31st Oct-2th Nov, 2017,Milad Tower convention center, Tehran, Iran
ANGVA2017.xxx
Hydrogen via Adsorption Storage
Alireza Abedin1, Seyed Hadi Mousavi2, Shima Najafi Nobar3
1Faculty of Mechanical Engineering; K.N. toosi University; Abedini.kntu@yahoo.com
2 Faculty of Mechanical Engineering; K.N.toosi University; sd.hadi.mousavi@gmail.com 3 Faculty of Mechanical Engineering; K.N.toosi University; sh.najafi@kntu.ac.ir
Abstract drive a vehicle about 200 Km in below 5 min refueling
A Comparison between hydrogen storage methods time and thats very appropriate. have been done and three type of adsorbent such MOF Conclusions and Carbon based materials have been investigated. For use of Hydrogen as a clean fuel in the vehicles, Three factors have been evaluated and the best Storage has a key element. Adsorption is the best adsorbent selected. method for vehicles purpose. In this work, evaluation Keywords: Hydrogen, Storage, Adsorption, Porous. of different type of adsorbents to choose best adsorbent have been done at different operational conditions. Introduction The main resource of energy is relying on fossil fuels and these resources have two main issues. These resources are depleting and have environmentally effect on the world. Therefore need to a non-toxic and high density energy carrier is necessary. Hydrogen as a green fuel with high energy density is a very good candidate to supply world energy demand. The storage of hydrogen for use in vehicles is perhaps the most difficult problem to overcome. There are many methods for hydrogen storage but that is not appropriate for vehicles. Adsorption of hydrogen is a very good candidate to storage it for vehicles purpose. Porous materials that have nanometer-sized pores is appropriate to use as an adsorbent. A wide range of carbons and metal-organic framework (MOF) and Zeolite materials with a wide variety of pore structure, surface chemistry, and structural flexibility have been studied. Two parameters for investigation of best adsorbent have been measured at two Temperatures: 1. Surface area of adsorbent 2. Pore volume of adsorbent
The best condition for adsorbents takes place at
cryogenic region but as this region its hard and expensive to reach and not appropriate for vehicles purpose, the amount of adsorption measured at ambient temperature.
Results and Discussion
Increase in the size of surface area leads to increase in the adsorbed amount but decrease in the amount of pore volume leads to increase of adsorbed amount and its shown adsorption in the micro-pores is most important than macro-pores. Carbon based adsorbent has a best condition. According to DOE1 report by this amount of adsorption on carbon based adsorbent can 1 Department of Energy (USA)
(Chemical Engineering Methods and Technology) Oscar L. Ortiz, Luis D. Ramirez-Coordination Polymers and Metal Organic Frameworks__ Properties, Types and Applications-Nova Science Pub Inc (2012)_2.pdf