ANSWER KEY

CHEMISTRY MATHS PHYSICS

Q.NO ANSWER Q.NO ANSWER Q.NO ANSWER
1 3 31 1 61 4
2 4 32 1 62 4
3 2 33 3 63 2
4 3 34 2 64 3
5 2 35 2 65 1
6 3 36 3 66 2
7 3 37 1 67 4
8 4 38 3 68 4
9 4 39 2 69 3
10 2 40 3 70 2
11 1 41 2 71 4
12 2 42 1 72 3
13 2 43 2 73 1
14 2 44 2 74 2
15 2 45 3 75 1
16 4 46 1 76 1
17 2 47 2 77 4
18 3 48 3 78 2
19 4 49 4 79 4
20 1 50 1 80 3
21 2 51 2 81 1
22 3 52 2 82 1
23 1 53 2 83 1
24 1 54 3 84 1
25 3 55 2 85 3
26 1 56 4 86 4
27 4 57 4 87 2
28 3 58 1 88 4
29 2 59 1 89 2
30 3 60 2 90 4
 CHEMISTRY
C–NH2 Br2 in C–NH2 ..
1. CCl4 
NH2
O  .. :
O O
Br
+ Br
Br

–H+ NH2
NH
O O
Br Br

2. HA(aq) H+(aq) + A–(aq)

Initially c 0 0
At equilib. c(1–) c c
(c) 2 (0.1 c) 2 0.01 c
Ka = = =
c (1  ) 0.9 c 0.9

0 .1 c 9 Ka
Ka = ; c= = 90 Ka.
9 0 .1

3. Among option (a) and (c), rate would be less in (a) (HNO 3 and HCl are both
strong acids). Among (a), (b) and (d), the conc. of TA is same but the conc.
of H+ will be 0.20 M in (a) and less than 0.20 M in (b) and (d) each. As
acetic acid is a weaker acid than HCO2H, the least rate of hydrolysis will be
with 0.1 M in TA and 0.20 M in CH3CO2H.
4. Conceptual
5. Conceptual
Alcoholic
6. R–OR + H–I  R–OH + R–I AgNO3
  AgI + R+ NO3
solution

Ether with one mole of methoxy group reacts with one mole of HI to form
one mole of CH3I, which can react with alcoholic AgNO3 to give 1 mole of
AgI precipitate. Similarly, 1 mole of ether with ‘n’ moles of methoxy group
reacts with ‘n’ moles of HI to give ‘n’ moles of AgI precipitate.
0.2063
Moles of organic compound =
168

0.2063 0.8658
Moles of AgI produced = n =
168 235

n = 3.

Sr. IIT-IZ-CO-SPARK_JEE_MAIN _Sol Page 2

7. Conceptual
8. Let total number of moles of Ni are x, out of which 96% are in +2 state and
4% are in +3 state.
Maintaining the electroneutrality,
 96   4 
 x  100 (2)   x  100 (3) =2

200 50
x= = = 0.98
204 51

9. Tributyl stannane reduces alkyl halide to corresponding alkane by free-radical

mechanism.


CIS: Me2C(CN)–N=N–C(CN)Me2 
  N2 + Me 2C(CN)

Me 2C(CN) + Bu3Sn–H  
Bu 3S n + Me2CH(CN)

Br . .
CPS: Bu3Sn
+ Bu3Sn–Br

. .
ring Bu3Sn–H + Bu3Sn
closure

Ease of formation of a five membered ring is greater than that of a six membered
ring.

10. – d[A] = k1[A]

dt 1  k 2 [A]

At high concentration of A ([A] >> k2), 1 + k2[A] ~ k2[A]

– d[A] = k1
= k.
dt k2

Thus, order of the reaction is zero.

At low concentration of A([A] << k2), 1 + k2[A] = 1

– d[A] = k1[A]
= k1[A]
dt 1

The order of the reaction is unity.

1.004  10 23
11. n= N
= = 1.
NA 6.023  1023 6
 PV 1 1 6
T= = 1
= = 73.08 K ~ 73 K.
nR  0.0821 0.0821
6

3RT 3  8.314  73
RMS = = = 9.1  105 ms 1 .
M 2  103

12. Conceptual
13. I2 + 2Na2S2O3  2NaI + Na2S4O6
Millimoles of Na2S2O3 consumed = 6.
Millimoles of I2 consumed = 3.
3I2 + 6NaOH  5NaI + NaIO3 + 3H2O
30  6
Millimole of I2 reacted with NaOH = = 12
2

Total millimole of I2 consumed in this reaction = 15.

15
Initial concentration of I2 = = 0.1 M.
150

14. Conceptual
O
CH2–OH O O O–C–CH3
3CH3–C–O–C–CH3
15. HO–CH2–CH–CH–CHO H3C–O–H2C CH CH–CHO
O
OH
(A) CH2–O–C–CH3

One mol of this compound can react with only 1 mol of HIO4. It is oxidised
by Br2/H2O to give carboxylic acid which forms a lactone ring of five
member on heating.

