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SYLLABUS
B.Sc. Chemistry
(Part-I, II & III)
(Effective from the Academic Session 2016-2017)
Faculty of Science
UNIVERSITY OF KOTA
MBS Marg, KOTA (Rajasthan)-324 005
INDIA
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Bachelor of Science
CHEMISTRY
(Three Year Course)
SCHEME OF EXAMINATION
Page 2 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Bachelor of Science
CHEMISTRY
(Three Year Course)
Syllabus
Page 3 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 4 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 5 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 6 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
number, mean free path and collision diameter. Liquification of gases (based on
Joule-Thomson effect.)
Unit III Liquid state:
Intermolecular forces, structure of liquids (a qualitative description). Structural
differences between solids, liquids and gases.
Liquid Crystals: Difference between liquid crystal, solid and liquid. Classification,
structure of nematic and cholestric phases. Thermography and seven segment cell.
Colloidal State: Definition of colloids, classification of colloids. Solids in liquids
(sols): Properties, kinetic, optical and electrical, stability of colloids. Protective action,
Hardy-Schulze law, gold number. Liquids in liquids (emulsions): types of emulsions,
preparation, emulsifier. Liquids in solids (gels): classification, preparation and
properties, inhibition, general applications of colloids.
Unit IV Solid State:
Definition of space lattice, unit cell. Laws of crystallography (i) Law of constancy of
interfacial angles (ii) Law of rationality of indices (iii) Law of symmetry. Symmetry
elements in crystals. X-ray diffraction by crystals. Derivation of Bragg's equation
Determination of crystal structure of NaCl and CsCl (Laue's method and powder
method.)
Unit V Chemical Kinetics and Catalysis:
Chemical kinetics and its scope, rate of a reaction, factors influencing the rate of a
reaction: concentration, temperature,pressure, solvent, light, catalyst, Concentration
dependence of rates, mathematical characteristics of simple chemical reactions zero-
order, first order, second order, pseudo order, half life and mean life period.
Determination of the order of reaction: differential method; method of integration,
method of half life period and isolation method. Radioactive decay as a first order
phenomenon. Experimental methods of chemical kinetics: conductometric,
Potentiometric, optical methods, polarimetry and spectrophotometry.
Theories of chemical kinetics: effect of temperature on rate of reaction, Arrhenius
concept of activation energy. Simple collision theory based on hard sphere model,
transition state theory (equilibrium hypothesis). Expression for the rate constant based
on equilibrium constant and thermodynamic aspects. Catalysis, characteristics of
catalysed reactions, classification of catalysis, miscellaneous examples.
Books Suggested :
1. Principles of Physical Chemistry : B. R. Puri and L. R. Sharma
2. A Text Book of Physical Chemistry : A. S. Negi and S. C. Anand
3. Physical Chemistry, Pt. I & II : C. M. Gupta, J. K. Saxena and M. C. Purohit
4. Computers and Applications to Chemistry: Ramesh Kumari, Narosa Publishing House P. Ltd.
Distribution of Marks:
Inorganic Chemistry Experiment - 25
Organic Chemistry Experiment (Two experiments) - 20 (10+10)
Page 7 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Books suggested :
1. Practical Chemistry: Giri Bajpai and Pandey, S. Chand & Co. Ltd., New Delhi
Page 9 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Bachelor of Science
CHEMISTRY
(Three Year Course)
Syllabus
Page 10 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Books Suggested :
1. Text book of Quantitative Inorganic Analysis : A. I. Vogel (Chapter I, II and XXIII)
2. Text book of Quantitative Inorganic Analysis : I. M. Kothoff and E. R. Sandell
3. Concise Inorganic Chemistry : J. D. Lee
4. General Inorganic Chemistry : J. A. Duffy
5. Principle of Inorganic Chemistry : B. R. Puri and L. R. Sharma
6. Basic Inorganic Chemistry : Cotton and Wilkinson and Gaus, Willey
Page 11 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 12 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 13 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Distribution of Marks :
(i) Inorganic Chemistry Experiment (two experiments) - 25 (10+15)
(ii) Organic Chemistry Experiment - 15
(iii) Physical Chemistry Experiment - 15
(iv) Practical Record (for regular students only) - 10
(v) Viva-voce (for regular students) - 10
(vi) Viva-voce (for non-collegiate students) - 20
Page 14 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Inorganic Chemistry:
Two experiments-one from each section
Section-A 10 Marks
Calibration of fractional weights, pipettes and burettes. preparation of standard
solution. dilution-0.1M to 0.001M solutions.
