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EFFECT OF PEAK-AGED HEAT TREATMENT ON CORROSION BEHAVIOR OF THE AA6063 ALLOY CONTAINING Al 3Ti
The purpose of this study is to analyse the microstructure and corrosion properties of homogenised and aged AA
6063 aluminium alloys, containing up to 2% Ti, after the conventional casting technique. The microstructure of the
homogenised and aged alloys was examined using an optic microscope, and scanning electron microscope. The micro-
hardness test was used for the hardness measurements of the investigated alloys. Corrosion tests were performed by
suspending samples of certain sizes into 30 gr/l NaCl + 10 ml/l HCl solutions, measuring the mass loss; potentiodynamic
polarisation measurements were carried out in the same solution. The microstructure characterization of the investigated
alloys shows the Al (matrix), non-shaped dark globular grey-coloured phase and rod-shaped phases formed at the grain
boundaries. The non-shaped dark grey-coloured phase is Mg 2Si. The rod-shaped phase, formed in the microstructure of
the Ti-added AA 6063 alloys, is Al3Ti. The Ti content of the alloy increases, the Al3Ti phase tends to elongate and become
plated. The results of the corrosion tests proved that the corrosion rate decreased in alloys containing less than 1% Ti, and
the rate of corrosion increased in alloys containing more than 1% Ti, regardless of whether the alloys were homogenised
and aged. Another observation was that aging heat treatment improved corrosion resistance.
Keywords: non ferrous metals and alloys, casting, corrosion, micro structure
Celem niniejszej pracy jest analiza mikrostruktury i waciwoci korozyjnych poddanych obrbce cieplnej stopw
alumi-nium AA 6063, zawierajcych do 2% Ti, po odlewaniu konwencjonalnym. Mikrostruktur homogenizowanych stopw
zbadano za pomoc mikroskopii optycznej i skaningowej mikroskopii elektronowej. Test mikrotwardoci zastosowano do
pomiaru twar-doci badanych stopw. Badania korozyjne przeprowadzono poprzez zawieszenie prbki o okrelonych
rozmiarach w roztworze 30 gr/l NaCl + 10 ml/l HCl i pomiar ubytku masy; pomiary potencjo-dynamicznej polaryzacji
zostay przeprowadzone w tym samym roztworze. Charakterystyka mikrostruktury badanych stopw pokazuje matryc Al;
ciemnoszare, nieregularne wydzie-lenia fazy Mg 2Si; oraz na granicach ziaren prcikowe wydzielenia fazy Al 3Ti, obecne w
mikrostrukturze stopw AA 6063 z dodatkiem Ti. Ze wzrostem zawartoci Ti, wydzielenia fazy Al 3Ti staj si wyduone i
pytkowe. Wyniki testw korozyjnych wykazay, e szybko korozji spada w stopach zawierajcych mniej ni 1% Ti, a
wzrosa w stopach zawierajcych wicej ni 1% Ti, niezalenie od tego, czy stopy byy homogenizowane i starzone.
Zaobserwowano, e obrbka cieplna podwysza odporno stopw na korozj.
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periments, were ultrasonically cleaned in distilled water and tials (Ecorr ) and corrosion current densities (icorr )
alcohol, after which they were weighed using a 0.1 mg- were calculated using a Tafel type fit in the software.
sensitive electronic scale. At the same time, the pH, the
temperature, and the electrical conductivity of the corrosion
solution were measured. The normalised mass loss values 3. Results and discussion
of the investigated alloys were calculated as g/mm2 by
dividing the mass loss of the each sample by their initial 3.1. The Microstructure and the micro-hardness of
total surface area. Finally, the cross section images of the the alloys
corroded samples were examined using an optical
microscope in order to determine the mor-phology of the Fig. 1 illustrates the SEM images of the investi-gated
developed corrosion, after applying the conventional alloys. The microstructure images illustrated in Fig. 1 show
metallographic preparation procedure. the dark globular grey-coloured phase and rod-shaped
For the electrochemical corrosion tests, samples were phases formed at the grain boundaries. EDS analysis
attached to a copper wire and embedded into an epoxy results taken from the dark non-shaped grey-coloured
2 phases (Fig. 1, Phase No. 2) proved that this phase was
resin holder, to allow an open surface area of 0.19 cm .
rich in Al, Mg, and Si. According to EDS analyses and
Potentiodynamic polarisation curves were obtained using a studies in literature [17,18], the non-shaped dark grey-
Gamry PC+/300 mA potentiostat/galvanostat, controlled by
a computer with DC105 corrosion analysis software. The coloured phase is Mg2Si. The EDS results tak-en from the
potentiodynamic polarisation curves were generated by rod-shaped phase, formed in the microstruc-ture of the Ti-
sweeping the potential from a cathode di-rection to an added AA 6063 alloys, showed that this phase is rich in
anode direction, at a scan rate of 1 mV/s, starting from terms of Ti; in accordance with studies in literature [19,20],
-500 mV up to +500 mV. Corrosion poten- this phase is thought to be Al3Ti.
Fig. 1. SEM Micrographs and EDS analysis taken from the microstructure of the alloys heat treated peak-aged conditions at 150 C
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stant at 760 volt. In line with mass loss test results, icorr ing corrosion(mass loss rate and corrosion current den-
values indicate a faster corrosion rate for Ti-free, and 2 sity). As a result, hydrogen ions are used in the adjacent
% Ti-added AA6063 alloys were higher than region of the electrode surface, and the pH value of the
AA6063 alloys containing 1% Ti. solution increases. With the increase in corrosion, as a
result of the investigated alloys dissolving in ionised form,
the conductivity of the solution increased. The pH (Fig. 6)
and the conductivity (Fig. 7) of the used solution in this
study were measured before and after the corro-sion
experiment. Conductivity and pH in the corrosion solution
of the AA 6063+1% Ti alloy was lower than the others.
However, in a study conducted by Ralston et
al. [25] they determined that the icorr values decreased
as low as a certain pH, after which the pH increased to-
gether with the increase in the icorr values, in
accordance with this study.
Fig. 3. The mass loss values of the (a) homogenized and (b)
aged alloys as a function of the time
Fig. 7. The cumulative conductivity change for the (a) homogenized and (b) aged alloys as a function of time
Fig. 8 illustrates the optic microscope images taken gressing inwards from the surface decreased with
from the cross section of the alloys, prepared after cor- aging heat treatment.
rosion experiments. Corrosion progressed in the form of Previous corrosion studies conducted on Al alloys
pitting. Pitting in 2% Ti-added alloys nucleates and [2,4-15] have focused on the corrosion susceptibly in
proceeds around the Al3Ti intermetallic. In accordance with corrosion solution e.g. Sodium chloride. Researchers [7-
the results stated above, aging heat treatment slowed 9,13] reported that pits initiate around secondary
down corrosion significantly. In Ti-free alloys, corrosion was particles within the matrix. However, Kiourtsidis and
caused by pitting and progressed between grains. Skalianos [29] explained that the progress of corrosion
Literature [5-9,14,15] states that Al alloys containing using two anodic reactions; namely corrosion of the ma-
precipitate are susceptive to inter-granular corrosion. The trix adjacent to intermetallic regions, and pitting of den-
cross section image of the alloy, taken after the exper- drite cores, instead of galvanic corrosion, developed be-
iment, illustrates cracks that start from the surface and tween the intermetallic and matrix.
progress inwards. In Ti-free AA 6063 alloys, cracks pro-
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Fig. 8. LOM micrographs showing cross section of homogenized and aged alloys
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Received: 20 November 2011.
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