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MATERIAL SAFETY DATA SHEET

PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : NALFLEET(R) 9-303

APPLICATION : FUEL OIL STABILIZER FUEL OIL STABILIZER

COMPANY IDENTIFICATION : NALCO EUROPE B.V.


Postbus 627
2300 AP Leiden, The Netherlands

EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers.

Date issued : 04.12.2007


Version Number : 2.4

COMPANY CONTACT TELEPHONE NUMBERS.

NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO AB (SE) +46 (0)8-50074000 NALCO POLSKA Sp.z.o.o. (PL) PRZEMYSLOWA 55
PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
e-mail: office@nalco.pl
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO POLSKA Sp.z.o.o. (PL) GZEGZOLKI 4
02-804 WARSZAWA
TEL: +48(0)22 648 02 25
FAX: +48 (0)22 644 79 38
NALCO APPLIED SERVICES OF +31 (0)73 6456980 NALCO PORTUGUESA LDA. (P) +351 214130996
EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 NTD S.r.l (IT) +39 (0) 313351325
NALCO DANMARK A/S +45-48195800 CHEMIA BRUGG AG (CH) +41 (0)56 4606260
NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 OEKOPHIL AG (CH) +41 (0)41 760 2220
NALCO ESPAOLA S.A. (E) +34 93-4095555 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 ZAO Nalco (RU) +7 (0)495 980 72 80
NALCO FRANCE SAS +33 (0)3 20 11 70 00 NALCO STERREICH Ges.m.b.H. + 43(0)1 27026350
(A)
NALCO HELLAS S.A. (GR) +30 210 238 9620 First Distributor: Nalco Czechia s.r.o. Stankova 882/2,CZ-149 00
(CZ) Praha 4,Czech Republic,+420
(0)2 679 123 50
NALCO ITALIANA S.R.L.(I) +39 06-542971 Local Support: Nalco Hungary Kft. +36 (0)1 471 91 81
(HU)
NALCO LIMITED +44 (0)1606 74488 Local Support: Nalco sterreich +385 (0)1 377 95 21
Ges.m.b.H., Representation Office
Predstavnistvo Zagreb (HR)
NALCO NETHERLANDS B.V. +31 (0)13-5952200 Local Support: Nalco sterreich +40 (0) 21 224 17 93
Ges.m.b.H. Representation Office
ROMANIA (RO)

For Product Safety information please contact Jacqueline Bland, e-mail EUProductSafety@nalco.com

2. HAZARDS IDENTIFICATION

HAZARD CLASSIFICATION :

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

Causes burns. Limited evidence of a carcinogenic effect. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness.

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

HUMAN HEALTH HAZARDS - ACUTE :

INHALATION :
Irritating, in high concentrations, to the eyes, nose, throat and lungs. Product mist or vapors may cause
headache, nausea, vomiting, drowsiness, stupor or unconsciousness. Can cause central nervous system
depression.

SKIN CONTACT :
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid
administered.

EYE CONTACT :
Corrosive. Will cause eye burns and permanent tissue damage.

INGESTION :
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. May cause
nausea and vomiting. Can cause central nervous system depression.

HUMAN HEALTH HAZARDS - CHRONIC :


This product contains naphthalene. The International Agency for Research on Cancer (IARC) has evaluated
naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in
experimental animals and inadequate evidence in humans).

ENVIRONMENTAL HAZARDS :
Keep out of waterways. This product may pose a risk to the aquatic ecosystem if released.

PHYSICAL AND CHEMICAL HAZARDS :


Combustible.

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.

Hazardous Substance(s) EINECS / CAS NO SYMBOL R-PHRASES / % (w/w)


ELINCS NO NOTAS
Amine Substituted Resin Proprietary Proprietary Xi R36 30 - 60
Heavy Aromatic Naphtha 265-198-5 64742-94-5 Xn, N R51/53, R65, 10 - 30
R66, R67
1-(2-Hydroxyethyl)-2-Tall Oil-2- 263-171-2 61791-39-7 C R34 10 - 30
Imidazoline
Naphthalene 202-049-5 91-20-3 Xn, N R22, R40, 1- 5
R50/53
1,2,4-Trimethylbenzene 202-436-9 95-63-6 Xn, N R10, R20, 1- 5
R36/37/38,
R51/53

Refer to Section 16 for descriptions of relevant risk phrases and Notas.

