You are on page 1of 1

1

XI (F.Sc.) CHEMISTRY CHAPTER # 3

26-10-2013 10 10 MINUTES

Q.No.1 Choose the best option. 10


(i) Which of the following is contrary to kinetic molecular theory of gases?
(a) volume of gas is neglible (b)effect of gravity upon gas molecular is neglible
(c)there are present forces of attraction among the gas molecules
(d) kinetic energy of gas molecules is directly related to absolute temperature
(ii) In a mixture of two gases H2 excretes 200 torr and N2 exerts 800 torr partial pressure. Then
we can conclude:
(a) moles of H2 are greater than N2 (b) moles of N2 are greater than H2
(c) moles of gases are not related to partial pressure (d) moles of N2 are equal to moles of H2
(iii) At STP one mole of H2 gas occupies 22.414dm3 volume of 1 mole of CH4 is ______through it
is 8 times havier than H2.
(a) 44.8dm3 (b) 22.414cm3 (c) 22.414dm3 (d) 11.2dm3
(iv) Amount of energy required to raise temperature of 1 mole of an ideal gas by 1K is:
(a) 8.314 kJ (b) 8.314J (c) 8.314cal (d) 4.18J
(v) According to Van der Waals a is the measure of attractive forces among the gas molecules.
For which gas its value should be maximum.
(a) H2 (b) N2 (c) SO2 (d) NH3
(vi) No of molecules in 1dm3 of water is close to:
(a) 6.2 1023 (b) 12.04 1023 (c) 18 1023 (d) 55.6 x6.02 x 1023
22.4 22.4 22.4
(vii) Equal masses of CH4 and oxygen are mixed in an empity container at 25oC. The fraction of
total pressure exerted by O2 is:
(a) 1/4 (b) 1/3 (c) 8/9 (d) 16/17
(viii) Select most appropriate statement about meta stable particles:
(a) they are more stable than ground state of atoms
(b) they are selective in their activity (c) they are always radioactive
(d) they are radioactive with small half life
(ix) The molar volume of CO2 is maximum at:
(a) STP (b) 127oC & 1atm (c) 0oC & 2atm (d) 273oC & 2atm
(x) The order of rate of diffusion of four gases NH3, CO2, SO2, and Cl2 is:
(a) NH3 > SO2 > Cl2 > CO2 (b) Cl2 > SO2 > CO2 > NH3
(c) Cl2 > SO2 > CO2 > NH3 (d) NH3 > CO2 > Cl2 > SO2

30 50 MINUTES

Q.No.2 Give Short Answers. 10x2=20


(i) Water vapours do not behave ideally at room temperature. Justify.
(ii) Why densities of gases are expressed in g/dm3 rather than g/cm3?
(iii) In equation PV = K. K depends upon temperature justify.
(iv) Calculate no of molecules in 1CC of CH4 at STP.
(v) Give necessary conditions for the gases to be ideal or non-ideal.
(vi) Why critical temperature of CO2 is greater than O2?
(vii) How temperature change affects density of an ideal gas?
(viii) Why isotherm goes away from both the axis at higher temperature?
(ix) Differentiate diffusion and effusion.
(x) Why gas molecules do not settle down in a vessel?
Q.No.3(A) Define daltons law of partial pressure. Derive formula to calculate value of partial
pressure for an ideal gas in a mixture of gases.
(B) What pressure is exerted by a mixture of 2g of H2 & 8g of N2 at 273K & 10dm3 vessel? 05

You might also like