Methanol

8/18/2016
Methanol (data page) - Wikipedia, the free encyclopedia
Methanol (data page)

From Wikipedia, the free encyclopedia
This page provides supplementary chemical data on methanol.
Contents
1
2
3
4
5
6
7
8
9
Material Safety Data Sheet

Structure and properties
Thermodynamic properties
Spectral data
Vapor pressure of liquid
Properties of aqueous methanol solutions
Distillation data
References
External links
Material Safety Data Sheet

The handling of this chemical may incur notable safety precautions. It is highly recommended that you seek the Material Safety Datasheet
(MSDS) for this chemical from a reliable source such as SIRI (http://www.siri.org/msds/index.php), and follow its directions. MSDS is available
at J.T. Baker (http://hazard.com/msds/mf/baker/baker/files/m2015.htm) and Loba Chemie (http://www.lobachemie.com/HPLC-Grade-Solvents00199/METHANOL-CASNO-67-56-1.aspx)

Index of refraction, nD
1.328 at 20 C
Dielectric constant, r
32.66 at 20 C
Bond strength
Bond length
Bond angle
all 109.5
Magnetic susceptibility[1] 5.3107 cm3g1

Surface tension
22.5 dyn/cm at 20 C
Viscosity[2]
0.808 mPas at 0 C
0.690 mPas at 10 C
0.593 mPas at 20 C
0.449 mPas at 40 C
0.349 mPas at 60 C
Thermodynamic properties
Phase behavior
Triple point
175.5 K (97.7 C), ? Pa
Critical point
513 K (240 C), 78.5 atm
Std enthalpy change

of fusion, fus Ho
3.1773 kJ/mol
https://en.wikipedia.org/wiki/Methanol_(data_page)#Thermodynamic_properties
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8/18/2016
Std entropy change

of fusion, fus So
18.1 J/(molK)
Std enthalpy change

of vaporization, vap Ho
+38.278 kJ/mol
Std entropy change

of vaporization, vap So
113 J/(molK)
Solid properties
Std enthalpy change
of formation, fHo solid
? kJ/mol
Standard molar entropy,

So solid
? J/(mol K)
Heat capacity, cp
? J/(mol K)
Liquid properties
Std enthalpy change

of formation, fHo liquid
238.4 kJ/mol

So liquid
127.2 J/(mol K)
Enthalpy of combustion cHo 715.0 kJ/mol

Heat capacity, cp
79.5 J/(mol K)
Gas properties
Std enthalpy change

of formation, fHo gas
-201.3 kJ/mol

So gas
239.9 J/(mol K)
Heat capacity,[3][4] cp
52.29 J/(mol K) at 77 C
61.43 J/(mol K) at 100-223 C
Heat capacity ratio,[3][4]

= cp /cv
1.203 at 77 C
van der Waals' constants[5]
a = 964.9 L2 kPa/mol2
b = 0.06702 liter per mole
Spectral data
UV-Vis
max
? nm
Extinction coefficient,
?
IR
(liquid film)
Wave number transmittance
2/9
8/18/2016
3347 cm1
6%
3336 cm1
8%
cm1
18%
2833 cm1
22%
2522 cm1
77%
2046 cm1
84%
cm1
47%
1116 cm1
62%
1030 cm1
4%
2945
Major absorption bands[6]
1460
662
cm1
58%
NMR
Proton NMR
3.97 ppm, 3.417 ppm[6]
Carbon-13 NMR
50.05 ppm[6]
Other NMR data

MS
Masses of
main fragments
Vapor pressure of liquid

P in mm Hg 1
T in C
10
40
100
400
760
1520 3800
44.0 16.2 5.0 21.2 49.9 64.7 84.0
7600
15200 30400 45600
112.5 138.0 167.8
203.5
224.0
Table data obtained from CRC Handbook of Chemistry and Physics 44th ed.
3/9
8/18/2016
Log10 of methanol vapor pressure vs. temperature. Uses Antoine's equation:

from Lange's Handbook of Chemistry 10th ed.
Methanol vapor pressure vs. temperature. Uses

Antoine's equation:
from Lange's Handbook of Chemistry 10th ed.
Here is a similar formula from the 67th edition of the CRC handbook. Note that the form of this formula as given is a fit to the Clausius
Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures:
log10(P) = -(0.05223)a/T + b, where P is in mmHg, T is in kelvins, a = 38324, and b = 8.8017.
Properties of aqueous methanol solutions