4. FIRST AID MEASURES

INHALATION :
Get medical attention. Remove to fresh air, treat symptomatically.

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

SKIN CONTACT :
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large
splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with
plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.

EYE CONTACT :
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately
flush eye with water for at least 15 minutes while holding eyelids open.

INGESTION :
Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to
drink.

NOTE TO PHYSICIAN :
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of
the patient, the physician's judgement should be used to control symptoms and clinical condition.

5. FIRE FIGHTING MEASURES

FLASH POINT : 66.1 C PMCC

EXTINGUISHING MEDIA :
Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use
water spray or fog, thoroughly drenching the burning material.
Water mist may be used to cool closed containers.

UNSUITABLE EXTINGUISHING MEDIA :


Do not use water unless flooding amounts are available.

FIRE AND EXPLOSION HAZARD :


Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may
contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under
fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :


In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS :
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by
trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.)
readily available. Notify appropriate government, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP :


SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches
or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13
(Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS :
Prevent material from entering sewers or waterways. This product may pose a risk to the aquatic ecosystem if
released.

7. HANDLING AND STORAGE

HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labeled. Do not use, store, spill or pour near heat, sparks
or open flame.

STORAGE CONDITIONS :
Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of
ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be
grounded to avoid electrical charges. Store separately from oxidizers.

SUITABLE CONSTRUCTION MATERIAL :


Teflon, Aluminum, Mild steel, Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, Hastelloy C-276,
Plexiglass, PTFE, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is
tested prior to use.

UNSUITABLE CONSTRUCTION MATERIAL :


Copper, Neoprene, Ethylene propylene, Polypropylene, Polyethylene, Kalrez, EPDM, Alfax, Brass, PVC, Buna-
N, HDPE (high density polyethylene), Natural rubber, Polyurethane, Hypalon, Viton

SPECIFIC USE(S) :
FUEL OIL STABILIZER
FUEL OIL STABILIZER

For specific dosages and customized applications please contact your representative.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.

Country/Source Substance(s) Category: ppm mg/m3


____
Manufacturer's Heavy Aromatic Naphtha TWA 100
Recommendation

AUSTRIA Naphthalene MAK 10 50


Skin*

Trimethylbenzene MAK 20 100


MAK STEL 30 150

BELGIUM Naphthalene TWA 10 53


STEL 15 80

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

Skin*

Trimethylbenzene TWA 20 100

DENMARK Naphthalene GV 10 50

Trimethylbenzene GV 25 120
GV 25

FINLAND Naphthalene HTP 8H 10 53


HTP 15MIN 20 110

Trimethylbenzene HTP 8H 20 100

FRANCE Heavy Aromatic Naphtha VME 1,500

GERMANY Naphthalene Skin*

Trimethylbenzene MAK 20 100


PEAK CAT

IRELAND Naphthalene TWA 10 50


STEL 15 75

Trimethylbenzene TWA 20 100


Skin*

ITALY Naphthalene TWA 10 50

Trimethylbenzene TWA 25

NETHERLANDS Naphthalene MAC 10 50


MAC-TGG 80
15
MAC 50
MAC-TGG 80
15

Trimethylbenzene MAC 20 100


MAC-TGG 40 200
15

NORWAY Naphthalene ADM. NORM 10 50

Trimethylbenzene ADM. NORM 20 100

SPAIN Naphthalene VLA-ED 10 53


VLA-EC 15 80

SWEDEN Naphthalene NGV 10 50


KTV 15 80

Trimethylbenzene NGV 25 120


KTV 35 170

SWITZERLAND Naphthalene TWA 10 50


Skin*

Trimethylbenzene TWA 20 100


STEL 40 200

UNITED KINGDOM Trimethylbenzene TWA 25 125

POLAND Naphthalene MAC-NDS 20

Trimethylbenzene MAC-NDS 100


MAC- 170

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

NDSCh

HUNGARY Naphthalene K 50
Skin*

CZECH REPUBLIC Naphthalene PEL 50


NPK-P 100

CROATIA Naphthalene MDK 10 50


KDK 15 75

Trimethylbenzene MDK 25 125

SLOVAKIA Naphthalene TWA 10 50


Skin*

SLOVENIA Naphthalene TWA 10 50

* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.

