LVN VN BN K THUT O LNG VIT NAM

LVN 243 : 2011

BNH CHUN TNG PHN

QUY TRNH KIM NH
Scaled Vessels - Methods and means of verification

H NI - 2011

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Li ni u:

LVN 243 : 2011 do Ban k thut o lng TC 8 o cc i lng cht lng

bin son, Vin o lng Vit Nam ngh, Tng cc Tiu chun o lng Cht
lng ban hnh.

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 VN BN K THUT O LNG VIT NAM LVN 243 : 2011

Bnh chun tng phn Quy trnh kim nh

Scaled vessels Methods and means of verification

1 Phm vi p dng
Vn bn k thut ny quy nh quy trnh kim nh bnh chun dung tch tng
phn, dung tch n 200 m3, cp chnh xc n 0,2.
2 Gii thch t ng
Cc t ng trong vn bn ny c hiu nh sau:
- Dung tch ca bnh chun tng phn (sau y c vit tt l BCTP) ng vi
vch chia bt k trn thang o l th tch nc m BCTP cha c ti nhit
20C khi nc c np ti vch chia .
Ghi ch: Np ti vch chia c ngha l mt cong ca nc trong ng thy ca
BCTP c iu chnh sao cho mt phng ngang i qua mp trn ca vch chia l
tip tuyn vi im thp nht ca mt cong khi quan st trong mt phng ny.
- Dung tch danh nh ca BCTP l dung tch ng vi vch chia ng vi tn ca
BCTP.
- Vch chia chnh l vch chia trn thang o c ghi gi tr dung tch danh nh
tng ng.
3 Cc php kim nh
Phi ln lt tin hnh cc php kim nh ghi trong bng 1.
Bng 1

Theo iu Ch kim nh
Tn php kim nh no ca Ban nh Bt
QTK u k thng
1. Kim tra bn ngoi 7.1
2. Kim tra k thut 7.2
3. Kim tra o lng 7.3


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LVN 243 : 2011

4 Phng tin kim nh

Phi s dng phng tin kim nh ghi trong bng 2.
Bng 2
p dng
Tn phng tin kim theo iu
TT Yu cu k thut v o lng c bn
nh mc ca
LVN
1 Chun o lng
(Sau y gi tt l chun)
1.1 B bnh chun kim loi - Dung tch bnh chun ln nht khng 7.3
nh hn 1/20 dung tch BCTP cn kim
nh
- khng m bo o U 0,05 %; (P
= 95 %; k = 2)
1.2 B bnh chun thy tinh - Dung tch (0,01 2) L 7.3
- Cp chnh xc A
1.3 Pipet k - Dung tch (1 25) mL 7.3
- Cp chnh xc A
2 Phng tin o s dng
cng vi chun
2.1 Nhit k - Phm vi o khng nh hn 50 C 5; 6; 7.3
- Gi tr chia khng ln hn 0,2 C
2.2 Nhit k - Phm vi o khng nh hn 50 C 5; 6; 7.3
- Gi tr chia khng ln hn 0,5 C
2.3 Thc cp - Gi tr chia 0,1 mm 7.2.2
2.4 Thc vch - Gi tr chia 1 mm 7.2.2
2.5 ng h bm giy - Gi tr chia 1 s 7.2; 7.3
3 Phng tin ph
3.1 Bnh cha, x, phu, ng
cao su hoc nha mm, ....

5 iu kin kim nh
Khi tin hnh kim nh phi m bo cc iu kin sau y:

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 LVN 243 : 2011

- Qu trnh kim nh phi c tin hnh nhit mi trng v nhit nc

t 15 C n 30 C.
- S thay i nhit ca nc trong qu trnh thc hin mt php o khng c
vt qu 0,5 C.
- S thay i ca nhit mi trng trong qu trnh kim nh khng c vt
qu 2 C.
- Nhit mi trng c xc nh vi chnh xc n 1 C, nhit ca nc
c xc nh vi chnh xc n 0,2 C.
6 Chun b kim nh
Trc khi tin hnh kim nh phi thc hin cc cng vic chun b sau y:
- BCTP v cc phng tin kim nh phi c n nh nhit khng t hn 12
gi trong khong (15 30) C.
- Dng nc sch v cht ty ra lm sch b mt bn trong ca BCTP.
- t bnh chun v BCTP vng chc v n nh trn b phng, iu chnh cho cn
bng. Bnh chun v BCTP phi c b tr sao cho cht lng khng b ng li
trn ng ng x.
7 Tin hnh kim nh
7.1 Kim tra bn ngoi
Phi kim tra bn ngoi theo cc yu cu sau y:
Quan st bng mt xc nh s ph hp ca BCTP vi cc yu cu quy nh
trong mc 1 v mc 2 ca ph lc 1
7.2 Kim tra k thut
Phi kim tra k thut theo cc yu cu sau y:
7.2.1 Kim tra kn
Np nc vo BCTP cn kim nh n vch chia ng vi gi tr dung tch ln
nht trn thang o v gi trong khong thi gian 30 pht. Nu trong thi gian
khng pht hin thy hin r r ti cc mi hn, ch ni, van v mc nc trn
thang o khng thay i th BCTP c coi l kn.
7.2.2 Kim tra ng thy
Dng thc cp kim tra s ph hp ca ng thy vi cc yu cu quy nh
trong mc 3.4 ca Ph lc 1.
7.2.3 Kim tra vch chia

