

Alloy C = 0.3 mpy

aeration. lab test 29.5 days

MnO and MnO,


1.5 percent orgamc salts. Alloy C = 0.16 mpy

45.55

--

71

155.175

68-79

155.165

68.74

--

plus 0.8-0.9 oz./gal

7.5-E

200.210

93.99

--

plus 3 percent alummum sulfate. 1 percent lerru sullate pfus traces of


calcium and magnewm
sulfates. Alloy C = 1.6 mpy

120.140

49-60

--

steel ouklina tank. Allav C = 4.7 mov

copparto 60 gilwe.
40. sdver 0 to 12 gILtye. 3.5. Sokds consfist of
precious metals, sdlca. lead sulfate. and a few 0 or less of selemum.
tellurium. anew
antimony and bismuth
plus 0.35 oz/gal. NaNO,. Alloy C = 34 mpy
LND,

m plckkng tank. Alloy C = 2.1 mpy

less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

(continued)

714

Corrosion Resistant Materials Handbook

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

(continued)

TYpr

concon-

316
Stoinloss
Stool

HA6lELLOV~ alloy

Tompontoro

trotion.
Corrosive
Sullurlc

Modio

dep.

wow

ACld

do6.

80.120

27.49

B/B-Z

WC-276

--

Sulfuric

Acid

10

175-180

80-82

Sulfuric

Acid

10

200

93

Sulfwc

Acid

10

Bodmg

Sullwc

Acid

10

225

107

Sullur~c

Acid

15

238.266

115.130

Sultunc

Acld

16

165

74

Sullur~c

Acid

18

170-180

77.82

--

Sullwc

And

Bodmg

19.28
I

140
I

Sulfuric

Acid

20

Sulfurtc

Actid

20

Room

Temp.

Temp
15-90

3%

chromic

672

hrs.

/ 120

hrs.

water

,mpr,t,es.

240 hrs

hydrate

reactlon

to 5% (flnal before dlscardmgl.


(fInall
InhIbIted
wdh Acbvol

220

ferrous
3591

pilotplant

hrs,

sulfate

PIUS 1 6 10 4 8 Percent cOPPer sulfate


C = I6 mpy

, Alloy

I -

1-

1Zr-HF

--

0 09.-

ior~g~nal) to 0 54,:

I plckllng
staInless fad wdh 3 Percent HCI added
Flrsf pIckle,sfollowed
by 15 ml I 10 percent cold HNO,
Alloy C = I mpy
-

$0,. ZH,OT. 0 5 percent


Alloy C = 2 mpy

lab test

1dlcyclopentadlend

E
I

I percent
of Na,W,

I-I

in dewwed

acid

nickel sulfide

Room

S
I

59.194

60
/

E
--

Conditions
plus I percent HF. 3 percent Na,SO,.
1 Na&Fi.
balance
water I separabon

IOr flash

plckllng

of brass

separation

plus cobalt
mpv

sulfate.

ferrous

sulfate.

traces of copper

sulfate

Alloy

7000 oz./ton AK. 200 oz /ton Au. 0 5. Sb. 0 5-. Co.


Trace AK. Au. Sb. Co 90 days

brasw

plus 9 6 percent

E
C
S
B
U

Less than 2 mov IO.05 mm/v1


2 IIIPY IO.05 &I&)
to 10 mf& (0.25 mm/y]
Over 10 mpy IO 25 mm/y)
to 20 mpy (0.51 mm/y)
Over 20 mpy IO 51 mm/y)
to 50 mpy (I 27 mm/y)
More than 50 mpy (I 27 mm/y]

PBnS

ferrous

sulfate

12 percent

anode

C = 12

10.12

mud

lrom

electrolybc

11 as sulfate

Wax

pitting

=3

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

Sulfuric krd

Sulfuric Acrd

25

Sulfurrc krd

2540

28

Sulfurrc Acrd
Sulfurrc krd

25

28

150

Sulfurrc Acrd

I -

I 120

8oihng

Boiling

158

70

lJ

--

135.5

66

267

57.5

100
150

131

G
1

;rz

G
1

G
u

(continued)

hrs.. lab test

340 g/l sodium sulfate


10.15% phosphorrc acrd. 0.5% fluonda.
agitation and aeration - hrgh

G
1

phosphate

1-

sulfur dioxrde purge

8oding
200

i?o;;g

u;

125.135

52.57

--

acrd regenerabon of resin. Alloy C = 0.8 mpy

Sulfurrc Acrd

190.210

88.99

--

plus 22 percent HsPO, rn ran exchanger.

Sulfurrc Acrd

4045

Room

Room

--

40

176

80

Sulfuric krd

40

176

80

Sulfurrc Acrd

40

176-194

--

Sulfurrc Acid

40

Sulfurrc Acrd

41.63

Sulfurrc Acrd

43

8090

257

125

68.203

20.95

:
85

Ambrent
Ambient
Ambrent
Ambrent

Ambient
Ambrent
Ambient
Ambient

Sulfurrc Acrd

45

Ambrent

Ambient

Sulfurrc Acrd

45

Boding

Sulfurrc Acrd

50

Ambient

Ambient

Ambiint

Ambient

Ambrent

Ambrent

Sulfurrc kid
Sulfurrc Acrd

Acrd

Sulfuric krd
Sulfurrc Acrd
E
G
S
8
U

50

50

1
I
I
I

50
50

50
~4

70

21

21

70

50

Sulfurrc Acrd

Sulfuru

50

Sulfurrc Acrd

Sulfurrc krd

50

77

1 &ling 1 Sulfurrc Acrd

Alby C

cetic acid, 12.3 percentHr0

Sulfunc Acrd

U*

) -

--

11

1 E

1-

1
I

acetate fiber productron. held test -

1-

120%

ethanol, 1% ethyl ether, balance watar. 432 hrs. lab test

saturated wrth Cl,. 8 day test

1-

I -

1-

I-j-1

Clr. 113 days


plus 1% CP hydrofluorrc acrd: also 45% CP sulfunc acrd bath wrth ndrogen
purge, 4 days

Clr. 3 days. lab test


40 days
saturated wdh Nr. 3 days, lab test

1109days,
saturated
**welded
Ourabon
Agdabon

--

27

1 -

1-

I
I
1

122

I
I
I

50

I-I-1

70

I -

I u I saturated

- Less than 2 mpy (0.05 mm/y)


- 2 mpy (0.05 mm/y) to 10 mpy (0.25 mm/y)
- Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
-Over
20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
- More than 50 mpy (1.27 mm/y)

saturated wrth CI,. welded

and annealed

wdh Clr. *as-welded


and annealed
of test - 132 days
- 4.1 ft./see.

saturated wdh chlorme. lab test

25

Ambrent

28 days

plus propylene. Alloy C = 24 mpy

80

158

at liquid-vapor utterface.

Zr-HF separabon

Ambient

0.3 mpy

28 day rmmersion test (plant) and various organrcs.


U

E*
E**

saturated wrth Clr. Alloy C = 1.6 mpy


-

plant.

1 tests for selection of material for an acetic acid recovery column for an
acetatdehyde unit, 23 hrs.

Sulfurrc Acrd

Sulfurrc krd

ferbluer

hydrofluonc acrd 5.9%

715

I-

1welded

sample m acrd saturated rith chbrine.

Alloy C = 0.6 mpy

saturated wth chlorine, lab test

wdh CI,. 66 days. 4.1

n/Kc. nor rate

I CI~. 36 days

(continued)

716

Corrosion Resistant Materials Handbook

TABLE 5.18:

E
G
S
B
U

NICKEL-BASE

ALLOYS-CABOT

Less than 2 mpy (0.05 mm/y)


2 mpy IO.05 mm/y) to 10 mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy 10 51 mm/y) to 50 mpy (1 27 mm/y)
More than 50 mpy (1.27 mm/y)

WROUGHT

PRODUCTS

(continued)

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

717

(continued)

deg. C for 18 hrs. then cooled and later dned at 170 deg. C I 10%

E
G
S
B
U

Less than 2 mpy IO.05 mm/y)


2 mpy 10.05 mm/y) to 10 mpy 10.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
Mare than 50 mpy (1.27 mm/y)

M t -

Molar
percent P,O,

(continued)

718

Corrosion Resistant Materials Handbook

TABLE 5.18:

Corroriva

NICKEL-BASE

COrKeotratioo.
parcant

Ydia

Sullur~c Acid Sludge


Sullwc

Acid Vapors

Sultunc

Acid Vapors

Sullurous
Sulluryl

80.98

All

190

100

16-49

70

Tall 011

Tannlg

LlqUOr

Tar Acid

Tar Acid

1
/

Tar Acid
Tartarlc Acid

Acid

Trlchlorobenzene
Vapor. (Commencal)
Ammoma & Chlorides
Trtchlaroethylene

E
G
S
B
U

All

Less than 2 mpy (0


2 mpy IO.05 mm/y)
Over 10 mpy (0.25
Over 20 mpy (0.51
More than 50 mpy

All

m atmosphere

wet process (as ortho acldj. Total P,OI 68.54%. ortho P,OI 51.08%: Fe,O?
= 2.30%: SO, q 2.19%; Al201 = 1.92% F = 0.33% Concentrabon gradually
reduced to 80% H,PO, 154% PIOIl

155

68

wet process. PlOs 70.5%. (HlPO, eqwalent


97.3%). SO, 4.70%. A1201
3.05%. Fe>03 1.67%. MgO 111%. SiO, 0.72%. CaO 0.44%. F 0.25%

400

204

200

93

300

149

--

i -

/ -

*and Its glycerolesters.


phases)

40 percent chestnut extract.


percent hemlock lhquor

300.550

149.288

to 290
288.343

75

24

plus 0 5.1 0 percent


Alloy C = 0.2 mpy

to BP

to BP

302

150

to B P
to B P

to B P
to B.P

05 mm/y)
to 10 mpy (0 25 mm/y)
mm/y) to 20 mpy (0.51 mm/y)
mm/y) to 50 mpy (127 mm/y)
(1 27 mm/y)

BP

H,SO,.

I-

/ -

1-

1 plus

1 E

/ -

/ -

1,j* Alloy
C..O1mpy

/ -

/ -

1I dlstlllabon

!-l-l

/
I

S
-

--

H,SO,,

H+F,

811 and moisture.

to 705 P?O,
2-3 percent

lhgnm m and discharge

durmg successwe esterlllcabons. amldlzabons.


(111.421 hours (hquld and vapor phase)

HIPO,.

lhne

durmg successive estenbcabons. amldlzabons and sulfurlzabans m hvghtemperature reactor. Alloy C = 0 1 mpy llquld and vapor phases

212-3g2 1 1oo-200
1 j 180
/ toB.P

wet process and. concentrating


-

,!-

toB.P

100.200

-I-

S
-

212-392

356

1
j

vented

171

amlds and sulfurlred

30 percent

and sulfurlzabons

products

bwlfated

of tall

lflquld and vapor

quebracho.

30

benzmc acid. H,SO,, Na,SO,. at PH =4 for 11 days then 76days wth


tar acids contammg Na,SO,. Na,CO, at pH = 8. Alloy C ~0.1 mpy

washed cresyl~c acid dlstlllabon

/ 60-70
l - j E 1- l - l
I - I 140-158

Tetrachforoethane

Trlchloraacebc

plus H,S m two stage neutralwr

l-l-l

340

to 554
550.650

100

plus trace water. Alloy C = 2 mpy

Acid

-,--

Over exhaust stack contammg


Alloy C = 0.3 mpy

Superphosphorx

plus 2 percent au. 5 percent CS,.0.2 percent H,S. 93 percent H,O. Alloy C
= 0.2 mpy

to 163

Acld

Tall 011

--

--

Superphosphonc

l-l-l

--

94.8

Tall 011

Acid

(by volume)

Conditions
m large volume 01 011

Superphosphow

21

TYP
316
Sbinlass
Stnl

to 325

(continued)

--I

93

I toB.P

alloy

---

08

toB.P

Oust

82
I

PRODUCTS

WC-276

w-2

66-93

60.120

Superphosphate

Tall 011

HASTELLOvo
dq.

200

Chforlde

180
I

Acid

da;.

150-200

16-22

Suliur~c Acid Sludge

WROUGHT

Tsmprntun

IO.15

Sullur~c Acid Sludge

ALLOYS-CABOT

plus Na,SO,. N&O,

as lmpurmes

pH =

Alloy C = 0 026 mpy

plus some d!chloroethane


H 0. HCI. Cl,. acetylene and a~ I chlqrlnabon
of acetylene Alloy C .O i ;py

aeration

vapor and lhquld

Balling Pmnt

(continued)

Nonferrous

TABLE 5.18:

Twesyl

Phosphate

NICKEL-BASE

ALLOYS-CABOT

304 I

700

371

700

371

570

299

88.go I

580

Tr~cresyl Phosphate

88.90

Trlcresyl

Phosphate

89.90

Twesyl
Crude

Phosphate,

Trlcresyl Phosphoric
Acid. Crude
Trlethanolamme
Hydrochloric
Acld Slurry

90-220

Trlfluoromethyl
Oiphenylamme

Thmcarbamlde,
Hydrochloric
Acld

Urea

Ore

28

3oo

1 14

139

59

113

45

179.182

355.360

E I -

1 -

I -

--

E
G
S
B
U

58.4

350

177

column

trace of cresyhc acld. Alloy C = 0 05 mpy. 13.8OiJ.hr


I

test

--

30 percent

1-

HCI IS added to trlethanolamme

m thlonabon
~AllovC=9mo

I steel tank

process plus some sulfur. todme and monochlor

benzene.

--

pulped uranwm ore contamng


60 percent sohds: 28-55 grams/lder
HzSO,. 5.10 grams/liter fernc loos, some ferrous tons. about 0.1 percent
NaCIO,. Alloy C = 1.3 mpy

--

plus 32 2 percent ammoma. 20.5 percent water. 19 percent CO?.0 3

an aldehyde (unspecified). acebc actd (concentration


neutrabzed wdh 23% sodium hydroxide.

percent ~nerts. plus ar


= 17 mpy
Urea

traces of HCI and orgamc chlorides..

plus 5 percent cresyhc acid, 5 percent thlophenols. traces of HCI MgCI,


and orwvc
chlortdes. 43.day test exposure. Allov C = 0 2 mov
90 days m dlstlllation

1 G I -

phosphate,

plus 5 percent cresyhc acld. 1 percent MgC12. 5 percent thlophenols


Traces of HCI. organfc compounds.
residue tar tank cleaned Inter.
mdtently by sand blasttog. Alloy C = 0.1 mpy

--

719

(continued)

plus5 percent tnphenyl


IAlloC=O1m

E
I

32.104

PRODUCTS

-_-

80

176
!

Uramum

WROUGHT

Metals and Alloys

ammonia

unspwhed).

MIX

In lhquld urea reactor 3 It below top head Alloy C

16.8%. carbon dlorlde

14.8%. water 9.9%. aerabon

Less than 2 mpy (0.05 mm/y)


2 mpy (0.05 mm/y) to IO mpy (0.25 mm/y)
Over 10 mpy (0.25 mm/y) to 20 mpy (0.51 mm/y)
Over 20 mpy (0.51 mm/y) to 50 mpy (1.27 mm/y)
More than 50 mpy (1.27 mm/y)

(continued)

720

Corrosion Resistant Materials Handbook

TABLE 5.18:

Corrosive

NICKEL-BASE

COnCmltration.
percent

Media

HASTELLOY

dQ.

70

21

Gas

(continued)

TYW
316
Stain-

alloy

C/C-276

6/B-2

PRODUCTS

. less
Steel

Conditions
lmpurlbes formaldehyde

--

oxygen 05 -2.0%. N2 upto 10%. HCI 0-1Oppm.


O-5 ppm. aeratmn

H,OO-11%.

above alumma bed m drier Alloy C = 0 1 mpy


*Plus methvl methvl ethvl ketone Allov C = ml mov

Vapor

!i;i:?,lm
Waste

WROUGHT

Tompentun
dq.

Vmyl Chlonde
Liquid and Vapor
Vinyl Chlonde

ALLOYS-CABOT

200

93 1

93

complex solubon, exact camp unknown.


cept durmg 0.1 N HNOl wash ProductIon
1 moderate. idustabfe

I - j - / contalnlng

Cl,. 98 days, moisture

Na,SO, present. pH 12.86 ex.


of N tube phosphors Aerabon

droplets

wth

NaOH. NaCl

Waste Gas

200

Water, Brackish

Water. Brackish

45

Newark Bay Contams 0 70% N&I.


ppm HCI. moderate aerabon

Water. Cold (Fresh)

54

12

at treatment plant Alummum sulfate 20 ppm. chlorine 2 0 ppm. potas.


swm permanganate 0.3 ppm, clay 5 ppm. starch IO ppm Turbidity 5 0.
50 0 units pH 7 3 to 8.0

Water. Cold (Potable)

54

12

at treatment plant Chlorine 08-l 0 ppm. alummum


suspended alum floe [alummum hydroxide) contalmng
lde pH 7 3 to 7 6. saturated

Water, Dlstlfled
and Degassed

600

315

--

water Purlflcabon
Solubon

68

20

Water. Residues of
lnsectudes
and
Breakdown Products

85

29

Water. Rwer and Lake

52

11

Water. Saturated
wth Carbon Oloxlde

204.218

Water. Inclnerator scrubber

Water. Scrubbed
Sewage Sludge
lncmetator Gases

Water. Scrubber

140-165

60-74

Water. Scrubber

160-180

7182

Water. Scrubber

300-400

149.204

Water. Sea

60-95

Water. Sea

75

Water. Sea

82

Water. Sea

95.500

400.425

170.190

contammg

--

droplets

wth

NaOH. NaCl

m exhaust fumes aft 01 mulfler of 40-11 utlhty boat m New York harbor
20.day test Alloy C = 0 1 mpy
100 ppm Ca ++ as CaCOj. pH 6 7.60

Alloy C ~0 1 mpy

Only very slight dlscoloratlon

solotIon

sulfate 0.2 ppm.


manganese d!ox-

water purlflcatlon
(2 5? HCII

mcludmg parathion. morganlc salts mcludlng amnon~um and sodium


chlorides. argan,c reagents mcludlng urea. solvents. pH range 1 5 to
13 5. usually above 8. moderate aeration

Lake Ontarlo pH 8 0 to 8 5 contains


bldlty 5 0 to 50 0 umts

aeration

aeratmn

dUB110

16-35

24

--_

28

--

77-88

Cl,, 167 days, moisture

35-260

1000 grams ground carbon.

2 5 gal water

algae. small fish. lake debris

Tur-

plus 0 008 percent SO, and traces ol dissolved afr Alloy C = 0 6 mpy (IIquid). 0 3 mpy vapor phase
aeratvxl

plus 1 8 percent total solIds. l-2 5 percent SO: absorbed with water I absorption sump Alloy C 0 1 mpy
scrubber

strong Ihquor. I8

percent

SO,. 1 7 percent

NaCl

20 000 ppm. Cl eons at a pH of 6 6 Contans from 2 5 to 104 5 mg 0; per


lhter Test at suction end 01 pump casing under high ag,tat,on
_

I asphalt plant gas scrubber

Plus 0~. SO- hydrocarbon

Alloy C = 0 8

mpy

Water.
Sea

203

95

Water. Sea

325

163

--

I discharge

Water. steep

125.135

5257

--

plus 0 10.0 14 percent SO, Alloy C 0 1 mpy (I,quld and vapor)

Water. steep

150

Wash Water from Rayon


Staple Bleach Machme

Wash Water from Rayon


Staple Bleach MachIne
E
G
S
6
U

Less than 2 mpy (0


2 mpy (0 05 mm/y)
Over 10 mpy (0.25
Over 20 mpy 10 51
Mote than 50 mpy

66

145.150

162 168

63-66

72-75

___

_.

saturated

with Cl, Alloy C = 3 mpy


lhne of tubular

heat exchanger

plus 0 02 percent SO>. 0 5-l 0 percent


E

Velocity

IactIc acld

= 5 11 per xc

pH 3 5-4 5

aer.aon

1 E 1 E 1 E / aerat,on

05 mm/y)
to 10 mpy 10 25 mm/y)
mm/y) to 20 mpy (0 51 mm/y)
mm/y) to 50 mpy (127 mm/y)
I1 27 mm/y)

(continued)

Nonferrous Metals and Alloys

TABLE 5.18:

NICKEL-BASE

Conosiw

COlW4ltntion.
pwxnt

Media

ALLOYS-CABOT

dy.

dw.C

70
-

26

176.212

80-100

PRODUCTS

we-2

C/C-276

TYW
316
StainIns
Steel

HAnELLOr~

TCmpm-aturo

Waste Effluent

Whey Salts

WROUGHT

dloy

--

721

(continued)

Conditions
contammg
sutlurx
moderate aerstmn

acid.

esters.

lime.

waxes.

011s. lormaldehvde.

plus tacbc acld. NaCI. and lactose I 70 percent ethyl alcohol

Alloy C = nil

wv
-

70-100

21-38

___

194.302

go-150

--

m malelc acid dehydrabon column Plus lmpurlbes such as benzene. 1


percent malelc acld as malelc anhydrIde and tracesol water Alloy C 0 1

Xylerle

325-350

163.177

--

effluent mixture contammg water. acetic acid. benzoac acad. tolulc aad.
tolualdehvde. acetophenone and hvdrocarbons as pr!mary constituents
under 25.111 vawum
Alloy C = ml py

XYlOl Solvent vapors

77-293

25.145

Leot1te water Softener

--

300 ppm chlorides. 10.38 ppm carbonates. 0 6 ppm bicarbonates I


dome of deaerator m steam Extenwe aeratmn and high agabon
Alloy C
=Olmpv

Zmc Carbonate

70-180

21.82

--

2 lb per gallon Z&O> plus 10 percent Na,CO> sullldes and sullur~c acid
as lmpuribes Process IS conversion of Na,CO, to Na SO, Alloy C = 0 03
mLw

1-

Wood fracbons

alternately crude pine tar 011.pvrollgneous


1 percent methanol, phenols)

acld (2-5 percent acetIc acid

mpv

Slurry

Zmc Chloride

71

Zmc Chloride

80

Zmc Chloride

21nc Chlarlde.

Chromated

211x Chlwde

flux

Zinc Ckhvdrogen
Phosphate

Zmc Hydrosulbte

225

1 -

107

Bolllng

fto1hng

All
100

to 6.P
to 700

to 8 P
to 371

to 260

to 127

--

75.80

24-27

l-l-l

Room

--

::
36
50

75
150
75
150

;;

7
_
-

E
U
E
u

---

45lbs/gal

21nc Sullate

30.34

21nc Sulfate

34

21nc Sullate

:;t

IJ

38.47

solubon made by mwng


tm~m plnlng = 2 mpv

Ireserwr

plus I to IO percent

above steam chest ol smgle stage evaporator


percent free H.SIF, 40.day peraod

m manulacture

Na:Cr 0 H,O and lead peronde


Alloy C = I5 mpy

232

Ill

as ZnSO, 6H 0 plus 8 8 percent 2nCl


water Alloy C galned wght
shghtlv

to BP

to BP

68.122

20-50

21nc Suilate.
Anhydrous

219-232

21nc Sudate
Drw Fumes

103-111
I

lerrous

sultate

ZnSO, plus

I 04

lb ZnCl per Walton 01 water Allov C =

above rotary drum drwr

plus traces al Fe. Na. Cd. Cu. conslderabte 0 In flash evaporator


concentrat,on ot load lhquor Alloy C = 0 5 mpv

93 percent

220

104

21nc Chlonde

269-293

132.145

21rcer Llquld Phase


Hvdrochlorlnabon

795

424

and

213 g/l

1 percent

BP

added to remove fron and manganese

43

05 mm/v)
to IO mpv IO 25 mm&l
mmivj to 20 mpy 10 51 mm/v)
mm/y) to 50 mpv I1 27 mm/v)
[I 27 mm/y)

Alloy C = 0 1 mpy

Less than 2 mpv (0


2 mpv IO 05 mm/y1
Over IO mpv 1025
Over 20 mpy (0 51
More than 50 mpv

1percent
HCI 1

plus (at start) 252 gil H SO,. 56 6 g/l Zn. 0 04 gil Fe At llmsh
H.SO,. 48 3 gil Zn. 0 41 g/l Fe and 046 g/l Cu
2 42 lb anhydrous
IOO3mpv

I-

to

110

I-

Plus

21nc Sullate
Monahydrate

lree H:SIF,

E
C
S
8
U

Alloy C = 0 16 mpy

111

Max

Alloy C = 0 007 mpy

ndrosvl chlonde

38-104

232
100-220

and 20 percent Na CrO

to 40

40

80 percent InCl

tank pr,or to welding

plus small amount

Zmc Sulfate.
Acid Sotubon

Zmc Sulfate
Monohydrate

---

Room

loo-116

PCI, and HCI

25

1-

plus 2 percent

COllC

Zmc Fluosdlcate

21nc Fluoslllcate

E
-

for

H.SO, plus 34 percent InSO,

aelatIOn

U
s

AICI,. NH,CI plus gaseous HCI. 7 day3 I hquad


, soor

9Oltlng POlnt

(continued)

Nonferrous

TABLE 5.18:

NICKEL-BASE

ALLOYS-CABOT

WROUGHT

PRODUCTS

Metals

and Alloys

723

(continued)

HASTELLOY
alloy G-3 is an improved
wrought
version
of HASTELLOY
alloy G. Alloy
G-3 has the same excellent
general
corrosion
resistance
as alloy G, along with greater
resistance
to heat affected
zone attack
and excellent
weldability.
HASTELLOY
alloy G-3 has outstanding
resistance to hot sulfuric and phosphoric
acids. Alloy G-3 will
withstand
the corrosive effects of both oxidizing and reducing agents and can handle both acid and alkaline solutions. Alloy G-3 has excellent resistance to mixed acids, sulfate compounds, contaminated
nitric acid and flue gases.
Alloy G-3 is resistant to stress-corrosion
cracking as measured by the boiling MgCls Test (ASTM G30 and G36). In
oxidizing acid chloride pitting media, alloy G-3 has good resistance to localized attack.
Alloy

Aqueous Corrosion Data for HASTELLOY


Average

Penetration

G-3
Rate per year

Concentration,
percent by
weisht

Test
Temp.,
F (C)

Alloy G-3
mils
mm

99

Boiling

0.6

<0.02

10

Room

0.1

<O.Ol

14

0.36

10

122 (50)

30

0.76

a5

2.1

Ferric Chloride
+ lO%NaCl

Room

Nil

NII

122 1501

Nil

Nil

Formic Acid

30

Borlina

0.10

40

Boding

0.10

60

Borlino

0.13

88

Boilina

0.15

Media
Acetic

Acid

Ferric Chloride

Hydrochloric

Acid

Nitric Acid

Phosphoric

Acid

150 (66)

0.3

<O.Ol

Room

5.7

0.14

10

Boiling

0.8

0.02

0.8

0.02

65

Boilrna

10

0.25

22

0.56

0.2

<O.Ol

30

Borlrng

2.4

0.06

0.10

50

Boiling

0.10

0.18

55

Boihna

0.13

70

300

8.6

0.22

(1491

Boiling

27

68 (20)

1.1

95 (35)

2.5

0.06

150 (66)

9.4

0.24

Boihno

12

0.30

11

0.28

10

Boding

19

0.48

14

15

Boilina

26

0.66

Gas

Sulfuric Acid

Saturated

with Chlorine

mm

20

a5
Seawater

Alloy G
mils

0.69
co.03

20

0.51

0.36
-

0.81

Room

Nil

Rnnm

<0.03

44

86 (30)

0.2

co.01

Sulfuric Acid

50

Boiling

12

0.30

+ 42 g/l Fe2(SO.&

50

Boiling

17

0.43

Sulfuric Acid + 3% HCI


+ 1% FeCl3 + 1% CuCl2

7
7

Sulfuric Acid
+ 6% HN03

*With cwwce bolt


All weld metal IshIelded metal arc welded1
-Not tested

724

Corrosion

TABLE 5.18:

Resistant

Materials

NICKEL-BASE

ALLOYS-CABOT

LOCALIZED

AVERAGE

Handbook

CORROSION

COMPARATIVE

WROUGHT

RESISTANCE

PRODUCTS

kontinued)

IN PULP AND PAPER INDUSTRY

FIELD CORROSION

DATA IN SO,

ENVIRONMENTS

CONTAINING

CHLORIDES

Field tests of corrosion


test spools
in a variety of SO? pollutton
control environments resulted ln noselective
corrosion on any of the HASTELLOY@ alloy
G or C-276 samples. All other alloys tested showed pitting and/or crevice corrosion to varying degrees A complete summary of the data IS shown in the
table below

Chloride Average To11


TOmpW~tUrC.
Avenge
CO~lWlt,
PPM
deg. F (deg. C)
pH
Low pH Conditiona 165
550
1000
1500

105
120
120
127

Under 4.6 pH

Low Chloride Condilionr


500
500
550

2 5-7
45
4
3 5-5 7

(41)
(49)
(49)
(53)
-

125
200

5
54
49
-

120
120
120
115

::

(49)
(49)
(49)
(46)

55
59
6
6
62

High Chloride Conditiona 2250


2900
2900

120 (49)
110 (43)
110 (43)

High Chloride Conditions


1500
2900
3000
10000

127
110
120
120

High-Temper4lurc
2100
2100
2300

10)
15)
58)
18)

5 (0 13)
17 (0 431
0

3 (0081
lo
0

1(0

00
0
0

1 (003)

0
0
0

0
0
0

:
0

0
0

: (0 18)
0
03)
1 (0 03)

E
i

4.5 lo 5.5 pH
5
45
5.5

(53)
(43)
(49)
(49)

6 (015)
1 10031
0

5.5 to 6.5 pH

120 (49)
120 (49)

500
200
500
850
1000

(0
(0
(0
(0

4.9 to 5.4 pH

130 (54)
120 (49)
130 (54)

Low Chloride Conditionr

4
6
23
7

11 (0 28)
4 (0 10)
3 (0 06)

pH above 5.7
57
85
7
6

0
0
1 (0 03)
2 (0 05)

7
65
6

10 (0251
28 (071)
22 (0 561

Condilionr

160 (71)
160 171)
150 1661

1 (003)
0 (0 25)
(0411

i 16

2 (005)
10 (025)
9 (0 23)

Nonferrous

TABLE

5.19:

NICKEL-BASE

ALLOYS-STAINLESS

FOUNDRY

Metals and Alloys

725

& ENGINEERING

ILLIUM
98 and ILLIUM
B perform
very well in processes which involve
the use of sulfuric,
phosphoric,
hydrofluoric,
nitric,
acetic
and fluosilicic
acids as well as sodium
chloride
brine. They resist erosion
to abrasion
in corroding environment.
These alloys have high mechanical
rigidity.
The 98 alloy is nonhardenable
while the B alloy is hardenable.
Results of ILLIUM

ILLIUM

98

ILLIUM

Sulfuric Acid
Sulfuric Acid

2120

0.015

95%

Sulfuric

212

0.01

Sulfuric

Phosphoric

Acid
Acid

212

0.0065

0.0095

0.0195

Acid

(Super
98%

Phosphoric
and

fluorine

compounds

Phosphoric

7%

Phosphoric,

0.044

compounds

Phosphoric

237O

0.024

0.0001

NJ.

Hydrofluoric,
Sulfuric

Acids,

60'

Water

Saturated

with

brine

None
N.R.

in

evaporator

hydro-

and fluorine
compounds

1000

0.0027

Acid

Hydrofluorilitic
1 boo

Acid

I l/.

60'

Acids,

Water

Sodium Chloride Brine

fluoric

N.R.

(Saturated)

fluorine

13%

0.001

3%

and

Hydrofluosilicic

1 O-300

Detected
375-410

Hydrofluoric,

3%

0.0066

ILLIUM

(in

tolumn)

otid

sulfuric,

sulfuric,

Atid

90%

390-460'

voporr

39%

100-O%

4%

0.0053

with

sulfuric
98%

fluorit,

8b0/e Sulfuric
300

Phosphoric)

98

Hydro-

Sulfuric
10%

ILLIUM

Acid

loo/_

stripping

Phosphoric,

101%

55%

0 to

0.005

Corrosion
Rate
Inches
Per Year

Temp.
OF

ENVIRONMENT
Hydrofluoric

98%
90%

B in Tested Applications

Corrosion
Rate
Inches
Per Year

Temp.
OF

ENVIRONMENT

98 and ILLIUM

1860

C 0.0001

< 0.0001

Soturoted brine in
evaporator hoot
exchanger

233O

< 0.0001

< 0.000

Saturated brine in
evoporotor
discharge

248

NR -

Hydroftuorilitic

1bO*

Acid

0.0021

Not

recommended

for

this

0.0001

0.0002

N.P.

0.0017

service,

NJ.

lLLlUM
G is highly rated for its resistance to a wide variety of corrosive chemicals.
It withstands the corrosion of
both oxidizing and reducing agents, acid and alkaline,
up to moderately
high temperatures.
It is especially
resistant
to most sulfur compounds.
Generally
it is not recommended
for halogen;
halogen acids or halogen salt solutions;
it
is, however, highly resistant to seawater and to fluorine compounds in an oxidizing
environment.
Results of I LLIUM
Code: R =
A =
B=
C=
D =
E=

Substance or Process

-SO%
Aluminum Sulfate
Ammonio

Applications

Recommended for use-quantitative test results not furnished


Not more than 0.004 penetration per annum - less than
0.004 to 0.015 penetration per annum
1 mg/cm*/day
0.015 to 0.050 penetration per annum-approx.
1 to 3 mg/cm2/day
0.050 to 0.125 penetration per annum
Over 0.125 penetration per annum

Conditions

Acetic Acid
-Concentrated
-50%
5%
Concentrated

G in Tested

Plus 20% by Vol. 25%


Formic Acid
Plus approximately 2%
KMnO.
HISO boil of clay
Effluent from clay boil

Temp.
OF.

RaIa

Boiling
Boiling
Boiling

A
A
A

Boiling

230
300
210
70

A
E
A
A

Subrtanco or Procorr

Conditions

lamp.
lF.

Rok

Ammonium

Bromide-30%

120

Ammonium

Carbonate-25%

70

Chloride-30%
-25%
Ammonium Hydroxide
-Concentrated
-Conce.nMed
-28%
Ammonium Sulfide
Saturated

330
70

A
A

70
70
70

A
B
A

Ammonium

Still solution
Agitated solution
Agitated solution

70
A
(continued)

726

Corrosion Resistant Materials Handbook

TABLE

5.19:

NICKEL-BASE

Substance or Process

ALLOYS-STAINLESS

Conditions

Arsenic Acid-75% to
90%
BoricAcid-liquor
- 6%
Butyric Add-60%

Solution concentrated by
boiling

Colcium Hypochlorihs

2% available chlorine

Saturated with free sulfur


Plus 3% by volume of
Bromine
Chlorine
Moist
Dry
Chrome Tanning Solution Concentrated

Citric Acid
Copper Sulfate-25%
-9% to 10%

33%

Plus 5% by Vol. H,SO,


Pump handling 1t/s% to
36% acid
(See olso H,SO, mixtures)
Solution concentrated by
boiling

Ethyl Acetate-Crude
Ethyl Acetate

Rate

A
A
A
A
C
A
A

Boiling
150
70
7o

Carbon Tetrathloride

Chromic Acid-SO%
-25%
-25%
-35%
-Varying

lamp.
OF.

FOUNDRY

Distillotion

Ethyl Gasoline

7o
Boiling
Boiling

E
E
R
A
A
E
E
E
A

Boiling
2oo
76O
76O
Boiling
Boiling
180
7o
7o

R
R

7o

Boiling
167O

A
B

212O

7o

Fatty Acids

Ferric Chloride-43%
Ferrous Sulfate
formoldehyde-lO%
Formic Acid-80%
-25%
Fruit-Juices
Gasoline

176O

7o

R
A

(See also H,SO, mixtures)


Boiling
7o
With H,P04, SiO, ond
steam in vopor phase of
polymerization tower

Hydrochloric Acid-Conr
Concentrated
-32%
Hydrochloric Acid-22%
-22%
-16%
Aerated solution
-10%
-10%
- 7%
- 7%
- 5%
Wosh liquor
- 1%
Concentrated fumes
Hydrofluoric Acid
-Anhydrous
-Anhydrous
Plus 5% by Vol. 98%
HzSD.

5oo
loo0
7o
105O
1200
7o
120
loo0
70
120
7o
7o

A
A
R

A
E
E
E
E
D
E
C
A
E

113O

:
R
A

7o

7o

& ENGINEERING

Substance or

Process

Hydrofluoric Acid
-Anhydrous
-Anhydrous

(continued)

Conditions

Plus 77% by Vol. 98%


H,SO.
Plus 57% by Vol. 98%
HSO.
_ .

5%

Tamp.
OF.

Rotm

70

70
70

A
A

&So

A
R
A
A
R
R
A
R
A
R
R
A
A
B
A
B
R
A

HydrofluosilicicAcid
- 0%
Hydrogen Peroxide
lactic Acid-10%
-10%
Lithopone Sludge
Magnesium Citrate
Malic Acid
Mine Water (acid)
Mercury
Nickle plating solution
Nitre Cake Solution
Oleic Acid-Comm.
Olive Oil
Oxalic Acid-15%

16D
700

70
See Note 1
9
15% H,SO,

- 8%
Phosphate Rock Acidulation Hot gases (SD,, SD,, CD
Pickling Solutions
10% to 12% H,SO,
Spent solution
Cold woter wash tank
solution
Hot water wash tank
solution
Picric Acid4onc.
Potassium Aluminum Sulfate-30%
-15%
Potassium Dichromote--S% (See also H,SO, mixtures)
Potassium Hydroxide
-30%
Potassium Permanganate
- 2%
Pyrogollic Acid-30%
Pyroligneous Acid-pure
Rayon-Viscose process
Coagulating Bath

(See OISOHxSO, mixtures)

Sodium Acid Fluoride

70

A
A

250
70
70=

B
A
A

Boiling

70
70
70

A
A
A

lor removed
Various solutions generally
containing 10% to 15%
70e
H,SO, with sodium sulfate to
and other salts
200

Sea Water-Gulf of Mexico Completely immersed


Partially immersed
Intermittent immersion
(tides)
Sewoge
Silver Nitrate-SO%
Sludge Acid

70
?
?
70
70
Boiling
70
lSOO

Atmos.
Atmos.

A
A

Atmos.

120

R
A

160

140

Meter parts
Refinery waste-37%
HaSO.
Refinery waste-25%
HSO.
Saturated soln containing
HF

A
8
R

1200
c
(continued)

Nonferrous Metals and Alloys


TABLE 5.19:

NICKEL-BASE

ALLOYS-STAINLESS

FOUNDRY

(continued)

& ENGINEERING

Temp.
Substorw

or

Process

Sodium Aluminum Sulfote


Sodium Chloride
-Saturated
-16%
Concentrated
-36%
Sodium Hydroxide-70%
48%
-36%
-25%
- 5%
-Concentrated

Sodium Hypochlorite
Sodium Metophorphate-1.3%
Sodium Nitrate-IO%
Sodium Sulfide- 8%
Sodium Thiorulfate-Commertiol
Stonnic Chloride-24%
Sulfonotion Proczrs
(Petroleum products)
Sulfur (Molten)
Sulfur Dioxide
Sulfuric Acid
-Fuming (109%)
Sulfuric Acid-Mixtures with
Acetic Anhydride

Copper Sulfate--SO%

Rate

(See also H,SO, mixtures)

Sodium Acid Sulfate


-24%

Sulfuric Acid-Mixtures
Chlorine

.F.

Conditions

Pump in service
Strong crude

Salt spray test


Kept olkoline with NaOH
Plus traces of free Cl,

Sulfuric Acid-Mixtures
Copper Sulfate-10%

R
A

B
A

Boiling

Boiling

Boiling

Boiling

7o

Boiling

Boiling

54O

21

Boiling

Boiling
Potossium Dichromote
Boiling
- 5%
Potossium Permonganote
Boiling
- 5%
Sulfurous M-0.75%
175O
lortoric Acfd-25%
70
Tetraphosphoric AddConcentration not reported 140
Concentration not reported 24B
Concentrationnot reported 356O
Urea
Under 1125 Ibs. pe.rsq.
3180
in. pressure
Vegetoble Juices
Yeast Wort
94O
Zinc Chloride
70
From shorted dry cells

1100
350
150

125O

R
B

wpillority.
where
Note

This
exact

No.

2-MOLTEN

cate

that

lllium

G,

gain

in

weight

or

periods

of

time.

tokc

tendency

volumes

common
to
and

up

with

prohibits
dimensions

many

dimensions

other

Mercury

SULFUR-Tests
unlike

5%

71/1$:f soln with 921/,%


Cant H,SO,
23% of soln with 77% of
78% H&
Equal parts with 25%
H,SO,
Equol parts with 25%
HSO.
Equol parts with 25%
H&
Equal ports with 25%
H,SO.

Sodium Dichromote
45%
Sodium Sulfate-10%

250

tendency

-Concentrated

7o

l-MERCURY-In
(I

5%

-10%

63% H,SO, saturated with


104O
Cl,
Equol parts with 25%
Boiling
f&SO.

No.

Hydrochloric Acid
-Concentrated
Nitric Acid -25%

With

exhibits

5%

-10%

Note

Equal parts with 25%


H,SO.
Equal parts with 25%
HSO.
Mixed with H,S04
Equol parts with 25%
HaSO.
Equal ports with 10%
HSO.
Equol parts with 25%
HaSO.
Equal ports with 10%
HSO.
5.8% of soln Cont. 1.8%
H,SO.
Equal parts with 25%
H,SO.
Equal parts with 25%

Boiling
138O

120
87O
77O
70
Boiling
7o
7o

Equal parts with 98%


H,SO.

With

-16%
Ferrous Sulfote-Sot.

160

its

Rare

OF.

85O
140
122O
194O

25% HzS04, then 25%


No,SO,, 25% NoOH
See Note 2
Plus SO, ond CO, gores

Conditions

Boiling

80
7o
loo0
Plus NoCl, Na,SO,
NaClO,
Effluent from cell, olro
contoins NoCl, No,SO,,
No,CO,, NoClO,
15% avoiloble Cl,
Bleaching solution (?)
Bleaching solution (?)

Tamp.

Substance or Procars

104O
150
7o

727

complex

through

5%

alloys,

some

use

for

thermometer

must

be

kept.

conducted

other

corrosion

from

immersion

in

molten

resistant
in

the

llllurn

intcrgranulor
bulbs,

sulfur

alloys,
tluid

does
over

etc.,

indinot

long

E
B
A
A
A
A
A
A
:
A

728

Corrosion Resistant Materials Handbook

TABLE 5.20:

NICKEL-BASE

ALLOYS-WALL

COLMONOY

Corrosive media in which Colmonoy

Acetic Acid (cold)


Alcohols
Alum
Aluminum Acetate
Aluminum Chloride
Ammonia (anhydrous)
Ammonium Bicarbonate
Ammonium Carbonate
Ammonium Chloride*
Ammonium Hydroxide
Ammonium Nitrate*
Ammonium Oxalate*
Ammonium Persulfate*
Ammonium Phosphate*
Ammonium Sulfide
Amy1 Acetate
Arsenic Acid
Azo Dyestuffs
Barium Hydrate
Barium Nitrate
Benzoic Acid
Benzyl Alcohol
Black Liquor, Soda
Black Liquor, Sulphate
Boric Acid
Butyric Acid
Calcium Carbonate (cold)
Calcium Chlorate (dilute)
Calcium Chloride
Calcium Hydroxide
Cane Sugar Liquors
Carbolic Acid (Phenol)
Carbonic Acid 1
Carbon Dioxide
Carbon Disulfide
Carbon Tetrachloride
Caustic Potash
Caustic Soda
Chlorine (anhydrous)
Chromic Acid
Citric Acid (to 15%)
Copper Acetate
Copper Carbonate
Core Oils
Cotton Seed Oil
Developers, Photographic
Di-Methyl Ethers
Ethyl Chloride

nickel alloys are generally resistant

Ethylene Glycol
Fatty Acids
Formaldehyde
Formic Acid (5%)
Ferrous Sulphate
Ferrous Arnmonium Citrate
Callic Acid
Gasoline
Gelatine
Glutamic Acid
Glycerine (Glycerol)
Helium
Hydrocarbons
Hydrochloric Acid (dilute
and cold)
Hydrofluoric Acid (cold)
Hydrogen
Hydrogen Peroxide*
Hydrogen Sulfide (anhydrous)
Kerosene
Lead (up to 900 F)
Liquid Sodium, Potassium,
or Nak (up to 900 Fj
Linalyl Acetate
Lye
Lysol
Malic Acid
Manganese Carbonate
Manganese Chloride
Magnesium Chloride
Magnesium Hydroxide
Magnesium Nitrate
Magnesium Sulfate*
Mercury
Molasses
Molten Class
Monoethanoiamine
Naphtha
Natural Gas
Nitric Acid*
Nickel Sulfate*
Oleic Acid
Palmitic Acid
Peroxide Bleach Liquors

Petfoleum Oils
Phosphoric Acid*
Phosphorus Bromide
Potassium Carbonate (cold)
Potassium Chlorate
Potassium Hydroxide
Resins
Rosin
Shellac
Silver Nitrate
Silver Chloride
Sodium Citrate
Sodium Hydroxide
Sodium Nitrate*
Sodium Peroxide
Sodium Silicate
Stannous Chloride*
Steam (up to 1000 F)
Sulfur Dioxide*
Sulfuric Acid*
Tannic Acid
Tar
Tartaric Acid*
Toluene or Toluol
Trichloroethylene
Turpentine
Uric Acid
Vanadium Oxide
Varnish
Vegetable Oils
Vent Gas
Vinegar (cold)
Vinyl Chloride*
Viscose
Water (hot and cold)
Whiskey
Wines
Xylene or Xylol
Yeast
Zinc Chloride
Zinc Sulfate
*Resistant under certain conditions.

TABLE 5.21:

NICKEL-BASE

AND OTHER

HIGH ALLOY

PIPE AND TUBING-COLT

INDUSTRIES

wnt, ch*moul shipping drums.


mnt and piping. *lecbonic parts,
zmponmt,. rocket mototqrcr.
tit

and Wcb-onic compownts,


! v.?meIs and
I teat

I Fu~ee mutfkn. &c.tmnic compbwnta. chemiut and


xstrinp equipment, hoat Wlttng quipmom
wgensnto, tubing.
ALLOY

601
ALLOY

625
ALLOY

G
ALLOY
G-3

20

Q 23.00

UNS WMOl. ASME Co& clrr


Ni 51.00

Hiih smnpm md toughnear (mm c*og+nic


1SWF (OWC) good oxidltton
nittlncc, oxoptional btigue sbongth and #ood
nsirllncc to m8ny conosivcs.

trmprnbns
to

Chcmic#l md pWtion co~tml quipmsnt, ducttng, bit


bftw hmv3linpquipmcnl twl mxzk~. alter bumm.

UNS ND5M7 ASTM S-625 T&m.


ASTU Sdl9 pip
CI 22.50Yo 5.50 Ni 44.00 Cu 2.W

E~cslknt nairbmc in many m&a. Resists pttttnp,


cwicc conwion md mtwgnnulm eonotbn.

Y~nutxtw~ end USCot ph osphxmc md ruttulic uidr,


ftuc.ge, scwbbcn and 0th @Ipotlvbon control q*PmW
cnponto,,, b.1 ..eh.m

UNS No6985ASTM S-S28 Tub@,


ASTM S-619 Pge
b 21.00uo 1.00 )(i 724

Simlu to G. batter Ior welding, no anwll

600

Cl 21.w Nt

ALLOY

826

3%

E-515 TW

URS Row10 ASTM B-515 Tub@.


ASTM S.514 Pt@
Q 21.00Nt 32.50
WS -25
ASTM b7Y Tubr,
ASTM b7S5
c12.5SyoS.% Nt42xQCuz20

Sbonp and nrisunt

A Q-E

AG-EG

NR G-E G-E G-E G-E

NR

GO-EG-EX

Q-E G-E G-E

NR

NR

A G-E G-E G-E A

G-E E G-E G-E G-E

G-E

Q-E Q-E G-E G-E G-E G-E Q-E G-E Q-E

mquimd.

ASlW&454F+p@
Cl 19.00Ma 2.00 11131.q w 3.q
f&tt4

800H

E~cellcnt hiih-bmpntwe
pmpefttie& resistance to
Ra cxchmgcn, ha4t-tmating bqk@s and hrmmr.
ordizinp, ulwizinp.
and udtur-con(lining W1~sph4nr. ndiutt tube& thcmwwpk
b~ubrr.combusbon qnr,
Wcmti engine wnr.

UNS NM525 ASTM 5704 Tube.


ASTM 11-705pip4
Cl 21.50Ma 9.w Ni 61.00

ALLOY

ALLOY

1500

to orid8tion and c.(lrbukHton It

dewted
tempcntunr.
Rwi4t1 rutt&

I
1Heat
crch~n~cn.

pmctrr.pping,

ClfbUdzabOn ttxWNS Wd

oxid&m, ruling and conosion in I


*wtpbww

Stmilr M 800 wtth brnrr high tempntun


stmngth
h,, drrign stmqth vaiwt IDI YH &we 115OF
(5%C). Imprwd cmep aid ,tro,-to-rupem
pmpetier
in 1lWF to lMOwF(595C to 950%) ngc.
Exd*m n,t,br_
._ i._ .__i__. _. __-_:____

Chemical and po*ur plant rupcr helter and n-hwtcr


tubby, hqtan and lumacc tubing, pmcesl piping.

Rwista pttbng and


oxtdirino

I I I I I I I I I
1 1 1 1 1 1 1 1 1
I I
A

NR

A Q-E G-E

,
A

C___. _.__I___
.__I_I____. - __..__. ^L__ i__l *-..L.

_:_ .,__. _..__.__,__.._


mm-boundary urbda

I._____._.._.._..__._.
zone.

.
Q-E

E Q-E G-E NR G-E Q-E G-E Q-E

I I

730

Corrosion Resistant Materials Handbook

TABLE 5.22:

NICKEL-BASE

RODS, ELECTRODES

AND WIRES-CABOT

Nickel-Base

Alloys

Nominal chemical composition,

percent
W

Hardness,
Rockwell

2.5

C-42

2.5

c-51

Bal.

3.5

C-57

Bat

2.3

C-46

Bal.

B-96, C-37

Form

Cr

Si

Mn

MO

DELORO alloy
No. 40

11

0.45

2.55

2.25 Bat

DELORO alloy
No. 50

12

0.35

3.5

Bat

HASTELLOY
alloy C

HAYNES alloy
No. 711

15

0.75

D,E

12

0.7

3.0

17

0.1

17

Co

1.5

B-96, C-35
27

2.7

23

Bat

12

c-40. C-43

B
A

HAYNES alloy
No. 721

C-42
26

1.1

1.5

29

23

11

0.5

3.5

C-30, C-32
C-24

B
17

0.4

17

5.5

Bat

6.5

4.5

C-27:

B
D

29

1.1

1.5

5.5

Bal.

0.6

c-37

Corrosion

C-39

c-22. C-36

C-26
Code:
A-Bare Cast Rod
B-Covered
Electrodes
C-Tube Wrre-Sub-Arc
D-Tube Wire (Gas Tungsten Arc)
E-Tube Wtre (Gas Metal Arc)

Maxrmum
** Work-hardened
Gas-tungsten
arc only

Comparativa

Ni

HAYNES alloy
No. 716

HAYNES alloy
No. N-6

Fe

NrckeCBase Allow

DELORO alloy
No. 60

STELLITE

Data*

Gas Tunasten Arc Deoosits

Concentration
and Temperature

HASTELLOY
alloy C

DELORO
alloy
No. 40

Acetic Acid

30%, Boiling

Nitric Acid

65%. 150 deg. F


(66 deg. C)

Formic Acid

60%. Boiling

Sulfuric Acid

5%. 150 deg. F


(66 deg. C)

Media

Five 24-hr. test periods. Determined in laboratory tests. It is


recommended that samples be
tested under actual plant
conditions.

DELORO
alloy
No. 50

DELORO
alloy
No. 60

STELLITE
alloy
No. 6

Code:
E-Less
G-5

than 5 mpy (~0.13 mm/y)

mpy (0.13 mm/y) to 20 mpy (0.51 mm/y)

S-Over

20 mpy (>0.51 mm/y) to 50 mpy (1.27 mm/y)

U-More

than 50 mov (~1.27 mm/v)

HAYNES
alloy
No. 716

TABLE

5.23:

TANTALUM-NRC

Temperatures

at which various media attack Tantalum

Air
Alkaline solutions

g*

Ammonia

gas
gas
gas
gas
aqueous

Br0mine
Chlorine, dry
Chlorine, wet
Fluorides, acid media
Fluorine
Hydrobromic acid, 2570
Hydrocarbons
Hydrochloric acid, 25%
Hydrotluoric acid
Hydrogen
Hydrogen bromide
Hydrogen chloride
Hydrogen fluoride

aqueous

gas
aqueous
gas
aqueous
aqueous
gas

Iodine
Xtrogen
Oxalic acid, sat. soIn.

gas
gas
gas
gas
gas
aqueous

Oxygen
Phosphoric acid, 85%

gas
aqueous

Potassium carbonate

aqueous

Potassium hydroxide 10%


Potassium hydroxide
Potassium pyrcsulfate
Sodium
Sodium
Sodium
Sodium
Sulfuric

carbonate
hydroxide 10%
hydroxide
pyrosulfate
acid 98%

Sulfuric acid (&urn)


(over 98% HSOJ
Sulfuricttioxide
Water

aqueous
molten
molten
aqueous
aqueous
molten
UlOltell
aqueous
fuming
gas
aqueous

Comparison of corrosion rates for Tantalum,


304 Stainless Steel and Platinum

At temperatures over 300C


At pH > 9, moderate temperatures some corrosion
Pits at high temperatures and pressure
At temperatures over 300C
At temperatures over 250C
At temperatures over 350C
All temperatures and concentrations
At all temperatukss

AICI, (lOye soln)


SH,CI (10% win)
HCI, 20%

Begins to corrode at temperatures over 190C


React at temperatures around 1500C
Begins to corrode at temperatures over 190C

HNOI, 20%

Corrodes at all temperatures and concentrations


Causes embrittlement, especially at temperatures over 400C
At temperatures over 400C
At temperatures over 350C
At all temperatures
At temperatures over 300C
At temperatures over 300C
At temperatures of about 100C
At temperatures over 350C
Corrodes at temperatures over NW, at higher temperatures
for lower concentrations
Corrodes at moderate temperatures depending on concentration
Corrodes at about 100C
Dissolves metal rapidly (over 360C)
Diisolves
Corrodes
cOrrodes
Dissolves
Dilves
Begins to
trations
Corrodes

metal rapidly (over 300C)


at moderate temperatures depending on cow.
at about 100C
metal rapidly (over 320C)
metal rapidly (over 400C)
corrode at temperatures over 175C; lower concenbegin to corrode at higher temperatures
at all temperatures

At all temperatures
Corrodes at pH > 9; reacts at high temperatures

Niobium, Titanium,

S.S.

Acetic Acid

, ronc.

, 70%
, 65yc
HJO,, S-5%
H,SO,, 10%

, 40%
196%
I w%
! 99%
>98%
3WC

100
100
100
21
109
21
100
100

F
212
212
212
70
212
70
212
212

loo

212

170
25
100
25
25

338
76
212
76
76

25
50

76
122
212
392
4S2

loo

200
250
H,SO,. fuming (15% SOa) 23
70
Aqua regia
25
75
Chlorine, wet
25
H,O, Cl, sat
25
, sea
21
Oxalic acid
96
21
NaOH, 5%
100
100
910%
SO
49%
25
HP, d%

73
15s
78
167
76
76
70
205
70
212
212
176
76

Ta
nil
nil
nil
nil
nil
nil
nil
nil
nil
<l
nil
nil
nil
nil
nil
nil
nil
3
rapid
0.5
rapid
nil
nil
nil
nil
nil
0.1
nil
0.7
<l
rapid
rapid

Sb
-(a)
nil
0.04
-

Ti
nil
nil

304
20
20

<0.5
-

> 20
-

175

0.1
4(b)
nil

rapid
nil

nil
-

<5

<l
3(b)
nil
0.1
0.2
O.S(b)
115(b)
rapid
-

8
40
7
60
high
rapid
-

nil
nil
nil
nil

35
nil

1.1
rapid
rapid

rapid

nil

(assume rapid)

0.6(b)
-

high
-

5
nil
8
5
rapid

7
> 50
> 50
> 50
>>50
> 50
50
<
<

1
1
5

Pt
nil
nil
nil
nil
1
nil
nil
nil
nil
nil
nil
nil
8cQ
0.1
nil
nil
nil
nil
nil
nil

732

Corrosion Resistant Materials Handbook

TABLE 5.24:

TANTALUM

AND

TANTALUM-COLUMBIUM

ALLOY-CABOT

KBI

The corrosion resistance of tantalum


is generally compared with that of glass, although it withstands higher temperatures and offers the intrinsic
advantages of a metal from a fabrication
standpoint.
Tantalum
equipment
is
frequently
used in conjunction
with glass, glass-lined steel and other nonmetallic
materials in chemical equipment.
It is used extensively
in repairing
damage and flaws in glass-lined steel equipment.
Heat transfer equipment
constructed of tantalum
includes straight-tube
heat exchangers, condensers, bayonet heaters, spiral coils and U-tubes.
Tantalum
is also used in thermocouple
wells, dig pipes, orifices,
valves, diaphragms,
and in other special areas. The
leading anticorrosion
applications
are in the manufacture
of hydrochloric
acid and hydrogen peroxide, recovery of
sulfuric acid, in bromine
heaters and stills, in condensing ethyl bromide,
and in the preparation
of certain highpurity chemicals.
Corrosion

Resistance

of Tantalum

(Reagent grade chemicals used


when appropriate)
S = no attack up to about 15OC (302F),
or as specified
V = variable depending on concentration
and temperature
X = not resistant
Chemical

Chemical

Chemical

Acefic acid
AC+
anhydride
Air, below 300 C (570 F)
Air! above 300 C (570 F)
Al6minum chloride
Alhminum sulfate
Amines

S
S
S
X
S
S
S

Hydrochloric acid
Hydrofluoric acid
Hydrogen
Hydrogen bromide
Hydrogen chloride
Hydrogen fluoride
Hydrogen iodide

S
X
V
S
S
X
S

Sodium
Sodium
Sodium
Sodium
Sodium
Sodium
Sodium

bisulfate, molten
bisulfate, solution
bromide
carbonate
chlorate
chloride
hydroxide, dilute

X
S
S
V
S
S
V

Ammonia
Ammonium chloride
Ammonium hydroxide
Ammonium nitrate
Ammonium phosphate
Ammonium sulfate
Amy1 acetate or chloride

V
S
V
S
S
S
S

Hydrogen peroxide
Hydrogen sulfide
Hypochlorous acid
Iodine. below 300 C (570 F)
Lactic acid
Magnesium chloride
Magnesium sulfate

S
S
S
S
z
S

Sodium
Sodium
Sodium
Sodium
Sodium
Sodium
Sodium

hydroxide, cont.
hypochlorite
nitrate
pyrosulfate, molten
sulfate
sulfide
sulfite

X
S
S
X
S
V
S

Aqua regia
Barium hydroxide
Body fluids
Bromine, dry, below 300 C (570 F)
Bromine, wet
Calcium bisulfite
Calcium chloride

S
S
S
S
S
S
S

Mercury salts
Methyl sulfuric acid
Mixed acids (H2S04-HN03)
Nickel salts
Nitric acid
Nitric acid, fuming
Nitric oxides

S
S
S
S
S
S
S

Sulfamic acid
Sulfur, below 500C (930 F)
Sulfur chlorides
Sulfur dioxide
Sulfur trioxide
Sulfuric acid, to 175C (350 F)
Sulfuric acid, over 175C (350 F)

S
S
S
S
X
S
V

Calcium hydroxide
Calcium hypochlorite
Chloric acid
Chlorinated brine
Chlorinated hydrocarbons
Chlorine, dry, below 250 C (480 F)
Chlorine, wet

S
S
S
S
S
S
S

Nitrogen, below 300C (57OF)


Nitrous acid
Nitrosyl chloride
Oleum (fuming sulfuric acid)
Organic chlorides
Oxalic acid
Oxygen. below 3OOC (57OF)

S
S
S
X
S
S
S

Sulfurous acid
Sulfuryl chloride
Thionyl chloride
Tin salts
Zinc chloride
Zinc sulfate

S
S
S
S
S
S

Chlorine oxides
Chloroacetic acid
Chromic acid
Chrome plating solutions
Citric acid
Cleaning solution
Copper salts

S
S
S
S
S
S
S

Ethylene dibromide
Ethyl sulfate
Fatty acids
Ferric chloride
Ferrous sulfate
Fluoride salts
Formic acid
Hydriodic acid
Hydrobromic acid

S
S
S
S
S
V
S
S
S

Perchloric acid
Phenol
Phosphoric acid, ~4 ppmF
Phosphorous, below 7OOC (1290 F)
Phosphorous chlorides
Phosphorous oxychloride
Pickling acids, except HNO,-HF

S
S
S
S
S
S
S

Phthalic anhydride
Potassium carbonate
Potassium chloride
Potassium dichromate
Potassium hydroxide, dilute
Potassium hydroxide, cont.
Potassium iodide-iodine
Potassium pyrosutfate, molten

S
V
S
S
V
X
S
X

Liquid metals
Bismuth to 900C (1650F)
Gallium to 450 C (84OF)
Lead to 1000 C (1830 F)
Lithium to 1OOOC (1830F)
Magnesium to 115OC (2100F)
Mercury to 600C (1110F)

S
S
S
S
S
S

Potassium to 9OOC (1650F)


Sodium to 9OOC (165O*F)
Sodium-potassium alloys to
900 C ( 1650 F)
Zinc to 5OOC (930 F)
Tin
Uranium

S
S

(continued)

S
X
V
V

Nonferrous Metals and Alloys

TABLE

5.24:

TANTALUM

KBI-40
Alloy is
ties in common
priced tantalum
bayonet heaters,

AND

TANTALUM-COLUMBIUM

ALLOY-CABOT

KBI

733

(continued)

a solid solution of 60% tantalum


and 40% columbium.
As such, it has many application
possibiliwith both its elemental components,
particularly
tantalum.
It is interchangeable
with the higherin many applications,
including:
plate and shell-and-tube
heat exchangers,
reactors, condensers,
thermowells,
spiral coils, U-tubes, rupture discs, distillation
columns, and piping.
CORROSION
RESISTANCE
KBI 40 ALLOY

Ammonium nitrate
Bromine, dry, below 200 C
Bromine, wet
Chlorinated brine
Chlorinated hydrocarbons
Ferric chloride
Ferrous sulfate
Ferrous salts
Hydrochloric acid

:
ss
S
s

OF

Hydrofluoric acid
Nitric acid
Nitric acid, fuming
Organic chlorides
Phosphoric acid, 4 ppm F
Phosphorous chlorides
Pickling acids, except HN03-HF
Potassium dichromate
Potassium hydroxide, dilute

z
S
z
S
V

Sodium hydroxide, dilute


Sodium hydroxide, cont.
Sodium nitrate
Sodium sulfide
Sulfuric acid, to 160 C
Sulfurous acid
Zinc sulfate

:
:
S
S

Key: S = Totally resistant to about


150 C (302 F) or as specified
V = Varies depending on
concentration and temperature
X = Not resistant
KBI-40

Corrosion

Information

The following tests have been conducted with reagent grade chemicals;
impurities. Field testing is highly recommended. (Rate is in mils/yr.)

Solution
5% HCI

10%
10%
10%
10%

HCI
HCI
HCI
HCI

15% HCI
15% HCI

actual field testing could differ because of

Salt

TemDerature. C

Pure Ta

KBI-40

10% NaCl
-

101 boil

nil

nil

102 boil
190
190
102 boil

nil
nil
nil
nil

nil
nil
nil

109 boil
109 boil

nil
nil

nil
nil

16
-

110 boil
110 boil
190
190
150

nil
nil
<l
nil
nil

nil
nil
2
<l
nil

30
-

92 boil
92 boil
190
190

nil
nil
1
1

nil
nil
36
31

64
-

nil
nil
0
a

<l
nil
141
259

0.005% FeCI,
10% NaCl
10% NaCl
0.005-0.040% FeC13
-

20%
20%
20%
20%
20%

HCI
HCI
HCI
t-ICI
HCI

30%
30%
30%
30%

HCI
HCI
HCI
HCI

0.005% FeCI,
-

36%
36%
36%
35%

HCI
HCI
HCI
HCI

0.005% FeCI,
-

0.005-0.040% FeCI,
0.005-0.040% FeC13
-

0.005% FeCI,
-

Pure Cb
1
<l
-

0.005% FeC13

01 boil
81 boil
190
190

65% HNO,

0.1% FeC13

121 boil

nil

nil

cl

10% H2S04

0.1% FeC13

101 boil

nil

nil

<l

10% H2S04

0.01% FeC13
-

101 boil

nil

nil

102 boil

nil

nil

190

nil

nil

107 boil
107 boil

nil
nil

nil
nil

113 boil
190
113 boil

nil
nil
nil

41
nil
Cl

20% H&O.
20% HISO.,
30% H$Oa
30% H,SO,
40% HzS04
40% H$O.,
40% H?SO,

O.Oi-0.1% FeC13
5-15% AICI,
O.Ol-0.1% FeCI,

5
7
-

(continued)

Corrosion Resistant Materials Handbook

734

TABLE 5.24:

TANTALUM

AND TANTALUM-COLUMBIUM

Salt

Solution

Temperature,

Pure Ta

KBI-40

Pure Cb

<l
<l
nil
<l
nil
Cl

100
141 boil
190
90-100
120
120
141 boil

nil
Cl
<l
nil
nil
nil
Cl

nil
<2
<2
nil
cl
nil
1

100
165 boil

nil
<l

nil
6

100
175
189 boil

nil
2
2

nil
32
40

Fe&

O.Ol-0.1% FeCI,
O.Ol-0.10/o Fe&
O.Ol-0.1% FeCI,
0.01% FeCI,
0.05-0.1% FeCI,
O.Ol-0.10/o FeCI,

H2S04
HsSO.,
H2S0,
HrSO4
H.SO.

hminued)

nil
nil
nil
nil
nil
nil

O.Ol-0.1%
-

60% H*SO.,
60% HPSOd
600/o H2SOd
60% H,SO,
60% HZS04
60% H,SO,
60% H;SO;

oC

KBI

123 boil
123 boil
110
120
120
123 boil

z&0 H,SO,
5OYo H2S04
5OYo HrS04
50% HIS04
50% HzS04
50% HPSOd

70%
70%
77%
77%
77%

ALLOY-CABOT

85% H-SO.

260

93% H-SO.

260

15

96% HSO.

260

21

80% H,SO.

10Y0 NaCl

141 boil

nil

49

70% H,SO,

10% NaCl

165 boil

<l

123 boil

nil

<l

101 boil

nil

nil

ASTM G-28
(50% HrSO,

+ 42gIliter

Fe&SO,&*)

Green Death
(12Y0 H2S04 + 1.2% HCI + 1% FeCI, + 1% CuCI,)
Soiling temperatures

may vary with salt additions.

*Highly

oxidizing

acid solutions.

Nonferrous Metals and Alloys

TABLE 5.25:

TITANIUM-INDUSTRIAL

TITANIUM

COMMERCIALLY PURETITANIUM IS BEING USEDSUCCESSFULLY IN ALLOFTHE

FOLLOWING MEDIA.

SALTS
Aluminum Hydroxide
Aluminum Potassium Sulphate
Aluminum Sulphate
Amonium Chloride
Amonium Hydroxide
Amonium Sulphate
Aniline Hydrochloride
Antimony Trichloride
Barium Carbonite
Barium Chloride
Barium Nitrate
Barium Sulphate
Calcium Carbonate
Calcium Chloride
Calcium Hydroxide
Calcium Hypcchlorite
Carbon Tetrachloride
Copper Carbonate
Copper Chloride
Copper Cyanide

Copper Nitrate
Copper Sulphate
Cupric Chloride
Ethylene Chloride
Ferric Chloride
Ferrous Chloride
Hydrogen Peroxide
Hydrogen Sulphide
Lead Acetate
Manganese Carbonate
Manganese Chloride
Magnesium Carbonate
Magnesium Chloride
Magnesium Hydroxide
Magnesium Nitrate
Magnesium Sulphate
Mercuric Chloride
Mercuric Cyanide
Nickle Chloride
Potassium Bichromate

Potassium Bromide
Potassium Carbonate
Potassium Chloride
Potassium Chlorate
Potassium Ferricyanide
Potassium Ferrocyanide
Potassium Hydroxide
Potassium Iodine
Potassium Nitrate
Potassium Oxalate
Potassium Permanganate
Potassium Sulphate
Potassium Sulphide
Silver Chloride
Silver Cyanide
Silver Nitrate
Sodium Acetate
Sodium Benzoate
Sodium Bicarbonate
Sodium Bichromate

Sodium Bisulphate
Sodium Borate
Sodium Carbonate
Sodium Chlorate
Sodium Chbride
Sodium Citrate
Sodium Flouride
Sodium Hydroxide
Sodium Nitrate
Sodium Phosphate
Sodium Silicate
Sodium Sulphate
Sodium Sulphfte
Stannic Chloride
Stannous Chloride
Sulphur Dioxide
Titanium Tetrachloride
Zinc Chloride
Zinc Sulphate

Chromic Acid CR
Citric Acid
Hydrocyanic
Lactic Acid
Malic Acid
Nitric Acid

Nitrous Acid
Oleic Acid
Oxalic Acid
Phosphoric Acid
Pyrogallic Acid
Salicylic Acid

Stearfc Acid
Sulphurus Acid
Sulphurous Spray
Tannic Acid
Tartaric Acid
Uric Acid

Furfural
Gasoline
Hydrocarbons
Meat Juices
Mercury
Petroleum Ether

Phenol
Salt
Salt Brine
Water- Hot, Sea, Salt
Brakish, Steam
Whiskey

ACIDS
Acetic Acid
Acetic Anhydride
Acetic Vapors
Carbonic Acid
Chloroacetic Acid
Chromic Acid

MISCELLANEOUS

Alcohol- Methyl, Propyl


Butyl Ethyl
Aniline
Beer
Blood
Chlorinated Water

Chlorine Gas-Moist
Chloroform
Flue Gases
Fluorine
Formaldehyde
Fruit Juices

Only

735

Nonferrous Metals and Alloys


TABLE 5.26:

TITANIUM

MEDIA
Chlorineheadersludge
and wet chlorine
Chlonne gas.dry
Chlonnadioxlde

Chlorlnedloxlde
I steam

Chlorinetrliluorlde

Femc chloride
Ferricsulfate .9 Ii,0
Fenous chloride +
0.5% HCI + 3%
resorcinalpH 1
Ferrous suffate
Fluotmncacid

ALLOYS-TIMET

T
207 (97)

R
0.03(0 001)

~0.5 H,O
5 in steam
gas + H,O
and stir
fS+some
HOC1and
wet Cl,
5

room
160 (62)

may react
<O.l (<OW3)

llO(43)

ml

210(99)

ml

llO(43)

II

upto
i some
HOCI. Cl,
8 HZ0
100

160 (62)
bwng
room
bolllng

wgorous
reaclon
C5.OfCO 127)
15 Of.cO 127)
7 5.12.3(0 191-0.31;
0 01 (0.000)

203 (95)
bolllng
75 (24)
160(62)
75 (24)
160 (62)

0 1 (0.003)
0.1 (0 003)
0.2 (0 006)
06(0015)
0.5 (0.013)
1.l (0 026)

171(77)
70(21)

56.3 (1 46)
<o l(~O.003)

212(100)
212(1W)
140 (60)
212(1W)

0.36 (0 009)
0.03 (0 001)
0 01(0.000)
<5.0(<0 127)

boilmg
3W(149)
room
bolllng
room

5-50 (0 127-l -27)


corroded
nil
nil
07(0016)

ambtent

nil

boilmg
bolllng
246(119)
(boilmg)
room
194 (90)
room
302 (150)

nil
0.2(0.005)
0.1 (0.003)
nil
co.1 (<O.W3)
nil
0.1 (0.003)

100
100

212(100)
bolllng
355 (179)

<0.5(<0.013)
0.29(0 007)
4(0.102)

1W
95
100
100
100
1O-20
1O-30
1O-40
50

nil
0.5 (0.013)
nil
0.2-5.O(O.W5-0.127)
nil
nil
<0.5(<0.127)
nil
nil

50
10
30

mom
bolllng
room
boiling
rc0m
room
212(100)
boilmg
236(113)
(bollmg)
302(150)
room
175 (79)

0.1 (O.W3)
nil
0.2 (0.006)

saturated
5-20

room
elevated

nil
rapid

Chloracetlcacid 30
Chloracetlcacid 100
Chlorosulfonlcacld 100
Chloroform vapor 8
llqutd
Chloroplc 100
Chromlcacld 10
Chromicacid 15
Chromicacld 15
ChromicacId 50
Chromicacld 50
Chromiumplatmgbath 240 g.l
contammgfluorlde platmgsalt
5
Chromicacld +
5% mtrlcacid
Cttrlcacid 10
Cltrlcacid 25
Cltrlcacld 50
CitricacId 50
aerated
Cttncactd 50
Cltrlcacld 62
Copper mtrate
saturated
50
Copper sulfate
Copper
sulfate +
saturated
2% H,SO,
Cupriccarbonate +
saturated
cuprichydroxide
Cupricchloride 20
Cupr~cchlorlde 40
Cupricchloride 55
Cupriccyanide
Cuprouschloride
Cyclohexylamine
Cyclohexane(plus
traces of formicacld)
Dlchloroacebcacid
Dkzhloroacetlcacid
Dlchlorobcnzene +
4-5% HCI
Dtethylenetrlamine
Ethylalcohol
Ethylalcohol
Ethylenedichlonde
Ethylenedlamme
Femc chloride
Ferric chloride
Femcchlonde
Fenicchlonde

AND TITANIUM

saturated
50
100

~66 (30)

737

kontmued)
MEDIA
Fluorine.commercial

Fluorine,HFhae
Fluorine,HF free
Fluorine.HF free
Fluorosilicicacid
Food products
Formaldehyde
Formamidevapor
Formicacid.aerated
Formicacid. aerated
Formicacid, aerated
Fomw acid, aerated
Formtcactd.
non-aerated
Formicacod.
non-aerated
Formccaad.
non-aerated
Formicacod.
non-aerated
Formicacid. -0
Furfural
Glucomcactd
Glycerin
Hydrogenchloride.gas
Hydrochloricacid
aerated
Hydrochloricaad.
aerated
Hydrochloncaad,
aerated
Hydrochloncacld.
aerated
Hydrochloncacld
Hydrochloncacid
Hydrochloricacid
Hydrochloricacid.
nitrogensaturated
Hydrochloricaad.
nitrogensaturated
Hydrochloricaad.
nitrogensaturated
Hydrochloricacid,
oxygen saturated
chlorinesaturated
Hydrochloricacid,
200 ppm Cl,
Hydrochloricacid,
+ 1%HN03
+ l%HNO,
+ 5% HNO,
+ 5% HNO,
+ lO%HNO,
+ lO%HNO,
+ 3% HNO,
+ 5% HNO,
+ 5% HN03 + 1.7 g/l
TiCI,
Hydrochloricacid,
+ 2.5% N&IO,
+ 5.0% NaCIO,
Hydrochloncacid.
+ 0.5% 003
+ 0.5% 00,
+ l%CQ
+ l%ClQ,
Hydrochloricacid,
+ 0.05% cuso,
+ 0.05% cuso.
+ 0.5% cuso.

C
gas-liquid
aftematad

T
gas-109
liquid(43)
-320 (-196)
-320 (-196)

0.06(O.W2)

10
25
50
90
10

-320 (-196)
-320 (-196)
room
ambient
boilmg
572 (300)
212(1W)
212(1W)
212(1W)
212(1W)
212(1W)

co.43 (0.011)
0.42 (0.011)
1670 (47.5)
no anack
nil
nil
0.16(O.W5)~~
0.04(0 001)
0.04(0.001)
0.05(0.w1)~*
nil

25

212(100)

96 (2.44)

50

boilmg

126 (3.20)

90

212(1W)

116 (3.00)

9
loo
50
81,mixture
5

122 (50)
room
room
room
amblent
95 (35)

<5(<0 127)
nil
ml
nil
nil
1.5 (0 036)

10

95 (35)

40 (1.02)

20

95 (35)

175 (4.45)

37.5

95 (35)

1990 (50.6)

1
3
5
3

boilmg
boilmg
boilmg
374(190)

>lW(>2.54)
550(14 0)
400 (10.2)
>1120(>26.5)

374(190)

>1120(>26.5)

10

374(190)

>1120(>26.5)

3
5
10
5
10
36

374(190)
374(190)
374(190)
374(190)
374(190)
room

>1120(>26.5)
>1120(>26.5)
>1120(>26.5)
<l (~0.025)
>1120(>26.5)
17.0 (0.432)

lW(36)

nil

5
5
5
5
5
6.5
1
1

2w (93)
lW(36)
200 (93)
lW(36)
200 (93)
176 (60)
boilmg
boitlng

3.6 (0.091)
0.64 (0.025)
1.2 (0.030)
nil
7.2 (0.163)
2.0 (0.051)
2.9(0.074)
nil

10.2
10.2

176 (60)
175 (79)

0.37 (0.009)
0.25 (0.006)

5
5
5
5

lW(36)
200 (93)
lW(36)
200 (93)

nil
1.2 (0.031)
0.72(0.016)
1.2 (0.031)

5
5
5

lW(36)
200 (93)
lW(36)

1.56 (0.040)
3.6(0.091)
3.6(0.091)

*liquid
lZgas
liquid
gas
10
37

R
16-34 (0.457xK664)

(continued)

738

Corrosion Resistant Materials Handbook

TABLE 5.26:

TITANIUM
C

MEDIA
Hydrochlonc

AND TITANIUM

ALLOYS-TIMET

200 (93)

MEDIA

20

104 (40)

0 21 (0 005)

2.4 (0.061)

Nftricaad.

aerated

30

122 (50)

0 61 (0 015)
064(0016)

lOO(38)

1.2 (0.031)

Nftnc ac!d. aerated

40

122(50)

+ 1% cuso.

200 (93)

3.6 (0.091)

Nrtrtcactd,

aerated

50

140 (60)

1 46(0

037)

+ 5% cuso,

0.8 (0.020)

Nrtnc acrd. aerated

60

140 (60)

1 56(0

040)

+ 5% cuso,

1OOW)
200 (93)

2.4 (0.061)

Nitnc actd. aerated

70

158(70)

156

boiling

2.5 (0.064)

Nttncacrd.

aerated

40

392 (200)

24(0

610)

boikng

3.3 (0.094)

Nrtrlcacrd.

aerated

70

518 (270)

48(1

22)

10

150(66)

0.88-1.32(0.017-0.025)

+ 0.5% cuso.
Hydrcchlonc

acid,

+ o.o5%cuso.
10

150 (66)

nil

+ 0.5% cuso,

10

150 (66)

nil-O.68

+ l%CUSO,

10

150 (66)

0.88 (0.023)

10

boilrng

11.6 (0.295)

10

boiling

11.4 (0.290)

+ o.2o%cuso.

+ o.o5%cuso,
+ 0.5%CUSO,
+ 02%cus0,

+ 0.2%

organic amme
Hydroftuoric
acid
Hydrofluoric

acid,

10

boikng

20

554 (290)

12 (0 305)

35

176 (80)

2-4 (0 051-O

Nrtncacid.

70

176 (60)

1.3 (0 025-O 076)

Nrtric acid. aerated


non-aerated

(0.023)

100

Hydrofluoric-mtnc

17

bolllng

3-4 (0 076-O

Nltnc acrd

35

bolllng

5-20 (0 127-O 506)

Nrfnc acrd

70

bo!l!ng

2 5-37 (0 364-O 940)

room

0.1 (0.003)

room

nil

180 (82)

6.0(0.152)

252 (122)

<5.0(<.127)

Nitrtcacid.
whrte fumrng

9.0(0.229)

whtte fuming

room

rapid

room

5.0-50(0.127-l

!iqurd
or vapor

Nitricacid,

.27)

l-HF

Nitrtc acrd,

room

rapid
<5(<0.127)

whitefuming

-15HN0,

Nttric actd.

Hydrogen

peroxtde

room

Hydrogen

peroxtde

room

<5(<0.127)

Hydrogen

perxoide

30

room

<12(<0.305)

Nitricacid.

<about

7.85

206-230

nil

red fumfng

2% H,O

Nitric actd.

>about

red fummg

2% H,O

steam

(93-l

mercaptans

Hydroxy-aceticacid
Hypochlorous
Cl,0

acid

17

gas

10)

104 (40)

1.2 (0.031)

100 (38)

0.001 (0.000)
<4(<0.102)

room

nil

saturated

room

pttted

Lacttc acid

1 O-85

212(100)

<5.0(<0.127)

Lactic aced

10

boiling

<5.0(<0

Lead

1500(816)

snacked

Lead

615-1100

good

potassium

127)

Lfnseedofl,

botled

Lrthium,

molten

saturated

II

room

nit

6OiXOO

nil

Magnestum
Magnesiumchlonde

50

40

borkng

4.8-7.4

+ 0.1%

40

bolllng

II-0.62(11-0.016)

Wr@s
Nttncacid
+ 10%

40

+ t 0% FeCI,

Nitnc acrd. saturated


with ztrconyl

nttrate

Nrtncacid

+ 15%

NaNOs

bolkng

0.12-1.40(.003-0.036)

245(118)

I!

65

260 (127)

II

20.8

bolllng

S-11 6(0.127-0.295)

27.4

bolting

19-115(0.483-292)

ambrent

0 26-23.2

nitrate

+ 17991

and 329/l

NaCl

Nitnc acrd + 170 g/l


NaNO,

It

(0.093-0.025)

(0.122-0.188)

33-45

and 2.9 gl NaCl


011 well crudes.

300 (149)

sensitive

Nttric acid

ziconyl

(316-482)
Lrthfumchlonde

not lgnltlo
0.12-0.99

Nitricacid

room

sensitive
room
b&ng

NaCIO,

(324-593)
Lead acetate

lgmtion

40

Iodide

Iodine in alcohol

<5.0(<.127)

room

Nitric acid + 0.1% CrOs


Nitric acid

70 (21)

dry

lodtne in water

320(160)

white fuming

and Cl, gases


lodtne.

varytng

amounts

(0.007-0.589)

of

1400(766)

kmrted

8 1750 (954)

resrstance

Oxalic

actd

98.6 (37)

12 (0.025)

5-20

212(100)

<0.4(<0.010)

Oxaltc actd

borllng

4247(1079)

molten

abraston

S-40

bolllng

II

Oxaltc acrd

25

140(60)

470(11

saturated

room

II

Oxakc acrd

saturated

room

20 (0.508)

saturated

room

nil

106

86 (30)

0.07 (0.002)

5-20

212(100)

II

18-20

95 (35)

.06 (0.002)

99

86 (30)

212(100)

0.01 (0 000)

212(100)

0 42(0.011)

Mercuncchlonde

10

212(100)

0.04(0.001)

Mercuncchlonde

saturated

212(100)

<5(<0.127)

Phosphonc

acrd

Mercunccyanrde

saturated

room

II

Phosphonc

acrd

Mercury

100

up to 100 (38)

satisfactory

Phosphonc

actd

borltng

lO(O254)

Mercury

106

room

II

Phosphonc

actd

10

botkng

400(10

700(371)

119.4 (3.03)

Phosphonc

acrd

30

bolllng

1030(26.2)

Phosphonc

acrd

10

176 (80)

72(1

acrd + 3%

81

190 (88)

15(0.381)

Magnesium

chlonde

Magnestum

hydroxfde

Magnestum
Manganous

sulfate
chlonde

Maleic

acid

Mercuncchlonde
Mercuncchlonde

Mercury

Perchloryl

95 (35)

II

+ Fe

700(371)

3.12 (0.079)

Mercury

+ Cu

700 (371)

2.48 (0.063)

+ Zr

706 (371)

1 28(0.033)

700(371)

3 26 (0.083)

212(100)

0.17 (0.004)

20

212(100)

0.11(0.003)

50

room

II

alcohol

Mercury
Mercury
Nickel

91

+ Mg
chlonde

Nickel chlonde
Ntckel nttrate

6H,O

fluonde

Perchloryl

fluonde

1% H,O
Phenol

Phosphonc

Phosphorus

tnchlonde

room

0.19(0

005)

Potasstum

bromrde

room

9.69 (0 246)

Potasstum

chloride

30

room

0.17 (0.004)

40

room

0.08 (0 002)

aerated

50

room

0.08 (0.002)

Nttnc acrd. aerated

60

room

0.02 (0 091)

Nttnc acrd. aerated

70

room

0.18 (0.005)

Nltncacfd,

10

104 (40)

0.10 (0 003)

aerated

1 O-30

room

0.8-2 (0,020-O

30-80

room

Z-30 (0.051-0.762)

051)

2)

83)

100

room

0 14(0

saturated

room

II

saturated

room

II

Potassiumchlonde

saturated

room

II

saturated

room

II

saturated

140 (60)

Potasstumdtchromate
Potassium

004)

<50(<0.127)
acrd

10

aerated

40(0.102)

Photographrcemulsrons

20

aerated

1 (0.063)

70(21)

water
Phosphomsoxychlonde

Nttnc actd. aerated


Nttncacid.

saturated

nttnc actd and 16%

Pthaltc

Nltncactd.

kqurd 11 4 (0 290)
vapor0

Solutlo

Nttnc actd. aerated

Nttncacid.

9)

liqutd CIO,

Mercury

Methyl

102)

whrte fuming

actd

sulfide,

102)

Nltnc actd

Nitric acid,
1.48

(0 040)

Nttric acrd. non-aerated

anhydrous

Hydrogen

aerated

+ 1%cuso,

+ o.o5%cuso,

and 0.077%

Nrtncactd.

acid.

+ 05%cus0.

kontinuedJ

Ol(0

006)

II
ethyl

10

room

II

saturated

room

II

zanthate
Potassrumferncyanrde

(continued)

739

Nonferrous Metals and Alloys

TABLE

5.26:

TITANIUM
C

MEDIA
Potassium

hydroxide

13

AND TITANIUM

ALLOYS-TIMET

II

85 (29)

Potaswm

hydroxide

50

hydroxide

10

80 (29)
boiling

0.4 (0.010)

Polasslum
POtasslum

hydroxide

25

bolllng

12 (0.305)

Potasswm

hydrowde

50

bolllng

lOa(2.74)

Potaswm

hydroxide

Sot0

465-710

40-60(1.02-1.52)

anhydrous

(241-377)

lodlde

Potass~m

perchlorate

cS.O(cO.127)

saturated

room

ml

saturated

roi3m

II

perchlorate.

20

room

o.t2(0003)

O-30

122 (50)

0.1 (0.003)

- NaCl0,.600-900gl
KCL. O-5009
6-24 g

Potasswm

sulfate

I
10

room

II

Potass~umth~osulfate

II

Prop~on~cacld

vapor

374 (190)

Pyrogaltlc

35591

room

rapld
II

saturated

room

II

76 (24)

II

acid

Sallcyllcacrd
Seanater
4%~year test
Sebaclc

acld

464 (240)

Sodwm
Sodlum acetate
Sodlum aluminate
Sodium blfiuorfde

0.3 (0.008)
II

to 1100 (593)

saturated

room

good
II

25

boiling

3.6(0.091)

saturated

room

rapid

room

II
72t1.83)
II

blsulfate

saturated

Sodwm

bisulfate

10

150 (66)

btsulftte

10

bolllng

Sod&urn blsulflte

25

bolllng

II

25

boiling

nil

Sodiumcarbonate
Sodwm

Na,Cr,O,

saturated

room

II

104 (40)

0.1 (0.003)

saturated

rmrn

nil

+
14 g/l

carbon 0.3-0.9

g/l

Sodium chloride
chloride pHl.5

Sodium chloride pH 1.2

rwm

1.08 (0.027)
nil

saturated

bolllng

II

25

boiling

II

20

room

nil

ambient

II

Stannic chloride

212(1Oq

0.12(0.003)

Stannic chlonde

24

bolllng

1.76 (0.045)

100
saturated

150 (66)
room

nil
II

180 (82)

0 01 (0.000)
II

Sodlum sulfite
Sodium thiosulfate
Sodium thiosulfate

SolIs. corrosive

Steam
Steam

23

bolllng

II

23

bolllng

26(0.711)

23

boiling

Corrosion

23

boiling

nil

saturated

rwm

II

saturated

room

II

saturated

rwm

nil

saturated

room

0.3(0.008)

5-12

230(110)

co.1 (<0.003)

5-10

70(21)

0.04 (O.Wl)

wthteflon

In crevice

chlorine

Sodtum citrate
Sodiumcyamde
Sodiumdlchromate

Sodium fluonde
Sodturn hydrosulflde

amounts of

sodium sufflde and


polysulfides
Sodium hydroxide
hydroxide

10

boilmg

0.84 (0.021)

Sodium hydroxide

20

room

0.1 (0.003)

Sodium hydroxide

40

176 (80)

5.0(0.127)

Sodium hydroxide

50

135 (57)

0.5 (0.0127)

Sodium hydroxide

73

265 (129)

Sodium hydroxide

50-73

370(188)

>43

mom

nil

1.5-4

150-200

1.2 (0.030)

Sodwm

Sodium hypochlorlte
Sodium hypochlorite
12-15%NaCf
NeOH

200.230

hydrogensulfIde

(93-l

10)

mercaptans
100

356(180)

0.1 (0 003)

Sucww

acid

100

365(165)

II

Succvw

acid

saturated

room

II

Sulfamltc acid

saturated

room

nil

Sulfamlc acid

3.75 gl

bolllng

II

Sulfamlc acld

7.591

boiling

lOS(274)

Sulfamlc acid +

7.591

boiling

1.2 (0.030)
II

FeCI,
100

464 (240)

Sulfurmonochlorlde

major

395 (202)

>43(>1.09)

Sulfurdioxide,

near 100

room

0.1 (0.003)

16

600 (316)

0.2 (0 006)

140(W)

0.3 (O.W8)

Sulfuric aad. aerated


with a+r

140 (60)

0.5(0.013)

Suffuric acid, aerated

140(M))

190 (4.83)

Sulfuric aad, aerated


with aar

10

95 (35)

50(1.27)

Sulfuric aad. aerated


with air

40

95 (35)

340 (8.64)

Sulfuric aad. aerated


wth aw

75

95 (35)

42 (1.07)

Suffuric acid, aerated


wth aw

75

roam

427(10.8)

Sulfuric acid, aerated

75

bolllng

6082(1545)

Suffuric aad. aerated


with air

212(100)

0.2 (0.005)

Sulfuric acid, aerated


with atr

212(1W)

920 (23.4)

Suffunc acid. aerated


with air

212(1W)

810 (20.8)

Sulfuric acid, aerated


with air

80

room

316 (8.03)

Suffurfc acid, aerated


with air

80

boiling

7460 (189.5)

Suffuric acid. aerated


v&hair

concen-

room

62 (1.57)

boiling

212 (5.38)

water

saturated
Sulfurdioxidegas

small amount SO3 and


approx. 3% 0,
Sulfuric acld. aerated
wth air

wtth av

Sodium chloride. pH 1.2

unknown

+ air

+ 7.65%

Steanc actd, molten

Sodwmchlonde.
titanium in contact

SOme dissolved

20% acetlc acld

with air

O-721 g/t

chlorate

chlorate

NaCl80-25091

Scdwm

room

100

Sodwm

Sodwm

boiling

saturated

Sulfur. molten

II

Silver nttrate 50

Sodwm

10

Scdlum sulfide

.3759/i

sodtumsalt
Seawater,

Sodium sulfide

0.17%

NaCI. O-25OgI
N&IO,.

R
II

Stannicchloride,
molten
Stannicclonde

~TI spec~mencafhodc)
Potaswm

T
room

Sodiumsulfate

chlonde

Potasstum

C
saturated

MEDIA

+ 13% potassium

Potasslumpermanganate

(continued)

+ 1%

7.0(0.178)
(>1.09)

(66-93)

Sodium nitrate

saturated

room

nil

Sodium nitrite

saturated

room

nil

900 g/f

122 (50)

0.1 (0.003)

saturated

room

nil

Scd0pm perchlorate
Sodium phosphate

trated
1

212(1W!

282(7.16)

212(100)

830(21.1)

212(100)

loso(26.9)

boiling

700(17.8)

aerated

with nitrogen

Sutfuricacid.aerated
withnitrogen
Sulfuricacid, aerated
withnitrogen
Sulfuricacid
Sulfuricaad,

sodium catttonate

Sodium slkcate

25

boiling

nil

Sodium sulfate

1 O-20

boiling

nil

concert-

Suffuric acid. aerated


withair
Sulfuricacid.

Sulfuricacid

+ l-2%

trated

+ 0.25%

boiling

lWO(25.4)

200 (93)

nil

CuSO.

+ 0.25KCuSO.

30

lW08)

2.4 (0.061)

+ 0.25%

30

2.64 (0.067)

cuso.

3.48 (0.088)

+ 0.5%CuSO,

30

200 (93)
100 (38)

+ o.5%cuso.

30

200(93)

32.4 (0.823)

+ 1 .O% cuso,

30

10008)

0.78(0.020)

(continued)

740

Corrosion Resistant Materials Handbook

TABLE 5.26:

TITANIUM

MEDtA
Sulfuric acid, aerated
+ 1.0% cuso,
+ 0 5% cro,
+ 0.5% CrCs
+ 1.O%cuso,
Sulfuric acid vapors
Sulturic acrd vapors
Sulfuhc acrd vapors
Sulfuric acid,
+ 10% HNO,
+ 30% HNO,
+ 50% HNOs
+ 70% HNO,
+ 90% HNO,
+ 90% HNO,
+ 50% HNO,
+ 20% HNOs
Sulfuric acid saturated
with chlorme
Sulfuric acid saturated
wrthchlortne
Sulfunc acrd saturated
withchlorme
Sulfuric acid saturated
wrth chlorine
Sulfunc acrd + 4.79
glTi+
Sulfurousac~d
Tannic acid
Tartaric acid
Tartarrc acid
Tartaric acid
Tartarrc acid
Tartarrc acrd
Tartarrc acid
Tartaric acrd
Terepthalic acid
Tetrachloroethane.
kqurd and vapor
Tetrachloroethylene
+ H,O
Tetrachloroethylene
Tetrachloroethylene.
kqurd and vapor
stabrkzed wth ethyl
alcohol
Tin. molten
Trtamum tetrachlonde
Trtanrum tetrachlorrde
Tnchloroacetlc acrd
Tnchloroethylene
Uranium chlohde
Uranyl ammomum
phosphate filtrate +
25% chloride + 0.5%
fluorrde. 1.4%
ammoma + 2.4%
uramum
Uranyl nrtrate
contamlng25.3g.l
Fe..6.9g.l
Cr..2 8gjl
NI 1.5.9molar NOB
4.0 molar H _, 1.O
molar Cl
Uranyl sulfate + 3.1
molarL@O,, +
too-200 ppm0,
Uranyl sulfate * 3.6
molar LI,SO,. 50 psi O2
Urea-ammoma
reactloo mass

AND TITANIUM
T

ALLOYS-TIMET

MEDIA

34.8 (0.884)
nil
nil
65 (1.65)

90
70
50
30
10
10
50
80
45

200 (93)
200 (93)
200 (93)
boiling
100(36)
150(66)
200-300
(93-149)
room
room
room
room
room
140 (60)
140(60)
l40(60)
75 (24)

62

60(16)

0.07(O.W2)

374(190)

<1(<0.025)

02

122 (50)

>47(>119)

30
5
30
30
96
96
96

(contlnud)

nil
nil
0.4-0.5(0.010-0.013)
16(0.457)
25(0.635)

Urea + 32% ammoma,


r 20.5% H,O. 19% CO
Water. degasss
Water, over. saturated
wth Cl,
Water, synlhetrc sea
X-ray developer solution
Zinc, subjected to zinc
ammonium chloride
oreflux

26

4.0(0.102)

Zincchlonde
Zinc chloride
Zinc chlohde
Zmc chloride
Zinc sulfate

I-VI
0.45(0.011)
15.7(0399)
62.5(1.59)
0.13(O.W3)

* May corrode

212(1W)

passwe

6
25
10-M
10
25
50
10
25
50
77
100

room
212(1W)
212(100)
140(60)
140 (60)
140 (60)
212(1W)
212(1W)
212(100)
425(216)
boollihg

nil
ml
<5(<0.127)
0.10 (0.003)
0.10(0.003)
0.02 (0.001)
0.13(0.003)
nil
0 2.0.49(0.005-0.0121)
ntt
0.02(0 001)

boiling

5 (0.127)

100
100

bolllng
bolllog

orI
0.02(0001)

100
99.6

930 (499)
572 (300)
room

resistant
6211.57)
hII

bowg
bollng
70- 194
(21-90)
165

573 (14.6)
0.1~5(0003-0.127)
hII

* TiCode-

bolllng

IllI
hll

20
50
75
60
saturated

in crevices

Corrosion Rate Data TiPd


C = Concentration

R = Corrosion rate.
MEDIA
Alummum Chlohde
Calcium Chlorrde
Chlorine, wet
Chlorme, H,OSatd.
Chromrc actd
Ferric chloride
Formrc actd
Hydrochloncacrd.
H,saturared

Hydrochloricacrd.
Air saturated

,.O.l (iO.003)

012 (0.000)

3.1 molar

482(250)

O-0.76 (. 0 020)

3.8 molar

662 (3501

0 22-17 (0.006-O 432)

elevated
temp. and
pressure

no attack

hll
hll
wthstood
several
thousand
contact
cycles
l-M*
nil
24(0.610)
6000 (203 2)
nil

(Ti-Pd) immune

Hydrochloncacrd.
0, saturated

120 g. I u

600(316)
2w (93)

25(0.635)

40

20.9

Fl

3 l(O.079)

95 (35)
room
molien

100

T -= Temperature

trated
100
99

T
360(162)

Hydrochloncacrd.
Cl, saturafed
Hydrochlorrc acrd

Hydrochloncacrd
- 5g IFeCI,
* 16glFeCI,
+ 169 IFeCI,
A 16g.ICuCI,
+ 169 ICuCI,
Nrtnc acrd

c
10
25
62
73
10
30
50
l-15
20
25
1
5
10
15
20
25
3
5
10
15
land5
10
15
20
25
3
5
10
3and5
10
5
10
15
20
lo
10
20
10
20
30
30
65
65
65

Oo
F

(C)
mpy (mrny)
1
212(1W)
212(1W)
310(154)
350(177)
room
room
boiling
tkxkng
bmkng
room
room
room
156 (70)
158 (70)
158 (70)
158 (70)
158 (70)
156 (70)
374(190)
374(190)
3741190)
374(190)
158(70)
158(70)
158 (70)
158 (70)
158 (701
374(190)
374 (190)
374 ( 190)
374(190)
374(190)
borkng
bolllng
borkng
bolllng
bolllng
bolkng
bollmg
borkng
bo,!lng
374(!90)
482 (250)
borkng
374(190)
462 (250)

R
(1 (~0.025)
1 (0.025)
MI
ml
skght gam
<l (~0.025)
skght gam
skght gam
3 (0 076)
< 1 (-0.025)
4(0 102)
11 (0.279)
3(0.076)
3 (0.076)
7 (0.176)
13 (0.330)
61 (1 55)
169(4 29)
l(0 025)
4 (0.102)
350 (6 69)
1620(41 1)
b: 1 (~.0.025)
2 (0.050)
6(0 152)
26 (0.660)
78 (1 98)
5(0.127)
5 (0.127)
368 (9 34)
- 1 (.O 025)
1140(29OJ
7(0 178)
32(0 613)
267 (6 78)
770 ( 19.6)
11 (0 279)
3 (0 076)
113(267)
5(0 127)
146(3 71)
9412 39)
sl1ghtgarn
26(0 661
sltght garn
slightgafn

(continued)

TABLE

5.26:
MEDIA

TITANIUM

AND

TITANIUM

MEDIA

Nitricacid,
Unbleached
Phosphonc

acid

Sodium chlonde
EInne
Sodrumchlonde
Sullurlc acid.

60

boiling

15 5 (0.394)

10

boiling

5 6(0.147)

200 (93)

0 0005 (0 000)

10

374 (190)

r0Cllll

Metals and Alloys

Fl

Sulfunc acid
+ 0.0I?~CuSO~

30

boiling

1090 (27 7)

+ o.o5%cuso,
+ 0.50% cuso,

30
30

boiling

I310(33

bolllng

79 (2.01)

30

bolllng

69 (1.75)

I .O% cuso.

1 (, 0 025)

IO

room

1 (0 0251

rOOm

9 (0 229)

60

room

34 (0 664)

60

WXTl

645116

95

rOOm

66 (1 73)

Sulfuncacid.

156 (70)

610 152)

C = Concentratton

N, saturated

IO

156(7Oj

IO (0 254)

T r Temperature

40

156 (70)

67(221)

60

156(70)

164 (4 67)

R = Corrosion rate, mpy (mm/y)

80

156 (70)

226 (5 74)

96

156 (70)

62 (1 57)

374 (190)

5(0

127)

374(190)

5(0

127)

10

3741190)

59(1

20

374(190)

355 (9 02)

Sullunc acid.

374(190)

5(0

0, saturated

374 (190)

3 (0 076)

10

374(190)

5(0.127)

20

374(190)

59 (I .50)

30

374 (190)

2440 (62.0)

1 and 5

374(190)

<l

Sulfuncacid.
CI,saturaled

Sulfuncacld.
Air saturated

Sullunc acrd

Corrosion

4)

MEDIA
Ammonium

374((19Oj

2(0.051)

374 (190)

15(0.361)

30

374(190)

3060 (77 7)

156(70)

3 (0 076)

10

156(70)

4 (0.102)

40

I56 (70)

37 (0.940)

Remarks

30

bolllng

nil

no hydrogenplck-up
500 hours

boiling

nil
24 (0.610)

10

boiling

nil

Citric acid

50

190 (66)
boiling

0.5 (0.013)

Formic acid

45

bolllng

nil

- 3 parts HCI)
Ammonium
Chlonnecell
off-gas

,035 (0.001)

Formic acid

06

boiling

nil

90

boiling

20.5(0.521)

156 (70)

392 (9 96)

120 (49)

0.1 (O.qo3j

158 (70)

447(114)

Hydrochloric

acid

150 (66)

0.2 (0.005)

acid

acid

2OOwj
200 (93)

1.2(0.031)

96

156 (70)

63(2.11)

Hydrochloric

boiling

20 (0.0511 j

Hydrochloric

acid

10

boiling

59 (1.50)

HCI + 2g/l FeCI,

20

boiling

207 (5.26)

HCI + 2g/l FeCI,

2
3.32

196(91)

1 .O (0.025)

4.15

196(91)

2.3(0.056)

0.54

boiling

0.6 (0.015)
35.4 (0.699)

7 (0.176)

Sulfunc acid

1.06

bolllng

Sulfunc acid

1.62

boilrng

IO

boiling
bolllng

6(0.152)

40

boiling

67 (2.21)

15

bolllng

25 (0.635)

576 (14.7)

Vapor above boiling


HNO,
MgClz
Sodium Sulfate

Sulfuric acid

0.6 (0.020)
saturated

bo1lrng

II

500 hours

10

boiling

nil

acrdifled lo

bolllng

2.4 (0.061)

500 hours

600(316)

II

500 hours

Sulfunc sod
t

PHI
5% NaOCl

10% FeSO,

NaCl +

11% Solids. and


I70 g/l T102

natural

1176 (29.9)

Sulfuricacid
boiling

20

natural

aeration

60

+ 16g/lFe,(SO,j,

natural

aeration
Fonicacid

60

10

3700 hours

aeration

Hydrochloric

+ 16gIFe,(SO,j,

+ 15%CUSO,

boiling

(~0.025)

10

%
F (C)

10

Chloride

20

Rate Data for TiCode-

(I pa HNO,

Aqua regla

127)

~1 (~0.025)

+ 4Og:I Fe&S0,j3

hydro-

oxide
AlumlnumChlonde

50)

Sulfunc acid
+ 0 591 Fel(SO,)s

3j

cl(.-0025)

40

N, saturated

741

(continued)

ALLOYS-TIMET

Nonferrous

to212(IOOj

23

NaCl

64(2.13)

Titanium
Timet
Designation

Ti-35A
Ti-5OA
Ti-75A
Ti-6AI-4V
Ti-Pd
TiCode-

ASTM
Grade

Commercially

1
2
4
5
7
12

35,000

50,000
80,000
130,000
50,000
70,000

saturated

Alloys Used in Industry

Ultimate
Tensile Strength (min.)

Pure (Unalloyed)

+ 2%

4% NaOH

psi
psi
psi
psi
PSI

psi

Titanium

Yield Strength (min.)


0.2% Offset

25.000
40,000
70,000
120,000
40.000
50,000

psi
psi
psi
psi
psi
psi

Nominal Composition

C.P. Titanium
C.P. Titanium*
C.P. Titanium*
6% Al, 4% V
0.15% Pd
0.3% MO. .8% NI

742

Corrosion Resistant Materials Handbook

TABLE 5.27:

ZINC ALLOY-NEW

JERSEY ZINC

The following are the ASTM Specification B 86 requirements for Zamak 3


die castings:
Alloy AG 40 A (Zamak 3)*
% by Weight

Ingredient

Aluminum
Copper
Magnesium+*
Lead
Cadmium
Tin
Iron
Zinc

3.5 - 4.3
.25 Max.
.020 - .05
.005 Max.
.004 Max.
.003 Max.
.lOO Max.
Remainder

*Zinc alloy die castings may contain nickel, chromium, silicon, and manganese in
amounts of .02, .02, .035, and .5% respectively. No harmful effects have ever
been noted due to the presence of these elements in these concentrations and
therefore, analyses are not required for these elements.
**Magnesium may be as low as .015% provided that the lead, cadmium, and tin
do not exceed 803, .003, and .OOl% respectively.
THE CORROSION

RESISTANCE

OF ZINC ALLOY

DIE CASTINGS

Zamak alloys have the strong resistance to atmospheric corrosion and weathering that has been associated for centuries with rolled zinc and zinc-coated iron.
This corrosion resistance was confirmed by 10 years of test data compiled by
NJZs research department and the appearance of die cast test bars after 20 years
of exposure at the several ASTM exposure sites.
Corrosion of Zinc, Galvanized Iron, and Zamak 3
(Penetration in Inches per Year)
Palmerton, Pa.
New York City
.00028
.000064
Rolled Zinc
.00027
.000052
Galvanized Iron
80022
.000078
Zamak 3
The above data establish that zinc weathers slowly and uniformly, with the
corrosion rate influenced by the degree of industrial contamination and the frequency of fogs and mists.
HYDROCARBON
FUELS AND LUBRICANTS
In the absence of moisture, zinc
alloy die castings are strongly resistant to attack by acid-free hydrocarbons. In the
presence of water some corrosion takes place which, while not seriously detrimental to the strength of the casting may, in the case of fuel handling devices, create
some binding or clogging effect.
It may be commented, in general, that no lubricants of animal fat origin
should ever be used with zinc alloy die cast parts. This restriction applies also to
those proprietary oils which contain varying quantities of animal oils in the
formula.
INK Printing inks appear to have little or no effect on zinc. The use of zinc engravings and lithographic plates in the printing industry gives ample evidence on
this point.

