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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

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ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST II


(Paper-2)

Q. No. PHYSICS CHEMISTRY MATHEMATICS


ALL INDIA TEST SERIES
Program & 4423 Students from All Programs have qualified in JEE Advanced, 2016

1. BC AC CD
2. AD ABCD AD
3. ABD ABCD ABCD
4. B ABC ABC
5. AC A BC
6. A A ABCD
7. BC ACD ABCD
8. BC BD BCD
9. B B B
10. C C C
11. B C B
12. C B A
1. 5 4 1
2. 6 7 6
3. 4 3 Zero
4. 2 4 9
5. 2 3 1
6. 5 6 2
7. 4 9 Zero
8. 8 1 3

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

Physics PART I

SECTION A

1. BC
Sol. F.B.D. of ball in frame of container 4Vg
4Vg Vg Y
ay 3g
V Va 4Va
L 1 L X
3gt 2 t
2 2 3g Vg
4Va Va
ax = 3a
V
1 2L
L 3at 2 t
2 3a
2L L
Ball to collide at point Q, t a = 2g
3a 3g

2. AD
R dB R
Sol. E 2B o T
2 dt 2
QER = mgR
3. ABD
Sol. Concept based. Maximum error is equal to least count.
4. B
qE
Sol. v2 v02 2 0 x0
m
v 2v 0
qE0 v0
an
m v 2x v 20
3
v2 [m2 v 20 2qE0mx0 ] 2
R = 4 2 x0
an qE0 v 0m2
5. AC
Sol. Apparent position of the object wrt lens.
10 10
u 15 cm
1 2
1 1 2(1.5) 1 m=+1

15 v R
v = 7.5 cm
7.5
Image size = 1 = 0.5 cm
15

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

6. A
Sol. XL L 100 0.5 50
1 1
XC 100
C 100 100 106
20 1
Z1 100 2; I1
100 2 5 2
1 20 2
Vacross100 100 10 2
5 2 2 2
R1 100
Phase difference between I1 and V cos 1
Z1 100 2
I1 lead V 1 / 4
20 2
Z2 50 2 ; I2
50 2 5 2
2
Vrms across 50 50 10 2
5 2
R 50 1
Phase difference between and V cos 2 2
2 Z2 50 2 2
2 / 4
I2 lag V by /4
I I1 I2
4 1 5 1
I 0.316
25 2 25 2 50 10
7. BC
Sol. vL = vC = vR ;
xL = xC = R
when inductor is short circuited
Z = R 2 x 2C = 2 R
30 30
I=
Z 2R
30 30
VL = ixL = R=
2R 2
(A) is incorrect and with similar calculations (B) will be correct.
Here f0 is the resonance frequency as vL = vC
1
0 = 2f0 =
LC
xL L
= = 2LC
x C 1 C
Given f = 2f0
= 20
xL
=4
xC
(C) is also correct.

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

8. BC
m 2gh
Sol. Velocity of m when the string just become taut = upward and acceleration =
Mm
Mm
g downward.
Mm
2m 2gh M m 2m 2h
t
M m (M m)g M m g
2
1 m 2gh 1 2 Mm
E = (M m)
2 Mm
m
2
2gh =
Mm
gh

9. B
dNy
Sol. xNx yNy
dt

10. C
Sol. For Y to be maximum
dNy t t
0 y e y x e x 0
dt
ln( y / x )
t
y x

11. B
12. C
Sol. 11 & 12
The cylinder has a uniform charge density on its surface. The angular velocity of the
cylinder increases as the mass accelerates downward, the electric current caused by
revolution of the cylinder that flows in azimuthal direction, increases. Due to increase in
current, magnetic field varies with time, so electric field induces at the surface of the
cylinder. Due to this electric field, a torque is generated on the cylinder.
v
So mg T ma ; v at and
R
Q Qv Qat
I
2 2R 2R
B at axis of cylinder
Qat 1
B 0nI 0 n
2Rl l
Induced electric field at surface of cylinder
R dB 0Qa
E
2 dt 4 l
Net torque on the cylinder is zero. So
Q2a
TR QER ; T 0
4 l

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

SECTION C

1. 5
1 1 1
Sol.
v u f (2,0.1)
1 1 1 0.1m x
; v = 6m (0,0)
v 2 1.5 x 0.3m
v 2m d
m 3
u
0.3
x 6 d ; tan
x
d = 5m.

2. 6
Sol. For equilibrium of the cylinder in the horizontal direction.

