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a
Thermal Engines and Renewable Energies Group MYER, School of Engineering, University of Valladolid, E-47011 Valladolid, Spain
b
CIDAUT Centre for Automotive Research and Development, E-47151 Boecillo, Spain
Received 20 October 2005; received in revised form 28 April 2006; accepted 10 May 2006
Available online 10 July 2006
Abstract
This article discusses a mathematical model for the thermochemical processes in a downdraft biomass gasifier. The model combines
the chemical equilibrium and the thermodynamic equilibrium of the global reaction, predicting the final composition of the producer gas
as well as its reaction temperature. Once the composition of the producer gas is obtained, a range of parameters can be derived, such as
the cold gas efficiency of the gasifier, the amount of dissociated water in the process and the heating value and engine fuel quality of the
gas. The model has been validated experimentally. This work includes a parametric study of the influence of the gasifying relative fuel/air
ratio and the moisture content of the biomass on the characteristics of the process and the producer gas composition. The model helps to
predict the behaviour of different biomass types and is a useful tool for optimizing the design and operation of downdraft biomass
gasifiers.
Ó 2006 Elsevier Ltd. All rights reserved.
1. Introduction the charcoal that has passed through the oxidation zone
without reacting, forming the final producer gas.
The gasification process in a downdraft gasifier can be A wide variety of theoretical and experimental works on
divided into four parts. In a first and second stage, the bio- biomass gasification have been published. Their main goal
mass is dried and converted into volatile substances and is the study of the thermochemical processes during the
charcoal. The third exothermic stage, where the volatile gasification of the biomass, evaluating the influence of
substances are partially oxidised, provides the heat con- the main input variables, such as moisture content and
sumed during the first and second stages, as well as in the air/fuel ratio, the producer gas composition and its calorific
last, char gasification, stage [1]. In the oxidation zone, vol- value. Some studies only consider the final composition in
atile molecules are broken down into smaller molecules. If chemical equilibrium [2–6], while others take into account
the temperature reached in this zone is not high enough, the different processes along the gasifier, distinguishing at
part of the volatile molecules, characterised by their high least two zones [1,7,8].
molecular weight such as tars, can pass through this zone Altafini and Mirandola [2] present a coal gasification
and condense when cooled, causing serious problems in model by means of chemical equilibrium, minimizing the
certain applications such as the use of producer gas in Gibbs free energy. The authors analyse the influence of
reciprocating internal combustion engines. In the last stage, the ultimate analysis and the gasifying agents/fuel ratio
the main part of the sensible enthalpy of the combustion on the equilibrium temperature (adiabatic case) in order
gases is consumed during the reduction of these gases by to obtain the producer gas composition and the overall
and conversion efficiency. They conclude that the equilib-
rium model fits the real process well. Similar conclusions
*
Corresponding author. Tel.: +34 983 423367; fax: +34 983 423363. for biomass gasification are presented by the same authors
E-mail address: juanpb@eis.uva.es (J.F. Pérez). [3], simulating the gasifying process in a downdraft gasifier,
0196-8904/$ - see front matter Ó 2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.enconman.2006.05.004
60 A. Melgar et al. / Energy Conversion and Management 48 (2007) 59–67
Nomenclature
where the object of study is the effect of the biomass mois- effect of the operating parameters (biomass moisture and
ture content on the final gas composition assuming chemi- ultimate analysis, temperature and amount of gasification
cal equilibrium. The biomass gasification process is agent) on the producer gas composition, its heating value
modelled by Zainal et al. [4] based on thermodynamic equi- and the process efficiency. A description of a two zone
librium. They investigate the influence of the moisture con- model in a downdraft gasifier is adapted by Jayah et al.