(continued)

Nonferrous Metals and Alloys

TABLE 5.27:

ZINC ALLOY-NEW

JERSEY ZINC

(continued)

ALCOHOL
While pure ethyl and methyl alcohol are considerably less corrosive
to zinc than water, mixtures of alcohol and water are more corrosive than water
alone. This fact, combined with the probable presence of iron rust, makes undesirable the use of zinc alloy die castings in automobile cooling systems except in
the presence of a suitable inhibitor.
Alcohol-water mixtures represented by beverages are a special case, as the
use of zinc alloy die castings in direct contact with potable alcoholic mixtures is
not recommended.
GLYCERINE
Pure glycerine produces a smooth, light etch on the surface of the
Zamak alloys. There is evidence, however, that glycerine-operated door checks
and similar devices can be satisfactorily made of zinc alloy die castings.
Glycerine-alcohol mixtures produce only a light surface etching on the Za,
mak alloys when a pure grade of glycerine is used. The presence of water or the
use of a low grade glycerine will result in pitting.
INSECTICIDES
In dry form insecticides have relatively little action on zinc. In
water solution, those materials which contain copper, arsenic or lead tend to accelerate the corrosion of zinc by electro-chemical replacement. It is not recommended that zinc alloy die castings be used in insecticide spray devices.
SOAPS AND CREAMS Ordinary good grade laundry soaps have a definite inhibiting effect on the corrosion of zinc in hot water. This is particularly well illustrated in the practically perfect surface found on washing machine drain cocks after years of service.
In recent years soaps have largely been replaced by detergents, some of
which are corrosive to zinc die castings.
TRICHLORETHYLENE
- CARBON TETRACHLORIDE
In short periods of exposure necessary for degreasing prior to electroplating, neither trichlorethylene
nor carbon tetrachloride will have any visible effect on zinc alloy die castings. Dry
carbon tetrachloride has no visible effect on continued exposure of much longer
duration. Dry trichlorethylene over a period of four months shows a very slight
etching action.
ILLUMINATING
mak alloys.

GAS

Dry illuminating gas has no apparent effect on the Za-

FOODS AND BEVERAGES


It is the considered opinion of medical authorities
who have studied the subject that zinc salts in moderation are not toxic. Where
moisture and acidity are encountered, zinc salts may accumulate. In sufficient
quantity these salts are irritating and may cause nausea. Such applications of zinc
alloys should be scrupulously avoided.

743

744

Corrosion Resistant Materials Handbook

TABLE 5.28:

ZINC COATING-ALCOA

Corrosim
12-YEAR

lNSPECTION
PANEL

TYPE
ZINC

OF PANEL
COATING

TYPE

OF ATMOSPHERlC

EXPOSURE

TYPB

PREPARATION
THICKNESS,

OF SEAL COAT

TESrSrrB

coLuMBus.

RESULTS

METALLIPD

0.003

0.003

NO=

l l

ON

inches

Tests

TESTS

wP+Av-1

ZINC

COATED

CARBON

STEEL

PANELS

3
1

0.003

0.006

CR-2

N=

ENVIRONMENT

OHIO

URBAN

Base metal shows red


Nsroa3%ofthe
front of the DaneIs.
Spnycd me& shows
red tust stain on 60 %
of the remainder of the
front. Back of wnefs
chin ahi~rusc

INDu.sTRuL

Base metal shows red


tusr staining. S rayed
merrl shows I 5,
staining OQ 60 % of
the from nuface. CR
seal coat dissipated on
front. Sal coat 00 back
lmaffccmd.

Ease meal nm atacked.


Sprayedmeal in9a.
bur shows very chin
white nut OD front and
back of paoelr

Base meal ax attacked.


Sprayed metal intact.
CR seal coat on from
of panel.9 completely
dissipated, showing a
gencrpl fight PY
deposit stain. Seai car
on back una&cred.

Eksc meal ncx amcked.


s rayed mad 00 froot
o P panels shows a
general Ii r dcpair
ruin. Bat p d panel9
show a pnctal very
thin whm run

Base mad shows red


fust. Spayed metal 00
from of panels show
redtusr0tl50%
oft&
sutface. CR seal copr is
dissiparcd OD. nel
fronts. Back or paneIs
s$ygd.
h

Base metal *oc am&d.


Spayed meal shows

Basemetal 10%
exposed on front of
panels and 1% on back,
showing red nut in
these areas. Sprayed
meal shows red nut
stain on 25 % of the
ygtz
k_rq+a~d

on back.

rusrova65%
ofthe
front of thepond. Back
of panels shows red rust
alon& buxom edge.
Edges of jnnels show
thick ahm tusr.

KURB BEACH.
NOR:%
FRYLJNA

Base meal LI(X nmckui.


Spnyed metal showa
many pinpoint nodea
and some medium sized
noda of white rust a0
front of panels. Vinyl
seal car 75 % dissipated
011front. sprayed
md

cmbackshonrmall7

pinpoint nodes of white


nut. Viny1 ral coat
SO% dissipated 00 back.

KURB BEACH,
NORTH CAROLINA
( 800~ft la)

SALT-AIR

INDUSTRIAL
NEw

y=

Cxn!

Base metal not atracked.


S rayed meal w front
d panels shows vev
thin white tusr. ahach
is ptcsem as horizontal
scnpes. BDck of panela
shows a ray rbm white
Iuc

Bw meal tmt am&d


Sprayed meal intact.
VinM&coar

Base mcpl nor amcked.


S rayed me& on front
o P panels show a very
thin white nut. Spnycd
metal intact 00 back. CR
seal 0x1 is completely
dissi r~o~~~
front
and Izc
.

Base meal not am&d.


Spmyed metal shows
traces of very thin white
tusr on from and back
of panels.

Base metal shows red


rust on front of pan&
Sprayed metal on frost
is complmly dissipated.
00 back of pan&
spnyedmetalislS%
dissipnr$ and the
$$;e~
maaf

Base meal nor am&cd.


Sprayed metal iprarr
wn&lseal&c II

Base metal OII front of


anelr shows ted nut.
s prayed metal on from
is rained with ted luff.
CR seal coat is comlet& dissipated oa
ProtIt. sprayed meal
imacr on back. Seal coat
oL1back ullaaacd.

Base metal DO(am&cd.


s tared metal on from
o P pnnelr shows a thin
deposit stain. Sprayed
meal oa back shows
a ety thin white Nx.

Reminder
me$olcka

SALT&R

of sprayed
rbor

Base meai not amckcd.


s rayed metal oil front
d panels shows large
light blue-green stams.
S rayed metal on back
o P paneIs shows general
datk gray stains.

Base meal not amckcd.


Base metal not affected.
Spnyed metal show
S rayed meal on front
whim rust node and
o P pen& shows general
green stain o* 1520%
thin white tust with
of the from of panels.
green stains Spnyed
Vinyl seal coat diui ared metal on back shows
blotchy white tust. CR
00 same 15-20% B
seal coat completely
panel fronls. s rayed
meal shows wriate rust
dissipated O(I both sides.
Edges show thick white
noda on 3,S% pf back
zg$;F;a!a
-

SaeuTypel.

(continued)

Nonferrous Metals and Alloys

TABLE

5.28:

ZINC

COATING-ALCOA

(continued)

12-yEAR INSPECTION RESULTS OFATMOSPHEIUCEXFOSURITESTS


PANEL TYPE
TYPE OF PANEL PREPARATION
ZINC

COATlNG

THICKNESS.

EMCTC*GO.

KURE BEACH,
NORTH CAROLINA
(80-h la)

incha

INDUSTRIAL

ZZtZ5

745

ON METALUZEDZLNC

COATEDCARBON

0.006

.S~JIIC
9) TIPC 2.

0.006

SamcasType3.

STEEL P,QJEu
a
1

0.009

SuneCrTmrl.

0.009

SameuTlpe2.

Panela Missing,

KURE BEACH.
NORTH CAllOWA
( 800-ft la)

SameuType3.

SameuTypel.

pdUCt.

(continued)

746

Corrosion

TABLE 5.28:

Resistant

Materials

Handbook

ZINC COATING-ALCOA

I~.YEAR INSPECITON

(continued)

PANEL TYPE
TYPE OF PANEL PREPAB.ATION
ZINC COATING

THICKNESS,

TYPE OF SEAL COAT


TsT

coLuhtBus.

EXPOSURE TESTS ON METALLIZED

RESULTS OF ATMOSPHERIC

SITE

OHIO

KURE BEACH,
NORTH CAROLINA

(800.frla)

NEw
Z CnY

incher
l

ZINC COATED CARBON

10

11

12

0.009
CR-2

0.012

0.012

None

wP+Av--I

0.012
CR-2

STEEL PANELS
13
2
0.015
NODC

BNVLRoNhtBNT

URBAN

SALT-AIR

LNDUSTFUAL

T%Z

?&

Na Taad.

SamcuTlpe2.

gz

Et!

;:

gg?

Na Taai.

tzed.

Y&d

(continued)

747

Nonferrous Metals and Alloys

TABLE 5.28:

ZINC COATING-ALCOA

12.YEAR INSPECTION
PANEL

RESULTS

(continued)

OF SEA WATER

lYPE

BASE hiETAL
PREPARATION

TEST

OF SW

COAT

SITE

WRIGHTSVILLE
BEACH,
NORTH CAROLINA
( b&w-low-tide)

FREEFQRT.

SITE

TEXAS

WRIGHTSVILLE
BEACH.
NORTH CAROLINA
(man-tide)

STEEL

PANELS

0.003

0.003

CR-2

TOTAL
IMhfERSION

Base mernl shows deep


corrosion pita over 20 %
of the pa&l surfice.
from and back Spnyed
mm1 show generaI red
aad white rust ovet the
entire sutface. CR sal
coat is completely
dissipated.

Base mcol shows dee


corrosion pits ovct 4- 8 %
of rhe p&l surface,
from and back. Sprayed
metal rhows general ted
and white tust over the
attire surface. CR sea1
copt is completely
dissipated

TOTAL
IhlhfERSION

Barn mm1 shorn deep


corrosion pits and Iti
of steel at the edge&
Spnyed meal shows ted
nut. CR suI ccat complnely dissipated.

-lYPE

btIXtUTlp1.

Same as Type 1

0.006

0.006

None

CR-1

Base metal shows deep


corrosion pi0 over 1%
of the paiic1 sufnce.
front and back. Sptayed
metal show thin white
rust and Iarge ted nut
stains. front and back

Saw as Type 2.

Base metal show


cottosioo pits and lom
of rtel at the edge.
Sprayed metal sha
scattered red rust.

SameuType

Base metal sha


deep
corrosion pits and lar
of steel at the edge&
Sprayed metal sha
ted
tusandtwtstaitu.

1.

Same u Type 1.

0.009

0.009

COAT

0.006

CR-2

CR-1

NOtK

0.009

CR-2

ENVIRONMENT

TOTAL
IMMERSION

Same as Type 2.

Base mcmI LIQ amckcd.


Sprayed metal shows
enI white nut ovct
r 0% d&epMel
uuface,frontMdbuk.

Bucmrcllthorroolas
of necl. Sprayed PI
WRIGKTSVTLLE BEACH.
NORTH CAROLLVA
( below-low-tide)

CARBON

ZINC COATING
THICKNESS.
incho

TEST

COATED

Base meal shows deep


corrosion pin and loss
of steel at the edges.
Sprayed mccaI show
ted rust and rut stains.
CR suI CODIcompletely
dissipated.

BASE MFTAL
PREPARUION

OF SW

ZINC

CR-1

WRIGHTSVILLE
BEACH,
NOR~~_~dO~A

TYPE

ON METALLIZED

ENVLRONMENT

FREXPORT. TEXAS

PANEL

TESTS

ZINC COATlNG
THICKNESS, incha
TYPE

EXPOSURE

TOTAL
IMMERSION

SameuTyp

I.

z!rzzf:

SameuTypc2.

Bucmecnlsba~few
corrosion pio and lorrofstcel~ithe
cd&. spnSpn~et.&

Tot panels
Lost-1965

Basemenlnocmackcd
Sprayed metal shows
vhitc rust ovu eatire
surface. CR seal cost
complctcl9 dissipated

amI cat cotnplealy


diuiaaed.

?S%F
ATMC&ERE
SEA+ZER

SUUeuTgpC

1.

Buetnetdshowlrd
amout of corrosion.
SpnyedmcraIshoasred
runandrusts&u.

SlmcuTlpcl.

Base men1 not rtackcd


s rayed mcol compPetely corroded showmg white rust. CR
ual colt CompI~Iy
dissipated.

(continued)

748

Corrosion Resistant Materials Handbook

TABLE 5.28:

ZINC COATING-ALCOA

12.YEAR INSPECTION

(continued)

RESULTS OF SEA WATER

EXPOSURE

PANEL TYPE

10

I1

12

13

BASE METAL.
PREPARATlON l

ZINC COATING
THICKNESS. in&n

0.012

0.012

0.012

0.01s

0.018

NW

NW

TYPE OF SW

COAT

None

l l

TEST SITB

ENVIRONMENT

FREEPORT. TEXAS

TOTAL
IMMERSION

WRlGHTSVILLE BEACH,
NORTH CAROLINA
( below-low-ride)

TOTAL
IMMBRSION

smbeuTIpe8.

Ami%F

Base mea1 Dot mskmi.

Tat pmelr
La-1965

WRIGI4TSVILL.E BEACH,
NORTH CAROLINA
(

TESTS ON METX.LIZED ZINC COATED CARBON STEEL PANEI.

AT&&J?

CR-2

al-l

Tar pmelr
Last-1965

Tat paneIs
La-1965

tg?

g?

TFgL

T%Z

man-tide)

SEA WATER

(0 American Welding Society, Inc.)

~.!f&

ZkZi%

gz

TEg

T%a

Nonferrous Metals and Alloys

TABLE

5.29:

ZIRCONIUM

ALLOYS-TELEDYNE

WAH

CHANG

749

ALBANY

Zirconiym
is used in a wide variety of industrial and chemical processing applications.
This wide use is due to zirconium s excellent
resistance to many chemical solutions, even at elevated temperatures
and pressures. Zirconium
is very resistant to corrosive attack in most organic and mineral acids, strong alkalis, and some molten salts. Because of zirconiums
unique corrosion properties,
it is an excellent material for use in chemical processes which require alternate contact with strong acids and alkalis. Zirconium
alloys are not readily attacked by oxidizing media
unless halides are present. It has excellent oxidation
resistant properties to 400C in air, steam, carbon dioxide, nitrogen and oxygen. Zirconium
alloys have little need for anodic protection
systems. Zirconium
alloys have high resistance to localized forms of corrosion, pitting, crevice corrosion, and stress corrosion cracking. The combination
of these factors make zirconium alloys suitable for use in a wide variety of corrosive environments.

Chemical Compositions of Zircadyne Alloys

Chemw.l
Zr

Compositions.

Fe

Percent

Hf. mm.

Hafnium.

99.2

max.

97.5

4.5

+ Cr

020

max.

Tin
Hydrogen.

max.

Nl!rogen.

max.

Carbon,

Zircadyne
705
(R60705)

Zircadyne
704
(R60704)

Zircadyne
702
(R60702)

Grade
(ASTM Designation)

max.

95.5

4.5

4.5

0.2-0.4

0.2

1 O-z.0

0.005

0 005

0.005

0.025

0.025

0.025

0 05

0.05

0.05

2 O-3.0

0.16

Zirconium

max

0.16

Corrosion

0.16

Data
,

CORROSION
CCJNCENTRATION
CORROSIVE

MEDIA

RATE. mpy

TEMPERATIJAE

46

Zr 702

Zr 704

Zr 705

Acelaldehyde

100

Bollmg

<2

Acetvz Acid

5-99 5

35-Boiling

<l

Cl

AcetIc
Acellc

-Tgg

Ac:d (anhydrIde)
Acid (glacjal)

Aluminum

Chlorale

Alummum

Chloride

Alummum

Chloride

Alummum

Fluoride

Alummum

Potassum

Alumuum

Sulfate

Ammonla
Ammonium

(aerated)

(wet)
Carbamate

~1

1 -

_
-

99 7

Bolllng

<5

30

100

<2

~1

5. 10. 25

35- 100

Cl

25
40

Bolllng
100

<;
<2

<l
-

5, 10

60

<2

>50

1 -

1 -

I 20
Sulfate

IRoom-Boiling

Room

n,, 1 -

1PH

= 3.2

1 ml 1pH

= 32

10

Bolllng

25
60

Boiling
100

nil
<2

ml
-

+ water

36

<5

193

<,

REMARKS

56.4% Urea.
16 0% Ammoma.
14 6o CO>. 9 9% Hz0
at 3.200-3.500

PSI

(continued)

750

Corrosion Resistant Materials Handbook

TABLE 5.29:

ZIRCONIUM

ALLOYS-TELEDYNE

WAH CHANG ALBANY

(continued)

CORROSION RATE, mpy


CONCENTRATION

TEMPERATURE

OC

CORROSIVE MEDIA

Ammonium Chloride
Ammonium Hydroxide

11.10. saturated
28

Zr702

Zr 704

135-100

1 4

1 -

1 -

IRoom-

/ -

1 -

x50
>50

20

<l

pH = 6
pH = a

20

20
96

Ammonium Oxalale

100

100

<2

Ammonium Sulfate

5. 10

100

<5

Aniline Hydrochloride

5. 20
5.20

35- 100
100

41
c2

Aqua Regia

3:l

Room

>50

Banum Chloride

5. 20
25

35 100
Boiling

Cl
5-10

3 parts HCI/l part HNO,

Bromrne

loo-Liquid
Vapor

20
20

Cl0
-

20-50
250

Bromochloromethane

100

100

c2

Cadmrum Chlonde

100

Room

Calcrum Bromide

100

100

<2

I -

Calcium Chlonde

5. 10. 25
70
75
Mrxture

35-l 00
Boiling
Bowling
79

Cl
Cl
c5
Sl

Cl
-

Calcium Fluonde

Saturated
Saturated

28
90

nil
nil

Calcium Hypdchlorite

2. 6, 20

100

c5

Carbonic Acid
Carbon Tetrachloride

Saturated

1 o-100

< 2

I -I
-

14% CaCI, 6% NaCl


0.2% Ca(OHb
pH = 5
pti = 5

100

-=5

I -

I -I

Room-100

1~ 2

1 -

Room
75

>50
>50

c2

Chlonne Gas
(more than 0.13% H,O)

100

94

250

Chlonne Gas (dry)

100

Room

c 5

Chlorinated Water

Chloroacetic Acid

100

Boiling

c 1

Chromrc Acid

10-50

Bolting

c 1

Citric Acrd

1O-50
10. 25, 50
50

35-100
100
Boiling

< 1
Cl
c 5

Cupnc Chloride

B.P. = 162OC

100

66

12-50

Prtting
Pitting

I - I -I

Chlorine
(water saturated)

Chrome Plating
Solution

REMARKS

Zr705

1 -

1 s-50(;;:hemicals

I
I 5. 10, 20
20, 40. 50

35-l 00
Boiltng

250
>50

150
>50

>50
>50

Cupric Cyanide

Saturated

Room

=-50

Cupric Nitrate

40

Boiling

W.G.

W.G.

Dichloroacetic Acid

100

Boiling

420

Ethylene Dichloride

100

Boiling

c5

B.P. = 115C

(continued)

Nonferrous Metals and Alloys


TABLE

5.29:

ZIRCONIUM

ALLOYS-TELEDYNE

CONCENTRATlON

CORROSIVE

MEDIA

WAH CHANG ALBANY

TEMPERATURE

Ferric Chloride

O-50
O-50

CORROSION

Room- 100

RATE. mpy

>5(
xi<

Boiling

IO

O-100

<;

Formaldehyde

6-37

Bolllng

O-70

Room- 100

C;

5-20

Elevated

>5(

Acid

(continued)

Zr 702

Ferric Sulfa&

Fluoborlc

751

FIUOSIIIC~CAcid

10

Room

>5c

Formic

Acid

1 O-90

35Boiling

<:

Formic

Acid (aerated)

1O-90

Room-l

00

<E

Hydrazlne

<

ml

Hydrobromlc

Acid

Hydrochloric

Acid

20% HCI + Cl, gas


37% HCI - Cl, gas
10% HCI * 100 porn FeCI,

40

Bolllng

<5

Mixture

Bolllng

<

2
5

225
Room

10
20

35
35

32

30

1
c 1
c 1
< 1
<1

32

62

<

58

I-

I-

I56

I-

I30

5-10
<5
<

5-

I0

c5
<5
Dlssolvec
DlssClW
==50
Hydrogen

PeroxIde

Hydroxyacetlc

Actd

50

I-

c2

100

c5

140

Cl
<

L4ercurlc

Wkel

Chloude

Chloride

Chloride

1 5.20

Room-

100

ml
-

<2
rlll
Manganese

<

1 -Saturated

35-100

<

Saturated

Bollmg

<

5. 20

35-100

5-20
30

100
Boiling

c 1
< I
ml
<

=z 1
c 1
-=z 1

rlll

< 1
< 1
-

<

< 1
-

SCC

Observed

(continued)

752

Corrosion

TABLE 5.29:

Resistant

Materials

ZIRCONIUM

Handbook

ALLOYS-TELEDYNE

WAH CHANG ALBANY

CORROSION

(continued)

RATE, ml

TEHPEPATURE

CORROSIVE

N~lrft Acid

"C

MEDIA

+ 1% Fe

65

zr 702

204

Zr 70 4

_N,tr~c Acid

Ntlrlc

* 1% Cl-

Acid

1 45% 304 S S

ml

65

3xaa

1o/o
FeCli
100

?erch?sr~c Acfd

100
Salurated

otassium

Acid

ChIctIde

<

c2

<5

Roar_-

Dhosphorlc

llll

Acla

Phenol

)
_

* 1% S&water

N!lr~c 4cfd *

fas NaCI)
N~trlc And

i!r 7(

_
_
-

5-30

Room

<5

5-35

60

C5

5-50

100

<5

35-50

Room

c5

45

Eolllng

c5

50

Bolllng

<5

65

100

5-10

5-10
_

10-l!

B.P = 106C

c20

70

Bolllng

>50

05

38

5-20

a50
-

65
65

60
Bolllng

20-50

20.5(

>50
_

BP = 156C
36% t&PO4 + 0 5% HNO,
36% H,PO, + 5% HNO,

>50

35% H,POa + 4% HNO,

MIXlUre

Room

>50
nil

MlXtUIe
MIXlUre

Room

WG

69

>50

60
Room

.=

Saturated
Saturated

<

BP

= 123-126C

_
-

ofaswm

Fluoride

lolasstum

Hydroxfde

20

26

nil

,H=09

20

90

Bolllng

,H=69

03

a50
< 1

50
10

27
Bolllng

<

.z 1

25

Bolting

< 1

50

Bollbng
241.377

<5

>50
< 1

50.anhydrous
Mixture

29

13% KOH.

13% KU

otasslum

lodlde

Room- 100

<2

otassium

Nllrlte

Room- 100

c2

iher NIlrate
10
;odlum

ROOfT

<5

Bolllng

<

-= 1

35.Bolltng
3ol!Ing

.z

3atutated

=400m

<

;aturated

301ilng

< 1

jaturated

107

<

1
1

iaturateo
iodium
iafurared
iodtum
iaturaled

Chloride

3P

= 107oc

1
_
-

nil

< 1
-

Tiodum

!9

3-Saturated

Chlortde

35

30

nil

!5

30

f-Ill

Saturated

30

nil

idlusted

lo pH = 1

rdlusled

lo pH = 0

SO2
Chlorlae
SO;
Chloride
SO,

(continued)

Nonferrous Metals and Alloys

TABLE 5.29:

ZIRCONIUM

CORROSIVE

ALLOYS-TELEDYNE

WAH CHANG ALBANY

(continued)

REMARKS

MEDIA

Sodium

Ffuorlde

Sodum

Hydroxide

753

9-11%

NaOH.

10% NaOH.

7% NaOH.
7% NaCIO,.

15% N&l
10% NaCl

&

53% NaCI.
60-l 00 ppm

nded salt-violent

jodlum

Sulfide

jlannlc

Chloride

juccinlc

;ulfurlc

Acid

Acid

O-50

100

<2

100

150

<2

o-75
60
60
77 5
75
77

20

<l

60

Cl

Cl

20
30
60
50
50

C5
20-50
10-20
<l
5-10

>50
>50
>50

>50
Cl0
_

50

a50

>50

=-50

75

60

<5

<5

65

100

Cl

70
75

100
100

<2
<5

<5
<5

76
77

100
100

Cl0
<20

775
60
65

100
130
130

>50
Cl

>50
-

250
<5
-

70

140

<5

Cl0

(continued)

754

Corrosion

TABLE

5.29:

Resistant

Materials

ZIRCONIUM

Handbook

ALLOYS-TELEDYNE

WAH CHANG ALBANY


CORROSION

CONCENTRATION
CORROSIVE

MEDIA

?/,

Zr 704

Zr 705

<1

<5

Boihng

es

1O-20

64

Boiling

66

Bohng

-=5
<5

20-50
-

69
71

Bohng
Bohng

<5
<5

72-74

BOlllng
Boiling

5-10

>50

1 O-20

so

60

Boiling

<,

BP

60

Boiling

<5

Added

65

Boiling
Boiling

<5

B.P. = 152-155C

5-10

Added

Acid

+ 1000 ppm

Fe

+ 10,000 ppm

Fex*

Sulfuric

Acid

+ 200-l

000 ppm

+ 10,000

ppm

Fe3

65

Fe

- 141 ppm

Fe,-

+ 200 ppm
+ 1410 ppm-10.000

+ 20,000
Sullurlc

ppm

Fe3

Boiling

5-10

B.P. = 167-l

Boihg

10-20

Added

70

Bohng

>50

<5
<5

FeC13

60
60

Bolllng

ppm
ppm

Fe&

60

Bohng

FeCI,

Bohng

20-50

<5

<20

~20

20-50
>50

20-50

65
65

Bowling
Bottling

c5
-=5

c5
c5

<20
<20

65

Boiling

<5

-=5

<20

Sullurlc Acid
+ 10 ppm F&l,

100ppm

FeCl,

70

Bohng

<20

<20

,50

70
70

Boiling

c20

<20

a50

+ 200 ppm FeCI,


+ 1000 ppm FeCI,

Boiling
Boiling

<20

c20

70

c20

c20

a50
>50

+ I 0.000 ppm Fe&

70

Boiling

20-50

>50

>50

60
60

Boiling

<5

Boiling

<l

65

Boiling

<5

Acid

+ 200 ppm

Cuz*

+ 1000- 10.000
Sulfuric

+ 3 ppm

ppm

Cu2.

CW
ppm

CW

Added

as CuSO,

Added

as CuSO,

Added

as CuSO,

Added

as NaNO,

Added

as NaNOx

Added

as NaNO,

Added

as HNO,

as HNO,

70

Boiling

5-10

70

Boiling

250

60
60

Bohng
Bohng

<5

=-50

Acia

+ 1000-l

0.000 ppm

+ 50,000

ppm

Sulfuric

c1.12.

Acid

+ 27-226
Sulfuric

ppm

Acid

+ 200- 10,000
Sulfuric

N03-

NOa-

Acid
65

Boiling

c5

+ 10.000 ppm NO,-

65

Boiling

10-20

+ 50.000 ppm

65

Boiling

>50

+ 200-1000

Sullurrc

ppm NO,NO,-

Acid

+ 200 ppm

NO,-

+ 6000 ppm
Sulfuric

71 C

as Fe,(SO&

Acid

+ 200 ppm FeCI,


+ 1000 ppm FeCI,

Sulfuric

as Fe?(SO&

70
70

+ 10.000 ppm FeCI,

55OC

as Fe&SO&

Acid

+ 1000 ppm
+ 10,000

= 152-t

Acid

+ 14 ppm

Sulfurtc

REMARKS

Zr 702

Bohng

75

Sulluric

RATE. mpy

m.wEwTURE

56
62

3~1lur1c Acid

Sulfuric

(continued)

NO,-

70

Boiling

5-10

70

Bohng

20-50

Acid

+ 1000 ppm

N03-

60

Bohng

c5

+ 10,000 ppm

NO3-

60

Bohng

10-20

+ 50,000

NO%-

60

Bohng

>50

65

Bohg
Bohg

<5
a50

Added

Mwture

Room-100

Cl

1% H,SO,.

Mlxlure

Room- loo
Bolllng

10% H&YiOa, 90% HNO,

<l

>50
Cl

a50
-

>50

MIxlure

100
Room

MIxlure

Bohng

a50

>50

Sulfuric

ppm
Acid

+ 1000 ppm

NOs-

+ 10.000-50.000
Sullurlc

Acid

ppm

N03-

65

Mixture
MIxlure

ml

99% HNOl

14% H,SO,.

14% HNOl

25% HsSO,,

75% HNO,

50% HzSO,.

50% HNO,

>50

66% t-GO,,

5% HNOz

(continued)

Nonferrous Metals and Alloys

TABLE 5.29:

ZIRCONIUM

ALLOYS-TELEDYNE

WAH CHANG ALBANY


CORROSION

CONCENTRATION
CORROSIVE

Sulfuric

MEDIA

Acid (Cont.)

RATE,

(continued)
mpy

TEMPERATURE

Mixture

Eoillng-135

Mixture
Mixture
Mixture

Room
Bolllng

Zr 702

Zr 704

Zr 705

1 O-20
>50
<,

1 O-20
>50
-

>50
>50
-

REMARKS

68% H,SO,.
75% &SO,.

1% HNOa
25% HNOa

<,

MIxlure

Eolllng
Bollwig

7 5% H,SO,. 19% HCI


34% H>SOd. 17% HCI

<,

40% H,SO,.

Mixture
Mixture

Boiling
Boiling

1-5
Cl

56% H>SO,,

10% HCI

60% H,SO,.

1 5% HCI

MIxlure

Bolllng

Mixture
Mixture

Bolllng

<5
10-20

69% H,SO,.
69% H,SO,.

1.5% HCI
4% HCI

>50

Mixture

Bolllng
Boiling

<20
>50

14% HCI

72% H$SOd, 1 5% HCI


20% H&O,.
7% HCI wtth
50 ppm F lmpuritles

Sulfurous

Acid

Room

<5

Saturated

192

5-50

755

Corrosion Resistant Materials Handbook

756

TABLE 5.30:

TUNGSTEN

AND MOLYBDENUM-SCHWARZKOPF

DEVELOPMENT

Corrosion Behavior in Acids, Alkalis and Corrosive Solutions


Media

Tungsten

Molybdenum

. . . . . . .. . . .. .. . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . At 2oc (68~).
Hydrochloric
acid, 10%
Sulfuric acid, 10%
Nitric acid, 10%
Hydrofluoric
acid, 3%
Acetic acid, 10%
Potassium hydroxide,
10%
Sodium chloride solution, 3%

resistant
resistant
resistant
resistant
resistant
I.01
resistant

resistant
resistant
resistant
resistant
resistant
1 .o*
resistant

. . .. .. . . .. .. . . . . . . . .. . . .

. . . . . . . . . . . . . . . . . . . . . . . At 100C (212F)
Hydrochloric
acid, 10%
Sulfuric acid, 10%
Nitric acid, 10%
Hydrofluoric
acid, 3%
Acetic acid, 10%
Potassium hydroxide,
10%
Sodium chloride solution, 3%
Corrosion

5.31:

TABLE

Comparative

COBALT,

Corrosion

resistant
resistant
attacks
approximately
resistant
resistant
resistant

0.5+
5
0.5*

NICKEL

AND STAINLESS

STEEL ALLOYS-CABOT

STELLITE

Data

and
Temperature

STELLITE
alloy

TRIBALOY
alloy
T-400

T-700

T-600

No. 6

DELORO
alloy
No. 60

Stainless
Steel Type

Nominal
Chemical Composition,
Weight Percent
TRIBALOY
T-400

316

50%.
Baling

Acid

lO%,
Room Temp.

Ferric
Chloride

Formic

Acid

30%,
150deg.F
(66 deg. 2)
45%.
Boiling

Hydrochloric
Acid

Nitric

Acid

Sodium
Chloride

65%.
150 deg. F
(66 deg. C)

65%.
150 deg. F
(66 deg. C)

10% + 5% FeCl
Room Temp.

5%.
150deg.F
(66 deg. C)

5%.
Boilmg

10%.
Ewmg

Sulfuric
Acid

Delermmed II laboratory
tests. II IS recommended
thal samples be lested
de, actual plant
codMms.

T-800

B&

Co+Fe

30

Ni

El.91

Ni+Fe

30

MCI

30

28 5

32 5

28.5

Cr

8.5

15.5

17 5

Si

26

34

3.4

.08

.OB

08

Maximum

5%.
150 deg. F
(66 deg. C)

65%.
Bolllng
Phosphoric
Acid

alloy
T-700

Bal

CO
Acetic

5*

rate, grams per square meter per day.

concentration
Media

resistant
resistant
approximately
approximately
resistant
approximately
resistant

Code:
E-Less than 2 mpy
(CO.05 mm/y)
G-c20
mpy (co.51
mm/y)
S-Dver 20 mpy (>0.51
mm/y) lo 50 mpy
(1.2: mm/y)
U-More than 50 mpy
(~1.27 mm/y)

STELLITE
Alloy No. 6:
cobalt-base alloy
DELORO
Alloy No. 60:
nickel-base alloy

757

Nonferrous Metals and Alloys

TABLE

5.32:

STAINLESS

STEEL, NICKEL

AND COPPER ALLOYS-CARPENTER

TECHNOLOGY

Corrosion Resistance Table


This table shows the resistance of a number of materials to the more common chemicals. Many factors
influence the resistance of materials to various solutions. Factors which must be given consideration for
service in corrosive.environments are: temperature,
concentration, aeration, influence of inhibiting or accelerating contaminants, influence of re-circulation,
solids in suspension, velocity, frequency of use, and
equipment design.

Code:
l Corrosion
0 Corrosion
0 Corrosion
X Corrosion
360 6s2r

Rate less than 0.002 per year


Rate less than 0.020 per year
Rate from 0.020 to 0.050 per year
Rate greater than 0.050 per year
20

4l

60

80

rml

too

300--

The influence of contaminants is probably the


most important from a commercial standpoint. Few
corrosive solutions will be free of all contaminants.
The majority of these contaminants have no influence on corrosion, but those that do generally affect
the conditions greatly.

250

462

The corrosion data for all grades except Carpenter 20Cb-3 stainless is reprinted from Corrosion Data
Survey, 1974 Edition, published by the National
Association of Corrosion Engineers. The corrosion
ra!es for Carpenter 20Cb-3 stainless represent a
composite of the NACE Corrosion Data Survey and
more current data developed in Carpenters Corrosion Laboratory.

125

257

loo

212

75

167

777

212-175

347

150--

--.__----.--___-I-_-_

60-25

*F

20

4,;

60

Percent Concentration

80
in Water

(continued)

758

TABLE

Corrosion Resistant Materials Handbook

5.32:

STAINLESS

STEEL, NICKEL

AND COPPER ALLOYS-CARPENTER

TECHNOLOGY

(continued)

(continued)

Nonferrous

TABLE 5.32:

STAINLESS

STEEL, NICKEL

AND COPPER ALLOYS-CARPENTER

Metals and Alloys

TECHNOLOGY

(continued)

/1
r
1

t
a
+
(
2
lY

(*

e
c
c

tA
_
t
F

1
3
;
.

Glutamc
ACld

(continued)

760

Corrosion Resistant Materials Handbook

TABLE 5.32:

STAINLESS

STEEL, NICKEL

AND COPPER ALLOYS-CARPENTER

TECHNOLOGY

(continued)

(continued)

Nonferrous

TABLE 5.32:

STAINLESS

STEEL, NICKEL

AND COPPER ALLOYS-CARPENTER

Metals and Alloys

TECHNOLOGY

761

(continued)

(continued)

762

Corrosion Resistant Materials Handbook

TABLE 5.32:

STAINLESS

STEEL, NICKEL

AND COPPER ALLOYS-CARPENTER

TECHNOLOGY

(continued)

Sodium
Chloride

Sulfite
Liquor
with 10%
Sulfur
Dioxide

Sulfur
Chloride

(continued)

Nonferrous Metals and Alloys

TABLE 5.32:

Regtstered
RegIstered

STAINLESS

STEEL, NICKEL

AND COPPER ALLOYS-CARPENTER

TECHNOLOGY

763

(continued)

Trademark of Cabot Corporation


Trademark of INCO

Footnotes for Corrosives:

Footnotes for Data Squares:

1
2
3
4
5
6
7
6
9
10
11
12
13
14
15
16
17
16
19
26
21
22
23
24

1
2
3
4
5
6
7
6
9
10
11
12
13
14
15
16
17
16
19
20
21
22
23
24

m1son
TOXIC
Explosw
Flammable
Ingestlo poson
Inhalant potso
Attacks skin
lrrttant
Vapor harmlul
lgnltes organics
Fummg llqu!d
Hygroscoplc
Liberates HCI in water
Narcotic
Volatile
Hazardous under pressure
lgnttes combustibles
FIR hazard
Exptoswe war 70%
lgnltes I moist arr at 30C
Exothermtc in water
Dust explodes
Explosive dust
Exothermlc wth water

No water
No aw, oxygen
Low aw. oxygen
Pits
Stress cracks
Sfress c~rros~~
Discolors
Crewce attack
Intergranular attack
No chlorides
May dwzolor
May catalyze
May pit
May stress crack
Transgranular attack
Vapor
Aerated
Catalyzes
Static
Agttated
-7 pH
<7 pH
>7 pH
No HCI. HISOI. NaCl

25
26
27
26
29
36
31
32
33
34
35
36
37
36
39
46
41
42
43
U
45
46
47
46

No femc chloride
-0.1% acetic actd
Also sludge
NO ro satts
No sulfuric acid
Explosive
With HzSOI
With steam
No sutlur
No stress
No ammOma
300 psi
Stress rekeved
No HCI. Cu. Ni ions
No Cu, Fe ums
Over 70% aor
ZO-70% air, 530 psi
With sulfur, <34oC=x
<10mg/1
No H&O.
Go PSI
No sulfides
~20% zinc
Trace HCl

49
56
51
52
53
54
55
56
57
56
59
66
61
62
63
64
65
66
67
66
69
76
71
72

pti 2 to 3.5
Annealed, Immersed
>2.25% MO
Erratic
With NaCl
With NaCI. HCI. Hz02
No Fe. Cl
Wtth +-0.05-l%
HIPOI or HzSOI
+SO, or HCOOH
<RC 22,6O.CXXl
Annealed
No cold work
No HIS
Permeable to HP
Unsullatad
With or without steam
240 psi
Cold worked
>60% copper
>20% sullur~c. bal. nitric acid
No MO; low C
Red turning
Pits I chlorides
over 4M)c

73
74
75
76
77
76
79
66
61
62
63
64
65
66
67

Steam and air


75-100% concentration
Low NaCl
With HCI
<17% zinc
~0.23%. 2M) ps,
300 psi
NO SOa
No NaCl
High pressure
75-120 ps,
No sodturn sulhte
+ ammonia
Avoid hydroxides
Saturated

764

Corrosion

TABLE 5.33:

Resistant

TITANIUM,

Materials

Handbook

ZIRCONIUM

AND TANTALUM-ASTRO

METALLURGICAL

CORROSION RESISTANCE CHART FOR TITANIUM, ZIRCONIUM, TANTALUM


The reactive
metals, titanium,
zlrconlum
and tantalum
offer unusual resistance to most materials encountered
In
rhe Chemical
Processing,
Metal Finishing
and Waste
Treatment Industries.
In many Instances they are the only
metals that meet the service life requirements
of the application.

THE IMPORTANCE

OF TEMPERATURE

Corrosion
data IS developed
by exposing
the material to
environments
at spectfic temperatures.
However,
when
applied
to process
equipment.
the fluid temperatures
may not always represent
the actual material exposure
temperature.
In evaluattng
corrosion
data, special attention
should
always be given to actual metal temperature
in the particular environment.
This IS especially important
in selectIng material for heat exchanger
services.
Often solutions
at higher temperatures
than those recommended
can be handled
in a heat exchanger
that is

MEDIA

CONCENTRATION
%

Acetaldehyde
100
Acetic Acid
5, 25, 50, 75, 99.5
Acetic Acid
Vapor-33
Acetic-Glacial
Acid
99.7
Acetic Anhydride
99
Acetone
100
Adipic Acid (plus 15/20%
Glutaric Acid, 2% Acetic Acid )
25
Adiponi trile Solution (NHJ)
Vapor
Alum
100
Aluminum Chloride (Aerated)
5, 10
Aluminum Chloride
25
Aluminum Chloride
25
Aluminum Fluoride
Saturated
Aluminum Hydroxide
100
Aluminum Nitrate
Saturated
Aluminum Sulfate
Saturated
Aluminum Sulfate (1% H&04)
Saturated
Aluminum Sulfate (1% Sodium Carbonate)Saturated
Amidation Reaction
Ammonium Acid Phosphate
10
Ammonia, Anhydrous (200 PSI)
100

IN MATERIALS

SELECTION

designed as a cooler. This is due to the fact that the tube


wall temperature
will be below the temperature
of the
incoming
solution.
On the other hand. In heating applications. tube wall temperatures
can exceed otherwise
safe temperature
limits even though
the solution
leaving the heater is within prescribed
temperatures
for the
metal used.
Consequently,
in selecting
material for heat transfer
equipment,
it is often important
that theactual
tube wall
temperature
should
be computed
before
evaluating
material selection
for the planned process conditions.

TEMPERATURE
F TlTANlUM tlRCONlUM TI-PO
150
Boiling
Boiling
Boiling
Room
150
390
700
212
140
212
Room
Room
212
Room
Room
Room
Room
212
Room
104

A
A
A
A
A
B
A
A
C
A
A
_
A
A
A
A
A
A
A

A
A
A
A
A
A
_
_
A
A
A
A
C
A
A
-

_
_
A
A
_
_
-

TANTALUM

A
A
A
A

A
A
A
C
A
A
-

(continued)

Nonferrous

TABLE 5.33:

TITANIUM,

ZIRCONIUM

AND TANTALUM-ASTRO

METALLURGICAL

MEDIA

CONCENTRATION
%

TEMPERATURE
F

Ammonia

50

Ammonia
Ammonium
Bicarbonate
4mmonium
Carbonate
(Aqueous)
Ammonium
Carbonate
Ammonium
Chloride
Ammonium
Fluoride
4mmonium
Hydroxrde
Ammonium
Perchlorate
4mmonium
Sulfate
4mmonium
Sulfate
Ammonium
Sulfate
Ammonium
Sulfate (Aqueous)
Aniline, plus 2% AlCb
Aniline Hydrochloride

Plus Water
50
50
50
1, 10. Saturated
10

190
_

Aqua
Aqua

Regia
Regra

Banum
Banum
Bartum
Banum
Banum
Banum
Barium
Banum
Banum
Banum

Carbonate
Carbonate
Chloride
Chlortde
Chlonde
Chlonde
Hydroxide
Hydroxrde
Hydroxrde
Nrtrate

- 8H20

Benzaldehyde
Benzene
Benzene
Benzene
Benzorc Acid
Benzorc Acrd
Benzyl Sulfontc
Acrd
Bone Acid
Bone Acrd
Boric Acid
Bromrne
Bromine
3romine
3romrneMethyl Alcohol
3utync Acrd
3utync Acrd

:alcrum

Brcarbonate

:alcrum
:alcrum
Zalcrum
Zalcrum

Brsulfrte
Carbonate
Chlonde
Chlonde

:alcrum
Ialcrum
:alcrum

Hydroxtde
Hydroxide
Hypochlorrte

Calcium Hypochlorite
Zarbolrc Acrd
Carbon Tetrachloride
Carbon Tetrachlonde
Carbon Tetrachlonde

28
15-20
50
5. 10. Saturated

212
212
Boiling
212
Room

5. 10
10

80
80-190
212
Room
212
Boiling

98
5. 20
3HCL:
3:l

316
99
Room
170

1 HN03

Metals and Alloys

(continued)

IITANIUM
A

A
A
A
A
A
A
A
A
_

A
_
_
_

A
A
A
B
A
A
B

A
A
_
_
_

A
A
_

A
A

100
_

212

212
Borlmg

2. 6
Saturated
Saturated
99
Lrqurd
Vapor

212

Room
Boiling
Room
Room
Bowling
Borlmg
Boiling

_
_
_
_
_

A
_

Room
212
212
Borlrng
Room
Room
212
Room
Room
212
212
Room
176
212
Room
212
Borlmg
212
Room
86
86
Room
Room
Room
212

5. 10. 20
28
Saturated
Saturated

_
_
_
_
_
_
_

A
_

212

Saturated

A
_

15
Saturated
5. 20
20
25
Saturated
Saturated
50
Saturated
10
100
100
Lrqurd
Vapor & Lrqurd
75
Saturated
100
10
50
Saturated
Liquid
Vapor
Water
1
Undiluted
Undiluted

80
Boiling

765

_
A
A
A
A
C
_
_
A
A
A
A
A
A
A

A
A
A

A
A
A
A
4
A

A
A
A
A

A
A
A
A

A
A

A
A

A
C
A
A

A
A
A
A

_
C

B
A

A
A

A
A
A
A
A
A
A
A
A
A
A
A
A

A
A

A
A
A
A
A
A
A
A
A
A

(continued)

766

Corrosion

TABLE

5.33:

Resistant

TITANIUM,

Materials

ZIRCONIUM

HEOIA
Chlorine

Handbook

AND

TANTALUM-ASTRO

CONCENTRATION %
Dioxide

Chlorine (Water Saturated)


Chlorine (Water Saturated)
Chlorine Gas (Dry)
Zhlonne
Gas (more than 0.13% HzO)
Zhloroacetic
Acid
zhloroacetlc
Acid
Chloroform
Zhromlc
Acid
Chromic Acid
Chromic Acid
Citnc Acid
Citnc Acid
Citnc Acid (Aerated)
Citrtc Acid (Non-Aerated)
Copper Cyanide (Electroplating
Solution)
Copper Nitrate
Copper Sulfate
Copper Sulfate
Cupnc Carbonate-Cupric
Hydroxide
Cupnc Chlonde
Cupric Cyanide
Cupric Sulfate
Cuprous
Chlonde
Cyano Acetlc Acid
Cyclohexane

METALLURGlcAL

TEMPERATURE F

TlTANlUM

ZIRCONIUM
_

180

_
_

Room
167
Room
200
180
Bowling
Boiling
Boiling
Room
195
212
140
212
212
Room
Room
Room
Boiling
Room
Boiling
Room
212

B
A

195
212
302

100
100
30
100
100
10
20
365
10. 25
50
50
50
Saturated
5
Saturated
Saturated
20. 40. 50
Saturated
50
50
100

(continued)

C
A
A
A
A
A
A
B
A
A
A
B
A
A
A
A
A
A
A
_

B
C
B
A
A
A
A
A
A
A
A
A

_
_
C

A
A
A
A
A
A
A

_
A
_
_

1:
_
_

A
A
A
A
A
A
A
A
A
A
A
A
A
A

A
A
A
_

100
100

100
212

Dichloroacetic
Acid
Dlchloroacetlc
Acid
Dimethyl
Ether
Dloxane

100
100
100
100

212
Bollmg
212
212

A
A
_

Esters
Ethyl Acetate
Ethyl Alcohol
Ethyl Alcohol
Ethyl Alcohol
Ethylene
Dvzhlonde

_
2-100
95
Llquld
Partial

A
_

100

250
212
Bolllng
Room
Room
Bolllng

A
A
A
A

A
A
A

A
A
B
B
A
A

Ferric
Ferric
Ferric
Ferric

Chlonde
Chloride
Chloride
Sulfate

5. 10 20, 30
5, 10. 20. 30

Room
212

A
A

C
C

5. 10. 2L. 30. 40. 50


10

A
A

Ferric
erric

Sulfate
Sulfate

A
A
_

A
_

-errlc Sulfate
luobonc
Acid
Fluorine
Fluonne

IO
Saturated
49
5-20
Gas
% liq.-% gas

Boiling
Room
212
Room
212
Elevated

Eluorine
rluorlne
Fluorme. liquid
Fluorme. gaseous
Fluorme, gaseous
Fluorosiliclc
Acid
Formaldehyde
Formaldehyde,
plus 2%% HzSO~

Llquld
Gas
(4 hr. exposure)
(8 hr. exposure)
(288 hrs. exposure)
IO
37
50

Room
310

TANTALUM

A
A
_

Cyclohexane
Cyclohexane

Im-erslon

TI-PO

C
0
A

_
_
_

A
A

A
A
A
A
A

A
C
_
_

C
A
A
(continue

Nonferrous

TABLE

5.33:

TITANIUM,

ZIRCONIUM

.-

MEDIA

AND

TANTALUM-ASTRO

______..-^._ --CONCENTRATION
%

Formamide
Vapor
Formrc Acrd
Formrc Acid (Non-Aerated)
Formrc Acid (Non-Aerated)
Formic Acid (Non-Aerated)
Formrc Acid (Non-Aerated)
Formic Acid (Aerated)
Formrc Acid (Hz0 Solutron)
Furfural Alcohol
_~
Glue Polyvrnyl
Glycerrne

10. 25. 50. 90


10
25. 50
25
80
10-90
9

Fiesrn

METALLURGICAL

___^__.____
TEMPERATUREF

---

Room
Room

A
A

Hydrrodrc Acrd
Hydrobromrc
Acrd
Hydrochlorrc
Acrd
Hydrochlonc
Acrd
Hydrochlorrc
Acrd
Hydrochloric
Acrd
Hydrochlonc
Acrd (Aerated)
Hydrochlonc
Actd (Aerated)
Hydrochlonc
Acrd (Aerated)
Hydrochlorrc
Acrd Plus 1% HNO,
Hydrochlonc
Acid Plus 5?0 HN03
Hydrochlorrc
Actd Plus 10% HNO,
Hydrochlonc
Acrd Plus 10% HN03
Hydrochlonc
Actd Plus 0.05% CuSO4
Hydrochlonc
Acrd Plus 5% CUSOI
Hydrochlonc
Acid Plus 1% CuSO4
Hydrochlorrc
Acrd Plus 5% CuSO4
Hydrochlonc
Acrd Plus 50% Cr03
Hydrochlorrc
Actd Plus 1% Cr03
Hydrochlorrc
Actd Plus .50% CuSO4
Hydrochlorrc
Acrd Plus .lO% CuSO4
Hydrochlorrc
Acid Plus .20% CuSO4
Hydrochlorrc
Acrd Plus .25% CuSO4
Hydrochlorrc
Acrd Plus .50% CuSO4
Hydrochlorrc
Acrd Plus 1% CuSO4
Hydrochlonc
Acid (Non-Aerated)
Hydrochlorrc
Acrd (Non-Aerated)
Hydrochloric
Acrd (Non-Aerated)
Hydrochlonc
Actd (Non-Aerated)
Hydrochlonc
Actd (Non-Aerated)
Hydrochlonc
Acrd (Non-Aerated)
Hydrochlorrc
Acrd (Non-Aerated)
Hydrochloric
Acid (Non-Aerated)
Hydrochlonc
Actd (Non-Aerated)
Hydrofluonc
Acid
Hydrofluonc
Actd (Andydrous)
Hydrofluonc
- Nttric Acid
Hydrogen
Peroxide
Hydrogen
Peroxide
Hydrogen
Peroxide
Hydrogen
Sulftde
Hydrogen
Sulfide
Hydioxyacetrc
Actd

3. 6
30
50
Saturated
Saturated
_

Iodine m water Plus


Potasstum
lodtde

Room

Lactic

lo-85

212

Acrd

57
40
5
10
20
35
5
10
20
5
5
5
5
5
5
5
5
5
5
10
10
10
10
10
10
1
1
1

Room
Room
Room
95
95
212
95
95
95
100. 200
100. 200
100
200
100. 200
100. 200
100, 200
100, 200
100. 200
100. 200
150
150
150
150
150
150
100
160
Boiling

3-5
3-5
3-5
5
10
10
48
100
(lHF:l5HN03)

Room
160
Borltng
125
Room
160
Room
Room
Room
Room
Room
140
Room
70
104

HOH
HOH

--

TITANIUM llRCONlUM
A
A
A
C
C
C
A
B

(continued)

~--

572
212
Borlrng
Botltng
212
Botlrng
212
125
337

B
A
A
B
C
C
A
B
C
A
A
A
B
A
A
A
A
A
A
A
A
A
A
A
A
B
B
B
B
B
B
B
B
B
C
B
C
A
B
_
A
A

767

Metals and Alloys

TI-PO

TANTALUN

C
A
A
A
A
A
A
_
_

_
_
_
_
_
_
_
_
_
_
_
_
_
_
A
_
_
_
A
_
C
_
_
A
_
A
_
_

A
A
_
A
A
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_
_

A
[continue

768

TABLE

Corrosion

5.33:

Resistant

TITANIUM,

Materials

Handbook

ZIRCONIUM

AND

TANTALUM-ASTRO

METALLURGICAL

(continued)

MEDIA

CONCENTRATION%

Lactrc Acrd
Lead Acetate
Lmseed Oil, Boiled

Saturated

Room
Room
Room

A
A
A

Magnesrum
Chlonde
Magnesrum
Chlonde
Magnesium
Chlonde
Magnesium
Hydroxrde
Magnesrum
Sulfate
Magnesium
Sulfate
Malerc Acrd
Manganous
Chlonde
Mercurrc
Chlonde
Mercurrc
Chlonde
Mercurtc
Chlorrde
Mercurrc
Cyanrde
Mercury
Methyl Ethyl Ketone

5-40
5-40
40

Room
212
212

A
A
_

A
A

Saturated
Saturated
37

Room
Room
200
Room
212
212

A
A
_

A
A

A
A
A
A
A
A
A
_

A
A
A
A
A
A
A

Nrckel Chlonde
Nickel Nrtrate Plus 61 HOH
Nrckel Sulfate
Nttnc Acrd (Aerated)

5-20
50
40
98
5. 10. 20. 30
5-69.5
65
40
70

Nrtrrc
Nrtrtc
Nttrrc
Nrtrrc
Nrtrrc
Nrtrrc
Nrtrrc
Nrtnc
Nrtnc
Nrtrrc
Nrtrtc
Nrtrrc
Nrtrrc
Nrtrrc
Nrtrrc

Acid
Acrd
Acrd
Acrd
Acrd
Actd
Acrd
Acrd
Acid
Acrd
Acrd
Acrd
Acrd
Acid
Acrd

Nrtrrc Acrd

10-100

5-20
1. 5. 10. 55
Saturated
Saturated
Saturated
All

(Aerated)
(Aerated)
(Aerated)
(Aerated)
(Aerated)
(Aerated)
(Non-Aerated)
(Non-Ae:ated)

- Whrte
- White
White
Whrte
-

20
65
98
10. 20. 40. 69.5
10, 20, 40. 69.5
65
90

Fumrng
Fumrng
Fumrng
Fumrng

170 Adrprc

Lrqurd
Acrd

Nrtrrc Acrd
Red Fuming ~
Less than 1% water = pyrophonc
Oxalrc
Oxalrc
Oxalic
Oxalrc
Oxalrc

Acrd
Acrd
Acid
Acrd
Acrd

Perchloromethylmercaptan
Plus 2 to 19/o Hz0
Perchloromethylmercaptan
(Anhydrous)
Phenol (Carbohc
Acrd)
Phosphonc
Actd
Phosphonc
Acrd
Phosphonc
Acrd
Phosphonc
Acrd
Phosphonc
Acrd
Phosphonc
Acid
Phosphorrc
Acid
Phosphonc-Sulfunc
- CuSOa

or Vapor

38

TEMPERATUREF

Room
200
Room
Room
Borlmg

TITANIUM

212
Room
180
80

A
A

95
212
347
392
518
554
Boll - 250
Room
95
212
Borlmg
180
252
320
Room

A
A
A
B
B
0
A
A
A

194-203
Room

A
A
B
B
B
A

IRCONlUM

TI-PD

TANTALUM
A

A
A
A
A
A
A
A

A
A
A

A
A
A

A
A
A
A
A

A
A
A
A
A

A
A

A
A
A

reactlc
1
0.5
5
10
0.5-25

Saturated
5-30
35-85
40
5-3 5
85
5
10
15H3POzvlOHzS04

98.6
95
95
95
140

B
B
0

Room

Room

Room
Room
Room
212
140
100
212
175
150

A
A
B
B
B
B
B
B

B
A
A
B
A
A

A
A
A
A
A

continue

Nonferrous

TABLE 5.33:

TITANIUM,

ZIRCONIUM

MEDIA
Phosphorus

Trichloride

Photographic

Emulsions

AND TANTALUM-ASTRO

CONCENTRATION

TEMPERATU
REF

Saturated
_

Room
_

Potassium

Bromide

Saturated

Potasswm

Chloride

36

Room
Boiling

Potassrum

Chloride

Potassium

Dichromate

Saturated
_

Room
_

Potassium
Potasstum

Ferncyanrde
Ferricyanide

Saturated
0.5

Room
Room

Potaswm

lodfde

Potasstum

Iodide

Potassium
Potassium

& 5% NaCl

Saturated

Room

Saturated

Room

Permanganate
Hydroxrde

Saturated
10

Room
Boiling

Potasstum

Hydroxrde

25

Boiling

Potassium
Potassium

Hydroxide
Nitrate

50
100

Boiling
212

Sulfate

10
1

Room

Vapor
_

374

Sea Water
Silver

Nitrate

50

Room

Silver

Nitrate

15

90

Potassrum
Potassrum
Propionic

Sodium
Sodium
Sodiun

& 0.1% NazCO3

Throsulfate
Acrd

Acetate
Alumrnate
Bisulfate

METALLURGICAL

Boiling

Saturated

Room

25
Saturated

Boiling
Boiling

TITANIUM

Metals and Alloys

(continued)

TI-PD

_
_
_
_
_
_
_
_
_
_
_
_
_

Bwlfate

10. 25

Boilrng

Sodium
Sodium

Carbonate
Chlorate

10. 25
Saturated

Boiling

Sodium

Chlorate

lo-25

Room

Sodturn
Sodrum

Chloride
Chlonde

29
Saturated

Boiling
Room

A
A

Sodium

Chloride

Saturated

Boiling

Sodrum

Crtrate

Room

Sodium

Cyanide

Saturated
Saturated

Sodium

Dlchromate

Saturated

Room

Sodrum

Fluoride

Saturated

Room

Sodium

Fluonde

20

90

Room

Room

Sodrum

Hydroxide

10. 25

Borlmg

Sodium

Hydroxrde

26

Room

Sodium

Hydroxrde

40

176

Sodium

Hydroxide

Saturated

Room

Sodrum

Hypochlonte
NItrIte

6
Saturated

Room

Sodium

Room

Sodium

Nitrite

50

200

Sodium

Phosphate

Saturated

Room

Sodium
Sodium

Phosphate
Silicate

20
25

90
Boiling

Sodium

Sulfate

10-20

Boiling

Sodrum

Sulfate

Saturated

Room

Sodium

Sulfide

10

Boiling

Sodium

Sulfide

Saturated

Room

Sodrum

Sulfite

Boiling

Sodium

Sulfite

IO
Saturated

Sodium

Sulfite

Saturated

Boiling

Sodium

Thtosulfate

IO. 25

Boiling

Sodium

Thiosulfate

Stannic

Chlonde

Acid

TANTALUM

_
_
_
_
_

Sodrum

- Acetic

769

_
_

Room

20-20

Room

212

(continue

770

Corrosion

TABLE 5.33:

Resistant

TITANIUM,

Materials

Handbook

ZIRCONIUM

AND TANTALUM-ASTRO

METALLURGICAL

7-

MEDIA

CONCENTRATION
0,

TEMPERATURE
F

Stannic Chlonde
Stanmc Chloride
Stannic Chloride
Stannous
Chloride
Stannous
Chloride
Steanc Acid
Succinic
Acid
Sulfur Plus HO4
Sulfur (Molten)
Sulfur Droxrde (Water saturated)
Sulfur Dioxide (Dry)
Sulfunc
Acrd
Sulfunc
Acid
Sulfuric
Acid
Sulfuric
Acid
Sulfuric
Acid Plus 0.25% CuSO4
Sulfurtc Acid Plus 0.25% CuSO4
Sulfuric
Acid Plus 0.25% CuSO4
Sulfunc
Acid Plus 0.5% CuSO4
Sulfuric
Acid Plus 1.0% CUSOI
Sulfunc
Acid Plus 1.0% CuSO4
Sulfunc
Acrd Plus 0 5% 003
Sulfunc
Acrd Plus 0.5% CrO,
Sulfuric
Acid Plus 1 0% Cr03
Sulfurtc Acrd Plus 1 .O% Cr03
Sulfunc
Acid Vapors
Sulfunc
Actd-Nitrtc
Acid
Sulfunc
Acrd-Nrtnc
Acrd
Sulfuric
Acrd-Nitnc
Acid
Sulfuric
Acid-Nitric
Acid
Sulfunc
Acrd-Nitric
Acrd
Sulfuric
Acid-Nrtric
Acrd
Sulfuric
Acid-Nitric
Acrd
Sulfunc
Acid-Nrtnc
Acid
Sulfurous
Acid
Sulfurous
Acrd
Sulfurous
Acid-Partial
lmmersron
Sulfurous
Acrd-Partial
lmmersron

24
24
100
Saturated
68
100
_
_

Boiling
140
Molten

Tannic Acrd
Tartanc Acrd
Tartanc Acrd
Tetrachloroethane
Toluene Sulphone

25
IO-50
10. 25, 50
100
_

212
212
140
Boiling
Room

A
A
A
B
A

Tnchloroacetic
Tnchloroethylene

100
99

C
B

Tnsodium

5. 20

212
Boiling
212

Elevated
Temp. 8 Pres

Room

Borlmg
212
Room
Room

A
A
A
A
_

(water mrxture)
Chlortde

Phosphate

100
_
1. 3
5
15
To 70%
5
30
30
5
30
30
5
30
5
30
96
90-10
70-30
50-50
30-70
1O-90
1O-90
50-50
50-50
6
Saturated
Saturated
Saturated

Urea-Ammonra

X-Ray

Developer

Zinc Chlonde
Zinc Chlonde
Zmc Chlonde
Zinc Sulfate
Zmc

Solution
10
20
Saturated
Saturated
Molten

Room
212
360
365
Room
464
Room
275
140
140
Room
212
200
100
200
200
100
200
200
200
200
200
100-300
Room
Room
Room
Room
Room
140
95
140
Room
375
Room
100

(continued)

rlTANlUM !ISCONIUM TI-PO


- _
A
A
A
A

A
A
_

TANTALUl
A
A
A
A
A

A
A
A
A
B
B
A
B
A

A
A
A
A
A

A
A
A
A
A
0
A
A
A
A
A
0
0
B
A
A
A
A
B
A

A
A
A
A
A
A
A
A
A
A
A

A
A

A
A
A

Nonferrous

TABLE 5.34:

TUNGSTEN,

TANTALUM

AND TITANIUM

CARBIDE

Metals and Alloys

771

ALLOYS-KENNAMETAL

Kennametal hard carbide alloys


grade K602 is a carbide of tantalum and tungsten
with a small amount of binder. It is used success.
fully for applications
in which both corrosion and
wear are exceptionally
severe. The corrosion
resistance of K602 is almost equal to that of platinum,
while its resistance to wear is better than most other
tungsten
carbides.
Compressive
yield strength at
elevated temperatures
is exceptionally
high.
K602 is used successfully in seal rings, including
applications
where the material runs against itself.
Other applications
include nozzles, orifice plates,
bushings, valving parts, mortar and pestle sets. It
has been found to be an ideal material where corrosion resistance and wear life are critical. It is sufficiently nonmagnetic for wear parts in magnetic tape
recorders, particularly
video tape applications.
grade K701 is a tungsten carbide with chromium
cobalt binder. It provides maximum wear resistance,
good to very-good
corrosion
resistance,
and is
stronger than K602. K701 is recommended
where
the higher corrosion resistance of K602 may not be
required, or where more strength is needed than that
provided by K602.
Used for homogenizing
valve parts, K701 is withstanding solid-fluid
dispersion
materials at almost
1000 feet-per-se&ond
in processing such products
as food, paint, and tobacco. It is used in nozzle and
valve parts for handling slurries in refining petrochemicals,
clay, soap, detergents,
and other bulk
products. Other applications
include catalyst compacting dies and wear parts for coal processing.
grade K703 also conralns chromium and cobalt.
It is not quite as resistant to corrosion and wear as
is K701, but it is stronger and more easily fabricated.
It has been used extensively
for pulverizing
coal,
minerals and chemicals.
grade K714 has an excellent combination
of resistance to wear, corrosion and shock. It is easily
fabricated
and lower in cost than either K701 or
K703. It has been applied with particular success in
valving and nozzle applications
where the components are used as sintered or with very little finishing because of cost considerations.
grade K801 is the strongest of the Kennametal
corrosion-wear
grade series, but has less wear resistance than the other grades. It is a hard tungsten

carbide made with a nickel binder instead of cobalt


-the
binder usually found in tungsten
carbides.
K801 was developed for use where other grades are
not sufficiently
corrosion resistant but where conditions may not require the higher corrosion resistance
and correspondingly
higher cost of K602 or K701.
K801 has proved to be a better choice than other
carbides for seal rings and other parts subjected to
moderately corrosive conditions. It provides distinct
advantages where electrolytic
attack of the binder
or etching may occur, such as when immersed in
mineralized or boiler feed water.
In sodium hydroxide and hot sulfuric acid tests,
K801 has shown better corrosion
resistance than
K701. K801 can also be used to advantage in radioactive atmospheres
because the nickel binder has a
much shorter half.life than the cobalt used as a
binding element in most other carbides.
grades K3404, K3406, K3047, K3411 are used
where highhardness and high resistance t0 imPaCt
are primary requirements.
Included in such applications are form crush rolls and hammermills;
also
inserts and tips for bits used to cut and drill Coal,
rock and other minerals.
grades K82, K84, K86 are a gall resisting series
made under the most rigid quality control to accept
the fine surface and polish required. They have fine
grain size, cobalt binder and-due
to the large WTiCZ
content-a
high resistance to pickup
or galling.
Compared to other Kennametal grades, they have
slightly less abrasion resistance, but good strength,
moderate
rigidity and medium thermal expansion
rates. The softer grades have higher cobalt content.
These grades are applied most extensively to tube
and bar drawing operations,
sheet metal drawing,
cupping, deep drawing applications and sizing mandrels. They are used where the slippery
quality
of the tungsten-titanium
carbide, well known in the
metal cutting field, provides properties that are not
available in straight tungsten tarbide grades.
grades K92, K94, K95, K96 are a wear resisting
series, essentially tungsten carbide of fine grain size
with a cobalt binder. The t,ardest grades have the
highest wear resistance and rigidity. When compared
with other Kennametal
grades, thermal expansion
rates are low to medium.

(continued)

772

Corrosion

TABLE

5.34:

Resistant

Materials

TUNGSTEN,

Handbook

TANTALUM

AND TITANIUM

CARBIDE

ALLOYS-KENNAMETAL

(continued)

Kentanium
grade K162B has a nickel-molybdenum
binder
and is the best general purpose Kentanium grade. It
has the greatest resistance to oxidation at temperatures in the 1000 to 1400 F range. It is used in
seal rings and bearings (can run against itself), also
for valve parts, check valve balls and hot flash trimming tools.

Kennametal
grades with the lowest cobalt content
have the highest resistance in hot solutions. For more
severe corrosive conditions the corrosion-wear
series
of Kennametal compositions
has been developed. The
corrosion resistance of grade K602, the carbide of
tantalum and tungsten with a small amount of binder,
is almost equal to that of the noble metals while possessing much greater resistance to wear than these
more expensive metals.
Use of carbides for their corrosion resistance alone
is seldom justified since other materials having this
property are more workable and less costly. However,
when abrasion is involved, the combined corrosionwear resistance of Kennametal or Kentanium will give
far better results.

corrosion resistance of Kennametal and Kentanium is largely determined by the corrosion resistance
of the binder metal since carbides themselves are
nearly inert. At room temperature,
cobalt has corrosion resistance about as good as other commonly
used wear resistant materials. At elevated temperatures, however, it is attacked more rapidly. Therefore,

corrosion-wear resistance of some carbides and metals


The

weight

loss

in milligrams

per

square

tyb?,yzr*

decimeter

50%

per

day

is shown

5%

NaOH

in the

table:

HNO,

5%

HrSOa

grade
22oc

1oooc

22%

100%
I

corrosionwear

WC-TaC-Co K602

0.3

3.1

WC-Co-Cr

0.8
nil

1.8
2.3

K701
K703

series

_
,WC-Ni

structuralwear.
impact series
die and
wear parts

390
928

K714

nil

31.7

364

K801

ml

nil

534

WC-CO

K3047

WC-CO

K96

high temp.
resistance
series
$t+entanium)

Tic-Ni-Mo

498
2310

123

3868

760

53.3 1354

380

21
71

2126

110

10

706

/ d;;;e$- /

95

/ d;;;,$- /

20

0.2 1

106
decom-

-I-113

nil

1 65.4 1 ,$,

posed

123

1661

273

2327

39

232

1231

39

poor

3041

K1626

monel

825

363

nickel

metals

1713

67

125
920

complex
carbide-Co

series

23,500

0.2

35.1

9.5

470

3.4

very

I poor I

16

0.05

poor

Co-Cr.Ni-W
castalloy
*Corrosion
resistance
tests were performed
with
averages
of duplicate
runs. Solution
strengths
new solutions
each day.
**corrosion-wear

l**Kentanium

has

factor

better

corrosion

abrasion

resistance
resistance

ground
samples
were
calculated

factor
than

the

10 i

cobalt

22-C
binder

in a Huey
on a weight
HCI

Corrosion
Tester
for
basis and strengths

seven days.
The
were mamtained

loss.

tungsten

carbides

in salt

solutions.

above
values
by replacing

are
with

Nonferrous Metals and Alloys


TAB1 .E 5.35:

VARIOUS

Nickel

METALS AND ALLOYS-DURIRON

195.0
I

Chlorimet

Chlorimet

il.00

max

17.0-20.0

min

_ ._ _

Bal

130.0-33.0

Bal

17.0-20.0

51

Superchlor
Durco

DC-5

l1.C

1 .OO max

1.00

max

0.07

14.20-14.15

1.50

max

0.70-1.10

3.25-5.00

14.20-14.75

1.50

max

0.75-1.15

Bal

3.25-5.00

14.20-14.75

1.50

max

0.75-1.15

Bal

Duriron
Durichlor

_.

ll.OOmax

Proprietary

Cobalt

Base Shaft

Alloy

0.35

max.

N.0.05

Titanium-Pd

N, 0.05

7ircnnium

N. 0.03 max. H 0.004 mar. 0 0.20 max. Hf 4.5 max

max;
max;

H,O.OlOO

Sleeve

Titanium

H, 0.0100

max;
max;

0,
0,

0.35

max;

Pd. 0.12

min.

max

13.0

max
Bal

0.10

max

0.30

max

0.10

max

0.30

max

0.10 mar

0.30 max

(continued)

773

774

Corrosion Resistant Materials Handbook

TABLE 5.35:

VARIOUS

METALS AND ALLOYS-DURIRON

Brine, acid

PPPPPSPEEEEGEEE

Brine, alkaline

GGEEEEEIEEGGEEEE

(contmued)

Nonferrous

TABLE 5.35:

fhosphmc

VARIOUS

METALS AND ALLOYS-DURIRON

Metals and Alloys

775

kontmutd

acid+2

(continued)

776

TABLE

Corrosion

5.35:

Resistant

VARIOUS

Materials

Handbook

METALS AND ALLOYS-DURIRON

(continued)

Sea water

S[S

Sodium bicarbonate

EIE

E = Excellent-Virtually
unattacked
under all conditions. G = Good-Generally
acceptable with a few limitations.
Suitable under many conditions; not recommended
for remainder. P = Poor-Unsuitable
under all conditions.

S = Satisfactory-

Nonferrous

TABLE 5.36:

VARIOUS

METALS

AND ALLOYS-GENERAL

CORROSION

MEDIA

777

Metals and Alloys

METALS TECHNOLOGIES

DATA-SALTS

I
f
1
1
/
I
/
I
I
I
1

1
/
1
1
1

1
I
t

I
1

I
1

1
I

1
1
1

1
1
I
I
1

I
I
I

(continued)

778

Corrosion

TABLE 5.36:

Resistant

VARIOUS

Materials

METALS

Handbook

AND ALLOYS-GENERAL
CORROSION

METALS

TECHNOLOGIES

(continued)

DATA-SALTS

.
/

.
.

/
,
I
I
I
I

.
.
.
.
.

I
/
/

e
/

I
/
I

A-Fully
resatant
B-Slightly
attacked
C-Unratisfactorv

&Sublect
to pbttmg at air line or when allowed
=--Keep
solution alkalme
t t -May
attack when wlphurlc
acid is present

to dry

t-May
attack when hydrochloric
acid 8s present
o-Tlll.CO.3ted
-Not
recommended
for use with beverages

(continued)

lLlWOW~

WCCIWS
W,WS

9lC Idols
na,uw,s
bOC I~W
%,l,WS
llOlij
O,l,lS

001 IPlW

QQ******

*urn

*********
4

41

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4.4~
m

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a**

**a

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**o

**v

Q*44*4***

zz
****.I

44

mmm

*QQQQQ

**

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440

*****

4Q

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4Q.Q

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zrn$m

:.:mm

tjmtjm

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9:

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zYj:z

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0

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z,$

v.amrn~~v~*vv*

zm.. z

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mmmLDIDu*

yg~#y*

Q*QO*Q*Q

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008 ~OIO~UI

**~Q*mI.

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l ****

***m**m~(D

1 ; 1:

addog

c 9302 on
mmdq

an,e,url

wn,un(~

7::
-0.

,.

*
*,>>n

gg>g;

kg

no,

*>>*n

.>>>

gg*

**>>>>*>>>>

gig,

>>>*>*>.>>

**;..>>

ng

>>>>>n

>>>O>>

mo>>g

>>>:g:m :>g>n
n::

DD

n>*>>

**>>>>

*>>>>
DD

>>>>

>>>>>D>>.>

~:>>~Dnff

o**mnmo~~>>*n~cmD>o

>.>>>>>>.>>>>>>.>n>,>>>>D>*>***>>>DD>>D>D

ID

>>

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D,

>>>*>*>**>

>>>>nn*

>~>n>>

>I0

n>nm

"D~brn,

on

~n>nnDnDn>~D.n

C
HlldlO

Mod

Incontl

4w

Km

Incolo 025

Incolo 000

nutllloy

Nttkd

CVO

Tll,llT

Nonferrous Metals and Alloys

TABLE 5.37:

VARIOUS

781

METALS AND ALLOYS-WALWORTH

In an effort to be specific, first and alternate choices are designated in the following table for each solution listed.
In making the first choice, consideration was given to such factors as corrosion resistance, material availability and
economy. An alternate
choice material is listed for most solutions.
The alternate choice in most cases is equal in
corrosion resistance to the first choice material, but is usually more costly.

Corrosive

First
Medium

Acetic Acid
In cont. to 100%
In cont. to 100%
In cont. to 60%
60% to 100%

Acitii /Anhydride
00

100%
Acetone
Acetyl Chloride
Acid Mixtures
50% HN03-50%
H2S04
50% HNO,-50%
H,SO,
50% HNO,-50%
H,SO,
25% HNOJ-75%
H,SO,
25% HNO,-75%
H,SO,
10% HN03-70%
H,SO,
10% HNO,-70%
H SO,
5% HN03-30%
H,$O,
5% HNO,-30%
H,SO,
5% HNO-15%
H,SO,
5% HNO,-15%
H,SO,
90% Acetic-Z%
H,SO,
Acid & Salt Mixtures
Fuming HNO,-10%
KNO,
Fuming HNO$-10% AI(NO&
10% H,SO,-10%
CuSO,
10% H,SO,-2%
Fe,(SO,),
Acid Mine Water
Aerorine-50
Alcohol
Ethyl
Methanol
Alkylation-Sulfuric
Acid
Aluminum Acetate
All Concentrations
All Concentrations
Aluminum Chloride
All Concentrations
10%
All Concentrations
Aluminum Fluoride-20%
Aluminum Hydroxide
Saturated
10%
Aluminum Sulfate
In cont. to 50%
Saturated
Aluminum Chrome Sulfate-S%

Temp F

Choice

150
200
Boiling
Boiling

18-8s
18-8SMo
18-8SMo
A-20

18-8SMo
A-20
A-20

175
244
Boiling
Boiling

18-8SMo
N-3
18-8s
A-20

A-20

140

18-8SMo
A-20

::

18-8s
18-8SMo
A-20
18-8SMo
A-20
18-8s
A-20
18-8SMo
A-20
18-8SMo
A-20
18-8SMo

Boiling
Boiling
Boiling
Boiling
70
100

;;I;;
18-8SMo
A-20
18-8SMo
18-8s

$1;;;;
A-20

212
212
100

18-8SMo
18-8SMo
A-20

A-20
A-20

160
212

18-8s
18-&MO

18-8SMo
A-20

;:oo
200
250
140
Boiling
140
230
200

1::
300
160

2::
212
212
70

Alternate

18-8SMo

A-20
18-8SMo
A-20
A-20
A-20

A-20

A-20
A-20
N-2
Nickel
A-20
A-20
18-8SMa A-20
A-20
18-8SMa A-20

Corrosive

Medium

Alum
(Potassium Aluminum Sulfate)
10%
All Concentrations
Digestion of Bauxite in H,SO,
to make Alum
Ammonium Bicarbonate
In cont. to 90%
Ammonium Carbonate
All Concentrations
Ammonium Chloride
(Sal Ammoniac)
In cont. to 50%
In cont. to 50%
In cont. to 100%
Ammonium Chlorostannate
(Saturated)
Ammonium Hydroxide
Amgm30/ni;m9~/trate_Neutral
00
00
Ammoniated Ammonium Nitrate
Ammonium Oxalate
In cont. to 30%
Ammonium Perchlorate
In cont. to 10%
In cont. to 40%
Ammonium Persulfate
In cont. to 30%
Ammonium Phosphate
In cont. to 30%
Ammonium Sulfate
In cont. to 10%
In cont. to 50%
Saturated
Plus free H,SO,
Ammonium Sulfite
In cont. to 50%
Ammonium Bisulfite
(Sulfite Cooking Liquor)
Ammonium Thiocyanate
In cont. to 50%
Amyl Alcohol-SO%
Amyl Mercaptan
Aniline-Cone.
Aniline & Ferric Chloride
Arsenic Acid
In cont. to 30%
In cont. to 100%

Temp F

First
Choice

Alternate

18-8SMo
A-20

A-20

A-20
18-8s

18-8SMo

18-8s

18-8SMo

1::
212

18-8SMo
A-20
Monel

A-20
Monel
Nickel

70
212

18-8SMo
18-8s

A-20
18-8SMo

212
160

18-8s
18-8SMo

18-8SMo
A-20

200

18-8s

18-8SMo

200
200

18-8s
N-3

18-8SMo

200

18-8SMo

A-20

200

18-8s

18-8SMo

212
160
212
150

;I;;

212

18-8SMo

A-20

280

18-8SMo

A-20

175
350
300
200
650

18-8s
A-20
A-20
18-8SMo
N-3

18-8SMo

A-20
N-2

(continued)

782
TABLE

Corrosion Resistant Materials Handbook


5.37:

Corrosive

VARIOUS

Medium

Barium Carbonate
All Concentrations
10%
Barium Chloride
$/Concentrations
00
Barium Nitrate-All
Concentrations
Ba$y
Sulfate
CoiEentrated
Benzene (Benzol)
Benzene Sulfonic Acid-go%
Benzoic Acid
In cont. to 100%
100%
Black Liquor (Sulfate Pulping)
In cont. to 75% Solids
Borax-5%
Boric Acid
In cont. to 50%
In cont. to 100%
Boron Trifluoride-100%
Bromine
Wet Gas
Dry (Gas or Liquid)
Butyric Acid
In cont. to 5%
In cont. to 25%
In cont. to 100%
Carbonic Acid-In
cont. to 100%
Calcium Bisulfite
(Sulfite Cooking Liquor)
Cadmium Sulfate-30%
Calcium Chlorate
In cont. to 10%
In cont. to 30%
In cont. to 100%
Calcium Chloride
In cont. to 80%
In cont. to 100%
Calcium Hydroxide
In cont. to 50%
ca!lc~~. f!fy~~~if/~~fi~Chlorine
In cont. to 40 g.p.1. available
Chlorine
Ca;b;n Tetrachloride
Plus H,O
Cellulose Acetate
Chloroacetic
AcidIn cont. to 100%
Chlorobenzene-Concentrated
Chloroform-Concentrated
Chlorine Dioxide
Solution from
absorbers to bleach
Solution from neutralizer
Chlorine Trifluoride
Chlorine Gas-moist,
saturated
Chlorosulfonic
Acid-99.5%

METALS

AND

ALLOYS-WALWORTH

emp

First
Choice

Lltemate

70
!12

18-8s
18-8s

18-8SMo
18-8SMo
A-20

70
!12
!12

18-8s

18-8SMo

!12
!12
!12
175

18-8s
A-20
18-8s
A-20

18-8SMo

!12
100

18-8SMo

;;I;;;;

340
!12

18-8SMc
18-8s

A-20
18-8SMo

)OO
L25
350

18-8s
18-8s
18-8s

18-8SMo
18-8SMo
18-8SMo

!12
125

N-3
Monel

Nickel

150
too
!65

18-8s
A-20
N-3

18-8SMo

212

18-8s

18-8SMo

300
212

18-8SM(
18-8s

A-20
18-8SMo

212
212
212

18-8SMr
A-20
N-3

A-20

125
180

18-8SM(
A-20

A-20

212

18-8SMI

A-20

70

18dSMI

A-20

125

N-3

200
200
150

18-8SMI
A-20
18-8SMI
N-3
18-8SM1
18-8s

317
A-20
Monel
N-3
18-8s

A-20
A-20

A-20
18-8SMo

A-20

(continued)

Corrosive

remp F

Medium

Chromic Acid
5%
In cont. to 50%
Citric Acid
In cont. to 50%
All concentrations
Coca Cola Syrup
Coffee
Copper ChlorideIn cont. to 100%
Copper Cyanide-In
cont. to
Saturated
Copper Nitrate-In
cont. to
Saturated
Copper Sulfate
In cont. to saturated
Plus 10% H,SO,
Creosote
Cresylic Acid
Cyanogen Gas
Dichloroethane
Diethanolamine
Dinitrochlorobenzene
Melted and Solidified
Distilling
Wort
Dyewood Liquor
Epsom Salt (MgSO,)-In
to saturated
Ether
Ethylene Chloride, dry
Ethyl Acetate, cont.
Eth&Chloride

cont.

10%
Fatty Acids (Tall Oil Distillation)
High Rosin Acids--over
50%
High Fatty Acids-over
60%
Ferric Chloride18% (HCI-24.7%)
Ferric Nitrate
In cont. to 100%
In cont. to 100%
Ferric Sulfate
10%
In cont. to 100%
In cont. to 100%
Fluorine-Dry
Formaldehyde
In cont. to 100%
In cont. to 100%
Formic Acid
In cont. to 100%
In cont. to 100%
Fruit Juices
Furfural-In
cont. to 100%

First
Choice

Rlternate

18-8SMo

1::

;;;
70
300
70

A-20

t8zMo
L8-8s
18-8s

18-8SMo
18-8SMo

Y-3

212

18-8s

18-8SMo

212

18-8s

18-8SMo

212
150
200
350
70

18z?Mo
18-8s
1-20
18-8s

212
212

18-8s
18-8SMo

18-8SMo
18-8s

70
212

18-8s
18-8s
18-8s

18-8SMo
18-8SMo
18-8SMo

212
70
70
200

18-8s
18-8s
18-8s
18-8s

18-8SMo
18-8SMo
18-8SMo
18-8SMo

600
175

18-8s
4-20

18-8SMo

A-20
18-8SMo
18-8SMo

:!PMo

A-20
N-3

700

N-3

N-2

125
212

18-8s
A-20

18-8SMo

212

18-8SMa

A-20

1;:
800

18-8SMa A-20
A-20
Nickel

Monel

125
212

18-8SMc
A-20

125
212
212
212

18-8SMr
A-20
18-8s
18-8s

A-20

212
140

18-8s
18-8SM(

18-8SMo
A-20

18-8SMo
18-8SMo

Nickel
18-8SMo

Gallic Acid-In
cont.
Glue (Acid Solutions)

to 100%

(continued)

Nonferrous

TABLE

5.37:

Corrosive

VARIOUS

Medium

Hydrazine
Hydrobromic AcidIn cow. to 50%
Hydrochloric
AcidIn cont. to 37%
Hydrocyanic Acid
Hydrofluoric
Acid
In cont. to anhydrous (Air free)
In cont. 90% to Anhydrous
Hydrogen Fluoride-Gas
Hydrogen Peroxide
In cont. to 90%
Hydrogen Sulfide
OrY
Wet
lodoform
Ink
IsomerizationButane (HCI & AIC13)
Kraft Mill Solutions
Black Liquor
In cont. to 75% solids
White Liquor
Green Liquor
Lactic Acid
In cont. to
In cont. to
Lard
Lead Nitrate
In cont. to
In cont. to
Linseed Oil
Plus H2S04

100%
100%

100%
60%

METALS

AND

ALLOYS-WALWORTH

Temp F

First
Choice

125

18-8s

200

N-2

212
125

N-2
18-8SMo

A-20

:;i
500

Monel
A-20
Monel

Nickel

150

18-8s

18-8SMo

900
125

18-8s
18.8SMo

18.8SMo
A-20

70

18.8SMo
18-8SMo

A-20
A-20

100

Alternate

N-2

340
300
260

18-8SMo
18-8SMo
18-8SMo

A-20
A-20
A-20

160
212
Hot

18-8SMo
A-20
18-8s

A-20

3;;

18-8s
18-8SMo
18-8s
A-20

18-8SMo
A-20
18-8SMo

1::
300

18-8SMo
A-20
Nickel

A-20

212
70

18-8s
18-8s

18-8SMo
18-8SMo

2;;

18-8SMo

Magnesium Chloride
In cont. to 5%
In cont. to 50%
In cont. to 40%
Magnesium Nitrate
In cont. to 10%
In cont. to 100%
Magnesium Sulfate
In cont. to 100%
Maleic Acid
Maleic Anhydride
Methyl Chloride-Dry
Mayonnaise
Methylene Chloride-Dry
Milk
Mineral Oil
Monochloroacetic
Acid-70%
Monoethanolamine
In cont. to 100%
Mustard

212
212
350
212
70
212
212
300
120

18-8SMo
18-8SMo
18-8SMo
18-8s
18-8s
18-8s
18-8s
18-8s
N-3

A-20
A-20
A-20
18-8SMo
18-8SMo
18-8SMo
18-8SMo
18-8SMo
A-20

212
70

18-8s
18-8SMo

18-8SMo
A-20

Nickel Sulfate-In
cont. to 100%
Nicotine Sulfate-8%
to 15%

212
200

18-8SMo
18-8SMo

A-20
A-20

N-2

Metals and Alloys

783

(continued)

Corrosive

Medium

Nitric Acid
In cont. to 80%
In cont. to 65%
50 to 85%
Fuming-86%
and Higher
Nltro Cellulose
Nitrogen Tetroxide
Nitrous Acid-All
cont.
Oleic Acid

Oxalic Acid
In cont. to 90%
All Cont.
Paraffin
Pentaborane
Petroleum Ether
Phenol (Carbolic Acid)
C.P. or crude
Vapors
Phosphoric Acid
In cont. to 60%
60 to 85%-Aerated
In cont. to 85%-Air
Free
85% to 100% Air Free
Photographic
Developer
Phthalic Acid
Phthalic Anhydride
Picric Acid-In
cont. to 100%
Propionic Acid-66%
Propyl Acetate
Polyvinyl Acetate, 2% H*SO
Potassium Bicarbonate
In cont. to 100%
In cont. to 40%
Potassium Carbonate
In cont. to 100%
In cont. to 60%
Potassium Chlorate
In cont. to 100%
In cont. to 30%
Potassium Chloride
Quiescent-5%
Aerated-20%
Saturated
Potassium Dichromate
In cont. to 60%
In cont. to 100%
Potassium Ferricyanide
In cow. to 100%
In cont. to 60%
Potassium Ferrocyanide
In cont. to 30%
In cont. to 90%
Potassium Hydroxide

Potassium NitrateIn cont. to 100%

Temp -F

First
Choice

Alternate

125
212
150
110
70
100
70

18-8s
18-8s
A-20
A-20
18-8s
18-8s
18-8s

70
400
600

18-8s
18-8SMo
A-20

18-8SMo
A-20

2:;

18-8s
A-20

18.8SMo

18-8s
18-8s
18-8s

18-8SMo

Hot
70

18-8SMo
18-8SMo

18-8SMo
18-8SMo
18-8SMo

18-8SMo

360
700

18-8s
A-20

200
200
200
275
70
360
285
212
300
192
150

;;:;g$~ A-20
A-20

160
150
212

I iYMo

A-20
N-2
18-8SMo
18-8SMo
18-8SMo
18-8s
A-20
18-8s
18-8SMo

A-20
A-20
A-20
18-8SMo
N-3
18-8SMo
A-20

18-8s
18-8SMo

18-8SMo
A-20

18-8s
18-8s

18-8SMo
18-8SMo

18-8SMo
18-8SMo

A-20
A-20

A-20
A-20
Monel

Monel
Monel

212
70

N-2

18-8SMo
18-8SMo

2;:

18-8s
18-8SMo

18-8SMo
A-20

200
200

18-8s
A-20

18-8SMo

200
250

18-8SMo
Nickel

::z

18-8s
A-20
Nickel
Nickel

212

18-8s

18-8SMo

lnconel

(continued)

784

Corrosion Resistant Materials Handbook

TABLE 5.37:

VARIOUS

METALS

Corrosive Medium

AND ALLOYS-WALWORTH

Temp F

Potassium Oxalate
In cont. to 100%
In cont. to 40%
Potassium Sulfate
In cont. to 100%
In cont. to 20%
Pyrogallic Acid
In cont. to 100%
In cont. to 60%
Rayon Spin Bath
i7to, lp;oH,SO,
Ov 2 .
Sea Water
Selenious Acid-In cont. to 30%
Silver Nitrate
In cont. to 100%
In cont. to 70%
Sodium Bmarbonate
In cont. to 100%
In cont. to 40%
Sodium Carbonate
All concentrations
In cont. to 50%
All concentrations
Sodium Chlorate
In cont. to 100%
In cont. to 70%
Sodium Chloride
Puiescent-5%
Aerated-20%
Saturated
Sodmm Hydrosulfide-65
to 68%
Sodium Hydroxide
t2Cga;stic Soda)

18-8s
18-8s

18-8SMo
18-8SMo

18-8s
18-8SMo

IS-8SMo
A-20

18-8s
A-20

18-8SMo

;I;0
A-20
18-8s

18-8s
18-8s

18-8SMo
18-8SMo

18-8s
18-8SMo
A-20

18-8SMo
A-20

18-8SMo
18-8SMo

A-20
A-20

2::

;:;x

160
175
212
176

!4o,nn:t

Monel
18-8s

18-8SMo

18-8s
A-20
Nickel
Nickel

18-8SMo
Nickel

18-8SMo

A-20

lnconel

N-3

iOO% Molten
Sodium Sulfate
In cont. to 30%
Concentrated
Sodium Sulfide
In cont. to 100%
In cont. to 50%
So&+ Sulfite

~ 70
1 200
175
200

300;
Spirits of Wine
Starch Solution

18-8s
18-8s

18-8SMo
18-8SMo

18-8SMo
18-8SMo

A-20
A-20

18-8SMo
A-20

~A-20

18-8s
A-20
18-8s
18-8s

100

18-8SMo

I 18-8Shlo
~ 18-8SMo

Aloyco 18-8s Stainless Steel


ASTM A351 Grade CF8

Sulfur
bdicon

.._...

..

percent
0.08 Max.
1 SO Max.
0.04

Max.

.........

0.04

Max.

..........

2.00

Max.

..........
.

400
130

18-8s
18-8s

200
575

18-8SMo
18-8s

A-20
18-8SMo

300
300
200

18-8SMo
A-20
Nickel

A-20

125
200
175
150

KY?
90;
Oleum
Sulfurous Acid
All Concentrations
All Concentratfons
Tall Oil
Tannic Acid
Tanning Liquor
Ta;t,arJc Acid
50:
Trisodium Phosphate-20%
Turpentine
Unsymmetrical
Dimethyl Hydrazine
Urea
Vegetable Juices
Vmegar
Water, High Purity
Zin;2Qnwrium

Chloride-

Zmc Chloride
In cont. to 70%
In cone. to 90%
In cont. to 50%
All cont. to 100%
Zinc Cyanide-Moist
Zinc Nitrate, 10%
Zinqo~lfate

18-8SMo

I 18-8SMo

Monel

;:;;
A-20
A-20
A-20
A-20
A-20
A-20
N-3
N-2
N-2
N-2
N-2
A-20

300
150

A-20
18-8SMo

A-20

525
150

18-8SMo
18-8SMo
18-8s

A-20
18-8SMo

212
212
175

18-8s
18-8SMo
18-8s
18-8s

18-8SMo
A-20
18-8SMo
18-8SMo

140
260

18-8s
18-8SMo

212
150

18-8SMo
18-8s

750

18-8s

A-20
18-8SMo
18-8SMo

180

N-3

A-20

18-8SMo
A-20
Monel
N-2
18-8s
18-8s

A-20

18-8SMo
18-8SMo

A-20
A-20

1::
:t;
70
175

Satirated

N-2
18-8SMo
18-8SMo

Aloyco 18-8s ELC Stainless Steel


ASTM A351 Grade CF3
..........
..........
..........

Chromum
Nickel

Temp F

Stearic Acid-Cone.
Sugar & Sugar Solutions
Sulfonic Acrd
Sulfur Oioxide
Gas, Moist
Gas, Dry
Sulfur, Molten
Ory
Plus Moisture
Sulfur Monochloride (plus CCI,)
Sulfuric Acid
All Concentrations
5%
iO%

18-8s
A-20

50;
75%
100%
Sodium Hypochlorite
3 g.p.1. Available Chlorine
In cont. to 40 g.p.1.
available Chlorine
Soikiu; Nitrate

Chemlcrl Requlrementr
Carbon . . . .._.............
Manganese
. . .
Phosphorus

Corrosive Medium

Alternate

2:;

150
190
160
212

(continued)

..........

18.00
8.00

to 21.00
to

11.oo

Chemical Requlromento
Carbon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .._..._....
Manganese . . . . . . . . . . . . . . . . . . . . . . . . . .._........._
Phosphorus . . . . . . . . . . . . . . . . . . . . . . . . . . . . .._..._..
Sulfur . . . . . . . . . . . . . . .._.........._...............
Silicon . . . . . . . .._.................._.........._._
Chromium
.. . .
. .
.._
Nickel

. ............

........ ....

...

percent
0.03 Max.
1SO Max.
0.04 Max.
0.04 Max.
2.00 Max.
17.00 to 21.00
8.00

to 12.00

(continued)

Nonferrous Metals and Alloys

TABLE 5.37:

VARIOUS

METALS

AND ALLOYS-WALWORTH

Aloyco 18.8SMo Stainless Steel ASTM A351 Grade CFEM


Chemlcel Aequlrementr
Carbon..

percent

........................................

0.06 Max.

Manganese ......................................
Phosphorus ....................................

1.50 Max.
0.040 Max.

Sulfur ...........................................
S&con ..........................................
Chromrum .......................................

0.040 Max.
1.50 Max.
16.00 lo 21.00

Nrckel ..........................................

9.00 to 12.00

....................................

Molybdenum

Aloyco 18-8SMo ELC Stainless


ASTM A351 Grade CF3M

2.00 to 3.00

Steel

0.04 Max.

0.04Max.
1.50 Max.

Chromium .....................................
Nrckel ...........................................

..17.~lO

21.00

9.Wlo13.W

.....................................

2.00 IO 3.00

Aloyco 18-8 SCb Stainless Steel


ASTM A351 Grade CFEC
petcent
0.06 Max.

....................................

Sullur ...........................................
Srhcon .......................................
Chromrum

.............................
....

Molybdenum
Manganese

Remamder

................................
.................................

26.0 lo 30.0
1.O Max.
1.O Max

Srhcon .....................................
Iron ........................................

4.0 to 6.0

...................................

Vanadium ................................
Chromium ..................................

.6

Cast Nickel-Molybdenum-Chromium
Atoyco N-3

0 12 Max.
0 20 IO 0.60
1.W Max.

Carbon Mm -

Chemical Requlremenle

percent

Manganese
Phosphorus
................................
Sullur .......................................

15 5 IO 17.5
3 75 IO 5.25
4.5 IO 7.5
1.O Max

Vanadrum

Manganese

Carbon

................................

16.0 to 16.0

1.O Max.

.................................
.....................................

0.20 to 0 40
0.12 Max.

12.0.

1.0 Max.

Nickel-Chromium-Iron
Aloyco lnconel

Alloy

ASTM A744lA494 Grade CY-40


Chemlcel Requlramanlr

percent

0.04 Man.

Nickel ......................................

0.64 Max.

Chromium ..................................

1.50 Max.

Carbon

19.0 to 22.0
27.5 lo 30.5

NIckeI ...........................................
Molybdenum ....................................
Copper.. ........................................

Chromium.. ................................
Molybdenum ................................

2.00 Max

1.50 Max.

S~lrcon ..........................................
Chromium .......................................

Remainder

Sihcon .....................................

pwcont
0.07 Max.

..........................
...............................

Alloy

ASTM A944 Grade CW-12M


ASTM A494 Grade CW-12M-1

1SO Max.

9010

Chemlcel Requlrementr
Carbon

percanl

Chemlcel Requlrementr
Nrckel ......................................

0.04 Max.
0.04 Max.

ASTM A351 Grade CN-7M

20

ASTM A744 Grade N-12M


ASTM A494 Grade N-12M-1

Tungsten ...................................
Iron ........................................

16.00 IO 21.0

Nickel ..................
Columbrum ........
AIC~CC

Alloy

Nickel ......................................

Chemical Requlremenlr
Carbon .........................................
Manganese ......................................
Phosphorus

Cast Nickel-Molybdenum
Aloyco N-2

1 SO Max.

Phosphorus .....................................
Sullur ...........................................
Srlicon ..........................................

Molybdenum

(continued)

Carbon..
percent
0.03 Max.

Chemlcel Requlfementa
Carbon ..........................................
Manganese ......................................

785

2.0 IO 3.0
3.0 IO 4.0

.....................................

Remamcler
14.0 to 17.0
0.40 Max.

Iron ........................................

11 .O Max.

Manganese .................................
Silicon .....................................

3.00 Max.

1.56 Max.

Tenelle Requlremantr
AI~YCC

CD-~

ASTM A351 Grade CD4MCu

Chemicel Requirements
Carbon .........................................
Manganese ...................................
Srhcon .........................................
Sulfur ..........................................
........................
Phosphorus ......

Copper

Nickel

1.OOMax.
0 04 Max
0 04 Max.

...

Nickel
Molybdenum

..........................
............................
ASTM A744lA494

Srlicon ..........................................
Carbon.. ........................................
Manganese

......................................

Iron .............................................
Copper ..........................................
Nrckel ...........................................

24.510 26.5
4 75 to 6.00
1.75 IO 2.25
2.75 to 3.25

Grade C&l00

Chemlcel Requlrementa

........................

Yreld Stranglh. psi ..........................


Elongabon. percenl in z ....................

70000 Mm.
26000 Mm.
30 Mm.

1.00 Max.

.....................

Chromwm

Tensrle Slranglh. psi


percent
0.04 Max.

perconl
2.00 Max.
1.00 Max.
1.50 Max.
3.00 Max.
1.25 Max.
95.0 Min.

NIckelCopper
Alloy
Aloyco Monel
ASTM A744lA494 Grade M-35
percant

Chamlcel Roqulramenle
Nrckel ......................................
copper .....................................
Srlicon .....................................
Iron ........................................
Manganese .................................
Carbon .....................................
Tenrlle Requlremente
Tensile Slrength. psr ........................
Yreld SlrengIh. psi ..........................
Elongabon. percenl in 2

....................

Remainder
26.0 lo 33.0
2.00 Max.
3.56 Max.
.50 Max.
0.35 Max.

65000 Min.
3OooO Mm.
25 Mtn.

Glass, Ceramics, and Carbon-Graphite

TABLE

6.1:

CARBON-GRAPHITE-U.S.

GRAPHITE

787

(contmuedJ

GRAPHITAR SEAL GRADES

GRAPHITAR

TYPICAL APPLICATIONS

GRADE

Grade 30A

For low to medium pressure oil sealing applications. This grade has relatively high porosity, which aids seal face lubrication.

Grade 38

For low to medium pressure applications.


economical in many applications.

Grade 39

A universal grade for use in high pressure applications. Can be used to seal almost any
medium except very strong oxidizing or alkaline agents. Grade 39 is the hardest of all
GRAPHITAR grades, with a scleroscope reading of 105.

Grade 38 is relatively easy to mold and is most

Grade 67

Similar to grade 30A in low to medium

Grade 70

Similar in many respects to grade 38, this grade will also perform well in non-lubricated
service such as sealing air.

Grade 86

A universal grade for lubricated or non-lubricated service. Grade 86 offers excellent


compressive strength, an extremely low porosity and excellent wear resistance.

Grade 114

A very strong, hard grade which is resistant to any chemical


function
at all. Frequently
used in sealing gasses.

Grade 2690

A high temperature
material
for seal applications
which exceed
used almost exclusively for sealing high temperature gasses.

Grade 3048

Superior for aircraft engine main shaft seals.


oxidation resistance for long service life.

Graphitar

Grades

2
64
3
67
18 75
30A 80
34 84
48 110
2413

14
35
38
39
40
47
70

by Chemical

compatibility

77
86
88
89
92
94
95
108

101
102
103
105
107
109

2831
2832
2833
2835
2837
2859
2887
2957
3030

category.
F

2767
2840
2864
2865

2690

2866
2936
2980
3648

111
112
113
114

pressure applications.

Combines

in which

excellent

GRAPHITAA

700F.

Grade

can
2690

is

lubricity with good

Resistance
to chemical
attack
varies among the
GRAPHITAR
Grades because of formulation
and
processing
differences.
While each Grade was developed to meet specific physical requirements,
the
differences
do produce chemical effects. The following chart provides a guide to the selection of the appropriate
GRAPHITAR
Grades. They can be grouped
into six chemical compatibility
categories-see
chart
at left.

GRAPHITAR COMPATIBILITY CHART


Chomiul

ACIDS
Abrehc

Aceltc
Acehc Anlrydrlde

Acel~lsal~cyl~c
Adrplc
Aqua Reds3
AlWll~
Ascorbic
Battery
Ben~enrullomc

Benzorc
BoderActid Phosphates
8or1c

EU~IIC

Carbohc

ABCD-f
ABDAB.D
ABCD-f
ABCDABCDABCD
ABD.
ABCDABCDABCD.F
ABCD.
ABCD-f

f
F
f
f

f
f
f
f
f

Carbomc
Chloro?e Anhydrous Llquld
Chlorlc
Chloroos
Chloroacehc
Chlorosultorhc
Chromic
Cllrlc
Cresyhc
Cyanlc
f ally Acids
flooborlc
FlUOSlllClC
formIt

Crrphitrr
C&gory
Su~crtrd

Craphitar
Cstr8ory
Se~Slsd
ABABAB-.

D-f
D-f
-f

Ai:

b: f

AE-

D-f

kiib.

f
f

ABCD.f
ABD-F
ABCDf

ii::::
ABCD-f

Galhc
Glulamlc
Hydrobromlc
Hydrochloric
Hydrocyamc
Hydrolluorlc
Hvdrotluos~hc~c
Hidrogen PeroxIde
Hywchlorous
Isophlhal~
La&
Lauw
Malelc
Mahc
Muriahc

ABCDABCDABD.
AB.
D.
A8.
D-

;i::.F
AB:
D.
ABCD.
ABCD.
AB.
DAB
D
A8.D
(continued)

f
f
f
f
f

F
f
f
f
f
f
f
f

788

Corrosion Resistant Materials Handbook

TABLE 6.1:

CARBON-GRAPHITE-U.S.
Crrphitrr
Catqory
Suggerled

Chrmical
Nrlrahng To 7Sp;,
Nrrrrc 0 to ZOZ;
Nrtrrc 20 to 100%
Nitrous
Olerc
Oleum
Orlhophosphorrc
Organrc Acrds
Oxalrc
Palmrhc
Perchlorlc
Phenolsulfonrc
PhOsphorK Glrcral
Phthahc
Prcrrc
Propronrc
Pyrofialhc
Sahcyhc
Sorbrc
Slearrc
Succmrc
Sulphurrc 0 15%
Sulphurrc 15 96x,
Sullurour
lannrc
Tarlarrc
Terephlhahc
Toluenesultomc
TOIUIC
Trrchloroacelrc
urrc
Valerrc
Vrnyl Acetate

ALKALINE

(continued)

Chemical

Craplitrr
Category
sugpslod

SALT SOLUTIONS

ABD.
AB.
D.
ABCDABCD-f
ABAB.
ABABAB.
AD.
AB-

D-f
D.
DDD-f
D.
D-f

F
f
f

F
f
F
F

;t;;::
AB.
D-f
ABD. f
A.
_.
.f
E&:
ABCD
AB
AB
AB
AB
AB
AB
AB

D
D
DD
D
D
D

f
F
f
f
f
f
f
f

CHEMICALS

Ammonrum Carbonale
Ammomum Hydrorrde
Amyl AmInesAnhydrous Ammonra Lrqurd
Barrum Hydroxrde
Bleachmg Powder
Bulyl Ammes
Calcrum Carbonate
Calcwm Hydroxrde
Calcrum Hypochlorrle
Calcrum Oxrde
Causbc Soda
Cycloherylamme
Delernenls
Orethanol Amrne
Drsodrum Phosphale
Hydrazme
Hydroxylamme
Lame Slurrres
Lrlhnrm Carbonate
Ldhrum Hydroxrde
Lye
Magnesrurn Hydroxrde
Monoelhanolamrne
Morpholme
Potassrum Brcarbonale
Polassnrm Carbonate
Polassrum Chlorate
Polassrum Cvanrde
Polassrum Hydroxrde
Polassrum Phosphate
Pyrrdme
Soap 8 Soap Solubons
Sodrum &carbonate
Sodrum Carbonale
Sodnrm Hydroarde
Sodrum Hypochlorrle
Sodrum Perorrde
Sodrum Phosphate
Sodnrm Telraborale
Telramrne C
Trrelhanotamrne
Trrelhvlamme
Trrsodrum Phosphale
Urea
Waler Glass

GRAPHITE

AB
AB
AB-D
A
AB

D
D
DD-f
D

AB-D
AB
AB
-D
Aft
ABAB
AB.

