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szepesy, en
sur
t of the Adsorption Isotherms of Gases on Activated Carbon up
Acta. Chirn: Hung., 37 (1963a).
to;:ssures
" of 1000 torr.
of Gases and Gas MIxtures. II: Measurement of the Manuscrpt received August , 1983; reviio receved January 1984 and acepted
Adsorptio
sorbed ph under Pressures of January 12.
rption Isotherms of Gases on Activated Carbon
and j
lrface phase
reen species j
as phase
The dispersion equation is used to calculate the average There have been many experimental measurements of the
,tion of Nitro-
ve Type lOX," concentration of a solute in a porous medium under flow con- longitudinal dispersion coeffcient in packed beds and its de-
ditions (Bear , 1972; Dullen , 1979). The dispersive term accounts pendence on the Peelet number (Harleman and Rumer , 1963;
a and Kinetics for the spread of the solute about the mean pulse position due Edwards and Richardson , 1968; Rifai et aI. , 1956; Carberry and
lecular Sieves to molecular diffusion and the coupling of interpartiele velocity Bretton , 1958; Ebach and White , 1958; Pfannkuch , 1963;
and concentration gradients (Whitaker , 1967; Gray, 1975). It Blackwell et aI. , 1959; Gunn and Pryce , 1969). The Peelet number
Chern. Phys. consists of the double scalar product of a dispersion tensor , or dependence of the lateral dispersion coefficient has not been
total dispersivity tensor (Brenner , 1980) with the second deriv- measured as extensively but there are some data at low Peelet
Compounds," ative of the average solute concentration in the porous medium. numbers (Harleman and Rumer , 1963; Gunn and Pryce, 1969;
For the case of an isotropic porous medium, the total dispersivity Grane and Gardner , 1961; Hassinger and von Rosenberg, 1968;
Ethane , Eth-
:tures on 13X - tensor has non-zero components only along the diagonal. The Blackwell, 1962). Implicit in these studies is the assumption that
iagonal element corresponding to the mean direction of flow the dispersion coefficients are constants that depend on the
.erm Data for IS called the longitudinal dispersion coeffcient and it contrib- value of the Reynolds and Schmidt numbers only, and are in-
es (1982). utes to the spread . of solute pulses along the flow direction. The dependent of position in the packed bed or porous medium.
Adsorption other on-diagonal elements are called the lateral dispersion However , G. I. Taylor (1953 , 1954) in his original work on dis-
, 1 319 coeffcients and they contribute to the spread of the solute in persion in capilary tubes was very careful to point out that
the directions orthogonal to the mean flow. dispersion models become valid only after a suffciently long
Ir Mixed Sur- time has passed since the insertion of the solute pulse. How long
972).
this time is in a particular experiment was shown to depend on
lteraction be- ,
73). Conespondence concerning this paper should be addressd to R. G. Carbonell. the value of the molecular diffusivity, the tube radius , and the
uid and Liq- eung- won Han is presently at the Department of Chemical Engineering, Chon-nam National average fluid velocity. More recently, Brenner (1980) showed
mversity, Kwang-ju , Korea.
!53 (1976). ork done while authors were in the Chemical Engineering Depaent , University of California
that dispersion models are valid asymptotically in time for the
m Adsorptio Da VI.
W. case of dispersion in spatially periodic porous media , while
Carbonell and Whitaker (1983) demonstrated that this should workers interested in applying dispersion models to p
be the case for any porous medium. Unfortunately, in the design in transport processes in soils , coal gasification , or oil shaler S adjust
of most dispersion experiments in packed beds this possible torting, for example , where there are fairly large distributio values
dependence of the dispersion coefficient on time was not in- of particle sizes. Carbonell (1979; 1980a b) has made Some dispel
pr s
vestigated. The first objective of this work is to measure the axial liminary estimates of the effect of particle size distribution o prove'
dispersion coeffcient at various axial positions in a packed bed dispersion using a capilary tube model for the porous mediu an eXI
for a fairly wide range of Peclet numbers. At very low flow rates, However , with the exception of some early work of Nieman to cia!
