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fleas, and so
ad infinitum". Jonathan Swift.
Although atoms are said to be the smallest building blocks of matter, they themselves consist of
smaller 'sub-atomic' particles. So what are sub-atomic particles made from? That, happily,
remains the domain of the physicist and, as such, has no place in this book!
Atoms are the fundamental building blocks of matter. However, even atoms are constructed of
smaller, sub-atomic particles. It was originally thought that the atoms were small indivisible
particles (atomos = indivisible), however a paradigm shift occured with the discovery that the
Evidence for this emerged though the experiments conducted in the nineteenth century on
cathode rays, culminating in the experiments of Rutherford (the nuclear atom) and Chadwick
It is now known that even these sub atomic particles themselves have an even deeper sub-
The fundamental sub-atomic particles are protons, neutrons and electrons. The protons and
neutrons are held together by strong nuclear binding forces in the nucleus of the atom. The
electrons may be considered to be tiny particles that exist in regions of space known as orbitals
This model of the atom is precisely that, a model. It is impossible to see atoms and, in order to
be able to describe their properties, we use models representing this microscopic world that is
invisible to us.
Similarly, the sub-atomic world is a strange place with unusual forces acting over infintesimally
small distances. The rules of behaviour that govern the macroscopic world often break down in
this strange environment, and it is important to understand that our representations and
The picture of the atom above is easy to discuss and is comfortably familiar. However, if you
consider the actual dimensions of an atom compared to the nucleus you can see just how
You should appreciate that the nuclear radius is much smaller than the atomic radius by a
factor of about 100,000. This means that the atom is mostly empty space with a very solid and
tiny nucleus. This was originally demonstrated by the scattering experiments of Ernst Rutherford.
Particle mass
The actual masses of these sub-atomic particles are very small and to the nearest whole
number measured relative to the mass of a carbon-12 isotope being equal to 12 units:
Proton nucleus 1
Neutron nucleus 1
Although these values suggest that the protons and neutrons are identical they do, in fact,
have very slightly different masses, which is only of concern to us when considering changes in
the structure in nuclear chemistry. Compared to the mass of the protons and neutrons the
electrons have negligible mass and can be ignored when carrying out calculations involving
mass.
Protons have a mass of 1 atomic mass unit. They are all together in the nucleus, but they
cannot repel one another because of the strong nuclear force exerted by the protons and the
neutrons. You could consider the neutrons to be the nuclear glue that holds the nucleus
together.
A full
description TOK: This picture of the atom is a model to help us understand the
underlying structure. It does not imply that the atom is actually identical to
of the
this description, nor does it suggest that it is a simple arrangement of
electron is particles. It's just a model to help explain observed properties.
rather
complicated
as they
behave both
as particles
in some
circumstanc
es and
waves in
others. This
has lead
quantum
physicists to
calling them
wavicles -
things that
possess the
characteristi
cs of both
particles
and waves.
This model allows us to use the atomic theory successfully to explain many observations in the
microscopic world. Its use in modern particular science has been refined by the introduction of
another model, which is rather more difficult to understand, called the quantum model.
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Electrical charges
The forces that hold atoms together (and to one another) are largely electrical in nature (apart
from the strong nuclear charge that binds the particles in the nucleus together).
Electrically charged particles have an associated electrostatic field, rather like a magnet has a
magnetic field. If another electrical charge comes into this field it will feel a force of either
attraction or repulsion, depending on whether the charge carried is opposite or the same.
Overall, atoms are neutral, which means that they must have as many positive charges as
negative charges.
Protons carry a single positive charge and the electrons carry a single negative charge, so in
the neutral atom there are always the same number of protons and electrons.
The electrons are tiny in comparison to the protons and neutrons. The overall charge on an
atom is zero, the charges of the electrons cancel out the positive charges of the protons in the
nucleus.
Mass number
The atomic mass number is represented by the symbol (letter) 'A'. This is not to be confused
with the relative atomic mass Ar.
The mass number gives the integral number of nucleons, protons and neutrons found in the
nucleus of an atom.
The relative mass is a value that is not necessarily integral that compares a mass to the mass
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Atomic number
This is represented by the symbol (letter) 'Z'. It shows us the number of protons in an atom
Mass number
The atomic mass number is represented by the symbol (letter) 'A'. This is not to be confused
with the relative atomic mass Ar.
The mass number gives the integral number of nucleons, protons and neutrons found in the
nucleus of an atom.