D
D.
D-f
D
D
D-f
D
D.

f
f
f
f
f
f
f
f
F
f
f
f
f

AB-

D.

AB
AB-D
AB
ABAB--D-f
AB.0

:
f
f

ADABABCDAB
AB-

D.
D-I

D
D-F
D- f

b.
DDD.

F
f
F
f
F

t
f

-.D.f
AD:
Aft.
ABABAEABAB
AB.

D:
D.
D.
D.
D.
D.
D
D-f

f
f
f
f
f
f
f

Alkylaryl Sullonales
Ally1 Chlorrde
Alum r Ammonra I
Alum rChromer
Alum t Polash I
4lumlnum
Chloride
4lummum Sullale
Ammoncurr Brcarbonate
Ammonrum Carbonate
Ammonrum Chlorrde
Ammonwm Nrtrate
Ammonrum Phosphate
Ammonnrm Sullale
Ammomum fhrocyanale
Arsenrc frrchlorrde
Bakmg Soda
Barurm Carbonate
Barnrm Chloride
Barrum Suttate
Barrum Sullrde
Borax
Boner Feed Waler Compou
Calcwn Brsulhte
Calcrum Chlorrde
Calrrum Sullale
Calgon
Chromwm Potassrum Surlale
Copper Chlorrde
Copper Nrtrate
Copper Sullale
FemC
Chlorrde
Ferric
Sullale
ferrous Chloride
ferrous Sulfate
Clauber s Salt
Ink
Lead Acetate
Lead Carbonate
Lead Nrlrale
Lrlhrum Carbonate
Mapnesrum Chlorrde
Magnesnrm Oxrde
Magnesrum Sulrate
Manganous Sullale
Mercury Salts
Nrchel Acetate
krchel Chlorrde
Nrckel Nrlrale
Nrcher Sullale
Nylon Salt
Phosphorus Trrchlorrde
Polassrum Brsullrde
Polassrum Carbonale
Polassrum Chlorrde
Polassrum Chromale
Polassrum Cyanrde
Potasstum lodrde
Polassrum Permanganale
Polassrum Phosphates
Polassrum Sultale
Sal Ammonrac
Sal Soda
Sea Waler
Sdver Nrtrale
Soda Ash
Sodurrn Alummale
Sodrum Acrd Sullale
Sodrum Brcarbonale
Sodrum Brsullale
Sodrum B6ulhle
Sodrum Borate
Sodnrm Carbonate
Sodrum Chlorrde
Sodrum Chromate
Sodrurn Cyanrde
Sodrum Drchromale
Sodrum fluorrde
Sodrum Ndrale
Sodrum Nrlrrle

ABCD
AB
AB-D
AB
AB
AB.
AB.
ABAB.
AB
ABABAB.
ABABAB.
AB.D
ABAB-D
AB.
AB.D
ABCD-f
AB.D
AB.
AB.
ABCDABABAB.
AB.
AB.
ABAB.
AB
AB.

DD
D
D.
D.
0.
0.
D.f
D.
D-f
D.
D.
D.
D.
DD-f

F
f
f
f
f
F
f
f
f
f
f
f
f
f
f
f
f
f

0.
D.

F
f
f
f
f
f
f
f

D.
D
D.
D.
D-f
D-f
D-F
D
f
D-f

;;:
ABABAB.D
ABAB.
AB.
ABABAB.
AB
AB.D
AB.
AB.
A
ABAB.
AB.D
AB.
AB.
ABA___.f
AB.
AB.
AB.
AB.
AB.
.D.__f
AB.
AB.

;::
DD-f

;;:
AB.
AB.
ABAB.
AB.
AB.
AB.
ABABABAB.

;::
D. F
D. f
D. f
D. f
D- f
D- f
D-f
D- f
D- f
0.
f
0.
f

f
D- f
D. f
D-f
D- f
D- f
D-f
D.f
f
D- f
0.
f
.f
D. f
D- f
F
D-f
D
f
D. f
D. F
D-F
D-F
D-f
D. F
D.f
D.

Chrmiul
Sodwm Phosphates
Sodrum Sdrcale
Sodrum Sullale
Sodrum Sullrde
Sodurrn Sulhle
Sodrum Throsullale
Slannrc Chlorrde
Slannous fluorrde
Sulhle Lrquors
Sultale Lrquors
Trrsodrum Phosphale
lrnc Acelale
2mc Ammonrum Chlorrde
2rnc Chlorrde
2rnc Hydrosullrle
Zrnc Sullale

Crrphitrr
Catagory
Suggested
ABABAB.
AB.
AB-

D-f
DD-f
D-f
D-f

AA;:
ABAB.
AB.
AB.
AB.
AB.
AB.
AB.
AB.

;::
D- F
D- f
D- f
D- f
D. f
D. f
D-f
D. f
D-f

FOOD & FOOD PRODUCTS


Asprrm
Alcohol
Ale
Beer
Beet Sugar Lrquors
Butter
Bulterrnrlk
Cane Sugar Lrquors
Castor 011
Cheeses
Chocolale
Crder
Crlrus Jurces
Coconut 011
Cotlee
Cola Drunks
Corn 011
Cornstarch Slurry
Collonseed 011
De&m
Dextrose
LUG
f rsh 011
frurl Jurces
Gelahn
Hydrogenaled fats
Ice Cream
Jelly
Kelchuo
Lard
Mall
Monnrlol
Mayonnarse
Maple Syrup
Mrlk
Mrneral 011
Molasses
Monosodrum Dlulamale
Dleomargarrne
Dhve 011
Palm Or1
Prchle Solubons
Salad 011
Sorbrlol
Saccharme
Soybean 011
Sugar Solubons
Soll Drrnhs
Starches
Vegetable 011
Vmegar
Whrskey (L Wme
Waler
Yeast
Yogurt

GASES
Acetylene
Au
Ammonia IWeIr
Ammonia (Anhydrousr
Argon rlnerlr

ABCD.f
B.B
B.
BB.
B.
-B
BB.
B.
B.
B.
B.
8.

E.
B-

6.
8.
BBB.

8.
8.

B.
BB.

E.

B-

D.
D-f
0.
D.
D.
D.
D.f
D.
D.
DD.
D-C
DD-f
D.
D.
D-f
D-f
D.
D.
D-f
D.
D.
D.
D.
DDDD-f
D-f
D.
D-F

f
f
F
f
f
f
f
F
f
f
f
f

B8.
8.
B.
E-D-f

f
f
f
F
f
f
f
f
F
f

B-

D.

:;:;::
BB.

D.
D-

f
f

: 5:
b-

;::
D.

D-f
D.f
D.
D-

f
f

: D:D:;
BB-

B.

B: ;:
EB.
8.
B.
B.

;::
0.
f
D. f
D. f
0.
f
D-f

x::

AB.
D.
A0.
ABCDEF

(continued)

f
f

789

Glass, Ceramics, and Carbon-Graphite

TABLE 6.1:

CARBON-GRAPHITE-U.S.

GRAPHITE

(continued)

Crrplitar
Chemical

Crtrpory
suggested
AR-

~;m;T~dluor~dc

Carbrlols t Dlethylene Glycol Ethers1


Carbon Lhsulhde
WoZ; Telrachlorlde

A&;:
ABCDEf
ABCOEf

Butadrene
BUlane
Bulylenc
Carbon Dlondc
Carbon MonorIde
Chlorme
Cyanopen
$c;ny
ne

x::
&ii!
ABCDLf

Elher
Ethylene
fluorme
freons
Hydrogen
Hydrogen Chloride
Hydrogen fluorrde
Hydrogen Sulhde
lodme
Melhrnc
Natural Gas
Neon
klrlc Ollde
NIlrogen
Nrlrous Oarde
Oxygen
Phosgene
Propane
Propylene
Sleam 110 5OOf.j
Sullur Dlollde
Sullur TrIorIde

SOLVENTS

0.

ox::
ABib;;
ABCDEF
ABCDEf
AB:

f
:;

z;;
ABCDEf
ABCDCf
ABCDff
ABCDEf
ABCDEf

Ef

;;;::

Acelaldehyde
Acetone
Acelophenone
Acrolem
Acetate Solvents
Almond 011
Amy\ Acelale
Amy1 Alcohol
Amy1 Chloride
Andme
Anlhracene
Asphalt
fk&ehyde
Bulyl Acetate
Bulyl Alcohol
Bulyl Cellosolve
Camphor

MATERIALS
AtcCD-f
ABCD-f
;;;;::
;;;;::
ABCD.
ABCD.f

;;;;::
ABCD-f
ABCD-f
;;;;::
ABC0.f
ABCDABC6.f
ABCD.f

Craphitar
Category
suggested
ABCD.

Chlorobenzene
Chlorolhene
;;Egslrn

;t;;::
ABCDA6CD.f
ABCDABCD-f

Creosote
Cresol
;;;e;Jdehyde

;;i;::
ABCD.f
ABCD.

Cycloherane
Dlacelone
Dlbulyl PhospWe
Chbulyl Phlhalale
Lhchloroelhane
DrchlorOpenlane
Chesel 011
Dlelhylbenzene
D~elhyleneglycol
Dlelhyl Sullale
;rxl$I
Phlhalale

z:.:
ABCD
ABCD.f
ABC0.f
ABCD.f
ABCD
ABCD.f
ABCDABCD-f
ABCD.
ABCDABCD.
ABCD.
ABCDABC0.f
ABCD.
ABCD
ABCD.
ABCD-f
A8CD.f
ABCD.f
ABCD-

D:penlene
Dlphenyl
Dowtherms
Elher.Dlelhyl
Ether. Petroleum
Ethyl Acetate
Ethyl Alcohol
Ethyl Benzene
Ethyl Chlorrde
Ethyl Mercaplan
flhyl Sullale
Ethylene
Ethylene Dlchlorrde
Ethylene Glycol
Ethylene Orlde
formaldehyde
:;yO;Lwehed
I

jk;;:

& ORGANIC

Chemical

furlural
furluryl Alcohol
Gasohne
Glycerme
Glue
Heplane
Hydrazme Hydrate
Isobulyl Acetate
lsobulyl Alcohol
Isopropyl Acelate
Isopropyl Alcohol
j;p;fcp;l Ether
Kerosene

- Not ruommended lor IhIs enwronment Tins does not predU ladure lor a
Owen Glade
only that aMthe Grade would be prelerable. all other
conslderabons bemg equal.

ABC0.f
ABCD
ABCDABCD
ABCD-f
ABCD
AECD
ABCD-f
AECO-

ABC0.f
ABCDABCDABC&f
AeC0.f
ABCD.f
ABCD.f
ABCDA8CD.f
ABC0.f

Chtmical
f
f
f

f
f

f
f
f
f
f
f
f
f
f
F

f
f
f
f
f
f
f
f

Ketones
Lubrrcalm Or1
Lacquers 1 Lacquer Solvents
Lmseed 011
Lrgrorn t Petroleum Ether I
Methyl Acetate
Methyl Acrylale
Methyl Alcohol
Methyl Cellosolve
Methyl Chloride
Melbylelhyl Ether
Methyl Ethyl Ketone
Methyl formate
Methyl Isobulyl Ketone
Melhyl Sahcylale
Mmeral 011
Mmeral Spurts
Monochlorobenzene
Naphtha
Naphthalene
Ntilrobenzene
Oclyl Alcohol
Oleyl Alcohol
Orlho Drchlorobenzene
PIml 6 Parnl Vehules
Paraflm
Paratlrn 011s
Para Drchlorobenzene
Paralormaldehyde
Paraldehyde
Perchloroethylene
Phenol
Pme Chl
Polyethylene
Polystyrene
Polyurethane
Preslone
Propyl Alcohol
Propylene Oxhlorlde
Resorcmol
Sloddard Solvent
szrene
Telrachloroethane
Telrachloroethylene
Toluene
Tr%hlorobenzene
Tr~chloroelhylene
Trlcresyl Phosphate
Turpenbne
Varmsh
Vmyl Acetate
Vmyl Chloride
Waler
Wares
Xylene

Craphitar
Category
Suggested
ABCD.
ABCD.
ABCD.
ABCDABCD.
ABC&f
ABCDABCD
ABCD.
ABCDABCD
ABC0
ABCDABCD
ABC0
ABCDABCD.
ABCD.
ABCD-f
ABCD.f
ABCD.
ABCD.
ABCDABCDABCD.
ABCD.
ABCD.
ABCD.
ABCD.
ABCOABCD.

f
f
f
f
f
f
f
f
f
f
f
f
f
f
F
f
f
f
f
f
f
f
f
f
f
f
f
f

:;:;::
;;:;::
AECD
ABCD.
AECDABCD.
ABCD.
ABCD
ABCD
AECD
AECD
ABCDABCDAECDABCD
ABCD
AECD
ABCD
AECDAECD-f
AECD
ABCD.
AECD

f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f

790

TABLE

Corrosion Resistant Materials Handbook

6.2:

CERAMIC

FIBER

PRODUCTS-3M

NEXTEL
312 Ceramic
Fibers are continuous
polycrystalline
without the aid of other fiber or metal inserts. Nextel fabrics,
products designed to meet the toughest thermal and electrical
far beyond the useful limits of other high temperature
textiles.
Individual fibers of NEXTEL
metal oxides are (by weight)
(SiOs).

metal oxide fibers suitable for producing textiles


tapes and sleevings are exceptional,
high temperature
performance
requirements
and to offer performance

312 are transparent,


smooth and continuous.
62% aluminum
oxide (AlsOs),
14% boron

NEXTEL
312 Fibers, in terms
oxide (BsOs), and 24% silicon

of their
dioxide

The effects of metals on NEXTEL


312 Fabric heated in air at 2000F are shown below. The metals which cause
attack (molten copper and tin) are extremely
reactive at test temperature.
Most common metals, however, have no
effect on NEXTEL
312 Fibers. The effects of chemicals on NEXTEL
312 Fibers after exposure to 10% chemical
baths (room temperature)
are also shown.

Effects

of Metals on NEXTEL

Metal

312

Fabric

Effect at
1100C (20 12F)

aluminum,
platinum,
chromium,

boron,

No attack

cobalt,

No attack

gold,

No attack

iron, nickel, silicon,

No attack

soft solder

No attack

copper,

tin (molten)

Severe attack

Effects

of Chemicals

HCI (hydrochloric
HA04

on NEXTEL

acid)

hydroxide)

90

less than 1

CaO (calcium oxide-lime)


to 10% chemcal

Fibers

50

(sulfuric acid)

After exposure

312

40

baths and 10 ml at 815C (149YF)

Glass, Ceramics,

TABLE 6.3:

CERAMIC

and Carbon-Graphite

797

LININGS-ABRESIST

ABRESIST is a mineral material, a silicate with a high compressive strength and a high modulus of elasticity, with
extreme
resistance to abrasion, whereby
a certain sensitivity to impact is also present. In addition to its abrasion
resistance, fused cast basalt does not rust and thus always presents a smooth sliding surface. Even after an idle period
in a wet transportation
system, clogging and plug formation
are largely eliminated.

Resistance of ABRESISP

agalnst Bases

Agent

a1

Potash lye (KOH 25 %)


.353 K. hot, llowmg

60C

100 % *

OperatIonal
112davs

Potash lye (KOH 10 %).


Sbll

2OC

100 % *

Materials Tesbng lnstltute Neuwled:


no weight loss after 30 days

Soda lye (NaOH 25 %)


353 K, hot. flowmg

6OC

almost 100 %

OperatIonal test: weight toss


of 0.6 % after 9 months

Soda lye (NaOH 10 %)

20C

almost 100 %

Materials Tesbng lnsbtute Neuwled;


0.9 % weioht loss after 30 davs

Soda solubon (Na,CO, 5 %)

20C

almost 100 %*

Materials Testmg tnstltute Neuwled.


0.2 % weight loss alter 30 days

Calcium chloride (CaCI,).


pasty, sbll and flowmg

20C

100 %

Operabonal lest;
no weight toss after 25 days

Test
* Plate test
test. no weight loss after

The values cited are average values.

Resistance of ABRESISP

aaainst Acids

Agent

al 293

Test
Plate to*1
** Powder tss1

operational lest up to 41 days;


weight loss less than 0.2 %
weak bleaching of surface

Hydrochloric acid (HCI 25 %).


flowing

almost 100 %

rlydrochloric acid (WI 36 %).


stilt

almost

Sulfuric acid (l-l&01 40 %).


still

loo %

Sulfuric acid (f-f&01 94 %).


St111

almost

Sulfuric acid (HzSO~),


concentrated

almost 100 %

0.003 % weight loss after 7 days


(19 Dec. 1966)

Nitric acid (HNO3 65 %).


still

loo %

Materials Testing Institute Neuwied;


no weight loss after 30 days

Hydrofluorlc acid (HF 20 ?&)

LimIted resistance* Operational test; 0.5 mm w= etched


away at surface after 20 days

Hydrofluorlc acid (HF 40 %)

Limlted resistance* Materials Testing Institute Neuwied;


22.8 % weght loss after 30 days

Probintiure,

loo %

Materials testing lnstttute Neuwied;


no weght loss after 30 days

loo %

Attests by many dairies and the Kiet


Testing Instihrte.
No weight loss after 3 years

Protective layer

still

Lactic acid (6 %).


flowmg and still

loo

%'

Materials Testing Institute, Neuwied;


0.6 % weioht loss after 30 davs
Operational test; no weght loss
after 60 days

100%

Materials Testing Institute Neuwied;


0.4 % weight loss after 30 days

792

Corrosion

TABLE

6.4:

Resistant

FOAMED

Materials

GLASS

Handbook

BLOCK-PENNWALT

A totally
inorganic
borosilicate
foamed
glass block containing
no binders,
PENNGUARD
Block offers excebtional
resistance to most acids, solvents and weak bases, and over a temperature
range up to 960F (516C).
It is controlmanufactured
as a 100% closed-celled,
foamed
glass block, impervious
to acidic liquids and gases, is extremely
lightweight,
and possesses low thermal
conductivity
values even under completely
acidic liquid operating
exposures while
its low coefficient
of thermal
expansion
provides
high resistance to thermal
shock. PENNGUARD
Block does not
support
combustion
and can be used alone or in combination
with
refractory
or chemically-resistant
masonry/
monolithic
linings at higher temperatures
to provide
a unique combination
of acid corrosion
protection
and heat
conservation.
The block
is installed
in a manner
similar to a chemically-resistant
masonry
lining, utilizing
special
mortar or an adhesive/membrane
to fully
bond the block to the substrate
and to fully side joint between adjacent
block.

Acid Condrnsste Solutlons end Gases

Bese end Selt Solutions

Sulfuric Acid t-I&O,

Sodium Sulfate. Na&O.

Nitric Acid. HNO,

Sodium Sulfite. Na2S03

Hydrochloric Acid, HCI

Ammonium NItrate, NH,NO

Phosphoric Acid, H3P04

Oraanlcs

Acetic Acid

Heptane

Hydrofluoric Acid, HF

Steam Impingement

Kerosene
Benzene
Toluene

5:_

Base and Salt Solutions


Ammonrum Hydroxide, NH,OH

Magnesium Hydroxide, Mg(OH)2

Calcium Hydroxide, Ca(OH)*

Potassium

Hydroxide,

KOH

Sodium Carbonate. Na.CO,


.

Sodium Chloride. NaCl

1
I

Diethvl Ether

Ethyl Acetate

All concentrations including gaseous forms.


TABLE

6.5:

GLASS

PIPE-CORNING

Acids
Sulfuric, hydrochloric, nitric, and
acetic are only a few of the most
corrosive materials PYREX@ pipe
can handle with ease.

.8

.32

2 .28
?

/
CORROSION
OF
CODE 7740 GLASS
t BY NaOH SOLUTIONS

E .24

Halogenated Hydrocarbons
Bromine, chlorine, brominations and
chlorinations all are perfect for Cornings corrosion resistant systems.

0
2.20
6

Pharmaceuticals
Solutions are in contact only with
PYREX@ Bra& Pipe and virgin TFE
preventing possible contamination of
product.

Z.16

t i i i i i i i rii

Alkalies & Hydrofluorlc Acid.


Low temperature can generally be
handled. However, hot alkalies and
hydrofluoric acid should be avoided.
Addltlonal Applications
Hydrogen peroxide
Brines
Hot. food grade phosphoric acid
All chemicals in the neutral pH
range

20

60

100

TEMPERATURE,
Concentrated
hydrofluorrc
acid attacks
Code 7740 glass at all temperatures.
Mild
solutions dumped mto drainlines can be
tolerated at room temperatures.

140

180

220

OF.

Alkaline solutions attack g/ass very slow/y


at room temperatures,
but as temperature
IS Increased over IOOF. the corrosion
rate rises rap/d/y.

Glass, Ceramics,

TABLE 6.6:

GLASSED

and Carbon-Graphite

STEEL-PFAUDLER

The glass coating of the GLASTEEL


composite
is a non-conductive
mixture of low energy oxides that can
only by a self-limiting
ion exchange reaction (acids) or by direct chemical solution (alkalis). Consequently,
rosion rates of GLASTEEL
can be accurately measured and valid predictions of service life can be made.
Acid

793

corrode

the cor-

Resistance

Outstanding
acid resistance under extreme
process conditions
is a primary
feature of Pfaudler GLASTEEL.
The
charts which follow can be regarded as reliable quantitative
laboratory data on the corrosion resistanceof GLASTEEL
5000 in five common reagent-grade
acid solutions (liquid phase). Chart data are presented in terms of glass loss expressed in millimeters
per year. Average Pfaudler glass thickness is approximately
1 to 2.25 mm (40 to 90 mils) on
reactors, high voltage tested. Therefore,
approximate
years of anticipated
service life may be estimated from the
charts.

Acid Corrosion Charts


GLASTEEL 5000-HYDROCHLORIC
Temp.

ACID
Temp.

GLASTEEL 5000-SULFURIC
Temp.

ACID

Temp.

C
!32

,
!04

177

I49

121

93

66
10

20
Cont.

The

graph

hydrlodic

shown
and

here

30

37

10

20

30

chloroacetlc

GLASTEEL

typlcal

50

60

70

80-100

Cont. _ WI.%

- wt. %
IS also

40

The

for hydrobromic.

acids.

SOOO-PHOSPHORIC

graph

shown

sulphurous

acid.

ACID
Temp. . C

Temp.

aF

here

IS also

GLASTEEL

valid

for

5000-ACETIC

ACID
Temp..

(continued)

Glass, Ceramics,

TABLE

6.6:

GLASSED

STEEL-PFAUDLER

GLASTEEL 5000-SODIUM
Temp.

795

kontlnut?d)

CARBONATE

and Carbon-Graphite

GLASTEEL 5000-AMMONIA

Temp.

C
100

Temp.

Temp.

356

320

284

204

t-

140

240

176

176

60

140
7

10

11

12

60
7

PH

11

Miscellaneous Media

Acids
accordrng to IS0 2723
accordrng to IS0 2733
according to IS0 2743. (This
procedure gwes quantttatwe
hquid and condensmg vapor
phase data for most acids.)

Water
Sample Preparatron
Test Unit
Procedure

according
according
accordmg
procedure
kqurd and
data.)

to IS0 2723
to IS0 2733
to IS0 2744. (Thrs
grves quantdative
condensrng vapor

Alkali
Sample Preparation
Test Unit
Procedure

13

Point.

Testmg up to the boihng point is done usmg the equipment


and procedures
specified
by the International
Oragnrza.
tion for Standardization
(ISO).

Sample Preparatron
Test Unrt
Procedure

12

PH

Corrosion Testing
Testing to the Boiling

10

according to IS0 2723


accordrng to IS0 2734
accordrng to IS0 2745. (This
procedure gives quantitative
liqurd phase data for all
alkaline solutrons up to 80C
(176F). For temperature
above 80C. consult
Pfaudler.)

Agent

Aqua Regia
Barium Hydroxide sat. sol.
Bromine
Chlorosulfonic Acid
Ferric Chloride. 10%
Hydriodic Acid, 20%
Lithrum Chloride, 10%
Lithium Chloride, 30%
Monochloracetic
Acid, 20%
Oxalic Acid, 50%
Phosphorous Acid, 70%
Sodium Fluoride, sat. sol.
Sodium Sulfide, 5%
Succinic Acid, sat. sol.
Tri-sodium Phosphate 5%
Water
Water

Temperature
(C) (F)

150 (302)
B.f?
70 (158)
150 (302)
B.P
160 (320)
B.P
B.f?
B.P
150 (302)
110 (230)
B.P
B.P
200 (392)
B.P
B.P
200 (392)

Corrosion Rates
(mm/yr.)
liquid
vapor
phase
phase

CO.5
(0.1
to.1
(0.2
to.1
CO.5
(0.1
(0.1
(0.1
to.2
(0.1
<O.l
CO.1
CO.5
CO.5
CO.1
CO.5

CO.2
CO.1
<O.l
to.1
<O.l
(0.1
CO.1
<O.l

Comparative Resistances of Materials of Construction

TABLE 7.1:

STEEL, ALUMINUM
AND GLASS FIBER REINFORCED
PLASTIC TANK CONSTRUCTION
MATERIALS-AMERICAN
IRON AND STEEL INSTITUTE

CORROSION

RESISTANCE

OF TANK-CONSTRUCTION

MATERIALS

Material

Type 304
Stainless

Chemical

Type 316
Stainless

TO AGRICULTURAL

CHEMICALS

and Rating
Glass-FiberReinforced
Plastic

Carbon
Steel

FERTILIZERS
Nitrogen solutions (no free ammonia)
Nitrogen solutions (free ammonia)
Aqua ammonia
Mixed liquid fertilizer (1-3-O)
Mixed liquid fertilizer (X-X-X)
Phosphoric acid (55% P2Os)
(chloride free)
Phosphoric acid (55% P2Oa)
(300 ppm chloride)

A
C
C
ND
ND
A
C

::
A
A
A
A
B

2
A
A
A
A
B
A

:
B
A
B

A
NO
A
ND
A

2
A
A
A
A
B

::
A
A
A
B

:
ND

A
NO
A
C
A
A

A
ND
A
C
A
A

INSECTICIDES
Aldrin (1 oz/gal)
Aldrin (100%)
BHC (1 or/gal)
Calcium arsenate
Chlordane (% lb/gal)
DDT (5% in water)
DDT (10% in water)
DDT (paste)
Dieldrin (1 oz/gal)
Dieldrin (10%)
Lead arsenate (100%)
Parathion (0.5%)
Parathion (10%)
Toxaphene (10%)

:
B

::
A
A
NO
ND
A
ND
ND

:
C

FUNGICIDES
Copper sulfate (10%)
Pentachlorophenol
Carbamates (5%)
Mercuric chloride (10%)
Sulfur (100%)
Zinc sulfate (10%)

C
ND
A
C
A
B

A
ND
A
NO
ND
ND

HERBICIDES
2.4-D (3 oz/gal)
2,4,5-T (3 or/gal)
Sodium TCA (1 k lb/gal)
Sodium chlorate (10%)
Sodium arsenite (8 oz/gal)
Arsenic acid (10%)

r!
ND
A
C

;
ND
ND
ND

DEFOLIANTS
Magnesium

chlorate (10%)

Resina used to formulate glass-fiber-reinforced


plastics vary in their resistance to alkaline solutionr.
k caniad in a plastic tank unleu the tank is recommendelf swcifically for alkaline aolutionr.

Solutions containing frw ammonia should not

Kay to Symbols:
A. Resirtent to corrosion. Should pfwide low wvice life with little maintenance. (Ccaxion
rates at wnbia-tt
genwally IOU than 0.002 inch pet yew.)
B. Mod~ratelv resistant. Will corrode to some extent. Maintenance and eventual replacement may ba necessary. (Corrosion ratea
ambient twnfmrature are generally betwnn
0.002 and 0.020 inch per year.)
C. Not resistant to conosion and not recommended for continuous UY. (Corrosion ratea at ambient tsmpwatun
are gansnlly gnatat than 0.020 inch per you.)
ND = No data.
796

tmpwrtunam

at

Comparative Resistances of Materials of Construction


TABLE 7.2:

METAL,

CARBON,

CERAMIC,

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING

ACETIC
ACID, 100%. CH. COOH
ACETIC
ACID, Dilute
ACETIC
ANHYDRIDE.
(CH. CO),0
ACETONE.
CH, COCH,
ACETYL
CHLORIDE.
CH. CCC1
ALUhlINUM
CHLORIDE.
AICI.

HYDROXIDE.
Al (OH).
SULFATE.
Al, SO,,
ALUM?,. CONC., AI&SO.), *K. SO., etc.
ALUMS.DILUTE
AMINES,
various
NH.
AMMONIUM

CARBONATE,

(NH.),

CO.

--x
o_

0
o

--x
_

x
+

00x----*x
xxxxx

AMVL
.

ALCOHOL,
C.H,.OH
CHLORIDE.
C&&J
ANTIMONY
TRICHLORIDE,
StCI,
ARSENIC
ACID. HAsO,
BARIUM
CARBDNATE,
EkCO,
..
HYDROXIDE,
Ba(OH).

SULFIDE.
BaS
BENZALDEHYDE.
C.H. CHO
BENZENE,
C. H.
BENZOIC
ACID, C. H. COOH
BORAX,
NaeB.Or
BORIC ACID. H.BO,
BROMINE,
Wet. Br.
BUTANOL.
C.H.OH
BUTYL
ACETATE,
C.H.COOCH.
BUTYRIC
ACID. C. H, COOH
CALCIUM

BISULFATE.

CALCIUM
n

CARBONATE,

CHLORATE.
CHLORIDE.
HYDROXIDE,

CaHSO,
C&.
C&IO.
Cdl,
Ca (OH).

..

HYFOCHLORlT&Ca@CI).
SULFATE.
Ca SO.
CARBON
DIOXIDE
&y).
CO.
.

ti &,&
cY).>
CARBON
DLSULFIDE.
CS.
CARBON
TFlRACHLORlDE
(Moist) CCI.
CHLORACEIIC
ACID. CICHd33.H

CHLOW
ACID.
CHLORINE. (DRY).
n

(wa).
Cl.
CHLOROBENZENE.
C
CHLOROFORM.
CHCL

xx

xx

++t+;

xy

x
x

-+xX>
xXxXx>
xx
__-

0
0

00 0
xxx
x

x
0
x
t

xx
xx
+xx

x
.
xx>
X)
XXI

x
+

xx1
x
x x 1
Y,

x--xxxxx
oo+tt--x~
0

x:

000x0
ox
0
I I
_vl

x:
ox
-

xx
-rn
__

tt-

xx.
+
--t

_ o
_~^
x

0
vx

xx

tt+x

:,

_
Iv
x

x x
;

x
- _

n
xxxxx
0 0 00

H. Cl

HCIO.
Cl.

xx
xxx

NH,,PO.

xxx
xxx
xxx
xxx
x
xxx
x
xxx

SULFATE,
(NH&SO.
ACIiTATE.
C.H,,COOCH.

MATERIALS-

xxx

Cl 0

x
0
x

x
xx
xxxx
x
x
x
xx
xxx
xxx
xxx
xxx
x
xx
x

x
xx

797

798

Corrosion Resistant Materials Handbook

TABLE 7.2:

METAL,

CARBON,

CERAMIC,

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

z <a*
nlr-.

MATERtAf.9
x -VUyGXdScn(&W
+ - Modmtc
Scnka
- LWtd
or
Vartablc Semkr
0
- uadaf8cly
Bhmk - No Inform&tom

n
..-

MATERIALS-

&-,
,-,

CtiE.\IICALS
SOLIDS ASSU~IED IN SOLN.
HOO\I TEJIPEHATUttW
ASSU>tED
USLESS OTtlElWISE
STATED

CHROMIC
ACID. CI 0. mln
COPPER
CHLORIDE.
Cu Cl.

XXXX

xx
t

CYANIDE,Cu(CNh

x
x

I.
**

SULFATB
CRESYLIC
AClD
DICHLORETHANE.

xxxxx
x
x

Cu SO.
C. H. Cl.

x
x
x

x x
x
xxx
xxx
xxxxxxx

DICHLORIDE,

C.H.

x
x

x
x

x
xx
xx

x
*

Cl

,
:

FUEL

OIL

xxx

ml
1
@Vd
ACID, (Cat.),
I

*
HYDROCYANIC

HCN
fDil. & Gad

xx

x
x
:

x x

+r

II

0
0
0 0 0

0
0
0 3 0 0 0

0
x-x
0

oo--0
x
x
,.

xxxxx
,.

0
0

ox

tt-

x0

txx

x0

XL

ix-o-x-x
xx

:-t-000+
*-0

--xx

ox

~""""""-

-A

GALUC
ACID. (DHX C.H.CGOH
-txmms,
Remed
GLYCEROL.
CH. OH.CHOH
CH. OH
HYDROBROMIC
ACID, HBr
HYDROCHLORIC
AClD.
V2ac.l. HCl.

xx
xx
x

xxx
xxx

--t

0+x

-xx

o----x

<Y

xxx
-xx
xxx
xxx

-ott-c xx
XXfX
-ttx
c xx
c xx
t+tx
(XX-fXXX
--"""""x
+#
k
1 Ott
o----t
L

xx

xxx

xxx
xx

xxx

x-x--x

,000+--t
., -ot+t-t

x
x

txx

ox

+xx

-xx

30-

----

IXY

xxrx

x*x.

xx

<xx

xxxx

xxx

xx

1.

xxxxx

t
IXtt+X
x--x++0x---

x
-

t
x

-xx

xc

-xx

xxx

-x+

1.

xc

_
LEAD

ACETATE,

*
MALEIC

ACID.

PMCH.

Coo).

SULFATE,
Mg So.
CO. H C. H. CO.

Ii

0
___

x
tot
XX

xt

xx

t-xxx
xt
xx
t +XxX
xx

PtXttttX
x

xxx
Y

XXI

)I

(continued)

Comparative Resistances of Materials of Construction

TABLE 7.2:

METAL,

CARBON,

CERAMIC.

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

799

MATERIALS-

MATERLAIS
X - very Good Sewh
+ - Modentr !kr*icc
- Lhhrd
or
Vukbk
Serrkt
0
- Umwiaf*ctmry
Bkmk - No Inlormatka
CHE>IICALS
SOLIDS ASSU\IEU
IN SOLN.
HOO\I TE>IPEHATURES
ASSU.\lED
UULESS OTHERIIISE
STATED
MA&lMERCURIC
MERCURY.
METHANOL.

1
c
-0.
&&DE,
;iS. CL
Hg
Cont.. CH.OH

(DdUre)
METHYL
CHLORLDE,
CH. Cl
NAPHTHA.
Petrokum
MCKEL
CHLORIDE.
Ni Cl.
SULFm
.I.N. SO
NITRATING
ACID @15% H.SO,)
..
,.
(0%
H. SO.1
3.

(05%
HNO.)
NlTRlC
..

ACID.
*.

NiTROBENZENE,

tr 1% Aad)
Gmc.. HNO.
Dilute
6. N.

NO.

OLELC ACID. c. HI, CH:CH(CH.hCO.H


OXALIC
ACID. CO. H CO. H
PHENOL
(Co&.) C. H. OH
(mute)
PHOSPHORIC
ACID
I
.
PHOSPHORIC

ACID

WO%),
045%

tlP0.
Hot)

@45%

Cold)

ACID (45%)
ANHYDRIDE.

DN

x
*
x

or Moist

+-l-Y-

~MoiresP,O.

PHTHALlC
ANHYDRIDE.
C. H. (CO). 0
PICRIC ACID. Sch., H0.C. H. (NO,).
POTASSIUM
BROMIDE.
KBr
..
CARBONATE,
K, CO,

CHLORATE,
KCIO,
..
CHLORIDE.
KC1

CYANIDE.
KCN

DICHROMATE,
K. Cr. 0,
FERROCYANIDE.
K.FdCNI.
HYDROXIDE.
KOH
..
NITRATE,
KNO.
PERMANGANATE,
KMnO,

SODIVM.

..
n

.,
*

Molten 210ACETATE;

400-F.

Na CH.

COO

BICARBONATE,
NaHCO.
BISVLFATE.
Na HSO.
BISVLFITE.
NaHSO,
BORATE Na BO.
CARBONATE.
Na. CO.
CHLORATE.
CIO.
CHLORIDE.
Na Cl
CYANIDE,
NaCN
FLVORIDL
NaF
HYDROXIDE,
(Gmc.), NaOH

Ns

x
x

x
x

x
x
x
x

I
x
x

*
SULFATE.
K. SO.
SULFIDE.
K. S
PYROGALLOL.
C. HI (OH).
SILVER NITRATE.
AS NO.
SODWM
..
*.

---

-0

x
x

x
x

xx

x
x

x
x
x

x
xx

xxxx

xx

xx
x x

--ox

I,

x
x xx
xxx

A0 :

(continue

800

Corrosion Resistant Materials Handbook

TABLE 7.2:

METAL,

CARBON,

CERAMIC,

RUBBER,
CORNING

PLASTIC

AND WOOD CONSTRUCTION

MATERIALS-

(continued)

HATRRIAIS

-verycod- Mdmtc
ScrvtN
- U&hd
OI
VUtSbkSWh
0
UMDMK1~
s*nk
. No lnhrmwjom
+
-

CHEMICALS
SOLIDS ASSULIED
IN SOLN.
ROO8I TEMPERATURES
ASSUMED
UNLESS

SODIUM

.I
I

OTIIERWISE

STATED

HYDROXIDE,
(Dilu*)
HYDRDSULFITE
HYPOCHLORITE.
N&Ct
HYPOSULFATE
NITRATE_
Na NO.
PEROXIDE.
Nan 0.
PHOSPHATE,
Crri) Na. PO.

SWAT&
N&SO.
SULFIDE,
N&3
SULFITE.
Na. SO.
STANNIC
CHLORIDE.
Sa CL
STANNOUS
CHLORIDE.
So Cl.

.--I+
X+XxX

x-

O--x--xX
0

00

-0

--x
0

txotoxo
t+txtxx

--

xxxxx

xx
x
--x

00

.x+xXxXx
XXXXXXX

x
x
x
x

.,

-RIG

ACID,

SULFUR,

Motlen.

CH.

(CH.),.

COOH

SULFUR
I

CHLORIDE.
(WCC). S. Cl.
DIOXIDE
(Dry). SO.
DIOXIDE
(Wet)

TltIOXIDE
So.
SULFURIC
ACID (FuminS to 98%)
.
(Hot Ccc.)
H. SO.
I
I
(cold c-4

*
(7SclL9Sk)
*.
n
(IO%-7Sk)
I
*
(do%)
SULFUROUS
ACID. H. SD.
SULFURYL
CHLORIDE
so. Cl.
TANNIC
ACID
TARTARIC
ACID, (CHOH
CODHh
TOLUENE,
CH. C. H.
TR1cHL0RErHYL
ENE. Dty.C3.. C CHU

-+txxxxx

x
x
x

xxx
xxx
x

TF
+

xxxxx

xx

xxxxxxx
x
-

t
tttxx
-+t+ttxx

x
x

x
x

xx

xxx

x x

(continued)

Comparative

TABLE

7.2:

METAL,

CARBON,

CERAMIC,

Resistances of Materials

of Construction

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

MATERlAlS
x -VcryGcmdSmica
+ _ Moderate Servicc
- Lided
01
Variable Scrvkc
0 . unsal&fact.ry
Ulank - No lnfommth
CHEMICALS
SOLIDS ASSUMED IN SOLN.
ROOM TEMPERATURES
ASSUMED
UNLESS OTHERWISE STATED

801

MATERIALS-

ACETIC ACID, 100%. CHI COOH


ACETIC ACID. Dilute
ACETIC ANHYDKIDE,
(CH. CD),0
ACEl ONt, CH, COCH,
ACETYL (HLOKIDE, CH, COCI
ALUMINUM

CHLOKIDE.

AICI.

Al (OH),
SULFATE, Al, SO, 3
ALUMS. CONC.. AI&O.h *K. SO,, etc.
ALUM& DILUTE
AMINES. ar,ous
,.
._ NH.
Am
AMMONIUM
CAKBONATE, (NH.), CO
*.
CHLORIDE, NH, Cl
..
HYDROXIDE. NH. OH
..
N-h.
NH. NO,
PERSULFATE. (NH.). Sz
PHOSPHATE, (NH.k
P(
..
(NH.).H PO<
NH. aPO.
SULkATE. (NH.&O.
AMYL ACBTATE, C.H,,COOCH,
.. . ALCOHOL, C,H,,OH
*I
. HLORIDE. C.H,,CI
ANTIMONY
TRICHLORIDE.
SbCI,
AKSENIC ACID. HAS 0.
BAKIUM CARBDNATE,
BaCO,
HYDROXIDE, Ba(OH),
*.
SULFIDE. BaS
BENWLDEHYDE,
C.H. CHO
HENZENE. C. HI
tJbNW1C ACID, C. H. COOH
BORAX, Na.B.O1
BORIC ACID, H&O,
BROMINE. Wet. Br,
HUTANOL. C.H.OH
BUTY 1. ACETATE, C,H.COOCH.
BUTYRIC ACID, C> HI COOH
HYDKOXIDE,

x
-A

x x
-

---_I

I,

CALClUM
..

BISULFATE. CaHSOa
ft&,J FITF
C&,.%0,
CALCIUM CARBONATE, CaCOa
..
CHLORATE, CaCIO.
.I
CHLORIDE. C&I,
HYDROXIDE. Ca (OH),
,,
HYPOCHLORITE,
01 @Cl)
..
SULFATE, Ca SO.
CARBON DIOXIDE (Dry), CO.
I.

(continued)

802

Corrosion

Resistant

TABLE 7.2: METAL.

Materials

CARBON,

Handbook

CERAMIC,

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

MATERIALS-

MATERIALS
x-vuyGadsmkm
+ - Moderate Service
-

- Li&kdor
Vu*bksaria
0 - Udactw
Blank . No Infornutia
CHElMlCALS
SOLlDS ASSUMED IN SDLN.
ROOM TEMPERATURES ASSUMED
UNLESS OTHERWISE STATED
CARBON DISULFIDE. CS,
CARBON TETRACHLORIDE (Moist) CC%
CHLORACETIC ACID. C1CH.CO.H
CHLQKIC ACID. H&p
CHLORINE (DRY). CL

mw, CL

CHLOROBENZENE, C. Ha Ci
CHLOROFORM. CHCL
CHROMIC ACID. CT Ch sob
COPPER CHLORiD& Cu CL
.
CYANIDE, Ch(CNh
n
SULFATE Cu SO
CRESYLIC ACJD
DICHLORETHANE. Cs H. CL
OIETHYLAIUINE
!J&&),
NH
DIPHENYL. C2LC.H.
ETHERS, Vlriour
ETHYL ACETA~C.
if,cmcb
tITHYspN&

CHLOROHYDRlN.
Cl (C. H&Xi
DICHLORlD$ C.H. CL
QLYCOL. CH. OHCH. OH

FATrY ACJDS, Vuiow


FEKRlC CHLOKLDE. PeCL
.*
NITRATE. PdNOd.
I Fe*(w)
FERROUS CHLOKIDE, Fe ;
a*
SULFATE; Pas01
tLUOKIN&, P.
C&O
FOKMIC ACtD, HCOOH
PUU OlL
GALIJC ACID. (OHh C.H,CX)OH

--xx
-x-x
x

x *

GLYCEKOL. CH. OH.CHOH CHI OH


HYDKORROMIC ACID. HBr
HYDROCHLORIC
ACID. (Coot). HU.

(huou)
HYDROCYANIC ACID, (Cant..), HCN
I

(D&l. A Gu)
(COllXHp
*
*
ma&
HYDROPLUOSLLJCIC ACID. HSiP.
HYDKOCARBONS h4lwhutic~

*x
*xx

-xx

xxx

xxx

x*- 0
x

--

n x

---x

(continued)

Comparative Resistances of Materials of Construction


TABLE 7.2:

METAL,

CARBON,

CERAMIC,

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

803

MATERIALS-

CHEMICAL.5
SOLIDS ASSUMED IN SDLN.
ROOM TEMPERATURES ASSUMED
UNLESS OTHERWISE !XATED
HYDROCARBONS -1
HYDNOGW GAS, Ii.
HYDRDGEN PliuuuJx
..
*.
.

IODINE. I. WU
IODOI-ORM. CHL

wA3Dc.h tb 0.
t-j
1m 1 n. s
Cd,

Kfil-ONESS.Vuiou
LACIIC ACID, CHa CHOHCOOH
LWD ACWATE. PMCHa COO).
-.H8.I
HYDKOXIDE. Ma (OH).
,.
SULFATE Hy SO.
MALUC
ACID. CO. H C, H. CO. H

MERCURY. Hy
METHANOL. tic.. CH.OH
tDdUW
METHYL CHLOKJDE, Ciia Cl
NAPHTHA. Petdouat
NICKEL CiiLOKIDE. NI Cl.
!xJLFxrFR-so
* I
.
Nl-IllATING
ACID
@I,%
ti.%h)
..
,.
(~15% HI So.)
**
n
(05% HNO.)
( IkAca
NlTLUC ACID. Cum:, IWO.
,.
.*
Dilula
NI.1 ROtbENZENE,

6.

N.

NO.

OLEIC ACID. C, H,, CH:CHtCH.hCO.H


OXALIC ACID. CO, H CO, H
PHENOL 0mc.) C. H. OH
w 1w
PHOSPHOKl~AClD
(100%). H.PO.
045

HUI)

PHOSPHORIC ACID D45% Cdd)


,.
ACID (45%)

ANHYDRIDE. Drr or M&I


Mollca,
P.O.
PHTHALIC ANHYDRIDE, C. H, (CQh 0
PICRIC ACID, Soln.. H0.C. H. @do.).
POTASSIUM BROMIDE. KBr
*.
CARBONATE. K, CO.
.I

. .

(continued)

804

Corrosion Resistant Materials Handbook

TABLE 7.2: METAL,

CARBON,

CERAMIC,

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

MATERIALS-

*(ATERlAls

x - very Goad
+

- Modmt.

Scrvh

- LImIted ot
vulmbk Srmim
0 - Um.utiaaM~~
Blwk . No Infonnatia

CHEMICALS
!JDLlW ASSUMED IN SDLN.
ROOM TEMPERATURES ASSUMED
UNLESS OTHERWISE STATED
POTASWJMCHLORATE.

CHLORIDE.
*
.

KCIO,
Kc1

CYANIDE.
KCN
DICHROMATE,
K. Cr. 0.
FERROCYANIDE.
K.FdCN),
HYDROXIDE.
KOH
NITRATE.
IWO.
PERMANGANi+E,
KMnO,

..

..
I.

SULFATE, K. So.
SULFIDE. K, S
PYROGALLOL.
C. H. (OH).
SILVER NITRATE. AS NO.

..

SODIUM.
SODIUM

..
..
*.

1.

*
..
I
w

Molten 210ACETATE;

400-F.

BICARBONATE.
NsHCO.
BISULFATE.
Na HSO.
BISULFITE. NaHSO.
BORATE NI 00.
CARBONATE.
Na. CO.
CHLORATE.
Ns CIO.
CHLORIDE.
Nn Cl
CYANIDE.
NaCN
FLUORIDE.
Nfi
HYDROXIDE.
0mc.). NmOH
HYDROXIDE,
(MU@
HYDRGSULFlTE
HYPOCHLORITE,
N&cl
HYPGSULFATE
NITRATE.

Na NO.

PEROXIDE.

Na. 0.

PHOSPHATE.

ACID.

CH,

(CH.),.

COOK

SULFUR, Molten. S
SULFUR CHLORIDE.
Wet). S, CI.
.
DIOXIDE
(Dry). SO.

DIOXIDE
(Wet)
*
nuOXmE
So.
SULFURIC ACID ~Fiunin9 to 911%)
*.

*
I
SULFUROUS

(Hot CODL) H, SO.


(cola c-4
i73%-9JI1
(IO%-75%)
(*IO%\

A&.-H.

SULFURYL
CHLORIDE
TANNIC ACID

xxx
I x x
xxxxxx
XXXYXX
xxxx

x
x

xxx
xxx
:

xx
1 ~

x x x x x
I x-0

~ x

x x
--x

xx
x

x
Y
--xx
-

x--xXxX

oii) Na. PG.


0.
I
SULFATE, N&SO.
*
SULFIDE. NoS
*.
SULFITB. Na. So.
~ANNIC
CHLORIDE.
Sa CI.
STANNOUS CHLORIDE.
SD CI.
STEARIC

Ns CH. Coo

x
x
x

I x x
x
x -x
*x0x

x
x

xx-0

---0
0
xxotq
0

x
x
0
0
+

0 0 0
000
0
lxx-x/-x

(XXXz4XX

iD.
s(x Cl.

TARTARIC
am. (CHOH 030~k
TOLUENE, CH. C H.
TRICHLORErHYL
BNB. l7w.Q..
C. CHcl

kx
x

-x

LXXX

(continued)

Comparative

TABLE

7.2:

CARBON,

METAL,

CERAMIC,

Resistances

of Materials

of Con.struction

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

MATERIALS-

MATEUAIS

x - very
+

- Llmud

servtce

tioud

Modcnle

kvica

Variabk

or
Servke

CHEMICALS
SDLlDS ASSUMED IN SDLN.
ROOM TEMPERATURES ASSUMED
UNLESS
OTHERWISE STATED

y/c.CH.

COOH

L AChlATE. C.H,,COOCH.
*. ALCOHOL, C,H,,OH

AMY

,.

Hl.OKIDE.

ANTIMONY

TWICHLOIIIDE.

ARSENIC

ACIO.

t)AtLIlJM
.,

HYDROXIDli.

.*

SULFIDE.

HliNLCNti:.

C.

ACID.
Ns,U&h

WWIC

ACID.

OtlOMINti:.

ACID.

xx

C. H. COOH

x
0

x
--I

xxxx

IL

ox--00

x
xx

xx
xx

x x xx

x
00

---ox

x
-

x x

x -xx-x0---00
x x xxx

I
x

H. COOH

CALCIUM RISULFATE. CaHSO,


*.
CALCIUM CARBONATE. CuCOa
*.
CHLORATE. CaCIO.
..
CHLORIDE. C&I,
..
HY DWOXIIW CA KIHI.
HYFOCHLOUTE. Ca @Cl).
**
SULFATE, Ca SO,
CARRON DIOXIDE (Dry). CO.

xx
xxx

x x

I
x

tk.

C.

xx

x x x

x
x

lh(OH).
CHO

IllJTANOl.. C.li.OH
YUTYL. ACETATE,
C.H.COOCH.
LiUTYKlC

xx

--

IhCO,

HdlOa

WCI.

xx

H.

BORAX.

-I
xx-

SbCL

BaS
C.H.

HLNWIC

x-

HAIO.

CARBONATE.

OENZALDEHYDE.

Q&cl

x
x x
x
x I
x
x

.*

+*

xxx
00X

x
x

x
I[

x
x0x
x x x
0 x
x x
0
x

805

806

Corrosion

Resistant

TABLE 7.2: METAL,

Materials

CARBON,

Handbook

CERAMIC,

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

MATERIALS-

CHEMICALS
SOLIDS ASSUMED M SOLN.
RoWI TEMPERATURES ASSUMED
UNLESS OTHERWISE STATED
x

CAKBON DISULFIDE. CS.


CARBON TETRACHLORIDE
wlsc)ca6
CHLORACEX-IC ACiD. C1CH.CO.H
CHLOYIC ACU). tiClo*
CHLORINE (DRY). Cl.
3.

wet).

CHROMIC
COPPER

C.

H. Cl

ACID,
CHLORlDE

CYANIDE,

Cr

0.

dn

Cu CL

xx

--.

xx

--

00

ox

00

01

C.

H. COOCH.

00

Vmau
ACETAIlS

---

CXCNh

SULFATE Cu So*
CKtSYLIC
ACID
OICHLORETHANE.
C, H. cl*
OIEYHYNH
DIPHENYL. C.H.C.H.
ETHYL

XII

CHCL

I.

ETHERS.

XI

CL

CHLOROBENZENE.
CHLOROFORM.

0
0

--

-0

--x

&ivr&f8Rt~ti3.H~na
tiTtiYffne
CHLORoHYDRlN.
U (C. HJQn
DICHLUWDti. c.u. CL
I
c~LYCOL. CH, OHCH. OH

x:

---

. >
-

x
-

_-

--xx

CHLOKU&, Pact
NWRAII!. PaNO.).
SULVATE.PG-w~
CEYYOUS CHLoKIIXi.
tw it
..
SUL.pATl& Faso,
tl UCMINE. t.
--wxwirnE
FOKMIC ACID. HCOOH
IJuts. ml
(IALLIC ACID. (OH). GH&OOH
-txxmFlE
# ucr~LYCulOL.
CH. OtI.CnoH CM. on
IIYDKULIYUHIC
ACID. Hklr
HYl)YO~tiLOKIC
A(lD. t-k.
HCI
V(DilsJ
I
(DIY 0-J
HYDYDCYANIC ACID, (Cm.), HCN

.
(Dk k ciu)
CZD G30 1. HP

.. khlulz,
HY DYOPLUosIuClC
ACID. HSIP.
HY~MJCAK~WNS(A~I~~O~I~~

t+KKlc
..

-x

XX

xx

xx

x
*

xxxx

LXX

\
A

x
I

xxx

x
-_

x
-

)I

--

_x_

*
_
I

__

--x1

(continued)

Comparative

TABLE 7.2:

METAL,

CARBON,

CERAMIC,

Resistances

of Materials

of Construction

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

807

MATERIALS-

CHEMICALS
SOLIDS ASSUMED IN SDLN.
RDD,M TEMPERATURES ASSUMED
UNLESS
OTHERWISE STATED
HYDWDCARIONS
HYDYWW

-1

cijw.

H.

Pwwxluli KiJcw. Hv 0.
.I
(DIIUKJ~

HYDYO(iW

.*

(WeI)

IODlNE. L Wa

Mt.AlCUKlC

CHLOKJLW..

Ml!I(CUYY.

ng

MKI

tIANO1.

H&

I
I

CH.OH

Cuuc..

__
II

CL

tlSiLW)

*
*

MEIHYL CHLORlDE, CH. Cl


NAYHIHA, Pei~dorrm

___-y

NlrROUENLENE.

C.

N. NO.

PHOSPHORIC ACID 945% Cold)


**
ACID &4J%) w
ANHYDKIDE.

..
PICKIC

ANHYDIUDE.

Dry

ACID.

POTASSIUM
..

Soln

C. H.

HOC.

BHOMIDE.
CAKBONATE.

H.

,>

k
or MOIU

Mullen.

PHTHALIC

lxx

P.O.

(CO).

(NO.).

Kbr
K. CO.

(continued)

808

Corrosion

TABLE 7.2:

Resistant

METAL.

Materials

CARBON.

Handbook

CERAMIC,

RUBBER, PLASTIC AND WOOD CONSTRUCTION


CORNING (continued)

MATERIALS-

HATERLALS
x - Vwy cod
srwia
+ . hladmc~ *rvica
-

. Lhllr(
or
Varisbk Senl~

0 . UualUu(*ry
Blah . No Infarma(br
CHEMICALE
SOLIDS
ROOM
UNLESS

ASSlJ,MED

IN

OTHERWISE

!
;fi

SOLN.

ASSUMED

TEMPERATURES

STATED

-m
-

..

BlCARLiONATE.

NaHCO.
x

x,

+ t

t1

x>

XI

-I

7
-

---cl<

0,

._
-

RK

ACID.

CH.

(Cl&)..

COOli

SULFUR. Mollco. S
WUR
CHLORIDE.
(We). S, Cl.

DIOXIDE
(Dry). SO.
-
DIOXIDE
(Wet)
TRIOXlDE,
SO*
SULFURIC ACID (Fumes to 91%)
I.
L
(Hoc Caac) H. SO.
I
I
cAd Cm4
I

f719b-9JZ)

x
x

x 0

00

000

01

,<

01

j7
> I

00
0

xxxxx--x

--

oxx-

--x

---

---x

-.

SULFUROUS ACLD. H. SO.


SULFURYL
CHLORIDE,
SD, Cl.

c
---x
x

lDurcon

5 would be the preferred

formula

Comparative Resistances of Materials of Construction


TABLE

7.3:

POLYMERIC

HOSE AND STEEL, ALUMINUM

LISTING

OF GATES

AND BRASS COUPLERS-GATES

HOSE

STOCK

809

RUBBER

TYPES

Stock Twe

CornPosition

Natural Rubber and Styrene Butadlene.

D2

Slmllar to Type D stock except rt IS white and compounded

D3

Gum Rubber, tan color.

lsobutylene

Ethylene, Propylene and Dtene (EPDM).

Chlorosulfonated

Polychloroprene

AZ

Similar to Type A stock except white color and is used principally

Acrylonltnle

CZ

A blend of Type C stock and plastic. Used pnmanly as hose cover matenal

C3

Modlflcatlon

Specially compounded

Fluorocarbon

Eplchlorohydrin.

Polyamide

to handle food products

and lsoprene (Butyl).

Polyethylene (Hypalon).
(Neoprene).
for edible products.

and Butadiene (Buna-N).

of Type C. Has some properties similar to Type A stock


cross-linked

polyethylene

(Gatron)

(FPM)

Resins (Nylon type)

GATES

CHEMICAL

RATING

SYSTEM

Code:
1 This fluid is expected to have minor or no effect on the polymer.
2 This polymer should give reasonably satisfactory service. Due to
the nature of this chemical and under prolonged continuous exposure, the rubber may exhibit minor to moderate deterioration
and/or solution discoloration.
Environmental
changes such as
temperature, concentration,
etc., may promote increased degradation.
x The polymer is unsatisfactory for this chemical and should not be
used.
- Insufficient
or no data available for this material. Testing is advised.
Ratings shown in the table are based on a temperature
solutions unless otherwise noted.

of 70F and 100% concentrated

or saturated

(continued)

Comparative

TABLE 7.3: POLYMERIC

HOSE AND STEEL, ALUMINUM

AZ

of Materials

POLYMER

Cz

TYPES
Cs

RUBBER
COUPLING

It

877

of Construction

AND BRASS COUPLERS-GATES


HOSE

CHEMICAL

Resistances

(contd)

MATERIAL

A -Continued
ASTM
ASTM
ASTM
ASTM

011 No 1. ................
011 No 2
......................
...................
011 No 3 ....
Reference
Fuel A

Bardol B .............
Barrum Carbonate
......
Barrum Chlorrde
......
Barrum Hydroxrde
Eiirm
Sulfate.
..........
Barrum Sutlrde
.......................

.....
...
.....
.....
......
.............
.........
........
Beer .... ....... ........
....

.......................
...
................
.......................................

d) ................................................

.........................................................
lol ...................................................
..............................

.........

.....

.....................................................
C

1
ake Alum.. .........................................................
;
alcme Lrquor .....................................................
2
alcrum Acetate ...............................................
i
1
alcmm Brsuliate ...............................................
2
1
alctumBrsullrte..
1
1
atcrumCarbonale
.......................................................................................
2
2
atcrumChlorate
...............................................
1
1
alcrumChlorrde.
................................................
1
1
alcmm Hydroxrde.. ............................................
..............................
X
2
alctumHypochlorrte
(5%).
X
2
atcrumHypochlorrte
(15%)......................

Use FoodGrade Hose Onty

0 Cover

:
..

i
1

:
....

2
1

stock rating only; rating for tube stock X.

f
x

:
X

I
1

1
x

x
x

2
x

1
1

..
2
2

(continued)

Comparative

TABLE 7.3:

POLYMERIC

HOSE AND STEEL, ALUMINUM

Resistances

of Materials

of Construction

AND BRASS COUPLERS-GATES


HOSEPOLYMERTYPES

Da
02
D

CHMCAL

/ AZ
A

813

RUBBER

(contd)

COUPLINGMATERIAL

Cz

Cj

Iron or 304
Carbor ss
Steel

316 AUMBRA SS
SS

C -Continued

...

....... 1.
..

Cycloheranone
Cymene

DR>co fR15~,fRZOO,fRZOO6. fR310


Dasco IfR...........
DCZOC
DC5101 DC550, DC560
.............

Decalm
..........
DelonuedWater .........

...
.:.

Dracetone Alcohol

............
P@e_ntiE!her,,,_.

3tbutyl Ether ...............


3rbutyt Phthalate. ........................
lrbutyl Sebacate

Irchlorobenzene
.....................................
.I.........
llFselP~!.:~,.~,LL~_~.~
I~
Irethylamme.. ..........................................
Irethylbenzene .......................................
lrethyl Ether.. ........
Irethyl Phthalate.. .........

yrpentene.. ......................................................
hrco 011s..........................................................
)owthermA.. ......................................................

)uroFR HD
......................................................
IuroOils.. .........................................................
tP47.200 Flurd. Dow..
.......................................

E
nergol HL 68 ......................................................
x
nergol HLPC 68 ..................................................

thy1 Acetate.. .....................................................

thylMercaptan ..................................................
thy1 Oxalate .......................................................
thylPentachlorobenzene.. .................................
thylSrlrcate .......................................................

X
2
X
2

0 Cover stock rating only; ratrng for tube stock X.

X
2
X

...

X
2
X

X
X

X
X
X

X
X
X

X
X
X

X
X
X
2

...

...

.........

...
....

(continued)

814

Corrosion

TABLE 7.3:

Resistant

POLYMERIC

Materials

Handbook

HOSE AND STEEL, ALUMINUM

AND BRASS COUPLERS-GATES


HOSEPOLYMERTYPES

DJ
D7
D

CHMlCAL

AZ
A

Cz

Ca

I K

RUBBER

(contd)

COWLING MATERIAL
W

I Z

Iron or 304
Carborx SS

316 ALUM. BRAS


SS

Steel

E -Continued
Ethyl Bromrde (DI)
Ethylene Chlortde (DI)
Ethylene Chlorohydrm
Ethylene Dramme
Ethylene Glycol

:
2

2
1

x
x

x
x

x
x

X
1

_
Factovrs 52
Fatty Actds
ferrrc Chiorrde
.:
,.
~e~~_Nrtrate,,~ .l~
Ferrrc Sulfate.
.....
Ferrous Chlorrde
Ferrous Nltrate
Ferrous Sulfate ,.
Fertrhzer (Lrquld. Manure! .
:
Fne ResIstant Hydra-Fturd~I[exaco)
Fluoborrc Acrd (65%)
:
Fluorrne (Lrqurd)
FIUOSIIICIC
Acrd (50%) _........
Formaldehyde (37%)
..,
formtc Acrd
.._.. ..._..L :j
_: __L_
?RTiztT~.r.~
FA tlydraukc flurd
._.....
.._
FRM (Code 6SS22)
_.....
Freon 114
.._.
Freon 12 ,,
_._..~-_~_ll...

rid asz:::::...:... .._.


Fumarlc Acid ._..... ,...,..,..

Furan (Furturan)
.._......_.......
..__.
Furfural (Ant 011) .._.....
Fuse1011
~1:_~1~_
Fvmuard 150. 200
.._
Fyrquel 90. 150. 220. 300. 550, 1000. 15R60,
220R&O, 550R&O .,...._..
.._...
Frrtec 290, MF ,.,..__........
..,.,.
.,.

._

Y.
X

I 1

!
:
:2

22

2
2

:
2

:
1

hc*cx
x

1
I
SDEC a, b

)ec

z-

X
2

I:

Galhc Acrd.. ....................................... .............


Gasokne (Standard) ...........................................
Gasoline iPremIum j ........................................
dasolme (Unleaded Up To 50% Aromahcs) ........
Slat&rs Salt .....................................................
3lucose .._...,_..,..__..._....,........,,.....,......................
3lue ._,....,,_...__..._,_......,,.,............,,,....
.__,..,..........
3lycerme (Glycerol) ._...._____..._..,...,..........
SOIS
..
.
.
;lycol FR Flurds .__...__.......__.._.............,................
irease ..__..._._._,._................................................
ireen Sulfate Ltquor ._.._____._.._._.___.......................
;ult FR flurd G-200 ._.._.._._._.._..............................
,ulf fR FluidP.37. P.4.6, P-43.P.45T47

talowax 011.................................................
larness @I. .............. II ......................................
teptane.. .........................................................
IFiexaldehyde .................................................
lexane ................................................................
lexene .................................................
..........
L
lexyl Alcohol (Hexanol) ................................... .
loughto Safe271, 416. 520. 525, 616, 620.
625, 640 ......................... _...............................
loughto. Sale 1010, 1055, 1115. 1120. 1130..
bughto Safe 5046, 5046W .........................
0 Cover stock rating only, rating for tube stock X.

(continued)

Comparative

TABLE 7.3:

POLYMERIC

HOSE AND STEEL, ALUMINUM

Resistances

of Materials

AND BRASS COUPLERS-GATES


HOSE POLYMERTYPES

CtEutCAl

Ds
Dt
D
M

AZ

Cz

Cs

817

of Construction

RUBBER

(contd)

CDUPLING MATERIAL

kcm or 304 316 ALUM.


BRAS
CarborSS SS
Steel

-Continued

Monoethanolamme
Mould 011
MurlatlcActd (Hydrochlorrc)
Mustard

2
X

:
.I./

I.

:
x

1
I

N
Naphlha (Low Aromatrc Content**)

.,

Naphthallnet

Natural Gas
Neutral 011

:... . ..

.._

X
X

.,
Nickel Chiorrde
:
Nrchel Nitrate
.._.
Nrckel Platmg Soluhon
,..
:
Nrchel Sullate .,,.
Nrcotme Salts
.,. ,..
;
Ntler Cake (Sodrum Bwltate)
Ndrrc Acrd (10%) ..,.....
!
Nrtrrc Acrd (25%)
Ndrrc Acrd (40%)
.._._..........
i
Ndrrc Acrd (60%)
..,...
.._.....
Nrtrrc Acrd (Red Fummg) ._..
x
Ntlrobenzene ._.....__..._...........
2
Nitroethane ._._.....,.._...........
.._.
....................................
Nitrogen ...........
..........
1
Yttrogen Tetroxrde ..........................................
............ 2
Rrtromethane ....................................
x
Vitropropane.. ..... .................... ............ ...........
Ydrosyl Chlorrde. ......... .......... ..............
Yvvac FR Flurd ...............................................
Yyvac FRZOOflurd
x
bvac 20 (WG). 3D(WG)
.._..... ,.......
i-Mane
.._._.....,.

x
x

2
x

x
x I ii I 1

Contact De;vl er

i
:

:
i

2
2

1
x

;
x

;
x

:
X

:
x
x

:
X
x

x
x

x
x

x
x
2
1

z
2
1
2
2

!
:
;
x
2

i t
No Hke AvaIlal ble

x
x
:

:
x

1
1
:

xI-I2l~IxI2

0
:
Y (SAE) ...........................................................
:
i
)lerc Acrd ...........................................................
x
Ileum (Fumtng Sullurtc Acrd) ............................
x
2
)Itve Oil.......... ...................................................
2
)xahc Acrd ..........................................................
)a ygen ................................................................
x
2
Izone ..................................................................
ktyl Alcohol ....................................................

!
2

:
2

:
X-

horone ..____.....................................................
hosohonc Acid(50%)_(
.,,.,....

hosohorlcAcid (85%)

.._..._............................
cri; Acrd (Water Sol&n). ..............................
me 011...............................................................
inene ................................................................
prazme Hydrochlorrde S&Don (34%) ...........

* ForSpecial NaphlhasContactGates
t

Soba At Room Temp

- - -

.....
acemaker Types 1501.3001.5001 (Cdgo)
amt ...................................................................
aim Drl ..............................................................
lalmitic Acrd .......................................................
araffm (Petroleum) ..........................................
aralormaldehyde ....................... . .......................
eanut 011...........................................................
ennant Motor Dds .............................................
erchlorrc Acid ....................................................
erchlorocthvlene..
......................
I.......................
entatol ..............................
etrokum 011s.....................................................
henol (Cartwhc Acrd) ........................................

. Check

Solvents

f(5*) 0

x
:

;
:

F1x
x x
: :2

c:

2
x

:
x

f
e
:

-5 +2
X

;?

x
i

2
x

x
x
i

x
x

i-

2
2
L

2
X

2
X

Fluid dlscoloratfon may occur under cenam condmons


Tesmg on lhe actual appkatlon for sultablllty IS recommended

(continued)

818

Corrosion

TABLE 7.3:

Resistant

POLYMERIC

Materials

Handbook

HOSE AND STEEL, ALUMINUM

AND BRASS COUPLERS-GATES

DJ
02
D

AZ

Cz

C3

(contd)

CCMFLING MATERIAL

HOSEPOLYMER
TYPES

CHMICAL

RUBBER

Iron u

304

316 ALUM

Carbor

SS

SS

Steel

1
AS

P -Continued
Pla!mg Solution (Chrome)
Polyester Resin
Polyurethane (lo Iii
f )foam
Potaswm Acetate
Potaswm Carbonate
Potaswm Chlo:ate
Potassium Chloride
Potaswm Cyanide
Potasstum Dlchromate
Potasswm Hydroxide !3@?) (Caustic
Potaswm NItrate.
Potaswm Permanganalf
1
Potasswm Sulfate.
Potasswm Sulfite
Pakwll!tY
IMe!)
.1....1. ~.
:
Prlmatol A. S. P (Agrlc Sprayi
Propane Gas
Proplow Acid
Propyi Acetate
Propy Alcohol (Propanoli
Propylene (Llquld or Gas)*

Potash).

Purma lnseckfde

.._..
Pyronai (Transformer

011)

Q
Qumtolubrlc

1 I

822

I 1I l I

I l II

R
Ramrod(Ag
Spray)
Rando 011s
Rape Seed 011
.,,,
--~Acid)
Red &I (Comm. Olelc

.__
.._.....

Regal 011s R&O


_..............................
Ruklene 011s .._.._...............
.._............___............

____.__S

iiltconeGrease
illlcone:.

t 150.

.._...___..__.....................
-__
.. ...

*Only tf temperature

IS above -45F

(continued)

Comparative

TABLE 7.3:

POLYMERIC

HOSE AND STEEL, ALUMINUM

Resistances

of Materials

AND BRASS COUPLERS-GATES


HOSE POLYMERTYPES

DJ

CHMlCAl

AZ
A

of Construction

Cz

Ca

It

RUBBER

879

(contd)

COWLING MATERIAL
W

Iron or 304
Carbwl SS
Ski

316 ALUM BAA


SS

S -Continued
Sodium Acetate
Sodium Bicarbonate
Sodium Blsulfate (NlterCakej....

..I.

Sodtum Blsulllte.

Sodturn Borate.
Sodium Chlorfde
Sodium Cyamde
Sodium Fluorfde (70%)
: :I.::.
Sodium Hydroxide (40%)
Sodium Hvdroxide (50%. 115 f ).

,.
1:
..

__
Sodturn H;pochlorrk (5%)
Sodlum Hypochlortte (20%)
Sodium Metaphosphate.
Sodium Nrtrate

5brnPiZate

Sodium Perorlde.
Sodium Phosphates
Sodturn Sulhte.

S&p&oh_losulfate
(HP01

.._....
_

Sodium Trqmlyphosphate (STPP)

Solnus
011s

Solvac 3535G...

.._.._....

Soybean011..,,.,.......,...
SpentAcid..

.._...

Stanmc Chloride...
Stanorl No.15. 18, 25. 31. 35. 51
._.......
jtautler Jet 1 .,...
jtautfer Jet 2... .._.............

jtaysolFR

steam...._.........._......
jtearlc Acid
jtoddard Solvent
jtyrene (Monomer) .._.........
iucrose Solutions ...... .............. ........
;ulfamrc Acrd (10%) ....................................
iultamtc Acid (10%. 170 f ) ............. ......
........
iulfur (200 f.) ...............................
Mur Chloride ..................................................
iullur [horIde (Dry) ................. ......................
.......T
;ulfur Trroxrde (Dry) ...........................
iulfurrc Acrd (10%) ..........................................
iultutlc Acid (30%) ..........................................
iutiurrc Actd(50%) ..........................................
iulfurlcAcrd (75%) ........................................
............
,ulfurrc Acrd (93%) .............................
;uliurlc Acid (98%) .........................................
;ulturw Acrd, fuming ..........................................
;ulfurous Acid (10%).........................................
ulfurous Acid (75%) .........................................
un R&O OllS......................................................
,unsale F ............................................................
untac HP Oils ....................................................
untac WR 011s....................................................
unvrs 011s700, 800, 900 ...................................
uper Hydra& 011s (Conoco) ...........................

I-

se N

--_

t
X
HOSI
2

1
;

;I
X

..................
yrup...............................................
T

t (5%)

:
2

03 flwd (Conoco)............................................
ynthehcOS(Cltgo)........................................

X
X
all01l (To 150 f.). ........................................
2
allow ................................................................
2
X
anmc Acrd (10%) .............................................
X
X
ar(Brtummous). ........................................

e On

X
2

X
2

2
2
2
2

ConsultlnausfrtalHoseCalalog39993ForSelecfmgTheCorrectSteamHose
(continued)

Corrosion

820

TABLE 7.3:

Resistant

POLYMERIC

Materials

Handbook

HOSE AND STEEL, ALUMINUM

AND BRASS COUPLERS-GATES

01
02
0

ii

AZ
A

Cz

(contd)

COUPLINGMATERIAL

HoSf POLYMERTYPES
CHLlCAL

RUBBER

boil or 304
Carb
SS
Skel1

316 ALLM
SS

T-Continued
Tartax Acrd
Tellbs 011s
Ten0 011s.
Ter !o!
Terpmeol
Terresshc
Tetraethyllead (TEL)

..

.. 1

IetraTydrsfuran W)

Tdanrum Tetrachlorrde
Toluene !Toluol)
loluew Onsocyanate
Transformer 011 (Petroleum lvpe)
lrans!ormer 011 (Askarel Types)
Transmrssron FlGrd r lvpe AI
Trrbutoryethyl Phosphate
lrrbutyl Phosphate
Trrchloroeth lene
Trrcresyl Phosphate
Trrethanolamme (TEA).
..I.
Trrpoyphosphate (STPP).
lung 011.
.._...
Turpentme
Tyco! Avaion 50. 51. 60
Tycol A Turblo 37. 50. 58. 60

2
X

:
2

X
X
x
x
x
X
X

!
x
x
X
2
x
x
1

x
x
2
x
:
:
2
x
X
X

:
x
x

:
X

:
x

X
x
x
X
x
x
x
2
2
x

x
x

x
x

1
x

1
X

x
X
X

:
2
x
2
X
X
x
X

2
X

:
1

$X

U
UconMl

Ucon Hydrolube Tyksl~OCP: ZOkP. 275CP.


3OOCP.55OCP.9OOCP.150OB. 2750B. ISOtT.
ZOOLT.275Ll. 30011. ZOONM. 300NM
Urnon C-2 Flurd. ,.,
,, ,,
Urnor C P 011.
Union ATT Oexron
., .
Umon ATF Type F
.._...
Jnror ttydraultc 011AW
Jnror Hvdrauhc Tractor Flurd
Jrea Soluhon ..,
..

1
X
X

x
x

2
2

2
x

x2
x

x
x

x
x

:-

i
X
X
2

V
larmsh
_.
legetable Ok**
lerwlube F.50 , F.44 _..
lmegar
..,............._._..._........................
lmyl Acetate
.._..._..
lmyl Chloride (Monomer) ................................
lmyl Fluorrde ................................
.............
Mrea 011s
.._....._._._........ ..__......

x
2

x2
x

x:
x

x2
x

1
2..

-11

2
1
1
x

i
x
2
1

w
Vater .................................................. .............
Vtnese ............................................................

I ; I 1 I ! I ! I :

i
i
1
1

1
1
1
2
1
1

I ! I ! I ! 1 ! I ! I ! I ! II : 1:

1
1

1
2

2
x

1 ; 1 ! I :

X
.ylene

..,.......,...,............

I x I x I x I x I x I x I x I x IO1

._

I1

I2

II

I2

I1

I2

errc

..,..,....,,,..,.._
mcMate ,,.,.,.. ,..._ ._..
mcChlorrde Solubons
Chromate
rnc Sulfate Solutions~

_._....... _...._.

:
2

2
2

mc

A (20%)

.._

-011 Contamrnahon May Be A Pro&m

2
l

1
1

4;

* Use Food Grade Hose Only.

1
2

1
0

1
l..

Fluid discolorabon
may ocwr under certain condttions.
Testrng on the actual application for suilabiltty is recommended.

Comparative

TABLE 7.4:

RUBBER,

Resistances

of Materials

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER

of Construction

821

AND WOOD LINING

Table A lists all those solvents denoted by a letter in Table B and should be referred to when indicated in the chemical listing. Always use the lowest temperature
recommendation
shown for either the chemical or the solvent. Table B
shows lining materials, chemicals, solvents, concentration
and temperature
limits for use. The lining materials are described across the top as column headings. The various rubber groups are listed in their approximate
order of relative
cost, with natural rubber being the lowest. The chemicals are listed on the left hand side. These tables contain not
only the common names of the chemicals, but also any names which may be synonymous.
To the immediate
right of the chemicals is a list of letters that denote the common solvents for the chemical.
In
some instances, a reference is given to See Solvents. This indicates that the chemical is solid, insoluble in water.
The chemical will be dissolved in a solution of one of the indicated solvents or a solvent characteristic
of the application. In the columns headed Concentration,
either the word Any
or a percent concentration
will appear.
Any concentration
refers to a water solution of chemical from very weak to a saturation value. The percent concentration refers to a limiting ratio of chemical to water in weight percent. If the concentration
is left blank, then generally that chemical will be used in its pure form and not in solution with any other compound.
The temperatures
shown in the tables are for pure chemicals. The rows of figures to the extreme right of the chemicals, each in a column for a given lining material, indicate the maximum
recommended
temperature
which will give
satisfactory service with the tank lining. In some instances, a lining material will be given a rating of 75F for a particular chemical. This indicates that the chemical was determined to be satisfactory at room temperature,
has a possibility for use and could be tried at somewhat higher temperatures.
A blank space in any material column indicates
no available data.
Code: Unmarked
chemicals are liquids at room temperature.
gas at room temperature.
xLining material not recommended.
Table A:
CHEMICAL

RESISTANCE

FOR LINING

MATERIALS
CoCetratl0

*Indicates a solid at room temperature.


-No information
available.

Solvent

a
5

3
2

zi

$3

g,

Sd

rd

62

I
110
I
la5
150

Code
I

e
0
2

$2
2%
lia

110
x
x
180
2oo

110
x
x
150
150

loo
180
loo
1oiJ
150

ii
0
z

:
P

la5
loo
150
150
185

120
x
x
200
2cxl

150

150
loo
130
x
x

200
loo
loo
x
x

2io

115

120

175

150

x
75
75
170
150

140
70
150

x
170
150

x
170
150

150
70
110
70
100

150
go
70
70
70

go
90
170
70
150

150
70
110

100
110
100
125
150

130
110
100
100
150

f5
110
loo
loo
150

x
70
170
70
150

150
70
70
75
150

70
70
70
75
75

CY
dg
dt
e

Cyclohexanol
lItethylene Glycol
bxane
Ether
Elhyl Acetate

AY
AY
AY
AY
AY

x
150
x
x
x

x
la5

x
180
80

a0
180
x

x
180
x

150
x

loo

Ethylene Dlchlorlde
Elhvlene Glvcol
Es&
Ferc Salt Solul~ons
Gasolme

AY
AV
A;

x
la5

x
185

x
150

x
180

x
150

AY

x
150
x
150
x

150
x

150
x

200
100

150
loo

Glycerine
Acid Solutions Except
Organic Actds

AY
AY
AY

150
150
loo
x

150
150
70

la0

110

150
120

Hydrochloric (HCI)
Sulfuric (H2S04)
hc

NMc (HN03)
Hydrocarbons

ho
k
ke

Alkalme or Bass Solutions


KerOSee
Ketones

m
me
rno

Methanol

38
50
25
AY
AY
AY
AY

150

a0
x
x
150
x

AY
AY
A;
AY
AY

0s
Pe
ph
PY
I

Organic Solvents
Petroleum Elher (Llgrotn)
Petroleum Hydrocarbons
Pyrldme
Toluene

AY
A;
AY
AY
AY

x
x
x
x
x

Tanax
Ac!d
Turpenf~ne
Vegetable 011
Water
xyksne

AY
A;
AY
AY
AY

150
x
x
150
x

ta
tu
0

w
XY

134 100
75
x
185

x
x
100

hlonobutyl Ether
MIneral Oil
Naphlha
MIneral 011s

la.5

x
x
x
x

1I

x
loo

110 x

10
x
ao
200

a0

I(

a0
1;
150
150

120

loo

a0

x
x

x
ao

130

x
a0

x
130

a0

130

x
x
x
loo
x

185
x
x
170
x

ia5
x
loo
la5
x

x
x
x

loo
150
70

150
110
150

100
x

a0

io

la5
a0

a0

x
x

x
x

100
x
x
200
x

150
150
150
150
x

x
75
75

110
x
x
x
x

io

a0

x
x
75
x

75
140
110
150
170

x
x
150

a0

70
75
70
180
70180
70
130
70
210

120
120
go
x
170

120

75
75
75
75
75

150
70
loo
70
70

a0

x
x
75
75
75

150
loo
75
x
170

x
x
x
x
x

150
120

210
180
180
210
210

x
200
75
75
loo

x
x
x
x
x

70
70
180
130
100

x
x
x
x
x

75
75
75
75
75

x
loo
70
70
130

x
x
x
x
x

la0

75
x
75
x
x

70
170
loo
70
loo

x
x
x
x
x

18

210
400
210
lao
190

70
130
loo
70
75

AY
AY
AY
AY
AY

210
x
210
75
70

loo
75
180
130
70

Benzene
aulyl Acetate
Carbon 51 (01) Sulhde
Chlorolorm
Carbontetrachlorlde

a0

3
z

loo
70
70
130
70

b
ba
cb
Cl
ct

ed
ea

!z
s

loo
70
75
x
75

AY
AY

150

70

130
I

75

70

70
150

150
I

75
75

150
70

b:
d

B
s

150
170
180
75
75

a0
70
x
150
150

eS

210
170
180
go
75

Alcohol
Acehc Acld
Acetone
Alummum Salt Solur~on
Ammoma Salt Solur~on

150
75
400
x
x

a
aa
ac
al
am

P
0

z
<

Solvenls

ea

$
rii
P
ti

lDo5
&?i

Index

AY
AY

**Indicates

150

70
I
170
70
x
x

loil
75

100
150
x
70
170
75

210
210
140
210
170

75

x
x

75
75

210
250
230
210
4oo

x
x
x
x
x

75
75
75
75
70

4oo
75
x
170
180

210
110
170
75
170
130
140
130
210
150
175
210
170
75
75

75

75

70

70

75

75

x
75

75

75

75

75
x

75
75

75
I

75

(continued)

822

Corrosion

TABLE 7.4:

Resistant

RUBBER,

Materials

Handbook

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)

AND WOOD LINING

Table B: Chemical Resistance for Lining Materials


The list of Chemical
shows
recommended
concentration as water
chemicals insoluble in
reference to solvents is
CHEMICAL

RESISTANCE

FOR LINING

MATERIALS

Resistance of Lining Materials


maximum
temperatures
for
solutions against the lining. For
water, 100% liquid is listed or a
given

is

eE

sz
LE
Acelaldehyde

Any

75

Any
10
25
50

x
150
80
*

AY

a. e. w

1w
25

x
x
*

Aceftc Ester
Acehc Ether
Acehc Oxide

a. Cl. e. w
a. Cl. e. w
a. e. w

Any
Any
25

ACetOne

a. Cl. 8. 0. w

Any

x
x
x
*
x

Aceloacel~c Ester
Acetophenone
Acelylbenzene
Aceryl Chloride

a. w

OS.
w

Any

AY

80

0% VI
a. ac. e

AY
Any

Acetylene

a. ac. w

AY

:O

a. e
a. e
a. 8. w

100
100
25
50
150

8.
n.
a.
a.

Acetamlde
Acellc Acid

icehc

Aldehvde

ac. b. e. g,
I, I. xy, w
e. w
e. gl. VI

a. ac. b. e. o.

120

80

80 x

210

75

180 x

600

220
210
180

75

180

180
180

x
x

400
4OG
400

x
x
x

75
75
75

125

210

210

75

600

400

x
210
210

75
*
x

*
x

x
x
*
x
75

75
75
I
x
75

n. 1. 1. xy. w
GlaClal

Acellc

AnhydrIde

Acetylene Telrabromtde
Acetylene Telrachlorlde
Acefyl Oxide
Acrylamlde

50

50

80
120

x
150

x
x

x
x

200
x

75
80
80

180
170

180
180
180

:o
70

loo
100
150

x
x
x

x
x
x

x
x
x

75
75

120

75
75
170

150

loo

400

loo
100
180
180
160

130
130
70
70
160

210

210
210
,210
210
210

80 x
801

x
x

60x

x
*

x
x
x.
.

75
200
200

170
350
350

75
150
150

150
150

75
175
175

200

400

180

75

75

75

75

75
170
170

75

180
180

70
70

x
x

80

120

80 x

80 I:

i0

i&l

80

60

150

80x

OS. w

AY

80

80

Adlplc Aad
Agar-agar
Agricultural
Ax

w
aa. gl. v
gl. h. w

AY
AY
AY
AY

80
150
150
150

60
185
165
185

x
185
185
185

x
x
180
180
200
200
200200150

AY
AY
AY
AY

150
80
x

185
x

li5
165

200
120

70
200
110

AIrshow
Air-slaked
Alcohol
Aldehyde

gl.
a.
a.
n.

Lame

h. w
e. w
ac. b. e. g,
1. tu. *y, w

x.

80 x

lrw)
100

loo
150
125

200
210
210

x
150
210

x
210
75

x
210
600

75
75
x

75
75
x

75

x
75

125

75

75

75
I

x
x

125
100

x
x

x
100

75
x

75

x
75
x

70
100
2w

70
loo
110

x
100

200
210
170

x
x

75
75

150

75

75

210

75

180
75
70
75

Ii0

II
75

180
180
x

f5

x
75

x
x
x
x

75
150
200
180

100
70
x
x

100
75
100

100
200
75
200

x
180

75

75

100
70

180
70

x
100

x
75

75
75

75
75

210

150

150

75

160
210
100
210

200

75

210

75

80
*
200

80

130

loo

185

150
185
185

2iO

150

210

AY

150

165

120

120

120

AY
AY
AY
AY
see Solvent

150
150
150
150

185
185
165
185

15c
120
150
185

120
180
200
200

120
180
200
200

150
150
150

220

150

165
165
165
185

185
200
185
200
165
200
185
200
___~~
160
200
75
x
100
x
140
80

200
180
200
200

150
150
150
150

75
200
200
200

18C
x
x
80

150
150
I

ho
ho
ac. w

Amewa
Ashes
Ammobenzene
Ammod!methylbenzene
Amlnoelhanol
Amlnoxylene

w
a.
a.
a.
a.

Ammoma Alum
Ammoma Water
Ammorxated
Cwc

gl. w

Ammomum
Ammomum
_

Acid

Bjtluotlde
Carbonate

aw
w

b. e
e
Cl. ct. w
e

210

150
110

120
II
1M

Hydroxtde
Nwile
Polawum
Sulfate
Sodwm Sulfate
Sulfate

x
x

75

50

Alummum
Alummum
Alummum
Alummum
Alumtnum

x
x

75

a. a. 91. w
a. Cl. e. w

w
e. Cl. w
8. w

75
210
210

x
x

gl.
a.
a.
w
____ h.
h.
a.
w
w
w

75

x
80

Sulfale

75

175
x

100
100

Ammomum
Bromide
Chloride
Flourlde
Gel

75
75

70
200

a. Cl. e. pe
a. e

Alummum
Alummum
Aluminum
Alumtnum
Aluminum

x
100

Alpha
Alpha

h, ho
w

2aO
100

see Solvent
100
AY

AY
AY
see Solvenls

200

70
70

150
150

HCI
a. Cl. e. pe
a. w

Alpha Hydroxyproplonac
Aad
Alpha Hydroxytoluene
Alum
Alumma Trlhydrale
Alummum
Acetate Solution

Algaroth Powder
Ally1 Chloride
Allomaleac Aad
Chloropropylene
Chlorotoluene

120

Acrylon~tr~le

Lame

75

210

75

See Solvent
AY
AY
AV
A;
AY
100
100
AY
100

150
150
150

I 50
x

185
x

;o

100 x

x-

150

AY
36
AY

150
150
150

185
150
185

120
185
185

120
200
150

120
200
110

1so150
150

200

75

180
200

75

10
AY

x
150

x
185

x
185

x
200

80
x

100
150

70
75

x
140

x
70

150

100

100

I
200

75 --

70
75

(continued)

Comparative

TABLE 7.4:

RUBBER,

a. gi, iv

Ammonium
Ammomum
Ammomum
Ammontum

a gl. w
a. ho. rv
w
w

Ammomum Sulfate
Amy1 Acetate
Amyl Alcohol
AmyI 8oraie
Amvl Carbmol
Am;1 Chloride
Amy1 Chloronaphthalene
Amyl Hydrate
Amyl Naphlhalene
Anderol L-774
Anhydr:re

Anv
AV
38
38
AV
Any
Any
A;
Any

a e
a. e

AV
100
AV
A;
I0
100

a e.w

A?

a. e
a e w

AV

tgl. ho

See Solvents

a. b e
a. e. w

100
AV

e.

a,b
AnMe

Salts

Anl~mony Chloride
Anl~mony Oxychlorlde

A!Ty

loo--

a. e. w

a,b

100
Any

HCI
HCI
a. e. w

See Solvent
See Solvenl
AnV
30
See N~trtc Acld

Aqua Regla
Arachtdontc Acad
Aragonlle

Arsenic Acid
Arsemc Trlchlorlde

a. gl. ho. w
Cone HCI. ps

See Solvent
Any
100

Apple Aad
Aqua Ammoma
Aqua Foms

Askew (Translomer 011)


Asphalt
ASTM Oil Il. 2 h 3
ATE
Aad

Azo11c

Baking Soda
Banana 011
Bardol B
Barium Carbonate

150
80

150

150
150
150
150
150

150
150
x
150
x
x
x

.
hc

100
See Nltrlc Acld

Any

a, e

100

200
100
200
200
200

200
too
200
100
200

150
80
150
150
150

200
180
200
200

x
x
75
75
70

100
x
200
200
100

x
x
75
75
75

:0
1w
llxl

185
150
185
185

185
I85
185
185

200
200
200
200

200
200
100
200

150
150
150
150

200
200
180

x
80
x

100
200
70
70

x
140
x
x

x
x
70
70

210
210
210
75

185

185
x
180
x

200
x
180
100

200
x
180
100

150
*
150

200
75
200

x
75
70

150
70
70

x
70
75

70

210
210

150

_x__x
x
180

120 100
x
-75
80

150
x
150
x
100

75

75

150

:5
185
150

100
x
160

;
x
150
x
160

80
150

150
150

x
185

x
150

x
100

x
x

:o

120

x
x

150

x
x

II

x
85

70
x

70
I

100
x

75
x

210
210

75
I

75
I

100

140
70

100

100
70

210
210

75

120
80

140
200

x
75

150
200

75
75

75
100

150
210

x
75

io

200

2cM

2LO

75
400

75

75

150

II

150

75

75
170
170

170
170

75
70
170

170
170

75
170
170

1w
75
170

150
70
170

I
70
170

170

150
200

150

$0
180

1:o
150

150
x
x

185

185

200

200

1M

h (except H2S04)
w

See Solvents
AV

150

185

185

200

200

150

Barium
Barurn
Barwm
Barwm
Banurn

a.
a.
a.
w
a.

Any
Av
AY
AV
AV

150
150
150
150
150

185
185
185
185
185

185
185
185
185
185

200
200
200
200
200

200
200
200
200
200

150
150
150
150
150

Bawm Sulfate
Barium Sulhde
Bar~te
Basu IrOn Sulfate
Battery Aad
Beer
Beer Sugar Liquor
Bengal Gelatm
Benzaldehyde
Benzene
Benzene Carbanol
Benzene Carboxylc Acld
Benzene Sulfomc Acid
(Llgroln)
Benzolc Acld

BmZlne

Benrou
Be201

Aldehyde

Benrol Hydride
Benzophenol

e. w
e. w
e. w
e. w

Cone

H2S04

:onc
v

H2S04

See Solvent
Av
See Solvent
AV
See Sulfunc Aad

200
200

-.
-

150
210
170

7s
*

75

75

70

120

75

1w

75

100
100

150
150

x
x

x
x

180
180
180
100
180

75
75
75
75

x
x
x
x
x

100

150

75

100
loo

150
150

x
x

x
x

185

185

200

200

150

180

100

150

loo

185

2w

200

150

75

70

75

210

80
80
185
x
I

80
150
185
75
x

80
80
180
x
x

80
180
x
x

80
150
150
x
x

170
170
70
150
loo

170
170
175
70
loo

170

200
x
x

70
170
x
x
loo

170

AV

80
80
150
x
x

x
70

210
210

75
x

75
75

Any
AY
10
loo
AY

x
150
x
x
150

x
150

80
150

1;o
-

x
75
200
200

x
x
x
110
x

150
150
120
110
150

70
150
x
110
150

x
x
70
x

210
210
210
140
210

75
75
-

150
140
-

75
x
-

x
150

75
70
x

75

Any
Any

x
x

75
x

x
x

x
x

150
x

x
180

x
loo

150
loo

70
loo

x
70

210
210

75
x

75
75

Any
AY

x
x

loo

150
x

x
x

x
110

150
200

70
175

x
70

210
250

75
I

75

Av

91.0.w

75
75

-.

75
x

1.35

am, em, w
a, aa, ac. cb.
ct. e

9. e. w
P. aa. ac. cb,
ct. e
a.. aa. ac, cb. 0
a. ab, cl, e. ho.

75
I

150

a. w

170
100
x

150

aa.91.w

a. e. w

1
75

-.

Barwm Chloride
Hydrate
Hydroxide
Monohydrale
Monosulfrde
Oclahydrate

-.

75

75

75

75
210
210
170
210

150
150

75
x-

200
70
x

x..

170
70
x
75
*

:o
150

140

x
150
*
x
x

I:
x
x

.x

70

-.

09
r
I
I
I

x
60
x
x
100

150
x

70

100
*

75
x

100
75

x
x

l&l

150

x
x
x
x
x

75
75

140

210

x
x
80
80
80

x
I(
75
75

2:o
210
210

70_x_mm

:a0

210

x
180

823

AND WOOD LINING

1.35
150
185
185
185

x
x

of Construction

185
x
185
x
185

x
150

100

Anhydrous Ammoma

Anwnal Fats
Ant 011
A,,chlor.

of Materials

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)

Ammanlum Chloride
Ammonium Fluoride
Ammonwm Hydrate
Ammonium Hydroxide
Ammonfum Metaphosphale
Murate
Nitrate
Persulfate
Phosphate

Resistances

.
-

(continued)

Corrosion

824

TABLE 7.4:

Resistant

RUBBER,

CHEMICAL

RESISTANCE

Benryl Alcohol

BenrylBenmale
Banzyl Chlonde
Betula 011
Btsmulh Carbonate.
Bwnulh Oxvcarbonate
Bwnulh Subcarbonate
Black Sulfate Liquor
Black Ash
Blanc Flxe

Materials

Handbook

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)
FOR LINING

MATERIALS

a. Cl, a. w
a. Cl. e
a. e
aa. a. v
HCI. HN03
t-0. t-IN09
HCI, HNOj
&K
H2SO4

Blast Furnace Gas *

AY
100
Any
see Solvents
See Solvenls
see Solvents
Any
Any
see Solvents

loo
200

200
200

150
150

200
75

x
150
130
150
150

75
75

AY

175
185

150
150
185
185

I(
80
200
200

1:o
200
290

AW

150

175

105
150

200
60

200
180

AY
AY

a. b. cb. cl. e

See Solvents

a, cb. cl. a. w

100

200
200

180
180

150

150

150
150
150
I

185
175
la5
.

185
185
185
150

200
200
200
loo

200
200
200
150

150
150
150

x
x
x

I:
x
x

x
x
x

x
x
x

x
x
x

x
.
-

x
.
.

OS

Any
loo
loo
loo
AY

;o

Go

a, w

x
120

x
-

130

91. w

Any
Any
loo

80
200

150
150

x
x

:o
x

150
200
70
loo

Any

x
185
x
x

x
185

a. e. w

x
150
x
x
x

a. e. w
a. a, 0. w

Any
Any

150
,x

150
x

150
x

x
150

.
-

180
x
150
75

150

150
x
x
x

185
x
x
x
150

AY

OS

Ph.maw

AW

150
70

170
x
75
75
x

170
200
75
75
200

170
110
75
75
70

170

170
170
75
75
210

150
loo
.

150
loo
.

70
150
loo
.

150
150
.

210
180

I:

210

1w
70

75
70

210
180
.

x
x
.
-

;5
.
.

150

loo

150

75

f,
180

x
_

x
l5g

x
m

150
150

x
75

x
x

x
x

75

.
l4q

:5
.

70

.
.

75

loo
75
.

.
.

75
x

x
.
170

.
-

75

.
-

.
.

loo

loo

150

180

.
.
.
.

75
.

75
.

75
.

75
_

.
_

.
.

75
75
-

.
.
75

_
.

200

140
x

75
75
.

I
_
.

210
_
.

x
.
_.

x
.

70
70
.

MO
80

150
-

1w
210

x
150

letI
150

x
75

lW2w
210

x
200

75
75

x
120

120
200

150

130
75

70
x

130
180

70
I

75
75

185
185
185
185
150

200
200
200
200
I

200
MO
200
203
80

150
150
150
150
150

200
2w
loo
200
200

140
140
loo
rw
70

150
130
200
200
70

185
150

It35
185

200
x

200
80

150
150

loo
70

185

185

150

290

150

loo
75
200
75

loo

Euytric Alcohol
Cajaputene

x
180
x

x
150
x

150
x

Cake Alum
Calamme

w
a. Cl. ct. w

Any
Any

200
80

Calclne
CalcIte
Caklum
Calcium
Calcium

150
185
185
80
140
__~_~.._._-..-

h
a. w
a. w
h

see Solvenls
Any
Any
see Solvents

SO
120

150

180
120

a. w
a. w
gt. h. w
gt. h. w
w

Any
Any
Any
Any
15

150
150
150
150
80

la5
185
185
150

a, ac. w

Any
15
See Solvents
Any
Any

150
150
150
80

;. ho
h. w

210
150

x
-

Liquor

70
70

x
x

mo, 0
r-no. 0
mo. 0
w

x
70

x
x

loo
loo
see Solvenls
see Solvenls

e.
e.
8.
8.

150
130

.
-

a.
a.
a.
a.

x
70

75

150
x

.
.
.

loo

x
x

.
.

76

75

150

Any
1w

.
75

150

.
.

150
x
x
x

x
x
x

75

150

150

100
100
loo

180

150
x
*
x

Any
Any

75
-

100

185
x
*
*

x
x

200

75
75
75

150

I
x
x

1&

Any
Any

300
180
300

75
x
75
.

X
I:
_

Nrtrate
Oxychlonde
Sulfale
Sulfide
Slllco-alummate

.
210

130
130
130

140
x

x
150
x

Calctum
Caktum
Calcium
Calcwm
Calcwm

loo
x
loo

150
x
150
150

Calcwm Hydroxtde
Calcium Hypochlonle

200

1w

130200
70
120

.
.

200
.

x
130
70.200.

150
150

75

70
180
70

x
x
.

200
70

1.
70
x
x

100

150

a. a. gt. w
a. e. hc. w

.
-

loo

Any

a, a. w

Any
An;
loo

Calcwm Chlorate
C&urn
Chloride
Calcium Hydrate

x
75
75

x
70

2ou
.

OS
a. cb. I, w

a. e. w
a. e
dg. me
ph. mo. w
OS

loo

Any

Acetate
Bisulfite
Carbonate

130

1w

loo
75

185
185

a. a. w
a. 8. w
a

Butyrlc
AC&d

150

AY
AY

150

I
75
x
x

1w

150

Any

170
loo

-.

:0
150
150

Bulyl Hydride
Butyl 01eate
Butyl Octadecanoate
Butyl stearateBulyraldehyde

150
185

150

w
v
w

Butylamww
Bu1yl Benzoate
Butyl Carbltol
Butyl Cellosolve
Butyl Ether

185
185

Boracoc Acid
Bordeaux MIXtUra
Bone Aod
Brake flwd. Vea
Brimstone
-

Butter Of ZlllC
Butyl Acetate
Bulyl Acetate Rtcmoleate
Butyl Acrylate
Bulyl Alcohol

io

x
x
x

70
x
150
150

gt. w
a. cb. cl. a. 1
a. w
w. gt
WY.gt

Butarol
Butanone
Butoxyethanol
Butter
Butter 01 Tm

x
x
x

80

35
loo

Blue vllrloI
Boiled Lmseed 011
Bolet~c Actid
Borax*
Borax Decahydrate

Bunker 011
Burnt Alum
Butadlane
Butane*
Butanes Acld

75
150

100
a. w
cl. cb, a, 1
gt. w
a. VI

a.

105

x
x
x
x

100

Bleachmg Powder
Blown Llnsaed 011
Blue Cc.ppwas* Copper Sullate
Blue Salts

Bromma
Bromtne Trifluwde
Bromobenzene
Bromochloro Methane
Brown Acetate

AND WOOD LINING

70
I

150
75

140
x
x
x
70

I
x
I
1

210
210
x
2:o

130
70

70
70

x
I

100
210

loo

70

-_

75

x
x
75
75
75

75
75
75
75

75
:5

75

Comparative

TABLE 7.4:

RUBBER,

CHEMICAL

RESISTANCE

Caprolc
Caproxl
Caproyl

Aldehyde
Alcoh&
Alcohol

Capryl Alcohol
Caprylic Alcohol
Carbamlde
Carbllol
Carbazotlc
Carbohc

Actd
Acid

of Materials

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)
FOR LlhihG

z
2

MATERIALS

E
;

;g
Lzz
9 2

COCe-

Callche Liquor
Cane sugar Liquor

Resistances

Solvenrs

trat,0n

a. gl. w

AY

150
150

8. a
a. e

100
100
100

x
x
x

a. Cl. e
a. Cl. e

loo
loo

a.b.

AY

x
x
150

8. w

;;
0%

b
B%

0
5
h

22 022
i9
z$
180
150

185
150
150
lx

x
x
x

185

200
200
a0
x

x
x
x

52
150
200
x
x

lia:s

25,
150

x
x

130
170

150
x

150
150

150

100

a*

z
+

E
2
E

r;G, 5
170
170

75
200

0
_m

ll0

210
170

05

75

75

120 100.
loo x 140
1M) x 140

150
150

loo

825

AND WOOD LINING

+
1%(I)
4

:
-N
p:

of Construction

140

140 -

loo
70
75

70
150
x

180
150
70

180
15o
x

150
x

200
180
210

1.
x

110

200

175

70

250

75

a. b. cl, e. w

Any

a. ct. e.

AY

a. b., e. w
a. b. e. w

AY
AV

x
x
150

x
x
165

x
x
185

x
x
200

x
1.
MO

x
x
150

a0
a0
200

75
75
170

70
70
170

180
180
170

180
180
170

180
180
170

75
75
75

75
75
75

100
AY
AY

x
x
150
150
160

x
x
la5

a0
x
185

x
x
200

x
x
2uo

x
150
150

200

a. b. cl. e. n. 0

700
75
70
x

700
70
150
150
150

350
70
70
150
150

75
lal
x
x

700
210
210
210
75

75
75
x
x
75

75
75
75
75

185
la5
la5
la5

150
185
185
185
ra5

120
200
200
200
200

150
200
2~)
150
150

150
150
150
150

100
140
200

110
100
100
x
100

170
150
200
150
200

200
x
x
I
x

170
x
x
x
l!O

75
75
75
loo

x
75
75
150

150
150
150

x
x
x

x
x
150

75

100

loo

loo

150

la0

75

75

loo

100

loo

150

rao

75

100

gl.ho.0.w
Carbon
Carbon
Carbon

Blsulhde
D!sulftde
Dmxlde

Carbon Monoxide
Carbon Tetrachkmde
Carbontc Acid
Carboxybenzene
CaseI
Castor 011
CallstIc earyta*
Causr~c Lime
Caustic Potash
Caustic Soda

a. b. cb. cl. e

100

a0
150
150
150
150

a.8.w

AY

gl. h. w
a. e. $. w
a. gl. w

Any
AY
AY

Cellosolve
Cellosolve Acetate
Cellosolve Butyl
Celulose Acetate
Cellulubes

JO. ph. w
hc. w
mo. ph. w
ac, ea. ed. xy

AY
Any
AY
See Solvents

Cetyllc Acid
Ceylon G&II
Chalk
Chile N~ter
Ch,le Nitrate

a. e
aa. gl. w
h
a. gi. w
a. gl, w

see Solvents
AY
see Solvets
AY
AY

Chile Saltpeter
Chmabean 011
Chlnawood 011
Chtnese Gelatm
Chloe
Aqueo

a. gl. w
a. cb. cl. e
cb. cl. e. o

Chloride
Chlorine
Wet
Llauld
Waler

Dtoxlde
Gas, Dry

Chlorine Tr,tluor,de
Chiorlnaled
L,me
Chlorlnaled
Salt Brine
Chlorlnaled
Solvenls
Chlorlnaled
Tar Camphor

Chloro~ro&4ene

Oxide

ChlCronaphthalene
Chloro N~tro Elhane
Chlorosulfonlc
Acld
Chlorololuene
Chlorolr~~luoroethylene
ChlCVOX

x
x
x

la5

185

la0

180

150

200

70

175

iao
160

150
150

200
200

1%
15o

150
150

100
loo

180
iao

200
200

75
75

1
x

210
210

75
75

75
75

AY
loo
loo

150
x

la0

150

200

150

150

loo

75

AY
AY

150
x

ia5

ia5

150

200

75
170
170
175

75

aa. gl. w

200
170
150
70

210

12u
180

la0
110
110

120
la0

ho, w
ho, w

AV

70

x
185
x
150

x
x
x
x

x
x
x
x

I(
x
x
x

150
150
x
150

200
200
200
100
la0

x
x
x
150

150
150

150
x

x
x

150

75
75

75
x

75

75
150

150

x
x
x

x
x

150
x

x
x

I
x

x
x

200

I
x
x
x
x

I
x

a. w
Q. e. es. 0. 0s
b. ct. 0

05
a. w
0s. w
05 w
a b. e. o. n. w

CnlorDpropaoe
Chloropropene
ChloroProPvlene

170

180

150

CCllorobromomelhane
Cllorobuladlene
Cloroelhae
Chloroethyl Alcohol
C%rolorm

ClOrOpetee
Chloroprene

x
x
x

75
75
75

150
150

0s

Cnlorohydnc
Acid
Cwxomethane

150
150

Chloroacetlc
Acad
Chloroacefone
Chloroallylene
Chloroazolfc
Acid
Chlorobenzene

a0

a. e. w
a. Cl. e. w
pe

a.Cl.8.

