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1.
Given the following information for magnesium, oxygen, and magnesium oxide calculate the second electron gain
enthalpy for oxygen {i.e. for O (g) + e O2 (g)}.
for Mg (s), Hsub = +148 kJ/mol
1st ionization energy for Mg = +738 kJ/mol
2nd ionization energy for Mg = +1450 kJ/mol
2.
Consider an ionic compound MX2 where M is a metal that forms a cation of +2 charge, and X is a nonmetal that forms an
anion of 1 charge. A Born-Haber cycle for MX2 is given below. Each step in this cycle has been assigned a number
(1 7).
M (s)
X2 (g)
6
M (g)
MX2 (s)
M+ (g)
2
(g)
______________
b.
_____________
c.
_____________
d.
Use the following energy values to calculate the lattice energy (in kJ/mol) for MX2.
Hosub = 296 kJ/mol; Hof = -421 kJ/mol; 1st ionization energy = 378 kJ/mol;
2nd ionization energy = 555 kJ/mol; bond dissociation enthalpy = 310 kJ/mol;
electron affinity = -427 kJ/mol.
2 X (g)
M2+
a.
2 X- (g)
Born'Haber CYcle,PracticeProblerns
C)\eM lltl
eh#{B
i.
energy1'orO. = +-199kJ/rnol
bonclclissociation
gaincnthalpy1'orO = -l'11 k.l/mcll
l" elcctt'ott
I-orMgO (s),leitticceIrerg)'= +3890k.l/ttrol
1'orMgO (s),cnthalpyof'lbnnation= 602 k.l/rnol
= +148 k.l/lriol
lbr Mg (s), AH.,,.,
l ' ' i o n i z a l i o ne n c r g ) ' f o rM g = + 7 3 8k . l / m o l
lirr Mg = +1-l-50k.l/rnol
cnerg_\'
2'r ioniz.ation
'/z 0e tJ )
-t tt"+
>
J,r.co*airr)
N.tJ
M 1 ( s )+
a,l"{5u{-
ts4 $ ru
o-Ls)
*$o-ri
ry'*'J) +
rqt-?38-'T;l':#
tlo= [-uoe+3rqo-
z"[ea
*^u0*
aHlr = a[l*t
o(s)'. 2"te=
'+r"rrl,u';:iil^il_
o tt)
rs\;de
NU3)
r'llr'll(tll uillll
or-rJ)
= t Sttt{ Kv-ol
2.
i\l (s)
-l
i
.j"*'
+
.l
+
Nl,(g)
lrt: (g)
Xl (g)
"lt
ri.
b.
3,'l r 5, lo
zi(st
NL\: (s)
to AH"t:,'
Which stcp ( I - 7) corlcsl.rotttls
L . l s et h e l b l l o r v i n gc n c r g y ' v a l r r ctso c a l c t t l a t ct h c l a t l i c ec n c r . g r ' ( i nk J / n r o l )f i r r ' l \ ' l X .
AHu.ul,= 296 k.l/nrol; AI'lu,= -'12I lt.l/nrol; l't iottiz'ationetrcrg\'- 378 k'l/rrtol;
. l / n r o l ; b o n cdli s s o c i a t i o pc n t h a l p l ' = . 11 0 k . l / n r o l ;
2 ' ) ( il o r r i z a t i o 'e n c r g y* - 5 - 5k- 5
-127
k.llnoI.
clectron afl'inrt1'=
rl
- LE
A H a ; s+
, 2(r4)
-aHl
+z(il
AHj'^b + l s l j - t + z n A : - ,+Ea l - l a i s s
tV*ol
: $ - q , , +3 - 1 8 + s s s3+1 0 +2 G q a - -r k) L t L ' t
L-
lsfhcetvJJ
=. + llot K{n^ut
-=#=-==-