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2

ADVANCES

IN

CHEMISTRY

SERIES

Corrections for Azeotropic DataI


The following errors appeared in "Azeotropic Data,"

ADVANCES IN C H E M I S T R Y

S E R I E S N O . 6.

Page

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

4
6

System
65
131

7
8
9
10
13
19
23

176
240
281
306
482
834-835
1059-1060

28
33
83
114
123

1389
1696
4708-4709
6546

149
154

8651
8920

Replace -component, thionyl chloride, with sulfuryl chloride.


Azeotropic composition is 7.9 wt. % . This is an error in the
original reference.
Formula should be C H N 0 .
Replace 57% with 43% for azeotropic composition.
This system should follow system 277.
Replace "cyclohexane" with "cyclohexene."
Replace 6.32 by 6.32 for b.p. of methylamine.
-component formula is C H B r .
Between systems 1059 and 1060 insert:
A = C H I Diiodomethane b. 181 C.
Replace 59.05 with 49.05 for azeotropic b.p.
-component formula is C H B r C l .
Replace 43.6 with 38 for -component b.p.
Replace 11 with 154.5 for azeotropic b.p.
Between system 7090 and 7091, omit:
A = C4H9I l-Iodo-2-methyl propane.
Replace reference 244 with 243.
Replace C H 0 , 2-[2- (2-methoxyethoxy ) ethoxy]-ethanol,
with C H 0 , 2-(2-ethoxyethoxy)ethanol, and insert after
system 8909.
% B-component should be 93.4%.
% -component should be 8.5%.
Formula C 1 0 S .
Replace thionyl chloride with sulfuryl
chloride.
Under C H 0 , pyrocatechol, replace system 3510 with 3570.
Formula C H .
Replace 3-ethylheptane with 3-methylheptane.
3

284
296

251 14519
257 14658
267

1 6

1 4

1 8

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

INTRODUCTION

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Calculation of Azeotropic Data for Immiscible Systems


There are many binary heterogeneous azeotropes which are not listed in the
literature because the azeotropic data can readily be calculated from the vapor
pressure data of the components.
For a mixture of two completely immiscible liquids the total vapor pressure
is equal to the sum of the vapor pressures of the two components at a given tem
perature. Therefore, from a plot of the vapor pressures of the two components,
it is possible to determine the temperature at which the sum of the vapor pres
sures is equal to 760 mm. This temperature is the azeotropic boiling point of the
system at 760 mm. The boiling point at any other pressure can be obtained in a
similar manner.
Further, the azeotropic composition can be calculated from the expression
Mole % A
V
V

100

= vapor pressure of component A


= vapor pressure of component

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Table I.

Binary Systems

B-Component
No.

Formula

A
1 o

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

BeF

Germanium

Ethyl

chloride

ether,
25-100

p.s.i.g.

Bromine Trifluoride

Bromine
Bromine,
"
Hydrogen
Uranium

8 F H
9 F U
6

BrF

pentafluoride
1760 m m .
3800 m m .
fluoride
hexafluoride

Hydrogen fluoride
4 atm.
Uranium hexafluoride
"
3 atm.
.1
o
"
90
"
100 p . s . i . a .

F U
6

7 0

Br

F H
F U
CC1

15

C C1 F

16

C C1 F

17

C HC1 F

18

C H C1 F 2

19

20

^7^5F

21

Cn

Br P
2

86.5

Nonazeotrope

v-1

298

v-1

299

...

Nonazeotrope

v-1

206

Nonazeotrope
75
84.4
100
81.5
Azeotropic
Nonazeotrope

v-1
v-1
v-1

200
101
101
91
91

135

...
...
19.4
56

19.4

56
...
. .
...

20

56
79
M i n . b.p.
82
Nonazeotrope
Nonazeotrope
Nonazeotrope
62.5

v-1
v-1
v-1

4,91
91
91
203
203
203
91

Hydrogen fluoride
Uranium hexafluoride
Carbon tetrachloride,
736 m m .
l,l,2-Trichloro-l,2,
2 -1 r i f l u o r o e t h a n e
1,1,1,2- Te trachl or 0 2,2 - d i f l u o r o e t h a n e
l,2,2-Trichloro-l,ldifluoroethane,
736 m m .
l,l-Dichloro-2,2difluoroethane,
735 m m .
l,2,2-Trichloro-l,l,
3,3,3-pentafluoropropane
a, a, a - T r i f l u o r o t o l u e n e

19.4
56

91
91

Azeotropic
Azeotropic

76

57.7

89.1

v-1

311

47.6

41

40.8

v-1

312

91.6

57.8

89.5

v-1

312

71.1

54.1

73.5

v-1

313

59

49.6

62

v-1

313

72.5
103.9

49.1
58.1

60.5
97

v-1
v-1

312
312

Phosphorus T r i b r o m i d e 175.3

71
232
340
237

58.9

Bromine

12
13
14

v-1
v-1
v-1
v-1

Bromine Pentafluoride

F H

11

11

...
...
...
...
Nonazeotrope

Nonazeotrope

Diborane

10

...
...

Sodium fluoride,
509-1061C.

2_ 6

BrF

Ref.

Beryllium Fluoride

FN a

6 BrF
7 B r

Wt.%A

130

Arsenic Chloride

3
4

B.P.,C.

Data

-186
-183

1-15 a t m .
90-96K.
Perfluoropentane, 25C.

C 5 F 1 2

B.P.,C.

Oxygen

AsCl

Name

Argon
2

3 GeCl

Azeotropic

Paraffin

hydrocarbons

Min.

b.p.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

234

ADVANCES

IN

Azeotropic

B-Ccmponent
No.
A=

Formula

Name
Carbon Dioxide
Hydrogen sulfide,
20-80 a t m .

CO 2
22 H S
2

23 N 0
24 C H

N i t r o u s oxide
Acetylene
'
Crit. press.
E t h y l e n e , <4 a t m .
12 a t m .
"
Crit. press.
Ethane
"
Crit. press.

25

C H
2

26

C H

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

A =

C1F

11

Chlorine T r i f l u o r i d e
Hydrogen chloride
Hydrogen fluoride
"
1183 m m .
90 p . s . i . g .
"
125 p . s . i . g .
143 p . s . i . g .
"
148 p . s . i . g .
Uranium hexafluoride

27 c m
28 F H

B.P.,C.

-59.6
-90.7
-84

.. .
.. .
-88.6

...

A =

A =

Cl
33 F H

C1 S0
2

34 CCI4

35 C C 1
36 C H C 1
2

37 C H C12
2

A =

CI3HS1
38

A =

C H
6

C H
C H
C H
cWie
C Hi
C H
6

1 2

1 4

1 6

1 6

Cl Si
4

45 CH3S1CI3
46 C H S i C l
4

A =

Cl Sn
47 C C I .
4

Nonazeotrope

v-1

Min. b.p.
Nonazeotrope
Nonazeotrope
Nonazeotrope
28.9
51
59.5
77.5

v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1

16,
17
293
293
293
293
293
293
293
293

4
91
90
91
91
91
91
89,
91

Hydrogen Chloride
C h l o r i n e , 350 m m .
W a t e r , 100 p . s . i . g .
"
520 p . s . i . g .
860 p . s . i . g .
"
1360 p . s . i . g .
"
1815 p . s . i . g .
Methanol

-85
-44
169
244
275
306
328
64.7

Nonazeotrope
177
85.2
250
93.5
280
97.2
310
99.4
330
99.9
Max. b.p.

Chlorine
Hydrogen fluoride,
350 m m .

-34.6

Sulfuryl Chloride
Carbon tetrachloride
Hexachloroethane
1,1,2,2,-Tetrachloroethane
1,2- D i c h l o r o e t h a n e

69.1
76.75
184.8

Nonazeotrope
Nonazeotrope

v-1
v-1

338
338

146.2
83.45

Nonazeotrope
Nonazeotrope

v-1
v-1

338
338

3.0
19.4

Trichlorosilane
Benzene, 30-40C.

CI3P
39
40
41
42
43
44

A =

Ref.

B.P.,C. W t . % A

56*

11

32 C H . O

Data

Reacts
Azeotropic
20
93
94.5
94
93.8
93.7
Nonazeotrope

-85
19.4

11

SERIES

-78.5

11

C1H
30 C l
31 H 0

CHEMISTRY

Phosphorus T r i c h l o r i d e
Cyclohexane
Hexane
2.2- Dimethylpentane
2.3- Dimethylpentane
2.4- Dimethylpentane
2,2,3 - T r i m e t h y l b u t a n e

76
80.75
68.8
79.1
89.8
80.5
80.9

Silicon Tetrachloride
Methyl trichloro
silane, 20-66
Methyl dichlorosilane, 20-66

57.6

T i n Chloride
Carbon tetrachloride
Il-Octane

.
114.1
76.8
125.7

-47
-35

v-1

v-1

4
334
334
334
334
334
76

4
4

92

Nonazeotrope,
v.p. curve

302

Nonazeotrope
68.7
8 v o l .%
234,
M i n . b.p.
74.5
98.8 v o l . %
74.2
73
74.5
77

236
234
236
234
234
234

Nonazeotrope,
v.p. curve
Nonazeotrope,
v.p. curve

Nonazeotrope
Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

179
179

v-1
v-1

34
34

TABLE

BINARY

SYSTEMS
Azeotropic Data

-Component
No.

Formula

CI4T1

4 9 2CI4O
50 C2H2CI2O
51 C2H2CI4
A=

DH
52 D
53 H
2

54 H

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

A =

B.P.,C.

Titanium Tetrachloride
146.2
Trichloroacetyl
chloride
118
Chloroacetyl chloride
105
1,1,2,2- Tetrachlor ethane, 740 m m .
136.6
Deuterium Hydride
Deuterium, 18-28K.
H y d r o g e n , 18 - 2 8 K .

-249.7
-252.7

Deuterium

-249.7

A =

Name

Hydrogen, 18-28 K .

FH
55 F S b
56 F U
5

-252.7

Hydrogen F l u o r i d e
19.
Antimony pentafluoride 142.
Uranium hexafluoride
"
85 p.s.i.g.
110 p . s . i . g .
"
132 p . s . i . g .
145 p . s . i . g .
Dichlorodifluoromethane,
150 p . s . i . g .
48
Chlorodifluoromethane
7
70 p . s . i . g .
150 p . s . i . g .
29
"
230 p.s.i.g.
45
Trifluoroacetic acid

Nonazeotrope
Nonazeotrope
135.4

Nonazeotrope

Nonazeotrope

58 CHC1F

11

11

5 9 C2HF3O2
A=
60

F S
C F

61

F W
CjFxo

A=

6 2 C5F

A =

12

HNO3

63

H2O

Sulfur Hexafluoride
Perflnoropentane, 25C,
Tungsten Hexafluoride
Perfluorocyclopentane
Perfluoropentane,
1140 m m .
Nitric Acid
Water,
50m
100 m
200 m
400 m
760 m
11

11

11

11

6 4 CHCI3
H 0
H 0
2

65

66 H2SO4
67

H4N2

Water
Hydrogen peroxide
Hydrogen sulfate
200 m m .
Hydrazine,
124.8 m m .
281.8 m m .
"
411.2 m m .
"
560.4 m m .
700.6 m m .
760 m m .
Nitrogen pentoxide
11

11

11

M
II

69 C S

70 CHCI3
71 CH2O2

.
.
.
.
.

Chloroform

11

68 N2O5

m
m
m
m
m

v-1
v-1

300
300

v-1

32

v-1
v-1

238
238

v-1

238

v-1

301
91
91
91
91

22
18
15
14

11

CC1 F

91.7

Nonazeotrope
Nonazeotrope

11

57

Ref.

B.P.,C. W t . % A

7.5

334

3
<7
2.7
24
2.8
36
Nonazeotrope

v-1

334
334
334
222

Nonazeotrope

v-1

237

39

25/1019; 45/1982 m m .
25/833
45/1642
40.86
86
37
51.6
66.5
83.0
100
See a l s o
61

25/1035
45/2010

85.4
83.4

v-1
v-1

288
288

28.11

93.2

v-1

13

13.7
13.8
14.0
14.2
14.4

v-1
v-1
v-1
v-1
v-1

19
19
19
19
19

57.8
72.4
86.4
103.2
120.7

H2O-N2O5
47.5

below
15

258

100

.. .
. . 330
...
...

66.8
86.5
96.8
105.2
111.7
113.8

...

.. .
...

Carbon disulfide
46.5
Chloroform
61
F o r m i c a c i d , 40-760 m m . . . .
II
100.75

v-1
1.7
1.6

74.2
93.3
103.6
111.3
117.6
120
Max. b.p.
Min. b.p.
Max. b.p.
43.6
56.1

33.2
32.3
31.0
31.4
32.6
32.3
40
14.3
12.5
2
2.8

107.65

25.5

...

...

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

104
334
334

30
30
30
30
30
30
199
199
199
334
56
v-1
42
v-1
56,
217, 360
v-1
v-1
v-1
v-1
v-1
v-1
v-1

ADVANCES

IN

B-Component
No.

Formula

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

H2O

Azeotropic
B.P.,C.

Water (continued)

72
73

CH N0
CH 0

74

C j C L j F a

75

C 2 C 1

76

C 2 H F 3 O 2

7 7

C j H g c y s r O a

Nitromethane
Methanol
1,1,2 - T r i c h l o r o t r i fluoroethane
Tetrachloroethylene

78

C2H3CI3

79

C H N

80

C 2 H

Name

C 1

Trifluoroacetic acid
Methyl N,N-dichlorocarbamate
1,1,2-Trichloroethane
A c e t o n i t r i l e , 10 m m .
"
50 m m .
"
760 m m .
1,2 - D i c h l o r o e t h a n e
M

150 m m .
"
75 m m .
Acetic acid
2 -Bromoethanol,
150 m m .
2-Chloroethanol,
50 m m .
"
100 m m .
Nitroethane
Ethyl alcohol,
150-350 C .
250-2500 m m .
Ethylene glycol,
76-760 m m .
2 - Aminoethanol
"
100 m m .
1,1 - D i m e t h y l h y d r a zine,
102 m m .
11

81
82
83

84
85

4
C HsBrO
2

C 1 0

C H5N0
C H60
2

11

86

C He0

87

C H NO

88

C H N

II
89

90

C HF 0

91

C 3 H 3 N

1,2 - E t h y l e n e d i a m i n e
"
>3400 m m .

H e N 2

II

92
93
94
95
96
97
98

99

C3H3NS
C3H 0
C H 0
C H 0
C H 0
CjEUCl
4

C 1

C H NO
3

100

C g H g C i p

101

C H 0
3

11

102
103

C H 0
C H^O
3

II

104 C H p
105 C ^ Q ,
106 C a H O a
3

Propylene oxide
1,3-Dioxolane
Ethyl formate

B.P.,C.

SERIES

Data

Wt.%A

Ref.

100
101.2
64.7

83.59
23.6
Nonazeotrope

54, 55
v - -1
68

47.5
121
121

...

44.5
88.5
87.7
105

1.0
17.2
15.8
21

334
334
17d
222

...

93

113.8
-15
13
80.1
83.5

...
...
...

118.1

86.0
16.4
2.6
<-16
<12
5.8
16.3
76.5
8.2
71.6
8.2
75.5
4.9
33.5
19.0
4.9
Nonazeotrope

100

58

60
75
114.07

37.1
51.1
87.22

60.2
59.3
28.5

...
.. .

. ..
...

...
...
.. .

Nonazeotrope
Nonazeotrope
Nonazeotrope

.. .

82.5
Max. b.p.
Nonazeotrope
18.0
Nonazeotrope
119
18.4

170.5
112

116

...

77.2

.. .

111.5
52.8
115
141.2

...

44.9

.. .

229.7
183.8
56.1

.. .
...
...
...
...

96.90
47.9

...

35
75.6
54.2

109
10
14.3
70.6
90
34.8
92.1
35.3
52.4
2.6
97
54.5
Nonazeotrope
Nonazeotrope
2.2
43.0
0.9
33
Nonazeotrope
99.4
87
Nonazeotrope
Nonazeotrope
5.2
125.4
7.2
157.6
9.4
168.4
206.0
14.3

...

39

50 v o l . %

55.7

116.9

Pentafluoropropionic
acid
Acrylonitrile
T h i a z o l e , 695.5 m m .
"
750 m m .
Acrolein
2-Propyn-l-ol
Acrylic acid
Ethylene carbonate
3 -Chloropropene
M ethylvinyl chloride
Hydr acrylonitrile
2,3-Dichloro-lpropanol
Acetone
"
50 p . s . i . a .
"
100 p . s . i . a .
"
200 p . s . i . a .
250 p . s . i . a .
500 p . s . i . a .
A l l y l a l c o h o l , 752 m m .
Propionaldehyde
11

CHEMISTRY

...

2
47.5
2.5
47.5
Nonazeotrope
7
71.9
5
52.6

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v - -1

334
336
336
336
334
55
55
55
56
76

334
334
54, 55
v --1
v --1

14
251

v --1

60
334
334

v - -1

v - 1
v - -1

v --1
V " -1
v --1
V -1
v --1
V -1
v --1

v --1

37
37
76
76
334
222
334
219
219
334
95
334
334
334
334
334
334
254
254
254
254
254
254
130
334
84
60
334
334

TABLE

BINARY

SYSTEMS
-Component

No.

Formula

H 0

Name

B . P . / C .

Water (continued)

107
108

Azeotropic

C H 0
3

92

109
110
111

C H C1
C H C1
C H NO
3

56^
"
265 m m .
30
1 -Chloropropane
46.6
2 -Chloropropane
36.5
Dimethylf or mamide,
500 m m .
138
200-760 m m .
>
1 -Nitropropane
131.18
2 -Nitropropane
120.25
P r o p y l a l c o h o l , 47 m m . .. .
"
200 m m .
11

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

112
113
114

C H N0
C H N0
C H O
3

11

"

400
600

Wt.%A

88.5

12.8

77

Nonazeotrope
56.1
5
30
1.5
44
2.2
35.0
1

131
334
334
334
334

Nonazeotrope
Nonazeotrope
91.63
36.5
88.55
29.4
31.8
56.68
29.6

334
319
54, 55
54, 55
117
v-1 228,
306
v-1
306
v-1
306
v-1
306
72
v-1

71.92
29.0
81.68
28.5
87.65
28.3
In 1.5M C a C l Solution

mm.
mm.

II
II

115

C3H O

Isopropyl alcohol,
95 m m .
"
190 m m .
"
380 m m .
760 m m .
3087 m m .
150-300

...

82.5

11

11

11

II

C.

II

116

C He0
3

2-Methoxyethanol,
100 m m .
752 m m .
"
150 m m .
"
760 m m .
"
100 p . s . i . g .
1,2 - P r o p a n e d i o l
1,3- P r o p a n e d i o l
Propylamine
Trimethylamine

11

117
118
119
120

C H 0
C H 0
C ^ N
CaHN
3

" o-ioo c.

121
122
123
124
125

C
C
C
C
C

126

C H 0

H9NO
HF 0
H5N
HjN
H C1N
7

1 -Amino - 2 -propanol
Perfluorobutyric acid
3-Butenenitrile
Methac rylonitrile
2 - C h l o r o -2 - m e t h y l propionitrile
C rotonaldehy de,
111 m m .
273 m m .
412 m m .
11

II

127
128
129
130
131
132
133
134
135
136

cfto

C H N
C H NO
4

M ethac r ylaldehyde
3-Butenoic acid
trans-Crotonic acid
Crotonic acid
Butyrolactone
V i n y l acetate
Propylene carbonate
2-Chloroethyl vinyl
ether
Butyronitrile
2-Hydroxyisobutyron i t r i l e , 30 m m .
50 m m .
11

Ref.

100

2 -Methoxyacetalde h y d e , 770 m m .
Methyl acetate,
<10 p . s . i . a .

B.P.,C.

Data

36
49.33
63.90
80.10
120.45

13
12.8
12.6
12.0
11.7

Evaporation data
.. .
E f f e c t of d i s s o l v e d s a l t

.
...

79.2
124.6
212
188
214.8
47.8
3.2

...

159.9
122.0
118.9

.. .

51.5
80.5
99.2
81
Nonazeotrope
99.9
84.7
169
73.3
Nonazeotrope
Nonazeotrope
Nonazeotrope
75.5
10
Nonazeotrope
97
71
89.4
34
76.5
16

116

87

22

84.9
112.3
126.4
102.4

40
60
70
84

19
22
23
24.8

68.0
185

...

204.3
72.7
242.1
109.1
117.6

...

63.6
7.7
Nonazeotrope
Nonazeotrope
99.9
97.8
Nonazeotrope
66
7.3
Nonazeotrope
84
88.7

17
32.5

Nonazeotrope
Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v-1

v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1

v-1
v-1
v-1
v-1

347
347
347
347
347
14
196
265
152
152
334
334
334
60
334
334
148
148
334
222
334
269
269

334
334
334
96,
142, 334
269, 334
334
334
84
334
334
334
334
334
334
334

ADVANCES

IN

B-Component
Formula

H 0

B . P . / C .

Water (continued)

137

C H C1 0

138

C H 0

Name

Azeotropic

Bis(2-chloroethyl)
ether
2 -Butanone
"
3.5 p . s . i . g .
9.2 p . s . i . g .
30 p . s . i . g .
"
60 p . s . i . g .
14.7 p . s . i . a .
"
50 p . s . i . a .
"
100 p . s . i . a .
250 p . s . i . a .
500 p . s . i . a .

179.2
79.6

11

11

11

t!

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C H30

Butyraldehyde

II

140
141
142
143

C f t O
c ^ o
C HeOS
4

Ethyl vinyl ether


I sobuty raldehyde
Methyl propenyl ether
2 -Methylthiopropionaldehyde, 85 m m .
"
412 m m .
753 m m .
759 m m .
1,4-Oxathiane
p-Dioxane
~
"
260 m m .
Ethoxyacetaldehyde
2 - Hydr oxybutyr a l d e h y d e , 80 m m .
Isobutyric acid
3 -Methoxypropional d e h y d e , 100 m m .
2 - M e t h y l-1,3 -dioxolane
Methyl propionate
2-Vinyloxyethanol
Morpholine
N-(2-Hydroxyethyl)
acetamide
Butyl alcohol
250-2500 m m .
"
30 m m .
sec-Butyl alcohol
11

11

144
145

C HeOS
C He0

146
147

C He0

148
149

C Hg02
C

150
151
152
153
154

C H 0
C^O?.
C^eOz
C H NO
C H N0

155

C H

J>2
4

1 0

11

156

C H
4

1 0

II
II

20 m m .
E t h y l e t h e r , 20 p . s . i . g .
Isobutyl alcohol,
745 m m .
1,2 - D i m e t h o x y e t h a n e ,
100 m m .
11

157
158
159

C^ioO
C H O
4

1 0

4 102
H

II
II

160

C H
4

1 0

2 -Ethoxyethanol,
<100 m m .
200 m m .
400 m m .
11

11

II
11

11

II

161

C H
4

1 (

P3

mm.
mm.

Diethylene glycol,
10 m m .
B u t y l a m i n e , 575 m m .
"
20 p . s . i . g .
11

162

200
400

Data

Wt.%A

Ref.

100

11

139

B.P.,C.

SERIES

74.8

...

35.5
63.5
46.3

98
65.5
11.0
73.4
79.3
12.1
88.0
12.5
15.8
111
18.3
125
v-1
73.3
11.6
15.9
112.2
139.0
19.3
23.4
180.7
26.4
216.1
Evaporation behavior
68.0
9.7
6.7
67.8
1.5
34.6
6.7
64.3
46.3
0.5

...

48
82
97.5
97.5
14^2
95.6
E f f e c t of d i s s o l v e d
60
...
90
105

64
60
68
63
48
salt
15.4
21.8

v-1

334
78
78
78
78
78
254
254
254
254
254
196
334
84
334
84
334
76
76
76
76
334
265
60
77

.. .

Nonazeotrope
98.8
71.8

334
84

.. .

45
30
75
8
71.0
8.2
98
65
Nonazeotrope

334
76
84
94
334

Nonazeotrope
Evaporation behavior
v-1
...
...
52.4
28
87.0
v-1
26.8
Evaporation behavior
32
88.5
16.0
32.2
60
2.0

334
196
251
335
352
196
334
147
334

154.5

82.5
79.7
143
128.3

...

48
99.5

.. .

99.5
27.3
62

...
35
85.2
85

...
...

134
96.5
115.6
135.6

.. .

69
106

...

...

6
10.4
10.1

Nonazeotrope
70
66.4
79
82.4
87
98.2
66.4
85
82.4
76
71.2
99.4
Nonazeotrope
Nonazeotrope
1.3
69
6.5

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v-1

335
CO CO

No.

CHEMISTRY

76

v-1
v-1
v-1

v-1
v-1

18
18
18
18
334
334
334
60
60
334
334

TABLE

BINARY

SYSTEMS

11

B-Component
No.

Formula

Name
Water

163

(continued)

N O

2-Dimethylaminoethanol, 27 p . s . i . g .
"
744 m m .
540 m m .
250 m m .
2,2' -Iminodiethanol
2-Furaldehyde,
1-18 a t m .
Pyridine
120 m m .
758 m m .
"
>760 m m .
"
>760 m m .
"
>760 m m .
11

11

165
166
167

N 0

C H0
5

CsHgN

11

11

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

B.P.,C.

168

55.5

174
133.9
123.4
100.7

.. .

161.7
115.3

...

.
...
...
...
Effect

2 -Methylpyrazine,
737 m m .

133
130
2 - M e t h y l f u r a n , 740 m m . 62.7
3 - M e t h y l - 3-butene nitrile
137.0
A l l y l vinyl ether
67.4
Cyclopentanone
130.8
"
740 m m .
130
1 -Methoxy-1,3-buta
diene
90.7
3-Penten-2-one
123.5
3 - M e t h y l - 3-butene 2-one
97.9
4-Pentenal
106
A l l y l acetate
104.1
Ethyl acrylate
99.5
195 m m .
61
Isopropenyl acetate,
"
200 m m .
60.2
It
97.4
Methyl methacrylate
100.8
2,4 - P e n t a n e d i o n e
140.6
-Valerolactone
V i n y l propionate
95.0
B i s (2 - c h l o r o e t h o x y )
methane
218.1
3-Dimethylaminopropionitrile
174.5
cis-l-Butenyl methyl
ether
72.0
trans-1-Butenyl
methyl ether
76.7
Isopropenyl ethyl ether
61.9
Isopropyl vinyl ether
55.7
P r o p y l vinyl ether
65.1
Tetrahydropyran
88
Vale raldehyde
103.3
Vale raldehyde s
(isomers)
98.6
Ethyl propionate,
350 m m .
76.0
3-Methoxybutyral dehyde, 100 m m .
200 m m .
II
131
II

169
170

CjHgO
C H7N

171
172

C HeO
CgHeO

173

S**

174
175

C HeO
CsHgO

176
177
178

C HeO
CjHeOj

179

C He0

180
181
182
183
184

A l
5

C5He0

CgHg^
05 0
050
C H Cl O
8

1 0

185

186

C H

187

C H

188
189
190
191
192
193

11

5 10 2
H

1 0

O
p

C 5 H 1 0 O

C5H10O
C H
5

1 0

<^5 1

C H
C H
5

1 0

1 0

O
O

194

5 102

195

5 102

11

B.P.,C.

Wt.%A

Ref.

100

Diethylamine
It

164

Azeotropic Data

.. .
...

E f f e c t of N a O H o n v -1
Nonazeotrope
v- 1

334
334
334
334
334

90.2
99
92.6
91
95.2
71
98.2
Nonazeotrope

3 0-

93.6

41.3
46.2
40.5
40.7

50
40.7
80
of d i s s o l v e d s a l t

150
149,
334

v- 1

216
147
117
117
v- 1
146
v- 1
146
146, 360
v- 1
265

97
92.6
57.3

55
36 v o l . %
3.4
v - 1

351
279
310

93.0
60
94.6
92.6

43.2
5.4
42.4
v - 1
36 v o l . %

334
334
334
279

76.2
92

12.7
28.6

334
334

81.5
84.3
83
81.1
48

18.4
21
16.7
15
12

334
334
334
283
334

11
48
13.4
79.3
83
14
41
94.4
Nonazeotrope
13
79

334
334
283
334
334
334

99.4

86.8

334

99.6

84

334

64

6.1

334

67
58
51.8
59
71
83

7.2
2
2.7
5
8.5
19

334
334
334
334
82
334

80

17

334

61

13.3

334

37
37
35

334
334
334

50
64
>92

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

12

IN

-Component
No.

Formula

H 0
^5

Name

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

10

C5H10P2
C5H10P2

acetate,
200-700 m m .
Valeric acid
Valeric acid (isomers)
1 -Vinyloxy-2 -propanol
3 -Vinyl oxy-1 -propanol
3-Ethoxypropionic acid
3-Methoxybutyric acid
Methoxymethyl propio
nate
4 -Methylmorpholine
Pentane
1-Methylpiperazine
1,2 - D i m e t h o x y p r o p a n e
1-Ethoxy-2-propanol
3 -Methoxy-1 -butanol
1,5-Pentanediol
2 -Propoxyethanol
N-Methylbutylamine
1-Ethylamino-2propanol
N,N-Dimethyl-1,3propanediamine
A n i l i n e , 742 m m .
6 atm.
11 a t m .
16.4 a t m .
3-Picoline
4-Picoline

204
205
206
207
208
209
210
211
212
213
214

C H

215

C ^ N

C H O2
10

C5H10O2

C5HKJO3
C H

1 0

C H

P3
p

C H
5

N O

5^12
2

5 122
H

C5H12P2
C

5 122
H

C H
5

1 2

5 122
C H N
C H NO
C

1 3

B.P.,C.

11

11

C H N
C H N

218
219
220
221
222
223

C H N
CgHgO
C H O

224
225

...

185.5
183.2

219.2

6 10
C H O
H

1 0

It

226

C H
6

1 0

227
228
229
230
231
232
233

C H

1 0

234
235
236
237
238
239

6 10
C H O
C

1 0

6 102
H

C6HS02
C

6 1<P
H

6 llN
C ^ J N O
H

C
C

N 0

6 12
H

C H
6

240

C6H

241

C H
6

1 2

1 2

C1 0
2

CLj0
Q

Ref.

2 -Ethylcrotonalde hyde
2-Hexenal
5-Penten-2-one
2 -Methyl - 2 -pentenal
Ethyl crotonate
V i n y l but y r a t e
Vinyl isobutyrate
Ethylene glycol
diacetate
Diallylamine
6 -Caprolactam,
50-760 m m .
2 -Methyl -2-nit ropropyl
v i n y l e t h e r , 10 m m .
Cyclohexane
4-Methyl-2-pentene
Bis(chloroisopropyl)
ether
l,2-Bis(2-chloroethoxy) ethane
Butyl vinyl ether

v - -1
89
99.8
85
99.6
~100
75
~100
75
Nonazeotrope
Nonazeotrope

307
334
334
94
94
334
334

36.1
138.0
92
132.2
161.1
242.5
151.5
91.1

95
56
24
94.2
1.4
34.6
Nonazeotrope
80
11
97.3
50.1
98.5
80
Nonazeotrope
70
98.8
82.7
15

334
334
334
334
334
334
334
334
334
334

159.4

Nonazeotrope

334

134.9

154*
93.3
171
138.5
133.9

Nonazeotrope
80.8
98.6
76.6
155
76.2
182
77.4
200
60
97
62.8
97.35
63.5
97.4
65
98.5
77.0
11.7
70
98.
35.6
93
31
92

66.9

Nonazeotrope
5.3
60.2

...
...
...

144.1
144.3

2,5-Dimethylpyrazine
2,5-Dimethylfuran
2,4-Hexadienal
1,3-Butadienyl acetate
V i n y l crotonate
3,3'-Iminodipropionitrile
2 - E t h y l - 1 , 3 - butadiene
Cyclohexanone,
< 760 m m .

6 82
6 82

Wt.%A

100

11

216
217

B.P.,C.

Propyl

197
198
199
200
201
202
203

SERIES

Azeotropic Data

Water (continued)

196

CHEMISTRY

. ..

v --1
v --1
v --1
v --1
v --1
v --1

334
143
143
143
143
365
365
334
351
334
334
334
334
334
334

155.6
155.4

...

90
96.3
95

55
61.6

135.3
149
128.9
138.2
137.8
116.7
105.4

92.7
95.1
92.1
93.5
93.5
87.2
83.5

38
48.6
35.3
40
38
20.4
17

334
334
334
334
334
334
334

190.8
110.5

99.7
87.2

84.6
24

334
334

...

.. .

. ..

77-78
80.8
56.7

69.5
53.5

8.6
8.4
3.5

341
147
334

187.0

98.5

62.6

334

240.9
94.2

99.7
77.5

94.0
11.6

334
334

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

-1
v --1

V -1

121
121
334

333

TABLE

BINARY

SYSTEMS

13
Azeotropic

-Component
No.

Formula

H 0

A =

C H
6

B.P.,C.

Water (continued)

242

Name

C y c l o h e x a n o l , 42 m m .
"
57 m m .
95 m m .
158 m m .
252 m m .
385 m m .
"
570 m m .
"
684 m m .
11

.. .
.. .

160.65
160.65
116.7
83.4
128.3
118.3

35
40
50
60
70
80
90
95
97.8
90
87.5
70.5
91.0
88.5

86
84.8
82.5
80.2
77.8
75.2
72.6
70.7
69.5
74
23.7
7.8
31.3
23

169.7
194.2
205.7

97.8
99.7
99.8

61
87
92.1

11

11

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

243
244
245
246
247

C
C
C
C

H
H
H
H

248
249
250

C H
C H
C H

"
<760 m m .
2 -Ethylbutyraldehyde
Isobutyl vinyl ether
Hexaldehyde
2 -Methylpentanal
2-Ethylthioethyl vinyl
ether
2-Ethylbutyric acid
Hexanoic acid
4 - Hydroxy - 4 - methyl 2-pentanone
100 m m .
"
200 m m .
"
400 m m .
"
760 m m .

O
0
0
0
^12', O S

0
0
0

t !

It

251
252
253
254
255
256
257

C H
6

2-Ethyl-2-methyl1,3-dioxolane
2-Methylpentanoic acid
4 -Vinyloxy-1 -butanol
Tetrahydropyran2-methanol
2-Ethoxyethyl acetate
Methyl 3-ethoxyp r o p i o n a t e , 50 m m .
2 - (2- V inyloxyethoxy)
ethanol

6 122
6 122
C H 0
C

6 123

6 123

6 123

It

258
259

C H C1
C H >
6

1 3

1 -Chlorohexane
Cyclohexylamine,
40 m m .
70 m m .
100 m m .
200 m m .
"
300 m m .
500 m m .
"
760 m m .
Hexamethyleneimine
2,6-Dimethyl morpholine
4 -Ethylmorpholine
4 -Morpholineethanol
Hexane
2,5- Dime thylpipe r a zine
4-(2-Aminoethyl)
morpholine
1 - Pipe razine ethanol
Butyl ethyl ether
2-Ethyl-1-butanol
Hexyl alcohol
Isopropyl ether,
131 m m .
297 m m .
481 m m .
"
1520 m m .
11

11

11

11

260
261

C H
C H

262
263
264
265

C
C
C
C

266

C H

1 3

N
NO

H NO
H
N0
H
H lSr

1 3

1 4

N 0

267

C H

268

CHUO

269
270
271

C H 0
C Hi40
C , H O

1 4

N20
4

11

11

Ref.

Wt.%A

100

11

it

B.P.,C.

Data

...

.. .
.. .
123.5
143
161
169.2
117.6
196.4

187.2
156.2

Nonazeotrope
Nonazeotrope
97
66.4
90
82,6
99.5
85
87
99.6

...

334
334
334
V
V
V
V
V

-1
-1
-1
-1
-1

125
125
125
125
125
335

20
87.9

334
334
94

Nonazeotrope
97.5
55.6

334
334

88.5
99.4
M i n . b.p.

37

207.6
134.5

v - -1

374
374
374
374
374
374
374
374
374
122
334
334
334
334

50

~100
97-8
Nonazeotrope
29.7
91.8

334
94
334
334

69.0
66.0
64.1
60.7
59.1
57.0
55.8
49.5

38
38
38
38
38
38
38
81

146.6
138.3
225.5
68.7

70
99.6
96.7
46.2
Nonazeotrope
5.6
61.6

334
334
334
334

164

Nonazeotrope

334

204.7
246.3
92.2
147.0
157.1

Nonazeotrope
Nonazeotrope
11.9
76.6
96.7
58
67.2
97.8

334
334
334
335
335

51.4

72
90.9
102.5
118.9
134.5
138

22.47
41.82
54.75
92

31.7
41.9
49.0
63.6
72.7
85.3
96.4
95.5

20.0
38.0
50.0
88

2.6
3.4
4.0
7.6

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

334
334
334
334

ADVANCES

IN

B-Component
No. ,

Formula

H 0
2

272
273
274
275
276
277
278
279

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

280

QH14O
QH14O2
C6H14O2
C6H14O2
C

6 142

6 142

C H
6

6 143
H

Azeotropic

Name

B.P.,C.

W a t e r (continued)
2 - M e t h y l -1 -pentanol
4 - M e t h y l - 2 - pentanol
1,1 - D i e t h o x y e t h a n e
1,1 - D i m e t h o x y b u t a n e
1,3 - D i m e t h o x y b u t a n e
1,1 - D i m e t h o x y - 2 methylpropane
2-Methyl-l,5pentanediol
3-Methyl -1,5pentanediol
B i s (2 - m e t h o x y e t h y l )
ether, 100 m m .
"
760 m m .
800 m m .
760 m m .
2 -(2 -Ethoxyethoxy)
ethanol
Diisopropylamine
1,3- D i m e t h y l b u t y l amine
Dipropylamine
-Ethylbutylamine
Hexylamine
Triethylamine
11

11

281

282
283

C H
Q>H

284
285
286
287

C
Q
C
C

288
289
290

C H
C H
QH

291

QH

292

C H

293

QH

294

C H

295
296

C7H 0
C H C10

297
298
299

C7H9N
C7H9N

300
301

C7H10O4

302
303

6 143
H

H
H
H
H

1 5

N
N
N
N

1 5

1 5

1 5

1 5

1 5

1 6

NO
NO
NO

N
N

1 5

C H
7

l 0

^7^12

C Hi20
7

7 122
H

304

7 122

305
306

C Hi204
C H 0

307
308
309

C H
C H
C H

310

1 4

2 -Butylaminoethanol
2 -Diethylaminoethanol
1 -Isopropylamino2-propanol
4-(2 - A m i n o e t h y l )
piperazine
N,N-Diethylethylenediamine
,,','-Tetramethylethylene diamine
Toluene
II

0
0
0

40

Guaiacol
2 -Chloroallylidene
diacetate
2,6-Lutidine
Tetrahydrobenzonitrile
1,2,3,6 - T e t r a h y d r 0 benzaldehyde
Allylidene diacetate
2,4-Dimethyl-1,3-pen t a d i e n e , 750.6 m m .
3-Hepten-2-one
Butyl acrylate
II

A m y l acetate

B.P.,C.

SERIES

Data

Wt.%A

Ref.

100
148
131.8
102.1
114
120.3

97.2
94.3
82.6
87.3
89.6

60
43.3
14.3
20.3
30

334
334
334
334
334

104.7

83.9

14.3

334

242.4

Nonazeotrope

334

248.4

Nonazeotrope

334

103
162
164
164

99.55

89.5
80.2
80
78

v-1

9
9
9
76

202.8
84.1

Nonazeotrope
9
74.1

334
334

108.5
109
111.2
132.7
89.4

89.5
28.6
86.7
87.5
43.6
95.5
49
Compound forma- v-1
tion
Nonazeotrope
98.9
74.4

334
41
334
334
315

199.3
162.1
164.5
222.0
144.9

119-22
110.7
110.6
205.0

99.8

334

86

Nonazeotrope
99.8

334
334

334

79.5

334

30
95.6
Evaporation behavior
20.2
85
87.5
99.5

287
196
334
96

212.1
142
195.1

99.7
96.02
98.8

85
51.8
78.3

164.2

96.9
98.7

60
71

334
334

76.8
96
94.5
94.3
47.8

13
55.7
40
38
41

334
334
76
334
334

93.6
34.9
Nonazeotrope

334
334

93.3
162.9
147

...
...

"
100 m m .
2-Ethoxy-3,4142.9
dihydro-1,2 -pyran
P i m e l i c a c i d , 100 m m . 272
Butyl isopropenyl
ether
114.8
147.6
3-Heptanone
143.7
4-Heptanone
5 - M e t h y l - 2 -hexanone
144
II

CHEMISTRY

( i s o m e r s ) 146

86.3
94.6
94.3
94.7
93.0
94

18.8
42.2
40.5
44
75
36.2

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v-1

334
365
334

334
334
334
334
84
334

TABLE

BINARY

SYSTEMS

15

-Component
No.