35

x70
70
x
x

100
10
AY
loo
See Aqua
loo
loo
AY
100
AY
Any

a. b. cl. ct. OS.


w
a. e
aw

AY

Acid
x

100

AY

a.
a.
a.
0s
b

AY
100
100
100
100

x
x
x
x
x

100
100
100

I
x
x
)I.
x

ct.0

a. e. ae. b. cl
a. b. ke

x
1.

a0 120 -

x
x
x
a0
x

x
x
x
x
x

x
x
x
x
x

a0

x
x

75

70
70

70

75

70

75
210

75
I

15o

75
210

I(

1%

180

x
75
75 ___

75

125

a0

150

150

150

1M

210

x
x
x
x
x

150
75
200
150
x

150
125
200
150
130

x
70
150
150
130

70

x
140
x

150
150
130

210
210
210
210
210

75

100

75

x
75

70
125

x
70

x.

200

75

Regla

See Hydrochloric

Cl. e. w
Cl. e. pe
e. Cl. De

x
x

x
x

x
x
x

x
x
x

x
x
x

x..
x

150

x.
120

100

150

210
210
iao

75
210
210
210

x
x
130
150

125
120
200
150

x
x
75
x

x
x

75
x

a0
100

70
x

100

75

-.

70

75

75

75

210
x
150
x
x
75
150

75
75
75
75

75
I(
x

-.

70

x
x
75
75

75
75
200

x
i

75

(continued)

826

Corrosion

TABLE 7.4:

Resistant

RUBBER,

CHEMICAL

RESISTANCE

Materials

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)
FOR LINING

MATERIALS

COCe,MY)

Solvents
Chrome Alum
Chrome Ammomum
Chromic Aced

Handbook

w
aw
e. w

Alum

AY
Any
10
25
50
80

Chromic Anhydrlde
Chromvxat

5
3

a
2

ZB

$2

$E

$2

?Z

;a

150
150
x
x
x
x

185
185

le.5
185
100
75

200
200

200
200

x
x
x

x
x
x

185
185

200
200

80
200
200
120

See Chromic Acld

Chromium Ammomum Sulfate


Chromium Potassium Sulfate
Cnromum Trtoxlde

a. w
w

Clee
Ctrco Ltghl Process 011
CIVIC Acad
Cleaners Naphtha
Cobalt Chloride

100

a. e. w
a ac.w

AY
100
Any

x
150

185

185
x
185

x
150
150
x
2c3

a ac,w
a. cb. cl. e

Any
100

150
x

185
x

185
150

200
80

a. cb. cl e. ea.

100

150

150
150

150
150
150
120
80

75
75
150
x
x
x

x
x
x
x
70
75

70.

200
200

150
150

75
75

x
x

75
75

x
180

x.
150
150
80

x
AY

AND WOOD LINING

185
185

75
75
70
70
70
x

x
x
70
x
x
x

70
70
130
130
130
130

140
140
210
210
210
210

x
x

70
70

140
140

210

x
x
x
x

x
x
x
x

See Chromic Acld

Cobaltons Chloride

Gxoanut011
codLwc!r 011

x
*

--x
x

-.
200

180

100

170

180

100
75

120

cologne
Spmts

a. Cl. e

100

150

185

150

150

Copper Acetate
Ferrous Sulfate
CoDper Arsenate

Cqweras

a. e. w
w
h. ho

AY
AY
See Solvents

150
150

185
185

185
185

150
200

150
200

150

75

180
70

210

75

Copper Chlortde
Copper Cyanide

w
h. ho

AY
See Solvents

150

150

185

200

200

150

200
200

150

75

Copper Nllrate
Capper Sulfate
Corn 011

aw
gl. w
b cb, cl. e

185
185
100
185
150

200
200
x
120
x

200
200
x
120
150

150
150
150
150
150

120
200

180
180
170
170
70

130
170
170.

210
200
170
170
210

75

x
x
170
170
70

x
x
170
170

a. e, 9. PY. w

150
150
x
120
150

185
175

Corrosw

AY
Any
100
Any
AY

a.
a.
a.
a.
a.

100
100
Any
AY
AY

x
x
x
x
x

100
x

150
120

150
200

140
75
75
75

170
75
75
75
75

170
150
100
100
100

170
,70
100
100
100

170
x
x
x
x

170
210
210
210
210

x
x
x
x

75
75
75
75

x
150
x

70
185

70

x
x

70
70
70

70
x

70
70

70
140

70
70

150

cornSyrup

a. gl.w

Subltmate

Cottonseed 011
Creosote
CZSOl
Cresyl Alcohol
Cresyk Acfd
Crude 011
Cryollle
Cryscoat F H Rmse
Cryscoat HC
Cryscoat LT 8 SW

b,
e.
e.
8.
e.

cb. cl.
0
gl. ho.
gl. ho.
gl. ho,

al. fe

e
w
w
w

See Solvenrs
01

Cryscoal
47.

185

x
x
x

x
x

87, 89. 6 89M


Crystal Ammoma
Cumene
Cupnc Chloride
Cyanide

Cuprc

w
a. b, ct. e
w
h. ho

Any
100
AY
See Solvents

x.
150

Cupc Nitrate
Cupric Sulfate
Cvclohexane
C&lohexaol
Cyclohexenone

a. w
gt, w
05
0. OS, w
OS

Any
AY
100
100
100

150
150
x
x
x

Cylene

a. cl. e

100

x.

DBP

0s. w

AY

100

150

185
150

185
185

200
200

200
200

150
150

120
100
75

x
x
70

180
180
70

x
x
70

130
70

210
200
75

x
x

75

70

70

70

75

150
x
.

150
70

150
70
.

130
70

180
75
.

75
75
.

100

x.

LIecane

100

DeaOl
Decyl Alcohol
Deionized Waler
Denatured Alcohol

a. 8
a. e

100
100

x.

100

150
150
150
80
80
x
x

Damme

a.w

AY

kmmoelhane
Dtbenzyl Ether
Chbromoethane
Wulyl Ether

a. e. w.
as
v
OS

Any
100
AY
100

80
x
x
x

Dlbutylamlne
Dlbul;l Phthalete

P. 8. hc
OS. w
a. b. e

100
AY
100
100
100

x
x
x
x
x

Duhlorobenzine
Dichloroditluoromethane
Dichloroelhane

OS. w

w
a. es, hc. w

150

x
x
x
x

75

150

x
x

70
75

x
x

200

200

70
150

x
x
x

200

100

a.es.hc.

x
x

185

8. e

Dtacetone Alcohol

150
150

150

a. e

Any
AY
AY
Any
Any

180
1.90

185

DealI

a. w
a. w

x
x
x

185

x
x
x.

Developing Solubo
Daacetfc Acid
Dwebc
Ester

150
180
x

x
x
x

x
200

DDT 6 Kerosene
Dscahydronaphlhalene

Dlacetone

x
180

x
x
x

150

x..

80 80
x
x
x
x
x

x
150
x

x
150
x

150
.

75
75
.

-.

150

140
140

100

100

150
150

200
180

150
150

185
80
80
100
100

200
x
x
x
x

200
x
x
x
x

150
x
x

100

100
75

80
x

80
x

:o

140

.
-

x
x

x
x

x
x

75

75
150
70

75

180

loo

x
75

x
x

x
75
75

75

75
75
70

75

75

70
75
75

-.

140
140
-

75

150

-.

150
150

-.

70
200

70
170
170

180

70

75
75

75

75

75
170
75

70
170
x

150
70
75
100

150
130
70150200
70
100
70
loo

170
70
.

210
75
75

75
210
170
75
.
75
180
75
210

:5
75

.
x

.
75
75
75

(continued)

Comparative

TABLE 7.4:

RUBBER,

RESIN, STEEL, ALUMINUM,

RESISTANCE

FOR LINING

05.w

0. OS

1W

Olester Syn Lube 011


Olethylamme
Orethylbenzene
Olethylene Otoxlde
Olethylene Ether

a. w
a. b. ct. e
0s. w
0s. w
a. ac. 8. eg. w

Olethyl Sebacate
Olgalltc Acod
O~hydroxysucc~n~c Aad
Olhydroxydrethyl
Ether
Owsopropylbenzene
01.tsopropyl Ether
01.tsopropyl Ketone
Ormethyl AmIme
Olmethyl Benzene
Olmethyl Carblnot
Olmethyl
Ownethyl
Olmeth$
Ormethvl
olnltro

0. OS
a. e

100
loo
loo

Elher
Formamade
Ketone
Methane

ioluene~

01ocfyl Phthalate
Ovxtyl Sebacate
OlOXXle
OlO*Olane
Oloxethylene
Ether

Ether

70
loo
.

75
75
.

150

120
*

x
*

x
.

75
.

x
.

loo

70
.

180
.,

Any
AY

x
x

x
x

x
x

x
x

x
x

loo
loo

loo
loo

70
70

Any

150

185

180

150

130
x
x

170
70
70

loo
x
x

70180
70
150
75
70
150
.
.

x
75

x
75

75
.

75

x
x
70

210
175
180

x
75
x

70
70

1w
75
210

180
150

180
150
150
150

150

x
120

x
x

loo
70

loo
70

loo

180

loo

x
x
x
x
x

180
x

AY
AY
Any
100

100
150
150
x

0s. w

AY
1M)
100
100

80.

a.e

x
x
x

AY

OS. w
0s. w
a. Cl. 8. 0, w

Any
AV
A;

a. e

see Solvents

x
x
x
*

AY
see Solvents
see Solvents
100
100

See Sulfwc
a. e. cl w

100
100

70180
70180

x
x

x
x

70180
x
210
x
210

x
x
I

120

70

70

185
185
180

x
x
loo

x
1w
180

x
150
180

150
150
150

x
x
130

180
150
170

x
70
loo

.
x

loo
x
120

x
x
120

x
x
120

x
150
120

150
70

.
75
70

75

150

1w
150

x
x

x
x

x
x

x
1w

180
75

180
75

210
75

210
75

140

x
x
x

75
75

x
80.
x
x

loo
loo
80
*

x
x
x
*

x
x
x
*

x
x
x
.

x.

-.

-.

150
75

400
75
75

70

75

75

75

loo
.

loo
.

70
.

70
.

180
.

I
.

x
.

loo

loo

70

70

180

-.

-.

120

loo

II
I

100

x
150

75

x
150
75

x
-

-.

150
a5

x
1%
x
x
70

100

Any
100
100

x.
x
x

Any

x
x

x
x
x

x
Lb
x
x

70

75
70

75

170
75
x

-.

70
150

.
-

-.

75

170

70

-.

75
75

x
x

x
x

x
x

180
180

1w
loo

100
loo

70
70

150

150

x
x

x
x

x
x

x
x

185

185

200

200

150

75
75
75
75

130
130
100
170

200
200
150
150

.
x

75
70

70

-.
loo
IW

210
210

x
x

150

150

210

170

75
75
loo
150

75
75
140
70

75
75
210
210

150

150

125

210

210

75600x

150
70
400
75

180
1M
70
180
loo

loo
75
70
75
130

70
75
70

75
75

Acld

Ac!d
0s
OS
a. gl. w
a. b. e. w

See N~trrc Acld


loo
loo
AY
Any
100

a. 8. n. w
a. a~. b. 8. 9.
a,
a.
a.
a.
a.
recommended.

75

70
70
70
70

Solvents
Solvents
Solvents
Sulfuric Acrd

100
a. ct. e

x
*
x
x

x
x
x

150
185
185

183

a.e.w

75
75

75
.

x
x
x

*
a. ac. w
a. 8. w
a. ac. 8. eg. w
b. ct. e

dg. me

Any
Any
Any
Any

150

dg. me
0% w
a. b, cl. n. 0. w
a. 8. ea. OS. w
a. b. cl, n. 0. w

a. e

140
*

a.ac.

OS, w
a. e
a. e
mo

compounds

.
loo
70
.

DMF
ONT
Dodecanolc Acid
DOP
Douglas Fir 011

(1) Lrght.colored

.
70
75
.

loo
see
See
see
See

Ethyl Acetate

.
loo
x
.

lotl
*

a
a. e
a. e
a. e

Ethanol
Ethanolamme
Ether
Ethme

.
.

100

01pentene
Olphenyt
Olphenyl Ether
Olphenyl OxideDlpprng Acid

E!hane
Elhanethlol
Ethanolc Acrd
Ethanal

.
x
x
.

AY
100

loo
loo

EP~
Eplchlorohydnn
EFsom Salts
Essence of Myrbane

*
x
x
*

AY
Any
Any

Engravers

*
x
x
*

lo

Dry Cleanmg Flutds


Dutch Llquld
Dutch 011
Electrolyte Acld
EMK

*
x
x
*

OS. w
w
OS. w

Dowfume W40
Dow Purtfloc C-31
Oowtherm A
Dowtherm E
Oryad(1)

AND WOOD LINING

(continued)

x
x
*

Oratky Ether
Monoalkyl Ether
Monoalkyf
Monobutyl

827

COlICentratlon

Oachlorolsopropyl
Ether
Olchloromethane
Olchlorotetrafluoroethane
Olcyclohexytamme
Diesel 011

Olethylene Glycol
Otethylene Owde
Olethyl Ether
Orethyl Oxalafe
Olethyl Oxlde

RUBBER

of Construction

MATEAIALS

Solvents

Olethylene Glycol
Olethylene Glycol
Olethylene Glycol
Orethylene Glycol
Ether Acetate

of Materials

LEAD, GLASS, CONCRETE

MATERIALS-GATES
CHEMICAL

Resistances

Cl, e
Cl. ct. w
b. cl. n. 0. w
ac, w
Cl, 8. II

Any
See Acetic Aad

x
x
150
x

x
x

Any

IW
Any
AY
AY
AY

150
80

150
80

3
x

but they may Cause some cloudiness

80

80 x
x
x
I
x

80X
185
140
:0
loo

in the bleach.

150
80
:o
x

x
x

x
.
x

150
80
120
80
x

150

170
210

150

x
80
x

2;
x

70

.
2w

210
(50
75
210

200
75
75
x

75
75
75
75

(continued)

828

Corrosion Resistant Materials Handbook

TABLE 7.4:

RUBBER,

CHEMICAL

RESISTANCE

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)
FOR LINING

MATERIALS

Solvents
Ethyl
Ethyl
Ethyl
Ethyl
Ethyl

Acebc Acid
Aceloacetale
Acrylate
Alcohol
Aldehyde

Ethyl
Ethyl
Ethyl
Ethyl
Ethyl

Benzene
Benreroate
Buranoare
Bufyrafe
CeiliJose

a. 8. w
a. *I
a. Cl. e

E,, Chlor,de
Ethy Chlorocar~orale
E!hi Chlorolormc:e
E!h,iene
Ethi:ene Alcohol
ElhVlene
Ethv~ene
Eth,Iene
Emyiene
E~hVIene

Any
Any
100
loo

a. ac. b. e. g, n,
I, tu. xy. w

Any

a.
a.
a.
a.
9s

AY
100
100
100
See Solvents

b. ct. e. w
e
e
e

0s w
a b cl e
a b cl e

BromNdt
Chloride
Chloroh,or,n
Dlamme
Dlbromldt

Concentratnnl

7
5

a
2

zj

;j

%d

:a
x

cl0
x
150
x

a ~~
Cl e

I
x
x
I
x

Any

100

05 w
cew
w

Anv
V
Av_

i0
x

a e w
mo ph w
hc v

100
00
I
Any

x
150

Ferric Subsulfate
Ferrx Sulfate
Ferw Trtchlorlde

w
w
a gt w

A;
Any
Any

150
150
150

Feruc Tr~sulfate
Ferrous Chlortde
Ferwus Nitrate
Ferrous Sulfate

w
a u

Av
AV
An;
Any
25

ElhVlene D~chlorlJt
Ethylene Glycol
Ethylene Glycoi Mowbutyl
Emflene Glycol Mowbutyl
Ettw Acetate

E!er

Formaldehyde
Formtc Actd
Formtc Aldehyde
FWlTlOnltle
Frauds Reagent

125

210

210

x
1w

175

x
*

x
x

140

x
x

I
I

x
x

I
I

140
140

75

150

150

160
160

160
160

tw
100

A I
x
I
100 x

123

x
x
180

165

150

160

;5

x
x

II
x

80 x
100 80 it6
x
x
x

75

600

150

210

75

150
150

210
210

180 loo

2oc

2oc

150

150

75

100

70

720

1
x

75

75
70
150
75
75

II
150
150
70
I

150

210

75

75

75
75

75

210

ko

75

70
150
150
75
70

70

75

150
70
100

120
120
150

150

2:o
100

150
100
100

210
210

70
150

75
210
210

210
75

75
200

x
x
x

70
70
x

x
x
x

75
75
x

210
210
210

x
x
x

75

150
150
150
150

165
165
165
165

165
165
165
165

200
200
150
60200150200
200200150200
200
200
150

75

x
x

70
70

x
x

75
x

210
210

x
x

200

70

75

210

75

150

150

165

200

200

150

200

75

200

100

100

150
150

150
150

150
150

160
160

60
100

150
150

200
200

41
AV

60
150

loo
165

160
165

120
200

120
200

150
150

200
100

75
x

200
160

100
x

100
100

200

75

a. b cb. cl. e
a. cb cl. e. I. pe

100
100

x
x

150
160

x
70

x
70

75

75

150
75

)I

130

a g1.w

Any
100
See Solvents
65
100

150
x.

210

75

300

350

350

200

300

100
100

x
x.
x
100
60

a. b cb. cl e
aw
a. e
a. b ke
w

a.e.w
a,e w
a. e. w
a.e w
w

10
50
40
Any
40
Any
10

165

150
x

60
io
60
150

150

160

150

150

60200150200

150

60

150

x
x
x
x

165
165
x
x
x

x
150
75

75
75
75

200
200
150
200
200
150
60200150200

I
160

210
75
75

165
165
165

*
165
150

165
165
165

(no-pm?ss,

Flares Mart~s
Flortnated Cyckc Ether
Flowers 01 Sullur
Fluoborlc Acid
Fluorme*
-Fluorobenzene
Fluorochlroethylene
Fluorolube
Fluosttc~c Acad

70
75

x
150
150
x

Ammonum
Phosphate (Neutral)
Balanced MM (Complete Analysts)
Nttrogen (Low Pressure)
Falter Alum
Frwood 011
Fish 011
Flaxseed 011

200
170
70

x
165
x
150

Fenil~zer Solul~ons
Aqua Ammonia 6 N~lroqen
Solution

x
75
120

150

I
loo
I
x

100
100
100
100
100

AND WOOD LINING

II

x..

160

75

75

200
200

-.

2:o

150

x
x

x
x
x
x

165
165

150
60

150
60

150
150

75
75

x
x

x
x

x
x

70
70

x
x

150
150
150
150
150

60
150
60
x
x

60

150
60
150
150
150

100
100
100
120
200

x
x
x
x
x

100
150
100
150
x

-150
70
150
70
x

70
x
70
x

210
210
210
210
210

60
x
x

x
x..
x
x

450

-.

-.
-.

75
x
x
x
x

75
75
x

(continued)

Comparative

TABLE 7.4:

RUBBER, RESIN, STEEL, ALUMINUM,

RESISTANCE

FOR

100
100

150
100

185
185

185
185

100

100

150

185

185200200.
;5
x
150.

Freon' TA

100

Freon' TF
Freon' TMC
Freon' T-P 35

100

100

100

Fmnn

100

x
x

x
75
x

100

x
x
x

Fumartc Acid'
Furan
FUrfUr&
FIJIWall

aw
ae
abe

Any
100
100

I30
x
x

ae

100

_ krv
___

Fuel 011 (Acldlc)

200
200

200
150.

120
75
120
120
150

150
75.
150
150
150

x
x

x
x

-.

185

A~y_________~~

150 ~~~~~_._.__.__._
180
180

180
__~

._~~
150

a, e. 91.w
a, ac. w

aa.e.w

AW
Any
100

AV

150
100
x

x
x
x

x
x
100

150
150
100

aa. 91.w

Any

150

180

180

150

Glauber'sSalt'
Glucose
Glue
Glycerme
Glycerol

gl.w
a. 01.w
91,-h.w
a. w
a. w

Any
AW
A&
AW
Any

150
120
120
150
150

200
120
150
150
150

200
120
150
180
180

GlycerylTr~acetale
GlycerylTnoleate

a. e. OS. w
a, Cl.ct.e

Any
Any

x
x.-

GlvcervlTripalmMe

Cl.e

120

150
-

150
120
8Oxxx

150

15U
150
x

150
185
185
150
180

150
200
150
100
x

180
200
150
150
120

x
150
150
150

GlycolChlorohydrm

0s. w

see Solvents
loo
Any

GlycolAlcohol
Graham's Salt'
Grain Alcohol
Grain 011
Gray Acetate'

a. w
w
a. e. Cl
a. e. w
a. w

Any
Any
100
Any
Any

150
150
150
x
80

Grease 011

a, b. cb. cl,e

100

Green Copperas'
Greenland Spar'
Green SulfateLiquor

w
al.18

Any
See Solvents

Green Vitriol'

Any

Gypsum'
Halite'
Hartshorn'
Heavy Spar'
Hepar Calls'

ho, am. h
a. 91.w

See Solvents
Any
Any
See Solvents
Any

Heptyl Carbinol
Hexachlorodlphenylmefhane

a, Cl,e

GI&JI-

.~

ZO",. H2S04
h. w

100
100

150
150

75
75

140
170
170
110
110

180
170
100
150
150

150
170
170
xx)
290

70

150

200
140

75
150

70
150

75
150

75

110

150
70
180
70
130

200
x
100
75
70
75

170

140
170
170
70
70

75

x
x

75
75

75
__ .

210
210

.
-

150
70

x
-

70

210

210

75

120
200

75
75

75
75

75

170
75

75

70

75

185
185

200
200

160
200

150

75
75

75
140

70
70

x
150

185

185

150

200

150

75

100

100

70

x
x

x
x

100
x

x
x

170
75

x
x.

80

80

75

70

70

70

70

75

150
x

80

lo
80
120

70
70
75

70
70

70
70
75

70
70

75
75
75

x
x

fo

80
x
80
120
x

75
75

150
x
x
x

;O

80

Hexahol
H.%erW

a. 8

100
100

x
x

.
x

Hl?XOfW
Hexyl Alcohol
Hydrated Lime

OS. w

Any
100
Any

;o
150
x

75.

.
-

100

120
150.

loo

75
80
185

x
100
200

70

150

150

150

150

185

1;O
200

l&l
150

loo

1M)

200

210
140
x

150

loo

75
_

x
.

75
.

75
.

x
.

150
200
200

x
x
x

x
x
x

x
x
x

x
x
x

150
x
x

x
x
x

I
120
x

150
150
80

140

75
-

75

75

120

185
185

110.

210
210
140
150

150

185
185

200

70

210
170
170
210
210

200

150

100
150
150

100

70

Any

38

150
150
150
x
x

100
15

70

x
170

75

Hexanedtolc Acid

180
70

~~

75
210
170
75

150

185

80.

x
170
75
x

150

150

x
x

75
100
75
200

130
x
170
75
175

150

150

100
100

140

200

150

100

75

-.
140
._

70.

200

a. ac. e

75

210

150

OS
OS

~~~~
70
70

100

100

185

nexane

140

150

Hexaldehyde
Hexamethylene
Hexanaphlhene

100

70
70

120

x.

130

150

SeeSolvents

Hydrobromlc Acld
HydrochlortcAcvd

808080x.
loo
80120

100

Any

100
Any
Any

a.e

;i.eh,w

150
185

75

a. 8. w

100

;lo
185

Hexadecanolc Acod'
Hexahydrobenrene
Hexahydropyr!dme

OS

150

170

75

sew

150

150

Fusel 011

150
185

.
-

150100

GallicAcid'
Galloramc Acid'
Gasolme
Gaultherla011
Gelatm'

a. w

AND WOOD LINING

Concsrltrabel

Freon' 116"
Freon' 502"

Hydrauk 011
Hydrazme
Hydrazmobenzene

829

RUBBER (continued)

Freon' 503
Freon' MF

T-Wrl

of Construction

LINING MATERIALS

SOlWlW

__

of Materials

LEAD, GLASS, CONCRETE

MATERIALS-GATES
CHEMICAL

Resistances

75

75

75

75

75
.

x
.

210
210
210

x
x
x

75

75

(continued)

830

Corrosion

TABLE 7.4:

Resistant

RUBBER,

CHEMICAL

RESISTANCE

Materials

Handbook

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)
FOR LINING

MATERIALS
CoCentrsfK)n

SOlVentS
Hydrocyanu

Acbd

a. e. w

Hydrofluorlc

Acld

(Anhydrous)
Hydrotluoroslllclc
Acid
(Hvdrofluosllxx
AcIdI
Hydrogen.
Hvdrooen Bromide
I

Hydrogep
Hydrogen
Hydrogen
Hydrogen
Hydrogen

Cyamde
Dloxlde
Fluorlde

Carboxyk

Hydrogen
Hvdroqe
Hydrogen

PeroxIde
Sulfate
Sulfide

Acid

Chloride'
.

Hvdrooulnol.
Hydroqumone
Hydroskfluorlc
Ac!d
Hydrous Alummum
Oxide
Hyaroxyaceflc
AcidHydroxlpropane
Trlcarboxyk
Hyaroxybenzene

Ac,d

20
98
10
20
48
75

150
80
75
x
x
x

a. e. w
w

10
50
Any
AW

x
100
80
x
100

s. e. w
w
a. e. w
a. w
w

Any
See Hydrochlow
AY
10
20

a. w
a. w

10
See Sulfuric
Any

a. e. w
a. e. w

AV
A;

h. ho
a. e. w
d. e. w
a. Cl. e. gl.
ho. 0. w. Cb

x
Acid
80
80
x
80

120
120
x
x

150
150
180
180
150
75

x
x
x
x
x
x

x
185
185

x
185
185

I
150
80

x
150
80

x
150
150

150

150

150

150

150

80

75

150
x

x
x

io
80

150
100
100

120
140
200

80

100

140

150

75
120
120

See FIUOSIIICIC Acid


see Solvents
10
x
AY
150
AY
x

x
150
x

80
80
x
150
320

Iceslone*
lod~ne Penfafluorlde
lodoform
IPA
Iron Chlortde
~___
fro Olchlor,de

al. 18

See Solvents
100
AY
AY
AY

x
x
120
150

AY
An;
AY
AY
AY

150
150
150
150
150

AMY
AY
Any
Any
AY

1%
185
50
185
150
185
185
150
185
150 --___
150
Ez
80

Nitrate

Iron Perchloride
IrOn Persulfale
iron ProtochlorIae
~____
IrOn
Iron
Iron
iron
Iron

Sulfate
Sesqulchlorlde
Susqulsulfate
Tersullate
Trlchlorlde

gl.w

aw
w

a. gi. w
w
w

a.

gl.w

IrOn Vltrlol

lsobutanol
lsobutyl Alcohol

a. e. w
a. e, w

AY
Any
A;

lsopropaol

a. e. w

Any

io

Isopropyl Acetate
Isopropyl Alcohol
Isopropyl Chloride
lsopropylcarbmol
Isopropyl Ether

OS, w
a. e. w
e. m. w
a. e. w
0s. w

AY
AY

I.120

AY
Any
AY

.io
80

fsopropyldleneacelone
lsopropyltoluene
Japanese Gelatm
Jet Fuel
Type A&Al Kerosene
Type B Gasolme-Kerosene

P. e. w
a. e. Cl
as. gl. w

Any
100
Any

i
I.
150

ISo-OClSW

150
185
150
x
x
185
185
185
185

a.Cl, e.

0, w

-.
75
75
75
150

x
x
600
x

x
x
600
x

x
x
600
x

70
70
75
x
x

21-x

70
100
x

75
100
x

70
x
75

210
210
x

100

100

210

70
70
70

100
70
70

70
70
70

70
70
70

75
125
125x

100
175

70
x
70

210
210
210

75
150
70
x

210
150
175
210
150

150
x
75
x
x

x
x

x
x

x
x

100
185
100

*
150
x

x
110
x

x
150
x

120
x

x
110

200
180
200

140
x
80
185
x

80
x
x
200
I

60
x

120

210
140

2iO
x

,:O
120

150
150

150
x
200
x
x

150
150
350
70
x

x
x
120
185

x
x
.x..
120
120
120
80200150200

185
185
185
185
185

80
200
80
200
80

200
200
200
200
200

150
150
150
150
50

75
100
200
75
75

185
185
185
185
185

200
80
200
200
80

200
200
200
200
200

150
150
150
150
150

185
100
100

200
80
80
80

200
80
80
120

150
80
80

li5

120

120

BOX
120
120

x
120
;O

80

1;

-I
185

x
x
75
210

Anv
A;
Any
20

x
185

75
75
x

75
75

75

75
x

75
75
75

x
x

i0

75
x

210
210

x
x
x
*
x

210
210
210
210
210

*-

x
I
1

70
70
x
70
70

x
x
x

75

75
200
75
75
200

x
x
*
x
x

70
x
70
70
x

x
x
x
x
x

210
210
210
210

x
x
x
x

75

75

70

75

210

75

80

75

70

70

120

75.
75

70

75

70

70

175

75

170
170

70
70

170
170

170
170

170
170

75
75

170
170

70
70

170
170

170
170

170
170

150
75
100

170
x
400
x

170
70
180
1:
x

170
70
210

75

70
70
180
70
x

170
75
210
210
150

80

-.

180

180

150

200

150

150

100

100

120

150

100

loo

100

100

150
185

x 120 150
x 120 x
80 150
x
x x
x
200

x
200

x
-.

70
x

x
150

75

x.

x
x

75
75
75

70
x

I
x
L
150
I

200
I

75
x

x
x
x
x

75
75
150

-.

I
x.
x
x
I
0s

140
120
120

100

JP-1 Naphtha-Kerosene
JP-3 Gasolme-Kerosine
JP-4 Gasolme-Petroleum
JP-566 Kerosene
JPx
Kerosene
Ketohexamethylene
Ketopropane
Kurrols Salt
Labarraques
Solution

_
AY
Any
Any
Any
5

a. w
a. w
a.

;o
80

a. Cf. ct w
a. e. w
0s. w
I. w

a. cb, cl. e. gl
a. e. w
a. gl. w

Acid

Hydroxyethylamme
Hydroxysucctmc
Acad.
Hypnone
Hype
Hypochlorous
Acid

Iron

AND WOOD LINING

x
150
120

70

x
75
I
75

75
75

XL10

75

210

75

210
210

75

75

.
75

-.

-.

75
75

75

(continued)

Comparative

TABLE 7.4:

RUBBER,

RESIN, STEEL, ALUMINUM,

CHEMICAL

RESISTANCE

FOR LINING

a, b. cb, cl, e
a. e

Any
100
see Solvents

Lavender 011
Layor caralga
Lead Acelate
Lead Arsenate

a, cb. cl. ct. pe


aa. gl. w
a. gl. h. w
HNO, II

Lead N~lrate'
Lead Styphnale
Lead Sulfate
Lead Tr~n~troresorcmate'

a. e, gi. w

150
x

100
Any
Any
See Solvents

II
1%
80

x
165

a. w

Any

w
h. w
w
w
a. w

Any
Any
AW
A;
Any
100

60

130

Lime
Lime Acetale
Lime Bleach
Lame Hydrate

;th.w
a. w
a. w
gl. h. w

AY
Any
Al%,
AlI;

150
80
120
150

165
-

165
180
150.
185

200
x

200
120

150

200

2W

150

LlOnETne

100

I.

Lime Saltpeter
LImestone
LOll

a, ac, w
h

Any
see Solvents
100

200

200

L~nole~cAcld

OS

x.
x

Llgroln

Lfnolemc Acid

50
1W

150
x

80
x

80
100

:5

:o

,:o

x
165
120

x
180
80

100
160
80

150
120

1M

180

120

120

120

120
175
120
120
175
150
165
&l.._x__

185
165
165
185

160
180
180
200

120
120
120
160

120
120
120
150

165
165

185

100

150

100

150

80

a, cb, cl. e. tu. pe

100
100
100

I:
x
x

150
x
x

180
x
x

180
x
x

130
x..
x

x
x

a. w

Macassargum
Maddrells Sal!
Magnesia Alba

Magnesium
Magneswm

Bwlhte
Carbonate

Magneswm
Magnesium
Magneswm
Magnesium
Magnewm

Chloride
Hydrate
Hydroxide
Nitrate
Sulfate

Any

150
150
150
150

185
150

w
h

Any
Any
see Solvents
Any
see Solvents

a. w
a. h, w
a. h. w
a. w
w. a. gl

Any
AY
Any
Any
Any

aa. gl. w

b, cb. cl. e

MaIre 011
M&x
Acld
Malelc AnhydrIde

a.b. w
BC.cl. e.

Malemtc Aad
Maltc Acld

a. b. w
a. e. w

Manganese
Marble
Marl

w
h
h

hc

MEA (monoethanolamme)
MEK

a. Cl. ct. w
a. e. 0, w

Mercwc Chlwde
Mercunc Cyanide'
Mercuroos Nltrale'
MercwY
Mercury Bachlonde'

a. e. gl.PY. w
a. w
HN03.w
a. 8. gl.PY, w

loo
25
see SolvenIs
25
Any

120

60

130

75

150

175
x

100

70

200

loo

210

150

180

75

75

75

x
70

x
70

x
150

75

75
75

loo

100

2W

75

75

100

100

130

70

100

75

600

75

600
200

75

200

500

500

200
200
200

x
75

70
500
70

-.

70
500
70
-.

loo
170
170
75

400
170
170
150
.

x
170
170
x

70
70

175
x

165
150

150
150
150
150
150

150
150
150
150

200

120
120
200
150

185
185

180
200

160
200

150
150

200

120

120

120

loo

-.

-.
170
170
x

600
170
170
x

75

210

_
75

loo

loo

70

75
75
75
70

150
150
150
150
150
150

185
185
185
185
185

x
80150x
80

80

185
la5
185
185
165

200
200
200
200
200

2W
2W
200
200
200

130
130
130
150
150

200
75
75
75
200

70
70
70
70
110

70
70
70
70
150

x
x
x
70
110

x
x
x
140

140
140
140
210
210

loo

x
x

x
1:

150
120

200

170
x

170
70

170
70

170
-

170
210

x
x

70
150

70
75

210
150

75

75

200

210
210

200
170

200
150
210
.
200

x
x

-,

150
150

x
x

x
x

x
150

120
120

loo
140
75

150

150

185

200

200

150

80
x

60
x

140
IW

80
x

80
x

A"Y
Any
A"Y
loo
A"Y

150
150
150
150
150
x

185

150
150
150
185
150

x
I:
80
200
I

150
150
60
200
150

x
x

185
165

150
150
150
150

.g
.

75
150

200
75
70
75

x
1.

x
70
140
x
x

x
x
x
x
I(

75
x

70
rw

150

70

75
210

150

210

75

75

75
75
210
170

75

.
75

150
I
*
x
x

150

fo
150

loo

cl0
loo

150

Methanol

a. e. w

Any

1w

185

loo

150

120

loo

150

150

90

hc. I
w
a. e. w
a. b. e

See Acetic Acad


Any
Any
Any
100

x
x
loo
x

.
-

75

la5
x

loo
x

150
x

loo
170

150
170

75
75
150
170

75
90
170

150
170

loo

75

180
150

lea
x

70
_

70
_

.
-

x
loo

loo
70

Methyl Butanol
Methyl Butyl Ketone

a. e. w
a. e. w

Any
Any

150
x

Methyl Chlortde
Melhylene Chloride

a. b. cl. cl. OS. w


a. e

Any
100

x
x

.
-

60x
x

12-J
150

180
x

150
I

150
150

-I

150
150

ia

210
x

100

Methyl Bromide

75

200
130

Any
40

Actd

75

100
70

a.e.w

Melhanecarboxyhc
Methyl Acetate
Methyl Acrylale
Methyl Alcohd
Methylbenzene

75

100
130

Meaty1 Oxide
Methanal
Methane

a. e. w

x
x

Any
See Solvenls
see Solvents
Any
A"Y

Mercury Vapor"

75

x
185
-

70
100

-.

loo

x
x

x
x

x..

OS

80

200
200

:5.

150

Sullate

130

OS

Llquld Rosm
Lubrlcahng 011s
Lube Oils
Lye
LYSOl

AND WOOD LINING

RUBBER (continued)

120
I
I
x

Lmol~c Acid
Lmseed 011
L!quld Oxyqen
Llquld Petroleum Gas

831

Ctientratlon

Lactic Acld
LXIOI
Lacquer Solvents
Lard Oil
LaurtcAad

Llchemc Acid'

of Construction

MATERIALS

SOlVentl

LeUCoge

of Materials

LEAD, GLASS, CONCRETE

MATERIALS-GATES

Resistances

115
x

75
150

lf

70

75

, -

.
.
140 .
210
.
75
-

.
.
-

70

(continued)

832

Corrosion Resistant Materials Handbook

TABLE 7.4:

RUBBER,

CHEMICAL

RESISTANCE

RESIN, STEEL, ALUMINUM,


MATERIALS-GATES
FOR LINING

OS

COnCell.
tratlo
100

OS. w
a. e

100

100
100

x
x

a.e.0.w

A?

a. e. w
d. Cl. e

100
100

a, 8. w
a, e. w
w. 05

Any
Any
Any

x
x
x
x
x.

Methyl Merihacrylate
Methyl Oleate
Methvlohenol
Methyl Polyslloxanes
Methylpropanol

w
a. as

Any
100
AllV
100

x
x
x

Any

fo

Methylpropytbenrene
Methvl Sal&ate
Milk i,c,d
Mtlk 01 Magnesrd
Milk. Whole

a. cl. e
aa. e. w

100

x.
x
120
150
100

Methyl
Methyl
Methyl
Methyl
Methyl

Formate
Hexyl Carbmol
lsobutenyl Ketone
lsobutyl Ketone
Isopropyl Ketone

,_

Mmeral
Mmeral
Mmeral
Mmerat

a
e.al. ho.~.w
~.~.=.
8. e. w

a.e.gl.w
am. h. w

011
Pttch
Spmts
Thinner

AflV
50
Any
100

100
100

x
x
x
x

Mmerat Turpentme

d. b. e

See Solvents

Mlrabllite
Molasses
Molyslte
Monobromo Benzene
Monobromotr~tluoromethane

gt. I*
w
gl. w

Any
Any
Any
Any
100

150
150
150
x
x

Monochloroacetlc Acid
Monochloro Benzene

s. e. w

10
Anv
100
100
Any

x
x
x
x
60

100
100
25
100
Any

x
x

a.

Monoethanolamme

a. Cl. ct. w

Monomethylanlllne
Monomethylether
Monosodwm Acid Methanearsenate
Monownyl Acetate
Monsels Salt

a. Cl, 8. w

Marea Premhz
Morrhua 011
Motor Spmts

w
ae. a. cb. cl, e. pe

Muthmans Llquld
Myrtst~c Acid
Naphtha
Naphthatene
Na;hthec
Acld

100
100
See Hydrochloric

Murlatlc Ac!d
Mustard

x
150
150
x
x
Acid
x

x
.

x
.

x
100

x
x

x
x

x
x

100

150

70
150

100
150

70
150

*o 120 *

75
150

70
150

150

150

x
.

70

70

100
-

100

70

x
x

165

165
165

60

x
x

x
x

f.

160
60

60.

x
x
80

x
x

x..
x

150
165
1M)
x
x
x
165
165
160
x
150

75

75
x
70
170

60
200
loo

60
200
100

130
130
loo

120
60
x
x

150
150
x
x

150
150
x
x

75
75
loo

200

x
x
x

140

60
*

80 x

110
170

140

160

150

140

x
-

70

100

70
70
75
75
150

70
70
75

loo
loo

75

70

75

170

70

150.
150
x

120
100

x.

x
x

150

-.

Nickel
Nickel
Nickel
Nickel
NuXine

ho. w
a. w
a. w
a. w

Any
Any
Any
Any
Any

150
150
150
150
150

a. e. I
a. gl. w
w

Any
Any
Any
10
25
40

150
150
150
x
x
x

a. b. 8. w
a. ac. 11
w

Any
Any
Any

I
x
I
150
60

II

100

x..

60

x
100

170

x
-

75
-

75
75

75
210

-.
75
200
140
170

170
170
75
75

x
x

210

75

210

75

100

210
75
75
210

75

200

210

170

170

70

75

75

200

130

210

170
170

170
170

170
170
170

170
170

75

x
x
x
I

100
70
70
70

140
210
120
120

x
x

70
70
x
x
x

75
210
203
400
4cu
400

70

200
200
too
200

x
70
x
x

70
70
70
70

130
x
x
I
x

70
130
150
200
175
140

70
160
x
70
x
x

70
70
:50
133
75

70
75
150
70
75

165
165
165
100
75
x

200
200
MO
60
x
I

200
160
160
x
x
x

150
150
150
150
115
100

I
I
I

x
x
x

x
x
x

200

200

150

150
185
1652fXI200
See N,trtc Acld
150
165
150
150
See Nwc Acfa
See ww
4cla

150

150

80 I

75
130

II

150
150
150
150
150

165

.
-

170

200
200
200
200
200

165

170

100

150
x

200
200
200
200
200

ii0

175
75
210

75

x
120
70
150

150
150
165
165
165

160
165

75
210

75
.

75

-.

60

80 I
165
165
165
165

.
.

x
x

-.
x

210

75

150

200

75

I
x
-

200

75
70

170
70
75
75

165

-.

70
170
70
70

210

165

170
75
75

x
100

160.

70

2&

60

200

-.

x
x
x
-

165

x
-

70
70
150

110

200
200
150
200
200
150
602CO150200
*
x
x

x
I
x

75

75
loo
75
170

x
x
x

75

x
I

;0

x
x
x
x

x
x
100

,65

Any

150

150

x
80

150

100
Any

A?

a. cl. e. k
a. w

~IrN)~--

.
.

x
x

100

x
x

Owxtae
Fe~~luer Solution
Petoxlae
Tetraoxlde

100

Nltrogeo
Nlrrogen
Nitrogen
Nitrogen
Nltwgen

150

a. b. e

Concentrated
Fum.,rg
Nmobenzene
Nmocalclte
N!tro Ethane

Naphthylbenzene
Natural Gas
Nave0
Neatstool 011
Nvzkel Acetate

iicotme Sulfate
Nlter
N~ter Cake
N!tr!c Acid

*
x

75

x.
x

a. b. e
hc. OS. w

a. e

x
x

lcil
see Solvents
100
See Solvents
Any

Chloride
NItrate
Salts
Sulfate
Bentonite

a. e

AND WOOD LINING

MATERIALS

SOtVentS
Merhylene Chlorobrom!de
Methvlcvclo~ntane
Meth;l tithe;
Methylene Ovchlorlde
Methyl Ethyl Ketone

LEAD, GLASS, CONCRETE


RUBBER (continued)

170
170

150
100
125
125
60

80

x
x

x
x

75
100

170
100
75

_~.___~-.___-_

I
70
x

75
x
x
1.
x

210
150
210
loo
75

x
75
x
I
x

I(

75

~-~---

(continued)

833

Comparative Resistances of Materials of Construction

TABLE 7.4:

RUBBER,

CHEMICAL

RESISTANCE

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)
FOG Ll&iiNG MATERIALS
COCenvatlo

SOlVetS

COflC

NWohydrochlonc
Actd
Nltro Methane
NrlromurMc
Acid
N~tropropane
Nltroxanthlc

Norge Nlter
Norway Sattpetr~
Nonveglan Saltpeter
NPN
Oak&z Acid Mater&

w
a b.cI

e w

a. ac. w
a ho w
a ac,w
(I)

Oaktte Alkahne Mater,als (1)


Oaktle OC 31 Ill
OC 32 (1)
33 (1)

AY
AY

50 :

75
70

f5
x

210

100
100
loo

130
130
130

70
70
70

x
x
x

1w
100
1w

x
I
I

75

75
70

70
x

:o
70
70
x

100
loo
100

AY

150
70
70

195
too
100

185

200
85
85

150

150
70
70

100

x
x

100
100
loo
x

Cryscoals

47. 87. 69. 89M


Cryscoat FH rmse

a5

a5

x
70
70
x
x
a. ac. e ph
0s
a, e. 0s
a. ac

100
100
100
100
100

:o

100

85

100
100
x
x
80

200
x

70

70
loo
75

70
70
70
.

x
100

210
75

x
150

140

$5

1:o

150
150

70
150

x
70

140
210
210

x
x

120

150
loo

a, e. 0s
a. cl. ct. e

100
100

x
x

x
loo

a. ac. b. e. cu. w

loo
Any

Acid

8.8.W

10
100
40

PaInters Naphtha
Palm 011

a. cb. cl. e

loo
loo

Palmax Actd
Pahnm!c Ac!d

a. e
a. e

see Solvents
see Solvets

Palmmn

Cl. e
w
a, 8. w
ho. w
ho, w
w
Cb. cl. e. pe
w
w
a. e

Oxahc Acid
Oxygen.
Oxymethelene

a. e. w

Patent Alum
Peanut 011
Pear Alum
Pearl Ash
Pear 011

:o

:
150

:o

Ozone
-*

Paper Alum
Paradihydroxybenzene
Paraform
Paraformaldehyde

150

150

150

150

150

150

200

70

1w

70

70

70

loo

80

,&

185

200

200

150

150

k
185
loo
150

x
x
200
100
80

x
x
150
loo
80

x
x
130
loo
150

75
75
200

75
x
x

loo
70

1w

loo

150

75

75

75

210

75

75

400

70

130

300

75

loo

75
210
210

;o

x75

75
75

210

75

70 x
70

,@J

x
70
70
70

180
70
70
70

x
70
70
70

loo
70

.
-

200
125
75
75

:5
75

75
75
75
75

150

100
.

x
-

180

loo
-

200
.

x
.

75
.

200
180

150
150

100
150
75

x
loo
75

180
180
70

x
x
70

loo
x

200
180
210

x
75

75
75
75

185

185

200

AY
100

150
x

185
x

185
x

200
x

200
150.

AY
AY
1w

150
150
x

185
185

185
180

200
200

loo

loo
120
75
75

150
80
x
x

x
x
x

200

75

see Solvents
AY
Ai
Any
A;

2crJ

150
120

,!=&.

x
x
x

x
x
x
x

x
x
x
x

x
x
x
x

x
x
x
x

x
x
I
x

x
x
x
x

75
75
75
75
75

75
75
75
75
75

.
.

75
75
75
75
75

.
.

.
.

.
.

120
x
75

120

loo
x
70

Penramethylene Amme
Pentasodwn Triphosphate

a. e. w
w

AY
AY

x
x

.
.

.
.

x
x

x
x

.
.

.
.

Perchlorelhytene
Perchlow Acid
Perchloromethane

a. e. 0. w
w
a. b. cl, e. n, o. w

AY
10
Any

x
150
x

.
x

x
150
x

x
II
x

x
I
x

I
150
150

loo
200

but they may cause some cloudiness in the bleach.

70

f0
x

75

x
I
x

75

(1) Light-colored compounds recommended.

;0

;olx,.

Penlachlorodlphenyl
Pentachlorodlphenyt Ketone
Pentachlorodfphenyl Oxvde
Pentachloroethylbenzene
Pentachlorophenylbenzoate

x
x

80 80 x

x
x

90
150

x
L
x

Ortho-dlchlorobenzene
Ortho.hydroxybenro1c

x
x

ISO

185

70

75

x
x

70
70

70

150

x
x

70
70

$0
x
x
x
x
70
x
70
x
70.

80x

100

?.

AY

:0

x
x

a. cb. cl. e

:o
70
70

120
80
150

100

70

AY
AY
See Sutlur~c Acid
100

Orthoborlc Actd

70

120
x

a cl. e

Oleum Spmts
Okve 011

70
70

a. a. w
a. b. e. w

011. SAE

70
70

x
x

x
x
x
x
x
x

70
70

70
70
70

70

75
75
75

70
70
70
70
70

I
x

:o
70

70

Oclyl Alcohol

Olelc Acid
Olel

70

70

:5
85

011 01 Biller Almonds


011 of Mlrbane

011
01Vltrlol

70

:o

70

x
x

x
x
x
x

x
x
x
x
x

:o
70

x
x

Cryscoals LT 6 SW
0 Drycld (1)
OFM 184 (I)
0 Stnpper SA
Oaklte Solvent Matenals

85

Cryscoal
HC

x
x
x
I
x
x
x

x
I

Ac!d

75
x

150
150
150
120

70

Ocladecenmc Acid
Oclalluorocyclobulane
N-Octane

75

200
200
200

0 Chromlcoat

Ocladecane
Octadecatrmolc

I(

200
200
200

100

185
185
195
120

131 (1)

x
75

120

195
150
185

70
70
70
x

:5

80

150
150
150

I
x

x
75

A)
AY
Any
100
See Solvents

oc
oc 34(1)
oc 36 (I)
oc 84H(1)
OC 84M (1)
cc 85 (1)
oc 88(1)

oc

Lo -

AY

ACld

AND WOOD LINING

.
-

.
.

75
75
75
75
75

.
.

.
.

.
.

.
.

.
.

70

75
210
210

.
x
75

x
75

loo

(continued)

834

Corrosion

TABLE

7.4:

RUBBER,

CHEMICAL

Permanent
Peroxvde

Resistant

RESISTANCE

White

Materials

Handbook

RESIN, STEEL, ALUMINUM,


MATERIALS-GATES
FOR LINING

LEAD, GLASS, CONCRETE


RUBBER (continued)

MATERIALS

con I+$04
a. w

See Solvents
10

60x

60

100

120

100

100

60

120

100

loo

150
150

165
165

xx)
200

200
200

150
150

x
x

Anv

loo

100
AV
100

x
x
x

180

75

150

Any

30

gl. w
gl. w

Any
Any

Phenol

a. cl. gl. ho

Phenol Polysdoxane
Phenol Tr~n~lrale
Phenvlamme

0. w. Cb. e
a. b. cl. e. w
a. b. e

Peroxydol
Peroxyhydrate

Ph$enzent
Phenylcarbmol
Phenvl Chloride
Phen;lethane
Phenyl Ether
Phenyl Ethyl Ether

a. Cl. 8. w
0s
a. b. ct. e. w
a. e

Phenylmethane
Phenyl Methyl Ketone
Phenylsulfomc Aad
Photone
Phosphate Esters
Phosphonc Aad

Any
100
Any
see Solvents
Any

x
x
x

165
x

x
x

x
x

200

110

200

175

70

210

75
x

x
70

70
70

x
100

x
75

210
210

x
75

75

210
210
210

x
75
75

75

-.
175
140

150
x

X..

a. cb.. cl. 8. gl.


ho. 0. w
a. b. e

Any

100

100

150

170

OS. w
a. w

Any
10
100
Any
50

80 x

x
x
150

165

Phospholeum
Phosphoric Anydrlde
Pickle Alum

w
w

65
150
106
x
106
x
See Phosphoric Aad
Any
150

P~crtc Acid
P~cron~tr~cAc,d
P~melwz Ketone

a. b.. cl. 8. w
ab. cl. e. w
0s

Any
Any
100

x
x
160

x
x
80

150

165
120
120

165

165

200
120

80

60
x

100
150
150

100
150
150

100
150
150

150

150

210

75

110

200

175

70

210

lb
-.

150

2cxJ

170

200
x
-.

170

170

170

170

350
120

150
x
-.

150
70

175
210

200

300

75

70
70
70

210
400
400

x
x
x

75
75
75
75

75
-

130

x
x
x

I
x
x

200

150

100

160

100

75
75
75

x
x
x

70
70
70

x
x
70

x
x

75

-.

140200
200
200

x
x

75
150
75

-.
75

70
70

150
60.

70
x
120
165

x.

x
x

210
210
140
140

70
70

Any
Any

Phenylformlc Aad
Phenyl Hy+z~ne
Phenyllc Aftd

AND WOOD LINING

x
x

loo

200

x
x
70

210
210
75

x
x

180

Potaswm

Acetate

a,w

Any

120

175

150

120

150

75

75

loo

75

75

Potaswm
Potassum
Potassium
Potassium
Potasswm

Alum
Carbonate
Chloride
Cupro Cyamde
Cyanode

w
w
a. w
w
a. gl. w

Afly
Any
Any
Any
Any

150
150
150
150
150

165
165
165

165
160
165
150
150

200
200
150

160
160
150

200
150
200

1.
loo
70

120

70

70
x
70
x
x

100
x
70
x
x

200
160
210
75
100

75
75
70

150

150
160
150
70
100

160
75
x

150

150
150
150
150
150

75

75

Potassum
Potasswm
Potassium
Potasswm

01 (61) Chromate
Hydrate
Hydroude
Mur~ate

w
a. e. gl. w
a. e. gl. w
a. w

Any
A?
Any
AY

x
150
150
150

x
165
165
165

150
165
165
165

120
200
200
150

150
150
150
150

150
150
150
150

200
100
100
75

130
75
75
70

150
130
130
150

140
x
x
70

130
x

160
x

:o

2:o

x
75
75
x

x
75
75
70

Potasswm

N~trafe

a. gl. w

Any

150

160

165

200

160

150

200

130

130

160

70

210

75

loo

(continued)

Comparative

TABLE 7.4:

RUBBER,

RESIN, STEEL, ALUMINUM,

LEAD, GLASS, CONCRETE

MATERIALS-GATES
CHEMICAL

RESISTANCE

Propenenllrlle
Propyl Acetate
Propy~acetone
PrOF/t Alcohol
Propylene
Propyllormlc Acid
Propyl Nitrate
PrOtochlOrlde-

FOR LINING

RUBBER

OS, w

AY

80

a. hc. k. o

100

a.e.w
a.e.w
-____

120

a.e.w

AV

x
x

a.w

150
80

Pruss c Ac,d

a. e. w
w
d. b. e. w
a, Cl. e. 0. w
a. w
b. e

Any
Any
Any
Any
100

x
x
x
x
*

100
A"Y

a.
a.e.I

Red ,,I

a. e. *I
a. cb cl
d cb. cl. e. me
a. e. 35

Red Potasswm Chromate


Relined Lmseed 011
R,onus 011

w
a Cb Cl. e tu. pe
b cb. cl e

100
100
100

80 x
x

150
120

x
120

x
120

x
I(

x
x

120

30
x
x
*

185 80
185
x

150

150

130
100
150

I
1
x

150
x
x

150

100 x

210

x
100
75
x

x
100
210
100

130
210
210
140
210

75

75
75
75

x
75
75

75

70

70

70

70

125

130

150

150

75
I

75
70

70
100

70
76

200
210

75

150
150
150
185
120

x
180
120
200
120

150
180
150
160
120

150
130

75
75

130
75

140
70
200

150

75

150
70
170
70
150

200

2io

Salt Cake
Salt 01 Lemery
Salt oI Tartar
Salrpeler
Salt water

gl. w
w
w
a. gl w

AY
Any
AW
An;

150
150
150
150
150

185
185
180
185

185
185
180
185
185

203
200
200
200
ZOO

209
180
180
180
180

Sand Acid
Salt
Seed 011
Separan NP-10
sewage

w
a. gt. w
a. b cb. cl.e
a. ac. w

50
Any
100

80
150
x
150.
x

185
185
x

x
185
too

BO
200
150

80
180
150

150

180

180

AV
50
100

x
80
80

150
x

180

100

x
80
120

80
150

100

lx)

a. e. 91. w

100
A*Y

150

200

180
180

185
185
185

130
185
150
185
185

x
200
180
200
200

x
200
180
200
200

80 x

80
180

Skydrol
Staked Lwne
Soap Solullons
Soda.
Soda Alum

PI. h. w

100
Any

w
w

AW
An;

x
150
150
150
150

Soda Ash
Soda N~ter
Soda Saltpeter
Sodurn Aietate.
Sodwm Aod Carbonate

w
a. gi. w
a. at w
a. e. w
w

Any
AV
AW
Ani
Any

150
150
150
150
150

185
180
180
185
185

185
185
185
185
185

200
200
200
120
200

2W
150
150
150
200

Sodwm
Sodwm
Sodwm
So&urn
Sodwm

w
w

AW
A;
See Solvenls
See Solvents
Any

150
150

185
185

185
185

200
200

160
160

150

185

200

200

al. fe
w

70

1w
loo
180
70
100

120

185

Aad Sullate
Aod Sulllte
Alummo S~hcate
Alummum Fluoride
Alummum Sullate

75

too
100
180
70
140

120

185

70

75
125
dw
x
00

x
I50
130

120
200
2w

SIllcone 011s
Salver Nttrate

75

120
130

120
200
200

185

120

x
185
:50

120
185
185

75
210

185

75

120
150
150
80
150

Slllcale Esters
S~t~cofluor~cAod
SMzone Grease

75
x

Any
Any
Any
Any
Any

sea

75
70

a. w gi
w
a. ac b, e tu. w
w

75
200

75

75
x

Any

Solutions

150
70

185

185

a
a,91w

75
x
120

120

io
150
120

Saccharum Solutfons
Salammomac
Sal Chalybls
Salqhc Acud
Sal Soda*

AND WOOD LINING

Saccharose

835

(continued)

RockSalt

AlV
lci
100

80

AY
AY

Purple Salt
Pyrldre
Pyroacellc Ether
Pyrol gneous Acid
Pyronuc~c Aldehyde _
Pyrr01e
Raoeseed 011
Raw C seed 31

of Construction

MATERIALS

too
AW
An;

0Ul"Ol

Resistances of Materials

-.

110
75

50

130
170
100
130

75
75

75
75

75
x
x
x
75

75
75
75
75
75

:5
75
75
75

75
75
75
x
75

75

75

x
x
x
120

150
too
70
loo
100

70
x
75
70
x

100
x

150
210
210
210
140

150
150
150
150
150

100
75
150
150
75

140
70
100
130
75

100
100
180
130
70

150
100
x
180
x

140
75
x
70
100

210
130
180
210
130

150
150
140
150

75
75

x
75
170

70
70
170

x
x
170

70
100
170

x
130
170
-

200

70

110

150

75

70

70

210

130
x

180
200
170
120
150

200
75
75
70

150
150

_
-

75

150

200

130

150

100

200
70
100
200

75

75

70
x
x

170
x
75

170
140
75

75

150

100
170
120
x

70
100

75
:

150
150

70
100
100

120
130
130

100
170
170

x
75
75

x
x
x

140
210
210

75
75
75

75
75
75

150

75

100

150

150
150

75
75

100
x

150
100

*
x

70

150
x

75

150

100

200

75

75

150

(continued)

836

Corrosion Resistant Materials Handbook

TABLE 7.4:

RUBBER, RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)

CHEMICAL

RESISTANCE

FOR LINING

MATERIALS

SOlVents
Sodturn &carbonate
Sodwm &sulfate

CQncen,ratDn

=
S

Ei

$E

$2

PO

52

165
165
165

_9
s
z

:
I

=%
61

5
<

165

165
165
165
165
165

200
200
200
2W
200

200
160
160
160
200

150
150
150
150

75
200
75

100
100
x

x
x
x

100

120

150
150
loo
150
loo

150
150
120
100

200
200
160

75
100
75

170
100
100
75
175

75
75
x
x

Sodrum Bwlf~te
Sodwm Borate
Sodwm Carbonate

w
w

150
150
150
150
150

Sodurn
Sodwm
Sodun
Sodwm
Sodturn

a. gl. *I
a. VI
w

AV
Any

150
150

165
165

165
150

200
150

Any
Any
See Solvents

150
100

150

165
150

200
1M)

160
160
200
160

Any
AY
Any
5

150
150
150
x

150
165
165
120(Z)
120

165
165
165
120
60

150
2W
200
x
x

150
150
150
x
x

150
150
150
120
120

165

165
165
165
165
165

200
200
200
200
200

200
200
200
150
200

150
150
150
150
150

165
165
165

200
200
200

2W
200
160

120
150
150

Chloride
Cyanide
Dloxlde
D~sulf~fe
Fluoalummate

AV

::
s
De
2s
u.IL

t
:
I
z

AV
AY
AV

al. te

Sodium Hexamelaphosphale

Scdwm
!%dwm
Sodum

Hydrate
Hydroxide
HypOChlonlefl)

a. gl w
a. gl. w
w

Sodwm
Sodum
Sodurn
Sodwm
Sodwm

Iiyposulftle
Melaborale Peroxy-hydrate
Melaphosphate
N~lrala
Perborate

I. w
gl. w

Sodurn Peroxide
Sodturn Phosphate
Sodun Pyroborate
Sodwm Sesqurcarbonate
Sodium Sihcale Sulfate

20

a, gl. w
gl. w
w

a.w

91. I
w

150
150
150
150
150

Any
Any
Any

150
150
150

165

Any
AY

150
150

165

185
165

xx)
200

200
200

Any
Any
Any

150
150
150

.
-

150
150
165

x
200
200

150
200
200

150
150
150

Any
Any

150
150

165
165

165
165

200
200

200
200

150
150

AY
Any
Any

200
2w
200
200
200

2w
180
200
200
200

120
150
150

185
165
165

165
165
165
165
165

Sodwm
Sodoum
Sodwm
Sodw-r~
Sodturn

Slannic Chlonde
Sulfare
Sulfate Decahydrale
Subsulfrle
Sulfite

a. cb. I. w
gf. w
gl, w
I. w
a. w

Sodwm
Sodurn
Sodum
Sodium

Suparoxode
Telraborata
Thiosulfate
Triphosphale
Tnpolyphosphale

w
w. 91
I. w
w

A!

Any

150
150
150
150
150

loo
loo

x
x

120

100

150
150

150

Wwm

soya011
Soybean
Oil

a.cb. cl, e
a.cb. cl, a
a.aa.Cl. e

Spirrts of Turpentine
Splrlls Of Wlne

a, Cl. e

Slanmc Chlonde

a.cb.

Slannous Chloride
Starch Syrup
Slearic Acid
Sloddards Solvenl
STPP

loo

Llnw

15
150

l&l
150

150
165
75

I
120
60

150
120
200
_.

150
150
150

200

120
.

150
x

165

165

1M

2-X

150

I
I

150
x

166
1M
60

I
x
x

I
x
x

140
-

x
I

x
I

x
I

x
I

loo
loo

150
150
60
x
x

16.5
166
150
x
x

166
166
150
1w
I

180
170
80
x
I

150
loo
80
I
x

150
150
150
60
x

x
x
x
x
x.

X
150
150

x
150
loo
x
I

x
I
x
x
II

120
I
x
x
x

x
130
x

a. a. Y

AV

(1)Lrghl colored compounds recommended.

MO-210
75

120
150

Sulfurous Acd Anhydride


Sulfurous Oxychbrlde

x
150

120
150

AnV
IO
75

120

75
-

.
.

a. b. cl. o. n. w

loo
x

:
75

IM
150

Sulfurr Ether
Sulfurws Acid

loo
150
150

75

140
75
210
210
210

ArlV
An;

10
30
50
75
95

x
x

x
70

120
120

Sulfuric Acii

:5
x

100

120
120
60

cb. a
a. b. cb. a

70
x

loo
150
70

:o

160
120
80

a.b.

75
75

75
75

210
140
210
210
140

70
loo
70
170
loo

75
75
75
75

x
x
75

165
lx)
120

Any

x
x
150
150

210
210
210
210
x

a. 0. -

x
x
x
x

x
140
140
70
70

Any
Any

100
x
x
x
x

75
75
70
.
-

x
150
150

a. 8. *I
a. 1

160
130
130
I
x

75
75
75

x
160
180
70
150

x
120
120
60

Sulfur Duwde

SulfureIIad Hydrogen
Sulfur Hexaffuorida

130
210
140
210

x
140
140

75
170
200

.
-

x
loo
x
x
70

75
200
loo
100

Any
An;
AY

see SolvenIs
Any

x
x
x
100

75

x
x
x
x

a. b. cb. cl. e
h. v

75

70
100
loo
70

75

Any

a. b. cb. a

150
150
x
75
140

70

140

a. gl. h. w

H
%

x
x

120
x
x
x..

a. e

s
0

x
x

Any
Any
Any
loo

h. w

J
cl

100
170

80 I
x
x
x

75
150

f
-j

120
170

60120.
60120
150
1;o
150
I
150

130
100

::f

70
200

il.

Sulfur Chloruh

Sulfur Monochbrida
Sulfur Subchbrtda

a, ho. Ia. w
a. gf. w
cb. cl. cl. a. w

Sulfite L~auors
Sulfamic ica
Sulfur
Sulfurated

200

Any

loo

I. w.

Stripper SA
styrene
Sublimed While Lead
Sucrose Solullon
Sugar of Lead

Any
Any
Any
Any
Any

165
160

AND WOOD LINING

75

x
IW

70

loo

120

110
70
x

170
170
70
180
I(

170
170
70
loo
I:

I
170
120

150
170
150

110

70

210

I:

210

I
170
150

1:o
x

210
170
450

.
x

.
-

.
x

75
.

.
, .
x

75

75

.
-

.
x
-

75
75

x
.
x

70
150
150
1w

75
x
70
x

150
130
x

70
75
160
150
200

.
75
75
x

75
7;
75

.
.

I
.

100
.

I
.

100
.

170
.

x
.

x
.

75

100

loo

70

75

70150.

I
70
75

170
loo

x
70

x
x

I
x

x
I

170
170
170
I
x

I
I:
I
70
70

70
I

I
I:
x
I(
x

200~400
200
400
200400r
1704rxl
75
400

x
I

I
75
75
75
_

70
x
x
x
x.

70
70
70
170

70
70
70
x
x

70
70
70
150
1M

75
x
x
I:
I

loo
75
75

lo
M

150
70

.
x

75

150
75

I
7s

70150.
70150.

150
210
210
150
210

75
75

x
x
x

70
70
70
70
70
75
75

but they may causa sorna cloudiness in the bleach.

(2)Use 26666 compound for storage and Hard Rubber for manufacturing

processes of Sodium Hypochlorile.

(continued)

Comparative

TABLE 7.4:

RUBBER,

CHEMICAL

RESISTANCE

Resistances

of Materials

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)
FOR LINING

MATERIALS

of Construction

837

AND WOOD LINING

5
e

Sultur Trtoxlde
Superphosphonc Aad
sweet 011
Sweet Birch 011
Table Salt

SOlVetS

tratlon

a. cb. cl. e
aa. 8. w

100
106
100
AY

a.w.gl

AY

Tallol
Tall 011
Tanntc Acld
T.dl
Tanmng Solurtons

a. ac, w
a. ac. w

AY
AV

Tar. Sltummous
Tar Camphor
Tartar~c Aad
TCA
TCP

b. cb
a, b. e
a. e. w
a. e. w
OS

see Solvets
see Solvets
AY

TEA
Terra Alba
Terra Ponderosa
Terp~neol
Tertwy Butyl Alcohol

a. Cl. w
gl. ho

Tenlaw Bulvl Calechd


Ten&
Bl;l Mercaptan
Telrabromoelhane
Telrabromomethane
Tetrabutyl Tltanate

a. e. w

a. e
a. Cl. e. w
OS

Telrachlorcethane
Tetrachloroethylene
Tetrachloromethane

a. e
a. e. 0
a. b. cl. 8. n. a w

Tetradeconac Acld
Terra Elhyl Lead
Tetraethyl Orthoslkate
Tetrafluoromethane
Tetrahydrofura

a. e
OS
a

Tetrahydronaphthalene
Tetralan
Trlmethyl Pentane
Tetrol
Thenardtte
Thtonyt Chloride
Tmcal
TI Chloride
Tin Crystals
Trn Olchlonde
Tin Protochlonde
Tm Salt
Tin Telrachlorlde
Titanium Tetrachlorlde
TOlUee
Transformer 011
Transmwo
FluId
TrZlVertle
Trlacetm
Trlbutoxy Elhyl Phosphate
Trlbutyl Phosphale
Tchloroacel~c Aad
Tnchlorobenrene
Trlchloroethane
Tr~chloroethytene

OS. w

160 .

x
x
150

loo

AY
AY

loo
loo
loo
100
100

185
165
150

loo
a. e. w
a. e. es. OS. 0
a. e. es, OS. 0

AY

a. b. e. n. 0. w

AY
loo

a.e.es.OS,
0

1w
loo
AY
Av

70

loo
400
lW4WX
x
180
x
160
70

70
-

100

400
-

x
-

x
x

70
70

70

70

150
I50

80

150

120

80

75

75

75

70

75

.
.

.
.

75
75

70
70

1w
loo
75

75
75
75

70

100

210

.
.
loo
.

210
75

:5

*
..

.
-

f5
x
x
*
x

x
x

;5 ,&
&lmr
x
x

$0

f5

x
loo

x
120

x
x
I
*

x
x
x
*

x
x
x
*

150

x
x
x
x

-120
180
x

x
x

iI3

180
x

*
x
*

200

75

75
x

75

70

75
75

120

175
210
75

75

210

75

75

.
75

75
75

-.

200

200

150

loo

140

160

150

140

210

x
200
I
x
I

x
180
150
150
150

x
150
150
150
150

75
120
120

150
x
150
150

x
I
x
x

IM
.
x
x
x

210
75
210
210
210

x
185
150
150
150

150
150
150
100

150
150
150

120
120
75

I
I
*
.

150
150
*

x
I
I

x
I
*
.

210
210
210

150

150

150

150

150 I

x
x

150
150
x
I

*
I
x
x

x
I

I
x

120
loo

80 80
120

75

-.

75

*
x
x

1.

70

150

150

150
loo

x
I

75

75

80
x

x
x

75

x
x

I
x

I
x

75

I
I

II

185
150

x
1M

-.
x
150

x
x
x

150 x

x
x

If

x..
x.
x
x
120

75

70

75

II

:o

75

75
75

-.
-.

150
80

75

75

130

x
I

75

75

x
I

-.

70

@J

150
x

:5
75
I

x
x.
II
150
80

185

&I
60

.&
75
x
x
x

x..
.........
*
........
.........
.........
x
x
x
x
x
75
75

180
x

-600.
x
210
x
210
70
210

x15

75

x
x

75

600

75

75

75
130

loo

1w
AY

100
x
160

200
200
75
75

75
x

150

x
x

AY
loo

150
150
150
150
150
IW

150
150
150
x
x

hc
OS
a. b. Ire
a. e. gl. w
a. ct. w

150
150
150

160
150
150
x
x
160

75
75

150

AY
AV
A;
IW
loo

Trlethyt Alumanum
Triethyt Sorane
Tr~lluorov~nyl Chloride
Trlhydrorybenzolc Aad
Trlhydroayethyt Am,e

x
x

75
75

a. ho. ta. w
a. ho. ta. w
a. cb. 1. w
HCI. w

OS
a. Cl. w

150

x
x

E
s

100

AV
A;
AY
Any

h
a. e. OS. w
Of

200

.
x

I
cl

165

w
a. cb. 1. w
P. ho. ta. w
a. ho. ta. v

loo
loo
see Solvers

.
-

1
<

185

x.
150
150
150
150

a. b, e

915
no3

go

AY

a. 8
gt. w

100
loo
100
loo

165

see Solvents
100
loo
100

s
I

60,2fJ.

185

100
see Solvents
see Solvents

Any
loo

i$

eo

185

150

AY
100

AY
A;
100

x
x
100
loo
100

x
x
x
x.
150

OS
OS

Trlchloromethane
Trlchloromonoltuoromethane
Trlchlorotrlttuoroethane
Trlcresyt Phosphate
Trlethanol AmIne

p
z

75
loo

12-J

130
75
75
150
75

130
70
70
x
70

130
loo
loo

210
75
75
210
210
75
75
75

75

210
-.

75

75

-.

lea
75

75

70

:_

210

75

(continued)

838

Corrosion

TABLE 7.4:

Resistant

RUBBER,

Materials

Handbook

RESIN, STEEL, ALUMINUM,


LEAD, GLASS, CONCRETE
MATERIALS-GATES
RUBBER (continued)

Tnn,trophenoI
Trtn~l~ololue~e
Trtoctyl Phosphate
TrlOleln
Tnpalmrl!n

a b. cl e w
a e
a,ac
e
a Cl. e. CI
Cl e

AV

Trfpolyphosphale
Tnsodwm Phosphate
Trltolylphosphale
Tung 011
TlJrpenhne

Av
Av

OS
e cb cl. 0
a aa Cl. e

100
100
100

x
150
80
x
x

a aa. Cl e
a b. e, w

100
100
Anv
100

x
x
150
x

100

80

8
AnV
Any
Any

150

Turpenl~ne Subshlute
1lJrps
urea.
VarnlSh
eoetable

cm

Vers~lube

FM 8 F50

x
I

loo
loo
See Solvents

x
x

e gl w
Cl e. w
w
e

x
x

185

185
185
x
x

x
x
185
I
x

x
x
150
x
100

150

150

150

190
x

I
x

120
x..

.#

x
185
120

x
200
120

x
150
120

x
150

150
185
150
185
150

150
200
150
180
150

150
150
150
120
150

150
150
150
120
150

io
x

I
80

,nvl Trlchlonde
VM~(L P Naqhlha
water
WalerproofIng !&all

a. e. ke es

100
100
Any
Any

x
x
150
150

Whiskey
Whtte Caustic
White Coppea
While Lead S~liate
Wh,,e Vllnd

a. gl. w
Ql. w
i. w
gl. w

100
AnV
Any
An;
Any

150
150
150
120
150
150
x
1Oa
x

100
Any
100
100
AnV

Zinc
Zmc
zmc
Zmc

a. w
a. e. pi. w
gt. w
gl. w

Any
Any
Any
Any

150
150
150
150

Acetate
Chloride
Sulfate
Vllrlol

e. 0
w
e
e

x
185
185
185
195
185

100 x

.
x

185
185
185

170

170

170

170

170

75
75
70

180
100
130

180
130
70

x
70
70

400
210
150

75

75
75
70
x

70
75
150

75
75
75

75
75

75
75
75
210

x
75
x

75
75

1w
100
75
100

70
75
x
x
x

x
130
200
150
200

x
x
I
)I

x
170
150
170

2:o
180
210

75
I
75
x

75
75
75
75

f5
150
110

150
150

x
75
90
170

150

75
210

75

75

75
x
150
-

150
70
150

70
70
75

75

x
x
I

100
200
200

x
x
x

200
75
130

75

150

150

150

150

185

100
120

150
120

120

75
100

x
100
x
100
loo

x
x
x
I
120

x
x
x
x
150

70
x

75
x
-

150
185
150
150

x
150
150
150

x
150
150
150

150
150
150
150

100
100
loo

80

I
x

150
x
150

80

a.
a.
a.
a.
w

150

Any

Wood Tar
wood vmegar
xy1ene
Xylldme
Zeollte

)I

OS w

e. aa. w
a. e. w
e. cb. cl. o

x
120

120

Vtnyl Cyanide

See Solvenls
100
Any
AnV
100

2k

100

a
a.
a.
a.

Whltlng
Wine
WIntergreen 011
Wood Alcohol
wood 011

x
100

100

wnegar
Vinegar Niwhtha
vmegar SalIs
my, Chlor,de

AND WOOD LINING

70

75
170
170

210
140
75
100

210
210
210

I
x

75
75
75

x
I
x

x
75
75

Comparative

7.5:

TABLE

IRON,

BRONZE, STEEL, SYNTHETIC

Resistances

of Materials

RESIN AND RUBBER PUMP MATERIALS-ITT

Chemical Resistance Table*

KEY TO SYMBOLS:

WES,

May be suitable
dependent on concentration
and
temperature.
Contact
factory
for Engrneering
Assistance.
N Not recommended.
0 Blank:
Information
lacking at tome of printrng.
Contact
factory.

IMPELLERS

SHT rs, etC.

A Satisfactory.

Acetald*
-_-- ___-.
Acetamide
_._
--._
Ace@
Solv.(Crude)
AcelaJe Solv. (Pure)
Acetic. Acrd
GlacraliY
. ._t.

I* 10% --~
I825%

$u
-2

5:
:C.._A:

CH,CHg
CHXONH,

N N
N N
A
N
N
N

-CH,COOH

A
C
C
C

.N __c
N C

C,H..CH,OH
C,tl;CH;!IH

CH,OH
CH-H,XH,OH
_ __ ~.
C:H.CH,OH

:-Prwl
Aluminum Etch
Aluminum Chloride

I2

AICI,

1.Wroxide:.~_ _ __~~AI(
Oxide

AIO,

lSil!ate
Amines

AIISOJ,
R-NH,

Carbonate ~___~
__~._._
_I(Ceenite6
LChloride

II

contained

C
Anlj_FEeze!by

N
A
N

9.
A
A
A
A
A
_~.

A--A_
_A_-!.
N
A_

-4 _A
_A

i-

-A

CA.
_C_ _AA A
1
A
C..A
N
N

A-C
A A
A A
A A
A
N

c
--N

-N
-A

C
C

N
A

N
N

IN
-N

N
C

N-

/i

.!!.

ma-Sta, Permaguard, Pyro Perm.,


Sears, Shellzone. Smith-Blue Cold,
. Prestone
Pyro Super ~--_.~.
mm--3
.a..;
-. varworene
Aromatic Hydrocarbons
.(+sjlt
Factory)
Arsenic Acid
_. __._ H,ASO.
. ..i

:
P 1.
A_ _CC
N.-. N

N
1
C
CC

N A;..._ _
A-A __c
N_: A c_ .._!
A-t A ;!._A
A!AI
A

J-A

.f!_ -A

_tj N
_A

AIA_N
NT-A
--N.A:.._J!
C;A.A

C
i

CJ
N

A__!!
C
jI_
-C__
L 1

_!._._A -._A
P
N _!G
A
A h
_A_!
---~
A
-K _!! _&-A
A
JL!!
_!L_!
shaft

_A__.N

_!_A
A
A
A

A
A
A

A-N

F. Titanium

P;A;Np
C-A
_A 9
N - A.----c
A
N :.A__

Bay Oil__
Beef Extract

! _ _.f!.

N~tU,o
(NI(&cJ

_!-A
A C
A
c

A
A

4
A
N

_N_ f!

_N_N

A
A
A

fNHJ:CO,

-4.

@lel~~el~~

.A.
A

KEY TO FOOTNOTES:
2. To 25%
concentration-150
3. To 25%
concentration
5. Use Hastelloy
B shaft
Data

C
A
A
-A
A
-.A

NH,HCO,
HH.F.HF

50%
___-__

~- Oxalate
Persulfate
-_--~

.C
A
A
C

_N_H,o_H JLA
NH,NO -- A

<itrate
44

c
x

A ~mr! .P
A
A A
A
F; Ii
A
A A
:i
Ki A
A
A
A

N&Cl

_1_Hydroxide

_A
A

j-

AmmonLa. &@~~:_Lii_qujd_
NtJ _A .mN
_:>jquors -__.
NH OH.H:O_. !!__N
Nrtrate
A N
NH,NO,
.~__
Am_Fonium Bicarbonate
Bifluoride

2
m
-.
P
C

A
-~A
A

._Y .BeW
_Bulyl
------C,!@ilOH
_/_D!acetone
LCH,lXDHCH,COCH~
~. ~--__
_ __._.~
__Jthyl ~_____~
CH&lltj
C,H,&tf,OH
_~_._Hexyl
C,H$y_
C:H.CH:Ofi
.

B
A
_~.

C
__
A

C_C
CZ~_C
A A
A-. NN N

Acetic Anhydjde
~_
._~~c_H,co~~P
Acetone
.__ ~rX&O.CH>
Acelylene
HC*CH
kcetylene Telrabromid;
f$liBJ,),
Acetylsaiicyhc Acid (Asp&l
CH,CO*O*C..H,COOH
~~~__..___
Acrylomlrile
CH,=CHCN
Pdhesive (PVA)
Bordon Chem.
Co.
-;, Fmdley__
. . ~~_._ ____

~*_I~~propy!
Methyl
-..-__.
I Octyl _-I

IMPELLERS

z
z
!iI

$0

(* 50%
_lPy!e
~__1: Vapor

IsobuK

JABSCO

.-___._

:Pgcific Soap
Alc_ohol.~Amyl

DI ES,
i. etc.
-rb--r--.-

-SI

839

of Construction

Union Oil
Brewery Slop

Brinc.lfuL.l.dldik
6.
8.
12.

Slow speed
10%
at 85
F.
Titanium
shaft

in the table is based on results of tests taken at ambient

15.

temperatures

To 10%

concentration-100

unless otherwise

noted.

F.

(continued)

840

Corrosion

TABLE 7.5:

Resistant

Materials

Handbook

IRON, BRONZE, STEEL, SYNTHETIC

RESIN AND RUBBER PUMP MATERIALS-

ITT JABSCO (continued)


BODIES,
SHAFB.2

.--_

Jigtane
_Bu&not

_Catt
CaCI,I C 1 Al Al.-A

calcium Hypochlorde I0 Ia CafClO),

1~1 N

Tetrachloride

Chlorinated Lime
Chlorinated Trisodium Phosphate

Zhloro.Acetone

A.
A
A ~A
A
A ~A ._I.
A
A A
_&-&A
A
A
A
A
A

Disulfide

_A_ A A
C A A
4-A
A
N
X
N_
N_c -..A
A.. A
A.-A._
CC
A
A,

A
A
A
A

!!__A_
&-AA- _A_
A
A
A --A -A .-

IC

A
A

c
A
N NA
A
N N A
A
--.-- N
!I.-!!__
C__A-.X
. IN__k!__A
.._. -.-_!NCA_
A - N._.__-N
N
N -.-...
A
.._._.....
2.._.-_-.
c --

HXrO,

A A
A __ _, A--.-_-_N C--C_ .-A.
U
N ._.....
N
.._ . .._..
A_&
c_______
__
N
4.-._-.-tUA
A

t!.
tU<
.- ..-.. .- N
A
AN AA N 1U_.._..._._
N:. A.. .!!!____ N

I!_ C.-C.
IY.--_
._IU-Y-A

IU..._!U. .._A..

____
C,H,O-H,O
L_.

I4.- ----.._
-!
.-I
_!
._I

i
_!
..!
!
I

Clove Oil

KEY TO FOOTNOTES:
5. Use Hastelloy 3
IO. Chlorinated lime

shaft

Corn Oil

_I$&jiSG~i -. .------._-

+$

Cream
h
Creosote_Oil
I A
Cresols
_CLesylic
.-. Acid
-______
Cutting Oh ((Water Soluble)
(Sulfur Base)
______..
Cyanic Acid
~
cycle Hexane
_Darex A.E.A.
Oegerm, Deodorants (by trade name1
-.-_
Blue
Chip
---_
Flushex~____
H7BD tSO%l
tloo%t
Monogram OG19

IY!!!__!?

Chocolate Syrup
Jhlo_c_AcM~Cotd
I 50%
Cider
Cinnamon
Oil
..___ ._.~
Citric Acid
---__-_Citric
____Oils

IMPELLERS

L. .L_

(HACH:&t,
NrA
tsee Butyl Atco&ol)
f

CalrJ~Bisulfate__ _
Calcium Chloride

BODIES,
SHAFTS, etc.

IMPELLERS

_kYEL-55___.

.I

L-55 #IO1
u

atlfl?

__.

..---

11._-.::-

J~fia_s_j_Menascol
Dele!gen_t_t_. __...
--_
Ofievloqrng SoJrtion Copy Mach

Dibromochloropropane

teobjt-Special

*I

Shell-Premium
--_
Standard~_
Oil
Texaco 448
_
Fuel Chief
BjesterSyn. Lub._O~ .---__.
A
Ehethytene Gtycol __! ](Cti&t@l),
,A
Diethyl Sebacate [CCtM~coocJi,]l
Di-Isopropyl Ketone
fCXl,)IC_tCOCHfCH>L
------ i.
Oinitro Toluene

_0:lyinfectantDeodorant

11. Sodium He* _...___ r.._ sphate


12. Titanium shaft
All impeller compounds i normally ok when concentration

At A
N1.A
NIA
NtA
-...

N
N
N

A
A
A
A

A
A
A
A

A.A
!_.A

AAA A
A .A

_..

A
A
A.
A

A
A

-i

is 1 part oil to 50 parts water.

(continued)

Comparative Resistances of Materials of Construction

TABLE 7.5:

841

IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued)
BODI

S,

etc.

b!!

DIES,
TS, etc.

IMPELLERS

P
ii

GoM.Monocyanide
Grapefruit @I
Grape Juice __

-_
.A

Et&n+mine _,_~_H,N.~H_~CH;OH___.
Ether Co?po_Fnds-_.
.c
EJlyyl
Acetate
CH,COO*C,H,
---_---_._---.
-A
- Axlate
CHXHCOOCzH-.
_--.-.
._ _..--..
_Chloride
_ -- - ~-- CH,CH$I _-C
___:_Ether_.-_. -__ C,H,@+ _C
E!~~_nep~ide_~~~Cl~C~~~C~_
_.
HOCtlz*CH,OH
A
Glycol
___.__.______._
__._
__.._
Ethylene Oxide
(CH&O_J
Fatty&ids
C
.___
Ferric Chloride
Fe&
y_
---- Nitrate
--.FeNO, Oxide
___-K!?__ Sulfate
FeSO, _y
ferrous
FeCI, .N
_ .._-___.Chloride
-.-___..
Sulfate _-. --- :.-_.. FeSO,.-- N
Fish
Batter
N
__.._-.---_-.
fluoboric Acid
HBF, i;
Fluosilicic Acid?PVC 25%) H$iF.. N_
Formaldehyde
HCHO C
@@c Acid
HCOOH__v
Freon II (MFP6
-~ --~-_
CCl,F C_
.___-.
_
_k!2We!-.
I_ 22.
113 ITi+

W_!~ice___
Furan Resiq,

.-- Arabol
.____-Cohoes
Emhar!
Lavoris

A
A

C
A
A
:ti
II?
.-

A
A
A
A
A
-A
[A
A
N
-_.
-..A

--~--._Hydraulic
.__..._. Fluid__
-. Skydrol
_-.- 700_Petroleg_Base

IQ _.C
C N
.N A
N .I!
._
!J _G
N A
A A
C C
A 3
.-... _..____...__
_A 3 .N
..___.CCIF,
..C .A c
____CJ&~,__ A .~
.__i c _.A
A .A
,__
.A A
A
A
-.
-.A -A

_ _ _

Glycolic
Acid (70%)
-__._-._-----_
KEY
5.
6.
!2.
14.
15.

A
A

Hair Solution (by trade name)


Breck
._ Clairol
_ _ __-.__
._ __ _-. Ouart
--___-_
- Mentos
----_-._

HOCHICOOHL
._ -

- _._~~_

Hydrazine (Water Base)


_____ __ ~____._____-__
(Alcohol Base)

,-..__ .._.. ~... ~._.


HY&l*ric

_h _A
_.A A
_. -A
A 3
4 ..A
A
a -A
-A
_ 1_-

-.

__..-___
Kerosene

Acid 6IFx,6-&INA.

HCN! N; N_A_N_A+A{A/Ai
N., NL_._ C_ C

C AJ

~--

L._

TO FOOTNOTES:

Use Hastelloy 6 shaft


Slow speed
~ita~n_ium shaft
._
To 40% concentration
150
To 10% concentration-100
Hype-See sodium thio sulfate

F.-Hastelloy
F.

Bshaft

Impeller
16. Use Polyurethane
17. To 40% concentration
To 20% concentration.
Use Hastelloy
Water soluble

B shaft

lmunallc
acid t

(continued)

Corrosion

842

TABLE 7.5:

Resistant

Materials

Handbook

IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued)
IDIES,
TS, etc.

IMPELLERS

-__--_
Lactic Acid

CHJHOHCOOH

Lard

_____.~
Larvacide (Trichloro Nitro Methane)
_!C_h!o~oP&i!~_
____.. CCI.I.NO,
Latex:_
_~
Lead Sulfamate
Lemon Oil
~_______._
Lignin
~._
~ Lirpror
Lime
_CaC
Lindol
Ljnseed Oil
Lithium
Bromide
LiBr*H,O
-__
__ _.
Lubricants (by trade name1

Multi-Circuit

_C!o!vn!~&avY.OutY
Multi Puppse
.__~._.._
Lubrico-M6
Marfak--2H0

N+pyl

__IEthylKetone

Acetate

N-Pro~~~Al~ohol.
Naphtha
Naphthalene..
Nickel Chloridell

A_

__60%.
SC%_

~_

A A_
A. _A

C_H,COOCHfCtt,~~ _A_ A
__CH,lCH.),OH
.~~ __ A_ _A
.tmjxturej
A _A

.___

Nickel Sulfate
Nrtric_Acjd fdilute)r2_

__ _MgO~
Sulfate
-..-.---.___
___ MgS_O?t7_ti,0
&aanese Nitrate_MnfNOJ1*6H,0
Mash
Mayonnaise
-.--~___.-..__.
Melamine5
N.CfNH,)N.CtNH:)N*CfNH,!
__--_
Mercury6
Hg
Met~a~ol_fMethyl Alcohol)
-___ flOO%l
..__
fSO%J
Mercuric Chloridqf_
HgCI,__
Methyl Acrylate
CH*CHOOCH,

___ Chloride____
_L_!Wowk~e

_ __C_HACH,T,CH,
CH.,tC.H,l,CH,

N-Pentane

Oxide-

CH,tCHJ,OtCHJ,CH,
_ _ ._~ -____.
_ _C_ A_
__. _
__ _
CHI(Ctl>XN
CH.,(CHJ;CH,
A A,

N-Heptane
N-Hexane

Magnesium Chloriderx MgCI$H,o_


Hydroxide
_ __MgfCl$,
I_ Nitrate
MgfN_OJ<2H~O_

:: U!y!_Ke@e
Cellosolve

CHXOOtCHUH,

N_&Gritrile

.__Ww

Etch

Mustard
__-.__
N,Butyl_&etate
N -Butyl Ether

C_
N

NiSO,

HNO,_N
.__~_F.

_Z_-!?ude_.____
Red Fuming

C,.,HI _A
NiCt,
N

~_~_

N
Ir
N
N
N __ N

i.. ..N

NitrobenzeneNitropropane ----.

0:

C..H:.NOz C_ C_
CH,fCHJ,NO, __~
_._CICH
_. ...!OH ___ _
Ch!oro-Phenol_

._

0-Oichlorobenzene
Oit .- --- Aniline

C..H,CI,
A

Anise ___~_
-ASTM
f 1

___ _~_
A A
A A

ASTM #3

:_Hay_-_.

CH.8CO!CH&?ltl_
CHJ$tJXH,OH

_-!%!I
C,,H,
CH,CO4H,CH,

lsobutyl Ketone
_____CH,COCHfCH,)CH:CH,
Isopropyl Ketone
_~__CH,C$tHCHfCHJz_
Methacrylate
CH.CfCH
.---___-<AL_._.XOCH
Methylene

Bromide.

Chloride

Dichloride
-----________

_____HrCti_
--

CH,CI,
_CH:CI,

Creosote
-----~,
Diester Syn.--.
Lub.
----

Milk

I Dromus A
-__..___

Mineral Oil
KEY TO FOOTNOTES:
5. Use Hastelloy B shaft
6. Slow speed

* c--_
__--12.
22.

Titanium shaft
Water soluble-slow

._^-

Muriatrc Acrd-See

Hydrochloric

Acid 20%.

speed
(continued)

Corwafative

TABLE 7.5:

Resistances

of Materials

of Construction

843

IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued)
BODIES,

BODIES,
SHAflS,
etc
-7-7
r- 7

IMPELLERS

IMPELLERS

Photographic Developer
Crude

___

_ _

~~~

_________
Palm
--- Peanut
__-

WBirchwood
-__--

. Palm
._-___Oil
_Palplex 662
Peanut Oi!
Peppermint Oil
Perchloro E*lene
-__

Cyanide Bath
Fluoborate Bath
Chromic-Sulfuric Bath
Fluosilicate Bath\
Fluoride Bath
-__-- Black Chrome Bath**
Barrel Chrome Bath!
Copper Sulfate Baths5
Copper Fluoborate Baths
Copper Strike Bath
Rochelle (1 Potassium Salt Bath?
Rochelle & Sodium Salt Baths
Barrel Copperjath
Gold Plating (Teflon Face Seal)
Indiueaanide PIat&
Chloride Bath
_____
.~_
FerrousSulfate Bath
FerrousAmmonium
--___ SulfateBath
Sulfate-ChlorideBath
Fluoborate Baths
Lead Fluoborate Plating
Nickel Fluoborate Bath
All otkfirNkgL@ths*

Amber 16S2010)
__~____.._
_~ Amber (6S2001)
Lily White.___ Snow White
_~_
___~______
Phenol (Carbolic Acid)
Potassium
____
------- Bicarbonate
Carbonate (Potash)

-y7-_ 45:&W.sL_

__.__-_.

TO FOOTNOTES:
Use Hastelloy 8 shaft
Titanium shaft
To 10% concentration-100

-I?_
C
-!-A
A
1
-A 1
A
A_
-AA
_&A
_A-_
_A__
A
-z
2. 1
AA
A-2
TA-__
_A__~!
A__!
&a
_A__
AA
_A._
A
1---f-

phe?-!_C_qmgou_nds
Phosphoric Acid, Crude
I* O/45%_
__ ~_
KEY
5.
12.
15.

A
A
A A
A
A
A
A
A A
A
c__
--C_ _
c_

KHCO
Klco

-. -___

tAll Impeller compounds are normally C+I when concentrabon IS 1 part 011to 50 parts water
F.
(continued)

844

Corrosion

TABLE 7.5:

Resistant

Materials

Handbook

IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued)
BOO
BOD :s.
IMPELLERS
SHAFT
etc.

IMPELLERS

-7 .--7- T-7

&

g
>
-:

-.Sodium
.-.-Hydroxide

2
_!_!

Hydroxide
-(Caustic Potash)
--_______
__
---- Permanganate
___ Phosphate
__- Mono
_
~_ Sulfate

$4
_.

1
-_
&
A
__.
._.-

-ResinSolvent 17073)
Rose Oil
Rum

-7

l---r;

-.
-

!!_

j&k
Stearic Acid
Stoddard Solvent

Shellac-Orange
Silica Gel
Silicate Ester

c
-

Stannic Chloride

Chlorinated Trisodium
Phosphate
Klenzade
Sesame Seed Oil

c
C.-

___-

Silicone L45

_Silicone X527
Silver Nitrate

Sulfur Chloride
Dioxide*_ ._
___.
~Rvlolten)___ __
I. Trioxjde, Dry
Sullurrc Acid 0%
~. 60%
_.__-__-_._..
.
Over 75%
__.-__
fuming___
___.
Sulfurous Acid:_
Tannic Acid
_.
Tanning
Liwrls_
.._
_

Soda Ash Eodmm Carbonate)

Bicarbonate
-__
Carbonate

--- Oil
KEY TO FOOTNOTES:
5. Use Hastelloy
B

12. Titanium
26. To 20%

shaft
shaft
concentration

27.

Has effect

-.._-

-.-._

i_
I\
.-

A
A
.-

c
k

on binder for carbon seals and bearmgs: Model 3010-l

recommended.

E
-~

151

(continued)

Comparative

TABLE 7.5:

Resistances of Materials

of Construction

IRON, BRONZE, STEEL, SYNTHETIC RESIN AND RUBBER PUMP MATERIALSITT JABSCO (continued)
6
DIES,
S,
IMPELLERS
SHI

el
_-

TS, etc

~~~~~
Tetralin tletrahydronaphthalenel

N
-~ _..

ThioAlycolic Acid

-. c
N

N -Y
.-C
4 ._?!

Trichloroethane
-__
Trichloroethane
_____

Triethyl Gorane
Triethytaluminum
_~_~_
..____.__
Triethanolamine
___.-_-Ift?
Tungil
Turco W.O.
~.. #I --_-_
Turpentine

:SplayJ*e
--_- Vacate (Dactalt
&I
& Wines
White Liquor (Pulp Mill)
.~___

Undertakers Restorative
Urea formaldehyrje
Urine
-.-_____
;__--_KEY TO FOOTNOTES:
5. Use Hastelloy 8
12. Titanium shaft

Vanilla Extract
-._._-___.__
Valclene 200 (DuPont)
__~__
-.___
Varnish
______
-_-Vegetable Juice
Vegetable Oil
-Vinegar
Water Acid Mine
2: Soiler-;
--~--.~__.___-..
_.
-.- Orstilled, Lab Grade
fresh
H:O
Water, Salt~__~_
CoJd
-___
Weed Killers (by trade name1
Amino-Triazole
Atrazine-Divron
._~ ~____
_-.- Karmex-Diuron
_.._.. -_---.--.-.- Ktoben
7-Prop@ne-50W
_-__.
Simazine-BOW

shaft

- White
-_.---Water tPapar_MrIU
.-_-.~
WRDA
Xylene
C&Ck,
_~
_ ~--.-~
Zinc Chloride
znct,
Hydrosulfite
ZnS:O,
---.--.__
Sulfate
-@SO,

IMPELLERS

845

846

Corrosion

TABLE

7.6:

Resistant

IRON,

Materials

Handbook

NICKEL AND COPPER ALLOYS

FOR CASTINGS AND FORGINGS-JANNEY

CYLINDER

CORROSION RESISTANCE CHART

Acid Mixtures

50%

Acid Mixtures

25% HN03

Chlorine

(Moist)

Chlorine

Dioxide

Ferric

HNO,

Sulphate

1 O-30%

__

._

--

--

--

--

(continue id)

847

Comparative Resistances of Materials of Construction

TABLE 7.6:

IRON, NICKEL AND COPPER ALLOYS FOR CASTINGS AND FORGINGSJANNEY CYLINDER (continued)

\
Fluorrne

.
t

Formrc Acrd
Hydrobromtc

..

All

Acrd
Acrd

All

Pe&rde

_.

Hydrotluorrc

_.
_--

Hydrogen

Sulphrde

(Dry)

Hydrogen

Sulphrde

(Morst)

_.

Hypochlorrtes
Lactic

Acrd
--~--

Magnesrum
Mercunc

Chlorrde

---__
Nickel Sulphate
.- - --~
Nitric Acrd
-----.~_--______._
Nitrrc Acid

_.

A
0

_.
-~

I _____~___
__

Chloride

__

__
O-7040

..

_.

_.

__

..
A
-__._
_.

c
-._..
c

O-5%

H~drochlorrc~Acrd

Hydrogen-

O-50%

Acrd

Hydrochlorrc

_.

..

A
_
._

-~

r
C
J--

--

_.

8
_c

--

._

..

_.

--

-.

-.

--

-A

--100%
.___
__

Ol&c Acid
---Oxalic Acid

A
___0

c
__~_.
A

All

__

A
__-A

A
_-._
c

A
--

All

__
7

__Phosphoric

Acid
--

Picric Acid
Potasstum

Chloride

O-30%

Drchromate

Silver
Sodium

Nitrate

_.

__

--___
O-10%

Chloride

Sea Water
Sodium Hydroxrde
._
__-.
____
Sodium Sulphide
-_-._
___
Sulphur Dioxide (Moist)
.--__.
___
Sulphuric Acid
~_____
Sulphuric Acid

l
l l

--

c
_.

-.

6
__-A

--

_.

__

__

__

0
~_

All

__

-0

__

t t

-A

-_

__

-z

_
i

B
0

AA-Excellent
resistance
B-Good resistance
C-Poor resistance
-No information

--

__

_~___
2590%
.-___-_
9ti%

All
____

_.

A
_____
_-

___

___Potassium

--

.~__

Bpar Langley .4lloys


Cabot
lnco

TABLE 7.7:

VARIOUS

RESIN, ELASTOMER

AND STEEL TANK MATERIALS-NALGE

;Th,i,s chart will assist in the selection of NALGENE


tanks for use with common chemicals. Under normal conditions, chemicals rated
S may be safely handled in NALGENE
tanks. Chemicals rated U are not recommended
for storage in NALGENE
tanks. This
chart applies to unsupported tanks at operating temperatures
from 70F/21C
to 140F/600C.

Acetic Anhydride
Acetone+
Acrylic Emulsions
Actylonitrile
Adioic Acid

&

:
S

;
S-___

s
_

;
_

s
s

I
s

:
u

i?

ii-j:

:
s

k!
;

U
G

50

loo

s
_

loo

s
Iv)

8
13

Ov)

3cn

,*m

,v)

>mfn

ES

v)

3m

3v:

3v:

U-J=

3v:

*=

3=

3=

Comparative Resistances of Materials of Construction

849

850
Corrosion

Resistant

33u
I

Materials

ov)

Handbook

n*

nv,

Iv)

Iv,

Comparative

Resistances

of Materials

of Construction
851

852

Corrosion

Resistant

Materials

Handbook

v)

v)

WY

3
>

>
>
,
1

Iv)

Iv)

3v)w

3v)

n
13m<

Comparative Resistances of Materials of Construction

nou
-

ov)v

Iv)

1 t

Corrosion

854

TABLE

7.8:

Resistant

METAL,

Materials

ELASTOMER

Handbook

AND

PLASTIC

PUMP

MATERIALS-OBERDORFER

KEY SYMBOLS: This Chemical Resistance Guide was compiled from available charts and tables provided by material manufacturers
Their
nomenclature was condensed into key symbols. Their descriptive words shown below can aid in making judgements as to pump suitability for
specific applications.
(A) ACCEPTABLE:
Excellent Resistance
Fully Resistant
Suitable
Recommended
Excellent Compatiblity
Fully Compatible

(0) QUESTIONABLE
Good Resistance
Minor Effect
Moderate Effect
Slight Effect
Slight Attack
Fair Resistance

CHEMICAL

(N) NOT RECOMMENDED


Severe Effect
Unsatisfactory
Not Acceptable
Do Not Use
(

RESISTANCE

) DATA NOT AVAILABLE

AT THIS TIME

GUIDE
NON-METALLIC

EIASTOMERS

CODELETTERS
Acceptable
aA Questranable
Not Recommended
N
BLANK-No Inlormatcon
Sublect to pitting when allowed to dry.
Sublect to attack when hydrochloric acid IS present.

NAME OF LlQlJlO

Acetaldehyde

Cold

Acelamrde
AcetateSolvents
Acetone
Acetyl Chloride
Acelomtrde

1 ColdA Soilino
Cold8 Bodmg
Cold

Acetoohenone

Cold

Acetylene

Cold

Acetylene Tetrabromide
Acetyl Chloride

Cold 6 Boding

Acrd Mine Waler

Cold

Acid, Acebc (50% Unaeraled)

Cold

Acrd. Acebc (50% Unaerated)

Boiling

Acid. Acehc (100% Unaerated)

Cold

Acid. Acehc (lC@io Unaeraled)

Boiling

Acid. Acehc AnhydrIde

Cold

Acid. Acehc Anhydrrde

Boilmg

Acid. Acehc. Vapor

ZE
N
A
A

Acrds, Fatly

Acid. Fluoroborlc

Acrd. Fluorosduc
Acid. Formic

0
Cold lo Hot

N A/O

ONOOOAA

(continue1

Comparative

TABLE 7.8:

METAL,

BLANK-No

ELASTOMER

Resistances

of Materials

AND PLASTIC PUMP MATERIALS-OBERDORFER

of Construction

855

(continued)

lntormalmn

(continued)

856

Corrosion Resistant Materials Handbook

TABLE 7.8:

METAL,

BLANK-No

ELASTOMER

AND PLASTIC PUMP MATERIALS-OBERDORFER

(continued)

Inlormation

Subject to plthng when allowed to dry.

\lum

Uummum Acetate (Saluraled)


,I.._.^.....

1
I

0
Cold

0
A

A
I

N
A

(continued)

Comparative Resistances of Materials of Construction


TABLE 7.8:

METAL,

ELASTOMER

AND PLASTIC PUMP MATERIALS-OBERDORFER

857

(continued)

Acceptable
0
Ouesbonable
N
Not Recommended
BLANK-No Information
A

NAMEOFLIIJUIO

Anhyotous Hydrogen Fluoride


Anhyorous Hydrazme

I
_ _ ^

I IAl
IAl
1 IA]A~A]

I
I

1 I

(continued

Comparative

TABLE 7.8:

METAL,

ELASTOMER

Resistances

of Materials

AND PLASTIC PUMP MATERIALS-OBERDORFER

859

of Construction

(continued)

Acceptable
A
Puesbonable
a
Not Recommended
N
BLANK-No lnlormatlon
Subtect to pltlmg when allowed to dry
Subtecl to attack when hydrochlonc acid IS present

:alcum Acetate
:alcwm Bisulphate
.^I^:..- O.^..,_L.~^

0
n
,u,

N
I

N
n
,u,

A
111A

I,,,,-,

Al
A
I

AIA
.
.
,rr,n,n,

A
.

N
1

(continued)

860

Corrosion

TABLE 7.8:

Resistant

METAL,

Materials

ELASTOMER

Handbook

AND PLASTIC PUMP MATERIALS-OBERDORFER

CODE LETTERS

A
Acceptable
a
Questionable
N
Not Recommended
BLANK-No lnlormatron
Sublect to prttmg when allowed to dry.
Subtect to attack when hydrochlortc acrd rs present

y?
$

El5

3
F
E g Iii
Li 25
m
5 f
k2

NAMEOFLIQUIO

Calctum Carbonate
Calcium Chlorate (Dilute)
Calcium Chloride

Cold
Hot or Cold
Cold

Calcrum Hydroxide (10%)

8orlino

Calcrum Hydroxtde (50%)

Bodmg

Calctum Hypochlorite (2%)

Cold

Calcrum Hvoochlorrte I%% on Ptashcst


Calcrum Ndrate

Cold

Calcrum Phosphate
Calcrum Salts
Calcium Sulphate

Cold

Calgon
Cahche Liouors
Camphor
Cane Sugar Liquors
Caoella AA
Carhamate

Carbmol (Methanol)
Carbon Otsulphtde

Cold

Carbon Dioxtde
Carbon Drsulphrde

ii

T
-i
-

a
-

-A- x-

n T-ii- si1 x
n

a -ii a
n
-

Caushc Soda (See Sodrum Hydroxide)


Cetlosolve
Cellulose

A
A

Cellutherm
Cetane (Hexadechte)
Chma Wood Oil (Tung)

ii-

Chlormated Lime
Chlormated Salt Bone
Chlormated Solvents (Chl. Water on Plashcs)
Cold

Chlormated Brphenyl
Chlorine (Anhyrous Liquid)
Zhloroacetone
Cold

A
-

T
- - - -

A
-

a
a
- i-

a0
i T n -ii

ii

4/1
- a
- T
T
-

7
-

n
- n
7
n 7

Yi

Li

s
I

i-r

n
- n
- Ti0
-ii -T
- - ii-

4= a
-

n
n
-

ii-

2
-

%
*
z

T
0
-

n
Iii
Iiii-

A
0
T
- i-

i;i-

ii
ii

A
-

li-

n
-

n
-

n
-

w
n
7
-

A
-

4
4

!z

n
iiij-

i?
cc

ii

T
2
8
%
*

ii

T
- 7

T
- - A
- -

Cellulube

I-

n a
iz
- -

a
- - ii- -iT
- - - n

Catsup

Zhloro Bromomethane

Y
k?
8
Y

nn

n a
a
- - - -i
- - - n
- Yi
- T
- -7
- - - - - - - - A
ii
T T n n
0 n -6
- n
T

T
- 0
- T

grobenzene

(1
- a
- -0

Chlormated Water (Saturated)

is

-6 A ii
T ii 5

Carbonated Beverages
Castor 011

a
ii

Carbon Telrachlorrde
Casem

B
2
a - a ii
n - -ii
- Aa

T T

Carbon Monoxtde

(continued)

n
- n
- - - - - - ii- -

4
A
- +

A
0
iiiT
-

n
-

n
-

n
;i
A
-

T
Ti
-

z
ii
(continued)

Comparative

TABLE 7.8:

METAL,

ELASTOMER

Resistances

of Materials

AND PLASTIC PUMP MATERIALS-OBERDORFER

of Construction

861

(continued)

Not Recommended
BLANK-No Information
N

Subject to prthng when allowed to dry.