Data obtained from Lange's Handbook of Chemistry, 10th ed. and CRC Handbook of Chemistry and Physics 44th ed. The annotation, d a
C/bC, indicates density of solution at temperature a divided by density of pure water at temperature b known as specific gravity. When
temperature b is 4 C, density of water is 0.999972 g/mL.
% wt
% vol
freezing
d 15.6 C/4 C d 0 C/4 C d 10 C/4 C d 20 C/4 C
methanol methanol
temp C
0
0.99908
0.99984
0.99970
0.99820
1.25
0.99728
0.9981
0.9980
0.9965
2.50
0.99543
0.9963
0.9962
0.9943
3.75
0.99370
0.9946
0.9945
0.9931
0.0
4/9
8/18/2016
3.9
0.9938
2.2
4.99
0.99198
0.9930
0.9929
0.9914
6.22
0.99029
0.9914
0.9912
0.9896
7.45
0.98864
0.9899
0.9896
0.9880
8.68
0.98701
0.9884
0.9881
0.9863
9.91
0.98547
0.9870
0.9865
0.9847
8.1
10
0.9872
11.13
0.98547
0.9856
0.9849
0.9831
10
12.35
0.98241
0.9842
0.9834
0.9815
11
13.56
0.98093
0.9829
0.9820
0.9799
12
14.77
0.97945
0.9816
0.9805
0.9784
12.2
15
0.9810
13
15.98
0.97802
0.9804
0.9791
0.9768
14
17.18
0.97660
0.9792
0.9778
0.9754
15
18.38
0.97518
0.9780
0.9764
0.9740
16
19.58
0.97377
0.9769
0.9751
0.9725
16.4
20
0.975
17
20.77
0.97237
0.9758
0.9739
0.9710
18
21.96
0.97096
0.9747
0.9726
0.9696
19
23.15
0.96955
0.9736
0.9713
0.9681
20
24.33
0.96814
0.9725
0.9700
0.9666
20.6
25
0.968
21
25.51
0.96673
0.9714
0.9687
0.9651
22
26.69
0.96533
0.9702
0.9673
0.9636
23
27.86
0.96392
0.9690
0.9660
0.9622
24
29.03
0.96251
0.9678
0.9646
0.9607
24.9
30
0.964
25
30.19
0.96108
0.9666
0.9632
0.9592
26
31.35
0.95963
0.9654
0.9628
0.9576
27
32.51
0.95817
0.9642
0.9604
0.9562
28
33.66
0.95668
0.9629
0.9590
0.9546
29
34.81
0.95518
0.9616
0.9575
0.9531
29.2
35
0.957
30
35.95
0.95366
0.9604
0.9560
0.9515
31
37.09
0.95213
0.9590
0.9546
0.9499
5.0
8.3
11.7
15.6
20.0
25.0
5/9
8/18/2016
32
38.22
0.95056
0.9576
0.9531
0.9483
33
39.35
0.94896
0.9563
0.9516
0.9466
33.6
40
0.950
34
40.48
0.94734
0.9549
0.9500
0.9450
35
41.59
0.94570
0.9534
0.9484
0.9433
36
42.71
0.94404
0.9520
0.9469
0.9416
37
43.82
0.94237
0.9505
0.9453
0.9398
38
44.92
0.94067
0.9490
0.9437
0.9381
39
46.02
0.93894
0.9475
0.9420
0.9363
40
47.11
0.93720
0.9459
0.9403
0.9345
41
48.20
0.93543
0.9443
0.9387
0.9327
42
49.28
0.93365
0.9427
0.9370
0.9309
43
50.35
0.93185
0.9411
0.9352
0.9290
44
51.42
0.93001
0.9395
0.9334
0.9272
45
52.49
0.92815
0.9377
0.9316
0.9252
46
53.54
0.92627
0.9360
0.9298
0.9234
47
54.60
0.92436
0.9342
0.9279
0.9214
48
55.64
0.92242
0.9324
0.9260
0.9196
49
56.68
0.92048
0.9306
0.9240
0.9176
50
57.71
0.91852
0.9287
0.9221
0.9156
51
58.74
0.91653
0.9269
0.9202
0.9135
52
59.76
0.91451
0.9250
0.9182
0.9114
53
60.77
0.91248
0.9230
0.9162
0.9094
54
61.78
0.91044
0.9211
0.9142
0.9073
55
62.78
0.90839
0.9191
0.9122
0.9052
56
63.78
0.90631
0.9172
0.9101
0.9032
57
64.77
0.90421
0.9151
0.9080
0.9010
58
65.75
0.90210
0.9131
0.9060
0.8988
59
66.73
0.89996
0.9111
0.9039
0.8968
60
67.69
0.89781
0.9090
0.9018
0.8946
61
68.65
0.89563
0.9068
0.8998
0.8924
62
69.61
0.89341
0.9046
0.8977
0.8902
63
70.55
0.89117
0.9024
0.8955
0.8879
64
71.49
0.88890
0.9002
0.8933
0.8856
65
72.42
0.88662
0.8980
0.8911
0.8834
30.0
35.6
6/9
8/18/2016
66
73.34
0.88433
0.8958
0.8888
0.8811
67
74.26
0.88203
0.8935
0.8865
0.8787
68
75.17
0.87971
0.8913
0.8842
0.8763
69
76.08
0.87739
0.8891
0.8818
0.8738
70
76.98
0.87507
0.8869
0.8794
0.8715
71
77.86
0.87271
0.8847
0.8770
0.8690
72
78.75
0.87033
0.8824
0.8747
0.8665
73
79.62
0.86792
0.8801
0.8724
0.8641
74
80.48
0.86546
0.8778
0.8699
0.8616
75
81.34
0.86300
0.8754
0.8676
0.8592
76
82.18
0.86051
0.8729
0.8651
0.8567
77
83.02
0.85801
0.8705
0.8626
0.8542
78
83.86
0.85551
0.8680
0.8602
0.8518
79
84.68
0.85300
0.8657
0.8577
0.8494
80
85.50
0.85048
0.8634
0.8551
0.8469
81
86.31
0.84794
0.8610
0.8527
0.8446
82
87.11
0.84536
0.8585
0.8501
0.8420
83
87.90
0.84274
0.8560
0.8475
0.8394
84
88.68
0.84009
0.8535
0.8449
0.8366
85
89.45
0.83742
0.8510
0.8422
0.8340
86
90.21
0.83475
0.8483
0.8394
0.8314
87
90.97
0.83207
0.8456
0.8367
0.8286
88
91.72
0.82937
0.8428
0.8340
0.8258
89
92.46
0.82667
0.8400
0.8314
0.8230
90
93.19
0.82396
0.8374
0.8287
0.8202
91
93.92
0.82124
0.8347
0.8261
0.8174
92
94.63
0.81849
0.8320
0.8234
0.8146
93
95.33
0.81568
0.8293
0.8208
0.8118
94
96.02
0.81285
0.8266
0.8180
0.8090
95
96.70
0.80999
0.8240
0.8152
0.8062
96
97.37
0.80713
0.8212
0.8124
0.8034
97
98.04
0.80428
0.8186
0.8096
0.8005
98
98.70
0.80143
0.8158
0.8068
0.7976
99
99.35
0.79859
0.8130
0.8040
0.7948
7/9
8/18/2016
100
100
0.792
0.8102
0.8009
0.7917
97.8
% wt
% vol
freezing
d 15.6 C/4 C d 0 C/4 C d 10 C/4 C d 20 C/4 C
methanol methanol
temp C
Distillation data
Vapor-Liquid Equilibrium
of Methanol/Water[7]
P = 760 mm Hg; T = 72.4 C - 100.0 C
BP
Temp.
C
% by mole methanol
liquid
vapor
of Methanol/Water[7]
P = 760 mm Hg; T = 64.6 C - 72.0 C
BP
Temp.
C
% by mole methanol
liquid
vapor
of Methanol/Ethanol[7]
P = 760 mm Hg
BP
Temp.
C
% by mole methanol
liquid
vapor
100.00
0.0
0.0
72.0
56.5
80.5
78.3
0.0
0.0
99.25
0.5840
4.5705
71.5
58.5
81.6
76.6
13.4
18.3
96.9
1.2
11.4
71.4
60.0
83.1
75.0
24.2
32.6
95.7
2.6
15.7
70.6
66.2
85.7
73.6
32.0
42.8
92.2
5.0
29.3
69.9
67.5
86.5
72.3
40.1
52.9
90.15
7.38
36.65
69.6
70.0
87.4
71.7
43.5
56.6
87.5
10.2
43.0
69.1
71.4
87.8
70.0
54.2
67.6
86.50
11.76
48.55
67.8
80.0
91.8
68.6
65.2
75.9
84.8
14.0
51.4
66.9
85.0
93.0
67.7
72.8
81.3
84.3
15.0
52.2
66.50
88.08
94.17
66.9
79.0
85.8
82.9
17.5
56.0
66.2
89.0
95.6
66.6
81.4
87.5
81.5
20.0
59.0
66.1
90.0
96.1
65.8
87.3
91.9
78.0
30.0
67.5
65.7
92.0
96.5
65.6
91.0
93.7
75.4
40.0
73.5
65.4
95.0
98.1
64.6
100.0
100.0
73.7
47.3
76.5
64.95
96.57
95.69
72.6
52.6
79.4
64.70
98.71
97.78
72.4
54.0
80.1
64.6
100.0
100.0
References
1.
2.
3.
4.
5.
6.
7.
NMR-002: Sample Devices and Magnetic Susceptibility (http://nmr.chem.umn.edu/ResReports/NMR002.html)