the experiments last a suffciently long time so that the asymp- (1969), little experimental information is available on under
totic value of the dispersion coeffcient can develop. This would partiele size distributions affect dispersion coefficients. The porou
be reflected in a constant value of the axial dispersivity at var- second objective of this study is to vary systematically the dis. attent
ious positions along the column length. At very high flow rates tribution of particle sizes in a packed bed and to study the effect carefl
the experiments take a very short time and the dispersion of this change in porous medium structure on the magnitude dispel
coeffcient should be a function of axial position in the column. the longitudinal and lateral dispersion coeffcients. the ef
By analyzing these results , a quantitative criterion can be de- The data on lateral dispersion coefficients in packed beds has latera
veloped for the time required for the dispersion coeffcient to been limited in previous studies to particle Peclet numbers less deper
become constant. than 10 . The third objective of our work was to extend the range Frc
Most experiments on dispersion coefficients , both longitu- of available values of lateral dispersivities to particle Peelet equat
dinal and lateral , have been carried out with partieles with a number of 10 or greater. Both longitudinal and lateral disper. was a
very narrow size distribution. There has been little systematic sion coefficients were measured in the Peelet number range matio
effort to determine the effect of partiele size distribution on to 10 the fo
dispersion coeffcients. This information would be of use to
dispersion
porous medium (Whitaker , 1967; Gray, 1975; Bear , 1972). Car- capilaries with radii , lengths , and angular orientations governed
bonell and Whitaker (1983) and Brenner (1980) have shown that by probability distribution functions. The agreement of these 6. Pf
for the case of spatially periodic models of porous media , one can models with experimental data is not complete. For example, the
have a predictive theory that can be used to calculate values of the spatially periodic models studies so far tend to overestimate the 7. B\
dispersion coeffcients without any adjustable parameters. Eidsath Peclet number dependence of axial coeffcients an 8. G,
et al. (1983) have computed axial and lateral dispersion coeffcients grossly underestimate the magnitude and Peclet number depen-
in packed beds based on these spatially periodic models , and have dence of lateral dispersivities. The probabilistic models have many
Page 278 February, 1985 AIChE Journal (Vol. 31, No. AICI
lliI
() =
() =
Is to probleDl unless a constraint of the type shown in Eq. 2 is satisfied , there are
)r oil shale r djustabl parameters , and it is diffcult to predict a priori what
the no experimental data to verify these results for real porous media.
, distributions values of the parameters should be used to represent accurately
addition to im- In principle there can be a serious error in measured values of
ade some pre. dispersion behavior in a given porous medium. In
dispersion coeffcients in packed beds if the constraint of Eq. 2 is
istribution On
proved theoretical and computational efforts, it is important to have 1(3 in Eq. 2 to be
not satisfied. This can be seen clearly if we allow
an expanded data base of dispersion coeffcients which can be used
rous mediuDl. the characteristic length of pores in a bed filed with particles of
k of Niemann to clarify and support theoretical developments and improve our
diameter and void fraction (Whitaker, 1972)
able on ho understanding of the relationship between the structure of the
ffcients. The porous medium and its dispersive properties. In this paper we focus l(3 =d (3)
ically the dis. attention on three aspects of solute dispersion which have not been 1 -
udy the effect carefully examined. The first is the possible dependence of the axial
If the distance from the inlet is L , and the interstitial velocity is
magnitude of dispersi coeffcient on position in a packed bed. The second is
(v)(3 the characteristic time for a dispersion experiment becomes
the effect of the distribution of particle sizes on longitudinal and
IltS. . Substituting these expressions in Eq. 2 , we see that we
lateral dispersion coeffcients , and the third is the Peclet number
L/ (v)
cked beds has
dependence of the lateral dispersivity.
