OSPHO METAL TREATMENT
SAFETY DATA SHEET
14. Productidentiter
Product form ‘SOLUTIONMXTURE
‘radeneme osPHO
Chemical name + Orhophosphorc acid
AS No 1984-36-2
Product code 2 NIA
Formda HaPO¢
‘Synonyms ORTHOPHOSPHORIC ACID
REACH regisraton No. 01-21 10485924-24-0021
12, Relevantidentiied uses ofthe substance or mixture and uses advised against
Use ofthe solutonimixture
Meta surface treatment product
13. Details ofthe supplior of the safety data sheet
‘The Skybryte Company
3125 Perkins Avenue,
Cleveland, Ohio 44114-4689
SDS "Preparer: Stephen L Pitcher
‘Date: May 25, 2015,
14. Emergency telephone number
In case of emergency: CHEMTREC 1-900-424-9300
Emergency phone number: IN THE EVENT OF A CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT Call CHEMTREC: 1-
800-424-9300, Toll re in the connenial U.S. Hawai, Puerio Rico, Canada, Alaska, or US. Virgin llands. For eal oginang elsewhere dal 703.
527-3867 (collect cals aocepied) Nationwide Polson crit center 1-800-222-1222
For other counties, see secon 18.6
Classification ofthe ‘solution or mixture
GHS-US classification
Skin Corr. 18 314
Fall tx of H phrases: se secton 16.
VOC = 0%
22 Label elements Ce
GHS-US labeling
Hazarépietograms (GHS-US) :
CORROSIVE IRRITANT
‘Signal word (GHS-US) Danger
Hazard statomonts (GHS-US) B14 Causes severe skin Burns and eye damage
Precautonary statemonts (GHS-US) 260 -Do not breathe spray, mist, fume, 02s, dst, vapours
200 - Wear protective gloves, protective clothing, aye prolecton, face protection
P301+P320¢P331 - IF SWALLOWED: rinse mouth. De NOT induce vomiing
P303+P3614P353 - IF ON SKIN (or ha: Removo/Take off immediately all contaminated
‘dotting. Rinse skin wih waterfsnower
'P305+P351+P336 fn eyes: Rinse cautiously wth water fr several minutes. Remove contact
lenses, i present and e087 to do, Continue rinsing
234 - Keep only in oxgnal container
5/25/2015. ey Page TOSPHO
Safety Data Sheet
scoring to Feder Retr / Va 7, Ho 58 Mondo, More 28, 2072 Read Regan
P310 - modlataly calla POISON CENTER, a doctor
23. Otherhazards
No addtional information avaible
24. Unknown acute toxicity (GHS-US)
No applicable
SER
34. Substance
Neme Orthophosphoric Acid
caso 1382
[ne | rear 3 ‘ES sseaton
[Samat ana asta Paxmmor sinter ie
Full teat of phrases eee section 16
32. Solution/mixture
Specific Gravity (H20=1) 1.22 +/-.04
SECTION 4: first-aid measures
441. Description of first ald measures
Fist od measures ater inhalation Remove vit to fresh ar. persistent breathing woubes, Immediately sek medical attention.
Fstaid measures ater okin contact + Rinse immediatly wit clean water fox 20-30 minutes. Remove contaminated clothing and
shoes fon skin lake off contaminated clothing. Get medical avicelttenton.
Fistaid measures after eye contact Got medical advceattenion. n case of eye contact, immediately ringe with clean water for 20-
30 minutes.
Fistaid meesures after ingestion I owalowed ise mouth with water (oly ifthe person ls conscovs), Do not induce vorning.
Cal's docter,
42, Most important symptoms and effects, both acute and delayed
‘Symplomsfrjures “The vepour causes sight itatons in eyes, heat and skin. Cauees aye and skin bums.
43. Indication of any immediate medical attonton and special treatment needed
‘Soe Heading 4.1. An endoscope ora stomach wash might be considered but might cause eevere stomach or oesophagus damage.
ST fi
54. Extinguishing media
Suitable extinguishing mecia (602. Powders. Foam. Water spray
Unsutable extinguishing media Hwy water seam,
52. Special hazards arising from the substance or mixture
ce hazard Not fommable,
Reactivity + Contact wit metas produces hycrogen which may form explosive mixtures with a. Reacts
vith strong bases.