16. 6HCHO C6H12O6

c
c(1–)
6

c
c(1  ) 
M theoretical 30 6
= =
M observed 150 c

 = 0.96.
 K2Cr2O7
17. (CH3)3C–CH2–CH2–OH (CH3)3C–CH2–COOH
SOCl2
(CH3)3C–CH2–COCl
(A) (B)
2(CH3)2NH

CH3 O
LiAlH4
(CH3)3C–CH2–CH2–N–CH3 (CH3)3C–CH2–C–N(CH3)2
(P) (C)

18. Conceptual
19. Conceptual
20. Conceptual
21. NH 2  is angular while N3 is linear. So bond angle increases in this convention .
In the remaining cases bond angle decreases
22. During partial hydrolysis XeF6 convents to XeOF4  sp3d 2  or XeO2 F2  sp3d 

23. AgBr is photosensitive and give image when exposed light

24. CO act as reducing agent to below 10000 C while carbon act as reducing agent
above 10000 C .
25. On adding excess slaked lime temporary hard water becomes permanent hard
water.
26. 2 AgClO3  Cl2  2 AgCl  2ClO2  O2

27. In  CH 3 3 N  B  CH 3 3 the dative bond is weaker since Boron accept electron

pair weakly due to electron releasing effect of methyl groups and steric hindrance
28. Due to back bonding from fluorine to silica Si-F bond has double bond character
and is stronger
29. The colours observed red, blue, green and violet are complimentary colours of
green, orange, red and yellow so the order of energy of these radiations is
a>d>b>c
30. Smaller the cation more the hydration energy. Though Zn 2 ion is smaller than
Ni 2 , due to extra crystal field stabilization energy Ni 2 has more hydration
energy.
 MATHS
31. Lt f  x   f  0
x 0
2 2 2
32. 
a  b  b  c  c  a  0  3  2 a.b  b.c  c.a  0 
abc  0
2a  5b  5c  3 a  3

5a  9b  9c  4 a  4
33. Augmented matrix
1 2 1 1  1 2 1 1  1 2 1 1 
 1 3 4 k   0 1 3 k  1   0 1 3 k  1 
1 5 10 k 2  0 3 9 k 2  1 0 0 0 2
k  3k  2

It has a solution when k 2  3k  2  0

 
sin 1 x    sin 1 x
2  4
34.    sin 1 xdx   dx
 
2
35. Conceptual
36. Let di = xi -8
2
2 2 1 2 1  9
     d    di  
x d 18 i  18  4
3
x
2
37. Conceptual
1 1 1
1 1  1
38.    1 1 1 
             25d
  
1   1   1    abcd

39. Conceptual
1
 sin 2  cos 2 x  sin 2 2 x
x  cos 4 x  sin 2 x cos 2 x 
40. y  4
sin 4 x  cos 4 x  sin 2 x.cos 2 x 1 2
1  sin 2 x
4
 1  y  cos 2 2 x  4cox 2 x  3 y  1  0
∆>0
3 y2  2 y  5  0
5
  y 1
3
41.    
V  aX b X a  aX b X b

V   b  a 1  a.b    b  a 
42. Clearly 2 side are x  2 y  1  0 and x  y  0
 Orthocenter lies on x-2y+1=0
Given le right angled at B
1 5 2
Circum radius  AC 
2 3
 3  x  1 2
 1
2  x   1
 2 3
43. f(x)  x 1  x  1   0
 3 1 x  2
 2  x  1

f 1  x  D.N.E at x=-1, 0, 1
44. Conceptual
dt g1  x  t2
45. t 
dx g  x g x
1 dt 1 g  x
1
1
  
t dx t g  x g  x
2

1
Let  z
t
dz g  x 
1
1
  Z I .F  g  x 
dx g  x g  x
g  x
Solutionis Z .g  x  x  c   xc
t
46. f  x     x   2 x  3 x  ......   nx 
1 1 1
Period of f  x  L.C.M 1, , ,....   1
 2 3 n
  
47. f  A  sin  2sin 1   A    sin 2 A
 2 

  2
2
 A f  x .sin 2 A dx   A sin 2 A dA    sin t dt 
2 2

0 0 0
4
48. Total No. of tickets =15+15=30
49. Conceptual
50. A 1  3t ,3  t ,  2  t 
B  3  3 ,3  2 ,5  4  are two points on given line
DR’s of AB are one proportional to 7, 4, -1
51. Conceptual
52. Conceptual
53. f  0   0, f  1  0   lies in  1, 0 
1
 tan 1      cot 1 
 
54. favourable cases are (1,1) (1,2) (2,1)
Probability = 3
36
 3
55. Equation of normal at  is 2 x sec   y cos ec  1It passes through  , 2     
2 4  
S.D = (distance from p(θ) to centre ) – radius
3 1

2
56. Using L.M.V theorem
57. Conceptual
58. Conceptual
1 1
1
59. Dr   1  x
0
50 101
 
dx  x 1  x 50 101
  0   x 101 1  x
0
50 100
  50 x dx
49

  
  5050  1  x50 x50  1  1 dx  Nr  5050 Dr
0

Nr
  5051
Dr
60. Conceptual
PHYSICS
61. In positive half cycle, diode becomes forward biased and conducting, capacitor
will be charged until voltage across it becomes peak value. In negative half
cycle, diode becomes reverse biased and no charge can flow through it. Hence
capacitor cannot discharge.
62. Comment for discussion. In the ideal case that we normally consider each
collision transfers twice the magnitude of its normal momentum. On the face
EFGH, it transfers only half of that.
63. Conceptual