cannot expect the dispersion coefficient in a packed bed to be a
numbers less constant unless the ratio of the distance from the inlet to the particle
From the form of the exact solution to the convective- diffusion
:end the range
equati in laminar flow in a capilary tube , Taylor (1953 , 1954) diameter is related to the Peclet number by
artiele Peclet
was able to argue quite effectively that the dispersion approxi-
ateral disper-
mation would be valid for times
after the pulse injection such that Pe (4)
nber range of 1 -
the following constraint is satisfied
:It where
(1)
(v)(3d
(5)
Here () is a dimensionless time , R is the tube radius , and :I is the :I
parently they did not make a systematic effort to study the effect where D* is the total dispersivity tensor (Carbonell and Whitaker Sy,l
of column length on the measured values of the dispersivity. In this 1983). The total dispersivity has contributions from diffusion a
paper we provide data on longitudinal dispersivities as a function well as hydrodynamic dispersion Figure
;. In the next
the theory of ( c) /mo (23)
s followed by ( C)
The first absolute moment is the mean residence time for the pulse
s and results
at a given axial position
gitudinal and
(X) mdmo. (24)
Substituting Eq. 20 in Eq. 22 with = 1, we find that
Il (x) (0) x/ (vx (25)
where (0) is the mean residence time for the pulse introduced
ation for the
kes the form at = O. From experimental measurements of the mean residence
time at a given axial position one can experimentally determine
the interstitial velocity. Of course , if the bed has a uniform void
(6)
fraction E , this should agree with
Coordinate Step Input Pulse Input Lateral
ad Whitaker System Experiment Experiment Dispersion Q/A
l diffusion a Experiment (Vx (26)
Figure 1. Coordinate system and schematic of longitudinal and lateral dis-
persivity experiments. where Q is the flow rate , A the column area , and is the su-
perficial velocity. The second central moment 1l2(X) is a measure
(7)
of the average pulse spread relative to the mean residence time
varying concentration which is independent of the directions
normal to the flow direction 1l2(X)
J: r (t (C) t)dt (1l
)2 (27)
mo
(8)
(c) =F(t) x=O (15) If we substitute the expression for the Laplace transform of (c)
into Eq. 22 and calculate m2 and 112 we can show that
Since there is zero flux of solute in the and directions along the
column length , Eq. 6 reduces to
(9) (0)j3 (28)
ot
1l2(X) J.2(0) (1l (X) - 1l
:rage defined
o(c)
-=D*
o(c)
ox (C)
xx OX (16) which can also be written as
(10) where D;x is the longitudinal or axial dispersivity. For very long 1l2 (X) 1l2(0) + 2D;, (( (29)
columns it is appropriate to use the boundary condition (vx
: local spatial
value to the (c) -+O asx-+co (17) The quantity
column at
1l2(0) is the spread of the pulse introduced into the
= O. From measurements of 112 at various axial posi-
so that the column outlet does not influence the concentration tions it is possible to use Eq. 29 to cal"ulatethe longitudinal D;x,
(ll) profies in the bed. The solution to Eq. 16 subject to a step change dispersivity, from pulse inputs into the column. Both the pulse
in concentration at the bed entrance response and the step response are convenient techniques for
Hum when a Iheasuring the axial dispersivity. The accuracy of these methods
I of the solute ;I(t) u(t) at = 0 (18)
wil be compared in the section discussing experimental results.
is given by The most convenient technique to measure lateral dispersivities
(12) (c) x- (vx is to consider a steady-state experiment where a uniform concen-
12erc tration of solute is introduced at the column entrance distributed
y'D
ially periodic From measurements of the concentration as a function of time at (C) fco (30)
the tortuosity a fixed axi iI position it is possible to use this relation to compute -Cy-CO
that follows the axial dispersivity.
lie tensor D* 11 is also possible to measure D;x from pulses introduced into the The coordinate system is shown in Figure 1. The concentration at
:hat if Eq. 12 column at = O. These pulse responses can then be analyzed by = 0 is independent of and as a result Eq. 6 reduces to
ensor cannot the method of mom nts. The Laplace transform of the solution to
o(c)
flect itself in
points in the
Eq. 16 subject to the boundary conditions of Eqs. 15 and 17 is given
(vx ):x
ox = D*
(C)
xx ox D*
YY oy
(c)
(31)
(13) The error caused by the neglect of the axial dispersion term is less
se of uniform (c) t)dt n = 0 (21)
than 1% for most values of Furthermore , the boundary con-
ltion reduces = J: dition in Eq. 30 can then be approximated very well by
From a knowledge of the Laplace transform of (c , we can (c) =co u(y) atx=O (33)
compute these moIhents
is a unit step function. Eq. 32 can then be solved subject
(14)
(-l)n-
where u(y)
(c)
= 0 (22)
)fg the flow
(c) =O asy-+::co (34)
luce a time- The absolute moments of (c) with respect to time are obtained
by the simple expression The solution is
31, No.
