Test Paper : II Test Booklet Serial No.

: ______________________
Test Subject
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: CHEMICAL SCIENCES
Hall Ticket No.
A-02-02
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Name & Signature of Invigilator

Name : ____________________________________ Signature : ___________________________________

Paper : II
Subject : CHEMICAL SCIENCES
Time : 1 Hour 15 Minutes Maximum Marks : 100
Number of Pages in this Booklet : 16 Number of Questions in this Booklet : 50
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CHEMICAL SCIENCES
Paper II

1. The correct increasing order of second 3. Condensation of water vapour is

accompanied by
ionization energy of elements X, Y, Z with
(A) a decrease in entropy
respective atomic numbers 19, 20, 38 is
(B) an increase in entropy
(A) X, Y, Z
(C) no change in entropy
(B) X, Z, Y
(D) either increase or decrease in entropy

(C) Z, Y, X
4. The characteristic feature of an
(D) Z, X, Y electroactive ion among the following in
normal voltammetry is
2. Nicotine molecule is composed of
(A) Residual current
I. Pyridine
(B) Diffusion current

II. Furan (C) Summit potential

III. Pyrrolidine (D) Half-wave potential

IV. Pyrimidine 5. The reaction

NH3 (l)
3 NH4I + BiN BiI 3 + 4 NH 3
The correct statement is
belongs to which type ?
(A) I and II
(A) Complex formation
(B) I and III
(B) Redox
(C) II and IV (C) Solvolysis

(D) I and IV (D) Acid-base

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6. Non-aromatic species among the 7. The number average ( Mn ) and weight

following average (Mw ) molar masses of

monodisperse and polydisperse

CH3 polymers are as follows

I)
(A) Mn = Mw and Mn = Mw

(B) Mn = Mw and Mw > Mn

SO3H
(C) Mn > Mw and Mw > Mn
II)
(D) Mw > Mn and Mn = Mw

8. The distance dependence of potential

energy in ion-ion type interaction is

III)
(A) 1 2
r

(B) 1 3
r

(C) 1r
IV)
(D) 1 6
r

The correct combination is

9. The most stable among the following is

(A) I and IV (A) LiF

(B) III and IV (B) LiI

(C) HgF2
(C) II and III

(D) I and III (D) BeI2

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10. The ions with paramagnetic character 13. The Miller indices of a cubic crystal plane
among the following are 1
which intercepts the x, y and z axes at a,
2
+
I. Na 2 and
b c are
3
II. Fe3+
(A) 1 2
III. VO2+

IV. Sc3+ (B) 4 3 0

(A) I, II (C) 2 3 0

(B) II, III

(D) 2 3
(C) III, IV

(D) II, IV 14. The increase in the molar conductance of

KNO3 with increase in the dilution of its

11. Retinol is
aqueous solution is due to the
(A) enzyme

(B) hormone (A) increase in the speed of the solvent

(C) vitamin molecules

(D) provitamin
(B) increase in the transport numbers of

12. Toluene in proton decoupled 13C NMR K+ and NO 3 ions

spectrum gives +
(C) increase in the velocities of K and
(A) 5 signals
NO 3 ions
(B) 4 signals
(D) increase in the number of K+ and NO 3
(C) 3 signals
ions
(D) 6 signals

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17. Match the following :
15. Gas liquid chromatography is used for the

separation of compounds that have/are

I. Low vapour pressure

I. 1. 1,1-Dimethyl-3-
II. High vapour pressure isopropyl
cyclopentane
III. Stable at high temperatures

IV. Unstable at high temperatures

(A) I, III II. 2. 1-Cyclobutyl-3-

ethylcyclo-hexane
(B) II, III

(C) I, IV

(D) II, IV III. 3. 1,1,2,3- Tetramethyl-

cyclobutane
16. Assertion (A) : HF is the strongest acid in

water among HF, HCl,

HBr and HI
IV. 4. 3-cyclopropyl-2-
methyl-heptane
Reason (R) : HF has the largest

electronegativity 5. 1-cyclobutyl-3,4-
dimethyl
difference among all cyclopentane

(A) Both A and R are true and R is the

I II III IV
correct explanation of A

(B) Both A and R are true, but R is not the (A) 1 3 2 4

correct explanation of A (B) 4 1 2 3

(C) A is true, but R is false (C) 5 2 3 4

(D) A is false, but R is true (D) 4 5 1 2

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18. D-Erythrose on oxidation gives
(A) (+) tartaric acid
(B) ( ) tartaric acid
(C) meso-tartaric acid
(D) () tartaric acid
21. Assertion (A) : A liquid can be used as
the stationary phase
in a chromatography
technique.
Reason (R) : A liquid has the property
of moving.
(A) Both A and R are true and R is the
correct explanation of A
(B) Both A and R are true, but R is not the
correct explanation of A