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LVN 243 : 2011

Dng thc cp, thc vch v thc cun kim tra s ph hp ca cc vch
chia vi cc yu cu quy nh trong mc 3.5 ca Ph lc 1.
7.3 Kim tra o lng
Bnh chun c kim tra o lng theo trnh t, ni dung, phng php v yu
cu sau y:
7.3.1 Phng php kim tra
BCTP c kim tra o lng theo trnh t ni dung, phng php v yu cu
sau:
i vi kim nh ban u vic kim tra dung tch c tin hnh ti tt c cc
vch chia chnh.
i vi kim nh nh k v kim nh bt thng, vic kim tra dung tch c
tin hnh ti 3 vch chia chnh l vch chia ng vi tn gi ca bnh chun, vch
chia chnh thp nht v vch chia chnh nm gia thang o. i vi cc BCTP c
s vch chia chnh khng ln hn 3 th tin hnh kim tra dung tch ti tt c cc
vch chia chnh.
Vic kim tra dung tch ti cc vch chia chnh c th tin hnh theo 2 phng
php: x nc t bnh chun vo BCTP hoc x nc t BCTP vo bnh chun.
Ti mi vch chia chnh cn kim tra phi tin hnh xc nh dung tch t nht 4
ln.
7.3.1.1 Phng php x nc t chun vo BCTP
Trng t b mt bn trong ca BCTP bng nc sch, sau x ht nc ra v
ch cho nc chy thnh git trong thi gian 30 giy.
Np nc vo bnh chun n dung tch danh nh. o nhit tc ca nc ti
bnh chun.
X nc t bnh chun vo BCTP v ch cho nc chy thnh git trong thi gian
tng ng vi yu cu ca bnh chun.
Dng cc bnh chun c dung tch nh ph hp v pipet k thm nc
vo (hoc bt nc i) cho n khi mt cong ca nc trng vi vch chia cn
kim tra, o nhit tb ca nc ti BCTP.
7.3.1.2 Phng php x nc t BCTP vo chun
Trng t b mt bn trong ca cc bnh chun bng nc sch, sau x ht
nc ra v ch cho nc chy thnh git trong thi gian tng ng vi yu cu
ca bnh chun.
Trng t b mt bn trong ca BCTP bng nc sch, sau x ht nc ra v
ch cho nc chy thnh git trong thi gian 30 giy.

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 LVN 243 : 2011

Np nc vo BCTP n vch chia cn kim. o nhit tb ca nc ti BCTP.

X nc t BCTP vo bnh chun n dung tch danh nh. o nhit ca nc t
ti bnh chun.
Dng cc bnh chun c dung tch nh ph hp v pipet k thm nc
vo (hoc bt nc i) cho n khi mt cong ca nc trng vi mc dung tch
danh nh ca bnh chun.
*Ghi ch: phng php ny khng p dng khi chun l pipet kim loi (bnh chun
kim loi hng 1 kiu chy trn)
7.3.2 Xc nh dung tch ti vch chia chnh mi ln o
Dung tch ca BCTP ti vch chia chnh th k ln o th j V20j (L) quy v 20
C c xc nh theo cng thc:
V20k j = Vc [1 + c ( t c 20) b ( t b 20) + ( t b t c )]
(1)
Trong , Vc: dung tch ca bnh chun ti 20 C, L;
tc: nhit ca nc o c ti bnh chun, C;
tb: nhit ca nc o c ti BCTP, C;
c: h s dn n khi do nhit ca vt liu ch to bnh chun, (C)-1;
b: h s dn n khi do nhit ca vt liu ch to BCTP, (C)-1;
: h s dn n khi do nhit ca nc, (C)-1.
Trong trng hp s dng nhiu bnh chun (bnh chun c dung tch danh nh
nh hn dung tch ti vch chia chnh), cng thc (1) c p dng cho tng bnh
chun.
7.3.3 Xc nh dung tch ti vch chia chnh
Dung tch V20k (L) ca BCTP ti vch chia chnh th k quy v 20 C c xc nh
theo cng thc:
m
V20k j
j=1
V20k =
m (2)
Trong , m: s ln tin hnh php o.
lp li ca cc php o khng c vt qu 0,1 %
7.3.4 Xc nh sai s ti vch chia chnh
Sai s tng i quy i qdk (%) ca BCTP ti vch chia chnh th k c xc
nh theo cng thc:

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LVN 243 : 2011

k
Vvd V20k
qd
k
= 100%
Vdd (3)
Trong , Vvdk : gi tr dung tch ca BCTP ti vch chia th k, L;
Vdd: gi tr danh nh ca BCTP, L.
qd
k
Sai s tng k (%) ti vch chia chnh th k c du trng vi du ca v c gi
tr c xc nh theo cng thc:
Uk
k = qd
k
+ 100%
Vdd (4)
Trong , U k : khng m bo o m rng khi xc nh dung tch ca BCTP ti
vch chia th k, L;
Sai s tng ca BCTP ti mi vch chia chnh khng c vt qu 0,2%. Hiu sai
s tng ti 2 vch chia chnh bt k khng c vt qu 0,1%.
Kt qu o v tnh ton c ghi v trnh by theo mu cho trong Ph lc 3.

8 X l chung
8.1 Bnh chun tng phn t cc yu cu quy nh ca quy trnh ny th c:
- Cp giy chng nhn kim nh v / hoc ng du kim nh v / hoc dn tem
kim nh theo quy nh;
8.2 Nu bnh chun tng phn khng t mt trong cc yu cu quy nh ca quy
trnh kim nh ny th khng thc hin mc 8.1 v xa du kim nh c (nu c).
8.3 Chu k kim nh ca bnh chun tng phn l 2 nm.

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 Ph lc 1
CC YU CU K THUT V O LNG
I VI BNH CHUN TNG PHN

1. Vt liu
BCTP phi c lm bng kim loi khng g, c nt hoc van x di y, c thang
o, ng thu v c cu ch th v tr cn bng. Thnh v y ca BCTP phi vng chc
khng b bin dng trong qu trnh s dng, vn chuyn.
2. Hnh dng
2.1 Thng thng bnh chun kim loi c ch to theo hai dng c bn sau y :
2.1.1 Dng y cn c m t trn hnh 1.

Bin nhn hiu

ng thu Thang o

Ni v

Van x

Hnh 1. Bnh chun tng phn y cn

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2.1.2 Dng y phng c m t trn hnh 2

Bin nhn hiu

ng thu Thang o

Ni v
Vch "0"

Van x

Hnh 2. Bnh chun tng phn y phng

Ghi ch:
BCTP phi c bin nhn hiu, trn t nht phi th hin cc thng tin sau:
- Tn gi bnh chun;
- Kiu ch to;
- Dung tch danh nh 20 oC;
- Sai s ln nht cho php;
- Ni ch to;
- S v nm ch to;
- Vt liu ch to v h s gin n khi do nhit ca vt liu ch to.

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3 Kt cu
3.1 Nguyn tc chung
3.1.1 Kt cu bn trong BCTP phi m bo trnh c vic to thnh cc ti kh,
khng c vt li lm, khng c v tr ng cht lng, khng c cc khoang trng gy
thay i dung tch ca bnh chun.
3.1.2 BCTP phi c kt cu bn vng, khng b bin dng khi cha y v khi s
dng.
3.1.3 BCTP phi c kt cu ph hp m bo ng vng trn mt phng ngang, trc
ca bnh chun phi vung gc vi mt phng ngang.
3.1.4 BCTP phi c c cu ch th c cu ch th cn bng (thng l niv hoc qu
di).
3.2 Thang o
3.2.1 Thang o phi c ch to bng vt liu khng r, lin v c kt cu cng. B
mt thang o phi phng, cc vch chia phi r nt, d c.
3.2.2 Thang o phi c lp t theo phng tip tuyn vi mt trc hoc trc tip
ngay pha sau ng thu. Trng hp c lp t k bn ng thu th khong cch t
thang o ti ng thu khng c vt qu 5 mm. Nu thang o c lp t pha
sau ng thu th phi c hp bo v ng thu.
3.2.3 Thang o phi c v tr nim phong hoc ng du kim nh m bo khng th
tho d v dch chuyn thang o sau khi nim phong.
3.2.4 Thang o phi c im "0". Nu im "0" khng nm trn thang o m l van x
th phi quan st c pha sau van x. i vi mi thang o, vch "0" phi c ko
di ht b rng ca thang o.
3.2.5 n v ghi khc trn thang o i vi tt c cc loi BCTP phi c biu th
bng mL v / hoc L.
3.3 ng x
3.3.1 ng x c bt u t im thp nht ca BCTP v phi c nghing nht
nh m bo x ht cht lng.
3.3.2 Van x c lp t trn ng x phi l van ng nhanh v c v tr ng, m
c nh. Cui van x phi l khong trng hoc c thit b kim tra c th kim tra
bng mt pha sau van.
3.4 ng thy
ng thu phi c ng knh trong khng nh hn 15 mm, c hp bo v v c ni
vi y bnh chun qua ng ni sao cho c th tho ra thay th hoc bo dng m
khng lm nh hng n v tr ca thang o v dung tch ca BCTP.