Formula

Name

Water (continued)
311

C H
7

1 4

Ethyl 3-ethoxypropionate
100 m m .
3-Methoxybutyl acetate
2 -(2 -Methoxyethoxy)
ethyl acetate
Heptane
5 -Methyl - 2 -hexanol
1 -Butoxy- 2-r
thoxyethane
1 -Butoxy-2-propanol
2 - E t h y l -1,5 -pentane diol
1 -(2 -Ethoxyethoxy) 2-propanol
2-Ethoxyethyl
2-methoxyethyl ether
2 -(2 - P r o p o x y e t h o x y )
ethanol
1 -Diethylamino -2 propanol
3-Diethylamino propylamine
Styrene
2-(2,4-Dichlorophenoxy) ethanol
Acetophenone
(Epoxyethyl)benzene
Ethylbenzene

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

11

312
313

C H
C H

314
315
316

C7Hi
C H 0
C H 0

317
318

C H
C H

319
320
321

0
0

C H

0
0

Aez

322

C H
7

1 7

NO

323

C H

1 8

324
325

CgHgCLjOj,

326
327
328

QHeO
C H

329
330
331
332
333

CeHio

334

8 10
H

N
N
N

335

C H

336

340
341
342
343
344

C
C
C

H K P

8 122
H

8 124
8 14
C H 0

C H 0
C Hi 0
C Hi 0
8

8 14 - 2
8 142
H

<

>

345

8 142

346

8 143

347
348
349

350

C H 0
^8^ 0
8

8 15

8 16

B.P.,C.

m-Xylene
-Methylbenzyl alcohol
-Ethylaniline
-Methylbenzylamine
2-Methyl ^5-ethylpyridine
ar-Methyl-1,2,3,6tetrahydrobenzonitrile
2-Methyl-l,2,3,6tetrahydrobenzaldehyde
3,4-Dihydro-2,5dimethyl-2H-pyran2 - carboxaldehyde
Diethyl fumarate
Diisobutylene
Bicyclo[2.2.1]
heptane - 2 - methanol
Diisobutylene oxide
2-Ethyl-2-hexenal
2-Octenal
1,1 - D i a l l y l o x y e t h a n e
2 -Ethyl - 3 -hexenoic
acid
Vinyl 2-methylvalerate
B i s (2 - v i n y l o x y e t h y l )
ether
Butyl acetoacetate
Diethyl succinate
2 - (Aminomethyl)
bicyclo[2.2.1]
heptane
2 -Ethylhexaldehyde

B.P.,C.

Wt.%A

Data
Ref.

100
170.1
107.8
171.3
208.9
98.4

. . .
149.9
170.1

97
50.5
96.5

63
71
65.4

334
334
334

Nonazeotrope
12.9
79.2
96.5
59.1

334
334
84

95.6
98.6

42
72

334
334

253.3

Nonazeotrope

334

198.1

Nonazeotrope

334

215.8

99.5

82

Nonazeotrope

334
334

159.5

97.2

55

334

169.4
145.1

99.8
93.9

93
40.9

334
334

139.1
203.4
204.8
188.6

~100
99.1
99.2
92
91
94.5
99.7
99.2
99.4

~99.6
81.5
77.6
33.0
30.6
40
89
83.9
83.8

334
334
334
334
84
334
335
334
334

178.3

98.4

72

334

205.4

99.1

82.6

334

176.4

97.7

92.2

334

170.9
218.1
102.3

97.4
99.5
82

56
87.5
12

334
334
334

203.9

150.9

99.7
94
97.6
99.2
95.3

91
37
60.9
76.2
41

334
334
334
334
334

231.8

99.9

97.4

334

148.8

95

38

334

198.7
213.9
216.2

99.4
99.4
99.9

82
84.1
91

334
334
334

185.9
163.6

99
96.4

82
51.6

334
334

.. .

201.6
194.2
136.2

It

H
H
H

337
338
339

Azeotropic

.. .
176

...

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

IN

-Component
No.

Formula

Water (continued)

H 2 O

351

C H

1 6

352

C H
8

353

C H
8

354

C H

355

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

356
357

358
359

360

361
362

8
8

8
8

II

l P 2

l c P 2

l t P 2

l P 2

l P 2

l P 3
l P 3

363

364

C H
8

365

C H

1 7

366

CgHnN

36 7

Q H n N

368

CeH

1 7

369

CeH

1 7

NO

l A

C1

370
371
372

CeHieO

373
374

8 18^2

375
376

CeH
C H
8

0
0

377

C H

378
379

2,4,4-Trimethyl1,2-epoxypentane
2,4,4-Trimethyl2,3 - e p o x y p e n t a n e
2-Butylthioethyl vinyl
ether
2-Butoxyethyl vinyl
ether
2,3-Epoxy-2-ethylhexanol
2-Ethylbutyl acetate
2-Ethylhexanoic acid

l t P 2

C H
8

182

1 8

182

C H
8

380

381

C H

382

C H

383
384
385

C H
C H
C H

386

C H
8

N0

387

C H

N0

388

C ^ O ,

8 iaP3
H

03

1 8

1 9

1 9

1 9

Name

N
N
NO

Hexyl acetate
Iso-octanoic acid
(isomers)
4 - Methyl - 2 -pentyl
acetate
2-Butoxyethyl acetate
2,5-Diethoxytetrahydrofuran
2-Ethoxyethyl 2vinyloxyethyl ether
2 - (2 - E t h o x y e t h o x y )
ethyl acetate
l-Chloro-2-ethylhe x a n e
N - E t h y l c y clone x y l amine
5-Ethyl-2-methylpipe ridine
ar-Methylcyclohexylmethylamine
4-Ethyl-2,6-dimethylmorpholine
Octane
2 - E t h y l -1 - h e x a n o l
Iso-octyl alcohol
(isomers)
2 - E t h y l -1,3 -hexanediol
1-Butoxy-2-ethoxyethane
1,1 - D i e t h o x y b u t a n e
5 -Ethoxy- 3-methyl pentanol
2-Ethyl-3-methyl1,5-pentanediol
2 -Hexyloxyethanol
2 - (2 - M e t h y l p e n t y l o x y )
ethanol
2 - (2 - B u t o x y e t h o x y )
ethanol
B i s (2 - e t h o x y e t h y l )
ether
l,2-Bis(2-methoxyethoxy) ethane
Dibutylamine
2 -Ethylhexylamine
2 -Diisopropylaminoethanol
2,2'- Butyliminodi ethanol
1,1' - E t h y l i m i n o d i 2-propanol
V i n y l benzoate

CHEMISTRY
Azeotropic

B.P.,C.

B.P.,C.

Wt.%A

SERIES

Data
Ref.

100
140.9

93.4

33

334

127.3

91

25

334

210.5

99.3

80

334

.. .
..
162.3

97.0

52.8

334

100
97.0
99.9
99.5
97.4

99.5
52.4
96.4
97.6
61

334
334
334
84
334

227.6

...

171.0
220

99.9

96

334

146.1
192.2

94.8
98.8

36.7
71.9

334
334

173.0

98

60

334

194.0

99.3

82.3

334

217.4

Nonazeotrope

334

173

97.3

55

334

164.9

97.1

58

334

163.4

97.1

57.0

334

.. .

99.0

79

334

158.1
125.7
184.8

97.5
89.6
99.1

49
25.5
80

334
334
335

186.5
243.1

82
99.8
Nonazeotrope

334
334

164.2
146.3

96.8
94.2

50
34.5

334
334

211.7

99.9

97

334

Nonazeotrope
99.7
91

334
334

265.5
208.1
197.1
230.6
188.4

...

159.6
169.1

190.9

.. .
238.9

99.6

86

Nonazeotrope
99.4

69

Nonazeotrope
97
50.5
98.2
64
99.2

85

334
334
334
9
334
334
334

Nonazeotrope

334

Nonazeotrope
99.3
82.6

334
334

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

TABLE

BINARY

SYSTEMS

17
Azeotropic

-Component
No.

Formula

H 0

Water (continued)

389

390

CHuN

l,2-Epoxy-3phenoxyp ropane
5-Ethyl-2-vinylpyridine
Cumene
Bicyclo[2.2.1]hept5-ene-2-ol acetate
5-Ethyl-2-pyridine ethanol
Isophorone
"
25 p . s . i . g .
l-Methyl-2,5endomethylene cyclohexane -1 methanol
Triallylamine
5-Ethyl-3-hepten2-one
Dimethyl pimelate
2,6-Dimethyl-4heptanone
2-Heptyl acetate
3-Heptyl acetate
3-(2-Ethylbutoxy)
propionic acid
Nonane

1 0 P 2

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

391
392
393

C H

394

CHiP

395

C H

396
397

CoHiijsr

398
399

CcHi 0
C H O

400
401
402

NO

1 3

CoH

1 6

i e

^-9

C H
C H

1 2
0

1 8

0
O

403

C 9 H 2 0

404

C9H20O

405

C9H20O2

406

C9H20O3

II

407

408

C9H20P3

409
410
411

C H
C H
C H
9

2 1

2 1

412

C H

413
414

C
C

415
416

C
C

1 0

1 0

Name

H
H
H
H

N
N
N0
N0

O
O

1 0

1 2

2,6-Dimethyl-4heptanol
2 -Ethyl-2-butyl 1,3-propanediol
1 - (2 - B u t o x y e t h o x y ) 2-propanol
2-Methoxymethyl2,4-dimethyl1,5-pentanediol
1,1,3-Triethoxypropane
-Methyldibutylamine
Tripropylamine
1,1' - I s o p r o p y l i m i n o di-2-propanol
2-(2-[2-(3-Aminopropoxy) ethoxy] ethoxy)ethanol
Dimethyl phthalate
2-Phenoxyethyl ace
tate
Dicyclopentadiene
N i c o t i n e , 110 m m .
478 m m .
572 m m .
624 m m .
760 m m .
Ethyl bicyclo[2.2.1]
hept-5-ene-2carboxylate
2 - (2 - P h e n o x y e t h o x y )
ethanol
N-Butylaniline
N-Ethyl - a-methylbenzylamine
N,N, a-Trimethylbenzylamine
11

B.P.,C.

99.8

96.1

334

15^4

99.4
95

85
43.8

334
334

188.6

98.6

70

334

.. .

215.2
251

418

419
420

C10H5N
Ci H

1 5

421

Ci H

1 5

142

Nonazeotrope
83.9
99.5
130
86.5

334
334
334

211.1
151.1

99.7
95

90.6
38

334
334

193.5
248.9

98.7
99.9

73.4
96.8

334
334

169.4
176.4
173.8

97.0
97.8
97.5

51.9
58.9
57.6

334
334
334

15!7
150.8

100
94.8
95

> 99
82
39.8

334
332
334

178.1

98.5

70.4

335

Nonazeotrope
230.3

...
163.1
156
248.6

...

282.9
260.6
172

...
...

11

10

Ref.

244.4

11

Wt.%A

100

11

417

B.P.,C.

Data

198
297.9
240.4

99.9

334

95

334

Nonazeotrope

334

334
334
41

Nonazeotrope

334

Nonazeotrope
98.9
100

334
334

99.9
97.4
67.7
98
Nonazeotrope
99.70
...
99.02
.. .
98.50
...
99.85
97.48

334
334
106
106
106
106
106

99
96.5
94.3

99.2

70
48.0

80

Nonazeotrope
94.4
99.8

-1
-1
-1
-1
-1

334
334
334

201.2

99.2

80

334

195.8

98.6

74.8

334

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

IN

B-Component
No.

Formula

Name

Water (continued)
422

423
424

CIOHHP

425
426
427

CioHi 0

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

428

1 0

1 5

NO

10 ltP

1 0

l P 2

10 182

l<f*2<P

429
430
431

C10P2 0O2

432

433

^10^21^1

434

P 1 A 1 N

435

C 1 0 H 2 2 O

436
437
438
439
440

C 1 0 H 2 0 O 2
C 1 0 H 2 0 O 2

H2o0

1 0

C 1 0 H 2 2 O
C 1 0 H 2 2 O

H 2O2

1 0

C 1 0 H 2 2 O 2

H 2O

441

1 0

442

443
444

CioH

445

446
447
448

1 0

2 3

H 2O4
2

2 3

C10H23N

NO

11 1403
11 1403
H

449

450

CiiH

451

452
453
454

C11H20O4

ll

lP3

H 2

C H220
n

C11H22O2

455

456
457
458
459
460

11 24
H

C11H24O
C11H24O2
C H2402
n

2-(a - M e t h y l b e n z y l amino) ethanol


Dicyclopentenol
Trimethyltetrahydrobenzaldehyde
Diisopropyl maleate
V i n y l 2-ethylhexanoate
V i n y l octanoate
(isomers)
2-Ethylhexyl vinyl
ether
2-Ethylbutyl butyrate
2 - E t h y l h e x y l acetate
4 - M e t h y l- 2 - p e n t y l
butyrate
2-Butoxyethyl 2vinyloxyethyl ether
C h l o r ode c a n e
(isomers)
- Butylcyclohexylamine
Decyl alcohol
(isomers)
2 -Ethyloctanol
2 -Propylheptanol
1,2- Dibut oxyethane
1,1 - D i i s o b u t o x y e t h a n e
2 -(2 -Hexyloxyethoxy)
ethanol
l,2-Bis(2-ethoxyethoxy) ethane
Bis[2-(2-methoxyethoxy)ethyl] ether
Decylamine (isomers)
Diamylamine
(isomers)
N,N-Dimethyl-2-ethylhexylamine
2 -Dibutylaminoethanol
Butyl salicylate
Ethyl 6 -formylbicyclo
[2.2.1]hept-5-en-2carboxylate
Allyl 6-methyl-3,4epoxycyclohexane carboxylate
Isopropyl 6-methyl3-cyclohexenecarboxylate
5 - E t h y l - 3- nonen 2-one
Diethyl pimelate
5 - E t h y l - 2 - nonanone
2,6- Dimethyl- 4 -heptyl
acetate
4-Methoxy-2,6dipropyl-1,3dioxane
Undecane
5 - Ethyl - 2 -nonanol
2,2-Dibutoxypropane
2,6-Dimethyl-4heptyloxyethanol
1,1,3,3 -Tetraethoxypropane

CHEMISTRY
Azeotropic

B.P.,C.

B.P.,C.

Wt.%A

SERIES

Data
Ref.

100

.. .
.. .

Nonazeotrope
100
96.6

334
334

204.5
228.7
185.2

99.0
99.9
98.6

77.0
93
68

334
334
334

.. .

99.1

74

334

177.7
199.6
198.4

97.8
98.6
99.0

59.1
74.9
73.5

334
334
334

182.6

98.2

60.8

334

226.7

99.8

90

334

210.6

99.7

84

334

209.5

99.5

81

334

217.3
220.5
217.9
203.6
160.5

100
99.9
99.8
99.1
97.4

94.8
94.0
92
76.8
52.5

335
334
334
334
334

259.1

100

98.1

334

246.9

Nonazeotrope

.. .

Nonazeotrope
82
99.5

203.7

334
9, 3 3 4
334

190

99.3

76

334

176.1
228.7
268.2

98.2
99.9
99.9

58
91.0
95.8

334
334
334

.. .

100

97

334

251.4

100

98.1

334

84

334

99.6
100
99.6

92
98.3
87.1

334
334
334

192.2

98.7

67.6

334

223.6
194.5
225.4

99.6
98.85
99.7
98.9

88.1
96
89.1
69.6

334
332
334
334

225.5

99.9

91

334

220.1

99.8

87.4

334

215.2
226.4
268.1
222.9

.. .

99.7

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

TABLE

BINARY

SYSTEMS

19
Azeotropic

-Component
No.

Formula

Name

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Water (continued)
461

462
463
464

C
C
C

465

Ci H o0

466
467
468
469

Ci H
C H

470

471
472

473

Ci H

474
475
476
477
478
479

C
C

480

H
H
H

1 2

P4
P

2 f l

1 2

2 2 2

1 2

2 2 2

H
H

1 2

H
H

p
0

C
H p
Ci H
Ci H >
1

12

2 P

262

Ci H
Ci H

483
484
485
46
487
488

492
493

04
0
N

481
482

489
490
491

1 4

N O

0
0

Ci H

C i 2 H

C i 2 H

Ci H
Ci3H
2

Ci H
C H
4

0 P
0

2 4

0
N

14 24
H

14 2tt4
H

CuH^O

494

495

496

14 282

497

14 282

498

499

500
501
502

0
p

H
H

N
P

14 3P2
H

Cl5 284
H

C 1 5 H 3 2 O

1 -Dibutylamino-2propanol
Diethyl phthalate
Triisobutylene oxide
- B u t y l - a- m e t h y l benzylamine
sec-Butyl - 6- methyl 3-cyclohexenecarboxylate
Dibutyl fumarate
D i b u t y l m a l e ate
2-Ethylhexyl crotonate
V i n y l decanoate
(isomers)
Diethyl 2-ethyl3 -methylglutarate
Dicyclohexylamine
2,6,8-Trimethyl4-nonanone
2-Ethylbutyl 2ethylbutyrate
2-Ethylbutyl hexanoate
Hexyl 2-ethylbutyrate
Hexyl hexanoate
Dodecane
2-Butyl-l-octanol
2,6,8-Trimethyl4-nonanol
1,1-Diethoxy2-ethylhexane
1,1 - D i i s o p e n t o x y e t h a n e
3-Ethoxy-4-ethyloctanol
Bis(2-butoxyethyl)
ether
1,1,3 - T r i e t h o x y h e x a n e
Dihexylamine
Tributylamine
T r i b u t y l phosphate
Decyl acrylate
(isomers)
2 -(Ethylhexyl)phenol
-(Ethylhexyl) aniline
1,3,6,8 - T e t r a m e t h y l 1,6 - c y c l o d e c a d i e n e
Dibutyl adipate
Trimethylnonyl vinyl
ether
2-Ethylbutyl 2-ethylhe x a n o a te
2-Ethylhexyl 2-ethyl
butyrate
2-Ethylhexyl
hexanoate
Hexyl 2-ethylhexanoate
-(2-Ethylhexyl)
cyclohexylamine
7-Ethyl-2-methyl4-undecanol
2-(2,6,8-Trimethyl4 - n o n y l oxy) e t h a n o l
Dibutyl pimelate
2,8-Dimethyl-6isobutyl - 4 -nonanol

B.P.,C.

B.P.,C.

Data

Wt.%A

Ref.

100
229.1
294.3

.. .
239.3

99.8
99.9
99.3

88.4
98.4
72

334
334
334

99.8

92

334

92
98.5
98.4
93.4

334
334
334
334

88

334

.. .

100
99.9
99.9
99.9

.. .

99.9

285.2
280.6
241.2

255.8
255.8

100
97.1
Nonazeotrope

334
38

218.2

99

84

334

222.6
236.2
230.3
245.2
214.5
253.4

99.6
99.7
99.7
99.8
99.45
99.9

85.6
91.2
88.8
93.3
98
97.5

334
334
334
334
332
334

225.5

99.6

89.7

335

207.8
213.6

99.3
99.3

78.6
78.8

334
334

249.2

100

98

334

254.6

99.8
99.6
99.8
99.8
100

94.7
85
92.8
82
99.4

334
334
334
334
334

99.9
100
100

94.9
> 99
99.3

334
334
334

99.5
100

82.3
>99

334
334

223.4

99.6

84.3

334

261.5

99.9

95.8

334

252.8

99.9

94.8

334

267.2

99.9

96.4

334

254.3

99.9

94.6

334

99.7

334

96.3

334

99.0
> 99.5

334
334

.. .

239.8
213.9

.. .
...

297.0

.. .
220.5

.. .

.. .
264.3

.. .
.. .
265.4

100
99.9
100
100
99.9

97.2

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

334

ADVANCES

IN

CHEMISTRY
Azeotropic

-Component
No.

Formula

Water (continued)

H 0

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

503

504

1 8

505

Ci$H

3 0

506

Ci6H

3 1

507

Ci6H

508

1 6

3 4

509

1 6

3 5

510

Ci H

511

512

CieH

3 8

513

CieH

3 9

NO

514

3 6

1 6

1 8

2 0

3 2

0
N
0

3 6

2 4

5 1 5 C20H36O4
516

517
518
519
520
521

C H
C oH4
C H
C iH
C H

522

2 0

4 0

2 0

2 0

4 3

3 8

2 4

5 2

H5 0
8

B.P.,C.

11

11

524

C H
3

Ammonia

H N
3

525
526

C ^ N
C

527

C ^ g F

528

C HJQ
4

11

11

529

C H^
8

Wt.%A

100

98.7

334

100
100

99
98.8

334
334

100

99.45

334

99.9

97.9

334

99.8

96.4

334

97.6

334

100
100

>99

334

100

>99.9

334

.99.9

334

100

>99.5

334

100

>99.9

334

100

>99.9

334

>99.5
100
100
99.6
99.8
100
100
99.6
Nonazeotrope

334
334
334
334
334

100

99.9

334

100

99.8

334

-21.6
-6.5
5
15
23.5
7.8
37.1
56
72
84.2
95

7.9
11.6
14.5
17.1
19.6
75.2
82
83.7
87.2
89.9
92.7

99.0

v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1

159
159
159
159
159
161
161
161
161
161
161

Nonazeotrope
-45
44.3
34
-40.5
56.8
43
59.0
66
60.9
81
62.1
94
63.4
104

v-1
v-1
v-1
v-1
v-1

334
127
127
160
160
160
160
160

M i n . b.p. 98-100%

v-1
v-1

162
162

-33.4

Ethylamine, 0-30 C.
-32
Propadiene
2-Fluoropropene
-24
B u t a n e , 300 p . s . i . g .
500 p . s . i . g .
700 p . s . i . g .
900 p . s . i . g .
1100 p . s . i . g .
I so-octane,
200-1600 p.s.i.g.
"
> 1400 p . s . i . g .
11

Ref.

B.P.,C.

-59.6

E t h a n e , 200 p . s . i . g .
"
300 p . s . i . g .
400 p . s . i . g .
"
500 p . s . i . g .
600 p . s . i . g .
P r o p a n e , 200 p . s . i . g .
"
400 p . s . i . g .
"
600 p . s . i . g .
"
800 p . s . i . g .
"
1000 p . s . i . g .
"
1200 p . s . i . g .

CjHg

Data

100

Bis( - methylbenzyl)
ether
286.7
Bis(4-methyl-2pentyl) maleate
Tridecyl acrylate
Bis(methylcyclohexylme thyl) a m i n e
...
2-Ethylhexyl 2ethylhexanoate
280.4
B i s (2 - e t h y l h e x y l )
ether
269.8
Bis(2-ethylhexyl)
amine
280.7
3,9-Diethyl-6tridecanol
309
Bis(a - methylbenzyl)
ethylenediamine
1,1 - B i s ( 2 - e t h y l h e x y l o x y )
ethane
2-[Bis(2-ethylhexyl)
a m i n o ]ethanol
Bis(2-ethylhexyl)
fumarate
Bis(2-ethylhexyl)
maleate
2-Ethylhexyl 3(2 - e t h y l h e x y l o x y )
butyrate
Decyl ether (isomers)
Eicosanol (isomers)
Didecylamine (isomers)
...
A l l y l 9,10-epoxystearate
...
Tetra(2 -ethylbutoxy)
silane
Tri(2-ethylhexyl)
1,2,4-butane tricarboxylate

Hydrogen Sulfide

HS
523

O
0
N
03
0 Si

4 2

3 1

Name

SERIES

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

TABLE

BINARY

SYSTEMS

21
Azeotropic

-Component
No.

A =

Formula

He

530 C H

A=

Methane, 5-170 a t m .

Sulfur Dioxide

0 S
2

Methyl

532
A

533

ether

Sulfur

S
Se

Selenium

CHC1F

Chlorodif luor 0 methane


"
4.93 a t m .
2059 m m .
Chloromethane,
5380 m m .
1,1 - D i f l u o r o e t h a n e
11

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

534

535

268.9

...

C H 3 C I

C 2 H 4 F 2

II

60 p . s . i . a .
"
112 p . s . i . a .
M e t h y l e t h e r , 2340 m m .
Hexafluor opr opene,
2059 m m .
Heptafluoropropane,
2328 m m .
Perfluorocyclobutane,
2059 m m .

536 Czi^O

538

C HF

539

C F

A =

CC1 F
3

540
541

A=

C H 0
C2H 0
2

688

CC1

C H 4 O

543
544

C HC1
C H N

545

546

C H Q

542

C l 2

CsHp

-6.1

-7.1

...

17
21

24.9

Carbon Tetrachloride

76.74

20.2
32

64.7
Methanol
Trichloroethylene
86.2
A c e t o n i t r i l e , 371.2 m m . ...
1,2 - D i c h l o r o e t h a n e
83.45
A c e t i c a c i d , < 50 m m .
...
90 m m .
...
340 m m .
"
530 m m .
...
760 m m .
118.1
"
1080 m m .
"
1400 m m .
...
Ethyl alcohol
78.3
Acetone, 513.2m m .
...
31.29
300 m m .
450 m m .
41.56
600 m m .
49.36
760 m m .
56.08
Allyl alcohol
97.1
97.2
Propyl alcohol
2 - B u t a n o n e , 342 m m .
...
It
79.6
11

11

11

551

C H<p
C H80
3

Cftf)

552 C ^ g C ^
553
C H O
554
C H 0
555 CgHg

556

1 0

C 7 H 8

282
260
260
260
260
281
281
282

...

11

549
550

v- 1

25.0
-30.5
0.00
24.90
40.08
4.44
25
0

.. .

33.5

11

CjjHgO

102

86
261
346

11

548

165

25
-41.4
0.00
2.1
Nonazeotrope

-40.8
0.04

11

547

v- 1

65

Compound formation

Trichlorofluorom ethane

Acetaldehyde
Methyl formate

Ref.

444.6

11

Nonazeotrope

-23.6

II

C F

Wt.%A

-10

II

537

B.P.,C.

Dichlorodifluoromethane -29.8

C C I 2 F 2

B.P.,C.

Helium
4

531 C Hf>
A=

Name

Data

E t h y l acetate
-Butyl alcohol
2"-Furaldehyde
Benzene
"
40 C .
"
760 m m .
"
>1800 m m .
Toluene

76.7
117.75
162
80.1

...

80.1

...

110.7

0.00

78
77.55
73.80
71.22
69.31
76.2
74
90
46.3

v - -1

86.5

261

Nonazeotrope

15.6
20

346

102
102

55
82

Ideal system
84.5
45
80
75.5
Nonazeotrope
18.7
99.28
99.42
51.5
99
64.6
98.46
76
97.7
90
97.0
...
84
65
9
45
9.03
31.22
11.80
41.47
12.48
49.26
12.6'
55.98
88.5
72.3
88.5
72.8
84.3
50.0
73.7
81.6
57
74.8
97.6
76.55
Nonazeotrope
M i n . b.p.
98
Nonazeotrope
Nonazeotrope
M i n . b.p.
. ..
Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

346

v --1
V " -1
v --1

V
V
V
V
V
V

V
V

-1
-1
-1
-1
-1
-1

-1
-1

-1
-1
-1
-1
-1

-1

V
V
V
V

245
184
22
197
132
132
132
132
132
132
132
136
23
10
10
10
10
334
334
108
108,
184
334
136
349
245
107
107
107
245,
309

22

ADVANCES

IN C H E M I S T R Y

-Component
No.

Formula
CS
CH I

Carbon Disulfide
Iodometfrane
1,1 - D i c h l o r o e t h a n e
1-Chloropropane
E t h y l acetate
Ethyl ether

557
558
559
560
561

C 2 H 4 C I 2

C H CI
3

C H 0
C HidO
4

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C H C 1 F

562

563

C 2 H 2 C I 2 F 2

564

C F

565
566

C 1 F

Name

Chlorodifluoromethane
Chloropentafluor 0 ethane
l,2-Dichloro-l,2difluoroethane,
755 m m .
Hexafluor opropene,
2059 m m .
Perfluoropropane,
6.064 a t m .
P r o p a n e , 86.2p . s . i . a .
6.002 a t m .
Perfluorocyclobutane,
2059 m m .
t !

567

C H C 1

568

569
570

C l 2 F

C H C 1

CH 0

Chloroform
Formic acid
Methanol
400 m m .
500 m m .
600 m m .
Tetrachloroethylene
Acetonitrile
Acetic acid
Ethyl alcohol,
20 p . s . i . g .
A c e t o n e , 101 m m .
"
129 m m .
202 m m .
250 m m .
308 m m .
"
455 m m .
"
546 m m .
Methyl acetate

CH 0
4

11

11

11

571
572
573
5-74
575

C 2 C I 4

C H N
2

C H 02
2

C H 0
3

Azeotropic Data
B.P.,C.
46.2
42.55
57.2
46.6
76.7
34.6

11

fl

C H<0

577
578
579

C Hg02

41.2
46
45.2
46.1
34.4

Wt.%A

18.6
94
55
97
1

Ref.

v - -1

116
334
334
334
334

- 4 0 . 8 (-17.1V2059 mm.)
-38.5

-45.6

48.7

15

29.8

-41.4

87.6

96

-6.1

-17.3

69.7

346

12.5

0
0
0

46
68
68.3

261
280
261

.. .

8.6

21.0

61.2
100.75
64.7

...

...
...

121.1
81.6
118.1
101.7

...
...

11

576

B.P.,C.

Nonazeotrope

Dichlorofluoro7.63/723 m m .
methane
1,2-Dichloro-l,1,2,2tetrafluoroe thane,
0.00
2.22
723 m m .

SERIES

...
...
.. .

57.1

...

25

. ..
. ..

88.9
36.3
88.4
41.6
46.2
87.9
Nonazeotrope
Nonazeotrope
Nonazeotrope
82
15
20
30
35
40
50
55
64.74

346

89
74.3
75.0
76.1
76.3
76.7
77.1
77.3
64.35

261

-1
-1
-1
-1
-1
-1

-1

56
31
233
233
233
64
334
56

-1

335
286
286
286
286
286
286
286
31,

V
V
V
V
V

Ethyl formate
2 -Bromopropane
2-Butanone

C H Br
C HeO
3

C HeO
4

580
581
582
583
584

C 4 H 8 O 2

C H
4

C H
6

1 0

1 2

1 2 2

C9H O
10

C H 2 C l B r

585

CH2CI2
C H 2 C I 2

586

14

2-Butanone
Isopropyl formate
Ethyl ether
4 - M e t h y l - 2 -pentanone
Butyl acetate
Ethyl benzoate

54.1
59.35
79.6
79.6
68.8
34.5
115.9
126.2
213.3

Bromochloromethane
Dichloromethane

69
40.7

Dichloromethane
2,2- D i m e thylbutane,
742 m m .

40.0
49.74

87
62.7
62.2
65
Nonazeotrope
17
79.9
70
13
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope

Nonazeotrope

35.6

53 v o l .

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

qc;

195, 252
195, 252
V -1
183,
184
334
195
177
V -1
V -1
157
V -1
63
334

96

235

TABLE

BINARY

SYSTEMS

23
Azeotropic Data

B-Component
No.

A =
587
588

Formula

CH2O2
C2H4O2
C H NO
3

Name

Formic Acid
Acetic acid
N,N -Dimethylf
amide
11

11

589

"
Pyridine

C 5 H 5 N

CH Cl Si
3

590

C H SiCl
3

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

CH3NO2

B.P.,C.

100 m m .
200 m m .
760 m m .

Nitromethane

C
C
C
C
C

Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol
Benzene
Cyclohexane

A =

H
H
H
H
H6

1 0

1 0

1 0

l 0

C6 !2
H

CH
603
604

A =

O
O
O
O

153.0

153.2
158.8
98.5
117.0
158.8
107.43

90'

107.9
153
115.5

Chlorotrimethylsilane

597
598
599
600
601
602

Nonazeotrope

Trichloromethylsilane

Methanol
Acetonitrile, 60 C .
Ethyl alcohol
Acetone, 45 C .
Isopropyl alcohol
Propyl alcohol

178.1

CH 0
C C1 F

607

C2H2CI2

608

C2H2CI2

609
610
611

C2H Cl2

612
613
614
615

C
C
C
C

616

C H 0
C H 0

179

64.51

.. .

78.32

.. .

82.40
97.25
97.15
117.73
99.53
82.41
107.89
80.1
80.75

64.33
12.2
Nonazeotrope
76.05
29.0
Nonazeotrope
79.33
27.6
Nonazeotrope
89.09
48.4
97.99
71.4
91.14
45.8
80.04
21.2
94.46
57.6
12.7
69.5
26.5

v-1
v-1

55
22
55
22
55
135
55
55
55
55
55
343
343

v-1
v-1

268
268

v-1
v-1
v-1

H60
H60
H N
H 0
3

3 62
H

C H NO
C H NO
3

Nonazeotrope
Nonazeotrope

V.p. curve,
azeotrope

302

non

64.7

1,1,2 - T r i c h l o r o t r i fluoroethane
cis-l,2-Dichloroethylene
trans -1,2 - D i c h l o r o ethylene
1,2 - D i c h l o r o e t h a n e
Acetaldehyde
Acetic acid

47.5

39.9

60.3

51.5

15.1

48.3
83.5
20.2
118.1

9.02
41.9
35
59.5
Nonazeotrope
Nonazeotrope

-1

-1

V
V

-1
-1

47
14.8

-1

56.1
108
132
150
57.1

Nonazeotrope
32
102
124
46
140
56
17.7
53.9

-1

107
132
149
131.18
120.25

29
99
34.6
120
40.4
135
Nonazeotrope
Nonazeotrope

it
"
"
"
Methyl

4.4 a t m .
"
7.8 a t m .
"
11.2 a t m .
1 -Nitropropane
2 -Nitropropane

-1
-1

Nonazeotrope

4.56 a t m .
7.82 a t m .
11.6 a t m .
acetate

335

Ethyl alcohol
78.3
Methyl ether
-23.65
A c r y l o n i t r i l e , 1 7 5 m m . 37
A c e t o n e , 752 m m .
...

11

617
618

non

Dichloromethylsilane

Methanol

606

61.4

101.2

Chlorotrimethyl silane, 30-40

v-1
v-1
v-1
v-1

295
210
210
210
210
360

1.2

V.p. curves,
azeotrope

...

Ethane
Propane

56

Methane

C2H.6
C H8

CH^ljSi

A =

v-1

orm-

CH 0
C H N
CaHgO
CaHgO
C H O
C H O
2

Ref.

100.75

591
592
593
594
595
596

B.P.,C. W t . % A

.. .

29
55.07

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

5
5
335
171
205,
285
7, 6 8
130
335
7,
130
192
335
335
335
31,
58
335
335
335
55
55

ADVANCES

IN

B-Component
No.

Formula

CH 0

Name

B.P.,C.

2 -Methoxyethanol
752 m m .
800 m m .
T r i m e t h y l borate
60 p . s . i . g .
"
30 p . s . i . g .
200 m m .
V i n y l acetate

C3H9BO3

11

11

621
622
623
624

C H60
4

C H80

2 -Butanone
Butyraldehyde
e t r a h yd r o fu r a n ,
740 m m .
E t h y l acetate, 40-60

C4H8O
C HeO
4

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

625

626
627

11

C H
4

1 0

628
629
630
631
632

633

C HeO

Methyl propionate
Butyl alcohol, crit.
region

D i e t h y l a m i n e , 740 m m .
Isoprene
3 - M e t h y l -1,2 -butadiene
is -1,3 -Pentadiene
trans -1.3- Pentadiene

^ H g

C5H3

634
635
636
637

1,3-Butadienyl methyl
ether
3-Methyl-1-butene
2 - M e t h y l -1 -butene
2 - M e t h y l - 2 - butene
1 -Pentene

^5 10
5 10
5 10
H

638
639
640
641

CsH
C H
C H

642
643
644
645

^-5 12
C H 0
C H 0
C H

1 0

1 0

1 0

O
O

5 12
H

is-2 -Pentene
2-Pentanone
Isopropyl acetate
2 -Methylbutane

Pentane
A m y l alcohol
2,2 - D i m e t h o x y p r o p a n e
Benzene

...

11

11

646
647
648
649

QHgO

650

C6 12

651
652
653
654
655
656

^6^12

CH

1 0

^6 10
6 10

Q H 1 2 O

C H
6

l z

C6H14

CeHi4

6!

.. .
...
...

72.7
72.6
79.6
74.8

65

76.7
79.7
117.75
54.7
34.3
40.8
44.0
42.0

90.7
21.2
32
37.7
29.92
30.1
37.1
102.2
88.7
27.6

...

36.15
137.8
80
80.1

108
64.7 p.s.i.a.
128
112.7 p.s.i.a.
141
159.7 p.s.i.a.
152
"
209.7 p . s . i . a .
161
259.7 p . s . i . a .
93.3
2,5 - D i m e t h y l f u r a n
72.9
1,3-Hexadiene
82
2,4-Hexadiene
3-Methyl-l,377
pentadiene
C y c l o h e x a n e , <760 m m .
"
<760 m m .
...
"
<760 m m .
...
"
<760 m m .
...
66.4
cis-3-Hexene
94.2
Butyl vinyl ether
116.2
4 - M e t h y l - 2 -pentanone
49.74
2,2 - D i m e t h y l b u t a n e
60.27
2 -Methylpentane
3 -Methylpentane
63.28
"
"

B.P.,C.

Wt.%A

Ref.

64.7

11

620

SERIES

Azeotropic Data

Methanol (continued)

619

CHEMISTRY

Nonazeotrope
Nonazeotrope
54.0
27
100
33
84
29
22
25
58.8
36.6
59.05
36.6
70
64.5
Nonazeotrope

v-1
335
v-1
335
115, 335
335
335
335
335
96
135
v-1
37

59.1
31.1
% alcohol i n
creases with
pressure
62.1
48.6
62.0
50

v-1
v-1

Nonazeotrope

v-1

66.2
29.57
34.7
38.1
36.5
36.5

335
84

40
5.2
8.5
16 v o l . %
15 v o l . %
12.9
v-1

62
57.5
v-1
17.9
4.28
v-1
27.4
8.1
11.2
33.1
v-1
13 v o l . %
26.4
8.92
v-1
26.3
31.8
7 vol. %
Nonazeotrope
v-1
70.2
64.0
24.62
4
24.2
6.98
v-1
7
30.85
v-1
Nonazeotrope
61-62
45
58
38
v-1
1

102
123
138
148
159
61.5
<58
-58

49
54
58
62
65
51
-40
-40

v-1
v-1
v-1
v-1
v-1

-58
-40
27.5
34
30
32.6
31.6
38
42
26.8
26 v o l . %
49.6
52
62
Nonazeotrope
v-1
17 v o l . %
39.6
21 v o l . %
45.6
47.1
20 v o l . %

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

115
228

75,
135
335
324
324
291
291
249
335
249
249
249
291
249
291
135
335
324
249
324
135
201
182,
9 7^

2
27
75
5
275
275
275
335
80
80
80
317
317
317
317
291
335
135
291
291
291

TABLE

BINARY

SYSTEMS

25

B-Component
Formula

No.

CH 0

Methanol (continued)
Hexane

657

6 14

658
659
660
661
662

C H

663

7 16

1 4

It

Butyl ethyl ether


1,1 - D i m e t h o x y b u t a n e
2,2- Dimethoxybutane
Toluene
trans -1,3 -Dimethyl cyclopentane
Heptane
406 m m .
2-Methylhexane
3-Methylhexane
2,2,3 - T r i m e t h y l b u t a n e
-Xylene
2"-Ethyl-2-hexenal
Octane
406 m m .
2,6-Dimethyl-4heptanone
N o n a n e , 406 m m .

6 142
6 142

Name

7 14

Azeotropic
B.P.,C.

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

7
7
7
Q
Ce

16
16
16
10
H 0
1 4

8 18
H

11

670
671

C H
9

C9H20

672

673

674

C H

675

C4H10

676

CH N
C H
4

677

C H

II

D e c a n e , 406 m m .

10 22
H

II

U n d e c a n e , 406 m m .

CH S

Methanethiol
2-Methylpropene,
95 p . s . i . a .
2-Methylpropane

Methylamine
Butadiene
"
5 atm.
20 a t m .
1 - Butene
"
5 atm.
"
20 a t m .

90.77
98.4
9!5
91.85
80.88
138.35
176
125.75

...

169.4

...

150.7

...

171.8

...

26.4
49.5
50.57
28
56
62.6
Nonazeotrope
64.5
81.5
70.8
63.6
57.3
45 v o l .
58.8
46.1
43.83
44 v o l .
57.1
44 v o l .
57.6
38 v o l .
54.1
64.0
5
Nonazeotrope
67.5
62.75
47.65

C C1F

Chloropentafluoroethane
1,1 - D i f l u o r o e t h a n e

678

C2H4F2
C2Cl2F

679

C4H10
C2G13F3

680

C2C14F2

681
C2C1
682
683
684
685

686
687
688
689
690

C2H3CI3
CaHgO

C3H3O
C4H10O
C2HCI3
C2H4CI2
C2H4O2
C3H6CI2
C.HgO
C He0
4

Ref.

v-1
%

175
324
335
334
201
202
291
174
366
291
291
291
84
334
174
366

%
%
%

Nonazeotrope
48.93
83.4
64.1
Nonazeotrope
Nonazeotrope
Nonazeotrope

v-1

334
366
174
366
249
366

6.00

...

-11.70

53
-13.00

19.5
4.9

145
21

-6

.. .

