Temperatura [C]

100
101
102
103
104
105
106
107
108
109
110

xA

yA

0.00
0.05
0.10
0.15
0.20
0.30
0.40
0.50
0.60
0.80
0.90
1.00

0.00
0.30
0.58
0.71
0.79
0.90
0.96
0.98
0.99
0.995
1.00
1.00

X
0.20
0.30
0.40
0.50
0.60
0.70
0.80

1.20
1.00
0.80

yA

0.60
0.40
0.20
0.00

10

11

12

xA

1/(Y-X)
8.33
7.14
6.67
7.14
7.69
9.09
14.29

16
14
12

f(x) = 49.3571428571x^2 - 41.2142857143x + 14.915

R = 0.9404150428

10

1/(y-x)8
6
4
2
0
0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

11

12

+ 14.915

0.70

0.80

0.90

Temperatura [C] Temperatura [K]

60
62
64
66
68
70
72
74
76
78
80
82
84
86
88
90
92

333.15
335.15
337.15
339.15
341.15
343.15
345.15
347.15
349.15
351.15
353.15
355.15
357.15
359.15
361.15
363.15
365.15

X
0.3
0.35
0.4
0.45
0.5
0.55
0.6

1/(Y-X)
4.762
4.545
4.545
4.762
4.762
5
5.263

SOLUCIN REAL tratada como ideal

Presin de vapor (pis) (hexano) [mmHg]

572.8037
612.0374
653.3578
696.8403
742.5619
790.6003
841.0347
893.9449
949.4121
1007.5182
1068.3462
1131.9799
1198.5041
1268.0042
1340.5664
1416.2780
1495.2265
5.40
5.20

Presin de vapor
(pjs)(heptano)
[mmHg]
210.5751
227.0975
244.6528
263.2876
283.0497
303.9879
326.1522
349.5938
374.3649
400.5187
428.1098
457.1933
487.8259
520.0650
553.9689
589.5972
627.0102

a)
f(x) = 15.0285714286x^2 - 11.6471428571x + 6.8532142857
R = 0.9409931699

5.00

1/(y-x)

4.80
4.60
4.40
4.20
4.00
0.25

0.30

0.35

0.40

0.45

0.50

0.55

0.60

0.65

Fraccin lquido Xi Fraccin vapor Yi

1.0337
0.9298
0.8327
0.7420
0.6571
0.5775
0.5027
0.4325
0.3663
0.3039
0.2451
0.1894
0.1367
0.0868
0.0394
-0.0056
-0.0484

8532142857

.55

0.60

0.65

1.0121
0.9727
0.9301
0.8839
0.8341
0.7804
0.7228
0.6608
0.5945
0.5234
0.4475
0.3665
0.2801
0.1882
0.0904
-0.0135
-0.1237

Constantes

hexano

15.8366

B
C

2697.55
-48.78

1.2000
1.0000
0.8000
0.6000
0.4000
0.2000
0.0000
-0.2000

heptano

presion [mmHg]

15.8737

585.0000

2911.32
-56.51

10

11

12

13

14

15

16

17

Temperatura [C]
100
101
102
103
104
105
106
107
108
109
110

Temperatura
100.00
96.40
93.50
91.20
89.30
87.70
84.40
81.70
78.00
75.30
73.10
71.20
69.30
67.50
66.00
65.00
64.50

xA

yA

0.000
0.020
0.040
0.060
0.080
0.100
0.150
0.200
0.300
0.400
0.500
0.600
0.700
0.800
0.900
0.950
1.000

0.000
0.134
0.230
0.304
0.365
0.418
0.517
0.579
0.665
0.729
0.779
0.825
0.870
0.915
0.958
0.979
1.000

X
0.20
0.30
0.40
0.50
0.60
0.70
0.80

1.200
1.000
0.800
0.600
0.400
0.200
0.000
0.0000.0200.0400.0600.0800.1000.1500.2000.3000.4000.5000.6000.7000.8000.9000.9501.000

1/(Y-X)
8.33
7.14
6.67
7.14
7.69
9.09
14.29

16
14
12

f(x) = 49.3571428571x^2 - 41.2142857143x + 14.915

R = 0.9404150428

10

1/(y-x)8
6
4
2
0
0.10

0.20

0.30

0.40

0.50

0.60

0.70

0.80

9501.000

+ 14.915

0.70

0.80

0.90