Subject to attack when hydrochlorrc acrd is present.

Copper Sulphale (5%)


Copper Sulphate (Saturated)
^
^

Cold
1

Borhng

iNIN

INI

lAi+lAlAlAl

~o~N~Q~N~A~A[A~AIA~AI

I,

,.I

1 I iAiNlAl
I I IAINIAIoIA]A]
I I
I 1 ,.I

lAtA/
I

(continued)

862

Corrosion

TABLE

7.8:

Resistant

METAL,

Materials

ELASTOMER

Handbook

AND PLASTIC PUMP MATERIALS-OBERDORFER


-I-

CODE LETTERS

B
c

NAMEOFLl@JlO

Cotton Seed 011

Hot

:teosote 011(Coal Tar)


Phosohale

Zrotonaldehyde
:rude 011
:umene
Hot

:upric Chloride
:upr~c Nftrate
Zuprous Ammoma Acetate

z
z

v,
_i

_
_
-

- T
T
T -ii
- 7
_ A
- -

:uttmg Oil (Sulfur Base)

7
- T
-

Yi
-

:yamc Compounds

_ - T
._ - - - - -

Zyclehexamone
Zycleweld LB08
Zvclohexane

:vclohexanol
Zyclohexanone
:yclohexylamine
)OT (Toluene Solvent)
)OT (Kerosene Solvent)
Iecalm

1300 Series Motor 011

)elvac Special Motor 011


lenatured Alcohol

--

!eteraent Water Soluhons


levelopmg Soluttons (Hypes)
lkacetone
lkacetone Alcohol
llamvlamme
ltbenzyl Ether
Iibenzyl Sebacale
llbromoethyl Benzene
libutyl Cellosolve Adlpate
Nlbromochlotopropane

J-

T
-

ii-

7
T

P
%
P

a
-ii
Ti
-

T
T
- -

iii

iiE
- ILI

a-

n
-

T
- A
- b

Yi
n
A

0
7i
-

ii-

n
n
-

;;
-

i7
-

n
-

n
n

n ii-

A
-ii
-

2 2
g ii?
>
K
T

T
-

-A:
- n
- - - - - - 0
- a
- a
- a

n
-

z < Y
2 H$

z
z

z
s5
x

-ii- Ji Yi
-

G
-

n
-

n
-

n
-

A
-

A
-

A
-

P
B
Y E

- ii
- a
- _ _
- T

IaIry EE2

Mac

T
3

Zyanogen

z
T

Mvac 12tIl Series Motor 011

-I
-

74 n

Ielvac 1100 Series Motor 011

&

:uttmg 011(Water Soluble)

Delco Shock Absorber FluId

7 7 7
n n
- T

Zreosols

i4
2

:ream

E
3

e
:

:orn 011

Iecane

ELASTOMERS
1
-

E
B
9

Sub]ect to plttmg when allowed to dry


Subject to attack when hydrochlortc acid IS present

:resvldmhenvl
,.,

METALS
-

A
Acceptable
0
Ouestmnable
N
Not Recommended
BLANK-No lnlormahon

(continued)

n
-

7 7
T ii

-ii- Yi
Qi
- Ji
-_
G -

n
-

A
- i-

z
-

E
t
$
-

-x 7-

n
-

77
ii- n
-

n
-

7
-

t+

Tr
- - -

_
-

T
- ii7 7
A
n-

Ti
N
-

- nn
ii- 7
A 7
- - A
ii-

SJ

El

n
-

7-

A
-

n
Ji
n
A
K
-

n
-

-A
_
-

3i-

n
n
_
n
n

n
A
A
-

(continued)

863

Comparative Resistances of Materials of Construction


TABLE

7.8:

METAL,

ELASTOMER

AND

CODE LETTERS

PLASTIC
P

A Acceptable
Ouesbonable
0
Not Recommended
N
BLANK-No lniormatton

PUMP

MATERIALS-OBERDORFER

-7

NON-METALLIC

ELASTOMERS

METALS

(continued)

H
9

Sublecl lo plttmg when allowed to dry


Sublecl to attack when hydrochloric acid IS present.

NAME OF LlljUlO
IIIbutyl

Ether

I
I

I
I
I

I
I

I
I
I
I
I
I
I
1
[
I
I
[
I
[
[
[
[
[
[
[
[
I
C
C
C
t
C
C
C
C
C
C
C
r
IDlphenyl. Ether

IDloctyl. Phthalate
O~smleclant Deodorant

IAl

IAl
IAlA
I1 IAI
1~1~1
I
I I I I1
11
I I IAlA
IQlAlAl

IAlA/

I I I1
I IAI 1 II II 11
IAIAI 1
11
I

IAI

(continued)

>

>

BP

2-B

>?a

2-P

zz

>?a

ZZ>P
z

ZD

>x-PPP>Yax.IIZ

>POD?-P~x-I>~~P~P

x. D

PROPVL.

CHEMICALGRAOECARBON

RVTON

POLYESTER

NORVL

NYLON

TEFLON

BUTVL

ETHYL

URETHANE

-5
F
s

,k
IT

Comparative Resistances of Materials of Construction

TABLE 7.8:

METAL,

ELASTOMER

AND PLASTIC PUMP MATERIALS-OBERDORFER

865

(continued)

NAMEOFLlfJJlO

I,,

,,,,,,,,

,,,,,

,n,

(continued)

866

Corrosion Resistant Materials Handbook

TABLE 7.8: METAL,

ELASTOMER

AND PLASTIC PUMP MATERIALS-OBERDORFER

(continued)

Acceptable
a
Ouesbonable
N
Not Recommended
BLANK-No lnlormat1on
A

Sublecl to pitting when allowed to dry.


Subject lo attack when hydrochloric acid IS present

f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
f
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
AAAAAPAA

Fuel Oil

Fwan. Furloran
F.._.__..I

A
A
~~LlllbULl3-l

AAAAAA
A

A
,+

A
1

A
d

(continued)

Comparative Resistances of Materials of Construction


TABLE

7.8:

METAL,

ELASTOMER

AND

CODE LETTERS

PLASTIC

PUMP

MATERIALS-OBERDORFER
ELASTOMERS

867

(continued)
NON-METALLIC

Acceptable
a
Ouestlonable
N
Not Recommended
BLANK-No lnlormabon
Subject to pittmg when allowed to dry.
Subfect to attack when hydrochlortc acid is present.

x
B
z5

NAME OF LIQUIO
f:urfurylAlcohol

(
(
(
(
(
(
(
(
(
(
(
(
(
(
(
(
(
t
t
t
t
1
t
t
t
t
t
t
t
t
t
t
t
t
t
t
H
H
H

(continued)

868

Corrosion Resistant Materials Handbook

TABLE

7.8:

METAL,

ELASTOMER

AN0

PLASTIC

PUMP

MATERIALS-OBERDORFER

(continued)

METALS

CODE LETTERS

NON-METALLIC

Acceptable
a
Ouestronable
N
Not Recommended
BLANK-No lnlormation

x
B
5

Sublect lo prttmg when allowed to dry


Subject to attack when hydrochlorrc acrd is present.

El g
% Li
t s

z3
a

ii
-

&
NAME OF LIQUIO
Hvdrocarbons Liaht
Hydro Drive MIH Lrght
Hydro Drive (MlHlO and SO)
Hydrogen
Hydrogen Eromrde
Hydrogen Chlonde
tlvdroaen Peroxide

Cold

Hvdroaen Peroxrde

Hot

Hydrogen Peroxrde (10%)


Hvdrogen Peroxrde (50%)
Hvdroaen
__ Sulohrde
Hydrolube-Waler/Ethylene Glycol
ifydroqumone
lvdvne
iyposulphrte Soda (Hype)
ce Cream
nk
nsechctdes
odme
odme (In Alcohol for Plastics)
dnfnrm

ron Sulohate
sotane
so-Butane
so-Butvl Alcohol
so-Butyl Methyl Ketone
so-Butyl N-Butyrate
so-Butvlene
so-Butyraldehyde
so-Octane
so-Pentane
soPropyl Alcohol
so-Propyl Benzene
soPropyl Ethers
so-Butvl Alcohol
sododecane
sophorone (Ketone)
sopropanol

Cold

x -T
ii- -iiTi
- 7
- - -

T
-

a
iiii
-

ii.N
-

A
- - - -

n
ii-

iT
7
0
K

7
A
A
-

2
I3

Y
k+
bi b
d

z
-

A
ii
i-

iT
-

Fi
-

si
i
i
i
iii-

- - A
- A A A
-

i-

A
- 7
- -

A
- - - -

n
-

A
-

A
-

1-

i- A
- a
- -

4
1
u
-

Ti- ir

A
- - -

A ii
-

rn i-

r- r- - - ii- A n- - - - -

n
-

A
7i
-

$
a

2
-

ii-

A Ii-ii
I- ii
Yi ii
T
- ii

r
4-

s
-

Ti

- -

Jet Fuel (JPI - JF6)

rA
-

sopropyl Chlorrde
cntnr

x-

ii- 7
-

sopropyl Alcohol
sopropyl Ether

L
>

zE
-

A
- A
-

Pi/CI

0
-

x n-

j_
- - -

iia
a

n
-

2
-

i\- PI/(
- I A
- A i/CI A
- ii- i-

a
- - ii-

5
Li
Y % I

- - - i- -

- A
- -

- - -

- - -

Li

si-

(continued)

Comparative

TABLE

7.8:

METAL,

ELASTOMER

AND

PLASTIC

PUMP

Acceptable
a
Oueshonable
N
Not Recommended
BLANK-No lnformatron

2
f
3
<

Flurd

l-

ii

9
2
-

P
8
ki

cerosene

n n

kerosene 8 Naphlha

T
-

A Yi

1 0 T. 33 Oil

1. I. Case No. 144 011

{etones
(eyslone No 87 HX Grease
(eyslone Penelralmg 011
teyslone Vetostan

T
-

n
-

-Ii-

T A 7 A
T
- T
- Yi +A
A
- n
- A- - - r - ii
- -

.aquers
Cold

.arvacrde
.alex
.avender 011
.ead
.ead Acetate
.ead Nrtrate
.ead Sullamale

n
- iii

.emon 011

.rgnm Lrquor
.rme
.rme Bleach
.rme Waler
.mdol

-ii-

.mseed 011
.rquld Petroleum Gas (LPG)
.rquor Lame

- Pulp Mdl

.rquor Sleep
.rquor Sulphate
.rthum Bromrde
.rlhrum Chlorrde

7
- 7
- -

an

7
0
7-i
T
-

n
n
T

7 A
7 A
- A
-

T 7-i
- - N

.rme Sulphur

0
T
T
T-

T
A

ii-

TT
7
-

5; Li-

.rlhrum Hydroxrde
.ube 011SAE 10,20.33

T n
T
- -A
- -

Elc

.ubncabng OrIs
.ye. Caustic (34%)
.y?.ol

NON-METALLIC

NAME OF Ll@JlO

.rquor

(continued)

ELASTOMERS

R E
H

.ard

869

of Construction

to prlhng when allowed to dry


to attack when hydrochlorrc acrd IS present

1 0 Auto Transmwon

of Materials

MATERIALS-OBERDORFER

- METALS

CODE LETTERS

Subpxl
Sublecl

Resistances

HOI

Eorlmg

dagnesium Acetate
lagnesrum Carbonate
lagnesrum Chlorrde (5%)

Cold

nagnesrum Chlorrde (5%)

Hot

0
-

n
- - a
- i-

Yi

n
T
A
-

z
I

5
-

El

* ?

Hd
ii Yi

7
-

Fs
- A
- - -

2
-

0.

n
-

A
-

A
-

A
-

n
-

ii-

ii
A
-

iL

z
r-

/
,

ii
-

i-

I
I

(continued)

870

Corrosion

TABLE 7.8:

Resistant

METAL,

Materials

Handbook

ELASTOMER

AND

PLASTIC

PUMP

-n

CODE LETTERS
A
Acceptable
a
Questronable
N
Not Recommended
BLANK-No lntormation

25

7i
-

Nrtrate

Waonesrum Oxrde
Hot

Wagnesrum Sulphite 8 Sulphate


Walathon Sprav (50%)
Waletc Anhvdrlde
Waleic Hydroxrde
Walt Beverages
Wanoanese Carbonate
Boiling

Wanganese Nrtrate
Warsh Gas
Wash
Wassey Ferguson Hyd 011
Wavonnarse

Wedwm Synthehc 011A


Walamme Resms
Wercaptans
Wercwc ftichlorrde

( 07%)

Wercuric Chlonde

tiercurrc Cyamde

Uercurous Nrtrate
Mercury
tierwry

Salts

tiesrtvl Oxrde

Methanol
Methyl Acetate
dethvl Acrvlate
A

dethyl Bromrde
dethvl Eutvl Ketone

+-

dethyl Cellosolve
tiethyl Chloride
vlethvl Chlorosllanes
dethyl Cyclopentane
dethyl Ether
vlethvi Ethvl Ketone

vllethyl Ethyl Ketone Peroxrde

dethyl Formate
dethyl lsobutyl Ketone
vlethyl isopropyl Ketone
dethyl Methacrylate
dethyl Oleate

s
8
s

2
ii-

T
T
7

-ii 5
- -

x-

n
-

n
-

T
-

T
-

n
T
-

T
_
-

0
-

-iT
- ?3
- T
T ii
-K
- ii
-

Metahcotl A165

dethyl Alcohol

2 z
i z
f
g
z

Wanganese Chlorrde (5001.)

LA

IS

NAME OF LIQIJIO

Wagnesrum Sulphate (5%)

(continued)

ii

iii ii

Sublect to prttmg when allowed to dry


Sublect to attack when hydrochlorrc acid IS present

Wagnewm

MATERIALS-OBERDORFER

0
-

=F
A

0
-

T
- A
- n
-

Ti-

T
- T
- n
7
-ii i
- - - A
-

T
-

- T
-

n
-

n
iT
A

Ti

ii-

i-

ii

+
A

+
A
1
+

ir
0
-

ii
1
L

2
8
E

9 L

2
-

n
- - -

5;
-

n n
- -

nn
A

n
n
- a
i;
-

A 4
n
- i-- -

i? F
2

i?

n
n
_
-

e
e %

Li

H2 E
T
K
i- 7
- n
A
- A
- iT
- A
- _ - - - A
- - - +
- - -

--I-

- - - - - n
- A
-

h
-

+
+
-A

- - ii- - n
- - n
- - n
- i- -

a
-

n
- r- n
A u L
n
- r- -

4
-

A
- a- -4 -

n
- s
-

A
0

A
A

a
- i - AL
- - - - - - -

5
A

A
-

i-

*1

(continued)

Comparative

TABLE 7.8: METAL,

ELASTOMER

Resistances

of Materials

871

of Construction

AND PLASTIC PUMP MATERIALS-OBERDORFER

(continued)

NAMEOFLIIJIIO

Cold

Ickel Chloride
lckel Ndrate

(10%)

tckel Plalmg

Solution

Cold
N

(1

A
A
A

A
A

(continued)

872

Corrosion

TABLE 7.8:

Resistant

METAL,

Materials

ELASTOMER

Handbook

AND PLASTIC PUMP MATERIALS-OBERDORFER

(continued)

Acceptable
Questmnable
0
Not Recommended
N
BLANK-No lnformatlon
A

11,Peanut

II,Pella

I
I

iAlA

/AiAlAl
iNlAlAl
1 IAlA
lNlAiAl
I I . I . I1 . I I

I
I
I

I
I
I

IAl
I I

I
I

I
I

(continued)

Comparative

TABLE 7.8:

METAL,

ELASTOMER

Resistances

of Materials

of Construction

AND PLASTIC PUMP MATERIALS-OBERDORFER

873

(continued)

Acceptable
0
Ouestmnable
N
Not Recommended
BLANK-No informalloo
A

NAMEOFLIQUID
(
(
(
(
(
(
(
(
(
(
(
(
(
(
(
(
(

(
(
(
(
(

(
(
(
(
(
(
(
(

(
(
f
f
f
f
f
f
f
f
f
farker O-Lube
feanuf 011
f

_.

I
IAlA

I I

I I

[AlAi Ai

IAI

lNlA/Al

111111111*1111111111

1 iAI
1

1 I

I I

I
I

(continued)

874

Corrosion

TABLE

7.8:

Resistant

METAL,

Materials

ELASTOMER

Handbook

AND

PLASTIC

PUMP

COOELETTEAS

Sublecl to plltmg when allowed to dry.


Subfect to attack when hydrochloric acid IS present.

;
?

w
E
z
-

NAME OF LlljUlO
Llquld

enola Llrws
eppermmt 011
emI

Cola

entachforo

Phenol

entasol

n
n

Whloroethvlene
etrolatum
etroleum Ether
henol. Formafdehvde MIX
henohc Resms
henyl Benzene
henyf Ethyl Ether
henyf Hydrazme
henyf Benzene
henvl Cellosolve
hasphate Esters
hosphorlc AnhydrIde (Dry)
hosohorous Trlchlorlde
hthahc AnhydrIde
Icklma Sofubon
lcofme Alpha
llP._I-Ill
_..
Ine Tar 011
Inene
Ipefme Cleaner
lashcizer
olydetm Moisturizer Lohon
ofyvmyl Acetate
ofyvmyf Acetate Emulsion

Elchromale

otaswm

Bicarbonate

Cold

otasslum Ffromlde

Cold

otasswm Carbonate

Cold

olassium Chlorate

Cold

otassium Chloride

Cold

olassIum Chromate
otassmm Cupro Cyamde

T
- - T
-i n
- - .-

n
7
-

T-

77
- 0- -

A
-

A
-

Yi
-

-_
-

-r-

ii

A
-

0
Yi
- 7;
- 0
- Yi0

A
ii

7-

ii A
A A
ii

n
-

B
%

- - -

ii

n
-

Ji

0
-

ii-

_
-

a
-

n
n
a
ii

n
-

A
ii- i-- ii-

n
7
A

5 5

n
- n
- A_
-ir 0 n

n
-

Y 2

T
-.
i -

7
-

7
T
- ii- A
- -

n
-

(1
_
-

s z
s
8 1 5

;-i SJ

(continued)
NON-METALLIC

ostage Meter Ink


otaswm

_
-

w
ti
:

H d2 2 2
t :: z a

77
- i7- - -

htographlc Developer

Acetate

z 2

a
- 7i- - - _
- - - - -

henol (Carbohc Actd)

olaswm

a:

sz
- - - T
- - n
- - - - -

enolalube

METALS
-

A
Acceplable
a
Ouestmnabfe
N
Not Recommended
BLANK-No lnlormatlon

enctllm.

MATERIALS-OBERDORFER

ic
A

A
-

a
-

i0
- A
A
- s
- 4 i7
--

r s

cr sn
- ;; - n
- - A
nn4
K
- ii- bA
7
-

r
ii
A

4
i-

n
_
_
A
_
-

2
_
_
-

n 4
ii- 4

n
n
a
n
-

4
4
h
T-

L
-

%
2

z
-

_
-

ii-

ZJ
Y

x
GE
- - - - - _ - - T
-

A
-

ii- -A
- -

_
-

_
-

A
-

A
K
-

;
+
-

i1
i.
-

4
-

A
n

4
-

4
-

(continued)

875

Comparative Resistances of Materials of Construction


TABLE

7.8:

METAL,

ELASTOMER

AND

PLASTIC

CODELETTERS
Acceptable
a
Oueshonable
N
Not Recommended
BLANK-No lnformahon
Subject lo pltlmg when allowed to dry.
Subfecl lo attack when hydrochlorcc acid IS present

Dlchromate
Cold

otasswm Hvdrate
otaswm

Hydroxide (50%)

otassum Hvdroxlde 150%)


Wassum

Hot
HOI

Boilmg

Hvoochlarlte

otassium lodlde
otasswm Ndrate

Cold

otasswm Oxalate
otasswm Perlluoroacetate
otasswm Permanganate
otasswm Phosohate
otassium Sihcate
otaswm

Sulphate (5%)

Cold

otassum Sulphate (5%)

Hot

otasswm Sulphlte
restone
RL 3161 011
RL High Temp Hyd 011
toducer Gas
topane
rooone Proflomtrde
ropanol
roplon-Aldehvde
roovl Acetate
I-Propyl Acetone
ropyl Alcohol
ropyl Ndrate
roovlene
ropylene Chlorohydrm
topylene Dxhloride
ropylene Glycol
vrldme
ub Coloone
ulp Stock
urelube Motor 011s
uritan Motor 011
ydravls
yrolube
umme Bwlphate

(Dry)

umme Sulphate (Dry)

22
5 z

g
>

F T
ii n
- ii- n Yi
z- - - 0- -

n -

A
-

kd

32gz

is 0
ij- T
ii- a
- -

Ll

zi L
F ii x

Yi

T A

-r

iF
- A
- -

n
- A- - - - i -- - - i- A

ii_

n
ii4
-

Ir
- -K - - i - 1
ii
i - h
-. - - -

A
-

A
A
-

A
i-

n
c
A
-

A
A

It

z n
n -

1
/
/

T A
A
- -

7
- A
- n
A n
ii A
z
- -

1
,

1
I

ir
- - - a
- - - - -

- - - u

_-

b
_
_

4
i-

i
r
r-

iK
A
-

n
iizin
ii0
-

iiI
I
I
/

ii-

ii4
iii
i-

i=

G
-

j_
-

A-

n n

Yi Fi
ii- n
- -

A
-

n
-

i-

a
- r- -a
- - -

ii-

I
i
I
I
i

A
- A
- -

4
1 K 4 K b
1 n
- 4- A- 4
i - - - ii- - 4
- - - - - - - - - - - - - i
- - - r ii- u
i - - - r- - - i4
- - - 1ii - - - i i- i - a
- i
- i
- r- 1 - - - \- L

I
,

n
n ic iin
- -N n
- - -

- 4
- h
- s

ir n
-

I
I

/
i
/
i

1
-

E 2 Y %
* B
z
G
z

2
-

c-

9
L

z n
-

A ii- Ti

n
n
- - - - 0 7 - i- 7
i
0
- - - - n
0 7 ii n A
0
- -A
- _
_
A - - -

zz
; E

Ji
ii A

n
-

- NON-METALLIC
- -

fl

(continued)

c
B

otassium Cvamde

otasswm Hydroxtde (5%)

?I
- s

;
y?
8

NAME OF LIQUIO

olasswm Ferrlcyamde

MATERIALS-OBERDORFER
-I

otaswm

PUMP

L
,L

4
E

LA
\A

-I

I
+

(continued)

876

Corrosion Resistant Materials Handbook

TABLE 7.8:

METAL,

ELASTOMER

AND

PLASTIC

PUMP

MATERIALS-OBERDORFER
1

METALS

COOE LETTERS

(continued)
NON-ME

ELASTOMERS

il

l-

A
Acceptable
0
Oueshonable
N
Not Recommended
BLANK-No lnformatlon

x
4

25

Subject to plttmy when allowed to dry


Subject to attack when hydrochloric acid IS present

Y
Y
%
%

NAME OF LIIJJIO

It
A

?apeseed Oil
Red Gage 011

ii-

Resm Solvent

ii
ii
-

Rose 011
Rosm
Rum

Rust lnhlbltors

ix
-

Salad Oressmg

0
T
-

Sal Ammomac
Salt Brme (Sat

Salt Cake

Al

Salt Solutlon

Salt Water

jamhzers

*A

Sea Water
Sesame Seed 011

I
A

Sewaoe

Shave Cream
Shell Alvama Grease No 2

3hcate Esters
3lhcone X527
3hcone Tettachlorlde
SIllcone 011s
3dver Bromide
3lver Chloride
Sdver Cyamde
Sdver Ndrale

Skellv Solvent 6. C. E
500

8 7KYl

soap Soluttions
jocony ALHO No 1
joconv 60195
jocony Auto. Transmtssion Flwd
jocony Delvac
jocony M-4731-A
jocony Mobil Type A
jocony XRP 226A
jocony XPP 227A
jocony RL-362A Shock

Cold

T
T

n
-

Filrmg Starch

3lver Salts

Sdica Gel

+A

T
-ii
T

Shell Tellus No 27

jkvdrol

41

T
_-

n
T
T
-

0
ii
0
0
0
ii
0

a
0
ii

5
::

El

z
if B

4 iz
E2

s5

2 E E
I

h
-

- - - - ii- a ii - i sii;
- - a
- - - - - - 1
i n
i

4
i
i
i-

i
i
i
i
-

ir
-

i A
i-i
- i
i
4
i
s
4
i
4
-

n
-

iii
-

A
-

i
-

4
-

A
-

4
-

ri-

-n h- - - - - - - /

z
n
n
A
Ii-

K
-

(continued)

Comparative Resistances of Materials of Construction

TABLE 7.8:

METAL,

ELASTOMER

AND PLASTIC PUMP MATERIALS-OBERDORFER

877

(continued)

NAMEOFLIIJUIO

(continued)

878

Corrosion

TABLE 7.8:

Resistant

METAL,

Materials

ELASTOMER

Handbook

AND PLASTIC PUMP MATERIALS-OBERDORFER

(continued)

Acceptable
a
Ouesbonable
N
Not Recommended
BLANK-No informalloo
A

NAMEOFLIIJUIO

Sulphur (Wet)
Sulphur Oloxlde (Dry)
Sulphonaled Fatty Alcohols

A
A

A A/O

A
N
A

II

(continued)

Comparative

TABLE

7.8:

METAL,

ELASTOMER

AND

PLASTIC

PUMP

Resistances of Materials

MATERIALS-OBERDORFER

Acceptable

0
N

Questranable

(continued)

ELASTOMERS
-

METALS

CODE LETTERS

879

of Construction

NON-METALLIC

Not Recommended
BLANK-No
Informalron
Subtect
Subject

to prttmg
to attack

when
when

allowed
to dry
hydrochlorrc
acid

IS present

E
NAME OF Ll(Wl
iulohonated

Veoetable

iulohurrc

011s

iunoco

SAE 10

;unoco

No 3661

~unoco All Puroose


#per Shell
,yrrthehc

Cold

Grease

s- 3
n
-

Gas

Detergent

n
n
-

I-

all 011

T
T
A

allow
annm
annmg

Lrquors

annmg

011

ectyl

r-

T
+
+ _ *
/
-

ar

502

eeool

eresso

011 No 47

ertrary

Butyl

Alcohol

erharv

Butvl

Catechol

ertrary

Eutyl

Mercaptan

Trtanate

etrachloroethane
etraethyl

Lead

etrahvdroturan

I
I
i
I
i

A
A
0

I
/

$
A

,
t

/
,
/

E
/!
E
P

h
- - -

Capella

6 8 0

exaco

Regal A&B

exaco

3450 Gear 011

ntonyl

(RO) Startak

No 2

A
-

Chlorrde

ide Water

011 Eteedol Mulh.

Gear 140

in Salts
rtamum

Tetrachlorrde

i- -

P
P

oluene

Ortsocvamde

IF-

n
-

b
-

z 9 25
- - - - - - - - - - - - - - - - - - -

1
-

r*

_
-

z
- *
A

11
-

i-

a
A

1
t

A
A

A
-

oluene

exaco

etra Bromethane
etra Rutvl

1
s
A

n
-

ale Slurry

2
-

Anhvdrrde

2
1
L

c
(

(A

II

II

&
I

IA,

(continued)

880

Corrosion

Resistant

TABLE 7.8: METAL,

Materials

ELASTOMER

Handbook

AND PLASTIC PUMP MATERIALS-OBERDORFER

(continued)