Section-B 15 Marks
Quantitative Analysis:
Volumetric analysis
Determination of acetic acid in commercial vinegar using naOH
Determination of Alkali content in anta-acid tablet using HCl.
Estimation of calcium content in chalk as calcium oxalate by permangano-
metry.
Estimation of hardness of water by EDTA.
Estimation of ferrous and ferric by dichromate method.
Estimation of copper using thiosulphate.
Gravimetric analysis
Analysis of Cu as CuSCN and Ni as Nickel dimethylglyoxime.
Page 15 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Thermochemistry:
To determine the solubilies of benzoic acid at different temperatures and to
determine H of the dissolution process.
To detrermine the enthalpy of neutralization of a weak acid weak base verses
strong acid and strong base and determine the enthalpy of ionisation of the
weak acid/weak base.
To determine the enthalpy of solution of solid calcium chloride and calculate
the lattice energy of calcium chloride from its enthalpy data using born haber
cycle.
Books Suggested:
1. Practical Chemistry: Giri Bajpai and Pandey, S. Chand & Co. Ltd., New Delhi
2. Practical Chemistry (Hindi Ed.): Suresh Ameta & P. B. Punjabi, Himanshu Publication
Page 16 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Bachelor of Science
CHEMISTRY
(Three Year Course)
Syllabus
Page 17 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 18 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Books Suggested :
1. Organic Chemistry, Morrison and Boyd, Prentice Hall.
2. Organic Chemistry, L.G. Wade Jr. Prentice Hall.
3. Fundamentals of Organic Chemistry, Solomons, John Wiley.
4. Organic Chemistry Vol. I, II, III S.M. Mukerji, S.P. Singh and RP. Kappor, Wiley Eastern Ltd. (New
Age International)
Page 19 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Unit-III Spectroscopy:
Introduction, electromagnetic radiation, spectrum, basic features of different
spectrometers, statement of the Born-Openheimer approximation, degrees of freedom.
Rotational Spectrum: Diatomic molecules, energy levels of a rigid rotator (semi-
classical principles), selection rules, spectral intensity, using population distribution
Page 20 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Unit-IV Photochemistry:
Interaction of radiation with matter, difference between thermal and photochemical
processes. Laws of photochemistry: Grothus-Drapper law, Stark-Einstein law,
Jablonski diagram depicting various processes occurring in the exited sate. qualitative
description of fluorescence, phosphorescence, non-radiative processes (internal
conversion, intersystem crossing), quantum yield, photosensitized reactions-energy
transfer processes (simple examples).
Books Sugegsted :
1. Physical Chemistry, G.M. Barrow. International Student Edition, McGraw Hill.
2. Basic Programming with Application, V.K. Jain. Tata McGraw Hill.
3. Computers and Common Sense. R Hunt and Shelly, Prentice Hall.
4. University General Chemistry, C.N.R Rao, Mac Millan.
5. Physical Chemistry, RA. Alberty, Wiley Eastern Ltd.
6. The elements of Physical Chemistry, P.W. Atkins, Oxford.
7. Physical Chemistry Through problems, S.K. Dogra and S. Dogra, Wiley Eastern Ltd.
8. Principles of Physical Chemistry : B. R. Puri Sharma and M. S. Pathania
9. A Text Book of Physical Chemistry : A. S. Negi and S. C. Anand
10. A Text Book of Physical Chemistry : Kundu and Jain
Page 21 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Distribution of Marks :
(i) Inorganic Chemistry Experiment (two experiments) - 20 (10+10)
(ii) Organic Chemistry Experiment (two experiments) - 20 (10+10)
(iii) Physical Chemistry Experiment - 15
(iv) Practical Record (for regular students only) - 10
(v) Viva-voce (for regular students) - 10
(vi) Viva-voce (for non-collegiate students) - 20
Inorganic Chemistry
Synthesis and Analysis
Preparation of sodium trioxalato ferrate (III). Na3[Fe(C2O4)3] and determination
of its composition by permagnomotry.