The relative mass is a value that is not necessarily integral that compares a mass to the mass
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Atomic number
This is represented by the symbol (letter) 'Z'. It shows us the number of protons in an atom
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AZE
Any isotope of any element can be defined by using the A value, the Z value and the element
symbol.
Using the values of A and Z it is possible to calculate the number of sub-atomic particles within
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Ions
The system can be extended to cover ions simply by adding the charge onto the element
ion:
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Isotope definition
Isotopes are atoms of a specific element that have a definite number of neutrons and
consequently a different mass. In effect all atoms are isotopes of one element or another.
Most elements have several isotopes, some of which are stable, and others that spontaneously
For example, the element hydrogen has three isotopes, 1H, 2H and 3H. 1H is the most common of
the isotopes and makes up 99.99% of any sample of hydrogen. 2H is also called deuterium and
comprises the other 0.01% of naturally occurring hydrogen. The third isotope is called tritium
Tritium is radioactive and breaks apart spontaneously releasing radioactivity, in this case, a fast
moving electron.
Note that the product of this radioactive process is helium. Effectively, one of the neutrons in
the tritium nucleus has emitted an electron (called a beta particle) and turned into a proton.
hydrogen 1 1 0
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Relative abundance
The 'relative abundance' of an isotope means the percentage of that particular isotope that
occurs in nature. Most elements are made up of a mixture of isotopes. Clearly the sum of the
Example: Chlorine has two isotopes 35Cl and 37Cl, with relative
75% of the atoms are Cl-35 atoms and 25% of the atoms are
chlorine-37 atoms.
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Properties of isotopes
Isotopes differ only in their number of neutrons. This means that they have identical electronic
configurations and identical chemical properties. The masses of the isotopes affects any
Diffusion is a process that is dependent on the density of the diffusing species. According to
Graham's law, the rate of diffusion is proportional to the square root of the reciprocal density
This principle is put to use in the purification of uranium 235 for use in the atomic energy
industry. The uranium occurs naturally as two isotopes 235
U and 238
U with relative abundances of
Only the uranium 235 can be used for atomic energy and so needs to be concentrated in the
sample. This is done by reacting the uranium with hydrogen fluoride to form uranium
hexafluoride UF6, which is a volatile solid that can be converted to a gas at easily attainable
temperatures.
235
UF6
238
UF6
Once in the gaseous form, use is made of the different diffusion rates of the two compounds.
The relative masses of the two hexafluorides are so similar, the gases must be diffused using a
series of centrifuges, each one increasing the percentage of the required uranium isotope in the
mixture.
The uranium hexafluoride is then turned into uranium dioxide for use in fuel pellets.
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Uses of isotopes
Isotopes are used in medicine, industry, and in many other applications. The danger of
radioisotopes revolves around their ability to cause cell damage by ionising the atoms that are
involved in molecules and hence, breaking bonds. Radioisotopes may emit three different
common types of radiation, alpha, beta and gamma radiation, depending on the specific atom.
Alpha radiation consists of particles containing two protons and two neutrons (equivalent to a helium nucleus); is highly
destructive to living tissue, but has very low penetration power and is stopped by a few centimetres of air. It is only
seriously dangerous if ingested in some way.
Beta radiation consists of highly energetic electrons. It has poorer ionising characteristics than alpha radiation, but has
greater penetrating power.
Gamma radiation is electromagnetic in nature and has the lowest ionising ability, but extremely great penetrating power.
Living organisms respire. Plants breathe in carbon dioxide and animals eat plants (and other
animals!). The consequence is that all living things take up carbon throughout their lives. The
the form of carbon dioxide. At the same time the carbon 14 nuclei are decaying. There is an
carbon-12 carbon-14
This means that the proportion of carbon-14 compared to carbon-12 found in all living
organisms is also constant. However, when a living organism dies it stops taking up both forms
of carbon. The carbon -14 isotope decays naturally with a half life of about 5,600 years. So, a
simple procedure involving counting the radioemissions due to carbon-14 from a sample of
material that was once alive, can be used to estimate how long ago it died.
Therapeutic applications
Beta rays are fast moving electrons. They can be focussed onto cancerous tissue to destroy it
Iodine-131 and Iodine-125 are used as medical tracers and for treating certain cancers.