NAMEOFLIQIJIO

Vershbe F-50

Vfnegar

I
1

cold

~~~o~o~o[A[AIA~o~~INI
I

IllI

III

Ii

I
I

IAIAIAIAIAIAI
III
III

(continued)

Comparative

TABLE

7.8:

METAL,

ELASTOMER

AND

PLASTIC

CODE LEllERS

PUMP

lttrlol Oil

Vater lo 180F - lap

Vater. Bodmg

T
ii G
7 i-

Vater Boder

?+

vatnr lllsllllsd

Vater. Mme

A
-_-

Cold

Vater, Salt

Cold

Vater Sea

Cold

A
A
A/O

Vater wth Soluable 011

Veed Killers

Vemco C
Vhlskey 8 Wmes
Vhlte Gas
0

Vhde Lmuor

:ylene

A
A

A
A

yhdenes - Mixed Aromahc Ammes


A

.yl0l

A
A

eohte
0

mc Acetate

mc Ammomum Chloride
mc Chloride

Cold

mc Chloride

Bollmg

mc Cyamde
N

mc Hydrosulflle

mc Nltrate

n
ij-

n
-

T
- A
- n
G
;i-

A
n
is
r-

z
I

Eh
5

n-

A
- r-h/O
- - r-- -

53

ir 7
ii- n
A
- -

n
ii-

a
4

s
i4
i-

b
1
-

i-

mc Salts
0

iiiii
-

\_
_

n
-

n
n

h
i-

t/I 1 A

i- N
-

%
i

_
-

NON-METALLIC

mc Phosphate Solubon
mc Sulphate (25%)

t5 Y
5
E 2ik
1 z

lmvlideoe Chloride

mc Sulphale (Saturated)

(continued)

NAME OF UOUIO

881

of Construction

ELASTOMERS
-

METALS

Sublect to plttmg when allowed to dry


Sublect to attack when hydrochlor!c acid IS present

Vater - Oelomred

of Materials

MATERIALS-OBERDORFER

A
Acceptable
0
Ouesbonable
N
Not Recommended
BLANK-No lniormatlon

Resistances

i-

$ sA

L
-

n
I

-L-

1
-

3
-

i
-A

i-

r
-

/4

n-

E
-

,4

(I

-s

(I

a-

$
4

4-

882

Corrosion

TABLE 7.9:

Resistant

Materials

Handbook

GLASS, METAL AND PLASTIC PIPING SYSTEMS-0-I,BCHOTT

PROCESS SYSTEMS

Chemical Resistance of Corrosion-Resistant Piping Systems


Ylaximum Opwatin~ Tampentura
MATERIALS

MATERIALS

A-Very
Good Service
8-Moderale
Service
C-Limoted
0, Varlablc
F-lJnsat,slaclo,y
Blank-No
lnlormal~on

4-Very
Good Service
B-Moderate
Scrvlce
Z-Limited
o, Variable
F-Unsatisfactory
Blank-No
Information

Service

To
2,
P

Service

:HLMICALS

CHEMICALS
Salads assumed

hlids

an solu11on.

assumed

ip
in solution.

5
F
C

ACETIC ACID. 100%. CHI COOH


ACETIC ACID. Dilute 50%
ACETIC ANHYDRIDE, (CHJ CO)?0
ACETONE, CHJ COCHI
ACETYL CHLORIDE. CHJ COCI
ALUMINUM CHLORIDE, AlCh
ALUMINUM HYDROXIDE. Al (OH)3
ALUMINUM SULFATE. Al? (SO,),

C
A

4
A

It
tA

Data represented
IS to be used as a
wade only. For spechc mtormat~cn.
test
rnde, actual operatang conddvans.

CHLORINE (Dry), Cl?


CHLORINE (Wet). Cl?
CHLOROBENZENE. Cs l-lb Cl
CHLOROFORM, CHCIJ

ABBA
A C f
ABBA
A B.F

CHROMIC ACID, Cr 03 soln


COPPER CHLORIDE, Cu Cl?
COPPER CYANIDE, Cu(CN)z
COPPER NITRATE Cu (NO&

A B F
A F F
ABBA
A A A

A
A
A

COPPER SULFATE Cu SO,


CRESYLIC ACID
DICHLORETHANE. Cq H, Clr
DIETHYLAMINE,
(&-ii,);
NH

AMMONIUM
AMMONIUM
AMMONIUM
AMMONIUM

CARBONATE, (NH,)? CO1


CHLORIDE. NH, Cl
HYDROXIDE. NH, OH
NITRATE. NH, NO3

A
A
A
A

A
A
A
A

A
A
A
P

DIPHENYL. CrH&Hh
ETHERS, Various
ETHYL ACETATE. C-_HI_COOCHz
ETHYL ALCOHOL, CvHbOH

AMMONIUM
AMMONIUM
AMMONIUM
AMMONIUM

PERSULFATE,
PHOSPHATE,
PHOSPHATE,
PHOSPHATE,

A
A A A
A I A IA

A
A

z
A

ETHYL CHLORIDE, CI Hj Cl
ETHYLENE CHLOROHYDRIN,
Cl (C? H,)OH
ETHYLENE DICHLORIDE, C?H, Cl?

P
P

A
A

A
A

A
A

FERRIC NITRATE, Fe(NO:JI


FERRIC SULFATE, Fe: (SO,),
FERROUS CHLORIDE, Fe Cl:
FERROUS SULFATE, FeSO,

BARIUM SULFIDE, BaS


BENZALDEHYDE. CaHs CHO
BENZENE, Cs Hs
BENZOIC ACID, Cs Hs COOH

A
A
A
L

FLUORINE, Fj
FORMALDEHYDE. CH.>O 37%
FORMIC ACID, HCOOti
FUEL OIL

BORAX, Na&l,Oi
BORIC ACID, HJBOI
BROMINE, Wet, Br?
BUTANOL. C,HUOH

:
P
A

GALLIC ACID, (OH)3 CsHjCOOH


GASOLINE, Refmed
GLYCEROL, CHr OH.CHOH CHi OH
HYDROBROMIC ACID, HBr

AAFA
A A A A
A B B A
A I B I C IA

AMMONIUM
SULFATE. (NH&SO,
AMYL ACETATE, CbH,,COOC&
AMYL ALCOHOL. CSHIIOH
AMYL CHLORIDE. CsHilCl
ANTIMONY TRICHLORIDE, SbCh
ARSENIC ACID, HAS 03
BARIUM CARBONATE, BaCOx
BARIUM HYDROXIDE, Ba(OH)l

BUTYL ACETATE. C.H&OOCHz


BUTYRIC ACID, CJ H7 COOH
CALCIUM BISULFATE. CaHSO,
CALCIUM BISULFITE. Ca HSOs
CALCIUM
CALCIUM
CALCIUM
CALCIUM

CARBONATE, CaCO.1
CHLORATE. CaClOr
CHLORIDE, CaCI,!
HYDROXIDE. Ca (OH):!

CALCIUM HYPOCHLORITE, Ca (OCI)?


CALCIUM SULFATE, Ca SO,
CARBON DIOXIDE (Dry), CO?
CARBON

DIOXIDE

(Wet

or

H,

COJ)

CARBON DISULFIOE. CS:!


CARBON TETRACHLORIDE (hlolst)
CHLORACETIC ACID, CICHzCOzH
CHLORIC ACID, HCLOJ
KIMAX-

II the reglrtared

trade

mark

of

Owens-llllnolr,

Inc.

IAIAIBIA

ETHYLENE GLYCOL. CH, OHCH:! OH


ETHYLENE OXIDE, CH$ OCH:
FATTY ACIDS, Various
FERRIC CHLORIDE, F&l:,

;:
A
A

HYDROCYANIC ACID (011. and Gas)


HYDROFLUORIC ACID, (Cow.). HF
HYDROFLUORIC ACID, (Dilute)
HYDROFLUOSILICIC
ACID, H.ISIF~

:
A
A

Ccl.

A
A

I AABA
I I I

:
A
A

lAlA\AlA

HYDROCHLORIC ACID, (Cont.). HCI


HYDROCHLORIC ACID, (Dtilute)
HYDROCHLORIC (Dry Gas)
HYDROCYANIC ACID, (Cont.), HCN

B
r,
#-

.;LR

A
A

A
A

mf
5

-I%
D

A
A

8
A

ALUMS, CONC., AI:(SO,)I - Kt SO,. etc.


ALUMS. DILUTE
AMINES. var,os
AMMONIA (Gas), Moist. NH3

AA
A A

s
.u

A
A

(NH,)? S? 0,
(NH&Hz PO<
(NH&H PO4
(NH,)JPOI

3
&

sg

z:
A
A

$_

z-.,;
z,

z
9
;

Zz=;%

e
*Data
represented
IS to be used as a
guide only. For speclhc ~nlormatlon.
lest
under actual operatang condltoonr.

cd 1
m
ny
;
=
g-
22
d
m:u

HYDROGEN PERbXlDE

(Cont.),

H, Oz

(continued)

Comparative

TABLE 7.9:

Resistances

of Materials

GLASS, METAL AND PLASTIC PIPING SYSTEMS-0-I/SCHOTT

883

of Construction

PROCESS SYSTEMS (contd)

Maximum Operating Temperaturs


MATCRIALS
A-Very
Good Service
B-Moderale
Service
C-Ltmlled
or Varaable
F--U~S~llSl~ClO~y
Blank-No
lnlormal~on

B-Moderale
C-L~mlted

Servxe

CHEMICALS
Soltds assumed

Service
or Variable

F-Unsatislactory
Blank-No
lnlorn

Service

tion

CHEMICALS

Solids assumed in solution.

in solubon

*Data represented
15 to be used as a
gutide only. For specli~c Inlormabon.
test
under actual operatmg cod,t,ons.

*Data represented
is to be used as a
guide only. For SPSCI~IC mformabon.
test
under actual operating condibons.

IODOFORM. CHIJ
KEROSENE
KETONES, Various
LACTIC ACID, CHJ CHOHCOOH

zp 2 5 !z
2% =a 25:
clo,%:E

POTASSIUM SULFIDE. Kz S
PYROGALLOL. Cc Hs (OH)3
SILVER NITRATE. Ag NOa
SODIUM. Molten 210-4OOF.

A A A
ABBAE
A A 0
AAACf

1
4
4
4

LEAD ACETATE. Pb(CHa COO)2


MAGNESIUM CHLORIDE, Mg Cl;!
MAGNESIUM HYDROXIDE, Mg (OH)?
MAGNESIUM SULFATE, Mg SO,

: A

MALEIC ACID, CO! H C? Hz CO2 H


MALIC ACID, CO? H CHr CHOH CO2 H
MERCURIC CHLORIDE, Hg, Cl%
MERCURY, Hg

Ii
:: AA

A
A
A
A
WDIUM SULFIDE. Na&
SODIUM SULFITE: Na;SO,
STANNIC CHLORIDE. Sn Cl,
STANNOUS CHLORIDE. Sn Cl.

PERCHLORIC ACID
PHENOL (Cont.) Cs
PHOSPHORIC ACID
PHOSPHORIC ACID

STEARIC ACID. CH, (CHz),( COOH

70%
H5 OH
(100%). HJPO,
(>45% Hot)

IFI

:
i
\

Cold)
Cold)

zEE~~o:pI;2;~
SULFURIC ACID (Fuming to 98%)

liji

A
A

::
A
A
::
A
-

POTASSIUM BROMIDE, KBr


POTASSIUM CARBONATE, K* CO3
POTASSIUM CHLORATE, KCIOJ
POTASSIUM CHLORIDE. KCI

::
2

~z&i,?L~Iji

CYANIDE, KCN
DICHROMATE. K2 Crt 0,
FERROCYANIDE.

TRICHLORETHYLENSE. Dry, Cl2. C. CHCI t

mark

0, Owens-llllno~r,

A
A
A
A

HYDROXIDE, KOH
NITRATE, KNOJ
PERMANGANATE. KMnO,
SULFATE, Kz SO,
trade

A
A
A
A

A
-

PHOSPHORIC ANHYDRIDE,
Molten, PzOs
PHTHALIC ANHYDRIDE. Cs H, (CO)2 0
PICRIC ACID, Soln.. HO.& Hf (NO&

registered

A
A
A

NITROBENZENE. Ca N$ ~0~
NITROUS ACID, HNO!
OLEIC ACID, CI Hi7 CH:CH(CH2),C02H
OXALIC ACID, CO2 H CO2 H

POTASSIUM
POTASSIUM
POTASSIUM
POTASSIUM
m
KIMAXIs tha

P
::
P

NITRATING ACID (<15% HN03)


NITRATING ACID i<l% Acld1
NITRIC ACID, Conk. HriOa
NITRIC ACID, Dilute

POTASSIUM
POTASSIUM
POTASSIUM
K,Fe(CN)s

F
A

NICKEL CHLORIDE. Ni Cln


NICKEL SULFATE, Ni SOI
NITRATING ACID (>15% HnSOd)
NITRATING ACID (<15qr, Hz SO,)

PHOSPHORIC ACID (>45%


PHOSPHORIC ACID (<45%
PHOSPHORIC ANHYDRIDE,
Dry or Moist

/
E

I A

METHANOL, Cow., CHIOH


METHANOL [Dilute\
METHYL CHLORIDE, CH3 Cl
NAPHTHA, Petroleum

A
A

Inc.

Corrosion

884

TABLE

7.10:

Resistant

NATURAL

Materials

AND

Handbook

SYNTHETIC

FIBERS,

POROUS

STONE

OR POROUS

CARBON

FILTER

TUBE

MATERIALS-SETHCO
Sethco filter
tubes are fabricated
of natural or synthetic
fiber wound
over a perforated
plastic or metal core. The
precision winding
pattern
covers the entire depth of the filter tube with hundreds
of funnel shaped tunnels which
become gradually
finer from the outer surface to the center of the tube and trap progressively
finer particles as the
fluid travels to the center. This allows much greater solids retention
capacity
than is associated with surface filter
media of the same dimensions.
Types of Filter Tubes and Supporting
Cores:
Cotton,
Dynel, polypropylene,
acetate, porous stone or porous carbon
filter tubes are available.
Supporting
perforated
cores for cotton,
Dyne1 or polypropylene
are stainless steel, polypropylene
or steel. Supporting
cores for acetate tubes are tin plated copper with voile liner. Porous stone and porous
carbon
filter tubes do not require supporting
cores. Stainless steel cores are recommended
for mildly
acid and all
alkaline
solutions,
pH 4 to 14. Polypropylene
cores are used where all metal contact
must be eliminated
or where
stainless steel is attacked,
such as high chloride
and sulfuric
acid solutions.
It is recommended
for all acid and alkaline solutions,
pH 0 to 14. Two types of polypropylene
cores are available:
mesh polypropylene
and rigid perforated
polypropylene.
The mesh type of polypropylene
is satisfactory
for temperatures
below 140F. The more expensive
rigid polypropylene
cores are used for temperature
applications
over 140F, and for double
and triple tiered filter
chambers because their greater strength
is needed here. Perforated
steel cores are used for dilute alkaline solutions,
solvents, lacquers, oils, emulsions,
etc.
Filter Tube Selection:
Cotton
filter tubes are recommended
for moderately
acid and alkaline solutions
in the pH
range of 3 to 11. Polypropylene,
Dyne1 and porous carbon filter tubes are recommended
for concentrated
acid and
alkaline
solutions
and for all fluoborate
solutions
over the entire pH range of 0 to 14. Polypropylene
filter tubes are
also recommended
for electropolishing
solutions,
as well as certain other highly corrosive
solutions.
Porous stone
filter
tubes are recommended
for concentrated
acid solutions.
Acetate
filter tubes are recommended
for water.
Sethco filter tubes are available in densities to filter out particles from 150 down to 1 micron.

FILTER
ACID TYPE
,ROBORITES,
ACID TYPE
,NOT ~LUOBORATES,

Copper.Iron,Lead,

Tin

Copper, Tin and Zinc-Less


than 6 m/gal
sulfuric
Copper, Tin and Zinc-Over
6 w/gal
sulfuric acid
Chromium
Gold. Indium. Rhodum,
Palladium
Iron Chloride (190F)
Nickel (Woods)
Nickel (Wattts type & Bright)
Nickel (Hi-chloride)
Nrckel Sulfamate
Electrotype Copper and
Nickel

ALKALINE

TYPE

ALKALINE
CYANIDE TYPE

ELECTROLESS

Yatrriaf/Cor*

ACIDS

Poilypropylene
or
Cotton/PP
Polypropylene/PP
or Oynel/PP
Polyprapylene/PPor
OynellPP
Polypropylene/PP
or Ovnel/PP
Polypropyl&re/Rigid
PP or
Porous Stone
PolypropylenejPP
or Dynel/PP
Polypropylene/PP
or Cotton/PP
Polypropylene/PP
or Cotton/PP
Polypropyfene/PP
or Cotton/PP
Polypropylene/PP
or Cotton/PP

Tm (stannate)

Cotton/SS

Brass*, Cadmum,
Copper. Zmc
Gold, Indium. Platinum.

Cotton / SS. PolypropylenelPP


or DyneljPP
cotton/ss
or
Polypropylene/PP

Silver

PYROPHOSPHATE

TUBE

Polypropylene/PP
or Dynel/PP

TYPE

Copper, Iron, Tin, etc.

c0tt00fss or Cotton/PP

TYPE

t&eke1 Plating, Solutions


Below 140F:

Polypropylene/PP
Cotton/SS or Cotton/PP

Above 140F:
Copper
Below 140 F:
Above 140F:

Polypropylene/RPP
cotton/ss

FILTER

Acetic-Dilute

Cotton/SS
or
Polypropylene/PP
PolypropylenelPP
or Oynel/PP
Cotton/SS
or
PolypropylenefPP
PolypropylenelPP,
DynelIPP
or Porous Stonet

Acetic-Concentrated
Boric Acid
Chromic Acid, Hydrochloric,
Nitrrc, Phosphoric, and
Sulfuric
Hydrofluoric. Fluoboric Acids

ALKALIES

Sodium or Potassium
Hydroxide
Ammonium
HydroxideDilute
Ammonium
HydroxideConcentrated

CHEMICALS. MISC

Pharmaceutical
Photographic

solutions
solutions

Radioactive solutions
Ultrasonic cleaning solutions
Nickel Acetate
Food Products

190F

or
OR6ANlC

LIQUIDS

Polypropylene/PP
Polypropylene/
RPP

PETROLEUM

*When
ttorous

CHEMICALS

operated
as hi-speed
baths at high temperatures
(above
Stone is recommended
for all acids except
hydrofluoric

14OF)
or with
and fluoboric.

PRODUCTS

high

Carbon Tetrachloride
Oichlorethylene
Hydraulic Fluids
Lacquers
Perchlorethylene
or
Trich!orethylene
Solvents
Fuel Oil, Diesel. Kerosene.
Gasoline, Lube Oil

alkali

content,

TUBE

M~teri~f/Cor~

PolypropylenelPP

or OynellPP

Polypropylene/PP
CottanlSS
or
Palypropylene/PP
Polypropylene/
PP or
Oynel/PP

c0n0n/ss, PolypropylenelPP
or Porous Slonet
Porous Stone or
PolypropyleneiPP
cottan/ss, Polypropylene/PP
or Porous Stonet
CottonlSS
or
Polypropylene/PP
Cotton/SS
or Porous Stonet
Cotton Special B
Compound/SV
Cotton/SS
Cotton / SS or
Polypropylene / PP
Cotton/Steel or SS
CottonjSteel
Cotton/Steel
Cotton/Steel
Cotton/Steel

or
or
or
or

Cotton/Steel

or SS

Cotton/

SS
SS
SS
SS

Steel or SS

use PolVProPVlene/PPor

DVnel/PP.

Comparative

TABLE 7.11:

RESIN, STEEL, ALLOY, TITANIUM,


PUMP AND FILTRATION

Resistances

of Materials

CERAMIC, RUBBER, NATURAL


SYSTEM MATERIALS-SETHCO

of Construction

885

AND SYNTHETIC

FIBER

Plating Solutions

PLATING
SOLUTION
ANTIMONY
ARSENIC
BRASS

Reqular Brass Bath


Hrah Speed Brass Bath

TEMP.
130F
1loF

I4

0-D

14

A,

1001 F
110F

B-D

A,

AL

RT
160F
100F

B-D /

Pi

II3

P,

AL

PI

B-D I

P4

PL

90F
100F

B-E ,

/4

P,

B -11

c4

I4

130F
95F
130F
115F
95F

A-

EI

I4

A.

bi

I4

A-

EI

I4

A.

P,

Ef

I4

A.

-D

/4

I4

AT
12oF

I1

I4

B -I3

/4

I4

120F
150F
180F

A,

B-C)

I4

I4

P,

I\

I4

PL

I4

I4

BRONZE
Copper-Cad. Bronze Bath
Copper-Tin Bronze Bath
CopperZn. Bronze Bath
CADMIUM
CYamde Bath
Fluobonte
Bath
CHROMIUM
Chromic-Sulfuric
Bath
Fluosilicate Bath
Fluonde Bath
Black Chrome Bath
Barrel Chrome Bath
COPPER fACIO1
Copper Sulfate Bath
Copper Fluoborate Bath
COPPER ICYANIDE
Copper Strike Bath
Rochelle Salt Bath
Hugh Speed Bath
COPPER fMISC.1
Copper Pvrophosphate
Copper fElectroless1
GOLD
Cyanrde
Neutral
Acid
INOIUMSULFAMATE
IRON
Ferrous Chloride Bath
Ferrous Sulfate Bath
Ferrous Am.Sulfate Bath
Sulfate-Chloride
Bath
Fluoborate Bath
Sulfamate
LEA0 FLUOBORATE
NICKEL
Watts TYpe
Hugh Chloride
Fluoborate
Sullamate
Electroless
RHOOIUM
SILVER
TIN-FLUOBORATE

TIN-LEAD
ZINC
Aod Chloride
Acrd Sulfate Bath
Acid Fluoborate Bath
Alkaline Cyanide Bath

A
A

140F
140F

PL

PL

14

Ii

I4

,&

IE

150F
75F
75F
RT

P,

P6

f3

c)

P,

c)

/1
4

8I

P,

IE

190F
150F
150F
160F
145F
140F

IE

I2I

eI

I3

eI

EI

C1

EI

EI- D

EI

i4

EI

<

EI- D

r-E

C1

/4

PL

r-E

t1

EI

C)

r-E

EI

E3. D

C1

E3

I\

P,

PL

P,

/1

f3

/1

P/

f3

PL

I4

I4

PL

P,

f3

f3..D

PL

f3

f3..D

PL

PL

f3

P,

I4

P/

f3

PL

f3

C)

f3

f3..D

PL

,4

I4 I A

PL

115.16OF
130.160F
100.17BF
100.140F
200F
120F
BO-120F

100F
1OoF
140F
150F
RT
RT

SYMBOL
A - Excellent
f3 - Good
C - Good to 80F

D E -

IDENTIFICATION

Moderate

F - Autocatalytic

effect

(use

under

limited

Not

recommended

conditions)

X -

Unknown

(continued)

886

Corrosion

TABLE 7.11:

Resistant

Materials

Handbook

RESIN, STEEL, ALLOY, TITANIUM,


CERAMIC, RUBBER, NATURAL AND SYNTHETIC
PUMP AND FILTRATION
SYSTEM MATERIALS-SETHCO
(continued)

FIBER

Industrial Chemicals

CHEMICAL
ACETALDEHYDE
ACETIC ACID, 20%
ACETIC ACID. 80%
ACETIC ACID; GLACIAL
ACETIC ANHYDRIDE
ACETONE
ALUMINUM
CHLORIDE
ALUMINUM
FLUORIDE
ALUMINUM
SULFATE
AMMONIA,
10%
AMMONIUM
CHLOAIOE
AMMONIUM
NITRATE
AMMONIUM
PERSULFATE
AMMONIUM
PHOSPHATE
AMMONIUM
SULFATE
AMYL ACETATE
AMYL ALCOHOL
AMYL CHLORIDE
ANILINE
AClUA REGIA
ARSENIC ACID
BARIUM CHLORIDE
BARIUM SULFATE
BEER
BENZALDEHYOE
BENZENE
03ENZOLl
BENZOIC ACID
BORAX (SODIUM BORATE)
BORIC ACID
BROMINE WATER
BUTY L ACETATE
EUTY RIC ACIO
CALCIUM
BISULFITE
CALCIUM
CHLORIDE
CALCIUM
HYPOCHLORITE
CALCIUM SULFATE
CARBON TETRACHLORIOE
CARBONIC
ACID
CHLOROACETIC
ACID
CHLORINE
WATER
CHLOROBENZENE
CHLOROFORM
CHLOROSULFONIC
AC10
CHROMIC ACID. 10%
CHROMIC ACID. 30%
CHROMIC
ACID, 50%
CITRIC ACID
COPPER CHLORIDE
COPPER CYANIDE
COPPER NITRATE
COPPER SULFATE
CRESYLIC
AC10
ETHYL ACETATE
ETHYL CHLORIOE
ETHYLENE
GLYCOL
FATTY ACIDS
FERRIC CHLORIDE

EI

)I

>

E3

El

C1

L\

CI

EL

Ei

/1

fi

<

.D

[1

I1

>

I4

I4

I\

I\

I4

I4

[1

I4

I(

I4

I\

I1

I\

I4

I4

I4

I\

I4

I4

I3

t3

I4

I\

I1

III

t3

I4

,4

I(

)<

I:

l3

I:

I3

.E

I1

I(

<

I(

I3

,4

IE

ID

IE

IE

IE

IB

IB

Cl

0,

A-l

A-l

A\

A-l

Pi

C1

P,

I3

El

-t

P,

P,

SYMBOL
A -

Excellent

I3 -

Good

C -

Good

D -

IDENTIFICATION

Moderate
(use under

to 80F

E -

Not

effect
limited

conditions)

F -

Autocatalytic

X -

Unknown

recommended
(continued)

Comparative

TABLE 7.11:

RESIN, STEEL, ALLOY,

TITANIUM,

PUMP AND FILTRATION

CERAMIC,

Resistances

of Materials

RUBBER, NATURAL

SYSTEM MATERIALS-SETHCO

887

of Construction

AND SYNTHETIC

FIBER

(continued)

CHEMICAL
FERRIC NITRATE
FERRIC SULFATE
FERROUS CHLORIDE
FERROUS SULFATE
FLUOBORIC
ACID
FLUOSILICIC
ACID
FORMALOEHYOE.40%
FORMIC ACID

FREON 12 (WET)
FUEL OILS
FURFURAL
GASOLINE
GLYCERINE
(GLYCEROL)
HEPTANE
HEXANE
HYOROBROMIC
ACID, 20%
HYDROCHLORIC
ACID, 0.25%
HYOROCHLORIC
ACID. 25.37%
HYOROCYANIC
ACIO
HYOROFLUORIC
ACIO. 10%
HYOROFLUORIC
ACID. 30%
HYOROFLUORIC
ACID. 60%
HYOROFLUOSlLlClC
ACID, 20%
HYDROGEN
PEROXIDE.
30%
HYDROGEN
PEROXIOE,50%
HYDROGEN
PEROXIOE.SO%
HYDROGEN
SULFIOE.AO.SOL.
IODINE (IN ALCOHOL)
KEROSENE
KETONES
LACOUER
THINNERS
LACTIC ACID
LEADACETATE
LUBRICATING
OIL
MAGNESIUM
CHLORIOE
MAGNESIUM
NITRATE
MAGNESIUM
SULFATE
MALEIC ACID
METHYL
ALCOHOL
METHYL
CHLORIDE
METHYL
ETHYL KETONE
METHYL
ISOBUTYL
KETONE
METHYLENE
CHLORIDE
NAPHTHA
NAPHTHALENE
NICKEL CHLORIOE
NICKEL SULFATE
NITRIC ACIO. 10%
NITRIC ACIO. 20%
NITRIC ACIO; 50%
NITRIC ACIO. ANHYOROUS
NITRO BENZENE
OILS AND FATS
OLEIC ACIO
OLEUM, 25%
OXALIC ACID
PHENOL

I(

c
c

<

>

>

I\

1-c

:.c

I(

C
C

1.

II

El

I3

Cl

SYMBOL
A -

Excellent

B -

Good

C -

Good

to 8OF

D E -

4
4

IDENTIFICATION

Moderate

effect

(use

under

limited

Not

recommended

conditions)

F -

Autocatalytic

X -

Unknown
(continued)

888

TABLE

Corrosion

7.11:

Resistant

Materials

Handbook

RESIN, STEEL, ALLOY, TITANIUM,


CERAMIC, RUBBER, NATURAL AND SYNTHETIC
PUMP AND FILTRATION
SYSTEM MATERIALS-SETHCO
(continued)

FIBER

CHEMICAL
PHOSPHORIC ACID. II?1096
PHOSPHORIC ACID, 50-100x
POTASSIUM BICARBONATE
POTASSIUM BROMIDE
POTASSIUM CARBONATE
POTASSIUM CHLORATE
POTASSIUM CHLORIDE
POTASSIUM CYANIDE
POTASSIUM OICHROMATE
POTASSIUM HYOROXIOE
POTASSIUM NITRATE
POTASSIUM PERMANGANATE
POTASSIUM SULFATE
PROPYL ALCOHOL
SOAPS
SOOIUM ACETATE
SODIUM BICARBONATE
SOOIUM BISULFATE
SODIUM BISULFITE
SODIUM CARBONATE
SODIUM CHLORATE
SODIUM CHLORIDE
SODIUM CYANIDE
SODIUM HYOROXIOE,ZO)(
SODIUM HYDROXIDE. 9%
SODIUM HYPOCHLORITE
SODIUM NITRATE
SODIUM SILICATE
SODIUM SULFATE
SODIUM SULFIOE
STANNIC CHLORIDE
STEARIC ACID
STOOOAROS SOLVENT
SULFURIC ACID, O-1024
SULFURIC ACID. 10.75%
SULFURIC ACIO. 75.100%
TANNIC ACID
TANNING LIOUORS
TARTARIC ACID
TETRAHYOROFURANE
TOLUENE (TOLUOL)
TRICHLOROETHYLENE
TRICRESYLPHOSPHATE
TURPENTINE
UREA
VINEGAR
WHITE LIGUOR (ACID)
XYLENE (XYLOL)
ZINC CHLORIDE
ZINC SULFATE

eI

EI

.E

.E

t-C

I(.

<

<

<

I(

I(

C
A

L\

I\

D,

a
i
a
a

f3

PI

r\

L\

P,

P,

,-I

.L

>

SYMBOL
A - Excellent
B - Good
C - Good to 80F

IDENTIFICATION

D - Moderate
effect
(use under limited
E - Not recommended

conditions)

F - Autocatalytic
X - Unknown

Comparative

TABLE

7.12:

PLASTIC

Comparative

AND

STEEL

PUMP

Resistances

of Materials

889

of Construction

MATERIALS-THOMPSON-CHEMTROL

Resistance of Thompson

CF Pump Construction

Materials

to Various

Corrosive

Media

CODE
A
B
c
D
E

Excellent
Good
Good to 80 Fahrenheit
Moderate
effect:
May
Not recommended

OPERATING
Polyvinyl
Polyvinyl
Teflon

Dichloride
Dichloride

be

used

under

TEMPERATURE
(CPVC)
(CPVC)

Type 316 Stainless steel


Hastelloy C - 276

(PVDC)
(PVDCI

certain

conditions

LIMITS
225O F (non-pressure)
180 F (oressure)

500
Very

F .
high

Very

high

Type
PVDC

316
SS

Hastelloy
C-276

Type
Tef Ion

PVDC

316
SS

Hastelloy
C-276

Teflon

Acetaldehyde

Borrc Acrd

Acetic Acrd, 20%

Bromrne Water

Acetrc Acrd, 80%

Butyl Acetate

Acetrc Acrd. Glacial

Butyrrc Acrd

Acetrc Anhydrrde

Calcwm Brsulfrde

Acetone

Calcrum Carbonate

Aiumrnum

Chlorrde

Calcwm Chlorrde

Alummum

Fluorrde

Calcwm

Alummum

Hydroxrde

Calcrum Hypochlorrte

Alummum

Sulfate

0,

Calcrum Sulfate

C. D
B

Carbon Brsulfrde

Carbon Tetrachlorrde

Ammoncum Carbonate

Carbonrc Acrd

Ammonrum

Chloride

Chloracetrc Acrd

Ammonrum

Hydroxrde

Chlorine Water

Ammonra

Lrqurd

Ammonrum

BrFluorrde

Hydroxrde

Ammonrum

Nitrate

Chlorobenzene

Ammonrum

Persulfate

Chloroform

Ammonwm

Phosphate

Chlorosulfonrc

Acrd

Ammonwm

Sulfate

Chromrc Acrd

, 1OY0

A. B

Amyl Acetate

Chromrc Acrd. 50%

Crtrrc Acrd

Amy1 Chlorrde

Copper Chlorrde

A. B
A
_

Amy1 Alcohol

Copper Cyanrde

Copper Nrtrate

Copper Sulfate

A
A

Arlrlrlle

Aqua Regra

Arsentc Actd

D. E
A

Barwm Carbonate

Cresylrc Acrd

A
A

A
.-

Barrum Chlortde

Ethyl Acetate

Barwm Hydroxrde

Ethyl Chlortde

Barrum Sulfate

Ethyl Dichlorrde

Barrum Sulfide

Ethylene

Beer

Fatty Acrds

Glycol

Benzaldehyde

Ferric Chloride

Benzene (Benzol)

Ferric Nitrate

B. C
A

Bensocc Acid

Ferric Sulfate

Benzorc Acrd

Ferrous Chlorrde

Ferrous Sulfate

Borax (Sodium Borate)


___~~~

(continued)

890

Corrosion

TABLE 7.12:

Resistant

Materials

Handbook

PLASTIC AND STEEL PUMP MATERIALS-THOMPSON-CHEMTROL

(continued)

Type
PVDC

316
SS

Type
Hastelloy
C-276

Teflon

PVDC

316
SS

Hastelloy
C-276

Teflon

Acid

Oleum

Fluosilicic Acid

Oxalic Acid

Phenol

A. B
A

Formaldehyde

A. B
A

Formic Acid

Phosphoric Acid, O-50%

A. B

Freon 12 (wet)

Phosphoric Acrd, 50-100%

Potassrum Bicarbonate

A. B
A

Fuel Oils
Furfural

A. B

Potassium Bromide

Gasoline

A.

Potassium Carbonate

Potassrum Chlorate

A-

Heptane

Potassium Chloride

Hexane

Potassium Cyanide

A. B
B

Potassrurr, bichromate

Fluoboric

Glycerine

(Glycerol)

Hydrobromrc

Acrd, 20%

Hydrochloric

Acid, O-25%

B. C

A
----B

Hydrochlorrc

Acid, 25.40%

Potassium Nitrate

Hydrocyanrc

Acid

B. C
-

Potassium Permanganate

Potassium Sulfate

A. B
B

Potassium-e

HydroFluorrc

Acrd, 10%

HydroFluorrc

Actd, 30%

Propyl alcohol

A-

HydroFluorrc

Actd, 60%

Soaps

Sodium Acetate

30%

Sodium Bicarbonate

Hydrogen Peroxide, 50%

Sodium Bisulfate

HydroFloursrlrcrc

Acrd

Hydrogen Peroxide,

Sodium BiSulfite

Hydrogen Sulfide, Aq. Sol.

Sodrum Carbonate

Iodine (tin alcohol)

Sodium Chlorate

Kerosene

Sodium Chloride

A
A

Hydrogen PeroxIde,

90%

Ketones

Sodrum Cyanide

A. B
-

Lacquer Thrnners

Sodium Hydroxrde,

20%

A. B

Latic Actd

Sodium Hydroxrde,

50%

A. B

Cead Acetate

Sodium Nitrate

Liquors

Sodrum Srlrcate

A, B
B

Lubrrcants

Sodium Sulfate

Magnesrum Chlorrde

Sodium Sulfide

Magnestum Hydroxide

Stannrc Chlorrde

Magnesrum Nitrate

Stearrc Acrd
Stoddards Sulfuric

Magnesrum Sulfate

Malerc Acrd

Sulfuric Solvent

Mercurrc Chloride

A. B

Sulfurrc Actd, 0.10%

Mercurrc Cyanrde

B. C

Sulfurrc Acrd. 10.75%

Mercury

Sulfurrc Acid, 75.100%

B.C
B

Methyl Alcohol

Tannic Acrd

Methyl Chlorrde

Tanning Liquors

Methyl Ethyl Ketone

Tartarrc Acrd

Methyl lsobutyl

TetrahydroFurane

Toluene

(Toluol)

Trichloroethylene

Trrcresylphosphate

Nrckel Chlorrde

Turoentine

Nrckel Sulfate

Urea

Methylene

Ketone

Chloride

Naphtha
Naphthalene

Nitrrc Acrd, 10%

Vinegar

White Ltquor

Nrtrrc Acrd. 50%

Xylene (Xylol)

Nrtrrc Acrd, anhydrous

B. C
A

Nrtrrc Acid

, 2oY0

Nitro benzene

C. D
A

Oils and Fats

Oleic Acid

znc

Chlorrde

Zinc Sulfate

Comparative Resistances of Materials of Construction

TABLE 7.13:

STEEL, TITANIUM,

ZIRCONIUM, COLUMBIUM AND TANTALUM


COI LS-VULCANIUM

HEATING

891

AND COOLING

Selection of the proper material for your


heating or cooling coil requires that three
factors be considered: 1) the solution; 2)
the desired life of the coil; 3) the coils cost.
To assist you in making the proper
selection, we have developed the following
table.
To use this table, follow these steps:
1. From the column on the left, select the
solution into which the coil will be
placed.
2. Scan to the right and locate the column
with a checkmark (ti)
3. Move up that column to find the
material which Vulcanium recommends
as being best suited for use.

*,ln msnyappl~calions
where

mald steel
tolls gwe adequate serwce. a 304
stainless steel co11wll gwe better
serwce at e modest increase I cost.

SPECIAL NOTE ON MATERIALS:


than those l~sled above. includmg

Vulcanium
can fabrncate coils from msler~als other
Carpenter 20. Haslelloy and Inconel.

Corrosive Material Index

This index relates to the chemicals listed by manufacturers in the main portion of the book. Indexing in a book of
this nature is complicated by the fact that different nomenclature is used by different firms for the same chemical.
For example, most of the tin chemicals are listed under stannic or stannous; however, there are also headings for tin
chemicals and tin salts. As another example, the reader will find information regarding HCI listed under Hydrochloric acid, Muriatic acid and Hydrogen chloride. The user of this Index should utilize as many synonyms and group
designations as possible for the particular substance in which he is interested, in order to obtain as much pertinent
information as possible.
Some of the products listed are registered trademarks; however for purposes of this Index, trademarks have not
been differentiated from generic names. Absence of trademark indication does not exclude the possibility that the
name may be a proprietary name or the subject of proprietary rights.
AN-O-3 - 355
AN-O-6 - 355
AN-O-366 - 355
AN-VV-O-366b - 355
ASTM G-28 Test - 666,734
ASTM oils - 110, 111, 148, 150, 154, 156,267,
274,285,287,288,291,293,296,297,299,
304,307,310,313,316,
318,319,320,
321,
322,323,324,
325,326, 327,328,329,
330,331,332,
333,334, 335, 336,337-354,
356,811,823,839,858,872
ASTM reference fuels - 284,287,288,289,
291,293,304,307,310,316,337-354,
356,811
ATE - 823
ATL-857 - 356
Abietic acid - 157, 610, 657, 787
Abrasive solutions - 367
Absorption oil - 810
Acetal - 156,810
Acetaldehyde - 27,47,60,63,65,69,106,
113,
1.14, 122, 149, 153, 154, 156, 159, 170, 174,
181,226,236.242,247,251,263,273,299,
355,375,379,
389,392, 393,397,398,399,
406,446, 610, 657, 663, 667, 736,749,764,
789,810,822,839,848,854,886,889
Acetaldehyde, fumes - 181
Acetaldehyde mixtures - 446,447
Acetamide - 63, 69,226,251,263,273,
355,
810,822,839,848,854
Acetanilide - 610,657
Acetate solvents - 27, 69, 122, 156,221, 368,
632,773,789,839,854
Acetic acid - 2,4, 6,9, 10, 17, 26, 27, 33, 34,
36, 37,39,41,43,44,45,46,47,52,53,
54,60,61,62,
63, 65, 67,69,95,
102, 104, r
106, 107,108, 109,111, 112,113,114,117,

118, 120, 122, 142, 147, 149, 151, 153, 154,


155, 156, 159, 169, 170, 174, 181,218,221,
225,236,239,240,242,247,
251, 263, 273,
285,291,296,299,303,306,
309,312,314,
355,359,368,369,371,373,374,375,379,
382, 383, 384, 387, 388,389, 392, 393,394,
395, 396, 397, 398, 399,406, 412, 413,416,
424,432,434,448,449,450,610,632,639,
640,642,644,
645,646, 650, 657, 663, 667,
668,669,725,728,731,732,735,736,756,
757,764,773,779,781,787,792,793,797,
801,805,810,822,839,846,848,854,882,
884,886,889,891
Acetic acid-acetic anhydride, boiling - 413
Acetic acid-anhydride - 434, 757
Acetic acid, boiling - 418, 419,420, 423, 424,
425,428,440,444,445,643,
645,647,666,
667,668,669,723,730,736,749,764,779,
78 1,854,
Acetic acid mixtures - 181,450,451,452,453,
454.455,781
Acetic acid mixtures with formic acid - 455,456,
457,458,459,460,461
Acetic acid, vapor - 181,434, 448, 632, 669,735,
757,764,779,839,846,854
Acetic aldehyde (see Acetaldehyde)
Acetic anhydride - 27,39,41,
43,44,45,
46, 47,
54, 60,65,69,
103, 109, 114, 147, 149, 153,
154, 156, 157, 159, 170, 174, 181,218,221,
232,240,247,251,263,299,355,368,375,
379,392,393,397,398,399,406,440,461,
610,632,650,657,669,732,735,749,764,
773,779.781,787,797,801,805,810,822,
839,846,848,854,882,886,889
Acetic anhydride, boiling - 440, 669, 736, 749,
779,854
Acetic anhydride mixtures - 461,462, 736

900

Corrosive

Acetic

anhydride

mixtures

with acetic acid

- 462,

Acid cleaner-31%
Acid crude tar

463

HCI - 109

ester (see Ethyl

acetate)

Acidic

and biochemical

Acetic

ether (see Ethyl

acetate)

Acidic

fumes

- 62, 181

Acid pulping

(ammonia

- 657

Acetoacetic

acid

ester (see Ethyl

- 1, 2, 4, 6, 7, 9, 11, 18, 26, 27, 33, 34,

Acetone

37, 39,46,
103,

104,

52,53,54,

60,63,

106, 109,

111,

297,

65, 69,95,

112, 113,

114,

117,

118, 120, 122,

142, 147, 149,

151,

156, 157,

159,

174, 181, 218,

158,

169, 170,

230,239,247,251,263,273,
293, 296,299,304,

153, 154,

284,285,291,
307,

310,313,315,

355,

368,370,372,373,374,375,379,383,384,
387,

392, 393,

394,

395,397,398,

399,406,

434,

610, 632,

646,

650,

669,

764, 781,

789, 792,

657, 663,

757,

797,801,805,810,822,

839,848,854,882,886,889
Acetone cyanohydrin
- 657
Acetone

cyclohexane,

Acetone

mixtures

Acetone

oil - 399,406

hexane,

- 181

water

218, 232,

241,247,251,273,463,

610,

669,

810,848,854

- 230, 657

Acetophenetidin
Acetophenone
157,

158,

273,355,

- 69, 103,

108, 122,

181,218,230,241,
657,

Acetophenone

142,

156,

247,251,263,

669,789,810,822

with

phenol

- 463

- 726
- 303, 432, 648, 663, 664, 785
Acid soil slurry pH 4 - 61
Aconitic acid - 610, 669
Aconitic acid mixtures - 464
Acridine - 657
Acriflavine
- 122
Acrolein - 610, 657, 789,810
Acrylamide
- 181,822
Acrylic acid - 33, 37, 39, 43, 45, 109, 159, 170,
- 157

Acrylic

anhydride

Acrylic

dispersion:acrylonitrile
dispersion:vinylidene

Acrylic

emulsions

105, 106,

156,

158,

170,

355,

370,

372, 383,

Adipic

263,

carbon

acid

beds

- 399,406

Adipic

acid mixtures

chloride

- 34, 53, 69, 156, 174, 181,218,

Adipol

BCA - 291

399,406,

657,

- 54, 65, 69, 122, 149, 154, 156, 247,


379, 440,

632,

646,

650,657,663,788,810,822,839,854
Acetylene

dichloride

Acetylene

tetrabromide

(see Dichloroethene)
(see Tetrabromo(see Tetrachloro-

- 251

Adrenalin
Adrenalin
Adrogen
Aero

- 736, 764

- 181

lubriplate

Aeronautical

- 355

and automotive

items

- 273, 355, 810


oils and grease - 156,273,

- 13

2300

Aeroshell
Aerosols

Acetyl

dl leucine

Acetyl

dl methionine

Acetyl

nitrite

- 263

Acetyl

oxide

(see Acetic

Acetyl

salicylic

- 251

Aerosol

285, 355,810,

- 610
wetting

Aerospace,
anhydride)

acid (see Aspirin)

agent

50

Agar-agar

- 822

Air (see Atmosphere)

(see Tetrabromo-

tetrachloride

(see Tetrachloroethane)

components

Agricultural

chemicals

Agricultural

lime

Agricultural

spray oil

- 62

- 822
- 156
- 33, 37, 67, 156, 170, 251,

273,355,646,691,731,732,747,748,788

ethane)

chemical

- 729

- 355,781,856

Aerozene

Acetylene

tetrabromide

- 181

missile, rocket

- 657
Acetyl dl tryptophan
- 251
Acetyl dl valine - 251
thiophene

Acetylene

263,

856

ethane)

Acetyl

- 181

chloride

Aero-safe

ethane)
Acetylene Tetrachloride

657,810,

- 736, 764
- 181, 736
hydrochloride
- 142, 230
in oil - 142, 230

Adiponitrile
Adipyl

777,781,797,801,805,822,846,854,882
375,

181, 214,218,
610,

- 27, 53, 69, 149, 154, 181,251,

bromide

355,

174,

355,375,379,610,657,736,787,822,848

(see Acetophenone)

299,

chloride

251,

Acetyl

263, 273,

- 181

- 181
- 62, 114, 122, 181, 210,848
Acrylic spray liner - 181
Acrylic wet ink varnish - 181
Acrylonitrile
(vinyl cyanide) - 27, 39, 47, 54, 69,

Acrylic

Acetyl

Acetylene

285,

396, 432,

Acids, organic

Adhesives - 839

355, 384,

250,

372,

648,735,787,795,854

Activated

263,

371,

822,839,856

- 610, 657
- 285, 355, 657
Acetyl dl alanine - 251

251,

225, 240,

369, 370,

Acid sludge

p-Acetotoluidide

241, 247,

- 181

181, 220,

302, 303,

Acetylacetone

Acetylbenzene

base) - 669

174,181,375,379,383,464,610,669

- 181,463

- 39, 53, 69, 147, 170, 174, 181,

Acetonitrile

Acids - 116, 120,

- 384

environment

Acid rinse, photographic

acetoacetate)

Index

- 156

Acetic

Acetoacetic

Material

plant

- 183,431

907

902

Corrosion Resistant Materials Handbook

Air (contd)

Alkyl

chlorine

containing

coal dust

- 183

Alkyl

heated

- 810,822

humid,

trace sulfur

Alkyletheramine

- 181, 196
- 633, 634, 635, 669, 744,745,

sulfide, methanol - 181


- 633, 634, 635, 636, 637, 638, 744,

745,746
steam - 669
Aircraft

engine parts - 729

Aircraft

hyd. oil AA

Airshow

- 822

- 273,810

- 14, 22

- 29, 56, 106,

226,

240, 273,

368,

632,

625,743,

303,

306,

309, 312,

315,

639, 642,

646,

648,

650, 728, 822,

- 63, 116

- 104, 117
- 116,226,241,303,306,309,312,

phenate
powder

- 182

based

Aliphatic

halogen compounds
solvents

- 646

670, 788, 810,

- 856

cleaning - 891

- 182
Alkaline soak cleaner - 182
Alkaline soil slurry pH 10 - 61
Alkaline solutions - 610, 731
Alkane sulfonic acid - 658
Alkanolamide,
fatty acid - 182
film stripper

Alkanolamide,

- 856
- 611

Almond

- 157

- 658

oil (see Essentials oils)


olefin

Alum

(see Aluminum

Alum,

ammonium

- 182

sulfonate

potassium

Alum,

chrome

Alum,

potassium

(see Chromium

Alum,

sodium

potassium

(see Aluminum

(see Aluminum

sulfate)

potassium
sodium

sulfate)

sulfate)

- 273
- 156, 611, 650
Alumina hydrate - 670
Alum

- 790

Aluminum,

molten

Aluminum

acetate

- 642, 646, 736


- 12, 18, 156, 355, 440, 611,
781,810,822,856

ammonium

sulfate

nonionic

surfactant

- 182

- 273, 355,810,856

anodizing

Aluminum

borate

hot seal tank - 891

Aluminum

brazing flux

Aluminum

bright dip - 891

Aluminum

bromide

- 355, 393, 399,406,810,822,

Aluminum

chlorate

- 658, 749

Aluminum

chloride

(sal ammoniac)

- 611
- 670

108, 109,

113, 114,

118,

122, 142,

154, 156,

170,

174, 182,218,

- 153
- 464
Alkyl amines - 464, 669
Alkyl aryl sulfonates - 658,669,

788,810

387,388,

Alkylate,

vapor) - 669

406,

157, 159,

240,242,247,252,263,273,299,

substituted
sulfonates,
aromatic

151,

152,

221,231,236,
302,

305,

308,311,314,355,370,372,375,379,384,

- 182
- 182, 781
hydrocarbon
- 182
benzene type

linear

- 12, 18, 27, 33,

34, 37, 47, 54, 60, 63, 66, 70, 106,

aldehyde

(liquid,

788,810,

822,857

alcohol

lighter

ammonium)

611,777,

Aluminum

Alkyl

butane,

(Alum,

355,

Alkyl

Alkylation,

ammonium

sulfate)

856

resin - 39

Alkylate,

sulfate)

(see Aluminum

54, 154, 218,252,263,

- 226, 250, 297, 639, 664, 665, 792, 795

Alkylate

251,

carbonate

Alpha

Aluminum

Alkaline

Alkyd

658,

399,

658,670,728,777,

- 368

Alkalies

Alkazene

393,

Aluminum

- 822

- 182

Alkaline

182,218,

379,

Alumina

- 610

form

174,

375,

Ally1 sulfide

Aliphatic
Alka

159, 170,

263,

Ally1 methacrylate

315,432,822

Alipal

156,

119, 124,

285,

aliphatic

Algaroth

154,

(see Food

839,846,848,856

Aldol

- 27, 39, 54, 63, 70, 109, 114, 122,

149,

beer)

- 36, 39, 53, 62, 67, 69, 120, 156, 225,

Algaecide,

acid)

- 157
Ally1 alcohol - 27, 69, 114, 142, 149, 154, 156,

114, 118,

154. 227,228,238,256,266,267,

Aldehvdes

- 610

Ally1 isothiocyanate

788,844,850,876

Alconox

- 670

trifluoride

822,856

beverages (excluding

Alcohols,

- 658

acid

acid (see Fumaric

Allyldiglycol

Air Wick odor neutralizer

Alcohols

- 182

- 182

Ally1 acetate

Ally1 chloride

- 822

Air slaked lime

products)

chloride

225,251,263,610,658,669,848

- 633,634,635,744,745,746

Alcoholic

sulfonic

sodium sulfate

Allomaleic

669

- 464,465

phenol

Alkyl

methyl

urban

Alkyl

Alkylphenol-boron

746
salt air

182, 495,

oxide surfactant

Alkylnaphthalene
746

- 53, 431, 633, 634, 635, 744,745,

marine

acid - 109,

- 42, 153

chloride

Alkyldimethylbenzylammonium

exhaust - 669,682

industrial

- 856

benzene

Alkylbenzenesulfonic

- 691

389,

392,

393,394,

395,

398, 399,

434, 440,

465,

609,

646,

647, 650,

611,

658,670,728,

731,732,736,

740,741,749,

757,

777, 781,788,

797,801,805,

764,773,

810,822,839,846,857,876,882,886,889

Corrosive

Aluminum

chloride,

fluosilicic

Aluminum

chloride,

spent catalyst

Aluminum

chloride

Aluminum

chloride

- 182

acid

308,

311,314,

355,373,

374,375,

379, 382,

384,

388, 389,

392,

393,

394, 395,

mixtures

396, 397,

398,

399, 406,

434,

440,

sludge

611, 632, 647,

650,

736,

764, 773,

chlorohydrate

Aluminum

chlorohydride

- 182

solution

- 465
- 670

- 182
- 70

Aluminum

chlorohydroxide

Aluminum

chrome

- 109,

170, 182,247

- 781

sulfate

- 170, 182

citrate

Aluminum

desmutter

Aluminum

- 182,839
- 658
fluoride - 27, 39, 54, 70, 108, 118,

122,

156,

658, 670,736,

399,407,440,

749,

764,

857,886,889
Aluminum
fluorosulfate

611,

fluosilicate

Aluminum

formate

Aluminum

gel

Aluminum

hardening

Aluminum

hydroxide

- 465, 658, 670

632,

650, 658,735,

384,

bath - 182
- 27, 47, 54, 70, 113, 154,

182,218,252,263,273,
764, 777,

inhibitors

Amine

hydrochlorides

Amine

salt solution

303,

fixing

315, 355,

797,801,805,

432,

466, 467,

810,

839,857,

882

- 658

Aminoazobenzene
Aminobenzene

398,

(see Aniline)

Aminobenzenesulfonic

781, 797, 801,

acid

Aminobutyric

Aminodimethylbenzene

355,

2-Aminoethanol

611, 658, 736,810,822,

857

- 658

acid

- 658
acid - 252

Aminobenzoic
263, 273,

- 670
- 182

312,

736,

- 27, 33, 47, 54, 70, 109, 159,


242, 252,

acid)

- 285, 286

- 42, 43, 70, 120, 226, 240, 285,

organic

306, 309,

236,

388, 389,465,

- 857

- 611

acid (see Sulfamic

corrosion

Amines,

805,810,822,839,846,848,857,882,889
nitrate

tartrate

670, 732,

159, 170,

170, 182, 218,

sulfate chlorohydride

Aluminum

Amine

- 822

156,

Aluminum

Aluminum

Amidosulfonic

632,

777, 781,810,822,

- 658
- 611, 658

Aluminum

788, 797,

Amchem

159, 182,218,252,263,

393,397,

781,

- 67, 114, 122,367,399,406,848,882


- 182
Amerex - 182
American ashes - 822
Amidation
reaction - 764
Amides - 226

- 182

ethylate

152, 154,

777,

466,

732, 735.

Alums

and deoxidizer

etchant

273,355,

749, 757,

465,

658, 670, 725,

801,805,810,822,839,857,882,886,889

Aluminum

Aluminum

Index

302,305,

Aluminum

Aluminum

Material

(see Xylidine)

- 69, 108,

182, 240,247,

611,

822,856

- 465, 764
- 611, 777,857

Aluminum

nitrate

Aluminum

oxalate

Aluminum

- 182,839,857
oxychloride
- 27, 54, 154, 252, 263
phosphate - 355
plating solution - 182
potassium sulfate (Alum) - 12, 19,

Aluminum
Aluminum
Aluminum
Aluminum

solutions

Aminoethoxyethanol

- 182

- 182
- 658
3-Aminopyridine
- 670
Aminosalicylic
acid - 658
Aminoethyl

oxide

piperazine

Aminophenol

Aminoxylene
Ammonia

(see Xylidene)

- 1, 27, 33, 37,47,

70, 102, 122,

62,70,86,

169,

182, 218, 247,

252,

375,

379,393,

398, 440,469,

106,

165, 169,

170,

149,

150, 154,

156,

159,

182, 205,218,221,232,236,

142,

149,

53, 54, 63, 65, 67,

27, 33, 34, 36, 37, 39, 47, 50, 54, 57, 58, 61,

397,

151, 154,
263,

242,251,

263,

355,

373,

374, 382,

384, 388,

639,

642,

646,

648, 650,

389,407,

434,

440,

642,

646, 647,

650, 658,

728, 731,

732,

736,

670,

726,

728, 735,

749, 757,

764,

773, 777,

795,797,801,805,810,823,839,848,857,

781,

788,

797,801,

805,810,822,846,

856,

882
Ammonia,

857
Aluminum

potassium

sulfate,

vapor and condensate

182
Aluminum

reduction

pot plant roofing

Ammonia

aqueous

159,

159,

299,

658,

663,

670, 725,

749, 764,

765,

777,

Aluminum

salts - 149, 355, 367,810,

Aluminum

sodium sulfate

hydroxide)

- 27, 65, 149, 154, 156, 157,

liquid

169, 182, 252,263,

Ammonia-lithium

848

- 58, 154, 270, 658,

Ammonia-nitric
Ammonia-SOs

670,822

- 611

Ammonia

Aluminum

stearate

Aluminum

sulFate - 1, 12, 18,27,

33, 37,54,

355,

663,

671,788,

63, 65, 66, 70, 106, 109,

113, 114,

142, 151,

170,

152,

154, 156,

231,236,240,242,247,

118,

Ammoniated

122,

Ammoniated

174, 182,221,

252,263,273,299,

Ammonium

metal

in solution

- 355

- 183
scrubber - 183
fumes

solution

60,

788,

- 467, 468,469

839,857,889

182

355,

611, 632,

(see Ammonium

gas mixtures

Ammonia,
and siding -

156,

273,

(household)

mercury

ointment - 231
- 40, 54, 122, 154, 159,

mercury
acetate

- 130

- 13, 20

183,252,263,273,611,658,736

903

904

Corrosion Resistant Materials Handbook

Ammonium acid phosphate - 736, 764


Ammonium alum (see Aluminum ammonium
sulfate)
Ammonium aluminum chloride, molten - 736
Ammonium azide - 658
Ammonium benzoate - 183
Ammonium beryllium fluoride - 252
Ammonium bicarbonate - 47, 122, 156, 159,
170, 183, 273, 393, 398,469, 611, 658, 728,
736,765,777,781,788,839,857
Ammonium bifluoride - 12, 18, 27, 54, 70, 154,
218,231,252,263,470,658,671,822,839,
857,889
Ammonium bisulfate - 40, 156, 183, 777,810,
846,857
Ammonium bisulfide - 54, 263
Ammonium bisulfite - 34, 47, 159, 183, 658,
671,736,781
Ammonium bromide - 40, 60, 156, 252, 392,
393,399,407,671,725,777,857
Ammonium carbamate - 611, 658, 736, 749
Ammonium carbonate - 27, 47,54, 60, 63, 70,
113, 114, 118, 122, 152, 154, 156, 159, 169,
170, 183, 218, 232, 252, 263, 273, 355, 375,
379, 392, 393, 394, 395, 397, 398, 399,407,
434, 440, 469,611, 658, 671, 725, 728, 757,
765,777,781,788,797,801,805,810,822,
839,857,882,889
Ammonium caseinite
.839
Ammonium chlorate - 736
Ammonium chloride - 12, 19,27, 33, 34,54, 60,
63.67.70,
106, 108, 109, 113, 114, 118, 123,
151, 152, 154, 156, 157, 159, 170, 183, 218,
221,236, 240,247, 252,263, 273,299,302,
305, 308, 311, 314, 355, 364,370,372,373,
374, 375,379,384,388,
389,392,393,394,
395, 396, 397,398, 399,407, 434, 440, 469,
470, 609,611, 632, 646, 650, 658,671, 725,
728, 731, 732, 735, 736, 741, 750, 757, 765,
773, 777,780,781,
788, 797,801,805,810,
823,839,846,857,882,886,889
Ammonium chlorostannate - 781
Ammonium citrate - 159, 183, 658
Ammonium dichromate - 54, 252, 263, 609,
611
Ammonium dihydrogen phosphate - 671
Ammonium diphosphate - 658
Ammonium fluoride - 27, 47,54, 60, 106, 108,
114, 118, 123, 149, 152, 154, 159, 183,218,
221,252,263,392,
393, 398, 399,407, 609,
611,658,671,736,750,765,773,823
Ammonium fluosilicate - 658, 672
Ammonium formate - 658
Ammonium hydrogen sulfate (see Ammonium
bisulfate)
Ammonium hydroxide - 1,2,4, 6, 9, 10, 17, 26,
27,32, 33,36,37,40,47,53,54,
60,61, 62,

63, 65,70,71,95,96,97,98,
102, 104, 108,
109, 111, 114, 117, 118,120, 122,142, 147,
149, 151, 152, 154, 155, 156, 159, 169, 170,
174, 182, 183,218, 221,226, 236, 239,240,
242, 247, 252, 263, 273, 285, 294, 296,297,
302, 305,308, 311, 314, 355, 367, 370, 372,
373, 374, 375, 379, 382, 383, 384, 388, 389,
392,394,395,396,
399,407,432,440,611
632, 639, 641, 642, 647, 650, 658, 663, 672,
725,728,732,
735, 736,741, 750, 765,773,
777,781, 788, 790, 792, 796,797,801,805,
810,822,823,839,846,848,
857,882,884,
886,889
Ammonium hydroxide mixtures - 467, 468, 469,
672
Ammonium hydroxylamine
- 658
Ammonium iodide - 611
Ammonium
lactate - 611
Ammonium
lauryl sulfate - 183
Ammonium metaphosphate - 27, 54, 114, 123,
154, 156,252,263,273,658,810,823
Ammonium metatungstate - 183
Ammonium molybdate - 231, 609, 611
Ammonium muriate (see Ammonium chloride)
Ammonium
nitrate - 12, 19, 27, 33, 37, 47, 54,
60, 62, 65, 67, 71, 108, 113, 114, 118, 123,
152, 154, 156, 159, 170, 183,218,221,236,
240. 243, 247, 252, 263,273, 302, 305, 308,
311,314, 355, 370, 372, 373, 374, 375, 379,
384, 387, 388, 389, 392, 393, 394, 395, 396,
397, 398, 399,407, 434,440, 470, 609,611,
632, 650, 658, 672,728,732,733,
736, 757,
773, 781, 788,792, 797,801,805,810,823,
839,846,857,882,886,889
Ammonium
nitrate (ammoniated) - 612, 781,
857
Ammonium
nitrate fertilizers - 672,810
Ammonium
nitrite - 273, 355, 810,857
Ammonium orthophosphate
- 183
Ammonium oxalate - 156, 612, 658, 672, 728,
736,750,777,781,839,857
Ammonium perchlorate - 156, 440, 470, 612,
672,736,765,781
Ammonium persulfate - 27, 37, 47, 54, 71, 108,
113, 114, 123, 147, 154, 156, 159, 170, 183,
252, 263, 273, 355, 367, 370, 375, 379, 399,
407, 612, 658, 672, 728,777, 781,797,801,
805,810,823,839,857,882,886,889
Ammonium phosphate - 27,33,47,
54, 60, 62, 67,
71, 102, 108, 109, 123, 154, 155, 156, 159,
170, 183,218,221,252,263,273,
302. 305,
308, 311, 314, 355, 375, 379, 392, 393, 399,
407,471, 612, 632, 658, 672, 728,732,773,
777, 781,788, 797,801,805,810,823,839,
857,882,886,889
Ammonium picrate - 658
Ammonium polysulfide - 658

Corrosive Material

Ammonium
salts - 36, 149, 355, 367, 383, 648,
663,848
Ammonium
salts, insecticide - 231
Ammonium
salt of primary alcohol glycol ether
sulfate - 108, 183
Ammonium
silicofluoride
mixture - 471
Ammonium
sulfamate - 612, 658
Ammonium
sulfate - 12, 19, 27, 33, 34, 47, 54,
60, 62, 65, 67,71,
106, 108, 109, 113, 114,
118, 123, 151, 154, 155, 156, 159, 170, 183,
218, 221, 236,240,243,247,252,263,273,
299, 355, 370, 372, 373, 374, 375, 379, 384,
388, 389, 392,393,
394, 395,396,397,398,
399,407,434,440,471,
472, 609, 612, 632,
650, 658, 672,732,
735, 736,750,
757, 765,
773, 777,781,
788, 797,801,805,810,823,
839,857,882,886,889
Ammonium
sulfide - 27, 54, 106, 114, 118, 152,
154, 156, 183, 252, 263, 273, 355, 375, 379,
399,407,
612,658,725,728,857
Ammonium
sulfite - 71, 183, 440, 658, 672, 781
Ammonium
thiocyanate
- 27, 108, 109, 113,
114, 118, 123, 154, 156, 170, 182, 183, 184,
231,252,
263,273,472,
612, 658, 781, 788,
810,857
Ammonium
thiocyanide
- 857
Ammonium
thioglycolate
- 231, 612
Ammonium
thiosulfate
- 109, 170, 184, 612,
839,857
Ammonium
tungstate - 184, 400, 407, 658
Ammonium
tungstate mixtures - 472
Amsco BKOH solvent - 184
Amseed oil - 142
Amy1 acetate - 27, 54, 60, 63, 65, 71, 108, 113,
114, 118, 123, 142, 149, 153, 154, 156, 159,
170, 184,218,227,236,241,243,
247, 252,
263,273,
284,299,
303, 306,309,312,
315,
355, 370, 372, 375, 379, 389,392,
393,398,
400,407,434,
612, 646, 650, 658, 672, 728,
732, 757, 777, 789, 797,801,805,810,823,
839,848,857,882,886,889
Amyl acetate, iso - 18, 156, 227, 620
Amy1 alcohol - 27,34,53,67,
69, 108, 109, 114,
118, 123, 142, 149, 153, 154, 156, 170, 184,
218,236,240,243,247,
252,263,
299, 355,
389, 393, 397,398,400,407,472,
612, 650,
672, 781, 789,797,801,805,810,823,
839,
848,856,857,882,886,889
Amylalcohol,
iso- 10, 17, 60, 106, 156, 176,
286, 392,620
Amy1 alcohol, n - 10, 17, 174,225
Amy1 alcohol, tert - 10, 17, 823
Amylamine
- 103,788
Amy1 borate - 273, 355,810,823,
857
Amy1 carbinol (see n-Hexanol)
Amy1 chloride - 27, 34,54,71,
113, 114, 118,
123, 149, 151, 153, 154, 156, 170, 184,218,

Index

252, 263, 273, 355, 393, 472, 632, 646, 658,


672,732,777,
789,797,801,805,810,
823,
848,882,886,889
Amyl chloronaphthalene
- 273, 355, 810, 823,
857
Amylcinnamaldehyde
- 226, 472
Amylene - 473
Amylene hydrate (see tert-Amy1 alcohol)
Amy1 laurate - 658
Amylmercaptan
- 232, 473, 612, 672, 781
Amy1 naphthalene
- 273,355,810,823,857
Amy1 nitrate - 857
Amylphenol - 156,273,473,658,672,810
Amylphenol,
sulfur substituted - 713
Amy1 phthalate - 142,227
Amy1 propionate
- 658
Amy1 valerate - 612
Anderol esters - 355
Anethole - 65, 273
Anethym
oil - 232
Ang-25 - 355
Anhydrite
- 823
Aniline - 6, 7, 13, 20, 27, 33, 34, 40, 54, 60, 63,
65, 67, 71, 95, 108, 113, 114, 123, 149, 157,
753, 154, 157, 158, 159, 170, 174, 184, 218,
226, 236, 240, 243, 247, 252, 263, 273, 285,
296,299,
303, 306, 309, 312, 315, 317,318,
319, 320, 321, 322, 323,324,
325, 326, 327,
328, 329, 330, 331, 332, 333, 334, 335, 336,
355,370,
372, 373, 374, 375, 379,388,
389,
392, 393, 394, 395, 397, 398, 400, 407, 434,
440, 473, 612, 646, 650, 658, 663, 672, 735,
736,757,765,
780, 781,789,810,822,823,
839,846,848,857,886,889
Aniline chloride - 823
Aniline chlorohydrate
- 27, 154, 263
Aniline compounds - 646
Aniline dyes - 756, 227, 355, 650, 773,870,
823,
839,858
Aniline, ferric chloride - 781
Aniline hydrochloride
- 27, 60,71,
114, 149, 154,
159, 174, 184,221,252,263,
355, 392,400,
407, 658, 735, 736, 750, 765, 773, 777,810,
823,858
Aniline oil - 857,872
Aniline oils, fats - 273,355,823
Aniline paint oil - 156
Aniline salts - 823
Aniline sulfate - 159, 184, 658
Aniline sulfite - 434, 658, 672, 758
Aniline tint - 4
Animal fats and oils - 36, 67,84,
755, 756, 203,
279, 285, 355, 361, 382, 383,403,410,
646,
663,8 10,823
Anionic polyelectrolytes
- 184
Anionic surfactants - 184
Anise oil (see Essential oils)

905

906

Corrosion

Resistant

Materials

Handbook

- 118, 123

Anisole
Anisole,

Aromatic

- 672

boron trifluoride

Anodizing

- 34, 184, 212,221,

solutions

672,

773

(see Hydrocarbons,

mercaptan - 200
- 184
Arsenates - 663
Arsenic - 367
Arsenic acid - 27, 54, 71, 106, 113, 114, 149, 154,
Aromatic

Arquad

- 37

Anolyte

- 355,858
- 858
Anthium dioxide - 184
Anthracene
- 663, 789
Anthracene
oil - 53, 184, 658
Anthraquinone
- 27, 54, 154, 263, 658
Anthraquinone
disulfonic acid - 184
Anthraquinone
sulfonic acid - 27, 54, 149, 154,
Ansul ether
Ansul oil

264,658

- 473, 474, 673

Antibiotic

mixtures

Antifreeze

- 5, 107, 123, 155, 156, 273, 284,

291,

305,308,

311,

313,

316, 358,364,

Antimony

chloride

- 113,

123,

152,

375,

156, 273,

384,400,407,658,673,810,823,848

- 673
- 393, 400, 407, 823
pentachloride
- 108, 170, 184, 658,

Antimony

fluorochlorides

Antimony

oxychloride

Antimony
673
Antimony

plating

solution

- 698,834,843,

885,891
tartrate - 400, 407
- 67, 273, 474, 673,858
sulfate - 658
trichloride - 27, 34, 54, 63, 71, 106,

Antimony

potassium

Antimony

salts

Antimony
Antimony
108,

147, 149,

154,

264,

393,

735, 736,773,777,797,801,

398,

170,

184,218,221,252,

(see Sodium

396,
773,

796,

797,801,

810, 823,

779, 781,
Arsenic

compounds,

acid (see Malic acid)

Apple

brine

Apple

pomace

- 612
- 474

(see Nitric

pentoxide

Arsenic

plating solution

60, 71, 114,

154,

156,

170, 174,

264,

273,

379,

389, 392,393,400,

407,

732, 736,

765, 787,

823,848,858,886,889

- 184
- 658
Arachidic acid - 658
Arachidonic
acid - 823

123,

184,218,236,

355, 373,

731,

741,750,

- 400, 407,

- 475
- 834,843,

mixtures

885

- 67, 273
Arsenic trichloride
- 355, 658, 788
Arsenic trioxide - 612, 658
Arsenous acid - 47, 159, 170, 184
Arsenous oxide - 736
Arylsulfonic
acid - 27, 149, 154, 252, 264
Asbestos - 612
Ascorbic acid - 475, 658
Askarel (transformer
oil) - 273, 355, 810, 823
Aspartic acid - 612
Asphalt - 27,71,
123, 156, 184, 274,299,
355,
475,612,632,650,789,810,823,839,858
emulsions, topping - 71, 247,839,858
- 63, 142, 230, 399, 406, 610, 612, 787,

Asphalt
Aspirin

788,839

- 22, 230
dominion

- 356

- 612
industrial

(see also Air)

- 94, 184,

marine

374,

612,646,

375,
673,

795,810,

- 94, 431, 475, 476, 638,

648,650

Atmosphere,

mild

Atmosphere,

rural

- 433
- 94, 638, 639, 642, 648, 650

- 673

Atropine

243, 252,

or acid

salts

Atrazine

acid)

- 27, 40,53,54,

neutral

Arsenic

Atmosphere,

Apple

805,

858

639,642,

mush

787,

839,848,854,882,886,889

431,433,475,476,638,639,642,648,650

- 184

149, 152,

355,
758,

Atmosphere,

thiosulfate)

Ant oil (see Furfural)

239,

264,

658, 726, 728,

Atlantic

- 658

trifluoride

Antichlor

regia

221,252,

612,

Atmosphere

Antimony

Aqua fortis

170, 184, 218,


398,434,

Atabrine

805,858,882

Apache

156,
397,

Arsenic

379,612,789,810,839,858

Aqua

hydrocarbons

aromatic)

sulfate

Avon cream cake

- 142, 231
- 22

- 106
- 184
Azobenzene
- 658
Azo dyestuffs - 728
Azotic acid - 823
Axle

oil

Azelaic

acid

Aqua regia, fumes


Arabic

acid

Aragonite

(see Calcium

BTX

- 52

Bacon, bacon fat


Bactericide,
carbonate)

- 273
- 355,612.788,858
Armeen - 184
Aroclor - 71, 273, 355, 858
Aromatic fuel - 355

Bakery

- 14,227

phenate

products

Arco C-2 100

Baltic types 100,

Argon

Banana oil

based

150, 200,

Bardol

300, 500

- 823
- 274,811
- 839,858

Banvel, concentrated
Barbeque

- 184

- 382

sauce

- 356,811,823,858

- 274, 811

Corrosive Material

Barite(seeBarium sulfate)
Barium acetate-47,159, 170, 184
Barium bromide -231
Barium carbonate-27,47,54,71, 108, 113,
114, 118, 123, 142, 152,154, 156,159, 170,
184,218,231,252,264,274,393,397,434,
609,613,650,658,735,736,758,765.7777,
782,788,797,801,805,811,823,858,882,
889
Barium chlorate- 658
Barium chloride- 27,33,47, 54, 60, 63, 65,71,
108,113,114,118, 124,154,156,159,170,
184,218,221,231,236,240,243,247,252,
264,274,303,305,308,311,314,356,373,
374,375,379,384, 388,389,392,393,397,
398,400,407,434,440,476,609,613,632,
650,658, 673,735,736,750,758,765,773,
777,782,788,811,823,839,858,886,889
Barium cyanide- 72, 658
Barium fluoride
- 736
Barium hydroxide (hydrate)-9,28,47,53,54,
60,72, 113, 114,118, 124, 151,154,156,
159, 170,184,218,236,243,247,252,264,
274,299,302,305,308,311,314,356,379,
384, 389, 392, 393, 394, 395, 397, 398,400,
407,434,613,650,658,673,728,732,736,
758,765,777,788,795,797,801,805,811,
823,839.858,882,889
Barium nitrate
- 54,72, 156,221, 236,243,264,
379,384,388,389,407,434,477,609,613,
658,728,735,736,758,765,773,777,782,
839,858
Barium peroxide- 658
Barium polysulfide
- 658
Barium salts
- 67, 124, 149, 156, 356, 367,848
Barium sulfate
- 28, 47, 54, 72, 109, 113, 114,
118, 124, 151,152, 154, 156,159, 170, 184,
221,247,252,264,274,356,373,374,434,
650,658,735,758,773,777,782,788,811,
823,858,886,889
Barium sulfide
- 28, 47,54, 63, 72, 114, 118,
124, 151, 154, 156,159, 170, 184,218,236,
243,252,264,274,303,305,308,311,314,
356,367,388,389,397,398,400,407,613,
650,658,788,797,801,805,811,823,858,
882
Bases- 116, 120,220,240,285,302,432
Bath oil,bubble- 22
Bath oil,pine - 14,23
Bath salts,
Coty - 14
Batteryacid (seeSulfuric
acid)
Bauxite- 613
Baygon-273
Bay oil-839,872
BayolD- 356
Beans - 613
Beer - 1, 15,23,28,37,47,54, 60,62, 65, 67,

Index

72,106,114, 118,124, 149,154,156,159,


170,184,227,238,252,264,274,299,356,
370,372, 373,374.375,379,382, 392,440,
613, 632, 650, 735, 788,811, 823,839,858,
886,889
Beer,brewing- 477
Beeswax- 613
Beeswax, bleachsolution- 673
Beet juice - 124,227
Beltoil- 156
Bengalgelatin
- 823
Bentec- 184
Benzalchloride(benzyldichloride)
- 174, 184
Benzaldehyde- 1,20.28, 34, 40, 53,54, 63, 65,
72, 109, 118, 124, 142,149,154,158, 170,
174, 184, 185,218,226,239,241, 247,252,
264,274,299, 303,306,309, 312,315,317,
318,319,320,321,322,323, 324,325,326,
327,328,329, 330,331,332, 333,334, 335,
336,356,375,379,393,398,400,407,613,
658,663,736, 765,789,797,801,805,811,
823,839,848,858,882,886,889
Benzaldehydeconcentrate- 1
Benzaldehyde sulfonicacid
- 658
Benzalkonium chloride-252,264
Benzamide-658
Benzanthrone- 658
Benzedrine-142,232
Benzene (benzol)-1,2,4,6,7,9, 11, 18,28,33,
34,40,52, 53,54, 60, 61, 62, 63, 65, 67, 72,
95,104,106,108,109,111,112,113, 114,
117, 118, 124, 142, 147,149, 151, 153,154,
156, 158, 160, 169, 170,174, 184,218,223,
224,229.236,239.243,247,252,264,274,
285,291,293, 296,299, 304, 306, 309, 312,
315,356,370,372,373,374,375,379,383,
384, 387, 389, 392, 394, 395, 397, 398,400,
407.434.477.478, 613,632, 651, 658, 663,
673,736,758,765,782,789,792,797,801,
805,811,823,839,846,848,859,882,886,
889
Benzene in kerosene-47,160
Benzene in methanol-285
Benzene carbinol-823
Benzene carboxylicacid (seeBenzoic acid)
Benzenedisulfonicacid
- 108,156,184
Benzene hexachloride(Lindane)-34,229,
478,613,658
Benzene monochloride (seeChlorobenzene)
Benzenesulfonicacid
-28,37,47,53,54, 63.72,
108,114, 124, 160, 170, 174, 184,218,236,
240,243,247, 252,264,356. 373,374, 375,
379,388, 389, 398, 400, 407, 434, 658, 673,
758,765,782,787,811,823,839,848,854
Benzenesulfonylchloride
- 174,400,407
Benzidine-658
Benzidinedisulfonic
acid- 658

907

908

Corrosion

Resistant

Benzidine-3-sulfonic
Benzil

Materials

Handbook

- 658

acid

- 613
- 658

Benzilic

acid

Benzine

(see Petroleum

sulfate - 659

of mercury

Bichromates

53,54,63,67,72,
106,
108, 113, 114, 118, 124, 142, 149, 151, 153,
154, 156, 160, 170, 184, 218,221,
225,236,
243,252,264,274,356,369,371,373,374,
375,379,382,384,388,389,393,394,395,
398,400,407,434,440,613,646,
651,658,
673, 728, 736, 758, 765, 773, 779,782,787,
797,801,805,823,839,848,854,882,
886,
889
(see Benzaldehyde)

Benzoic and salicylic

acid ointment

- 230

Biological

carbonate

154,156,253,264,393,398,811,824
Bismuth-lead
Bismuth,

molten - 642, 673, 736


- 642, 646, 732, 736

eutectic,

molten

- 613

Bismuth

nitrate

Bismuth

oxycarbonate

Bismuth

subcarbonate

Bisulfite

in scrubber

almond,

Bitumen

mixture - 375, 379


- 823
Benzol still residue - 156
Benzonitrile
- 72, 157,233,241,247,658,859

chloride)

- 663

- 884
- 28, 54, 114, 124, 149, 152,

solutions

Bismuth

Bitumastic

(see Benzene)

(see Mercuric

(dichromates)

- 185

Biocide

Bitter

- 232

Benzoic resin

Beryllium

Bichloride

- 184
Benzoic acid - 28,47,
Benzoflex

Benzol

- 613, 658
- 659

- 824
Betz sulfite - 185

acid

Benzoic aldehyde

chloride
fluoride

Betula oil

ether)

- 658
- 658

Benzobenzoic
Benzocatechol

Beryllium
Beryllium

- 824
- 824
- 109

oil (see Essential oils)

- 23,811
- 63
- 613

Benzole-alcohol

Bituminous

Benzol hydride

Black ash (see Barium

Benzophenol

- 613
Black chrome bath - 185
Black liquor - 28, 33, 34, 37, 40, 44, 54,90,
Blackberry

- 823

- 356,658,811
Benzotrichloride
- 175, 185, 356, 658
Benzotrifluoride
- 658
o-Benzoyl benzoic acid - 47, 159, 185
Benzoyl chloride - 53,60,
124, 157, 175, 185,
Benzophenone

Benzoyl
Benzyl

chloride

- 142, 227,

379, 400,

407,

65, 67, 72, 106,

158,160,175,

118,

185,218,225,252,
309,

392,400,407,613,

160,

673,728,762,

170, 185,

8 11,824,848,859

- 356

Black point 77

gas

Bleached

pulp

sulfate)

- 156,356,811,824
hypochlorite)

- 185

with KBr - 185


- 373,374,673,729,859
Bleaching powder - 285, 651, 780,788,824,825

160, 175,

185,218,229,241,247,253,304,
312,

315,

356, 375,

(pulp mill)

- 109

- 15, 23, 72, 156, 375, 379, 396, 440, 735


- 185
Blue salts - 824

379,383,

Blow gas absorber


Blue vitriol

72,
384,

- 658

Benzylphenol

- 658

Benzylphenol

salicylate
acid
acid

- 174, 184

basic)

- 787

compounds

- 788

- 824

- 185

Bone oil - 839,872


Boracic acid (see Boric acid)

Benzyl ether - 1, 230


Benzylethylaniline

acid

Bonderite
chloride)

sulfate,

Boiler acid phosphates


Boletic

- 234
(benzal

(see Copper

- 124, 233
Body fluids - 732
Bluing

Boiler feed water

- 40

o-Benzyl-p-chlorophenol
cyanide

liquor

Blood

400,407,658,811,822,824,839,859

Benzyl dichloride

Bleaching

Bleach lye - 114

307,

Benzylsulfonic

782,783,

840,860

benzoate

Benzylsulfanilic

374,439,

773,

Bleach liquor

- 253
- 185,233,356,811,824,859
Benzylbutyl
phthalate - 658
Benzylcellulose
- 658
Benzyl chloride (a-chlorotoluene)
- 40,47,

Benzyl

373,

651,

658,728,811,822,

Benzylamine

310,

253,264,274,356,

312,315,356,375,

824,839,848,856
Benzyl

156,

Bleach, ferricyanide

- 53,60,63,

263,274,303,306,
379,

218, 221.
540,

Bleach (see Sodium


375,

613,658
Benzyl alcohol
124,157,

149,

541,

151, 154,

109,

114, 147,

Blast furnace

- 658,839

peroxide
acetate

- 478

vapors

sulfide)

juice

Blanc fix (see Barium

252,299,375,379,392,478,613,658
Benzoyl

paint

Borax

(see also Sodium

- 658

- 658
- 765

tetraborate)

- 22, 28, 40,

124, 142,
149, 154, 156, 157, 170, 185,218,
231,247,
253,264,
274,299,
356, 392, 396, 609, 632,
651, 659, 782, 788, 797,801,805,811,824,
55, 60,67,72,88,

106,

839,848,859,882,886,889

113,

114,

Corrosive

Bordeaux

- 67, 156, 185, 274, 356, 613,

mixture

651,811,824,859
109, 113, 114,
155,

156,

124,

142,

149,

157, 170,

175,

185,218,221,225,

236,243,

253,

264,274,

314,

369,

371,

356,

384, 388,

389,392,

400,407,434,440,
646,

773,779,

302,

154,

Bromic

- 185

311,

308,

379,382,

Bromides

393,

394,

395,

396,

398,

Bromine

609,

613,

632,

642,

728,736,758,765,

Borneo1 in butanol

155,218,264,659

- 663
- 1, 28, 36, 40, 53, 55, 60, 63, 65, 67,

72,73,
157,

782, 787,797,801,805,811,824,

- 356
- 28, 55, 114, 149, 151, 152, 154,

acid

305,

108,
158,

- 478
- 274

114,

160,

233,240,

839,848,854,882,884,886,889
Boric acid mixtures

113-356
114

375,

674,726,

Boric copper sulfate

Brom
Brom

373,374,
478,

651, 663,

151, 152,

124,

169,

375, 379,

642,

646,

647,

659,

674, 732,

Bromine,

hydrochloric

Bornyl

formate

- 659

Bromine,

methyl

Bromine

Boron - 790

- 356

Boron fuels - 839,859

- 478, 659, 674


mixtures

Boron trifluoride

- 28, 63, 479, 613, 659, 674,

- 479

- 479,

674

pentafluoride
trifluoride

Bromine

vapor

- 55, 124, 149, 185,264,


- 28, 33, 37,55,

water

156,

160,

170,

185, 218, 236,

243, 264,

356,

388,

389,

392,

400, 407,

- 227
- 185
Brake fluid - 5, 20, 52, 96, 97, 98, 104, 106,

mono
315,

Bourbon

Bromobutane

Bromochloromethane

107,

117, 118,

185, 233,274,285,286,301,

356,

357, 359,

363,

663,8

Bromo
11, 824,

Brass pickling

- 30, 47, 58, 85, 115, 135,


368,834,

- 674

Brazing flux
Breeder

- 28, 149, 154

Bret 710

- 356
slop - 839,859

Brilliantine

fumes

bromide)

613,

(see Hexyl

Bromomethane

(see Methyl

luoro methane
solution

- 832
- 160, 185,843,884,

(see Calcium

- 4, 52
-4
pH 10.0 - 4, 52

pH 4.0

- 185

pH 7.0

hair dressing

- 14, 22

Build detergent

(see Sulfur)

- 186
- 613

solution

Bulk (dry)

Brine saturated

with chlorine - 156


- 674
Brine solution - 2, 28, 34, 55, 62,88,

Burnt alum (see Aluminum

Brine slurry

1,3-Butadiene

169, 185,

839,859

632,

acetate)

- 185

Buffer

- 221, 253, 774


Brine, alkaline - 221, 253, 774
Brine, chlorinated acid - 253

156,

bromide)

- 55,253,264

Brown stock washer hoods

Brine, acid

415,417,

659

bromide)

885,891

Brewery

Brimstone

Bromohexane

Brown acetate

pellets, fish

Brew kettle

(see Ethyl

Bronze plating

- 356
- 674

- 39, 41, 43, 44, 45, 46

- 37,253,

Bromotrif

- 356

Bray GG-130

357,

- 356

chlorotrifluoroethane

Bromotoluene

solution

bromide)

- 11, 18, 156,275,

Bromodichlorophenol
Bromoform

843,884,885,891
Brayco

- 55, 106, 253, 304,307,

356,363,663,824,859,871

(see Butyl

Bromoethane

- 124,238
185, 259,269,

736,

659,750,812,824,825,840,860

839,859

160,

60, 63, 114, 118,

154,

Bowl cleanse

150, 153, 154,

647,

765,848

124, 149,

310,312,

383,

- 356
- 356,824

Bromine

Bromobenzene,

- 185

366,

acid - 285
- 736, 765

solution

780,849,886,889

- 613

solution

797,

acid, sulfuric

alcohol

Bromine

Bromine

782,789
etherate

chloride

674,731,736,

Boron trichloride

Brass plating

733, 736,

792,795,

- 253

- 659

Brandy

370,

801,805,811,824,839,846,848,859,882

- 659

Bottle washer solution

356,

651,

780,782,789,

chloride

Borosilicates

299,

397, 398,400,407.

acetate

Boron trifluoride

264, 285,

156,

185, 218,221,

393,

Bornyl

Boron trichloride

149, 154,

175,

392,

Bornyl

Boron fluids (HEF)

142,

170,

247, 253,

372,

750.765,774,

- 13

Index

- 414, 415,417

Brine with sodium carbonate


Broke chest fumes

Boric acid - 17, 28, 33, 37, 53, 55, 60, 63, 67, 72,

Material

190,218,264,274,
642,

646,

Bunker

oil

Burndys

109,

124,

356,414,

651, 674,729,

792,

materials

- 274,292,356,811,824,859
A - 26

penetrox

170,218,247,253,264,356,
8 11,824,849,859
Butadiene

potassium

sulfate)

- 11, 20, 28, 55, 73, 149,

latex

- 186

613,

154,

156,

632,789,

909

910

Corrosion Resistant Materials Handbook

1,28, 55, 65, 67,73, 124, 149, 154,


156, 170, 229, 247, 253,264, 274, 299, 356,
479, 480, 613, 632, 651, 659, 674, 789,811,
824,840,849,859
Butanediol - 113, 114,253,
659,849

Butane-

- 233

Butanethiol
Butanol
Butanone

(see Methyl

ethyl

ketone)

Butozyl
Butter

- 186
ethyl)phthalate
- 253

313,

316,

356,382,

Butter

- 73, 156, 440,788,840,859

of tin (see Tin chloride)

Butter

of zinc (see Zinc chloride)

Butter

oil

- 9, 10, 17,26,28,

63, 73, 108,


154, 156,

111,

157,

118,

160,

120, 124,

243,247,253,264,274,

299,

356,

389,

393, 397,398,400,407,434,

674,758,

777,789,

37, 40,47,55,
142,

147,

149,

374,

375,

379,

384,

614,

659,

iso - 11, 18, 142, 620, 789

Butyl acetate,

set

ricinoleate

159,

170,215,236,240,

273,

291, 293,

379,

388,

356,

370,

106,

735,789,

108, 109,

149, 153,

154,

243, 247,

253,264,

372,

373,

389,392,393,400,407,

651,663,

156,

374,

375,

480,

614,

226, 277,

iso - 10,81,
360,

142,

156,

170,

198,

620, 789,815,830,839,

n - 10, 17,28,54,

848,

149,

154,

175,

set - 10, 17,28,

47, 54, 149,

154,

186,218,225,226,263

Butyl alcohol,

tert - 10, 17, 186, 218,225,

365,

837,879
Butyl alcohol,
ketone

ethyl

hexylacetate,

Butylamine,
Butylamine,
Butylamine,
Butylated

diisobutyl

- 186
- 28, 73, 157, 158, 186,247,
- 218,240
- 2 18
tert - 218

- 659

- 824

Butyl

- 370,372,
614
- 218, 253, 659
mercaptan, tert - 365,811,837,879
methacrylate
- 157
octadecanoate
- 824
oleate - 356, 824,859
oxalate - 659
phenol - 28, 55, 149, 154, 218, 253, 264,
lactate

mercaptan

480,659,663
Butyl

phenol,

Butyl

phthalate

p-tert - 694

- 147

- 28, 73, 108, 124, 142, 186, 227,

241,247,253,264,659,859
Butyl

- 55, 156,264,

stearate

356,

- 659

urethane

- 28
- 149, 154,264
Butyraldehyde
- 40, 156, 170, 253,299,
(erythrital)

Butynediol

315, 356,480,

614,

303,

306,

659,811,824,

840,859
acid - 1, 28, 34, 47, 53, 63, 73, 106,

109, 114,

149,

154,

156, 160,

218,

225,236,

243,253,264,

373,

374, 375,

379,

382,

389,

170,
356,

369,

393,

398,400,
659,

441,

481,

614,

632,

651,

726,728,

736,

758, 765,

779,

782,787,

Butyric

anhydride
chloride

C-56

- 186

CWT

102 - 190

- 233, 614

- 659
- 229

108,

175, 186,

407,434,

801,805,811,824,840,849,882,886,889
356,

659,811,824,

859

set

hydroxyanisole

ether)

- 856

hydride

Butyryl

- 47, 63, 160, 186


- 186

alcohol

Butyrolactone

788,811,824,859

356

Butyl

Butyric

186,218,225,263
Butyl alcohol,

- 293,

ether (see Dibutyl

309, 312,

Butyl alcohol,

Butylamine

Butyl

Butynedial

856,868

159,

oxide

Butyl

797,801,805,811,824,

832,839,848,849,856,859,882
Butyl alcohol,

glycol

Butylene

Butyl

- 28,40,

propanols)

60, 63, 65, 67, 69, 103,


147,

- 614

ricinoleate

chloride,

Butylene

Butyl

methyl

glycol monobutyl

- 73, 218, 229, 253, 659


iso - 661
Butyl chloride, n - 175, 292, 615
Butyl chloride, set - 175, 615
Butylene - 28, 55, 73, 218, 247, 253, 264, 356,
Butyl

Butyl

- 218, 253, 356,824

124, 142,

adipate

- 356, 480, 674,824

(butanol,

114,

acetyl

Cellosolve

Butyl

Butyl acrylate

110,

Cellosolve

- 413

Butyl alcohol
47,55,

Butyl

Butyl

- 17, 156
boiling

879

(see Ethylene

Butyl

Butyl

842,849,859,882,886,889

Butylacetyl

glycol monobutyl

- 365,837,

tert

Cellosolve

Butyl

797,801,805,824,840,

mixture,

(see Diethylene

Butyl glycolate

290,291,293,

373,

Butyl acetate,
Butyl acetate

carbitol

Butylethyl

170, 186,218,227,236,

241.

370, 372,

Butyl

632,789,849,859

- 811

Butyl acetate

bromide

Butyl chloride

613,

663,788,824,840,859
Buttermilk

- 218, 253
Butyl butyrate - 227, 356, 659,859

Butyl

ether)

- 14, 22, 67, 124, 142, 156, 227, 238,


304, 307,310,

- 160

Butylbenzylphthalate

Butyl

- 379

274,

- 147

(BHT)

- 356,659,824,859

Butylcatechol,

186,225,824

2,2-Butoxyethoxyethanol
Bis(2-Butoxy

hydroxytoluene

Butyl benzoate

ether)

(see Butyl alcohol)

2-Butoxyethanol-

Butylated

371,
674,
797,

Corrosive

Cacodylic acid - 481


Cadmium bromide - 231
Cadmium chloride - 47, 160, 236, 243, 388,
389, 407, 614,750
Cadmium cyanide - 28, 55, 154, 264, 659
Cadmium, molten - 642, 780
Cadmium nitrate - 236, 243, 388, 389, 407
Cadmium plating solution - 30, 47, 58,85,
115,
135, 150, 153, 154, 160, 186, 259,269,
368,834,885,891
Cadmium salts - 149, 156,849
Cadmium stearate - 231
Cadmium sulfate - 221, 236, 243, 388, 389,
434,481,614,659,758,774,782
Caffeine - 142, 230
Caffeine citrate - 264
Cajeputene
(see Limonene)
Cake alum (see Aluminum
sulfate)
Calamine - 824
Calcine liquors - 356, 811, 824, 859
Calcite (see Calcium carbonate)
Calcium acetate - 356, 659,811,824,
859
Calcium acid phosphate - 659
Calcium arsenate - 65, 274, 663, 796
Calcium benzoate - 659
Calcium bicarbonate
- 657, 659, 765
Calcium bisulfate - 152, 156, 218, 221, 274, 774,
797,801,805,811,840,859,882
Calcium bisulfide - 55, 67, 114, 154, 186, 218,
253,264,274,859,889
Calcium bisulfite - 47, 55, 60, 73, 125, 154, 160,
170, 186, 221, 236, 243, 253, 264, 274, 299,
356, 367, 375, 379, 384, 388,389,392,
396,
434, 632, 651,657,
659,732,
736, 758, 765,
774,782,
788, 797,801,
805, 811,824,860,
882,886
Calcium bisulfite, bleach liquor - 253
Calcium bromide - 231,481,
659, 674, 750
Calcium carbide - 614
Calcium carbonate - 28, 47, 55, 73, 113, 114, 118,
125, 151, 152, 154, 156, 160, 169, 170, 186,
218, 253,264,
274, 356, 385, 434, 441, 614,
629, 657, 659, 663, 674, 728, 735,736,758,
765, 777, 788, 797, 801, 805,811,824,
860,
882,889
Calcium chlorate - 28, 34, 47, 55, 108, 114, 118,
125, 156, 160, 170, 186, 218, 253,264,
274,
375, 379, 393, 398, 434, 659, 674, 728, 758,
777,782,797,801,805,811,824,860,882
Calcium chloride - 1, 12, 19, 26, 28, 33, 34, 36,
37, 47, 55, 60, 63, 65, 67, 73, 106, 108, 109,
111,113,114,118,120,125,147,151,152,
154, 155, 156, 157, 160, 170, 175, 186,218,
221, 231, 236, 240, 243, 247, 253,264,
274,
299, 303, 305, 308, 311, 314, 356, 370, 372,
373, 374, 375, 379,382,
383, 385, 387, 388,
389,392,393,394,395,396,397,398,400

Material

index

407,423,
434, 441, 481, 482, 609, 614, 642,
646, 647, 651, 659, 663, 675, 728, 732, 735,
736, 740, 750, 758, 765, 774, 777, 782, 788,
791 t 797,801,805,811,824,
840, 860, 882,
886,889
Calcium chloride brine - 675
Calcium chloride in alcohol - 63
Calcium chlorohypochlorite
- 156
Calcium chromate - 614, 659
Calcium citrate - 482
Calcium cyanide - 356
Calcium dihydrogen
sulfite and SOs - 659
Calcium disulfide - 659
Calcium fluoride - 659, 750
Calcium gluconate - 614, 659
Calcium hydrosulfide
- 482
Calcium hydroxide - 9, 17, 28, 36, 48, 53, 55, 60,
67,73,
113, 114, 118, 125, 151, 154, 155, 156,
160, 170, 186, 218,221,
226, 236, 243,253,
264,274,
299, 302, 305, 308, 311, 314, 356,
370, 373, 374, 375, 382, 385, 387, 388, 389,
392, 393, 394, 395, 396, 397, 398, 400, 407,
482, 614, 632, 651, 659, 663, 675, 728,732,
735, 736, 765, 774, 777, 782, 788, 792, 797,
801,805,811,824,840,860,882,889
Calcium hypochlorite
- 12, 19, 33, 35, 37, 40, 48,
53, 55, 60, 63, 67, 73, 106, 113, 114, 118, 125,
142, 147, 152, 154, 156, 160, 170, 175, 186,
218,221,231,253,264,274,285,299,
303,
305, 308, 311, 314, 356, 367, 370, 372, 373,
374, 376, 379, 380, 392, 393, 394, 395, 396,
397,398,400,407,482,
614, 632, 651, 675,
689, 726, 732, 735, 736, 750, 765, 774, 777,
782, 788, 797, 801,805,811,
824,840,849,
860,882,886,889
Calcium lactate - 483, 659
Calcium, magnesium, sodium chloride solution - 186
Calcium nitrate - 28, 33, 48, 55, 65, 74, 106, 113,
114, 118, 152, 154, 160, 170, 186, 218,236,
240,243,
247, 253, 264, 274, 356, 373, 374,
376, 379, 385, 388, 389, 393, 400, 407, 614,
659,812,824,860
Calcium oxalate - 659
Calcium oxide (lime) - 55, 67, 82, 172, 186, 231,
253, 264, 278, 609, 614, 620, 652, 780, 788,
790,842,851,869
Calcium oxychloride
(see Bleaching powder)
Calcium oxysulfide
- 29, 57,81,
132, 156, 253,
267,278,361,652,869
Calcium phosphate - 12, 19, 28, 118, 125, 221,
356,483,659,774,860
Calcium propionate - 147, 614
Calcium pyridinesulfonate
and sulfuric acid 659,675
Calcium salts - 67, 125, 149, 156, 356, 367,849,
860
Calcium silicate - 274, 356, 614,812

911

912

Corrosion

Resistant

Materials

Handbook

- 824

Carbon dioxide

- 1, 28, 35, 48, 53, 74, 108,

Calcium

silicoaluminate

Calcium

stearate - 659

118, 149,

154,

156,

Calcium

sulfaminate

253,

376,

380, 400,

Calcium

sulfate - 1, 12, 19, 28, 33, 48, 55, 74,

- 659
152, 154,

156,

160,

264,

373,

114, 118,

170,

186,218,231,247,253,

374,

376, 380,

385,

387,

393, 397,

398, 400,

441,

407,

435,

646, 659,

676, 758,

777, 788,

849,882

484,

485,

Calcium

sulfide
sulfite

- 253, 274, 357, 659,812,824


- 48, 118, 125, 160, 357, 483,

659,675

- 357

thiosulfate

Calgon (sodium

- 788,840,

hexametaphosphate)

849,860

- 156, 357, 812, 825,860,861

liquors

Camphene

- 659

Camphene,

chlorinated

68%

- 186

632,

dry

639,

- 55, 125, 218, 264, 274, 357,

642,

wet

651, 797,801,805,812,

- 55, 125, 186, 218, 264, 274,

614,659,663,758,780,789,860
Camphor

55, 60, 63, 65, 106,

111,

112,

114,

121,

149,

156,

157,

160,

170, 175,

151,

153,

154,

186,218,

221, 236,

243, 247,

253,

264, 274,

304,

307,

310,

313,

315,

357,

370, 372,

383,

385,

389,

392,

376,

380,

397,

398, 400,

651,

659,

407,435,485,

663, 728,

Carbon disulfide

vapor

Carbon fluorides

- 659

758,

774,

393,

394, 395,

614,

632, 646,

777,

789,

- 186

152,

154, 156,

160,

170,

186, 221,

357,

367,

393,

396,

397,398,

659,

676, 728,

- 15,23
Can cleaner, acidic - 186
Candelilla wax - 676
Canning plant waste - 186
Can treatment - 186
Capella AA - 860
Capric acid - 186, 659
Caproic acid - 285, 614
Caproic aldehyde - 357, 659,825
Caprolactam
- 614

Carbon tetrabromide

- 659

Caprolactone

Carbon tetrachloride

(tetrachloromethane)

Caproxyl

alcohol
acid

676

646,

782, 787, 812,825,

Carbon

methyl

Carbon

monoxide

735, 750,
840,849,

- 48
- 28, 48, 53, 55, 67, 74, 114,

cellulose

125, 149,

151,

154,

156, 160,

170, 186,253,

264, 299,

357,

376,

380, 435,

485,

- 825
- 825

109,

- 1, 2,

33, 34, 37, 40, 48, 52,

53, 55, 60, 63, 65, 67, 74, 95, 104,

- 825

663, 758,

12,825,840,849,860

4, 7, 9, 11, 18, 26,28,

- 48, 53, 55, 108, 109, 160, 170,

alcohol

614,
779,

789,8

186,218,253,264,614
Caprylic

441,

758, 774,

854,882,886,889

- 825

alcohol

Caprylic

435,

- 842
alcohol

Caproyl
Capryl

254,265,274,

Balsam

Capronitrile

797,

- 28, 48, 55, 63, 74, 114, 118, 125,

acid

149, 151,

acid - 659

- 659,

125,

299,

Carbonic

oil - 114, 125,849

Camphorsulfonic

- 2, 13, 20, 26, 28, 33, 37, 40, 48,

Carbon disulfide

802,806,812,825,840,849,860,882,889

- 63, 142, 186,230,264,398,435,

Camphor

Canada

609,

357,632,642,797,801,805,849,882

Calcium

Caliche

Carbon dioxide,

Carbon dioxide,

886,889

Calcium

408,

860

113,

169,

797,801,805,812,824,840,860,878,882,

114,

170, 186, 233,247,

614,651,663,676,728,736,789,825,840,

109,

483,

125,

299,

160,

106, 108,

111,

112,

114,

117,

118,

121, 125,

147, 149,

151,

153,

154,

158,

160,

236,239,

142,

170, 175,

186,218,

221,229,

253,

264,

274,

285, 291,

292, 293,

241,243,247,
296, 299,

304, 307,

310,

312, 315,

357,

372,376,

370,

Carbazotic

acid (see Picric acid)

377,380,381,383,385,387,

389,

392, 393,

Carbamate

- 357,796,

394,395,

397,

398, 400,408,

435,

485,

Carbamide

(see Urea)

632,

642,

651,

659,663,

676,

694,726,728,

735,

736,

743,

750, 758,

765,

ethyl
Carbolic
Carbon

- 186,825

- 226, 233, 659

Carbazole
Carbitols
Carbitol

812, 860

(Diethylene
solvent

glycol ethers)

(see Diethylene

- 253,789

789, 792,

glycol mono-

797, 802,806,812,

Carbon tetrachloride

acid (see Phenol)

Carboseal

- 483,484,

Carbonated

water

Carbonated

beverages (see also Soft drinks)

beads, water treatment


bisulfide

Carbon

dichloride

- 186

(see Carbon disulfide)

- 676

- 186

compounds

Carboxymethylcellulose
Cardamon

Carbon

vapor

gas antileak

- 160,187
Carboxybenzene
- 825

carbonated)

156,651,860
Carbon

777,782,
840,846,

Carbowax

614, 676
(see Water,

774,
825,

849,860,882,884,886,889

ether)

Carnalite

(spice)

- 131

- 659

Carnauba

wax

Carotene

- 659

- 233

615,

- 160, 187

- 15, 23

Corrosive

Carpet

shampoo

Carroting
Carrot

solution

- 238

liquified
oil

Carter

motor

- 274, 812

oil

125,

126,

142, 149,

154,

218,

233,

254,

275, 291,

265,

156,

160,

170, 187,

293,299,

307,310,313,316,357,368,393,651,

Caustic handling

pollution

382, 788,

hydroxide)

hydroxide)

Cell putty
Cellulose
Cellulose

Chloranil
glycol monoethyl

(see Ethylene

glycol

(see also Ethyl

glycol

ether)

monoethyl

monoalkyl

- 74, 247, 254, 659


- 187
- 275,357,812
- 156, 615, 663,860
acetate - 221, 233, 432, 615, 659, 774,

782,825
Cellulose

acetate

butyrate

Cellulose

nitrate

- 233, 659

Cellulose

tripropionate

- 55,265,

- 615, 659

659

- 659

Chloranthraquinone

- 659

- 15, 24, 67, 175, 229, 275, 357,

Chlordane
615,659
Chlordane,

5% in water

Chlorendic

anhydride

Chlorethanesulfonic

- 156
- 187

acid - 659

- 357
Chloric acid - 28, 74, 149, 154,265,

Chlorextrol

cracking

Chloride

salts

Chloride

(water)

- 154, 430,

Chlorinated

benzene

Cerium

Chlorinated

glue

- 486, 659
Cerous chloride - 486
Cerous nitrate - 187
Cesium bromide - 231

Chlorinated

hydrocarbons

Cesium chloride

Chlorinated

linseed oil

Chlorinated

lye (see Sodium

Chlorinated

organics

Cerium

- 659

sulfate

- 659

Cesium hydroxide
Cetane

(hexadecane)

- 659

- 157,357,860

Chlorinated
Chlorinated

445

- 40
- 673
biphenyl - 860,863
brine - 33, 37, 160, 357, 732, 733,

- 275, 357,812,825,840,860
Cellutherm - 357,860
Cement - 106,615,663
Cereal - 615
Cellulube

676,

- 664, 665
- 383, 445, 663

Chloride

aromatic

- 659

659,

732,779,797,802,806,854,882

Chlorinated

fluoride

acid)

265

ether acetate)

Cellugard

- 825

acid (see Chloroacetic

Chloramine

(see Ethylene

nitrate)

- 175, 254, 393, 400, 407, 659, 789


Chloral and MCB - 175
Chloral alcoholate - 40
Chloral hydrate - 28, 55, 63, 149, 154, 175, 254,

- 227
Cellophane - 233,486
acetate

(see Sodium

Chloral

- 187
- 143,233

Cellosolve

saltpeter

oil (see Tung oil)

Chinese gelatin

Celery salt

ethers)

nitrate,
oil

Chloracetic

Caustic potash (see Potassium

Cellosolves

- 143, 227, 615


- 486, 615
Chestnut wood extract - 676
Chicken gravy - 227
Chicken soup (MBT) - 227
juice

China wood
oxide)

- 676

Cellosolve

- 729

- 825
China clay slurry - 187

- 426

Caustic soda (see Sodium


oil

equipment

- 187

Chinabean

Caustic lime of soda - 891

spent

control

processed

Chile niter,

hydroxide)

- 187

Caustic lime (see Calcium

Cedarwood

drums - 729

Cherries,

- 729

liquor

- 187

processing - 729

- 15,23

Caustic etch tank vapor

Caustic,

- 62, 382, 615, 788


- 105

Cheese water

Cherry

(see Barium

Caustic mixtures

Cheese

Cheese spread

Chemical

840,860
compound

smoke) - 840
- 305, 307, 310, 313, 316

Chassis grease

Chemical

- 187

- 14, 22, 38, 156,227,

Catsup (ketchup)

Causticized

- 126

(liquid

663,

- 187

quaternary

Caulking

- 825

Chem- Rez
feed

acid)

- 825

Chemical

- 285

refining

Caustic baryta

gelatin

304,

788,812,825,840,849,860,872

Cationic

Ceylon

Charsol

- 28, 275, 382, 485,825,


860
Cassia oil - 142,233
Castor oil - 28,48,
55, 60, 67, 106, 113, 114,

Catalytic

acid (see Palmitic

Char-co-sol

Casein

Castro1 325

Cetylic
Chalk

- 125

Carrot

Index

- 126, 143, 225, 659

Cetyl alcohol

- 227

juice

Carrot,

- 187,207
- 485

Material

solvent

825,860

- 840
- 126, 632, 678, 732,

733,840
Chlorinated
bleaching

lime (see Calcium

hypochlorite

powder)

- 187

- 187,241

hypochlorite)

and

973

CorrosionResistant
Materials
Handbook

914

- 254

Chlorinated

phenol

Chlorinated

phenol disinfectant

Chlorinated

pulp stock

Chlorinated

rubber

Chlorinated

solvent

- 187

- 187

- 187
- 32, 36, 46, 156, 297, 357,

polymer

221,236,

243,254,

265,299,303,

312,314,

357,

369,

371,

373,

374,

376,

382,

388,

389,

393, 397,

398,

400,

408, 441,

487,

615, 632,

735, 737,

750, 766,

774,

- 840

Chlorinated

TSP

Chlorinated

washer

Chlorinated

water

732,

787, 795,

840,

854,882,886,

water)

- 33,

677, 735,

774,

(see also Chlorine


645,

676,

- 48, 160, 187, 217

Chloroacetyl

55, 60, 63, 65, 67, 74, 108,

109,

114,

126,

- 254, 265, 659


- 678

chloride
acid

- 825

Chloroallylene

- 13, 20, 28, 34, 35, 36, 37, 40, 48, 53,

Chloroaminobenzoic
Chloroaniline

acid - 659

- 659

- 825

143, 147,

149,

158,

160,

169,

Chloroazotic

187, 218,

254,265,275,393,

394,

395,

397,

o-Chlorobenzaldehyde

398,

408, 435,

659,

663,

676,

Chlorobenzene,

401,

151,

154,

157,

615, 646,

- 187

absorption

106,

- 825
Chlorine cell off-gas - 741

Chlorine

aqueon

Chlorine

cell plant surfaces

Chlorine

dioxide

171, 187,

188,218,

389, 393,

659,

677,

Chlorine,

678,737,

395,

114,

118,

126,

161,

171, 188,201,

218,229,

254,

265, 275,

291,

363,

370,

372,377,

381,

385, 389,

392,

393,

398,

401, 408,

487,

615,

632, 661,

673,

678, 777,

789,

797.802,806,

663,

171,

299,

357,

373,

639,

642,

646,

376,

380,

385,

389,

632,

726,

731,

732,

737,

750,766,780,787,

842,849,860,871,882,886,

Chlorobenzene

with sulfur dioxide

Chlorobenzol

651,

Chlorobenzotrifluoride

797,

Chlorobenzoyl

chloride

Chlorine

kill tanks

Chlorobromomethane

Chlorine

mixtures

Chlorobromopropane
Chlorobutane

(see Bromochloromethane)
- 659

(see Butyl chloride)

Chlorine

solution,

Chlorodifluoromethane

Chlorine

stripping

Chlorodiphenylamine

water

(see also Chlorinated

55, 60, 63, 67, 114,


155,

156,

161,

118,

171,175,

water)

126, 149,

- 53,

151, 154,

373,

374,

376,

(see Ethyl

Chloroethanol

alcohol

Chlorofluocarbon

(see Ethylene

382, 385,388,

389,392,394,395,

401,

Chlorofluoromethanes

731, 736,

750,812,825,849,

860,

Chloroform

wet - 149,

154,

160,

169,

171,

175,

187, 221, 236,243,

254,

265, 299,

357,

374,

376, 380,

385,

389,

392,424,

632,

373,
642,

644,

646, 651,

666,

677,

726,731,

732,

735,

736,

740, 750,

766,

774,

780, 782,

797,802,

806,812,825,846,882,891
Chlorites

- 53

Chloroacetaldehyde
Chloroacetic

- 659

acid, mono

- 28, 33, 34, 37, 40, 48,

49, 53, 55, 63, 74, 83, 109,


153,

154,

156, 161,

114,

171, 177,

133,

188,201,

149,
218,

- 678,832
- 2, 11, 18,26,28,

(see also Freons)

(trichloromethane)

103,
106,111,114,118,121,126, 143,147,149,
153,154,156, 157, 161,171, 175, 188,215,
218,230,236,239,241,243,247,254,265,
275,285,286,292,299, 304, 307,310,312,
315,357,370,372,373,374,380,385,388,
389,392,393, 394,395,397,398,401,408,
435,615,632,646,651,659,663,678,735.
737,758,766,780,782,789,797,802,806,
812,825,840,849,861,882,886,889
33, 37,40,48,53,55,60,63,65,67,74,

886,889

chlorohydrin)

- 108, 188

380,

Chlorine,

chlorohvdrin)

- 363, 659, 873

408,

740,

chloride)

(see Ethylene

o-Chloroethylbenzene
Chloroethyl

187,218,233,236,

243,254,265,275,286,367,

- 681
- 487

- 357

Chlorododecane
Chloroethane

825

- 659

- 55, 254, 265

- 357,825,840,861

Chlorobutadiene

NaCI, NaOCl - 286


- 187
Chlorine trifluoride
- 275, 357, 737, 782, 812,

- 659

chloride

Chlorobenzyl

- 187
- 678
Chlorine monoxide - 737
Chlorine oxides - 678, 732

- 659

- 156

374,

802,806,812,825,882

Chlorine

782,

292, 293,

889

175,

243, 254,265,

151,
236,

247,

812,825,840,

782,825,846

149,

357,

357,

169,

147,

241,243,

487,

160,

143, 144,

299,
243,254,

766,774,
154,

- 229

mono - 1, 11, 18, 28, 33, 34, 37,

154, 156,

396, 401,408,

221,236,

394,

dry - 149,

187, 236,

- 187

- 34, 48, 53, 62, 109, 160, 169,

388,

acid

38, 43, 48, 53, 55, 60, 63, 66, 74, 83, 103,

677,728,758,789,792,840,849,860
Chlorine

797,

860
Chloroacrylic

wax

849,

- 156, 177, 357, 659, 825,840,

Chloroacetone

780
Chlorinated

659, 676,
782, 783,

380,

889

- 187

hoods

34, 35, 37, 74,221,

Chlorine

651,
779,

802,806,812,825,

639,825,860

306, 309,

Chloroform
Chlorohydric

- 188
- 825

alkaloids
acid

Corrosive

- 254, 659

Chlorohydrin

156, 157,

Chloromethonic

ester - 659

4Chloromethyl

phenoxyacetic

Chloro-P-methyl

quinone

acid

- 678

- 488
- 376, 380, 401, 408, 659,

Chloronaphthalene
678,825

158,

161, 169,

171,

175, 188, 218,

225, 236,

240, 243,

247,

254,

265, 275,

286,

299,

305, 308,

311,

314,

357, 369,

302,

371,

373,

374,

376,

380, 385,

387,

388, 389,

392,

393,

396,

397,

398, 401,

408,

424, 435,

615,

632,

639,

642,

644,

663, 726,

728,

732,

735, 737,

646,

- 376, 380, 615, 659


- 357,825
I-Chloro-I-nitropropane
- 254

Index

221,

441,489,

- 230, 357,812

a-Chloronaphthalene

Material

490,

651, 660,

645,

Chloronitrobenzene

750, 758,

766,

774, 779,

782,

787, 798, 802,

I-Chloro-I-nitroethane

806,

825,

840, 846,

849,

854,

Chloropentane

Chromic

acetic acid - 659

383,488,659,663,

Chromic

- 254, 663
- 254, 265, 489, 679, 738, 842
- 825

Chromic

acid, with

Chloropicrin

Chromic

chloride

Chloropropane

- 1, 230,

Chloropropylene
Chloroquinine

292

- 659

Chlorosilanes

- 659

Chlorosulfonic

acid

- 28, 40, 48, 55, 63, 74,

112,

114, 126,

149,

161,

171, 175,

188, 218, 247,

153,

275,

156, 157,

299,

302,

305,

308,

393, 401, 408,

435,

659, 679,

779, 782,

795, 812,

787,

158,

254,265,

311, 314,

357,

737, 758,

825, 840,

846,

acid and 50% sulfur trioxide

659

- 37, 40, 188, 789,812,840

Chlorothene
Chlorotoluene

a-Chlorotoluene

sulfonic

- 489,

659, 825

- 787

Chloroxylenols

- 659

- 660

Chloroxylols
Chocolate

- 660
- 188

chloride

Chromates
Chrome

oxide

Chromium

plating solution

bath - 189

fixing

- 615

153,

161,

188,

364,

368, 394,

- 30, 58, 85, 115, 135,

195, 254, 259,

269, 280,

395,

737,

647,

732,

357,

750, 780,

Chromium

plating solution,

Chromium

potassium
114,

252, 263,
679,

vapor

sulfate
126,

275,

149,

355,

- 188

(chrome
152,

alum) - 19,
154,

357, 401,

171, 189,

408,

555,

788,826,849,861

Chromium

salts

Chromium

sulfate

Cinene
Cineol

(see Limonene)

- 233

Cinnamon

- 226
- 106, 227

Cinnamon

oil (see Essential oils)

Cinnamaldehyde

860
Cholesterol
Choline

66C

788,840,861

- 615, 788
syrup - 14, 22, 126, 238, 275, 840,

Chocolate

- 188, 189, 726, 737

408,

- 67, 275
- 48, 161, 189, 615, 660
Chromium trioxide - 152, 254, 609, 615, 826
Chromous sulfate - 108, 189
Chromyl chloride - 218, 254, 660
Cider - 65, 114, 126, 156, 275, 382, 615, 651,

acid - 659

- 659

Chlorotrifluoroethylene
acid

hardening

Chromium

615,660,

chloride)

- 188, 275, 357

o-Chlorotoluene

Chlorous

Chromium

232,

(see Benzyl

Chlorotoluidine

other acids

- 393, 401,

fluoride

28, 54, 106,

- 659, 861

Chlorotoluene

175, 188,

818,834,861,884,885,891

849,854,886,889
Chlorosulfonic

155,

- 660
Chromic hydroxide - 660
Chromicoat
- 826
Chromic oxide - 188, 357
Chromic phosphate - 660
Chromic sulfate - 435, 660, 679, 758
Chromium - 615, 790
Chromic

- 822, 825
oxide - 825

a-Chloropropylene

acid - 114,

acid, sulfuric

225,233,286,849

678,842,861

2-Chloro-4-phenylphenol
Chloroprene

- 424, 645, 679, 737, 740,

acid, boiling

766,779,854

- 40, 74, 175, 241, 247, 357,

Chlorophenol

882, 884,

886,889,891

(see Amy1 chloride)

Chlorophenohydroxy

812,

- 663

Circa light process oil - 291,

acid evaporator

- 188

Chrome

alum (see Chromium

Chrome

ammonium

Chrome

anodizing

solution

Chrome

reduction

process

Chrome

tanning

Circosol
potassium

alum (sulfate)

solution

sulfate)

- 826

- 188
- 188

2XH

Citgo oils and fluids


Citraconic
Citrate

357, 826

- 291

anhydride

- 275, 280, 817


- 233

process for SO* removal

- 189

Citric acid - 1, 2, 4, 10, 17, 26, 28, 33, 34, 36, 37,

- 726

48, 53, 55, 69, 61, 63, 65, 67, 75, 95, 104, 106,

- 1, 2, 6, 10, 17, 28, 33, 34, 35,

111,

114, 117,

118, 121,

126,

143,

37, 48, 53, 55, 60, 63, 65, 67, 75, 95, 104,

151,

153, 154,

156,

161,

171,

189, 218, 221,

106,

118,

225,

236, 238,

239, 243,

254,

265, 275,

155,

303,

306,309,312,314,357,

Chromicacid

108, 109,

126, 143,

147,

112, 113,
149,

114, 117,

151, 152,

154,

147, 149,

368,369,371,

299,

975

916

Corrosion

Resistant

385,

387, 388,

396,

398, 401,

609,

615,

Handbook

- 373, 374, 376, 380, 382,

Citric acid (contd)


384,

Materials

389,

392,

408,421,432,

632, 642,

646, 651,

393,

394,

395,

435,

441,

490,

660,

679, 726,

Cod liveroil
227,
Coffee

- 1, 62, 106,

126,

- 104, 105,

106,

357,382,491,

616,

126,
651,

Citric acid, ammoniated

- 14, 22
- 227
Coffee, powder - 227
Coffee roasting fumes - 189

Citric

Cognac - 106

728,

732, 735,

737,

750,

758, 766,

774,

779,

Coffee

grounds

782,

787, 812,

826,

840,

846,849,

854,

886,

Coffee,

liquid

889,891

- 822
- 420, 444, 647, 679, 741, 750,

acid, boiling

Coke

779,854
Citric,

- 840, 861, 872


- 840
Citrondropar
(lemon) - 126

Cola drinks

Citroflex

Collodion

- 864

Elba Lyn

- 875

Cologne

spirits

Clarifier

Cologne

sticks

Pub

juice

liquid - 679

- 615

Columbium
615,861

Cleaner 508 - 189

- 732

Cleaning

solution

Cleaning

solution,

food grade acid

- 840

- 22
Lighthouse - 22
Old Dutch - 23
Sano-Genio - 23
Clorox ~2, 14, 102, 126, 155, 233, 275, 307,
Clove oil (see Essential oils)

- 615
- 53

Coal dust scrubber

- 275, 594,595,
water

Cobalt

- 790

Cobalt

acetate

reducible

596,

615,789,861

chloride

compounds

Cobalt,
Cobalt

phosphate

- 812, 834

- 189
660

Coca-Cola

syrup (see Foods, soft drink

Cocamidopropyl

betaine

Cocamidopropyl

dimethylamine

Coconut
161,

fatty
oil

syrup)

- 189

- 189

- 106

acid diethanolamide

- 189

- 28, 48, 55, 60, 62, 126, 143, 156,

189, 218,

227, 254,

265,

357,

368,

oil alcohols,

towers,

Copper

- 790

Copper

acetate

water - 189

derivatives

- 156,

171,

189, 357,

376,

380,

728,777,826,861

Copper

ammonium

Copper

arsenate

chloride

(also see Cuprous,


106,

108,

113,

cupric)

114, 118,

- 28, 33,

152,

154,

156,

161,

171,

188, 218, 236,

243, 254,

275,

299,

357,

373,

374,

376,

380,

388, 389,

393,

397,

398, 401,

408,

491, 492,

651, 660,

679,

735, 777,

788, 798, 802,

806, 826,

392,

Copper

chloride,

Copper

cleaner,

782,

- 114, 849

silver nitrate
Copper

265,

compounds
cyanide

151,

Brite

- 189

- 148

- 616
- 28, 48, 55, 60, 75, 114, 118,

Copper
Copper

154,

161,

171,

189, 218,

357, 392,

393,

397,

398,

798, 802,

806,

826, 840,

782,

616, 788,826,840,861,872
Coconut

oil

840,861,882,886,889

- 143,227,812,861

Cocoa, chocolate

liquor - 679

- 228
- 357,861
Coolant brines - 376, 380
Cooling tower inhibitor - 188, 189
Cooking

48,55,67,

sulfate - 491,

Coconut

Cooking

735,777,861

Cobaltous

Cocoa butter

types

Copper

and tri-m-

- 189

nickel plating solution


nitrate

Condor

acetate - 861
- 67, 156, 274, 826
Copper carbonate - 55, 154, 156, 254, 265, 728,

Cobalt di(2-ethylhexyl)phosphate
butyl

1008

393,401,408,

- 189

- 357, 826, 861


- 616

Cobalt

- 491

- 861
- 812
Conoco fluids - 282, 819
Convelex 10 - 357,861
Condor

- 616, 663
Copal varnish - 861

- 491

Cobalt

- 106, 156

- 616

Copal

Coal water slurry - 189


Coatings,

oil

Cooling

- 189

Coal gas (see Gas, coal)


Coal tar

gases - 189

Compressor

Coolanol

310,313,316,357,812,825,840,860,861

Coal dust, moist

- 491

Condiments

Bon ami

- 826
- 14, 22

Combustion
Concrete

Cleanser

Coal

238, 289,

Cologne

(see Essential oils)

Clay slurry - 189, 490,

143, 227,
782,788,861

- 227, 228, 788, 861, 874


- 616

- 382, 615, 788


Citrus pectin liquor - 840, 861

Clay

189,

- 616

Citric oils

Citrus fruit,

156,

Coke oven gas (see Gas, coke oven)

lactic acids - 189

Citronella

143,

357,616,663,812,826,840,861,872

889

254, 265,

679, 735,
861,

275,

766, 777,
882, 886,

Corrosive

Copper

electrolytic

Copper

extractant

Copper

fluoride

Cosmetics

cells - 189, 766

- 493,

Avon

- 189

- 28, 48, 55, 75, 114, 118, 154,

cream

Bath oil, bubble

Cologne

leach tanks
matte

Copper

nicotinate

Copper

nitrate

- 189

dipping

bath

- 48, 109, 161, 189

- 22
- 22

- 14, 23
- 14

Bath oil, pine

Bath salts, Coty

Copper

- 864
- 875
sticks - 14, 22
Elba Lyn

- 492

Pub

- 28, 33,48,

55, 75, 108,

113,

114,

118, 152,

154,

156,

161, 171,

189, 221,

Hair dressing

236,

244,

265, 275,

373, 374,

376,

380,

388,

389, 393,

398, 401,

408, 435,

651,

735,

737,

774,

782,

798,

- 14, 22
- 15, 23
Wildroot
- 15, 23
Hair solutions
- 841, 867

245,

397,

758, 766,

777,

788,

802,806,826,861,882,886,889
Copper

oxide

- 231

Copper

oxide,

dust

Copper

oxide,

red - 1, 232

Copper

oxychloride

Copper

pellet

Copper

153,

154,

161,

refining

cells

189, 190, 259,

Lady

269,

salts

Copper

smelter

Copper

sulfate

fumes

Esther

- 14, 22

- 23

Perfume

Cadenza - 859
Perfume alcohol 5DA40

- 190

- 127, 149, 357, 367, 646, 732, 861


Copper silver nitrate - 774
Copper slimes - 384
Copper

lotion

- 867
Hinds - 14, 22
Nivea - 872
Lipstick
- 144
Coty - 14, 22

368,834,843,859,861,884,885,891
Copper

cream,

Grace

smelter

135, 150,

Brilliantine

Vitalis

Hand
- 189

- 189
- 189
pickling
bath - 48, 161, 189, 190
plating solution
- 30, 48, 58, 85, 115,

Copper

- 190, 679

- 19, 28, 33, 34, 36, 37, 48, 55,

- 226
- 874
Powder base cream, Max Factor - 14
Sachet powder - 26
Shampoo,
baby - 232
Shampoo,
liquid - 207, 235
Polyderm

moisturizer

60,65,67,75,

106,

113,

114,

118,

121,

127,

Shave cream

143, 151, 152,

154,

156, 161,

171,

175,

190,

Talcum

powder,

218,

236,

244,

254,

265, 275,

Waving

lotion

221, 231,

Index

616
cake

161, 189,218,254,265
Copper fluoroborate
- 370, 372, 492, 840
Copper

Material

247,

lotion

- 14, 626, 876


Marie

Earle

- 14, 22

- 493

Toni - 15, 23
- 376, 380
oil - 6, 7, 28, 48, 55, 60, 67, 75, 104,

Richard

Hudnut,

291,

293, 299,

357, 367,

373,

374,

376,

380,

388,

389, 392,

393.

394,

395,

396,

397,

398,

Cottage

401,

408, 435,

492,

493,

609,

632,

651,

679,

Cottonseed

680,

726, 735,

737,

758,

766,

774,

777,

782,

113,

143,

147,

149,

154,

788,

796, 798, 802,

806,

826,

840,

846,

861,

190, 218,

233,

247,

254,

265,

275, 291,

293,

299,

307,

310,

313,

316,

357, 368,

376,

380, 392, 441,

616,

651, 728,

788,812,

826,

882,886,889
Copper

sulfate,

Copper

sulfate-sulfuric

737,

- 67, 824
acid - 190, 384, 416,

Core oils

oil

Cream

- 28, 127, 156, 728

- 663
- 227, 616,840,

Creosote

- 616

156, 161,

190, 218,

227,

372,392,

616, 651,788,812,826,

254, 275,

291,

143,

293,

840,862,872
oil, Mazola

- 102, 228, 238

- 48, 161, 190, 632, 680, 788


Cornstarch
slurry - 861
Corn sugar - 161, 190
Corn syrup - 55, 61, 149, 154, 171, 190, 265, 382,
Cornstarch

616,812,826

- 131, 238, 278


sublimate
- 826

Corn syrup,

Karo

862

- 15, 24, 63, 67, 75, 127, 156, 275, 299,

357,
oil) - 1, 48, 60, 67, 118, 127,

357,370,

Corrosive

304,

156, 161,

Coumarin

- 812

Corn oil (maize

Corn

114, 117,

840,849,862,872

774,782

Cordage
Cork

basic

cheese

393, 398,

493,

651,

660,

680, 782, 789,

812,826,840,872
Creosote,

coal tar - 156, 357, 862

Creosote,

wood

- 357

Cresal

- 127

Cresol

(methylphenol)

- 28, 37, 40, 55, 63, 65, 75,

106, 113,

114,

127,

149,

151,

154, 190, 218,

241, 247,

254,

265,

275,

357,

376,

380, 401,

408,

616,

660,

663, 789, 812,

826, 840,

493,

849,862
Cresol, fumes
Cresol,
Cresolic

xylene

- 190, 201

- 156
- 233

solution

compounds

977

918

Corrosion

Resistant

Materials

Handbook

Cresyl alcohol - 826


Cresyldiphenyl
phosphate - 75, 241, 247, 862
Cresylic acid - 28, 55, 63, 67, 75, 114, 149, 154,
156, 161, 171, 190, 218,254,
265,291,
357,
369, 37 1, 392, 393, 397, 493, 616, 660, 680,
782, 787, 798, 802, 806, 826, 840, 849, 854,
882,886,889
Cresylic acid, fumes - 190
Crisco - 227
Crotonaldehyde
- 28, 55, 149, 154, 218, 254, 265,
494, 660, 789,862
Crotonic acid - 660
Crude oil - 28, 33, 38, 55, 62, 66, 75, 84, 85, 147,
149, 154, 155, 156, 184, 190, 203, 218,247,
254, 265, 275, 288, 357, 364, 373, 374, 376,
377, 380, 381, 396, 537, 623, 651, 680, 728,
738,817,826,862,872
Crude oil, refined - 57, 66, 145, 156, 268, 632
Crude oil, sour - 13, 22, 38, 48, 50, 51, 57, 58,
62, 135, 150, 151, 154, 156, 161, 165, 166,
169, 171, 190, 203, 210, 219, 261, 268, 285,
286, 632, 762,852
Crude oil, sweet 48, 50, 135, 161, 165, 169, 171,
190,203,
214,537
Crude oil, tank bottoms - 190, 203
Crude oil with sulfur - 439
Crude oil, waste - 203
Cryolite - 156, 616, 812, 826
Cryscoat products - 826
Crystal ammonia - 826
Cumenaldehyde
- 660
Cumene (isopropylbenzene)
- 357, 494, 616, 660,
663, 680,789,812,826,862
Cumene
Cupric

- 660, 680

hydroperoxide

- 812

arsenate

Currants

(black

Cutback

diluent,

Cutting
Cyaf

5101

Cyanic
Cyanides

Cyanoacetic

- 663, 862
acid - 254, 660, 766

Cyanoacetic:methyl
Cyanogen
Cyanogen

chloride

441,

644,

645, 680,

735,

Cyanuric

chloride,

Cycleweld

chloride,

boiling

Cupric

chloride-sodium

Cupric

cyanide

fluorinated

Cyclohexane
ene)

- 190

ether

(see Fluorinated

cycle

(hexahydrobenzene,

hexamethyl-

- 40, 48, 53, 55, 63, 65, 75, 106, 113,

127, 147,

156,

157,

171,

190,218,

226, 241,

247,

254, 265,

275,

286,

299, 304,

315,

370,

372,

376, 380,

766, 789, 812,

826, 840,

307,

309, 312,

616,

646,

161, 169,
357,

660, 737,

849,862
Cyclohexanol

- 1, 28, 33, 55, 63, 65, 75, 112,

114, 118,

127,

143, 149,

171, 218,

225,

240,

370,

151,

153,

247, 254,

113,

154, 156,

265, 275,

357,

372, 660,826,862

Cyclohexanol

- 660

esters

Cyclohexanone

(pimelic

ketone)

40, 55, 63, 65, 75, 103, 106,

- 1, 11, 18, 28,


114,

118,

127,

147, 149,

151,

153,

156,

157,

161,

190, 218,

230, 241,

247,

254,

265,

275,

286,

357, 370,

376,380,

737,

750,

Cycle-octadiene

- 40, 226, 660, 737, 788, 862


hydrochloride

- 190

- 190
- 660

Cyclopentane
Cygon

660,813,826,849,862

- 106, 660

Cyclohexylamine

- 190

p-Cymene

- 127, 435, 660, 737, 750, 759,

scrubber

ether)

385,

- 424, 645, 737


chloride - 644

caustic

- 862

L808

314,

766,774,812,826,846,862
Cupric

- 175, 680

Cyanuric
Cyclic

- 190
862

acid

Cyclohexylamine

392, 424,

782,789,

- 175, 190
chloride - 680

Cyanuric

Cyclohexene

308, 311,

isobutylketone

- 156, 660,

carbonate-cupric

306,

371, 372,

- 660
- 75, 787,840

acid

chloride

303,

357,

- 190

Cyanamide

Cupric

254,

- 190

271, 283,

812,840,843,844,862,873,878

Cupric

221, 231,

refinery

oil - 59, 262,

372,

hydroxide
- 737, 766
- 34, 60, 63, 75, 127, 147, 175,

- 616

and red)

- 156,233,

275,

357,

616,813,826,830,

873

766,812,826
Cupric

fluoride

Cupric

nitrate

- 55, 127, 154, 171, 265


_ 127, 441, 647, 680, 750, 777,

812,826,862
