11/21/2015 TechnicalSpecification

TYPICALTECHNICALSPECIFICATIONOFLPGMARKETED
BY
TOTALGAZ

LPG

GENERAL

>ConformingtoIndianStandard IS4576/IS14861
specifications

>VaporPressureat65oC(Max)Kg/cm2 16.87

>Volatility.Evaporationtemp.inoC 2
For95%volumeatNTP

>Copperstripcorrosionat38oC NotWorseThan1

>Dryness Nofreeentrained
water

>Odour Level2

CHEMICALCOMPOSITION

Ethane% 1max

Propane% 38max

IsButane% 19max

NorButane% 41min

IsoPentaneandolefins% 1max

Volatilesulfur% 0.003max

LIQUID

Densityat15oCKg/liter 0.557

Volumeofliquidperkgat15oCLiters 1.85

Vaporpressureat15oCBar 5.3

GrossCalorificValueKcal/kg 11840

NetCalorificValueKcal/kg 10920
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BoilingPointatatmosphericpressureoC 0

VAPOR

Densityat15oCKg/m3 2.21

Volumeofgasperkgat15oCm3 0.48

Latentheatofvaporizationat 86
15oCKcal/kg

GrossCalorificValueKcal/Nm3 26200

NetCalorificValueKcal/Nm3 24100

Airrequiredforcombustionm3/m3 29

SAFETYINFORMATIONSHEET
PL1
NAME(S):LIQUEFIEDPETROLEUMGAS,LPGUNNO:1075

CHEMICALFORMULA:MixtureofPropane/Butane

PHYSICALPROPERTIES OTHERCHARACTERISTICS

S.G:0.530.57(15oC)
E.L:1.89.6%byvol.Inair
V.D:1.5TO2.0(Air=1)
I.T:405450oC
Colourlessgasatroom
temperature.CommercialLPG
usuallycontainstracequantitiesof
anodorisingagent(Mercaptan)
whichimpartsacharacteristic
pungentcolour.LPGgenerally
contains20to40%C3compounds
and6080%C4compoundswith
C2andC5compoundsintraces.
OnevolumeofliquidLPG
producesabout250volumesof
LPGvapor.

TLV/MACVALUE: ppm:1000ACGIH(TWA)
mg/m3:1800ACGIH(TWA)

HAZARDS PRECAUTIONS EXTINGUISHING

AGENTS

Extremelyflammable Keepawayfromheat Carbondioxide,dry

andflame chemicalpowderor
Keepawayfrom waterspraymaybe
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gas Keepawayfrom waterspraymaybe

oxidisingmaterials. usedtoconfineand
Donotallowtoleak controlLPGfire.
Fire:Dangerous, out.
whenexposedto Adequateventilation
heatorflame

Disaster:Highly
dangerouscanreact
withoxidising
materials.

SYMPTOMS PRECAUTIONS FIRSTAID

Inhalation: Donotallowgasto Removevictimto

Exposuretohigh leak freshair.Rescuers
shouldtakesuitable
concentrationofLPG precautiontoprevent
willproduce Usegasmask theirbeingexposedto
unconsciousness contaminated
andsubsequent atmosphere.Ifvictim
Usehandgloves isnotbreathing,give
asphyxiation.Can assistedrespiration,
alsocauserapid Adequateventilation preferablybymouth
respiration,mental tonosemethod.If
unconsciousbut
dullness,poor breathing,placeinthe
judgementand unconscious
nausea. (recovery)position.
Giveexternalcardiac
massageifnecessary.
Skin&Eyecontact: Intheeventofcold
Ifliquidgasescome burnsobtainmedical
intocontactwith advice.Coverthe
woundswithsterile
unprotectedskinand dressingonly.Donot
eyes,theywill applyointmentor
evaporatequickly powders.
andthecoolingeffect
couldproducefrost
biteorcoldburns.

ADDITIONALINFORMATION:

MATERIALSAFETYDATASHEET

1 CHEMICALIDENTITY:

Chemicalname:LiquefiedPetroleum Chemicalclassification:
Gas Fuel

Synonyms:Bottledgas Tradename:Cooking
gas
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Formula:Mixtureof C.A.S.No.:68476857 U.NNo.:1075

Propane&Butane

Regulated Shippingname Hazchem

identification :Petroleumgases, No.:2WE
liquefied

Codes/labels:223/ Hazardous
Class2,Flammablegas wasteI.DNo.:
5

Hazardous C.A.S Hazardous C.A.S.No.

ingredients No. ingredients

1.Propane(C3H8) 74986 2.Butane(C4H10) 106978

2 PHYSICAL&CHEMICALDATA:

Boilingrange Physicalstate:Gas@ Appearance:

:42oCto2oC 15oC&1atm. Colourless

Vaporpressure@35oC Odour:Ethyl
:120psi@38oC Mercaptanadded
forodourwarning

Melting/
freezingpoint:
47oC

Vapor Solubilityinwaterat30oC Others:Soluble

density(Air=1): :Immiscible,liquidfloats inorganic
1.8 andboilsonwater solventsand
alcohol

