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OSPHO METAL TREATMENT SAFETY DATA SHEET 14. Productidentiter Product form ‘SOLUTIONMXTURE ‘radeneme osPHO Chemical name + Orhophosphorc acid AS No 1984-36-2 Product code 2 NIA Formda HaPO¢ ‘Synonyms ORTHOPHOSPHORIC ACID REACH regisraton No. 01-21 10485924-24-0021 12, Relevantidentiied uses ofthe substance or mixture and uses advised against Use ofthe solutonimixture Meta surface treatment product 13. Details ofthe supplior of the safety data sheet ‘The Skybryte Company 3125 Perkins Avenue, Cleveland, Ohio 44114-4689 SDS "Preparer: Stephen L Pitcher ‘Date: May 25, 2015, 14. Emergency telephone number In case of emergency: CHEMTREC 1-900-424-9300 Emergency phone number: IN THE EVENT OF A CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT Call CHEMTREC: 1- 800-424-9300, Toll re in the connenial U.S. Hawai, Puerio Rico, Canada, Alaska, or US. Virgin llands. For eal oginang elsewhere dal 703. 527-3867 (collect cals aocepied) Nationwide Polson crit center 1-800-222-1222 For other counties, see secon 18.6 Classification ofthe ‘solution or mixture GHS-US classification Skin Corr. 18 314 Fall tx of H phrases: se secton 16. VOC = 0% 22 Label elements Ce GHS-US labeling Hazarépietograms (GHS-US) : CORROSIVE IRRITANT ‘Signal word (GHS-US) Danger Hazard statomonts (GHS-US) B14 Causes severe skin Burns and eye damage Precautonary statemonts (GHS-US) 260 -Do not breathe spray, mist, fume, 02s, dst, vapours 200 - Wear protective gloves, protective clothing, aye prolecton, face protection P301+P320¢P331 - IF SWALLOWED: rinse mouth. De NOT induce vomiing P303+P3614P353 - IF ON SKIN (or ha: Removo/Take off immediately all contaminated ‘dotting. Rinse skin wih waterfsnower 'P305+P351+P336 fn eyes: Rinse cautiously wth water fr several minutes. Remove contact lenses, i present and e087 to do, Continue rinsing 234 - Keep only in oxgnal container 5/25/2015. ey Page T OSPHO Safety Data Sheet scoring to Feder Retr / Va 7, Ho 58 Mondo, More 28, 2072 Read Regan P310 - modlataly calla POISON CENTER, a doctor 23. Otherhazards No addtional information avaible 24. Unknown acute toxicity (GHS-US) No applicable SER 34. Substance Neme Orthophosphoric Acid caso 1382 [ne | rear 3 ‘ES sseaton [Samat ana asta Paxmmor sinter ie Full teat of phrases eee section 16 32. Solution/mixture Specific Gravity (H20=1) 1.22 +/-.04 SECTION 4: first-aid measures 441. Description of first ald measures Fist od measures ater inhalation Remove vit to fresh ar. persistent breathing woubes, Immediately sek medical attention. Fstaid measures ater okin contact + Rinse immediatly wit clean water fox 20-30 minutes. Remove contaminated clothing and shoes fon skin lake off contaminated clothing. Get medical avicelttenton. Fistaid measures after eye contact Got medical advceattenion. n case of eye contact, immediately ringe with clean water for 20- 30 minutes. Fistaid meesures after ingestion I owalowed ise mouth with water (oly ifthe person ls conscovs), Do not induce vorning. Cal's docter, 42, Most important symptoms and effects, both acute and delayed ‘Symplomsfrjures “The vepour causes sight itatons in eyes, heat and skin. Cauees aye and skin bums. 43. Indication of any immediate medical attonton and special treatment needed ‘Soe Heading 4.1. An endoscope ora stomach wash might be considered but might cause eevere stomach or oesophagus damage. ST fi 54. Extinguishing media Suitable extinguishing mecia (602. Powders. Foam. Water spray Unsutable extinguishing media Hwy water seam, 52. Special hazards arising from the substance or mixture ce hazard Not fommable, Reactivity + Contact wit metas produces hycrogen which may form explosive mixtures with a. Reacts vith strong bases. 