In several conditions the body can be scanned for problems using iodine, which is easily taken
up by the body and transported through the lymphatic system. The isotopes 131
I and 125
I are
Use is made of the destructive effect on cellular tissue to destroy cancer cells in treatment with
radioisotopes. Radioactive sources are used that have a short lifetime in the body, but which
radioisotope is injected into the body. After a few hours the technetium circulates around the
body and binds to areas of bone damage. By detection of areas of unusually high concentration
Industrial applications
Detection of leaks in gas pipes by injection of a radioisotope into the pipeline and detecting
where the radiation emerges. Beta emitters are used in measurement of thickness in the paper
industry.
Both uranium-235 and plutonium-239 are neutron emitting radioactive isotopes. The neutrons
emitted cause further events in neighbouring nuclei leading to chain reactions, which release
large amounts of energy as the nuclei break apart (fission). This energy is used to heat up
water into steam to drive turbines for electricity production.
Nuclear energy remains controvertial and there are strong arguments both for and against its
use.
Other applications
Instrumental details
A sample is injected into the mass spectrometer and is vaporised before meeting a stream of
high energy electrons, that turn the atoms into ions (by dislodging electrons) or, if we are
dealing with molecules, causes the molecules to break apart (fragment). The ions that are
produced in each case are deflected by magnetic fields and detected with a high degree of
accuracy.
The final read-out may be graphical or digital and gives information about the relative
abundance of all of the ions produced by the stream of electrons, as well as their exact masses.
In summary a single beam mass spectrometer has the following stages of operation (refer to
diagram below):
inert solution.
Vaporisation - If necessary, the sample is heated to produce a vapour and the gas
diffuses into the...ionisation chamber.
Ionisation - An electron beam knocks electrons off the vaporised particles, producing
positive ions.
Acceleration - The positive ions are attracted towards negatively charged plates.
Deflection - The stream of ions passes through into the magnetic field which deflects
Detection - The magnetic field is varied by the controller and ions with different masses
The operating principles are no longer a requirement for core and AHL.
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Operating principles
The curved path travelled by each ion depends on its mass (actually the mass:charge ratio, but
as the charge is always the same and equal to the charge on an electron, but positive, then we
can talk about the mass alone). Heavier ions have more momentum and require more force for
deflection.
The magnetic field strength of the deflector coils is varied and allows detection of all ions
The ions arriving at the detector constitute a flow of positive charge and can be recorded
electronically.
In this way, the relative atomic mass of each 'peak' is recorded on the mass spectrum read-
out. The height of the peak represents the abundance of the specific particle.
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Fragmentation
The energy of the electrons in the ionisation chamber of the mass spectrometer not only can
ionise the molecules it encounters, but also cause the ions produced to fragment into smaller
pieces. This is called fragmentation. The smaller pieces, or fragments, themselves may be
detected if they are in the form of ions. The peak that occurs at the highest m/e value is called
the molecular ion. It is the ion produced by removing one electron from the molecule itself and
can be used to determine the relative molecular mass of the species under investigation.
Notice that only ions are shown as only ions can be detected in
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The chlorine spectrum shows several lines, all of which are due to positive ions formed in the
The line with the highest m/e value comes from the molecular ion, it is due to the [Cl 2]+ ion.
Chlorine has two different isotopes, therefore there are three possible molecular ions.
[37Cl-37Cl]+
[35Cl-37Cl]+
[35Cl-35Cl]+
to 25% respectively.
Relative mass
The term relative atomic mass refers to the average mass of an atom of a specific element as
Example
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Mr determination from MS
Here we can see that there are two peaks in the
electrons. This is also called the fragmentation pattern and may be useful in elucidation of the structure of a molecule.
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The ions can be focussed onto the detector electronically. This allows determination of the m/e
of the ion, to an accuracy of 8 decimal places. The mass of the electron that has been lost can
be taken into account, giving masses for the atoms that are very accurate.
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The masses of the atoms can be found to such great accuracy that the mass of each molecule
becomes unique, according to the number and type of each atom present.
Example: The relative molecular mass of carbon monoxide = C +
O = 28 (to two significant figures places)
differentiated:
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Structural information
Spectra of molecules are rather more complex due to the breakup (fragmentation) of the
Here we can see that there is a fragmentation pattern caused by the molecule breaking apart in
The molecule is shown on the spectrum and the most important peak is the one at m/e = 116
which gives the relative molecular mass of the molecule. This peak is said to be due to the
"molecular ion" and is caused by the molecule itself losing only one electron before going to the
detector.
The m/e value of the molecular ion can be measured to such a degree of accuracy (many
decimal places) that it can be used to determine the exact number of each type of atom within
the molecule.