In the vertical direction, N2 + N1 = F + Mg .. (ii)


Solving these two equations with F = 40 N, M = 2 kg and = 1/3,
we get
N1 = 18 N
and N2 = 54 N
Now, Fd = (N1 + N2)r
N1 N2 r 1 / 3 18 54 0.1 = 6 cm.
d =
F 40

3. 4
Sol. Since rate of heat flow remains same in both the cases, so
2R R
dx dx
nk 4k n = 4
k2 x l R l
R nk 2 x
4 2

4. 2
Sol. Velocity of ball when it hits the floor,
V0 2gH = 100 m/s
Normal impulse on the ball when it hits the floor,
JN = meV0 ( mV0) = mV0 (1 + e)
Frictional impulse Jf = JN = mV0 (1 + e)

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

So velocity of ball immediately after collision


Vertical velocity : vy = eV0 = 50 ms1 ;
J
Horizontal velocity vx = f = V0 (1 + e) = 50 ms1
m
So time taken to hit the wall after it strikes the floor is given by,
x = vxt = 250 = 50 t
t = 5 seconds
1 1 1
h = vyt gt2 = 50t 10 t 2 = 50 5 10 25 = 125 m.
2 2 2

5. 2
Sol. Fact based

6. 5
r
Sol. V1 V2 = ln 2
2o r1

7. 4
/ 2
o N Rd 2
Sol. R / 2 ir and r = Rsin.
0 2R3

8. 8
Sol. w d sin 30 = (g 1) t

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

Chemistry PART II

SECTION A

1. AC
Sol. Xe contains two lone pairs. There is no distinction between axial and equatorial positions
for octahedron. The observed bond angles are 90o and 180o. The dipole moment of the
molecule is zero. The lone pair moments are cancelled each other and the bond pair
moments are cancelled each other. No bond pair moment cancels the lone pair moment.

2. ABCD
HI
Sol. CH3OC2H5 CH3 OH C2H5I CH3I C2H5 OH
All four products are formed.

3. ABCD
Sol. Reaction (A) takes place at anode site. Reaction (B) takes place at cathode site.

4. ABC
Sol. (A) O H3 C OH

CH3MgBr

H2O/H

O H3 C OH
(B) OH

OH
(C) O O
HOOC COOH
MnO4 /H

HOOC COOH
O O
O

Heat

CO2

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

5. A
Sol. OH

O B
HO
B O
O
O B
OH
B O

OH

6. A
Sol. Kp is constant & change with temperature only.

7. ACD
Sol. B is not a conjugate acid-base pair.

8. BD
Sol. Le-Chateliers principle.

9. B
Sol. According to the equation
log A = 14 or log A = log 1014 A = 1014

10. C
Sol. k Ae Ea /RT
For k to be equal to A, e Ea /RT should be equal to 1
e Ea /RT = 1 = eo
Ea
or, 0T
RT

11. C
Sol. The alcohol should contain one benzyl group because ozonolysis of the alkene (I) forms
aldehyde (J) which forms two compounds when reacts with NaOH, i.e. (J) undergoes
Cannizzaro reaction.
In (A) the benzyl group from Grignard reagent forms a 2o alcohol. In (C), the benzyl
group forms a 3o-alcohol.

12. B
Sol. O
O3
PhCH C CH3 PhCHO CH3 C Ph
Ph NaOH
One aldol product
NaOH
PhCH2 OH PhCOONa

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

SECTION C
1. 4
Sol. SiO2 has a three dimensional network structure in which silicon forms four sigma bonds.
2. 7
Sol. CH3COOH NH4OH CH3COONH4 H2O
CH3COOH is salt of weak acid and weak base
pKa pKb
pH 7
2
3. 3
t1/ 2 2 a1 n1 n 1
Sol. or 4 2 n 1, n 3
t1/ 2 I a2
4. 4
Sol. In solid state BeCl2 exists as
Cl Cl
Be Be Be
Cl Cl

5. 3
Sol. H Ka1C1 Ka2C2

1.8 105 0.02 6.4 10 5 0.01 1 103
pH 3

6. 6
Sol. 2NH3 (g) N2 (g) 3H2 (g)
to 76 0 0
Teg 76-2x x x
Total pressure after dissociation =76-2x+x+3x=76+2x
Increase in pressure =2x=24cmhg
X=12comhg
Partial pressure of H2 (g) 3x 36cmhg
6y 36
y 6

7. 9
Sol. A = SiF4, B = H2SiF6
8. 1
Sol. The isomer having highest pKa (least acidic) is:
CH 2CH 3
H3C - C - COOH

CH3

It contains one secondary carbon atom.