tent and reaction temperature on the producer gas [8] where the two zones correspond to flaming pyrolysis
composition and its calorific value. Lapuerta et al. [5] pre- and the gasification. In the flaming pyrolysis zone, the pro-
dict the producer gas composition as a function of the fuel/ ducer gas composition and its temperature is estimated by
air ratio by means of an equilibrium model. A kinetic chemical equilibrium. These parameters form the input of
model was used to establish the freezing temperature, the second zone where a char particle is considered to move
which is used for equilibrium calculations in combination downwards vertically through the gasifying zone. The
with the adiabatic flame temperature. Ruggiero and model estimates the temperature profile, the producer gas
Manfrida [6] emphasize the potential of the equilibrium composition and conversion efficiency throughout the gas-
model considering the Gibbs free energy. This proceeding ifying zone. The model is calibrated with experimental data
can be used under different operating conditions for from a downdraft gasifier. The model has been applied to a
predicting producer gas composition and the correspond- sensitivity study with variable biomass size, moisture con-
ing heating value. tent, inlet air temperature, heat loss and throat angle;
A model for studying the biomass gasification with which attempts to optimize the gasifying zone length by
steam in fluidized bed gasifiers is presented by Schuster means of maximizing the conversion efficiency. Di Blasi
et al. [7]. The model considers two zones, one gasification [1] presents a dynamical one-dimensional model (solid
zone (fluidization with steam) and a combustion zone, in and gaseous phase) of a downdraft gasifier that considers
which the producer gas composition is estimated through the evaporation of water, the pyrolysis, combustion and
an equilibrium model with Gibbs free energy minimization. gasification of char, the combustion of the gaseous phase
The model is used for a parametric study considering the and the thermal cracking of tars and takes into account
A. Melgar et al. / Energy Conversion and Management 48 (2007) 59–67 61
the heat transfer along the gasifier. The author studies the tants is supposed to be high enough to reach chemical equi-
effect of the air/fuel ratio on the dynamics and efficiency of librium, a hypothesis that has been confirmed by other
the gasifying process and the composition and quality of authors, such as Ruggiero and Manfrida [6] and Zainal
the producer gas. et al. [4]. Secondly, we assume that all the carbon in the
An experimental study is described by Zainal et al. [9] biomass is gasified, and thereby, the formation of charcoal
using a downdraft gasifier fed with wood industry residues. can be neglected.
The authors determine the influence of the air/fuel ratio on Through the energetic balance of the process, it is possi-
the producer gas composition, its heating value and the ble to estimate the final reaction temperature and calculate
overall efficiency. Rao et al. [10] study the exergetic irrever- the producer gas composition in equilibrium as a function
sibilities of a downdraft gasifier plant, comparing different of this temperature. The model also takes into account the
types of biomass. heat loss in the reactor and the preheating of the reactants.
In order to increase the efficiency of downdraft biomass Because the chemical equilibrium constants and the ther-
gasification plants a thermochemical model has been pre- modynamic characteristics of the gases, such as the specific
sented. This model is based on the chemical equilibrium heats, are functions of temperature, this parameter is
of the process, minimizing the Gibbs free energy, while adapted in each iteration of the calculation process, reach-
considering the process to be stationary. Through this ing, in the end, a thermodynamic as well as a chemical
model, we attempt to study the influence of the input equilibrium. The maximum temperature that can be
parameters, such as the relative gasifying fuel/air ratio, reached is affected by the relative gasifying fuel/air ratio
the moisture and the biomass composition, and to establish and the biomass moisture content, two parameters that
some parameters that determine the overall process have been studied in greater detail in Section 3.
efficiency.
If the installation is working properly, we can assume 2. Methodology
that the products leaving the gasifier are all gaseous, pre-
dominated by chemical species of minor molecular weight, In Fig. 1, the structure of the equilibrium model has
principally CO, CO2, H2O, H2, N2 and CH4 and traces of been presented. In a first stage, starting from the mass frac-
other chemical substances. tions of carbon, hydrogen, oxygen, nitrogen and sulphur
Because the work produced during the gasifying process (CHONS) in the biomass and the relative mass of the mois-
equals zero and the heat losses are very small and can, thus, ture, the substitution fuel and the molar water content can
be neglected, the enthalpy of the reactants entering the pro- be calculated. From the gasifying relative fuel/air ratio, the
cess and the enthalpy of the products leaving the process molar quantity of air consumed during the process can be
are equal. The combination of the laws of conservation obtained. The total enthalpy of the reactants is also
of energy in an open system, the chemical laws of conserva- calculated.