53. Advice for firefighters Fiefihting instuctons Use water sprayig for cooling, Protection during firefighting Wear complete protective antacid clothings, loves and boots Use sel-conained breathing ‘apparatus. SECTION 8 FSO EEE 5.4. Personal precautions, protective equipment and emergency procedures General measures ‘pil shoud be handled by tained cleaning personnel propety equipped wth respiratory and ‘eye protection. Keep pubic anay fram danger area. Good venblaon of the workplace reed. s8e Sections) 82. 644. For nonemergency personnel No adstional infomation avaible 612. No addtional information avaliable 5.2. Environmental precautions Prevent en to severs and surface waters, Prevent entry lo sowers and eo we Enea) a OSPHO Safety Data Sheet ‘econ Federal Rater VoL 7. No.8 Mondoy, Mach 2, 2042 Reson Regt 63. Methods and material for containment and cleaning up Methods fr clearing up + Clean up any spls 2s soon as possible, using ah absorbent atrial to cll It Transfer in ai appropriate container propery labled inorder to st up a flureeatment. Newraze with ‘sou carbonate, calcu carbonate, ore. nse wit plenty of water. 64. Raference to other sections No adaitonal information avaiable SECTION 7 Handling andstorage 74. Precautions for safe handling Precautions fr safe handing + Good ventilation ofthe workplace required. Use suitable material. Follow he exposure tims ‘given on this material safety daa sheet. For preference use pumping techniques fr unloading and discharging. Waterproof retention basin. Avoid any drt eantact wih the product. not breathe vapours. Never Introduce waler or any aquaous agent ino tanks or containers. Do not ‘subjec to Spates. Always add th product othe walr fo lulonimstre. Do nok mi with Incompatie materials (8 secon 10.5). Hygiene measures \Wash hands and other exposed areas with milé soap and water befoe eating, drinking or “smoking and when loving work. When using do not et, dink or emke. Remove Contaminated doting and shoes. 7.2 Conditions for safe storage, including any incompatibilities Storage conditions + Stove in dry, coo, well-ventilated area. Do nol store under det sun ght. Store at oom lemperaure above crystalization pot Incompatible products + Keep away rom alkalis, sulfides, cyanies and metal powers, Packaging materiale + Stainless steal. glass, Plyethyone thigh density). 72 Specific end use(s) [No additonal infrmation avaiable SECTION 8: Exposure controle/personalprotection==. s &t._Controtparamaters ee — “ACGIH AEG TWA gla) Tat ‘OSHA (OSHA PEL (TWA) (ng) “gin 82. Exposure controls ‘Appropriate engineering tots sein closed process (for example in close loop syst). Good vention ofthe workplace required. Monto te almosphere al regula intwale. Emergency eye wash fountaine snd salely showers shouldbe avalible in he immediate vic of any potential exposure. Hond protection ‘Wear chemical protctve gloves. Eye protection ‘Chemical goggles or face shield with safety gasses, ‘Skin and body protecson + Wear acid resistant protective doting, Wear impervious ruber safety shoes, Respiratory protseien ' Vapours or aerosols: Respiratory protection programs must comply wih 28 CFR 1910.134, Use ory eutdoors ora wel-ventlaed ae Environmental exposure controls + For preference use pumping techniques for unloading and discharing SSCL EES 9.4. Information on basle physical and chemical properties Physical state Uiuid Appearance = Slightly viscous lauid Molecular mass + 88gimol Colour green (dur Acts (Odour tweshotd 1 No data avatabte pH <18 Relative evaporation ate (oublacetate=1) No data availabe Meking point ATC BKC Freezing point + No data avaltble Boling point 1 36%: 1048S 85%: 154 ‘saeaS Enea, oF OSPHO Safety Data Sheet sccoitng le Feral Rese Vo. 77, No 28/ Monday Mach 28,2012 Resa Regulations Flash paint + Not fammable ‘Autosgnitontemperatire No data avaible Decompositon temperature No data avaliable Flammability (sd, gas) = No data