Cupric

salts - 849

Cupric

sulfate

231, 265,

303,

492,493,

766,812,826

Cupric
Cuprous

chloride

127,
Cuprous

Cuprous

306,

sulfate-ferric
ammonia

(herbicide)

Dairy

EEZ

Dairy

products

- 15, 24, 156, 161, 616, 796

- 862
- 616

Dane Head radiator

- 12, 55, 63, 67, 127, 154, 156,

Cuprous

2,4-D

308,

311, 314,

acid - 190

- 862

Dasco products

- 26

- 275,813

152, 154,221,265,680,737,766,

DBP

- 826

DC 200,510,550,560

- 12, 19, 55, 106, 114, 118,

oxide - 231
salts - 849

seal

- 190,840

Dazad - 190

sulfate-sulfuric
acetate

385, 441,

Darax

774

DDT-

15,53,

- 813

65, 127, 190,233,

660,862
DDT

and kerosene

- 156, 826, 862

275,495,

616,

Corrosive Material

Decahydronaphthalene
127, 143,

- 28, 63, 106, 118,

(Decalin)

- 357,826,862
- 190, 225, 826

Decane
Decanol

Dechlorinated

Oakite

Rinse Dry

cleaner - 15, 23

- 316-336

Servac - 15, 23

(see Decanol)

Skip-

- 840
Dehydroacetic
acid - 225
Denatured alcohol - 275, 291, 293, 358, 813, 826,
80

110

Stanley
Temp
Tide

- 15, 23

floor cleaner
cleaner - 15, 23

- 15, 23, 307, 310, 313, 316-336,

337-354,

495

862
Dental

- 14, 131, 234


- 14, 23

creams

Dentrifice,

- 15, 23,840

Deodorants,

powder

Desalination

sea water

Descaling agent
Desulfurizer
Detergent

- 233
- 813
Dextrin - 28, 55, 113, 114, 127, 149, 153, 154,

- 207

Dexoxyn
Dexron

- 254, 265

hydrochloride

SOZ

2 18, 265, 275,

- 190

Dextron

general - 1, 5, 6, 7, 28, 33, 55, 63, 76,

95, 106,

107,

114, 127,

171, 185,

130, 143,

149, 154,

265,

681, 788,849

- 191

DFR-121

265,

275,

Diacetic

313,

316, 317,

318,

Diacetone

325, 326,

327,

190, 203,

233, 247,

307, 310,

289, 296,

304,

319, 320,

321, 322,

323,

324,

328, 329,

330, 331,

332,

333, 334,

358, 432,

495,

646, 743,

616,

- 10, 17, 143,

335,

336,

Diacetone

849,

254,

- 190

Dialkyl

household

- 52, 130, 304, 307, 310,

Diallylphthalate

293,

370,

372, 616, 813,

- 826

317,

318,

319, 320,

321,

322,

Diamine

323, 324,

325,

326,

327, 328, 329,

330,

Diaminoethane

331,332,

333,

334,335,

336,495

-5

Acclaim

- 232

- 22
Calgonite - 5, 52, 102, 304, 307, 310, 313,
Axion

diamine)

- 48, 65, 161, 191,275

- 862

Diamyl

naphthalene

Diamyl

phenol

Diamyl

phthalate

- 156

- 156
- 156

- 276, 358
Diazo saits - 28, 114, 127, 149, 154, 255, 265, 849

Cascade - 187
Cleaner, all purpose, liquid
Dishwashing liquid - 192

- 185

- 14, 22

- 660

Dibenzyl

ether

Dibenzyl
biodegradable

- 190

- 5, 162, 192

- 103, 291, 304, 306, 309, 312, 315,

sebacate

Dibromoethane

- 14,22

(see Ethylene
benzene

Dibrombmethane

- 22

- 14,22,233,304,

- 316-336
Lux liquid - 373, 374

dibromide)

- 358, 862

(see Methylene

bromide)

- 48, 161, 191


1,2-Dibromopropane
- 255
Dibutoxyethyl
phthalate - 255, 265
Dibutylamine
- 226, 358, 826, 863
Dibutyl Cellosolve adipate - 862
Dibutyl ether (butyl ether) - 48, 73, 156, 161, 175,
Dibromophenol

- 2, 5, 131, 198
- 105

Lestoil - 102, 234, 304,

- 358,862
- 840, 862

Dibromochloropropane
Dibromoethyl

Fab - 495
Andy

Dibenzyl

358,813,826,840,862

- 19

Dishwashing,

Lux flakes

(see Ethylene
phosphate

Diazinon

316

Electrosol

Diammonium
Diamylamine

Ajax with ammonia

lgepal

291,

- 660
- 33, 161, 171, 191

sulfates

313, 316,

Ivory

789, 813,

826,839,848,856,862
germicidal

Handy

358,

- 54, 76, 127, 156, 218, 225,

alcohol

263, 275,

Detergents,

Glim

156, 230,

826,862

Detergents,

Dicrobe

- 826

acid, ester

788, 840,

862,879

Dreft

788,849

- 275, 358
Dextrose - 28, 55, 113, 114, 127, 149, 154, 254,

- 190

alcohols - 190

Detergents,

- 51, 167, 190, 211, 270, 711


- 48, 109, 161, 191, 211
solution (copy machine) - 840
sulfated

sulfonated

Developing

- 15, 23

feed, refinery

Desulfurizing

- 23

Detergents,

- 16, 25

Desoxyephedrine

157,

Wisk

Detergents,

liquid

Deodorants

Joy

- 190, 204

Rad household

- 840

Dehydratine

- 153, 203, 872

Pax Hyspeed

brine - 190

- 15, 23, 26
Dectol R&O oils - 275, 813
Decyl alcohol

- 495

oz - 495

Decongestant

Degreaser

- 23, 234

Mr. Clean
Nytron

156,233,275,357,813,826,862

Index

307,310,313,316
316-336

186, 191, 230,

241, 247,

813,824,826,840,842,859,863

293,

356,

358, 811,

979

920

Corrosion Resistant Materials Handbook

Diethylene

glycol monoalkyl

(Carbitol
Dibutyl

ether acetate

Dichromate

- 827

acetate)

phosphite

- 789

phthalate

- 60, 63, 76, 108, 112, 114,

153, 156,

157, 171,

265,

276,

291, 293,

175,

299,

191,227,255,

358, 392,

393,

660,

789,813,826,863
Dibutyl

118,155,156,

- 7, 104, 117, 143, 156, 157,

sebacate

197, 227,

255,

265, 291,

293, 303,

306,

thioglycolate

Dibutyl

thiourea

309,

Dibutyltin

dichloride
phosphate

389,616,

171,191,

255,388,

- 41, 44, 45,48,

161, 171,

175,

660,681,737,813.826,863

244,

265,

276,

Diethyl

388,

45, 60, 143, 203,230,

255, 292,

363,

392,

663,789,842,873
Dichlorobenzene,
363,663,

- 11, 18, 143, 230,358,

789,873

- 34, 358, 863


ether - 18

Dichlorobutane
Dichlorodiethyl

Dichlorodifluoromethane

681,

782, 789,

798,802,

806,
380,

191,218,

789,813,
157,

827

161, 191,

- 55, 218, 265


- 103

Diethyleneamine

triamine

Cellosolve

- 193

- 230

Diethylene

dichloride

Diethylene

dioxide

Diethylene

glycol - I, 10, 17, 48, 63, 76, 108, 109,


128,

(see Dioxane)
143, 156,

162, 171,

175, 191,

380,617,660,663,789,813,

827,840,849,863
glycol dialkyl

383,488,

Diethylene

glycol

Diethylene

glycol monobutyl

826, 846,

863,

399,406,

660,

160,

- 827

ether

monoalkyl

- 827

ether (Carbitols)
ether (butyl

186, 191,233,

291,293,

Carbitol)

304,

306,309,312,315,356,400,407,811,824,
827,859

884

- 48, 55, 65, 76, 128, 156, 161,

Dichloroethylene

- 863

Dichlorohexylamine

Diethylene

- 663

Dichlorohydrin
Dichloroisopropyl

- 358,827

(see Methylene

Dichloromonofluoromethane

Diethylene

(see also Freon)

- 39,41,43,46,

191,488,

489,

681

- 41
- 191, 676
- 674

acid

Dichlorophenoxybutyl

acetate

acid

Dichloropropane

- 161, 191
- 161, 191

Dichloropropionic

Dichlorotetrafluoromethane
156

- 663

(see Tetrahydrofuran)

- 33, 37, 171, 191, 218, 226,

ether (ethyl

ether)

- 1, 7, 11, 18,28,

114,118,

128, 129,

162,171,

175,

157,

230, 236,

239,

143, 147,

176, 191,

193,

244, 255,265,276,286,

321, 322,

323,

331,

332, 333,

359,370,

372,

373,

392,393,394,395,

- 827

324,325,

329, 330,

646, 660,681,
(see also Freon)

33,

67, 76, 77, 95, 104,

153, 154,

320,

- 191, 255

Dichlorotetrafluoroethane

oxide

- 191

299,304,306,309,312,315,317,318,319,

- 175

Dichlorophthalic
Dichloropropene

oxide

106, 112,113,
218,

Dichlorophenoxyacetic

ether - 11

glycol monomethyl

37, 48, 52, 55, 60, 63,65,

- 789,863

2,4-Dichlorophenol

Dichromates

- 11,

ether (Carbitol)

255,376,380,737,863
Diethyl

Dichlorophanol

monoethyl

Diethylenetriamine

chloride)

156,681
Dichloropentane

glycol

Diethyleneimide

ether

Dichloromethane

678,

Diethylene

147,233,264,304,357,659,825,860

191,255,265,276

663,

Diethyleneamine

11, 108,
- 191, 376,

128, 156,

Diethylene

882
Dichloroethene

-41,

- 660

(DDD)
191, 292,

161, 175,

617, 660,798,802,

- 161, 191,358,663,

carbonate

113, 114,

(see Freon)

- 40,76,

1,2-Dichloroethane

156,

358,

- 660, 663,863

229,358,376,

Dichlorodiphenyldichloroethane

276,

233,863
Diethyl

- 11, 18, 33, 37,41,42,43,

128, 161,

660,663,782,

806,813,827,849,863,882

55, 76, 156,

389,616,

Dichlorobenzene,

- 41, 55,76,

Diethylbenzene

191,236,

- 840,863,872

255,276,617,

265,

Diethylaniline

- 191

Dichlorobenzene

Lub. oil

226,

226, 255,

750,766

2,6-DichloroGaniline

358,376,

788,863

- 191, 236,244,

acid

291,

- 1, 65, 76, 108, 109,

Diethylamine

- 171, 191

737,

172,191,218,241,

380,632,789,813,827,840,849,863,884
Diethanolamine

- 175, 480
- 171, 191

Dichloroactaldehyde

171,

284,286,

Diester synthetic

- 660

- 660

Dicalcium

161,

247,255,265,276,

312,315,358,813,863
Dibutyl

Dichloroacetic

chloride - 191
- 358,827
Dicyclopentadiene
- 191
Dicyclopentenyl
alcohol - 617
Diesel fuel - 28, 33, 41,48,
55, 63, 76, 106, 108,
ammonium

Dicyclohexylamine

127,

Dibutyl

seal - 891

Dicocodimethyl

formamide

Diethyl

glycol

397,398,

401,

- 191,863

- 276
adipate

358,

380, 385,389,

782,789,792,813,827,841,

Diethyl

Di-2-ethylhexyl

326, 327,328,
335,336,

374, 376,

850,863,865

334,

- 17

408,

617,

34,

Corrosion Resistant Materials Handbook

Diethylhexylphosphoric
phthalate

Di-2-ethylhexyl

sebacate

Dimethylaniline

- 104

- 287, 288

ketone-

1, 143,

153, 156,

171,

175,

191,

230

N-alkyl

Dimethylbutane

- 356

carbinol

maleate

Diethyl

malonate

- 191,863

Diethyl

oxalate

Diethyl

oxide

Diethyl

phthalate

Diethyl

sebacate

Dimethyl

- 827
ether)

ammonium

ether (methyl

660,728,

(see Diethyl

- 156, 299, 358, 813, 827, 840,863

- 34, 108, 162, 191, 681, 789, 863


- 233
Difluorodibromomethane
- 358
Difluoroethane
- 660
Digallic acid - 827
sulfate

N,N-Diethyl-m-toluidine

- 4, 7, 28, 37, 41, 63, 76, 95,

117,

118, 128,

157,

218,

226, 239,

241, 248,

255, 265,

376,380,
265,617,

(also see UDMH)

681,
ketone

Dimethyl

methane

Dimethyl

morpholine

Diglycolamine

2,4-Dimethylpentane

Diglycolic

Dimethyl

- 191

tallow

p-Dihydroxybenzene

ether

Dihydroxydiphenylsulfone
Dihydroxysuccinic
Diiodomethane
Diisobutyl

adipate

- 255

Dimethylterephthalate

acid)

iodide)

Dinitrobutylphenol

Diisobutyl

and aromatics

ketone

- 192
- 782,863,864

(DNCB)

- 358, 827, 840,863


- 156, 293
Dioctylphosphate
- 65, 276
Dinitrotoluene

- 291

- 156, 175, 191,218,

- 617, 864

in acid waste

Dinitrochlorobenzene

255,291,358,813,863
Diisobutylene

(DMT)

- 376,380

Dinitrobenzene

- 157
- 76, 156, 162, 191, 218, 248,

Diisobutylene

358, 370,

sulfate

Dimethyl

aniline)

(see Methylene

- 660

248, 255,

- 41
- 233, 255, 617
sulfoxide - 76, 158, 192, 241, 248, 863

Dimethyl

acid (see Tartaric

Diisobutyl

- 41, 48, 76, 143, 156, 162,

192, 218, 227,

Dimethylpropanolamine

- 827
- 660

Di-P-(3,4-dihydroxyphenol

- 162, 192
- 363

372,789,813,863

(see Hydroquinone)

Dihydroxydiethyl

(see Propane)

phthalate
175,

- 55, 157,

(see Acetone)

vapors - 191

Dihydrogenated

192,

- 230

2,6-Dimethyl-4-heptanone

171,

171,

296, 358,

784

- 191

265,369,371,660

162,

617,813,827,863

Dimethylhydrazine

Dimethyl

- 192

- 128, 156, 157,

106,

Digester blow-down

- 191
acid - 28, 55, 114, 149, 154, 218, 255,

chloride

ether)

104,

Digester

room spills

alcohol)

766,813,827,842,870

Dimethylformamide

- 156, 370, 372, 813

- 191

- 526

Dimethyldistearyl

- 255, 681

detergents

(see Isopropyl

Dimethylchloroacetyl

Diethyl

Diethyl

(see Xylene)

Dimethylbenzyl
Dimethyl

- 681

hydrochloride

Dimethylbenzene

- 863

Diethylhydrazine
Diethyl

- 162, 191

acid

Di-2-ethylhexyl

255,

Dioctyl

adipate

Dioctyl

phthalate

114, 118,
248,

813,863

- 108, 109, 162, 191


- 863
Diisooctyl
phthalate - 128, 358
Diisopropanolamine
- 162, 191
Diisopropylbenzene
- 358,827,
863

- 17, 28, 55, 63, 65, 76, 113,

128,

147,

149,

154, 156,

162,

255, 266,

291,

293,

299,

306, 309,

303,

192,

Diisobutyl

phthalate

312,

315, 317,

318,

319, 320,

321,

322,

323,

Diisobutyl

sebacate

324,

325,

326,

327,

328, 329,

330,

331,

332,

333,

334,

335,

336,

358, 617, 813,

827,

849,

Diisopropyl

ether (isopropyl

56, 60,81,
277,

131,

300,

360,

147,
385,

156,

ether)

863
Dioctyl

- 11, 18, 42,

176, 237,

388, 389, 402,

244,267,
409,

789,

815,827,851,868
Diisopropyl

ketone

- 11, 18, 156, 358,813,827,

Dimethanolamine
Dimethoxybutane

- 255
- 526

Dimethylacetamide
154,

- 28, 55, 114, 128, 149, 153,

358,

Dioxolane

13,827,863

248,255,

128,
266,

660,766,789,813,827,863

- 358,827,863
- 358,789,813,827,863
(biphenyl)

376,

380,

(phenylbenzene)
617,

660,

663, 789,

- 76, 358,
798,

802,

- 226,547,
660, 663, 681
- 547
Diphenylchloride
- 660
Diphenylene
oxide - 660
Diphenylenimine
- 226
Diphenyl ether (oxide) - 76, 171, 177, 192, 231.
Diphenylamine

Diphenylcarbonate

- 377.381,403,

- 376,380
- 76, 156, 218, 233, 240, 248,

Dimethylaminoethanol
255,358,8

276,286,

233,241,

806,827,863,874,882

410
Dimethylaniline

- 11, 20, 37, 55, 63, 77, 106,


192, 218,

364,

- 191,255

benzophenone

- 156, 286, 358, 813, 827, 840,

156, 157,

Diphenyl

171,218,255,265

p-Dimethylamino

1,4-Dioxane

Dipentene

840,863

Dimethylamine

sebacate

863

248,

255,358,

376,

380, 624,

663,827,840,863

921

922

Corrosion Resistant Materials Handbook

Diphenylmethane

- 663

Diphenylmethane

diisocyanate

Diphenyl

oxide

(see Diphenyl

Dipping

286,291,299,358,789,813,827,864
Drain cleaner - 192

ether)

- 660

Diphenylpropane

Drain cleaner,

- 827

acid

Dipropylene

- 33, 48, 76, 162, 171, 192,

glycol

Drewsperse

Dipropylene

- 192
- 255

dibenzoate

glycol methyl

Dipropyl

phthalate

Dirco oils

- 813

ether

Dry cell solution,

- 698

chlorinated

- 22

DTE

phenol - 192

- 14, 22, 104, 105, 728, 780, 831,869


Showersan - 25
Zephiran - 148
Lysol

Disinfectant
Disinfectant
Disodium
Disodium
149,

- 840, 863
methyl arsenate - 171
phosphate - 28, 50, 55, 113, 114, 128,
deodorant

152,

154, 166, 209,

255,

266, 788,

DXE

Distillery

syrup

Distilling

wort

Di-syston

- 192

Diversey

- 37
- 782, 841, 864

- 128
anodized

Dye plant water

treatment

liquor

DMP:MEK:MEK

- 161
peroxide

- 192

193, 682

- 192

EP 52-A65
EVA

- 103, 192
acid - 827
Dodecene - 108, 192
Dodecyl alcohol - 48, 161, 192

- 192,

- 827

EMK

- 128

acid

- 193

310,

Dodecanoic

Eggs

313,

316

- 617, 788
- 382

Egg yolk

- 358, 864

Elco 28-EP

lubricant

Electrolyte

- 681

- 156

Electrolyte

acid (see also Sulfuric

kiln gases, wet - 192

Electrolytic

sodium

Electronic,

electrical

Electronics

plant waste - 192

Dodecylbenzene

- 156

Dodecylbenzene

sulfonic

Dodecyltoluene

acid

- 192, 681

- 128

- 827

Douglas fir oil

- 827

- 37,255,256,864

- 358
- 358
ET 588 - 358

Electropolishing
Electrostatic
Elixis

ET 378

Elvase - 192

EC - 192

Embalming
Emulsifier

fluid

fluids

Enamels

- 276

surfactant

Energol

HL68

Energol

H LPC68

W-40 - 156,827

- 305, 308, 311, 313, 316, 358,858


Dow latex - 37
Dow Purifloc C-31 - 827

- 864

- 276, 827
- 276,827

Engravers acid (see Nitric


Ephedrine

hydrochloride

Ephedrine

sulfate

Epi

- 884
- 192

- 192, 646

Dowfax

- 233, 358, 359, 864


- 37
Dow fluid DP47, 200 - 276

parts - 729

solutions

Dow Corning
9N9

acid)

production

- 841

50-4

Dow Chemical
Dow Chemical

chlorate

precipitator

Dow Chemical

Dowfume

- 63, 238, 304, 307,

Edible fats and oils, general

Dodecane

Dowgard

- 780,782,864

- 37, 55, 156, 192, 255, 266,


EDTA

- 891

- 192

- 368

Dyestuffs

6 weed-killer

Dowclene

aluminum

Dye seal - 891

663,864

Dowanol

- 841, 864

base

Dye for coloring

Dyewood,

Divinylbenzene

Dolmite

- 841, 864

abrasive

844,

water

- 37

- 192

Dobanic

- 617

Dyanamite

- 192,203

stillage

- 192

- 192

Rit

Distillery

fluids

Dye - 495,496,617

849
Dispersants

- 233

light oil

DW-875

and cleaner - 192

and NH4CI

- 358, 663, 827,864


- 358
Duckseal sealant - 148
Dukes mixtures - 681
Duro oils - 276, 813
Dutch !i;uid, oil - 827
Drycleaning

Breath 0 Pine

MnOz

- 827

Drycid

Disinfectant

DOP

- 192

- 841
Drip oil - 156, 291, 864
Dromus oil - 842
Drinox

Dipropyleneglycol

Donax

- 148

acidic, Clobber

- 156

Drain oil

663

DMA

- 28, 77, 156, 233, 241, 248, 276,

Dowtherm
- 192

- 827

- 230

acid)

- 230

- 827

- 827
cell - 295

Corrosive Material Index

Epichlorohydrin
- 77, 128, 156, 162, 175, 192,
218, 241, 248, 255, 299, 358,488,
660, 678,
681,813,827,841,865
Epoxy hardener - 24
Epoxy resin - 24, 358
Epoxy spray liner - 192
Epsom salt (see Magnesium sulfate)
Eptam herbicide - 192
Erional NW - 192
Erythritol
- 496
Esam-6 fluid - 358
Essence of myrbane (see Nitrobenzene)
Essential oils - 13, 21, 67, 145, 234, 276, 617,
646,852
Almond oil - 122, 133, 182,227,
234,789
Anise seed oil - 232,234,
612, 839, 858,872
Bitter almonds - 13, 21
Borneol, 50% in butanol - 13
Cinnamon oil - 840,861,872
Citronella - 13, 21, 233, 663
Clove oil - 13, 126, 227, 234,840,
861,872
Eucalyptus - 13,21,
617
Ginger oil - 841, 867, 872
Lavender oil - 21, 361,831,
869
Lemon oil (flavor) - 13, 21
Lilac, artificial - 234
Menthol, 50% in butanol - 13
Nutmeg oil - 134, 228, 234
Palmarose - 13, 21
Pennyroyal
- 13,21
Peppermint
oil - 135,234,
623,843,872,874
Rose geranium - 234
Sandalwood
- 234
Sassafras oil - 228, 234
Spearmint - 13, 21, 234, 235
Sweet orange oil - 21
Terpineol - 14, 21, 150, 178, 271, 282, 365
Thyme - 14,21
Turpentine
(essential oil) - 14, 21
Vanilla - 21
Wintergreen
oil - 14, 21, 234
Esso fuel - 358
Esso oils and fluids - 358, 865
Esstic 42, 43 - 358
Ester gums - 617
Esterification
- 681
Esters - 36, 48, 116, 120, 149, 154, 218, 227,
241, 291, 293, 303, 306, 309, 312, 315, 432,
496,497,498,632,648,766,846
Esters, aliphatic - 646
Esters, fatty acid - 192
Etchant, fresh, spent - 193
Ethanal (see Acetaldehyde)
Ethane - 77,358,660,789,827,865
Ethane tetrachloride
(see Tetrachloroethane)
Ethanethiol
(see Ethyl mercapten)
Ethanoic acid (see Acetic acid)

Ethanol (see Ethyl alcohol)


Ethanolamine
- 28, 43, 49, 77, 83, 128, 147, 156,
164, 177, 193, 201, 219, 248, 258, 268,276,
358, 363, 436, 498, 617, 622, 661, 663, 728,
760, 683,788,813,827,841,865,
871
Ethanolamine
hydrochloride
- 692
Ether petroleum - 789
Ethers - 28, 36, 53, 77, 149, 151, 154, 156, 241,
248, 276, 291, 293, 304, 306, 309, 312, 315,
358, 632, 651, 663, 798,802,
806, 841, 846,
865,882
Ethine (see Acetylene)
Ethoxyethanol
- 225
2-Ethoxyethyl
acetate - 681
Ethoxylated
alcohol, CIz-ls - 181, 193
Ethoxylated
nonylphenol
- 193
Ethoxylates
- 682
Ethyl acetate - 1, 2,4,7,
9, 10, 17, 26, 28, 33, 37,
41, 48, 53, 55, 60, 63, 65, 77, 95, 103, 104,
107,111,
112, 113,114,117,
121, 128,143,
147, 149, 153, 154, 156, 157, 158, 162, 171,
175, 193,218,
227, 236, 239, 241, 244,248,
255, 266, 276, 284, 286, 291, 293, 296, 299,
303, 306, 309, 312, 315, 358, 370, 372, 373,
374, 376, 380, 383, 385, 387, 389, 392, 393,
394, 395, 397, 398, 401, 408, 435, 496, 497,
617, 651, 660, 663, 681, 726, 759, 766, 777,
782, 789, 792, 798, 802,806,
810, 813, 822,
827,841,850,865,882,886,889
Ethylacetic
acid (see Butyric acid)
Ethyl acetoacetate
- 41, 108, 193, 218, 227, 255,
266,358,813,822,828,865
Ethyl acrylate - 28, 33, 37, 41, 56, 128, 149, 154,
162, 193, 218, 255, 263,266,
358, 497, 813,
828,841,865
Ethylacrylic
acid - 358
Ethyl alcohol - 1, 2, 4, 7, 9, 10, 17, 26, 28, 33,
34, 37, 41, 47, 52, 54, 55, 60, 61, 63, 65, 67,
69,95,
103, 104, 106, 108, 109, 110, 111, 112,
113, 114, 117, 118, 121, 128, 129, 143, 147,
149, 151, 153, 154, 155, 156, 157, 158, 159,
169, 170, 175, 193,218,225,
226,236,239,
244, 255, 263, 273, 276, 291, 293, 296, 299,
303, 306, 309, 312, 315,317,
318, 319, 320,
321, 322, 323, 324, 325, 326, 327, 328, 329,
330,331,
332,333,
334,335,
336, 337-354,
358, 370, 372, 373, 374, 375, 376, 379, 380,
382, 383, 385, 388, 389, 392, 393, 394, 395,
396, 397, 398, 401, 408, 435, 440, 498, 617,
651, 657, 663, 669, 681, 735, 737, 743, 759,
766, 781, 789, 798, 802, 806, 813, 827,828,
839,848,850,856,865,882
Ethyl alcohol, vapor, condensate - 193
Ethyl alcohol, 50% in water - 96, 97, 98, 104, 111,
117, 121, 128, 129,743
Ethylaldehyde
(see Acetaldehyde)
Ethylamine
- 103, 106, 156, 376, 380, 401,408,
499,813,865

923

924

Corrosion

Resistant

Materials

Handbook

N-Ethylaniline
- 233, 617
Ethylbenzene
- 33, 37,48, 77, 109, 143, 162,
176, 193, 229,255,
286, 304,307,309,
312,
315, 358, 617, 660, 663, 681, 789, 813,828,
865
Ethyl benzoate - 77, 143, 156, 227,286,
359,
828,865
Ethyl bromide - 1, 153, 156, 162, 193, 359, 393,
401,408,663,814,850,865
Ethyl butanoate
(see Ethyl butyrate)
2-Ethyl butanol - 499
2-Ethylbutene-1
- 356
Ethylbutyl
acetyl ricinoleate - 617
Ethyl butyrate - 63, 77, 113, 114, 617, 660, 813,
5827
2-kthylbutyric
acid - 41, 147, 225
Ethyl Cellosolve - 171, 359, 865
Ethylcellulose
- 156, 233, 359, 660, 663, 813,
827,865
Ethyl chloride - 28, 33, 56, 67, 77, 108, 114, 129,
143, 149, 153, 154, 156, 162, 171, 176, 193,
218, 230, 248, 255, 266, 276,299,
359, 376,
380, 393, 398,401,
408,435,651,
660, 663,
682, 728, 759, 777, 782, 789, 798, 802, 806,
813,828,841,846,850,865,882,886,889
Ethyl chloroacetate
- 227, 255, 266
Ethyl chlorocarbonate
- 359,828,
865
Ethyl chloroformate
- 176, 193, 359, 828,865
Ethyl cyanoacetate
- 255
Ethyl cyclopentane
- 359
Ethyl dichloride (see also Ethylene dichloride)
156,865,889
Ethylene - 359,499,
617, 660,663,789,828,865
Ethylene, cracked gases - 682
Ethylene bromide (see Ethylene dibromide)
Ethylene chloride (see Ethylene dichloride)
Ethylene chlorohydrin
(chloroethanol)
- 28, 41, 42,
56, 63, 65, 74, 77, 106, 108, 109, 114, 149,
154, 162, 171, 193,218,
230, 247, 266, 276,
286, 359, 393, 398, 615, 660, 798, 802, 806,
814,828,860,865,882
Ethylene cyanohydrin
- 660
Ethylenediamine
- 41, 56, 63, 77, 103, 147, 171,
193, 218, 226, 240, 248, 266, 359, 617, 737,
814,828,865
Ethylenediamine,
hydrochloride
- 682
Ethylenediamine
tetra acetic acid (see EDTA) 192, 193,682
Ethylene dibromide
(ethylene bromide) - 28, 41,
56, 77, 149, 154, 156, 157, 193,218,
255,
266, 359, 435,499,
660, 663, 732, 759, 828,
865
Ethylene dichloride (ethylene chloride) - 5, 8, 11,
29, 33, 34, 41, 48, 53, 56, 60, 63, 72, 95, 104,
106, 111, 112, 114, 117, 121, 129, 143, 149,
154, 156, 171, 176, 193,218,
221,230,
236,
239, 241, 244, 248, 255, 266, 276, 291, 293,

296, 300, 304, 307, 310, 312, 315, 359, 370,


372, 373, 374, 376, 380, 385, 388, 389, 392,
393, 394, 395, 397, 401, 408, 435, 500, 617,
660, 682, 735, 737, 750, 759, 766, 774, 777,
782, 789, 798, 802, 806, 814, 828, 841, 846,
850,865,882,889
Ethylene disulfonic acid - 401, 408
Ethylene glycol - 1, 5, 10, 17, 26, 29, 33, 37, 41,
48, 49, 56, 63, 65, 67, 77, 102, 109, 111, 114,
118, 121, 129, 143, 147, 149, 151, 154, 155,
156, 157, 162, 169, 171, 176, 193, 218, 229,
236,239,
240, 244, 248, 255, 266, 276, 284,
291, 293, 300, 303, 306, 309, 312, 315, 359,
368, 370, 372, 373, 374, 376, 380, 382, 385,
387,388,
389, 393, 394, 395, 396, 397, 398,
441, 500, 617, 632, 651, 660, 663, 682, 728,
789, 798, 802, 806, 841, 850, 865, 882, 886,
889
Ethylene glycol monobutyl
ether (butyl Cellosolve) 11, 37,55,
147, 160, 161, 170, 186, 193, 233,
264, 291, 293, 356, 614, 789, 812, 825,828,
859
Ethylene glycol monobutyl
ether acetate - 828
Ethylene glycol monoethyl
ether (Cellosolve) 11, 18, 26,28,
40, 55, 111, 121, 126, 143, 147,
149, 154, 156, 171, 218,227,
233,241,
265,
275, 291, 293, 306, 309, 312, 315, 357, 359,
825,860.865
Ethylene glycol monoethyl
ether acetate (Cellosolve
acetate) - 9, 11, 18, 40, 55, 143, 156, 275, 357,
812,825
Ethylene glycol monomethyl
ether (methyl Cellosolve)
11, 18, 43, 57, 65, 83, 219, 234, 258, 268, 279,
286,361,377,380,789,816,842,851,870
Ethylene glycol monomethyl
ether acetate - 11, 18,
26
Ethylene glycols - 682
Ethylene glycol/water
- 52, 193, 216, 286
Ethylene oxide - 13, 20, 29, 56, 65, 77, 129, 143,
149, 154, 218, 231, 256, 266, 300, 359, 393,
401,408,
617, 660,789,
798, 802, 806,828,
841,850,865,882
Ethylene trichloride
- 156, 256, 359, 865
Ethyl ether (see Diethyl ether)
Ethyl formate - 359, 617, 660,865
2-Ethylhexanediol-I,3
- 17
Ethylhexanol
- 865
Ethyl hexoate - 157
2-Ethylhexoic
acid - 660
Ethyl hexylacetate
- 193
2-Ethylhexyl
alcohol - 10, 17, 103, 156, 291, 293,
359,660
Bis(2-ethylhexyl)phthalate
- 117
2-Ethylhexyl
sebacate - 8
Ethyl iodide - 156
Ethyl isobutyl ether - 156
Ethyl lactate - 10, 18, 143, 227, 617, 660

Corrosive

Ethyl

mercaptan

- 276, 359, 660, 789,813,

816,

Ethylmorpholene

stannous

Ethyl

nitrate

- 34

Ethyl

oleate

- 118,

Ethyl

oxalate

Ethyl

parathion

octoate

- 359,

813,

828,

pentachlorobenzene
phenyl

Ethyl

propionate

ether

- 359,813,828,865

Ethyl

- 18, 617
propyl
ether - 156
pyridine
- 865
salicylate
- 227, 663

Ethyl

silicate

Ethyl

stearate

Ethyl

suberic

Ethyl

sulfhydrate

Ethyl

sulfate

- 193,
acid

mercaptan)

162,

193,

236,

244,

388,

789,865

acid

408

- 193

Exhaust

gases

Exsiccated

exhaust)

(see Gas,

alum

caloria

Exxon

latex

in water

Exxon

turbo

oil

Fabric

HT

43

Fats,

and

cooking

Fatty

acid

- 682

gas - 193

33, 34, 35, 36,48,


53, 56, 62,
151, 154, 162, 171, 193, 218,

256,

266,

276,

359,

376,

380,

383,

393,

397,398,401,408,432,

441,

500,

501,

617,

632,

646,

663,

682,

692,

726,

728,

732,

369,

371,

774,

779,

782,

787,

798,

802,

828,841,850,854,

FC-43

- 359

FC 75

Fluorocarbon

FC-77

(cyclic
feed

compounds

ether)

- 248

- 193

Feran

- 156

Ferri-

and ferrocyanides

Ferric

acetate

Ferric

acid

Ferric

ammonium

Ferric-chlorate

- 193

- 359

fluorinated

- 171,

salts

- 401,
193,

- 60, 149,
sulfate
ion

162,

171,

193,

198,

218,

221,231,

240,

248,

256,

276,

300,

303,

306,

311,

314,

359,

308,

370,

372,

373,

374,

376,

380,

393,

394,

395,

397,

398,

401,

408,

412,

414,

417,

422,

423,

424,

428,

429,

441,

444,

445,

502,

609,

617,

632,

639,

642,

644,

645,

646,

647,

651,

660,

663,

682,

722,

723,

726,

732,

733,

735,

737,

750,

756,

766,

774,

777,

782,

788,

798,

802,

828,

830,

841,

846,

866,

882,

886,

chloride,

boiling
750,

- 424,

445,

645,

647,

682,

766,777,795,866

Ferric

chloride-hydrochloric

Ferric

chloride-sodium

Ferric

ferrocyanide

Ferric

hydroxide

acid
chloride

- 221,
- 29,

660,

154,

- 109,

256

- 644,

723

774

156,

266,

502,

777,

108,

113,

- 29,

33,

114,

118,

129,

152,

154,

156,

162,

171,

193,

218,

221,

256,

266,

303,

306,

308,

311,

314,

nitrate

34,

374,

376,

380,

359,

373,

398,

401,408,

435,441,

782,

798,

806,

802,

374,

67,

- 384

408

266
392
- 19, 231,

- 618,

48,

56,

78,

393,

394,

395,

397,

682,

759,

774,

777,

841,

866,

882,

814,828,

841,

866

- 828

Ferric

phosphate

Ferric

salts

Ferric

sesquichloride

Ferric

subsulfate

Ferric

sulfate

- 157

- 60, 149,

367,

392,

850

- 828
- 828

- 29,

33,
156,

34,

37,

162,

48,
171,

56,

67,

193,

78,

218,

106,

113,

118,

154,

256,

266,

276,

359,

373,

374,

376,

380,

393,

394,

395,

397,

398,

401,

408,

435,

441,

502,

221,

632,

645,

646,

651,

660,

682,

683,

737,

751,

759,

766,

774,

777,

782,

788,

798,

802,

806,

814,828,841,846,866,882,887,889
Ferric

sulfate,

Ferric

sulfate-sulfuric

Ferricyanide

boiling

- 645,

bleach

- 416,

423,

774

- 193

Ferrous

ammonium

citrate

ammonium

sulfate

chloride

682

acid

Ferrous
Ferrous

nitrogen

FCU

373,

865,882,886,

889
Fatty

158,

perchloride

221,

806,814,

157,

oxide

- 65, 162

- 29,
149,

156,

Ferric

- 663

esters

154,

Ferric

manufacture

exhaust

Fatty acids
77, 129,

152,

- 193

- 617

Fat splitting

121,

151,

- 286

52 - 276,814
- 828

lime

56,

118,

887,889

- 300

softeners

Factovic

exhaust)

- 828

Exxon

48,

114,

176,

Ferric
oils)

617

air (see Air,

37,

113,

866

oil (see Essential

Exhaust

34,

108,

266,

Ferric

- 500

- 13, 233,

33,

106,

889

(see Ethyl

- 660
acid - 401,

19, 29,

78,

806,814,

632,732,

Ethylsulfuric

Fats

874

- 12,

Index

63,67,

737,740,

- 77, 109,

Eucalyptus

Fat

834,

- 660

Ethylsulfonic

Exalt

- 364,

359,813,828,865

389,401,408,

Eugenol

865

(phenetole)

chloride

129,

- 193

Ethyl

Ethyl

- 359

129

Ethyl

Ethyl

Ferric
62,

828,865

Material

- 29,

48,

- 728, 777,
- 660, 683
56,

63,

78,

866
113,

114,

118,

129,

143,

152,

154,

156,

162,

171,

176,

193,

218,

248,

256,

266,

276,

393,

397,

398,

502,

651,

660,

683,735,

737,

777,

788,

798,

802,806,814,828,866,882,887,889
Ferrous

chloride-HCI

Ferrous

hydroxide

Ferrous

iodide

Ferrous

nitrate

- 256,
- 266

737

- 502
- 48, 56, 109,

156,

162,

171,

193,

218,256,266,276,814,828
660

Ferrous

salts

Ferrous

sulfate

- 60, 149,
- 1, 29,

367,
36,

392,
48,

56,

733,

850

63,

108,

114,

925

926

Corrosion Resistant Materials Handbook

Ferrous sulfate (contd) - 118, 129, 147, 151, 152,


154, 162, 171, 193, 218, 221, 231,256,
266,
276, 303, 306, 308, 311, 314, 370,372,
393,
397, 398,435,
502,503,
618, 651,660,
683,
726, 728, 732, 733, 737, 759, 774, 777, 788,
798,802,
806,814;
826, 828,866,882,887,
889
Ferrous sulfide - 503
Ferrous sulfite - 231
Fertilizer - 24,48,
62, 162,503,504,
618,672,
683,796
Fertilizer fumes - 193
Fertilizer scrubbing - 194
Fertilizer solution - 153, 155, 194, 202, 215,
814,828
Fibers, wood - 683
Filter alum - 828
Fire resistant hydra-fluid
- 814
Fire retardant liquid - 194
Firtec 290 - 814
Firwood oil - 828
Fish - 129, 238, 618, 620, 625, 629
Fish batter - 841
Fish oil - 106, 194, 359, 788, 828, 866
Fish oil meal, exhaust gas - 194
Fish solubles - 29, 114, 149, 154, 256, 266,
850
Fish stickwater - 504
Fish tanks - 194
Flavoring (see Foods and Essential oils)
Flaxseed oil - 828
Flexol 3 GO - 291
Flo-Cool 180 (silicate ester) - 248, 866
Floor polish - 106
Floor wax polymers - 194
Flores martis (see Ferric chloride)
Flour - 618
Flue gas (see Gas, five)
Flue gas desulfurization
- 416
Flue and stack gas scrubber - 729
Fluoboric acid (see Fluoroboric
acid)
Fluophosphoric
acids - 618
Fluoride salts - 194, 663, 684, 731, 732
Fluorinated,
chlorinated
acid organics - 194
Fluorinated
cyclic ethers - 359, 828, 866
Fluorinated
hydrocarbons
- 618
Fluorine - 29, 53,56,
63, 65, 78, 114, 149, 151,
154, 171, 194, 256,276,
359, 376, 380,393,
397, 398, 401,408,435,441,
618, 642, 646,
660, 684, 731, 735, 737, 759, 766, 780, 782,
789,798,802,806,814,828,847,850,882
Fluorine, wet - 154, 266
Fluorobenzene
- 156, 359,828,866
Fluoroboric
acid - 29, 41,48,56,
78, 114, 149,
154, 162, 171, 194, 256, 266, 276, 359, 367,
369, 371, 376, 380, 401,408,
504, 660, 684,

737,751,
766, 787,814,828,841,850,
854,
884,887,890
Fluorocarbon
oils - 359
Fluorocarboxylic
acid - 660
Fluorochloroethylene
- 828
Fluorolubes - 194, 359, 828, 866
Fluoronaphthalene
- 157
Fluoronitrobenzene
- 157
Fluorosilicic
acid (see Fluosilicic acid)
Fluosilicic acid (hydrofluorosilicic
acid) - 10, 17,
29, 33, 37, 41, 48, 49, 53, 56, 60, 63, 67, 78,
80, 109, 113, 114, 118, 129, 149, 151, 152,
154, 155, 156, 162, 169, 171, 194, 197,218,
221, 236, 244, 248, 256, 266, 276, 300, 359,
360, 367, 373, 374, 376, 380, 382, 388, 389,
392,393,
397, 398, 401,408,
426, 435, 518,
519, 652, 655, 660, 663, 684, 688, 725, 726,
737, 759, 766, 775, 779, 787, 798, 802, 806,
814, 815, 828, 830,841,850,
854, 855,882,
887,890
Fluosilicic acid fumes - 688, 779
Fluosulfonic
acid - 194, 504
Fluothane - 63
Flux - 505
Fly ash - 618
Fly ash slurry - 194
Food brine - 505
Food processing - 433, 729
Foods and food products - 618, 737,743,
884
Accent - 848
Bacon - 14
Bacon fat - 227
Bakery products - 382
Barbeque sauce - 839,858
Beans - 613
Beef - 142, 228
Beef, extract - 839, 858
Beef, gravy - 227
Beer - 1, 15, 23, 28, 37, 47, 54, 60, 62, 65,
67, 72, 106, 114, 118, 124, 149, 154, 156,
159, 170, 184, 227, 238, 252, 264, 274,
299, 356, 370, 372, 373, 374, 375, 379,
382, 392, 440, 613, 632, 650, 735, 788,
811,823,839,858,886,889
Beet juice - 227
Blackberry juice - 613
Bourbon - 227
Brandy - 124, 238
Butter - 14, 22, 67, 124, 142, 156, 227, 238,
274, 304, 307, 310, 313, 316, 356, 382,
613,663,788,824,840,859
Buttermilk
- 73, 156, 440, 788, 840, 859
Carbonated
beverages - 156, 65 1,860
Cardamon - 131
Carrot juice - 227
Carrot, liquified - 238

Corrosive Material Index

Foods and food products

(contd)

Castor oil - 28,48,


55, 60, 67, 106, 113, 114,
125, 126, 142, 149, 154, 156, 160, 170,
187, 218, 233, 254, 265, 275, 291, 293,
299, 304, 307, 310, 313, 316, 357, 368,
393, 651, 663, 788, 812, 825, 840, 849,
860,872
Catsup (ketchup) - 14, 22, 38, 156, 227, 382,
788,840,860
Celery salt - 227
Cereal - 615
Cheese - 62, 382, 615, 788
Cheese spread - 105
Cherries, processed - 143, 227, 615
Cherry juice - 486, 615
Chicken gravy - 227
Chicken soup - 227
Chocolate - 615, 788
Chocolate syrup - 14, 22, 126, 238, 275,
840,860
Cider - 65, 114, 126, 156, 275, 382, 615,
651,788,840,861
Cinnamon - 106,227
Citric oils - 840, 861, 872
Citrus fruit, juices - 382, 615,788
Citrus pectin liquor - 840,861
Coca-Cola - 227, 861
Cocoa butter - 143,227,812,861
Cocoa, chocolate - 106
Coconut oil - 28, 48, 55, 60, 62, 126, 143,
156, 161, 189,218,
227, 254, 265, 357,
368,392,616,788,826,840,861,872
Cod liver oil - 1, 62, 106, 126, 143, 156, 189,
227, 357, 616, 663,812,
826, 840, 861,
872
Coffee - 104, 105, 106, 126, 143, 227, 238,
289, 357, 382, 491, 616, 651, 782, 788,
861
Coffee, cream - 227
Coffee, dry powder - 227
Coffee, grounds - 14, 22
Coffee, liquid - 227
Coffee, paste - 227
Coffee, sugar - 227
Cognac - 106
Cola, drinks - 227, 228, 788, 861, 874
Condiments
- 491
Cooking oil - 228
Corn oil (maize oil) - 1, 48, 60, 67, 118, 127,
143, 156, 161, 190, 218, 227, 254,275,
291, 293, 357, 370, 372, 392, 616, 651,
788,812,826,840,862,872
Corn oil, Mazola - 102, 228, 238
Cornstarch - 48, 161, 190, 632, 680, 788
Cornstarch slurry - 861
Corn syrup - 55, 61, 149, 154, 171, 190, 265,
382,616,812,826

Corn syrup, Karo - 131, 238, 278


Cottage cheese - 376, 380
Cottonseed oil - 6, 7, 28, 48, 55, 60, 67, 75,
104, 113, 114, 117, 143, 147, 149, 154,
156, 161, 190, 218, 233, 247, 254, 265,
275,291,
293, 299, 304, 307, 310, 313,
316,357,368,
376, 380,392,441,
616,
651, 728, 788, 812, 826, 840, 849, 862,
872
Cream - 616,840,862
Currants (black and red) - 616
Dairy products - 616
Dextrin-28,55,
113, 114, 127, 149, 153, 154,
218,265,275,
788,849
Dextrose - 28, 55, 113, 114, 127, 149, 154,
254,265,681,788,849
Edible fats and oils, general - 63, 238, 304,
307,310,
313, 316
Eggs - 617, 788
Eggs yolk - 382
Fish batter - 841
Fish - 129, 238
Kippers - 620
Sardines - 625
Tuna - 629
Fish oil - 106, 194, 359, 788,828,
866
Flour - 618
Fruit - 618
Fruit extracts - 382
Fruit juice- 62, 63, 118, 129, 153, 156, 194,
238, 256, 276, 370, 372, 618, 651, 663,
726,735,782,788,841,850,866
Fruit juice
Apple - 123
Grape - 15, 23, 105, 227, 373, 374, 619,
841,850,867
Grapefruit
- 1, 106, 227, 515, 619
Lemon, lemonade - 14,22,
144,228,523,
620
Lime - 621
Orange - 15,23,
106, 145,228,
623, 693
Pineapple - 228, 624
Fruit juice concentrates,
frozen Grape - 15, 23
Grapefruit
- 14, 23
Lemonade - 14, 23
Orange - 14, 23, 145, 228
Pineapple - 14, 22
Tangerine - 14, 23
Fruit juices, pulp- 29, 56, 65, 114, 129, 149,
151,154,256,266,850
Fudge - 618
Garlic salt - 227
Gelatine - 29, 56, 67, 79, 130, 156, 195, 266,
277, 305, 308, 311, 313, 316, 359, 514,
618, 651, 663, 685, 728, 788,841,850,
867

927

Corrosion Resistant Materials Handbook

928

Foods and food products

(contd)

- 56, 114, 118,227,256,266,850


Grapefruit
peel, oil - 106, 841, 867
Grapes - 62

Gin

Grape sugar - 114, 130,

149, 153,

paste

- 133

-2,6,

50,53,84,

117, 119,

121,

363,

- 144,228,619,841,850,867
- 14, 22, 144, 228, 382,841,

382,

623,

Onion

flakes

Onion

juice

Orange peel, oil

Ketchup

(see Catsup)

Oregano

Kool-Aid

soft drink

112,

salt

- 106, 228,238,843,873
- 228
Palm oil - 145, 156, 234, 280, 539, 623, 788,

144,

156, 228,

310,313,

316,317,

Paprika

324,

Parsley flakes

817,833,843,873

- 228

304,307,

318,

319,

320, 321, 322,

323,

326,

327,

328, 329, 330,

331, 332,333,

Pasta

336,

372, 373,

Peanut butter

334, 335,

361, 371,

325,
374,

lime, orange emulsion

Licorice

powder

Liquors,

liqueurs

- 228

flavoring

- 228

oil and peel

- 29, 106, 154, 267,890

Peel oil

- 382,525,

Pepper

632, 788,

- 788
621,788

- 14,23,

Margarine

- 227, 228
- 228,874

304,

307, 310,

788

- 14,22,

132,

371,372,426,783,

- 62,382,

Pickles

105, 228,

313,316,382,621,
Mayonnaise

- 624

Plums
156, 228,238,278,

788,842,870

Raspberry
Rhubarb

Meat sauce - 132, 133

Rice

- 14, 22, 29, 57, 62, 63, 66, 67, 83, 106,
133,

144, 150,

154, 156, 201,

219,228,238,258,268,279,363,37

1,

372,

373,

374, 377,

381,

529,

622,

652, 663,

788, 816,832,842,

382,396,

528,

851,871
paste

- 228

- 382
Mincemeat - 228
sour

water

- 106

Molasses - 29, 57, 67,83,


150, 154,

156, 238, 258,268,


529,

622,

115, 133,

279,382,

632, 728, 788,816,

632,842,851,871
glutamate

- 625
- 228
- 106, 119,228,625,844,876

Root beer
Rum
Rye

- 228

Saccharin,

solution

- 377, 381, 662, 788

- 136
Salad dressing - 876
Safflower

oil

- 370, 572,

- 14, 23, 66, 83, 104, 105, 106, 144,


228,279,

780,783,817,832,842,871

- 228

Saponified

oil

Sauerkraut

- 136, 238,281,

Sausage fat

- 228

625

- 238
- 238
Sesame oil - 228,260,843,844,
Seafood

Shortening

873,876

- 115,382,852

- 227
- 238,365,
Shrimp - 228
Crisco

(MSG)

709,788
153, 201,

- 625

Scotch
104, 105,

396,442,
Monosodium

juice

- 625

Salad oil - 106, 382,788

- 228

powdered

- 106, 281, 364, 818,835,843,

Rapeseed oil
844,873,876

- 62, 621
- 735

119,

624

- 788

Pickle solution

Meat juices

Mustard

873

- 204
- 106

Pepsi-Cola

Maple syrup - 229,

Mineral

382, 544,

- 238

Pepper, black

870
Mannitol

Milk,

623,694,817,833,843,873

145, 231,

Pectin, Certo

Malt, beverages, liquors

Milk,

- 14,23, 105,228,
371,372
- 62, 134, 135, 145, 153, 204,228,

280,363,
Pectin,

- 228

- 228

- 62

Peanut oil

376,380,663,783,788,816,842,869
Lemon,

- 115,852

Orange extract

238,289,

Milk

726, 788, 817,833,

- 106
- 228
Orange drink - 104,105

- 14

mix

- 14, 22, 67,81,

115,

663,

Onions

Onion

Ice cream

Milk

112,

- 228
- 623

fats - 788
- 382, 620, 788, 868
Iced coffee and tea - 14, 22
Jam, jelly - 382, 788
Jam, jelly, grape - 105
Hydrogenated

Meat

111,

- 228

Olives

867

Lemon

104, 106,

165, 172,203,234,

843,872

Horseradish

Lard

134,

279,304,307,310,313,316,337-354,
154,266,

850
Honey

Mustard,
Oliveoil

37 1, 372, 382,622,

Spry

Soft drinks,

878

beverages

- 228,382,
- 382

743,

788

Soft drinks concentrates


Soft drink

syrup concentrates

15, 24, 37, 114, 156, 227,

(fountain
228,238,616,

syrups)

782

Corrosive Material Index

Foods and food products(cont'd)


Sorbitol-51,166,210,627,788
Soup solutions-156,382
Soybean oil-139,156,228,282,301,365,
788,819,836,843,844,873,878
Soybean oil,epoxidized
- 162, 192,210
Soy sauce- 844,878
Spices-228, 229
Starches-788
Strawberries
- 627
Sugar,beet and cane liquor- 28,51,54,55,
62.72, 125,149,151, 154, 156, 160, 167,
184, 186,210,252,253,264,274,356,
357,441, 578,579, 614, 632,650,651,
728, 788,811,812,823,825,839,840,
858,860
Sugar juice- 90,878
Sugar,simplesyrup- 1,229,238
Sugarsolution,syrup-139, 153, 156, 173,
211,222,235,365,373, 374,377, 381,
382, 396, 646, 653,663, 711,776,784,
788,819,836,878,879
Sugar,sucrose-51, 146,167,365, 371, 372,
382,627,711,878
Tea-140,146,382,628
Tea,powder-229
Tia Maria - 238
Tomato- 140,238,628
Tomato concentrate-106
Tomato juice - 15,22,59,92, 104,106,229,
249,262,271,373,374,628,879
Tomato pulp,puree - 38,879
Vanillaextract- 115,229,845,853,880
Vegetable juice - 370, 372, 727, 784,845,880
Vegetableoils-36, 51, 57, 60, 63, 64,84, 121,
134,156,167,203,216,262,268,279,
283, 285, 289, 293, 366, 371,372, 373,
374, 378,382,383,385,392, 393, 396,
403,410, 442, 538, 632, 646, 663, 728,
788,820,838,843,845,852,873,880
Vegetables- 625,629
Vinegar- 1,31, 34,38,51,59,60, 61,62,64,
66.67.93, 106, 115, 119, 140, 150, 151,
153, 154, 156, 167,173,216,229,238,
249,262,271,283,289,366,368,371,
372,373, 374,378, 382, 392,426, 629,
646, 653, 663,728, 784, 788,820,838,
845,853,880,888,890
Vodka-106,119
Wesson oil-22,23, 111, 141,229,241
Wheat germ oil-141
Whey-62,217,721
Whiskey - 31,59,60,67,93, 115, 119, 141,
150, 151, 154, 156,217, 228,229,238,
262, 271, 289, 366, 392, 606, 607, 629,
728,735,788,838,845,853,881

Wine -25,31, 59,60, 62,64, 66,67,94, 106,


115, 141, 150, 153, 154, 156, 238.262.271,
366,371,372,393,629,728,788,820,838,
845,853,881
Worcestershire
sause- 146, 229
Yeast - 115, 141, 153, 156, 382,646,778,788,
853,881
Yogurt- 788
Formaldehyde - 1,2, 13,20, 26, 29, 33, 34, 37, 41,
48, 53, 56, 60, 63, 65, 67, 78, 106, 108, 111,
113, 114, 118, 121, 129, 143, 147, 149, 151,
153,154, 156, 157, 162, 171, 176, 194,218,
221, 226, 236, 239, 241, 244, 248, 256,266,
276.300,359,368,370,372,373,374,376,
380, 382,385, 388, 389,392,393, 394,395,
396, 397, 398, 401, 408, 435,441,505, 526,
618,632, 646,647, 651, 660, 663,684,685,
726, 728, 735, 737, 751, 759, 766, 774,780,
782, 789, 798,802,806,814, 828,841,850,
866,882,887,890
Formaldehyde,gas- 618
Formaldehydemixtures-506, 507, 766
Formalin (seeFormaldehyde)
Formamide- 176,194,618,660
Formamide,vapor- 737,767
Formic acid- 2, IO, 17, 29, 33, 34, 37, 41,48, 53,
56, 60, 63,65, 67,78, 106, 109, 114, 118,129,
143, 149, 151, 153, 154, 156, 157, 162, 171,
176, 194,218,221,225,236,239,240,244,
248,256, 266, 276, 300, 303, 306, 309, 312,
314,359,368,369,371,373,374,376.380,
382, 385, 388, 389, 392, 393, 396, 397, 398,
401, 408,412, 416, 418,424, 432, 435,441,
507, 618, 632, 644, 646, 651, 660, 685, 726,
728, 732, 737, 751, 756, 759, 767, 774, 779,
782,787, 798, 802,806, 814,828,841,847,
850,854,882,887,890
Formicacid-aceticacid
mixtures-507
Formic acid,boiling
- 418, 420,424, 428,444,
445, 643, 647, 666, 685, 723, 726, 730, 740,
741,751,756,767
Formicacid,vapor- 194
Formonitrile(seeHydrogen cyanide)
Fourdrinier
dryingsectionfumes- 194
Fourdrinier
liquor-194
Fraud'sreagent-828
Freon - 1, 16,25, 29,37,52, 56, 63, 65, 67,76,78,
83, 92, 106, Ill, 129, 147, 154, 156, 158, 162,
167, 194, 215, 233,239, 248, 256,266,276,
284, 286, 300, 359, 618, 632, 642, 651, 660,
678, 789,814, 826,829, 841,850,866,887,
890
FR FluidD - 276, 814
FRM-276,814
Fructose- 29, 113, 114, 129, 149, 154, 256, 266,
850

929

930

Corrosion Resistant Materials Handbook

Fruit - 62, 143,227,


675, 618, 624
Fruit extracts - 382
Fruit juice - 7, 74, 75, 22, 23, 705, 706, 778, 123,
729, 144, 745, 753, 756, 194,227,
228,238,
256, 276, 370, 372, 373, 374, 515, 523, 678,
67 9, 620,627,
623, 624, 650, 652, 663, 693,
726,735,788,841,850,866,867
Fruit juice concentrates,
frozen - 74, 15, 22, 23, 145,
228
Fruit juices, pulp - 29, 56, 65, 114, 729, 149, 757,
154,256,266,850
Fudge - 67 8
Fuel gases - 639
Fuel oil - 21, 29, 33, 41, 60, 62, 78, 95, 7 14, 737,
132, 756, 7 62, 177, 7 94, 27 8,223,
224, 248,
256,276,265,304,307,
370,373,
376, 359,
392, 537, 678, 651, 663, 789, 798, 802, 806,
814,850,866,882,884,887,890
Fuel oil, acidic - 359, 829
Fuel oil No. 6 - 359
Fuel oil with sulfuric acid - 29, 780
Fuels - 1 IO, 286,366,
639,841
Fuels, ASTM reference (see ASTM reference fuels)
Fumaric acid (allomaleic acid) - 39, 41, 42, 43, 44,
45, 276, 359, 368,376,380,
874, 822,829,
855
Fumigants - 194
Fumigants, soil - 270
Fundal - 41,43
Fungicides, organic - 53, 194, 204, 796
Fungus - 7 94
Furan - 78, 757,218,248,276,
359,874,829,
866
Furan resin - 847, 850
Furfural - 20, 29, 36, 60, 78, 774, 729, 747, 149,
157, 753, 154, 156, 762, 777, 176, 194, 218,
247, 248, 256, 266, 276, 300, 303, 306, 309,
37 2,37 5,359,368,376,
380,392,393,
394,
395, 397, 398,407,408,
435,507,
678, 632,
657, 660, 685,735,
737, 759,780,
782, 789,
874,829,847,866,887,890
Furfuryl alcohol (fury1 carbinol) - 36, 60, 65, 174,
729, 743, 756, 776, 794, 226, 273, 359, 376,
380,392,767,789,867
Furfuryl alcohol resin - 47
Furnace mufflers - 729
Furnace oil - 7 94
Furniture polish
Dart - 22
OCedar - 23
Pride - 23
Radiant - 23
Fuse1 oil - 156,874,
829
Fusion 72-62 - 195
Fyrguard - 276,814
Fyrquel- 276, 300, 359, 814

G-61 - 795
Gallic acid (trihydroxybenzoic
acid) - 29, 56, 67,
78, 113, 774, 749, 153, 154, 156, 795, 275,
278, 225, 256, 266, 277, 359, 368, 376, 380,
407, 409, 435, 685, 728, 759, 779, 782, 787,
798,802,806,874,829,850,855,882
Gallium, molten - 642, 732
Gallotannic
acid (see Tannic acid)
Gallotannin
- 7 95
Galvanizing line fumes - 795
Garbage incinerator,
fumes and scrubber - 195
Garlic salt - 227
Gas - 685
Gas
Coal - 65,278,
254,275,
675
Coke oven - 29, 55,126,
751, 156,265,
275,
357,432,508,
67 6,87 2,867
Exhaust - 508,682,685
Flue-48,
762, 794, 508, 509, 678, 683, 684,
692,735,
780
Illuminating
- 743
, Manufactured
- 29, 750, 754, 278,256
Natural - 78, 29, 33, 38, 49, 56, 67, 79, 733,
750, 754, 156, 162, 218, 256, 266, 276,
279, 287, 363, 432, 622, 632, 652, 728,
789,877,832,871
Sewerage - 706
Sour - 286
Town - 378, 382
Gaseous stream - 685
Gas odorizers - 24
Gasohol - 795, 277, 287, 288, 289, 297, 663
Gas oil - 41, 42, 43, 129, 795, 203
Gasoline1, 2, 5, 73, 20, 21, 26, 29, 32, 33, 37,
49, 53, 56, 60, 67, 62, 63, 65, 67, 79, 96, 97,
98, 704, 706, 707, 108, 709, 711, 772, 774,
777, 721, 730, 740, 743,147,
749,157,154,
155, 756, 757, 763, 769, 171, 176, 195, 200,
207, 278, 223, 224, 229, 236, 239,247,
244,
248, 256, 266, 277, 284, 286, 297, 297, 300,
305, 307, 310, 373, 376, 378, 319, 320, 327,
322, 323, 324, 325, 326, 331, 332, 333, 334,
335, 336, 358, 359, 363, 365, 370, 372, 376,
380, 383, 385, 388, 389, 392, 393, 396, 409,
447, 570, 618, 632, 642, 657, 663, 685, 726,
728, 735, 789, 798, 802, 806,814,829,847,
850, 858, 859, 867, 865,867,877,879,887,
882,884,887,890
Gasoline alkylation
- 570, 57 1
Gasoline-benzene
mixture - 63
Gasoline components
- 7 95
Gasoline, cracking - 570
Gasoline distillation
- 570
Gasoline fractionation
- 512
Gasoline, miscellaneous
processing - 57 2, 57 3
Gasoline reforming - 513, 574

Corrosive

Gasoline

Glycolic

oil - 829

248,256,

- 29, 56, 67, 79, 130, 156,

305,

308, 311,

313,

195, 266, 277,

316, 359,514,

618,651,

Geyser water

- 195

- 37, 42, 163, 171, 195, 370, 372, 686


acid-formaldehyde
- 384

Glyoxal-acetic
Glyoxylic

Girling

Gold - 790

brake fluid - 359

acid - 195

- 236, 244, 388, 389, 841, 850, 867


- 195
Gold plating solution - 30, 49, 58, 85, 115, 135,

Glass cleaner - 195

Gold cyanide

- 233
Glass wool - 618

Gold pickling

Glass wax
Glaubers

salt (see Sodium

Globrite

- 195

Gluconic

sulfate decahydrate)

150, 153,

- 106

putty

acid - 49, 163, 171, 195, 514,

618,

660,

49, 56, 65, 67, 79, 114,


305,

308, 311,

Grain alcohol

619,

632, 651, 814,829,

313,

316,

- 195

polymetaphosphate)

- 829

- 62

277,

Grain mash

(see Ethyl

alcohol)

- 867

Grain oil - 829

841,850,867

- 67, 79, 130, 156, 277, 300, 360, 368, 396,


515,

619, 651,

Grape sugar - 114, 130,


Graphite

780, 782,789,814,829,

149,

153, 154,266,

850

- 619

Gray acetate - 829

841,850,855,867
Glue, polyvinyl

resin

- 767

(glycerol)

- 1, 10, 17, 26, 29, 33, 37, 49,

56, 60, 63, 65, 67, 79, 106, 108,


121, 130,

144,

147, 149,

171, 176,

- 5, 21, 65, 130, 156,277,

Grease

- 867
Glutamic acid - 435, 515, 660, 685, 728, 759, 787
Glutaric acid - 163, 685
Glutaraldehyde
- 163
Glue, sizing

109,

151,

111, 113,

153,

154,

361,

364, 365,

366, 515,

859,867,869,87
Green copperas,
Green

vitriol

liquor - 29, 33, 37, 42, 44, 90, 147,

Green soap solution

293,

Gulf oils, fluids, greases

368,

370,372,

312,

376,

Gum, acacia

380, 382,

385, 388,

389,

392, 393,

394,

395,

Gum, arabic - 619

396, 409,

435,

619,

632, 646,

652,

660,

Gum, tragacanth

515,

- 16, 111, 121, 130


- 277, 360, 814

195,218,221,233,
291,

306, 309,

686, 728, 737,

743, 759,

767,

798, 802,806,814,829,841,850,

- 230
- 230

- 106

774, 789,

Gypsum

867,

Gypsum,

slurry - 195,829

Hafnium

hydroxide

882,

156,

195,360,439,681,762,783,814,829,867

163,

315, 360,

(see Ferrous sulfate)

- 734

Green death

256, 266,

300, 303,

355, 360,
841, 850,

1,876,879

155, 156,

277,

284,

663, 814,

Grease oil - 819

236,244,

663,

gas, dust - 195

salt (sodium

382, 396,

256, 266,

Glycerin

Grahams
Grain

153,

360, 368,

130, 144,

163, 171, 195,218,

233,

114,

furnace

368, 834,

- 195

154, 156,

149,

441,

Golden-Glo

195, 259, 269,

Golf ball scouring solution

- 1,29,

147,

Glue

154, 163,

843,884,885
Gold smelting

737
Glucose

195, 218,

619, 660, 738,

- 660
- 53, 56, 62, 229, 266, 360, 646, 814,

Ginger oil (see Essential oils)

Glaziers

380, 521,

monoether

Glyoxal

condensate

154, 163,

850,867

- 195

water

376,

887,890
Glycerol

dibromhydrin

Glycerol

triacetate

- 660

- 515

Hair dressing
Vitalis

- 619

Glyceryl

trioleate

Glyceryl

tripalmitate

118,

- 256, 366, 371, 372,

- 14, 22
- 15, 23

Brilliantine
acid

Glycerophosphate

Glycol

- 195

(triacetin)

628,829,837
Glycerophosphonic

Glycine

931

acid) - 29, 49, 56,

130, 149,

266,

Index

751,767,841,850,855
Glycol
Glycols

663,685,728,788,841,850,867
Geothermal fluid - 415
Geothermal

acid (hydroxyacetic

79, 113, 114,

- 118, 130, 234

Gear box oil


Gelatin

- 514

storage

Gaultheria

Material

Wildroot

- 829

- 15, 23

- 15, 23, 493,841,

Hair solutions

- 829

Halite

- 233, 256
- 2, 9, 29, 63, 65, 79, 96,97,

(see Sodium

Halogenated
98, 106, 114,

149,

154,156,195,218,376,380,829

hydrocarbons

291,292;293,
Halothane

304, 307,

- 360
oil - 360,814

Glycol

acetate

- 376, 380, 401, 409

Halowax

Glycol

alcohol

- 829

Halso 99 - 195

Glycol

chlorohydrin

Glycol

FR fluids

(see Ethylene

- 277, 814

chlorohydrin)

Hand cream,
Grace

lotion

- 867

867

chloride)

- 116, 120, 229, 230,


310, 312,

315, 619

171,

932

Corrosion

Resistant

Hand cream, lotion

Materials

Handbook

(contd)

Hexanedioic

- 14, 22

Hinds

Hexanol

- 872

Nivea
Hannifin

- 360
- 156, 814

Hartshorn

(see Ammonium

Heat treating

equipment,

carbonate)

- 41,42,44,
Heavy metal salts - 663
Heavy spar (see Barium
Helium

45

619, 728, 867

sulfide)

11, 18, 26, 29, 33, 39, 41,42,

111, 113,

149, 154, 156,

114, 121,

163, 171,

241,248,256,

309,312,315,

266,
360,660,

130,

133,

147,

acid - 369,

Heptyl

alcohol,
aldehyde

Heptyl

carbinol

371,

376,380

- 144, 226

(see Octyl

alcohol)

- 195, 196, 376, 380

Hexachlorodiphenylmethane
Hexachloroendomethylene

- 829
tetrahydrophthalic

- 196
- 157, 660
- 233

Hexachloroethane
Hexachlorophene

acid - 829
(see Cyclohexane)

Hexahydropyridine

(see Piperidine)

Hexamine

products

- 102,

867

156, 277, 291,

360,

- 867

Houghton

products

Huey test

- 418, 772

- 196

- 53,201
- 277, 815
Hydra fluids - 277, 815
HydraSol - 277,815
Hydratite
liquid - 841
Hydraulic fluid and oil - 1, 21, 33, 49, 52, 66, 67,
Humidity,

100%

Hy-Chock

oil

107,

207,

274,

282,

284,

275,

110,

155, 156,

276, 277,

163,

278, 279,

171, 196,
280, 281,

285,286,

287, 288,

289, 291,293,

300, 301,

305,

308,

310,

313,

316,

317, 318,

319,

320,

321,

322,

323,

324,

325,

326,

328,

329,

330,

331,

332,

333,

334,

335, 336,

355,

360,

365, 366, 639, 811,

361,

363,

364,

813,814,

815,

816,

818, 819,

841,

862,

864, 867,

850,

870,

327,

820,829,835,
872,

875,876,

glycol - 156
- 80, 157, 163, 171, 196, 267, 277,

polyalkylene

300,

355,

360,

516,

619,

660, 751,

783,788,

814,815,829,841,850,857,867
Hydrazine,

(see Cyclohexane)
tetramine)

- 79, 196,

435,516,528,646,660,663,686,759,867
Hexane

- 14, 22, 144, 228, 382, 841,

Hydrazine

- 156,360,814,829,867

(hexamethylene

Hexanaphthene

- 360,867
- 360, 867

- 144,228,619,841,850,867

Horseradish

Hydraulic

- 829

Hexamethylene

- 196

878,884

Hexahydrobenzene
Hexaldehyde

Honey

79,87,88,

Hexachlorocyclopentadiene

chloride

- 230

High viscosity lubricant


Hog fuel flue gases - 196

Huff

- 619

- 256
- 867
Hexachlorobenzene
- 230
Hexachlorobutadiene
- 660
Hexachlorobutene
- 660

Hexahol

glycol ammonium

ether

814,867

Hexachloroacetone

Hexadecanoic

Hexylene

Hough-O-Safe

307,

789,792,814,841,

276,281,616,796,845
Hercolyn plasticizer

anhydride

glycol - 49, 163

277,

- 15, 24, 25, 156, 161, 195, 217, 235,

Herbicides

- 229

Hexylene

Hot stack gases - 49, 163

296,304,

154

(see Methylisobutylketone)

176, 195,218,229,

842,850.867,887,890

Heptyl

- 29, 80, 114, 149,

High energy fuel

52, 53, 56, 63, 65, 79, 95, 102,

Heptanoic

tertiary

- 814,829
bromide

Hexyl

- 660

- 1, 5,8,

239,

Hexanol,

Hexyl

- 277

Heptachlorobutene
44,45,49,

iso
n

Hexene

- 360

108, 109,

360,814,816,

- 103
- 144,226,303,306,309,312,315,

Hexanol,
Hexanol,

Hexone

- 79, 156, 195, 360,

Heptane

- 729

sulfate)

Hepar calis (see Calcium


Heptachlor

263,

360,823

heat exchangers

Heavy alcohols

Heavy water

acid)

829,839,848,856,867

Lube A

Harness oil

acid (see Adipic

- 54, 156,226,234,

dihydrochloride

Hydrazine

hydrate

Hydrazine

sulfate

Hydrazinobenzene

(see Cyclohexane)

- 1, 2, 18, 29, 33, 37, 39, 41, 42, 44, 45, 49,

acid

- 401, 409
(see Phenylhydrazine)

- 176, 196, 218, 256, 385, 393,

402,409,660,689,732,767,795

53, 56, 63, 79, 103,

104,

117, 118,

147,

156,

157,

163, 169, 171,

196,

Hydroabietyl

alcohol

236, 239,

244,

248,

256, 266,

277,

Hydrobromic

acid - 29, 33, 34, 37, 42, 49, 53,

318,

56, 60, 63, 79, 109,

113,

327,

152,

171, 176,

149,

218, 229,

154,

307,

130, 144,

Hydriodic

- 256

- 789

286,

300, 304,

309, 312,

315,

319,

320, 321,322,

323, 324,

325,326,

328,

329, 330,

332, 333,

334,

331,

317,

335, 336,

- 619

154,

156,

163,

244, 256,

266,

287, 360,

337-354,360,385,389,409,516,619,686,

385,

388, 389,

392,

814,829,841,842,867,887,890

516,

652,

686, 731,

661,

393,

114, 130,

147, 149,

196, 218,

367, 373,

397, 401, 409,


732,

236,

374, 380,
441,

751, 767,779,

Corrosive

Hydrobromic
acid (contd)
783, 787, 798, 802, 806, 814,829,
841, 847,
850,855,882,887,890
Hydrocarbon
gases - 632
Hydrocarbon,
light - 868
Hydrocarbons
- 120, 196, 241, 304, 307,309,
312, 315, 360, 619, 642, 648, 686,728,
731, 735, 742
Hydrocarbons,
aliphatic - 36, 116, 229, 291,
798,802,806,882
Hydrocarbons,
aromatic - 36, 116, 123, 149, 154,
184, 229, 273, 291, 293, 798,803,807,
839,
858,882
Hydrocarbons,
chlorinated
- 126, 678, 732, 733,
840
Hydrocarbons,
halogenated - 116, 120, 229, 230,
291,293,304,307,310,312,315,619
Hydrochloric
acid - 1, 2, 4, 6, 9, 10, 17, 26, 29,
32, 33, 34, 35, 37, 39, 40, 41, 42, 44, 45, 46,
49, 52, 53, 56, 60, 61, 62, 63, 65, 67, 79, 95,
102, 104, 106, 107, 108, 109, 111, 112, 113,
114, 117, 118, 121, 130, 144, 147, 149, 151,
152, 154, 155, 156, 157, 158, 163, 169, 171,
176, 196, 197,218,
221, 223, 224,225,
236,
239, 240, 244, 248, 256, 266, 277, 286, 291.
293, 294, 296, 297, 300, 302, 305, 308, 311,
314, 317, 318, 319, 320, 321, 322, 323,324,
325, 326, 327, 328, 329, 330, 331, 332, 333,
334,335,
336,337-354,
360,367,369,
371,
373, 374, 376, 380, 382, 383, 384, 385, 387,
388, 389, 392, 393, 394, 395, 396, 397, 398,
402, 409, 413, 420, 423, 424, 428, 432, 441,
516, 517, 619, 632, 639, 640, 642, 644, 645,
646, 647, 652, 655, 661, 663, 664, 665, 666,
686, 687, 723, 726, 728, 731, 732, 733, 737,
740, 741, 751, 759, 767, 772, 774, 779, 783,
787, 790, 791,792,
793, 798,802,806,
814,
829,841,
847,850,855,882,884,887,890,
891
Hydrochloric
acid, boiling - 413, 424, 445, 644,
645,647,666,686,733,740,756,767,855
Hydrochloric
acid, chlorine - 647, 737, 740, 751
Hydrochloric
acid-chromium
trioxide - 737, 767
Hydrochloric
acid-copper sulfate - 737, 738, 767
Hydrochloric
acid-cupric chloride - 737, 740
Hydrochloric
acid-ferric chloride - 655, 733, 740,
741,751
Hydrochloric
acid, ferric chloride, ferrous chloride
(boiling) - 647
Hydrochloric
acid fumes - 726, 779
Hydrochloric
acid-HCN - 436
Hydrochloric
acid mixtures - 196, 197, 384, 647,
733,737,
751,767
Hydrochloric
acid-nitric acid - 737, 767
Hydrochloric
acid pickling (see Pickling, acid) 891
Hydrochloric
acid saturated with chlorine - 163

Material

Index

Hydrochloric
acid-sodium chlorate - 737
Hydrochloric
acid-sodium chloride - 733
Hydrochloric
acid-sulfuric
acid - 655
Hydrochloric
acid waste pickle liquor - 221, 774
Hydrocyanic
acid - 29, 34, 49, 53, 56, 67, 80,
131, 149, 151, 154, 156, 163, 176, 197,218,
236, 244, 256, 267, 277, 300, 360, 377, 381,
385, 388, 389, 393, 397, 409, 517, 619, 632,
652, 735, 759, 779, 783, 787, 798, 802, 806,
815,830,841,850,882,887,890
Hydra-drive
oil - 277, 360, 815, 868
Hydrofluoboric
acid (see Fluoroboric
acid)
Hydrofluoric
acid - 10, 17, 29, 33, 35, 37, 42, 49,
53, 56, 60, 63, 67, 80, 95, 102, 106, 114, 118,
131, 144, 147, 149, 151, 152, 154, 156, 157,
163, 169, 171, 176, 197, 218, 221, 225,236,
244, 248, 256, 257, 267, 277, 286, 300, 302,
305, 308, 311, 314, 360, 367, 369, 371, 373,
374, 376, 380, 382, 384, 385, 388, 389, 392,
393, 394, 395, 396, 397, 398, 402, 409, 425,
436, 517, 518, 619, 632, 644, 646, 652, 661,
664, 665, 687, 688, 725, 726, 728, 729, 731,
732, 733, 738, 751, 756, 759, 767, 775, 779,
783, 787, 791, 792, 798, 802, 806, 815, 830,
841,847,850,855,882,884,887,890
Hydrofluoric
acid-boron trifluoride
- 688
Hydrofluoric
acid mixtures - 197, 517, 518, 688,
725,726,738,
767
Hydrofluoric
acid vapors - 779
Hydrofluorosilicic
acid (see Fluosilicic acid)
Hydrogen - 29, 53, 56, 65, 67, 80, 114, 131, 149,
154, 156, 197, 218, 248, 257, 267, 277, 300,
360, 436,519,
619, 632, 646, 652, 688, 728,
731, 732, 759, 789, 798, 803, 807, 815,830.
851,868,882
Hydrogenated
fats - 788
Hydrogen bromide - 49, 53, 114, 131, 163, 197,
661,731,732,830,868
Hydrogen carboxylic
acid - 830
Hydrogen chloride (gas) - 33, 37, 49, 53, 80, 108,
114, 131, 163, 197, 218, 257, 277, 436, 519,
520, 619, 661, 688, 689, 731, 732, 737, 759.
789,798,802,806,830,851,868,882
Hydrogen cyanide - 29, 56,80,
218,257,267,
620,689,798,802,806,830
Hydrogen dioxide (see Hydrogen peroxide)
Hydrogen fluoride - 29, 49, 53, 80, 131, 163,
197, 267, 277, 355, 436, 632, 689, 731, 732,
759,783,789,830,857
Hydrogen iodide - 197, 689, 732
Hydrogen peroxide (hydrogen dioxide) - 1,4, 6, 7,
14, 20, 26, 29, 33, 35, 37, 42, 49, 53, 56, 60,
63, 65, 67, 80, 95, 104, 106, 109, 111, 112,
113, 114, 117, 118, 121, 131, 144, 147, 149,
152, 154, 155, 156, 157, 163, 171, 176, 197,
198, 218, 221, 234, 236, 239, 244,248,257,
267, 277, 286, 295, 296, 300, 360, 370, 372,

933

934

Corrosion Resistant Materials Handbook

Hydrogen
373,

peroxide

Hypotower

(contd)

374, 376,

380, 382,

385, 388,

393,

394, 395,

396, 397,

398,402,409,436,

442,

520,

620, 632,

689, 726,728,
775, 777,

646, 647, 652,

732, 735,

798, 803,

807,

663,

Ice cream (see Foods)

767,

lcestone

815,

llmenite
lmol-

830,841,847,851,868,882,887,890
Hydrogen

phosphide

(see Cryolite)

- 198

ore

277,815

lminoethyl

- 29, 56, 114, 149, 218,

267,851

alcohol

- 198

Incinerator

Hydrogen

sulfide - 13, 20, 29, 33, 35, 37, 49, 53,

56, 60, 62, 63, 67, 80, 114,


152, 154,

156,

219,

231, 236,

360,

367,

131, 149,

151,

171,

176, 198,218,

Garbage - 195

257,

267, 277,

300,

Scrubber

385, 389,

392, 393,

396,

689, 728, 732,

735,

642, 646,

652, 661,

663,

738,

767, 777,

783, 789,

Hydroiodic

acid (see Hydriodic


- 156, 277,

Hydrolubric

798, 803, 807,

acid)

144, 149,

Hydrosulfite

- 13, 20, 29, 56, 63,

151,

153, 154,231,

257,

acid)

hydrosulfite)

acid (see Glycolic

Aldrin

- 53, 612, 743, 796, 868

- 796

BHC - 796

acid)

arsenate - 796

- 15, 24, 67, 175, 229, 275, 357,

Chlordane

615,659,796

- 830,

- 15,53,65,

DDT

841

495,616,

Hydroxybenzene

- 610

Dieldrin

acid (see Salicylic

Hydroxyethylamine

Ethyl

acid)

Hydroxylamine

- 788

Hydroxylamine

sulfate - 29, 149,

198,

267

190,233,275,

- 193

- 41,43
- 67, 144, 156, 231, 278, 661,

Lead arsenate
154, 195,

156,

- 796

parathion

Fundal

(see Ethanolamine)

127,

660,796,862

- 276, 358

Diazinon

(see Phenol)

o-Hydroxybenzoic

153, 154, 843,

- 156, 815
- 15, 24, 26, 106, 114, 131, 234, 277, 620,

Calcium

acid (see Fluosilicic

o-Hydroxyacetophenone

150,

742,783,788,815,841,851,868,874

bleach (see Sodium

Hydroxyacetic

135,

- 277, 360, 815


- 631

lndustron

Inks

267,360,376,380,521,815,830,851,868
Hydrosilicofluoric

plating - 115,

884,885

Insecticides

hydroquinol

114, 131,

198, 692

- 642

Ink oil

360, 868

- 277, 815
- 661

Hydroquinone,

- 195,

molten

Inhibitors

oil

Hydroquinine

Indium,
lndium

815,830,841,847,851,868,882,887,890
Hydrolube

Flue gas - 692

163, 169,

376, 380,

759,

- 198

Chemical

244,248,

398,402,409,436,520,521,609,620,632,

663,796

- 278
- 25
Malathion - 26, 278, 361, 816, 870
Methoxychlor
- 278
Methyl parathion - 41
Mortemoth
- 24
Parathion - 204,796
Purina - 28
Lindane

2-Hydroxy-1,2,3-propanetricarboxylic

acid (see

Citric acid)
a-Hydroxypropionic

acid (see Lactic acid)

- 65

Hydroxyquinoline
Hydroxysuccinic

acid (see Malic acid)

a-Hydroxytoluene
Hydyne

(see Benzyl

- 360

Hykil

No. 6 in water

Hypnone

alcohol)

- 360,868

Hyjet

Hypo

- 620

Ice

661,

738,751,759,

783, 787, 792,

- 295

simulation

389, 392,

- 156

Rotenone

- 281, 818
Sobicide - 235
Toxaphene - 16,25,

- 156,815

Sevin

(see Acetophenone)

(see Sodium

thiosulfate)

Insect repellent

Hypochlorene

acid - 149,

Hypochloride

bleach (see also Calcium

hypochlorite)
Hypochlorous
114,

Malaphos

154
or Sodium

acid

- 34,42,49,
154, 163,

267, 277,

360,

369, 37S, 373,

396,

397,

Hypophosphorous

oil

tape

374, 376,

380,

Insulin extract

732,

Invert sugar

80, 109,

lodides

acid - 198
acid

23, 25, 127,

129,

- 176, 198

- 156, 815
- 106

Insulating
Insulating

398,402,409,661,

738,787,815,830,851,855
Hypophosphoric

14, 15, 16,22,

198,219,257,

53,56,
172,

385, 393,

156,214,262,628,796

- 22

133,233,235

- 689, 775, 847

149, 151,

Insect spray-

6-12

- 689

- 620

- 663

Iodine - 13, 29, 33, 36, 37, 53, 56, 60, 80, 104,
105,

149, 154,

156,

172,

176,

198, 219,221,

Corrosive Material

Iodine

- 230, 234, 257, 267, 277, 360,

(contd)

392,

393,

398, 401,

689, 731, 732,

409,

521,

775,

780, 789,

737,

620,

lsooctanoic

alcohol

151, 230,

lsooctyl

798,803,

305,

308, 311,

313, 316,

lsoprep - 198

738,868,887,890

Isopropyl

- 63, 114, 732, 738, 767, 851


Iodine pentafluoride
- 360,830
Iodine,

KI solution

Iodine vapor - 198, 257,


lodoform

thioglycolate

lsopentane

- 63, 112, 118, 131, 144,

solution

234, 277,

- 156,219,

689,

257,

- 620

acid

- 830
- 868
lsophorone - 42, 103, 360,868
lsophthalic acid - 787

661, 663,

807,815,841,851,868,882
Iodine,

acetate - 11, 18, 81, 103,

156, 227,

Isopropyl

- 2, 8, 9, 10, 17, 29, 33, 37, 41,

alcohol

42, 43, 45, 47, 54, 60, 63, 65, 81, 102,
409,

277,

360,663,789,815,830

738

360,402,

Index

620,

118, 131,

661.780,783,798,803,807,830,868,883

145, 148,

155,
277,

291,

293,

315,

360,

370,

372,

lrgasol DA - 198

392, 393, 397,

398, 559,

620,

661,

663,

689,

Iron - 790

789,815,830,839,841,848,851,856,868

300, 303,

Iron and steel cleaning


Iron chlorides

bath - 49, 163,

(see also Ferric,

198

ferrous

Isopropylamine

chlorides)

Iron nitrates

(see also Ferric,

236,244,

ferrous

nitrates)

385,389,409,830

Iron ore sinter, fluegas, scrubber - 689


Iron perchloride
Iron persulfate

(see Ferric chloride)

- 830

Iron plating solution

- 49, 163,

198, 259, 834,

843,

Iron protochloride

(see Ferrous

Iron sesquichloride
Iron sesquisulfate
Iron sulfate

chloride)

carbinol

(see Butyl

chloride

- 360, 559, 689, 830, 868

Isopropyl

ether (see Diisopropyl

basic

- 830
- 830

- 42, 45, 109

Isopropyl

palmitate

- 49, 163,

lsotane

ferrous sulfate)

- 237,

- 868
- 868
acid - 198, 620
(see Foods)

Jet aircraft

- 830

engine oil

155, 156,
278,

164,

169,

172, 198, 219,

287, 288,

289,

291,

Jet II Hydrocarbon

fluid

Jet propulsion

- 21

fuel

lsoamyl

acetate

(see Amyl

acetate,

iso)

JM adhesive - 198

lsoamyl

alcohol

(see amyl alcohol,

iso)

JP fuel

lsoamyl

aldehyde

- 156

alcohol

lsobutyl

butyrate

- 360,868

lsobutyl

chloride

(see B%rtyl chloride,

(see Butyl alcohol,

Kaolin
iso)

361,

370,

372,

277,

- 42, 45

- 361

117, 144,

148, 149,

169, 172,

198, 219,229,

257, 267,

278, 284, 286,

361, 370, 372,

+ d-alloisoleucine
- 257
- 8, 56, 63, 81, 95, 104, 1 IO, 117, 131,

360,815,830,841,851,868

360,

43, 45, 49, 53, 56, 60, 65, 67, 81, 104,

- 360,868

158, 267,

293, 300,

Kerosene - 1, 5, 6, 7, 21, 29, 32, 33, 37, 41, 42,

lsoeugenol - 620

148, 156,

291,

slurry - 198

Kel F liquids

lsocure - 198

lsooctane

- 284

Kelex ligand (solvent extraction)

- 156, 868
lsobutyl phosphate - 661
lsobutyraldehyde
- 868
Isobutyronitrile
- 234

I-lsoleucine

380,

iso)

lsobutylene

lsododecane

267,

374, 376,

815,830,851,868

lsobutyl

- 65

373,

154,

257,

- 107, 198, 215, 219, 257, 267, 278, 287,

288, 289,

- 277,815,868

- 198

- 304, 307, 310, 313, 316

789,815,830.841,851,868
sulfate)

- 277, 815

lsodecanol

198

Jet fuel - 29, 33, 37, 49, 56, 81, 109, 149,

- 823

(see Ferrous

lsocyanates

oxide)

(see Cymene)

Japanese gelatin

- 620
Iron tersulfate - 830

lsobutane

iso)

ether)

(see Mesityl

myristate

Jam, jelly

Iron sulfide

Iron vitriol

alcohol,

Isopropyl

ltaconic

244,376,380,385,389,409,830,868

lrus fluid

Isopropyl

and Ferric salts)

(see also Ferric,

Iron sulfate,

- 663

Isopropyl

lsotox

Iron salts (see Ferrous

257

- 663

bromide

lsopropyltoluene

884,885

198, 226,

(see also Cumene)

lsopropylideneacetone

- 620

Iron oxides

- 49, 163,

Isopropylbenzene
Isopropyl

236,244,385,388,389,409,830
Iron iodide - 176

263, 273,

103, 107,

156, 159,

309, 312,

- 131

176, 198, 226,

153,

306,

losan

170,

144,

286, 290,

296,

300,

373,

388,

389, 392, 409,

728,

789, 792,

151, 154,

374,

110,

155,

156,

237,

239,

244,248,

164,

292,

296,

297,

300,

376, 380,

382,

385,
663,

521, 522,

620,

652,

798, 803, 807,

815,

830,841,

851,869,883,884,887,890

- 841,869
- 131, 296, 304, 307, 310, 313, 316

Kerosene and naphtha


Kerosine

Kester, No. 135 - 102

935

Corrosion

936

Resistant

Materials

Handbook

- 199

Kester No. 1544 - 102

Lauryl

mercaptan

- 522

Lauryl

pyridinium

Lauryl

sulfate - 29, 257

Ketenes

Ketohexamethylene

(see Cyclohexanone)

Ketones - 29, 36, 53, 81, 116, 120,


156, 219, 241,
307, 310,

248, 278,

313,315,

149,

285, 291,

522, 632,

154,

Keystone

grease

Layor caranga (see Agar-agar)

642, 646,

789,

Lead

113, 115,

- 361, 869

- 132
Kleenosan - 132
Knotter

- 132

washer solvent

132,

fumes - 198

resin solution

221,

231,

237, 244,

257, 267,

388,

389,

393, 397,

- 620, 661

Lead-bismuth
- 198

alloy,

salt (see Sodium

hypochlorite)

620, 632,

652, 789, 816,

60.63,

106, 109,

149, 153,

890

199, 219, 221,

225, 237,

278,

303,

368,

369, 371, 373,

300,

113,

115,

132,

172,

176,

248,

257,

222,

314,

361,

393, 402, 409,

376, 380,

382,

383,

396,

397, 398, 402,

409,

436, 442,

522, 523,

620, 632,

646,

652,

759,

767, 768,

689,

726, 732,

735,

738, 751,

775,

779, 783,

787,

791, 798, 803,807,

661,
816,

822,831,842,847,851,855,883,887,890

- 444, 647, 689, 690, 751,

244, 267,
436,

361,

620, 661,

385, 388,
759,

389,

775, 783,

788,816,831,869

- 523, 620,661,
663
- 661
Lead plating solution - 30, 58, 85, 115, 135, 150,
Lead oxide

Lead peroxide
153, 154,

164,

199, 259, 269,

368,

523, 698,

- 150, 367
- 63
Lead styphnate - 831
Lead sulfamate - 81, 361, 816, 842, 869
Lead sulfate - 56, 67, 154, 156, 267, 278, 661,

Lead salts

Lead stearate

- 777
- 156, 816,831
Lactose - 234, 523
Lanolin - 132, 144, 226, 371, 372, 663

Lactic acid salts


Lactol

816,831

bleach - 690

Lead sulfide

Lard (see Foods)

- 222, 775

Lead trinitroresorcinate

Lard oil - 29, 56, 149, 219,

257, 267,

355, 620,

816,831,851

Lead, white,

sublimed

Leather tanning

- 842, 869

Lasso - 164, 199, 278,816


Latex emulsions

and solutions

115, 164,

- 15, 24, 33, 81,

172, 199, 620,816,842,

851,

869

Lecithin

- 816

Lehigh

Xl 169

Lehigh

Xl 170

Lemon oil

- 831
- 836

and finishing

- 199, 620

- 361
- 361

- 57, 118, 132, 219, 257, 267, 842,869,

872

Laurie acid - 29, 49, 56, 148, 149, 154,

164, 172,

199,219,257,267,787,831
Lauryl alcohol
219,

231, 237,

834,843,884,885

779,855

Lauryl

- 620
- 33, 49, 56, 81, 144, 164, 172, 199,

Lead nitrate

240, 244,

374,

113,

869
Lead monoxide

306, 309, 312,

392, 393,

Lactic acid, boiling

- 523
- 81, 642, 646, 728, 732, 738, 780,

Lead fluosilicate

388, 389,

Larvacide

- 661
- 661

Lead, molten

154, 156, 164,

267,

Lanolin

Lead chromate

Lead dust, fumes - 199

- 6, 7, 29, 286,887,
acids - 361

65, 67,81,

144, 148,

- 690

- 56, 154, 199, 267, 380, 385, 393,

Lead dioxide

- 2, 10, 17, 29, 33, 34, 37, 49, 53, 56,

Lactic acid

- 690

402,409,661

- 81, 132, 156,

831,841,869,884
Lactams-amino

eutectic

- 788

Lead carbonate

Lacquers and lacquer solvents

Lacquer thinner

851,869,

- 67, 144, 156, 231, 278, 661, 663,

Lead chloride

300, 361,

738,759,768,775,

798, 803,807,816,831,

Lead, lead chloride

278,

392,

796,816,831

199

Labarraques

109,

164, 172,

385,

361, 380,

Lead azide

Kymene

156,

176, 199, 219,

Lead arsenate

- 830

salt

154,

883,887,890

- 132

Kurrols

LPC-

153,

278,

777,788,

liquor - 29, 149, 154, 267

Kresol

118,

398,436,620,661,735,

windshield

Kraft fibers, wood - 689


Kraft

- 157, 728

Lead acetate - 29, 49, 56, 60, 63, 81, 108,

Kleenezy

Kleer-View

- 21, 361, 831,869

oil

304,

(see Acetone)

oil, fluid,

- 199

293,

798,803,807,841,851,869,883,887,890
Ketopropane

Lavender

chloride

chloride
257,267

- 144, 199, 226


- 29, 49, 56, 149,

- 13, 21, 228


- 234, 257
Leucogen (I-Asparaginase)
- 831
Lemon oil (flavor)

dl-Leucine
164, 176,

199,

Levulinic
Lichenic

acid - 49, 164, 172,


acid

- 831

176,

199, 253,

690

Corrosive

- 15, 22, 234

Liquid

rosin

Lighter

fluid,

butane - 669

Liquid

wrench

Lighter

fluid,

naphtha

Lighter fluid

- 234

Lithium

- 286

Light oil

- 831
- 1, 234

bromide

- 19,49,57,

150, 154,

- 156

Light oil residual

Lithium

carbonate

Lithium

chloride

Light water

Lignin - 199, 842

436,524,621,661,690,738,759,795,869
Lithium chromate - 286

Lignin,

Lithium

- 199, 216

liquor

- 869

- 199

Lignosulfonate

ether)

oxide)
acetate)

- 278, 361, 816, 831, 869


(see Calcium

hydroxide)

- 661
- 642, 646, 732, 738

molten

- 156

Lithium

salts

Lithium

sulfate

Livestock

- 621

- 49, 164, 199

spray base - 189,

Lockheed

- 199

effluent

(see Calcium

nitrate)

115, 118,

219,233,248,257,
301, 357,

Lime slurry and caustic soda - 690

639, 742,789,813,

Limestone

- 621,831
slurry - 690
(see Calcium

oxysulfide)

acid - 29, 57, 81, 150,

Lye (see Sodium

Linolic

- 361
- 361
MCS 463 - 361
MIL-A - 362

154, 199, 219,

acid)

- 65, 278

- 2,5,21,

29, 33,57,

106, 112, 115,118,

132,

63, 67,81,

102,

148, 150,154,

156,
257,

164, 172,

199, 219,234,

237, 239,

244,

267,278,

291,

293, 300,

361,

371,

372, 382,

398,621,

652,

663, 738,

385, 389,393,

783, 789, 816,824,


872
Linseed oil, blue

831,835,842,851,

768,
869,

- 132, 267
- 199

Linseed oil, chlorinated


Linseed oil, standard

varnish

- 106

- 144

Lipstick

Coty - 14, 22

Liquid

petroleum

petroleum

MIL-C-

362

- 362
Ml L-F - 362
Ml L-G - 361,362
Ml L-H - 286,287,288,289,362,363
MIL-I - 362
Ml L-J - 362
MIL-L - 286,287,288,289,361,362,363
MIL-0 - 362
MIL-P - 362,363
MIL-S - 361,363
MIL-T - 362
Macassargum - 831
Machine oil - 21, 132, 150, 154, 267,278
Machine oil and S sumes - 199
Machine oil, light - 234
Maddrells salt - 831
Magenta dye, 2% solution - 132
Magnesia alba (see Magnesium

Lady Esther - 14,22


Liquefied

- 257

Ml L-E

acid (see Linoleic

Linseed oil

hydroxide)

hydrochloride

MCS 352

acid

Linseed cake

816,820,827,831,838,

MCS 312

- 57, 150
- 831

oil

Linolenic

367,537,

- 284
- 234

dl-Lysine

(cinene)

257,267,361,816,831
Linoleic

284,285,300,

364,365,366,

2,4-Lutidine

- 199

- 144, 156, 234, 869


- 824, 826, 831
Linalyl acetate - 728
Lindane - 278,816
Lindol - 156, 361, 842,869
Linear alkylate sulfonates - 199
Linoil - 831
Linoleic

361,

156, 172,

842,851,852,869,871,872,875,884,887,
890
Lubrizol

Lime water

Limonene

132, 150,

278,283,

Lime slurry - 199, 788

Limestone

- 13, 14, 21,

oil, grease (see also Greases)

29, 52,57,82,

Lime, thiosorbic

199

H 55 - 110

Lubricating

- 831

Lime sulfur

199, 436,

Lix 64N - 199

Lime neutralization
Lime saltpeter

156,

- 222,621,
661,775
Lithopone, sludge - 726

Lime liquor - 869

Lime oil

- 33, 37,81,

199,417,

Lithopone

- 199

Lime kiln stack gases


Lime mortar

172,

hypochlorite

Lithium,

(see Calcium

Lime hydrate

- 199, 788

- 33, 37,42,81,

hydroxide

Lithium

- 234

Lime (see Calcium


Lime bleach

199,

661,759,788,869

(see Petroleum

Lilac, artificial
Lime acetate

164,

257,267,286,523,524,842,869

Light process oil - 1, 234, 291

Ligroin

Index

- 361

Liquimoly

Light gas cycle storage - 199

Material

- 156

gas (LW

Magnesite

- 248, 361, 831,869

Magnesium

acid pulp mill liquor


acetate - 869

carbonate)

- 42, 199

621,

937

938

Corrosion

Resistant

Materials

Handbook

Magnesium arsenate - 663


Magnesium bicarbonate
- 199
Magnesium bisulfate - 82
Magnesium bisulfite - 49, 164, 199,376,
380,831
Magnesium bisulfite acid liquor - 199
Magnesium bromide - 231
Magnesium, calcium chloride - 436, 760
Magnesium carbonate - 19, 29, 33, 49, 57, 82, 108,
113, 115, 118, 132, 144, 152, 154, 156, 164,
172, 199, 219, 231, 257, 267, 278, 393, 398,
442,661,663,690,778,816,831,869
Magnesium chlorate - 796
Magnesium chloride - 12, 29, 33, 34, 37, 49, 57, 60,
63,65,67,82,
106, 113, 115, 119, 132, 151,
152, 154, 156, 157, 164, 172, 199, 200,219,
222, 237, 240,244,
248, 257,267,278,
300,
303, 306,308,
311,314,361,373,374,376,
380, 384, 385, 387, 388, 389, 392, 393, 394,
395, 397, 398,402,409,417,423,436,
442,
524, 609, 621, 632, 646, 647, 652, 661, 663,
690, 728, 732,735,
738, 751, 760,768,
775,
778, 783, 788, 798,803,
807. 816, 831,842,
847,869,882,887,890
Magnesium chloride, boiling - 444, 690, 722, 741,
751
Magnesium chloride hexahydrate;
filter aid - 199
Magnesium chloride vapors - 741
Magnesium citrate - 267, 726
Magnesium hydrate (see Magnesium hydroxide)
Magnesium hydroxide
- 29, 33, 38, 49, 57, 63,
67, 82, 113, 115, 119, 154, 155, 156, 164,
172, 200, 219,237,
244, 248,257,
267, 278,
300, 361, 382, 385, 388, 389, 393, 394, 395,
396, 398,426,
621, 632, 652, 661, 690, 728,
735, 738, 760, 768,788,
792,798,803,807,
816,831,842,870,883,890
Magnesium, molten - 646, 732, 738
Magnesium nitrate - 29, 33, 57,82,
113, 115, 119,
152, 154, 156, 172, 200, 219,237,244,
257,
267, 278,373,
374,385,
388, 389,393,
397,
398,402,409,
621, 728, 735,778,783,816,
831,842,870,887,890
Magnesium oxide - 200, 524, 621, 691, 788,842,
870
Magnesium salts - 361, 851
Magnesium silicate - 621
Magnesium sulfate - 12,29,33,
34,49,55,57,60,
63,67,82,
106, 109, 113, 115, 119, 132, 152,
154, 156, 164, 172,200,219,
222,237,
244,
257,266,
267,278,
303, 306, 308,311,
314,
361, 376, 380, 382, 385, 388,389,
392, 393,
396,397,
398,402,409,436,
441,442,
621,
632, 646, 652,657,
661, 691,728,
732,735,
738, 760, 768, 775, 778, 782, 783, 788, 798,
803, 807,816,831,842,
849, 870, 883, 887,
890
Magnesium sulfide - 132

Magnesium sulfite - 119, 361, 870


Magnifloc - 200
Magnus
Light - 278, 816
Medium - 278, 816
Maize oil (see Corn oil)
Malathion
Maleic

(see
acid

49,

tnsecticides)

- 29,

53,

57,

33,

60,

34,

38,

67, 82,

39,

109,

41,

42,

113,

43,

115,

44,

45,

144,

150,

151,

154,

164,

172,

176,

200,

219,

222,

237,

244,

257,

267,

361,

369,

371,

373,

374,

376,

380,

382,

388,

389,

392,

393,

398,

402,

409,

436,

524,

621,

646,

691,

738,

760,

768,

775,

783,

787,

798,

803.

807,

831,

851,

855,

883,

887,890
Maleic

anhydride

- 33, 38, 200,

621,661,691,
Maleinic

acid

Malicacid

257,

361,

200,201,

34,

222,

57,
225,

82,

132,

150,

257,267,

153,
361,
726,

369,

371,

436,

524,

525,

621,

661,

760,

775,

779,

787,

799,

803,807,

823,831,855,

- 148,

beverages,

728,
816,

621

liquors

ammonium

Manganese

carbonate

Manganese

chloride

525,

184,

368,

883

acid

Manganese,

156,

278,

735,

Malt

380,

- 831

- 29,

Malonic

376,

783,831,870

728,

735,

- 382,

525,

sulfates

632,

788,

870

- 200

- 728, 735, 778, 870


- 82, 222, 393, 402, 409,
738,

751,

760,

768,

775,

436,
778,

870
Manganese

nitrate

Manganese

oxide

Manganese

oxide-sulfuric

Manganese

salts - 132,

Manganese

solution

Manganese

sulfate

267,

278,

392,

- 842, 870
- 402, 409
acid
156,

- 384

278

- 62
- 60, 63, 82, 106,
393,

402,

409,

156,

525,

200,

690,

257,

788,

831
Manganese

sulfide

- 156

Mannitol

- 788
Maw
gas - 816
Marble
- 831
Margarine
Marine
Marl
Marsh

(see Foods)
fouling

- 2PO

- 831
gas (see Methane)

Mash

- 156,842,
Matar - 200

870

Maximul - 278,816
(see Foods)
Meat and beef - 62, 132, 133,
735,839,858
Melamine - 842
Melamine resin - 200,870
Melamine varnish - 278
Mentholatum
- 230
Menthol crystals - 230
Mayonnaise

142, 227,

228,

621,

Corrosive Material

Menthol

- 13

in butanol

2-Methoxyethanol

- 525
Mercaptans - 870

Methoxyethyl

- 200

Mercaptoethanol
Mercaptopropionic
acetate
chloride

154, 156,

- 200

113, 115, 119,

398,402,409,

367, 376,

525,
751, 768,

133, 144,

152,

691,

778, 796, 799,803,

Mercuric
219,

vapors - 691

cyanide

- 29, 57, 82, 115,

257, 267,

278, 393,

119, 154,

397, 398, 738,

nitrate

- 219, 222,

Mercuric

sulfate

- 57, 222, 267, 661, 775


- 14, 133,231

Mercurous

chloride
nitrate

154,

156,

768,

257, 436,

760, 775

- 49, 164, 172, 200


278,

393, 397, 398,

661, 778,

Mercurous
152,

sulfate

- 222, 775

- 29, 57, 63, 65,82,


154, 156,

267, 278,

300,

646, 652,

361, 376,

735, 738, 760,

133,

acrylamide

Methyl

acrylate

380,393,436,

661, 691,

768,

726,

621,
728, 732,

780, 799, 803, 807,

816,

102,103,104,
133, 144,

148,

169, 170,

244, 258, 263,

ammoniated
- 231
- 150, 156, 278, 621, 648, 652, 663,

315,

361, 366,
383, 385,

387, 388,

389,

392, 393,

394, 395,

397, 398,

402,409,

436,

440,

526,

621,

657, 661,

663, 669,

691, 735,

738,

743,

760,

781, 789,

816, 831,

839,

842, 848,

Methyl
380,

(see Plating solutions)

621,816,851
acetate

Methylamyl

alcohol

spirits,

- 43

industrial

(see Toluene)

Methyl

benzoate

Methyl

bromide

- 227, 361
- 65, 83, 115, 133, 200, 219, 258,

268,279,361,613,663,816,831,851,870
Methyl

D-bromide

Methyl

butanol

- 361

(see Amy1 alcohols)

Methylbutylcarbinol
butyl

ketone

carbonate

- 361

Cellosolve

(see Ethylene

Methallyl
Methanal

(see Formaldehyde)

- 200
268, 278,361,

acid (see Acetic

- 234
- 278

alcohol)

816,831,

acid)

glycol

monomethyl

ether)
Methylcellulose

- 361, 663

Methyl

- 29, 33, 57, 66, 67, 83, 115, 144,

chloride

150, 151, 154,

156, 172,

176, 200,219,

258, 268, 279,

361,

377,

380,

663, 691,

760,

527, 621,
803,

621,663,760,789,831,870

(see Methyl

- 402, 409

- 11, 18, 278,361,

Methyl

acid - 219, 258

- 234

(see also Hexanols)

glycol acetate

Methyl

219, 258,

- 816

(see also Hexanols)

- 363, 832

- 39, 43, 45

- 157, 172, 200, 258, 376, 526


chloride - 43, 44, 46, 176, 200
ether of o-nitrophenol
- 43, 44

Methoxychlor

- 156
- 156, 226, 279

842,851,870

acid

dl-Methionine

(see Formaldehyde)

Methylamyl

Methyl

Methanecarboxylic

652,

- 57, 82, 156, 268, 278, 279, 377,

- 200
acid - 176

Metal sulfate salts

Methanol

807,

aldehyde

Metal plating solutions

- 57, 65,82,

239,
293, 296,

382,

Methylbutylene

Metaphosphoric

292,

312,

- 361,816
Merthiolate,
tincture - 231
Mesityl oxide - 144, 234, 278, 361, 876, 831, 870
Metalicoil Al85 - 870
Metallic soaps - 278
Metal phosphate salts - 200
vapors

Methanesulfonic

286,

278,

380,

Methylaniline

732,788,851,870

436,

273,

155, 156,

309,

Methylated

Methane

219,226,237,

377,

Methylbenzene

Methanamide

176, 200,
306,

ointment,

Methallyl

117,119,121,
154,

153,

374,

salts

Methacrylic

111,115,
151,

303,

Mercury

Methacrylates

109,
150,

370, 372, 373,

Mercury
Mercury

- 278, 361, 789, 816, 831, 842,

Methylamylcarbinol

- 738

alloys

- 230
- 200

- 8, IO, 17, 26, 29, 32, 33, 34, 38,

alcohol

Methylamine

831,842,851,870,883,890
Mercury

Methyl

851,856,860,870,883,887,890
108, 115, 119,

157, 172, 200,219,234,258,

639, 642,

- 156, 361

- 156

792, 799, 803,

816,831,870
Mercury

acetone

297, 300,

- 29, 57, 82, 115, 119, 133, 152,

156, 267,

acetoacetate

Methyl

157,

Mercuric

Mercurous

144, 156,

380,393,

39, 41, 43, 44, 45, 46, 47, 49, 54, 60, 63, 65, 82,

778,816,831,870,890

Mercurochrome

Methyl

Methyl

chloride

377,

870

807,816,831,842,847,859,870,883,890
Mercuric

245,278,361,

Methylacetophenone

380,393,397,

632, 646, 647,661,


775,

- 57, 258, 267

oleate

402,409,497,691,789,816,831,851,870
57,

164, 172, 200, 219,222,231,257,

278, 300,361,

735, 738,

monomethyl

acetate - 11, 18, 63, 65, 82, 103,

176, 227,237,

- 236, 245, 389


(bichloride)
- 12, 29,34,49,

63, 67, 82, 106,


267,

Methyl

acid

Mercuric

glycol

ether)

Mercapsol

Mercuric

(see Ethylene

Index

652,

807,816,

831,

842,851,

230,

387, 398, 436,


783, 789,

799,

870, 883, 887,

890
Methyl

chloroform

Methyl

chloroformate

Methyl

chloromethyl

Methylchlorosilanes

- 57, 200, 219, 258, 268, 286


- 361
ether - 176, 258

- 870

939

940

Corrosion Resistant Materials Handbook

- 258
- 226
Methylcyclohexanol
- 377, 381,402,
409
Methyl cyclopentane
- 361,832,842,870,871
Methyl

cyanoacetate

Methylcyclohexane

Methyldichlorophosphine
Methylene

Methylnaphthalene
Methylol

polychlorophenol

156,

Methylphenol

(see Cresol)

Methylphenyl

ketone

chloride

(dichloromethane)

119, 133,

161,

164,

172, 177,201,219,230,248,258,

279, 292,
381,

144,

300, 361,

148, 150,

371,

393, 402,409,436,

691,760,

778,

783,

- 9, 11, 18,

372, 373,

374,

377,

527,

661,

663,

621,

87 1,887,890
chlorobromide

Methylene

dioxybenzene

- 268, 832
reaction

mixture

iodide

Methylene

succinic acid

ether

Methyl

ether of o-nitrophenol

Methyl

ethyl

- 46

ketone - 1, 2, 9, 11, 18, 26, 29, 33,


115, 119,133,

parathion

Methylpropanol

(see also Butyl

propyl

benzene

Methyl

n-propyl

Methyl

salicylate

279, 361,

ketone

371,

372,

144, 148,

103,
150,

151,

acid - 29, 57, 115, 150,

sulfuric

Methyl

trichlorosilane

279,284,

Mickro

Klene

286,

291, 293,

297,

300,

304, 307,

310,

313,

Milk

315, 317, 318,

319,

320,

321, 322,

323,

324,

Milk acid

327, 328,

329,

330,331,

332,

333,

Milk of lime

230,

374,

377,

381, 383,

385,

388, 389,

392,

393,

394,

395,

397, 398,

528,

621, 661,

691,

768,

789,792,816,832,842,851,870,887,890

Methyl

ethyl silicone

Methyl

eugenol

- 234

Methyl

formate

- 279,

DMP; MEK

- 200

peroxide

- 361, 870

peroxide

- 234

Methyl

hydrazine

Methylimino
Methyl
Methyl

291,

621, 789,816,832,

- 832

(2-octanol)

- 363

296,

300,

304,307,310,

368, 371,

372,

373, 374,

313.

316,363.

377,

381,

382, 383,

403,

385, 390,

392, 393,

396, 402.

622, 646,

663, 783,

788,

789, 816,

409, 410,
832,842,

- 832

pitch

spirits - 1, 15, 24, 32, 41, 42, 43, 155, 156,

Carbitol

789,816.832,87
Mineral thinner

isobutyl

ketone

- 172
(hexone)

172, 176,

- 9, 11, 18, 29,


133, 144,

177,200,

150,

201,219,

154,

230,

315,361,

371,

372,

622, 661,

686,

789,816,832,842,851,867,868,870,887,
890
isopropyl

816,832,842,870

ketone

234, 237,

Mineral
Minesafe

- 156, 230, 279, 361, 691,

245,

279,

297,

371,

372,

382, 388,

- 832
- 201

wool slurry

Miners oil
Mirabilite

248,258,268,279,290,291,293,304,307,

Methyl

117,

164, 172, 201,219,

Mineral

- 26
isobutyl alcohol - 47, 49, 133, 159, 164,

3iO. 313,

156,

57,

ketone

isoamyl

164,

150,

115,

851,852,871,872

38, 43, 49, 57, 66, 83, 103,


156,

144,

104, 113,

Mineral

172,268
Methyl

- 238, 832
- 201
Mineral acids - 663
Mineral heating oil - 106
Mineral oil - 2, 5, 6, 7, 12, 29, 33, 36, 38,49,
Milk waste

234,237,239,241,245,248,258,268,279,
361,

ether - 195, 201

Methylisobutyl

- 832
- 381

119, 133,

- 621

glycerol

Methylhexylcarbinol

(see Foods)

60, 63, 67, 83, 84, 95, 102,

870
Methyl

- 258

- 871

Milk of magnesia

334,335,336,337-354,361,371,372,373,

ketone;

154, 219,

258,268,732,851

164,

172, 200,219,

- 43, 172, 402, 409

acid

Methyl

248, 258,268,

ketone

154, 237,245,

Methylsulfonic

157,

ethyl

- 144, 234, 258,


789, 816, 832,

sulfate - 29, 43, 57, 66, 150,

245,

ethyl

622, 663,

144, 230

styrene - 49, 164,201

154, 156,

Methyl

oil)

Methyl

239, 241,

Methyl

- 11, 103,

Methyl

153,

326,

- 832, 856

alcohols)

- 832

(wintergreen

237,

325,

(see Acetophenone)

- 832

Methylpolysiloxanes

268,279,385,388,390,402,409

34, 38, 43, 49, 53, 57, 60, 63, 66,83,


111,

oleate

870

- 361

Methyl

107,

- 691

- 57, 258, 292


- 201

Methylene

Methyl

Methyl

Methyl

792,816,831,842,851,

Methylene

377, 381

111,

Methylene

115,

622, 816,832,

- 201

154,

- 57, 258, 268, 292, 842,871

113,

- 229,

acrylamide

106,

bromide

57, 63, 83, 103,

361,

- 361, 832, 870


- 41, 43, 201
2-Methylpentane
- 363
3-Methylpentane
- 363

Methylene

29, 33, 38, 43,49,

- 20, 57, 156, 157,

(monomer)

268, 279,

842,851,870

- 201

blend

laurate

methacrylate

172, 201, 258,

- 691

bisthiocyanate,

- 227

Methyl
Methyl

- 156, 816
Sunoco

3XF

(see Sodium

- 871
sulfate)

- 377, 381
Missile fuels - 618
Mixed acid - 83, 150, 151, 222, 393, 397, 398,
Miscible

oil

421, 432,
775,781,846

436,

529,

622, 647,

655, 732,760,

390,

Corrosive Material

Mobil

oils and fluids - 279, 286,

300,

355, 363,

816,871

115,

Molasses (see Foods)


Molten

- 728

glass

acids and oxides

Molybdenum

disulfide

Molybdic

- 402, 409

- 49, 164, 622

- 381, 691,692,

acid

779,855

(almond)

Monochloroacetic
Monochlorobenzene
Monoethanolamine

315,

363,

371,

372, 377,

530,

622,

646,

661, 663,

692, 760,

789, 817,

832,

842,

851, 871,

glutamate

glutamate)
Monosodium

methyl

acid)

acid

Naphthalenesulfonic

acid, with sulfuric

acid

(see Sodium

Naphthoquinone

- 201

Natural

- 832

Natural

- 832
- 43, 83, 109, 148, 201,219,

Neodol

- 21, 133, 363, 832, 871

oil

reaction

Morpholine

sulfate - 692

Neon

Morrhua

- 832

Neopentyl

- 622

- 622

- 201

Morpholine

Motor

- 692

- 304, 307, 310, 313, 316

- 832

Navee

Neatsfoot

240,248,258,788,871

oils)

gas (see Gas, natural)

Naval stores
234,

- 201

acid

- 832

fats and oils (see also Edible fats and oils;

Vegetable

- 363

- 402, 409

sulfonic

Naphthylbenzene

Morea premic

Moth flakes

- 157

Naphtholsulfonic

(see Sodium

mixture

- 363,789

glycol - 201
- 622
Neutral oil - 156, 817
Neville acid - 363, 855
Neoprene

- 234

oil (see also Oils, lubricating

oils) - 1, 2, 5,

13, 21, 22, 26, 29, 49, 52, 57, 83, 96, 97, 98,

Nickel

- 790

107, 111,

Nickel

acetate - 29, 57, 268, 279,

119, 121,

133, 144,

156, 164,201,

233,

234, 235,

241, 248,

268, 274,

279, 280,

285,

291, 293,

301,

307,310,

313,

305,

316,

358,383,812,817,862,871,875,879

- 156, 817
- 104
Mulsoline 6000 - 201
Multicircuit
etch - 842, 871

Nickel

ammonium

Nickel

anolyte
bright

Nickel

chloride

245,

113, 115,

279,

377,

381,

388, 779,

787, 817,832,

Mustard

(see Foods)

Mustard

gas

Mustard

oil

Muthmans
Myristic
NPN
Nak

66,83,

156,

164, 172, 201,

268, 279,

363, 373,

374,

377,

385, 388,

390, 392,

393, 394,

395,

397,

381,

398, 402,

409, 436,

531,

738,

751,

760.

775, 778,

817,

832, 842,

768,

871,

632, 647,
788,

883,887,

890
(see s-Tetrabromoethane)

acid - 49, 164, 201, 832

- 1, 15, 24, 29, 33, 38, 43, 49, 53, 57,


109,

154,

245, 258,

Nickel-cobalt

- 833
- 728

Naphtha

151,

222, 237,

799,803,807,

- 363
- 622
liquid

- 29, 33, 34, 38, 49, 57, 60, 67, 83,

133,

219,

691, 735,

855

- 201

- 201

Nickel,

acid) - 150,

- 222, 531, 661, 775

sulfate

liquor

Mould oil

acid ,(see also Hydrochloric

363, 367, 396,

788,817,832,871,884

Mouthwash

Muriatic

- 661
- 530

acid

manganese

- 201, 363, 393, 436, 530, 531,

- 363

arsenate)

brake fluid

Mortar

of lead, cobalt,
acid

Naphthols

arsenate

- 402,409
- 402, 409, 692

Naphthalenesulfonic

622,692,760,832,855

- 62
(MSG)

887,

- 692

sulfonated

Naphthylamine

Monsels salt

oil

chloride

Naphthenic

Monosodium

Morpholine

309, 312,
398, 436,

(see Chlorobenzene)

and dinitrotoluene

172,

279, 300,

307,

Naphthanates

plasticizers

157, 164,

381, 393,

(see Chloroacetone)
(see Ethanolamine)

Mononitrotoluene

Mopar

156,

258, 268,

Naphthalene,

acid (see Chloracetic

Monochloroacetone

methyl

153, 154,
230, 248,

Naphthalene

- 133
Monel and Ni cleaning baths - 201

Monomeric

150,

177, 201, 219,

890

(see Ferric chloride)

Mondludropar

- 11, 29, 49, 53, 57, 63, 66, 83, 209,

133,

304,

Molybdenum

Molysite

Naphthalene

Index

113,

115, 133,

169, 172, 201,

150, 154,

156,

164,

268,

279,284,286,300,363,371,372,

394, 395,

397,398,

692, 728,

789, 799, 803,807,817,

842,851,871,883,887,890

529,

219, 230,
530,

155,

248,258,
393,

622,

compounds

Nickel

electrolyte

Nickel

nitrate

- 622

- 201
- 30, 33, 49, 57, 83, 113, 115, 119,

134, 154,

156,

164,

172,202,

219,237,

245,

258,

268,

279,

373,

374, 377,

381, 385,

388,

390,

393,

397,

398, 437,

661, 691, 738,

760,

768,778,788,817,832,871
Nickel

plating,

Nickel

plating solution

- 202
- 30, 38, 49, 58, 86, 115,

electrorefining

663,

135,

150,

826, 832,

279,

368, 531,

632,

- 201

extraction

Nickel

153,

871,884,885,891

154, 156,

164, 202, 259,

692, 726, 817, 834,

269,

843, 859,

947

942

Corrosion Resistant Materials Handbook

Nickel salts - 134, 150, 156, 279, 363, 646, 732,


817,832,851
Nickel soap catalyst - 202
Nickel sulfate - 30, 33, 34, 38, 50, 57, 60, 63, 84,
106, 113, 115, 119, 134, 151, 154, 156, 164,
172, 202, 219, 237, 245, 258, 268, 303, 306,
308, 311, 314, 363, 373, 374, 377, 381, 384,
385, 388, 390, 392, 393, 394, 395, 397, 398,
402, 409, 437, 531, 632, 661, 692, 728, 760,
768, 778, 783, 788, 799, 803, 807, 817, 832,
842,847,872,883,887,890
Nicotine - 30, 57, 67, 115, 150, 154, 219, 268,
279,531,851
Nicotine bentonite - 156,832
Nicotine salts - 156, 817
Nicotine sulfate - 156, 622, 663, 783, 832
Nicotinic acid - 30, 57, 113, 115, 150, 154, 258,
268,531,851
Niter cake (see Sodium bisulfate)
Niter cake solution - 726
Nitrana - 156
Nitrates - 663
Nitrating acid (see also Mixed acid) - 788, 799, 803,
807,883
Nitrating acid, spent - 202
Nitration benzol (benzene) - 156
Nitric acid - 2, 4, 6, 9, 10, 17, 26, 30, 33, 34, 35, 38,
43, 50, 53, 57, 60, 61, 62, 63, 66, 67, 84, 95,
102, 104, 106, 107, 108, 109, 111, 112, 113,
115,117,119,121,134,144,147,150,151,
152, 154, 155, 156, 157, 165, 169, 172, 177,
202, 219, 222, 223, 224, 225, 237, 239, 240,
245, 248, 258,268,
279,286,
291, 293, 294,
296, 300, 302, 305, 308, 311, 314, 363, 367,
369, 371, 373,374,
377, 381, 382, 383, 384,
385, 387, 388, 390, 392, 393, 394, 395, 396,
397, 398, 402, 410,412,
413,414,
415, 416,
425, 428, 432, 437, 442, 531, 532, 533, 622,
632, 639, 641, 642, 643, 644, 645, 646, 647,
652, 655, 661, 663, 664, 692, 693, 728, 730,
731, 732, 733,735,
738, 740, 751,756,760,
772, 775, 779, 781, 783,788,
791, 792, 794,
799,803,807,8
17,832,842,847,851,855,
883,884,887,890,891
Nitric acid, boiling - 413, 419, 420, 423, 425,
426, 428, 442, 444,445,
644, 645, 647, 666,
692, 693, 723, 738, 740, 741, 751, 756, 779,
855
Nitric acid-chromium
trioxide - 738
Nitric acid-ferric chloride - 733, 738, 752
Nitric acid fumes - 50, 165, 741
Nitric acid, fuming - 84, 119, 129, 134, 202, 219,
258,286,
300, 363,437,
532,732,
733, 738,
760,768,779,783,817,832,842,855
Nitric acid mixtures - 152, 202, 219, 222, 384,
415, 423, 428, 437, 533, 534,535,
536, 537,
693,733,738,752,760,768,775

Nitric acid mixtures with hydrochloric


acid - 533,
534, 644,833
Nitric acid-potassium
dichromate
- 738
Nitric acid-sodium chlorate - 738
Nitric acid-sodium
nitrate - 738
Nitric acid-sulfuric
acid mixtures (see Mixed acid) 693,781
Nitric acid-zirconyl
nitrate - 738
Nitric acid with chloride, fluoride - 418
Nitric oxide - 202, 377, 381, 732, 789
Nitriding gases - 437, 693, 760
Nitrilotriacetic
acid - 177
Nitro alcohols - 63
Nitrobenzene
- 13, 20, 30, 34, 43, 50, 57, 63, 84,
106, 115, 119, 134, 150, 153, 154, 156, 157,
158, 165, 172, 177, 202,219,
222, 229, 237,
241,245,248,
258,268,279,286,
300, 304,
307, 310, 313, 315, 363, 377, 381, 385, 390,
393, 398, 402, 410, 622, 661, 693, 760, 775,
789, 799, 803, 807, 817, 832, 842, 851, 872,
883,887,890
2-Nitrobutanol
- 157, 622
Nitrocalcite
(see Calcium nitrate)
Nitrocellulose
- 661, 783
Nitrocellulose
lacquer - 106, 622
Nitrochlorobenzene
(see Chloronitrobenzene)
Nitro compounds - 42, 43
Nitroethane
- 279, 363, 622, 817, 832,872
2-Nitro-2-ethyl-1,3-propanediol
- 622
Nitrogen - 84, 156, 202, 248, 258, 279, 363, 537,
622, 632, 646, 652, 731, 732, 789, 817, 832,
872
Nitrogen dioxide - 258, 402, 410, 832
Nitrogen, liquid - 202
Nitrogen oxide - 67, 134, 154, 219, 279, 402,
410
Nitrogen peroxide - 832
Nitrogen solutions (fertilizer)
- 172, 796, 832
Nitrogen tetroxide - 157, 363, 402, 410, 623, 783,
817,832
Nitroglycerine
- 144, 234, 258, 268, 393, 402, 410,
437,623,661,663,760
Nitroglycol
- 268
Nitromethane
- 84, 157, 203, 219, 234, 241, 248,
258,279,363,623,817,833,872
2-Nitro-2-methylpropanol
- 157
hlitrooctane
- 156
Nitroparaffin
- 623
Nitrophenol
- 177, 203, 393, 402, 410, 623, 661
Nitropropane
- 30, 156, 279, 363, 377, 381, 623,
817,833,842,872
Nitrosyl chloride - 156, 393, 398, 661, 693, 732,
817
Nitrosylsulfuric
acid - 377, 381, 661
m-Nitrotoluene
- 234, 403, 410
Nitrotoluenes
- 623, 661
p-Nitrotoluenesulfonic
acid - 203

Corrosive

Nitrous

acid

- 57, 67, 84, 134, 156, 203, 219, 258,

Octyl

268,

279,

393, 397,

760,

779, 783,

735,

n-Octvl

788,

794, 799, 803, 807,

855,

Octyl

Index

- 156

aldehyde

661, 732,

398, 437,

Material

chloride

- 177

cresol - 115

- 235
- 843, 873
Oil of bitter almonds - 833
Oil, 3-in-One

883

- 663
Nitrous oxide - 30, 53, 57, 84, 150, 151, 234, 258,
Nitrous

gases

Oil of mirbane

268,402,410,437,623,693,760,778,789
Nitroxanthic

acid (see Picric acid)

Nonanedioic

acid

Nonautomotive
Nonyl

Oil of vitriol

- 203
- 13, 14, 21

- 145, 226
sulfide - 256

alcohol

- 203,693

Nonylphenol
Nonylphenol,

- 203

ethoxylated

Nonylphenoxytriethoxyethanol

sulfate,

sodium

- 203

salt

saltpeter)

(see Calcium

oils; Motor

oils; Synthetic

- 872

No. 4

102, 106, 112,

139, 156, 210, 235,

261, 275,

279,

280,

283,

284,

301,

307,

310, 313,

360,

361, 363,

304,

281, 282,
316,

285,

364, 365,

366,

367, 537,

538, 813,

815, 818,

819, 820,

827,

833, 842,

843,

864, 865,

Oils, ASTM

(see ASTM

862,

(see Ammonium

nitrate)

- 231

301, 361,817

- 30, 32, 53, 57, 112, 115, 150, 151,

Oils and fats

saltpeter

oils)
284,

- 377, 381

Oils, saponifiable

- 258

dl-Norvaline
Novocain

oils; Essential

oils) - 13, 14, 21, 67,

276, 277,

Oils, SAE - 156, 279,

nitrate)

Norway

acid)

867,868,872,873,875,876,878,879,880

Norge niter (Norwegian


Northia

(see Nitrobenzene)

(see Sulfuric

Oils (see also Crude oil; Lubricating

greases and oils

Nonylisophenyl

Oil of birchwood

154, 157, 258,

304,

307, 310,

313,

316, 403,

410,617,852,887,890

Nuclear

fuel recovery

Nuclear

steam generator

and waste - 729

Nuclear

swimming

Oils of vegetables and spices


Oil-water

tubing - 729

pool reactor

liner

- 203

emulsion

- 623
- 403, 410

Ointments

- 203, 729
Nujol (see Mineral oil) - 234

Oleates

Nutmeg

Oleic acid

Nuclear waste

Olefin

oil (see Essential oils)

- 203

Nut oil, ground

- 63

- 693

- 203
- 5, 6, 10, 17, 26, 30, 33, 34, 36, 50, 53,

(Al) sulfonate

57, 60, 63, 66, 67, 84, 95, 102, 104,

106,

111,

Nylon

- 623
Nylon salt - 788

113, 115,
153, 154,

156,

165,

172, 177, 203,

219, 222,

Nyvac fluids - 279, 817

237, 239,

245,

259,

268, 279,

281,

300,

306, 309,

312,

314, 363,

371,

373, 374,

- 363

O-A-548A
OPM

377,

- 203

381,

398, 403,

- 363

O-T-634b
Oakite

117,

- 153, 203, 872

- 833
- 833

387,

623, 632,

728, 735,

760,

775, 779,

818,

833,

stripper

Olein

Ocenol

- 30, 150,789

- 165, 203

- 363, 872
- 363, 833, 872

Oleum
acid)

- 833
- 157

(see also Freon) - 833


- 84, 103, 156, 219, 258, 279, 363, 817,

393,
Oleum

acid

- 50, 165, 203, 225

Octanoyl

chloride

alcohol)

- 230

OMO

solution,

Onion
Ores

Octyl

alcohol

- 177, 226

377, 381,

732,

775,

784,788,

- 130

5%

products

(see Foods)
21%

- 134

- 623

Ore smelting gas

- 203

Organic

chlorides

Organic

food acids

- 693,

- 36

172,203,

363,

Olive oil (see Foods)

OPC 60 solution,

alcohol,

693,731,

- 30, 43, 50,

165,

300,

(see Ocenol)

acetate - 156

Octyl

279,

- 203

Octene - 219

- 103, 145, 279, 363, 789, 817, 833,

151, 154,

spirits - 156, 363,833


alcohol

Octyl

839,848,856,872

268,

398, 584,

Olin 58981

833

259,

acid, fuming)

150,

817,852,873,887,890
Oleyl

(see Octvl

788,
852,

trioleate)

(see also Sulfuric

219, 222,

n-Octane
Octanoic

783,

843, 847,

- 203

57, 64, 119, 134,

Octafluorocyclobutane

Octanol

393,

661, 663,

- 383

(see Glyceryl

Oleoparathion

Octachlorotoluene

acid

303,

855,883,887,890

Oakite

alcohol

390, 392,
652,

807, 817,

Oleic compounds

n-Octadecyl

388,

693, 726,

acid materials

Octadecenoic

437,

148, 150, 151,

799, 803,

solvent materials

acid (see Linolenic

370,

382, 383,

Oakite

Octadecatrienoic

134, 145,

410,

Oakite

Octadecane

121,

732, 733

943

944

Corrosion

Resistant Materials Handbook

Organic

mercaptan

- 200

Orlon
Oronite

151, 154, 156, 172,204,


280,300,363,421,623,632,
817,833,852,855

- 216

Organic waste

- 623
- 305, 308, 310, 313, 316, 363, 873

Orthoboric
Orthocide

- 873

Orthocryl

yarn size

Orthoformic

Palm oil

- 24, 873

Paper

- 737

acid

fluid

Cooking

acid - 693

- 280, 363

liquor - 539,

Spent liquor - 539,540

- 203

Paper, alkaline

- 403,410
Oxalic acid - 2, 30, 34, 50, 53, 57, 60, 64, 66, 67,
Oxalates

84, 106, 109,

113, 115,

150, 151,

153,

219, 222,

225, 237,

306, 309,

312,

374,377,

381,382,385,

119,

154, 156,

134,

145, 148,