53. Advice for firefighters
Fiefihting instuctons Use water sprayig for cooling,
Protection during firefighting Wear complete protective antacid clothings, loves and boots Use sel-conained breathing
‘apparatus. SECTION 8
FSO EEE
5.4. Personal precautions, protective equipment and emergency procedures
General measures ‘pil shoud be handled by tained cleaning personnel propety equipped wth respiratory and
‘eye protection. Keep pubic anay fram danger area. Good venblaon of the workplace reed.
s8e Sections) 82.
644. For nonemergency personnel
No adstional infomation avaible
612.
No addtional information avaliable
5.2. Environmental precautions
Prevent en to severs and surface waters, Prevent entry lo sowers and eo
we Enea) aOSPHO
Safety Data Sheet
‘econ Federal Rater VoL 7. No.8 Mondoy, Mach 2, 2042 Reson Regt
63. Methods and material for containment and cleaning up
Methods fr clearing up + Clean up any spls 2s soon as possible, using ah absorbent atrial to cll It Transfer in ai
appropriate container propery labled inorder to st up a flureeatment. Newraze with
‘sou carbonate, calcu carbonate, ore. nse wit plenty of water.
64. Raference to other sections
No adaitonal information avaiable
SECTION 7 Handling andstorage
74. Precautions for safe handling
Precautions fr safe handing + Good ventilation ofthe workplace required. Use suitable material. Follow he exposure tims
‘given on this material safety daa sheet. For preference use pumping techniques fr unloading
and discharging. Waterproof retention basin. Avoid any drt eantact wih the product. not
breathe vapours. Never Introduce waler or any aquaous agent ino tanks or containers. Do not
‘subjec to Spates. Always add th product othe walr fo lulonimstre. Do nok mi with
Incompatie materials (8 secon 10.5).
Hygiene measures \Wash hands and other exposed areas with milé soap and water befoe eating, drinking or
“smoking and when loving work. When using do not et, dink or emke. Remove
Contaminated doting and shoes.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions + Stove in dry, coo, well-ventilated area. Do nol store under det sun ght. Store at oom
lemperaure above crystalization pot
Incompatible products + Keep away rom alkalis, sulfides, cyanies and metal powers,
Packaging materiale + Stainless steal. glass, Plyethyone thigh density).
72 Specific end use(s)
[No additonal infrmation avaiable
SECTION 8: Exposure controle/personalprotection==. s
&t._Controtparamaters
ee —
“ACGIH AEG TWA gla) Tat
‘OSHA (OSHA PEL (TWA) (ng) “gin
82. Exposure controls
‘Appropriate engineering tots sein closed process (for example in close loop syst). Good vention ofthe workplace
required. Monto te almosphere al regula intwale. Emergency eye wash fountaine snd
salely showers shouldbe avalible in he immediate vic of any potential exposure.
Hond protection ‘Wear chemical protctve gloves.
Eye protection ‘Chemical goggles or face shield with safety gasses,
‘Skin and body protecson + Wear acid resistant protective doting, Wear impervious ruber safety shoes,
Respiratory protseien ' Vapours or aerosols: Respiratory protection programs must comply wih 28 CFR 1910.134,
Use ory eutdoors ora wel-ventlaed ae
Environmental exposure controls + For preference use pumping techniques for unloading and discharing
SSCL EES
9.4. Information on basle physical and chemical properties
Physical state Uiuid
Appearance = Slightly viscous lauid
Molecular mass + 88gimol
Colour green
(dur Acts
(Odour tweshotd 1 No data avatabte
pH <18
Relative evaporation ate (oublacetate=1) No data availabe
Meking point ATC BKC
Freezing point + No data avaltble
Boling point 1 36%: 1048S 85%: 154
‘saeaS Enea, oFOSPHO
Safety Data Sheet
sccoitng le Feral Rese Vo. 77, No 28/ Monday Mach 28,2012 Resa Regulations
Flash paint + Not fammable
‘Autosgnitontemperatire No data avaible
Decompositon temperature No data avaliable
Flammability (sd, gas) = No data avalale
Vapour pressure + Notapphcable
Rolatve vapour density at 20°C + No data avaible
Relative density No data available
Density + (20°C) 36%: 1.205; 85M: 1.689
Sohibity Water 100%
og Pow No data avatable
eg Kow No data avaible
Viscosity, hinematic (25°C) 85%: 23"6
Viscosity, dynamic No data avalable
Explosive properties No data avaliable
Oxidising proportis + No data avaible
Explosive its ‘No data avaiable
9.2. Other information
No adtitonal information avalleble
SEE s gi
404. Reactivity
Contact with metals produces hydrogen which may form explosive mixtures wh alt. React wth song bases.
