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PHYSICAL CHEMISTRY

TARGET : JEE (MAIN) 2017


Course : ABHINAV (EA) Date : 04-05-2015 NO. 01

TEST INFORMATION

DATE : 31.05.2015 PART TEST-1 (PT-1) (MAIN)

Syllabus : Introduction to chemistry and Atomic structue (Upto Bohr atomic Model and Spectrum)

This DPP is to be discussed in the week (04-05-2015 to 09-05-2015)


DPP No. # 01
Total Marks : 34 Max. Time : 26 min.
Single choice Objective ('1' negative marking) Q.1 to Q.8 (3 marks, 2 min.) [24, 16]
Fill in the Blanks ('1' negative marking) Q.10 (10 marks, 10 min.) [10, 10]

Atomic masses (in amu) : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Au = 197, Hg = 200, Pb = 207]
1. 1 amu is equal to :
1
(1) 1.66 1024 kg (2) times the mass of one 16
8O
-atom
8
1 1
(3) times the mass of one 11H -atom (4*) times the mass of one 12
6C
-atom
2 12
1 amu fuEu ds cjkcj gksrk gS %
1
(1) 1.66 1024 kg (2) ,d 16
8O
-ijek.kq ds nzO;eku dk xquk
8

1 12 1
(3) ,d 11H -ijek.kq ds nzO;eku dk xquk (4*) ,d 6 C -ijek.kq ds nzO;eku dk xquk
2 12

2. The mass of half mole of electrons is about : (Given : Mass of one electron = 9.1 1028 g)
vk/ks eksy bysDVkWu dk nzO;eku] yxHkx fdruk gksxk % (fn;k gqvk gS : bysDVkWu dk nzO;eku = 9.1 1028 g)
(1) 0.546 mg (2*) 0.273 mg (3) 1.092 mg (4) 4.55 mg

3. 39.4 kg of gold was recovered from a smuggler. The number of atoms of gold recovered were :
,d rLdj ls 39.4 kg lksuk kIr fd;k x;kA kIr gq, lksus esa ijek.kqvksa dh la[;k D;k gS %
(1) 200 (2) 1.2044 1025 (3) 6.022 1025 (4*) 1.2044 1026
39.4 103

Sol. No. of atoms of gold recovered = Moles of gold NA = 197 NA = 1.2044 10
26

39.4 103

gy- kIr Lo.kZ dh ijek.kq la[;k = Lo.kZ ds eksy NA = 197 NA = 1.2044 10
26

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4. Which of the following has the least mass ?
(1) 2 g-atom of Nitrogen (2*) 3 1023 atoms of Carbon
(3) 1 mole of Sulphur (4) 7 g of Silver
fuEu esa ls dkSulk] U;wure nzO;eku j[krk gS ?
(1) ukbVkstu
ds 2 xzke-ijek.kq (2*) dkcZu ds 3 1023 ijek.kq
(3) lYQj dk 1 eksy (4) flYoj ds 7 g
Sol. (1) 2gm atom of nitrogen = 28gm
(2) 6 1023 atoms of C has mass = 12 gm

12 3 10 23
3 1023 atoms of C has mass = = 6gm
6 10 23
(3) 1 mole of S has mass = 32gm
(4) 7.0gm of Ag
So, lowest mass = 6gm of C.
gy- (1) 2gm ukbVkstu ijek.kq = 28gm
(2) 6 1023 C ijek.kq dk nzO;eku = 12 gm
12 3 10 23
3 1023 C ijek.kq dk nzO;eku gksxk = = 6gm
6 10 23
(3) 1 eksy S dk nzO;eku = 32gm
(4) 7.0 gm .Ag
vr%] U;wure nzO;eku = C ds 6gm.

5. The charge on 1 gram of Al3+ ions is : (e = electronic charge)


1 1 1
(1) N e coulomb (2) N e coulomb (3*) N e coulomb (4) 3 NAe coulomb
27 A 3 A 9 A
Al3+ vk;uksa ds 1 xzke ij vkos'k fuEu gS % e = bysDVkWfud vkos'k
1 1 1
(1) N e dwykWe (2) N e dwykWe (3*) N e dwykWe (4) 3 NAe dwykWe
27 A 3 A 9 A

1 1
Sol. Moles of Al3+ ions = so no. of Al3+ ions = N
27 27 A

1 1
so charge on these ions = NA 3e coulomb = N e coulomb
27 9 A

1 1
Al3+ vk;uksa ds eksy = vr% Al3+ vk;uksa dh la[;k = N
27 27 A

1 1
bu vk;uksa ij vkos'k = NA 3e dwykWe = N e dwykWe
27 9 A
6. If the mass of 0.25 mole of an element X is 2.25 g, the mass of one atom of X is about :
;fn ,d rRo X ds 0.25 eksy dk nzO;eku 2.25 xzke gS, rc X ds ,d ijek.kq dk nzO;eku yxHkx fuEu gS %
(1) 1.5 x 1024 g (2) 2.5 x 1023 g (3*) 1.5 x 1023 g (4) 2.5 x 1024 g
Sol. Mass of 0.25 NA atoms of X is 2.25 gram
2.25
0.25 N A gram = 1.5 10 gram
so, mass of 1 atom is = 23