Preparation of Ni-DMG complex [Ni(DMG)2].
Preparation of copper tetraammine complex [Cu(NH3)3]SO4.
Preparation of cis-and trans-bisoxalatodiaquachromate (III) ion.
Instrumentation
Colorimetry - Job's method and Mole-ratio method.
Adulteration - Food stuff.
Effluent analysis - water analysis.
Solvent Extraction - Separation and estimation of Mg(II) and Fe(II)
Ion Exchange Method - Separation and estimation of Mg(II) and Zn(II)
Volumetric Analysis
Iodimetric & Iodimetric titrations.
Organic Chemistry
Two experiments one from each section:
Section-A
Laboratory Techniques:
(i) Steam Distillation:
Naphthalene from its suspension in water.
Clove oil from Clove
Separation of o-and p-nitrophenols
(ii) Column Chromatography:
Separation of fluoressein and methylene blue.
Separation of leaf pigments from spinach leaves.
Resolution of racemic mixture of (Z)-mandelic acid.
Qualitative Analysis:
Analysis of an organic mixture containing two solid components using
water, NaHCO3, NaOH for separation and preparation of suitable
derivatives.
Section-B
Synthesis of Organic Compounds
Acetylation: Salicylic acid, aniline, glucose and hydroquinone.
Benzoylation: Aniline and phenol.
Page 22 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Aliphatic Electrophilic Substitution: Preparation of Iodoform from
ethanol and acetone.
Aromatic Electrophilic Substitution:
o Nitration:
Preparation of m-dinitrobenzene,
Preparation of p-nitroacetanilide
o Halogenation :
Preparation of p-bromoacetanilide
Preparation of 2,4,6-tribromophenol.
Diazotization/coupling: Preparation of methyl orange and methyl
red.
Oxidation: Preparation of benzoic acid from toulene.
Reduction: Preparation of aniline from nitrobenzene and m-
nitroaniline from m-dinitrobenzene.
Stereo-chemical study of Organic Compounds via Models
R and S configuration of optical isomers.
E and Z configuration of geometrical isomers.
Conformational analysis of cyclohexanes and substituted
cyc1ohexanes.
Section-C
Organic estimation: Amino group, phenolic group, carboxylic acid group
and glucose.
Physical Chemistry
Electrochemistry
To determine the strength of the given acid condcutometrically using standard
alkali solution.
To determine the solubility and solubility product of a sparingly soluble
electrolyte conductometrically.
To study the saponification of ethyl acetate conductometrically.
To determine the ionization constant of a weak acid conductometrically.
To titrate potentiometrically the given ferrous ammonium sulphate solution
using KMnO4 / K2Cr2O7 as titmate and calculate the redox potential of
Fe2+/Fe3+ system on the hydrogen scale.
Refractometry and Polarimetry
To verify law of refraction of mixtures for ego of glycerol and water) using
Abe's refractometer.
To determine the specific rotation of a given optically active compound.
Molecular Weight Determination
Determination of molecular weight of a non-volatile solute by Rast method /
Beckmann freezing point method.
Determination of the apparent degree of dissociation of an electrolyte (e.g.
NaCl) in aqueous solution at different concentrations by ebulliscopy.
Colorimetry
To verify Beer-Lambert law KMnO4 / K2Cr2O7 and determined the
concentration of the given solution of the substance.
Page 23 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
2. Vogel's Text Book of Quantitative Inorganic Analysis (revised), J. Bassentt. RC. Deney G.H. Jeffery and J.
Mendham. ELBS.