102. Chemica stabitty
Stable under normal conditions (Handling end storage)
103. Possibly of hazardous reactions.
‘No additonal information avaiable
104. Conditions to avoid
Hest. Light (dayigh).
10.5. incompatioie materiats
ikals. Cust products-Non noble metals
108. Hazardous decomposition product
May iberate tonic gas,
SSTONRRER IEP CENCE TERE es
‘41.4. Information on toxicological effects
Acute toil Not classed
‘OSPHO re) _
O50 ora ai 72600 maikg bodyweight SinlarIOOECD 423,
LOSO dermal rat No dota avaliable
{EGO inhalation rat fa) Ne daia avaiable
‘Shin earesionfitaton + Causes severe shin bums and eye damage.
pit<15
Serious eye damageliritaton + Not eased
(tating to eyes.)
piers:
Respirator or ski senstsaton + Not dosed
(Not relevant. Corrosive prodvct)
Germ cell mutagenicity Not casted
Carerogenicty Not classified
(No data avatabio)
Reproductive toxicity Not classified
sa5i2015 Neate)OSPHO
Safety Data Sheet
scorn to Federal Repster/ Vo. 7, No 38 Monday, Moc 28, 20121 Rules and Reasons
‘Speci target organ tox single exposure) + Not classed
‘pect trl rin ody (wpeated Not csied
epee)
_OSPHO_ (7664-38-2) _ - |
NOAEL (a aL BOys) [2m awn OECD we
‘span bard + Nt dats
SSI
2. Toxiey
| OSPHO. (7664-38-2) —
Ces RT 3 woh Gi) Lepomis asoas)
E680 Daphnia 7 TOD mg (1 -Depoia magna, OECD 208)
3 100 mgil (72 - Desmodesmus eubepicatue, OECD 267)
700 mgf (72 - Desmodesmus subspeatus, OECD 201)
Persistence and degradabilty
‘osPiio ~ (rae 38-2) ——
Persistence ad dogadabty [Rotapacabe
123, _Bioaccumulatve potential
[osPHo. (7684-38-7) 7
Bloaccumulatve pote [Not priate. —__}
124 Mobittym sot
Cee,
E209) - 8 [Ne dot vaio
125. Otheradverse effects
Effecton ozone layer
Etfeat on the glob warming + No known ecological damage caused by tis product,
SECTION 43: Disposal considerations
18.4. Waste treatment methods
‘Waste treatment methods
"Nevtaize wt sodium carbonate calc carbonate. or ime. When totally empty, continars
‘a recycable tke any other packing. Savage contehore mustbo fre of contamination before
This material when discarded in puro form is nota hazardous waste as dfined by 40 CFR.261,
the Resource Conservation and Recovery Act (RCRA). Dry materials may be landed or
‘recycled in accordance with fea, etal, and federal regulatons.matoais have become
‘contaminated with othe substances, dispose of in acoordanco with local, state, and federal
‘Waste disposal recommendations
‘equations
LECT
In accordance wit DOT
“Transport document descipton + UN1805 PHOSPHORIC ACID, SOLUTION, 8,
UNNo(007) = UN180S
Proper Sipping Name (DOT) + PHOSPHORIC ACID, SOLUTION
Department of Transportation (OOT) Hazard: ‘8 - Class - Corrotve material 49 CFR 178.196
CClasser
Hazard labels (007) 8- Corosive
Packing roup (DOT) Me Minoe Danger
B252015 ENE coOSPHO
Safety Data Sheet
scan Fedral ger Vo. 7, No. S/o March 28,202 Ros and Redo
‘DOT Special Provisions 49 OFR 172.102): AT- Slee pachagngs must be caoston-sitant or have protection agalslcorosion
183 Auturized ICs: Metal (918, 318 and SIN): Rig plans (341 and 31F2), Compost
(31121 and a2, 31M SHIN2, 31HD2 and SMF}. Atal Requrement Oly haus
‘nth a vapor pressre las han or ualto 140 KPa 50 (1t barat 122) oy 19045 a 58
‘C(.3 barat 131 F) are authorized, excep forUN2672 alo see Special Prvison IPS in abla
3 fr una)
‘Not - Aluminum constructon meters arene suhorizes fr ary pat ofa packaging which
‘ormalyin contact wih te azardous mata
‘ar ze 178.274 o¥2) Nomad. =~ A7B2TS(ENS)
TP1- The maxim degree of ig must nol exotod te degre of ling determined bythe
folowing: Degree ef ting = 87 (1a) Whee: els the msdn mean sk
temperature dung Varsport ad ise iemperalurein degrees cobs of te kqu deg
fing.
