Prof.

Rana Hassan Tariq

SUBJECT: CHEMISTRY (PART-I)
CHAPTER 1
1. How many neutrons are present in H2SO4?
(a) 44 (b) 46 (c) 48 (d) 50
2. How many oxygen atoms are present in 32 grams of SO2?
(a) 6.02 1023 (b) 3.01 1023 (c) 6.02 1022 (d) 12.04 1023
3. The volume occupied by 1.6 grams of O2 at STP is:
(a) 22.414 dm3 (b) 2.24 dm3 (c) 1.12 dm3 (d) 112 cm3
4. A ring is studded with 2 grams of diamond. How many carbon atoms are present?
(a) 1.003 1023 (b) 10.03 1023 (c) 1.003 1022 (d) 2.006 1023
5. The smallest collection of ions in an ionic compound is called:
(a) Chemical formula (b) Formula unit (c) Formula mass (d) Molecular formula
6. An organic compound contains 16% sulphur. The molar mass of the compound is:
(a) 200 (b) 800 (c) 1600 (d) 3200
7. The mass of 1 mole of electrons is:
(a) 1.008 mg (b) 0.184 mg (c) 1.673 mg (d) 0.54 mg
8. In spectrometry, ions are separated on the basis of:
(a) Masses only (b) Charge only (c) Charge to mass ratio (d) Mass to charge ratio
9. Law of conservation of mass was given by:
(a) Lavoiser (b) Proust (c) John Dalton (d) Gay-Lussac
10. Which of the following is always a whole number?
(a) Atomic mass (b) Mass number (c) Atomic volume (d) Both (a) and (b)
3
11. 2 mole of H2S and 11.2 dm of SO2 (at S.T.P) reacts to form moles of sulphur:
SO2 + 2H2S 3S + 2H2O
(a) 1.5 (b) 3 (c) 11.2 (d) 6
12. The no. of moles of CO which contains 8g of oxygen:
(a) 0.25 (b) 0.2 (c) 0.4 (d) 0.5
13. O2 gas contained in a flask at S.T.P was replaced by SO2 under same conditions. The weight of SO 2 will be:
(a) Equal to that of O2 (b) Half that of O2 (c) Twice that of O2 (d) One fourth of O2
14. 0.5 mole of CH4 and 0.5 moles of SO2 have equal:
(a) Volume (b) Mass in grams (c) Number of atoms (d) Number of molecules
+
15. 9.8g of aqueous solution of H2SO4 contains moles of H ions:
(a) 0.1 (b) 0.2 (c) 0.4 (d) 0.01
16. A compound having empirical formula C3H3O and its molecular mass is 110.02. Its molecular formula is:
(a) C3H3O (b) C6H6O2 (c) C9H9O3 (d) C3H6O2
17. How many atoms of carbon are present in 18g of glucose?
(a) 6.0 1023 (b) 3.6 1023 (c) 6.0 1022 (d) 3.6 1024
18. Which isotope need strongest magnetic field for equal deflection?
(a) Ne-20 (b) Ne-21 (c) Ne-22 (d) All need equal
19. Which is not same for isotopes of an element?
(a) Atomic number (b) Electronic configuration
(c) Position in periodic table (d) Physical properties
20. Among natural isotopes, number of isotopes with odd atomic number:
(a) 286 (b) 40 (c) 154 (d) 126
21. Which one is not molecular ions?
+ + +
(a) N2 (b) CH4 (c) NH4 (d) CO+
22. The empirical formula of oxalic acid is:
(a) CH2O (b) C2H2O (c) CHO2 (d) H2C2O4
23. 32 g of SO2 contains oxygen atoms:
(a) 3.01 1023 (b) 6.02 1023 (c) 1.204 1024 (d) 1.204 1022
24. The volume occupied by 1.4 grams of N2 at STP:
(a) 22.4 dm3 (b) 2.24 dm3 (c) 1.12 dm3 (d) 112 cm3
25. The empirical formula of acetic acid is:

