Professional Documents
Culture Documents
Version 1
42210030-M
- 108720
HOCUT 795 I
Not Applicable
Contains 2-Aminoethanol, N,N'-methylenebismorpholine
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use
Metalworking fluid
Houghton S.A.S.
604 Bd Albert Camus,
BP 60041
69652 Villefranche sur saone
France
Tel: (0) 4 74 65 65 00
Fax. (0) 4 74 60 08 44
Houghton Benelux
Meerpaal 12 A. NL - 4904.SK Oosterhout.
Telefoon: +31 162458400
Fax: +31 162 458205
Email: Marielle.Goossens@houghtonintl.com
_____________________________________________________________________________________________
Page 1 / 14
Mento AS
Kontinentalveien
Postboks 44
4098 Tananger
Norway
Tel: +47 51 64 86 00
www.Mento.no
Houghton Sverige AB
La Cours Gata 4
252 31 Helsingborg
Sverige
Tel: +46 42 29 55 10
E-mail: info.se@houghtonintl.com
Houghton CZ s.r.o.
Bar
t
oova3
602 00 Brno
Czech Republic
Phone: +420 542 213 332
office@houghton.cz
Houghton Romania
2A, Jiului Street
4th Floor / Room 2
013219 Bucharest
Phone: +40 21 667 06 15
Fax: +40 21 667 09 70
Hought
onKi
myaSan.A.
Kosuyolu Mah
Asma DalI Sok
No:1434718Kad
ky
st
anbul
Trkiye
Phone Number: +90 216 325 15 15
+35929154409
145; +41 (0) 44 254 51 51
Telefon za izvanredna stanja +385 1 2348 342
Tel
ef
onn
sl
opr
onal
hav
si
t
uace+420224919293
Ring til Giftlinjen p +45 82 12 12 12
Mrgistusteabekeskuse +372 626 93 90
Htpuhelinnumero +358 09 471 977
Numr
od'
appeld
ur
gence+33(
0)
145425959
Djmentesen hvhat zld szm +36 80 20 11 99
Emergency telephone number +353 01 809 2166
Val
st
sToksi
kol
oi
j
ascent
r
aSai
ndansunz
ui
nf
or
mci
j
ascent
r
s+37167042473
Neat
i
dl
i
ot
i
nai
nf
or
maci
j
aapsi
nuodi
j
us+37052362052
Telefoonnummer voor +31 30 274 88 88
Ndnummer +47 22 59 13 00
112
Nmero de telefone de emergncia +351 808 250 143
Numrdet
el
ef
oncar
epoat
ef
iapel
at
ncazdeur
gen
+0213183606(
08:
0015:
00)
Nr
odnt
ox
i
kol
ogi
cki
nf
or
mancent
r
um +421254774166
Nmero de telfono de emergencia +34 91 562 0420
Telefonnummer fr ndsituationer +46 08 33 12 31 (09:00-17:00)
(+)1 760 476 3959 ( Code 333938 )
_____________________________________________________________________________________________
Page 2 / 14
Signal Word
DANGER
Hazard Statements
H314 - Causes severe skin burns and eye damage
H412 - Harmful to aquatic life with long lasting effects
EUH208 - Contains 3-Iodo-2-propynyl butylcarbamate May produce an allergic reaction.
Precautionary Statements - EU (28, 1272/2008)
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing
P264 - Wash face, hands and any exposed skin thoroughly after handling
P501 - Dispose of contents/ container to an approved waste disposal plant
P321 - Specific treatment (see supplemental first aid instructions on this label)
2.3. Other hazards
No information available.
9.
899E05% oft
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Chemical Name
EC-No
CAS-No
Weight %
Classification
(Reg. 1272/2008)
REACH
Registration
Number
25% - 50%
**
202-980-7
101-83-7*
2.5% - 10%
2-Aminoethanol
205-483-3
141-43-5
2.5% - 10%
2-(2-Butoxyethoxy)ethanol
203-961-6
112-34-5
1% - 2.5%
_____________________________________________________________________________________________
Page 3 / 14
227-062-3
5625-90-1
1% - 2.5%
no data available
Neutralised 2-Aminoethanol
205-483-3
141-43-5*
1% - 2.5%
Additional information
Product containing mineral oil with less than 3% DMSO extract as measured by IP 346 See Section 11 for more information See
Section 15 for additional information on base oils.
** Substances for which there are Community workplace exposure limits
Full text of H- and EUH-phrases: see section 16
Immediate medical attention is required. Do not get in eyes, on skin, or on clothing. May
produce an allergic reaction.