3. Standard methods of chemical Analysis. W.W. Scott. The technical Press.
4. Experimental Inorganic Chemistry, W.G. Palmer, Cambridge.
5. Handbook of Preparative Inorganic Chemistry. Vol I & II, Braver, Academic Press.
6. Inorganic Synthesis, McGraw Hill.
7. Experimental Organic Vol I & II, P.R Singh, D.S. Gupta and K.S. Bajpai, Tata McGraw Hill.
8. Laboratory manual in Organic Chemistry, RK. Bansal, Wiley Eastern.
9. Vogel's Text Book of Practical Organic Chemistry, B.S. Furniss, A.J. Hannaford, V.Rogers,
P.W.G. Smith and A.R Tatchell, ELBS.
10. Experiments in General Chemistry, C.N.R Rao and U.c. Agarwal, East-West Press.
11. Experiments in Physical Chemistry, RC. Das and B.Behra, Tata McGraw Hill.
12. Advanced Experimental Chemistry, Vol I Physical, J.N. Gurtu and R Kappor, S Chand & Co.
13. Selected Experiments in Physical Chemistry, N.G. Mukerjee, J.N. Ghose & Sons.
14. Experiments in Physical Chemistry, J.C. Ghosh, Bharati Bhavan.
15. Practical Chemistry: Giri Bajpai and Pandey, S. Chand & Co. Ltd., New Delhi
2. Separation and estimation ofMg (II) and Fe (II) by solvent extraction method.
Or
Separation and estimation of Mg (II) and Fe(II) by ion exchange method.
Page 24 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 25 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 26 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 27 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 28 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 29 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 30 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 31 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 32 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 33 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 34 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 35 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 36 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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Page 37 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 38 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
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rki ij fuHkZjrkA fdpksZQ lehdj.kA
bdkbZ&II "ekxfrdh&II%
"ekxfrdh dk f}rh; fu;e% fu;e dh vko';drk] fu;e ds fofHkUu dFku] dkuksZV
p ,oa mldh n{krkA dkuksZV izes;] rkie dk "ekxfrd iSekukA
,UVkWih dh ladYiuk% ,UVkWih voLFkk Qyu ds :i es]a V o T ds Qyu ds :i esas