AIChE JOurnal (Vol. 31 , No. February, 1985 Page 281
y, ,,, .,.,""
Flow Divider
I 16 SPT Fastener
!,:i:' Outlet Manifoid
(.jl:j top
Inlet Distributor dra
'ii'
I.,
\:!I ane
wel
i:ii' (faJ
Manometer
rec
Support Ring Sealing Material
fol.
sol,
ROjameter Right Side of Column onl
eql
Sealing
Lt. Material
sta
tak
lil
cel
lim
Support
Ring Column !in
Pump
Left S,de of Column Wail de:
Figure 2. Overall schematic of experimental equipment. pIa
fl'
Figure 4. Device for lateral motion of probe.
reI
(35) the density of the NaCl solution. This helped in controlling natural con-
t3 vection effects at the lowest Reynolds nurnbers. in)
The concentration of NaCI was measured using the platinum conduc- lat
tivity probes shown in Figure 3. Platinum wires of 0. 065 cm diameter were
and from measurements of (C) t3as a function of we can calculate wound in grooves on the snrfa e of a ny Ion connector a distance of 0. 18 cm in-
the lateral dispersivity. apart. The ends of the platinum wires were soldered to copper wires which
were then inserted in glass melanine tubes of 1.27 cm outer diameter. The id,
tubes were given a thin wax coating to prevent penetration of water. The SOl
EXPERIMENTAL PROCEDURE platinum rings wound around the connector were in direct contact with sir
the fluid phase. All other portions of the wire were out of contact with the
fluid since the v were inserted in the platic tube. The ends of the tubes ex-
Set- tended throug h the column walls and the signals were recorded on a mul-
tichannel recorder. There were five probes located in the column at the
A plexiglas column of square cross section was constructed in order to following distances from the inlet: 2. 8 cm , 25. 7 cm , 47. 0 cm , 112. 1 cm , and fll
perform the experiments outlined in the previous section and shown 147. 6 cm. These probes are labeled 1 through 5 , respectively. Probes 3 and
I.
schematically in Figure 1. An overall diagram of the equipment is shown 4 were designed so that they could traverse the column cross section along
in Figure 2. The width W of the column is 27 cm and the height of the the direction by means of a screw assemblage shown in Figure 4. The total
packing section is 150 cm. A distributor at the top insures flow uniformity. moving span was 15. 2 cm or about 60% of the column width. For every turn
It consists of a 1.2'7 cm plexiglas plate with 0. 32 cm diameter perforations or rotation of the mechanism the probes translated a distance of 0. 16 cm.
every square centimeter. An inlet manifold 5 cm high was outfitted with As a result , it was possible to determine very accurately the probe location
a flow divider in order to perform the lateral dispersion measurements. At for the lateral concentration measurement.
the outlet , a distributor consisting of 1.9 cm diameter PVC tubes 11.4 cm The particles used in these experiments consisted of urea formaldehyde
long insured straight streamlines at the bottom of the porous bed. Two sets spheres of several diameters: 0. 25 cm , 0. 35 cm , 0. 45 cm , and 0. 55 cm. We
of reservoirs , pumps , and rotameters were necessary in order to make the also used glass spheres of 1.00 and 1.58 cm diameters. The density of the
lateral dispersivity measurements. formaldehyde spheres was 1.463 g/cm 3 and those of the glass spheres was
The inlet tracer consisted of NaCI in de- ionized water at approximately 94 g/cm 3 for the 1.00 cm spheres and 2. 83 g/cm3 for the 1.58 cm spheres.
5 X Hr g eq. /L. The molecular diffusivity of NaCI was estimated to be There was a variance of less than 0. 1 % from the mean particle diameter
equalto 1J = 1.545 X 10- , and the Schmidt number to beSc v/1J for both the glass and urea formaldehyde spheres. The void fractions were
= 560. The density of the water which did not contain NaCI was adjusted computed by carefully weighing the particles before inserting into the bed
by adding small amounts of sucrose so that it matched as well as possible and calculating the volume of particles from the density. All the volume
fractions of fluid in this experiment were in the range E = 0. 39 to E =
0.41.