19. ___________ radiation is used to record (C) A is true, but R is false

(D) A is false, but R is true
the ESR spectrum of a radical.
22. In the reaction
(A) Ultraviolet
O
(B) Infrared SeO
2
x

(C) Microwave
X is
(D) Radio frequency
O
(A)
20. The difference in molar heat capacities O

(Cp Cv) of any gas is equal to

O
E
(A) P (B)
V P
O
E
(B) V
P V
V (C)
(C) P
T P
V O
(D) T
P T
(D)
O

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25. Name the reaction :
23. Which of the following molecules do not

have IR active vibrations ? CN

OH
R CHO + R3N + CN
(A) H or
2 R
R3P
(B) NO
+ R 3 N o r R 3 P
(C) N2O
(A) Baylis-Hillman Reaction
(D) CH4
(B) Baylis Reaction

(C) Morita-Baylis-Hillman Reaction

24. Assertion (A): A quarter Faraday of
(D) Hillman Reaction
electricity passed through

an aqueous solution of 26. The value of the Plancks constant is

AlCl3 solution produces (A) 6.626 1034 JS
1
At.wt. of Al. (B) 6.626 1027 JS
12
(C) 1.380 1023 JK 1
Reason (R) : One Faraday of electricity
(D) 9.109 1031 Kg
passed through a solution

of an ion produces one 27. Assertion (A) :SOCl2 in liquid SO2 is an

acid
equivalent weight of that

ion. Reason (R) : Liquid SO2 autoionises to

give SO2+ and SO23
(A) Both A and R are true and R is the
(A) Both A and R are true and R is the
correct explanation of A
correct explanation of A
(B) Both A and R are true, but R is not the
(B) Both A and R are true, but R is not the
correct explanation of A correct explanation of A

(C) A is true, but R is false (C) A is true, but R is false

(D) A is false, but R is true (D) A is false, but R is true

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28. Identify the photo product : 30. Mn2P2O 7 (s) Mn2P2O 7 (l ) is
characterized by
I. No weight loss in TGA
h
h
[ X] [Y ] Photo
Pr oduct
II. Weight loss in TGA

(A) Phenanthrene III. Exothermic peak in DTA

IV. Endothermic peak in DTA
(B) Naphthalene (A) I, III
(B) II, III
(C) Anthracene (C) I, IV
(D) II, IV
(D) Phenylnaphthalene
31. Match the following :
I. Furyl acrylic acid 1. Skraup
29. If an arbitrary wave function is used to from furfural synthesis
II. 8-quinolinol from 2. Perkin reaction
calculate the energy of a quantum
0-amino phenol

mechanical system the calculated energy III. Indole-3- 3. Bischler-

carboxaldehyde Napieralski
is never less than the true energy of the reaction
IV. 1-Methyl Iso- 4. Reimer-Tieman
system. This statement is quinoline from reaction
-phenyl ethyl
amine 5. Grignard
(A) Heisenberg uncertainty principle reaction

(B) Perturbation theory

I II III IV
(A) 1 3 5 2
(C) Law of conservation of energy
(B) 4 2 1 5
(C) 2 1 4 3
(D) Variation principle
(D) 2 3 1 4

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32. A hypothetical molecule has a 35. Arrange the given molecules with the
increasing absorption maxima
configuration 1g2 1u2 2g2 1u4 14g 2u2
What is its bond order ?
COOR
(A) 1
1
(B) 2

(C) 0

(D) 1.5 H3C

N
H3C COOR
33. The selection rules for the appearance of
2
Q branch in the rotational-vibrational
spectrum of a diatomic molecule are