,UVkWih] P o T ds Qyu ds :i esas ,UVkWih] HkkSfrd voLFkk ifjorZu esa ,UVkih
ifjorZu] Dykfl;l vlerk] Lor% ,oa lkE; voLFkk fu/kkZj.k esa ,UVkih dh HkwfedkA
vkn'kZ xSlksa ,oa xSlks ds feJ.k esas ,UVWkih ifjorZuA
"ekxfrdh dk r`rh; fu;e% usULVZ "ek fl)kUr] vo'ks"k ,UVkWih dFku ,oa /kkj.kk]
"ek /kkfjrk vkdM+ksa ls fujis{k ,UVkWih dh x.kukA fxCt ,oa gsYegksYV~t Qyu% fxCt
Qyu (G) o gsYegksYV~t Qyu (A) "ekxfrdh jkf'k;a ds :i esAas "ekxfrdh lkE;
,oa ifjorZu Lor% ize esa A o G dh Hkwfedk;sa o ,UVkWih dh rqyuk esa mlds
ykHkA P, V ,oa T es ifjorZu ds lkFk G o A esa ifjorZuA
bdkbZ&III jklk;fud lkE;%
lkE; fLFkjkad ,oa eqDr tkZA nzO;kuqikrh f;k fu;e dk "ek xfrdh; fuxeuA yk
'ksrSfy;s dk fu;e] lerkih vfHkf;k ,oa levkirfud vfHkf;k] levkirfud&DysisjkWu
,oa Dykfl;l&DysisjkWu lehdj.k] mi;ksfxrk A
izkoLFkk lkE;% izkoLFkk] ?kVd ,oa Lora= dksfV inksa ds dFku ,oa muds vFkZA fxCt
izkoLFkk fu;e dk fuxeuA ,d ?kVd ra=&ty] CO2 ,oa S ra=ks ds fy, izkoLFkk
lkE;A f}?kVd ra=&Bksl&o] ljy ;wVsfDVd Bi-Cd, Pb-Ag ra=] lhlk fojtrhdj.kA
Bksl foyiu&;fxd fuekZ.k] lokZaxle xyukad (Mg-Zn) ,oa vlokZax xyukad (NaCl-
H2O) ij ;kSfxdksa dk cuukA fgehdj.k feJ.k%,lhVksu&'kq"d cQZA o&o feJ.k&vkn'kZ
o feJ.k] jky ,oa gsujh dk fu;e] vukn'kZ ra=&fLFkj DokFkukadh&HCl-H2O ,oa
,FksukWy&ty ra=A vkaf'kd feJ.kh; nzo&QhukWy&tyA mPp ,oa fuEu lafoysi rki]
Page 39 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
vdkcZfud jlk;u%
Hkkx&v
fHkUUkkRed ckaVka]s C;wjsVksa o fiisVksa dk va'kkduA ekud foy;uksa dk cukukA 0-1M
foy;uksa dk 0-001M rd ruqdj.k djukA
Hkkx&c
ek=kkRed fo'ys"k.k%
vk;ru&ferh; fo'ys"k.k%
(v) NaOH ds iz;ksx }kjk O;kikfjd fljds esa ,lhfVd vEy dk fu/kkZj.k A
(c HCl ds iz;ksx }kjk ,UVk&,flM VscysV esa {kkj dk fu/kkZj.k A
(l ijesaxuksehVjh }kjk pkd esa mifLFkr dsfY'k;e va'k dk dsfY'k;e vkWDtssysV
ds :i esa fu/kkZj.k A
(n ty dh dBksjrk dk EDTA }kjk ekiu A
(bZ MkbksesV fof/k }kjk QSjl ,oa QSfjd ds vk;u dk ekiu A
(Q Fkk;kslYQsV fof/k }kjk dkWij dk ekiuA
HkkjkRed fo'ys"k.k
Cu dk CuSCN ds :i esa o Ni dk fufdy MkbZefs FkyXykbvkWDthe ds :i esa
fo'ys"k.kA
dkcZfud jlk;u%
iz;ksx'kkyk izkfof/k;k%
v iryh ijr o.kZys[kdh% Rf eku dk ekiu ,oa dkcZfud ;ksfxd dks igpkuukA
gjh ifRk;ksa ds o.kkZda ksa dk i`FkDdj.k (ikyd dh ifk;ksa dks Hkh dke esa ys
ldrs gaSa A
Vkywbu ,oa gYds isVkfs y;e ds (40%60 feJ.k dks iz;ksx esa ysdj ,slhVksu]
2&C;wVsukWu] gsDlsu&2&vkWu ,oa gsDlsu&3&vWku ds 2]4&MkbZukbVksQsfuygkbMstksu
O;qRiUukas dks cukuk o mudk i`FkDdj.k djukA