The column was packed by letting the particles settle in water after
stirring and then tamping down slightly. The column was filled about 4
-- c - --- cm at a time using this procedure. Air bubbles were eliminated by de-
T ---- -.. gassing the water prior to use , and by carefully stirring the packing as the
column was being filled.
t:l
Melanine
Tube
:':e or
Wires
cu Wire
Procedure
In the experiments for measuring the longitudinal dispersivities , both
pulse inputs and step inputs were used. In the pulse input experiments the
column was filed with water and drained so that the manifold above the
distributor only contained about 3 mm of water. The solution containing
NaCI was then carefully and slowly introduced into the manifold. The
column was drained slowly so that the band of NaCl solution was introduc
at the top of the packing section. The manifold was filled with water again
and the pumps turned on to the desired flow rate. A recirculation or bypass
line attached to the inlet line of the column was used in order to set the flow
rate to the desired value prior to the start of the experiment. Once the flow
Connector rate was fixed , the fluid was diverted to the column by turning off the by-
( Nylon)
pass valve and turning on the inlet line valve. This way the liquid flow rate
Figure 3. Platinum conductivity probe. was at the desired level throughout the length of the experiment. ThIs
r ' :'111
11!
ca
and longitudinal dispersivity V;.
o .
. 0
. o 80 O
. 0
1.0
1.0
O;J
10;'
1.0
D;X
8 = (
Response
0 Probe 5
. Probe 4
Figure 10. Longitudinal dispersivity dependence on
to Probe 3
Ii .J
1 - E
)) 1. (37
-( 1() the values of D;. are nearly identical for all values of =L ratio of D;. to (D;. )oo oscilates about 1.0 with about a 10% varia-
or probe location. However , as the Peclet number nears 10 tion. This is a good measure of the accuracy of the experiment.
begins to notice a significant difference between the dispersion see that for Ii , one can be assured of being within 90% of the
final constant value of the longitudinal dispersivity. We can con-
coefficient calculated at 25. 7 cm and that computed at 147. 6 cm.
Basicaly, one can observe an increase in the value of the dispersion clude that Eq. 37 is too restrictive , and in fact one can expect
coeffcient with increasing distance down the column. The larger constant longitudinal dispersivities as long as
the value of the Peclet number , the larger the discrepancy between .J
Ii (38)
the dispersion coeffcient measured at = 25. 7 cm and = 147.
cm.
In Eq. 2 we have expressed the time criterion required in order This is the constraint that should be considered when requiring
to obtain a constant value of the longitudinal dispersivity. If we constant longitudinal dispersivities in a transient axial dispersion
associate with time since injection of the pulse the quantity L/ experiment. In Figure 10 we also show the theoretical prediction
dispersion
(v. , and substitute the characteristic length ltJ defined in Eq.
of Paine et al. (1983) on the time dependence of the axial dispersion
, we can rewrite the time constraint in Eq. 2 as coeffcient. Even though this calculation was done for a capilary
tube , one can see a very similar trend to that shown by the data.
In Figure 11 we compare our data for probe 5 , the largest dis-
persion distance , to a great deal of axial data in the lit-
erature , mostly from references listed in Table 1. There is a very
o x 0 147. 6 ern Probe 5 good agreement between our results and previous values even
o x 0 112.1 em Probe 4
to X = 74. 0 ern Probe 3
though our data tend to be on the lower side of the previously
'1 X = 25.7ern Probe 2 published results. We believe this is due to the fact that we have
taken great pains to reduce effe ts due to particle size distributions
0 0
0 to
o to
.. Pfannkuch
v Ebach and While
. Carberry and Bretton
o Edwards and Richardson
gij V Ji.
. Blackwell et al.
o Rital
o This Work ;joif: v .
103
102
102
103
10- 10-
Figure 9. Longitudinal dispersivities from step response experiments-uniform
particles. Figure 11. Longitudinal dispersivily values from various experimenls.
103
1.0
oll ell
. I =112.1 em - Probe 3 lJ Harleman and Rumer (19&3)
o I = 74.0 em - Probe 2 . Gunnand Pryce (1969)
0.7 .. Hasserman and Von Rosenberi (1968)
o ThisWork
102 s8 8
t 0. ;a e- - - - - - - - - -
-; 0.
0.3 p = 873 .