20
20
20
20
20
20

58
74
96
50
64
74

11

Wt.%A

64.7
68.95
68.95
92.2
114
106-7
110.7

11

664
665
666
667
668
669

B.P.,C.

Data

...
-38.5
-24.7

-41.3

1,2-Dichlorotetrafluoroethane
Butane

-0.5

-2.2

1,1,2-Trichlorotri-

47.5

fluoroethane
1,1,2,2 - T e t r a c h l o r o difluoroethane
Ethyl alcohol

92.4
78.3

83.8

198

59

102

Nonazeotrope
96.2
43.8

Tetrachloroethylene
1,1,2 - T r i c h l o r o e t h a n e
Acetone
Isopropyl alcohol
Butyl alcohol

121.1
113.65
56.1
82.3
117.7

112.9
26
Nonazeotrope
19
81.7
110
68

Trichloroethylene
1,2 - D i c h l o r o e t h a n e
Acetic acid
1,2 - D i c h l o r o p r o p a n e
2-Butanone
Ethyl acetate,
700-760 m m .

86.2
83.45
117.9
96.3
79.6

39
82.2
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

96, 334
335

v-1

197
64
334
334

197
334
334
184
v-1

274

26

ADVANCES

IN

B-Component
Formula

No.

C H
C H
2

691

Name

11

692

C H
2

"
Ethane

B.P.,C.
-84
103.7

Crit. press.
- 3 5 , 0 , 40 F .

.. .

-88.3

Crit. press
-35, 0, 4 0 F .
Propyne, -50 to 35 C .

C H
3

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C ^ C l ,
694
695
696
697
698
699
700
701

CaHgO
CaHgO
C3I5O2

^30
C HeO

C H2C1
2

702
703
704
705
706
707
708
709

CsHgO
C 3 H 6 O

H g 0

C HeO
C HeO
4

C H C1
C H C1
2

710
711

is-1,2-Dichlor 0 ethylene
Ethyl alcohol
Acetone
Ethyl formate
M e t h y l acetate
Methylal
2 -Butanone
Tetrahydrofuran
Isopropyl ether

C H C1
C H C1

.. .

Nonazeotrope

v-1
v-1

293
293
137
293
293
137
28

Calculated
61.9
73
Nonazeotrope
61.7
73
Nonazeotrope
Nonazeotrope
69.8
44.5
Nonazeotrope

v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1

5
5
5
5
103
5
103
103

Calculated
Nonazeotrope
Nonazeotrope
Nonazeotrope
48.6
79.3
Nonazeotrope
Nonazeotrope
Nonazeotrope

v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1

5
5
5
5
103
5
103
103

18
19
v-1
'. ! !

78.3
56.4
54.0
57.2
42.6
79.6
66.1
68.0

trans - 1 , 2 - D i c h l o r 0 ethylene
Ethyl alcohol
Acetone
Ethyl formate
M e t h y l acetate
Methylal
2-Butanone
Tetrahydrofuran
Isopropyl ether

78.3
56.4
54.0
57.2
42.6
79.6
66.1
68.0

Vinyl Chloride
1,2 - D i c h l o r o e t h a n e
Acetone

83.5
56.1

Nonazeotrope
Nonazeotrope

334
334

74.1
113.9
57.4

Nonazeotrope
Nonazeotrope

96
96

48.35

13.4

C 2 H 4 C I 2

C H F 0
CgHgO

2,2,2-Trifluoroethanol
Ethyl alcohol

...

714

Acetonitrile
715
716
717
718

C^H^Cla
C H3N
CaHgO
C H NO

81.55
83.15
77.1

719
720
721
722
723
724
725
726

5 12
C6H
C H N

7 16
Q 18
CHJJO
C

Qo 22
C H
H

C H
2

8 10
CeHio
C

Ethylene

78 .*3

...
153

.. .

65

...

134
98.4
125.75
150.7
173.3
195.4

1,2 -Dibromoethane
m-Xylene
-Xylene

81.75

226

57.65

-79.1
49
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
58
13
45
30.7
Nonazeotrope
69.55
76.7
79.82
81.45
Nonazeotrope

v-1
v-1

v-1
v-1

267
334
25
334
334
334
22
247
368
368
368
368
368

103.7

Ethane, -35, 0, 40 F . -88.3


" 0, -40, -100 F . ...

C H Br
728
729

1,2 - D i c h l o r o e t h a n e
Acrylonitrile
Acetone, 45 C .
, - D i m e t h y l f o r m amide
"
100-500 m m .
Pentane, 24 p . s . i . g .
Benzene, 278 m m .
2-Picoline
Heptane
Octane
Nonane
Decane
Undecane

C H
72 7

39*
44

60.3

1,1,1-Trichloroethane
1,1,2 - T r i c h l o r o e t h a n e
1,1 - D i c h l o r o e t h a n e

712
713

Ref.

B.P.,C. W t . % A

11

693

SERIES

Azeotropic Data

Acetylene
Ethylene

CHEMISTRY

131.5
139
138.4

...

...

Nonazeotrope

Nonazeotrope
131.0
94

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v-1
v-1

137
129

113
113

TABLE

BINARY

SYSTEMS

27
Azeotropic

B-Component
Formula

No.

730
731
732
733
734
735

C2H4CI2
C3I6CI2
CaHeO

C4H8CI2O
C H
C6H
C H
6

1 2

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C2I4O
736
737

C H C1
C H<p

738
739
740
741
742

C^HgOz

743

C4H8O
C4H

1 0

C H

Name

1,2-Dichloroethane

Acetaldehyde
Chloroethane
Propylene oxide,
35 p . s . i . g .
V i n y l acetate
Ethyl vinyl ether
Butane
Ethyl ether
Isopropyl ether

Ethylene Oxide

C2H4O2

Acetic A c i d

C H Q

745
746

C H<p
C H O

747
748
749
750

C H60

751

C H

752

C H N

C4H3O2
C4H3O2
C H9NO
4

760
761

C H

Nonazeotrope
119.4
79.5
Nonazeotrope

Pyridine

115.5
345
88.7
36.15
134
68.7
68.60
68.3
143.41
144

II

II

762
763
764
765

CHi 2

Cumene
Nonane

152.8
150.2
150.2

^10 16

C a m p h e n e , 100 m m .
Decane

C9H20
H

C H 2
1 0

II

769

CiiH

2 4

C 1 2 H 2 0 O 2

C12H26
C2H5CI
C4H10

Undecane
II

Isobornyl
Dodecane

.. .

173.3
173.3

II

767
768

165
117.1

98.25

Heptane

II

766

76.7

143.6
125.75

8 18

334

22

139.9

o-Xylene
Octane

-6.5

Acetic anhydride
-Dioxane
Ethyl acetate
N,N-Dimethylacetamide
Butyl alcohol

II

7 16

10.5

v-1
v-1

334
96
334
334
243
334

Ideal s y s t e m
Nonazeotrope

759

Nonazeotrope
Nonazeotrope
Nonazeotrope
-7
16
18.9
76.5
Nonazeotrope

140.7
97.25

Isopropyl ether
2,6-Lutidine

96

Propionic acid
Propyl alcohol

C Hi 0
^

73
72.5
35.5
-0.5
34.5
68.3

9.5

11

v-1

757
758

C H N

12.3

Nonazeotrope

C Hu

C5H12

334
334
334
235
235
235

118.1

alcohol

Crit. press.
Isopropyl acetate
Pentane
2-Picoline
Hexane

C 5 H 1 0 O 2

Nonazeotrope
72.7
60.8
Nonazeotrope
80.1
15 v o l . %
74.7
38 v o l . %
73.7
35 v o l . %

78.3

Ethyl

11

753
754
755
756

Ref.

Wt.%A

20.2

-0.5

Butane

B.P.,C.

83.65

96.3
1,2 - D i c h l o r o p r o p a n e
82.3
Isopropyl alcohol
B i s (2 - c h l o r o e thyl) e ther 1 7 9 . 2
80.1
Benzene
Cyclohexane
80.75
80.8
2,4- Dimethylpentane

C2H4O
C4H10

744

B.P.,C.

Data

acetate

Chloroethane
-Butane
"
738.6 m m .

194*5
194.5
225.8
216

205,
285
48
205,
285
334
180
334

295
205,
285
373
138.1
51.1
323
348
20.2
Nonazeotrope
334
Nonazeotrope
187
144.12
40.4
369
334
Nonazeotrope
187, 189
68.25
6.0
334
Nonazeotrope
v-1
358
147.28
24
364
148.1
22.9
370
162.3
19.5
187, 189,
91.7233
355, 373
372
116.6
78
105.7
53.7
v-1 189,
355, 359
76
116
84
112.8
69 187, 189, 355
324
113.25
69.6
v-1
294
60.6
90
116.75
79.5
187,
189, 355
324
117.2
79
v-1
358
116.10
87
117.72
95 187, 189, 355
324
117.17
78
v-1
294
Ideal system
Nonazeotrope
187
170.8
120.3

21.1
43

v-1

12.4
-0.5
-0.5

-1.4

15.6
20.2

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v-1

255
263

ADVANCES

28

IN

Azeotropic

B-Component
No.

A =

Formula

C H C10
2

770

C ^ C I O

7 7 1 C4H8CI2O

Name

B.P.,C.

2-Chloroethanol

7 7 2 C4H8O2
773

2-Chloroethyl vinyl
ether, 120 m m .
Bis(2 -chloroethyDether,
50 m m .
96
179.2
-Dioxane
101.3

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

A =

C2H5NO
11 10

Acetamide

C2H5N02

Nitroethane

774
775
776
777
778
779
780

C HeO
C HeO
C4H10C
C H p
C H p
C H O

781

C Fi

782

C HeO
CaHgO

A =

1 (

1 (

l 0

Ethyl alcohol
Isopropyl alcohol
Propyl alcohol
Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol

Ethyl Alcohol

C3H7NO2
C3H7NO2
CsHeO
C H O

1-Nitropropane
2-Nitropropane
Isopropyl alcohol
2 -Butanone

787
788
789

C H 0
C H 0
C H 0

Butyraldehyde
Ethyl vinyl ether
-Dioxane, 200 m m .
400 m m ,
600 m m .
760 m m .
E t h y l acetate, 40-60 C.

It

11

11

11

790

C H 0
4

"
"

791
792
793
794
795
796
797
798
799
800
801
802
803
804

QHKP
C4HKP
C4H10O2
C4H11N
Q H 1 1 N

C5HA
C5H10
CSHKP
C5H10O
C5H10O
CAP
CsH 0
C Hi 02
12

241.1

114.07
78.32
82.40
97.15
117.75
99.53
82.41
107.89

55.62

14

341
334
334
334

Nonazeotrope
Nonazeotrope
Nonazeotrope

...
78.03
81.82
94.49
107.94
97.16
82.22
102.68

55

98

12.6
10.6
31.8
58.6
27.6
4.5
40.8

55
55
55
55
55
55
55

77.4 m m .
760 m m .

131.18
120.25
82.3
79.6
79.6
75.7
35.5

.. .
...
...
...
...
...

II
77.05
117.75
Butyl alcohol
sec-Butyl alcohol
99.4
134
2-Ethoxyethanol
Butylamine
77.8
Diethylamine
55.5
E t h y l a c r y l a t e , 1 0 0 m m .4 4 . 9
31.10
2-Methyl-1-butene
Isopropyl vinyl ether,
737 m m .
54.8
102.35
2-Pentanone
Propyl vinyl ether
65.1
A m y l alcohol
137.8
Butyl methyl ether
70.3
80
2,2 - D i m e t h o x y p r o p a n e
Benzene, 310 m m .
...
180 m m .
400 m m .
...
168.4 m m .
...
233.5 m m .
"
336.4 m m .
...
"
584 m m .
...
209 m m .
80.1
760 m m .
11

11

11

11

11

11

Nonazeotrope

v-1

155

Nonazeotrope

v-1

7,
134
55
55
116
134
334
335
334
124
124
124
124
228

78.3
56.4

Acetone

783
784
785
786

Ref.

B.P.,C. W t . % A

222

P e rfluo roheptane,
crit. region

Data

Ethane

C H6
7

2 -Methylnaphthalene

SERIES

128.7

11

A =

CHEMISTRY

Nonazeotrope
78.28
93.6
v-1
Nonazeotrope
v-1
74.0
39
74.8
34
70.7
60.6
Nonazeotrope
v-1
46.4
68
62.4
82
72.19
88
78.25
>98
% A l e . increases v-1
with press.
15.95
...
30.97
72.18
25.8
Nonazeotrope
v-1
Nonazeotrope
v-1
v-1
Nonazeotrope
82.2
49 .
Nonazeotrope
32
54.4
30.1
22 v o l . %
52.6
78
93.3
60
18.4
Nonazeotrope
65.5
20
Min. b.p.
45
26.2
32.5
23.2
51.2
28.1
29.97
21.33
38.37
23.72
47.15
26.32
61.06
30.35
35.0
24.3
67.9
31.7

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v-1
v-1

v-1
v-1
v-1
v-1

v-1

117
117
228
134
134
335
335
334
335
291
334
134
334
134
334
201
22
240
240
328
328
328
328
256
191,
344

TABLE

BINARY

SYSTEMS

29
Azeotropic

B-Component
Formula

No.

C H 0
2

804

805
806
807
808
809
810

C H6
6

C H N
C Hio
6

CHIO

C Hio
QHio
6

1 2

Name

B.P.,C.

Ethyl Alcohol
(continued)
B e n z e n e (continued)
"
5570 m m .
"
11,720 m m .
"
19,160 m m .
Aniline
1,3-Hexadiene
2,4-Hexadiene
3 -Methylcyclopentene
3-Methyl-l,3pentadiene
C y c l o h e x a n e , 296 m m .
420 m m .
643 m m .
"
760 m m .
"
760 m m .
2-Ethyl-1-butene
1 -Hexene
cis-2-Hexene
cis- 3-Hexene
Methylcyclopentane
cis-3-Methyl-2-pentene
trans-3-Methyl-2pentene
trans-4-Methyl-2pentene
Butyl vinyl ether
Isobutyl vinyl ether
Paraldehyde
Hexane
"
1545 m m .
2 - Methylpentane
Ethyl butyl ether
Isopropyl ether
1,2- D i e t h o x y e t h a n e
Triethylamine
Toluene

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

11

C H

818

C H

819
820
821
822

C H 0
C H 0

823
824
825
826
827
828

C H

H i 2

H i 2

H i 2

C
C

1 2
H i 2

1 2

1 2

1 2

l P 3
C Hi
C

QH140
c ^ p
C

C H
C H

l P 2

1 5

...
...
184.35
72.9
82
64.9
77

.. .
..
64.95
63.49
68.8
66.4
72.0
70.52
67.6
58.4
94.2
83.4
124.5
68.95

...

60.27
92.2
68.3
121.1
89.7
110.7

327 m m .
800 m m .
1,3-Heptadiene
2,4-Heptadiene
1,1-Dimethylcyclo87.85
pentane
cis-1,2 -Dimethyl 99.53
cyclopentane
trans -1,2 - D i m e t h y l 91.87
cyclopentane
cis -1,3-Dimethyl91.73
cyclopentane
trans -1,3 -Dimethyl 90.77
cyclopentane
2 , 3 - D i m e t h y l - 1 - pe nte ne 84.2
103.47
Ethylcyclopentane
1,1,2,2- Te tr amethyl 75.9
cyclopropane
79.20
2,2 - D i m e t h y l p e n t a n e
89.78
2,3 - D i m e t h y l p e n t a n e
80.50
2,4-Dimethylpentane
86.07
3,3- Dimethylpentane
93.47
3 -Ethylpentane
98.4
Heptane
11

...
.. .
.. .

11

829
830
831

7 1 2
C H i 2

832

833

7 14

834

C H
7

835

C H

836
837
838

C H
C H u
C H

839
840
841
842
843
844

C H
7

H u

7 16
C H
C

7
7
7
C

16
16
16
H

11

180

Wt.%A

Ref.

132.9
166.9
191.1

56
69.5
81

M i n . b.p.
M i n . b.p.
57.2

...
20 v o l . %

256
256
256
138
80
80
291

M i n . b.p.
41.2
49.3
60.8
64.8
64.9
57.0
56.1
59.5
49.6
60.05
60.4

25.5
27.3
29.8
31.3
40
23 v o l .
22 v o l .
22 v o l .
26 v o l .
22.7
24 v o l .

B.P.,C.

78.3

11

811
812
813
814
815
816
817

Data

mm.

...

.. .

58.8

v-1

%
%
%
%
v-1
%

20 v o l . %

80
316
316
316
316
147
291
291
291
291
304
291
291

15 v o l . %
291
52.6
335
48
73
33
335
69.2
Nonazeotrope
334
20.8
v-1
304
58
26.3 v o l . % 251
2
91
12 v o l . %
53.1
73.8
49.3
335
17.1
335
64
Nonazeotrope
334
76.9
51
335
66.7
v - 1 138,
76.5
191
117
76.2
117
81.6
80
M i n . b.p.
M i n . b.p.
80

. .

.. .

68.0

3 7 vol. %

291

72.1

46 v o l . %

291

69.6

39 v o l . %

2-91

69.5

38 v o l . %

291

69.1
67.1
73.1

37 v o l . %
35 v o l . %
48 v o l . %

291
291
291

62.6
63.9
68.6
64.6
67.1
70
72

30
25
34
29
38
38
48

37.5

43

vol.
vol.
vol.
vol.
vol.
vol.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

%
%
%
%
%
%
v-1
239,
v-1

291
291
291
291
291
291
138,
335
158

ADVANCES

30

IN

B-Component
No.

844

Formula

Name

Ethyl Alcohol
(continued)
C

7 16

11

11

845
846
847

8 16

849

8 16

850

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

^7 16
7 16
C8 16

848

C8 16
H

851

8 16

852

8 16

853

8 16

854

8 16

855
856
857
858
859
860
861

C
C
C
C
C
C
C

862

C Hi

863

864

C Hi

865
866

CeHieO

8
8

H
H
H
Hi
H
H
H

1 8
1

8 18
H

8 182
H

C H60S
2

867

C H6

C H 0

C H 0

869

Dimethylsulf oxide
Benzene,

868

C ^ C i p

25-70

Ethylene G l y c o l

872

C He02
C H30
4

carbonate,
10 m m .
"
25 m m .
"
50 m m .
"
72 m m .
Bis(2-chloroethyl)
ether, 50 m m .

C5H12O3

2 -Vinyloxyethanol
Ethylene glycol
monoacetate
"
150 m m .
2 -(2 -Methoxyethoxy)
ethanol
50 m m .
"
200 m m .
Aniline, 37.1 m m .
"
104.7 m m .
"
257.9 m m .
11

873

C H N
6

B.P.,C.

B.P.,C.

Data

Wt.%A

Ref.

78.3

. .
...

90.05
91.85

54.5
71.0
68.7
69.3

43
45
36 v o l .
36 v o l .

119.54

76.2

65 v o l . %

291

124.32

76.9

70 v o l . %

291

124.45

76.9

70 v o l . %

291

119.35

76.2

64 v o l . %

291

121.52

76.5

66 v o l . %

291

117.5

75.9

62 v o l . %

291

109.29

74.3

52 v o l . %

291

104.91
106.84
115.61
117.73
117.65
118.93
117.71

73.9
73.6
75.5
75.8
75.8
76.0
75.8

50
46
57
60
59
61
61

%
%
%
%
%
%
%

291
291
291
291
291
291
291

109.84

74.3

53 v o l . %

291

99.24

71.8

40 v o l . %

291

114.76

75.3

56 v o l . %

291

113.47
142.1

57 v o l . %
75.1
Nonazeotrope

291
334

243.1

Nonazeotrope

334

V.p.

164

...
...

vol.
vol.
vol.
vol.
vol.
vol.
vol.

curve

v-1
v-1
%
%

158
158
291
291

197.4

Ethylene

It

870
871

Azeotropic

SERIES

Heptane

(continued)
400 m m .
750 m m .
2 -Methylhexane
3 -Methylhexane
1,1 - D i m e t h y l c y c l o hexane
cis -1,4 - D i m e t h y l cyclohexane
trans -1,3 - D i m e t h y l cyclohexane
trans -1,4 - D i m e t h y l cyclohexane
1-Ethyl-l-methylcyclopentane
l,cis-2,trans-3Trimethylcyclopentane
l,trans-2,cis-4Trimethylcyclopentane
2,4,4-Trimethyl2-pentene
2,2- Dimethylhexane
2,3- Dimethylhexane
3,4- D i m e thylhexane
2 -Methylheptane
3 - Methylheptane
4 -Methylheptane
2,2,3-Trimethylpentane
2,2,4-Trimethylpentane
2,3,3-Trimethylpentane
2,3,4-Trimethylpentane
Butyl ether
2-Ethyl-l,3hexanediol

CHEMISTRY

...
...
96
178.6
143

..
...
194
115
151

...
...
...

88
107
122
163

13.9
7.5
2.6
0

262
262
262
262

92.7
164

...
17.8
13

335
60
94

Nonazeotrope
Nonazeotrope

147
147

...

...

114
149
95
120
145

30
4
12
8.75
12.7
16.8

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

284, 335
335
335
59
v-1
59
v-1
59
v-1

TABLE

BINARY

SYSTEMS

31
Azeotropic

B-Component
No.

Name

Formula

C2H5O2
874

CgHiP

875

C H
6

1 4

Ethylene G l y c o l
(continued)
Hexyl alcohol
2 -(2 -Ethoxyethoxy)
ethanol

"
11

876
877
878
879

B.P.,C.

Q H e
C HaO
C HeO
C HoN
7

100 m m .
36 m m .

Toluene
Benzyl alcohol
o-Cresol
-Methylaniline,
31.8 m m .
"
95.3 m m .
244 m m .
-Xylene
,N -Dimethylaniline,
39.3 m m .
115 m m .
293 m m .
s-Collidine
B u t y l ether
2 - (2 - B u t o x y e thoxy)
ethanol
2 -Diisopropylaminoethanol, 10 m m .
50 m m .
100 m m .
Phorone
Naphthalene
2 -Hexylthioethyl
vinyl ether
Tripropylene glycol
methyl ether

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

CgH^o
C H N
8

Nonazeotrope

202.8
137.3
110.6
205.2
191

192
134
108.5
110.1
193.1
189.52

45.5
33
26.6
2.3
56
26

284, 335
335
243
335
60
188

22.9
26.6
30.0
6.9

v-1
v-1
v-1

144*4

95
120
145
135.7

17.6
21.8
26.5
9.7
6.4

v-1
v-1
v-1

171.3
142.1

95
120
145
170.5
139.5

230.6

M i n . b.p.

79
111
127
197.8
217.9

74
104
121
184.5
183.6

11

C H
CeH
C H

885

C H

1 8

N
0
0

NO

1 9

11

11

A =

886
887
888

CoH 0
CioH
Cj()H oOS

889

CXQH220

890

Ci2H

891
892
893

Ci H 0
Ci Hio
C H Q

2 6

1 6

3 4

CgH^S

8 9 4 C5H10
895

A =

1 4

C H
5

C 5 H 1 0

897

C 5 H 1 2

898
899

C H
C H
5

C2H6S2
900 C s H ^
9 0 1 C5H12S
902
C H
903
C H
904
C H
905
CeH
7

1 6

906
C8H
907 Q H

A =

1 8

C H N
2

Hexyl ether, 50 m m .
Anthracene
2-Ethylhexyl ether,
10 m m .

Methyl Sulfide
Cyclopentane
2 - M e t h y l - 2 -butene
2 -Methyl -1 -butene
2 -Methylbutane
Pentane
2,2- Dimethylbutane

896

Phenyl ether, 50 m m .

908 C ^ ^ N O

Methyl Disulfide
2 -Methylthiophene
Ethyl isopropyl sulfide
Toluene
Methylcyclohexane
Heptane
trans-1,3 -Dimethyl cyclohexane
2,3 - Dimethylhexane
2 -Methylheptane

Dimethy lamine
2 - (Dimethylamino)
ethanol

334

157.1

11

882
883
884

Ref.

Wt.%A

197.4

11

880
881

B.P.,C.

Data

59
59
59
188
334, 335
284
335
335
335
59
147

10
15
18
42
46

329

M i n . b.p.
243

i'o
259.3
137.0
340
135

192
138.5
111.5
120.4
192.3
112.8
197

59
59
59
335

82
77.2
75.1
62.3
64.5
35.6
98.3

v-1

76
76
76
335
59
335
305
335

87

37.32
87.5
53.6
17.0
25.0
46.6
79.8

70
70
70
70
70
70

111.92
107.22
110.85
101.05
98.40

Nonazeotrope
106.37
108.93
98.92
28.6
26.3
96.44

. ..
...

70
70
70
70
70

120.30
109.15
117.70

107.22
102.84
106.22

73.3
48.2
69.5

70
70
70

49.35
38.60
31.25
27.90
36.15
49.70

37.09
34.83
30.64
26.62
31.80
36.50

109.44

7.4
134.6

Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

334

32

ADVANCES

IN

B-Component
No.
A=

909
910

A=

C 4 H 1 1 N

C4H11NO2

A=

C^O
C H

N 0

C H N
C4H8
C HKP
2

913
914
915
916
917

Acetone
2,2-Iminodiethanol,
10 m m .
Ethylenediamine
p-Dioxane
Butyl alcohol
Isobutyl alcohol
Benzene
Toluene

C 4 H K P

CH
C H
8

C3UF 0

A =

Diethylamine
2,2'-Iminodiethanol

2-Aminoethanol

Name
Ethylamine

C2H7NO
911
912

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula
C H N

CHEMISTRY
Azeotropic

B.P.,C

B.P.,C.

SERIES

Data

Wt.%A

Ref.

16.6
55.5

Nonazeotrope
Nonazeotrope

334
334

Nonazeotrope

334

Nonazeotrope

334

Nonazeotrope
124.7
35.7
120.5
50
Nonazeotrope
104
30.8
103
30

334
335
335
334
76
334

171.0
56.1
150
116.9
101.3
117.7
107.9
80.1
110.7

Pentaf luoropropionic

Acid
918

A=

C6F14

P e r f l u o r o h e x a n e , 25 C .

CsHaClFaOj^
919

C H NO
3

C H F 0

A=

920

A =

C3H NO
7

. . .

3-Chloro-2,2,3trifluoropropionic A c i d
N,N, -Dimethylforma m i d e , 20 m m .

Nonazeotrope

115-120

2,2,3,3-Tetrafluoropropionic A c i d
N,N-Dimethylforma m i d e , 20 m m .

v-1

237

...

93

67

93

101-106

...

93

91-4
187

66
...

93
93

40

C3H3CIF3NO 3-Chloro-2,2,3921

A=

trifluoropropionamide
,-Dimethylf o r m a m i d e , 20 m m .

C3H NO
7

C3H3F4NO
922

A=

CjHyNO

C3H3N
923

A =

C H5N

A =

C 3 H 6
C 3 H 8
4

C H
C H
C3H
C H

928
929
930

A =

C3H4CI4
931

A =

C H C1
5

A =

C H 0
C H
3

932

0 3 ^ 0 2

933

C H 0
s

.. .
153

Acrylonitrile

77.2

Propadiene

C 3 H 4

C H

propionamide
,N - Dimethylf or m a m i d e , 20 m m .
"

Propionitrile

C3H4
924
925
926
927

2,2,3,3-Tetrafluoro-

97.4

Nonazeotrope

334

-32

Propyne
Propene
Propane
1,3-Butadiene

-23.2
-47.7
-42.1
-4.5

Nonazeotrope
Nonazeotrope
-42
11.6 v o l . %
Nonazeotrope

334
334
334
334

Propyne
Propene
Propane
1,3-Butadiene

-23.2
-47.7
-42.1
-4.5

Nonazeotrope
-42
11.7 v o l . %
Nonazeotrope

334
334
334

Nonazeotrope

250

Tetrachloropropane
Tetrachloropentane,
12-150 m m .
2-Propyn-l-ol
Benzene

115
80.1

Acrylic Acid
Ethyl acrylate

141.2
99.3

78

v-1

Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

95

334

TABLE

BINARY

33

SYSTEMS
Azeotropic Data

B-Component
No.

A =

Formula

C3H5CI
934

A =

3-Chloropropene
2 -Chloropropane

C^Cl
C H C10
3

9 3 5 C5H7CIO
A =
936
A =

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

. . .

10

341

Propene
Propane, 10--190F.

-48
. . .

Nonazeotrope

v - 1 128

Nonazeotrope
Nonazeotrope

334
334

C^O

939

C H 0

940

CaHgO
C H80

1.2- Dichlor opropane


Propylene oxide,
20 p . s . i . g .
1.2- P r o p a n e d i o l

96.3
60
187.3

Acetone
Isopropyl alcohol

56.5
82.3

Nonazeotrope

Nonazeotrope
Nonazeotrope

v-1

941
C H 0
942
C H 0
943 C ^ C l
4

Diketene
V i n y l acetate
1 - Chlor - 2- methyl propene
2 -Butanone,
15-500 p.s.i.a.

C HgO
4

CgHgOjj

946 C5H10
947
948

C H
C H

949

1 0

C H

C H

951
952

C H
C H

953
954
955
956
957

C
C
C
C
C

958
959

C H60
0
C HaO

960
961
962
963

CsHeOi
C H
C H
C H 0

H
H
H
H
H

1 2

1 2

Cyclohexane

0
0

1 2

1 4

72.7
68

1 4

964

C H50

965

CsHgO

966

C H60
C H O

967
968

C H 0
C H
C7H

A l l y l acetate
Cyclohexane
Hexane
Isopropyl ether

55.6

96.5
29.97
88.7
36.15

...
.. .

80.1
80.75
80.75
72.0
52.6
1 11155 . 99
126.2
58.0
68.95
98.4
96.6
82.3

8.*8
68.8
68.3

Propionaldehyde
Propylene oxide,
30 p . s . i . g .
2-Methylfuran

48.7

Propylene Oxide
Ethyl ether

35
34.5

69
63.7

45,
46
334
334
241

81

Nonazeotrope

67*4

CsHgO

Methylcyclopentane
1,1,2-Trimethylcyclopropane
4-Methyl-2-pentanone
B u t y l acetate
2.3- Dimethylbutane
Hexane
Heptane
A l l y l Alcohol
Isopropyl alcohol
A l l y l vinyl ether

Isopropenyl acetate
1 - Pentene
Isopropyl acetate
Pentane
"
<100 m m .
Benzene, 45 C .
it

950

A=

83

C H

938

A =

v-1

v - 1 337

A=

Nonazeotrope

Ref.

Nonazeotrope

C&Cl

A =

W t . % A

116.45
156.85

A=

945

45.15
34.9

B.P.,C.

Epichlorohydrin
1,2,3-Trichloropropane

944

2-Chloro-2-propen-l-ol
2-Chloroallyl vinyl
ether

B.P.,C.

CsHgClO
C H C1

9 3 7 C3H8

A =

Name

v-1

Nonazeotrope
28.9
19 v o l . %
Nonazeotrope
32.5
20
Nonazeotrope
Nonazeotrope
v-1
Nonazeotrope
v-1
v-1
53.0
67.5
67
57
42.3
32 v o l . %
v-1
Nonazeotrope
Nonazeotrope
v-1
46.5
256,
49.8
59
89.5

254,
334
147
291
334
131
131
23
36
186
256
256
291
157
63
256
334
256

5
63
58
12.5
Nonazeotrope

172
341
334
1
147
176
334

Nonazeotrope
Nonazeotrope

334
270

Nonazeotrope
66.6
95.1
74.0

32.6

10

49.6

v-1

243

1 0

1 6

1.3- Dioxolane
Toluene
Heptane

75.6
110.6
98.4

Nonazeotrope
72.3
81

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

334
334

ADVANCES

34

IN

Azeotropic

B-Component
No.

1,3-Dioxolane
(continued)

=
969
970

CgHxgO
C H o

Butyl ether
Nonane

C H 0

Ethyl Formate

971

C H Br

972
973
974
975
976
977
978
979
980
981
982
983
984
985
986
987
988
989
990

C H Br
CsHejO
C H
C H
C H
C H
CeHg
C H
C H

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Name

Formula

C H 0
3

991
992
993
994
995
996
997
998
999
1000
1001
=

2 -Bromopropane

Methyl Acetate

2 -Bromopropane
2-Methylfuran
Cyclopentene
Cyclopentane
1 -Pentene
Pentane
Benzene
1,3-Cyclohexadiene
Cyclohexene
Cyclohexane
2,3-Dimethyl-1-butene
2,3- D i m e t h y l - 2 - butene
3,3-Dimethyl -1 -butene
2-Ethyl-1-butene
1 -Hexene
cis-2-Hexene
3 - M e t h y l - 2 -pentene
4 - M e t h y l -1 -pentene
trans-4-Methyl 2-pentene
Methylcyclopentane
2,2 - D i m e t h y l b u t a n e
2.3- Dimethylbutane
Hexane
2-Methylpentane
3 -Methylpentane
2.4- Dimethylpentane
Heptane
2-Methylhexane
3 - Methylhexane
2,2,3 - T r i m e thylbutane

Q 12
C Hi
Q H
CeHi
CHi
Q H
C6H
Q H
Q H i
Q H
H

1 2

C H
Q>H
C6H
6

1 4

1 4

Q>H
Q
Q H
Q H
C Hi
C H
C H
H

1 4

C H 0
3

1002
1003
1004

C H60
CgHgN

1005
1006
1007

Q H u
Q H

C5H11NO
1

8 18
H

Propionic A c i d
Acetic anhydride
Pyridine
N,N-Dimethylpropionamide
Hexane
Heptane
Octane
M

"
1008
1009

C9H20

1010

C n H

=
1011
1012

CioH

Nonane
Decane
Undecane

2 2

C H<s0
3

C H
8

8 10

6 12

=
1013

A =
1014

Satd. with N a
propionate

Methyl Glycolate
Ethylbenzene
m-Xylene

s-Trioxane
H

C H C10
3

CgH^C^O

Cyclohexane

Propylene Chlorohydrin
Bisfchloroisopropyl)
e t h e r , 100 m m .

CHEMISTRY

] .P.,C.

B.P.,C.

SERIES

Data

Wt.%A

Ref.

75.6
.42.1
.50.8

334
334

Nonazeotrope
Nonazeotrope

54.1
59.35

53.0

59.4

195,

252

56.95
59.35

.. .

44.4
49.3
30.1
36.08
80.1
80.25
83.1
80.6
55.62
73.38
41.4
64.8
63.58
68.55
70.64
54.0
58.45
71.8
49.65
58.05
68.85
60.2
63.25
80.7
98.45
90.0
91.85
80.9

14.5
55.6
Nonazeotrope
27.7
41.7
37.9
43.2
30.0
3.3
22
34.05
99.7
56.7
98.0
56.7
90.2
56.5
83.0
54.9
42.8
48.95
71.8
55.1
39.9
8.8
60.1
52.8
63.6
52.5
69.8
53.7
73.7
54.45
36.7
48.3
50.0
53.0
43.7
48.0
51.75
49.25
50.05
54.7
56.65
56.0
56.3
55.1

195
270
126
126
126
126
126
126
126
126
126
126
126
126
126
126
126
126

51.3
68.0
38.2
48.25
60.7
51.6
57.4
72.4
96.45
88.6
84.9
74.2

126
126
126
126
126
126
126
126
126
126
126
126

140.7
138
115.5

Nonazeotrope
67.2
148.6

175.5
68.85
98.15
125.12
125.12

...

179.3
23.6
Nonazeotrope
2.0
97.82
24
120.89
24.2
...
6
.. .

150.67
174.06
193.85

134.27
54
80.5
139.76
Nonazeotrope

151.2
136.15
139

M i n . b.p.
M i n . b.p.

...

v-1

v-1
v-1

250
370
295
189
189
189
154
154
189
189
189

52
52

114.5
80.75

M i n . b.p.

52

73/100
121.9

Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

334

TABLE

BINARY

SYSTEMS

35
Azeotropic Data

B-Component
No.
=
1015

Formula

1017

Nonazeotrope

CjH NO

Propionamide
D e c a n e , 50 m m .
"
100 m m .
"
200 m m .
"
760 m m .
U n d e c a n e , 50 m m .
100 m m .
"
200 m m .
"
760 m m .
D o d e c a n e , 50 m m .
100 m m .
"
200 m m .
760 m m .

CloH22

11

24

1 2

2 6

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C H N0
3

=
1025
1026
1027
1028
1029
1030
=
1031
1032
1033

CaHeO
C H p
C H p
C H p
C H p
4

1 (

1 (

1 (

1 (

C H N0
C H 0
CsHeO
C H O
CiHidO
C H O
C H p
3

l d

l d

1 {

C H O
C Hs0
3

CAO2
C H30
4

1034
1035

C He0
QEfeCl

1036
1037
1038
1039
1040

C ^ X Q O

C H N
CsH O
C Hi O
4

10

216

26
26
26
26
26
26
26
26
26
26
26
26

1- Nitropropane
Isopropyl alcohol
Propyl alcohol
Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol

131.18
82.40
97.15
117.73
99.53
82.41
107.89

Nonazeotrope
8.8
96.95
32.2
115.30
4.1
99.40
Nonazeotrope
15.2
105.28

55
55
55
55
55
55

2- Nitropropane
Isopropyl alcohol
Propyl alcohol
Butyl alcohol
sec-Butyl alcohol
tert-Butyl alcohol
Isobutyl alcohol

120.25
82.40
97.15
117.73
99.53
82.41
107.89

4.2
82.24
24.9
95.97
52.4
111.61
18.0
98.70
Nonazeotrope
33.1
105.28

55
55
55
55
55
55

11

11

11

11

11

C
C
C
C
C

H
Hio
Hio
H O
H

1 0

1 0

1 2

11

11

1046
1047

C H 0
C HisN
6

1 2

...
173*3

...
.
194.5
...

Isopropyl Alcohol
82.3
72.7
V i n y l acetate
p-Dioxane
E t h y l acetate
77*05
"
40-60 C .
Methyl propionate
*79*6
1- C h l o r o - 2 - m e t h y l propane
68.9
Ethyl ether
34.6
Butylamine
77.8
Isopropyl vinyl ether
2- Pentanone
102.35
B e n z e n e , 155 m m .
"
243 m m .
509 m m .
607 m m .
"
760 m m .
"
196 m m .
512 m m .
4920 m m .
10,180 m m .
15,380 m m .
1.3- Hexadiene
72.9
2.4- Hexadiene
82
3 - M e t h y l - 1 , 3 - p e n t a d i e n e 77
M e s i t y l oxide
128
C y c l o h e x a n e , 129 m m .
270 m m .
"
434 m m .
549 m m .
"
760 m m .
4- Methyl-2-pentanone 115.9
Diisopropylamine
84.1
11

1041
1042
1043
1044
1045

222
3
5
7.5
11.8
15
16
17.3
21
26
26
26
31.6

11

C 3 H 8 O

52

88
106
126
168
105
123
142
183
115
132
152
193

11

1019
1020
1021
1022
1023
1024

Ref.

B.P.,C. W t . % A

N,N-Dimethylformamide 153
Benzene
80.1

11

1018

B.P.,C.

CjHyNO
C H
7

1016

Name

70.8

...
75.9
77"

22.4
2. 5.

v-1
v-1
v-1

28

63.8
19
Nonazeotrope
84.7
60
16.5
Nonazeotrope
31.8
20.6
41.8
23.6
60.4
29.9
65.3
31.4
71.74
33.7
37.2
22.4
60.3
30
134.7
62
166.3
79
186.1
91
Min. b.p.
Min. b.p.
Min. b.p.
Nonazeotrope
26.3
18.3
42.5
23.3
54.1
27.1
60.2
29.2
69.4
32
Nonazeotrope
79.7
40

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v-1

335
47
228
228
335
335
334
335
341
11
316
316
316
316
316
256
256
256
256
256
80
80
80
334
316
316
316
316
316
11
335

36

ADVANCES

IN

A -

Formula
C H O
3

Isopropyl Alcohol
(continued)
Hexylamine
Toluene

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1 0 4 8 C6H15N
1049

C H

1050

CeHu

1051

C H

1 6

1052

CgH

1 6

1 6

1053

C H

1054

C H

1055

C H
8

1 6

1056

C H
8

1 6

1057

C H
8

1 6

1058

C H
8

1 6

1059

C H

1 8

A =

II

Diisobutylene
trans -1,2 - D i m e t h y l cyclohexane
cis-1 -Ethyl - 2-methyl cyclopentane
trans-1-Ethyl-2methylcyclopentane
trans-l-Ethyl-3methylcyclopentane
1,1,2-Trimethylcyclopentane
1,1,3-Trimethylcyclopentan
l,cis-2,trans-3Trimethylcyclopentane
l,cis-2,trans-4Trimethylcyclopentane
2,2,4-Trimethylpentane

1 6

C HeO
3

1060
1061
1062
1063

C
C
C
C

H
H
H
H

S
0
O
O

Name

1 0

1 0

B.P.,C.

CgHgCl
CgHg

132.7
110.7
110.6
102.3

79 v o l .

291

128.05

82.2

83 v o l .

291

121.2

81.6

76 v o l .

