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Safety Data Sheet Toa Resin Corporation Limit

1. Identification
Product Name : Acrylic resin TOA ACRON XE-7036
Other Names:--
Recommended use and restrictions on use: For fabric coating
Names, addresses, and phone numbers of the manufacturer or supplier:
Names: Toa Resin Corporation Limited
Addresses: No. 15, Sun-Ming Rd., Hsin Chu Industry District, Hsin Chu, Taiwan, R.O.C
email:sales@toaresin.com.tw
Phone numbers: +886-3-5981224
Emergency contact phone numbers/fax numbers:
Emergency Number: +886-3-5981224
Fax numbers: +886-3-5981562

2. Hazards Identification
Product hazard class:
Flammable liquids 2
Acute toxicity oral 4
Serious eye damage/eye irritation 2A
Specific target organ systemic toxicity(single exposure ) 2
Aspiration hazard 1
Skin irritation category 2
Label content:
Symbol:Flames、Health hazards、Hazard

Signal Words:Warning
Hazard Statements:
Highly flammable liquid and vapor
Harmful if swallowed
Causes eye irritation
Causes skin irritation
May cause damage to organs through prolonged or repeated exposure
May cause kidney exhaustion
May be fatal if swallowed and enters airways.
Precautionary Statements:
1. For eye contact, immediately flush eyes with plenty of running water for at least 15 minutes.
Call a physician.
2. Keep away from heat and sources of ignition.
3. Store in a cool and dry place with good ventilation.
4. Wear proper gloves.
5. Avoid contacting with skin and eyes.
Other hazards:--

3. Composition/Information on Ingredients
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Pure material:
English name: Acrylic resin
Synonyms: --
Chemical Abstract Service No.(CAS No.): 67254-76-6
The hazardous ingredient (% of the content): 15

Mixture:
Chemical property:
English names of the hazardous ingredients Toluene
Chemical Abstract Service No.(CAS No.): 00108-88-3
Concentration or concentration ranges
85
(ingredient percentage)

4. First-aid measures
The first-aid measures for different exposure routes:
Inhalation:
Remove personnel from exposure area to fresh air immediately. If breathing is diffcult give
oxygen. If breathing ceases. Use a oxygen rescuer or similar device to perform artificial
respiration. Get medical attention immediately.
Skin contact:
Remove contaminated clothing. jewelry and shoes immediately. Wash with soap or mild
detergent and large amounts of water until no evidence of chemical remains(at least 15~20
minutes). If irritation or adverse system symptoms develop. seek medical attention.
Eye contact :
Flush eyes immediately with running water for at least fifteen minutes occasionally lifting
upper and lower lids, until no evidence of chemical remains.Get medical attention
immediately.
Ingestion:
Contact local poison control center or physician immediately. Never make an unconscious
perpon vomit or drink fluids When vomiting occurs, keep head lower than hips to help prevent
aspiration.If person is unconscious, turn head to side. Get medical attention immediately.
The most important symptoms and hazardous effects:
The protection of first-aiders:
wear nitrile rubber and neoprene gloves.
Notes to physicians:
according to different symptom with proper treatment and cure.

5. Fire-fighting measures:
Suitable fire extinguishing media: Dry Chemical, CO2, Water Spray, Foam.
Specific hazards may be encountered during fire-fighting:
Severe fire hazard. Vapor/air mixtures are explosive. The vapor is heavier than air Vapors or gases
may ignite at distant igmition sources and flash back. Electrostatic discharges may be generated by
flow or agitation resulting in igmition or explosion.
Specific fire-fighting methods:
1. Firefighters should wear proper protective equipment. Stay upwind and keep out of low areas.
2. Move container from fire area if it can be done without risk.
3. Cool container with water spray until well after the fire is out.

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4. Withdraw immediately in case of rising sound from venting safely device or any discoloration of
tanks due to fire.
5. For fires in cargo or storage area :Cool containers with water from ummanned hose holder or
monitor nozzles until well after fire is out.
6. For tank. rail car or tank truck: Evacuation radius:800 meters (1/2miles)
7. Do not scatter spilled material with high-pressure water steams.
8. Keep unnecessary people away, isolate hazard area and deny entry.
9. Let the fire burn. Water many be ineffective.
Special equipment for the protection of firefighters: As in any fire, wear self-contained
breathing apparatus pressure-demand, NIOSH (approved or equivalent) and protective rubber and
fire fighting clothes.