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

Mathematics PART III

SECTION A

1. CD
Sol. fn number of subset in which n appears + number of subset in which n does not
appears.
S 1,2,3,........ n 2 , n 1 ,n when n appears obviously (n 1) will not appear and
when n does not appear up to (n 1) will appear
fn fn 2 fn 1
f1 2
f2 3
f3 f1 f2 2 3 5
f4 f2 f3 3 5 8

2. AD
f 0 f 2
Sol. By intermediate value property f c , 0 c 2
2
By mean value theorem
f 1 f 0 f ' c1 , 0 c1 1
f 2 f 1 f ' c 2 , 1 c 2 2
By subtraction
f 0 f 2 2f 1 f ' c 2 f ' c 1
c 2 c1 f " c , c1 c c 2 f 0 f 2 2f 1 0
f 0 f 2 2f 1

3. ABCD
Sol. If we could show that f "' x 0 then all choices follow since f 0 f ' 0 f " 0 0
8 2
Indeed f ' x 1 x sec 2 x, f ' 0 0
3
16
f " x x 2 sec 2 x tan x f " 0 0
3
16
f "' x 2 sec 4 x 4 sec 2 x tan2 x
3
16

3

2 sec 2 x sec 2 x 2 tan2 x

0 x
6

max 2 sec 2 x sec 2 x 2 tan2 x
2
2 4 2 16
2
3 3 3 3

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

f "' x 0
Whence all choices follow.

4. ABC
Sol. Y y m X x
Put X 0
Y y mx
y mx x2 (0, y mx)
dy 1
y x (linear DE) 1
dx x (x, y)
Solving y x2 cx
x 1, y 1 0 1 2
c2
y 2x x 2

5. BC
Sol. (A) s b s c bc a b c Not possible
(B) b 2 sin 2c c 2 sin 2B 4R2 sin2 B.2 sinC cos C sin2 C.2 sinB cosB
4R2 .2 sinB sinC sin A
b a
8R2 . . sinc
2R 2R
2ab sin C
possible if C 30o
3 2 5 2 72 9 25 49 1 2
(C) cos C cos
2 3 5 30 2 3
Hence possible
A C AC A C
(D) cos cos 0 sin sin 0
2 2 2 2
Not possible

6. ABCD
1
Sol. Put x in both the quadratic equation
x
x 2 4x a 0

1 1
x1 x3

x 2 6x b 0

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

1 1
x2 x4
1 1 1 1
, , , are in A.P.
x1 x 2 x 3 x 4
1 1 1 1
Let A, A D, A 2D, A 3D
x1 x2 x3 x4
1 1
2A 2D 4 A D 2 (1)
x1 x 3
1 1
2A 4D 6 A 2D 3 .(2)
x2 x4
From, (1) and (2),
A 1, D 1
1 1 1
x1 1, x 2 , x 3 and x 4
2 3 4
1 1 1 1 1 1
a ,b
x1 x 3 3 x2 x 4 8
Now verify alternatives.

7. ABCD
Sol. As a912 ,a951 and a480 are divisible by 3, none of them is prime.
For a91, we have
1
a91 99.....9
9
91 times


10 91
1
9
1 7 13

9
10 1

107 13 1
7
10 1
107 1 10 1

7 12 11
10 107 ............. 107 1 106 105 ...... 10 1


a91 is not prime.

8. BCD
2 1
x sin 2 x0
Sol. (A) False, f x x

0 x 0
(B) This statement is true

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

x 0 x 1

For example: f x 1 x0
0 x 1

(C) f x x 2 cos x 4
Now f 1 1 1 4 6
and f 2 4 1 4 7
As f is continuous on 1, 2, so f c 2, for some c 1, 2
(By using intermediate value theorem).
(D) f 1 ' 4 f ' 10 1 1e x 21
x 0

9. B
x2 y2
Sol. If En : 1 and eccentricity of En is en
an2 b2n
If an bn
Then
bn2 an2 1 en2 ..(i)
According to question
bn bn 1 ..(ii)
and an 1 an en .(iii)
For ellipse En 1,

an21 bn21 1 en21 (iv) (let bn 1 and an 1 is semi major
and semi minor axis of En 1 )
From equation (i) and (ii),
bn21 an2 1 en2 .(v)
Substituting the values of an 1 and bn21 from equation (iii) and (v) in (iv), then

an2e2n a2n 1 en2 1 en21

e2n 1 en2 1 e2n1 ..(vi)
En is independent of n,
en en 1 e (say)
2

e2 1 e2
e 4 3e2 1 0
3 5
e2
2
2
6 2 5 5 1

4 2

5 1
e 0 e 1
2

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

10. C
x2 y2
Sol. E1 1
9 16
a1 3, b1 4 and
9 16 1 e12
7
e1 y
4
7
1
From equation (vi), e2 16 3
7 5 E3
2 E2
16
E1
9 x' x
1 C
and then e3 25 4
9 41
2
25
Also a1 a 2 e 2 and b1 b2
b2 4 b3e3 b3 41 y'