291

120.8

81.4

75 v o l .

291

113.73

80.4

66 v o l .

291

104.89

78.5

53 v o l .

291

117.5

81.1

71 v o l .

291

116.73

80.9

71 v o l .

291

99.3

77.3

48.5

66.4

8.65

P r o p y l Alcohol
97.25
1 - P r o p a n e t h i o l , 7 6 6 m m. 6 7 . 8
Ethyl acetate,
40-60 C.
77.05
3-Pentanone
101.8
P r o p y l acetate
101.6
200 m m .
"
400 m m .
"
600 m m .
"
760 m m .
132
Chlorobenzene
B e n z e n e , 239 m m .
" 44.7-309.7 p.s.i.g.
"
123 m m .
"
289 m m .
423 m m .
"
610 m m .
"
760 m m .
342 m m .
"
573 m m .
"
2420 m m .
5020 m m .
10,050 m m .
18,200 m m .
C y c l o h e x a n e , 161 m m .
"
250 m m .
"
429 m m .
560 m m .
760 m m .
4-15 atm.
8*3
2 -Methylpentanal
(Trimethylsiloxy)
p r o p a n e , 735 m m .
100.3
110.7
Toluene
110.6
II
110.7
II
S t y r e n e , 50 m m .
11

11

11

11

11

11

1067
1068

C H 0
C H OSi

1069

C H
7

1070

CeH

1 2

1 6

334
327
335
335

Nonazeotrope
52
69
80.6
54.5
77.8
81.4

11

C H

Ref.

Wt.%A

123.42

11

1066

B.P.,C.

82.3

1064
1065

SERIES

Azeotropic Data

B-Component
No.

CHEMISTRY

...
.. .

Nonazeotrope
57
94.9
94.7
49
31.4
59.96
39.2
77.06
88.04
44.8
94.7
48.9
80
96.5
10.5
45
E f f e c t of p r e s s .
8.0
28.0
49.8
11.6
59.9
13.6
15.7
70.1
77.10
17.1
53.7
12.3
15.3
68.6
27.5
117.6
37
147.5
50.5
183.8
218.3
66.1
9.9
33.8
44.3
11.8
15.0
58.0
16.5
65.4
18.5
74.69
E f f e c t of p r e s s .
95
86
87.5

v-1

181
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
316,
316,
316,
316,
316,

50.5
49
v-1
51.5
92.6
v-1
84
38.5
% P r O H increases
with press.
9...
2.6

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

29

228
334
264
306
306
306
306
334
24
277
344
344
344
344
344
256
256
256
256
256
256
316
316
316
316
316
278
334
193
327
334
202
211
211

TABLE

BINARY

SYSTEMS

37

B-Component
No.

Formula

C HeO

Name

1071

8 10

E t h y l b e n z e n e , 50 m m .

1072

8 10

-Xylene

2-Methylthioethyl
v i n y l e t h e r , 22 m m .

1073

^ 0
C H
3

1074
1075

2 -Methoxy ethanol

Benzene
Cyclohexane

Q H 1 2

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1076
1077

C H

1078

C H

1079
1080
1081

Ce io
C H

1082

CeHi

1083

^8^16

H i 2

1084

8 16

1085

8 16

1086

^8^16

1087

^8^16

1088

1089
1090
1091

C H
C Hi
C H

1092

9K20

1093
1094

C H o

8 16
H

C H 0
3

1095
1096
1097

C H

6 14

C
C

1 0

H 6

C
C
C
C
C

1104
1105
1106

^12^26
Ci H

H8
H60
H
H 0
H

1 8

16

2 O

C H 0
8

1,2 -Propanediol

1098
1099
1100
1101
1102
1103

1107

trans-2 -Heptene
1- tert-Butoxy-2methoxyethane
S t y r e n e , 57 m m .
"
62 m m .
E t h y l b e n z e n e , 62 m m .
-Xylene
?-Vinylcyclohexene,
57 m m .
cis-1,3-Dimethyl cyclohexane
trans-1-Ethyl-2methylcyclopentane
trans-1-Ethyl-3methylcyclopentane
1,1,3-Trimethylcyclopentane
l,cis-2,cis-3-Trimethylcyclopentane
l,trans-2,cis-3-Trimethylcyclopentane
2,4,4-Trimethyl1-pentene
2,4- Dimethylhexane
2,2,3-Trimethylpentane
1,1,3-Trimethylcyclohexane
2,2,3,4 - T e t r a m e t h y l pentane
2,3,4 - T r i m e t h y l h e x a n e
2,3,5 - r i m e thylhexane

7 16C>2

5 102
H

...
138.4

3-Vinyloxy-lpropanol

Wt.%A

Ref.

% P r O H increases
with press.
92
...

211
327

...
...

75

20

329

124.5
80.1
80.7

...

98.0

67.9

...

138.35

Nonazeotrope
v-1
Nonazeotrope
15
v-1
77.5
19 v o l . %
92.9

331
334
331
291

119
54.8
56.8
51.9
119.3

76
291
152
152
291

45
62 v o l .
50.1
34.3
54 v o l .

%
v-1
v-1
%

.. .

44.4

30 v o l . %

291

120.9

105.6

36 v o l . %

291

121.2

106.3

32 v o l . %

291

120.8

106.0

35 v o l . %

291

96.7

20 v o l . %

291

123.0

107.4

35 v o l . %

291

110.2

100.2

20 v o l . %

291

95.5
99.3
99.7

20 v o l . %
26 v o l . %
25 v o l . %

291
291
291

136.6

113.1

41 v o l . %

291

133.02
139.0
131.34

111.4
113.5
110.6

39 v o l . %
39 v o l . %
40 v o l . %

291
291
291

104.89

101.44
109.43
109.84

187.8

3 - V inyloxypropanol
...
Benzene
80.1
Dipropylene glycol,
10 m m .
.. .
Toluene
110.6
Coumarone
173
0-Xylene
144.4
142.1
Butyl ether
Naphthalene
218.1
Tripropylene glycol
m e t h y l e t h e r , 50 m m .
.. .
Dodecane
216
252.5
Tetradecane
Bis( 2-ethylhexyl)
e t h e r , 10 m m .
135

1,3-Propanediol

B.P.,C.

97.25

2-(Methylthio)ethanol

C H OS
3

B.P.,C.

P r o p y l Alcohol
(continued)

Azeotropic Data

M i n . b.p.
Nonazeotrope

94
334

Nonazeotrope
v-1
1.5
110.5
Azeo. distillation
10
135.8
334,
136
Azeo. distillation

60
335
120
335
335
120

Nonazeotrope
67
175
179
76
84

76
60
60
335

214
10-15

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

94

38

ADVANCES

1108
1109
1110
1111
1112
1113

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula
CaHgS
C H
6

1 2

12

12

C H
6

6 14
CTH
C

CHEMISTRY

Azeotropic

B-Component
No.

IN

B.P.,C.

SERIES

Data

Wt.%A

Name

l.P.,C.

E t h y l Methyl Sulfide
Cyclohexane
1 -Hexene
Methylcyclopentane
2,3- Dimethylbutane
Hexane
2,2 - D i m e t h y l p e n t a n e

66.61
80.35
63.50
71.85
58.10
68.75
79.20

Nonazeotrope
29.4
62.71
65.59
64.1
18.7
57.41
63.94
56.6
88.2
66.37

Ref.

70
70
70
70
70
70

1114

C ^ g O

C3H9BO3

T r i m e t h y l Borate
Tetrahydrofuran

68.7
65

Nonazeotrope

A =
1115

C H N
C H

Isopropy lamine
Hexane

32.4
68.7

Nonazeotrope

334

A =
1116
1117

CjHNO
CgHgCl
C H N0

1-Amino-2-propanol
Chlorobenzene
l,l'-Iminodi-2p r o p a n o l , 100 m m .
Toluene
Heptane

159.9
131

128.30

13

259

185
110.7
98.4

Nonazeotrope
110
5
6
96.6

334
259
334

1,2 - P r opanediamine
Butyl alcohol
Isobutyl alcohol
Toluene

120.9
117.7
107.9
110.6

126.5
123
105

49
65
32

335
335
334

1 4

1118
1119

C H
0,

1120
1121
1122

C
C
C
C

A =

H
H
H
H

1 6

N
O
O

1 0

1 0

1 0

C C1 F

1123

C C1 F

1124
1125

C H
CeF

1126
1127
1128

C
C
C
C

1129
1130

C H20
C H
C H 0

A =

A =

1 6

HF 0
H
H
H
7

A =

A =
1132
A =

1 6

2 2

C H
C H C1
4

1131

C4HA
C H
7

C H S
4

1133
1134

C ^ I Q S

1136
1137
1138
1139

QsHi
C H
C H
C H

1140
1141
1142

C H
C H

90.6
98.53
102.6

Nonazeotrope
92.3
76
67
96.35

Perfluorobutyric A c i d
Ethylbenzene
m-Xylene
-Xylene

122.0
136.15
139
138.4

115.4
117.5
117.6

238

Vinylacetylene
2-Chloro-l,3b u t a d i e n e , 740 m m .

83.97
85.15
84.76
80.10
80.85
71.85
68.75
90.80
89.90
80.55
98.40

V
V
V

-1
-1
-1

354
354
354

52
52
52

80
83
82

Nonazeotrope

334

Nonazeotrope

334

Nonazeotrope

Diketene
T o l u e n e , 60 m m .
Thiophene
2-Butanethiol
Isopropyl methyl
sulfide
Benzene
Cyclohexane
Methylcyclppentane
Hexane
trans -1,3 - Dimethyl cyclopentane
2,3- Dimethylpentane
2,4 - D i m e t h y l p e n t a n e
Heptane

115

97.4

2,2,3-Trichloroheptafluorobutane
1,2 - D i c h l o r o h e x a fluorocyclopentene
Heptane
P e r f l u o r o c y c l i c oxide

M a l e i c Anhydride
m - X y l e n e , 150 m m .
Uibutyl phthalate,
50 m m .

v - -1

v-1

151

41

10

84

82.27

. ..

70

83.42
. ..
Nonazeotrope
77.90
41.2
71.47
14.0
68.46
11.2
82.00
80.90
76.58
83.09

67.7
64
42.7
83.2

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

70
70
70
70
70
70
70
70
70

TABLE

BINARY

SYSTEMS

39
Azeotropic Data

B-Component
No.
A =

^HgCl

1143

1144

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula

C H C1
4

C H<p
4

Name
2-Chloro-l,3butadiene
1,3- D i c h l oro - 2 100 m m
"
340 m m
3-Butene-2-one,
100 m m
"
340 m m

B.P.,C.

butene,
.
.

Nonazeotrope
Nonazeotrope

v-1
v-1

151
151

.
.

Nonazeotrope
Nonazeotrope

v-1
v-1

151
151

A =
1145

Cfifi
0

2,3-Butanedione
2- Butanone

A =
1146
1147
1148
1149

QHgOa
C H O
C6H
C7H
C H 0

V i n y l Acetate
Butyl alcohol
Cyclohexane
Heptane
Butyl ether

A =
1150

QHgOa
C H80

Acetic Anhydride
Isopropenyl acetate
Isopropyl acetate
Isopropyl ether

139.9
97.4
88.7
68.3

2-Chloroethyl V i n y l
Ether
Isoamyl alcohol
50 m m .

109.1

1 0

1 2

1 6

1 8

1151

1152

C6H

A =

O 2

1 4

C H C10
4

1153

C Hi 0
5

11

C H Cl20
4

1154

1155
1156

C H
4

1 0

GiH O
u

C H
8

1 8

A =
C H O
1157 C ^ g C ^
4

1158

C H C1
4

1159

C Hi O

1160

C H<jO

Bis(2-chloroethyl
Ether)
Diethylene glycol
3- Heptanol
2 - E t h y l -1 -hexanol,
50 m m .
2-Butanone
Isopropyl formate
1 - C h l o r o -2-methyl propane
sec-Butyl alcohol
374 m m .
2-Methylfuran
Benzene
14.7 p . s . i . a .
"
66.7 p.s.i.a.
118.0 p . s . i . a .
"
125.0 p . s . i . a .
Phenol, 200-760 m m .
2,5- Dimethylf ur an
Cyclohexane,
14.7 p . s . i . a .
"
66.7 p . s . i . a .
118.0 p . s . i . a .
"
125.0 p . s . i . a .
11

90.7
79.6
72.7
117.7
80.7
98.4
142.1

131.8
67

11

CgHgO
C HaO
C H
6

1 2

245.5
156.4
109
79.6
68.8
68.8
99.5

.. .
8.
0 . 1.
...
.. .
..3 ..3
9

11

1 1 6 5 QH14
1166
C6Hi
1167
C Hi
1168
C Hi
1169 q , H

2,3 - D i m e t h y l b u t a n e
Hexane
Methyl cyclohexane
Heptane
2,5- Dimethylhexane

A =
1170
1171

C HeO
C H 0
C H 0
4

Butyraldehyde
Isobutyraldehyde
Butyric acid

Nonazeotrope

334

Nonazeotrope
67.4
61.3
72
83.5
Nonazeotrope

334
334
334
334

Nonazeotrope
Nonazeotrope
Nonazeotrope

334
334
334

109
39

99
99

335
335

174.6
141.2

92
28

60
334

96

90

335

178.65

11

1162
1163
1164

Ref.

B.P.,C. W t . % A

80.85
80.85
80.85
58
68.95
101.15
98.4
109.4
74.8
69.5
163.3

310

Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
47
78.1
45
78.2
133.0
67.6
90.0
160.7
Nonazeotrope
Nonazeotrope
Nonazeotrope
71.0
128.7
156.4
182.5
71.6
71.5

...

52.5
61.0
64.0
69.0
45.5
44
42
15.1
29.6
80
73
95

Nonazeotrope
Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

V
V
V
V
V
V
V
V
V

-1
-1
-1
-1
-1
-1
-1
-1
-1

310
8
8
310
74
321
321
321
321
33
334
321
321
321
321
186
73
256
256
256
256
256
256

96
334

ADVANCES

40

IN

B-Component
No.
A

C H O
1172
1173
1174
1175
1176

A =
1177
1178
1179

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula
4

C H

1 0

C H O
C H O
CeHi
C H 0
4

1 0

1 0

C 5 H 5 N

QH

NO

CllH

C H 0
C H O
Q H
O
Q H
C H 0

A =

C Hg0

1 0

C 7 H 8

1186
1187
1188
1189

CUHeQi

A =
1180
1181
1182
1183
1184

1185

Q H

C H40
C H
5

CHI

B.P.,C.

Butyraldehyde
(continued)
Isobutyl alcohol
1,1 - D i m e t h o x y e t h a n e
M e s i t y l oxide
Hexane
1,1 - D i m e t h o x y b u t a n e

74.8
Nonazeotrope
Nonazeotrope
Nonazeotrope
60
26
Nonazeotrope

334
334
334
334
334

Butyric A c i d
Pyridine
,N -Dimethylbutyr a m i d e , 100 m m .
Undecane

162.45
115.5

163.2

370

124.5
194.5

130
162.4

p-Dioxane
Butyl alcohol
Isobutyl alcohol
Benzene, 200-760 m m .
Isopropyl ether
Toluene, 200-760 m m .

101.3
117.75
108

Cyclohexane

233 m m .
"
301 m m .
"
415 m m .
"
581 m m .
"
756 m m .
Butyl acetate
2-Butoxyethanol

.. .

68.3

...

A =
1192
1193

C Hi20
C H 0
6

C He0
C5Hg0
4

Isobutyric A c i d
Methyl acetoacetate
Ethylbenzene
30 m m .
Mixed xylenes
"
56 m m .

1 0

8 10

...

135.1
161.45
80.1
80.75

...
...
...
...

126.1
171.1
154.7
171.7
136.15

11

1194

C4H 0

1195
A
1196
1197
1198
1199
1200
1201
1202
A =

Propyl Formate

Hexane

6 14
H

C^gS
C6H14S
C H
7

8 16
H

8 16
CgHig
C Hig

8 18
H

1203

C ^ C l
C H O

1204

C H9Cl Sn
CgH Cl Sn

1205

Ci H

A =

1 0

1 8

2 7

ClSn

92
32.6
84.5

Nonazeotrope
101.3
Nonazeotrope
Nonazeotrope
Nonazeotrope

295
370

v - -1
v - -1
V-

-1

V
V

-1
-1

-1

-1

215
208
124
334
124

77.05

11

1190
1191

Ref.

B.P.,C. W t . % A

107.9
64.5
128.3
68.7
114

Isobutyl alcohol,
100-760 m m .
2 -Ethoxyethanol
2-Furaldehyde
Benzene

Q H 1 0 O 2

SERIES

Azeotropic Data

Name

E t h y l Acetate

CHEMISTRY

.. .

...

...

38.7
50.1
45.1
51
53.6
52.3
63.0
54.1
71.1
55.3
Nonazeotrope
Nonazeotrope

316
220
350
43,
44
43,
44
316
316
316
316
316
334
334

Nonazeotrope
133.0
8.8
48.0
0.8
133.0
10.0
62
1.0

334
84
84
84
84

Nonazeotrope
Nonazeotrope
Nonazeotrope
71.6

56

80.9
68.95

63.6

324

29.5

Tetrahydrothiophene
Isopropyl sulfide
Toluene
trans -1,3 -Dimethyl cyclohexane
Ethylcyclohexane
2,5 - D i m e t h y l h e x a n e
2 - Methylheptane
Octane

120.79
119.25
110.85

118.40
Nonazeotrope

70
70

120.30
131.85
109.15
117.70
125.70

115.90
120.46
107.95
113.96
117.79

70
70
70
70
70

1-Chlorobutane
Butyl alcohol

77.9
117.75

Nonazeotrope

Butyltin T r i c h l o r i d e
Dibutyltin dichloride,
17 m m .
Tributyltin chloride,
17 m m .

113/17

43.1
80.7
16.8
38.2
60.3

-1

335

157

Nonazeotrope

334

166

Nonazeotrope

334

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

TABLE

BINARY

SYSTEMS

41
Azeotropic

B-Component
No

=
1206
1207

=
1208

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1209
1210

Formula

C4H9NO
C H
C H
8

l g

0
O

N 0

2-Methyl-2-nitropropyl vinyl ether,


10 m m .

B u t y l Alcohol
sec-Butyl alcohol
Isobutyl alcohol,
to c r i t . r e g i o n

1 (

C A P
C H p
4

1212
1213
1214
1215
1216

1217
1218
1219
1220
1221
1222
1223

C H!iN
4

C 5 H 5 N
5

- C

H i 2

C 6 H 1 2 O
C 6 H 1 2 O

C H
6

C 6 H 1 4

C H
C H
6

126.7

73

334

169.4

128

98

334

...

99.5

7 122
H

1226

C H
7

1 8

1227

C H

7 16
H

SiO
0

Nonazeotrope

v-1

Nonazeotrope
97.8
14.84
Nonazeotrope
118.6
69
Nonazeotrope
Nonazeotrope
Nonazeotrope

v-1

Cyclohexane
Butyl vinyl ether
Hexaldehyde
B u t y l a c e t a t e , 50 m m .

79.8
93.3
116.8

80.8
94.2
128.3

.. .

126.2
11
Hexane
68.95
171.1
2-Butoxyethanol
Toluene
110.7
"
200 m m .
.. .
"
400 m m .
...
600 m m .
...
760 m m .
...
B u t y l a c r y l a t e , 100 m m . 6 9 . 7 7
20 m m .
...
"
150 m m .
...
II
147
Heptane
98.4
II
98.4
(Trimethylsiloxy)
butane
.. .
E t h y l b e n z e n e , 50 m m .
...
"
100 m m .
...
300 m m .
...
500 m m .
...
"
760 m m .
136.15
Octane
125.75
Butyl ether
142.1
Dibutylamine
159.6
Nonane
150.7
11

A =
1232
1233
1234
1235
1236
1237

C H
C H 0
Q ^ N
8

C9HJJ0

C H O
4

s e c - B u t y l Alcohol

1 0

C H 0
Q>Hi 0
C H
C H
C Hj
C H
4

75,
334
335

11

1228
1229
1230
1231

334

Nonazeotrope

750 m m .
.. .
ether
to c r i t . r e g i o n
34.5
1 - B u t a n e t h i o l , 7 7 0 m m . 98
Butylamine
77.1
Pyridine
115.5
Methyl methacrylate
99.8
Benzene, 45
8u!l
1!

11

1225

341

8.6

v-1

107

11

71-81

117.75

11

1224

Ref.

Nonazeotrope

Ethyl

C A P

C H80

Wt.%A

142.1

11

1211

B.P.,C.

2-Methyl-2-nitro1-Propanol

C H p
4

B.P.,C.

128.3

Butyl ether
2,6 - D i m e t h y l - 4 heptanone

C4H9N03
Q H

Name

Morpholine

Data

Butyl acetate
s e c - B u t y l acetate
Methylcyclohexane
Heptane
Diisobutylene
Iso-octane

9.5
7.8
77.1
27.3
117.6
67.2
68.2
3.2
Nonazeotrope
105.5
27.5
66.8
17.7
85.45
22.9
97.7
26.5
105.3
29.7
69
75
39
87.7
77
92.2
117
98.2
93.85
18
-94
-16
Azeotropic
36.3
63.65
42.1
51.0
59.7
115.85
65.1
108.45
43.2
117.6
82.5
Nonazeotrope
115.9
71.5

75
181
334
v-1
141
147
v-1
24
v-1 344,
362
147, 335
335
335
117
117, 335
174, 335
v-1
335
v-1
377
v-1
124
124
v-1
124
v-1
124
v-1
334
76
76
76
174, 175
141
v-1
193
92
92
92
92
92
175
335
334
174, 175

v-1
v-1
v-1
v-1
v-1
174,

99.5
126.1
112.2
101.5
98.4
102.3
99.3

Nonazeotrope
Nonazeotrope
89.7
38.2
88.1
36.7
91
35
88.0
33.8

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

334
334
352
352
37
352

ADVANCES

42

IN

B-Component
No.

1238

Formula

C4H10O
C H
6

Name

Isobutyl Alcohol
Benzene
"
"
"
"
"

11

"
"
"

C H O

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1239

1240

1 0

C H

1 8

C H O
6

1242
1243
1244
1245
1246
1247
1248

Butyl ether, 600 m m .

C4H10O2
C Hio0

1241

Ethyl Ether

6 122

4 102

C 5 H 8 O 2

C5H10O2
C 6 H 1 2 O 2

C H
6

N2

1 4

C 6 H 1 4 O 3

C H
C H
8

1249
1250
1251
1252

C H

1253
1254
1255
1256
1257

8 16
C H

1258
1259
1260
1261
1262
1263
1264
1265
1266
1267
1268

^8^18

Q i o
C H
H

e 16
H

C
C

8 18
8 18
8 18
H

C9H12
C

9 12
H

C)H
C9Hi

18

C 9 H

C 9 H

C 9 H 2 0
C 9 H 2 0
C 9 H 2 0

1269

C 9 H 2 0

1270

C 9 H

1271
1272
1273
1274
1275
1276

C9H20

C 9 H 2 0

C9H20
C9H20
C9H20
C

9 20
H

1,2-Dimethoxy ethane
Isopropyl ether

1,4-Butanediol

$.P.,C.

Methyl methacrylate
P r o p y l acetate
B u t y l acetate
2,5-Dimethylpiperazine
2 - (2 - E t h o x y e t h o x y )
ethanol
S t y r e n e , 50 m m .
E t h y l b e n z e n e , 50 m m .
"
57 m m .
"
735 m m .
it
m - X y l e n e , 735 m m .
0-Xylene, 735 m m .
- X y l e n e , 735 m m .
trans -1,2- Dimethyl cyclohexane
Ethylcyclohexane
cis-2-Octene
2,5 - D i m e t h y l h e x a n e
3,3-Dimethylhexane
3-Ethyl-3-methylpentane
Octane
o-Ethyltoluene
M e s i t y l e n e , 735 m m .
Butylcyclopentane
Isobutylcyclopentane
Isopropylcyclohexane
1 -Nonene
Propylcyclohexane
3,3 - D i e t h y l p e n t a n e
-Nonane
, 2 , 3 , 3 - T e t r a m e t h y l pentane
2,2,4,4 - T e t r a m e t h y l pentane
2,3,3,4-Tetramethylpentane
2,2,3-Trimethylhexane
2,2,4 - r i m e t h y l h e x a n e
2,3,3 - T r i m e t h y l h e x a n e
2,3,5 - T r i m e t h y l h e x a n e
2,4,4 - r i m e thylhe xane
3,3,4 - r i m e t h y l h e x a n e

B.P.,C.

107

80*1

80*1

78.36
28.4
45.0
67.4
79.3
43.0
59.5
79.4
159.9
207.5

Wt.%A

Ref.

12
2.7
4.2
6.4
7.4
4.2
6.0
7.9
21.0
33

Ill
316
316
316
316
256
256
256
256
256

34.5
142.4

Ideal system

v-1

257

85.2
68.3

334

Nonazeotrope

230
94

Min. b.p.

4 -Vinyloxybutanol

2 -Ethoxy ethanol

SERIES

Azeotropic Data

80.1
111 m m .
240 m m .
525 m m .
760 m m .
206 m m .
394 m m .
759 m m .
5420 m m .
12,930 m m .

CHEMISTRY

134.0
99.8
101.6
126.2
164

Nonazeotrope
Nonazeotrope
125.7
13
Nonazeotrope

v-1
v-1

147
220
221
334

202.8

60*62
134.9
136.15
137.9
143.1
137.4

Nonazeotrope
42.5
v-1
59.8
27.6
v-1
53.9
42 v o l . %
50.0
43.3
v-1
126.2
45
v-1
128
48.9
v-1
127.7
57.2
v-1
129.6
47.9
v-1
127.3

334
110
110
291
167
227
167
167
167

123.42
131.78
125.6
109.10
111.97

115.6
120.2
117.9
105.1
107.1

27
33
28
16
17

118.26
125.75
165.15
163.4
156.56
147.6
154.5
146.87
156.72
146.17
150.8

111.7
122.5
135.0
133.7
130.2
127.4
129.6
128.1
130.2
126.4
128.0

23 v o l . %
33.6
v-1
91 v o l . %
85.7
v-1
61 v o l . %
49 v o l . %
56 v o l . %
48 v o l . %
59 v o l . %
45 v o l . %
50 v o l . %

291
227
291
167
291
291
291
291
291
291
291

140.27

124.1

40 v o l . %

291

122.28

114.3

26 v o l . %

291

141.55
133.60
126.54
137.68
131.34
130.65
140.46

124.6
120.8
116.8
122.8
119.5
119.1
124.0

41
34
26
41
32
34
40

291
291
291
291
291
291
291

...

vol.
vol.
vol.
vol.
vol.

vol.
vol.
vol.
vol.
vol.
vol.
vol.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

%
%
%
%
%

%
%
%
%
%
%
%

291
291
291
291
291

TABLE

BINARY

SYSTEMS

43
Azeotropic

B-Component
Formula

No

C4H10O2

1277

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C4H10O3

=
1278

C H

1 2

1279
1280

G H

1281

C HiP

1282

C H

1283
1284
1285
1286

C H N

1287

6 123

C8H

10

CeHio
C8Hi 0
8

8 184

1288
1289

CioHe
C H OS

1290
1291
1292
1293

1294
1295
1296

C
H
Gi H

H9N

1 2

C12H10
12So
C
H p S
C

2-Ethoxyethanol
(continued)
tert-Butylcyclohexane

10 20

Name

C14H10

Diethylene Glycol
2 -(2 - M e t h o x y e t h o x y )
ethanol
Benzene
2 -(2 - V i n y l oxyethoxy)
ethanol
2 - (2 - E thoxye thoxy)
ethanol
Triethylene glycol,
3 m m .
Indole
Ethylbenzene
-Xylene
2 - (2 - B u t o x y e t h o x y )
e t h a n o l , 10 m m .
2 - [2 - (2 - E t h o x y e thoxy)
ethoxy]ethanol, 2 m m .
"
3m m .
Naphthalene
2 -(Benzylmrcapto)
ethyl vinyl ether
C a r b a z o l e , >10 m m .
Biphenyl
Phenyl ether, 4 m m .
2-(2-Ethylhexylthio)
ethyl vinyl ether
H e x y l e t h e r , 50 m m .
Fluorene, 10-760 m m .
P h e n a n t h r e n e , 20 m m .
"
100 m m .
"
200 m m .
300 m m .
"
400 m m .
Benzyl ether, 5 m m .
Bis(2 -ethylhexyl) ether,
10 m m .
11

1297
1298

1299

C4H10S
C4H10S

2-Butanethiol

C H

Ethyl Sulfide

1 0

1300
1301
1302

C H
7

1303

C H

1304
1305
1306
1307
1308

C1A4O

6 12
C H
C

7 14
C Hi
C Hi
C

7 16
8 18
H

C4H10S

1309
1310
1311

C H
7

1312

C H

1313

6 12
C H

7 16
H

Isopropyl methyl
sulfide

B.P.,C.

Cyclohexane
Methylcyclopentane
trans -1,3 - Dimethyl cyclopentane
1,1- D i m e t h y l c y c l o pentane
3 - Methylhexane

Wt.%A

Ref.

134.0
171.5

133.3

73 v o l . %

291

245.5
193.6
80.1

.. .

Nonazeotrope
Nonazeotrope
Min. b.p.

334
334
94

Nonazeotrope

334

253
136.15
138.2

Nonazeotrope
v-1
Azeo. distillation
Azeo. distillation
Azeo. distillation

60
120
120
120

109

Nonazeotrope

334

87
135
Azeo.

43
83.4
distillation

335
60
120

M i n . b.p.
Nonazeotrope
Azeo. distillation
23

329
100
120
335

M i n . b.p.
129.9
Min. b.p.
146
180
203
217
226

329
335
100
100
100
100
100
100
335

202.8

.. .

98

.. .

218.1

.. .

294
355.9
100

137*
294

...
...
...

135

15.5
93
96.2
98.5
99.5
99.9
40

114

335

85.15
84.76

Nonazeotrope

70

Nonazeotrope
Nonazeotrope

70
70

92.07

80.10
Benzene
80.85
Cyclohexane
trans -1,3 -Dimethyl cyclopentane
90.80
1,1 - D i m e t h y l c y c l o 87.90
pentane
M e t h y l c y c l ohe x a n e
101.05
91.60
3-Methylhexane
89.90
2,3- Dimethylpentane
80.55
2,4- Dimethylpentane
2,2,4 - T r i m e t h y l p e n t a n e 99.30

Isopropyl Methyl Sulfide

B.P.,C.

Data

88.89

41.0

70

86.98
92.10
89.19
87.93
80.53
91.44

26.1
94.5
48.3
38.6
2.26
77.0

70
70
70
70
70
70

84.76
80.85
71.85

79.76
30
Nonazeotrope

70
70

90.80

84.38

80.4

70

87.90
91.60

83.62
84.38

64.9
82.4

70
70

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

44

ADVANCES

IN C H E M I S T R Y

B-Component
No, .

C4H10S

1314
1315
1316

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula

C H
C H
C H
7

1 6

1 6

1 6

C H
C H
C H

1320

C H
7

1 4

1321
1322
1323
1324

C H

1 6

=
1325
1326

=
1327
1328

=
1329

330

1 4

1 4

C9H20
C10H22

Ethyl Disulfide
Nonane
3-Ethyl-3-methylheptane

C4H11N

Diethylamine

C H
4

C H
C H

1 0

1 5

O
NO

C H N0

CjF

1 6

N0

1332

C F

Perfluorocyclopentane
Perfluoropentane,
9.6-25 C .
Perfluorohexane,
15-25 C .

5 12
F

C H4F 0
5

CgHiP
C H 0
5

1 2

1335

C H40
C H 0

1336

C H

1337
1338
1339
=
1340
1341
1342
1343
1344
1345

C5H5N
5

1 2
8

2 - F u r aldehyde
Furfuryl alcohol,
25 m m .
Benzene

Methylcyclohexane
Heptane

7 16

C H
C H
C H

2,2,3,3,4,4,5,5Octaf l u o r o - 1 -pentanol
Active amyl alcohol
Isoamyl alcohol

Cyclohexane

6 12

C H

2,2 -Iminodiethanol
2,2',2"-Nitrilotriethanol, 2 mm
1

1,2 - D i c h l o r ohexafluorocyclopentene
P e r f l u o r o c y c l i c oxide

C5F10
C

1333
1334

Isopropyl ether
2 -(Diethylamino)
ethanol

C H
6

N
0

Pyridine
Piperidine
3-Pentanol
Toluene

7 16

Heptane

8 10
8 10

Ethylbenzene
o-Xylene

Azeotropic Data
B.P.,C.

II

B.P.,C.

Wt.%A

Ref.

84.76
89.90
80.55
79.20

Methyl P r o p y l Sulfide
95.47
t h y l c y c l ope ntane
103.45
Methylcyclohexane
101.05
trans -1,3 - Dimethyl 90.80
cyclopentane
1,1- D i m e t h y l c y c l o 87.90
pentane
91.60
3-Methylhexane
89.90
2,3- Dimethylpentane
106.85
2,2-Dimethylhexane
2,2,4 - T r i m e t h y l p e n t a n e 99.30

^8 18

1331

Isopropyl Methyl Sulfide


(continued)
2,3- Dimethylpentane
2,4- Dimethylpentane
2,2 - D i m e t h y l p e n t a n e

C4H10S

1317
1318
1319

Name

SERIES

83.83
79.39
78.40

72.8
29.7
23.3

70
70
70

95.41
95.06

90.7
78.0

70
70

90.11

24.3

70

87.66
90.53
89.10
95.42
94.00

9.7
32.95
22.75
94.4
62.2

70
70
70
70
70

154.11
150.65

148.62

41.2

70

163.00

153.02

80.2

70

55.5
68.3
162.1

Nonazeotrope

334

Nonazeotrope

334

126/2 m m .
195

Nonazeotrope

334

90.6
102.6

v- -1

354

Nonazeotrope

v- -1

237

Nonazeotrope

V ' -1

237

90.4

80

...

.. .

128.5
132.0

330
330

Nonazeotrope
Nonazeotrope

161.45

80.1

Nonazeotrope
Nonazeotrope

-1
-1

80.75

Nonazeotrope

V" -1

101.05
98.40

100.8
98.3

4.1
5.3

115.5
106
115.6
110.8

105.8
117.4
110.1

3.4
45
22.2

98.40
98.40
136.15
143.6

95.60
25.3
13.3
95
Nonazeotrope
Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

v - -1
v - -1

-1

348
52,
331
52,
331
114
114

147
334
141,

355, 373
--1
141
363
372

TABLE

BINARY

SYSTEMS

45

B-Component
No. ,
A

1346
1347
1348
1349
A =
1350
1351
1352
1353

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

=
1354
1355
1356

Formula
C H N
C H
5

C9H20
C10H3N2
C

C H S
5

^7 16
C H

1 8

8 18
CePie
C

CsHeS
C H
7

7 16
8 16
H

1357
1358
1359
1360
A =
1361
1362
1363
1364
1365
A =
1366

A
1367
1368

C H
C H
Q H
8

1 8

1 8

C H
C H
5

1 0

C5H10
C H
5

C5H12
CsH Cl
C7Hi2Cl
8

C H 0
CsHiaO
C H 0
5

1 2

Name

109.5
56.1
115.1
89.9
Nonazeotrope
Nonazeotrope

2 -Methy lthiophene
Heptane
2 - Methylheptane
2,5-Dimethylhexane
2,2- Dimethylhexane

111.92
98.40
117.70
109.15
106.85

97.77
109.97
106.12
104.62

2.2
67.8
39.6
33.2

70
70
70
70

3 -Methy lthiophene
Ethylcyclopentane
Heptane
trans -1,3 - Dimethyl cyclohexane
1,1,2 - T r i m e t h y l c y c l o pentane
Octane
2 - Methylheptane
2,5- Dimethylhexane

114.96
103.45
98.40

102.82
3.9
Nonazeotrope

70
70

120.3

113.17

66

70

113.75
125.70
117.70
109.15

110.47
114.15
111.86
107.12

43.2
82
58.8
31.7

70
70
70
70

Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
33.6
72.5

v - -1

248
248
248
248
248

Nonazeotrope

v - -1

250

129.5
128.5
131.85

Nonazeotrope
127.8
60

v - -1

131.85
131.85
128.9
128.9

129.4
Nonazeotrope
127
124.6

330
87,
88
314
2
87, 88
314

99.3
68.3

Nonazeotrope

334

61.8/200 m m .
Methyl Methacrylate
Butyl methacrylate,
200 m m .
117.7
Nonazeotrope
2-Ethoxyethyl
Nonazeotrope
m e t h a c r y l a t e , 200 m m . 134.3

147

Isoprene
3 - M e t h y l - 1 -butene
2 - M e t h y l -1 -butene
2-Methyl-2-butene
2 -Methylbutane
P e n t a n e , 758 m m .

34.3
21.2
32
37.7
27.6
36

Tetrachloropentane

...

Tetrachloroheptane,
12-150 m m .

II

2 - M e t h y l -1- butanol

It

C5H4O2

1370

QH

1371

1372

C H

1373

C5H8O2
C5H8O2
C5H10

CsH 0
8

A =
1374
1375
A =
1376
A =
1377

8 142
H

C6H

1 4

Ref.

B.P.,C. W t . % A

115.5
125.75
150.7
274
173.3

Cyclopentanone
Active amyl alcohol
Isoamyl alcohol

C Hi 0

B.P.,C.

Pyridine (continued)
Octane
Nonane
2,2'-Dipyridyl
Decane

II

1369

Azeotropic Data

Ethyl Acrylate
Isopropyl ether

2,4- Pentanedione
Isopropenyl acetate

140.2
96.5

Nonazeotrope

Cyclopentane
Benzene
2,2 - D i m e t h y l b u t a n e

49.4
80.1
49.7

Nonazeotrope
49.1
82.3

C5H10
C5H12

3 - M e t h y l - 1 -butene

C5H10
C5H12

2 -Methy 1- 2 -butene

2-Methylbutane

Pentane

355
355
147
355

147

147

-1

230
214

22.5
27.6

Nonazeotrope

248

37.7
36.15

Nonazeotrope

248

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

46

ADVANCES

IN

B-Component
No.

A =

C H O
5

C Hi

1380

C Hi2

1381
1382
1383

C7H
C Hi
CeHi6

1384

C H

2-Pentanone

Cyclohexane

C H O
5

A =
1385

A =
1386

A=

3-Pentanone

1 0

Methylcyclohexane
Heptane
1,3-Dimethylcyclohexane
2,5-Dimethylhexane

1 4

1 8

C5Hio0

C HioQ2
5

NO

1 5

C H
5

Isopropyl Acetate
2,5-Dimethylfuran

CHSO

C7H

B.P.,C.

Cyclohexane
Heptane

C HidO

A=

Name

Valeric Acid
N,N-Dimethylvalera m i d e , 100 m m .

Pentane

1 2

B.P.,C.

Wt.%A

80.75
98.4

. . .
. . .

14.8
48

256
256

. . .

5.0

256

102.35
80.75

102
101.15
98.4

...
...

40
35

256
256

120.7
109.4

...
...

83
60

256
256

88.7
93.3

Nonazeotrope

334

145.8

295

186.35
141

30.8

36.15

Q H 6

Benzene

80.2

Nonazeotrope

1388
1389

C6H12
C6Hi

Cyclohexane
Methylcyclopntane

80.75
72.0

Nonazeotrope
Nonazeotrope

1390

O7F16

1391

C H

82.5
101.15

Azeotrope
Nonazeotrope

A=

Perfluoroheptane,
crit. region
Methylcyclohexane

C H 0
5

A m y l Alcohol

1 2

1392
1393
1394
1395
1396
1397

Q H O
C H O
C H N
QHie
CeH
C H2 02

1398
1399
1400
1401
1402
1403
1404
1405
1406

C H 0
C H C1
C H FO
05
QHioO
C7H F
Q H

1407
1408
1409
1410
1411

C
C
C
q

1412
1413
1414
1415
1416
1417
1418
1419

C5H

A=

1 4

1 8

C5H12O

A=

1 2

QH9N
Q H
7

Hi5N
H N
H
j H ^
1 5

C9H20

C5H12O
1 2

QH5CI
QH5FO
Q H N
Q H
p
C H
C H F
C H
7

Benzene
Methylcyclopentanone
2,5-Dimethylpiperazine
C paraffins
Octane
Diamyloxymethane
8

Active A m y l Alcohol
Isoamyl alcohol
Chlorobenzene
o-Fluorophenol
2-Picoline
M e sityl oxide
o-Fluorotoluene
Toluene
2,6-Lutidine
2,4-Dimethyl3-pentanone
1,2-Dimethylpiperidine
2,6-Dimethylpiperidine
Ethylbenzene
n-Octane
2,2,5-Trimethylhexane

Isoamyl Alcohol
3-Methyl-1-butanethiol
Chlorobenzene
o-Fluorophenol
1-Picoline
M e sityl oxide
C hydrocarbons
o-Fluorotoluene
Toluene
7

Ref.