lkbDyksgsDlsu ,oa ,fFky,lhVsV 8-5%1-5ds feJ.k }kjk jatdks ds feJ.k dk
i`FkDdj.kA
c dkxt o.kZys[kdh% vkjksgh ,oa orqZy (o`Rrkdkj Rf eku dk ekiu ,oa
dkcZfud ;ksfxdkas dk fo'ys"k.k A
Qsfuy ,ykfuu ,oa Xykblhu] ,ykfuu ,oa ,LikfVZd vEy] Y;wlhu ,oa XywVSfed
vEy ds feJ.kksa dk i`FkDdj.kAfuugkbfMu&fNM+dko vfHkdeZdA
fNM+dko vfHkdeZd fuugkbfMu }kjk n&C;wVsukWy%,lhfVdvEy%ty (4%1%5 ds
feJ.k ds mi;ksx ls D,L&,ykfuu] Xykblhu ,oa L-Y;wlhu dks feJ.kksa ls
i`FkDdj.kA
Page 41 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
HkkSfrd jlk;u%
lae.k rki%
fn;s gq, inkFkZ (mnkgj.kkFkZ MnCl2, 4H2O / Sr Br2.2H2O dk rkifefr @
Mkbyksfefr (Dialometric) fof/k }kjk lae.k rki dk fu/kkZj.kA
izkoLFkk lkE;%
nks vkaf'kd foys; foy;ukas (mnkgj.kkFkZ QhukWy&ty ra= ds kafrd foyiu rki
ij foys; mnkgj.kkFkZ NaCl, lDlhfud vEy ds izHkko dk v/;;uA
'khryu o fof/k }kjk f}?kVd ra= (mnkgj.kkFkZ MkbZQfs uy,sehu&csUtksQhukWu ds
voLFkk vkjs[k dks cukuk A
"ek jlk;u%
fofHkUu rkiksa ij cSUtkWbd vEy dk fu/kkZj.k ,oa ?kqyu ize }kjk H dk
fu/kkZj.k A
nqcZy vEy@{kkj ds izcy {kkj@izcy vEyksa }kjk mnklhuhdj.k dh ,UFkSYih dk
ekiu ,oa nqcZy vEy@nqcy Z {kkj ds vk;uhdj.k dh ,UFkSYih dk ekiuA
Bksl dSfYl;e DyksjkbM ds foy;u dh ,UFkSYih dk ekiu ,oa cksu&Z gscj p
ds }kjk ,UFkSYih vkdM+ksa dh lgk;rk ls dSfYl;e DyksjkbM dh tkyd tkZ
dh x.kukA
Page 42 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
foKku Lukrd
jlk;u'kkL=
f=o"khZ; ikB~;e
ikB~;e
Page 43 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 44 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 45 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
la'ys"k.k] Bksl izkoLFkk isIVkbM la'ys"k.kA izkVs hu o isIVkbM dh lajpuk] izksVhu lajpuk
ds Lrj] izksVhu dk fod`rhdj.k o iqu% LoHkkohdj.kA
U;wfDyd vEy% ifjp;] U;wfDyd vEy ds ?kVdA jkbcksU;wfDyvkslkbM o
jkcksU;wfDyvkVkbMA Mh-,u-, dh f}gsyhdy lajpukA
olk] rsy o viektZd% izkd`frd olk] [kkus ;ksX; vkSj vkS|ksfxd olk dk
okuLifrd mn~xe] lkekU; olh; vEy] fXyljkWbM~l] vlar`Ir olkvksa dk gkbMkstuhdj.kA
lkcquhdj.k eku] vk;ksMhu eku] vEy eku] lkcqu] la'ysf"kr viektZd] ,sydkby vkSj
,sfjy lYQksusV~lA
la'ysf"kr cgqyd% ;ksxkRed vFkok Ja[kyk&o`f) cgqydhdj.kA eqDr&ewyd foukby
cgqyhdj.k] vk;fud foukby cgqyhdj.k] thxyj&ukVk cgqydhdj.k ,oa foukby cgqydA
la?kuu vFkok in&o`f) cgqydhdj.kA ikfy,LVj] ikfy,ekbM] Qhuksy&QkWeYZs MhgkbM jsftu
vkSj ;wfj;k&QkWesZYMhgkbM jsftu] ,iksDlh jsthu vkSj iksyh;wjhFksuA izkd`frd ,oa la'ysf"kr
jcjA
la'ysf"kr jatd% jax ,oa la?kVu bysDVkfud vo/kkj.kk] jatdksa dk oxhZdj.kA eSfFky