Uniform size distribution
. b,4J!e
0.1 -t 0
18 ) eeee 00o
,fl.
small ratios of column- to-particle diameter , flow nonuniformities
and natural convection induced by density differences. One can 10- 103 104
can expect
short a column for the high flow rates used. As Figure 10 indicates
if the column is too short one can measure a dispersion coeffcient = 6 L ni L ni (39)
that is significantly lower than the final asymptotic value.
where V p and A p are the total volume and surface area of the
(38) is the di-
particles in the bed ni is the number fraction , and
Lateral Dispersivity Measurements- Uniform Particle Size
ameter of each size particle. Equation 39 can be rewritten using
rI requiring the weight fractions and densities of the different particles
In Figure 12 we show a typical plot of the lateral concentration
I dispersion
profies measured during steady-state experiments aimed at de-
I prediction (40)
termining the lateral dispersivities. There is an increase in the L (xd Pi L (xd pi
II dispersion
spread of the concentration profie from = 74. 0 cm to = 112.
. a capilary cm. Equation 35 was used to calculate D;y from known values of This is the most convenient way to compute d from measured
y the data.
(vx P and and the concentration profie. This was accomplished weights of each type of particle. The main difference between size
largest dis- distributions 1 and 2 is that size distribution 2 has a small percentage
by plottig the inverse complementary error function of 2 (c ) P /
:a in the lit- of very large particles where the ratio of maximum to minimum
as a function of and finding the slope (Harleman and Rumer
,re is a very particle diameter is 7. 3. Size distribution 1 has a ratio of maximum
1963). The results are shown in Figure 13 , together with some
ralues even to minimum particle diameter of 2. 2. Even though the large par-
collected values from the literature. The results are independent
previously of probe loction. We have plotted in Figure 13 all of the data taken ticles in size distribution 2 are only a very small fraction of the total
,at we have at both probes. Previous results for lateral dispersivities had covered number , they make up about 11% of the total volume.
istributions the Peelet number range from 10- to 10 . Our data extend the
available values up to :r'Peclet number of 10 . As can be seen from Longitudinal Dispersion
Figure 13 there is very good agreement between our results and
those of Harleman and Rumer (1963) in the Peclet number range /;n measured at different
1: . In Figure 14 we show the values of D
probe locations using step input experiments for the case of a uni-
.:1": where they overlap.
." V'
, 0
TABLE 2. PARTICLE SIZE DISTRIBUTION
Distribution 1 (E = 0. = 0. 35 cm)
Particle type , * i
Particle diameter dpl (cm) 0.45 1.00 1.58
Number fraction 649 237 074 040
Weight fraction
Volume fraction
Distribution 2 (E = 0. = 0. 35 cm)
Particle type, * i
Particle diameter dpl (cm) 0.45 1.00 1.58
Number fraction nj 6604 2808 0566 0017 0045
Weight fraction
Volume fraction 3328 3882 1665 0552 0573
12, 000
10, 000 3445
'1 " Size Distribut,on
0 0 Size Distribution 2
2095
000 Uniform VZ,
1455 1a
940 disj
D;y disl
Size Distribution 1 Ion
000 .'1
3320
000
2174 eXI
1462 the
D;x 803 esti
per
12, 000 Size Distribution 2
3884 102 rad
000
fro
of:
1642
000 Figure 16. Effect of particle size distribution on lateral dispersivities.
940
(Lld niformity near the electrode. This phenomenon was not observed
Probe 2 Probe 3 Probe 4 Probe 5 in either of the other two packings.