6. Accidental release measures:


Personal precautions:
1. Wear suitable protective device.
2. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry.
3. Notify Local Emergency Planning Committee and State Emergency Response Commission for
release greater than or equal to RQ(U.S. SARA Section 304)
Eye protection: Wear chemical splash goggles.
Respiratory protection: Use NIOSH approved respirator when ventilation is inadequate.
Hand protection: Nitrile rubber. Neoprene gloves.
Skin and body protection: wear personal protective clothing and equipment
Environmental precautions:
1. Avoid heat, flames, sparks and other sources of ignition.
2. Stop leak if possible without personal risk.
3. Provide appropriate protective device and ventilation equipment.
Methods for cleaning up:
1. Air release :Reduce vapors with water spray.
2. Soil release :Dig holding area such as lagoon, pond or pit for containment. Dike for later
disposal. Absorb with sand or other non-combustible material. Collect with
absorbent into suitable container.
3.Water release :Cover with absorbent sheets, spill-control pads or pillows. Apply detergents, soaps,
alcohols or another surface active agent. Collect with absorbent into suitable
container. Absorb with activated carbon. Remove trapped material with suction
hoses. Collect spilled material using mechanical equipment. Keep out of water
supplies and sewers.
4. Clean up small spills using sand or other non-combustible material.
5. Collect spilled material in appropriate container for disposal.
6. Large spills:Dike for later disposal.
7 Where feasible and appropriate remove contaminated soil.

7. Handling and storage:


Handling:
1. Wear protective equipment, if exposure conditions warrant.
2. Wash thoroughly after handling.
3. Use with adequate ventilation.
4. No smoking in work area.
5. Protect from physical damage.

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6. When transport or mix.container should be grounding and bonding.


7. Handle in accordance with all current requlations and standards.
Storage:
1. Keep away from heat, sparks and flames.
2. Store in a cool, dry, well-ventilated area.
3. Store in tightly closed container.
4. Store outside or in a detached building.
5. Bond and ground during transfer.
6. Keep separated from incompatible substances.
7. Storage in accordance with all current regulations and standards.
8. Subject to storage regulations.

8. Exposure controls/personal protection:


Engineering control:
Provide appropriate exhaust ventilation at machinery and at places where dust or fumes can be
generated. Ensure that eyewash stations and safety showers are proximal to the work-station
location.
Control parameters :
8 hours time weighted average exposure limits/Short-term exposure limits/maximum exposure
limits:--
biological standards:--
Personal protective equipment :
Respiratory protection: Use NIOSH approved respirator when ventilation is inadequate.
Hand protection: Nitrile rubber. Neoprene gloves.
Eye protection: Wear chemical splash goggles.
Skin and body protection : wear personal protective clothing and equipment
Hygiene measures:
1. No smoking and drinking in work place.
2. keep good habit to maintain administrative work.

9. Physical and chemical properties:


Appearance (Physical state, color, etc):
Physical state: Paste Odor: Aromatic odor
Color: Clear solution
Odor threshold:-- Melting point: --
pH value : -- Boiling point/boiling point range : 109~113℃
(230~234℉)
Flammability (solid, gas):-- Flash point: 4.4℃
Decomposition temperature:-- Test method: close cup
Auto-ignition temperature:-- Explosion limits: --
Vapor pressure: 22 ㎜Hg - Psi Vapor density (air=1):3.14
Density:-- Solubility : no solved
Partition coefficient (n-octanol/water, log Evaporation rate: 2.24
Kow): 2.73

10. Stability and reactivity:


Stability : Stable at normal conditions.

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Possible hazardous reactions under specific conditions: none


Conditions to avoid: Exposure to moisture. Heat, flames and sparks.
Materials to avoid: Strong reducing agent.
Hazardous decomposition products: Carbon oxides. Hydrocarbons. Metal fumes.

11. Toxicological information:


Routes of exposure:
Eye contact: Contact with eyes may cause irritation. Prolonged or repeated exposure may cause
irritation, pain, conjunctivitis and possible corneal damage.
Skin contact: Prolonged skin contact may cause skin irritation and/or dermatitis.
Inhalation: May cause irritation of respiratory tract. Inhalation of high vapor concentrations can
cause CNS-depression and narcosis.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

