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Glycerol(datapage)Wikipedia

Glycerol(datapage)
FromWikipedia,thefreeencyclopedia

Thispageprovidessupplementarychemicaldataonglycerol.

Contents
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2
3
4
5
6
7
8

MaterialSafetyDataSheet
Structureandproperties
Thermodynamicproperties
Vaporpressureofliquid
Freezingpointofaqueoussolutions
Distillationdata
Spectraldata
References

MaterialSafetyDataSheet
Thehandlingofthischemicalmayincurnotablesafetyprecautions.ItishighlyrecommendedthatyouseektheMaterialSafetyDatasheet(MSDS)for
thischemicalfromareliablesourceandfollowitsdirections.
ScienceLab(http://www.sciencelab.com/msds.php?msdsId=9927350)

Structureandproperties
Structureandproperties
Indexofrefraction,nD 1.4729at20C
Abbenumber

Dielectricconstant,r

42.50at25C

Bondstrength

Bondlength

Bondangle

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Magneticsusceptibility ?
Surfacetension

63.4mN/mat20C
58.6mN/mat90C
51.9mN/mat150C

Viscosity[1]

4.220Pasat2.8C
1.069Pasat20C

Thermodynamicproperties
Phasebehavior
Triplepoint

291.8K(18.7C),~99500Pa

Criticalpoint

850K(577C),7500kPa

Stdenthalpychange
offusion,fusHo

18.28kJ/mol

Stdentropychange
offusion,fusSo

62.7J/(molK)

Stdenthalpychange
ofvaporization,vapHo

91.7kJ/mol

Stdentropychange
ofvaporization,vapSo

201J/(molK)

Solidproperties
Stdenthalpychange
offormation,fHosolid

?kJ/mol

Standardmolarentropy,
Sosolid

?J/(molK)

Heatcapacity,cp

150.J/(molK)6C11C
Liquidproperties

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Stdenthalpychange
offormation,fHoliquid

669.6kJ/mol

Standardmolarentropy,
Soliquid

?J/(molK)

Enthalpyofcombustion,cHo 1654.3kJ/mol
Heatcapacity,cp

221.9J/(molK)at25C
Gasproperties

Stdenthalpychange
offormation,fHogas

577.9kJ/mol

Standardmolarentropy,
Sogas

?J/(molK)

Heatcapacity,cp

?J/(molK)

Vaporpressureofliquid
PinmmHg 1
TinC

10

40

100

400

760

125.5 167.2 198.0 220.1 263.0 290.0

TabledataobtainedfromCRCHandbookofChemistryandPhysics,44thed.

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log10ofGlycerolvaporpressure.Usesformula:

obtainedfrom

CHERIC[2]

Freezingpointofaqueoussolutions
%glycerol
byvolume[probablyatypofor"byweight"see

10

20

30

40

50

60

70

80

90

100

Freezingpoint
C

1.6

4.8

9.5

15.5

22.0

33.6

37.8

19.2

1.6

17.0

Specificgravity
d15

1.02415 1.04935 1.07560 1.10255 1.12985 1.15770 1.18540 1.21290 1.23950 1.26557

Lange'scitedbelow.]

TabledataobtainedfromLange'sHandbookofChemistry,10thed.Specificgravityisat15C,referencedtowaterat15C.
Seedetailson:FreezingPointsofGlycerineWaterSolutions(http://www.dow.com/glycerine/resources/table8.htm)DowChemical[3]

Distillationdata
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VaporliquidEquilibriumofGlycerol/water[4]
P=760mmHg
BP
Temp.
C

%bymolewater
liquid

vapor

278.8

2.75

93.15

247.0

4.67

94.73

224.0

6.90

95.63

219.2

7.67

97.43

210.0

9.01

97.83

202.5

10.31

97.24

196.5

11.59

98.39

175.2

17.56

98.99

149.3

30.04

99.64

137.2

38.47

99.76

136.8

38.95

98.78

131.8

43.58

99.76

121.5

56.33

99.84

112.8

70.68

99.93

111.3

73.86

99.94

106.3

84.42

99.96

Spectraldata
UVVis
max

?nm

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Extinctioncoefficient, ?
IR
Majorabsorptionbands ?cm1
NMR
ProtonNMR

Carbon13NMR

OtherNMRdata

MS
Massesof
mainfragments

References
1.Lange'sHandbookofChemistry,10thed.pp16691674
2."PureComponentProperties"(Queriabledatabase).ChemicalEngineeringResearchInformationCenter.Retrieved13May2007.
3.FreezingPointsofGlycerineWaterSolutions(http://www.dow.com/glycerine/resources/table8.htm)DowChemical
4."BinaryVaporLiquidEquilibriumData"(Queriabledatabase).ChemicalEngineeringResearchInformationCenter.Retrieved7June2007.

Exceptwherenotedotherwise,datarelatetostandardambienttemperatureandpressure.
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Categories: Chemicaldatapages
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