Inhalation
Skin contact
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin
with water/ shower. Immediate medical attention is required. May cause an allergic skin
reaction.
Eye contact
Immediately flush with plenty of water. After initial flushing, remove any contact lenses and
continue flushing for at least 15 minutes. Keep eye wide open while rinsing. Do not rub
affected area. Seek immediate medical attention/advice.
Ingestion
Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting
without medical advice.
Protection of First-aiders
Use personal protective equipment. Avoid contact with skin, eyes and clothing. Avoid direct
contact with skin. Use barrier to give mouth-to-mouth resuscitation.
4.2. Most important symptoms and effects, both acute and delayed
Main Symptoms
_____________________________________________________________________________________________
Page 4 / 14
_____________________________________________________________________________________________
Page 5 / 14
Metalworking fluid
Chemical Name
Highly refined base oil
(Viscosity >20.5 cSt @40C)
2-Aminoethanol
European Union
2-(2-Butoxyethoxy)ethanol
Neutralised 2-Aminoethanol
Chemical Name
Neutralised
Dicyclohexylamine
2-Aminoethanol
Germany
Skin
Italy
Portugal
The Netherlands
TWA: 2 ppm
TWA: 5.1 mg/m3
Ceiling / Peak: 4 ppm
Ceiling / Peak: 10.2 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
Skin
STEL: 6 ppm
TWA: 3 ppm
Skin
STEL: 7.6 mg/m3
TWA: 2.5 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
United Kingdom
France
STEL: 3 ppm
TWA: 1 ppm
STEL: 7.6 mg/m3
TWA: 2.5 mg/m3
TWA: 1 ppm
STEL: 3 ppm
TWA: 2.5 mg/m3
STEL: 7.6 mg/m3
Skin
STEL: 15 ppm STEL: 101.2 VME: 10 ppm VME: 67.5
mg/m3
mg/m3
TWA: 10 ppm TWA: 67.5 VLCT: 15 ppm VLCT: 101.2
mg/m3
mg/m3
STEL: 3 ppm STEL: 7.6
VME: 1 ppm VME: 2.5
mg/m3
mg/m3
TWA: 1 ppm TWA: 2.5
VLCT: 3 ppm VLCT: 7.6
mg/m3
mg/m3
Skin
2-(2-Butoxyethoxy)ethanol
Skin
STEL: 100 mg/m3
TWA: 50 mg/m3
STEL: 6 ppm
TWA: 3 ppm
Skin
STEL: 7.6 mg/m3
TWA: 2.5 mg/m3
Ireland
STEL: 10 mg/m3
TWA: 5 mg/m3
(Mist)
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
Skin
TWA: 10 ppm TWA: 67.5
mg/m3
STEL: 15 ppm STEL: 101.2
mg/m3
TWA: 3 ppm TWA: 8 mg/m3
STEL: 6 ppm STEL: 15
mg/m3
Chemical Name
Highly refined base oil
(Viscosity >20.5 cSt @40C)
Austria
Switzerland
Poland
2-Aminoethanol
Skin
STEL 3 ppm
STEL 7.6 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL 15 ppm STEL 101.2
mg/m3
MAK: 10 ppm MAK: 67.5
mg/m3
Skin
STEL 3 ppm STEL 7.6
mg/m3
MAK: 1 ppm MAK: 2.5
mg/m3
STEL: 4 ppm
STEL: 10 mg/m3
TWA: 2 ppm
TWA: 5 mg/m3
2-(2-Butoxyethoxy)ethanol
Neutralised 2-Aminoethanol
Spain
VLA-EC: 10 mg/m3
VLA-ED: 5 mg/m3
S*
STEL: 3 ppm
STEL: 7.5 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 15 ppm
STEL: 101.2 mg/m3
TWA: 10 ppm
TWA: 67.5 mg/m3
S*
STEL: 3 ppm
STEL: 7.5 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
_____________________________________________________________________________________________
Page 6 / 14
Finland
TWA: 5mg/m3 (ljysumu)
Denmark
TWA: 1 mg/m3 (Olietge)
Norway
TWA: 1 mg/m3 (Oljetke)
2-Aminoethanol
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
Skin
TWA: 10 ppm TWA: 68
mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
2-(2-Butoxyethoxy)ethanol
Neutralised 2-Aminoethanol
TWA: 10 ppm
TWA: 68 mg/m3
Chemical Name
2-Aminoethanol
Czech Republic
Ceiling: 7.5 mg/m3
TWA: 5 mg/m3
Skin
Hungary
STEL: 7.6 mg/m3
TWA: 2.5 mg/m3
Skin
2-(2-Butoxyethoxy)ethanol
Neutralised 2-Aminoethanol
Bulgaria
STEL: 7.6 mg/m3
TWA: 2.5 mg/m3
Skin
Sweden
LLV: 1 mg/m3
STV: 3 mg/m3
(Oljedimma)
LLV: 3 ppm
LLV: 8 mg/m3
H
STV: 6 ppm
STV: 15 mg/m3
LLV: 15 ppm
LLV: 100 mg/m3
STV: 30 ppm
STV: 200 mg/m3
LLV: 3 ppm
LLV: 8 mg/m3
H
STV: 6 ppm
STV: 15 mg/m3
Romania
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