Lange's Handbook of Chemistry, 10th ed. pp1669-1674
Lange's Handbook of Chemistry 10th ed, pp 1525-1528
CRC Handbook of Chemistry and Physics 44th ed. pp 2582-2584
Lange's Handbook of Chemistry 10th ed, pp 1522-1524
"Spectral Database for Organic Compounds" (Queriable database). Advanced Industrial Science and Technology. Retrieved 9 June 2007.
"Binary Vapor-Liquid Equilibrium Data" (Queriable database). Chemical Engineering Research Information Center. Retrieved 7 May 2007.
Linstrom, P.J.; Mallard, W.G. (eds.) NIST Chemistry WebBook, NIST Standard Reference Database Number 69. National Institute of
Standards and Technology, Gaithersburg MD. http://webbook.nist.gov (sample table of physical properties (http://webbook.nist.gov/cgi/flu
id.cgi?Action=Load&ID=C67561&Type=IsoBar&P=1&THigh=100&TLow=-40&TInc=10&RefState=DEF&TUnit=C&PUnit=bar&D
Unit=mol%2Fl&HUnit=kJ%2Fmol&WUnit=m%2Fs&VisUnit=cP&STUnit=N%2Fm7))
8/9
8/18/2016
External links
"Properties of pure Methanol". Chemical Engineering Research Information Center. Retrieved 5 May 2007.
Except where noted otherwise, data relate to standard ambient temperature and pressure.
Disclaimer applies.
Retrieved from "https://en.wikipedia.org/w/index.php?title=Methanol_(data_page)&oldid=724422073"
Categories: Chemical data pages
This page was last modified on 9 June 2016, at 04:47.
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Methanol (data page) - Wikipedia, the free encyclopedia