avalale Vapour pressure + Notapphcable Rolatve vapour density at 20°C + No data avaible Relative density No data available Density + (20°C) 36%: 1.205; 85M: 1.689 Sohibity Water 100% og Pow No data avatable eg Kow No data avaible Viscosity, hinematic (25°C) 85%: 23"6 Viscosity, dynamic No data avalable Explosive properties No data avaliable Oxidising proportis + No data avaible Explosive its ‘No data avaiable 9.2. Other information No adtitonal information avalleble SEE s gi 404. Reactivity Contact with metals produces hydrogen which may form explosive mixtures wh alt. React wth song bases. 102. Chemica stabitty Stable under normal conditions (Handling end storage) 103. Possibly of hazardous reactions. ‘No additonal information avaiable 104. Conditions to avoid Hest. Light (dayigh). 10.5. incompatioie materiats ikals. Cust products-Non noble metals 108. Hazardous decomposition product May iberate tonic gas, SSTONRRER IEP CENCE TERE es ‘41.4. Information on toxicological effects Acute toil Not classed ‘OSPHO re) _ O50 ora ai 72600 maikg bodyweight SinlarIOOECD 423, LOSO dermal rat No dota avaliable {EGO inhalation rat fa) Ne daia avaiable ‘Shin earesionfitaton + Causes severe shin bums and eye damage. pit<15 Serious eye damageliritaton + Not eased (tating to eyes.) piers: Respirator or ski senstsaton + Not dosed (Not relevant. Corrosive prodvct) Germ cell mutagenicity Not casted Carerogenicty Not classified (No data avatabio) Reproductive toxicity Not classified sa5i2015 Neate) OSPHO Safety Data Sheet scorn to Federal Repster/ Vo. 7, No 38 Monday, Moc 28, 20121 Rules and Reasons ‘Speci target organ tox single exposure) + Not classed ‘pect trl rin ody (wpeated Not csied epee) _OSPHO_ (7664-38-2) _ - | NOAEL (a aL BOys) [2m awn OECD we ‘span bard + Nt dats SSI 2. Toxiey | OSPHO. (7664-38-2) — Ces RT 3 woh Gi) Lepomis asoas) E680 Daphnia 7 TOD mg (1 -Depoia magna, OECD 208) 3 100 mgil (72 - Desmodesmus eubepicatue, OECD 267) 700 mgf (72 - Desmodesmus subspeatus, OECD 201) Persistence and degradabilty ‘osPiio ~ (rae 38-2) —— Persistence ad dogadabty [Rotapacabe 123, _Bioaccumulatve potential [osPHo. (7684-38-7) 7 Bloaccumulatve pote [Not priate. —__} 124 Mobittym sot Cee, E209) - 8 [Ne dot vaio 125. Otheradverse effects Effecton ozone layer Etfeat on the glob warming + No known ecological damage caused by tis product, SECTION 43: Disposal considerations 18.4. Waste treatment methods ‘Waste treatment methods "Nevtaize wt sodium carbonate calc carbonate. or ime. When totally empty, continars ‘a recycable tke any other packing. Savage contehore mustbo fre of contamination before This material when discarded in puro form is nota hazardous waste as dfined by 40 CFR.261, the Resource Conservation and Recovery Act (RCRA). Dry materials may be landed or ‘recycled in accordance with fea, etal, and federal regulatons.matoais have become ‘contaminated with othe substances, dispose of in acoordanco with local, state, and federal ‘Waste disposal recommendations ‘equations LECT In accordance wit DOT “Transport document descipton + UN1805 PHOSPHORIC ACID, SOLUTION, 8, UNNo(007) = UN180S Proper Sipping Name (DOT) + PHOSPHORIC ACID, SOLUTION Department of Transportation (OOT) Hazard: ‘8 - Class - Corrotve material 49 CFR 178.196 CClasser Hazard labels (007) 8- Corosive Packing roup (DOT) Me Minoe Danger B252015 ENE co OSPHO Safety Data Sheet scan Fedral ger Vo. 7, No. S/o March 28,202 Ros and Redo ‘DOT Special Provisions 49 OFR 172.102): AT- Slee pachagngs must be caoston-sitant or have protection agalslcorosion 183 Auturized ICs: Metal (918, 318 and SIN): Rig plans (341 and 31F2), Compost (31121 and a2, 31M SHIN2, 31HD2 and SMF}. Atal Requrement Oly haus ‘nth a vapor pressre las han or ualto 140 KPa 50 (1t barat 122) oy 19045 a 58 ‘C(.3 barat 131 F) are authorized, excep forUN2672 alo