Skin
TWA: 150 mg/m3
STEL: 250 mg/m3
TWA: 1 ppm TWA: 2.5
mg/m3
STEL: 3 ppm STEL: 7.6
mg/m3
Skin
2-(2-Butoxyethoxy)ethanol
20 mg/kg
2-(2-Butoxyethoxy)ethanol
2-(2-Butoxyethoxy)ethanol
10 mg/kg
2-(2-Butoxyethoxy)ethanol
_____________________________________________________________________________________________
Page 7 / 14
Fresh water
1 mg/L
Sea water
0.1 mg/L
Sea sediment
0.4 mg/kg
Soil
0.4 mg/kg
Engineering Measures
Eye Protection
Hand Protection
Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Remove
and wash contaminated clothing before re-use. Regular cleaning of equipment, work area
and clothing is recommended. Do not eat, drink or smoke when using this product. Handle
in accordance with good industrial hygiene and safety practice.
liquid
Mild
cloudy, amber
Not Applicable
Appearance
Odor Threshold
Values
9.7
No information available.
> 100 C / > 212 F
> 100 C / > 212 F
No information available
No information available
Note
@5%
ASTM D 92
No information available.
No information available.
No information available.
Vapor pressure
No information available.
Vapor density
0.9410
Relative density
Water solubility: emulsifiable
Solubility(ies)
Partition coefficient: n-octanol/water Not Applicable
No information available
Autoignition temperature
No information available
Decomposition temperature
> 77 cSt @ 40 C
Viscosity, kinematic
Not Applicable
Explosive properties
Not Applicable
Oxidizing Properties
g/cm3 @20C
ASTM D 445
No information available
No information available
No information available
None known
Eye contact
Skin contact
Corrosive; Repeated or prolonged skin contact may cause allergic reactions with
susceptible persons
Ingestion
2-(2-Butoxyethoxy)ethanol
N,N'-methylenebismorpholine
Neutralised 2-Aminoethanol
Skin corrosion/irritation
LC50 Inhalation
_____________________________________________________________________________________________
Page 9 / 14
None known.
May cause an allergic skin reaction.
None known.
Carcinogenicity
None known.
Reproductive toxicity
None known.
None known
None known.
Aspiration hazard
None known.
The document number 031 published 05-2013 by the DGUV Germany has been
considered in the production of this safety data sheet (SDS). As stated in this document the
classification of dicyclohexylamine is currently inconsistent between the manufacturer and
the REACH classification. The classification used in this document is based on the
European harmonised classification.
Symptoms
Causes burns. May result in permanent damage including blindness Repeated or prolonged
skin contact may cause skin irritation and/or dermatitis and sensitization of susceptible
persons.
Chemical Name
Neutralised
Dicyclohexylamine
2-Aminoethanol
2-(2-Butoxyethoxy)ethanol
N,N'-methylenebismorpholin
e
Neutralised 2-Aminoethanol
Toxicity to algae
15: 72 h Desmodesmus
subspicatus mg/L EC50
100: 96 h Desmodesmus
subspicatus mg/L EC50
15: 72 h Desmodesmus
subspicatus mg/L EC50
Toxicity to fish
62: 96 h Brachydanio rerio
mg/L LC50 static
227: 96 h Pimephales
promelas mg/L LC50
flow-through 3684: 96 h
Brachydanio rerio mg/L
LC50 static 300 - 1000: 96 h
Lepomis macrochirus mg/L
LC50 static 114 - 196: 96 h
Oncorhynchus mykiss mg/L
LC50 static 200: 96 h
Oncorhynchus mykiss mg/L
LC50 flow-through
1300: 96 h Lepomis
macrochirus mg/L LC50
static
55: 96 h Leuciscus idus
mg/L LC50
227: 96 h Pimephales
promelas mg/L LC50
flow-through 3684: 96 h
Brachydanio rerio mg/L
LC50 static 300-1000: 96 h
Toxicity to
microorganisms
_____________________________________________________________________________________________
Page 10 / 14
log Pow
3.5
-1.91
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or
disposal. Observe all label precautions until container is cleaned, reconditioned or
destroyed.
