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Topic 4 : Gases
DHS/P2/Q1b(ii,iii)
1) (i)
pVm / RT
HCI/P2/Q3e
2) (i) An ideal gas is a gas that obeys the ideal gas equation (pV=nRT), under all
conditions of pressure and temperature.
(ii) No. At high pressure, the gas molecules are close together such that the
volume of the molecules is significant compared to the volume of the
container (or such that intermolecular forces are stronger).
HCI/P3/Q3d(i)
3) Using pV = nRT,
0.080
32 x 103 x 150 x 106 = x 8.31 x 303
Mr
Mr = 42.0
{or CH2CO}
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Gases - Suggested Solutions
IJC/P2/Q1a
Hence, T2 = 500K
Using pV = nRT,
Hence, Mr = = 173.1
JJC/P2/Q1a
5)(i)
S O
O O
Bent/ angular/ v-shape [1] S
O O
trigonal planar
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Gases - Suggested Solutions
NJC/P3/Q1b(ii)
6) N2O will require the highest temperature to behave like an ideal gas.
NYJC/P2/Q1b
7)(i) High temperature and low pressure.
NYJC/P3/Q3a(i)
8) N2O (g) N2 (g) + O2 (g)
Initial P/kPa 25.0 0 0
Change /kPa -x +x + x
Final P / kPa 25.0 - x x x
PT = 25.0 - x + x + x = 25.0 + x
x = 2(PT - 25.0)
( where x = amt of N2O decomposed at any given time )
PN2O = 25.0 - x = 75.0 - 2PT
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Gases - Suggested Solutions
RI/P2/Q2
9)a) An ideal gas is one which experiences negligible intermolecular forces of
attraction and has negligible volume.
ideal gas
0 p
SAJC/P3/Q3a
10) B is NH3 at 300K while C is CH4 at 500K.
NH3 at 300K deviates more than CH4 at 200K.
CH4 at 500K deviates less than CH4 at 300K. This is because at higher
temperature, particles posses higher kinetic energy and is more able to
overcome the forces of attractions between particles such that the collisions are
more elastic.
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Gases - Suggested Solutions
TPJC/P2/Q1b(ii)
11)
TPJC/P3/Q2e
12)(i)
(ii) At lower temperature of 100K, the HCl molecules possess less kinetic energy
and they move slower.
YJC/P3/Q4d(ii)
13) High temperature and low pressure
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