X ds 0.25 NA ijek.kq dk nzO;eku 2.25 xzke gSA


2.25
vr%] 1 ijek.kq dk nzO;eku = 0.25 N xzke = 1.5 1023 xzkeA
A

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7. 1.5 1022 atoms of an element weigh about 0.9 g. The atomic mass of the element (in amu) is :
,d rRo ds 1.5 1022 ijek.kqvksa dk nzO;eku yxHkx 0.9 g gSA rRo dk ijek.kq nzO;eku (amu esa) D;k gksxk %
(1*) 36 (2) 18 (3) 54 (4) 72
Sol. Mole of element At. Mass of element = Mass of element

1.5 1022

NA At. Mass of element = 0.9

At. Mass of element = 36 u.
gy- rRo ds eksy rRo dk ijek.kq nzO;eku = rRo dk nzO;eku
1.5 1022

NA rRo dk ijek.kq nzO;eku = 0.9

rRo dk ijek.kq nzO;eku = 36 u.

8. 16g of oxygen has same number of molecules as in :


16g vkWDlhtu esa mrus gh v.kq gSa ftrusa fd %
(1) 16 g of CO (2) 28 g of N2 (3) 7 g of N2 (4*) 1 g of H2
(1) 16 g CO esa (2) 28 g N2 esa (3) 7 g N2 esa (4*) 1 g H2 esa

9. Fill the blanks in the table (where NA is the Avogadro number) :


fjDr LFkku dh iwfrZ djks tgka NA, vkoksxknzks la[;k gS :

Gram Mole Atoms


No. of atoms Mass removed
Atomic Moles of removed removed
S.No. Sample present in from the
mass of sample from the from the
the sample sample
sample sample sample

1. 8gO ___ ___ ___ ___ ___ ___

NA 1 mole NA
For Example 16 g mole 2g 8
2 8
2. 230 g Na 46 g

3. 60 g Ca 1 mole

4. 20 g He 3 mole

5. 56 g N mole

NA
6. 12 g Mg
4

7. 128 g S NA

3 NA
8. 93 g P
2

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uew us es a
uew us dk xz k e uew us ls uew us ls
uew us ds mifLFkr uew us ls gVk;k
uew uk ijek.oh; gVk;s x;s gVk;s x;s
eks y ijek.kq v ks a dh x;k nz O;eku
nz O;eku eks y ijek.kq
la [ ;k
8gO ___ ___ ___ ___ ___ ___

NA NA
mnkgj.k 16 g 1/2 eksy 2g 1/8 eksy
2 8

230 g Na 46 g

60 g Ca 1 eksy

20 g He 3 eksy

56 g N eksy

NA
12 g Mg
4

128 g S NA

3 NA
93 g P
2

Ans.

Gram
Relative Atomic Mass removed
Atomic Moles of No. of atoms Mole Atoms
S.No. Sample Mass for the from the
mass of sample of sample removed removed
element sample
sample

1. 8gO 16 ___ ___ ___ ___ ___ ___

NA 1 Mole NA
For Example 16 16 g Mole 2g 8
2 8
2. 230 g Na 23 23g 10 Mole 10 NA 46 g 2 Mole 2 NA

3. 60 g Ca 40 40 g 3/2 Mole 3/2 NA 40 g 1 Mole NA

4. 20 g He 4 4g 5 Mole 5 NA 12 g 3 Mole 3 NA

NA
5. 56 g N 14 14 g 4 Mole 4 NA 7g Mole
2
NA NA
6. 12 g Mg 24 24 g Mole 6g Mole
2 4

7. 128 g S 32 32 g 4 Mole 4 NA 32 g 1 Mole NA

3 NA
8. 93 g P 31 31 g 3 Mole 3 NA 46.5 g 3/2 Mole
2

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uew u s es a s
rRo d s fy, uew u s d k xz k e
uew u s d s mifLFkr uew u s ls gVk;k gVk;s x;s gVk;s x;s
S.No. uew u k v kis f {kd ijek.oh; ijek.oh;
eks y ijek.kq v ks a d h x;k nz O ;eku eks y ijek.kq
nz O ;eku nz O ;eku
la [ ;k
1. 8gO 16 ___ ___ ___ ___ ___ ___

For Ex a m ple 16 16 g eks y NA 2g 1 eks y NA


8
2 8
2. 230 g Na 23 23g 10 eksy 10 N A 46 g 2 eksy 2 NA

3. 60 g Ca 40 40 g 3/2 eksy 3/2 N A 40 g 1 eksy NA

4. 20 g He 4 4g 5 eksy 5 NA 12 g 3 eksy 3 NA

5. 56 g N 14 14 g eksy 4 NA 7g eksy NA
4
2
NA NA
6. 12 g Mg 24 24 g eksy 6g eksy
2 4

7. 128 g S 32 32 g 4 eksy 4 NA 32 g 1 eksy NA

3 NA
8. 93 g P 31 31 g 3 eksy 3 NA 46.5 g 3/2 eksy
2

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