Figure 14. Effect of particle size distribution on longitudinal disperslvity at Since size distribution 2 showed a larger required length
various probe locations. achieve constant axial dispersivities , we need to be a little careful
in deciding which are the final asymptotic longitudinal dispersi-
vities measured for this size distribution. Figure 14 indicates that
form particle size , size distribution 1 , and size distribution 2 for for a for 1 642 or less , the longitudinal dispersivity measured
representative Peclet numbers. We note that for size distribution at probe 5 is fairly close to its final value. In comparing the results
1 and the uniform particle size case , the longitudinal dispersivity for the three different size distributions we chose only those particle
values become constant at shorter dispersion lengths than for the Peclet numbers less than 2 000. This way we are more or less as- AtJ
wider size distribution 2. For example , it is not elear that the as- sured of comparing longitudinal dispersivities which have reached
ymptotic value of D /:J has been reached at a Peelet number of their final value at a particular particle Peclet number. In Figure
642 in size distrbution 2. However, for the uniform pareles and 15 we have plotted the highest values of V;, /:J measured for the
size distribution lone sees nearly constant values of longitudinal three size distributions for this small Peclet number range. Note
dispersivities at = 1 455 and 1 462 respectively. It is apparent that there is almost no difference at all between the results for the
that the wider size distribution has a longer characteristic length case of uniform packing and size distribution 1. Since the mean
than that used in Eq. 3. One can conjecture that this is due to a particle sizes are the same , the volume fraction is nearly the same
larger scale nonuniformity in the macroscopic flow field , but there and the ratio of maximum to minimum size is not too far from 1
are not enough data at this time to quantify the effect. Mention one does not observe much of a difference between size distribution
should be made of the apparent slight decrease in the longitudinal 1 and the uniform case. However , the values of D;. /:J for size
dispersivity found at the last probe in the experiments with size distribution 2 are larger by a significant amount (about a factor
distribution 1. We believe this is an artifact in the experiment 2) than those for the uniform particle size case. The two lines of data
caused by either a slight bending of the probe or a packing nonu- are nearly parallel , indicating that one could superimpose them
if there was a re- definition of the characteristic length in the Peclet
number for the case of wide particle size distributions. This
consistent with the results of Figure 14 , which also indicated that
there was a length scale , larger than the mean hydraulic radius,
. Uniform
'1 Size Distribution 1 which dominates the approach to a constant axial dispersivity
. Size Distribution value. ItJ
It should be noted that the three different pac kings used- the
uniform particles and size distributions 1 and 2- have nearly
identical hydraulic radii since they have the same value of and
nearly the same volume fraction. As a result , the observed differ-
ences in longitudinal dispersivities must be caused by the spread
of the size distribution alone. Eidsath et al. (1983) computed lon-
c;x 103 gitudinal dispersivities in two dimensional spatially periodic arrays
of cylinders with two different radii. They found that when the
ratio of cylinder radii was increased from 2 to 5 , the axial dis-
persivity increased by a factor of 1.5 at the same Peclet number.
This is an increase of the same order as was found in the experi-
mental observations presented in this work. Carbonell (1979) also
found a very strong dependence of longitudinal dispersivities
the spread of pore size distributions for a very simple capilary tube
model of the porous medium. If one is wiling to associate an in-
creased particle size distribution with an increased pore size dis-
102 tribution , the trend observed in the experiments just described
103
at least qualitatively the same as that predicted by the theory.
Additional experiments need to be done before this effect can
understoo fully, but it is clear that one needs to emphasize the role
Figure 15. Longitudinal dispersivities for uniform particles, size distribution of the width of the particle size distribution on the dispersion
1 and size distribution 2. process.
LITERATURE CITED
1,0. AIChE Journal (Vol. 31, No. February, 1985 Page 287
, " , :' , " , ", " ," ,,""
Porous Media , MS Thesis, Chem. Eng. Dept. , Purdue Univ. , Lafayette Slattery, J. c. Momentum , Energy, and Mass Transfer in COntinua
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SCOPE
Granular fitration has been applied extensively in the past vantage of continuous operation , which is desirable in large.
to control particulate emission and has proven effective for scale applications.
partieles with a wide size range. It is particularly suitable for This paper reports results obtained from a systematic exper-
operation under high temperature and pressure conditions. On imental study of the performance of magnetically stabilzed
the other hand, granular fitration is inherently unsteady state. fluidized (MSF) filters. The effect on filter performance of
The accumulation of fine particles within a filter requires pe- number of variables was examined, ineluding the magnetic field
riodic media regeneration. strength, gas velocities , bed height , and the size of fluidized
A possibleway of overcoming the shortcomings arising from partieles. Experiments were also conducted on the extent of
the cyelic nature of granular filtration is to operate filter beds partiele re-entrainment.
in the fluidized mode, thus allowing a continuous withdrawal The concept of the unit collector efficiency proposed by TieD
and introduction of fiter grains. Furthermore, if fluidization and Payatakes (1979) was used to assess the effectiveness of MSF
is carried out with magnetic stabilzation , the presence of gas filters and as a basis for comparing the performance of a MSF
bubbles in the bed can be eliminated and/or reduced. One may filter with its equivalent fixed-bed filter. The feasibilty
speculate that such an arrangement offers an ideal combination employing a phenomenological rate expression to describe the
of high collection effciency of granular fitration and the ad- dynamic behavior of MSF fiters was also demonstrated.