see Special Prvison IPS in abla 3 fr una) ‘Not - Aluminum constructon meters arene suhorizes fr ary pat ofa packaging which ‘ormalyin contact wih te azardous mata ‘ar ze 178.274 o¥2) Nomad. =~ A7B2TS(ENS) TP1- The maxim degree of ig must nol exotod te degre of ling determined bythe folowing: Degree ef ting = 87 (1a) Whee: els the msdn mean sk temperature dung Varsport ad ise iemperalurein degrees cobs of te kqu deg fing. DOT Packaging Gxcepfons 49.CFR 173200): 154 OT Packaging Non Buk 49CFR 173.00): 209 DOT Packaging Buk (49 CFR 172,00) an DOT Quanity talons Passenger acral: SL Gocre Tsay DOT Quanity Lmtatons Cargo akratonty (49: 60 crete 73) DOT Vessel Sowage Location +A The tei may be slowed “on deck” or“under deck" ona cargo vss and on a passenger vessel, Adattona information re iverson ‘No supplamentar fomaton avait, 40R Transport dociment scion LON 1995 PHOSPHORIC ACID, QUID, 8.) Packing run (ADR) im Cass (ADR) 8 - Conse subetances Hazard idencafon number Kener No): 80 Chasticaton code ADR) Pot ‘Danger abe (ADR) Conosive sutetances Orange plates Tunnel resticton code (ADR) € xcepted quantities (ADR) et ‘Transport by to UwNe. (MOG) +805 ‘iass (DG) 1 8 Coosie substances : Pcking aroup (MDG) 2 I~ eubeances presenting low danger MAGNO 2184 Ai tranaport LUNN ,QATA) 1 1805 Class WaT) = Corosves Chat Aeronautics Law + Conrosive substancastHazardous materials nce Appended Table 1 Arce 194 of ho Enforcoment Regulations) 2572015, EN aan) « OSPHO Safety Data Sheet «ort Fede Rept V7. No 86 Moday March 2, 2012/ Res ad Regatons STAT MI 15.1. US Federal regulations ‘OSPHO 7664-362), Usted on the United Slates TSCA (Tox Subslaness Control Ae inventoy, “SARA Secon 302 Thveshols Planing Quanity (TPQ) ‘Nol applicable ‘SARA Secion 311/312 Hazard Classes Immediate (acuie) heath Pazard ‘SARA Secion 315. Emission Reporing Not apotiable 'Al component fis product ao sod oF exsaied fom Feng, ne Und Sata Eien Proeclon Agen Tos Substances Corr Act (TSCA) veo except fot [pete etiophoephorinve [cas ho T8402 I ‘oom ‘This product or miu dos ot conlin ono chemical or chemicals n exces f te specale de miimisconcontation 2s pected in 40 CFR §372:38() subject othe reporting requements of secion 313 of Tle il of the Supertund Amencments and Reauthorization Ac of 1986 and 40 GFR Part 372 15.2. Imterational regulations CANADA ‘OSPHO. (Task se — —— Usted onthe Canadian NOS (Non-Domestic Subsianons Ut) WHMIS Classification [ Glass & - Corosive Matera Eu-Regulations "No additonal information avalisle Classification according to Regulation (EC) No, 1272/2008 {CLP} ‘Skin Cor. 18 M344 Ful xt of H pases: se secton 18. Classification according to Directive STIS4B/EEC [DSD] or 1990/4S/EC [DPD] Notebssited 1522 National regulations ‘OSPHO (7064-382) ~ ‘CERCLA reportable quantities: 6.0008 ‘ANSUNGF Std. 60 potable wolersystoms: Ceriiad US Food & Orug Admin: Recognized a8 Generally Recognized Hazardous chemical under the ceria ofthe OSHA Hazard Communication Standard (20 CFR 110.1200), Appendix A: Conotve 153. US State regulations Calforia Propsiton 65 - This product does not contain any substances known tothe state of California to cause cancer andlor reproductive harm SST ERROE Revision data 57252015, Daa sources Reach dossier. Taso EN aay OSPHO Safety Data Sheet _2ccrting io Federal Register/Vol, Na $8 / Monday, March 28, 2012 Res and Regions ‘Abbreviaons and acronym + ADN: European Agreement concerning international carlage of Dangerous goods by Iniand waterways’ ‘ADR: European Agreement concerning international cariage of Dangerous goods by Road ‘AF Assessment factor {BCP : Bioconceritation factor ‘Bw Body weight CCAS: Chemical Absiracts Sevico ELV: Emission fit values EN: European Norm EU: European Hazard Statement EWC: European Wasie catlogue |ATA

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