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Prof.Rana Hassan Tariq
 Prof.Rana Hassan Tariq
(a) CH2O (b) CHO2 (c) CH2O2 (d) CHO
26. The diameter of the atom is in the range of:
(a) 0.2 m (b) 0.2 mm (c) 0.2 nm (d) 0.2 pm
27. Which is true about the isotopes?
(a) Same number of neutrons (b) Same mass number
(c) Same physical properties (d) None of these
28. In mass spectrometry, ions are separated on the basis of:
m e
(a) Mass (b) Charge (c) ratio (d) ratio
e m
29. Which of the following is not monoisotopic?
(a) Fluorine (b) Iodine (c) Gold (d) Barium
30. Which of the following is macromolecule?
(a) Diamond (b) Sand
(c) Haemoglobin (d) All are macromolecules
31. 1 amu in grams is:
(a) 1.66 1022 (b) 1.66 1024 (c) 1.66 1027 (d) 1.66 1023
32. 0.5 moles of methane and 0.5 moles of ammonia gas have equal:
(a) Volume (b) Molecules (c) Mass (d) Atoms
33. Number of moles of CO2 which contains 8.0g of oxygen:
(a) 0.25 (b) 0.5 (c) 1.0 (d) 1.5
34. Mass of 1 mole of electron:
(a) 1.008 mg (b) 0.184 mg (c) 1.673 mg (d) 0.54 mg
35. What is the number of protons in one molecule of SO3?
(a) 24 (b) 32 (c) 40 (d) 64
36. NH3 reacts with O2 to form N2 and steam.
4NH3 + 3O2 2N2 + 6H2O
What is the volume of O2 remaining when 60 cm3 of NH3 is burnt in 100 cm3 of oxygen? All volumes are measured at same
temperature and pressure.
(a) 35 cm3 (b) 40 cm3 (c) 50 cm3 (d) 55 cm3
37. Methane reacts with steam to form CO and H2:
CH4(g) + H2O(g) CO(g) + 3H2(g)
What volume of hydrogen gas can be obtained from 100 cm3 of methane at STP?
(a) 300 cm3 (b) 200 cm3 (c) 150 cm3 (d) 100 cm3
38. How many electrons are present in 1 mole of H2?
(a) 6.02 1023 (b) 3.01 1023 (c) 1.204 1024 (d) Infinite
39. Stoichiometric calculations cannot be applied to reversible reactions because:
(a) Less product is formed (b) Reaction goes in only one direction
(c) Products again change to reactants (d) Products do not appear
40. A compound contains 50% sulphur and 50% oxygen by mass. The empirical formula of the compound is:
(a) SO (b) SO2 (c) SO3 (d) S2O3
41. An element A form a hydride MH3 which contains 90% of A by mass. What is the relative atomic mass of A?
(a) 27 (b) 30 (c) 87 (d) 90
42. Calcium reacts with water as shown below:
Ca + 2H2O Ca(OH)2 + H2
What is the total mass of solution that left behind when 40g of Ca reacts with 100g of H 2O?
(a) 58g (b) 138g (c) 74g (d) 140g
43. Find the mass of same number of atoms of potassium as are present in 11.5g of sodium:
(a) 39g (b) 19.5g (c) 78g (d) 22g
44. Out of 280 isotopes which occur in nature, how many are radioactive?
(a) 20 (b) 40 (c) 60 (d) 80
45. A puff of smoke weighs 0.1 grams. How many carbon atoms are present?
(a) 6.02 1023 (b) 5.0 1021 (c) 1.204 1024 (d) 3.01 1023
46. O2 gas contained in a flask at STP was replaced by SO2 under same conditions. The weight of SO2 will be:
(a) Equal to O2 (b) Half of O2 (c) Twice of O2 (d) One-fourth of O2
47. The number of formula units in 58.5 g of NaCl is:
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 Prof.Rana Hassan Tariq
(a) 6.02 1023 (b) 1.505 1023 (c) 3.01 1023 (d) 12.04 1023
48. 180 g of C6H12O6 contains moles of H-atoms:
(a) 6.02 1023 (b) 6 (c) 12 (d) 3.01 1023
49. Which of the following has maximum number of isotopes?
(a) Ca (b) Cd (c) Pd (d) Sn
50. The charge on 1 mol of electrons is:
(a) 1 Faraday (b) 2 Faradays (c) 3 Faradays (d) Zero
51. The number of H-atoms in 4.5 g of ice is equal to:
(a) 6.02 1023 (b) 3.0 1023 (c) 1.05 1023 (d) 3.01 1022
52. In a reaction, 4NH3 + 5O2 4NO + 6H2O. When one mole of NH3 and one mole of O2 are made to react completely
then:
(a) 1 mole of H2O is formed (b) Oxygen is consumed completely
(c) NH3 is consumed completely (d) 1 mole of NO is formed
53. A ring is studded with 6 grams of diamond. How many carbon atoms are present?
NA
(a) NA (b) (c) 2NA (d) 3NA
2
54. A hydrocarbon contains C = 80%, H = 20%. What is its empirical formula?
(a) CH2 (b) CH3 (c) CH4 (d) C2H6
55. What is the mass of Al in 204 g of Al2O3?
(a) 26 g (b) 27 g (c) 54 g (d) 108 g
56. What is the mass of 11207 cc of oxygen at STP?
(a) 8g (b) 16 g (c) 32 g (d) 64 g
57. Calcium and palladium are:
(a) Isopic (b) Isotonic (c) Isobaric (d) Isophratic
3
58. Molar volume of He is 44.828 dm at:
(a) 100C and 1 atm. (b) 25C and 0.25 atm. (c) 0C and 0.5 atm. (d) 40C and 0.5 atm.
59. A compound has 50% sulphur and 50% oxygen by mass, its empirical formula is:
(a) SO (b) S2O3 (c) SO2 (d) 2SO3
60. Gold has isotopes:
(a) 4 (b) 3 (c) 2 (d) 1
61. The percentage of oxygen in caustic soda is:
(a) 8% (b) 10% (c) 40% (d) 60%
62. How many molecules are present in one gram of hydrogen?
(a) 6.02 1023 (b) 3.01 1023 (c) 2.5 1023 (d) 1.5 1023
63. At S.T.P. number of atoms present in 11.2 litre of SO2 are:
3
(a) 6.02 1023 (b) 2 6.02 1023 (c) 6.02 1023 (d) 4 6.02 1023
2
64. Empirical formula of ascorbic acid is:
(a) CHO2 (b) C3H4O3 (c) CH2O (d) CHO
65. 90 g of glucose contains number of hydrogen atoms:
(a) 7.2 1024 (b) 3.6 1023 (c) 3.6 1024 (d) 7.2 1023
66. Mass of sodium in 53 g of Na2CO3 is:
(a) 23 g (b) 46 g (c) 92 g (d) 106 g
67. Polariziability is least prominent in:
(a) An atom (b) A molecule (c) An anion (d) A cation
68. The word ion means:
(a) Smallest entity (b) Indivisible (c) Wanderer (d) Charged
69. A mixture of 5 ml of CH4 and 10 ml of C2H6 will produce how much CO2 on complete combustion:
(a) 25 ml (b) 45 ml (c) 15 ml (d) 60 ml
70. The stated quantity of which substance is not equal to its one mole:
(a) 23 g of Na (b) 22.4 litre CO2 at S.T.P. (c) 18 g of ice (d) 22 g of dry ice
71. Isotopes have:
(a) Same physical properties (b) Same neutrons
(c) Same position in periodic table (d) All above
72. In combustion analysis, the weight of CO2 absorber is increased due to formation of:

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 Prof.Rana Hassan Tariq
(a) CO2 (b) KOH (c) K2CO3 (d) K2CO3 and H2O
73. Which of the following does not have same empirical and molecular formula?
(a) Formaldehyde (b) Sucrose (c) Ethylene glycol (d) Acetone
74. The volume of a gas is not effected by:
(a) Temperature (b) Pressure (c) Size of molecule (d) Size & mass of molecules
75. 16 g of H2 reacts with 16 g of O2. The mass of H2O formed is:
(a) 4.5 g (b) 9g (c) 18 g (d) 36 g
76. Large number of isotopes are known for the element whose masses are multiple of:
(a) Two (b) Four (c) Six (d) Eight
77. What is the mass of same number of calcium atoms as are present in 12 grams of Mg?
(a) 5g (b) 10 g (c) 20 g (d) 40 g
78. Mass spectrometry can be helpful to find out:
(a) Exact mass of an isotope (b) Number of isotopes of an element
(c) Relative abundance of isotopes (d) All above
79. The phenomenon of isotopy was discovered by:
(a) Soddy (b) Stoney (c) Aston (d) Dempster
80. The cracking of methane in the absence of air is carried out as:
CH4 C + 2H2
How many moles of CH4 is required as a source of H2 to get 5 moles of NH3?