vkSjsUt] dkaxksa jsM] eSysdkbV xzhu] fdzLVy ok;ysV] fQukWYQ~Fksyhu] Q~yv q ksfjlhu]
,syhtsfju vkSj bfUMxks dk jlk;u ,oa la'ys"k.kA
Page 46 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
bdkbZ&III LisDVferh%
ifjp;] fo|qrpqEcdh; fofdj.k] LisDVe] LisDVeekih ds vk/kkjHkwr fl)kUr]
cksu&Z vksiughej lUuhdVe] LorU=rk dh dksfV;kaA
?kw.kZu LisDVe% f}ijek.kqd v.kq] n`<&?kw.kZd ds mtkZ Lrj vZ}izkphu fl}kar] oj.k
fu;e] LisDVeh js[kk dh rhozrk] v.kqvksa ds ?kuRo forj.k vk/kkj esDlosy&clsYV~teku
forj.k ij ca/k&yEckbZ dk fu/kkZj.k] vn`<&?kw.kZd dh xq.kkRed foospukA leLFkkfud
izHkkoA
dEiu vojDr LisDVe% lkekU; xfrd gkeksfZ ud nksfy= ds mtkZ Lrj] oj.k fu;e]
'kq) dEiUu LisDVe] rhozrk] cy fu;rkad Kkr djuk ,oa ca/k fu;rkad o ca/k mtkZ
esa lEcU/k] LisDVe ij vizlaoknh ,oa leLFkkfud izHkko] fofHkUu fdz;kRed lewgksa dh
dEiUu vko`fr;kaA
jeu LisDVe% ?kzq.kork laadYiuk] f)ijek.kqd v.kq ds 'kq) ?kw.kZu ,oa 'kq) dEiUu jeu
LisDVk] oj.k fu;eA
bysDVkfud LisDVe% cU/kh o frcU/kh vk.kfod d{kdksa ds fy;s fLFkfrt mtkZ
ladYiuk] oj.k fu;e] asd&dkWUMu fl)kUr] , , n vkf.od d{kdksa ds mtkZ Lrjksa
rFkk buds lae.k dk fooj.kA
bdkbZ&IV dk'k&jlk;u%
fofdj.k dk inkFkZ ls la;ksx] m"ek&mtkZ vfHkfdz;k o izdk'k jklk;fud vfHkfdz;k esa
varj] izdk'k&jlklu ds fu;e] xzkFs kl&Mis j dk fu;e] LVkdZ&vkbZUlVkbu fu;e] mksftr
voLFkk esa fofHkUu ea d n'kkZrs gq, tscykWULdZks vkjs[k] izfrnhfIr] LQqjnhfIr]
fofdj.k jfgr lae.k mRltZu] vkUrfjd :ikUrj.k] vUrra= ya?ku] DokaVe yfC/k]
izdk'k&laosnu vfHkf;k,s&a izdk'k jklk;fud vfHkf;kvksa esa tkZ dk LFkkukUrj.kA
Page 47 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
vad foHkktu%
vdkcZfud jlk;u iz;ksx nks iz;ksx & 20 10$10
dkcZfud jlk;u iz;ksx nks iz;ksx & 20 10$10
HkkSfrd jlk;u iz;ksx & 15
izk;ksfxd dk;Z iqfLrdk dsoy fu;fer fo|kfFkZ;a ds fy, & 10
ekSf[kd fu;fer fo|kfFkZ;a ds fy, & 10
ekSf[kd Lo;aikBh fo|kfFkZ;a ds fy, & 20
vdkcZfud jlk;u
la'ys"k.k rFkk fo'ys"k.k%
lksfM;e VkbZ vkDlsysVks QsjVs dk cukuk o mldk la?kVu ijeSXuksfefr }kjk
Kkr djukA
fudy MkbesfFkyXykvkWfDle lady q [Ni(DMG)2] dk cukukA
dkWij VsVk,sEehu lady
q [Cu(NH3)4]SO4 dk cukukA
lei{k rFkk foi{k iksVfs 'k;e MkbZvkWDlsyVs ksMkb,Dok ksesV (III) dk cukuk
;a=hdj.k%
o.kZferh% tksc dh fof/k o eksy&vuqikr fof/k
[kk| inkFkksZ esa feykoV
cfg%L=ko fo'ys"k.k ty fo'ys"k.k
foyk;d fu"d"k.Zk Mg(II) vkSj Fe(II) dk i`FkDdj.k rFkk vkadyu
vk;u fofu;e fof/k Mg(II) vkSj Zn(II) dk i`FkDdj.k rFkk vkadyu