Methanol (data page)

This page provides supplementary chemical data on methanol.

Material Safety Data Sheet

Material Safety Data Sheet

Structure and properties

Magnetic susceptibility[1] 5.3107 cm3g1

175.5 K (97.7 C), ? Pa

513 K (240 C), 78.5 atm

Std enthalpy change

Methanol (data page) - Wikipedia, the free encyclopedia

Std entropy change

Std enthalpy change

Std entropy change

Standard molar entropy,

Std enthalpy change

Standard molar entropy,

Enthalpy of combustion cHo 715.0 kJ/mol

Std enthalpy change

Standard molar entropy,

Heat capacity ratio,[3][4]

van der Waals' constants[5]

Methanol (data page) - Wikipedia, the free encyclopedia

3.97 ppm, 3.417 ppm[6]

Other NMR data

Vapor pressure of liquid

44.0 16.2 5.0 21.2 49.9 64.7 84.0

15200 30400 45600

112.5 138.0 167.8

Methanol (data page) - Wikipedia, the free encyclopedia

Log10 of methanol vapor pressure vs. temperature. Uses Antoine's equation:

Methanol vapor pressure vs. temperature. Uses

Properties of aqueous methanol solutions

Methanol (data page) - Wikipedia, the free encyclopedia

Methanol (data page) - Wikipedia, the free encyclopedia

Methanol (data page) - Wikipedia, the free encyclopedia

Methanol (data page) - Wikipedia, the free encyclopedia

NMR-002: Sample Devices and Magnetic Susceptibility (http://nmr.chem.umn.edu/ResReports/NMR002.html)

Methanol (data page) - Wikipedia, the free encyclopedia

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