MONITORING MEASURES :
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be
desorbed or removed and analyzed as referenced below:
Substance(s) Method Analysis Absorbant
Naphthalene US NIOSH: 1501 Gas chromatography Charcoal

Heavy Aromatic Naphtha US NIOSH: 1550 Gas chromatography Charcoal

BIOLOGICAL EXPOSURE INDICES :


Heavy Aromatic Naphtha
A biological index of exposure to aromatic petroleum solvent, xylene based, is the detection of total xylene in the
blood post shift (Germany, 1.5 mg/l), or the detection of methylhippuric acid in the urine post shift (USA, 1.5g/g
creatinine; Germany, 2g/l).

ENGINEERING MEASURES :
General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions
near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of
confined spaces.

PERSONAL PROTECTION

GENERAL ADVICE :
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields. The applicable European
standard can be found in EN 166.

RESPIRATORY PROTECTION :
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: A-B-E-K-P The applicable European standard can be
found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown
concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required,

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

institute a complete respiratory protection program including selection, fit testing, training, maintenance and
inspection.

HAND PROTECTION :
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are
observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable
European standard can be found in EN 374.

SKIN PROTECTION :
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The
applicable European standard can be found in EN ISO 20345.

EYE PROTECTION :
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.

HYGIENE RECOMMENDATIONS :
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep
a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling
this product never eat, drink or smoke.

ENVIRONMENTAL EXPOSURE CONTROL PRECAUTIONS :


Consider the provision of containment around storage vessels.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Liquid

APPEARANCE Clear Amber

ODOR Hydrocarbon

FLASH POINT : 66.1 C PMCC


SPECIFIC GRAVITY 0.92 (15.6 C)
SOLUBILITY IN WATER Dispersible
VISCOSITY 106 cst (15.6 C) ASTM D-445
VISCOSITY 97 cps (15.6 C)
VISCOSITY 489 SUS (15.6 C)
POUR POINT < -29.9 C
VAPOR PRESSURE 0.69 kPa (37.8 C)

Note: These physical properties are typical values for this product and are subject to change.

10. STABILITY AND REACTIVITY

STABILITY :
Stable under normal conditions.

HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

CONDITIONS TO AVOID :
Heat and sources of ignition including static discharges.

MATERIALS TO AVOID :
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS :


Under fire conditions: Oxides of carbon, Oxides of nitrogen

11. TOXICOLOGICAL INFORMATION

The following results are for a similar product.

ACUTE ORAL TOXICITY :


Species LD50 Test Descriptor
Rat 1,932 mg/kg Product
Rat 2,500 mg/kg Product

ACUTE DERMAL TOXICITY :


Species LD50 Test Descriptor
Rabbit 5,600 mg/kg Product
Rabbit > 2,000 mg/kg Product

ACUTE INHALATION TOXICITY :


Species LC50 Test Descriptor
Rat > 2.0 mg/l (4 hrs) Product

SENSITIZATION :
This product is not expected to be a sensitizer.

CARCINOGENICITY :
This product contains naphthalene. The International Agency for Research on Cancer (IARC) has evaluated
naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in
experimental animals and inadequate evidence in humans).

For additional information on the hazard of the preparation, please consult section 2 and 12.

12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL EFFECTS :

The following results are for a similar product.

ACUTE FISH RESULTS :


Species Exposure LC50 NOEC Method Test Descriptor
Bluegill Sunfish 96 hrs 1.09 mg/l Product
Rainbow Trout 96 hrs 1.17 mg/l Product
Turbot 96 hrs 7.5 mg/l Product

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

ACUTE INVERTEBRATE RESULTS :


Species Exposure LC50 EC50 Method Test Descriptor
Daphnia magna 48 hrs 1.5 mg/l Product
Daphnia magna 48 hrs 1.5 mg/l Product
Acartia tonsa 48 hrs 6.2 mg/l Product

AQUATIC PLANT RESULTS :


Species Exposure EC50/LC50 Method Test Descriptor
Marine Algae 72 hrs 1.7 mg/l Product
(Skeletonema (EC50)
costatum)

AVIAN RESULTS :
Species Exposure LC50 Method Test Descriptor
Bobwhite Quail 8 Days > 5,000 Product
ppm
Mallard Duck 8 Days > 5,000 Product
ppm

PERSISTENCY AND DEGRADATION :

The organic portion of this preparation is expected to be inherently biodegradable.

BIOACCUMULATION POTENTIAL
Component substances have a potential to bioaccumulate.

13. DISPOSAL CONSIDERATIONS

If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.

Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be
burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT
suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.

Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.