64.
0 I
d  B  da    dr  L
2 r
x L
 IL dr  o IL  L
 o   ln 1  
2 x
r 2  x

Let l is the distance between two wires. Net flux through the loop is zero when
A and B carry currents in opposite directions and  A   B
 o  2 L  L  o (1) L  L 
ln  1    ln 1 
2  L 2  L  l 

 L  L 2L
 2ln 2  ln  1   1  4l 
 L  l Ll 3
nRT dV 3 dT v 3 T
PdV  nCv dT  dV  nCv dT    ln 2  ln 2  V T 3/2
65. V V 2 T v1 2 T1
V 2  CT 3 . where C is constant

2r 1
66.   r   l 
 2
 l  2r
l
 2
r

2 4 R
67. For cm of B, V  rw   2 R  
T T
1 1
KEB  MV 2  I c 2
2 2
1 2 1 MR 2 V 2
 MV   2
2 2 2 R
2
3  4 R 
 M 
4  T 

12 2 R 2

T2
68. At ‘O’, PE is same in both the orbits but KE may be different due to difference
in total energies.
69. In positions(1) and (2), PE of interaction between wire and loop is same
 U  0  work done is zero. According to same reason, W2  0 .
70. Conceptual
1  1 1
71.     1     5
f  R1 R2 

 1 1
 5  1.5  1    ....1
 R1 R2 

In liquid,
  
1  1.5   1 1
1
  1   
f 4  R R2 
  1
3

4/3  1.5  4 / 3   1 1
P1   4 / 3     .......  2
f  4 / 3   R1 R2 

1 5 0.5
 1
2 p 4 1 
3  8 
5
p1  D
3
1MSD
72. Least count 
N
1MSD
0.1mm 
20

F2
73. W , here F is same for both the springs since they are in series.
2K
W1 K 2 3
 
W2 K1 2

74. Net external force on the system =0  acm  0 . For the system, KEi  0 and at
maximum extension, KE f  0
F F
m
3m
x1
x2

1 2
Wext    PE   Fx1  Fx2  k  x1  x2 
2
2F
 x1  x2   xmax in spring
K
75. In steady state, VL  0  2 R,2 R resistances become ineffective as they will be
short circuited. Charge on capacitor is constant and no current flows through that
E
I
2R
branch. R and R will be in series. Current through the cell
E
Vc  VR  IR 
2
y 
76. For proper resolution,  1.22
D d

Where y=1mm,  =500nm, d=3mm

Dm
Dmax=5m.
77. At t =2 seconds, the position of both pulses are separately given by fig. (a) and
fig. (b) : the superposition of both pulses is given by fig. (c)

78.
In the first case K.E. of H-atom increases due to recoil whereas in the accond
case K.E decreass due recoil but E1  KE1  E2  KE2
1 2 2I
79. I   0 E C or E0 
2 0  0C

2X 4
 E0 
8.8 X 10 12 X 3 X 108
 55 NC 1
80.
r 3
 tan 37 0 
8 4
r  6m
F   P0  hpg   r 2  105  10(800)10    36  1.8(36) (105 )  2  107 N

a .b
Projection of a onb a
81.  b  7/5
Projection of b on a b .a b
a
82. V  2n  l2  l1  : for second resonance, water level in the tube has to be decreased.
For that, reservoir has to be descended down to equalize the water levels in both
tube and reservoir.
83.

3
84. I I0
4
3
I 0 cos 2   / 2   I0
4
3
cos  / 2  
2
 / 2   300
 
  600  
3 6

As it is formed between 5th maxima and 6th minima

 x 
 31
5  
6 6
31
   2  1  t
6
31
t substituting t  9.3  m
3  2  1 
85. After tow hours
No No
x: y  :  1:1
2 2
No 3 No
Four hours  :  1: 3
4 4
No 7 No
Six hours  :  1: 7
8 8
Here it is 1: 4
So t  4 hrs  6hrs
86. In general R (rate of collection ) =vA cos θ.
Where θ is the angle between the velocity of the rain and the normal to the cross
section A of the vessel.
R  vA cos 00  vA
When the wind blows, R’=v’A cos θ, where v’ is the new velocity of rain. Now
v '  u2  v2
v
And cos  
u2  v2
R '  v ' A cos 
 vA  R
87. r  1  x
For diamagnetic substance r  1   is negative.
88. Power factor cos ∅ =R/Z
If R is constant, then cos ∅ ∝ 1
Z
Z cos 1 1/ 4 1
 1     Z 2  2 Z1
Z 2 cos 2 1/ 2 2
2 Z 1  Z1
Percentage change  X 100  100 0 0
Z1
89. Follow color coding Table
1 2
KE TE  PE TE KA
90. Required ratio R    1 2 2
 1  n2  1
PE PE PE 1  A
K 
2  n