A full treatment of the fragmentation pattern is possible to give information regarding how the
Wave definitions
Waves are defined by velocity, wavelength, frequency and amplitude. This is shown in the
following diagram:
2. The frequency is the number of wavelengths that pass per second - f (sometimes the Greek letter 'nu', ). This is
3. The velocity of the wave in the case of electromagnetic radiation is the speed of light 'c' (3 x 10 8 ms-1 [data booklet])
4. The amplitude of the wave is represented by the letter 'a'. It is a measure of the intensity and is relatively
unimportant.
Electromagnetic energy
The energy carried by an electromagnetic wave depends on the wavelength - they are inversely
proportional, i.e. the shorter the wavelength the higher the energy.
However, as the speed of the electromagnetic radiation is always constant, the energy is also
directly proportional to the frequency of the wave. Higher frequency = greater energy. This can
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The wavelength of electromagnetic radiation varies according to its energy. The table below
shows the terms used for different regions of electromagnetic radiative energy and their
Effectively, there is no upper or lower limit to the wavelength and the energy.
The region of the electromagnetic spectrum that humans are able to see is very limited, called
the visible spectrum. We are all familiar with the colours of the visible spectrum:
Use the slider on the animation below to see the relationship between colour, wavelength,
The term 'ultra violet' (literally, beyond violet) refers to electromagnetic waves with energy
greater than the visible range. The term infra-red refers to wavelengths with lower energy than
A visible spectrum is produce when a light source (sunbeam, torch, laser etc) passes through a
refracting prism (piece of glass, or a Diffraction grating) and the light is bent through an angle
If the light wavelength is long ( for instance, red light, wavelength 700nm) it is not deviated as
Hence, any source of light consisting of several different wavelengths may be separated and
displayed.
If the light source contains all possible wavelengths (e.g. white light) then a continuous
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Continuous spectra
A spectrum may be continuous, or may comprise bright lines (an emission spectrum), or dark
A continuous spectrum results when the gas pressures are higher, so that lines are broadened
by collisions between the atoms until they are smeared into a continuum. We may view a
continuum spectrum as an emission spectrum in which the lines overlap with each other and
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Line spectra
These, as would be imagined, are spectra that appear as specific discrete lines on a
Emission spectra are produced by passing electrical or thermal energy through gases in which
the atoms do not experience many collisions (because of the low density). The emission lines
correspond to photons of discrete energies that are emitted when excited atomic states in the
As shown, emission spectra result from electrons within a sample becoming excited and moving
to higher energy levels. They cannot stay at the higher level for very long and they fall back to
the ground state, releasing energy equivalent to the difference between the energies of the two
levels.
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Absorption spectra
An absorption spectrum occurs when light of all wavelengths passes through a cold, dilute gas and
atoms in the gas absorb at characteristic frequencies. As the re-emitted light is unlikely to be
emitted in the same direction as the absorbed photon, this gives rise to dark lines (absence of
ions in solution.
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Summary
Emission spectrum showing only those discrete wavelengths that are emitted
Absorption spectrum showing a continuous spectrum with some specific wavelengths removed
The electron in the ground state energy level of the hydrogen atom receives energy in the form
It cannot remain at a higher level (excited state) for very long, and falls back to a lower level.
When the electron falls back down (relax) it must lose the energy difference between the two
energy levels. This loss of energy is performed by releasing electromagnetic energy in the form
When electron transitions take place the energy emitted can be detected and its wavelength
measured. This provides information about the relative energies of the shells.
In the hydrogen atom (the simplest case with only one electron to 'jump' between shells) the
energy emitted appears in several series of lines, each series corresponding to electrons falling
The Lyman series corresponds to transitions between the higher shells and the lowest shell
(ground state). The energy of these transitions produces radiation in the ultra-violet region of
the spectrum
The energy shells are usually given a letter 'n' to describe the specific energy level. The lowest
Transitions from higher shells (n>2) to n=2 produce radiation in the visible region of the
spectrum. It can be seen by splitting the light using a prism or diffraction grating and
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Convergence
As the energy levels increase in energy they get closer together. In other words level 2 and
level 3 are further apart than level 3 and level 4. The levels converge towards a limit.
Transitions that occur in any series must also converge towards a high energy limit, as the
largest transition is between the highest energy level and the level that is characteristic of the
specific series.
