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Enhancement of visible light photocatalytic activity of MoO3 with V2O5 additive
040
eCB MoO3 + H2O2 OH + OH
021
110
h+VB MoO3 + OH OH
020
060
intensity
111
Fig. 3 shows temporal variation of spectral contours for MO
101
150
002
200
210
081
2 11 11 2
161
230
171
041
130
042
aqueous solution with 5, 10, 20 and 25 wt% V2O5 in MoO3.
170
141
10 20 30 40 50 60
From the figure, it can be seen that complete decoloration in
2 theta these cases occurred for 180, 100, 90 and 30 min respectively.
10 % composite of V2O5 + Mehtyl Orange on 17-5-15
Fig 1. XRD pattern of MoO3 sample used. 1.2
0min
1.5
0 mnts
20min 20 mnts
5% V2O5 composite with MoO3+10ppm MO+H2O2 in bulb
1.0 40min 40 mnts
60min 60 mnts
bsorbance
180min
0.6
B
presence and in absence of H2O2 are depicted in Fig 2. 0.4 0.5
0.2
1.2 1.5
0min
0.1g MoO3+10ppm MO 60min 0.1g MoO3+10ppm MO+H2O2 in bulb 0.0 0.0
1.0 120min 400 450 500 550 600 400 500 600
60min
0.6
0min (a) (b)
25 % V2O5 composite with MoO3 + MO 0n 18-5-15 repeat
0.4 0.5
0.1g 20% V2O5 on MoO3+10ppm MO+H2O2 0 mnts
10 mnts
0.2 0min 20 mnts
30 mnts
20min
absorbance
0.0 0.0 40min 1
400 450 500 550 600 400 450 500 550 600
60min
Absorbance
wavelength wavelength 80min
90min
(a) (b)
Fig. 2. Temporal variation of spectral contours of aqueous
400 450 500 550 600
solution of MO+MoO3 as a function of irradiation time (a) in wavelength
0
500 600
wavelength
the absence and (b) in the presence of H2O2
(c) (d)
From the figure it can be seen that in the absence of H2O2, the
decrease in absorption intensity is very less indicating no Fig. 3. Temporal variation of spectral contours for MO
significant dye degradation for exposure up to 150 minutes. aqueous solution with (a) 5wt% (b) 10wt% (c) 20wt% and (d)
However, in presence of H2O2, there is 98 % decrease in 25wt% V2O5 as a function of irradiation time
intensity for 180 min of exposure. In photocatalytic process,
presence of external oxidant H2O2 has been found to be The observed decrease in lowering of degradation time could
beneficial in several photocatalytic studies over TiO2 [21], be understood in terms of the UV-visible diffuse reflectance
Bi2Mo3O12 [22] and Fe2Mo3O12 [19]. H2O2 increases the spectra of V2O5, MoO3 and 25 wt% V2O5 in MoO3 shown in
electron-hole recombination time by accepting the conduction Fig. 4. Since V2O5 shows higher absorption compared to
band electrons in the catalyst to form OH radicals which act MoO3 in the visible region up to ~550 nm, the observed
as powerful oxidants and attack dye molecular frame work increase in catalytic efficiency for 25 wt% V2O5 in MoO3 is
and disintegrate it. This provides an additional way for attributed to the additive.
degradation process besides the dye degradation due to e
directly. The enhanced activity due to H2O2 is attributed to the
following reactions.
MoO3 + hv eCB MoO3 + h+vB MoO3
1.2 0.8
3.0
MoO3 V2O5 25 wt% V2O5 in MoO3
1.8
0.6 0.4
1.2
0.3 0.2
0.6
Fig 5 shows UV-visible absorption spectra at different times for Rh-B, MB nd EY with H2O2 over MoO3 containing 25wt%
V2O5 under progressive irradiation.
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International Journal of Engineering and Applied Sciences (IJEAS)
ISSN: 2394-3661, Volume-2, Issue-11, November 2015
0 mnts
25% V2O5 com with Rh-B 0n 20-5-15 [5]. Zhou, X., Yang, H., Wang, Ch., Mao, X., Wang, Y., Yang, Y., Liu, G.,
0.5
20 mnts
40 mnts
60 mnts
2010. Visible light induced photocatalytic degradation of
0.4 80 mnts
100 mnts
Rhodamine-B on one dimensional iron oxide particles. J. Phys. Chem.
140 mnts
0.3
C. 114, 17051-17061.
Absorbance
[6]. CHAKRABARTI, S., DUTTA, B.K., 2004. PHOTOCATALYTIC
DEGRADATION OF MODEL TEXTILE DYES IN WASTE WATER USING ZNO
0.2
80min
0.20
120min IN DEIONIZED WATER. NANO TECHNOL.
160min
0.15
DOI:10.1088/0957-4484/19/19/195709.
0.10
0.05
[9] Hao, Y., Jiaqiang, X., 2010. Preparation, Characterization and
0.00
Photocatalytic Activity of Nanometer SnO2, Int. J. Chem. Eng.
500 550 600 650 700 750 800
wavelength
Applications, 1, 241-246.
[10] Sandip M., Chattopadhyay, T., Das, S., Sankar Roy, M., Swarup, N.,
(b) Debasis D., 2012. CdO and CdS nanoparticles from pyrolytic method:
0.6
0.1g 25% V2O5+10ppm EY+H2O2
Preparation, Characterisation and photocatalytic activity. Indian J.
0.5 0min
20min
Chem. 51A, 807-811.
0.4 40min [11] LIU, X., PAN, L., LI, J., YU, K., SUN, Z., 2013. VISIBLE LIGHT-INDUCED
absorbance
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