165, 172,

245, 259,

315, 363,

177, 203,

268, 280.

368, 370,

371,

388,390,392,

394, 395,

396,

397, 398, 403,410,412,416,

437,442,

538,

609, 623,

693, 726,

731,

732, 735, 738,

775, 779, 783,

788,

liquor

Pulp stocks

Paper alum (see Aluminum

373,

Paper and pulp mill gas, noncondensable

393,

Paper, bleach solutions

- 204
- 204, 206, 539, 724

Paper machine

760,

768,

Paper mill liquor

795, 799, 803,

807,

817,

Paper, neutral

726,738,779,855
acid

- 661

sulfite

- 541
- 542
Spent liquor - 542
Cooking

647, 693,

liquor

Pulp stocks

Paper, paperboard

- 542
- 542

waste

Oxidizing

agents - 116, 285

Oxidizing

gases

Paper pulp, bleached

Oxidizing

NaCI-HCI

Paper pulp slurry - 694

Paper, parchmentizing

- 53, 203, 693


solution - 422
acid - 623

Oxogluconic
Oxymethylene

- 30, 57, 66, 67,84,

115,

134, 147,

150,

280,

363,

377,

646, 652,

663,

731, 732,

219, 259,

381,

639,

623, 632,
liquid

Oxygen-nitrogen
Ozone

- 20,26,

154,

- 361, 831, 873


mixtures - 203
30, 57,84,

156, 157,203,

280, 285,

Paper, white water


Acid

- 543

Groundwood
Neutral

789,817,873
Oxygen,

363, 539,

115, 145,

147, 150,

204, 219,

234,

259,

268,

623, 632,

639, 817,

833,

- 544
- 544
Paracetic acid - 30
Parachloride - 230
Soda

Sulfate

Paraffin-

- 363
P-S-661 b - 363

392,

types (Citgo)

- 280, 817
539,

623,

Paint and varnish remover

- 16, 24, 25

- 156
- 280
naphtha

- 432, 632, 789

- 291,

plating solution

410,

652,

623,

377,

134,
381,

783, 789, 817,

- 234, 789

oil

Paraffin

ozone - 119

Paraffin

wax - 403,

Par-al-ketone

- 884

- 13, 21
Palmitic acid - 30, 53, 57, 67,84,

110, 119,

268, 280,

Paraffin

Paraldehyde

363,833,873

- 843, 872

Palmarose

106,

177,234,

410
(paraform)

- 156, 280, 623,

789,817,833,873

Paint vehicles
Palladium

393, 403,

Paraformaldehyde

Paint thinner,
Pale oil

156,

852,873
789, 817,

843,873

Paint solvents

1,57,60,64,84,

141, 150,

Paint - 15, 16, 24, 256, 280,

- 543
- 543

- 543
- 544

Newsprint

P-D-680

Paint oil

sulfite

Paperboard

852,873

Pacemaker

- 543

Paper stock - 694

268,

154, 156, 203,

- 694

Paper, sizing solution

(see Formaldehyde)

- 189,206

- 203
- 541, 693, 694, 724
pulp stocks - 541

Paper, groundwood

752,

acid, with sulfuric

sulfate)

Paper and pulp mill condensate

652, 661,

642, 646,

- 418, 419, 444,445,

acid, boiling

pulping

- 540, 693
- 540
Spent liquor - 540, 541
Cooking

303,

833,843,847,852,855,883,887,890

Oxygen

693

Pulp stocks - 539

- 363

Osmose Co. premix

Oxalic

- 623

Paper, acid pulping

Orthoformylbenzenesulfonic

Oxalic

(glyceryl tripalmitate)
- 833
- 145, 156, 234, 280, 539, 623, 788, 817,

833,843,873

OS 45 Hydraulic
OS 70

Palmitin

acid (see Boric acid)

219, 225, 259,268,


652,728,788,

Para oil

- 234

Paraplex

G62

- 119,

134, 623, 789

- 363, 873
- 843, 873

Para San - 156

oil

134, 145,

150,

Parathion

- 204, 796

Corrosive

Parco

- 204

Perfume

- 833

acid - 370, 371, 377, 381


- 843, 872
Penetrox lubricant - 24
Penicillin - 23, 231, 623, 874
Pennyroyal oil - 13, 21
Penolalube - 874
Penola univis - 874
Pentaborane - 783
Pentachlorobenzamide
- 157
Pentachlorodiphenyl
- 833
Pentachlorodiphenyl
ketone - 833
Pentachlorodiphenyl
oxide - 833
Pentachloroethane
- 177,292,
623, 661
Pentachloroethylbenzene
- 833
Pentachlorophenol
- 41, 42, 43, 156, 280, 623,

Pelargonic
Pella oil

663,796,874
Pentachlorophenylbenzoate

- 833

Pentaerythritol

- 623

Pentaerythrityl

tetranitrate

- 623

- 177, 285

- 103
triphosphate

- 833

- 234, 280, 817, 874

Pentasol

perborate)

- 834

Petrol

- 106, 110, 119, 834

(see also Gasoline)

Petrolatum

- 156, 259, 874

Petroleum

- 53, 60, 64, 67, 85,

ether (ligroin)

106, 112,

115,

119, 132,

267,

361,

392,

356,

156,

651, 735,

Petroleum

- 145, 231, 624


carbolated - 231
liquefier - 150, 154

Petroleum

oil and waxes, water

Petroleum

oils (see Crude oil)

jelly

Petroleum

jelly,

products

Petroleum

spirits

Phenetole

(see Ethylphenyl

Phenethyl

alcohol

(carbolic

ether)

acid) - 1, 5, 8, 13, 14, 20, 22, 26,


109,

115, 119,

172,

177, 204,

237,

239,

241,

245, 249,

253,

259,

280,

300,

303,

306,

309,

312,

315,

357, 364,

382, 388,

390,

392, 393,

394,

395,

396,

397,

632, 646,

651,

546,

614, 624,

663,

694,

728, 732,

787,

789, 812,817,

735,

- 204

761,

765, 775,

834,

840, 843,

- 694

Phenol formaldehyde

Pepsin - 694
acid - 154,268,

- 155,694,874

165,

172,

- 43, 204, 874


Phenolphthalein
- 547, 694
Phenols - 67,204

204, 219,

237,245,

259, 268,

280,

363,

367,

Phenol solution

370,

371,

377, 381,

388,

389,

393,

394, 395,

397,

398, 403, 410,

437,

623,

646,

694, 732,

Phenolic

623

- 30, 33, 53, 57, 64, 67, 85, 108,


150, 151,

154, 156,

752,760,788,817,833,852,855,883
Perchloroethylene

(see Tetrachloroethylene)

Perchloromethane

(see Carbon

Perchloromethylmercaptan
Perchloryl

fluoride

- 694

Perchloryl

fluoride

mixtures

Perfluoroxylene

268,274,

- 67, 280

Phenoldicarbonate

acid

225,

852,854,874,887,890
Phenolates

oil (see Essential oils)

115, 135,

219, 222,

153,

165,

661,

109,

150, 151,

157,

779, 783,

Perchloric

135,

156,

- 874
Pentylamine
- 226

Peracetic

- 204

emulsion

- 624

398, 437, 441,

Penthane

Pep Set

259,

789, 816,

- 250, 843
- 834
Petroleum thinner - 834
Pharmaceuticals
- 432, 545, 546, 792,884
Petroleum

Pentene - 229

Peppermint

172,204,
783,

823,839,874
Petroleum

67, 73, 106,

623,694,842,852

Pentasodium

(see Sodium

30, 33, 34, 36, 38, 43, 50, 53, 57, 60, 64, 66,

- 1, 67, 84, 103, 106, 156, 229, 280,

Pentanol

peroxide)

- 50, 165, 728

- 57
- 268
Persulfuric acid - 661
Pesticides - 544, 545, 612

Phenol

- 833

Pentamethyleneamine

Pentanedione

bleach

Persulfate

iso)

Pectin (see Foods)

363,544,

Peroxide

Perphosphate

carbonate)

Pear oil (see Amy1 acetate,

Pentane

- 663

(see Hydrogen

Peroxyhydrate

Pearl ash (see Potassium

- 834

Peroxide
Peroxydol

280,363,623,694,817,833,843,873

- 226

5DA40

white

Permanganates

sulfate)

(see Foods)

- 62, 134, 135, 145, 153, 204, 228,

Pear alum

alcohol

Permanent

Patent alum (see Aluminum


Peanut oil

945

Cadenza - 859

Paris green and lime

Peanut butter

Index

- 23

Perfume

- 156
Parkerizing solution - 344
Parker-O-Lube
- 363,873

Material

- 157

tetrachloride)

- 768

resin

-95,

111, 117,

142,

374,

377,

381, 385,

738, 752,

768,

799, 803,

371,

372, 373,

546,

547,

306,

135,

303,

315, 364,
410,

121,

259,

403,

309.312,

807852,883
Phenolsulfonic

acid

403,410,661,
2-Phenoxyethanol
Phenylacetic

- 50, 85, 109, 165, 204, 259,

694,788,834

Phenol trinitrate

- 738

104,

145,204,219,234,

acid

- 834
(Phenyl

- 547

Cellosolve)

- 226,874

946

Corrosion

Resistant

Materials

Handbook

697, 698, 728,

729,

Phenylamine

(see Aniline)

752, 756,

760,

768, 775,

Phenylarsine

- 547

792, 793,

796,

799,

Phenylacetonitrile

(see Benzyl

Phenylbenzene

(see Diphenyl)

Phenylcarbinol

(see Benzyl

Phenyl Cellosolve
Phenyl

chloride

Phenylethane

(see Ethyl
acetate

Phenylethyl

ether

Phenylformic
Phenylglycine,

- 663
- 63, 226

tetra - 439,

(see Ethyl

phenyl

salt - 259.
268,

364,834,

153,

- 30, 57, 150,

hydrochloride

acid (see Phenol)

- 661

Phenylmethane

(see Toluene)

Phenylphenol

- 204,259,
p - 663

sodium

663

Phorone

- 834

- 30, 150, 151, 154, 177, 219, 259,

ester oils - 156, 280

Phosphate

esters

Phosphate

mix

Phosphate,
Phosphate

acid scrap liquor


acid slurry - 697

Phosphoric

acid, wet process - 697, 698

Phosphoric

anhydride
acid

chloride

and yttrium

(see Phosphorus

pentoxide)

I 795
acid-phosphoric

acid - 698

- 624

suspensions

85, 219, 437,

554,

642,

698, 732,

- 30,259,269
- 145, 234,624
Yellow - 30,57,
115, 152, 154,259
269

- 204

661,698,
172,

(see Phosphoric

acid - 697, 725

- 42, 43, 237, 245, 386, 390,

Phosphorus

Phospholeum

- 696

- 44, 45

acid-sulfuric

gases - 726
- 204, 383, 663, 692

- 891

solution

Phosphoric

chloride

Phosphatizing

acid

Phosphoric

bromide

rock acidulation

vapors

- 204

oxysulfide

732,

- 44, 393, 403, 410, 728


- 43, 377, 381, 393, 403, 410,

733

- 34, 43, 53, 106, 135,

oxychloride

177, 205, 259,

393, 403,

410,

554,

was solution

acid - 1, 2, 9, 10, 17, 30, 33, 34, 35,

38, 43, 53, 57, 60, 61, 64, 66, 67, 85, 102,

- 157, 259, 661


- 624
(anhydride)
- 30, 50, 57,85,

Phosphorus

pentachloride

Phosphorus

pentasulfide

Phosphorus

pentoxide

115, 150, 152, 154, 165, 205,219,259,698,


778,799,803,807,852,874,883

106, 109,

112,

113,115,

119,

121,

135,

145,

Phosphorus

pentoxide,

molten

147, 150,

151,

152,

155, 156,

157,

158,

177, 204,205,219,222,

883
Phosphorus

sesquisulfide

280,294,

Phosphorus

tribromide

Phosphorus

trichloride

- 205, 624
- 661
- 30, 50, 53, 57,85,

165,

169,

172,

237,

239,

240, 245,
302, 305,

300,

301,

370,

371, 373,

387,

388,

154,
249,

259,269,

225,

308,

311,

314,

364,

367,

374,

377,

381,

382,

383,

386,

115, 150,

390, 392,

393,

394,

395,

396,

397,

245,

432,

437,

769,778,788,852,874

151,

249, 259,

398, 403,410,

413,420,

442,

547, 548,

549,

550,

551,

552, 624,

632,

Phosphotungstic

639,

641, 642,

643,

644,

645,

646,

647,

652,

Photographic

663, 664,

665,

666,

694,

695,

696,

655, 661,

425,427,

661,

732,738

acid, poly)

720
Phosphoric

Phosphoric

Phosphorus

salts

Phosphor

acid-nitric

acid pickling

- 624

Phosphate

- 647, 738

Phosphoric
Phosphoric

White

acid waste

Phosphate

- 204, 205, 222, 552,

647,696,725,752,768,775

Phosphorus

phosphoric

Phosphonitrilic

acid mixtures

761
Red

- 834,874
- 204

rock

acid mist - 696

Phosphoric

Phosphorus,

- 690

Phosphate

738, 741,

acid fumes - 165, 696, 725

Phosphor

268,377,381,393,400,408,661,694,789
Phosgene, chlorobenzene

- 413, 419, 420, 421, 427,

645, 647, 666, 723,

Phosphoric

Phosphorous

- 11, 18,280,364,817,834,874

Phosgene

763

Phosphoric

554,661

- 694

Phenylpolysiloxane

644,

Phosphorous

salt - 259

Phenylpiperazine

444,

553,554,

154,259,268

Phenylisocyanate

727,

acid, boiling

752

acid)

- 219,

259,

428,

ether)

874

Phenylic

843,

acid

Phosphoric

potassium

Phenylhydrazine

790,

817,834,

- 176
- 788
poly - 205, 834
super - 51, 167, 205, 213, 547, 718, 725, 837

benzene)

acid (see Benzoic

Phenylhydrazine

735, 738,

ortho

(see Diphenylether)
alcohol

803, 807,

733,

783, 788,

meta

- 843

Phenylethyl

779,

hypo - 198

(see Chlorobenzene)

Phenylethyl

731, 732,

847,852,855,883,884,888,890,891
Phosphoric

alcohol)

(see 2-Phenoxyethanol)

Phenyl compounds
Phenylether

cyanide)

154, 165,
269,
acid

- 799,803,807,

177, 205,

364, 386,

390,

- 554, 555
- 738, 769, 849

emulsions

106,

219,237,
661,

738,

Corrosive

Photographic
solutions, developers - 16, 24, 25, 30,
57, 85, 114, 115, 119, 127, 150, 153, 154, 191,
193, 194, 205, 210, 232, 233, 269, 275, 276,
280, 358, 555, 728, 780, 783, 813, 826, 840,
843,849,852,862,874,884
Phthalic acid - 34, 50, 64,85,
157, 165, 172, 205,
219, 222, 237, 245, 259, 280, 370, 371, 386,
388, 390, 393, 403, 410, 555, 738, 775, 783,
788
Phthalic anhydride, 85, 151, 205, 377, 381, 397,
398, 432, 437, 555, 624, 657, 661, 698, 732,
761, 783,799,803,806,874,883
Phthalic anhydride, vapors - 698
Phthalic, maleic anhydride - 437, 761
Phthaloyl chloride - 230
Pickle alum (see Aluminum
sulfate)
Pickles (see Foods)
Pickling solution
Acid - 38, 50, 53, 115, 165, 169, 301, 364,
632, 726, 729, 732, 733, 843, 852,874,
891
Alkaline - 53
Picolines - 624, 874
Picric acid - 30, 50, 58, 66, 67, 85, 113, 115, 135,
150, 154, 156, 172, 205, 219, 222, 237, 245,
259, 269, 301, 303, 306, 309, 312, 315, 364,
370, 371, 373, 374, 377, 381, 382,388,
390,
393, 410, 437, 442, 661, 726, 761, 775, 783,
788,834,843,847,852
Picric acid, alcohol solution - 165, 205, 398
Picric acid, water solution - 156, 205, 280, 303,
364,403,779,799,803,807,817,855,883
Picronitric acid (see Picric acid)
Pigment slurry - 205
Pimelic ketone (see Cyclohexanone)
Pine coating oil - 156
Pinene - 280, 364, 624,817,834,874
Pine needle oil - 235
Pine oil - 112, 156, 172, 235, 280, 364,789,817,
834,843,873,874
Pine tar, 156
Pine tar oil - 874
Pipe line cleaner - 843, 874
Piperazine - 624
Piperazine hydrochloride
- 280, 817
Piperidine - 157, 235, 364, 834
Pipe Seal Compounds - 148
Pitch - 280
Plaster - 624
Plasticizers - 156, 256, 259, 291, 293, 624, 843,
874
Plastic01 - 843
Plating baths - 843, 884,885
Plating solutions - 30, 34, 38, 47, 48, 53, 58,85,
109, 115, 135, 150,151,
154,222,259,
269, 364, 368, 378, 382, 775,834,
843,
852,884,885

Material

Index

Aluminum
- 182
Antimony
- 698,834,843,885,891
Arsenic - 834, 843, 885
Brass - 30, 471 58, 85, 115, 135, 150, 153, 154,
160, 185, 259, 269, 368, 834, 843, 884,
885,891
Bronze - 160, 185,843,884,885,891
Cadmium - 30, 47, 58, 85, 115, 135, 150, 153,
154, 160, 186,259,269,368,
834,885,891
Chromium
- 30, 58, 85, 115, 135, 153, 161,
188, 195, 254, 259, 269, 280, 357, 364,
368, 394, 395, 647, 732, 737, 750, 780,
818,834,861,884,885,891
Cobalt (nickel) - 812, 834
Copper - 30, 48, 58, 85, 115, 135, 150, 153,
154, 161, 189, 190, 259, 269, 368, 834,
843,861,884,885,891
Copper Brite - 161,859
Gold - 30,49,
58, 85, 115, 135, 150, 153, 154,
163, 195. 259, 269, 368, 834, 843, 884,
885
lndium115, 135, 150, 153, 154, 843, 884,
885
Iron - 49, 163, 198, 259, 834, 843, 884, 885
Lead - 30, 58, 85, 115, 135, 150, 153, 154,
164, 199, 259, 269, 368, 523, 698, 834,
843,884,885
Nickel - 30, 38, 49, 58, 86, 115, 135, 150, 153,
154,156,
164,202,259,269,
279, 368,
531,692,726,817,834,843,859,871,
884,885,891
Palladium - 884
Platinum - 109, 834, 884
Rhodium - 30, 58, 115, 135, 150, 153, 154,
207,259,269,884,885
Silver-30,
38, 50, 58.86,
115, 135, 150, 151,
153, 154, 166, 207, 259,269,
368,834,
843,884,885
Speculum - 259
Tin - 30, 51, 58, 86, 115, 135, 150, 153, 154,
167, 214, 259, 269, 368, 698, 834, 843,
884,885,891
Zinc - 30, 51, 58, 86, 115, 135, 150, 153, 154,
168,217,259,269,368,834,843,884,
885,891
Platinum - 790
Plus 5 - 205
Pneumatic service - 364
Polyacrylamide
- 205
Polyacrylonitrile
- 157
Polyamine - 698
Polycarbonate
- 16, 23
Polychlorocyclohexane
sulfide - 205
Polychlorophenates
- 205
Polyco 2631 - 205
Polyderm moisturizer
lotion - 874
Polyester resin - 280, 818

947

948

Corrosion

Polyester

Resistant

white

enamel,

Polyethylene

- 624,

Materials

water

reducible

- 205

Potassium

789

Polyethylene

glycol

600E

glycol

distearate

Polyethylene

glycol

- 259
- 229

monolaurate

Polyformaldehyde

- 229

(see Paraformaldehyde)
in water

polyphenyl

Polyoxymethylene

- 205

- 624

Polypropylene

glycols

135,

50,

145,

58,

150,

64,

154,

86,

106,

156,

165,

172,

205,

219,

232,

260,

269,

280,

377,

381,

397,

398,

403,

410,

437,

555,

624,

661,

699,

735,

738,

761,

769,

778,

799,

803,

807,

isocyanate

86,

- 198,

205

(see Paraformaldehyde)

Polypropylene

- 19, 30,

119,

393,

Potassium

emulsion

Polymethylene

115,

874,883,888,890

- 38, 259

Polymer-toluene

bromide

113,

Polyethylene

Polyglycol

Handbook

carbonate

109,

113,

- 30, 43, 50, 58, 60, 64, 66,

115,

119,

135,

152,

154,

156,

165,

172,

205,

206,

219,

237,

245,

260,

269,

280,

377,

381,

382,

386,

388,

390,

392,

393,

398,

403,

410,

437,

555,

556,

647,

652,

661,

699,

728,

731,

732,

735,

761,

778,

783,

788,

Polystyrene

794,

799,

803,

807,

818,

834,

843,

874,

883,

Polyurethane

888,890

- 663

- 624, 789
- 280, 789
Polyurethane,
foam - 23, 818
Polyvinyl
acetate
- 153, 172, 205,
624,

259,

364,

783,874

Polyvinyl

acetate

latex

Polyvinyl

alcohol

- 165,

Polyvinyl

alcohol

emulsion

Polyvinyl

butyral

resins

Polyvinyl

chloride

Polywet

ND-2

Powderbase

Max

Potash

(see Potassium
brines

Potash

mine
ore

170,

172,

205,

259,

624

Factor

206

carbonate)

- 205

- 624
slurry - 205

Potassa
Potassium

acetate

hydroxide)

- 86, 157,

280,

364,

818,

834,

874
Potassium

acid

Potassium

aluminum

chloride

Potassium

aluminum

sulfate

potassium

sulfate

(bisulfate)

- 30
- 260

- (see Aluminum

sulfate)

Potassium

amyl

Potassium

antimonate

xanthate

Potassium

34Baume

Potassium

bicarbonate

- 269

260,

269,

280,

377,

381,

393,

397,

398,

403,

410,

437,

556,

624,

661,

728,

735,

761,

778,

783,

788,

799,

804,

808,

818,874,883,888,890
chloride

45,

46,

135,

- 1, 12,

50,

58,

151,

232,

237,

245,

249,

260,

269,

308,

311,

314,

364,

373,

374,

377,

381,

386,

388,

390,

392,

393,

394,

395,

403,

410,

437,

442,

556,

624,

632,

646,

652,

661,

699,

732,

735,

738,

752,

761,

769,

775,

778,

783,

788,

799,

804,

808,

818,

834,

883,888,890

Potassium

chloride

Potassium

chloride,

Potassium

chromate

152,

154,

652,

661,699,

brine-

156,

260,

Potassium

cyanate
cyanide
151,

152,

156,

177,

206,219,

237,

245,

260,

269,

364,377,

381,

388,

390,

393,

394,

395,

396,

403,

410,

437,

632,

652,

699,

761,

778,

788,

799,

804,

808,

818,

- 30, 50, 64, 86, 102,

113,
172,

661,

834,844,875,883,888,890

390,

393,

397,

661,

698,

783,

788,

874,

165,
843,

121,

150,

151,

154,

156,

165,

dichromate)

172,

177,

206,

219,

260,

269,

280,

301,

303,

306,

309,

311,

314,

364,

367,

386,

393,

396,

- 30, 58, 60, 177,

397,

398,

403,

410,

437,

442,

555,

624,

652,

733,

735,

738,

761.

769,

222,232,269,392,661,775

- 788
- 30, 280,

303,

306,

309,

311,

314,661,699

- 624
- 30, 113,

115,

135,

150,

154,

661,

699,

726,

732,

778,

783,

799,

804,808,818,834,

- 30, 106,

232,260,269,280

113,

115,

135,

150,

844,847,

874,875,883,888,890
Potassium

dichromate,

Potassium

ethyl

Potassium

ferricyanide

86,

156,260,269
bromate

- 30, 50, 58, 64, 86, 106,

119,

- 661
sulfate)

dichromate
115,

(see Potassium
(acid

Potassium

172,

113,

888,890

154,205,

624,

- 110

388,

Potassium

135,

437,

135,

156,

borate

387,

119,

280,382,

Potassium

280,

- 30

154,

bitartrate

269,

- 699

119,

- 30, 280, 364, 834, 874


- 624
- 12, 19, 30, 34, 38, 58, 86, 115,

269,

Potassium

brine

761,788,835,844,874

cuprocyanide

152,

bisulfite

chloride

- 30, 58, 86, 115,

260,

Potassium

699

sodium

Potassium
Potassium

113,

115,

172,

306,

150,

bisulfide

165,

43,

113,

222,

245,

Potassium

156,

41,

303,

135,

bisulfate

155,

39,
106,

219,

237,

bifluoride

33,
86,

295,

119,

Potassium

154,

67,

206,

232,

Potassium

19, 30,
64,

280,

115,

bichromate

60,

152,

205,

Potassium

135,

219,

843,847,874,

(see Potassium

119,

205,

119,

- 14

- 30, 58, 86, 115,

156,

44,

- 384
fumes

chlorate

154,

Potassium

- 205
cream,

Potash

- 50, 165, 874

- 33, 50
- 624
latex - 50, 165, 205,

Potash

Potash

Potassium
219,

115,

sulfuric

xanthate
119,

acid

- 269,

- 19, 30,44,
135,

136,

- 135, 726

738
50,
145,

58,

154,

64,
156,

165,

172,

206,

232,

237,

245,

260,

269,

377,

381,

388,

390,

393,

403,

410,

437,

661,

699,

735,

738,761,769,778,783,875

Corrosive

Potassium ferrocyanide
- 50, 58, 64, 86, 115, 135,
136, 154, 165, 172, 206, 219, 237,245,
260,
269, 280, 388, 390, 397, 398, 403, 410, 437,
699, 735, 761,778,
783,799,804,808,883
Potassium fluoride - 30, 34, 38, 1 15, 119, 154,
206,260,269,280,393,661,663,756
Potassium fluoride, with HP - 286
Potassium hydrate (see Potassium hydroxide)
Potassium hydroxide - 1, 2, 28, 30, 34, 38, 44, 50,
53, 55, 58, 60, 64, 66, 67, 74, 82, 86, 106, 109,
113, 115, 119, 136, 145, 147, 149, 150, 151,
154, 156, 157, 165, 169, 172, 206, 219, 222,
226, 237, 245, 249, 254, 260, 265, 269, 275,
280, 294, 301, 302, 305, 308, 311, 314, 364,
367, 370, 372, 373, 374, 377, 381, 382, 383,
386, 388, 390, 392, 393, 394, 395, 396, 398,
403, 410, 437, 555, 556, 624, 632, 646, 647,
652, 661, 663, 699, 700, 726, 728, 731, 732,
733, 735, 739, 752, 761, 769, 775, 778, 783,
788, 790, 791, 792, 794, 799, 804, 808, 812,
818,834,844,852,875,883,884,888,890
Potassium hydroxide,
boiling - 419, 647, 699,
739,752,756,769,
778
Potassium hydroxide mixture - 752
Potassium hydroxide,
molten - 731
Potassium hypochlorite
- 30, 86, 156, 260, 269,
661, 699, 778,875
Potassium iodate - 661
Potassium iodide - 12, 58, 60, 136, 145, 222, 232,
269, 280, 392, 624, 661, 700, 735, 739, 752,
769,775,778,788,875
Potassium iodide-iodine
(see Iodine, KI solution)
Potassium metabisulfite
- 661
Potassium, molten - 642, 646, 728, 732
Potassium muriate (chloride) - 834
Potassium nitrate - 30, 34, 50, 58, 64, 66, 86, 106,
113, 115, 119, 136, 147, 152, 154, 156, 165,
172, 206, 219, 222, 237, 245, 260, 269, 280,
364, 373, 374, 377, 381, 386, 388, 390, 393,
396, 403, 410, 437, 624, 657, 661, 700, 735,
761, 769, 775, 778, 783, 799, 804, 808, 818,
834,875,883,888,890
Potassium nitrite - 663, 752
Potassium oxalate - 87, 156, 206, 393, 403, 410,
437, 735, 761,778,784,875
Potassium oxide - 835
Potassium perborate - 30, 115, 119, 136, 154,
260,269
Potassium perchlorate - 58, 106, 113, 115, 119,
136, 152, 154,260,269,557,
700,739
Potassium perchlorite - 30
Potassium perfluoroacetate
- 875
Potassium permanganate
- 12, 38, 44, 50, 58, 64,
66, 87, 106, 113, 115, 119, 136, 145, 150, 151,
152, 154, 156, 157, 165, 172, 177, 206, 219,
232, 240, 249, 260, 269, 280, 303, 306, 308,

Material

Index

311, 314, 317, 318, 319, 320, 321, 322, 323,


324, 325, 326, 327, 328, 329, 330, 331, 332,
333, 334, 335, 336, 377, 381, 392, 397, 398,
403, 410, 438, 442, 609, 625, 661, 663, 700,
726, 735, 739, 761, 769, 778, 788, 799, 804,
808,818,835,844,875,883,888,890
Potassium permanganate-sodium
chloride - 414,
417
Potassium peroxide - 44, 206, 377, 381, 393, 403,
410,438,661,
761
Potassium persulfate - 30, 50, 58, 106, 115, 136,
165, 172, 206, 260, 269, 280, 377, 381, 403,
410,557,625,661,700
Potassium phosphate - 172, 280, 647, 788, 844,
875
Potassium pyrophosphate
- 44, 45, 108, 206, 214
Potassium pyrosulfate
- 625
Potassium pyrosulfate,
molten - 731, 732
Potassium ricinoleate - 206
Potassium salts - 150, 364, 367, 852
Potassium silicate - 875
Potassium silicide - 87
Potassium sulfate - 12, 19, 30, 34, 38, 50, 58, 60,
64,66,67,87,
106, 113, 115, 119, 136, 152,
154, 155, 156, 165, 206, 219, 222, 232, 237,
245, 260, 269, 280, 364, 373, 374, 377, 381,
388, 390, 392, 393, 397, 403, 410, 438, 625,
632, 646, 652, 661, 700, 735, 739, 761, 769,
775, 778, 784, 788, 799,804,
808, 818, 835,
844,875,883,888,890
Potassium sulfide - 30, 64, 87, 115, 119, 136, 219,
232, 260, 377, 381, 393, 735, 778, 799, 804,
808,875,883
Potassium sulfite - 87, 113, 115, 119, 136, 156,
281,364,
661,700,818,835,875
Potassium tartrate - 625
Potassium thiocyanate
- 609, 625
Potassium thiosulfate
- 281, 739, 769
Potato oil - 835
Powerlube - 281,818
Powerplant
scrubber - 206
Prague pickling solution - 698
Premium oils - 284
Prestone - 156, 291, 305, 308, 311, 313, 316,
364,789,858,875
Primatol A,S,P - 281,818
PRL high temperature
hydraulic oil - 364
Probinsaure - 791
Producer gas - 156, 364, 835,875
Propadrine - 235
Propane - 11, 18, 26, 30, 38, 58, 66, 67,81,
87,
136, 150, 154, 156, 172, 219, 229, 260,269,
281, 364, 442, 625, 632, 652, 789, 818,835,
852,875
Propane, liquid - 156, 229
Propanol (see Propyl alcohol)

949

Corrosion

950

Propanone

Resistant

Materials

Handbook

(see Acetone)

Propargyl

alcohol

Propellor

oil

Propene

- 30, 106,

115,

150,

154,

263

Propionic
206,

225,281,438,558,

739,

761,769,783,788,818,844,855

136,

156,

559,

165,

625,

177,

661,

700,

- 44, 50, 58, 60, 64, 66, 87, 106,


177,

157,

165,

245,

249,

260,

269,

281,

301,

364,

371,

372,

377,

381,

386,

388,

390,

392,

393,

394,

395,

410,

438,

560,

625,

646,

661,

663,

700,

403,

anhydride

761,788,818,835,844,852,875

Propyl
150,

- 10,

151,

154,

sulfate

17, 30,

156,

54,

87,

219,

226,

106,

110,

260,

364,

370,

372,

387,

625,

663,

700,

735,

789,

Pyrogallol

835,

839,

842,

848,

852,

856,

875,

888,

Pyrogard

(propene)

Propylene

chloride

Propylene

chlorohydrin

Propylene

dibromide

Propylene

dichloride

154,

- 87, 364,789,
- 11,

glycol
115,

145,

297,

559560,625,

Propylene

glycol

Propylene

oxide

260,

150,

151,

Protargol

163,

34,

165,

38,

172,

49,

206,

50,

229,

87,

- 293

- 58, 87, 219,

235,

260,

269,

364,

acid

- 700

bleached

- 206
Pulp mill liquors - 383,
Pulp,
Pulp,

paper
paper

Pulp,

paper

Pulp,

paper

Pulp,

paper

Pulp

stock

Pulp

stock,

mill
mill

- 560
acid)

739,

799,804,808,

acid

(wood

761,835,856

aldehyde

Quaternary

761,

779,

883

vinegar)

- 87, 156,

364,

(see Furfural)
oil)

- 281,

818

835

ammonium

salts

- 44, 172,

206,

561,

844
Quaternary

softener

Quebracho

extract

- 206
- 561, 625

Quenching

oil - 156
- 16, 23, 231, 661
Quinine
bisulfate
- 87, 661, 778, 875
Quinine
sulfate
- 87, 156, 778, 875
Quinine
tartrate
- 661
Quinizarin
- 661

869

bleach
digester

chlorinated

Purina

woody
oils
salt

- 281,

291,

364,818,844,875

- 38

spray

822

- 206

R-2

solutions

RJ-1

- 364

RJ-4

Fuel

RP-1

- 364

Ramrod

permanganate)

Range

301,

305,

fluid
308,

and oil)
310,

- 66, 87,

313,

316,

381

- 818

- 207
- 285,

364

solutions

oils
oil

Rapeseed

- 884

hoods,

(agricultural

Rando

Hydraulic

661

- 377,

Quintolubric

- 156

818

625,

- 661

Radiochemical

818

(see Potassium

(see also
281,

sulfate

Radioactive

- 206

- 281,
plant

- 561,

Quinoline

Radiation

- 206,875

insecticide

(see Hydroquinone)

Quinoline
Quinone

- 206, 415
- 206
mill effluent
- 50, 165
mill recovery
boiler - 206
mill waste, acidic - 206

Purina

156,

735,

818

726,

- 364,

Quinol

water

(see Hydrocyanic

Pulp,

Pydraul

875

- 835

processing

Purple

844,

- 235
hydrolysate

Puropale

663,
364,

(transformer

Pyrrole

281,

663,844,875
ricinoleate

- 835
- 364, 835,

Protochloride
Prussic

726,

393,789,875
17, 32,

acid

nitrate

Prune

225,

701,

Quinine

Propylformic

Protein

156,

(see Acetone)

- 364,875

Pyromucic

560,663
Propyl

438,561,

875

875

145,

- 10, 17, 58, 87, 145,

- 219,

Pyronal
136,

775

- 281,

Pyrolube

- 260
- 30, 115,

- 10,

113,

835,

18

- 87, 249,

156,230,260,269,

Propylene

818,

661,

661,

Pyroligneous

890
Propylene

240,

784,788,852,856

281,

818,

Pydroil

438,

237,

560,

ether
acid

269,

115,

263,

- 560, 646
- 60, 222, 392,
acid - 661

Pyridinesulfonic
Pyrogallic

- 875

alcohol

bases

Pyridine
Pyroacetic

736,783,818,835,842,875
n-Propylacetone

Pyridine

219,

136,

156,

aldehyde

206,

119,

148,

Propionic

625,

364

281

Propionic

- 625, 875
- 103, 559, 625
Propionyl
chloride
- 206
Proprietary
compounds
- 700
Propyl
acetate
- 18, 87, 156, 281, 364,497,

- 281,

tetrachloride)

- 67, 235,
oil - 260

Pyrethrum

109,

oil)

364

(see Carbon

Pyridine

- 558
- 50, 106,

acid

- 156,

Pyrethrum

(see Acrylonitrile)

Propiolactone

(transformer

Pyranol
Pyrene

- 156

(see Propylene)

Propenenitrile

Pyranal

glove
spray)

- 281,818
- 156
oil - 106, 281,

873,876
Rare

earth

chloride

Rare

earth

sulfates

- 561
- 561

364,

boxes

- 207

- 281,

818

818,

835,

843,

844,

Corrosive

Raspberry

juice

Raylene

- 625

SCC

Rayon

bleach

Rayon

coagulating

bath

- 30, 115,

150,

154,

726,

hardening

Rayon

industry

bath

Rayon
Rayon

178,207,562,

563,

657,701,784
Rayon

spin

Recovery

bath,

fumes

boiler

Red

gage oil

Red

line

Red

liquor,

gases

- 207
- 207

- 876

100

oil
pulp

364,

381,

- 281,

Rendering

- 563,

Resin

solvent

Resins,

wet

chlorine

701,

- 844,

plating

- 153
145,

177,

235,

303,

barn

solution

salts

salt

- 150,

382,

788

(see Ammonium

chloride)

- 835
acid - 30

Salicic

- 58, 88, 219,226,


260, 269,
- 50, 58, 64, 87, 145, 166, 207,

acid
237,

245,

260,269,281,

364,

625
219,

377,381,

382,

386,

388,

390,

392,

403,

410,

438,

625,

662,

701,

735,

739,

761,

779,

788,

818,

835,

Salicylic

acid,

Sal soda

(see Sodium

Salt

cake

Salt

of Lemery

sodium

salt - 739
carbonate)

(see Sodium

sulfate)

- 835

(see Potassium

- 53,231,232,

nitrate)

302,

303,421,

648,

664,

665,735,788
of tartar

(see Potassium

Sandalwood
Sani-Fresh

oil)
237,

(see Sodium

245,

381,

carbonate)

Saponified

652,

(see Foods)

- 16, 25
- 701,

fluegases

705,

706

Scrubber

- 207
- 207
Synthetic
- 666

Sludge

Rotenone

and water
resinoid
oil

- 156

- 235
- 843,

Rubber

- 145,235,

Rubber

cement

Rubber

coagulating

872

564,565,625,663,

701

- 663

Rubidium

bath

- 565,

679

Scrubber

effluent

Scrubber

environment

Scrubber

environment,

Scrubber

for fly

Scrubber

water

Scrubbing

- 701
Rubilene
oils - 281, 818
Rust inhibitors
- 844, 876

Seafood,

Rykon

Seawater

2EP

oils)

Coal

- 701

Triton

oil (see Essential

retarder

- 207

818

Sauerkraut
Scale
625,

solution

Sassafras

Scrubbed
564,

- 234

- 876
- 281,364,
oil - 228

Santosafe

chloride)

oil
soap

Sanitizers

390

slurry

Rotenone
Royal

- 106,

- 207
- 207
Sand acid - 835

701,728,761,876
oil

- 136
- 876

Dry

- 207
Roofing
membrane
- 250
Rose geranium
oil - 234
Rose oil - 843,844,
873,876
Rosia oil - 156
Rosin - 87, 136, 156, 281,438,
Rosin

oil

- 26
- 28,818

Slurry

oil (see Castor

wool

Salad

Salt

- 136
- 207
1850 - 207
acid - 625

Ricinoleic

Rock

dressing

135,

oil

R ichonate

Rock

oil

Salad

Salts

CDA

Rochelle

Safflower

solution)

Sand

Richamide

Ricinus

215

Saltpeter

- 625
- 30, 58, 115,

153,154,207,259,269,884,885

Rice

powder

Safetytex

788

sugar

856

876

formaldehyde

- 625

Sachet

- 207

728

306,309,312,315,789
Resorcinol
150,

- 835

225,

- 64, 87, 119,

Rice

solution

Salicylic

ozone,

564,
strength

Resorcinol

Rhodium

Saccharum

818

fumes,

Resins

662,

(see Sucrose,

- 219

oils

381,

solution

Salicylaldehyde

- 53
charge - 207

365

- 377,

Saccharose

Sal chalybis

- 44, 207
acid) - 225, 281,

- 210
- 293,

solution

mill

gases

Refrigerants
Regal

fuel

Sal ammoniac

oil (see Oleic

Reformer

SR-10

- 364

818,835,843,844,873
Reducing

- 281,818

oil treatment

Saccharin,

- 562

- 625, 701
sizing bath - 562
spin bath - 34, 165,

- 281,818

Fluid

SP-181
SR-6,

Rayon

Index

- 207

SFR

- 701

852

Red

7204

SD-20

- 207

Material

- 102

Seasalt

liquors
shrimp

gas

- 701
- 701
sulfur

dioxide

- 722

ash - 719

- 706
- 701,

702,

(see Foods)

(see Sodium
(see Water,

chloride)
sea)

703,

704,

705,

706

951

952

Corrosion

Materials

Handbook

- 50, 166, 706, 739


- 706

Sebacic acid
Secondary

Resistant

discharge effluent

- 835
Selenic acid - 30, 115, 260, 269, 852
Selenious acid - 50, 166, 207, 784
Seed oil

Selenious

acid with sulfuric,

Selenium

- 566

Selenium

chloride,

Selenium

compounds

mono

367,

382, 386,

388, 390,

438,

442,

646,

662, 707, 726,

393,

728,

752, 761,

769,

778, 784,

799, 804, 808,

788,

nitric acids

- 662

- 232

Silver refining

- 707

Silver refining

cells

(see Plating solutions,

- 403, 410

707, 852, 876

Sequestering

Skydrol

NP-10

Silver sulfate

- 835
- 207

agents - 207
- 260
Sesame oil - 228, 260, 843, 844, 873, 876
Sevin - 281,818
Sewerage,
384,

150,

566,

154, 156,

183, 207, 281,

625, 652, 706,

364,

726, 780, 818,

835,

876

- 706

(see Hydraulic

Sewerage sludge incinerator

fluegas

- 706

- 207

treatment

Shampoo

- 207,232,235
- 14, 626,876

Shave cream

287, 288,

289, 291,

293,

308, 310,

313,

317-336,

301,

Skylube

hydroxide)

- 44
Slimicide - 44, 207
Sludge acid - 726, 844
Slurry - 707
Clay - 207
Coal - 207
Rockwool - 207
Sand - 207
Smokehouse

. 566

Smoke,

- 706

furnace

gas and dust

residues

- 137, 156, 844, 876


- 364, 835, 844, 876
Silicicacid
- 58, 113, 115, 150, 154, 269, 646,

Ivory

Silicate

Lava

esters

852

- 208

particulate

- 234
- 22
- 22

Lighthouse

- 7, 26, 30, 50, 52, 58, 64,

Soap and soap solution


acid (see Fluosilicic

acid)

66,88,95,

- 790

- 301
- 64, 284
Silicone grease - 22, 281, 301, 364, 818, 835
Silicone L-45 - 844, 876
Silicone oil - 2, 21, 58, 88, 102, 106, 119, 137,

104, 106,

166, 208,

281, 296,

301,

364,

368,

396, 432,

652, 743,

780,

788, 816, 818,

brake fluid

278,

567, 626,

843,

873,

876

269,281,735,778,876
Silver fines
Silver nitrate
115,

137, 145,

151, 152,

154, 156,

166,

172,

207,

219,

237, 245,

260, 269,

281,

364,

232,

566,

- 101

Soap coagulating
Soap curd

Soap oil

- 707

serum

- 62

- 707

Soapless detergent

- 137

- 156,818
- 208
- 106

Soap plant fumes


Soap, washing
Socony

oils, fluids and grease

Soda ash (see Sodium

- 364, 876, 877

carbonate)

Soda alum (see Aluminum

sodium

sulfate)

Sodan - 156
Soda niter (soda saltpeter)
Soda water

- 707
- 12, 19, 30, 50, 58, 64, 88, 106,

260, 270,

835,844,852,876,888,890
Soap, boiling

Soap fat

- 844, 876
Silicon tetrachloride
- 44, 403, 410, 706, 876
Silicon tetrafluoride
- 706, 707
Silicon tetraiodide
- 566, 707
Silver bromide - 88, 707, 778, 876
Silver chloride - 88, 707, 728, 735, 778, 876
Silver citrate - 728
Silver compounds - 626
Silver cyanide - 30, 58, 88, 151, 207, 219, 260,
X-527

632,

239,

130, 137,

157,

fluids

364, 818, 835,

117, 119,

154, 156,

Silicone

269, 281,

115,

150,

Silicone

156, 207,

- 207

- 382

Soap

Silica gel

Silicone

- 301

450

Smelting

(see Foods)

Silicofluoric

316,

37 1,818,835,841,876

lime (see Calcium

Shortening

Silicon

305,

337-354,364,

- 88, 136, 156, 281, 626, 632, 728, 876


orange - 844
Shell oil and fluids - 156, 364, 843, 873
Shoe polish - 15, 105, 137, 235, 626
Shellac

Shellac,

Silica

- 88, 107, 110,

281, 286,

Slimetrol

Sewerage,

Silica, acidified

fluid and oil)

156, 196, 207,

Slaked

Sewerage gas

silver)

- 207

Silver salts - 150, 156, 652,

dl-Serine

Separen

735, 739,

818,835,844,847,876,883
Silver plating solution

- 58, 154, 269


Sinclair Opaline Lube - 364
Sizing starch - 876
Skelly solvent - 235, 364, 876

Septic system

397, 398, 410,

(see Water,

(see Sodium

nitrate)

carbonated)

Sodium
Metal
Molten

- 234, 626, 728, 739


- 642, 646, 728, 732, 739, 799, 804,

808,883

Corrosive

Sodium acetate - 19, 30, 36, 50, 58, 64, 88, 115,
119, 137, 145, 150, 153, 154, 155, 156, 166,
172, 208, 219, 232, 237, 245, 260, 270, 281,
365, 377, 381, 388, 390, 393, 397. 398, 403,
410, 438, 567, 609, 626, 662, 707, 735, 739,
761, 769, 778, 799, 804, 808, 819, 835, 877,
883,888,890
Sodium acid fluoride (see Sodium bifluoride)
Sodium acid methanearsenate
- 832
Sodium acid phosphate - 31, 58, 138, 209, 270
Sodium acid sulfate (see Sodium bisulfate)
Sodium alkylaryl sulfonates - 166, 208
Sodium alkyl xanthate - 208
Sodium aluminate - 88, 166, 208, 626, 662, 707,
739,769,
788,877
Sodium aluminosilicate
- 835
Sodium aluminum fluoride - 609, 835
Sodium aluminum sulfate - 19, 58, 88, 154, 438,
727, 761,835
Sodium ammonium
phosphate - 208
Sodium antimonate
- 30
Sodium arsenate - 626
Sodium arsenite - 30, 626, 796, 844, 877
Sodium benzenesulfonate
- 626
Sodium benzoate - 30, 50, 58, 64, 88, 115, 137,
145, 154, 166, 172, 208, 219, 232, 260, 270,
281, 370, 626,735,778,877
Sodium bicarbonate
- 1, 12, 19, 30, 34, 50, 58, 60,
64, 67, 88, 106, 109, 113, 115, 119, 137, 145,
152, 154, 156, 166, 172, 208, 219, 222, 232,
237, 240, 245, 249, 260, 270, 281, 303, 306,
309, 311, 314, 365, 370, 372, 373, 374, 377,
381, 382, 388, 390, 392, 393, 394, 395, 396,
398, 403, 410, 438, 567, 568, 609, 632, 652,
662, 707, 735, 761, 776, 778, 784, 788, 799,
804, 808, 819, 823, 836, 844, 877, 883, 888,
890
Sodium bichromate
(see Sodium dichromate)
Sodium bifluoride - 50, 166, 572, 662, 707, 726,
739
Sodium bisulfate - 19, 30, 34, 50, 58, 60, 64, 88,
106, 115, 137, 154, 156, 166, 172, 177, 208,
219, 222, 260, 270, 279, 281, 363, 370, 372,
392, 393, 396, 397, 398, 403, 410, 412, 438,
442, 576, 626, 632, 647, 652, 662, 707, 727,
732, 735, 739, 752, 762, 769, 778, 788, 799,
804, 808, 819, 836, 844, 872, 877,883,
888,
890
Sodium bisulfate, boiling - 419, 769
Sodium bisulfate, molten - 732
Sodium bisulfide - 208
Sodium bisulfite - 12, 19, 30, 39, 41, 42, 44, 45,
50, 58, 64, 67, 88, 106, 115, 119, 137, 145,
152, 154, 155, 166, 173, 177, 208, 219, 222,
232, 260, 270, 281, 365, 367, 370, 372, 386,
393, 396, 397, 398, 403, 410, 438, 577, 626,
652, 662, 707, 739, 753, 762, 776, 788, 799,
804,808,819,836,844,877,883,888,890

Material

Index

Sodium borate - 12, 19, 67, 113, 115, 119, 137,


145, 152, 208, 232, 260, 270, 281, 303, 306,
309, 311, 314, 365, 735, 778, 788, 799, 804,
808,819,836,877,883
Sodium bromate - 50, 166, 173, 178, 663
Sodium bromide - 34, 38, 50, 58, 64, 89, 115,
137, 145, 154, 166, 173, 208, 219, 232, 260,
270,393,438,
663,707,732,
762, 778,877
Sodium bromide oil solution - 137
Sodium carbonate - 2, 4, 6, 12, 19, 26, 34, 36, 38,
43, 44, 45, 46, 50, 58, 60, 61, 64, 66, 67, 89,
95,104,
106,109,111,113,115,
117, 119, 121,
137, 145, 147, 152, 154, 155, 156, 166, 169,
173, 178, 208, 219, 232, 237, 239, 240, 246,
249, 260, 270, 281, 296, 364, 370, 372, 373,
374, 377, 381, 382, 387, 388, 390, 392, 393,
394, 395, 396, 397, 398, 403, 410, 438, 568,
609, 626, 632, 646, 647, 652, 657, 662, 663,
707, 731, 732, 735, 739, 762, 769, 778, 784,
788, 791, 792, 794, 795, 799, 804, 808,818,
836,844,877,883,888,890
Sodium carbonate, fumes, vapor, condensate - 208
Sodium chlorate - 30, 34, 38, 50, 58, 64, 89, 106,
115, 119, 137, 152, 154, 156, 166, 173, 208,
219, 222, 260, 270, 281, 377, 381, 393, 438,
568, 609, 626, 707, 732, 735, 739, 762, 769,
776, 778, 784, 796, 799, 804, 808, 877, 883,
888,890
Sodium chlorate-hypochlorite
- 384
Sodium chloride - 1, 4, 6, 7, 12, 19, 26, 30, 34,
36, 38, 39, 43, 44, 45, 46, 50, 52, 58, 60, 61,
64, 66, 67, 89, 95, 96, 97, 98, 104, 106, 109,
111,113,
115, 117, 119, 121, 137,145,151,
152, 154, 156, 166, 173, 208, 219, 222, 232,
237, 239, 240, 246, 249, 260, 270, 281, 291,
293, 295, 296, 297, 301, 303, 306, 309, 311,
314, 317, 318, 319, 320, 321, 322, 323, 324,
325, 326, 327, 328, 329, 330, 331, 332, 333,
334, 335,336,
377-354,
365,370,372,
373,
374, 377, 381, 382, 386, 387, 388, 390, 392,
393, 394, 395, 396, 397, 398, 403, 410, 414,
415, 416, 417, 420, 423, 430, 438, 444, 445,
568, 569, 609, 626, 632, 642, 646, 647, 652,
657, 662, 663, 666, 707, 708, 703, 726, 732,
735, 739, 741, 752, 756, 762, 769, 776, 778,
780, 784, 788, 792, 799, 804, 808, 819, 836,
844,847,876,
877, 883,888,
590
Sodium chloride, acetic acid - 423
Sodium chloride, alkaline - 727
Sodium chloride, boiling - 416, 420, 445, 666,
752,769,778
Sodium chloride brine - 725, 735, 741, 780
Sodium chloride, carbonate (boiling) - 417
Sodium chloride, chlorine - 208, 286, 727, 739
Sodium chloride, citric acid - 423
Sodium chloride, copper chloride - 642
Sodium chloride-hydrochloric
acid (oxidizing)
722

953

954

Corrosion

Resistant

Materials

Handbook

Sodium chloride mixtures - 569, 570, 571, 573, 756


Sodium chloride, molten - 201, 207
Sodium chloride, oxalic acid - 423
Sodium chloride, phosphoric acid - 423
Sodium chloride salt spray test - 727
Sodium chloride-sulfur
dioxide - 752
Sodium chloride vapor, condensate - 208
Sodium chlorite - 30, 50, 119, 138, 166, 208, 209,
260,270,286,
392,571,
662,709
Sodium clorite, acid solution - 60
Sodium chlorosulfonate
- 404, 410
Sodium chromate
- 19, 44, 50, 89, 109, 138, 156,
166, 209, 249, 386, 393, 403, 410, 438, 626,
652, 662,762,788,844,877
Sodium citrate - 89, 438, 735, 739, 762, 769, 778,
877
Sodium cumene sulfonate - 209
Sodium cyanide - 12, 19, 30, 34, 38, 50, 64, 67,
89, 115, 119, 138, 151, 154, 156, 166, 173,
178, 209, 219, 237, 246, 260, 270, 281, 365,
388, 390, 393, 397, 398, 410, 438, 571, 572,
626, 632, 652, 662, 663, 739, 762, 769, 788,
799, 804, 808, 819, 836, 844, 877, 883, 888,
890
Sodium dialkylorthocarbonate
- 709
Sodium dichromate
- 30, 50, 58, 88, 89, 115, 119,
138, 145, 152, 154, 156, 166, 173, 208, 209,
222, 232, 240, 260, 261, 270, 282, 301, 377,
381, 386, 393,403,
410,438,
626, 652, 663,
735,739,761,769,
776,778,788,877
Sodium dioxide (see Sodium peroxide)
Sodium disilicate - 626
Sodium disulfite - 836
Sodium dodecyl benzene - 261
Sodium dodecyl benzenesulfonate
- 209
Sodium ethoxy sulfate - 209
Sodium ferricyanide
- 30, 50, 89, 115, 119, 138,
154, 166, 173, 209, 222, 261, 270, 282, 393,
397,398,438,709,
762,776,778,877
Sodium ferrocyanide
- 12, 19, 26, 30, 50, 115,
119, 138, 151, 154, 166, 173,209,
261, 270,
282, 778,877
Sodium fluoaluminate
- 156, 836
Sodium fluoride - 12, 19, 31, 50, 58, 89, 115, 119,
145, 152, 154, 156, 166, 209, 219, 232, 261,
270, 282, 393. 397, 398, 572, 609,626,
663,
709, 735, 739, 753, 769, 778, 788, 795, 799,
804,808,819,877,883
Sodium fluorosilicate
- 50, 166, 209, 572, 626,
709
Sodium formaldehyde
sulfoxylate
- 438, 572, 709
Sodium formate - 753
Sodium glutamate - 370, 572, 709, 788
Sodium hexametaphosphates
- 50, 166, 209,836
Sodium hydrate (see Sodium hydroxide)
Sodium hydrogen phosphate - 209
Sodium hydrogen sulfate (see Sodium bisulfate)

Sodium hydrogen sulfide (hydrosulfide)


- 178
Sodium hydrosulfide
- 44, 45, 51, 166, 173, 178,
209,282,438,572,709,739,
762,784,878
Sodium hydrosulfite
- 49, 156, 572, 573, 662, 778,
800,804,808,877
Sodium hydroxide - 2. 4, 6, 10, 17, 26, 28, 31, 32,
34, 36, 38, 39, 41, 42, 43, 44, 45, 46, 50, 52,
53, 58, 60, 61, 62, 64, 66, 67, 74, 82, 89, 95,
96,97,98,
102, 104, 106, 107, 109, 110, 111,
112, 113, 115, 117, 119, 121, 126, 132, 138,
145, 147, 149, 150, 151, 152, 154, 155, 156,
157, 166, 169, 173, 178, 209, 219, 222, 226,
237, 239, 240, 246, 249, 254, 261, 270, 275,
282, 286, 291, 293, 294, 296, 297, 301, 302,
305, 308, 311, 314, 317, 318, 319, 320, 321,
322, 323, 324, 325, 326, 327, 328, 329, 330,
331, 332, 333,334,
335, 336, 337-354,361,
365, 367, 370, 372, 373, 374, 377, 381, 382,
383, 384, 386, 388, 390, 392, 393, 394, 395,
396,397,
398, 404, 411, 414, 416,425,
432,
438, 442, 573, 626, 632, 640, 642, 644, 646,
647, 652, 663, 666, 676, 709, 727, 728, 731,
732, 733, 735, 739, 753, 762, 772, 776, 778,
780, 784, 788, 790, 791, 792, 794, 799,800,
804, 808, 812, 819, 836, 844, 847, 852, 860,
869,877,883,884,888,890
Sodium hydroxide,
boiling - 100, 414, 416, 417,
420,444,645,
666,739,753,769
Sodium hydroxide,
chlorate, chloride - 417, 727
Sodium hydroxide,
fused - 222, 776
Sodium hydroxide
mixtures - 573, 574, 727, 753
Sodium hydroxide
pulp digester liquor - 709
Sodium hydroxide
scrubbing chlorine - 209
Sodium hydroxide
vapor, condensate - 209
Sodium hydroxide,
with sodium chloride - 422
Sodium hypochlorite
reactor - 209
Sodium hypochlorite
(bleach) - 2, 4, 6, 7, 12, 14,
19,22,31,
34, 35, 38,45,
51, 53, 54, 58, 60, 61,
62, 63, 64, 66, 67, 89, 95, 101, 104, 106, 107,
109, 111, 112, 115, 117, 119, 121, 126, 138,
145, 147, 149, 151, 152, 154, 155, 156, 157,
166, 169, 173, 178, 185, 209, 219, 221, 222,
232, 233, 237, 239, 240, 246, 249, 254,261,
264, 270, 275, 282, 286, 295, 301, 356, 357,
365, 367, 370, 372, 373, 374, 375, 377, 379,
381, 382, 386, 388, 390, 392, 393, 394, 395,
396, 397, 398, 404, 411, 417, 574, 575, 626,
646, 647, 652, 674, 709, 710, 727, 732, 739,
741, 753, 769, 776, 778, 784, 788, 800, 804,
808, 812, 819, 825, 836, 840,844,848,852,
860,877,883,888
Sodium hypochlorite
vapors - 209
Sodium hyposulfate
(see Sodium thiosulfate)
Sodium hyposulfite
(hypo) (see Sodium thiosulfate)
Sodium iodide - 58, 60, 261, 270, 392, 753
Sodium lactate - 626, 778, 877
Sodium lauryl sulfate - 51, 109, 166, 209, 626

Corrosive

Sodium metaborate
peroxyhydrate
- 836
Sodium mercaptobenzothiazole
- 626
Sodium metaarsenite
- 209
Sodium metaphosphate
- 58, 89, 138, 156, 170,
270,282,
365.727,819,836,844
Sodium metasilicates - 89, 438, 710, 762
Sodium methacrylate
- 209
Sodium methyl arsenate - 177
Sodium nitrate - 12, 19,31,
34, 51, 58, 64, 67,
89, 115, 119, 138, 152, 154, 156, 166, 173,
209, 219, 222, 232, 237, 246, 261, 270, 282,
365, 373, 374, 377, 381, 382, 386, 388, 390,
393,397,
398,403,410,
438, 575, 609, 626,
632, 652, 662, 710, 727, 728, 732, 733, 735,
739, 762, 776, 778, 784, 788, 800,804,
808,
819,836,844,877,883,888,890
Sodium nitrite - 12, 31, 58, 89, 119, 156, 166,
173, 209, 219, 261, 270, 393, 397, 398, 442,
575,627,
662,739,769,778,788,877
Sodium oleate - 710
Sodium orthophenyl
phenate - 844,877
Sodium oxalate - 393, 404, 411, 626
Sodium palmitate - 138, 270
Sodium perborate - 64, 89, 138, 156, 232, 270,
282, 365, 438, 627, 632, 662, 710, 762, 819,
836,844,877
Sodium percarbonate
- 627, 662
Sodium perchlorate - 34, 58, 156, 222, 270, 438,
710,739,762,776
Sodium peroxide - 58,89,
156, 157, 219,261,
270, 282, 301, 365, 377, 381, 393, 396. 404,
411, 627, 632, 653, 662, 710, 728, 753, 778,
788,800,804,808,819,836,844,877,883
Sodium persulfate - 38, 166, 209, 662
Sodium phenolate - 575, 710
Sodium phosphate - 36, 43, 45, 51, 64, 67, 89,
138, 156, 166, 201, 209, 219, 222,261,
282,
365, 373, 374, 377, 381 I 387, 438, 442, 575,
632, 647, 653, 662, 710, 735, 739, 762, 769,
776,778,788,819,836,844,877
Sodium phosphate, acid (see Sodium acid phospha te)
Sodium phosphate, alkaline - 58, 138, 270
Sodium phosphate, di - 28, 50, 55, 113, 114, 128,
149, 152, 154, 166, 209, 255, 266, 788, 844,
849,877
Sodium phosphate, dibasic - 627
Sodium phosphate, hexameta - 852
Sodium phosphate, meta - 58, 59, 138, 156, 170,
270,282,365,844,877
Sodium phosphate, mono - 51, 201, 209, 365
Sodium phosphate, neutral - 58, 138, 270
Sodium phosphate, poly - 844, 878
Sodium phosphate, polymeta - 829
Sodium phosphate, pyro - 214, 271, 731
Sodium phosphate, pyro, molten - 732
Sodium phosphate, tri (see Trisodium
phosphate)

Material

Index

Sodium phosphate, tripoly - 51, 166, 210, 282,


366,819,820,836,
844,878,880
Sodium phosphate-phosphoric
acid liquor - 209
Sodium phosphate vapors - 7 19
Sodium polyacrylate
- 209
Sodium-potassium
alloys, molten - 642, 710, 732
Sodium propionate - 370, 575, 627
Sodium pyroborate
(see Sodium borate)
Sodium resinate - 261
Sodium salts - 365, 367, 852
Sodium sesquicarbonate
- 836
Sodium silicate - 12, 19, 20, 31, 51, 58, 64, 67, 90,
119, 138, 147, 156, 166, 173, 209, 219, 261,
270, 282, 365, 439, 627, 632, 646, 653, 662,
663, 710, 728, 735, 739, 753, 762, 769, 778,
788,800,804,808,844,878,883,888,890
Sodium silicate sulfate - 836
Sodium stannic chloride - 836
Sodium subsulfite - 836
Sodium sulfate - 31, 34, 36, 51, 58, 60, 64, 67, 90,
106, 113, 115, 119, 139, 151, 152, 154, 156,
166, 173, 178, 209, 210, 219, 222, 232,237,
240, 246, 249, 261, 270, 282, 365, 370, 372,
373, 374, 377, 381, 382, 386, 387, 388, 390,
392, 393, 396, 398, 404, 411, 439, 442, 576,
609, 627, 632, 646, 653, 657, 662, 710, 732,
735, 739, 741, 753, 762, 769, 776, 778, 784,
788, 792, 800, 804, 808, 836, 844, 876, 878,
883,888.890
Sodium sulfate decahydrate
(Glaubers salt) - 360,
780,788,814,836,
867
Sodium sulfhydrate
(see Sodium hydrosulfide)
Sodium sulfide - 31, 34, 38, 51, 58, 60, 64, 66, 67,
90, 106, 115, 119, 139, 154, 156, 166, 173, 210,
219, 222, 232, 237, 240, 246, 249, 261, 270,
282, 365, 370, 372, 373, 374, 381, 386, 388,
390, 392, 393, 396, 397, 398, 404, 411, 439,
576, 577, 627, 632, 646, 653, 657, 662, 663,
710, 727, 732, 733, 739, 753, 762, 769, 776,
778, 784, 788, 795, 800, 804, 808, 844, 847,
878,883,888,890
Sodium sulfite - 20, 31, 51, 58, 60, 90, 115, 119,
139, 151, 152, 154, 156, 166, 173, 178, 210,
219, 222, 232, 237, 246, 270, 282, 365, 382,
386, 388, 390, 392, 393, 396, 397, 398, 411.
439, 577, 627, 653, 662, 710, 711, 732, 735,
739, 762, 769, 776, 778, 784, 788, 792, 800,
804,808,819,836,844,883
Sodium superoxide (see Sodium peroxide)
Sodium tartrate - 404, 411, 662
Sodium TCA - 796
Sodium tetraborate
(see Borax) - 51, 90, 145, 166,
2 10,232,663,788,836,878
Sodium tetrachlorophenate
- 210
Sodium thiocyanate
- 51, 166, 173, 210, 627

955

956

Corrosion

Sodium

Resistant

thiosulfate

Materials

- 20, 34, 51, 58,

(hyposulfite)

60, 64, 67,89,

Handbook

90, 139, 151,

156, 163,

178, 210,

219, 222,

232, 237,

249.

257,

261, 270,

282,

365, 382,

386,

390, 392,

393, 404,

411,

627, 653,

710, 727,

739,

776, 777,

778, 788, 800, 804,

769,

239,240,

166, 173,

triphosphate

Sodium

tripolyphosphate

282,
Sodium

(see Trisodium
(STPP)

xylene

Soft drink

E08,

phosphate)

- 51, 166, 210,

- 577

sulfate

concentrates

Soft drinks,

Soil

(see Foods)

beverages (see also Cola drinks)

- 14,

- 210

- 62, 210, 627, 739


- 215

Stainless steel pickle

108, 115,

119,

139,

Soft - 790

- 878

270,

282,

373,

381, 397,

627,

662, 711, 7 18.

770,

374, 377,

727, 735,

739,

753,

769,

800,

808,

819,

836, 844,

molten

- 739

804,

Stannic

chloride,

Stannic

fluoborate

Stannic

salts

Stannic

sulfate

- 282, 819
- 878
Solvac 1535 G - 282, 819
Solvents - 220, 884

Stannic

tetrachloride

(see Stannic

119, 139,

151,

154,

156,

157,

167, 173, 210,

261, 270,

282,

301,

365, 397, 439,

728, 735,

762,

770,

and aromatic

- 157

662, 711,
fluoride
salts

Stanoil

- 282, 819
- 58, 90, 115, 139, 150, 154, 156, 210, 270,

Starch

- 148, 788
- 51, 166, 210, 627, 788
Sorbose - 627
Sorghum - 844,878

852,878
Starch, digested,

282,

Sorbic acid
Sorbitol

- 7 11

- 365, 878
Soya oil - 22, 51, 62, 90, 167, 210, 237, 246,

Steam

Sovasol

382, 388,390,411,627,836

- 38

fatty

oil - 139, 156, 228,

282,

301,

- 162, 192, 210

- 577, 578

- 711

- 210

hydrolyzer

Jet 1, 2 - 819

- 282, 819
- 53, 90, 156, 210, 249, 285, 286, 289, 301,

365, 377,

381,

393,

578,

663,7

728,

735,

739,789,792,819,878

II,

115,

139,

146,

150,

151, 153, 154,

246, 261,

270,

282,

301, 303,

306,

309, 312,

315,

373,

374,

377, 381,

382,

383,

388,

390, 392, 404,

411,

421, 439,

627,

653,

663,

776, 779,

784,

788, 800,

852, 856,

883, 888,

365,

711,

735,

762,

770,

804, 808,

819,

836, 844,

Spent acid

- 210,819

219,222,

225,237,

890

Spent acid from chlorine

dioxide

generators

- 426, 724, 736

- 235
_ 13, 22, 843, 844, 873, 878
Sperry oil - 261

- 38

Stearic acid, molten


Stearin

- 739

- 66, 282

Spermaceti

Steel pickling

Sperm oil

Steep liquor - 869


Stoddards

bath

solvent

- 25, 210
- 16, 25, 31, 58, 67, 90, 150,

Spices (see Foods)

154, 156, 219, 235,

- 106, 112, 139


Spirits of turpentine
- 836

365,789,819,836,844,852,878,888,890

oil

646, 653,

178,210,

oil (see Essential oils)

Spindle

642,

173,

Spearmint

liquor

627,

156, 167,

Soy sauce (see Foods)

Spent sulfite

788, 844,

FR

67, 90, 108,

365,

788,819,836,843,844,873,878

Soy protein

711, 784,

Stearic acid - 10, 17, 31, 51, 53, 58, 60, 64, 66,

Soybean
Soybean

processing

646,

sizing

Stauffer
Staysol

- 291

Soybean

627,

- 876
Starch syrup - 836
Stauffer 7700 - 286, 365

Sour crude oil (see Crude oil, sour)

oil, epoxidized

396, 578,

Starch,

Soups (see Foods)

Soybean

776, 778,

- 210, 788
- 150, 367, 852

Stannous
Stannous

Solvesso - 156

acid

chloride)

219, 222,
627,

291,293,

888,

bisulfate

800,804,808.836,878,883

oil

Sovaloid

776, 778, 788,


878, 883,

- 150, 367, 852


- 64, 119

Solnus oils

Sour gas condensate

301, 365,

- 844, 878

Soluble

aliphatic

156, 167, 173,

232, 261,

- 662, 711
Stannous chloride - 31, 51, 58, 67, 90, 106, 115,

Solder

Solvents,

146, 154,

210, 219, 222,

Stannous

Soil, clay

Tin based

Stack gas scrubbing

890

382,743,788
Softener

- 711

- 210
- 210
Standard Oil Mobilube - 365
Stanisol - 235
Stannic chloride - 31, 34, 45, 51, 58, 60, 64, 90, 92,

366,819,836,844
vanadate

- 784, 836
- 210

Stack gases

- 210
Sodium xylene sulfonate - 51, 166, 210

Sodium

mastic

388,

- 411

thiosulfite

Sodium

Stackfas

246,

819,823,836,844,862,868,877,878,883
Sodium

Spirits of wine

Stove oil

- 210

241, 249,

261, 270,

282,

Corrosive

Straight

oils - 282
- 413
- 627, 711

test

Streptomycin
Stripper

Sulfonation
Sulfonic

- 836

SA

Stripping

solutions

Strobane

- 627

- 53

bromide

Strontium

carbonate

261,

- 173

106,

chloride

109, 156,

167,

365,627,663,
Succinic

173, 210,

739,

753,

770,

270,

Sugar, beet and cane liquor

411,
53, 64, 66, 90,
261,

282, 301,

370, 371,

627,

(see Foods)

- 579, 580

270,

628, 647,662,
739,

(see also Black,

139, 156, 270,282,

chloride

- 34, 42, 45, 60, 91, 139, 156, 173,

222,

261,

381,392,

393,

398,404,411,439,

632,

663,

732, 739,

59, 62,64,
154,

732,

755

711

Green liquors)

- 59,

67, 91, 109,

156,

167,

169,

reduction

Sulfidic

spent caustic

Sulfinol

- 90, 249,

process

- 211

- 211

439,

628,

711.

724,

762,

776, 836,

- 21 1
Sulfite liquors with sulfuric acid - 222
Sulfite pulping vapors - 711
Sulfoacetic acid - 711
5Sulfoisophthalic
acid, sodium salt - 211
Sulfolane

calcium

- 90, 241,

249,

base mill

878

- 211
Sulfonated compounds - 580,581,
582,712,878
Sulfonated detergents - 48, 109, 161, 191, 211
Sulfonation
- 712, 727
Sulfonation
acid (spent) - 712
Sulfonated

aliphatics

784,

219,

261

115,

139,

173,

178, 211,

150,

151,

219,222,

246,

249,

261,

270,

282,

286, 301,

381,

386,

390, 393,

394,

395, 397,
628, 632,

398, 404,

411,

439,

583, 584,

609,

639,

642,

646,

653,

662,

712, 713,

728,

732,

735,

739,

762, 770,

804,

808,819,836,

789,800,

663,

727,

776,

778, 784,

844,

847, 852,

878,883
fumes

- 724
- 211

removal, scrubber - 211, 422


- 53, 211
Sulfur fungicide - 211
Sulfur hexafluoride
- 282, 365, 836, 878

Sulfur

dioxide

Sulfur

fumes

acid - 1, 2,4,

6,9,

10, 17, 26, 31, 32, 34,

35, 38, 39, 42, 43, 45, 51, 52, 53, 59, 60, 61, 62,

878
liquors,

778,

377,

Sulfuric

878

- 34, 59, 90, 173, 211, 222, 270,

liquors

365, 426,

- 21 1, 213

electrorefining

776,

235, 237,

- 211

- 211, 383, 663

anolyte,

762,

365,

dioxide,

Sulfide

367, 377,
583,628,

13, 20, 31, 34, 35, 38, 45, 51, 53,

dioxide-chlorides

Sulfide

365,

- 648

Sulfur

boiler gases

282,

- 139, 211,

Sulfur

recovery

270,

oils (see also Crude oil, sour)

788,844,869,878

salts

762,

sulfide)

211, 219,

sulfate)

Sulfate

Sulfite

Sulfur

653,

770, 784,800,

- 211

of lime (see Calcium

Sulfate

Sulfite

burner gas

dioxide

- 711
Sulfanilic acid - 51, 167, 211, 739
Sulfated detergents - 51, 167, 190, 211,270,

Sulfate

Sulfur

Sulfur

Liquors

727, 739,

- 21 1

wettable

compounds

acid, boiling - 419,

712,

lime (see Calcium

dichloride

Sulfanilamide

Sulfate

Molten,
Sulfurated

Sulfur

379,

780, 784,

844,883

Sulfur

282, 375,

776,

233

653,

238

819,836,844
Sulfamic

632,

syrup (see Foods)

acid

261,

770,

762

- 231
- 34, 38, 51, 119, 139, 167, 211,

Sulfadiazine

- 1, 225,

Sulfur-containing

Sugar, sucrose (see Foods)


Sulfamic

219,222,

582, 583, 628,

800,804,808,819,836,844,852,878,883

Sugar of lead (see Lead acetate)


Sugar, simple syrup - 1, 229,

732, 762,

804,808,819,

Sugar, juice - 90, 878

Sugar solution,

712,

157, 211,

- 45, 90, 109, 211, 282, 301, 365, 404,

Molten

779, 788,795,855

Sugar, corn, conversion

156,

398, 439,

Colloidal

- 167, 210

Succinonitrile

154,
393,

796,819,836,852,878

789,819,836,844,852,878

acid - 59, 139, 261,

662,

151,

270, 365,

646, 653,

- 578, 711
Strontium
hydroxide - 156
Strontium
nitrate - 156
Strychnine - 231
Styrene acrylic emulsions - 210
Styrene monomer - 20, 34, 38,45,
Strontium

of fats and oils

acid

145, 150,

- 232

Strontium

Index

- 712, 879
- 45, 156, 367, 646, 712, 784
Sulfonyl chloride - 211
4Sulfophthalic
acid - 211
Sulfur - 20, 31, 42,45,
59, 64, 90, 106, 115, 139,

synthetic

Streicher

Material

64, 67, 91, 95, 96, 97, 98, 102,


108,

109,

110,

111,

112,

113,

104,

106,

117, 119,
152, 154,

121, 139,

140,

146,

147,

150,

151,

155, 156,

157,

167, 169,

173,

178, 212,

222,

224,

225, 237,

239,

240,

223,

261, 270,

271,

282,

286, 291.

297, 301,

302,

305,

308,

107,

115,

293, 294,

311, 314,

219,

246, 249,
365,

296,
367,

370, 372,

373,

374,

377,

381,

382,

383,384,

386, 387,

388,

390,

392,

393,

394,

395,

396,

586,

587,

397,

398,404,

411,412,413,416,420,421,

425,428,

432,

439,

444,

588, 628,

632,

639,

640,642,

584,

585,

647,

753,

656,

662,

663,

664,

665,

713,

714,

716, 717,

725,

728,

729, 730,

731,

732,

733,

643, 644,646,

957

958

Corrosion

Sulfuric

Resistant

Materials

Handbook

acid (contd)

739,

741,

753, 756,

784,

787, 788,

808,

819,823,836,

790,

301,365,

386,

390,

393,

397,

398, 411, 439,

763, 770,

772.

776,

779,

628, 646,

653,

662,

713,

731,

732,

763, 779,

791, 792,

793, 800,

804,

789, 800,

804,

808,819,

837,

844,

878, 879,

844,

847, 852,

855,

883,

Sulfuric

acid-acetic

Sulfuric

acid anodizing

Sulfuric

- 717

acid

- 891

428,445,

715,

717, 723, 733,


776, 779,855
acid-chlorine
acid-chromium
acid-copper

770,

656,

666,

714,

739,

741,

753, 754,

- 740

Sulfuric
Sulfuric

734,

418, 420,

647,

fluoride
oil

acid, ferric

53

oils and grease

- 282, 365,819
- 282, 819
Sunvis oils - 282, 819
Super hydraulic oils - 282, 819
Superphosphate
dust - 718
Sunsafe

- 445, 647, 666,

ions (boiling)

741,

754,781

- 717

acid fumes

acid fume scrubber

Super phosphoric

Sulfuric

acid, fuming

Surfactants

286, 301,

- 212
- 91, 112, 115, 237, 246,

359, 390, 411,

439,

727,

763,

- 717

Sulfuric

acid mist

Sulfuric

acid mixtures
592, 647,

717,

acid-nitric

723, 727,

734,

754,

acid, oleum
acid pickling

755,

- 214, 837
- 21
Sweetwater
- 214
Synthetic oils - 282, 285, 298, 358, 819, 827, 840,

- 717, 727

- 796
- 837
TCP - 837

acid saturated
acid sludge

Sulfuric

acid-sodium

with chlorine

acid-sodium
acid vapors

Sulfuric

anhydride

Sulfuric

ether (see Diethyl

- 718, 740, 770


(see Sulfur

Sulfur

monochloride
ointment

trioxide)

(see Sulfur

TT-N-95a
TT-N-97B

- 365
- 365

TT-S-735

Type

51, 59, 60, 64, 67,


154,

222, 237,

367,

373,

156, 167,

246,

374,377,

Talcum

powder

Tall oil (Tallol)

262,

271,

214,

381,

386,

594,628,682,

(see Cosmetics)

219, 262,

392,

393,

394, 395,

396,

397,

398,

Tall oil purification

432,

439,

593,628,

632,

653,

657,

Tallow

662,

663.

718,

727,

732,

733. 735, 740.

755.

879

763,

770, 776,

779,

784,

788, 800,

808,

Tallow,

804,

Tanners

819,836.844,847,852,856,883
Sulfurous

acid anhydride

Sulfurous

oxychloride

Sulfurous

spray

dioxide)

Tannic

chloride)

156,

- 411

subchloride

Sulfur

trioxide

(see Hydrogen

(see Sulfur

(sulfuric

53, 66, 91, 115,

150,

178, 211,219,237,

154,

sulfide)

chloride)

anhydride)
246,

261,

282,

718,

763,784,819,837,879

383, 432, 439,

169,
270,

282,

593,

amines of

- 670

oil - 156
acid - 10, 17, 31, 34, 38, 51, 53, 59, 60, 67,
167,

173,

140,

146,

150,

151, 153,

154,

178,214,219,222,225,237,

246, 261,

271,

282, 301,

303,

306,

309,

315,

368,

370,

382,

388,

390, 392,

735.

365,

372,

393,396,398,404,411,439.442,

- 31, 45, 51,

156, 167,

secondary

91, 115, 119,

- 779

Sulfur

173.

(see Sulfur

(see Thionyl

271,

vapors - 719
- 64, 91, 115, 140, 156, 282, 646, 819, 852,

390,
411,

hydrogen

chloride)

- 51, 59, 91, 150, 167, 173, 178,

388,

oxides

- 365

I-VI

- 365

404,

Sulfurretted

amine)

Table salt (see Sodium

chloride)

151, 152,

178, 213, 219,


365,

- 365

Talc slurry - 879

- 31, 38,44,45,
150,

(see Triethanol

TT-I-735b

TT-T-656b

ether)

- 231

140,

282,301,

TEA

- 657, 734
dichromate - 233, 727, 732
chloride

Sulfuric

acid

TCA

- 718

Sulfuric

Sulfur

2,4,5-T

- 891

Sulfuric

Sulfur

- 365

- 837

Sweet orange oil

863,870,872

acid)

(see Oleum)

Sulfuric

173,

Lube, Hypoid

acid (see also Mixed

Sulfuric

91, 115,

Swan Finch

770,781

Sulfuric

Sulfurous

acid, super)

Sweet oil

- 212, 213, 588, 589, 590,

770, 776
740,

acid (see Phosphoric

- 213, 214

Sweet birch oil

779,800,804,808,819,844,852,856,883

421,

- 301, 365, 879

- 282,819

Sulfuric

Sulfuric

804, 808,

- 262

Sulfuric

591,

732, 800,

Suntac oils

733,734,

261,

718,

- 156

Sun R&O oils

- 739, 740, 741, 754,

sulfate

662,

- 291
- 94

Sundex
Sunoco

- 770

trioxide

781

Sulfuric

Sulfuryl
Summer
Sunlight

Sulfuric

411,

883

632, 645,

756,

- 53, 106, 158, 178, 213, 377,

chloride

381,404,

acid, boiling - 100, 413, 416,

423,

883
Sulfuryl

884,888,890

642, 646,

653,

662,

663,

728,

763, 770,

776,

779,

784,

788, 800,

819,837,844,852,856,883,888,890

312,

628,

632,

740,

755,

804, 808,

155,

Corrosive

- 225
- 377,381,837,879

Tannic

Tetrachloroethane

- 214
Tanning liquors, extracts - 31, 59, 91, 115, 150,
Tanning

leather,

drums

154, 271, 594,662,

663,

718, 719,

726,

784,

- 843, 844, 873, 879

oil

Tan oil

- 154
594,

595.

596, 628,

282, 377,

653, 663,

381,

728,

Tar,
Tar
Tar,
Tar

- 718

- 222, 776
aromatic - 673
bituminous - 365, 819, 837
camphor - 214,837
chlorinated - 825
oil - 67, 91, 282, 377, 381

Tartaric

acid (dihydroxy

91, 111,

113, 148,

280,

284, 291,

319,

320,

- 38, 148, 230, 251, 628


(perchloroethylene)

259,

293,

300,

304, 317,

318,

324,

325, 326,

327,

334, 335,

336,

377, 381,382,

363,365,

371,

372,

372,

374,

437,

623,

628,

661,

663, 694,

488,

Tetrachloromethane

(see Carbon

succinic acid) - 10, 31,

Tetrachlorophenol,

sodium

Tetrachloropyridine

- 214

167,

173,

Tetradeconic

262,

271,

Tetra(2-ethylbutyl)

282, 301,

303,

306, 309,

312,

315,

365,

370,

Tetraethyl

372, 377,

381, 382,

- 214

silicate - 11, 20

- 31, 59, 66, 91, 115, 150, 154,

lead

386,

388,

390,

392,

393,

173, 219, 262,

432,

442,

596, 628,

632,

845,879

646,

662,

663,

718, 727,

728,

735,

Tetraethyl

776,

779,

784, 788, 800,

804,

Tetrafluoromethane

271,

278,

365,

- 837
- 31, 45, 59, 64, 66, 91, 113, 115,

119,

140,

150,

151,

153,

249,

262,

271,

283,

291, 301,

Tectyl

820,837,852,879,888,890

- 140, 845, 879


- 214

Tellus oils

Tetrahydrofurfuryl

- 282, 820, 876


- 214

- 235
- 282, 820
Terephthalic
acid - 214, 740, 788
Tergitol - 214, 820

Tetralin

chloride

Tetramethylammonium

hydroxide

- 14, 21, 150,

acid - 91, 662

Tetrapotassium

pyrophosphate

- 837
- 283, 820

Tetrasodium

ethylenediamine

Tetrasodium

pyrophosphate

Tertiary

butylcatechol

Tertiary

butylmercaptan

alcohol,

(see Butylcatechol,
(see Butyl

tert)
tert)

mercaptan,

- 788

s-Tetrabromoethane

Texaco

(see Furan)

oil, fluids, grease

titanate

Tetrachlorobenzene

355, 822,

- 365, 366, 879

- 718
- 167,214

bleach

Textone
Thallates

- 365, 837

- 365, 837, 879


- 673
Tetrachlorocyclopentane
- 214
Tetrachlorodifluoroethane
- 837
Tetrabutyl

pyre)
Tetrol, tetrole

Textile
- 11, 18, 157, 251,

837,839,854,879
Tetrabromomethane

pyro-

- 167
(see Sodium

Texas 1500 oil - 366

tert)
Tetramine

(see Potassium

phosphate)

sulfate)

(see Butyl

- 219
- 262

- 278

lead

Tetraphosphoric

Terresstic

alcohol

- 64, 91, 106, 140,

Tetramethylammonium

Terra ponderosa
butyl

chloride

(tetrahydronaphthalene)

Tetramethyl

(see also Essential oils)

178, 271,282,365,820,837,879

Tertiary

- 10, 17, 45, 146, 178,

146, 235,283.365,663,837,845,879

- 178, 628

Terra alba (see Calcium

377, 381,

214

oils

Terpenes

365,

Tetrakis(hydroxymethyl)phosphonium

fumigant

Terpineol

alcohol

154, 219, 235,241,

226

Tenite
Tenol

837,

(see Freon)

Tea (see Foods)


502 - 879

620, 820,

- 837

orthosilicate

Tetrahydrofuran

- 404, 411

salt

- 837

acid

396, 398, 404,411,

808,820,837,844,852,856,883,888,890

Tetrachloride)

- 262

2,3,4,6-Tetrachlorophenol

156,

Telone

718, 740,

760,789,817,833,837,843,852,874

154,

solution

165,

230, 249,

333,

237, 246,

scrubber

158,

219,

323,

151,

770,

292,

156, 157,

214,

332,

225,

647, 653,

155,

322,

150,

Teller

331,

222,

Teepol

845,

321,

119, 140,

Tartrates

657,

789, 822, 837,

330,

178, 214, 219,

740, 755,

770,

177, 204,

328,329,

34, 38, 51, 53, 59, 60, 64, 66, 67, 91, 106,
115,

755,

- 11, 18,

852,879

167, 172,

Tar, ammonia
Tar,

740,

tetrachloride)

381,404,411,463,

1 ,I ,2,2-Tetrachloroethylene

789,879
Tar acid

156, 178, 377,

662, 669,

959

11, 18, 30, 33, 34, 38, 43, 52, 53, 64, 66, 67, 85,

Tar - 59, 64, 91, 140, 156, 271,


432,

(acetylene

1,1,2,2-Tetrachloroethane

837,844,852,879,888,890
Tanning

91, 106,

Index

- 837

Tetrachlorodifluoromethane

jelly

Tannin

Material

Thallium,

of lead, cobalt,
molten

manganese

- 530

- 642

Thenardite

(see Sodium

Thermolin

RF-230

sulfate)

- 214

Thiocarbamide-hydrochloric

acid

- 719

phosphate,

960

Corrosion

Resistant

Handbook

- 628

Thiocarbanilde

249,

- 214

Thioglycol
Thioglycolic
Thiokol

Materials

acid - 109,

167, 214, 628,

845

146,

293,

317, 318,

319.

320, 321,

322,

329,

330,

366,

382,

383,

386,

387,

395,

398, 4104, 411,

377,

439,

628,

632,

653,

662,

663,

728,

763,

789,

792, 800,

804,

808,

820,

837,

845, 852,

178, 214,

235,

262,

- 214

vapor

140, 283,628

Thiosorbic

- 214

lime

- 662

Thorium

- 596

Thread

cutting

Thyme

(oil)

- 681

- 366, 879

Toluene

- 214
- 92, 214, 642,

732,

740,

780,

(see Stannous

411,597,

388,

or Stannic

390,

392,

393,

chloride)

788

Toiuic

acid, meta

- 718

- 628

products

Tin crystals (see Stannous

- 14, 23, 628, 845, 880


- 16, 25, 156,214,262,
628,796
Trancil 1 OC - 880
Transformer
oil - 6, 7, 13, 22, 38, 51, 59, 64, 92,

chloride)

of green soap (see Green soap solution)

Tincture

of iodine

- 106

95, 104,

Tin dichloride

(see Stannous

Tin fluoborate

- 597

156,

chloride)

(see Plating solution,

Tin protochloride

(see Stannous

Tin salts (stannic,

stannous salts)

tin)

chloride)

- 367, 732, 837,

(see Stannic,

stannous sulfate)

- 237,

Titanium

chlorides,

Titanium

dioxide

chloride)

275,

278,

283,

356, 358,

365,

837,

845,

865,867,

869, 871,

sulfate

- 404, 411

- 628

Titanium

sulfate

- 662, 718, 776

sulfate

reduction

Titanium

tetrachloride

150, 154, 232,

Tobacco

tars

Tobias acid

262,

740,763,

- 628

- 214

- 837

148,

150,

Tributyl

citrate

Tributyl

mercaptan

Tributyl

phosphate
158, 214,

219, 262,

Trichloroacetaldehyde
Trichloroacetic

366,439,

628,

662,

59, 67, 92, 106,

778,820,837,879

64, 66, 92, 95, 103, 104,


117, 119,

121,

140,

271,

283,

301,366,

146,

106,

- 214

acid - 10, 17, 34, 40, 45, 51, 53,


109,

119,

140, 156,

157,

167,

219,

249,

262,

271,

366,

372, 378,

382, 393, 404,

411,

647,

653,

718,

740,

Trichloroacetonitrile
Trichlorobenzene
178, 215,

755,

788,837,845,856

230,

- 215
- 39, 41, 43, 44, 45, 46, 60, 156,
292,

392, 628,

663,

789, 837,

880

151, 154,

156,

158,

167,

169,

173,

Trichlorobenzene,

219,

229, 237,

239,

241,

246,

Trichloroethane

222,

- 366, 880
- 31, 59, 66, 92, 148, 150,

271,

770,779,

115,

- 92, 262, 271

- 13, 20, 31, 92, 115, 146,

- 235
- 214

113,

triacetate)

phosphate

178, 214,

51, 52, 53, 59,60,

178, 214,

(see Glycerol

820,837,845,880

- 214
- 2, 5, 8, 9, 11, 18, 26, 31, 32, 34, 38, 45,

112,

876,

879,880

154,

process

tanks, aircraft

111,

366, 810,

820,837,880

Titanium

735,

837,845,852,867,880

- 5, 52, 96, 97, 98, 107, 214,

fluid

- 366, 718, 880


Tribromoethylbenzene
- 262
Tributoxyethyl
phosphate - 283, 291, 293, 366,

- 222

- 628

Tobacco

818,820,

140,

283, 296,

820,

Triaryl

(see Terpineol)

Titanium

119,

281,

273,

Triacetin

246,386,388,390,393,404,411,597
(see Stannic

273,

117,

271,

811,

Travertine

879

112, 115,

173, 214,

Transmission

Tin plating solution

sulfate

106, 109,

167,

364,366,

- 214

Tin tetrachloride

(see Foods)

powder

Toxaphene

Tincture

Tin sulfate

- 214

chloride

Toothpaste,

398, 404,

718,837

OF

- 770

- 214

vapor

Tomato

718,788

chloride

acid - 597,

o-Tolyl

237, 246, 386,

- 38, 45, 51, 167, 178, 214,

Toluic

Toluidines

790

- 837

Tin chloride

acid

Toluenesulfonyl

oils and grease

molten

mixture

373,374,377,382,404,411,

Tin
fumes

- 61
- 262

mixture

Toluenesulfonic

271

- 14, 21

- 662

sulfochloride

Toluene-isooctane

- 231

Tidewater

776,

- 45, 214, 278, 283, 366,

diisocyanate

Toluene-kerosene
oils - 59, 262,

334,

815,820,879
Toluene

and organic acid

331, 332,

879,883,888,890
Toluene

Thiourea

Toluene

328,

336,

394,

chloride

663,

326, 327,
335,

374,

173,

Thiophosphoryl

Titanic

324, 325,
333,

393,

- 34

Tirpineol

296,

373,

- 106,

Toilet

291,
315,

392,

Thiophene

Tinofix

286,
312,

371, 372,

Thiophenol

Tincal

284,
309,

388, 390,

165,

chloride

Thymol

283,
307,

150, 154,

271,366,662,732,837,845,852,879
Thionyl

271,
304,

- 366,879
chloride - 31, 45, 51, 53, 59, 64, 92,
TP

Thionyl

262,

297. 301,

845,880

vapor - 718
- 46, 167, 230, 366, 371, 372, 837,

Corrosive

l,l,l-Trichloroethane
103,

108,

- 9, 38, 40, 42, 46, 66, 92,

148, 215,628

53, 59, 60, 64, 66, 67, 92, 103,


115,

119, 140,

146,

diphenylamine

107,

111, 112,

148,

150, 151,

154,

chloride

Trifluorovinyl

- 9, 11, 18, 31, 34, 38, 46, 51,

Trihydroxybenzoic

acid (see Gallic acid)

- 837

Trihydroxyethylamine

156,

Trim

5050/H,O

- 102

157, 167,

173,

178, 215.

219, 230,

237,

239,

Trimethylacetic

acid - 178

246, 249,

262,

271,

283,

286, 291, 292,

293,

Trimethylamine

- 178, 262

301, 307,

310,

312,

315, 366,

372,

373,

Trimethylamine

hydrochloride

392, 393,

394,

Trimethylbenzene

374,

378, 382,

383, 388,

390,

411,

371,

- 215

- 629

- 12, 20

395, 397,

398, 404,

439, 488,

628,

632,

Trimethylbenzyl

ammonium

chloride

642,

647,

653,

662, 663,

676,

718,

719,

Trimethylbenzyl

ammonium

hydroxide

728,

740,

743,

755,

763,

770, 789, 800,

804,

Trimethyl

borate

- 215

808, 820,

837,

845,

852, 880,

Trimethyl

carbinol

682,
883,

884,

888,

890

Trimethylene

- 215

Trichloroethylene

fumes

Trichloromethane

(see Chloroform)

Trichlorofluoroethane

- 439,

Trichlorofluoromethane

763

- 837

- 178, 528
- 31, 150, 154, 262, 271

phosphate

Trinitrophenol
Trinitrotoluene

- 92, 156, 292, 439,

763,

845,

880

- 226
- 439,

phosphate

66, 92, 157,


306,

789,820,

(tritolyl

167, 215,

309,

312,

763, 837

- 31, 51,

phosphate)

262, 283,

315,

291,

366, 494,

719,

- 51, 167, 215


- 13, 31, 34, 38, 46, 59, 64, 92,

108,

115, 140,

150,

153,

173,

178, 215,

235,

262, 271,

306,

309,

315,

312,

382, 394,

395,396,

837,845,

880

154, 156,

Tripropylene

glycol - 92

Tripropylene

glycol

methyl

ether

(see Tricresyl

- 262
phosphate)

Tris(hydroxymethyl)nitromethane
Trisodium

phosphate

215

- 1, 31, 46, 51, 59, 60, 66, 93,

140,

146,

150,

151,

152,

154,

156, 167,

232,

237,

246,

249,

262,

271, 301,

386,

366,

368, 371,

372,

378,

370, 372,

373,

374,

378,

382,

629,

657,

788, 820,

393. 394,

395,

396,

397,

398, 404,

632,

663,

710,

755,

762,

662,

lauryl sulfate

hydrochloride

Triethylamine

salts

662,

770,

800,804,808,836,838,844,852,

- 215

- 215

- 215

glycol - 10, 17, 92, 146, 215,

371,372

229,

301,

357,

795,

366,

382, 388,

390,

411,

812,

880

- 178
- 156, 301, 366, 843, 873

- 366, 865

Turbo

oil

Turco

W.O. #I

Turkey

246, 283,

629,663,

acid
oil

red oil

Turpentine

- 146, 226

784, 788,

- 215

Tungstic

- 629

627,

Tung oil (China wood oil) - 93, 156, 237,

Turbine

- 366, 837, 845, 880

392,

439,

877,880,883

820,825,838,843,845,860,873,

- 44, 46

388, 390,
411,

- 262

dl-Tryptophan
Tuna oil

788

Triethylamine

phosphate,

219,

- 366, 837, 845, 880


- 31, 43, 59, 92, 103, 173, 215,

Triethylenetetramine

(see Sodium

115,

aluminum

Triethylene

(STPP)

tripoly)

108,

sulfonate

Triethylborane

Tripolyphosphate

173, 215,

linear alkylate

Triethylenediamine

- 108, 173, 215, 241, 249,

763,880

167,

Triethanolamine

271,629,

phosphite
547,662,

303,

- 719

219, 262,

- 609

157,

hydrochloride

Triethylamine

tripalmitate)

phosphate

283, 301,

Triethanolamine

ammonium

trioleate)

(see Glyceryl

Tritolylphosphate

sulfonate

Triethanolamine

Triethanol

301,

629,

837,845,880,888,890

Tridecylbenzene

Triethyl

(see Glyceryl

439,

- 286

Trichlorotrifluoromethane
Tricresyl
303,

Triolein

Triphenyl

Trichlorotrifluoroethane

- 20, 366, 629, 838, 880


- 366,838,
880

(TNT)

phosphate

Triphenyl

- 230

Trichloropropene

(see Picric acid)

Trioctyl
Tripalmitin

Trichloropropanolamine

- 103

Trimethyl

Trichloronitromethane

Trichloropropane

alcohol)
- 167

(see Isooctane)

Trimethylpropane

- 662, 842
- 51, 167, 215, 262, 663
sodium salt - 262

- 10, 17

Trimethylpentane

Trichlorophenol
Trichlorophenol,

(see Butyl

chlorobromide

3,5,5-Trimethylhexanol-3

(see Freon)

961

index

- 719
- 837, 880
chloride, oils, greases - 215

Trifluoromethyl
Trifluorovinyl

- 103, 215, 262, 292

1,1,2-Trichloroethane
Trichloroethylene

Material

95, 104,

- 845

- 235

- 2, 6, 7, 26, 31, 51, 59, 60, 66, 67, 93,


106,111,

115,

117,

119,121,140,146,

Triethyl

phosphate

- 92, 121, 249, 880

148,

150,

151,

154,

155,

156,

167,

173, 215,

Triethyl

phosphite

- 92

235,

249,

262,

271,

279,

283,

291,

293, 296, 301,

Tri Film 250

- 880

Trifluorochloroethylene
Trifluoroethane

- 366

- 679

219,

366,

373,

374,

378,

382,

392, 442,

597, 629,

632,

653,

662,

663,

728,

784,

789, 820,

838, 845,

852,

880,888,890

962

Corrosion

Turpentine

Materials

Handbook

- 838

substitute

Vacuum

- 167

Tween
Tycol

Resistant

pump oil

- 106

Vagh resin solution

- 283, 820

products

- 719

Vagh varnish - 719

I Fuel - 366
II Fuel - 366
Type III Fuel - 366
Typewriter
oil - 235
dl-Tyrosine - 262

- 845, 880

Type

Valclene

Type

Valerie

acid - 629,

Valves,

pumps - 729

200

Vanadium

oxide - 728

Vanadium

sulfate-sulfuric

Vanasol
UDMH

(Unsymmetrical

dimethyl

hydrazine)

- 219,

303,306,309,312,315,366
Ucon products
Udylite

- 102,

820

Ultrasonic

cleaning

Ultrawet

detergent

Undecyl

alcohol

Undecylenic

- 884

solutions

- 185, 215

- 366

fluid

- 156, 215
- 732
chloride

Uranium

extraction

- 597,

Uranium

fluoride

740

140, 271

_ 140

Aturbrio
oils

No. 60 - 880
- 36, 51, 57, 60, 62, 63, 64, 84,
374,

- 215

378,

382, 383,

385,

392, 393,

396, 403,

410,

442,

538, 632,

646,

663,

788, 820,838,

- 598,

728,

acid - 384

Vegetables,

- 740

Veneer

740

vegetable

drying

juices (see Foods)

- 215

fumes

- 728
- 283,366,820,838,
Vicks VapoRub - 23
Vent

gas

Versilube

- 34, 51, 59, 61, 64, 66, 67, 93, 115, 140,
151,

153,

154,

155,

219, 237,

246,

262,

271,283,

374,

378,

382,

383,

386,

388, 390,404,411,

432,

156,

167,

173, 215,

598,

599,

629,

663,

719,

371,372,
727,

373,

784,

788,

820,838,853,888,890
reaction

268, 279,

843,845,852,873,880

phosphate

- 740

mass - 740,

nitrate

mixture

- 845,

755,

770

- 215

Vicks

Va-Tro-Nol
D fumigant

Vinegar

(see Foods)

Vinegar

naphtha

Vinegar

and salt

Vinegar

salts

- 216

(see Ethyl

acetate)

- 780

- 838

acetate - 31, 38, 51, 59, 62,93,

168,

- 215

880

- 23

Vidden

Vinyl

880

173, 216,

219,

262,

271,

150,

154,

283, 498,629,

719,788,789,820,832,871

Uric acid - 1, 66, 67, 93, 225, 404,

411, 439,

442,

728,735,763,779,788,856

- 25,31,

262,

271,

59, 93, 115,


373, 374,

378,

- 108, 215
- 366

150,
382,

154,
845,

- 363, 842
- 42, 46, 64, 93, 156, 262, 283,

Vinylacetylene
Vinyl

853,880

chloride

366,439,

599, 629,

- 366

H-910

- 366

VV

I-530a

- 366

VV

K-21 Id, 220a

Vinyl

chloride

latex - 719

Vinyl

chloride

vapor

Vinyl

2-chloroethyl

VV

L-751 b, 800,82Ob,

VV

O-526

VV

P-216a.

- 366

- 366

- 678

Vinyl

ester resin 45% styrene


fluoride

Vinyl

Vinyltoluene-

- 38

- 156, 820

chloride

plastisol

Vinylpyridine

- 366

728,

(see Acrylonitrile)

Vinylmethacrylate
825a

719,

- 720
ether

Vinyl

Vinylidene

- 366

662,

820,838

Vinylcyanide

VV G-632,671~

236

oil

262,

nitrate

VV

- 59, 64, 102, 119,

372, 373,

sulfate

B-680

Vaseline
Vaseline

216,

Uranyl

VV

185E - 215
- 16, 25, 148, 215, 219, 235, 284

371,

Uranyl

Urine and Urea

629,

167, 203,

sulfate-sulfuric

Urea-formaldehyde

539,

293, 366,

ammonium

Urea-ammonium

156, 283, 366,

156,

719

Urotropine

- 93, 140,

289,

- 215

156, 235,

- 215

Varnish

134,

ore - 598,

Urea resins

- 215

222-90

285,

SX units

Urea-ammonia

K-300

Varisoft

121,

Uranium

150,

880

283,

- 215

Uranium

Urea

853,

- 140

Variquat

Vegetable

Uranium

Uranyl

- 115, 229, 845,

- 880

Veedol

Uranium

Uranium

- 629

Varsol

oils and fluids - 283, 820

Uran

extract

Vanillin

Varox

- 845

restorative

Unvis hydraulic

- 21, 140

Vanilla

632,653,728,789,820,838,845,880

- 93, 226

acid - 629

Undertakers

Vanilla

Vapona

light - 94

- 384

acid

- 215

Vanillindropar

- 215

feed

Union

366,

- 845

#61

Ultraformer
Ultraviolet

156, 283,

788

- 93, 262,
- 157

- 23
- 881
168, 216,

663

663,

881

763, 789,

Corrosive

Vinyl

- 216, 838
- 728, 881

trichloride

Viscose
Vitamins

- 629

VM&P

naphtha

- 148, 394

784

98, 99, 107, 110, 600,

- 216
- 222,601,632,642,652,775,871,881
Mineral - 106, 601
Oil well - 602
pH 3,7 or 10 - 216
Potable - 31, 51, 62, 141, 153, 216, 249, 250,
Irrigation

Mine

- 845
- 366
- 216

Washer hoods, ducts, chlorination

- 216

Wash solution
Washwater
Waste oil

601,

728,735,881

(see also Naphtha)

Wagner brake fluid

Waste gas

- 196, 600,

- 34, 64, 96,97,

Hot

- 216

organic contaminated

High purity

395,838
WRDA

- 216

Ground,

oils

from

27 1,283,358,653,

- 720

rayon staple bleach machine

- 720
- 156, 216

Wastewater

- 602,720

River and lake

- (see Water,

Wastewater,

720

- 663

Rain

chlorine - 740
- 31, 32, 34, 38, 51, 59, 60, 62, 93, 137,

River, saturated
waste)

Salt

- 217, 720, 721


- 216, 445
filters - 217

oils, chemicals

Wastewater

treatment

Wastewater

trickling

141, 150,

154,

155,

168,

173,262,271,290,

364,

632,

639,

701,

735,

392,

- 16, 26, 31, 32, 34, 36, 38, 51, 52, 59, 66,

Scrubber

Sea-31,34,36,51,53,59,62,66,88,112,115,

106,

146,

147,

107, 110,

111,

119, 121,

156, 157, 219,

239, 240,271,

284, 285,

286, 289,

290,

291,296,

366, 371,

372,

387, 393,

386,

141,

271,

93, 150,

283,

150, 151,

153,

154,

155,

207, 216,

219,

222,

249, 260,

394, 395,

629,

151, 154, 247,

Brackish

881

674,

720,

735, 891

- 66, 146, 233, 281,382,

626,

636,

639,

642,

646,

647,

652, 663,

664,

665,

666,

706,

720, 726,

731,

735, 739,

740,

747,

748, 755,

with solvents

Soil - 639

Deionized

- 216

With oxidizing

117, 150, 154,

168, 173,

190,216,249,262,275,813,826,881

- 28, 31, 34, 38, 40, 46, 51, 93,

Demineralized

168,173,

190,216,262,271,283

- 4, 6, 7, 25, 34, 36, 38, 41, 46, 51, 53,

59,60,61,

62,93,95,

169, 173,

255, 262,

128,

192, 216,

271, 283,

149,

153, 154,

218, 223,

224,233,

290, 302,305,308,

311,

314,

317,318,

319,320,321,322,323,

324,

325,

326,327,

328,329,

333,

330,331,332,

334,335,336,337-354,373,374,378,382,
383, 392,

663,

720, 800, 804,

salts - 156

- 881
- 235, 788
Water glycols - 283
Water-oil emulsions - 283
Water-oil separation - 216
Water paints, childrens - 235
Waterproofing
salt - 838
Water purification
solution - 720
Water softener - 52
Water soluble oil - 235
Water treatment chemicals - 62
Water glass

Water treatment,
808,

845, 853,

881,883

Waterworks

271, 297,

639, 642,

648,

373, 374,

378, 382,

720, 800, 804,

600,

808, 845,

softening,

primer

Waving lotions

- 34, 36, 51, 52, 93, 141, 150, 154, 168,

173, 262,

- 173, 216
720

With soluble oil

- 93, 104,

154,

- 604,605,

- 605
- 605
Waste - 605, 606

- 740

853,883

- 31, 59, 62, 88, 262, 271, 373, 374,639


- 604, 639

Treated

- 53, 216

tower

Degassed

- 207, 216
- 723

chlorine

Tap

Contaminated

632,

386,421,423,
625,

Steep

Cooling

Fresh

314,
604,

Steam condensate

- 216
Cold - 64, 845
Condensate - 216,600

168,

311,

Softened

City

Distilled

308,

602, 603,

Sewage

651,663

150,

305,

Sea, saturated

- 93, 599, 600,


(soda)

302,

Sea, desalination

- 283,285,639

Carbonated

173,

281, 297,

769,776,780,784,788,818,847,876,881

- 663, 881

Boiling

168, 169,
271,

445,

- 216

Boiler feed - 93, 599, 845, 859,

Brine

262,

301,

156,

426,431,

726,780,781,845,853,854

Acid organic

835,

- 720

297, 301,

728,731,788,789,795,820,838
Acid mine - 59,69,

780, 818,

845,853,876,881,891

67.93,

Water

index

- 216

Geothermal
Geyser

- 283, 820
Vitriol oil - 881
Vivo-Zyne
- 216
Vitrea

Material

solvent

(see also Cosmetics)

Wax - 93,606,629,663,789,812

- 217
- 156

Chlorinated
Distillate

coagulating

- 216

- 156
- 15,23,493

963

964

Corrosion

Resistant

Materials

Handbook

Wax (contd)

- 64

Molten
Refined,

- 281, 818
- 141, 235

petroleum

Wax crayon,

pencil

- 141

Wedac

- 15, 24, 25, 156, 161, 195, 217, 235,

Weed killers
276,

281,616,796,845,881

Wemco

146,

148,

150,

151,

154,

156, 157,

168,

178, 217,

219,

229, 237,

241, 246,

249,

262,

271,

283,

285, 286,

290,

291,

293,301,

304,

307,

309,

312,

366,

371,

372, 373,

374,

378,

382,

386,

387, 388,

390, 392,

393,

394, 395,

404,

411,

607,630,

632, 663,

721,

- 217, 607, 721


- 64
Xylidenes - 366, 822, 838, 881
Xylene

Wesson oil (see Foods)

mixtures

Xylenol

Wet gases from copper smelting

- 62

- 115, 629, 853


Wheat germ oil - 141
Whey - 62,217,
721

Yeast (see Foods)

White

Yogurt

Wetting

agents

Yeast wort

acid - 219

- 838
- 838
White iodine - 235
White

caustic

White

copperas

lead, sublimed

lead sulfate

150,

151, 154,

168,

173, 217,

271,418,

783,

White

liquor with
oil

White

pine oil - 291,

White

spirit

- 64, 94, 119, 141

White

vitriol

(see Zinc sulfate)

Whiting

black liquor

- 418

Zinc carbonate
293,

366

66,67,94,
carbonate)

146,

- 423

- 217

oil (see Methyl

salicylate

and

Essential oils)
Wire pickling
Witch

- 217
- 146, 231

fumes

hazel distilled

Wolmar

salt

- 283,291,

178, 217,

219,

222,

232,

237,

246, 249,

283,

291, 301,

303,

306,

309,

311,

373,

374,

382,

383,

386,

388,

378,

390,

392,

393,

394,

395,

397,

398,404,411,

439,

607,

608,

630,

632,

646,

647,

653, 662,

721, 727,

728,

732,

735, 740,

755,

763,

776,

784,

788, 800,

Zinc

- 630

Zinc
Zinc

- 838

Zinc
acid)

Zinc

- 67, 156

Worcestershire

778,

chromated
flux

804, 808,

770,

820,838,

- 721

- 721

- 31, 630, 820


- 31, 94, 156, 784, 881
dihydrogen phosphate - 721
dimethyldithiocarbamate
- 217
electrolytic
cells - 217
fluoborate - 217
fluosilicate - 608, 662, 721
formaldehyde
sulfoxylate
- 608
hydrate - 67, 283

Zinc hydrosulfite

sauce

- 146, 229

Zinc,

molten

- 94, 642,

Zinc naphthenate
solution - 740, 770
- 2, 9, 11, 18, 26, 31, 34, 38, 39,

developer

Zinc nitrate

788,

271,

303, 306,

309, 311,

374,

382, 386,

390,404,411,

111,

630,784,881

121,

770, 780

262,

103, 106,

115, 119,

732, 740,

- 630

373,

370,

113,

721,

- 31, 51, 59, 94, 154, 156, 168, 217,

46, 51, 53, 59, 60, 64, 66, 94,


112,

262, 662,

237, 246,

41, 43, 44,45,


108,

- 108, 217,

845,881

- 366
xylol

141,

271,

Zinc
293,366,838

Wood vinegar (see Pyroligneous

X-ray

119,

157, 158,

173,

Zinc

Wood pulp - 94

Xylene,

156,

Zinc cyanide

- 721

Wood preservatives

Xenon

110, 115,
155,

Zinc chromate
alcohol)

Wood creosote - 629

Wool oil

109,
154,

262,

Zinc chloride

(see Methyl

Wood fractions

tar

108,
152,

845,847,881,883,888,890

- 366

Wood alcohol

Wood

151,

Zinc chloride,

Wood - 629

Wood oil

106,

147,

314,366,

waste

Wintergreen

721,

- 217
- 51, 168
Zinc chloride - 12, 20, 31, 34, 38, 59, 60, 62, 64,

- 217
- 217

Storage

607, 662,

Zinc casting fumes

Wine

Winery

- 94, 146, 232, 439,

Zinc chlorate

(see Calcium

Wick test, modified


Fermentation

- 784, 788, 881

763

- 217, 845
- 235
838

chloride

- 630
Zinc bromide - 232

- 156, 366

- 629,

881
Zinc ammonium
Zinc borate

White

wax

- 366, 721, 838, 881


- 283, 820
Zimmite,
mud remover - 217
Zinc acetate - 173, 283, 366, 630, 788, 820, 838,
Zeric

845,853,881,888,890

White water

- 727

(see Foods)

Zeolites

- 836
- 838
White liquor, pulp mill - 31, 44, 46, 51, 59, 94,
White

White

White

315,

728,789,820,838,845,853,881,888,890

- 366,881

141,
173,

372,

314,

Corrosive

- 20, 64, 119, 141, 232, 283, 630


- 231
Zinc phosphate - 173, 217, 881

Material

Index

Zinc oxide

728,

732,

733,

735,

740,

763,

770,

776,

778,

Zinc oxide ointment

784,

788,

796, 800,

804,

808,

820,

838,

845,

Zinc plating solution

(see Plating solutions,

881,883,888,890

zinc)

Zinc sulfate fumes

- 721
- 384, 721

- 150, 367, 853, 881


Zinc smelter fumes - 217

Zinc sulfate-sulfuric
Zinc sulfite

- 217

Zinc stearate - 94, 146, 232, 630

Zinc vitriol

(see Zinc sulfate)

Zinc salts

Zinc sulfacarbolate
Zinc sulfate

- 31, 34, 51, 59, 60, 64, 67, 94, 106,

108,

109,

156,

168, 173,

246, 262,

- 232

Zircex

liquid

- 722

phase hydrochlorination

141,

151, 152,

154,

Zirconium

178, 217,

219,

222, 232,

237,

Zirconium

- 722
raffinate - 46

I 283, 366, 373, 374, 382, 386,

Zirconium

tetrachloride

- 608

Zirconium

tetrachloride

fumes

388,

390, 392,

393,

394, 395,

404,

411,

608,

630,

439,

solutions

119,

113, 115,
271

Zircex

acid

396, 397,

632, 653,

662,

398,
721,

chloride

_ 722

- 721

965

Company Name and Address Listing


The editor is indebted to the organizations
listed below for supplying the data used in
the preparation of this book.

Amoco Chemicals Corp.


200 East Randolph Drive
Chicago, IL 60601

Abresist Corp.
P.O. Box 38
State Road 13 North
Urbana, IN 46990

Ampco Metal
Division of Ampco-Pittsburgh
P.O. Box 2004
Milwaukee, WI 53201

Acme-Fisher Division
Broadway Rubber Corp.
P.O. Box 1135
Louisville, KY 40201
Allegheny Ludlum Steel Corp.
Division of Allegheny Ludlum Industries,
2000 Oliver Building
Pittsburgh, PA 15222

Corp.

Arco Metals Co.


American Brass
Two Continental Towers
1701 Golf Rd.
Rolling Meadows, IL 60008

Inc.

Allied Engineered Plastics


P.O. Box 2332Fi
Morristown, NJ 07960

Armco Stainless Steel Products


P.O. Box 600
Middletown, OH 45043

Aluminum Association, Inc.


818 Connecticut Ave., N.W.
Washington, DC 20006

Ashland Chemical Co.


Division of Ashland Oil, Inc.
P.O. Box 2219
Columbus, OH 43216

Aluminum Company of America


1501 Alcoa Building
Pittsburgh, PA 15219

Astro Metallurgical Corporation


Division of Harsco Corp.
3225 Lincoln Way West
Wooster, OH 44691

American Cyanamid Company


Organic Chemical Division
Wayne, NJ 07470

Atlas Minerals & Chemicals, Inc.


Farmington Road
Mertztown, PA 19539

American Iron and Steel Institute


1000 16th Street NW
Washington, DC 20036

Barnant Co.
28 W 092 Commercial
Barrington, IL 60010

Ameron
Corrosion Resistant Piping Division
595 West Lambert Rd.
Brea, CA 92621

Bethlehem Steel Corp.


Bethlehem, PA 18016
Brush Wellman Inc.
17876 St. Clair Avenue
Cleveland, OH 441 IO

Ametek, Haveg Division


900 Greenbank Rd.
Wilmington, DE 19808

892

Ave.

Company

Subsidiary

Reading,

Danvers.

of Illinois

30 Endicott

PA 19603
Division

Tool Works,

Inc.

St.

MA 01923

Dow Chemical

USA

Cabot Corporation

The Dow Center

1020 West Park Avenue

Midland,

Kokomo,

Listing

Devcon Corp.

Cabot KBI Division


Cabot Corporation
P.O. Box 1462

Cabot Stellite

Name and Address

Ml 48640

IN 46901
Dow Corning

Cabot Wrought

Products

Division

Midland,

Corp.

Ml 48640

Cabot Corporation
1020 West Park Avenue

E.I. du Pont de Nemours

Kokomo,

IN 46901

Carpenter

Technology

Carpenter

Steel Division

1007

Market

Wilmington,
Duriron

PA 19603

West Cedar Drive

Lakewood,

Co. Inc.

Box 1145

CEEL-CO
12990

DE 19898

Corporation

P.O. Box 662


Reading,

& Co., Inc.

St.

Dayton,

OH 45401

Eastman

Chemical

Products,

Inc.

P.O. Box 431

CO 80228

Kingsport,

TN 37662

Celanese Plastics Co.


Division

Elkhart

of Celanese Corp.

26 Main St.
Chatham,
Climax

Randolph

NJ 07928

Molybdenum

Division

Rubber

of Amax

One Greenwich
Greenwich,
Colt
2188

Industrial

High Point,

Co.

NC 27264

Inc.
Everflex

Plaza

Artell

CT 06830

Products,

Inc.

Road at Holyoke

St.

MA 01056

Industries
Tube Division

Exxon

Church

P.O. Box 3272

East Troy,
Corning
Corning,

St.

Houston,

WI 53120

Cyclops

Americas

TX 77001

Fabric0

Glass Works
NY

Chemical

4222

14831

South

Chicago,

Pulaski

Rd.

IL 60632

Corporation

Universal-Cyclops
650 Washington
Pittsburgh,
Dart

Park

P.O. Box 7385

Ludlow,

Trent

Inc.

Lois Lane

Specialty
Rd.

PA 15228

Industries

Special Projects

Steel Division

Gates Rubber
999 South

Co.

Broadway

P.O. Box 5887


Denver,

CO 80217

General

Electric

Inc.
Division

Co.

P.O. Box 37

Noryl

Paramus,

Selkirk,

NY 12158
Metals Technologies

NJ 07652

Ave.

Dayco Corp.

General

333 W. First St.

8800

Dayton,

Richmond,

OH 45401

Metro

Court
VA 23234

Corp.

893

894

Corrosion Resistant Materials Handbook

B.F. Goodrich
6100

Cleveland,
Haysite
5599

Chemical

Minor

Co.

Mobay

Plastics

1313

USA,

Division

800

St.

Alloys,

Chemical

Co.

Business Technology
1445 Summit
Columbus,
Huron

Nickel

WV 25720

Huntsman

Center

St.

Co., Inc.

OH 43201

Molded
VA 24203

Morton

Thiokol,

Morton

Chemical

Lower

Trenton,

Ltd.

Alexandria

Rochester,

Bay, NY 13607
Corp.

IL 60062

Interplastic

Corporation

N.E.

Inc.

Elkhart,

Ave.

IN 46515

MN 55413
NRC

ITT Jabsco
1485

Inc.

PA 18071

500 Simpson

Broadway

Minneapolis,

Corp.

Creek Dr.

NY 14602

Palmerton,
Nibco

2015

of Sybron

New Jersey Zinc Company,

Ave.

Northbrook,

Division
Rd.

Nalge Co.
Division

Titanium

Inc.

NJ 08650

75 Panorama

Commercial

Ave.

Ferry

P.O. Box 308

Industrial

Co.

Fiber Glass Co.

Bristol,

Casson Crane Division

3041

Products
Blvd.

400 Commonwealth

930

Chemicals

Polymer

N. Lindbergh

Morrison

Inc.

of the International

Huntington,

Division

St. Louis, MO 63166

DE 19894

Huntington

Corp.

PA 15205

Monsanto

Inc.

N. Market

Wilmington,

Chemical

Pittsburgh,

Erie, PA 16509

Inc.

NJ 07003

Plastics and Coatings

New Perry Highway

Himont

Company,
Street

Bloomfield,

OH 44131

Reinforced

Rubber

49 Ackerman

Oak Tree Blvd.

Inc.

45 Industrial

Dale Way

Newton,

Place

MA 02164

Costa Mesa, CA 92626


Janney

Cylinder

An Ampco-Pittsburgh
7401

State

Oberdorfer

Company

Syracuse,

13221

Company

Road

Philadelphia,

Pump Division
NY

Occidental

PA 19136

Jessop Steel Co.

Chemical

Walck

Rd.

North

Tonawanda,

Corp.
NY 14120

Jessop Place
Washington,

0- I/Schott

PA 15301

Process Systems,

1640 S.W. Boulevard


Kennametal
Latrobe,

P.O. Box T

Inc.

Koch Engineering
M.A.

Vineland,

PA 15650

Knight

Peabody

Co. inc.

South

Division

NJ 08360
TecTank

Industrial

Inc.
Park

P.O. Box 109

P.O. Box 996

Akron,

Parsons, KS 67357

OH 44309

Lead Industries
292 Madison
New York,

Association,

Ave.

NY 10017

Inc.

Pennwalt
Three

Corporation

Parkway

Philadelphia,

PA 19102

Inc.

Company

Shell Chemical

Pfaudler

Co.

Division

of Sybron

Rochester,

Phillips Chemical

Houston,
A.O.

Co.

of Phillips Petroleum

Bartlesville,

Co.

Smith-Inland

International

Avon,

Sohio Chemical
Midland

Merchandize

Stainless Foundry

Mart Plaza

Technology,

108 Lake Denmark


Rockaway,

OH 44115

Inc.

IL 60654

Radiation

& Engineering,

5 150 North

35th

Milwaukee,

WI 53209

Inc.

Street

Inc.
Sternson

Rd.

Limited

22 Mohawk

NJ 07866

Brantford,
Resistoflex

Co.

Bldg.

Cleveland,
Oats Chemicals,

Chicago,

St.

Rock, AR 72209

Inc.

Rd.

OH 44011

Quaker

Inc.

Plastics Division

West 65th

Little
Plastonics

Co.

TX 77001

Reinforced
2700

OK 74004

951 Jaycox

Listing

P.O. Box 1422

Corporation

NY 14603

Subsidiary

Name and Address

St.
Ont.,

Canada N3T 5NI

Corporation

Subsidiary

of UMC

Roseland,

NJ 07068

Industries,

Inc.

Ston hard, Inc.


Park Avenue
P.O. Box 308
Maple Shade, NJ 08052

Resolite
Division

of H.H.

Robertson

Co.
Sulcon Systems

P.O. Box 338


Zelienople,

P.O. Box 427

PA 16063

Champaign,
Revere Copper
Subsidiary

Products

IL 61820

Inc.

of Revere Copper

and Brass, Inc.

Teledyne

Allvac

P.O. Box 300

P.O. Box 759

Rome,

Monroe,

NY

13440

NC 28110

Rilsan Corp.

Teledyne

Subsidiary

P.O. Box 460

of ATOCHEM

139 Harristown
Glen Rock,

Albany,

Rd.

Wah Chang Albany


OR 97321

NJ 07452
Thermoplastic

Rohm and Haas Co.

1268

Independence

Stirling,

Mall West

Philadelphia,

PA 19105

A. Schulman

Inc.

Valley

Processes Inc.
Road

NJ 07980

Thermoplastic
3550

West Market

Affiliate

57 Stirling

St.

Warren,

P.O. Box 1710


Akron,

Scientifics,

of Thermoplastic

Inc.
Processes, Inc.

Rd.

NJ 07060

OH 44309
Thompson-Chemtrol

Schwarzkopf

Development

140 Lowland

St.

Holliston,
Sethco

MA 01746

Division

Corp.

Division

of Finish Engineering

921 Greengarden
Erie, PA 16501
3M

Met Pro Corp.

Ceramic

70 Arkay

3M Center

Hauppauge,

Dr.
NY 11788

Rd.

Materials

St. Paul, MN 55144

Department

Co.

895

896

Corrosion Resistant Materials Handbook

Wall Colmonoy Corporation


19345 John R Street
Detroit, MI 48203

Timet
400 Rouser Rd.
P.O. Box 2824
Pittsburgh, PA 15230
Union Carbide Engineering
P.O. Box 446
Marietta, OH 45750

Polymers

U.S. Graphite, Inc.


1621 East Holland
Saginaw, MI 48601
U.S. Industrial Chemicals Co.
Division of National Distillers and
Chemical Corp.
99 Park Ave.
New York, NY 10016
Vulcanium Corporation
3045 Commercial Avenue
Northbrook,
IL 60062

Walworth Co.
P.O. Box 873
Valley Forge, PA 19482
Watersaver Company,
P.O. Box 16465
Denver, CO 80216

Inc.

Westlake Plastics Co.


Distributor for Mitsui Petrochemical
Industries, Ltd.
P.O. Box 127
Lenni, PA 19052

Trade Name Index


Trade name designations of the materials for which
corrosion resistance data are given in the tables are
listed in this index.

ABRESIST

CH LOR IMET - 773,797


CH LOROSOL - 355
CLADKOTE - 388

- 391,393

ACIDSIL

AF LAS - 285
AL-6X - 412,445

COLMONOY

AL 29-4-2 - 414
AL29-4C-414
ALFANE
ALKOR

- 242

CHEMPRUF

- 791

- 728

CORESITE - 391,396
CO-REZYN - 159
CORLOK - 399

- 389
- 389

ALLCORR - 665
ALLOY 825 - 446

CYANACRY L - 284,298
CYANAPRENE
- 296

ALOYCO - 785
AMBRALOY
- 649

CYANASET

- 654

AMBRONZE

- 296

DELORO - 730,756
DELR IN - 220

AMPCO - 632
AMTEX - 355
AMZIRC - 654

DERAKANE - 108, 109,223


DEVCON - 32
DOW-251

AROPOL - 179
ASPLIT - 399

DOWMETAL
DP-3 - 429

ATLAC - 108, 109,223


ATLASTAFLEX
- 242

DURALON - 805
DURAN - 882
DURCO - 221,773

- 242

ATLASTIC

- 797

- 773

DURCOMET

BAREX - 9
BEV-A-LINE

DURCON - 34,221,805
DURCOTHENE - 221

- 172
BONDSTRAND - 33,170
BRUSH ALLOY

DUREZ - 95,805

25 - 639

DURICHLOR - 773,797,882
DURIMET - 427,773,797
DURI RON - 773,797,882

BUNA N - 355,809,854,885
BUTENE - 355
CABOT - 666

DURO - 355

CALSUN BRONZE - 654


CARBO-KOREZ
- 389
CARPENTER

20 - 446,797,885,891

CARPENTER

20Cb-3 - 421,422,423,427,

DYNEL - 884,885
E-BR ITE - 417
EPILOC - 391
EPON - 35

433,445,
CEEL-TITE

665,757,777
- 1, 151

ETHOCE L - 802

CELANESE

- 63

EVERDUR

CER-VIT

- 649,797

EXCELON - 154
EXTREN - 47

CELANEX - 52,239
CELCON - 3

FERRALIUM

- 882
- 802

FLEXANE

CHEMIGUM

897

- 420,429,445,846
- 297

898

Corrosion Resistant Materials Handbook

FLUOREL

- 355

MERLON - 106
MF-1 - 419

FLUOROFLEX
- 218
FLUOROSILICONE
WK-8870 - 355

MINCAR

FN - 399
FORAFLON

MIRCO - 355
MIRPRENE - 355

- 155

- 355

FURABOND - 406
FURALAC - 399

MONEL - 632,641,664,757,777,781,
782,783,784,797,846

FURASET

MULTIMET

- 406

FURNANE

- 382

GALVALUME
GATRON

- 638

- 809

GLASTEEL

- 793

GRAPHITAR - 786
GREEN THREAD - 37
HALAR - 54,848
HASTE LLOY - 69,445,665,666,730,
757, 777,797,846,854,885,889,

- 424

NALGENE - 848
NEOPRENE - 242,299,355,367,802,
809,839,848,854,885
NEXTEL - 790
1900 (UHMW Polymer)

NO RY L - 102,240,247,854,885
01 L ACE - 355

891
HAVEG - 174,805

OR LON - 885

HAYNES

PENCH LOR - 399


PENNGUARD - 387,792

- 644,666,730

HB - 399
HERCULOY
HERESITE

- 648
- 805

H.E.S. - 399
HETRON - 108,179,223
HYPALON - 250,299,355,809,885

- 272,299
- 426,725
INCOLOY - 665,777
INCONEL - 427,445,664,665,777,

PEBAX - 110

PENNTROWEL

- 375

PENTON - 247,802
PERMANITE - 60,391,392,805
PETROTHENE - 114
PLEXIGLAS - 6,802

HYTREL

PLIADUCT

ILLIUM

POLYCAST - 355
POLYMAN - 2
POLY THREAD - 37

783,797,891

- 112

N ITRON IC - 428
NORDEL - 299,355

- 149

PYREX - 792,797

IN 0 BOND - 406
IRONSIDES - 355
JS 700 - 413,429,445

QUACOR R - 39

JS 777 - 413

QUALATEX

K14 - 399

QU I K- LOCK - 33

KABO - 391,398
KBI-40 - 733
KEL-F - 802

RADGROUT-H - 383
RED THREAD II - 37
RESIBOND - 391,394,395

KENNAMETAL
- 771
KENTAN IUM - 772

RESIST-O - 355
RESISTOFLEX - 218

KIMAX - 882
KNIGHTBOND

RESOLITE

- 53

REVALON
REZKLAD

- 648
- 373,388

- 391,397

- 116
KOROSEAL - 242,367
KYNAR - 69,247,251,848,885
LIQUATHAN E - 297
LUCITE - 802,885
LUSTRAN - 225
LUSTR EX - 225
MASTE RF LEX - 238
MATCH LESS - 355
KODAR

PYROITE - 68
QO FA-RoK - 383
- 355

RYN ITE - 220


RYTON - 120,247,854
S12 - 429
S13 - 429
SAF 2205 - 429
SARAN - 251,802
SDX - 399
SILASTIC

- 287

Trade Name

SILIGLAS

- 294

ST - 290
STELLITE

TRISTELLE
- 425,643,730,756,797

STERNCHEM
STONCLAD

TR IBALOY

- 406
- 369

STON LAST - 293


STY RON - 805
SUCOAT - 384
SULCON - 384
SUPERCHLOR - 773
TALYCHEM - 379,406
TECLINE - 155
TEFLON - 69,156,157,247,802,854,
882,885,889
TEMPALOY - 649
TENITE - 10,104,111,120
THERMOFLEX
- 355

- 756
- 425

TUFCHEM - 375,387,399
TUFFLEX - 272
TYGON - 238,802
UDEL - 147
UN I LOY - 440
USCOLITE - 802
VAMAC - 299
VEW A905 - 429
VI-CHEM - 355
VISTALON - 302
VITON - 238,263,299,355,802,
839,848,854,885
VITREX - 389
VITROBOND
VITROPLAST

- 389
- 389

THIN SET - 375


THIOKOL - 355

WALLEX - 645
WORTH ITE - 797

TICODE- 741
TOBIN BRONZE 4641 - 649

XYDAR
ZAMAK

TPX - 118,239

ZIRCADYNE

TRANSITE - 797
TRENT - 729

ZYTE L - 220

- 107
- 742
- 749

index

899

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