The highest level is sometimes refered to as the 'infinite' level, as the levels get so close
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Ionisation
When dealing with the Lyman series in the ultraviolet, the transitions are down to
the ground state (level 1). The largest transition must represent a fall from the
infinite level, , to level 1. Viewed in reverse it can be considered to be equal to
the ionisation energy, as this is the energy required to move an electron from the
ground state to the infinite level (Note: Ionisation energy is usually expressed per
mole of electrons).
M(g) M+(g) + 1e
Consequently, the ionisation energy may be found by examining the Lyman series
at the convergence limit. The wavelength of light corresponding to the
convergence limit may be converted to energy using the relationship E = hc/
Example: Calculate the ionisation energy of hydrogen, if the
E = hc/
E = 2.17 x 10-18
This method may be used to find the first ionisation energy of any element.
Electron arrangement
The electrons in atoms are arranged in energy levels. The lowest energy (most stable) energy
level is the one closest to the nucleus. The first energy level can hold up to two electrons. Once
it is full, the next energy level may then start to fill up.
However, each energy level itself is subdivided into subshells containing regions of space in
which there is a 0.99 probability of finding electrons of a specific energy. These regions are
called orbitals.
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Atomic orbitals
The regions of space in which electrons are found were defined by Ernst Schredinger in the
early part of the 20th century, by solving equations relating their energy and the electrostatic
forces to which they are subject. These regions of space are termed 'orbitals'
Electrons behave like particles in some respects and waves in others, but in all cases they
behave as negative charges. They are very difficult to pin down in terms of location, however it
is possible to define a region of space in which the probability of finding the negative charge is
very close to certainty - about 99%. This region of space is called an orbital.
Each energy level is divided into sub-levels each of which in turn has a certain number of
orbitals.
One atomic orbital can house up to two electrons, each with a different 'spin'. The word 'spin' is
used to differentiate between the two different electrons. It does not imply that they actually
spin, but studies show that they do have slightly different energies and the idea of spinning
electrons allows us an easy image with which to differentiate between them. The first electron
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This is the first (lowest) energy level. It has no sub divisions and consists of only one orbital
with a spherical shape - called a 1s orbital. (the '1' refers to the energy level).
This is the first energy level to be split into sub-levels, 's' and 'p'. The 's' sub-level once again
has only one spherical orbital which is much larger than the 1s orbital from the 1st level. The
'p' sub-shell consists of three atomic orbitals shaped a bit like double headed balloons. Each of
the orbitals is designated a letter x, y or z to indicate the axis that it lies along.
The 'p' orbitals are of slightly higher energy than the 's' orbital, consequently the 's' orbital fills
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The third energy level is split into three sub-levels, 's', 'p' and 'd' sub-shells. Each of these has
The 3s sub-shell consists of one 3s orbital, spherical in shape, like the 1s and 2s orbitals, but much larger.
The 3p sub-shell contains 3 separate 'p' orbitals, the same shapes and orientations as the 2'p' orbitals but, once again,
larger in volume.
The 'd' sub-shell consists of five 'd' orbitals with specific shapes.
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Contains 's', 'p', 'd', and 'f' orbitals (7 of them), with relative energies s<p<d<f
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Summary
The energy levels are split into sub-levels, each with orbitals that have shapes corresponding to
1 1 s s
2 2 s,p s, px,py,pz
Atomic orbitals
Each energy level is split into sub-levels (except energy level 1). The sub-levels in turn, contain
Level 4 contains one 's', three 'p', five 'd' and seven 'f' orbitals
As stated above the electrons fill up the orbitals in order of increasing energy from the lowest
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This states that no two electrons can be identical within an atom. Simply stated, it means that
only two electrons can fit into each atomic orbital and they must have opposite spins. By
convention, we say that one electron spins up, and the other down , represented by up and
down arrows.
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Hund's rule
This states that electrons entering orbitals that have the same energy (degenerate orbitals,
represented by boxes on the same level) must be filled by parallel electrons (unpaired
allowed forbidden
Example: In the electronic configuration of carbon 1s2 2s22p2, the electrons fill up in the
following way:
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Anomalous configurations
The Aufbau principle works fairly well for the first 38 elements, but after that it starts to break
down. Even so, there are two configurations that do not seem to fit into the pattern. These are
Chromium (24 electrons) has an expected configuration of [Ar] 4s2 3d4. However, the actual
This is explained by suggesting that there is some energetic advantage to the atom to have a
half-full set of 'd' orbitals, and that this is enough to cause one of the 4s orbital electrons to
Copper (29 electrons) also has an anomalous configuration with the expected [Ar]
4s2 3d9 giving way to [Ar] 4s1 3d10.