95.4

1387

SERIES

Azeotropic Data

3-Methyl-2-butanone

1 0

Q5H12

1378
1379

A=

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula

CHEMISTRY

v-1

52,
229
v - 1 231
v - 1 52,
231
v-1
v-1

155
52,
231

137.8
80.2
138
164
120-130
125.75
. . .

Nonazeotrope
M i n . b.p.
Nonazeotrope
M i n . b.p.
121.8
. . .
Nonazeotrope

v - 1 344
87, 88, 314
334
314
314
334

128.5
131
132
.. .
129
129.5
114
111
144

Nonazeotrope
124.4
43
Nonazeotrope
132.8
49
Nonazeotrope
112.0
16
109.9
12
Nonazeotrope

125
128
128
136
126.0
124

124.1
130.3
130.7
125.0
117.0
115.5

21
...
54
53
34
29

v - 1 246
330
330
330
330
330
330
330
330
330
330
330
330
330

131
116
132
...
129
129.5
95-120
114
111

115.6
22.89
123.9
38
Nonazeotrope
132.8
61
Nonazeotrope
M i n . b.p.
112.1
14
109.7
10

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

181
330
330
330
330
314
330
330, 371

TABLE

BINARY

SYSTEMS

47
Azeotropic

B-Component
No.

Formula

C H
5

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1420

1 2

G7H9N

1421

C H

1422

C7H15N

1423

C7H15N

1424
1425
1426

^ 10
8 18

C9H20
C5H12O

1427
1428

C H
C H

1429

C6H

Isoamyl Alcohol
(continued)

2 , 6 - L u t i d i n e , 70 m m .
It
2,4-Dimethyl3-pentanone
1,2-Dimethylpiperidine
2,6-Dimethylpiperidine
Ethylbenzene
-Octane
^, 2,5- r i m e thylhe xane

2-Methyl-1-Butanol
7

C H

1 2

2 - M e t h y l - 2 -butanol
Benzene

11

1430

C H
7

C5H12O3

1432
1433
1434
1435
1436
1437
1438
1439
1440
1441
1442
1443
1444
1445
1446
1447
1448
1449
1450
1451
1452
1453
1454

C8H5CI2
C9 12
C Hi
H

C9H12
C H
9

9 12
H

9Hl2
CIOHH
C

CIOH

C
C
C
C
C

H
H
H
H

1 4

10 14
10 14
10 14
H

11 10
Ql 16
C H
C

C11H24
C
C

1 2

H 6
2

12 26
H

Q2 26
H

13 26
H

C F
6

1455

C F

1456

C Fi4
Q H

Perfluorocyclic Ether

330
330

125

124.5

330

128

132.5

81

330

128
136
126
124

132.6
125.7
117.0
116.0

76
49
30
26

330
330
330
330

128.9
95-120
110.7

Hexane, 325 m m .
"
479 m m .
689 m m .

314
314

M i n . b.p.
M i n . b.p.

101.7

...

80.0
l'.

15
4.95
56
32.5

v-1

52
272
52
272

v-1

192.95

...
...

. ..

161.99
161.31
165.15

86-90
100-101
161.4
160.9
164.3

9 vol.
13 v o l .
16 v o l .

%
%
%

49
49
291
291
291

176.08

173.4

26 v o l .

291

169.35
164.72
183.27
173.30
169.11
172.76
181.13
183.78
183.75
177.10

167.9
163.8
177.9
170.7
167.6
170.3
176.3
177.9
177.9
173.3

21
12
32
16
13
24
29
31
30
22

vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.
vol.

%
%
%
%
%
%
%
%
%
%

291
291
291
291
291
291
291
291
291
291

197.93
241.1
198.1
198.1
195.88
169.79

185.9
48
Nonazeotrope
40
182.8
40
180.6
178.7
40
52
144.2

vol.

vol.
vol.
vol.
vol.

%
%
%
%

291
98
291
291
291
291

185.6

173.6

30 v o l .

291

177.9
232.78

168.9
191.6

23 v o l .
70 v o l .

%
%

291
291

v-1

237

v-1
v-1
v-1

79
79
79

...
Nonazeotrope

Perfluorohexane, 25

Perfluorohexane

Ref.

Max. b.p.
Nonazeotrope

110.7

ar-Dichlorostyrene,
15 m m .
"
29 m m .
-Ethyltoluene
m - E thyltoluene
o-Ethyltoluene
1,2,3-Trimethylbenzene
1,2,4-Trimethylbenzene
Mesitylene
Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Isobutylbenzene
m -Diethylbenzene
-Diethylbenzene
5-Ethyl-m-xylene
-Cymene
1,2,3,5 - T e t r a m e t h y l benzene
2 -Methylnaphthalene
t e r t - A m y l benzene
tert-Amylcyclohexane
n-Undecane
n - D o d e c a n e , 217 m m .
2,2,4,4,6-Pentamethylheptane
2,2,4,6,6- Pentamethyl heptane
1-Tridecene

Wt.%A

144*

715 m m .

2 - (2-Methoxy ethoxy )
ethanol

11

B.P.,C.

131

80.2
715 m m .

Toluene

11

1431

B.P.,C.

C
hydrocarbons
Toluene

Name

Data

...
...
.. .

25
35
45

83.4
83.7
80.0

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

48

IN

Azeotropic

B-Component
No.
A

Formula
C F
6

1457

A =

1 4

C H C1
C H ^ O j
6

1458

A =

C6H4CI2
1 4 5 9 C9H6O2N2

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1 4 6 0 C15H10O2N2

A =
1461

C H Br
C H 0
6

Name

C H C1
C H
CH^O*
6

A =
1464

C H F
C H

A =
1465

C H N0
C H

1466

6 12
H

237

1,2,4-Trichlorobenzene
2,4-Tolylene
diisocyanate, 40 m m .

Nonazeotrope

v-1

119

67.0/15
o-Dichlorobenzene
2,4-Tolylene
Nonazeotrope
d i i s o c y a n a t e , 15 m m . 128.7
Di-p -isocyanatodi phenylmethane,
192.0
Nonazeotrope
5 m m .
Bromobenzene
Cyclone xanol,
250 m m .
"
500 m m .
730 m m .

156.1
127.0
144.4
158.6

113.6
136.8
150.6

Chlorobenzene
n-Hexane
^",4-Tolylene d i i s o
cyanate, 40 m m .

131.8
68.95

Nonazeotrope

Benzene
Cyclohexane

80.1
80.75

128 m m .
155 m m .
II
287 m m .
II
307 m m .
II
495 m m .
It
602 m m .
II
760 m m .
M
14.7 p . s . i . a .
It
66.7 p . s . i . a .
II
118.0 p . s . i . a .
186.8 p . s . i . a .
It
66.7 p . s . i . a .
It
116.5 p . s . i . a .
II
165.9 p . s . i . a .
II
217.0 p . s . i . a .
II
268.7 p . s . i . a .
Methylcyclopentane
4 - M e t h y l - 2- pentanone,
450-760 m m .
Hexane
It
4-18 a t m .
Perfluor ometh^lcyclo hexane
Perfluoroheptane
Methylcyclohexane
2,3-Dimethylpentane
2,4- Dimethylpentane
Heptane, 180-450 m m .

"

1469

CH

1 4

1470

C Fi

1471
1472
1473
1474
1475

C F

1 2

C Hi6
C H
C H
7

84.9
80.1
210.85
80.75

II

...

Nitrobenzene
Cyclohexane

II

6 12
0$

Ref.

B.P.,C. W t . % A

v-1

II

1467
1468

Data

Nonazeotrope

Fluorobenzene
Benzene

B.P.,C.

SERIES

Perfluorohexane
(continued)
Tris(perfluorobutyl)
amine, 25

11

A =
1462
1463

CHEMISTRY

It

80.75

...
...
...
...
...

...

...
...
...
.. .
...
...

71.85

.. .

68.95

.. .
73-78
83
101.05
89.79
81

.. .

98.4

85.5
81.5
74.8

147

147

-1
v - -1
v - -1
V"

318
318
318

52

Nonazeotrope

-1

119

Ideal

-1

12

system

52

Nonazeotrope

77.6

51.2

77.4
28.4
33.1
48.3
50.4
63.7
69.8
77.56
77.4
137.1
165.8
193.0

52.5
47.6
48.0
49.3
49.4
50.8
51.3
51.9
50.2
61.5
67.0
71.5
59.7
64.9
67.6
71
74
16

...
...
.. .

71.7

Nonazeotrope
Nonazeotrope
Nonazeotrope
59
61
Nonazeotrope
78.8
79.4
48.4
>75
Nonazeotrope
Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

44,
v-1
191, 3 4 3
74, 111
316
316
316
316
316
316
316
321
v-1
321
v-1
321
v-1
321
v-1
v-1
276
v-1
2 76
v-1
276
v-1
276
v-1
276
230
v-1
v-1
v-1
v-1

v-1
v-1
v-1
v-1

66
229
276
51
51
230
190
51
240
229

TABLE

BINARY

49

SYSTEMS
Azeotropic Data

B-Component
Formula

No.

C H
CeFieO
CeHie
6

1476
1477
1478
1479

Ceie
C Hi 0
8

C6H 0
C Hi O
6

1480

Name

B.P.,C.

Benzene (continued)
Perfluorobutyl ether
Octane
2,2,4-Trimethylpentane, 35-75 C .
2 - (2 - B u t o x y e t h o x y )
ethanol

80.1
100
125.75

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

CeHioCU
C H 0
6

1 2

11

1483
1484
1485
1486
1487
1488

A =
1489
A =
1490
1491
1492
1493
1494
1495
1496

C Hg0
C Hi 0
8

C H
C H
C H
9

1 2

1 2

1 4

SiO

0 6
C H
6

1 2

Pyrocatechol
1,3,5-Triethylbenzene

1 8

C 6 H 1 2 O

C H
6

1 3

Q H 1 4

C H
C H N
7

7 16
C H N

.. .
.. .
...

245.9
215.5

184.35
Aniline
Cyclohexanol
134
Cyclohexylamine
Hexane, 556-731 m m .
110.7
Toluene
- M ethylaniline,

95-145
98.4
Heptane
N,N -Dimethylaniline,
36.7 m m .
101.4 m m .
243.1 m m .
Iso-octane, 86-741 m m .
- C v m e n e , 50 m m .
"
100 m m .
300 m m .
"
500 m m .
760 m m .

C H N
6

230.6

..
.. .

C 9 H 1 0

11

e 18
10 14
H

11

11

71.5

Azeotropic
Max. b.p.
195.53
111
111
120
140
180
195.89

75.8
39.2
70
73
70
71
87
8.9

95.6
162
149
158.5

95
7
2
14

214.7

242
242
356
138

...

Nonazeotrope

v-1
v-1

59
138

...

95
74.5
120
76.1
77.5
145
Nonazeotrope
21.3
1()6!3
23

v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1
v-1

59
59
59
356
92
92
92
92
92

.. .
.
..

.. .

...
...

172.80

. ..
...

31.3

C H,C1N

Aniline H y d r o
chloride
Diphenylamine,
100 m m .
250 m m .
"
350 m m .
"
740 m m .
"
2500 m m .

...
.. .
215

45.8
48
50
65

1 8

11

324

v-1
147,
v-1
v-1

Nonazeotrope
Nonazeotrope
Nonazeotrope

27.3

34, 335
303
76
324

8.9

143.5

1 2

76
57
334
253
76
57
57
76
76
253

193

144
144.06

v-1

175.5

3-Picoline
2,6-Lutidine

H N
H 0
H
H o

1503

.. .

345
334

C H N
C H N

Nonazeotrope

Nonazeotrope
121.12
42
84.1
129.2

1502

v-1

128.8
124.5
125.75
150.7

C
C
C
C

51
52

2-Picoline
Paraldehyde
Octane
Nonane

A =
1499
1500
1501

Ref.

68
Nonazeotrope

...
.. .

11

1497
1498

Wt.%A

Nonazeotrope

181.42
Phenol
C y c l o h e x a n o n e , 5 0 m m . 73
If
155.6
50 m m .
Ethylene diacetate
189.86
Cyclohexanol, 60 m m .
"
70 m m .
90 m m .
"
200 m m .
160.65
11
195.14
Phenyl acetate
2-Ethyl-l-hexanol,
25 m m .
-Methylstyrene
152.8
Cumene
158.9
Propylbenzene
(Trimethylsiloxy)
181.9
benzene
11

1481
1482

B.P.,C.

334
369
369

v-1

27

...
...
...
265
.. .

233
270

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

153
153
153
153
153

ADVANCES

50

IN

B-Component
No.

Formula
C H N
6

1504

1 1

1 0

Azeotropic

Name

B.P.,C.

2 - Amino-3-methylpyridine
1 -Methylnaphthalene,
20 m m .
"
50 m m .
"
150 m m .
"
290 m m .
400 m m .
"
760 m m .
2 -Methylnaphthalene,
16 m m .
"
50 m m .
"
150 m m .
"
400 m m .
550 m m .
"
760 m m .

221

155.6

...

11

1505

244.8

...
...

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

11

CAoO
C H 0

Cyclohexanone

1506

1507
1508

C H O
C H 0
CgH^Ojj

M e s i t y l Oxide
4 - M ethyl - 2 - pentanone
4 - H y d r o x y- 4- m e t h y l 2-pentanone
3-Hepten-2-one
4-Methyl - 2-pentyl
acetate
2,6-Dimethyl-4heptanone

Cyclohexanol,

1 2

1 0

1 2

1509
1510

C H

1 2

1511

CgHigO

C6H12

C H
C H

1514
1515
1516
1517
1*518

C6H13N

1519

=
1520
1521

^6
C

C H
7

C H
6

1523

q,H

l P 2

C H
6

Toluene

1524

Methylcyclopentane
H e x a n e , 200-760 m m .

12

6 14

1 4

1 2

8 162
H

1525

=
1526
1527
1528

COH
Q H
C H

1 2

1 4

O
0

8 18
H

Butyl Acetate
s e c - B u t y l acetate
2 -Butoxyethanol
Butyl ether

98,
98,
98,
98,
98,
98,

99
99
99
99
99
99

109
57.5
137
69.5
165
76.8
196
92
209
96
Nonazeotrope

98,
98,
98,
98,
98,
98,

99
99
99
99
99
99

Nonazeotrope

-1

57

334
334

146.1

Nonazeotrope

334

169.4

Nonazeotrope

334

Nonazeotrope

334

80.85

.. .
.. .
68.95
110.7
80.5
98.4

71.72
68.95
110.7

. .

4-Methyl-2-pentyl
acetate
2,6-Dimethyl-4heptanone

115
68.2
136
75.2
166
89.7
187
96.4
198
98.7
Nonazeotrope

Nonazeotrope
Nonazeotrope

Cyclohexanol
161
Cyclohexyl formate,
50 m m .
Cyclohexyl vinyl ether,
45 m m .
4-Methyl-2pentanone

Ref.

169.2
162.9

80.8

Wt.%A

334

2,2,3 - T r i m e t h y l b u t a n e

Data

Nonazeotrope

7 16

1 2

B.P.,C.

SERIES

128.3
116.2

7 16
7 16

6 14
C H
C

...

161.1

1 2

1522

0
0

241.1

Cyclohexanol
4-Methyl-2-pentanone,
450-760 m m .
Cyclohexylamine
Hexane
Toluene
2,4 - D i m e t h y l p e n t a n e
Heptane

100 m m .

Cyclohexane

1512
1513

CHEMISTRY

-1
-1
-1
-1

-1

Nonazeotrope

-1

Nonazeotrope

-1

Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
80.2
48.6

80.0

V
V
V

46.6

66
242
231
230
214
52,
231
214

85,
231
230

79.4

50

147

71-80

21

341

116.2

146.1

Nonazeotrope

334

169.4

Nonazeotrope

334

Nonazeotrope
Nonazeotrope
125.9
95

334
334
334

126.1
112.2
171.1
142.1

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

TABLE

BINARY

51

SYSTEMS
Azeotropic

B-Component
No.

Formula

A =
1529

C H
C H

1530

C H

1 7

1531

NO

C H
9

0
O

1 2

S 0

1532
C

15 18

16 34

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1533

1534

A =

C H

151
142

75
75

225
225

Perfluoroheptane,
crit. region
Toluene
150-760 m m .
Methylcyclohexane

1 7

C H
8

Nonazeotrope
Nonazeotrope

113
113

77
92

Hexyl A l c o h o l
2-Ethylbutyl acetate

157.1
162.3

154.4

A =

CA4O

Isopropyl E t h e r
1,2- D i e t h o x y e t h a n e

68.3
121.1

Nonazeotrope

334

C H
8

4-Methy 1-2 -pentanol


4 -Methyl - 2- pentyl
acetate

131.8
Nonazeotrope

334

C H
8

Min. b.p.

329

02

1 6

O S

1 6

OS

C H 0
C H
C Hi6
Ci Hi
CioHu
Ci H
Ci H
CioH o
C H
CioH
CioH o
6

1 4

1 2

1 4

1 4

1 0

2 0

2 0

CIQH O
2

2 -Buty lthioethanol
2-Butylthioethyl vinyl
ether
2-Butoxyethanol
Cumene
cis -Hexahydroindan
Butylbenzene
sec-Butylbenzene
tert- Butylbenzene
p-Cymene
n- Butylcyclohexane
sec-Butylcyclohexane
Isobutylcyclohexane
cis-1 -Methyl -4 isopropylcyclohexane
trans-1 -methyl - 4 isopropylcyclohexane

!7
...

146.1

...
171.2
152.4
167.7
183.4
173.3
169.1
177.2
180.95
179.3
171.3

151.7
159.9
169.6
166.0
164.4
167.4
165.6
165.1
161.5

172.7

170.5

v-1

155
52
229
52,
231

89
106.9

1 4

68.95

Nonazeotrope

C6H 0
C Hi 0

1556

124
139
138.4

147.0
163.6

A =
1543

A =
1546
1547
1548
1549
1550
1551
1552
1553
1554
1555

334

2-Ethyl-l-butanol
2-Ethylhexaldehyde
3-(Chloromethyl)
heptane, 50m m .
100 m m .

1 4

11

1545

Nonazeotrope

101.15

C H 0
C H
0
C H C1
6

A =

156.2
110.6

Azeotropic
Nonazeotrope
Nonazeotrope
Nonazeotrope

1539

1544

b.p.

2,4-Dimethylsulfolane
A m y l naphthalene,
20 m m .
H e x a d e c a n e , 20m m .

Hexane

1538

1542

Max.

v - 1 289

353

m-Xylene
p-Xylene

C7F16

A =

Nonazeotrope

25

Paraldehyde

8 10
8 10

1537

1540
1541

205.15

Ref.

<80

Toluene

C . B.P., C. Wt.%A

4-Hydroxy-4-methyl
166
2-Pentanone
x - E t h y l t o l u e n e , 20m m .

2-Ethoxyethyl Acetate

CHI 03
7

1535
1536

Hexanoic A c i d
Octanoic acid,
20-100 m m .
N,N-Dimethylhexana m i d e , 100 m m .

B.P.,

C H
C6Hi 03

A =

Name

Data

v-1
v-1

334
335
335

61
68

335

72.5

%
%
%

168
291
168
168
168
168
291
291
291

162.0

45 v o l . %

291

160.9

41 v o l . %

291

10.3
38 v o l .
73.4
47.9
39.1
56.6
56 v o l .
53 v o l .
40 v o l .

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

52

ADVANCES

IN

Azeotropic

B-Component
No.
A =

C H
6

1557

A =

1 4

C HH0
6

C 3 H 1 0

1559

C H

1560
1561
A =
1562

C H
6

Naphthalene
2 - Methylnaphthalene

CJJH^Q
6

C H
8

A =
1564

C H O
C H N
6

155.5

1567

1568
A =
1569

A =
1570
1571
1572
1573
A =
1574
A =
1575
1576

C
C

H
H

1 0

Cj Hio
4

C H
6

C H
9

C F
7

N0

N0

CVH
C F
C H
C H

C H60

1 2

1 0

l,l -Iminodi-2-propanol
t

l,l',l"-Nitrilotri-2propanol, 10m m .

Phenyl ether, 100 m m .


Toluene
p-Cresol
ethylcyclohexane

291

Nonazeotrope

v-1

271

218.1

142.9

v-1

204

241.1

Nonazeotrope

98

Nonazeotrope
Nonazeotrope
Nonazeotrope

334

Nonazeotrope
Min. b.p.
Nonazeotrope
Nonazeotrope
Min. b.p.

100
334

Min.

100

288.7

Benzoic A c i d

C H
C H 0
C H
7

23 v o l . %

151.6

271

Triethylene G l y c o l

Perfluoroheptane
Heptane, crit. region
Perfluorocyclic oxide
Octane, crit. region
Nonane, crit. region

1 6

Ref.

v-1

202.8

Carbazole
L o w press.
Phenyl ether, 4 m m .
Fluorene
"
High press.
Phenanthrene,
Low
press.
Glycol decreases with
Benzyl ether, 5 m m .

1 2

B . P . , C . Wt.%A

Nonazeotrope

188.4
72
241.1

294

11

1565
1566

Data

171.2

2 - (2 -Ethoxyethoxy )
ethanol
Bis (2- ethoxyethyl)
ether
10 m m .
2- M e t h y l n a p h t h a l e n e
M

1563

SERIES

Dipropylene G l y c o l

C H

B.P.,C.

Hexylene G l y c o l
Ethylbenzene, 400 m m .
Ethylcyclohexane,
400 m m .

CioH

Name
2 -Butoxy ethanol
(continued)
3,3,5-Trimethylheptane

C10H22

1558

A =

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula

CHEMISTRY

102
294

340

12.4

334
98

100
100
100

b.p.

decreasing pressure
145.5
. . .
28

335

133/10
1
1 77
77

Nonazeotrope

334

82.5
102!6

Azeotropic
Nonazeotrope
Azeotropic
Nonazeotrope

v-1
v-1
v-1
v-1

155
354
155
155

189/100 m m .
181

176.5

27

76

110.7
201.7
101.1

Nonazeotrope
Nonazeotrope

v-1
v-1

213
114,
309

60-100 C.
1577
1578

C H
C HnN

1579
1580
1581
1582

C Hie
C Hi8
C H O
Ci H 0

A =
1583

A =
1584

1 0

2 2

C H O
7

1 0

C H 0
C H O
7

Benzyl Alcohol

C H

98

m - C resol
2

Ethyl

benzoate

297
114

99.3
217.3

Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope

225.5

Nonazeotrope

334

103

341

78.3

334

v-1
v-1

266
52
334

205.2

Benzyl vinyl ether,


25 m m .

Heptane
2-Methyl-5-ethylpyridine
1
Iso- octane
2,2,4-Trimethylpentane
Decyl alcohol (isomers)
2,6,8-Trimethyl4-nonanol

Evaporation data
Evaporation data v - 1

202.2
212.4

26.6

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

112

TABLE

BINARY

SYSTEMS

53

B-Component
No.
A

Name

B.P.,C.

B.P.,C. W t . % A

o-Cresol
s-Collidine

191
171.30

197.20

C H 0
C H N

202
163
157
142-5

204.9
204.4
202.5

202
71.8
Nonazeotrope

212
98

24.5

112

1586
1587
1588

C H N

x-Cresol
Pyridine
Pyridine
Pyridine

1589
1590

C H 0
CioH
CnHio

m,p-Cresols
Naphthalene
2- Methylnaphthalene

202
218.1
241.15

1591

C HeO
C H O

D-Cresol
Ethyl benzoate

201.7
212.4

CjHN
C HnN

N-Methylaniline
N,N-Dimethylaniline, 95 - 1 4 5

196.25

1592

2,6-Lutidine
Decane

143.41
174.0

o-Toluidine
D i e t h y l - 0- t o l u i d i n e ,
20 m m .

200.7

Methylcyclohexane

100.93
98

O 7 H 9 N
7

1 0

C7H9N

A
1593

1594

C H9N
C H
N

10 22
H

C Hi4

1595

C F

1597

C Hi 0
C H NO

C H
C F
H

1600

C H

1 6

11 10

1 6

C F
1602
1603
1604

C H
1601

1 9

1598
1599

Perfluorocyclic

1 6

C H C1
8

1605

C ^ Q O S

C H
C H
8

1606

1607

C Hio
8

A
1608

11 10
H

oxide

Heptanoic A c i d
N,N-Dimethylheptanamide

102.5

188

63.0

367
367
367

78
80
90

Nonazeotrope

v-1

59

Nonazeotrope

v-1

358

95.8

Nonazeotrope
85

173

48

40 v o l .

v-1

114,
309
207

222.0
Max. b.p.

295

Heptane
98
P e r fluor obutyl ether
100
136.15
Ethylbenzene
"
100-760 m m .
2,2,4- T r imethylpentane 9S

Min. b.p.
Nonazeotrope
Nonazeotrope
Nonazeotrope

50
52
229
52

Dipropylene G l y c o l
Methyl Ether
2- Methylnaphthalene

Nonazeotrope

241.15

P e r f l u o r o c y c l i c Oxide
102.5
131.78
Ethylcyclohexane
2,2,4- T r i m e t h y l p e n t a n e 99.24
2,3,4- T r i m e t h y l h e x a n e 131.34

e 16
H i
C H o
C

bases
bases
bases

Heptane

7 16

1596
A

Ref.

C H 0
QHiiN
7

1585

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula

Azeotropic Data

ar-Trichlorostyrene
2 - (2-Isoamyloxyethoxy )
ethanol, 6.7m m .
Styrene
Ethylbenzene,
10-100 m m .
"
30-120 C .
X y l e n e , 20 m m .
Methyl Salicylate
2- Methylnaphthalene

96.3
87.5
98.4

v-1

98

80 v o l . %
60 v o l . %
80 v o l . %

207
207
207

49

101
145

50'
222.3
241.15

Nonazeotrope

v-1

Nonazeotrope
Nonazeotrope

v-1

Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

40,
110
156
334

98

54

ADVANCES

IN C H E M I S T R Y

Azeotropic Data

B-Component
No.

Formula

A =
1609

CeHio
C Hi6

1610
1611

C Hi6
C Hi

C 9 H 1 2
C 9 H 2 0

1614

C 9 H 2 0

B.P./C.

B . P . / C .

Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope
Nonazeotrope

Nonazeotrope
139.0
96.1

CgH
C Hi 0
C Hi 0

m-Xylene
2-Ethyl-1 -hexanol
2-Ethylheptanal

139
184.8

A =

C H

C 9 H 2 0

o-Xylene
Nonane

143.6
150.7

C Hio
C H

p-Xylene
Octane

138.4
125.75

B i s (2 - v i n y loxy ethyl)
Ether
B i s (2-ethoxyethyl )
e t h e r , 10 m m .

196.5/10 m m .

10

A =
1618

A=

1 0

1 8

QH14O3
1619

A =

C H
8

C H
8

1620

A =

1 6

C9H

A =

2- Ethylhexanoic A c i d
2-Methylnaphthalene

C Hi 0

Octanoic A c i d
N , N - Dimethyloctana m i d e , 100 m m .

C 1 0 H 2 1 N O

CeHieOs
1623

A =

llHio

C H C1
8

1624

A =
1627
1628
1629

A =

1 8

Cl2Sn

C H ClSn
1 2

2 7

C10H20O2
C 1 1 H 2 5 N

C 1 0 H 2 0 O

C 1 0 H 2 0 O S

Octyl A l c o h o l
Octyl vinyl ether,
5 mm.
2-Hexylthioethanol
2-Hexylthioethyl vinyl
ether

v-1
v-1

v-1

372

81

Nonazeotrope

271
342
52
334
363
342

334
52

52

Nonazeotrope

v-1

Nonazeotrope

334

<50

98

241.15
238.5
187

241.15

190

26.0

Nonazeotrope

295

98

106.9/100 m m .

124.8

106

98

335

157/17

166

2-Ethyl-l-hexanol
184.8
Nonane
150.8
2-Ethylhexyl acetate
198.4
(2-Ethylhexyl)
p r o p y l a m i n e , 50 m m . 147

C 9 H 2 0

CJHIJOS

1631

Dibutyltin
Dichloride
Tributyltin chloride,
17 m m .

169.4

CeHieO

A =

3- (Chloromethyl)
heptane
2-Ethyl-1 -hexanol,
100 m m .

144.25

Ref.

146.1

Butyl Ether
2-Ethyl-1 -hexanol

C Hi 0
1630

2 -(2 -Ethoxyethoxy )
E t h y l Acetate
2- Methylnaphthalene

187.8

C Hi 0
C ^ O
8

1626

A =

1 7

C Hi 0

C H
1625

1,3-Dimethylbutyl
Acetate
2,6-Dimethyl-4heptanone

C Hi 02
C H

1622

A =

1 8

1621

Wt.%A

Ethylbenzene
136.15
Ethylcyclohexane,
400 m m .
121.6
1-Octene
125.75
Octane
152.4
Cumene
150.7
Nonane
2,2,5-Trimethylhexane 120.1

A =
1615
1616

1617

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1612
1613

Name

SERIES

142.1
184.8

Nonazeotrope

334

Nonazeotrope

334

Nonazeotrope
Nonazeotrope

334
334

Nonazeotrope

334

195.15
64

64

17

Min. b.p.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

341

329

TABLE

BINARY

55

SYSTEMS
Azeotropic Data

B-Component
No.

C8H

A=
1632

A =

1 8

1 6

3 4

C^oHg
C H
n

CnHio

1636

Ci H g

B.P.,C.

2-(2-Butoxyethoxy)
ethanol
Naphthalene, 100 m m .
1 - Methylnaphtha
l e n e , 20 m m .
"
100 m m .
"
200 m m .
2- Methylnaphtha
lene, 20 m m .
"
100 m m .

1635

Name

2-Ethyl-l,3243.1
hexanediol
Bis(2-ethylhexyl)ether,
10 m m .
135
269.8

CeHie03

1633
1634

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Formula

M
2

Dodecane, 100 m m .
1-Pentadecene,
217 m m .

1 6 3 7 C15H30
Cc,F N

A=

T r i s (per fluor opropyl)


amine
Cumene

2 1

1 6 3 8 C9H12
C9H N 0

A=

1639

A =

0962

C9H7N

B.P.,C. W t . % A

123
241

Ref.

40

335
335

231.2
144.35

Nonazeotrope

v-1

144

46.8
64.3
74

98
98
98
98
98
98
144

241.15
146.2

142.6

38
53.5
82
34

183.7

185.16

87 v o l . %

v-1

291

130
152

2,4-Tolylene
Diisocyanate
2,6-Tolylene di
isocyanate, 5-60 m m .

51

116

Nonazeotrope

v-1

53

Isoquinoline

1640

CnHio

2 - M e t h y l n a p h t h a l ene

241.15

<50

98

A =
1641

C H N
C H

Quinoline
2- Methylnaphthalene

237.3
241.15

>50

98

E t h y l Salicylate
Phenyl ether, 5 m m .
"
50 m m .
"
180 m m .

233.7

A =

C9HK1O3

1S42

A -

1643

A =

1644

A =
1645

A =

1 2

1 0

C9H12
C

C9H
C H
9

Mesitylene
1,2,4-Trimethylbenzene

12

1 2

C H OS
C H OS
9

1 2

1 4

C9H 0
14

1646

A =
1647

A =
1648

C H
C F
9

1 8

C9H20
C

Cumene
T r i s (per fluorobutyl )
amine

Nonazeotrope
Nonazeotrope
Nonazeotrope

177

118
118
118

138

51

Nonazeotrope

96

164.7
169.2

2-Benzylthio ethanol
2 -Benzylthioethyl
vinyl ether
Isophorone
2- Methylnaphthalene

v-1
v-1
v-1

329

Min. b.p.

241.15

Propycyclohexane
Per fluor otributyl amine

156.72

Nonane
Perfluorotributylamine

151

178.4

177

Nonazeotrope

145.4

55 v o l . %

Min. b.p.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

98

207

50

56

ADVANCES

IN

Azeotropic

B-Component
No.

A =
1649

Formula

C9H20O
C

Name
2,6-Dimethyl4-heptanol
2,6,8-Trimethylnonene, 8 m m .
52 m m .

B.P.,C.

C9H20O4

1650

1 2

H N

1651

294

A =
1653

CioH
Ci H g

Naphthalene
Dodecane, 100 m m .

A =
1654

CioHie
C H

Decahydronaphthalene
D e c a n e , 10 m m .
"
20 m m .
"
50 m m .

A =
1655

C H O
Ci H O

Menthone
Menthol, 5m m .
"
50 m m .
"
180 m m .

209.5

A =

CioH

3,3,5-Trimethylheptane
Perfluorotributyl amine

155.68

Decyl Alcohol
Dodecyl alcohol, 20,
50, 100, 300 m m .

232.9

1656

1 0

1 8

2 0

2 2

C^()H 0

22

1657

A =
1658

A =
1659
A =
1660

1 2

Q H
0

1 2

2 6

2 2

OS

H2 OS
4

CioH 04
22

CnHio
CnHio
C

218.1

178.4

241.15

1-Methylnaphthalene
5 - Ethyl - 2- nonanol,
19 m m .
50 m m .
150 m m .
"
200 m m .
"
400 m m .

244.8

2 -Methylnaphthalene
5- Ethyl - 2- nonanol,
20 m m .
"
50 m m .
"
90 m m .
"
200 m m .
"
300 m m .
400 m m .

241.1

CnH
C H
u

, f

Ref.

334
334

100
100
100
100
100
100

59.2

140.2

v-1

144,
204

Nonazeotrope
Nonazeotrope
Nonazeotrope

v-1
v-1
v-1

309
309
309

Nonazeotrope
Nonazeotrope
Nonazeotrope

v-1
v-1
v-1

118
118
118

55 v o l . %

147.3

system

v-1

207

290

329

Min. b.p.

11

A =
1661

Wt.%A

Nonazeotrope
Min. b.p.
Min. b.p.
Nonazeotrope
Min. b.p.
% glycol decreases
with decreasing
pressure

Ideal

2-(2-Ethylhexylthio)
ethanol
2-(2-Ethylhexylthio)
ethyl vinyl ether
Tripropylene Glycol
Methyl E t h e r
2- Methylnaphthalene

Data

18
32

56
95

11

1 6 5 2 C14H10

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Tripropylene G l y c o l
Carbazole
L o w press.
Fluorene, high press.
"
L o w press.
Phenanthrene

B.P.,C.

SERIES

104/52

11

A =

CHEMISTRY

98

<50

41.4
121
25.2
143
5.25
173
2
179.5
Nonazeotrope

98,
98,
98,
98,
98,

99
99
99
99
99

49.8
120
36.0
140.5
24.5
157
9.0
181.5
3.5
193.5
Nonazeotrope

98,
98,
98,
98,
98,
98,

99
99
99
99
99
99

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

TABLE

BINARY

57

SYSTEMS
Azeotropic

B-Component
No.

A =

Formula

C12H9N

1662

1 4

3 0

Name

B.P.,C.

Carbazole
Tetradecanol
Low press.
Heptadecanol
"
Low press.

355

A -

1664

Ci H
C H

A =
1665

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

=
1666

A =

1667

1 0

2 4

C
C

i 2

1 2

3 8

H
H

Biphenyl
Dioctyl phthalate,
10 m m .

255.9

2 4

2,6,8-Trimethylnonene
2,6,8-Trimethyl4 - n o n a n o l , 50 m m .
"
10 m m .
Dodecane
Hexadecane,
10-760

2 6

C 1 6 H 3 4

C13H10
q H
4

A =
1669

C
C

1 4

1670

A =
1671

C
C

A =
1672

Ci H3 0
C H 03

1 4

1 6

1 8

H
H

3 0

H
H

3 6

1 0

248

Nonazeotrope

334

137
103

Nonazeotrope
Nonazeotrope

334
334

216
Nonazeotrope

mm.

Fluorene
Tetradecanol,
Low press.
High press.
Heptadecanol,
Low press.
"
High press.

294

Phenanthrene

340

3 2

1 8

Tetradecanol

Heptadecanol

0
0
4

3 4

1673

Ci H3^D

1674

C 2 0 H 3 0 Q 2

Oleic A c i d
Ricinoleic acid,
5 mm.
Stearic acid,
5 mm.
Abietic acid,
1-10 m m .

v-1

163

Nonazeotrope
M i n . b.p.

100
100

Nonazeotrope
M i n . b.p.

100
100

% Phenanthrene i n
creases with pres
sure; m i n . b.p.
% Phenanthrene i n
creases with pres
sure; m i n . b.p.

100

Palmitic A c i d
Stearic acid, 5 m m .

Ref.

100
100
100
100

11

1668

Wt.%A

Nonazeotrope
M i n . b.p.
Nonazeotrope
M i n . b.p.

11

1663

B.P.,C.

Data

Nonazeotrope

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

100

v-1

139

v-1

139

v-1

139

v - 1 166

ADVANCES

IN

CHEMISTRY

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

58

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

SERIES

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

1692
1693

Water
Water

Water
Water

Water

Water
Water
Water
Water
Water
Water
Water
Water
Water

Hydrogen
chloride
Hydrogen
fluoride
Nitric acid
Water

Argon
Carbon
monoxide
Chlorine
trifLuoride

Name

20 atm. to critical point.


20 p.s.i.g.

1694
1695

1691

H 2 O

H o O

1682
1683
1684
1685
1686
1687
1688
1689
1690

HF

1679

H N 0 3

c m

1678

1680
1681

C 1 F

1677

A
CO

1675
1676

Formula

No.

A-Component

100

100

100

100

100

100

C H

C H

C H

C H

C H

CH N0

C H

C H C I 3

C H

100

100

CHCI3
CHCI3

100

100

100

C H C I 3

C H C I 3

100

CHCl,

100

100

so

...

C H N

100

FH

N
H

Formula

19.5

-85

-185.7
-192

B.P.,
C

19.4

115.5
100

Hydrogen
fluoride
Pyridine
Water

64.3

64.7
64.7
64.7
64.7

Methanol
Methanol
Methanol
Methanol

H F
7

C H
3

101

C HeO
3

C l 3 F

CJHJO
C H 0

C H N
CaHgO
5

100.75

Ca^O
C ^ O

C H 0

C H N

C H

C H 0

CHCl 3

10 8

F U

o
N

0
2

Formula

100.75

61
61
61
61
61
61

- 1 0

Water
Sulfur
dioxide
Chloroform
Chloroform
Chloroform
Chloroform
Chloroform
Chloroform
F o r m i c acid
F o r m i c acid
Nit ro meth
ane
Methanol
100

-195.8
-252.7

B.P.,
C.

Perfluorobutyric acid
Chloroform
61
Acetalde20.2
hyde
F o r m i c acid
100.75
Methanol
64.7
81.6
Acetonitrile
Acetic acid
118.1
78.3
Ethyl alcohol
79.6
2-Butanone
Acetic acid
118.1
Pyridine
115.5
Isopropyl
82.3
alcohol
47.5
1,1,2-Trichlorotrifluoroethane
Ethyl alcohol
78.3
Propionalde47.9
hyde
M e t h y l a c e t a t e 57.1
Isopropyl
82.3

218.1

56

-183
-195.8

Oxygen
Nitrogen
Uranium
hexafluo
ride
Naphthalene

B.P.,
C.

Name

C-Component

Ternary Systems

Nitrogen
Hydrogen

Name

B-Component

T a b l e II.

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

39.4

78.0

52.6

108

189.6

B.P.,
C.

28

60

3.0

Nonazeotrope
Nonazeotrope

Nonazeotrope
Nonazeotrope

0.6

96.4

Nonazeotrope
81
15
Nonazeotrope
Nonazeotrope
3.9
91.2
4.9
Nonazeotrope
Nonazeotrope
Nonazeotrope
11.7
36.8
51.5
4

92

12

Nonazeotrope

Nonazeotrope

v-1

v-1

v-1
v-1

v-1

v-1

v-1

v-1

v-1
v-1

Data

Composition, Wt. %
A
B
C

Azeotropic

58
334

68
334

335

56
335
334
56
335
334
56
360
176

258
273

222

322

91,292

97,194
2

Ref.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

Water

Water

Water

Water

Water

Water

Water
Water
Water

Water
Water

Water

Water

Water

Water

Water
Water

Water
Water
Water

H 0

H 0

H 0

H 0

H 0

H 0
H 0
H 0

H 0
H 0

H 0

H 0

H 0

H 0

H 0

H 0
H 0
H 0

1698

1699

1700

1701

1702

1703
1704
1705

1706
1707

1708

1709

1710

1711

1712

1713
1714
1715

H 0

1697

Name

Water

Formula

HzO

1696

No.

A-Component

100
100
100

100

100

100

100

100

100
100

100
100
100

.00

100

100

C H 0

CzHgO
C H G

C H 0

C H C10

C H 0

C H 0

C H C1

C H N
C H C1

C H N
C H N
C H N

C HC1

C HC1

C HC1

C C1 F

100

CH 0

100

CH 0

100

Formula

CH 0

100

B.P.,
C.