Page 48 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
vk;rukRed fo'ys"k.k%
vk;Mferh ,oa vk;Mhferh vuqekiu
dkcZfud jlk;u
Hkkx&v o c izR;sd esa ls ,d&,d iz;ksx
Hkkx&v
iz;ksx'kkyk rduhd%
Hkkih; vklou%
usQ~Fkyhu dk blds tyh; fuyEcu esa lsA
ykSax ls ykSax dk rsy
P&ukbVksQhukWy dk i`FkDdj.k
LraHk o.kZysf[kdh%
esfFkyhu Cyw rFkk Qyqvksjkslhu dk i`FkDdj.k
gjh ifRr;ksa ikyd esa mifLFkr jatd dk i`FkDdj.k
eS.Msfyd vEy ls jslhfed feJ.k dk fo;kstu
xq.kkRed fo'ys"k.k%
f}?kVd dkcZfud feJ.k dk fo'ys"k.kA ikuh] NaHCO3 vkSj NaOH dks dke esa
ysrs gq, i`FkDdj.k mi;qDr O;qRiUu cukukA
Hkkx&c
dkcZfud ;kSfxdksa dk la'ys"k.k
,slhfVyhdj.k% lSfyflfyd vEy] ,sfuyhu] Xywdkst vkSj gkbMkD
s ohuksuA
csUtks;yhdj.k% ,sfuyhu vkSj fQukWyA
,sfyQSfVd bysDVku Lusgh izfrLFkkiu] ,sFkskuksy vkSj ,lhVksu ls
vk;ksMksQkeZ cukukA
,sjksesfjd bysDVkuLusgh izfrLFkkiu
o ukbVhdj.k
MkbukVkscsUthu dk cukuk
ukbVks,slhVSfuykbM dk cukuk
o gSykstuhdj.k
p-czkseks,slhVSfuykbM dk cukuk
2]4]6&VkbczkseksQhukWy dk cukuk
Mkb,tksVhdj.k @ ;qXeu% esfFky vkWjUs t vkSj esfFky jsM dk cukuk
vkDlhdj.k% csUtksbd vEy dk Vkywbu ls cukuk
vip;u% ,sfuyhu dk ukbVkcs Us thu ls cukuk
ekWMy }kjk dkcZfud ;kSfxdksa dk f=foejklk;fud v/;;u
izdk'kh; leko;fo;ksa dk R vkSj S foU;kl
Page 49 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Hkkx&l
dkcZfud vkadyu% ,ehuks lewg] fQuksfyd lewg] dkjcksDlkbfyd ,flM lewg
,oa XywdkstA
HkkSfrd jlk;u%
fo|qRr jlk;u%&
pkydrk ewyd fof/k }kjk vKkr vEy foy;u dh lkUnzrk ekud ,ydyh
foy;u dh lgk;rk ls Kkr djukA
pkydrkekih }kjk fn;s x;s vEy foys; yo.k dh foys;rk rFkk foys;rk
xq.kkad Kkr djukA
,fFky ,slhVsV dk lkcquhdj.k dk pkydrkekih; fof/k ls v/;;u
pkydrkferh; fof/k }kjk nqcy Z vEy dk fo;kstu fLFkjkad fu/kkZfjr djuk
foHkoferh; vuqekiu }kjk vKkr QSfjd veksfu;e lYQsV foy;u dh
lkUnzrk
ekud KMnO4/K2Cr2O7 }kjk Kkr djuk rFkk gkbMkstu ry ij Fe+2/Fe+3
ds jsMkWDl foHko dh x.kuk djukA
viorZukadekih ,oa ?kzqo.kekih
,sch jsQsDVksehVj }kjk nks nzoksa fXyljksy o ty dk foy;u ds feJ.k
viorZukad fu;e dks fl) djukA
fn;s x, izdk'kh; lf; ;kSfxd dk fof'k"V ?kw.kZu Kkr djukA
v.kqHkkj fu/kkZj.k%
jk"V fof/k@ csdeku fgekad voueu fof/k ls vok"I'khy ;kSfxd dk v.kqHkkj
Kkr djukA
DoFkukadfefr }kjk fofHkUu lkUnzrkvksa ij fdlh oS|rq vi?kV~; (NaCl) dk
ty esa fo;kstu dh ek=k Kkr djuk
o.kZfefr
fc;j ySEcVZ fu;e dk lR;kiu KMnO4/K2Cr2O7 vkSj fn;s x, inkFkZ ds
fofy;u dh lkUnzrk Kkr djukA
Page 50 of 51
Syllabus: B.Sc. (Part-I, II & III) Chemistry
University of Kota, Kota (Rajasthan)
Page 51 of 51