Once again, this is explained by the extra stability due to a full set of 3d orbitals, providing the
1. I. Iron
2. II. Copper
3. III. Zinc
Iron has 6 'd' electrons to fit into 5 'd' orbitals. As the first five
must enter with parallel spin it has 4 unpaired electrons
Copper has a single unpaired electron in the 4s orbital and all the
'3d' orbitals are full
unpaired electrons.
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Ions are formed from atoms by the addition or removal of electrons depending on whether the
Metals lose electrons forming positive ions. The number of electrons lost depends on the metal
atoms. Group 1, 2 and 3 elements lose 1, 2 and 3 electrons respectively to give a noble gas
configuration.
The 'd' block (transition) metals have variable oxidation states and may lose a variable number
of electrons. The first electrons lost by the first row 'd' block metals are the 4s electrons. After
these have been removed the '3d' electrons are successively removed until the required ion is
obtained.
Example: Show the electronic configuration of iron(II) and
iron(III) ions.
Scientists deal with a microscopic world that can never be seen. So how do they "know" the
structure of an atom?
It is rather like a birthday present that arrives well wrapped. The recipient may try to guess the
contents of the package without actually opening it. Many people shake the box, listen to the
movement of the contents, try to gauge the weight and how the contents move around in the
box.
What they are doing is putting energy into the box and by sensing the response from the box
Its the same procedure with scientists and the microscopic world.
Energy is given to the particles (atoms, molecules or ions) and the response from the unseen
world is detected. Hypotheses are formulated which are then tested by all available means. If
the experimental evidence seems to fit the hypothesis then a theory is proposed which in time
1 Spectra
2 Successive ionisation energies
3 Ist ionisation energies of the different elements
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Spectra
Different types of spectra have already been covered in section 1.31. These may be
summarised as:
1 continuous emission
2 continuous absorption
3 line emission
4 line absorption
Line emissions arise from energy being emitted by the atom as a result of electrons in high
energy levels returning to their ground states. The electrons must emit the difference in energy
and this is seen as light (electromagnetic radiation) of a specific wavelength. They first arrive
at the higher level by absorbing energy in the form of either heat or electricity.
Summary:
The electron returns to the original level and emits the difference as a specific electromagnetic radiation.
The wavelength seen is related to the energy of the emission by Plancks equation E=h
where:
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The ionisation energy of the elements can be determined by several means. These
are beyond the scope of the Syllabus. Students must understand the definitions of
1st and successive ionisation energies and also the factors that affect them,
specifically electrostatic forces.
The first ionisation energy is defined as the energy required to remove one mole
of electrons from one mole of gaseous atoms to provide one mole of gaseous
single charged ions.
Na(g) Na+(g) + 1e
Na+(g) Na2+(g) + 1e
Successive electrons can be stripped from an atom until there is only the nucleus
left. If the energy required to achieve this for each ionisation is plotted on a graph
(with a log scale) against the ionisation number, the 'jumps' in the required
energy clearly show the main and sub energy levels.
In this example, it may be seen that removal of the first electron requires
(relatively) less energy than removal of the next (eight) electrons - there is a
distinct inflexion (change of direction) in the otherwise fairly linear graph.
Consequently the element concerned must be in group I.
Many exam questions focus on the ability of a student to recognise this inflexion
from purely numerical data and then ask for details of its group in the periodic
table.
Example: In the following table identify the groups to which the elements X, Y and Z belong (all
values in kJ mol-1).
It may be seen that the inflection (relatively bigger jump) for element X occurs between 1st and
2nd ionisation energies. It is therefore in group 1. Similarly the inflection for Y occurs between
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M(g) M+(g) + 1e
A graph of first ionisation energy against atomic number shows how the first
ionisation energy varies moving from element to element in the periodic table.
The outermost electron is being removed in each case and so the amount of
energy needed to remove it is a function of the force holding the electron in
position around the atom.
This force is dependent on two main factors and is 'fine-tuned' by a third factor.
As the charge on the nucleus increases so the energy required to remove the
electron increases.
As the distance between the outermost electron and the nucleus increases so the
energy required to remove it decreases.
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Summary
Spectral lines give evidence of electrons moving from one energy level to another
within the atom.
Successive ionisations of an atom suggest that there are energy shells with large
energy differences between them.
The 1st ionisation energies of the first 36 elements suggests that the energy
shells are split up into sub-shells and that some of these sub-shells have further
divisions (orbitals).