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3.5 Vch chia
3.5.1 Cc vch chia phi c b rng nh nhau. B rng ca vch chia khng c ln
hn 0,6 mm v khng nh hn 0,4 mm.
3.5.2 Cc vch chia chnh phi c di khng nh hn 6 mm, cc vch chia ph phi
c di khng nh hn 3 mm.
3.5.3 Ti vch dung tch danh nh, phi khc cc vch chia ph ty vo mc ch s
dng nh sau:
- kim nh ng h nc: phi khc cc vch chia ph pha trn v pha di mt
khong ti thiu tng ng vi 5% dung tch danh nh.
- kim nh xi tc t: phi khc cc vch ph trn ton thang o, trong khong
tng ng vi 5% dung tch danh nh, gi tr cc vch chnh phi tng ng vi
0.2% dung tch danh nh . Cc khong cch gia hai vch chia lin tip khng c
nh hn 2 mm v khng c lch nhau qu 0,5 mm.
3.5.4 Gi tr chia ln nht cho php l 0,2 % dung tch danh nh.Trng hp thang
o c lp t pha trc ng thu, cc vch chia phi c bt u t pha c ng
thu.

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 Ph lc 2
C LNG KHNG M BO O
1. khng m bo o tng hp uc (L) c xc nh theo cng thc:

u c = u std
2
+ u 2A + u 2pg (7)

Trong :
ustd: khng m bo o ca dung tch chun, L;
uA: khng m bo o loi A, L;
upg: khng m bo o do nh hng ca phn gii, L.
1.1 khng m bo o ca chun
- c tng hp t giy chng nhn ca chun v cc h s quy i t nhit .
1.2 khng m bo o loi A
- Xc nh theo cng thc:
n
(Vi Vtb )2
uA = i =1
(8)
n (n 1)

Trong :
Vi : th tch V20 ca cc ln xc nh, L;
Vtb : th tch V20 trung bnh ca n ln xc nh, L;
1.3 khng m bo o do nh hng ca phn gii
a read d
u pg = (10)
ld

Trong :
aread : kh nng phn bit ca mt ngi, aread = 1/4 gi tr chia ca thang o;
d : gi tr chia ca thang o, L;
ld : chiu di chia ca thang o, mm;
2. khng m bo o m rng U k (L) c xc nh theo cng thc:
U k = k uc (11)
Trong :
k: h s ph, k = 2 ng vi xc sut tin cy 95%.

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 Ph lc 3

Tn c quan kim nh BIN BN KIM NH

....................... BNH CHUN TNG PHN
S:...............

Tn chun o lng: Bnh chun tng phn

Kiu: S :
C s sn xut: Nm sn xut:
c trng k thut:
- Dung tch danh nh Vd :
- Phm vi thang o : Gi tr chia :
- Cp chnh xc:
- Vt liu ch to : H s b :
Ni s dng:
Phng php thc hin:
Chun, thit b chnh c s dng:
iu kin mi trng:
Ngy thc hin:
a im thc hin:

KT QU KIM NH

1. Kim tra bn ngoi v kt cu: t Khng t

2. Kim tra k thut:
2.3 Kim tra kn : t Khng t
2.4 Kim tra ng thy : t Khng t
2.5 Kim tra vch chia : t Khng t
3. Kim tra o lng :
Kt qu o
Vch Ln o 1 Ln o 2 Ln o 3 Ln o 4
chia, L Vc, L tc, C tb, C Vc, L tc, C tb, C Vc, L tc, C tb, C Vc, L tc, C tb, C

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Kt qu tnh ton
Vch chia, L V20k , L Uk , L qd
k
,% k , % Kt lun

4. Kt lun:

Ngi sot li Kim nh vin

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