M8

1stYear Chemistry Ch # 9
12-03-2016 12 10 Min

Q#1 Encircle the right option. 1x12=12

(i) The Unit of mole fraction when partial pressure of a particular gas and total pressure of all gases takes
into account.
(a)torr (b)atm (c)bass (d)no unit
(ii) The unit of concentration which depends upon the temperature is____
(a)Molarity (b)Mole fraction (c)parts per million (d)Molality
(iii) The example of partially miscible liquids ______
(a)H2O +C2H5OH (b)H2O +C6H5OH (c)H2O + CS2 (d)H2O + C6H6
(iv) In Raoult’s law (When both compounds are volatile) the straight line is obtained which explains the
behavior of ____solution.
(a)Normal (b)Ideal (c)Non- Ideal (d)clear
(v) Which of the following solutions boils at highest temperature?
(a)0.1 M Urea (b)0.1 M Ca(NO3)2 (c)0.1 M Al(NO3)3 (d)0.1 M sucrose
(vi) Consider, A component is less volatile then B component then residue keft behind in solution after
distillation.
(a)A (b)B (c)Both A and B (d)Distillation is not possible
(vii) 18 g glucose is dissolved in 90 g of water. The relative lowering of vapour pressure is equal to
1 1
(a)5 (b)5.1 (c)51 (d)6
(viii) A solution of glucose is 10% w/v. The volume in which 1 g mole of it is dissolved will be
(a)1dm3 (b)1.8dm3 (c)200cm3 (d)900 cm3
(ix) An azeotropic mixture of two liquids boils at a lower temperature than either of them when:
(a)it is saturated (b)it shows positive deviation from Raoult’s law
(c)it show negative deviation from Raoult’s law (d) it is supersaturated
(x) In azeotropic mixture showing positive deviation from Raoult’s law, the volume of the mixture is
(a)slightly more than the total volume of the components
(b)slightly less than the volume of the components
(c)equal to the total volume of the components (d)none of these
(xi) Two solutions of NaCl and KCl are prepared separately by dissolving same amount of the solute in water.
Which of the following statements is true for these solutions?
(a)KCl solution will have higher boiling point than NaCl solution.
(b)Both the solutions have different boiling points.
(c)KCl and NaCl solutions possess same vapour pressure.
(d)KCl solution possesses lower freezing point than NaCl solution.
(xii) The molal boiling point constant is the ratio of the elevation in boiling point to
(a)molarity (b)molality (c)mole fraction of solvent (d) mole fraction of solute

SUBJECTIVE TYPE Total Marks 28 Time 50 MINUTES

Allowed
Q#2 Write short answer of the following questions. 𝟏𝟎 ×2=20
i. The concentration in terms of molality is independent of temperature but molarity depends upon temperature.
ii. The sum of mole fractions all the components is always equal to unity for any solution.
iii. What are azeotropic mixtures?
iv. The boiling point of one molal urea solution is 100.52º C but the boiling point of two molal urea solution is less
than 101.04ºC.
v. How in summer the antifreeze solutions protect the liquid of the radiator from boiling over.
vi. Define water of crystallization with examples.
vii. What is meant by solubility curve? Give its types.
viii. If sea water has 5.65×10-3 in one Kg of water calculate concentration of oxygen in ppm.
ix. Compare ideal and non-ideal solutions.
x. Define molality. Give formula also.
Q#3 a) Define Raoult’s law in three different ways. 04
b) How depression in freezing point is helpful in determining the molar mass of nonvolatile and
non-electrolyte solute. 04