(a) 3.75 moles (b) 7.5 moles (c) 11.5 moles (d) 15.0 moles
81. Limiting reagent is that which:
(a) Control the yield of a reaction (b) Produce least amount of product
(c) is consumed earlier during reaction (d) All are correct
82. The least number of isotopes among following is of:
(a) Oxygen (b) Carbon (c) Tin (d) Chlorine
83. The energy of electrons as compare to visible light:
(a) Greater (b) Smaller (c) Equal (d) Cant be related
84. Select the cation which is different one:
+
(a) Mg2+ (b) NH4 (c) Fe3+ (d) Sn4+
85. 0.25 moles of Na3PO4 completely dissociates in water to produce total ions:
(a) 6.025 1022 (b) 6.02 1023 (c) 1.806 1023 (d) 3.01 1023
86. The largest number of atoms are present in:
(a) 1 g Ni (b) 1 g Ca (c) 1 g N2 (d) All have equal
87. A sample of (NH4)3PO4 contains 3.18 moles of H-atoms, the number of moles of O-atoms should:
(a) 0.265 (b) 0.795 (c) 1.06 (d) 3.18
88. The atomic weight of Cu is 63.546 a.m.u. There are two naturally occurring isotopes of copper Cu-63 and Cu-65. The natural
abundance of Cu-63:
(a) 10% (b) 30% (c) 50% (d) 70%
89. The value of gram molecular volume of ozone at S.T.P. is:
(a) 22.4 dm3 (b) 2.24 dm3 (c) 11.2 dm3 (d) 63.2 dm3
90. 0.5 mole of N-atoms have same number of atoms as are in:
(a) 12 g C (b) 32 g S (c) 8gO (d) 24 g Mg
91. Two elements X (atomic mass = 50) and Y (atomic mass = 16) combine to give a compound having 32% Y. The chemical formula
of the compound is:
(a) X2Y3 (b) XY (c) XY2 (d) X3Y4
92. The number of gram-molecule of oxygen in 6.02 1023 molecules of CO is:
(a) 0.5 (b) 1.0 (c) 5.0 (d) 10.0
93. How many molecules are present in 11200 ml of CO2 at S.T.P?
(a) 6 1023 (b) 1.5 1023 (c) 1.2 1023 (d) 3.01 1023
94. The mass of Ca present in Ca(NO3)2 that contains 42 g of nitrogen is:
(a) 50 g (b) 60 g (c) 70 g (d) 80 g
95. If four moles of SO2 are oxidized to SO3, how many moles of oxygen are required?
(a) 0.5 (b) 1.0 (c) 1.5 (d) 2.0
96. If empirical formula of a compound is CH2O and its molar mass is 30, what will be its actual formula?

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(a) CH2O (b) C2H4O2 (c) C4H8O4 (d) C6H12O6
97. What is the ratio of volume of 1 g H2 to the volume of 16 g CH4 at S.T.P.?
(a) 1:1 (b) 1:2 (c) 1:8 (d) 2:1
98. The number of electrons in one mole of H2:
(a) 6.02 1023 (b) 3.01 1023 (c) 1.2 1024 (d) Indefinite
99. The efficiency of a chemical reaction can be checked by calculating:
(a) Amount of limiting reactant (b) Amount of products
(c) Amount of excessive reactant (d) Amount of reactants left
100. Chlorine atom and chloride ions:
(a) are chemically identical (b) are allotropes of Cl
(c) have same number of electrons (d) have same protons
101. What is the mass of aluminium in 51 g of Al2O3?
(a) 27 g (b) 54 g (c) 13 g (d) 108 g
102. How many gram-atoms of oxygen are present in 0.16 moles of H 2O?
(a) 16 (b) 8 (c) 0.16 (d) 0.32
3
103. 11.2 dm H2 at S.T.P. contains molecules:
(a) 1 1020 (b) 1.5 1023 (c) 3.0 1023 (d) 6.01 1023
104. One molar volume of gas at S.T.P. is occupied by:
(a) 1 g gas (b) 6.02 1023 atoms of gas
(c) 22.4 m3 gas (d) 1 g molecule of gas
105. The highest percentage of oxygen by weight is possessed by:
(a) CH3OH (b) C2H5OH (c) HCOOH (d) H2O2
106. Sulphur has three allotropes. The number of isotopes of sulphur are:
(a) 2 (b) 3 (c) 4 (d) 8
107. The radius of atoms are in the order of:
o
(a) 2A (b) 0.2 nm (c) 200 pm (d) None of these
108. which one is the molecule of compound?
(a) Cl2 (b) S8 (c) HCl (d) All
109. 27g of Al will react with how many grams of oxygen to produce Al 2O3?
(a) 8g (b) 16g (c) 32g (d) 24g

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