(A) v = +1, J = 0

(B) v = +1, J = + 1 MeO

COOR
(C) v = 1, J = 1

(D) v = 1, J = 0 3

34. Identify the symmetry element present in

N
COOR

N
4

N
(A) 1 ; 3 ; 2 ; 4

(B) 2 ; 3 ; 1 ; 4

(A) C3V
(B) D3H (C) 4 ; 3 ; 2 ; 1
(C) C2V

(D) C3H
(D) 3 ; 4 ; 1 ; 2

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38. Identify the following as R or S
36. The crystal field stabilization energy

values of [Fe(CN)6 ] 3 and [CoF6 ] 3 CN CHO

CH3
considering pairing energy (PE) are H CH2 Cl H3C C CH H2N H

respectively CH(CH3)2 CH2 OH COOH

I. 2.0 o + 2 PE
(A) R ; R ; S ;
II. 0.4 o
(B) S ; S ; S ;
III. 0 (zero) (C) S ; R ; R ;
(D) S ; R ; S ;
IV. 2.4 o + 2 PE
39. Match the following :
(A) I, II (B) II, III
List I List II
(C) III, IV (D) II, IV
(Phenomenon) (Related
technique)
37. Assertion (A) :The pH of pure water at I. Koopmans rule 1. Raman
80C is less than 7.0. spectroscopy
II. Polarizability 2. Photoelectron

Reason (R) : The ionic product of water spectroscopy

III. Spin-spin 3. Mossbauer
increases with increase in
coupling spectroscopy
temperature. IV. Dipole moment 4. NMR
spectroscopy
(A) A is false and R is true
5) Infrared
(B) A is true and R is false spectroscopy
I II III IV
(C) Both A and R are true and R is the
(A) 2 5 4 1
correct explanation of A
(B) 2 1 4 5
(D) Both A and R are true but R is not the (C) 3 1 4 5
correct explanation of A (D) 3 5 4 1

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40. In the following reaction 42. In the reaction

H3C CH3
i. Sanger reagent
H
O [X ]
AlaGly-Phe ii [ X]
. hydrolysis
H
S

the major product [X] is

the major product [X] is

(A) E, E 2, 4-hexadiene

(B) Z, E 2, 4-hexadiene
CH3
(C) Z, Z 2, 4-hexadiene
O2N NH CH CO2H
(A)
(D) E, Z 2, 4-hexadiene
NO2

41. Match the following :

List I List II

(Process) (Catalyst used)

(B) O2N NH CH2 CO2H
I. Hydroformylation 1. Rh(Ph3P)3Cl
NO2
II. Monsanto 2. Co2(CO)8
acetic acid
process

III. Hydrogenation 3. [Rh(CO)2 I2 ] C) O2N NH CH CO2H

CH2
IV. Wacker process 4. ZSM 5 NO2
C6H5
5. [PdCl4 ]
2

I II III IV
(D) H2N CH CO 2H
(A) 2 1 3 5 |
CH3
(B) 2 3 1 5

(C) 3 5 1 4

(D) 4 3 1 5

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43. Match the following 45. Match the following :

List I List II
List I List II
I. Identify operation (Ion) (Number of
of doing nothing 1. Cn unpaired electrons)

II. n-fold rotation 2. E

I. Fe 2 + 1. 0
III. Reflection in a 3. i

mirror plane

IV. Inversion 4. II. Cr3+ 2. 2

through a centre
+
of symmetry 5. S III. Cu 3. 3
n

I II III IV

(A) 1 2 3 4 IV. Ni2+ 4. 4

(B) 2 1 4 3

(C) 1 2 4 5 5. 6
(D) 5 1 2 4

44. For the following reactions I II III IV

N2(g) + 3H2(g) 2NH3(g)

(A) 5 4 2 1
1 3
N2 (g) + H2 (g) NH3(g)
2 2

the equilibrium constants KP1 and K P2 are (B) 4 3 2 1

related as

(A) K P1 = 2K P2
(C) 4 3 1 2
1
(B) KP = K P
1
2 2
(C) K P1 = K 2P2
(D) 5 3 1 2
( )
(D) K P1 = KP2
1
2

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46. Anti inflammatory activity is exhibited by 49. Which of the following statements is

(A) ibuprofen wrong ?

(B) chloroequin (A) Nanomaterials show the same

(C) isoniazid properties as those exhibited by bulk

materials
(D) metronidazole

(B) Nanomaterials are prepared by either

47. The conversion of toluene to benzoic acid
top down or bottom up approaches
is faster in presence of
(C) Texture of nanomaterials is studied by
(A) Thermal energy
SEM / TEM

(B) Sonication
(D) Phase identification of nanomaterials

(C) Cooling
is done by XRD

(D) MW irradiation
50. The pollutant responsible for Bhopal

48. Salbutamol is useful in the treatment of disaster in 1984 is

(A) hypertension (A) Phosgene

(B) amoebiasis (B) Methylamine

(C) tuberculosis (C) Methyl isocyanate

(D) bronchial asthama (D) Carbon monoxide

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Space for Rough Work

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Space for Rough Work

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