Ethyl alcohol
Ethyl alcohol
Ethyl alcohol

Acetonitrile
1,2-Dichloro
ethane
1,2-Dichloro
ethane
Acetaldehyde
Acetaldehyde
2-Chloroethanol
Ethyl alcohol
Ethyl alcohol

47.5

78.3
78.3
78.3

78.3

128.7

C H 0

C H N

C H

6 123

20.2

C H 0
2

C H 0

C H 0

1 5

C H

C H N
C H O

C H 0

20.2

83.5

81.6
83.5

81.6
81.6
81.6

C H 0

86.2
8

3^0

86.2
3

C H 0
6

86.2
3

C H 0

4 10
H

1,1,2-Trichlorotrifluoroethane
Trichloroethylene
Trichloroethylene
Trichloroethylene
Acetonitrile
Acetonitrile
Acetonitrile

64.7

Methanol

C H 0

64.7

Methanol

Formula

C H 0

64.7

B.P.,
C.

Methanol

Name

B-Component

71.4

97.1

Azeotropic

Data

69.7

82.3

77.2

Acrylonitrile
Acrylonitrile
"
100
Acetone
Ethyl formate
Crotonaldehyde

mm.
56.1
54.2
102.4

80.1

124

78.0

<30

69.5

68.6
67.8
89.7
78.3

v-1

334
335

6
7.2

59

78.3

335
334
334

44
55
Nonazeotrope
5
13
82

73.3

31
77.1

...

19.0

63
15.7

20.3

71.0
6.6
9.0
84.4
Nonazeotrope
Nonazeotrope
4.8
87.9
7.3

8.7

Nonazeotrope

Nonazeotrope

7.7

335
334
334
335

335

334

334

133

335

335
72.9

20

78.3
55.5
68.3

73

176

334

335

69.4

8.1

12.5

95.5

82.3

84.8

80

3.9

334

84

334

Ref.

7.1

7.5

0.6

Nonazeotrope

Nonazeotrope

Nonazeotrope

Composition, Wt. %
A

97.3

Benzene

Paraldehyde

Isopropyl
alcohol
Ethyl alcohol

Propyl
alcohol
Isopropyl
alcohol
Ethyl alcohol
Diethylamine
Isopropyl
ether
Triethylamine
Ethyl alcohol

alcohol

Allyl

-11.7

79.85

42.6

B.P.,
C.

78.3

80.9

B.P.,
C.

Methyl
acrylate
Methyl
propionate
2-Methylpropane
Ethyl alcohol

Name

C-Component

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

TABLE

II

TERNARY

61

ri

lowing

m m
co co
co co

CO CO CO CO
CO CO CO CO

i f

+e

r-i

SYSTEMS

rH

co

in

m co co co

H H ( N

in

CM

CO*

Tf* rH* rt*

i-H r H

CO
CO CO CO
s

H H H

r H CO 00
C- CO CO

CO 05
d

CD H O )

cd

ul

O CM co co
CO CO CO COC
CO CO CO CO
co co co co

co co co

CO

m ^ m c-

in in in

co m m

m m

co co

r-i r H

CO

^ ai

CM CM

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

co"

te
' .

co

PQ

4-i
2

Cd

rH

.St
rt

I f

-rL

PQ H

cd

t-

CD C
O C
O
d

53
W

rH
^

St

L
b)

S >

fi

Cd " ^ r< \ C ^
^ "S s L >

> cd 7

ml

pq

co*"1

CO

S _
CM

en

t e a l
C
O "S
PC c o

cd

Pu

oo

* A

00 S B

CO CO CO
CO CO CO

pH C
O

oV

pq

1313


es

Sf

u
CO CO
CO CO

t>

CO CO CO
CO 00 CO
c-

CO
CO

If
m

CO
CO

0
0

se

CM

VO

CO
CO

nf

d
CO
CO

CO
CO

1313

13

13

73
>>

>>

-5

-S

a?
d

CO
CO

t-

sf

'cTcT

CO
00

CO
CO

CO
CO

CO CO
00 CO

c-

E"-

*c3

13

>>

>

eo i-i

VO

13 *c3

X
i-

eo

13

13 73

OO

OO

cd

Pu

OO
*

OO
es es

VO.

VO

. VO.

es es CM

VO

cd
cd cd

cd cd

cd

&

cd

cd

cd

cd cd

cd cd

S*

-3
S

OO
CD C-

OO
O O O O O O O O O O O
cscscscscscsescs
es .es es

OO OO
es es es es

XX

0 ) 0
r H CM

CM

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

XX
co ^
co co

XX
i n co
co co

ADVANCES

62
CO CO
CO CO

u
+-

I n co

CM CO

u
+-

cd

<
U

cd

rH rH
"8

-->

C- CO CO
li CO CO

co

CO

rH

IN C H E M I S T R Y

rH

rH <

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

ne

c c

ne

ne

ne

ne


Xi Xi Xi

r H r H I
r H r H I

< < << < < < <!<<

VO VO

EE

es

55

CM

(fes

"

CO

EE

ve VO VO

VO

VO

CO

OOO

U U U

co

jz

Id Id

rH

OO
EE
C- 00
CO CO

cd

es

es

es

es

es

es

"cd

cd

cd

cd

EE
co

00 rt<

m m m
i> c - t

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

SERIES

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

C H 0

C H 0

C H 0

C H O

C H O

C H 0

C H O

C H O

C H O

100

100

100

100

100

100

100

100

100

Water

Water

Water

Water

Water

Water

Water

Water

Water

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

1759

1760

1761

1762

1763

1764

1765

17.66

1767

1768

1769

1770

1771

C,H 0

100

Water

H 0

1758

C H 0

100

Water

C H Q

100

Water

Propyl
alcohol
Propyl
alcohol

It

C H 0

100

Water

It

fl

Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Propyl
alcohol
Propyl
alcohol
Propyl
alcohol

II

II

It

Propionic
acid
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol
Isopropyl
alcohol

Name

B-Component

II

II

II

II

II

C H 0

100

Water

H 0

1757

100

Water

C H 0

100

Water

H 0

Formula

1756

B.P.,
C.

Formula

No.

Name

-Component

97.3

97.3

97.3

12

102

1 0

C H

97.3
5

C H S

97.3

8 14

1 5

C H

82.3

82.3

82.3

C H O

C H O

82.3

1 2

82.3

C H

82.3

10

C H

82.3

C H N

82.3
82.3

C H 0

82.3

C H 0

140.7
4

Formula

B.P.,
C.

77.8

Butylamine

Cyclohexane

Benzene

11

Propyl
acetate
"
"

Diisobutyl
ene
1-Propane
diol
3-Pentanone

Data

81.2

50.23
66.07
76.26
82.45
68.5

101.8
101.6
200 m m .
400 m m .
600 m m .
760 m m .
80.1

66.6

60.8

67.5

76.3

5
6
6

9.3

13.1

67.7

20

31.6

38.2

60

59.1

48.7

8.5

10.0

81.5

Nonazeotrope
13.3
4.7
82.0
15.0
78.5
6.5
75.5
16.0
8.5
73.0
17.0
10.0
82.4
9.0
8.6

20

21.9

4
91
9
85
7
87
Nonazeotrope

10.4

73.4
61.8
95
81

76

47

88

8.2
19.8
72.
10
18
72
Nonazeotrope

13

40.5

65.7
90

12.5

11

Nonazeotrope

11

72.3

80.7

Azeotropic
Composition, Wt. %
A

75.5

83

73.4

B.P.,
C.

102.3

88.7
Isopropyl
acetate
80.1
Benzene
"
20 p . s . i . g .
4-Methyl116.2
2-pentanone
Butyl ethyl
92.2
ether
68.3
Isopropyl
ether
30 p . s . i . g .
15 p . s . i . g .
84.1
Diisopropylamine
110.6
Toluene

79.6

79.85

B.P.,
C.

Methyl
propionate
2-Butanone

Name

C-Component

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

v --1
V " -1
v --1
v --1
v --1

84

334

264
308
308
308
308
334

334

181

335

335

335
335
335
334

335

335
335
334

335

335

335

Ref.

H 2 O

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H 0

H O

H 0

H 0

H 0

H
H
H
H

H 0

H 0

1773

1774

1775

1776

1777

1778

1779

1780
1781
1782
1783

1784

1785

1786

1787

1788

1789

1790

1791

1792

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

0
0
0
0

H 0

Formula

1772

No.

C H 0

C H O

100

C H 0

100

Water

Water

Water

Water

Water

Water

Water

Water

Water

Water
Water
Water
Water

Water

Water

Water

C H 0

C H O

C H

C H

C H

100

100

100

100

1 0

1 0

1 0

1 0

1 0

1 0

C H

100

100

C H

100

0
0
O
0

100

C H 0

H
H
H
H

100

C
C
C
C

C H 0

C H 0

100

100

8 2

C H 0

100

Water

100

100

Water

C H O

100

Formu

B.P.,
C.

Water

Water

Water

Name

A-Component

Propyl
alcohol
Propyl
alcohol
Propyl
alcohol
2-Methoxyethanol
2-Methoxyethanol
2-Me thoxyethanol
1 , 2 - P r o p a n e diol
Crotonaldehyde
2-Butanone
2-Butanone
2-Butanone
Butyr alde
hyde
Butyr alde
hyde
Butyr alde
hyde
Butyraldehyde
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol

Name

B-Component

117.75

117.75

117.75

117.7

117.7

117.7

74.8

74.8

74.8

79.6
79.6
79.6
74.8

1 0

6 14

C H

1 2

l z

C H
6

C H N

C4H10 s

6 14

6 122

U
1 0

4 102

C H

1 0

6 6
6 12

C H
C H

12

162

C H

C H
7

187.8

l z

C Hi20

C H

Formula

102.4

124.6

124.6

124.6

97.3

97.3

97.3

B.P.,
C.

86
87.6

118.3
146.6

2-Methylpentanal
Dipropoxyethane
Benzene

Butyl vinyl
ether
Butyl
acetate
Hexane

sec-Butyl
alcohol
1-Butanethiol
Butylamine

2-Ethylcrotonaldehyde
Benzene
Cyclohexane
Hexane
Isobutyl
alcohol
1,1-Dimethoxyethane
Butyl
acetate
Hexane

Toluene

Toluene

Cyclohexane

58
51.6

28
27.4

21.0

14

10

2.9

19.2
61.5
68.95

29

90.7
126.1

10

77.9

63

88

Nonazeotrope
77.4

78.6

Nonazeotrope

94.2

77.8

97.5

99.5

75

21

68.7

Nonazeotrope

126.1
55

Nonazeotrope

8.8
26.1
65.1
5
35
60
1
22
77
Nonazeotrope

Nonazeotrope

64.5

80.1
80.7
68.7
107.9

135.3

Nonazeotrope

Nonazeotrope

110.6

Nonazeotrope

63

27

Nonazeotrope

110.6

Data

Composition, Wt. %
A
B
C

Azeotropic

80.7

68.2
63.6
55

87

127.2

2-Hexanone

80.1

B.P.,
C.

Name

B.P.,
C.

C-Component

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

oooo

174

335

335

334

181

334

334

334

334

334
334
334
334

334

334

334

334

334

334

334

123

Ref.

U
m
je
m

-<

H
79

m
</

>

TABLE

II

TERNARY

SYSTEMS

^
CO co CO
co co co

CO TjH
I> CO
rH

eu

EtH

65

CO
00

I> E> I> > "tf


CO CO CO CO co

co
00

CM

CO

CO

CM

m
co

co
co

co
co

co
co

m *
c o

CO CM

CD

O i rH
CM co

rH

rH

co

CM CO CO

CO

PQ

CO*
co

I>

rH

m*
CM

rH

142.
100 m

147
100 m
98.

in
CM

Oi

m
Oi -HH

00

-rjH I>

C
cd

oo o

m in

rH

CM

rH

Oi

co
m

CD

1 HQ
lay,

*1
rH rH*
" -

00

rH* g g g g g CM
d g g g g g C M
C O
r H
rH

CD
CM

00

00

rH
rH
O

o m
o o o o co
CM co ^ in co

00
Oi

rH

cd

38
^ "S.

PQ

cd

u
o
Pu

es

in

!
rH

Pu

c-

I>

I>

u*

.> o

Xi

VO

**.
oi

Xi

.> o .> u _> o

Oi

Oi

!
o

ri ni

ta
u

SB

eo

<y

ta

o
ta

00

O
CD

ai
Oi

CO

Oi

Oi*
Oi

Ah

go

<y

CM

>

00
Oi
co
O

'

3 * ,3 13 5 13 5 13
Q PQ PQ PQ col 73col 73
PQ P

te



"

cd"

0 0 0 0 0 0 0 0 0
es es es es es es es es


ta
*

es es

00
0

rH

"cd

"cd

"cd
r5

"cd

"cd
t5

0 0 0 0 O
es es es es ta
ta ta
ta
ta
m
co
CM
co

0
ta

0
ta

c0
00

00
0
00

0 O
es ta"
ta
Oi
0

- Id

O
00

"cd

0
00

rH

0
00

r^

0
00

0
00

cd"

"cd
t5

rH

cd"

^ r H

cd

^ t

rC

m - m -c


rj

8g

m
ai
Oi

sf

3
g

rQ

vo

^rH

H-

CM

r-

r-*

m
I>

in

t>

PQ

CM
O
o O
o
<N
O si

cd

co

vo

o
ta

ta

PQ

' rC Si

r H ^ d

-*H -H
^
Cd ^

0)

C +> iH (11
* 3 2

co
co

s
C D C O CO CO

HH *

co CM

co
co

u
a . "S

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

CM

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

rH

rH

0
00

"cd

00

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

C H

6 6

C H O

C H

100

100

100
100

100

100

100

100

100

100

Water

Water

Water
Water

Water

Water

Water

Water

Water

Water

H 0

H 0

H 0
H 0

H O

H 0

H 0

H 0

H 0

H 0

1823

1824
1825

1826

1827

1828

1829

1830

1831

765.4 mm.

1822

C H
C H

100
100

Water
Water

H 0
H 0

1820
1821

C H N
^5^8

1 2

l z

1 0

O
O

6 12 3

6 122

6 122

1 0

6 122

C H N
C H O

C 5 H 5 N

C5H5N
C H N

C 5 H 5 N

C H N

100
100
100
100
100
100
100

Water
Water
Water
Water
Water
Water
Water

0
0
0
0
0
0
0

H
H
H
H
H
H
H

1813
1814
1815
1816
1817
1818
1819

C H N

100

Water

H 0

1812

C HN

100

Water

H 0

1811

Name

Formula

Formula

No.

B.P.,
C

A-Component

2-Picoline
Cyclohexa
none
Butyl
acetate
Butyl
acetate
sec-Butyl
acetate
2-Ethoxy
ethyl
acetate
Isopropyl
ether
Toluene

Benzene

Isoamyl
alcohol

C*10^22^

1 8

C7H0

156.2

8 18

112.2

110.6

;6

6 123

C H

68.3

1 2

126.1

126.1

128.8
155.6

C H O

C H

132

1 4

C H
C H

12 2
C H <
C

102.3
138.0

80.1

1 4

lO 2 2
C H

7 16
8 18
C9H o
C

C H

55.5
115.5
115.5
115.5
115.5
115.5
115.5
99.3

1 9

Diethyl amine
Pyridine
Pyridine
Pyridine
Pyridine
Pyridine
Pyridine
Ethyl
acrylate
2-Pentanone
A m y l alcohol

C H

77.8

Butyl amine

Formula

B.P.,
C.

Name

B-Component

Nonazeotrope
Nonazeotrope
Nonazeotrope

Nonazeotrope

142.1
142.1
110.6

89.7
Triethylamine
2
1
7.3
Decyl alcohol
(isomers)

Nonazeotrope

Nonazeotrope
112.2

sec-Butyl
acetate
Butyl
ether
Butyl
ether
Toluene

Nonazeotrope
Nonazeotrope
124.5
160.65

86.6

Nonazeotrope
Nonazeotrope

Nonazeotrope

120

80.1

Nonazeotrope
14
13.5
70.5
22.5
25.5
52
30.5
37
32.5
35.5
45.5
19
38.5
51
10.5
40.5
54.5
5
Nonazeotrope

98.4
125.75
150.7
173.3
194.5
216
68.3

78.6
86.7
90.5
92.3
93.1
93.5

68.3

Composition Wt. %
A
B
C
Nonazeotrope

B.P.,
C.

Data

159.6

B.P.,
C.

Azeotropic

157.85

Dibutylamine
Isopropyl
ether
Heptane
Octane
Nonane
Decane
Undecane
Dodecane
Isopropyl
ether
Benzene
Diamyloxymethane
3-Methyl1-butanethiol
Hexyl
alcohol
Paraldehyde
Cyclohexanol

Name

C-Component

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

C H C I 3

CH C1

CH N0

CH

1847

1848

1849
1850
1851

-200 to 50 F.

CH Q

C H 4 O

CH 0

C H 4 O

C H C I 3

1846

Methanol
Methanol

Nitromethane
Methane
Methanol
Methanol

Dichloro
methane

Chloroform

Chloroform

64.5
64.5

-161.5
64.7
64.5

101.2

40.0

61

61

61

CHCI3

C H C I 3

Chloroform

61

61
61
61
61

CHCI3

Chloroform

Chloroform
Chloroform
Chloroform
Chloroform

C a r b o n t e t r a 7 6 . 7
chloride
Chloroform
61
Chloroform
61
Chloroform
61

100

61
61

1844

1852
1853

Name

Water

B.P.,
C.

Chloroform
Chloroform

C H C I 3

C H C I 3

1845

1842
1843

C H C I 3

1841

C H C I 3

C H C I 3

1837
1838
1839
1840

CHCl 3

C H C I 3

CCI4

1833

C H C I 3

H 0

1832

1834
1835
1836

Formula

No.

A-Component

C H 0
3 62

C H
C H 0
C H 0

C H

CH Q

C H O

C H Br

C H 0

C H 0
*3 0

C H 0

CH 0
CzHeO
C H O
C H 0

CH 0
CH 0
CH 0

C2HCI3

C He

Formula

Acetone
Methyl
acetate

Ethane
Ethyl alcohol
Acetone

Benzene

Acetone
Ethyl
formate
Methyl
acetate
2-Bromo
propane
Isopropyl
alcohol
Methanol

Acetone

Methanol
Ethyl alcohol
Acetone
Acetone

Trichloroethylene
Formic acid
Methanol
Methanol

Toluene

Name

B-Component

56.1
56.3

-88.6
78.3
56.1

80.1

64.7

82.3

59.4

57.1

56.4
54.1

56.4

64.7
78.3
56.4
56.4

100.75
64.7
64.7

86.2

110.6

B.P.,
C.
2 6

6 12

C Hi
6 u
C

8 183
H

C H
C H 0
3 62

C H 0

C H 0

C H Br

l z

C H
C H Br

H 0
H 0
^ O
H O

C H O

C
C
C
C

C H 0
C H 0
3 62

1 2

C H 0

Formula

Propane
Acetone
Methyl
acetate
Hexane
Hexane

2-(2-Butoxyethoxy)
ethanol
Cyclohexane

Acetic acid
Acetone
Methyl
acetate
2-Butanone
Acetone
2-Butanone
4-Methyl-2pentanone *
Isopropyl
ether
Toluene
2-Bromopropane
2-Bromopropane
Isopropyl
formate
2-Butanone

2,6,8-Trimethyl-4nonanol
2-Butanone

Name

G-Component

68.95
68.7

-44
56.1
56.3

80.75

230.6

79.6

68.8

59.4

110.7
59.4

68.3

79.6
56.1
79.6
115.9

118.1
56.1
57.1

79.6

225.5

B.P.,
C.

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

47
45

53.7

61.97

63.2

57.5
56.42

B.P.,
C.

Nonazeotrope

Nonazeotrope

Nonazeotrope

Nonazeotrope

Nonazeotrope

14.6
14

30.8
27

59.6
59

v-1
v-1

v-1

Nonazeotrope
v-1
5.3
15.7

Nonazeotrope
Nonazeotrope
17.4
5.8
76.8

79

Nonazeotrope

Nonazeotrope
65.3
10.4
24.3 v-1
Nonazeotrope
v-1
Nonazeotrope
v-1

Nonazeotrope
v-1
46.7
23.4
29.9 v-1
51.4
21.6
27
v-1

Nonazeotrope

Nonazeotrope

v-1

Azeotropic Data
Composition, Wt. %
A
B
C

105
335

268
7
335

343

334

334

195

195

296
195

334

334
224
62
157

56
335
31,143

184

334

Ref.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

118

78

C H Q

-35, 0, 40 F.

1878

78

78

Ethyl alcohol
Ethyl alcohol
Ethyl alcohol

C H 0

1876

1877

78. 3

Ethyl alcohol

114

Nitroethane

C H 0

118

1875

C H N0

1874

118

Acetic acid
Acetic acid

118. 1

118. 1

6 6

8 10

C H 0

CyHgN

118

II

118

C H 0
C H 0

118. 1

1
118. 1

C H N
C H N
C H N
C H N
C H N
C H N
CjHN
C7H9N

C H N
C5H5N
C H N

C H N

118. 1

118. 1

1872

C2H4O2
C2H4O2
C H 0
C2H4O2

2H4O2

Acetic
Acetic
Acetic
Acetic
Acetic
Acetic
Acetic
Acetic

II

118. 1

Benzene
Benzene
Benzene

Benzene

2,6-Lutidine
Ethyl
benzene
p-Dioxane

II

1 (

8 10
H

80.1
80.1

C H
C H

2
2 0

1 4

1 4

1 0

C H

101.3

0H1

10H22
ll?24

C H
C H

C9H00

10H22
11 24
C o_ H 18
i,
C

CoHno

CpH,,

144
136.15

115,
115,
134
134
134
134
144
144

115.5
115.5
115.5

Pyridine
Pyridine
2-Picoline
2-Picoline
2-Picoline
2-Picoline
2,6-Lutidine
2,6-Lutidine

115.5

Pyridine
Pyridine
Pyridine
Pyridine

11

C H

1 5

115.5

Pyridine

C H N

C H

56.4

6 12
2 6
C H N
C

80.1
-104
78.3

C H 0

Formula

68.7

B.P.
C.

Acetone

Trimethyl
borate
Benzene
Ethylene
Ethyl alcohol

Name

B-Component

C H 0

81

1873

1871

1870

1869

1868

1866

1867

1865

C2H4O2
C H 0
C2H4O2

1864

1863

1862

acid
acid
acid
acid
acid
acid
acid
acid

C2H4O2
C2H4O2
C H 0

1861

Acetic acid
Acetic acid
Acetic acid

118

118

Acetic acid

C2H4O2

1860

II

C2H4O2

1859

1,2-Dichloro
83 45
ethane
118 1
Acetic acid

1857

C2H4CI2

1858

C6H*
C H
C H60

C3H9BO3

Formul

-84

64

Methanol
Acetylene
Acetonitrile

CH4O
C2H2
C H N

1856

1855

64. 7

Methanol

CH4O

1854

Name

Formula

No.

B.P.,
C

A-Component

98.4

Heptane

Isobutyl
alcohol
Methylcyclopentane
Cyclohexane
Hexane
Methylcyclo
hexane

Nonane

Undecane

II

Decane
Undecane
Octane
Nonane
Decane
Undecane
Octane
Decane

11

Ethyl
benzene
-Xylene
Octane
Nonane

II

80.1

80.75
68.95
100.88

72

108

194.5
150.7

173.3
194.5
125.75
150.7
173.3
194.5
125.75
173.3

143.6
125.75
150.7

136.15

80.75
-88
89.7

65

B.P.,
C.

Tetrahydro
furan
Cyclohexane
Ethane
Triethylamine
Benzene

Name

C - Component

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Azeotropic

Data

65.05

362
326
326
30.4
58.8
10.8
Nonazeotrope
Nonazeotrope

208

372
355
372
355
355
370
369
369
369
369
364
323,364
358
370
363

373
355
363

35

304

v-1

v-1

223,362
137
335

115

Ref.

Nonazeotrope

50.6

17.7
31.7

102.87

162!

147.0

17.7
30.5
51.8
20.1
10.4
69.5
20.7
29.4
49.9
29.3
49.8
20.9
31.4
38.2
30.4
19.0
43.5
37.5
3.6
24.8
71.6
38.4
48.8
12.8
33.3
19.9
46.8
55.2
14.3
30.5
Nonazeotrope
12.6
74.3
13.1
...
7!
11.3
13!
Nonazeotrope

91.5
86.0
61.3

132.2
115.7
128.0
128.0
134.1
137.1
121.3
135.0
141.3
143.4

6.5
10.6
25.2

Nonazeotrope

v-1
v-1

Nonazeotrope
Nonazeotrope
8
58

2
3.4
13.5

34

v-1

Nonazeotrope

Composition, Wt. %
A
B
C

96.2
96.5
129.08

70.1

B.P.,
C.

m
79
m

79
<

>

TERNARY

SYSTEMS

00 00 00 00
^ 00 00 CO 00
CM

rH rH rH rH

69

^ " ^ ^
CO 00 CO CO
00 00 co co

oo co
r H 00

CM

61,74
61,321

II

209,362
320
331

TABLE

rH rH

rH

rH rH

in

> > > > >

o o o
0
0

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CM

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Nonazeol trope
Nonazeoltrope

CD

<u

Q>
eu a
o o
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CM +f +e
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cd ce
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fi
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CM CM CM C O

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c?
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00

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t-

CD

rH
rH
r-,
K ^ r H >>rH > 5 r H

CM

CM
rH

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rH

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0
vo

te

es

CD

OOOO

te te te te
te te te te
eo
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co oo oo
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eo

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00

00

tte

eo eo

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CD CD

00 00

CO

Oi

g
C

&3 a i i l i l 8 - l l l S

<<

cd

es

rr

te" tc^ te"

VO

VO

cd oo
X rH
fi
, rfi
H

r>.fi7^ ^

es

es

te

^ 3
S S

00

u co o
>>

00 CO CO t -

o
rfi

VO

CM X
I

es

H
rH
>>

es

ri"


rHrfi

CUrC o
>>

!5 ^ j C J ,

"

rfi
o
a
>>

0
VO 0 0 VO

ffi tC X X us tu te tu
tr - oo
<t vo

m in
co co cTj* Tj* O r H
00 00 r H CD

00 co

00 co oo

CD S

ane
16.7
ane

CM

ane

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

CM
CM

CM
CD

00

0
oo

te

eo

CO
CO
CO

0
00

te

CD

00

0 0
00
tc
te

m
CD
00

o
00

te

co

CO

Oi
00

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

1 0

C H

C H

C H

C H

C H

1904

1905

1906

1907

1908

C H N

C5H5N

1914

1915

C H

1917

6 6

1916

C H 0

1913

C H 0

1912

C H 0

1911

1 0

C H 0

1 0

1 0

1910

1909

1 0

C H

1903

1 0

C H Cl Sn

1902

C H 0
C H 0

1900
1901

Formula

No.

80.1

80.1

Benzene

1 2

7 16

^6 12

8 10

Benzene

115.5

Pyridine

C H

115.5

7 14

2 , 3 - D i m e t h y l pentane

Methylcyclo
hexane
Isoamyl
alcohol
Ethyl
benzene
Cyclohexane
89.8

1 2

2 7

1 2

2 0

C H

80.75

C H

136.15

C H

7 16

7 16

7 14

6 12

8 18

1 8

8 10

131

101.1

110.7

Toluene

161.7

80.1
C

136.15

110.7

161.7

6 12

C H

Toluene

Ethyl
benzene
Benzene

145

8 19

6 12

C H

161.7

C H8

C H

161.7

8 10

C He

135.1

135.1
II

126.1

6 122

Butyl
acetate
Styrene

80.1

Benzene

C H

117.75

117.7

115.5

Pyridine

C H N

117.75

77.8

Butylamine

C H N

117.7

ClSn

80.1

C H

107.0

2 7

Cj H

157/17

Dibutyltin
dichloride
Benzene

Cll 24
6 12

115.5
80.1

Pyridine
Benzene

CoHigClzSn

113/17

Formula

B.P.,
C.

Name

C H

C5H5N

Formula

B-Component

162.45
77.05

B.P.,
C.

hyde
2-Fur alde
hyde
Pyridine

hyde
2-Fur alde
hyde
2-Fur alde

2-Ethoxyethanol
2-Furalde-

It

Butyric acid
Ethyl
acetate
Butyltin
trichloride
Isobutyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
Butyl
alcohol
2-Ethoxyethanol

Name

A-Component

ether

48

98.4
110.7
150.7
115.9

Toluene
Nonane
4-Methyl-2pentanone
Perfluorotributylamine

4.1

87.3

v-1
v-1

Nonazeotrope

v-1

v-1

v-1

v-1

v-1
v-1

v-1

v-1

Nonazeotrope

Nonazeotrope

8.6

Nonazeotrope

Nonazeotrope

Nonazeotrope

Nonazeotrope
Nonazeotrope

Nonazeotrope

Nonazeotrope

48

67.4

98.4

20.7

Nonazeotrope
11.9

Nonazeotrope

110.19

77.42

108.7

101.1

80.75

136.15,
5 mm.
62 m m .
125.75

142.1

80.75

110.7

159.6

50

42

80.75

76.73

Nonazeotrope

166/17

Composition, Wt. %
A

C
Nonazeotrope
Nonazeotrope

B.P.,
C.

Azeotropic Data

194.5
80.75

B.P.,
C.

Heptane

Methylcyclo
hexane
Heptane

Cyclohexane

Octane

Ethyl
benzene

Butyl

Cyclohexane

Dibutylamine
Toluene

Tributyltin
chloride
Cyclohexane

Undecane
Cyclohexane

Name

C-Component

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

190

65

363

371

114

114

114

331

152
227

110

334

362

140

334

153,362

334

370
43,44

Ref.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

C H N

C H N

C H N

202

202

202

2-Cresol

2-Cresol

C H 0

C H 0

C H 0

1924

1925

1926

90 nm.
J 80 to 100 C.
400 ran.

C H
CeHio

184.35

Aniline
Hexylene
glycol
x-Cresol

C H N
C Hi 02

1922
1923

C H

184.35

Aniline

C H N

1921

1 2

C H

184.35

Aniline

C H N

1920

1 0

^6

182

Phenol

C H 0

1919

1 0

C H

182

Phenol

C H 0
4

Formula

1918*

B.P.,
C.

Formula

No.

Name

-Component

163

157
H

10 8

10 8

Cl0 8

C Hi
CeHi6

110.7
136.15

Toluene
Ethyl
benzene
Pyridine
bases
Pyridine
bases
Pyridine
bases
143

1 4

C H

110.7

Toluene

1 3

C H

160.65

C H 0

l z

186

C H

Formula

155.6

B.P.,
C.

Cyclohexan
one
Ethylene
diacetate
Cyclohexanol

Name

B-Component

202.03
202.39

218.1
218.1

Naphthalene
Naphthalene

101.1

16.5
17

65.5
62

81

Evaporation

21

18

10

data

Nonazeotrope

39.2

.202.48

34.4

218.1

26.4

Nonazeotrope
Nonazeotrope

194.45

Nonazeotrope

Composition, Wt. %
A
B
C

98.4
131.8

195.7

B.P.,
C.

v - -1
v - -1

v - -1

v - -1

Azeotropic Data

Phenyl
acetate
Cyclohexylamine
Methylcyclo
hexane
Heptane
Ethylcyclohexane
Naphthalene

160.65

B.P.,
C.

Cyclohexanol

Name

C-Component

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

57

367

367

367

138
271

297

242

253

Ref.

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

C
D

C
D

C
D

1932

1933

8 18

H 0
C H 0
C H

H 0
C H 0
Q H
QrHi

1 4

C H

H H

H 0
C H 0

H 0
C H 0
Q H

H 0
CzHO
C H
Q H

H 0
C H 0
C H60
C4H8O2

1 5

1931

1930

1929

1928

0
H N
H 0
H N

H
C
C
C

1927

Formula

No.

Water
Ethyl alcohol
Benzene
Iso-octane

Water
Ethyl alcohol
Benzene
Heptane

Water
Ethyl alcohol
Benzene
Methylcyclohexane

Water
Ethyl alcohol
Benzene
Hexane

Water
Ethyl alcohol
Benzene
Cyclohexane

Water
Ethyl alcohol
Crotonaldehyde
E t h y l acetate

Water
Acetonitrile
Ethyl alcohol
Triethylamine

Name

100
78.3
80.1

100
78.3
80.1
98.4

100
78.3
80.1
100.88

100
78.3
80.1
68.95

100
78.3
80.1
80.75

100
78.3
102.2
77.1

100
81.6
78.3
89.7

B.P.,C.

64.69

64.79

Nonazeotrope

Nonazeotrope

62.19
62.14

70

Nonazeotrope

B.P./C.

Table III. Quaternary Systems

6.7

6.8

7.1
6.1

8.7

17.7

18.7

17.4
19.2

11.1

Azeotropic

Data

61.4

62.4

21.5
20.4

0.1

80.1

14.1

12.1

54.0
54.3

Composition

Azeotropic

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

325

325

326

326

357
322,361

84

334

Ref.

TABLE

TERNARY

II

SYSTEMS

73

eu
Q

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

u
0

rQ

"

ci

PQ

cd
fi
O

Pu

[ . H H

H H [>

H m CD >

CO H O O l

CO < f

3 O* CD CM*
) rH CM "

OOiOCDO
rH rH CO m

co m co o
H H

co O CM CO
C - CO C - CO

00 ^ O CO
C - CO rH CO

rj*

PQ

o
o

Jfi

0)
rfi Cti rH
-M

cd
55

rH

S o cd
H PU

O
QQ

cd cd <D

fi

fi

>>
fi

PQ PQ PQ

00

CM

H
cd fi
fi <U
ro

G E E S3
CM ^

v CO

O
< PU

W 2 ;

CM

in co c/v

<PQUQ

<PQUQ

<PQUQ

CO r -

. <U

cd

< PU O l

rfi

>L cd

rfi

"S

tO

CM


CM

m co \

< PQ U

+3 fi

HIffi
CM vo VO

cd

CM

u u u u

fi 3

fi

WPQrlrM

CM

s .a ^

rH rH rH

+ 3

< -S

VO

< PQ U Q

VO t

00

vo

U
CM vo t - ru u u u
< PQ U Q

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

Formula Index
T h i s index l i s t s a l l c o m p o u n d s a p p e a r i n g i n the a z e o t r o p i c t a b l e s .
Included are
f o r m u l a , n a m e , s t a n d a r d b o i l i n g point, a n d n u m b e r s of the s y s t e m s i n w h i c h the
compound appears as a component. The inorganic substances are indexed f i r s t .
Formula
A

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

AsCl

BeF

BrF

BrF
Br

B r

CO
CO

C1F

C1H

Cl

ci o s
2

CI3HS1
CI3P
Cl Ge
4

Cl Si
4

Cl Sn
4

Cl Ti
4

DH
D

FH

FNa
F Sb
5

N a m e and System

Formula

Nos.

Argon
B.p., -186
1, 2 , 1 6 7 5
Arsenic chloride
3
B . p . , 130
Diborane
B.p., -87.5
5
B e r y l l i u m fluoride
4
Bromine trifluoride
6-9
B . p . , 135
B r o m i n e pentafluoride
6 , 1 0 , 11
Bromine
B . p . , 58.9
7, 1 2 - 2 0
Phosphorus tribromide
21
B . p . , 175.3
Carbon monoxide
1676
B.p., -192
C a r b o n dioxide
22-26
B.p., -78.5
Chlorine trifluoride
2 7 - 2 9 , 1677
Hydrogen chloride
B.p.,
-85
27, 3 0 - 3 2 , 1678
Chlorine
B.p., -34.6
3 0 , 33
Sulfuryl chloride
34-37
B . p . , 69.1
Trichlorosilane
38
Phosphorus trichloride
39-44
B . p . , 76
Germanium chloride
3
B . p . , 86.5
Silicon tetrachloride
4 5 , 46
B . p . , 57.6
Tin chloride
B . p . , 114.1
47, 48
Titanium tetrachloride
49-51
B . p . , 146.2
Deuterium hydride
5 2 , 53
Deuterium
B.p., -249.7
5 2 , 54
Hydrogen fluoride
B.p.,
19.4
8, 1 0 , 1 2 , 2 8 , 3 3 , 5 5 - 5 9 ,
1677, 1679
Sodium fluoride
4
Antimony pentafluoride
55
B . p . , 142.7
U r a n i u m hexafluoride
B . p . , 56
9, 1 1 , 1 3 , 2 9 , 5 6 , 1 6 7 7

F W
6

HNO3
H

H 0
2

22

H S
2

H S0
2

H N
3

He
N

N 0
2

25

o s
2

S
Se
CCI

CCI3F

CCI.

cs

CHC1F

CHC1F

N a m e and S y s t e m

Nos.

Sulfur hexafluoride
60
Tungsten hexafluoride
61, 62
B . p . , 19.5
Nitric acid
B . p . , 86
6 3 , 64, 1680
Hydrogen
B.p., -252.7
5 3 , 54, 1676
Water
B . p . , 100
31, 63, 6 5 - 5 2 2 ,
16791832, 1927-1935
Hydrogen peroxide
65
B . p . , 151.4
Hydrogen sulfide
B.p.,
-59.6
22, 523, 524
Hydrogen sulfate
66
Ammonia
B.p., -33.4
525-529
Hydrazine
B . p . , 113.8
67
Helium
B.p., -268.9
530
Nitrogen
B.p., -195.8
1675, 1676
N i t r o u s oxide
23
B.p., -90.7
N i t r o g e n pentoxide
68
Oxygen
B.p., -183
1, 1 6 7 5
Sulfur dioxide
B.p., -10
5 3 1 , 1681
Sulfur
B . p . , 444.6
532
Selenium
B . p . , 688
532
Dichlorodifluoromethane
B.p.,
-29.8
57, 533-539
richlorofluoro methane
B.p.,
24.9
5 4 0 , 541
Carbon tetrachloride
B.p.,
76.8
14, 34, 4 7 ,
542-556,
1833
Carbon disulfide
B.p.,
46.2
69, 557-561
Chlorodifluoromethane
B.p.,
-40.8
58, 533, 5 6 2 - 5 6 7
Dichlorofluoromethane
B.p., 7.63/723 m m .
568

74

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA
Formula

CH9CI2

CHoO,

Chloromethane

CH3CI
CHoCloSi

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

CH3l

CH Cl Si
2

CH 0
4

CH S
4

CH N
5

C C1 F
2

C C1
2

C C1 F

C C1 F

C C1 0
2

C HC1
2

C HC1 F
2

C HF 0
C H
2

C H C1 F
2

C2H2CI2F2

C H C1
2

C H C1
2

C H C1
2

CH C1
3

C H F 0
2

C H N
2

C H

C H Br
2

C H C1

C H C1

C H F
2

C H 0
2

C H 0
2

C H 0

C H 0

Hexachloroethane

C2CI6

C H C1 N02

ethane
B . p . , 47.6
15, 74, 6 8 0 , 6 8 1 ,
1691, 1699
Tetrachloroethylene
B . p . , 121
75, 5 7 1 , 6 8 2 - 6 8 5
1,1,1,2-Tetrachlorodifluoroethane
B . p . , 91.6
16
1,1,2,2-Tetrachlorodifluoroethane
B . p . , 92.4
680
Trichloroacetyl chloride
49
B . p . , 118

72, 5 9 1 - 6 0 2 , 1690, 1848


Methane
B . p . , -161.5
530, 6 0 3 , 604, 1849
Dichloromethylsilane
46, 605
Methanol
B . p . , 64.7
32, 7 3 , 542, 570, 5 9 1 ,
606-673, 1683, 16911698, 1835-1837, 1847,
1849-1855
Methanethiol
B . p . ,6.00
674, 675
Methylamine
B.p., -6
676, 677

B . p . , 101.2

1,1,2-Trichlorotrifluoro-

C2CI3F3

C H C1 0

562, 678
B.p., -38.5
1,2-Dichlorotetrafluoroethane
B.p., 2.22/723 m m .
568, 606, 679

C H C1

B.p., -24

Chloropentafluoroethane

C2CIF5

Name and System Nos.

534
Trichloromethylsilane
45, 590
Iodomethane
B . p . , 42.55
557

Nitromethane

CH3NO2

Formula

B . p . , 61.2 C ^ ^ l o ,

64, 70, 5 6 9 - 5 8 4 , 1 6 8 0 ,
1682-1687,
1834-1846
Bromochloromethane
585
B . p . , 69
Dichloromethane
B.p., 40.7
585, 586, 1847
F o r m i c acid
B . p . , 100.75
71, 5 6 9 , 5 8 7 - 5 8 9 ,
1682, 1688, 1689, 1834

CH BrCl

75

Name and System Nos.