Other Data
According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used.
_____________________________________________________________________________________________
Page 11 / 14
ADR/RID
Proper shipping name
Hazard class
UN No.
Packing group
Classification Code
Description
Environmental hazard
ADR/RID-Labels
Tunnel Restriction Code
ICAO/IATA
UN No.
Proper shipping name
Hazard class
Packing group
ERG Code
Description
UN3267
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. ( 2-AMINOETHANOL,
N,N'-METHYLENEBISMORPHOLINE )
8
III
8L
UN3267, CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (2-AMINOETHANOL,
N,N'-METHYLENEBISMORPHOLINE), 8, III
_____________________________________________________________________________________________
Page 12 / 14
WGK Classification
The highly refined base oil (Viscosity >20.5 cSt @40C) contains one or more substance with the following CAS/EC
numbers/REACH registration numbers:
Chemical Name
CAS-No
EC-No
REACH Registration
Number
01-2119489969-06-xxxx
101316-72-7
309-877-7
101316-73-8
64741-88-4
64742-01-4
64742-10-5
64742-52-5
64742-53-6
64742-54-7
64742-57-0
64742-58-1
64742-62-7
64742-65-0
64742-70-7
72623-86-0
309-878-2
265-090-8
265-101-6
265-110-5
265-155-0
265-156-6
265-157-1
265-160-8
265-161-3
265-166-0
265-169-7
265-174-4
276-737-9
02-2119822310-56-xxxx
72623-87-1
276-738-4
01-2119474889-13-xxxx
74869-22-0
8012-95-1
8042-47-5
278-012-2
232-384-2
232-455-8
01-2119487078-27-xxxx
01-2119488707-21-xxxx
01-2119488175-30-xxxx
01-2119467170-45-xxxx
01-2119484627-25-xxxx
01-2119489287-22-xxxx
01-2119480472-38-xxxx
01-2119471299-27-xxxx
01-2119487080-42-xxxx
01-2119474878-16-xxxx
_____________________________________________________________________________________________
Page 13 / 14
H341-Suspect
edofcausi
nggenet
i
cdef
ect
s
H350-Maycausecancer
H351-Suspect
edofcausi
ngcancer
H360-Maydamagef
er
t
i
l
i
t
yort
heunbor
nchi
l
d
H361-Suspect
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ngf
er
t
i
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i
t
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l
d
H362-Maycausehar
mt
obr
east
f
edchi
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dr
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H370-Causesdamaget
oor
gans
H371-Maycausedamaget
oor
gans
H372-Causesdamaget
oor
ganst
hr
oughpr
ol
ongedorr
epeat
ed
exposure
H373-Maycausedamaget
oor
ganst
hr
oughpr
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ongedorr
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exposure
H400-Ver
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i
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oaquat
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H410-Ver
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oaquat
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ewi
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hl
ongl
ast
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ngef
f
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s
H411-Tox
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oaquat
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cl
i
f
ewi
t
hl
ongl
ast
i
ngef
f
ect
s
H412-Har
mf
ult
oaquat
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H413-Maycausel
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mf
ulef
f
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st
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H360Df-Maydamaget
heunbor
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d.Suspect
edofdamagi
ngf
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H360D-Maydamaget
heunbor
nchi
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H360FD-Maydamagef
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i
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y.Maydamaget
heunbor
nchi
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d
H360F-Maydamagef
er
t
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H361d-Suspect
edofdamagi
ngt
heunbor
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H361f
d-Suspect
edofdamagi
ngf
er
t
i
l
i
t
y.Suspect
edofdamagi
ngt
he
unborn child
H361f-Suspect
edofdamagi
ngf
er
t
i
l
i
t
y
EUH066-Repeat
edex
posur
emaycauseski
ndr
ynessorcr
acki
ng
EUH210-Saf
et
ydat
asheetavai
l
abl
eonr
equest
.
EUH208-Maypr
oduceanal
l
er
gi
cr
eact
i
on
Exposure scenario
No information available.
Issuing Date:
05-30-2015
Revision Date:
06-11-2015
Revision Note
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
_____________________________________________________________________________________________
Page 14 / 14