tion of atomic species and the laws of chemical equilibrium In the second stage, the composition of the producer gas
provides a tool to predict the composition of the final pro- is estimated, minimizing the Gibbs free energy for calcula-
ducer gas. tion of the equilibrium constants. A Newton–Raphson
The proposed thermochemical model assumes two algorithm has been implemented. A posteriori, the reaction
important hypotheses. First, the residence time of the reac- temperature corresponding to the actual producer gas
HM C OM C NM C SM C ðP CH4 =P 0 Þ
m¼ ; p¼ ; q¼ ; r¼ ð1Þ K1 ¼ ð12Þ
CM H CM O CM N CM S ðP H2 =P 0 Þ2
From the substitution fuel formula, the specific molecular or as a function of the molar composition, assuming the
weight of the biomass, the molar quantity of water per behaviour of the producer gas to be ideal, taking into ac-
mole of biomass [4]; the stoichiometric air/fuel ratio and count the low working pressures (1 atmosphere)
the formation enthalpy of the biomass [11] can be
determined. dnT
K1 ¼ ð13Þ
c2
M bm h
w¼ ð2Þ
M H2 O ð1 hÞ The second reaction, also known as the water gas shift
1 X reaction, describes the equilibrium between CO and H2 in
hf;bm ¼ LHV db þ mi ~
hf;i ð3Þ the presence of water
M bm i¼prod
CO þ H2 O $ CO2 þ H2 ð14Þ
2.2. Chemical equilibrium We obtain the corresponding equilibrium K2 constant as
2.4. Water dissociation The variable Xa depends on the molecular weight of the
producer gas, while Fst,e represents the stoichiometric
With the equilibrium model, it is possible to predict the fuel/air ratio of the producer gas.
conditions under which part of the moisture is converted
into hydrogen, or the other way around, more water is pro- 3. Discussion and results
duced during the biomass-gas conversion than was initially
present. The dissociation factor can be calculated as the 3.1. Validation of the model
difference between the molar quantity of water in the pro-
ducer gas (e) and the initial molar quantity of water in the The model presented in this article has been compared
biomass (moisture, w) to the experimental and predicted producer gas composi-
tions presented by Jayah et al. [8], and the results are pre-
DH2 O ¼ e w ð26Þ sented in Table 1 (the bold face values have been calculated
in this work). The authors calibrate their model by the
If DH2 O < 0, part of the moisture has been decomposed into methane content. As we did not take into account the ther-
hydrogen. mal loss in the gasifier, our predicted values for methane
64 A. Melgar et al. / Energy Conversion and Management 48 (2007) 59–67
Table 1
Comparison between experimental and model predicted compositions for
the producer gas of rubber wood with 14.7% moisture content
Producer gas Model [8] Experimental [8] This work
composition (vol%)
CO 18.3 19.1 19.2 19.3
H2 16.4 15.5 16.6 17.6
CO2 11.1 11.4 11.0 11.1
CH4 1.1 1.1 0.2 0.4
N2 53.2 52.9 53.0 51.6
Frg 2.3 2.39 2.3 2.4
Fig. 4. Adiabatic temperature of the gasifying process as a function of the gasifying relative fuel/air ratio and the moisture content and the variation of the
methane concentration as a function of the adiabatic temperature. (a) Tad 800:100:2000 (K) and (b) CH4 vs Tad (K).
Fig. 5. Volumetric distribution of the components in the producer gas as a function of the gasifying relative fuel/air ratio and the moisture content of the
biomass. (a) CO 5:5:30 (%); (b) CO2 8:2:24 (%); (c) CH4 2:2:12 (%); (d) H2 2:2:16 (%); (e) H2O 2.5:2.5:20 (%); (f) DH2O 0.4:0.1:0.4 (%).
an appropriate design of the gasifier is it possible to sustain 3.2.2. Producer gas composition and quality
the process in these conditions [18]. In Fig. 5, the composition of the producer gas obtained
Through the equilibrium constants, the temperature from pine bark has been represented as a function of the
influences the chemical equilibrium reached in the gasifier biomass moisture content h and the fuel/air ratio Frg.
and the producer gas composition. The distribution of the concentrations of the different
66 A. Melgar et al. / Energy Conversion and Management 48 (2007) 59–67
Fig. 6. LHV and EFQ of the dry producer gas as a function of the gasifying fuel/air ratio and the moisture content of the biomass. (a) LHV 500:500:7500
(kJ/kg) and (b) EFQ 250:250:2500 (kJ/kg).
the gasification. Similar results are presented by other AP2003-1686; and the Programme AlBan, the European
researchers, who also conclude that the process efficiency Union Programme of High Level Scholarship for Latin
diminishes with increasing moisture content in the biomass America, scholarship No. E04D046253CO.
[3,4,7,8].
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