EUROPE WASTE CODE :


16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign
the most appropriate European Waste Catalogue Code.

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

9 / 13
MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

14. TRANSPORT INFORMATION

The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT
Proper Shipping Name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical Name(s) : 1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline
UN/ID No : UN 2735
Hazard Class - Primary : 8
Packing Group : III
ADR/RID H.I.n. : 80
CLASSIFICATION CODE : C7

AIR TRANSPORT (ICAO/IATA)


Proper Shipping Name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical Name(s) : 1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline
UN/ID No : UN 2735
Hazard Class - Primary : 8
Packing Group : III
IATA Cargo Packing Instructions : 820
IATA Cargo Aircraft Limit : 60 L (Max net quantity per package)
IATA Passenger Packing Instructions : Y818 / 818
IATA Passenger Aircraft Limit : 1L/5L

MARINE TRANSPORT (IMDG/IMO)


Proper Shipping Name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical Name(s) : 1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline
UN/ID No : UN 2735
Hazard Class - Primary : 8
Packing Group : III

OTHER APPLICABLE INFORMATION


CEFIC TREMCARD REFERENCE : 80GC7-II+III
EMERGENCY ACTION CODE : 2X

15. REGULATORY INFORMATION

CLASSIFICATION AND LABELLING :

GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations


Directive 1999/45/EC.

HAZARD SYMBOLS

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

CORROSIVE DANGEROUS FOR THE


ENVIRONMENT

Contains:..Naphthalene 1-(2-Hydroxyethyl)-2-Tall Oil-2-Imidazoline

RISK PHRASES
R34 - Causes burns.
R40 - Limited evidence of a carcinogenic effect.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67 - Vapours may cause drowsiness and dizziness.

SAFETY PHRASES
S23 - Do not breathe vapor.
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S57 - Use appropriate containment to avoid environmental contamination.

NATIONAL REGULATIONS FRANCE


Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see
table(s): 84, 4, 4 Bis
Special medical supervision - Decree of 11 July 1977: Relevant.
Classified Industrial Sites (ICPE): Relevant. Headings: 1173

NATIONAL REGULATIONS GERMANY


WGK 2 (Annex 4)

PRODUCT REGISTRATION NUMBER


Denmark 1896487
Norway 018398

INTERNATIONAL CHEMICAL CONTROL LAWS


EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.

Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.

UNITED STATES
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)

CANADA :
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Ministry of International Trade & industry List (MITI).

16. OTHER INFORMATION

LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3


R10 - Flammable.
R20 - Harmful by inhalation.
R22 - Harmful if swallowed.
R34 - Causes burns.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R36/38 - Irritating to eyes and skin.
R40 - Limited evidence of a carcinogenic effect.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 - Harmful: may cause lung damage if swallowed.
R66 - Repeated exposure may cause skin dryness or cracking.
R67 - Vapours may cause drowsiness and dizziness.
- REVISED INFORMATION: section(s):
- 12

This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.

EMERGENCY TELEPHONE NUMBER(S)

Trans-European +32-(0)3-575-5555
Belgium / Luxembourg +32-(0)3-575-0330
Czech Republic +420-602-669421
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
France / French Switzerland +33-(0)6-11-07-32-81
Germany / Austria / German Switzerland +49-(0)6232-130128
Hungary +36-30-9-506-447
Italy / Italian Switzerland +39-333-210-7947
The Netherlands +32-(0)3-575-0330
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81
(SPOT)
Portugal +351-91-911-1399
Russia / Belarus +7-812-449-0474
Saudi Arabia +966-(3)847-1515
Slovak Republic +421-(0)905-585-938
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
UK and Republic of Ireland +44-(0)7071-223-738
Nalfleet International +32-(0)3-575-5555

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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MATERIAL SAFETY DATA SHEET
PRODUCT

NALFLEET(R) 9-303

EMERGENCY TELEPHONE NUMBER(S)


See section 16, for Emergency Telephone Numbers.

POISON CONTROL CENTER TELEPHONE NUMBERS

Belgium +32-70-245245
Czech Republic +420 224 91 92 93
France +33-(0)145-42-59-59 ORFILA
Slovak Republic +421 (0)2 5477 4166

Prepared By : SHE Department


Date issued : 04.12.2007
Version Number : 2.4

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth

NALCO EUROPE B.V. Postbus 627 2300 AP Leiden The Netherlands +31 71 5241 100

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