16
and
a32 b23 1 e23
41 1 25
41
2 2
x y
Ellipse E3 is 1
25 41

11. B
Sol. Let b c x, bc y
A.M G.M.
bc
bc
2
x2 y and z a
Then b c a b c a bc x z x z y
2s 2s 2a bc
s s a 1
or
bc 2
A
or cos cos
2 3
2
A 120o
3

12. A
1
Sol. bc sin A
2
1 3 y 3
y.
2 2 4

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

SECTION C
1. 1
Sol. In the 1st case,
3
C2 nC2 1 6 n n 1 1
P (they match) n3
;
C2 2 n 3 n 2 2

2 n2 n 6 n2 5n 6
n2 7n 6 0
n 1 or 6
In the 2nd case,
3 3 n n 5

n3 n3 n3 n3 8
Solving, n2 10n 9 0
n = 9 or 1 (ii)
From equation (i) and (ii), n = 1
2. 6
Sol. For consistency,
a 1 b
b 1 a 0
a b ab
a b a b2 0
Either a b or a b 2
When a b, then ordered pairs are 0,0 , 1,1 , 2,2 , 3,3 , 4,4
When a b2 , then 4, 2
Hence, number of ordered pairs are 6.
3. 0
1 1 1
Sol.
1 2a 1 0 1 2a a2 11 a 1 a2 2a 2 0
2
a a 1
2a a 1 a a 2 0
2

2a2 3a 1 0
2a 2 3a 1 0
1
2a 1 a 1 0 a , 1 are two possible values
2
1
But for a ,1; two planes become parallel.
2
Hence, no value of a.
4. 9
Sol. Given,
a 19d log10 20 ..(1)
a 31d log10 32 .(2)

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

(2) (1)
32
12d log10 log10 16 1
20
12d 4log10 2 1
12d 1
log10 2 .(A)
4
Again (2) + (1)
2a 50d log10 640 6log10 2 1
2a 50d 1
log10 2 ..(B)
6
12d 1 2a 50d 1
36d 3 4a 100d 2
4 6
4a 64d 5
5
a
16d
4
17 th term

5 p
Hence, 17th term is rational and its value is p q 9
4 q
5. 1
2
t 2 f x 1 x 1 f t
Sol. lim 1
t x 1 f t f x 1
Using LH rule
2
2t f x 1 x 1 f ' t
lim 1
t x 1 f 't
2
2 x 1 f x 1 x 1 f ' x 1
1
f ' x 1
2x f x x 2 f ' x f ' x

2xy 1 x 2 dy
dx
2x dy
2
dx
1 x y

n 1 x 2 n y
2
1 x cy
f 0 1 c 1
y 1 x2

Lim

n 1 x 2 n 2
im
2x
1
x 1 x 1 x 1 1 x 2

6. 2
1 1
1 2
Sol. Given f x dx
0
f x2
3 0
dx

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AITS-CRT-II-(Paper-2)-PCM (Sol)-JEE(Advanced)/17

1
2
Consider, I1 f x 2 dx
0

2
Put x t 2x dx dt
2
1 1 f t
I1 dt
20 t
Equation (1) becomes
2
1
t 1
f t 2 t f t 1
2

2
0 t
dt
0 2 t 0

dt f t t dt 0

f t t
1 1
So, f
4 2
1
So, reciprocal of f 2
4
7. 0
Sol. Given curve is ellipse having centre (0, 0). All chords of ellipse through origin are
bisected at origin
pq0
8. 3
Sol. Given, z i (1)
2 2
and z 1 .(2)
From (1), on squaring we get
z2 2 2z 1 1 2z 1 [Using (2)]
zw 1 ..(3)
Now, let us consider a quadratic equation in x whose roots are z and .
x 2 ix 1 0
i i2 4 i 3
x
2 2
P (0, 0)
Let x

i 3 i 3
z
2 2
i 3
i 3 R
Q 2
2

0 0 1
1 3 1 1 3 3 3
So, ar. PQR 1
2 2 2
2 4 4 4
3 1
1
2 2

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