1. LD50: <870mg/Kg
2. LC50: 6,000ppm/6H

Symptoms:
1. Skin irritation and sensitization.
Acute toxicity :
Inhalation: Oder detection may be insufficient for warning due to olfactory fatigue. Exposure to
100ppm many cause irritation . 200~600ppm for up to 8 hours caused fatigue, weakness,
confusion, headache, nausea, impaired coordination and reaction time, paresthesias of
the skin, euphoria, dizziness, and dilated pupils. 800 ppm cause rapid irritation, nasal
mucous secretion, metallic taste drowsiness, and impaired balance. After effects
including nervousness, muscular fatiges, and insomnia lasted for several days. A worker
found unconscious after exposure to high vapor concentrations for 18 hours developed
hepatic and renal damage with myoglobinuria. Recovrey was complete within 6 months.
Hematologic effects occur rarely with exposure to high concentrations.
Skin contact:Contact with the liquid may cause irritation. Vapors may cause drying .Skin absorption
does occur. But it is generally too slow to produce signs of acute systemic toxicity.
Eye Contact:Liquid may cause irritation and corneal burns if not promptly removed.
Concentrations. around 300~800 ppm may cause noticeable irritation and lacimation.
Corneal lesions and very fine vacuoles have been reported in worker exposed to a
solvent containing toluene.
Ingestion: May cause a burning sensation in the epigastrium and abdominal spasms, Systemic
effects may occur as described in acute inhalation . Aspiration of the liquid into the
lungs may cause coughing gagging, distress, acute hemorrhagic pneumonitis, and
rapidly developing pulmonary edema.
Chronic toxicity or long term toxicity :
Inhalation: Repeated or prolonged exposure may cause mucous membrane irritation. vomiting.
insomnia. nosebleeds. chest pains. euphoria. headache. vertigo. nausa. anorexia.
momentary loss of coordination and impairment of reaction time. tinnitus. impaired
speech. vision. and/or hearing. Alcohol intolerance. and petechiae and abnormal
bleeding. Bone marrow hypoplasia and leucopenia have been reported occasionally. but
may be due to benzene contamination. Examination of workers esposed to 100~1100
ppm revealed hepatomegaly. mild macrocytosis. moderate erythropenia. and absolute
lymphocytosis but no leuckopenia. Other workers exposed to toluene fumes developed

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leuckopenia and especially neutropenia. Within 6 months. they showed decreased


prothrombin level and increased coagulation time Periodonal effects were also
noted.Volunteers exposed to 200 ppm for 6 hours/day for 2 days showed a significant
increase in heart rate Cardiac sensitization may occur and may result in cardiac arrest
due to ventricular fibrillation. Chromosome chages were observed in some workers up
to two years after cessation of occupationally exposed to toluene levels of 60~100 ppm
Reproductive effects have also been reported in animals.
Skin contact:Repeated or prolonged contact with the liquid many cause defatting of the skin with a
dry fissured dermatitic. Repeated application to rabbit skin produced slight to
moderate irritation and slight necrosis.
Eye Contact:Repeated or prolonged contact with irritation may cause conjunctivitis.
Ingestion: No effects were reported in rats fed up to 590 mg/Kg/day for 193 days.

12. Ecological information:


Ecotoxicity:
Fish toxicity :8110 ug/L 96 hours LC50(Mortality)Coho salmom. (Oncorhynchus kisutch)
Invertebrate toxicity :6000 ug/L48 hours EC50(Tmmobilization)Water flea (Daphnia magna)
Algal toxicity :9400 ug/L 8 hours EC50(Growth)Green algae(Selenastrum Capricornutum).

Persistence and degradability: --


Bioaccumulative potential: --
Mobility in soil:--
Other adverse effects:--

13. Waste disposal measures:


Methods of waste disposal:--
Waste from residues/unused products:
Dispose of according to all federal, state and local applicable regulations. Where possible
recycling is preferred to disposal or incineration.

14. Transport information:


United Nations number (UN No) : 1294
UN Proper shipping name:--
Transport hazard class(es): 3
Packing group:Ⅲ
Marine pollutant (Yes/No):--
Specific transport measures and precautionary conditions : --

15. Regulatory information:


Applicable regulations :
1. Labor safety and health law.
2. Regulations for labor safety and health installations.
3. Regulation of Labelling and Hazard Communication of Dangerous and Harmful Materials.
4. Methods and Facilities Standards for the Storage, Clearance and Disposal of Industrial Waste.

16. Other information:

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1. MERCK Index.
Literature 2. Globally Harmonized System of Classification and Labelling of Chemicals.
references 3. CNS 15030.
4. CNS 6864.
Organization Name: Toa Resin Corporation Limited
that prepared Address/telephone number: No. 15, Sun-Ming Rd., Hsin Chu Industry District,
the MSDS Hsin Chu, Taiwan, R.O.C. TAIWAN/+886-3-5981224
Prerson who
prepared the Title: Deputy Manager Name: Wei-Chiang Kao
MSDS
Date the
MSDS was May. 23th, 2017
prepared
「--」: N/A

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