Chloroform

CHCI3

C H

INDEX

35
B . p . , 184.8
Trichloroethylene
B.p., 86.2
543, 686-690,
1700-1702, 1833
1,2,2- T r i c h l o r o - 1 , 1 - d i
fluoroethane
B.p., 71.1/736 m m .
17
Trifluoroacetic acid
5 9 , 76
Acetylene
B.p.,-84
24, 6 9 1 - 6 9 3 , 1856

C H BrO
2

C H C1
2

C H C10
2

CoHrNO

is-l,2-Dichloroethylene
B.p., 60.3
607, 694-701
trans-1,2- Dichloro ethylene
B . p . , 48.3
608, 702-709
1,1-Dichloro-2,2-difluoroethane
18
B . p . , 59/735 m m .
l,2-Dichloro-l,2-difluoroethane
B . p . , 30
563
Chloroacetyl chloride
50
B . p . , 105
1,1,2,2-Tetrachloroethane
3 6 , 51
B . p . , 146.2
Vinyl chloride
7 1 0 , 711
B . p . , 13.4
Methyl dichlorocarbamate
77
1,1,1-Trichloroethane
712, 713
B . p . , 74.1
1,1,2-Trichloroethane
B.p.,
113.65
68, 6 8 2 , 712
2,2,2-Trifluoroethanol
714
Acetonitrile
B . p . , 80.1
79, 544, 572, 592,
715-726, 1684,1 7 0 3 1706, 1857, 1927
Ethylene
B . p . , -103.7
25, 6 9 1 , 727, 1856
1,2-D i b r omoethane
728, 729
B . p . , 131.5
1,1-Dichloroethane
558, 713
B . p . , 57.2
1 , 2 - D i c h l o r o ethane
B.p., 83.16
37, 80, 545, 6 0 9 ,
686, 710, 715, 7 3 0 735, 1707, 1708, 1858
1,1-Difluoroethane
535, 678
B.p., -24.7
Acetaldehyde
B . p . , 20.2
540, 610, 736-742,
1681, 1709, 1710
Ethylene oxide
743
B . p . , 10.5
Acetic acid
B . p . , 118.1
81, 546, 573, 587, 6 1 1 ,
687, 744-768, 1685,
1688, 1834, 1 8 5 9 1873, 1936, 1937
Methyl formate
B . p . , 32
541
2 - B r o m o ethanol
B.p., 100/150 m m .
82
Chloroethane
B . p . ,12.4
736, 769
2-Chloroethanol
B.p., 128.7
83, 7 7 0 - 7 7 2 , 1711
Acetamide
B . p . ,222
773

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES
Formula
C H N0
2

C H

Name and System Nos.

CzHgO

C H 0
2

C H OS

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C H 0
2

C H S
2

C H S
2

C H N
2

C ^ N
C H NO
2

C H N2
2

C H N
2

C3CI3F5

C F
3

C F

C 3 H F 5 O 2

C HF
3

C H C1F C>2
3

C H F 0
3

C H ClF NO
3

C H F NO
3

C H N
3

C H NS
3

C H

Nitroethane
P . p . , 114.0
84, 7 7 4 - 7 8 0 , 1874
Ethane
B.p., -88.6
26, 523, 6 0 3 , 6 9 2 ,
727, 7 8 1 , 1849, 1856
Ethyl alcohol
B . p . , 78.3
85, 547, 574, 593, 612,
681, 694, 702, 714, 744,
774, 782-866, 1686,
1692, 1699, 1703, 1707,
1709, 1712-1738, 1838,
1850,
1857,1875-1882,
1927-1933, 1938, 1939
Methyl ether
B.p., -23.7
531, 536, 612
Dimethyl sulfoxide
867
Ethylene glycol
B . p . , 197
86, 8 6 8 - 8 9 3 , 1883
Methyl sulfide
B . p . , 37.32
894-899
Methyl disulfide
900-907
B . p . , 109.44
Dimethylamine
B . p . , 7.4
908, 1739
Ethylamine
B . p . , 16.6
525, 909, 910
2- A m i n o ethanol
B.p., 170.5
87, 9 1 1 , 912
1,1-Dimethylhydrazine
88
E t h y l e n e d i a m i n e B . p . , 116
89, 913, 917, 1740
1,2,2-Trichloropentafluoropropane
B . p . , 72.5
19
Hexafluoropropene
B.p., -6.1/2059 m m .
537, 564
Perfluoropropane
B.p., 12.5/6.064 a t m .
565
Pentafluoropropionic acid
90, 918
Heptafluoropropane
B.p., 17/2328 m m .
538
3-Chloro-2,2,3-trifluoropropionic acid
919
2,2,3,3-Tetrafluoropropionic acid
920
3-Chloro-2,2,3-trifluoropropionamide
921
2,2,3,3-Tetrafluoropropionamide
922
Acrylonitrile
B . p . , 77.2
91, 614, 716, 923, 1712,
1741
Thiazole
B . p . , 116.8
92
Propadiene
B.p., -32
526, 924-927, 1 8 8 4 1886

Formula
C 3 H 4

C3H4C14
C 3 H 4 0

C 3 H 4 0

C H C1
3

C H C1
3

C 3 H 5 C I O

C 3 H 5 C I O

C 3 H 5 C I 3

C 3 H 5 F

C H N
3

C 3 H 5 N O

C H C1 0
3

^3H 0

IN

CHEMISTRY

SERIES

Name andSystem Nos.


Propyne
B.p., -23.2
693, 924, 928-930,
1884-1886
Tetrachloropropane
931
Acrolein
B . p . , 52.8
93
2-Propyn-l-ol
B . p . , 115
94, 932, 1742, 1743
Acrylic acid
B . p . , 141.2
95, 933, 1744
Ethylene carbonate
96, 868
3-Chloro propene
97, 934
B.p., 45.15
x-Methylvinyl chloride
98
2-Chloro-2-propen-l-ol
935
Epichlorohydrin
936
B . p . , 116.45
1,2,3- Trichloropropane
936
B . p . , 156.85
2- F l u o r o p r o p e n e
527
B.p., -23
Propionitrile
B . p . , 97.4
923, 1741
Hydracrylonitrile
99
B . p . , 229.7
Propene
B.p., -48
925, 928, 937, 1884
1,2- Dichloropropane
B.p., 96.3
688, 730, 938,
939, 1745
2,3 - D i c h l o r o - l - p r o p a n o l
100
B . p . , 183.8
Acetone
B . p . , 56.1
101,
548, 575, 594,
615, 683, 695, 703,
711, 717, 782, 9 1 1 ,
940-957, 1713, 17461752, 1835, 1 8 3 8 1842, 1850, 1 8 5 1 ,
1852, 1858, 1887-1890
Allyl alcohol
B . p . , 96.90
102, 549, 9 5 8 - 9 6 3 ,
1700, 1753-1755, 1891
Propionaldehyde
B.p., 47.9
103, 964, 965, 1693
Propylene oxide
B . p . , 38
104, 737, 9 3 8 , 964, 966
1,3-Dioxolane
B . p . , 75.6
105, 967-970
Ethyl formate
B.p., 54.0
106, 577, 696, 704,
971, 1714, 1843
Methoxyacetaldehyde
B.p., 92/770 m m .
107
M e t h y l acetate
B . p . , 57.2
108, 576, 6 1 6 , 6 9 7 ,
705,

972-1001,

1694,

1836, 1844, 1 8 5 1 ,
1853, 1887

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA
Formula
C H 0
3

C H 0
3

C H C1
3

C H 7Cl
,

C H C10

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C H NO
3

C H NO
3

C H N0
3

C H N0
3

C H
3

C H 0
3

C H 0
3

C H OS
3

C H 0
3

3 82

C H 0
8

3 82
H

C3HgS
C3H S
8

C H BO
3

N a m e and System

Nos.

Propionic acid B.p.,


745,
1002-1010,
1756, 1892

C H Br
3

77

INDEX

140.7

Methyl glycolate
1011, 1012
B . p . , 151.2
s-Trioxane
B . p . , 114.5
1013
2- Bromopropane
B . p . , 59.35
578, 971, 972,
1843-1845
1 - Chloropropane
1 0 9 , 559
B . p . , 46.6
2- Chloropropane
110, 934
B . p . , 34.9
Propylene chlorohydrin
B.p., 73/100 m m .
1014, 1745
, - D i m e t h y l f o r m a m i d e
B . p . , 153.0
111, 588, 718,
919-922,
1015
Propionamide
B . p . , 222.1
1016-1018
1 - Nitropropane
B . p . , 131.6
112, 617, 783,
1019-1024
2-Nitropropane
B . p . , 120.3
113, 618, 784,
1025-1030
Propane
B . p . , -42.1
524, 566, 604, 926,
929, 937, 1849, 1885
Isopropyl alcohol
B . p . , 82.5
115, 595, 684, 731, 775,
785, 940, 958, 1019,
1025, 1031-1059,
1690,
1695, 1702, 1708, 1746,
1757-1766, 1846, 1888,
1893-1895,
1934
P r o p y l alcohol B . p . , 97.25
114, 550, 596, 746, 776,
1020, 1026,
1060-1072,
1701, 1 7 6 7 - 1 7 7 4 , 1896
2- ( M e t h y l t h i o ) e t h a n o l
1073
2 - Methoxyethanol
B . p . , 124.5
116, 619, 1 0 7 4 - 1 0 9 4 ,
1 7 7 5 - 1 7 7 7 , 1897, 1898
Methylal
B . p . , 42.6
6 9 8 , 706
1,2-Propanediol
B . p . , 188
117, 939, 10951106, 1778
1,3-Propanediol
B . p . , 214
118, 1107
Ethyl methyl sulfide
1108-1113
B . p . , 66.61
1-Propanediol
B . p . , 67
1060, 1767
T r i m e t h y l borate
B . p . , 68.7
620, 1114, 1854

Formula
C H ClSi
3

C H N
3

C H N
3

C H N
3

C H NO
3

C H
3

1 0

C C1 F
4

C F
4

C HF 0
4

C H 0
4

C H

C H 0
4

C H S
4

C^sCl
C H N
4

C ^ N
C Hg
4

C H C1N
4

C H C1
4

C H 0
4

C H 0
4

C H 0
4

C H 0

C H 0

C H 0

C H 0

C H 0

C H 0

C H 0

C H 0

N a m e and System

Nos.

Chlorotrimethylsilane
590, 605
Isopropylamine
1115
B . p . , 32.4
Propylamine
B . p . , 48.5
119
Trimethylamine
120
B . p . , 3.2
1 - A m i n o - 2-propanol
B . p . , 159.9
121, 1116-1119
1,2-Propanediamine
1 1 2 0 - 1 1 2 2 B . p . , 120.9
2,2,3- Trichloroheptafluorobutane
B . p . , 97.4
1123-1125
Perfluorocyclobutane
539, 567
Perfluorobutyric acid
B . p . , 122.0
122, 1126-1128,
1679
Maleic anhydride
1129, 1130
Vinylacetylene
1131
Diketene
941, 1132
Thiophene
B . p . , 83.97
1133-1142
2 - C h l o r o -1,3 -butadiene
1131, 1143, 1144
3-Butenenitrile
123
B . p . , 118.9
Methacrylonitrile
124
1,3-Butadiene
B.p., -4.5
676, 927, 930, 1886
2-Chloro - 2- methylpropionitrile
B . p . , 116
125
1,3-Dichloro-2-butene
1143
Crotonaldehyde
B . p . , 101.5
126, 1715, 1779, 1928
Methacrylaldehyde
127
B . p . , 68.0
3-Butene-2-one
1144
2,3-Butanedione
1145
B . p . , 90.7
3-Butenoic acid
128
Butyrolactone
131
B . p . , 204.3
Crotonic acid
B . p . , 185
129, 130
Methyl acrylate
1696
B . p . , 80.9
V i n y l acetate
B . p . , 72.7
132, 621, 738, 942,
1031, 1146-1149,
1747
Acetic anhydride
B . p . , 138
747, 1002, 1 1 5 0 - 1 1 5 2
Propylene carbonate
133
B . p . , 242.1

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

78

ADVANCES

Formula
C H C1
4

Formula

Name andSystem Nos.

1 - Chloro-2-methylpropene
C H 0
943
B . p . , 68
2-Chloroethyl vinyl ether
B . p . , 109.1
134, 7 7 0 , 1153
C He0
Butyronitrile
B . p . , 117.6
135
C H 0
2- H y d r o x y i s o b u t y r o n i t r i l e
136
C H 0
1-Butene
B . p . ,-6
677
2-Methylpropene
B . p . ,-6
C H S
674
Bis(2-chloroethyl) ether
C H C1
B.p., 178.6
137, 732, 7 7 1 , 8 6 9 ,
C H C1
1154-1156
2-Butanone
B . p . , 79.6 C H C l S n
138, 5 5 1 , 579, 622, 689,
699, 707, 786, 944,
C H NO
1145, 1157-1169, 1687,
1716, 1748, 1757, 1 7 8 0 1782, 1833, 1837, 1839,
C H NO
1846, 1899
Butyraldehyde
B . p . , 75.7
C H N02
139, 6 2 3 , 787, 1 1 7 0 1176, 1717, 1749,
1783-1786
C H N0
Ethyl vinyl ether
B.p., 35.5
140, 739, 788, 1718
C Hio
Isobutyr aldehyde
141, 1170
B.p., 63.5
C H
Methyl propenyl ether
142
B.p., 46.3
C HioO
Tetrahydrofuran
B . p . , 66.1
624, 700, 708,
1114, 1854
2-(Methylthio)propionaldehyde
143
C Hi O
1,4-Oxathiane
B . p . , 149.2
144
Butyric acid
B . p . , 162.45
1171, 1177-1179, 1900
p-Dioxane
B . p . , 101
145, 748, 772, 789, 9 1 3 ,
C H O
1032, 1180-1184, 1874
Ethoxyacetaldehyde
146
B . p . , 105
C H O
E t h y l acetate
B . p . , 77.05
552, 560, 6 2 5 , 690, 749,
790, 1033, 1061, 1 1 8 5 1191, 1893, 1901, 1928
C HioO
2 - Hydroxybutyr aldehyde
147
Isobutyric acid
B.p., 154.5
148, 1192-1194
C H O
Isopropyl formate
C H O
B.p., 68.8
580, 1157, 1845
3- M e t h o x y p r o p i o n a l d e h y d e
4 102
149
2 - Methyl - 1 , 3 - dioxolane
150
B.p., 82.5
4

C 4 H 7 C I O

C 4 H 7 N

C H NO
4

C48

C HeCl 0

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C H 0
4

C H 0
4

C4H 0
8

C4H 0
8

C H O
4

1 0

C H 0
4

C H OS
4

C H OS
4

C H 0

C H 0

C H 0
4

4 82
H

1 0

1 0

C H 0
4

82

C H 0
4

C H 0
4

4 82
H

1 0

1 0

IN

CHEMISTRY

SERIES

Name andSystem Nos.


Methyl

propionate
B . p . , 79.7
151, 626, 1034,
1697, 1756
Propyl formate
B . p . , 80.9
1195
2 - V i n y l o x y ethanol
152, 870
B . p . , 143
Ethylene glycol monoacetate
871
Tetrahydrothiophene
1196-1202
B . p . , 120.79
1-Chlorobutane
B . p . , 77.9
1203
1 - Chloro- 2- methylpropane
1035, 1158
B . p . , 68.9
Butyltin trichloride
B.p., 113/17 m m .
1204, 1902
N,N-Dimethylacetamide
750
B . p . , 165
Morpholine
B . p . , 128.3
153, 1206, 1207
N-(2-Hydroxyethyl)
acetamide
154
2- M e t h y l - 2 - n i t r o - 1 propanol
1208
Butane
B.p., -0.5
528, 679, 740, 7 4 3 , 769
2- Methylpropane
675, 1698
B . p . , -11.70
Butyl alcohol
B . p . , 117.75
155, 553, 597, 627, 685,
751, 777, 791, 914,
1021, 1027, 1120, 1146,
1180, 1203, 1209-1231,
1787-1799,
1904-1907,
1935
sec-Butyl alcohol
B.p., 99.5
156, 598, 778, 792,
1022, 1028, 1159, 1209,
1232-1237, 1787, 18001807
tert-Butyl alcohol
B . p . , 82.41
599, 779, 1 0 2 3 ,
1029, 1800
Ethyl ether
B . p . , 34.5
5, 1 5 7 , 5 6 1 , 5 8 1 , 7 4 1 ,
966, 1036, 1211, 1239
Isobutyl alcohol
B . p . , 107
158, 6 0 0 , 780, 9 1 5 ,
1024, 1030, 1121, 1172,
1181, 1185, 1210, 1238,
1783, 1808, 1874, 1903
1,4-Butanediol
B . p . , 230
1241
1,1 - D i m e t h o x y e t h a n e
1173, 1784
B.p., 64.5
1,2-Dimethoxyethane
159, 1240
B . p . , 85.2

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA
Formula
C H
4

C H
4

C H
4

1 0

2-Butanethiol

C4H10S
C Hi S
4

C H

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1 0

C H
4

1 0

C4H10S2

C H
4

1 1

NO

N 0

C C1 F
5

C F
5

1 0

C F

C H F 0
5

C H 0
5

C5H5N

C H N
5

C H 0
5

C H 0
5

C H S
5

C H S
5

C H N
5

C H

CsH

5 8

5 8

B . p . , 85.15

C H

162, 794, 1037, 1213,


1719, 1758, 1789, 1811,
1904
Diethylamine
B . p . , 55.5
163, 628, 795, 909,
1327, 1328, 1704, 1812
2-Dimethylaminoethanol
B.p., 134.6
164, 9 0 8 , 1739
2,2'-Iminodiethanol
165, 910, 912, 1329
1,2-D i c h l o r o h e x a f l u o r o cyclopentene
B . p . , 90.6
1123, 1330
Perfluorocyclopentane
B.p., 25/833 m m .
61, 1331, 1332
Perfluoropentane
B.p., 40.86/1140 m m .
2, 6 0 , 6 2 , 1331
2,2,3,3,4,4,5,5-Octafluoro1-pentanol
1333, 1334
2-Furaldehyde
B . p . , 162
166, 554, 1187,
1335-1339,
1910-1913

C HeO

Pyridine

Name and System Nos.

C H C10

1133, 1299
Ethyl sulfide
B . p . , 92.07
1300-1308
Isopropyl methyl sulfide
B . p . , 84.76
1134, 1299, 1309-1316
Methyl propyl sulfide
1317-1324
B . p . , 95.47
Ethyl disulfide
B . p . , 154.11
1325, 1326

Butylamine

C4H11N

Formula

Name and System N o s .

B.p., 134.0
160, 7 9 3 , 1186,
1242-1277, 1809,1810,
1908, 1909
Diethylene glycol
B . p . , 245.5
161, 1154, 1278-1298
1- Butane thiol
B.p., 98/770 m m .
1212, 1788

1 0

79

2-Ethoxyethanol

O3

1 0

INDEX

B . p . , 77.8

B . p . , 115.5

167, 589, 752, 1003,


1177, 1214, 1340-1349,
1678, 1689, 1813-1818,
1859-1865, 1892, 1900,
1905, 1914, 1915, 1936,
1937
2-Methyl pyrazine
168
B . p . , 133/737 m m .
2-Methylfuran
B . p . , 63
169, 965, 973, 1160
Furfuryl alcohol
1335
2-Methylthiophene
B . p . , 111.92
900, 1350-1353
3-Methylthiophene
1354-1360
B . p . , 114.96

C5H8CI4
CsH 0
8

C H 0
5

C H 0
5

C H 0
5

c i^o
5

C He0
5

2
CsH 0
8

^5 8 - 2
H

C H 0
5

5 82
H

CsH 0
8

^5^8^ 3
C

5 10

5 10

5 10

'5 10

^5

2- C h l o r o a l l y l v i n y l ether
935
3- M e t h y l - 3 - b u t e n e n i t r i l e
170
B . p . , 137
Cyclopentene
B . p . , 44.4
974
Isoprene
B . p . , 34.3
629, 1361-1365
3- Methyl -1,2-butadiene
630
B.p., 40.8
cis-1,3- Pentadiene
631
B . p . , 44
trans-1,3- Pentadiene
632
B.p., 42.0
Tetrachloropentane
931, 1366
A l l y l vinyl ether
171, 959
B . p . , 67.4
Cyclopentanone
B . p . ,130
172, 1367-1369
1- M e t h o x y - 1 , 3 - b u t a d i e n e
173, 633
B . p . , 90.7
3- Penten-2-one
174
B.p., 123.5
3 - M e t h y l - 3-buten-2 - one
175
B . p . , 97.9
4- P e n t e n a l
B . p . ,106
176
A l l y l acetate
B . p . , 104.1
177, 960
3.3- D i m e t hoxypropyne
1742
B.p., I l l
Ethyl acrylate
B . p . , 99.5
178, 796, 933, 1370,
1720, 1744, 1819
Isopropenyl acetate
B.p., 97.4
179, 945, 1150, 1373
Methyl methacrylate
B.p., 100.8
180, 1215, 1242,
1371, 1372
2.4- Pentanedione (acetyl
acetone)
B . p . , 140.6
181, 1373
- Valerolactone
182
V i n y l propionate
183
B . p . , 95.0
Methyl acetoacetate
1192
B . p . , 171.7
Cyclopentane
B . p . , 49.35
894, 975, 1374, 1375
2- M e t h y l -1 - butene
B.p., 31.10
635, 797, 896, 1362
3- M e t h y l -1 - butene
B.p., 21.2
634, 1 3 6 1 , 1376
2-Methyl-2-butene
B . p . , 38.60
636, 895, 1363, 1377
1-Pentene
B . p . , 29.92
637, 946, 976
cis-2-Pentene
B . p . , 37.1
638
Bis( 2- chloroethoxy )
methane
B . p . , 218.1
184

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

80
Formula
C H
5

1 0

3-Dimethylaminopropionitrile
B . p . , 174.5
185
c i s - l - B u t e n y l methyl
ether
B . p . , 72.0
186, 1721
trans-1-Butenyl methyl
ether
B . p . , 76.7
187
Ethyl isopropenyl ether
188
B . p . , 61.9
Isopropyl vinyl ether
B . p . , 55.7
189, 798, 1038
3-Methyl-2-butanone
1378, 1379
B . p . , 95.4
2-Pentanone
B . p . , 102.2
639, 799, 1039,
1380, 1820
3-Pentanone
B . p . , 102
1062, 1381-1384, 1768
P r o p y l vinyl ether
B . p . , 65.1
190, 800, 1722
Tetrahydropyran
B . p . , 88
191

C 5 H 1 0 O

C 5 H 1 0 O

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Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

^ 5 ^ 1 0 ^

C H
5

1 0

C H
5

1 0

C H
5

1 0

C H

1 0

C 5 H 1 0 O

C H
5

1 0

Valeraldehyde

C5H10O
C 5 H 1 0 O S

C H
5

1 0

C H

1 0

C H

1 0

C H

C5Hio0

C5Hio0

C H
5

C 5 H 1 0 O 3

C H
5

C H

C 5 H 1 1 N

C H
5

N O

C 5 H 1 1 N O

C H
5

C H
5

1 2

Formula

Name and System Nos.

B.p.,

103.3

192, 193
2-Methylthioethyl vinyl
ether
1073
Ethyl propionate
194
B . p . , 99.1
Isopropyl acetate
B . p . , 88.7
640, 753, 947,
1151, 1385, 1723, 1750,
1759, 1888, 1894
3-Methoxybutyraldehyde
195
B . p . , 131
P r o p y l acetate B . p . , 101.6
196, 1063, 1243, 1769
Valeric acid
B . p . ,187
197, 198, 1386
3-Vinyloxy-l-propanol
200, 1095, 1107
1-Vinyloxy-2-propanol
199
3-Ethoxypropionic acid
201
B . p . , 219.2
3-Methoxybutyric acid
202
Methoxymethyl propionate
203
Piperidine
B . p . , 106
1340
N,N-Dimethylpropionamide
B . p . , 175.5
1004
4-Methylmorpholine
204
B . p . , 115.6
2-Methylbutane
B . p . , 27.90
641, 897, 1364, 1376
Pentane
B . p . , 36.15
205, 642, 719, 754,
898, 948, 977, 1365,
1377, 1387-1391

C Hi N
5

C 5 H 1 2 O

C H
5

C H
5

C H
5

C H
5

C H
5

C H

CsHi 0
2

5 122

5 122

^5

1 2

5 122

5 122

5 123

^5H

1 2

CsH

1 2

C H

1 3

C Hi NO
5

C H
5

CgFizO
C F
6

1 4

6 3
H

C 1

C6H C1
4

C H Br
6

C H C1
6

C H F
6

C H FO
6

C H N0
6

IN

CHEMISTRY

SERIES

Name and System Nos.


1 - Methylpiperazine
206
B . p . , 138.0
Active amyl alcohol
B.p., 128.5
1333, 1367, 1398-1411
A m y l alcohol
B . p . , 137.9
643, 801, 1 3 9 2 1397, 1821
Butyl methyl ether
802, 1724
B . p . , 70.3
Isoamyl alcohol
B . p . , 131.85
1153, 1334, 1368,
1398, 1412-1426,
1725, 1822, 1914
2- M e t h y l - 1 -butanol
B . p . , 128.9
1369, 1427, 1428
2 - M e t h y l - 2- butanol
1429,1430
B . p . , 101.7
3- P e n t a n o l
B . p . , 115.6
1341
1,2 - D i m e t h o x y p r o p a n e
207
B . p . , 92
2,2- Dimethoxypropane
644, 803
B . p . , 80
1 -Ethoxy-2-propanol
208
B . p . , 132.2
3-Methoxy-1 - butanol
209
B . p . , 161.1
1,5-Pentanediol
210
B . p . , 242.5
2 - Propoxyethanol
211
B . p . , 151.5
2- (2- M e t h o x y ethoxy)
ethanol
B . p . , 194.2
872, 1278, 1431-1454
E t h y l isopropyl sulfide
901
B . p . , 107.22
3 - M e t h y l -1 - but anet h i o l
1412, 1822
B . p . , 116
N - Methylbutylamine
212
B . p . , 91.1
1-Ethylamino-2-propanol
213
B . p . , 159.4
N,N-Dimethyl-1,3-propanediamine
B . p . , 1349
214
Perfluorocyclic ether
1455
Perfluorohexane
918, 1332, 1455, 1456,
1457
1,2,4-Trichlorobenzene
1458
B . p . , 213
o-Dichlorobenzene
1459, 1460
B . p . , 179
Bromobenzene
B . p . , 156.1
1461
Chlorobenzene
B . p . , 131
1064, 1116, 1399,
1413, 1462, 1463, 1889
Fluorobenzene
B . p . , 84.9
1464
o-Fluorophenol
1400, 1414
Nitrobenzene
1465
B . p . , 210.85

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

INDEX

81
Formula

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

N a m e and System Nos.


Benzene
3 . p . , 80.1
38, 555, 601, 645, 720,
733, 804, 867, 916, 932,
949, 978, 1015, 1040,
1065, 1074, 1096, 1135,
1161, 1182, 1188, 1216,
1238, 1279, 1300, 1336,
1374, 1387, 1392, 1429,
1464, 1466-1479,
1711,
1740, 1743, 1760, 1770,
1775, 1780, 1801, 1820,
1823, 1848, 1855, 1858,
1875-1879, 1889,
1890,
1895-1897, 1899, 1901,
1903, 1906, 1910, 1916,
1917, 1929-1933,
1938
Phenol
B . p . , 182
1162,
1480-1488,
1918, 1919
Pyrocatechol
B . p . , 245.9
1489
Aniline
B . p . , 184.35
215, 805, 873,
1490-1498, 1880, 1881,
1920-1922,
1939
2- P i c o l i n e
B . p . , 134
721, 755, 1401, 1415,
1499-1501,
1824,
1966-1869
3- P i c o l i n e
B . p . , 144.1
216, 1502
4- P i c o l i n e
B . p . , 144.3
217
1.3- C y c l o h e x a d i e n e
979
B . p . , 80.25
Aniline hydrochloride
1503
2-Amino-3-methyl pyridine
1504, 1505
B . p . , 221
2,5-Dimethylpyrazine
B.p., 154/742 m m .
218
2,5- D i m e t h y l f u r a n
B . p . , 93.3
219, 646, 1163, 1385
2.4- Hexadienal
B . p . , 171
220
1,3-Butadienyl acetate
221
B . p . , 138.5
V i n y l crotonate
222
B . p . , 133.9
3,3'-Iminodipropionitrile
223
Cyclohexene
B . p . , 83.1
980
2- E t h y l - 1 , 3 - b u t a d i e n e
224
B . p . , 66.9
1.3- H e x a d i e n e
B . p . , 72.9
6 4 7 , 806, 1041
2.4- Hexadiene
B . p . , 82
648, 807, 1042
3- M e t h y l c y c l o p e n t e n e
808
B . p . , 64.9
3 - Methyl - 1 , 3 - pentadiene
B . p . , 77
649, 809, 1043
Cyclohexanone
B . p . , 155.6
225, 1480, 1506,
1825, 1918

C H
6

1 0

C Hi O
6

CHIOO

C HioO
6

C HioO
6

C HioO
6

6 102

6 102

^6

^6

C H N
6

C H NO
6

C H N0
6

C Hi
6

6 12

6 12

6 12

6 12

6 12

C H
6

1 2

6 12

6 12

6 12

C Hi
6

N a m e and System

Nos.

2-Ethylcrotonaldehyde
226, 1779
B . p . , 135.3
2-Hexenal
B . p . , 149
227
M e s i t y l oxide
B . p . , 129.5
1044, 1174, 1402,
1416, 1507-1511
2-Methylcyclopentanone
1393
B . p . , 138
2 - Methyl - 2- pentenal
229
B . p . , 138.7
5- P e n t e n - 2 - o n e
228
B . p . , 128.9
Ethyl crotonate
230
B . p . , 137.8
Vinyl butyrate
231
B . p . , 116.7
Vinyl isobutyrate
232
B . p . , 105.4
Ethylene, diacetate
B . p . , 186
233, 1481, 1919
Diallylamine
B . p . , 110.5
234
6- C a p r o l a c t a m
235
2-Methyl-2-nitropropyl
vinyl ether
236, 1208
Cyclohexane
B . p . , 80.6
39, 237, 602, 650, 734,
810, 950, 961, 981,
1013, 1045, 1066, 1075,
1108, 1136, 1147, 1164,
1189, 1217, 1301, 1309,
1337, 1378, 1380, 1388,
1465, 1466,
1512-1519,
1726, 1771, 1776, 1781,
1848, 1855, 1876, 1890,
1893, 1895-1897,
1899,
1901, 1903, 1906, 1910,
1916, 1929
2,3-Dimethyl-1 -butene
982
B . p . , 55.62
2,3-Dimethyl-2-butene
983
B . p . , 73.38
3,3-Dimethyl-1 -butene
984
B . p . , 41.4
2-Ethyl-1-butene
811, 985
B . p . , 64.95
1-Hexene
B . p . , 63.49
812, 986, 1109
cis-2-Hexene
B . p . , 68.8
813, 987
cis-3-Hexene
B . p . , 66.4
6 5 1 , 814
Methylcyclopentane
B . p . , 71.8
815, 951, 991, 1110,
1137, 1310, 1389, 1467,
1520, 1521, 1875, 1938
c i s - 3- M e t h y l - 2 - pentene
816, 988
B . p . , 70.52
t r a n s - 3 - M e t h y l - 2 - pentene
817
B . p . , 67.6
4 - M e t h y l -1 - pentene
989
B . p . , 54.0
4-Methyl-2-pentene
238, 818
B . p . , 56.7

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

82
Formula

Name andSystem Nos.

C Hi2
6

6 12

C Hi Cl 0
6

6 12
H

C 1

22

C Hi 0
6

C Hi 0

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C Hi 0
6

C Hi 0
6

C H
6

C H

C H
6

C H

C Hi OS
6

C Hi 0
6

C i22
H

C Hi 0
6

C Hi 0

C6Hi Q

C Hi 0
6

C Hi 0
6

6 122
H

QH12O2
C6Hi 0 S
2

t r a n s - 4- M e t h y l - 2 - pentene
990
B . p . , 58.4
1,1,2- T r i m e t h y l c y c l o p r o pane
B . p . , 52.6
952
Bis(chloroisopropyl)ether
239, 1014
B . p . , 187.0
1,2 - B i s ( 2 - c h l o r o e t h o x y )
ethane
B . p . , 240.9
240
Butyl vinyl ether
B.p., 94.2
241, 652, 819,
1218, 1790
Cyclohexanol
B . p . , 160.55
242, 1461, 1482, 1490,
1506, 1512, 1522, 1523,
1825, 1918, 1920
2- Ethylbutyraldehyde
243
B . p . , 116.7
2-Hexanone
B . p . , 127.2
1772
Hexanal
B . p . , 128.3
245, 1219
Isobutyl vinyl ether
B.p., 83.4
244, 820, 1727
2- Methylvaleraldehyde
B.p., 118.3
246, 1067, 1773
4 - M e t h y l - 2- pentanone
B.p., 116.2
582, 6 5 3 , 9 5 3 , 1046,
1468, 1513, 1524, 1525,
1761, 1840, 1916
2-Ethylthioethyl vinyl
ether
B . p . , 169.7
247
Butyl acetate
B . p . , 126.2
583, 954, 1190, 1220,
1232, 1244, 1526-1528,
1785, 1791, 1826, 1827,
1907, 1935
s e c - B u t y l acetate
B.p., 112.3
1233, 1526, 1802,
1826, 1828, 1906
2-Ethylbutyric acid
248
B . p . , 194.2
2-Ethyl - 2- methyl -1,3dioxolane
B . p . , 117.6
251
Hexanoic acid
B.p.,
205.15
249, 1529, 1530
4- H y d r o x y - 4- methyl - 2 pentanone (diacetone
alcohol)
B . p . , 161
250, 1508
2-Methylpentanoic acid
252
B . p . , 196.4
Tetrahydropyran-2methanol
B . p . , 187.2
254
4-Vinyloxy-1 -butanol
253, 1241
2,4- D i m e t h y l suif olane
1532, 1533

Formula

C H

C Hi 0

C Hi N
3

C H
6

C6H13NO
C H
6

1 3

NO

C H

1 3

NO

C Hi N0
6

Co 14
H

C H
6

C H
6

C H
6

C H

C6H14N2

C H
6

N 0
2

C Hi N 0
6

C H
6

C Hi 0
6

C H
6

C H

Name andSystem Nos.

255,
Methyl
256
Paraldehyde
B . p . , 124
821, 1499, 1535,
1536, 1710, 1824
2-(2-Vinyloxyethoxy)ethanol
257, 1280
1-Chlorohexane
258
B.p., 134.5
Cyclohexylamine
B.p., 124.5
259, 1491, 1514, 1920
Hexamethyleneimine
260
B . p . , 138

SERIES

acetate
B.p., 156.2
1534, 1829
3-ethoxypropionate

C Hi Cl
6

CHEMISTRY

2-Ethoxyethyl

C O H 1:203

C H

IN

N,N-Dimethylbutyramide

B.p.,
124.5/100 m m .
1178
2,6-Dimethylmorpholine
261
B . p . , 146.6
4-Ethylmorpholine
262
B . p . , 138.3
4-Morpholineethanol
263
B . p . , 225.5
2,2-Dimethylbutane
B.p.,
49.74
586, 654, 8 9 9 ,
992, 1375
2,3-Dimethylbutane
B.p.,
58.05
955, 993, 1111, 1165
Hexane
B . p . , 68.60
40, 264, 657, 756, 822,
956, 962, 994, 1005,
1112, 1115, 1138, 1166,
1175, 1195, 1221, 1456,
1462, 1469, 1492, 1515,
1520, 1537-1539, 1728,
1753, 1782, 1786, 1792,
1852, 1853, 1877, 1887,
1930, 1938
2-Methylpentane
B.p.,
60.27
655, 823, 995
3-Methylpentane
565, 996
B . p . , 63.28
2,5-Dimethylpiperazine
B.p., 164
265, 1245, 1394
4-(2-Aminoethyl)morpholine
B . p . , 204.7
266
1-Piperazineethanol
267
B . p . , 246.3
Isopropyl propyl ether
1732
Butyl ethyl ether
B.p., 92.2
268, 658, 824,
1729, 1762
2-Ethyl-1 -butanol
B.p., 147.0
269, 1 5 4 0 , 1541
Ethyl isobutyl ether
1730
B . p . , 79

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA
Formula
C

C HuO
6

C Hi 0
6

C H
6

OS

l 4

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

COHUQS

C H
6

C H
6

C H

C Hi 0

0$

INDEX

83

Name and System Nos.


Hexyl alcohol
B . p . , 157.85
270, 874, 1542, 1323
Isopropyl ether
B . p . , 68.0
271, 701, 709, 742, 757,
825, 963, 1152, 1183,
1327, 1370, 1543, 1705,
1731, 1751, 1763, 1812,
1819, 1830, 1841, 1891,
1894
2- M e t h y l - 1 -pentanol
272
B . p . , 148
4-Methyl-2-pentanol
273, 1544
B . p . , 131.8
2-Butylthio ethanol
1545
2-Butoxy ethanol
B.p., 171.2
1191, 1222, 1527,
1546-1557
1,1 - D i e t h o x y e t h a n e
274
B . p . , 102.1
1,2 - D i e t h o x y e t h a n e
826, 1543
B . p . , 121.1
1,1-Dimethoxybutane
B . p . , 114
275, 659, 1176
2,2-Dimethoxybutane
660
B.p., 106-7
1,3-Dimethoxybutane
276
B . p , 120.3
1,1-Dimethoxy-2-methyl
propane
B . p . , 104.7
277
Hexylene glycol
1558, 1559, 1923
2-Methyl-1,5-pentane diol
278
B . p . , 242.4
3-Methyl-l,5-pentanediol
279
B . p . , 248.4
Bis(2 - methoxyethyDether
280
B . p . , 162
Dipropylene glycol
1097, 1 5 6 0 , 1561
2- (2-Ethoxyethoxy)ethanol
B.p., 202.8
281, 875, 1246, 1281,
1562, 1563
Triethylene glycol
B.p., 288.7
1282, 1564-1568
Isopropyl sulfide
1196
B . p . , 119.25
Diisopropylamine
'
B . p . , 84.1
282, 1047, 1764
1,3-Dimethylbutylamine
283
B . p . , 108.5
Dipropylamine
B . p . , 109
284
N-Ethylbutylamine
285
B . p . , 111.2
Hexylamine
B . p . , 132.7
286, 1048
Triethylamine
B . p . , 89.4
287, 827, 1706,
1830, 1857, 1927
2-Butylaminoethanol
288
B . p . , 199.3

Formula

C6H15NO
C Hi5NO
6

C H
6

C H

1 5

N0

NO 3

C6H15N3

C H
6

1 6

C H

1 6

CHioOSi

C7FH

C7F16

C H
7

C H
6

C Hi 0

CHI 0

C Hi 0
4

C Hi 0
6

C H
6

C H

C Hi S
6

C H
6

C Hi N
6

C H
6

Ce i5
H

C H
6

C H

C H

1 5

NO

C7H5F3
C7H60

C7H7F
C H
7

C H O
7

C H 0
7

C H 0
7

C H 0
7

C H O
7

C H 0
7

C7H9CIO

C7H9N

Name and System Nos.

2-Diethylaminoethanol
289, 1328
B . p . , 162.1
1-Isopropylamino-2-pro
panol
B . p . , 164.5
290
1,1'-Iminodi-2-propanol
B.p., 185/100 m m .
1117, 1569
2,2 ' , 2 " - N i t r i l o t r i e t h a n o l
1329
4-(2-Aminoethyl)piperazine
B . p . , 222.0
291
N,N-Diethylethylenediamine
B . p . , 144.9
292
,,','-Tetramethylethylenediamine
293
B . p . , 119
l-(Trimethylsiloxy) propane
B.p., 100.3/735 m m .
1068
Perfluoro(methylcyclohexane)
B . p . , 73-78
1470
Perfluoroheptane
B . p . , 83
371, 1390, 1471,
1537, 1570-1573
C 7 Hydrocarbons
B.p., 95-120
1417, 1427
, a, a - T r i f l u o r o t o l u e n e
20
B . p . , 103.9
Benzoic acid
1574
o-Fluorotoluene
B . p . , 114
1403, 1418
Toluene
B . p . , 110.7
294, 556, 6 6 1 , 828, 876,
902, 917, 967, 1049,
1069, 1098, 1118, 1122,
1132, 1184, 1197, 1223,
1342, 1404, 1419, 1428,
1430, 1493, 1516, 1521,
1534, 1538, 1575-1582,
1733, 1754, 1765, 1777,
1778, 1809, 1829, 1831,
1832, 1842, 1880, 1882,
1905, 1911, 1912, 1914,
1920, 1921, 1934, 1939
B e n z y l alcohol B . p . , 205.2
877, 1583
x-Cresol
B . p . , 202
1586-1588, 1924-1926
o-Cresol
B . p . , 191
878, 1585, 1883
m - and p-Cresol
B.p., 202
1584, 1589, 1590
p-Cresol
B . p . , 201.7
1575, 1591
Guaiacol
B . p . , 205.0
295
2-Chloroallylidene d i
acetate
B . p . , 212.1
296
2,6-Lutidine
B . p . , 144
297, 758, 1405, 1420,
1502, 1593, 1870-1872

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

IN

Formula

N a m e and S y s t e m Nos.

84
Formula
C H N
7

N-

C H N
7

C H N
7

C H N
7

C Hi O
7

C H
7

1 0

C Hi
7

C H

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

^7 12

C7H

C1

1 2

C Hi20
7

C H

C Hi 0

C H
7

C H
7

C H
7

1 4

C H
7

1 4

C Hi
7

C Hi

C Hi

C H

C H
7

N a m e and System N o s .

