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Introduction:
In that paper, the authors claimed that organic matter in shales has a strong
potential for adsorbing CO2. The equation for BET multiple-adsorbed-layer
model is given by:
P
1+(C1)P /P0
( oP)
V CP
V ( P)= m
Where
Hinckley, et al., explored the methods that are beyond the well-established
dual porosity model. Triple and Quad-porosity had been discussed. The
authors notice that the permeabilty of crushed samples is significantly
below than those measured in core plus, suggesting that micro-fractures
contribute greatly to the flow. This statement leads to a different research
direction of studying the nano- and micro-fractures which would increase the
understanding of overall flow in shales. Triple porosity, which is the next step
after the common dual porosity method, comes with the addition of those
micro-fractures. The comparison with the base model showed a good match.
Quad porosity comes in addition of kerogen and inorganic matrix which are
treated as distinct porosity types. The paper then discusses the physics
behind those parameters, such as the Knudsen number which will tell the
flow regime we are in. In the end comparison with all the models had been
made. Like in the paper by Feast, et al., the concluded that the inclusion of
adsorption phenomena and Knudsen diffusion show very good results. The
authors conclude the following findings based on their study: gas adsorption
significantly contributes to gas production in later times, gas diffusion
through a solid can be an important factor when modelling adsorption, the
consideration of micro-fractures increase the production; Knudsen diffusion
and slip flow phenomena greatly impacts matrix permeability. After all
considerations Triple-porosity the the abovementioned factors showed the
best results.
Zhang, et al., investigated the transport characteristics in organic nano-pores
through Lattice Boltzmann method (LBM). The effects of a Knudsen number
and slip flow are considered. LBM has been effective in finding the
permeability of the shales.
The flow ability of gas in shales depends on variety of factors, including gas
composition, organic richness, geometry of nano- and micro-fractures, and
how gas deviates from continuum fluid mechanics due to high Knudsen
numbers. As in the table provided in Hinkley, et al. (2013), high Knudsen
number results in free molecular flow regime. Knudsen diffusion occurs when
molecules interact with the walls of pores more often that with the fellow
molecules this concept is very applicable in shales that have nano-scale
level pores. As the size of pores decrease, this number increases. The paper
discusses the previous analytical and numerical methods that were
developed. Molecular Dynamic method got criticized for its high
computational cost. LBM has a solid theoretical foundation and numerical
superiority, it suits better for simulation of complex geometries, such as
different scales of pores. The LBM model that is discussed here establishes
flow characteristics of slip effect and high Knudsen numbers. The capillary
width is considered as a sensitivity factor. 2 types of boundary conditions are
used: bounce-back for solid wall and specular-reflection for top and bottom.
Permeability equation is presented with the addition of coefficient to
accommodate larger Knudsen number and the slip effect.
Another advantage of MINC method was that the flow between matrix and
fractures showed a realistic result by numerical simulation. Coupled MINC
Yan, et al. (2016), explored the models that go beyond the common dualporosity. Through microscopic studies its been revealed that shale reservoirs
contain extensive system of micro and nano pores. With this in mind the
dual-porosity models can no longer be reliable in prediction of fluid flow in
shale reservoirs as they cant accurately capture the flowing mechanisms.
For this matter a new model needs to be developed that can capture multiple
pore scales and flows. The authors present multiporosity model in 3 systems:
inorganic matter, organic matter, and natural fractures. Gas desorption and
diffusion are the dominant physics.
Flow has different regimes based on a Knudsen number. A more thorough
review of flow regimes based on Knudsen number can be found in Ziarani
(2012).
References:
1. Yan, B., Wang, Y., & Killough, J. E. (2016). Beyond dual-porosity modeling for the
simulation of complex flow mechanisms in shale reservoirs. Computational
Geosciences, 20(1), 69-91.
2. Jiang, J., & Younis, R. M. (2015, February). A generic physics-based numerical platform
with hybrid fracture modelling techniques for simulating unconventional gas reservoirs.
In SPE Reservoir Simulation Symposium. Society of Petroleum Engineers.
3. Zhang, X., Xiao, L., Shan, X., & Guo, L. (2014). Lattice Boltzmann simulation of shale
gas transport in organic nano-pores. Scientific reports, 4.
4. Hinkley, R., Gu, Z., Wong, T., & Camilleri, D. (2013, November). Multi-porosity simulation
of unconventional reservoirs. In SPE Unconventional Resources Conference Canada.
Society of Petroleum Engineers.
5. Feast, G., Wu, K., Walton, J., Cheng, Z.F. and Chen, B. (2015) Modeling and Simulation
of Natural Gas Production from Unconventional Shale Reservoirs. International Journal
of Clean Coal and Energy, 4, 23-32.
6. Eshkalak, M.O., Al-Shalabi, E.W., Aybar, U. and Sepehrnoori, K. (2014) Enhanced Gas
Recovery by CO2 Sequestration versus Re-Fracturing Treatment in Unconventional
Shale Gas Reservoirs. Abu Dhabi International Petroleum and Exhibition and
Conference, in Abu Dhabi, 10-13 November 2014, Paper SPE 172083
7. Ziarani, A., Aguilera, R.: Knudsens permeability correction for tight porous media.
Transp. Porous Media 91(1), 239260 (2012).
8. Agarwal, R. K., Yun, K. Y., & Balakrishnan, R. (2001). Beyond NavierStokes: Burnett
equations for flows in the continuumtransition regime. Physics of Fluids (1994present), 13(10), 3061-3085.