Specific pH:Notpertinent
gravity(Water=
1):0.562gm/l
@15oC

3 FIREANDEXPLOSIONHAZARDDATA:

Flammability:Yes LEL:1.5% Flashpoint:104.4oCto

60oC(CC)

TDG UEL:9.5% Flashpoint:Datanot

flammability:2 available(OC)

Autoignitiontemperature:405oC

Explosionsensitivitytoimpact:Mayexplode

Explosionsensitivitytostaticelectricity:Mayexplode
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Hazardouscombustionproducts:EmitsCOandCO2

Hazardouspolymerization:Doesnotoccur

Combustible Explosive Corrosivematerial:No

liquid:No material:No

Flammable Oxidiser:No Others:No

material:Yes

Pyropheric Organic
material:No peroxide:No

4 REACTIVITYDATA:

Chemicalstability:Chemicallystable

Incompatibilitywithothermaterial:Incompatiblewithstrong
oxidisers

Reactivity:Doesnotreactwithcommonmaterialsbutmayreact
withoxidisingagents

Hazardousreactionproducts:Datanotavailable

5 HEALTHHAZARDDATA:

Routesofentry:Inhalationanddermalabsorption(skin)

Effectsof Inhalation: Olefinicimpuritiesmaylendanarcotic

exposure/ effect.Highconcentrationcauses
symptoms asphyxia
:

Skin: Contactwithliquidcausescoldburns

Emergency Inhalation Ifinhaled,removethevictimtofresh

treatment: : air.Ifnotbreathing,giveartificial
respiration.Ifbreathingisdifficult,call
physician

Skin: Removewetclothing.Washthe
affectedareawithplentyofwater.
Covertheaffectedareawithclean
cloth/bandage.Keepthepatient
warm

Eye: Flushwithplentyofwater.Seek
medicalhelp

(ACGIII): 1000 1800mg/m3 STEL: Not

ppm listed

Permissible 1000 1800mg/m3 Odor 5000

exposure ppm threshold: 20000
11/21/2015 TechnicalSpecification

exposure ppm threshold: 20000

limit: ppm
15000
60000
mg/m3

LD50: Not LD50: Not

listed listed

NFPAhazard Health: Flammability: Reactivity: Special:

signals 1 4 0 Nil

6 PREVENTIVEMEASURES:

Personnelprotectiveequipment:Usefullprotectiveclothingwith
breathingapparatusset.

Handlingandstorageprecautions:Donottouchtheproductwith
barehands.Useproperhandgloves.Donotinhaletheproduct.
Standupwindwhilesampling/handlingtheproductinacool,well
ventilatedareaandawayfromthesourceofignition.

7 EMERGENCYANDFIRSTAIDMEASURES:

Fire Fire CO2,DCPandwaterspray

extinguishing
media:

Special Iffuelsupplyfeedingfirecannot
procedures: bestopped,allowthegastoburn
undercontrolledconditions.
Keepthecontainercoolby
sprayingwaterifexposedtoheat
orfire.
Fightfirefromupwinddirection.
Applywateronvaporspaceof
thecontainer

Unusual Neverstandintheaxisofbullets.
hazards: Heavyleakageofliquidcan
impairvisibility
LPGfirecancausesevereburn
injuries
Leakinggasmaytravellong
distancestillitmeetsanignition
sourceandflashbackorcause
vaporcloudexplosion

EXPOSURE Firstaid Antidotes/dosages:Notavailable

measures:A/a

SPILLS Stepstobe Eliminateallignitionsources.

taken: Arrestleaksifpossibleandsafe
orremoveleakycontainerto
isolateplace.Ventilatethearea.
Disperse/dilutetheleaking
productwithwaterspray.

Waste Allowgastoburnundercontrol.
disposal
method:
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disposal
method:

8 ADDITONALINFORMATION/REFERENCES:

Donotstorewithoxidisers
Gasfreethecontainersbeforeundertakingrepairs
Electricalequipmentinthestorageareashouldbeflameproof
type
Allequipment,pipelinesshouldbeproperlyearthed/bonded
Nakedflame/smokingstrictlyprohibited0
Periodicalinspectionaltestingrecommended
Laiddownsafeoperatingpracticesshouldbestrictlyobserved

9 MANUFACTURERS/SUPPLIERSDATA:

Nameoffirm:TotalOilIndiaPvt.Ltd. Contactperson:

Mailingaddress:#138,GroundandFirst Inemergency:
Floor,RahejaParamount,ResidencyRoad,
Bangalore25

Telephone/faxnumbers:08042730001
05

Telegraphicaddress: Localbodies
involved:

Localbodies
involved
Standard
packing
Tremcard
details/Ref
Others

10 DISCLAIMER

Informationcontainedinthismaterialdatasheetisbelievedtobe
reliablebutnorepresentationguaranteeorwarrantiesofanykind
aremadeastoitsaccuracy,suitabilityforaparticularapplication
orresultstobeobtainedfromthem.Itisuptothemanufacturer/
sellertoensurethattheinformationcontainedinthematerial
safetydatasheetisrelevanttotheproductmanufactured/
handledorsoldbyhimasthecasemaybe.TheI.C.M.Amakes
nowarrantiesexpressedorimpliedinrespectoftheadequacyof
thisdocumentforanyparticularpurpose.