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P
T P T
Property Relations for Homogeneous Entropy
Phases S V
P T T P
d nU Td nS Pd nV
Enthalpy
Helmholtz energy and Gibbs energy
H V
V T
A U TS P T T P
G H TS
d nH Td nS ( nV ) dP
d nA Pd nV ( nS ) dT
d nG nV dP ( nS ) dT
Fundamental property relations
dU TdS PdV
dH TdS VdP
dA PdV SdT
dFVdP
dG MdxSdT
Ndy
Where
F
M
x y
F
N
y x
M N
y x x y
Maxwell Equations
T P
V S S V
T V
P S S P
Enthalpy
P S and Entropy
T V V T as Functions
V S of T and P
T P P T