Methylaniline
879, 1494, 1592
Pyridine bases
1586-1588,1924-1926
Tetrahydrobenzonitrile
298
B . p . , 195.1
o-Toluidine
B . p . , 200.7
1594
1,2,3,6- Tetrahydrobenzal dehyde
B . p . , 164.2
299
Allylidene diacetate
300
2,4-Dimethyl-1,3-penta
diene
B . p . , 93.3
301
1,3-Heptadiene
829
2,4-Heptadiene
830
Tetrachloroheptane
1366
3-Hepten-2-one
302, 1509
B . p . , 162.9
Butyl acrylate
B . p . , 147
303, 1224, 1793
Cyclohexyl formate
1522
2-Ethoxy- 3,4-dihydro-1,
2-pyran
B . p . , 142.9
304
Pimelic acid
305
1,1 - D i m e t h y l c y c l o p e n t a n e
B . p . , 87.85
831, 1303, 1312, 1320
cis-1,2 - Dimethylcyclo
pentane
B . p . , 99.53
832
trans-1,2-Dimethylcyclo
pentane
B . p . , 91.87
833
cis-1,3-Dimethylcyclo
pentane
B . p . , 91.73
834
trans-1,3-Dimethvlc vclopentane
B . p . , 90.77
662, 835, 1139,
1302, 1311, 1319
2,3- D i m e t h y l -1 - pentene
836
B . p . , 84.2
Ethyl cyclopentane
B . p . , 103.47
837, 1317, 1354
trans-2-Heptene
1076
B . p . , 98.0
Methylcyclohexane
B . p . , 101.05
903, 1167, 1234, 1304,
1318, 1338, 1381, 1391,
1472, 1539, 1576, 1595,
1734, 1803, 1878, 1911,
1913, 1 9 2 1 , 1931
1,1,2,2- T e t r a m e t h y l c y c l o propane
B . p . , 75.9
838
Butyl isopropenyl ether
306
B . p . , 114.8

C H
7

C H

C H O
7

C H
7

C H

C7H

1 4

C H

1 4

C H
7

C H

C H

1 5

C H

C H

1 5

16

C H
7

C H

C Hi

NO

7 16

C H

7 16
H

C7 16
H

7 16
H

C H
7

1 6

C H

1 6

CHEMISTRY

SERIES

2,4 - D i m e t h y l - 3 - p e n t a n o n e
1 4 0 6 , 1421
B . p . , 125
3-Heptanone
B . p . , 147.6
307
4 - D i m e t h y l - 3-pentanone
308
B . p . , 143.7
5-Methyl-2-hexanone
309
B . p . , 144
A m y l acetate
B . p . , 146
310
Heptanoic acid
1597
B . p . , 222.0
Ethyl 3-ethoxypropionate
311
B . p . , 170.1
3-Methoxybutyl acetate
312
B . p . , 171.3
2- ( 2 - M e t hoxy ethoxy) ethyl
acetate
B . p . , 208.9
313
1,2-Dimethyl piperidine
1407, 1422
B . p . , 128
2,6 - D i m e t h y l p i p e r i d i n e
B . p . , 128
1386, 1408, 1423
N,N-Dimethylvaleramide
B.p., 141/100 m m .
1386
2,2 - D i m e t h y l p e n t a n e
B . p . , 79.20
41, 839, 1113, 1316
2,3-Dimethylpentane
B . p . , 89.78
42, 840, 1140, 1306,
1314, 1322, 1473, 1917
2,4 - D i m e t h y l p e n t a n e
B . p . , 80.50
43, 735, 841, 997, 1141,
1307, 1315, 1474, 1517
3,3-Dimethylpentane
842
B . p . , 86.07
3 - E t h y l pentane
843
B . p . , 93.47
Heptane
B . p . , 98.25
314, 663, 722, 759, 844,
904, 957, 968, 998,
1006, 1119, 1124, 1142,
1148, 1168, 1225, 1235,
1339, 1343, 1350, 1355,
1379, 1382, 1475, 1495,
1518, 1570, 1577, 1595,
1598-1600, 1735, 1794,
1804, 1813, 1859, 1879,
1881, 1882, 1912, 1913,
1922, 1932, 1939
2-Methylhexane
B . p . , 90.05
664, 845, 999
3- Methylhexane
B . p . , 91.85
665, 846, 1000,
1305, 1313, 1321
2,2,3- T r imethylbutane
B . p . , 80.88
44, 666, 1001, 1519
3-Heptanol
B . p . , 156.4
1155
5- Methyl - 2- hexanol
315

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA

85

Formula

N a m e and System

7 162

1 - Butoxy- 2- methoxyethane
316
B . p . , 149.9
1 - t e r t - B u t o x y - 2- methoxy
ethane
1077
1- B u t o x y - 2 - p r o p a n o l
317
B . p . , 170.1
2 - Ethyl - 1 , 5 - pentanediol
318
B . p . , 253.3
Dipropoxymethane
1774
B . p . , 146.6
Dipropylene glycol methyl
ether
1601
1 - (2-Ethoxyethoxy) - 2-pro
panol
B . p . , 198.1
319
2-Ethoxyethyl 2-methoxyethyl ether
320
2 - (2- P r o p o x y ethoxy )
ethanol
B . p . , 215.8
321
1 - Diethylamino-2-pro
panol
B . p . , 159.5
322
3- Diethylaminopropyl amine
B . p . , 169.4
323
( T r i m e t h y l s i l o x y )butane
1226
P e r f l u o r o c y c l i c oxide
B.p.,
102.6
1125, 1330, 1571,
1596, 1602-1604
Perfluorobutyl ether
1476, 1598
B . p . , 100
ar-Trichlorostyrene
1605
a r - D i c h l o r o styrene
1431
Coumarone
B . p . , 173
1099
Indole
B . p . , 253
1283
Styrene
B.p., 67.9/57
324, 1070, 1078, 1247,
1606, 1736, 1898, 1908
2-(2,4-Dichlorophenoxy)
ethanol
325
Acetophenone
B . p . , 201.6
326
(Epoxyethyl)benzene
327
B . p . , 194.2
P h e n y l a c e t a t e B . p . , 195.1
1483, 1919
Methyl salicylate
1608
B . p . , 222.3
Ethylbenzene
B . p . , 136.15
328, 1011, 1071, 1079,
1126, 1193, 1227, 1248,
1284, 1344, 1409, 1424,
1558, 1599, 1606, 16091614, 1860, 1873, 1898,
1908, 1915, 1923, 1936

C H
7

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

INDEX

7 162

7 lcP2

7 163

7 lo03

7 163

C H
7

1 6

C H
7

1 7

NO

C H
7

1 8

C H
7

1 8

OSi

C F

C Fi 0
8

C H5Cl3
8

C H C1
8

C H 0
8

C H N
8

C H
8

C H C1 0
8

C H O
8

C H 0
8

C H 02
8

C H 03
8

C H
8

1 0

Formula

Nos.

C H
8

1 0

C Hio
8

C Hio
8

C HioO
8

C H N
8

C H N
8

C H N
8

C H N
8

C H N
8

C H N
8

C Hi
8

C H
8

1 2

C H
8

1 2

C H

1 2

C Hi4
8

C H!P
8

C H
8

C H

1 4

C H

O
0
O

C H O
8

8 142
H

C H
8

8 142

8 142

C Hi 0

C H

8 143
H

N a m e and System Nos.


m-Xylene
B . p . , 139
329, 728, 1012, 1127,
1129, 1194, 1249, 1535,
1607, 1615, 1616
-Xylene
B.p., 143.1/735 m m .
760, 880, 1100, 1250,
1345, 1617, 1861, 1937
p-Xylene
B . p . , 138.35
~
667, 729, 1072, 1080,
1128, 1251, 1285, 1536,
1618
-Methylbenzyl alcohol
330
B . p . , 203.4
N,N-Dimethylaniline
B.p., 194.05
881, 1496, 1592
N-Ethylaniline
331
B . p . , 204.8
- Methylbenzylamine
332
B . p . , 188.6
2- M e t h y l - 5- ethyl p y r i d i n e
333, 1578
B . p . , 178.3
x-Methyl-1,2,3,6-tetrahydrobenzonitrile
334
B . p . , 205.4
s-Collidine
B . p . , 171.3
882, 1585, 1883
4-Vinylcyclohexene
1081
2-Methyl-l,2,3,6-tetrahydrobenzaldehyde
335
B . p . , 176.4
3,4-Dihydro- 2,5- d i m e t h y l 2H- pyran- 2- carboxaldehyde
B . p . , 170.9
336
Diethyl fumarate
337
B . p . , 218.1
Diisobutylene
B . p . , 102.3
338, 1050, 1236,
1766, 1805
Bicyclo[2.2.1 ]-heptane-2methanol
B . p . , 203.9
339
Cyclohexyl vinyl ether
1523
Diisobutylene oxide
340
2 - Ethyl - 2- hexenal
341, 668
B . p . , 176
2-Octenal
342
Butyl methacrylate
1371
1,1 - D i a l l y l o x y e t h a n e
343
B . p . , 150.9
2-Ethyl-3-hexenoic acid
344
B . p . , 231.8
Vinyl 2-methylvalerate
345
B . p . , 148.8
Bis(2-vinyloxyethyl)ether
346, 1619
B . p . , 198.7
Butyl acetoacetate
347
B . p . , 213.9
2-Ethoxyethyl methacryl
ate
1372

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

86
Formula
C H
8

C H

1 5

C H
8

1 6

C H
g

1 6

CQHI

C H
8

1 6

C H

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

1 6

^8 16
H

CeHi6

C H
8

1 6

C Hi
8

Ce l6
H

CeHi6

C H
8

1 6

C Hi
8

8 16
H

C H

1 6

C H

1 6

C H
8

C H i6
8

C Hi6
8

C H i6
8

C Hi6
8

C Hi
8

N a m e and System

Formula

Nos.

Diethyl succinate
348
B . p . , 216.2
2-(Aminoethyl)bicyclo
[2.2.1 Jheptane
349
B . p . , 185.9
1,1- D i m e t h y l c y c l o h e x a n e
847
B . p . , 119.54
trans-1,2-Dimethylcyclo
hexane
B . p . , 123.42
1051, 1252
1,3-Dimethylcyclohexane
1383
B . p . , 120.3
cis-1,3-Dimethylcyclohex
ane
B . p . , 120.09
1082
trans-1,3-Dimethylcyclo
hexane
B . p . , 124.45
849, 905, 1198, 1356
cis-1,4-Dimethylcyclohexane
B . p . , 124.32
848
trans-1,4-Dimethylcyclo
hexane
B . p . , 119.35
850
Ethylcyclohexane
B.p., 131.85
1199, 1253, 1559,
1602, 1609, 1923
1-Ethyl-1-methylcyclopentane
B . p . , 121.52
851
c i s - 1 - E t h y l - 2- methyl cyclopentane
1052
B . p . , 128.05
trans -1 - E t h y l - 2 - methyl cyclopentane
B . p . , 121.2
1053, 1083
t r a n s - 1 - E t h y l - 3- m e t h y l cyclopentane
B . p . , 120.8
1054, 1084
1-Octene
B . p . , 121.6
1610
is-2-Octene
B . p . , 125.6
1254
1,1,2-Trimethylcyclopentane
B . p . , 113.73
1055, 1357
1,1,3-Trimethylcyclopentane
B . p . , 104.89
1056, 1085
1,cis- 2,cis- 3 - T r i m e t h y l cyclopentane
B . p . , 123.0
1086
1,cis-2, trans- 3-Trimethyl
cyclopentane
B . p . , 117.5
852, 1057
1,trans-2,cis- 3-Trimethyl cyclopentane
B . p . , 110.2
1087
1,cis-2,trans - 4-Tr imethyl cyclopentane
1058
B . p . , 116.73
1, t r a n s - 2 , c i s - 4 - T r i m e t h y l cyclopentane
853
B . p . , 109.29
2,4,4-Trimethyl-1-pentene
493, 1088
B . p . , 101.44

C Hi
8

C H
8

1 6

C Hi 0
8

C Hi 0
8

C Hi OS
8

C Hi 02
8

C Hi 0

C Hi 0

8 162

8 162

C Hi 0

C Hi 0

8 162

8 162

8 163

8 163

8 163

8 164

C H
8

C1

1 7

C Hi Cl
8

C H
8

1 7

C H

1 7

C Hi NO
8

C Hi NO
8

8 18

8 18

C Hl8
8

IN

CHEMISTRY

N a m e and S y s t e m

SERIES
Nos.

2,4,4- T r i m e t h y l - 2 - pentene
854
B . p . , 104.91
2-Ethylhexanal
350, 1540
B . p . , 163.6
2,4,4- T r imethyl -1,2epoxypentane
B . p . , 140.9
351
2,4,4-Trimethyl-2,3epoxypentane
B . p . , 127.3
352
2-Butylthioethyl vinyl
ether
B . p . , 210.5
353, 1545
2-Butoxyethyl vinyl ether
354
1,3 - D i m e t h y l b u t y l a c e t a t e
1620
B . p . , 146.1
2,3- Epoxy- 2- ethylhexanol
355
2-Ethylbutyl acetate
356, 1542
B . p . , 162.3
2-Ethylhexanoic acid
3 5 7 , 1621
B . p . , 227.6
H e x y l acetate
B . p . , 171.0
358
Iso-octanoic acid (iso
mers)
B . p . , 220
359
4 - M e t h y l - 2 - p e n t y l acetate
B.p.,
146.1
360, 1510, 1524, 1544
Octanoic acid
B . p . , 238.5
1529, 1622
2-Butoxyethyl acetate
361
B . p . , 192.2
2,5- Diethoxytetrahydrofuran
B . p . , 173.0
362
2- Ethoxyethyl 2-vinyloxyethyl ether
B . p . , 194.0
363
2 - (2- thoxy ethoxy) ethyl
acetate
B . p . , 217.4
364, 1623
1 - C h l o r o - 2 - ethylhexane
365
B . p . , 173
3- ( C h l o r o m e t h y l ) h e p t a n e
1541, 1624
N-Ethylcyclohexylamine
366
B . p . , 164.9
5- Ethyl - 2- methyl piper i dine
B . p . , 163.4
367
ar-Methylcyclohexanemethylamine
368
N,N-Dimethylhexanamide
1530
4- E t h y l - 2 , 6 - d i m e t h y l m o r
pholine
B . p . , 158.1
369
2,2- Dimethylhexane
B.p., 106.84
855, 1323, 1353
2.3 - D i m e t h y l h e x a n e
856, 906
B . p . , 115.61
2.4 - D i m e t h y l h e x a n e
1089
B . p . , 109.43

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA

INDEX

Formula
C H
8

1 8

C H
8

1 8

C H

1 8

C Hi

C Hi

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

N a m e and System Nos.

8 18
H

C Hi

C Hi

C H
8

1 8

C^H^
C H
8

1 8

C H
8

1 8

C H
8

1 8

C H

1 8

Cl Sn
2

C Hi 0
8

C H
8

C H
8

1 8

1 8

C Hi 0
8

C Hi OS
8

C Hi 02
8

C Hi 2
8

C Hi 0
8

C Hi 02
8

2,5 - D i m e t h y l h e x a n e
B.p.,
109.15
1169, 1200, 1255,
1352, 1360, 1384
3,3-Dimethylhexane
1256
B . p . , 111.97
3,4-Dimethylhexane
857
B . p . , 117.73
3-Ethyl-3-methylpentane
1257
B . p . , 118.26
Iso-octane
529, 1237, 1497,
1579, 1806, 1933
2-Methylheptane
B.p.,
117.65
858, 907, 1201,
1351, 1359
3-Methylheptane
859
B . p . , 118.93
4-Methylheptane
860
B . p . , 117.71
-Octane
B . p . , 125.7
48, 370, 669, 723, 761,
1007, 1202, 1228, 1258,
1346, 1358, 1396, 1410,
1425, 1477, 1500, 1572,
1611, 1618, 1795, 1814,
1862, 1866, 1870
2,2,3-Tr imethylpentane
861, 1090
B . p . , 109.84
2 , 2 , 4 - T r i m e t h y l pentane
B.p.,
99.24
862, 1059, 1308, 1324,
1478, 1580, 1600, 1603
2,3,3-Trimethylpentane
863
B . p . , 114.76
2,3,4-Tr imethylpentane
864
B . p . , 113.47
Dibutyltin dichloride
B.p., 157/17 m m .
1204, 1 6 2 5 , 1902
Butyl ether
B . p . , 142.1
865, 883, 969, 1107,
1149, 1206, 1229, 1239,
1528, 1626, 1737, 1796,
1807, 1827, 1828, 1907,
1935
2- Ethyl-1 - hexanol
B.p.,
184.8
371, 1156, 1484, 1615,
1624,
1626-1629
Iso-octyl alcohol (isomers)
372
B . p . , 186.5
Octyl alcohol
B . p . , 195.15
1630
2- Hexylthio ethanol
1631
1-Butoxy-2-ethoxye thane
374
B . p . , 164.2
1,1- Diethoxybutane
375
B . p . , 146.3
5-Ethoxy-3-methylpentanol
B . p . , 211.7
376
2-Ethyl-1,3-hexanediol
B . p . , 243.1
373, 866, 1632, 1738

87
Formula
C
8

1 8

C Hi 02
8

C Hi 0

C H

QHieOs

C Hi 0

C H
8

C H
8

1 9

C H

1 9

C Hi NO
8

C H

C H

1 9

N0

NO 2

C F iN
9

C HgN202
9

C H N 0
9

C H N
9

C H N
9

C H 0
9

C H
9

1 0

^
C Hio02
9

C Hio0

C H
9

1 0

C H
9

1 1

C H

1 2

C Hi
9

C Hi2
9

N a m e and System Nos.


2- thyl - 3- m e t h y l - 1 , 5 pentanediol
B . p . , 265.5
377
2-Hexyloxyethanol
378
B . p . , 208.1
2-(2-Methylpentoxy)
ethanol
B . p . , 197.1
379
Bis(2-ethoxyethyl) ether
B.p.,
188.4
381, 1562, 1619
2-(2-Butoxyethoxy)ethanol
B.p.,
231.2
380, 884, 1286,
1479, 1 6 3 3 - 1 6 3 7 , 1847
l,2-Bis(2-methoxyethoxy)
ethane
382
2-[2-(2-Ethoxyethoxy)
ethoxy] ethanol
1287
Dibutylamine
B . p . , 159.6
383, 1230, 1797,
1811, 1904
2-Ethylhexylamine
384
B . p . , 169.1
2-Diisopropylaminoethanol
385, 885
B . p . , 190.9
2,2' - B u t y l i m i n o d i e t h a n o l
386
1,1'- E t h y l i m i n o d i - 2 propanol
B . p . , 238.9
387
Tris(perfluoropropyl)
amine
B . p . , 130
1638
2,4-Tolylene diisocyanate
1458, 1459, 1463, 1639
2,6-Tolylene diisocyanate
1639
Isoquinoline
1640
Quinoline
B . p . , 237.3
1641
V i n y l benzoate
388
-Methyl styrene
1485
Benzyl vinyl ether
1583
l,2-Epoxy-3-phenoxypropane
B . p . , 244.4
389
Ethyl benzoate
B . p . , 213.3
584, 1 5 8 4 , 1591
Ethyl salicylate
1642
B . p . , 233.7
5-Ethyl-2-vinyl pyridine
390
Cumene
B . p . , 152.4
391, 762, 1486, 1546,
1612, 1638, 1643
m-Ethyltoluene
1433
B . p . , 161.31
o-Ethyltoluene
B.p.,
165.15
1259, 1434

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

Formula

p-Ethyltoluene
1432
B . p . , 161.99
x "
y
1531
Mesitylene
B . p . , 164.72
1260, 1437, 1644
Propylbenzene
1487
B . p . , 158.9
1,2,3-Trimethylbenzene
1435
B . p . , 176.08
1,2,4-Trimethylbenzene
B.p.,
169.35
1436, 1644

C9H12

C H
9

1 2

CcjHxg
C9H12

C H
9

C9H12

C9.H12OS

C H

C H

1 3

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C H
9

C H
9

NO
O

1 4

C H
9

1 4

OSi

C H
9

1 5

C H

1 6

C H

C H

1 6

C H
9

C H
9

1 8

C H
9

1 8

C H
9

1 8

C H
9

1 8

C H
9

1 8

C H

1 8

C9Hi 0
8

C9H18O

C Hi80
9

Name and System N o s ,

CgH^Oj
C9H18O3

CgH^NO

2-Benzylthioethanol

1645
Bicyclo[2.2.1 ]hept-5-ene2-ol acetate
B . p . , 188.6
392
5-Ethyl- 2-pyridineethanol
393
Isophorone
B . p . , 215.2
394, 1646
1-Methyl-2,5-endomethylenecyclohexane-1 - meth
anol
B . p . , 211.1
395
Phorone
B . p . , 197.8
886
(Tr imethyl siloxy)benzene
1488
B . p . , 181.9
Triallylamine
B . p . , 151.1
396
cis-Hexahydroindan
1547
B . p . , 167.7
5-Ethyl-3-hepten-2-one
397
B . p . , 193.5
2,2-Bis(allyloxy)propane
1755, 1891
Dimethyl pimeiate
398
B . p . , 248.9
Butylcyclopentane
1261
B . p . , 156.56
Isobutylcyclopentane
1262
B . p . , 147.6
Isopropylcyclohexane
1263
B . p . , 154.5
1-Nonene
B . p . , 146.85
1264
Propylcyclohexane
B.p.,
156.72
1265, 1647
1,1,3-Trimethylcyclohexane
B . p . , 136.6
1091
2,6-Dimethyl-4-heptanone
B.p., 169.4
399, 670, 1207,
1511, 1525, 1620
2-Ethylheptanal
1616
2-Heptyl acetate
400
B . p . , 176.4
3-Heptyl acetate
401
B . p . , 173.8
3- ( 2 - E t h y l b u t o x y ) p r o p i o n i c
acid
402
N,N-Dimethylheptanamide
1597

ADVANCES

IN

Formula

Name andSystem Nos.

C920
C H
9

CQHOQ

C o9H 2. 0
n

C 9H 2, 0
Q

Con
H o
9

C H o
2

C H o
2

C H
Q

C9H o
2

C H
9

2 0

C H
9

2 0

C H

2 0

C9H20

C9H20O

C H
9

C9H20O2

9 202
H

C9H20O3

C H
9

O3

2 0

9 203
H

C H
9

2 0

C H o0
9

C H2iN
9

C H
9

C H2iNC>2
9

CHEMISTRY

SERIES

3,3-Diethylpentane
1266
B . p . , 146.17
n-Nonane
B . p . , 150.2
403, 671, 724, 763, 970,
1008, 1231, 1267, 1325,
1347, 1501, 1573, 1613,
1617, 1627, 1648, 1798,
1815, 1863, 1867, 1873,
1936, 1937
2,2,3,3-Tetramethylpentane
B . p . , 140.27
1268
2,2,3,4- Tetramethylpentane
B . p . , 133.02
1092
2,2,4,4- Tetr amethylpentane
B . p . , 122.28
1269
2,3,3,4-Tetramethylpentane
B . p . , 141.55
1270
2,2,3-Trimethylhexane
1271
B . p . , 133.60
2,2,4-Trimethylhexane
1272
B . p . , 126.54
2,2,5-Trimethylhexane
B . p . , 124
1411, 1426, 1614
2,3,3-Trimethylhexane
1273
B . p . , 137.68
2,3,4-Trimethylhexane
1093, 1604
B . p . , 139.0
2,3,5-Trimethylhexane
B.p.,
131.34
1094, 1274
2,4,4-Trimethylhexane
1275
B . p . , 130.65
3,3,4-Trimethylhexane
1276
B . p . , 140.46
2,6-Dimethyl-4-heptanol
404, 1649
B . p . , 178.1
Dibutoxymethane
1799
B . p . , 181.8
Diisobutoxymethane
1808
B . p . , 163.8
2-Ethyl-2-butyl-l,3propanediol
405
l-(2-Butoxyethoxy)-2propanol
B . p . , 230.3
406
2-(2-Isoamyloxyethoxy)
ethanol
1605
2-Methoxymethyl-2,4dimethyl-1,5-pentanediol
407
1,1,3-Triethoxypropane
408
Tripropylene glycol
1650-1652
N-Methyldibutylamine
409
B . p . , 163.1
Tripropylamine
B . p . , 156.
410
1,1 ' - I s o p r o p y l i m i n o d i - 2 propanol
B . p . , 248.6
411

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA
Formula
C H iN0
9

C9H21NO4

ClO 8
H

Ci H N
0

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

H o0

1 0

10 123

10 14

10 14

10 14

Hi

CioHi

10 14

10 14

C
C

10 14
H

1 0

1 4

10 143
H

Ci H

1 5

C10H15N
C10H15NO
C10H16
CioHi 0
6

CioHieO

CIQHI 0
6

INDEX

89

Name and System Nos.


1,1 ' , 1 " - N i t r i l o t r i - 2 - p r o
panol
1569
2-(2-[2-(3 - A m i n o p r opoxy )
ethoxy ]ethoxy)ethanol
412
Naphthalene
B . p . , 218.1
887, 1102, 1288, 1560,
1589, 1633, 1653, 1678,
1924-1926
2,2'-Dipyridyl
B . p . , 274.
1348
D i m e t h y l phthalate
413
B . p . , 282.9
2-Phenoxyethyl acetate
414
B . p . , 260.6
Butylbenzene
B . p . , 183.27
1438, 1548
sec-Butylbenzene
B . p . , 173.30
1439, 1549
t e r t - B u t yl b e n e n e
B . p . , 169.11
1440, 1550
p-Cymene
B . p . , 177.2
1445, 1 4 9 8 , 1551
Dicyclopentadiene
415
B . p . , 172
m-Diethylbenzene
1442
B . p . , 181.13
-Diethylbenzene
1443
B . p . , 183.78
5- E t h y l - m - x y l e n e
1444
B . p . , 183.75
Isobutylbenzene
1441
B . p . , 172.76
1,2,3,5-Tetramethylbenzene
B . p . , 197.93
1446
Nicotine
416
Ethyl bicyclo[2.2.1]hept5-en-2-carboxylate
417
B . p . , 198
2 - (2 - P h e n o x y e t h o x y )
ethanol
B . p . , 297.9
418
N - B u t y l a n i l i n e B . p . , 240.4
419
N-Ethyl-a-methylbenzylamine
B . p . , 201.2
420
,,-Trimethylbenzyl- '
amine
B . p . , 195.8
421
2 - ( a-Methylbenzylamino)
ethanol
422
Camphene
764
Dicyclopentenol
423
Trimethyltetrahydrobenzaldehyde
B . p . , 204.5
424
Diisopropyl maleate
425
B . p . , 228.7

Formula
CioHie
Ci Hi O

CioHi 0

CioHi 0
8

CioH

2 0

CioH o
2

CioH
C

2 0

10 20
H

CioH o
2

CioH o
2

C 10^20
CioH oO
2

CioH^O
Ci H
0

2 0

OS

CioH o0

CioH o0
2

H o0

1 0

C10H20O3
CioH iCl
2

C10H21N
C

1 0

2 1

NO

C10H22

CioH

2 2

CioH

2 2

C10H22
C10H22O
C10H22O
C10H22OS

^10^22^2

Name and System Nos.


Decahydronaphthalene
1654
Vinyl
2-ethylhexanoate
426
B . p . , 185.2
V i n y l octanoate (isomers)
427
Menthone
B . p . , 209.5
1655
n- Butylcyclohexane
1552
B . p . , 180.95
sec- Butylcyclohexane
1553
B . p . , 179.3
tert- Butylcyclohexane
1277
B . p . , 171.5
Isobutylcyclohexane
1554
B . p . , 171.3
cis-1-Isopropyl-4-methyl
cyclohexane
B . p . , 172.7
1555
trans-1-Isopropyl-4methylcyclohexane
1556
B . p . , 170.5
2-Ethylhexyl vinyl ether
428, 1810
B . p . , 177.7
Menthol
1655
Octyl vinyl ether
1630
2-Hexylthioethyl vinyl
ether
888, 1631
2-Ethylbutyl butyrate
429
B . p . , 199.6
2 - E t h y l h e x y l acetate
430, 1628
B . p . , 198.4
4-Methyl-2-pentyl butyr
ate
B . p . , 182.6
431
2 - Butoxy ethyl 2- vinyl oxyethyl ether
B . p . , 226.7
432
Chlorodecane (isomers)
433
B . p . , 210.6
N-Butylcyclohexylamine
434
B . p . , 209.5
N,N-Dimethyloctanamide
B.p., 187/100 m m .
1622
Decane
B . p . , 173.3
672, 725, 765, 1009,
1016, 1349, 1593, 1654,
1816, 1864, 1868, 1871
3 - E t h y l - 3- methylheptane
1326
B . p . , 163
3,3,5- T r imethylheptane
1557, 1656
B . p . , 155.5
Decyl alcohol
B . p . , 232.9
1 5 8 1 , 1 6 5 7 , 1831
2-Ethyloctanol
436
B . p . , 220.5
2- Propylheptanol
437
B . p . , 217.9
2 - (2 - t h y l h e x y l t h i o )
ethanol
1658
1,2- Dibutoxyethane
438
B . p . , 203.6

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES

90
Formula
^10^22^2
C10H22O3

10 224
H

10 224
H

Cl H
0

2 3

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C10H23N

^10^23^
C
C

1 0

NO

2 3

11 10
H

11 10
H

C H OS
n

1 4

C11H1403

11 143
H

11 16
H

CnH

C H
n

1 6

1 7

11 182
H

11 20
H

C11H20O4
C11H22
CllH

2 2

11 222
H

CnH 20
2

C11H24

Formula

N a m e andSystem N o s .
1,2 - D i i s o b u t o x y e t h a n e
439
B.p., 160.5
2 - (2- Hexyloxyethoxy )
ethanol
B . p . , 259.1
440
1,2 - B i s ( 2 - e t h o x y e t h o x y )
ethane
B . p . , 206.9
441
Tripropylene glycol methyl
ether
B . p . , 243
889, 1103, 1659
Bis[2-(2-methoxyethoxy)
ethyl ]ether
442
Decylamine (isomers)
443
B . p . , 203.7
Diamylamine (isomers)
444
B . p . , 190
N , N - Dimethyl - 2- ethylhexylamine
B . p . , 176.1
445
2- Dibutylaminoethanol
446
B . p . , 228.7
1- Methylnaphthalene
B.p., 244.8
1504, 1634, 1660
2- Methylnaphthalene
B . p . , 241.1
773, 1447, 1505,
1561, 1563, 1590, 1601,
1608, 1621, 1623, 1635,
1640, 1641
2- (Benzylmercapto)- ethyl
vinyl ether
1289, 1645
Butyl salicylate
447
B . p . , 268.2
Ethyl 6-formylbicyclo[2.2.1 ] h e p t - 5 - e n - 2 - c a r boxylate
448
t e r t - A m y l b enz ene
1448
B . p . , 198.1
Allyl 6-methyl-3,4-epoxycyclohexanecarboxylate
449
B . p . , 251.4
N,N-Diethyl-o-toluidine
1594
Isopropyl 6-methyl- 3cyclohexenecarboxylate
450
B . p . , 215.2
5 - E t h y l - 3- n o n e n - 2 - one
451
B . p . , 226.4
Diethyl pimelate
452
B . p . , 268.1
tert-Amylcyclohexane
1449
B . p . , 198.1
5 - E t h y l - 2 - nonanone
453
B . p . , 222.9
2,6 - D i m e t h y l - 4 - h e p t y l
acetate
B . p . , 192.2
454
4- M e t h o x y - 2,6- d i p r o p y l 1,3-dioxane
B . p . , 223.6
455
Undecane
B . p . , 195.88
456, 673, 726, 766,
1010, 1017, 1179, 1450,

CiiH

CHEMISTRY

SERIES

N a m e a n dS y s t e m N o s .
1817, 1865, 1869, 1872,
1892, 1900
5-Ethyl-2-nonanol
B.p., 225
457, 1660, 1661

2 4

IN

Diamyloxymethane

C11H24O2

1397, 1821
C11H24O2

2,2-Dibutoxypropane

C11H24O2

2- Nonyloxyethanol

458
459

C11H25N

CnH 5NO
2

C12F27N

C 1 2 H 9 N

C12H10
Ci HioO
2

HuN

1 2

Ci Hi 04
2

C12H18

Ci2Hi 0
8

C12H19N

C12H20O2

Ci H o0

H2o0

C
C

1 2

12 204
H

H2 0

1 2

1 2

2 2

1 2

2 2

Ci H

2 3

^1 H

2 4

2 4

1 2

B . p . , 225.5

1,1,3,3-Tetraethoxypro-

C11H24O4

pane
B . p . , 220.1
460
2-Ethyl-N-propylhexylamine
1629
1-Dibutylamino-2-pro
panol
B . p . , 229.1
461
Tris(perfluorobutyl)amine
B.p., 177
1457, 1643, 1647,
1648, 1656, 1917
Carbazole
B . p . , 294
1290, 1564, 1650,
1662, 1663
Biphenyl
B . p . , 355.9
1291, 1664
Phenyl ether
B . p . , 259.3
890, 1292, 1565,
1574, 1642
Diphenylamine
B.p., 265/350 m m .
1503
Diethyl phthalate
462
B . p . , 294.3
1,3,5-Triethylbenzene
1489
B . p . , 215.5
Triisobutylene oxide
463
-Butyl--methylbenzylamine
B . p . , 239.3
464
sec-Butyl 6-methyl-3cyclohexenecarboxylate
465
Isobornyl acetate
767
B . p . , 225.8
Dibutyl fumarate
466
B . p . , 285.2
Dibutyl maleate
467
B . p . , 280.6
2-Ethylhexyl crotonate
468
B . p . , 241.2
V i n y l decanoate (isomers)
469
Diethyl 2- ethyl-3-methylglutarate
B . p . , 255.8
470
Dicyclohexylamine
471
B . p . , 255.8
2,6,8-Trimethylnonene
1649, 1665
2,6,8-Trimethyl-4-nonanone
B.p., 218.2
472

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

FORMULA

INDEX

Formula

N a m e and System

CI2H24OS

C12H24O2
Ci2H2 C>2
4

H 40

1 2

Ci H 6
2

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C12H26

C12H26

C12H26O

Hexyl ether
891, 1294
2,6,8-Trimethyl-4-nonanol
B . p . , 225.5
479, 1582, 1665, 1832
l,l-Diethoxy-2-ethylhexane
B . p . , 207.8
480
1,1-Diisopentoxyethane
481
B . p . , 213.6
3- thoxy- 4- ethyloctanol
482
B . p . , 249.2
Bis(2-butoxyethyl)ether
483
B . p . , 254.6
1,1,3-Triethoxyhexane
484

C12H26O

12 262
H

1 2

^26 O 2

12

1 2

27

H27N

12 27

12 274

13 10

C13H24O2

13 26
H

C14H10
C14H10

C14H14O

Ci H
4

0
N

Formula

Nos.

2 - (2 - t h y l h e x y l t h i o ) e t h y l
vinyl ether
1293, 1658
2-Ethylbutyl 2-ethylbutyrate
B . p . , 222.6
473
2 - E t h y l b u t y l hexanoate
474
B . p . , 236.2
Hexyl 2-ethylbutyrate
475
B . p . , 230.3
Hexyl hexanoate
476
B . p . , 245.2
Dodecane
B . p . , 216
477, 768, 1018, 1104,
1451, 1636, 1653,
1666, 1818
2,2,4,4,6-Pentamethylheptane
B . p . , 185.6
1452
2,2,4,6,6-Pentamethylheptane
B . p . , 177.9
1453
2-Butyl-l-octanol
478
B . p . , 253.4
Dodecyl alcohol
1657

C12H24O2

91

Tributyltin chloride
B.p., 116/17 m m .
1 2 0 5 , 1 6 2 5 , 1902
Dihexylamine
B . p . , 239.8
485
T r i b u t y l a m i n e B . p . , 213.9
486
T r i b u t y l phosphate
487
Fluorene
B . p . , 294
1295, 1566, 1651,
1667, 1668
Decyl acrylate (isomers)
488
1-Tridecene
B . p . , 232.78
1454
Anthracene
B . p . , 340
892
Phenanthrene
B . p . , 340
1296, 1567, 1652,
1669, 1670
B e n z y l ether
1297, 1568
o - ( E t h y l h e x y l )phenol
489
B . p . , 297.0
N-(Ethylhexyl)aniline
490

CuH

N a m e and System

C14H28O

H 282

1 4

2 8

C14H28O2
Ci4H2 C>2
8

2 9

1 4

3 0

14 30

l 4

3 0

14 302

l 5

O2N

1 0

C15H18

<

-'15 28 - 4
H

Cl5 30
H

Cl5H

3 2

16 18

Ci6H28C>4

- l6 30 :

16 322
H

^i6 32 - 2
H

Ci H
6

16 34
H

^16 35^

Nos.

1,3,6,8-Tetramethyl-1,6cyclodecadiene
491
B . p . , 220.5
Dibutyl adipate
492
Trimethylnonyl vinyl ether
493
B . p . , 223.4
2-Ethylbutyl 2-ethylhexanoate
B . p . , 261.5
494
2-Ethylhexyl 2-ethylbu
tyrate
B . p . , 252.8
495
2 - E t h y l h e x y l hexanoate
496
B . p . , 267.2
Hexyl 2-ethylhexanoate
497
B . p . , 254.3
N-(2-Ethylhexyl)cyclohexylamine
498
Tetradecane
B . p . , 252.5
1105
7-Ethyl-2-methyl-4-undecanol
B . p . , 264.3
499
x-Tetradecyl alcohol
1662, 1667, 1669
2-(2,6,8-Trimethyl-4-nonyloxy)ethanol
500
Di-p-isocyanatodiphenylmethane
1460
B.p., 192/5 m m .
Amylnaphthalene
1532
Dibutyl pimelate
501
1-Pentadecene
B.p., 183.7/217 m m .
1637
2,8-Dimethyl-6-isobutyl 4-nonanol
B . p . , 265.4
502
Bis(a-methylbenzyl)ether
503
B . p . , 286.7
Dibutyl phthalate
B.p., 238/50 m m .
1130
Bis(4-methylbenzyl)ether
maleate
504
Tridecyl acrylate
505
l,l'-Bis(x-methylcyclohexyl )dimethylamine
506
2-Ethylhexyl 2-ethyl
hexanoate
B . p . , 280.4
507
Palmitic acid
1671
Hexadecane
1533, 1666
Bis(2-ethylhexyl) ether
B . p . , 269.8
508, 893, 1106,
1298, 1632
Bis( 2-ethylhexyl )amine
509
B . p . , 280.7

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

ADVANCES
Formula
Ci H

3,9-Diethyl-6-tridecanol
510
B . p . , 309
X "

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

C18H24N2

1 8

1 8

H380 2

3 9

Name andSystem Nos.

NO

C20H30O2

alcohol

1663, 1668, 1670


Bis(a-methylbenzyl)ethylenediamine
511
Oleic acid
1672
Ricinoleic acid
1672
Stearic acid
1671, 1673
1,1- B i s ( 2 - ethylhexyloxy)
ethane
512
2-[Bis( 2- ethylhexyl)amino]
ethanol
513

Abietic
1674

acid

Formula
0

2oH

20 364

20 403

3 6

C20H42O
C

2 0

4 2

C20H43N

21 383
H

24

384

^24 52^4^^

31 586
H

IN

CHEMISTRY

SERIES

Name andSystem Nos.


Bis(2-ethylhexyl)fumarate
514
Bis(2-ethylhexyl)maleate
515
2-Ethylhexyl 3-(2-ethylhexyloxy)butyrate
516
Decyl ether (isomers)
517
Eicosanol (isomers)
518
Didecylamine (isomers)
519
Allyl 9,10-epoxystearate
520
Dioctyl phthalate
1664
Tetra(2-ethylbutoxy)silane
521
Tri( 2-ethylhexyl)-1,2,4butanetricarboxylate
522

In AZEOTROPIC DATAII; HORSLEY, L., et al.;


Advances in Chemistry; American Chemical Society: Washington, DC, 1973.

Downloaded by 212.241.56.226 on December 5, 2012 | http://pubs.acs.org


Publication Date: June 1, 1973 | doi: 10.1021/ba-1962-0035.ch001

Bibliography
1. Adelson and Evans, U. S. Patent 2,605,216 (1952).
2. Akers and Eubanks, Proc. Cryogenic Eng. Conf., 2nd, Boulder, 1957, p. 275;
C.A. 52, 14267 (1958).
3. Albanesi, Pasquon, and Genoni, Chim. e ind. (Milan) 39, 814 (1957); C.A. 52,
3440 (1958).
4. Allen and Ellis, U. K. At. Energy Authority, IGR-R/CA, 216 (1957).
5. Alpert and Elving, Ind. Eng. Chem. 43, 1174, 1182 (1951).
6. Al'tshuler, Zviadadze, and Chizhikov, Zhur. Neorg. Khim. 2, 1581 (1957); C.A.
52, 7833 (1958).
7. Amer, Paxton, and Van Winkle, Ind. Eng. Chem. 48, 142 (1956).
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