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a. La ecuacin de gases ideales recopila las leyes de gases ideales PV =nRT por
lo tanto:
nRT
P=
V
g
1lb=454 g PM CO =1 C+1 O=12+16=28
mol
454 g 1mol
n=9,5 lb =154 mol
1lb 28 g
3 28,32 L
V =2 ft =56,64 L
1 ft 3
atm. L
Tomamos
R=0,082
mol . K
atm . L
P=
(
( 154 mol ) 0,082
mol . K )
( 206,89 K )
=46,12 atm
56,64 L
2
L2 .atm
P=
(
( 154 mol ) 0,082
atm . L
mol . K )
(
( 206,89 K ) 1,485
mol 2 )
( 154 mol )
L ( 56,64 L )2
(
56,64 L( 154 mol ) 0,03985
mol )
P=40,75 atm
2 2,5
RT a R Tc RT c
P= 1
donde a=0,42748 ; b=0,08664
V mb 2
Pc Pc
V m ( V mb ) T
1 06 Pa 1 atm
Para elCO :T c =133 K Pc =3,5 MPa =34,55 atm
1 MPa 101300 Pa
V 56,64 L L
V m= = =0,368
n 154 mol mol
atm . L 2 (
a=0,42748
( 0,082
mol . K ) 133 K )
2,5
=19,97
1
atm . L2 . T 2
2
34,55 atm mol
atm . L
b=0,08664
( 0,082
mol . K )
( 133 K )
=0,0273
L
34,55 atm mol
1
2 2
atm . L atm . L . T
P=
( 0,082
mol . K )
( 206,89 K )
19,97
mol 2
1
L L L L L
0,368
mol
0,0273
mol
0,368
mol (
0,368
mol
0,0273
mol )
( 206,89 ) 2
P=38,74 atm
kg 1000 g 1 mol
n=250 12 dias =187.500 mol
dia 1kg 16 g
1 atm
P=130 kPa =1,283 atm ;T =273+ 24 C=297 K
101,3 kPa
( P+
an
V
2 )
( V nb )=nRT
L2 . atm L
para elC H 4 :a=2,253 2
; b=0,04278
mo l mol
L2 . atm 2
( 1,283 atm+
2,253
mol 2
V
( 187.500mol )
2 )(
V 187.500mol 0,04278
L
mol) (
= (187.500 mol ) 0,082
atm
mo
10
( 1,283
7,752 10
V
2 )( V 8021,25 ) =4.566 .375
0,127 0,254
=
( 2.20 ) ( 0,30 ) ( 2,20 )n ( 0,60 )m
n m
2m=2
m=1
1,020 0,254
=
( 4,40 ) ( 0,60 ) ( 2,20 )n ( 0,60 )m
n m
2n=4
n=2
m+ n=1+2=3 reaccin de tercer orden
2
k ( 2,20 ) ( 0,3 )=0,127
k =8,75 102 M 2 s1
2
v =( 8,75 102 M 2 s1 ) ( 0,5 M ) ( 0,2 M )
M
v =8,75 104
s