DOT Packaging Gxcepfons 49.CFR 173200): 154
OT Packaging Non Buk 49CFR 173.00): 209
DOT Packaging Buk (49 CFR 172,00) an
DOT Quanity talons Passenger acral: SL
Gocre Tsay
DOT Quanity Lmtatons Cargo akratonty (49: 60
crete 73)
DOT Vessel Sowage Location +A The tei may be slowed “on deck” or“under deck" ona cargo vss and on a
passenger vessel,
Adattona information
re iverson ‘No supplamentar fomaton avait,
40R
Transport dociment scion LON 1995 PHOSPHORIC ACID, QUID, 8.)
Packing run (ADR) im
Cass (ADR) 8 - Conse subetances
Hazard idencafon number Kener No): 80
Chasticaton code ADR) Pot
‘Danger abe (ADR) Conosive sutetances
Orange plates
Tunnel resticton code (ADR) €
xcepted quantities (ADR) et
‘Transport by to
UwNe. (MOG) +805
‘iass (DG) 1 8 Coosie substances :
Pcking aroup (MDG) 2 I~ eubeances presenting low danger
MAGNO 2184
Ai tranaport
LUNN ,QATA) 1 1805
Class WaT) = Corosves
Chat Aeronautics Law + Conrosive substancastHazardous materials nce Appended Table 1 Arce 194 of ho
Enforcoment Regulations)
2572015, EN aan) «OSPHO
Safety Data Sheet
«ort Fede Rept V7. No 86 Moday March 2, 2012/ Res ad Regatons
STAT MI
15.1. US Federal regulations
‘OSPHO 7664-362),
Usted on the United Slates TSCA (Tox Subslaness Control Ae inventoy,
“SARA Secon 302 Thveshols Planing Quanity (TPQ) ‘Nol applicable
‘SARA Secion 311/312 Hazard Classes Immediate (acuie) heath Pazard
‘SARA Secion 315. Emission Reporing Not apotiable
'Al component fis product ao sod oF exsaied fom Feng, ne Und Sata Eien Proeclon Agen Tos
Substances Corr Act (TSCA) veo except fot
[pete etiophoephorinve [cas ho T8402 I ‘oom
‘This product or miu dos ot conlin ono chemical or chemicals n exces f te specale de miimisconcontation 2s
pected in 40 CFR §372:38() subject othe reporting requements of secion 313 of Tle il of the Supertund Amencments and
Reauthorization Ac of 1986 and 40 GFR Part 372
15.2. Imterational regulations
CANADA
‘OSPHO. (Task se — ——
Usted onthe Canadian NOS (Non-Domestic Subsianons Ut)
WHMIS Classification [ Glass & - Corosive Matera
Eu-Regulations
"No additonal information avalisle
Classification according to Regulation (EC) No, 1272/2008 {CLP}
‘Skin Cor. 18 M344
Ful xt of H pases: se secton 18.
Classification according to Directive STIS4B/EEC [DSD] or 1990/4S/EC [DPD]
Notebssited
1522 National regulations
‘OSPHO (7064-382) ~
‘CERCLA reportable quantities: 6.0008
‘ANSUNGF Std. 60 potable wolersystoms: Ceriiad
US Food & Orug Admin: Recognized a8 Generally Recognized
Hazardous chemical under the ceria ofthe OSHA Hazard Communication Standard (20 CFR 110.1200), Appendix A: Conotve
153. US State regulations
Calforia Propsiton 65 - This product does not contain any substances known tothe state of California to cause cancer
andlor reproductive harm
SST ERROE
Revision data 57252015,
Daa sources Reach dossier.
Taso EN aayOSPHO
Safety Data Sheet
_2ccrting io Federal Register/Vol, Na $8 / Monday, March 28, 2012 Res and Regions
‘Abbreviaons and acronym + ADN: European Agreement concerning international carlage of Dangerous goods by Iniand
waterways’
‘ADR: European Agreement concerning international cariage of Dangerous goods by Road
‘AF Assessment factor
{BCP : Bioconceritation factor
‘Bw Body weight
CCAS: Chemical Absiracts Sevico
ELV: Emission fit values
EN: European Norm
EU: European Hazard Statement
EWC: European Wasie catlogue
|ATA